Patent Publication Number: US-2023149226-A1

Title: Method and apparatus for producing a zoned and/or layered substrate

Description:
TECHNICAL FIELD 
     The present disclosure relates to methods and apparatuses that can produce a zoned and/or layered substrate and such substrates. More specifically, the present disclosure relates to foam-forming methods and headboxes that can produce a zoned and/or layered substrate and such substrates. 
     BACKGROUND OF THE DISCLOSURE 
     Current commercial personal care products, such as diapers, diaper pants, training pants, and adult incontinence products, typically include different components to provide an absorbent structure that are each typically prepared from different processing lines using different raw materials. Each component, such as the acquisition material (or surge), absorbent core, and core wrap (or distribution layer) performs well for its designed purposes. However, the compilation of each component on a commercial manufacturing line requires that these separate materials be bonded to one another, such as through the use of adhesives. The bonding interface can inhibit performance properties of the overall structure in comparison to its designed function and performance. For example, an adhesive interface between components in an absorbent composite can resist body fluid penetrating from one component to the other, which can provide a negative impact on fluid intake and distribution properties of an absorbent product. Not only can such an adhesive interface reduce fluid handling properties of specific structures within an absorbent composite, but it can also it negatively affect dry product properties, such as softness, flexibility, comfort and fit, etc. Similar issues can exist for layered or zoned products, for example, such as, tissues, wipes, and/or wipers. For example, adhesive bonding between adjacent plies in a tissue product can reduce softness of the tissue product. Thermal bonding and/or pressure bonding are two other techniques that can be used to combine two separate materials at discrete points. While such methods may not reduce softness as much adhesive bonding of separate components, such bonding techniques may still provide some negative impact on fluid handling properties at such bonded locations. 
     In addition, current manufacturing practices of creating separate components for an absorbent composite often do not provide the flexibility to provide zoned structural components that can provide enhanced performance within an absorbent structure and higher raw material efficiency or do not provide adequate control over the gradient between adjacent zones of a zoned substrate. 
     Thus, there exists a need to develop a method and apparatus for creating a zoned and/or layered substrate. There is also a need to develop a method and apparatus for creating a zoned substrate that can provide enhanced control of the gradient between adjacent zones of a zoned substrate. There is also a need to develop multi-layered structures without the use of adhesive materials between the layers and that can control the gradient between adjacent layers. There is also a need to develop multi-layered structures that include zoned substrates without the use of adhesive materials between the layers. 
     SUMMARY OF THE DISCLOSURE 
     In one embodiment, a method for manufacturing a substrate is provided. The method can include providing a first supply of fibers, providing a second supply of fibers, and providing a headbox. The headbox can include a machine direction, a cross-direction, and a first cross-directional divider. The first cross-directional divider can separate a first zone of the headbox from a second zone of the headbox in a cross-directional manner. The method can further include transferring the first supply of fibers and the second supply of fibers to the headbox. The method can also include transferring the first supply of fibers and the second supply of fibers through the headbox to provide the substrate. 
     In another embodiment, a divider for a headbox is provided. The headbox can include a cross direction and a machine direction. The divider can include a first surface and a second surface. The second surface can be opposite from the first surface. The divider can include a width defined in the cross direction. The divider can include a length defined in the machine direction. The divider can include a first cross-directional divider extending away from the first surface. The first cross-directional divider can include a cross-directional thickness and a machine-directional length. 
     In yet another embodiment, a headbox for manufacturing a substrate is provided. The headbox can include a machine direction and a cross direction. The headbox can further include an inlet, an outlet, an internal chamber, and a divider. The divider can at least partially be within the internal chamber. The divider can include a first surface and a second surface. The second surface can be opposite from the first surface. The divider can include a width defined in the cross direction. The divider can include a length defined in the machine direction. The divider can further include a first cross-directional divider extending away from the first surface of the divider. The first cross-directional divider can include a cross-directional thickness and a machine-directional length. The divider can separate a first z-directional layer of the headbox from a second z-directional layer of the headbox. The first cross-directional divider separates a first zone of the headbox from a second zone of the headbox in a cross-directional manner. The first zone and the second zone can be in the first z-directional layer. 
     In still another embodiment, a method for manufacturing a substrate including a first layer and a second layer is provided. The method can include providing a first supply of fibers. The method can include providing a supply of particulates. The method can also include providing a headbox. The headbox can include a machine direction, a cross-direction, and a z-direction. The z-direction can be perpendicular to a plane defined by the machine direction and the cross-direction. The headbox can also include a divider. The divider can include a first surface, a second surface opposite the first surface, a width extending in the cross-direction, and a length extending in the machine direction. The divider can separate a first z-directional layer of the headbox from a second z-directional layer of the headbox. The method can further include setting a z-directional position of the divider in the headbox to provide a target relative thickness setting of the second z-directional layer of the headbox. The method can also include transferring the first supply of fibers and the supply of particulates to the headbox such that the first supply of fibers enter the first z-directional layer of the headbox and the supply of particulates enter the second z-directional layer of the headbox. The method can additionally include controlling the first supply of fibers and the supply of particulates through the headbox to a forming surface such that a relative thickness of the second layer of the substrate is provided with less than 20% variation of the target relative thickness setting of the second z-directional layer of the headbox. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
       A full and enabling disclosure thereof, directed to one of ordinary skill in the art, is set forth more particularly in the remainder of the specification, which makes reference to the appended figures in which: 
         FIG.  1    is a side plan view of an exemplary headbox including a divider that can provide a zoned substrate of the present disclosure. 
         FIG.  2    is a top, perspective view of a divider, such as utilized in  FIG.  1   . 
         FIG.  3    is a cross-section view taken along line  3 - 3  from  FIG.  2   . 
         FIG.  4    is a top plan view of an exemplary inlet section to the headbox of  FIG.  1     
         FIG.  5 A  is a cross-section view of an exemplary zoned substrate of the present disclosure that can be provided by the headbox and divider as illustrated in  FIG.  4   . 
         FIG.  5 B  is a cross-section view of an alternative exemplary zoned substrate of the present disclosure that can be provided by the headbox and divider as illustrated in  FIG.  4   . 
         FIG.  5 C  is a cross-section view of yet another alternative exemplary zoned substrate of the present disclosure that can be provided by the headbox and divider as illustrated in  FIG.  4   . 
         FIG.  6    is a cross-section view of an alternative divider that can be utilized in a headbox, such as illustrated in  FIG.  1   . 
         FIG.  7    is a cross-section view of another zoned substrate of the present disclosure that can be provided by the headbox and divider as illustrated in  FIGS.  1  and  6   . 
         FIG.  8 A  is a photograph of an exemplary zoned substrate produced by a headbox and divider as illustrated in  FIG.  4   . 
         FIG.  8 B  is a photograph of an exemplary zoned substrate produced by a divider with no cross-directional dividers. 
         FIG.  8 C  is a photograph of a zoned substrate that was produced by a headbox with no divider. 
         FIG.  9 A  is a microCT image of a cross-section of the substrate of  FIG.  8 A . 
         FIG.  9 B  is a microCT image of a cross-section of the substrate of  FIG.  8 B . 
         FIG.  9 C  is a microCT image of a cross-section of the substrate of  FIG.  8 C . 
         FIG.  10    is a graph depicting fluid distribution versus product length for exemplary codes. 
         FIG.  11    is an exemplary analysis used in the Purity Gradient Test Method. 
         FIG.  12    is an exemplary analysis used in the Layer Relative Thickness Test Method. 
     
    
    
