Patent Publication Number: US-6911268-B2

Title: High strength hot-dip galvanized or galvannealed steel sheet having improved plating adhesion and press formability and process for producing the same

Description:
BACKGROUND OF THE INVENTION 
     1. Field of the Invention 
     The present invention relates to a high strength steel sheet useful as automobile, building, electric or other members and a process for producing the same. More particularly, the present invention relates to a high strength hot-dip galvanized steel sheet which has improved bulging formability at the time of press forming and improved plating adhesion and a process for producing the same. The term “high strength hot-dip galvanized or galvannealed steel sheet” as used herein includes high strength hot-dip galvanized steel sheets (GI) and high strength hot-dip galvannealed steel sheets (GA). 
     2. Background Art 
     To meet a demand for lower fuel consumption of automobiles and the like in recent years, studies have been made on a weight reduction of members such as cross members and side members of automobiles and the like. Regarding materials, studies on an increase in strength have been made from the viewpoint of ensuring strength even in reduced thickness of members. 
     In general, however, increasing the strength of materials results in deteriorated press formability of the materials. Therefore, in order to realize the weight reduction of the above members, steel sheets capable of simultaneously satisfying good press formability and high strength are required, and the development of such steel sheets has been desired in the art. 
     Among index values for formability are included elongation and, in addition, n value and r value in tensile tests. At ask to be accomplished in recent years is to simplify the step of pressing through one-piece molding. Therefore, what is particularly important is that the n value corresponding to uniform elongation is large. 
     To this end, hot rolled steel sheets or cold rolled steel sheets, which utilize transformation induced plasticity of retained austenite present in steel, have been developed. In these steel sheets, only about 0.07 to 0.4% of carbon (C), about 0.3 to 2.0% of silicon (Si), and about 0.2 to 2.5% of manganese (Mn) are used as basic alloying elements without incorporating any expensive alloying element, and heat treatment characterized by, after annealing in a two-phase region, performing bainite transformation at a temperature of about 300 to 450° C. is carried out to allow retained austenite to exist in the metallurgical structure. These steel sheets are disclosed, for example, in Japanese Patent Laid-Open Nos. 230715/1989 and 217425/1990. 
     Steel sheets, to which the above technique can be applied, are not limited to cold rolled steel sheets produced by continuous annealing. For example, Japanese Patent Laid-Open No. 79345/1989 discloses that this technique can also be applied to hot rolled steel sheets by controlling cooling temperature of a coiling or a runout table. 
     The production of automobiles of higher grade has led to a tendency toward coating of automobile members with a view to improving corrosion resistance and appearance. At the present time, galvanized steel sheets are used in most of the automobile members except for specific members mounted within the automobiles. Accordingly, from the viewpoint of corrosion resistance, coating which is useful for these steel sheets is hot-dip galvanizing, or hot-dip galvannealing wherein, after hot-dip galvanizing, alloying treatment is carried out. Among these high-tensile steel sheets, steel sheets having a high silicon content are likely to form an oxide film on the surface thereof. This poses problems including that very small non-coated sites occur in hot-dip galvanizing, or plating adhesion of the worked part after the completion of alloying is deteriorated. Thus, at the present time, any high-silicon-base high-tensile and high-ductile hot-dip galvannealed steel sheets possessing excellent plating adhesion of the worked part and, at the same time, excellent corrosion resistance have not been put into practical use. 
     In the steel sheets disclosed, for example, in Japanese Patent Laid-Open Nos. 230715/1989 and 217425/1990, however, it should be noted that 0.3 to 2.0% of silicon is contained and the retained austenite is ensured by utilizing unique bainite transformation of the steel. Therefore, the contemplated metallurgical structure cannot be provided without considerably close control of cooling after annealing in an intercritical temperature range or holding in a temperature range of about 300 to 450° C., and strength and elongation disadvantageously deviate from the target range. 