     DETAILED DESCRIPTION OF THE DISCLOSURE 
     The present disclosure is directed to methods and apparatuses that can produce a zoned and/or layered substrate and such substrates. While the present disclosure provides examples of zoned and/or layered substrates manufactured through foam-forming, it is contemplated that the methods and apparatuses described herein may be utilized to benefit wet-laid and/or air-laid manufacturing processes. 
     Each example is provided by way of explanation and is not meant as a limitation. For example, features illustrated or described as part of one embodiment or figure can be used on another embodiment or figure to yield yet another embodiment. It is intended that the present disclosure include such modifications and variations. 
     When introducing elements of the present disclosure or the preferred embodiment(s) thereof, the articles “a”, “an”, “the” and “said” are intended to mean that there are one or more of the elements. The terms “comprising”, “including” and “having” are intended to be inclusive and mean that there may be additional elements other than the listed elements. As used herein, the terminology of “first,” “second,” “third”, etc. does not designate a specified order, but is used as a means to differentiate between different occurrences when referring to various features in the present disclosure. Many modifications and variations of the present disclosure can be made without departing from the spirit and scope thereof. Therefore, the exemplary embodiments described herein should not be used to limit the scope of the invention. 
     Definitions 
     As used herein, the term “foam formed product” means a product formed from a suspension including a mixture of a solid, a liquid, and dispersed gas bubbles. 
     As used herein, the term “foam forming process” means a process for manufacturing a product involving a suspension including a mixture of a solid, a liquid, and dispersed gas bubbles. 
     As used herein, the term “foaming fluid” means any one or more known fluids compatible with the other components in the foam forming process. Suitable foaming fluids include, but are not limited to, water. 
     As used herein, the term “foam half life” means the time elapsed until the half of the initial frothed foam mass reverts to liquid water. 
     As used herein, the term “layer” refers to a structure that provides an area of a substrate in a z-direction of the substrate that is comprised of similar components and structure. 
     As used herein, the term “nonwoven web” means a web having a structure of individual fibers or threads which are interlaid, but not in an identifiable manner as in a knitted web. 
     As used herein, unless expressly indicated otherwise, when used in relation to material compositions the terms “percent”, “%”, “weight percent”, or “percent by weight” each refer to the quantity by weight of a component as a percentage of the total except as whether expressly noted otherwise. 
     The term “personal care absorbent article” refers herein to an article intended and/or adapted to be placed against or in proximity to the body (i.e., contiguous with the body) of the wearer to absorb and contain various liquid, solid, and semi-solid exudates discharged from the body. Examples include, but are not limited to, diapers, diaper pants, training pants, youth pants, swim pants, feminine hygiene products, including, but not limited to, menstrual pads or pants, incontinence products, medical garments, surgical pads and bandages, and so forth. 
     The term “ply” refers to a discrete layer within a multi-layered product wherein individual plies may be arranged in juxtaposition to each other. 
     The term “plied” or “bonded” or “coupled” refers herein to the joining, adhering, connecting, attaching, or the like, of two elements. Two elements will be considered plied, bonded or coupled together when they are joined, adhered, connected, attached, or the like, directly to one another or indirectly to one another, such as when each is directly bonded to intermediate elements. The plying, bonding or coupling of one element to another can occur via continuous or intermittent bonds. 
     The term “superabsorbent material” as used herein refers to water-swellable, water-insoluble organic or inorganic materials including superabsorbent polymers and superabsorbent polymer compositions capable, under the most favorable conditions, of absorbing at least about 10 times their weight, or at least about 15 times their weight, or at least about 25 times their weight in an aqueous solution containing 0.9 weight percent sodium chloride. 
     The term “zone” as used herein with respect to a substrate refers to a particular area of a substrate in the cross-direction of the substrate that is comprised of similar components and structure. 
     Method and Apparatus 
     In one embodiment, the present disclosure relates to a foam forming process and associated method that can be employed to manufacturing a zoned substrate  10 ,  110 ,  210 ,  310 .  FIG.  1    provides an exemplary apparatus  12  that can be used as part of a foam forming process to manufacture a foam formed product. The apparatus  12  of  FIG.  1    can form part of a foam forming process that can include a pulper that can mix fibers, a fluid, and a surfactant, as will be discussed in greater detail below. The pulper can mix (e.g., agitates) the surfactant and the fluid (e.g., water) with air to create a foam. The pulper also mixes the foam with the fibers to create a foam suspension of fibers in which the foam holds and separates the fibers to facilitate a distribution of the fibers within the foam (e.g., as an artifact of the mixing process in the pulper). Uniform fiber distribution can promote desirable nonwoven material characteristics including, for example, strength and the visual appearance of quality. 
     Foaming Fluid 
     The foam forming processes as described herein can include a foaming fluid. In some embodiments, the foaming fluid can comprise between about 85% to about 99.99% of the foam (by weight). In some embodiments, the foaming fluid used to make the foam can comprise at least about 85% of the foam (by weight). In certain embodiments, the foaming fluid can comprise between about 90% and about 99.9% % of the foam (by weight). In certain other embodiments, the foaming fluid can comprise between about 93% and 99.5% of the foam or even between about 95% and about 99.0% of the foam (by weight). In preferred embodiments, the foaming fluid can be water, however, it is contemplated that other processes may utilize other foaming fluids. 
     Foaming Surfactant 
     The foam forming processes as described herein can utilize one of more surfactants. The fibers and surfactant, together with the foaming liquid and any additional components, can form a stable dispersion capable of substantially retaining a high degree of porosity for longer than the drying process. In this regard, the surfactant is selected so as to provide a foam having a foam half life of at least 2 minutes, more desirably at least 5 minutes, and most desirably at least 10 minutes. A foam half life can be a function of surfactant types, surfactant concentrations, foam compositions/solid level and mixing power/air content in a foam. The foaming surfactant used in the foam can be selected from one or more known in the art that are capable of providing the desired degree of foam stability. In this regard, the foaming surfactant can be selected from anionic, cationic, nonionic and amphoteric surfactants provided they, alone or in combination with other components, provide the necessary foam stability, or foam half life. As will be appreciated, more than one surfactant can be used, including different types of surfactants, as long as they are compatible, and more than one surfactant of the same type. For example, a combination of a cationic surfactant and a nonionic surfactant or a combination of an anionic surfactant and a nonionic surfactant may be used in some embodiments due to their compatibilities. However, in some embodiments, a combination of a cationic surfactant and an anionic surfactant may not be satisfactory to combine due to incompatibilities between the surfactants. 
     Anionic surfactants believed suitable for use with the present disclosure include, without limitation, anionic sulfate surfactants, alkyl ether sulfonates, alkylaryl sulfonates, or mixtures or combinations thereof. Examples of alkylaryl sulfonates include, without limitation, alkyl benzene sulfonic acids and their salts, dialkylbenzene disulfonic acids and their salts, dialkylbenzene sulfonic acids and their salts, alkylphenol sulfonic acids/condensed alkylphenol sulfonic acids and their salts, or mixture or combinations thereof. Examples of additional anionic surfactants believed suitable for use in the present disclosure include alkali metal sulforicinates, sulfonated glyceryl esters of fatty acids such as sulfonated monoglycerides of coconut oil acids, salts of sulfonated monovalent alcohol esters such as sodium oleylisethianate, metal soaps of fatty acids, amides of amino sulfonic acids such as the sodium salt of oleyl methyl tauride, sulfonated products of fatty acids nitriles such as palmitonitrile sulfonate, alkali metal alkyl sulfates such as sodium lauryl sulfate, ammonium lauryl sulfate or triethanolamine lauryl sulfate, ether sulfates having alkyl groups of 8 or more carbon atoms such as sodium lauryl ether sulfate, ammonium lauryl ether sulfate, sodium alkyl aryl ether sulfates, and ammonium alkyl aryl ether sulfates, sulphuric esters of polyoxyethylene alkyl ether, sodium salts, potassium salts, and amine salts of alkylnapthylsulfonic acid. Certain phosphate surfactants including phosphate esters such as sodium lauryl phosphate esters or those available from the Dow Chemical Company under the tradename TRITON are also believed suitable for use herewith. A particularly desired anionic surfactant is sodium dodecyl sulfate (SDS). 
     Cationic surfactants are also believed suitable for use with the present disclosure for manufacturing some embodiments of substrates. In some embodiments, such as those including superabsorbent material, cationic surfactants may be less preferable to use due to potential interaction between the cationic surfactant(s) and the superabsorbent material, which may be anionic. Foaming cationic surfactants include, without limitation, monocarbyl ammonium salts, dicarbyl ammonium salts, tricarbyl ammonium salts, monocarbyl phosphonium salts, dicarbyl phosphonium salts, tricarbyl phosphonium salts, carbylcarboxy salts, quaternary ammonium salts, imidazolines, ethoxylated amines, quaternary phospholipids and so forth. Examples of additional cationic surfactants include various fatty acid amines and amides and their derivatives, and the salts of the fatty acid amines and amides. Examples of aliphatic fatty acid amines include dodecylamine acetate, octadecylamine acetate, and acetates of the amines of tallow fatty acids, homologues of aromatic amines having fatty acids such as dodecylanalin, fatty amides derived from aliphatic diamines such as undecylimidazoline, fatty amides derived from aliphatic diamines such as undecylimidazoline, fatty amides derived from disubstituted amines such as oleylaminodiethylamine, derivatives of ethylene diamine, quaternary ammonium compounds and their salts which are exemplified by tallow trimethyl ammonium chloride, dioctadecyldimethyl ammonium chloride, didodecyldimethyl ammonium chloride, dihexadecyl ammonium chloride, alkyltrimethylammonium hydroxides, dioctadecyldimethylammonium hydroxide, tallow trimethylammonium hydroxide, trimethylammonium hydroxide, methylpolyoxyethylene cocoammonium chloride, and dipalmityl hydroxyethylammonium methosulfate, amide derivatives of amino alcohols such as beta-hydroxylethylstearylamide, and amine salts of long chain fatty acids. Further examples of cationic surfactants believed suitable for use with the present disclosure include benzalkonium chloride, benzethonium chloride, cetrimonium bromide, distearyldimethylammonium chloride, tetramethylammonium hydroxide, and so forth. 
     Nonionic surfactants believed suitable for use in the present disclosure include, without limitation, condensates of ethylene oxide with a long chain fatty alcohol or fatty acid, condensates of ethylene oxide with an amine or an amide, condensation products of ethylene and propylene oxides, fatty acid alkylol amide and fatty amine oxides. Various additional examples of non-ionic surfactants include stearyl alcohol, sorbitan monostearate, octyl glucoside, octaethylene glycol monododecyl ether, lauryl glucoside, cetyl alcohol, cocamide MEA, monolaurin, polyoxyalkylene alkyl ethers such as polyethylene glycol long chain (12-14C) alkyl ether, polyoxyalkylene sorbitan ethers, polyoxyalkylene alkoxylate esters, polyoxyalkylene alkylphenol ethers, ethylene glycol propylene glycol copolymers, polyvinyl alcohol, alkylpolysaccharides, polyethylene glycol sorbitan monooleate, octylphenol ethylene oxide, and so forth. 
     The foaming surfactant can be used in varying amounts as necessary to achieve the desired foam stability and air-content in the foam. In certain embodiments, the foaming surfactant can comprise between about 0.005% and about 5% of the foam (by weight). In certain embodiments the foaming surfactant can comprise between about 0.05% and about 3% of the foam or even between about 0.05% and about 2% of the foam (by weight). 
     Fibers 
     The foam suspension of fibers can provide one or more supply of fibers. In some embodiments, the fibers utilized herein can include natural fibers and/or synthetic fibers. In some embodiments, a fiber supply can include only natural fibers or only synthetic fibers. In other embodiments, a fiber supply can include a mixture of natural fibers and synthetic fibers. Some fibers being utilized herein can be absorbent, whereas other fibers utilized herein can be non-absorbent. Non-absorbent fibers can provide features for the substrates that are formed from the methods and apparatuses described herein, such as improved intake or distribution of fluids. 
     A wide variety of cellulosic fibers are believed suitable for use herein. In some embodiments, the fibers utilized can be conventional papermaking fibers such as wood pulp fibers formed by a variety of pulping processes, such as kraft pulp, sulfite pulp, bleached chemithermomechanical pulp (BCTMP), chemithermomechanical pulp (CTMP), pressure/pressure thermomechanical pulp (PIMP), thermomechanical pulp (TMP), thermomechanical chemical pulp (TMCP), and so forth. By way of example only, fibers and methods of making wood pulp fibers are disclosed in U.S. Pat. No. 4,793,898 to Laamanen et al.; U.S. Pat. No. 4,594,130 to Chang et al.; U.S. Pat. No. 3,585,104 to Kleinhart; U.S. Pat. No. 5,595,628 to Gordon et al.; U.S. Pat. No. 5,522,967 to Shet; and so forth. Further, the fibers may be any high-average fiber length wood pulp, low-average fiber length wood pulp, or mixtures of the same. Examples of suitable high-average length pulp fibers include softwood fibers, such as, but not limited to, northern softwood, southern softwood, redwood, red cedar, hemlock, pine (e.g., southern pines), spruce (e.g., black spruce), and the like. Examples of suitable low-average length pulp fibers include hardwood fibers, such as, but not limited to, eucalyptus, maple, birch, aspen, and the like. 
     Moreover, if desired, secondary fibers obtained from recycled materials may be used, such as fiber pulp from sources such as, for example, newsprint, reclaimed paperboard, and office waste. In a particularly preferred embodiment refined fibers are utilized in the tissue web such that the total amount of virgin and/or high average fiber length wood fibers, such as softwood fibers, may be reduced. 
     Regardless of the origin of the wood pulp fiber, the wood pulp fibers preferably have an average fiber length greater than about 0.2 mm and less than about 3 mm, such as from about 0.35 mm and about 2.5 mm, or between about 0.5 mm to about 2 mm or even between about 0.7 mm and about 1.5 mm. 
     In addition, other cellulosic fibers that can be used in the present disclosure includes nonwoody fibers. As used herein, the term “non-wood fiber” generally refers to cellulosic fibers derived from non-woody monocotyledonous or dicotyledonous plant stems. Non-limiting examples of dicotyledonous plants that may be used to yield non-wood fiber include kenaf, jute, flax, ramie and hemp. Non-limiting examples of monocotyledonous plants that may be used to yield non-wood fiber include cereal straws (wheat, rye, barley, oat, etc.), stalks (corn, cotton, sorghum, Hesperaloe funifera, etc.), canes (bamboo, sisal, bagasse, etc.) and grasses (miscanthus. esparto, lemon, sabai, switchgrass, etc). In still other certain instances non-wood fiber may be derived from aquatic plants such as water hyacinth, microalgae such as Spirulina, and macroalgae seaweeds such as red or brown algae. 
     Still further, other cellulosic fibers for making substrates herein can include synthetic cellulose fiber types formed by spinning, including rayon in all its varieties, and other fibers derived from viscose or chemically-modified cellulose such as, for example, those available under the trade names LYOCELL and TENCEL. Some chemically-modified cellulose fibers that can be employed in substrates described herein can include chemically crosslinked pulp fibers, such as CMC535 fibers produced by International Paper. 
     In some embodiments, the non-woody and synthetic cellulosic fibers can have fiber length greater than about 0.2 mm including, for example, having an average fiber size between about 0.5 mm and about 50 mm or between about 0.75 and about 30 mm or even between about 1 mm and about 25 mm. Generally speaking, when fibers of relatively larger average length are being used, it may often be advantageous to modify the amount and type of foaming surfactant. For example, in some embodiments, if fibers of relatively larger average length are being used, it may be beneficial to utilize relatively higher amounts of foaming surfactant in order to help achieve a foam with the required foam half life. 
     Additional fibers that may be utilized in the present disclosure include fibers that are resistant to the forming fluid, namely those that are non-absorbent and whose bending stiffness is substantially unimpacted by the presence of forming fluid. As noted above, typically the forming fluid will comprise water. By way of non-limiting example, water-resistant fibers include fibers such as polymeric fibers comprising polyolefin, polyester (PET), polyamide, polylactic acid, or other fiber forming polymers. Polyolefin fibers, such as polyethylene (PE) and polypropylene (PP), are particularly well suited for use in the present disclosure. In some embodiments, non-absorbent fibers can be recycled fibers, compostable fibers, and/or marine degradable fibers. In addition, highly cross-linked cellulosic fibers having no-significant absorbent properties can also be used herein. In this regard, due to its very low levels of absorbency to water, water resistant fibers do not experience a significant change in bending stiffness upon contacting an aqueous fluid and therefore are capable of maintain an open composite structure upon wetting. The fiber composition and diameter of a fiber can contribute to enhanced bending stiffness. For example, a PET fiber has a higher bending stiffness than a polyolefin fiber whether in dry or wet states due to composition. The higher the fiber diameter, the higher the bending stiffness a fiber exhibits. Water resistant fibers desirably have a water retention value (WRV) less than about 1 and still more desirably between about 0 and about 0.5. In certain aspects, it is desirable that the fibers, or at least a portion thereof, include non-absorbent fibers. 
     The synthetic and/or water resistant fibers can have fiber length greater than about 0.2 mm including, for example, having an average fiber size between about 0.5 mm and about 50 mm or between about 0.75 and about 30 mm or even between about 1 mm and about 25 mm. 
     In some embodiments, the synthetic and/or water resistant fibers can have a crimped structure to enhance bulk generation capability of the foam formed fibrous substrate. For example, a PET crimped staple fiber may be able to generate a higher caliper (or result in a low sheet density) in comparison to a PET straight staple fiber with the same fiber diameter and fiber length. 
     In some embodiments, the total content of fibers, can comprise between about 0.01% to about 10% of the foam (by weight), and in some embodiments between about 0.1% to about 5% of the foam (by weight). 
     Binder 
     In some embodiments, a foam as provided herein can include binder materials. Binder materials that may be used in the present disclosure can include, but are not limited to, thermoplastic binder fibers, such as PET/PE bicomponent binder fiber, and water-compatible adhesives such as, for example, latexes. In some embodiments, binder materials as used herein can be in powder form, for example, such as thermoplastic PE powder. Importantly, the binder can comprise one that is water insoluble on the dried substrate. In certain embodiments, latexes used in the present disclosure can be cationic or anionic to facilitate application to and adherence to cellulosic fibers that can be used herein. For instance, latexes believed suitable for use include, but are not limited to, anionic styrene-butadiene copolymers, polyvinyl acetate homopolymers, vinyl-acetate ethylene copolymers, vinyl-acetate acrylic copolymers, ethylene-vinyl chloride copolymers, ethylene-vinyl chloride-vinyl acetate terpolymers, acrylic polyvinyl chloride polymers, acrylic polymers, nitrile polymers, as well as other suitable anionic latex polymers known in the art. Examples of such latexes are described in U.S. Pat. No. 4,785,030 to Hager, U.S. Pat. No. 6,462,159 to Hamada, U.S. Pat. No. 6,752,905 to Chuang et al. and so forth. Examples of suitable thermoplastic binder fibers include, but are not limited to, monocomponent and multi-component fibers having at least one relatively low melting thermoplastic polymer such as polyethylene. In certain embodiments, polyethylene/polypropylene sheath/core staple fibers can be used. Binder fibers may have lengths in line with those described herein above in relation to the synthetic cellulosic fibers. 
     Exemplary commercially available binder fibers include T 255 binder fiber with a 6 or 12 mm fiber length and a 2.2 dtex fiber diameter from Trevia or WL Adhesion C binder fiber with a 4 mm fiber length and a 1.7 dtex fiber diameter from FiberVisions. 
     Binders in liquid form, such as latex emulsions, can comprise between about 0% and about 10% of the foam (by weight). In certain embodiments the non-fibrous binder can comprise between about 0.1% and 10% of the foam (by weight) or even between about 0.2% and about 5% or even between about 0.5% and about 2% of the foam (by weight). Binder fibers, when used, may be added proportionally to the other components to achieve the desired fiber ratios and structure while maintaining the total solids content of the foam below the amounts stated above. As an example, in some embodiments, binder fibers can comprise between about 0% and about 50% of the total fiber weight, and more preferably, between about 5% to about 40% of the total fiber weight in some embodiments. 
     Foam Stabilizers 
     The foam may optionally also include one or more foam stabilizers known in the art and that are compatible with the components of the foam and further do not interfere with the hydrogen bonding as between the cellulosic fibers. Foam stabilizing agents believed suitable for use in the present disclosure, without limitation, one or more zwitterionic compounds, amine oxides, alkylated polyalkylene oxides, or mixture or combinations thereof. Specific examples of foam stabilizers includes, without limitation, cocoamine oxide, isononyldimethylamine oxide, n-dodecyldimethylamine oxide, and so forth. 
     In some embodiments, if utilized, the foam stabilizer can comprise between about 0.01% and about 2% of the foam (by weight). In certain embodiments, the foam stabilizer can comprise between about 0.05% and 1% of the foam or even between about 0.1 and about 0.5% of the foam (by weight). 
     Additional Additives 
     In the methods as described herein, the foam forming process can include adding one or more additional additives. For example, one additional additive that can be added during the formation of the substrates  10  as described herein can be a superabsorbent materials (SAM). SAM is commonly provided in a particulate form and, in certain aspects, can comprise polymers of unsaturated carboxylic acids or derivatives thereof. These polymers are often rendered water insoluble, but water swellable, by crosslinking the polymer with a di- or polyfunctional internal crosslinking agent. These internally cross-linked polymers are at least partially neutralized and commonly contain pendant anionic carboxyl groups on the polymer backbone that enable the polymer to absorb aqueous fluids, such as body fluids. Typically, the SAM particles are subjected to a post-treatment to crosslink the pendant anionic carboxyl groups on the surface of the particle. SAMs are manufactured by known polymerization techniques, desirably by polymerization in aqueous solution by gel polymerization. The products of this polymerization process are aqueous polymer gels, i.e., SAM hydrogels that are reduced in size to small particles by mechanical forces, then dried using drying procedures and apparatus known in the art. The drying process is followed by pulverization of the resulting SAM particles to the desired particle size. Examples of superabsorbent materials include, but are not limited to, those described in U.S. Pat. No. 7,396,584 Azad et al., U.S. Pat. No. 7,935,860 Dodge et al., US2005/5245393 to Azad et al., US2014/09606 to Bergam et al., WO2008/027488 to Chang et al. and so forth. In addition, in order to aid processing, the SAM may be treated in order to render the material temporarily non-absorbing during the formation of the foam and formation of the highly-expanded foam. For example, in one aspect, the SAM may be treated with a water-soluble protective coating having a rate of dissolution selected such that the SAM is not substantially exposed to the aqueous carrier until the highly-expanded foam has been formed and drying operations initiated. Alternatively, in order to prevent or limit premature expansion during processing, the SAM may be introduced into the process at low temperatures. 
     In some embodiments incorporating SAM, the SAM can comprise between about 0% and about 40% of the foam (by weight). In certain embodiments, SAM can comprise between about 1% and about 30% of the foam (by weight) or even between about 10% and about 30% of the foam (by weight). 
     Other additional agents can include one or more wet strength additives that can be added to the foam in order to help improve the relative strength of the ultra-low density composite cellulosic material. Such strength additives suitable for use with paper making fibers and the manufacture of paper tissue are known in the art. Temporary wet strength additives may be cationic, nonionic or anionic. Examples of such temporary wet strength additives include PAREZ™ 631 NC and PAREZ® 725 temporary wet strength resins that are cationic glyoxylated polyacrylamides available from Cytec Industries, located at West Paterson, N.J. These and similar resins are described in U.S. Pat. No. 3,556,932 to Coscia et al. and U.S. Pat. No. 3,556,933 to Williams et al. Additional examples of temporary wet strength additives include dialdehyde starches and other aldehyde containing polymers such as those described in U.S. Pat. No. 6,224,714 to Schroeder et al.; U.S. Pat. No. 6,274,667 to Shannon et al.; U.S. Pat. No. 6,287,418 to Schroeder et al.; and U.S. Pat. No. 6,365,667to Shannon et al., and so forth. 
     Permanent wet strength agents comprising cationic oligomeric or polymeric resins may also be used in the present disclosure. Polyamide-polyamine-epichlorohydrin type resins such as KYMENE 557H sold by Solenis are the most widely used permanent wet-strength agents and are suitable for use in the present disclosure. Such materials have been described in the following U.S. Pat. No. 3,700,623 to Keim; U.S. Pat. No. 3,772,076 to Keim; U.S. Pat. No. 3,855,158 to Petrovich et al.; U.S. Pat. No. 3,899,388to Petrovich et al.; U.S. Pat. No. 4,129,528 to Petrovich et al.; U.S. Pat. No. 4,147,586 to Petrovich et al.; U.S. Pat. No. 4,222,921 to van Eenam and so forth. Other cationic resins include polyethylenimine resins and aminoplast resins obtained by reaction of formaldehyde with melamine or urea. Permanent and temporary wet strength resins may be used together in the manufacture of composite cellulosic products of the present disclosure. Further, dry strength resins may also optionally be applied to the composite cellulosic webs of the present disclosure. Such materials may include, but are not limited to, modified starches and other polysaccharides such as cationic, amphoteric, and anionic starches and guar and locust bean gums, modified polyacrylamides, carboxymethylcellulose, sugars, polyvinyl alcohol, chitosan, and the like. 
     If used, such wet and dry strength additives can comprise between about 0.01 and about 5% of the dry weight of cellulose fibers. In certain embodiments, the strength additives can comprise between about 0.05% and about 2% of the dry weight of cellulose fibers or even between about 0.1% and about 1% of the dry weight of cellulose fibers. 
     Still other additional components may be added to the foam so long as they do not significantly interfere with the formation of the highly-expanded stable foam, the hydrogen bonding as between the cellulosic fibers or other desired properties of the web. As examples, additional additives may include one or more pigments, opacifying agents, anti-microbial agents, pH modifiers, skin benefit agents, odor absorbing agents, fragrances, thermally expandable microspheres, pulverized foam particles and so forth as desired to impart or improve one or more physical or aesthetic attributes. In certain embodiments the composite cellulosic webs may include skin benefit agents such as, for example, antioxidants, astringents, conditioners, emollients, deodorants, external analgesics, film formers, humectants, hydrotropes, pH modifiers, surface modifiers, skin protectants, and so forth. 
     When employed, miscellaneous additives desirably comprise less than about 2% of the foam (by weight) and still more desirably less than about 1% of the foam (by weight) and even less than about 0.5% of the foam (by weight). 
     In some embodiments, the solids content, including the fibers or particulates contained herein, desirably comprise no more than about 40% of the foam. In certain embodiments the cellulosic fibers can comprise between about 0.1% and about 5% of the foam or between about 0.2 and about 4% of the foam or even between about 0.5% and about 2% of the foam. 
     Formation of Foam 
     The foaming fluid and any other surfactant(s) or other fibers or agents is acted upon to form a foam. In some embodiments, the foaming fluid and other components are acted upon so as to form a porous foam having an air content greater than about 50% by volume and desirably an air content greater than about 60% by volume. In certain aspects, the highly-expanded foam is formed having an air content of between about 60% and about 95% and in further aspects between about 65% and about 85%. In certain embodiments, the foam may be acted upon to introduce air bubbles such that the ratio of expansion (volume of air to other components in the expanded stable foam) is greater than 1:1 and in certain embodiments the ratio of air:other components can be between about 1.1:1 and about 20:1 or between about 1.2:1 and about 15:1 or between about 1.5:1 and about 10:1 or even between about 2:1 and about 5:1. 
     The foam can be generated by one or more means known in the art. Examples of suitable methods include, without limitation, aggressive mechanical agitation, injection of compressed air, and so forth. Mixing the components through the use of a high-shear, high-speed mixer is particularly well suited for use in the formation of the desired highly-porous foams. Various high-shear mixers are known in the art and believed suitable for use with the present disclosure. High-shear mixers typically employ a tank holding the foam precursor and/or one or more pipes through which the foam precursor is directed. The high-shear mixers may use a series of screens and/or rotors to work the precursor and cause aggressive mixing of the components and air. In a particular embodiment, a tank is provided having therein one or more rotors or impellors and associated stators. The rotors or impellors are rotated at high speeds in order to cause flow and shear. Air may, for example, be introduced into the tank at various positions or simply drawn in by the action of the mixer. While the specific mixer design may influence the speeds necessary to achieve the desired mixing and shear, in certain embodiments suitable rotor speeds may be greater than about 500 rpm and, for example, be between about 1000 rpm and about 6000 rpm or between about 2000 rpm and about 4000 rpm. In certain embodiments, with respect to rotor based high-shear mixers, the mixer maybe run with the foam until the disappearance of the vortex in the foam or a sufficient volume increase is achieved. 
     In addition, it is noted the foaming process can be accomplished in a single foam generation step or in sequential foam generation steps. For example, in one embodiment, all of the components may be mixed together to form a slurry from which a foam is formed. Alternatively, one or more of the individual components may be added to the foaming fluid, an initial mixture formed (e.g. a dispersion or foam), after which the remaining components may be added to the initially foamed slurry and then all of the components acted upon to form the final foam. In this regard, the water and foaming surfactant may be initially mixed and acted upon to form an initial foam prior to the addition of any solids. Fibers may then be added to the water/surfactant foam and then further acted upon to form the final foam. As a further alternative, the water and fibers, such as a high density cellulose pulp sheet, may be aggressively mixed at a higher consistency to form an initial dispersion after which the foaming surfactant, additional water and other components, such as synthetic fibers, are added to form a second mixture which is then mixed and acted upon to form the foam. 
     The foam density of the foam can vary depending upon the particular application and various factors, including the fiber stock used. In some implementations, for example, the foam density of the foam can be greater than about 100 g/L, such as greater than about 250 g/L, such as greater than about 300 g/L. The foam density is generally less than about 800 g/L, such as less than about 500 g/L, such as less than about 400 g/L, such as less than about 350 g/L. In some implementations, for example, a lower density foam is used having a foam density of generally less than about 350 g/L, such as less than about 340 g/L, such as less than about 330 g/L. 
     Foam Forming Zoned and/or Layered Substrate 
     A first supply  14  of fibers can be transported to a headbox  16 , such as illustrated in  FIG.  1   , via conduit(s)  18 . Although one conduit  18  is illustrated in  FIG.  1    for transporting the first supply  14  of fibers to the headbox  16 , it is contemplated that more than one conduit  18  can supply the first supply  14  of fibers to the headbox  16 . A second supply  15  of fibers can also be transported to the headbox  16 . In some embodiments, the second supply  15  of fibers can include different fibers than the first supply  14  of fibers. In some embodiments, the second supply  15  of fibers can include the same fibers as the first supply  14  of fibers. In some embodiments, the second supply  15  of fibers can be provided from a foam slurry that is different from the foam slurry providing the first supply  14  of fibers in at least one characteristic. The second supply  15  of fibers can be transported to the headbox  16  via conduit  19 . It is contemplated that the second supply  15  of fibers can be transported to the headbox  16  in more than one conduit  19 . 