     This heat history can be realized on a commercial scale by continuous annealing equipment or a runout table after hot rolling and the step of coiling. Since, however, the transformation of austenite is rapidly completed at 450 to 600° C., control should be carried out so that the residence time is short particularly at 450 to 600° C. Further, even at 350 to 450° C., the metallurgical structure undergoes a significant change depending upon the holding time. Therefore, when the heat treatment conditions have deviated from predetermined conditions, only unsatisfactory strength and elongation are provided. 
     Further, since the residence time at 450 to 600° C. is long and a large amount of silicon, which deteriorates suitability for coating, is contained as an alloying element, the production of a coated steel sheet by passing the steel sheet through hot-dip galvanizing equipment is impossible. After all, poor surface corrosion resistance of the steel sheet containing about 0.3 to 2.0% of silicon disadvantageously hinders the widespread commercial use of the steel sheets. 
     In order to solve the above problem, for example, Japanese Patent Laid-Open Nos. 247586/1993 and 145788/1994 disclose steel sheets having suitability for coating improved by regulating the content of silicon. In the technique disclosed in the above publications, retained austenite is formed by adding aluminum (Al) instead of silicon. However, as with silicon, aluminum is more likely to be oxidized than iron (Fe). Specifically, aluminum is likely to form an oxide film on the surface of the steel sheet. Therefore, disadvantageously, satisfactory plating adhesion cannot be ensured. 
     Further, for example, Japanese Patent Laid-Open Nos. 333552/1992 and 346644/1992 disclose a hot-dip galvannealing method for a high-silicon-base high-strength steel sheet. In this method, after pre-coating of nickel (Ni), the pre-coated steel sheet is rapidly heated at a low temperature and is subjected to hot-dip galvanizing, followed by alloying treatment. Since, however, this method requires nickel pre-coating, disadvantageously, equipment for nickel pre-coating should be newly provided. 
     SUMMARY OF THE INVENTION 
     The present inventors have made studies on the solution of the above problems of the prior art and on an improvement in surface corrosion resistance and, as a result, have found the chemical composition and characteristics of the metallurgical structure of a high strength steel sheet which can be produced even in hot-dip galvanizing equipment and has good press formability. 
     An object of the present invention is to solve the above problems of the prior art and to provide a high strength hot-dip galvanized or galvannealed steel sheet possessing good press formability and plating adhesion and a production process which can efficiently produce this steel sheet. 
     The present inventors have made extensive and intensive studies on the relationship between suitability for coating and steel constituents with a view to providing a high strength hot-dip galvanized or galvannealed steel sheet and a production process thereof which can attain the above object of the present invention. This has led to the completion of the present invention. 
     (1) According to the present invention, there is provided a high strength hot-dip galvanized or galvannealed steel sheet having improved plating adhesion and press formability, said steel sheet comprising: 
     (a) a steel sheet substrate comprising, by weight, 
     carbon (C): 0.05 to 0.2%, 
     silicon (Si): 0.2 to 2.0%, 
     manganese (Mn): 0.2 to 2.5%, and 
     aluminum (Al): 0.01 to 1.5%, 
     said silicon and said aluminum having a mutual relationship represented by formula
 
0.4(%)≦Si+0.8Al (%)≦2.0%,
 
     said steel sheet substrate further comprising at least one member selected from the group consisting of 
     (i) 0.003 to 1.0% of tin (Sn), 
     (ii) 0.005 to 1.0% in total of at least one member selected from antimony (Sb), bismuth (Bi), and selenium (Se), 
     (iii) 0.005 to 1.0% in total of at least one member selected from beryllium (Be), magnesium (Mg), calcium (Ca), and zirconium (Zr), and 
     (iv) 0.005 to 1.0% in total of at least one member selected from scandium (Sc), yttrium (Y), lanthanum (La), and cerium (Ce), with the balance consisting of iron (Fe) and unavoidable impurities, the volume fraction of retained austenite in the steel structure being 2 to 20%; and 
     (b) a zinc (Zn) coated layer provided on said steel sheet substrate. 