     The headbox  16  illustrated in  FIG.  1    can be a vertical twin-wire headbox  16 , as generally known in the art. The headbox  16  as illustrated in  FIG.  1    can include first and second foraminous elements  20 ,  22 . The first and second foraminous elements  20 ,  22  can help define an interior volume  24  of the headbox  16 . The headbox  16  can include an inlet  26  and an outlet  28 . A series of vacuum elements  30  can be disposed adjacent each foraminous elements  20 ,  22 . The vacuum elements  30  can help to dewater the foam that is delivered to the headbox  16  and deposited on the foraminous elements  20 ,  22 . 
     The headbox  16  can include a machine direction  32 , a cross-direction  34 , and a z-direction  35  perpendicular to a plane defined by the machine direction  32  and the cross-direction  34  of the headbox  16 . In  FIG.  1   , the machine direction  32  can be viewed in a downward direction, or be defined as extending from the inlet  26  of the headbox  16  to the outlet  28  of the headbox  16 . Although the discussion herein is referred to with respect to a vertical twin-wire headbox  16 , it is to be appreciated that the methods and apparatuses discussed herein can be utilized with other headbox  16  configurations and orientations. 
     With reference to  FIGS.  2 - 4   , the headbox  16  can include a divider  36 . The divider  36  can include at least one cross-directional divider  38 . For example, in  FIGS.  2 - 4   , the divider  36  depicted includes two cross-directional dividers  38 . One cross-directional divider  38  is spaced apart from the other cross-directional divider  38  in the cross-direction  34  of the headbox  16 . In some embodiments, the divider  36  can include a first surface  40  and a second surface  42 . The second surface  42  can be opposite from the first surface  40  of the divider  36 . The divider  36  can include a width  44  in the cross-direction  34  and a length  46  in the machine direction  32 . In some embodiments, the length  46  of the divider  36  can be configured to be at least 50% of the length L of the headbox  16  (as labeled in  FIG.  1   ), or at least 60% of the length L of the headbox  16 , or at least 65% of the length L of the headbox  16 , or at least 70% of the length of the headbox, or at least 75% of the length L of the headbox  16 . 
     The cross-directional divider  38  can extend away from the first surface  40 . In some embodiments, such as the embodiment depicted in  FIGS.  2 - 4   , the divider  36  can include two or more cross-directional dividers  38  that extend away from the first surface  40  in the same direction. However, it is contemplated that in some embodiments the divider  36  could include one or more cross-directional dividers  38  that extend away from the first surface  40  and one or more cross-directional dividers  38  that extend away from the second surface  42  of the divider  36 , such as depicted in  FIG.  6    and discussed further below. In some embodiments, the cross-directional divider  38  extends away from the first surface  40  in a direction substantially perpendicular to a plane defined by the first surface  40 . In some embodiments, the cross-directional divider  38  can extend away from the second surface  42  in a direction substantially perpendicular to a plane defined by the second surface  42 . 
     The cross-directional divider  38  can include a cross-directional thickness  48  and a machine-directional length  50 . The cross-directional thickness  48  of the cross-directional divider  38  is to be measured in the cross direction  34  for the headbox  16 . In some embodiments, the cross-directional thickness  48  of the cross-directional divider  38  can be between about 0.5 mm to about 10 mm. The machine-directional length  50  of the cross-directional divider  38  is to be measured in the machine direction  32  for the headbox  16  between a proximal end  54  of the cross-directional divider  38  and a distal end  56  of the cross-directional divider  38 . In some embodiments, the machine-directional length  50  of the cross-directional divider  38  can vary based on the length  46  of the divider  36 . In some embodiments, such as the embodiment depicted in  FIG.  2   , the machine directional length  50  of the cross-directional divider  38  can be less than the length  46  of the divider  36 . 
     The height  52  of the cross-directional divider  38  is to be measured in a direction perpendicular to the machine direction  32  and the cross direction  34  of the headbox  16  and from the surface of the divider  36  from which it extends. As an example, the height  52  of the cross-directional divider  38  is measured from the first surface  40  of the divider  36  in a direction perpendicular to the machine direction  32  and the cross direction  34  of the headbox  16 , such as illustrated in  FIG.  3   . 
     The height  52  of the cross-directional divider  38  can vary along the machine directional length  40  of the cross-directional divider  38 . For example, in the embodiment depicted in  FIG.  2   , the height  52  of the cross-directional divider  38  at the proximal end  54  of the cross-directional divider  38  is greater than the height  52  of the cross-directional divider  38  at the distal end  56  of the cross-directional divider  38 . In some embodiments, the cross-directional divider  38  can include a first section  58  that has a substantially constant height  52  and a second section  60  that has a decreasing height  52  along the machine-directional length  50  of the cross-directional divider  38 . As illustrated in the embodiment of  FIG.  2   , the second section  60  of the cross-directional divider  38  can decrease in height  52  in a linear fashion. Of course, it is contemplated that the height  52  of the cross-directional divider  38  may decrease between a proximal end  54  and a distal end  56  of the cross-directional divider  38  in other ways. Not to be bound by theory, but it is believed that decreasing the height  52  along the machine-directional length  50  of the cross-directional divider  38  can help with intermingling of fibers between various zones in the headbox  16  if such a decrease in height creates a gap between the cross-directional divider  38  and the foraminous element  22 , as will be discussed in more detail below. 
       FIG.  4    illustrates a cross-sectional view of divider  36  within the headbox  16 , as viewed at the inlet  26  of the headbox  16 . As depicted in  FIG.  4   , divider  36  can have a width  44  (as labeled in  FIG.  3   ) that substantially spans across the width  62  of the internal volume  24  of the headbox  16  at the inlet section  26 . In some embodiments, the width  44  of the divider  36  can be at least 90%, or more preferably at least 95%, of the width  62  of the internal volume  24  of the headbox  16  at the inlet section  26 . The first surface  40  and the second surface  42  of the divider  36  can form a z-directional divider  64  for the headbox  16 . In other words, the divider  36  can form a z-directional divider  64  by forming a first z-directional layer  66  and a second z-directional layer  68  within the headbox  16 . 
     In some embodiments, the divider  36  can be positioned in the headbox  16  such that the z-directional divider  64  is evenly positioned between the internal surface  74  of the top of the headbox  16  and the internal surface  75  of the bottom of the headbox  16 . Such a configuration provides for an equal thickness for the first z-directional layer  66  of the headbox  16  and the second z-directional layer  68  of the headbox  16 . Of course, the divider  36  can be moved in a z-directional manner with respect to the headbox  16  to provide different target thicknesses for the first z-directional layer  66  of the headbox  16  and the second z-directional layer  68  of the headbox  16 , and in turn, different thicknesses for the corresponding layers  82 ,  84  of a substrate as described later herein. 
     As also depicted in  FIG.  4   , the cross-directional dividers  38  can create zones  70   a,    70   b,    70   c  within the headbox  16 , or within a particular z-directional layer in the headbox  16 . In the embodiment depicted in  FIG.  4   , the two cross-directional dividers  38  can create a first zone  70   a,  a second zone  70   b,  and a third zone  70   c  that each form part of the first z-directional layer  66  of the headbox  16 . For example, the first zone  70   a  and the second zone  70   b  are separated from one another by the left-most cross-directional divider  38  and the second zone  70   b  and the third zone  70   c  are separated from one another by the right-most cross-directional divider  38 . When creating zones that are distinguished from one another in the headbox  16  in a cross-directional manner at the inlet  26  of the headbox  16 , it is preferable that the cross-directional divider(s)  38  preferably have a height  52  (such as labeled in  FIG.  3   ) that substantially spans the distance between the two surfaces that provide a thickness for a particular layer of the headbox  16  at least near the inlet  26  of the headbox  16  (e.g., at the proximal end  54  of the cross-directional divider  38 ). For example, in the embodiment depicted in  FIG.  4   , it is preferable if the cross-directional dividers  38  of the divider  36  include a height  52  (as labeled in  FIG.  3   ) that substantially spans the distance  72  between the first surface  40  of the divider  36  and the internal surface  74  of the headbox  16  that defines the thickness of the first layer  66  in the headbox  16  at the inlet  26  of the headbox  16 . For example, the height  52  of the cross-directional dividers  38  can be at least 90%, or more preferably at least 95%, of the distance  72  between the first surface  40  of the divider  36  and the internal surface  74  of the headbox  16  defining the thickness of the first layer  66  of the headbox  16 . 
     While  FIG.  4    illustrates an embodiment including a divider  36  with two cross-directional dividers  38  that extend from the first surface  40 , it is contemplated that other arrangements for creating cross-directional zones within a headbox  16  can be created and utilized to create zoned substrates. For example, in some embodiments, a headbox  16  can include one or more cross-directional dividers  38 , without any z-directional divider  64 , such that there is only one z-directional layer  66  within the headbox  16 . It is also contemplated that a divider  36  could have a single cross-directional divider  38  extending from only one surface  40  or  42  to create only two zones within a particular z-directional layer within the headbox  16 , or there could be three or more cross-directional dividers  38  that create four or more zones within a particular z-directional layer within the headbox  16 . As illustrated in  FIG.  4   , in some embodiments, the divider  36  can create a z-directional layer  68  that only includes a single zone  73 . As will be described in other embodiments, the divider  36  can include at least one cross-directional divider  38  extending from the first surface  40  and at least one cross-directional divider  38  extending from the second surface  42  that create more than one zone in each of the z-directional layers  66 ,  68  of the headbox  16 . 
     In embodiments that include a cross-directional divider  38  and a z-directional divider  64 , the cross-directional divider(s)  38  can be integrally formed with the z-directional divider  64 . It is also contemplated that the cross-directional divider  38  can be formed separately from the z-directional divider  64 , but be coupled to the z-directional divider  64 , such as, for example, welds, adhesives, or other suitable bonding techniques. 
     The cross-directional divider(s)  38  and the z-directional divider(s)  64  can be formed from any suitable material. For example, the cross-directional divider(s)  38  and the z-directional divider(s)  64  can be formed from metals (e.g., steel, aluminum, etc.), plastics, or other suitable substances. In a preferred embodiment, the cross-directional divider(s)  38  and the z-directional divider(s)  64  can be formed from or coated with polytetrafluoroethylene (PTFE), as such dividers  38 ,  64  can prevent sticking of fibers, and particularly of some additives, such as superabsorbent material, to the dividers  38 ,  64 . 
     Supply of fibers and additional additives can be supplied to the various layers and zones of the headbox  16  to provide various configurations of a substrate.  FIG.  4    also illustrates how fibers and/or additives can be provided to the headbox  16  to provide a zoned substrate  10 , such as illustrated in  FIG.  5 A . For example, with the use a cross-directional divider  38  in headbox  16  as illustrated in  FIG.  4   , a first supply  14  of fibers can be transferred to the second zone  70   b  of the first layer  66  of the headbox  16 , such as through conduit(s)  18  coupled to inlet ports  76   b  that supply the second zone  70   b  of the first layer  66  of the headbox  16 . A second supply  15  of fibers can be transferred to the first zone  70   a  of the first layer  66  of the headbox  16 , for example, such as through the conduit(s)  19  coupled to inlet ports  76   a  in the first zone  70   a  of the first layer  66  of the headbox  16 . As illustrated in  FIG.  1   , the conduit  19  that provides the second supply  15  of fibers could be split to supply the first zone  70   a  and the third zone  70   c,  or there could be two separate conduits  19  that are connected to the second supply  15  of fibers and that supply the first and third zones  70   a,    70   c.  In some embodiments of manufacturing a zoned substrate  10 , such as the substrate  10  in  FIG.  5 A , the second supply  15  of fibers can also be transferred to the third zone  70   c  of the first layer  66  of the headbox  16 , such as through inlet ports  76   c  that supply the third zone  70   c  of the first layer  66  of the headbox. Importantly, while pairs of inlet ports  76   a,    76   b,    76   c  are each shown as supplying the first zone  70   a,  the second zone  70   b,  and the third zone  70   c  of the first layer  66  of the headbox  16 , respectively, it is contemplated that there could be a single inlet port or three or more inlet ports that supply a respective cross-directional zone and/or layer of the headbox  16 . 
     The first supply  14  of fibers and the second supply  15  of fibers can be transferred through the headbox  16  in the machine direction  32  for the headbox  16  to provide the substrate  10 . For example, referring back to  FIG.  1   , in a foam forming manufacturing technique the first supply  14  of fibers and the second supply  15  of fibers can be transferred to the headbox  16  in a foam slurry. As the first supply  14  of fibers and the second supply  15  of fibers are transferred through the headbox  16 , the foam slurry incorporating the first supply  14  of fibers and the foam slurry incorporating the second supply  15  of fibers can be dewatered by vacuum elements  30  as the fibers are deposited on one or more of the foraminous elements  20 ,  22 , as discussed above. 
     With the configuration noted above, the first supply  14  of fibers that is transferred to the second zone  70   b  of the headbox  16  and that is transferred through the headbox  16  can provide the substrate  10  as illustrated in  FIG.  5 A  with a zone  80   b.  The second supply  15  of fibers that is transferred to the first zone  70   a  and the third zone  70   c  of the headbox  16  and that is transferred through the headbox  16  can provide the substrate  10  with zones  80   a  and  80   c,  respectively. The substrate  10  can be at least partially dewatered through the headbox  16  as it exits the headbox  16  at the outlet  28  of the headbox  16 . The substrate  10  can be further dried, if necessary, and handled via equipment and processes as is known in the art. 
     Thus,  FIG.  5 A  provides for a zoned substrate  10  including two or more zones within a particular layer of the substrate  10 . Specifically, the zoned substrate  10  includes three zones  80   a,    80   b,    80   c  within a single layer  82  that forms zoned substrate  10 . The zoned substrate  10  can provide the advantage of having a central zone  80   b  that includes fibers (with or without additives) that are different than the fibers (with or without additives) in zones  80   a  and  80   c.  As an example, the zoned substrate  10  could be configured to provide an absorbent material that has absorbent fibers in the first zone  80   a,  the second zone  80   b,  and the third zone  80   c,  but with an additive being present in the second zone  80   b,  such as superabsorbent material, but not in the first and third zones  80   a,    80   c.  In another embodiment, the zoned substrate  10  could be configured to provide a combination of an intake/distribution material that has fibers in the first zone  80   a  and the third zone  80   c  that function particularly well as distribution fibers (e.g., such as a softwood pulp fiber, eucalyptus pulp fiber, or fine regenerated cellulose fiber and a binder fiber), and can have fibers in the second zone  80   b  that function particularly well as intake/acquisition fibers (e.g., such as a crimped PET fiber with a fiber diameter greater than 3 deniers and a binder fiber). 
     In another example, a two layer zoned substrate  110  is illustrated in  FIG.  5 B . The zoned substrate  110  can include a first layer  82  and a second layer  84 . Referring back to  FIG.  4   , a first supply  14  of fibers can be transferred to the second zone  70   b  of the first layer  66  of the headbox  16 , such as through conduit(s)  18  coupled to inlet ports  76   b  that supply the second zone  70   b  of the first layer  66  of the headbox  16 . A third supply  17  of fibers (as labeled in  FIG.  1   ) can be supplied to the second layer  68  of the headbox  16 , such as through conduit  21  coupled to inlet ports  78   a,    78   b,    78   c.  As previously noted, conduit  21  can be branched to feed multiple inlet ports  78   a,    78   b,    78   c,  and/or multiple conduits  21  can transfer the third supply  17  of fibers to inlet ports  78   a,    78   b,    78   c  of the second layer  68  of the headbox  16 . In doing so, the first supply  14  of fibers can provide a first layer  82  of the substrate  110  in a central zone  80   b  and the third supply  17  of fibers can provide a second layer  84  of the substrate  110 . Through the use of the two cross-directional dividers  38  in the headbox  16 , the first layer  82  of the substrate  110  including fibers from the first supply  15  of fibers can be controlled to be of a narrower cross-directional width than the second layer  84  of the substrate  110  that includes fibers from the third supply  17  of fibers. 
     In some embodiments, the zoned substrate  110  can include a two layered substrate  110  in which the first layer  82  includes fibers that are different from the fibers of the second layer  84 . For example, in one example, the zoned substrate  110  can be configured to provide an absorbent material that includes synthetic fibers in the first layer  82  in the zone  80   b  that function particularly well as intake/acquisition fibers (e.g., such as a crimped PET fiber with a fiber diameter greater than 3 deniers and a binder fiber) and absorbent fibers in the second layer  84 , such as cellulosic fibers. In some embodiments, the second layer  84  can include fibers other than just cellulosic fibers, including other absorbent fibers and/or non-absorbent fibers. In some embodiments, the second layer can include an additive, such as a particulate of superabsorbent material. 
     Another embodiment of a two layer zoned substrate  210  is illustrated in  FIG.  5 C . The substrate  210  can include a first layer  82  and a second layer  84 . The first layer  82  of the substrate  210  can be formed in some embodiments in a similar manner to substrate  10  as described above and as illustrated in  FIG.  5 A . Referring back to  FIG.  4   , a first supply  14  of fibers can be transferred to the second zone  70   b  of the first layer  66  of the headbox  16 , such as through conduit(s)  18  (as labeled in  FIG.  1   ) coupled to inlet ports  76   b  that supply the second zone  70   b  of the first layer  66  of the headbox  16 . A second supply  15  of fibers (as labeled in  FIG.  1   ) can be transferred to the first zone  70   a  and the third zone  70   c  of the headbox  16  and can be transferred through the headbox  16  to provide the first layer  82  of the substrate  210  with zones  80   a  and  80   c,  respectively. A third supply  17  of fibers (as labeled in  FIG.  1   ) can be supplied to the second layer  68  of the headbox  16 , such as through conduit  21  coupled to inlet ports  78   a,    78   b,    78   c.  In such an embodiment, the first supply  14  of fibers can provide a first layer  82  of the substrate  210  with a second zone  80   b  and the second supply  15  of fibers can provide the first layer  82  of the substrate  210  with the first and second zones  80   a,    80   c,  respectively, that surround the second zone  80   b  in the first layer  82 . The third supply  17  of fibers can provide a second layer  84  of the substrate  210 . The cross-directional location of the two cross-directional dividers  38  in the headbox  16  can control the cross-directional width of each zone  80   a,    80   b,    80   c  in the first layer  82  of the substrate  210 . 
     In some embodiments, the zoned substrate  210  of  FIG.  5 C  can include a two layered substrate  210  in which the first layer  82  includes fibers that are different from the fibers of the second layer  84 . The zoned substrate  210  can provide the advantage of having a central zone  80   b  that includes fibers (with or without additives) that are different than the fibers (with or without additives) in zones  80   a  and  80   c  within the first layer  82  of the substrate  210 . As an example, the zoned substrate  210  could be configured to provide an absorbent material that has fibers in the first zone  80   a  and the third zone  80   c  that function particularly well as distribution fibers (e.g., such as a softwood pulp fiber, eucalyptus pulp fiber, or crosslinked pulp fiber and a binder fiber), and can have fibers in the second zone  80   b  that function particularly well as intake/acquisition fibers (e.g., such as a crimped PET fiber with a fiber diameter greater than 3 deniers and a binder fiber). The substrate  210  can also include binder material, such as binder fibers, in one or more zones  80   a,    80   b,    80   c  of the first layer  82 . In some embodiments, the substrate  210  can include absorbent fibers in the second layer  84  that function well as absorbent fibers, and in some preferred embodiments, can include additional fibers and/or additives in the second layer  84 . For example, the second layer  84  can be configured to include binder fibers and/or particulates such as superabsorbent material. 
     Of course, a variety of other configurations of zoned substrates can be configured based on the divider  36  including two cross-directional dividers  38  and a single z-directional divider  64  as shown and described above based on the fiber and additive configurations to various zones and layers of the headbox  16 . 
     Additionally, other zoned and/or layered substrates can be made through the construction of different dividers for the headbox  16 . As but one additional example, another alternative divider  136  is illustrated in  FIG.  6   . The divider  136  can include a first surface  40  that includes two cross-directional dividers  38  spaced apart from one another that extend away from the first surface  40 . The divider  136  can include a second surface  42  that includes two cross-directional dividers  38  spaced apart from one another that extend away from the second surface  42 . As illustrated in  FIG.  6   , the cross-directional dividers  38  extending away from the first surface  40  can be cross-directionally aligned with the cross-directional dividers  38  extending away from the second surface  42 . However, it is contemplated that the spacing of the cross-directional dividers  38  on the first and second surface  40 ,  42  in the cross-direction  34  of the headbox  16  can be varied based on the resultant zoned substrate that is desired to be manufactured. Additionally, it is contemplated that the divider  136  could include only one cross-directional divider  38  on one or more of surfaces  40 ,  42  and/or three or more cross-directional dividers  38  on one or more of surfaces  40 ,  42 . 
       FIG.  7    illustrates an exemplary zoned substrate  310  that can be manufactured by utilizing divider  136  in headbox  16  as described in the processes noted above with respect to  FIGS.  1  and  4   . For example, the zoned substrate  310  can include a first layer  82  and a second layer  84 . The first layer  82  can include zones  80   a,    80   b,  and  80   c.  The second layer  84  can include zones  86   a,    86   b,    86   c.    
     As discussed above with respect to other embodiments of zoned substrates  10 ,  110 ,  210 , one or more of the zones  80   a,    80   b,    80   c  in the first layer  82  and one or more of the zones  86   a,    86   b,    86   c  can by supplied by various supplies of fibers (with or without additives) that can provide various characteristics to the zoned substrate  310 . As but one example, the first layer  82  of the zoned substrate  310  can be configured such that the second zone  80   b  includes fibers from a first supply  14  of fibers and a first zone  80   a  and third zone  80   c  include fibers from a second supply  15  of fibers. As discussed above, one preferable construction for such a layer  82  for a zoned substrate  310  may be to have the fibers from the first supply  14  of fibers in the second zone  80   b  include fibers that provide particular benefits for intake/acquisition functionality (e.g. a crimped PET fiber with a fiber diameter greater than 3 deniers and a binder fiber fibers). The fibers from the second supply  15  of fibers in the first and third zones  80   a,    80   c,  respectively, of the first layer  82  can include fibers that provide particular benefits for distribution functionality (e.g., a softwood pulp fiber, eucalyptus pulp fiber, or crosslinked pulp fiber and a binder fiber fibers). 
     The second layer  84  can include first and third zones  86   a,    86   c,  respectively, that include fibers from a third supply  17  of fibers that may include absorbent fibers. The second zone  86   b  of the second layer  84  of the substrate  310  can include particulates, such as from a supply  23  of particulates (e.g., SAM), as labeled in  FIG.  1   . The supply  23  of particulates can be transferred to the headbox  16  via a conduit  25 . The supply  23  of particulates, in some embodiments, can also include fibers, such as, but not limited to, absorbent fibers. As a result, the second layer  84  of the substrate  310  can include first and third zones  86   a,    86   c,  respectively, that can include absorbent fibers and can include a second zone  86   b  that includes additional additives (such as SAM) and/or absorbent fibers. 
     As can be seen from the examples of the substrates  10 ,  110 ,  210 ,  310  as described herein, the use of one or more cross-directional dividers  38 , and where desired, one or more z-directional dividers  64 , can provide a very functionalized, zoned substrate  10 ,  110 ,  210 ,  310  with various zones being created for enhancements of specific functionality for the end use in which the substrate  310  may be used in. In some embodiments, the zoned substrates as described herein can be utilized as part of or as an absorbent system in a personal care absorbent article. For example, the substrates  10 ,  110 ,  210 ,  310  can be utilized as part of an absorbent system in an absorbent article. It is also contemplated that the substrates  10 ,  110 ,  210 ,  310  could be utilized as part of or an entire absorbent article itself other than a personal care absorbent article, such as, for example a wipe, wiper, bath or facial tissue, or towel. 
     Not to be bound by theory, but it is believed that the use of z-directional dividers  64  and/or cross-directional dividers  38  can provide enhanced control of purity gradients at the interface between layers of a substrate and at the interface between adjacent zones within a particular layer of the substrates, respectively. For example, it is believed that that the height  52  of the cross-directional dividers  38  with respect to the dimensions of the headbox  16  can help separate zones (e.g.,  70   a,    70   b,    70   c ) within a layer (e.g.,  66 ) of the headbox  16  to control the fibers that are being transferred through the headbox  16  and formed into a substrate having interfaces  81  between zones (e.g.,  80   a,    80   b,    80   c ) of a substrate  10  with a higher purity gradient. In embodiments that have a gap between the cross-directional divider  38  and the headbox  16 , fibers from adjacent zones (e.g.,  70   a,    70   b,    70   c ) of the headbox  16  can intermingle in such a gap area as the fibers are transferred through the headbox  16 , and thus, can create zones (e.g.,  80   a,    80   b,    80   c ) of a substrate  10  with a lower purity gradient. A similar intermingling could occur between layers (e.g.,  66 ,  68 ) in the headbox  16  by having a z-directional divider  64  that has a width  44  that does not span the full width of the headbox  16 . 
     In addition, it is believed that the machine directional length  50  of the cross-directional dividers  38  may be particularly controlled to provide a desired purity gradient between adjacent zones within the substrate (e.g., zones  80   a,    80   b  in substrate  10  based on zones  70   a,    70   b  of headbox  16 ). For example, it is believed that by having a cross-directional divider  38  that is shorter in length, a lower purity gradient can be achieved between adjacent zones (e.g.,  80   a,    80   b ) of a substrate as compared to a longer cross-directional divider  38 . By having a shorter machine directional length  50  of the cross-directional divider  38 , more fiber intermixing can occur at the interface  81  (labeled in  FIG.  5 A ) between adjacent zones (e.g.,  80   a,    80   b ) of the substrate  10  after the cross-directional divider  38  and create a lower purity gradient at interface  81 . A longer machine directional length  50  of the cross-directional divider  38  can allow for greater formation of the substrate through the headbox  16  while the fibers are still relatively contained within separate zones, and thus, decrease the amount of fiber and/or particulate intermixing between adjacent zones (e.g.,  80   a,    80   b ) of a substrate while the substrate is being formed and transferring through the headbox  16 , and thus, create a higher purity gradient at interface  81 . 
     In a similar respect, the machine directional length  46  of the divider  36  (which can also be the machine directional length of the z-directional divider  64 ) can help control a purity gradient between adjacent layers within the substrate (e.g., layers  82 ,  84  in substrate  210  based on layers  66 ,  68  of headbox  16 ). For example, a divider  36  having a shorter machine directional length  46  can provide a lower purity gradient at an interface  81  between adjacent z-directional layers (e.g.,  82 ,  84 ) of a substrate as compared to a longer machine directional length  46  of the divider  36 . A longer machine directional length  46  of the divider (and thus, the machine directional length of the z-directional divider  64 ) can allow for greater formation of the substrate through the headbox  16  while the fibers are still relatively contained within separate layers, and thus, decrease the amount of fiber and/or particulate intermixing at the interface  81  between adjacent layers (e.g.,  82 ,  84 ) while the substrate is being formed and transferring through the headbox  16 , and thus, create a higher purity gradient at interface  81 . In some embodiments, it is preferable to have a machine directional length  46  of the divider  36  that is at least 50%, or at least 55%, or at least 60%, or at least 65%, or at least 70%, or at least 75% or more of the machine directional length L of the headbox  16 . 
     It is believed that there may be advantages to having some substrates formed with lower purity gradients at the interface  81  between adjacent layers and/or zones, whereas there may be advantages to having some substrates formed with higher purity gradients at the interface  81  between adjacent layers and/or zones. 
     EXAMPLES 
     Experimental codes were formed utilizing a foam-forming method as described above with respect to  FIG.  1    along with varying the divider construction. Purity gradients were measured at various interfaces  81  between zones of the substrates to determine how well a divider  36  including at least one cross-directional divider  38  can control the mixing at an interface  81  between zones. Relative layer thicknesses were also measured to determine the ability to control a relative thickness of a particular layer with respect to a target relative thickness setting in the headbox  16 . 
     The surfactant used in the foam slurry for each code was Stantex H 215 UP, available from Pulcra Chemicals, which is an aqueous solution of alkyl polyglucosides based on natural fatty alcohol C8-C10. The codes were produced to attempt to make a substrate similar to the substrate  210  shown in  FIG.  5 C  that includes three cross-directional zones  80   a,    80   b,    80   c  in a first layer  82 . The second layer  84  was desired to have a uniform construction, or in other words, only a single zone. To provide such a configuration, reference is made to the headbox  16  configuration of  FIG.  4   . The inlets  76   a  of the first zone  70   a  of the first layer  66  of the headbox  16  and inlets  76   c  of the third zone  70   c  of the first layer  66  of the headbox  16  were provided with exemplary distribution layer materials of crosslinked cellulosic CMC 535 fibers and T 255 binder fibers. The inlets  76   b  of the second zone  70   b  of the first layer  66  of the headbox  16  were provided with exemplary intake layer materials of synthetic based fibers of PET fibers and T 255 binder fibers. All of the inlets  78   a,    78   b,  and  78   c  of the second layer  68  of the headbox  16  were provided with materials to construct an absorbent layer by providing NBSK fibers, crosslinked cellulosic CMC 535 fibers, T 255 binder fibers, and superabsorbent material particulates. 
     Table 1 provides three exemplary codes that were formed utilizing fiber and/or particulates in the layers  66 ,  68  of the headbox  16  as described above to provide substrates  210 A,  210 B, and  210 C. The only variable between codes documented in Table 1 was the type of divider  36  (or lack thereof) used with the headbox  16  to produce each substrate. For code A, a divider  36  including two cross-directional dividers  38  extending from the first surface  40  of the divider  36  was used, such as the divider  36  illustrated in  FIG.  3    to make substrate  210 A. For code B, a divider  36  including no cross-directional dividers  38  was used, such that the divider  36  only provided a z-directional divider  64  to make substrate  210 B. For code C, no divider  36  was used in the headbox  16  to make substrate  210 C. In each of the codes, a small percentage of colored fiber was added to the center zone  80   b  for first layer  82  to help visually depict the amount of mixing between adjacent zones and layers of each material code. The colored fiber used in the center zone  80   b  was an acrylic fiber with 3 mm fiber length and was provided at 3 wt % in the center zone  80   b  of the first layer  82  based on total weight of the fibers at that zone, approximately 1.2 gsm. 
     
       
         
           
               
             
               
                 TABLE 1 
               
             
            
               
                   
               
               
                 Material Code Information 
               
            
           
           
               
               
               
            
               
                   
                 Layer 1 
                 Layer 2 
               
            
           
           
               
               
               
               
            
               
                   
                 Outside zones 
                 Center Zone 
                 Absorbent body 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                 CMC 
                 T255 
                 PET 
                 T255 
                 T255 
                   
                 CMC 
                   
                   
                   
               
               
                   
                 535 
                 binder 
                 curly 
                 binder 
                 binder 
                 NBSK 
                 535 
               
               
                   
                 fibers 
                 fibers 
                 fibers 
                 fibers 
                 fibers 
                 fibers 
                 fibers 
                 SAM 
                 % 
                 % 
               
               
                 Code 
                 (gsm) 
                 (gsm) 
                 (gsm) 
                 (gsm) 
                 (gsm) 
                 (gsm) 
                 (gsm) 
                 (gsm) 
                 binder 
                 SAM 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                 A 
                 31 
                 9 
                 26 
                 14 
                 23 
                 30 
                 23 
                 400 
                 4.8 
                 84 
               
               
                 B 
                 31 
                 9 
                 26 
                 14 
                 23 
                 30 
                 23 
                 400 
                 4.8 
                 84 
               
               
                 C 
                 31 
                 9 
                 26 
                 14 
                 23 
                 30 
                 23 
                 400 
                 4.8 
                 84 
               
               
                   
               
            
           
         
       
     
       FIGS.  8 A- 8 C  provide photographs depicting the substrates  210 A,  210 B,  210 C formed by material Codes A, B, and C, respectively. The colored fibers that were used in the center zone  80   b  help visually demonstrate the amount of mixing occurring at an interface  81  between adjacent zones  80   a  and  80   b  and zones  80   b  and  80   c  in the substrates. For example,  FIG.  8 A  that used a divider  36  including two cross-directional dividers  38  depicts the colored fibers of zone  80   b  (and thus the other fibers of the center zone  80   b ) of the substrate  210 A were relatively contained between the interfaces  81  between itself and zone  80   a  and zone  80   c.  However,  FIG.  8 B  that depicts a substrate  210 B that used a divider  36  without any cross-directional dividers  38  and  FIG.  8 C  that depicts a substrate  210 C that did not use a divider  36  whatsoever shows a significantly higher amount of dispersion of the colored fiber from the center zone  80   b  at the interfaces  81  between zone  80   a  and  80   b  and between zone  80   b  and zone  80   c.  Thus, Codes B and C providing substrates  210 B,  210 C visually show a lower purity level of the interfaces  81  between zones  80   a  and  80   b,  and between  80   b  and  80   c  in the first layer  82 . 
     Substrate samples from each experimental code substrates  210 A,  210 B,  210 C were harvested for analysis according to the Purity Gradient Test Method and Layer Thickness Test Method as described in the Test Methods section herein. The Purity Gradient Test Method provides quantifiable characteristics for the amount of mixing at an interface between adjacent zones of a layer, as documented in Table 2. 
     
       
         
           
               
             
               
                 TABLE 2 
               
             
            
               
                   
               
               
                 Results of Purity Gradient Testing for Adjacent Zones within a Layer 
               
            
           
           
               
               
               
               
            
               
                   
                 Code A (Substrate 210A) 
                 Code B (Substrate 210B) 
                 Code C (Substrate 210C) 
               
            
           
           
               
               
               
               
               
               
               
            
               
                   
                 zone 
                 zone 
                 zone 
                 zone 
                 zone 
                 zone 
               
               
                   
                 transition 
                 transition 
                 transition 
                 transition 
                 transition 
                 transition 
               
               
                   
                 width (cm) 
                 slope (gray/cm) 
                 width (cm) 
                 slope (gray/cm) 
                 width (cm) 
                 slope (gray/cm) 
               
               
                   
                   
               
            
           
           
               
               
               
               
               
               
               
            
               
                 Average 
                 2.5 
                 52 
                 3.9 
                 28 
                 3.8 
                 25 
               
               
                 Std. Dev. 
                 0.3 
                 9 
                 0.5 
                 1 
                 0.5 
                 9 
               
               
                 Max. 
                 2.8 
                 63 
                 4.4 
                 30 
                 4.3 
                 40 
               
               
                 Min. 
                 2.1 
                 43 
                 3.3 
                 27 
                 3.4 
                 16 
               
               
                 n 
                 5 
                 5 
                 5 
                 5 
                 5 
                 5 
               
               
                   
               
            
           
         
       
     
     The results of the Purity Gradient testing for adjacent zones within a layer of a substrate from Table 2 show that a cross-directional divider  38  provides a substantial increase in control of the amount of mixing between adjacent zones within a layer of a substrate. For example, Code A demonstrated a substrate  210 A having two zones in a layer with an interface having a purity gradient that includes a transition width of 2.5 cm, whereas Codes B and C only provided transition widths of 3.9 cm and 3.8 cm, respectively, for substrates  210 B and  210 C. Thus, preferable foam-formed substrates including adjacent zones in a layer can provide an interface between zones having a transition width of less than 3.8 cm, or more preferably, less than 3.0 cm., or more preferably, less than 2.8 cm. 
     Additionally, Code A demonstrated a substrate  210 A having two zones in a layer with an interface having a purity gradient that includes a transition slope of 52 gray/cm, whereas Codes B and C only provided a substrate  210 B and  210 C with an interface having a purity gradient that includes a transition slope of 28 gray/cm and 25 gray/cm, respectively. The higher the transition slope of the purity gradient, the greater the level of purity exists at the interface between zones. Thus, preferable foam-formed substrates including adjacent zones in a layer can provide an interface between zones having a transition slope of greater than 28 gray/cm, or more preferably greater than 30 gray/cm, or even more preferably greater than 40 gray/cm. 
     By using a foam forming process with a divider  36  having cross-directional dividers  38 , a substrate can be produced with an interface  81  between adjacent zones that provides a level of beneficial mixing to provide for proper integrity of the structure and fluid distribution between adjacent zones, yet the mixing can be controlled sufficiently at the interface  81  to still provide sufficient purity between different zones such that the intended purpose of different zones based on their fiber composition selection can be accomplished for the substrate  210 . For example,  FIG.  10    shows the efficiency of Code A in comparison to Codes B and C in terms of fluid distribution per product length. As shown in  FIG.  10   , Code A demonstrated a more even distribution of fluid for the entire substrate. Specifically, the moisture was lower near the insult as it was more evenly distributed throughout the length of the substrate. Code A demonstrated a higher moisture level than Code B or Code C at approximately 16-17 cm of length of the substrate. By having more efficient fluid distribution throughout the length of a substrate, substrates can be created that have lower amounts of material to perform the same functionality, and thus, provide raw material and cost savings for a particular intended end use. If used in personal care absorbent articles, the enhanced fluid distribution efficiency can also lead to thinner products, which may be more flexible, discrete, and/or comfortable for an end user. 
     Additionally, higher purity gradients between zones and/or layers can provide enhanced fluid intake rates due to distinctive intake and distribution zones in the first layer and an absorbent layer in the second layer. By having a higher purity gradient between zones and/or layers, absorbent substrates used in absorbent articles can perform multiple liquid handling functions, such as intake, distribution, and storage, such as for use in diapers or wiping, which can include fluid pick-up and lock-up, in multiple different structures that are designed for such particular functions. Notably, this is completed without the use of adhesives at such interfaces, as with other substrates in the prior art that look to make absorbent composites from separate materials that are adhered together. Adhesives at such interfaces can lead to lower performance of distribution and intake as the adhesives can act as a barrier to fluid handling. 
     Layer relative thicknesses and purity of layers can also be controlled more readily through the use of dividers  36  that provide a z-directional divider  64 . For the testing herein involving substrates  210 A,  210 B,  210 C including superabsorbent material, the Layer Relative Thickness Test Method was utilized that employed microCT equipment. The Layer Relative Thickness Test Method is described in detail in the Test Methods section herein. Cross-sectional images of material Codes A-C providing substrates  210 A- 210 C described above were taken utilizing microCT imaging equipment and are depicted in  FIGS.  9 A- 9 C , respectively. Table 3 provides the results of the relative layer thickness for a substrate  210  including a second layer  84  that includes superabsorbent material particles, where the relative thickness of the layer is measured as a percentage of the overall thickness of the substrate. 
     
       
         
           
               
             
               
                 TABLE 3 
               
             
            
               
                   
               
               
                 Second Layer Relative Thickness Results 
               
            
           
           
               
               
               
               
            
               
                   
                 Code A 
                 Code B 
                 Code C 
               
               
                   
                 (Substrate 210A) 
                 (Substrate 210B) 
                 (Substrate 210C) 
               
               
                   
                 Second Layer 
                 Second Layer 
                 Second Layer 
               
               
                   
                 Relative 
                 Relative 
                 Relative 
               
               
                   
                 Thickness 
                 Thickness 
                 Thickness 
               
               
                   
                   
               
            
           
           
               
               
               
               
            
               
                 Average 
                 34% 
                 53% 
                 70% 
               
               
                 Std. Dev. 
                  6% 
                  8% 
                  8% 
               
               
                 n 
                 7 
                 7 
                 7 
               
               
                   
               
            
           
         
       
     
     The relative layer thickness results documented in Table 3 demonstrate that the use of a divider  36  providing a z-directional divider  64  in the headbox  16  provides substantially more control over the purity of the layers  82 ,  84 , and thus, more control over the layer relative thickness of a substrate  210 , particularly where a layer includes particulate material (e.g., superabsorbent material particles). In producing Codes A and B (substrates  210 A and  210 B), the divider  36  was set up in the headbox  16  such that the divider  36  was evenly spaced in the z-directional  35  thickness of the headbox  16  (as illustrated in  FIG.  4   ) to try to produce a second layer  84  of the substrate that had the same z-directional  35  thickness as the first layer  82 . In other words, the divider  36  was positioned in the headbox  16  such that the z-directional divider  64  was evenly positioned between the internal surface  74  of the top of the headbox  16  and the internal surface  75  of the bottom of the headbox  16 . The z-directional divider  64  was also configured to extend approximately 66% into the length of the headbox  16 . On the other hand, Code C (substrate  210 C) did not include any divider  36  in the headbox  16 . With such a configuration of the divider  36  in the headbox  16  for producing Codes A and B, the divider  36  including a z-directional divider  64  provided for significantly more control of the superabsorbent material particles in the substrate for Codes A and B (substrates  210 A and  210 B) in comparison to Code C (substrate  210 C), and thus, more control over the relative thickness of the second layer  84  including such particulates. 
     Specifically, as documented in Table 3, Code A and Code B providing substrates  210 A and  210 B utilizing a divider  36  to separate first layer  82  from second layer  84  provided a second layer  84  relative thickness of 34% and 53% of the total thickness of the substrate  210 A,  210 B, respectively, whereas Code C providing substrate  210 C that was manufactured without utilizing a divider  36  provided a relative thickness of the second layer  84  that was 70% of the total thickness of the substrate  210 C. Because the headbox  16  and divider  36  within the headbox  16  were configured to provide a target thickness in which the first layer  82  and a second layer  84  had equal thickness, Codes A and B displayed the ability to control the thickness of the second layer  84  including particulates (such as SAM particulates) to a closer degree to the target thickness. In fact, Code C producing substrate  210 C did not appear to provide a two layer structure at all, as the superabsorbent particles and the fibers intended to be provided in a second layer were found to distribute largely over a significant portion of the substrate  210 C, including particularly near an upper surface  92  of the substrate  210 C.  FIG.  9 C  also depicts that fibers intended for the intake and distribution zones of the upper layer migrated towards the bottom surface  94  of the substrate  210 C. Substrate  210 C thus would not perform as well from an intake or distribution functionality without the proper fiber control. Therefore, use of a divider  36  including a z-directional divider  64  provides enhanced z-directional control of substrates  210 A and  210 B by providing higher levels of control of the relative thickness of the second layer  84 , but also helps to provide a two layer  82 ,  84  structure to the substrate  210 A,  210 B whatsoever. This control over the fibers and/or particulates is surprising from the standpoint that the foam continues to be mobile and prone to mixing until it exits the headbox  16  and is completely dewatered. 
     The configuration of the divider  36  extending at least 50% of the length L of the headbox  16 , or more preferably at least 60% of the length L of the headbox  16 , was believed to provide enhanced control of the mixing of the first layer  82  and the second layer  84  of the substrate  210  at the interface  81  between layers  82 ,  84 . Preferrable substrates can include a second layer  84  that includes particulates (e.g., SAM particles) that has a relative thickness with less than 20% variance from the target relative thickness, or more preferably, a relative thickness that is less than 15% variance from the target relative thickness, or even more preferably, less than 10% variance from the target relative thickness. In some embodiments, preferable substrates can include a second layer  84  of a substrate  210 A,  210 B that can have particulates (e.g., SAM particles) and have a relative thickness less than 70% of the overall thickness of the structure, or more preferably, less than 60%, or in some embodiments, less than 55% of the absorbent structure. Thus, it can be seen that by providing a divider  36  creating a z-directional divider  64 , a layer  84  can be produced to a relative thickness closer to a desired relative thickness, and therefore, can improve the overall purity of that layer  84  with respect to the resultant substrate. 
     Test Methods 
     Purity Gradient Test Method 
     The Purity Gradient Test Method can be used to measure the purity gradient of an interface  81  between two adjacent zones in a substrate, where the zones are in an external layer of the substrate. A digital camera, (such as a Sony DXC-5500), is used to take five digital images of each sample from a top-down view for purity gradient testing. The sample should be placed such that the layer including the zones and interface  81  being analyzed is facing up. The camera is set to black and white mode. The images are to be taken in an internal room with its lighting on. An additional light source is to be mounted on each side of the sample to be photographed. A Polaroid MP-4 Land Camera 44-02 stand (has ability to locate two lights on each side of sample) or similar set up is to be used to provide direct lighting on the surface of the sample. Care should be taken to ensure that no shadows are projected on the sample when taking the images with the digital camera. 
     The camera should capture images that encompass the interface  81  between adjacent zones for which the purity gradient is desired to evaluate, as well as at least a portion of each of such adjacent zone. For example, for samples described herein, the width of each image was approximately 14 centimeters (5.5 inches). A ruler is placed near the bottom of each image in order to set the length scale in later analysis. The five images taken for each sample should be taken at different machine directional locations along the interface  81 . The camera is focused on the sample using the automatic focus of the digital camera. In black and white mode, the images have the ability to discern the difference between different fiber types via color differences in the fibers in the software analytical tool. 
     ImageJ software should be downloaded (such as from the National Institute of Health (NIH)—https://imagej.nih.gov/ij/) on to a computer. The five images for each sample are loaded into the ImageJ software. Once an image is opened in ImageJ, Auto BC is set on the image to normalize the images and the grayscale for the light fibers in one zone should be set to be the same as the light fibers in the other images, and likewise for the dark fibers (or particulates) of a different zone with dark fibers (or particulates) of that zone in the other images. The entire image is selected for analysis using the selection tool in the ImageJ software. Thus, the analyzed area and width is the same for each of the five images for each sample. The Plot Profile function in ImageJ software was used to obtain the gray scale as a function of distance across the image width. The Plot Profile function averages the gray scale for the selected area across the width of the image, and the average gray scale is plotted as a function of distance across the image. 
       FIG.  11    illustrates ImageJ software Plot Profile function for two exemplary codes. As illustrated in  FIG.  11   , the transition width TW for each image is measured as the length of the interface determined from the gray scale plot based on where the gray scale began to increase from white and ending where it plateaued in the dark region. To account for the noise in the plot, the interface is taken to begin where the increase begins and continues to a grayscale of &gt;30% over the starting or baseline level. For the zone surface image, a ruler was placed in each image in order to set the length scale as noted above. For purposes herein, the purity gradient transition width value for a sample interface  81  is the average transition width of the five images for each sample. 
     The transition slope is measured as the (change in grayscale)/(transition width), or the slope of a line connecting data points at the left and right sides of the transition zone as depicted in  FIG.  11   . The change in gray scale was the same for each image after the AutoBC normalization. For purposes herein, the purity gradient transition slope value for a sample interface  81  is the average transition slope of the five images for each sample. 
     Layer Relative Thickness Test Method 
     The Layer Relative Thickness Test Method is used to determine a particular layer thickness of a z-directional layer of a sample including two or more z-directional layers. For each sample substrate, seven cross-sectional images are taken. Each cross-sectional sample is imaged with conventional microCT equipment, such as Bruker Skyscan 1272, to provide an image such as those illustrated in  FIGS.  9 A- 9 C . The width of each sample for cross-sectional imaging is about 7 mm. 
     ImageJ software should be downloaded (such as from the National Institute of Health (NIH)—https://imagej.nih.gov/ij/) on to a computer. The seven images for each sample are loaded into the ImageJ software, converted to grayscale, and rotated ninety degrees, such that the interface  81  between separate layers  82 ,  84  is oriented in a generally vertical fashion. The image is made grayscale using the Make Binary function in ImageJ. Auto BC is set on the image to normalize the images and the grayscale for the light fibers in one layer should be set to be the same as the light fibers in the other images, and likewise for the dark fibers (or particles) of a different layer with dark fibers (or particles) of that layer in the other images. 
     As illustrated in  FIG.  12   , the layer thickness LT is measured by measuring the width of the layer where SAM particles are present using the grayscale plot from the plot profile function and setting an appropriate threshold to distinguish the region such as the mid-point of grayscale between the pure fiber region and the pure SAM region. The total thickness for a sample is the width of the area selected for the plot profile function. For purposes herein, a layer relative thickness for an image of a substrate is the measured layer thickness divided by the total thickness for that image. For purposes herein, a layer relative thickness percentage of the total thickness of a substrate is calculated by averaging the layer relative thickness for the seven images. 
     Embodiments 
     Embodiment 1: A method for manufacturing a substrate, the method comprising: providing a first supply of fibers; providing a second supply of fibers; providing a headbox, the headbox comprising: a machine direction; a cross-direction; and a first cross-directional divider that separates a first zone of the headbox from a second zone of the headbox in a cross-directional manner; transferring the first supply of fibers and the second supply of fibers to the headbox; and transferring the first supply of fibers and the second supply of fibers through the headbox to provide the substrate. 
     Embodiment 2: The method of embodiment 1, wherein the first supply of fibers is transferred to the first zone of the headbox and the second supply of fibers is transferred to the second zone of the headbox; and wherein transferring the first supply of fibers and the second supply of fibers through the headbox provides the substrate with a first zone comprising fibers from the first supply of fibers and a second zone comprising fibers from the second supply of fibers. 
     Embodiment 3: The method of embodiment 1 or 2, wherein the headbox further comprises a z-directional divider comprising a first surface and a second surface, the second surface being opposite from the first surface, the z-directional divider providing a first z-directional layer in the headbox and a second z-directional layer in the headbox. 
     Embodiment 4: The method of any one of the preceding embodiments, further comprising a second cross-directional divider that separates the second zone of the headbox from a third zone of the headbox. 
     Embodiment 5: The method of embodiment 3, further comprising a second cross-directional divider that separates the second zone of the headbox from a third zone of the headbox; wherein the first zone, the second zone, and the third zone each form part of the first z-directional layer of the headbox. 
     Embodiment 6: The method of embodiment 5, wherein the first supply of fibers are transferred to the second zone of the headbox in the first z-directional layer of the headbox and the second supply of fibers are transferred to the second z-directional layer of the headbox; and wherein transferring the first supply of fibers and the second supply of fibers through the headbox provides the substrate with a first layer comprising fibers from the first supply of fibers and a second layer comprising fibers from the second supply of fibers. 
     Embodiment 7: The method of embodiment 6, wherein the first supply of fibers comprise synthetic fibers and the second supply of fibers comprise absorbent fibers. 
     Embodiment 8: The method of embodiment 5, further comprising: providing a third supply of fibers; transferring the third supply of fibers to the headbox; and transferring the third supply of fibers through the headbox to provide the substrate. 
     Embodiment 9: The method of embodiment 8, wherein the first supply of fibers are transferred to the first zone and the third zone of the first z-directional layer of the headbox, the second supply of fibers are transferred to the second zone of the first z-directional layer of the headbox, and the third supply of fibers are transferred to the second z-directional layer of the headbox. 
     Embodiment 10: The method of embodiment 9, wherein the first supply of fibers comprise at least one type of distribution fiber; the second supply of fibers comprise at least one type of intake fiber; and the third supply of fibers comprise absorbent fibers. 
     Embodiment 11: The method of any one of the preceding embodiments, further comprising: providing a supply of particulates to the headbox; and transferring the supply of particulates through the headbox to provide the substrate. 
     Embodiment 12: The method of embodiment 11, wherein the particulates comprise superabsorbent material. 
     Embodiment 13: The method of any one of the preceding embodiments 1, wherein the first supply of fibers are provided in a first foam slurry and the second supply of fibers are provided in a second foam slurry. 
     Embodiment 14: A divider for a headbox including a cross direction and a machine direction, the divider comprising: a first surface; a second surface, the second surface being opposite from the first surface; a width defined in the cross direction; a length defined in the machine direction; and a first cross-directional divider extending away from the first surface, the first cross-directional divider comprising a cross-directional thickness and a machine-directional length. 
     Embodiment 15: The divider of embodiment 14, wherein the first cross-directional divider extends away from the first surface in a directional substantially perpendicular to a plane defined by the first surface of the divider. 
     Embodiment 16: The divider of embodiment 14 or 15, wherein the first cross-directional divider further comprises a proximal end and a distal end, and wherein a height of the first cross-directional divider as measured at the proximal end of the first cross-directional divider is greater than a height of the first cross-directional divider as measured at the distal end of the first cross-directional divider. 
     Embodiment 17: The divider of any one of embodiments 14-16, further comprising a second cross-directional divider. 
     Embodiment 18: The divider of embodiment 17, wherein the second cross-directional divider extends away from the first surface of the divider and is spaced apart from the first cross-directional divider in the cross direction. 
     Embodiment 19: The divider of claim  17 , wherein the second cross-directional divider extends away from the second surface of the divider. 
     Embodiment 20: A headbox for manufacturing a substrate, the headbox including a machine direction and a cross direction, the headbox comprising: an inlet; an outlet; an internal chamber; and a divider at least partially within the internal chamber, the divider comprising: a first surface; a second surface, the second surface being opposite from the first surface; a width defined in the cross direction; a length defined in the machine direction; and a first cross-directional divider extending away from the first surface of the divider, the first cross-directional divider comprising a cross-directional thickness and a machine-directional length; wherein the divider separates a first z-directional layer of the headbox from a second z-directional layer of the headbox; and wherein the first cross-directional divider separates a first zone of the headbox from a second zone of the headbox in a cross-directional manner, the first zone and the second zone being in the first z-directional layer. 
     Embodiment 21: The headbox of embodiment 20, wherein the divider further comprises a second cross-directional divider. 
     Embodiment 22: A method for manufacturing a substrate including a first layer and a second layer, the method comprising: providing a first supply of fibers; providing a supply of particulates; providing a headbox, the headbox comprising: a machine direction; a cross-direction; a z-direction, the z-direction being perpendicular to a plane defined by the machine direction and the cross-direction; and a divider comprising a first surface, a second surface opposite the first surface, a width extending in the cross-direction, and a length extending in the machine direction, the divider separating a first z-directional layer of the headbox from a second z-directional layer of the headbox; setting a z-directional position of the divider in the headbox to provide a target relative thickness setting of the second z-directional layer of the headbox; transferring the first supply of fibers and the supply of particulates to the headbox such that the first supply of fibers enter the first z-directional layer of the headbox and the supply of particulates enter the second z-directional layer of the headbox; and controlling the first supply of fibers and the supply of particulates through the headbox to a forming surface such that a relative thickness of the second layer of the substrate is provided with less than 20% variation of the target relative thickness setting of the second z-directional layer of the headbox. 
     Embodiment 23: The method of embodiment 22, wherein the controlling of the first supply of fibers and the supply of particulates through the headbox comprises providing a divider including a length in the machine direction of greater than 50% of a length of the headbox. 
     Embodiment 24: The method of embodiment 22 or 23, wherein a relative thickness of a second layer of the substrate is provided with less than 10% variation of the target relative thickness setting of the second z-directional layer of the headbox. 
     Embodiment 25: The method of any one of embodiments 22-24, wherein the target relative thickness setting of the second z-directional layer of the headbox is 50% of a total thickness of the headbox. 
     All documents cited in the Detailed Description are, in relevant part, incorporated herein by reference; the citation of any document is not to be construed as an admission that it is prior art with respect to the present invention. To the extent that any meaning or definition of a term in this written document conflicts with any meaning or definition of the term in a document incorporated by references, the meaning or definition assigned to the term in this written document shall govern. 
     While particular embodiments have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.