     (2) In a preferred embodiment of the present invention, said steel sheet substrate further comprises, by weight, at least one member selected from nickel (Ni): not more than 2.0%, copper (Cu): not more than 2.0%, and cobalt (Co): less than 0.3%. 
     (3) In a preferred embodiment of the present invention, said steel sheet substrate further comprises, by weight, at least one member selected from molybdenum (Mo): less than 0.5%, chromium (Cr): less than 1.0%, vanadium (V): less than 0.3%, titanium (Ti):less than 0.06%, niobium (Nb): less than 0.06%, and boron (B): less than 0.01%. 
     (4) In a preferred embodiment of the present invention, said zinc coated layer is a galvannealed layer comprising zinc (Zn): 80 to 91%, iron (Fe): 8 to 15%, and aluminum (Al) not more than 1%. 
     (5) In a preferred embodiment of the present invention, said zinc coated layer is a galvanized layer comprising zinc: not less than 80% and aluminum: not more than 1%. 
     (6) According to the present invention, there is provided a process for producing the above hot-dip galvanized or galvannealed steel sheet having a galvannealed layer of the present invention, said process comprising the steps of: 
     providing a cold rolled steel sheet having the above chemical composition of the steel sheet substrate; 
     annealing the cold rolled steel sheet for 10 sec to 6 min in the intercritical temperature range of 650 to 900° C., then cooling the annealed steel sheet to 350 to 500° C. at a cooling rate of 2 to 200° C./sec, and subjecting the cooled steel sheet to hot-dip galvannealing process; and then 
     holding the coated steel sheet in the temperature range of 450 to 600° C. for 5 sec to 2 min and then cooling the coated steel sheet to 250° C. or below at a cooling rate of not less than 5° C./sec. 
     (7) According to the present invention, there is provided another process for producing the above hot-dip galvanized or galvannealed steel sheet having a hot-dip galvannealed layer of the present invention, said process comprising the steps of: 
     providing a cold rolled steel sheet having the above chemical composition of the steel sheet substrate; 
     annealing the cold rolled steel sheet for 10 sec to 6 min in the intercritical temperature range of 650 to 900° C., then cooling the annealed steel sheet to 350 to 500° C. at a cooling rate of 2 to 200° C./sec, holding the cooled steel sheet in said cooling temperature range for not more than 10 min, and then subjecting the cooled steel sheet to hot-dip galvannealed process; and then 
     holding the coated steel sheet in the temperature range of 450 to 600° C. for 5 sec to 2 min and then cooling the coated steel sheet to 250° C. or below at a cooling rate of not less than 5° C./sec. 
     (8) According to the present invention, there is provided a process for producing the above hot-dip galvanized or galvannealed steel sheet having a galvanized layer of the present invention, said process comprising the steps of: 
     providing a cold rolled steel sheet having the above chemical composition of the steel sheet substrate; 
     annealing the cold rolled steel sheet for 10 sec to 6 min in the intercritical temperature range of 650 to 900° C., then cooling the annealed steel sheet to 350 to 500° C. at a cooling rate of 2 to 200° C./sec, and subjecting the cooled steel sheet to hot-dip galvanizing process; and then 
     cooling the coated steel sheet to 250° C. or below at a cooling rate of not less than 5° C./sec. 
     (9) According to the present invention, there is provided another process for producing the above hot-dip galvanized or galvannealed steel sheet having a galvanized layer of the present invention, said process comprising the steps of: 
     providing a cold rolled steel sheet having the above chemical composition of the steel sheet substrate; 
     annealing the cold rolled steel sheet for 10 sec to 6 min in the intercritical temperature range of 650 to 900° C., then cooling the annealed steel sheet to 350 to 500° C. at a cooling rate of 2 to 200° C./sec, holding the cooled steel sheet in said cooling temperature range for not more than 10 min, and then subjecting the cooled steel sheet to hot-dip galvanizing process; and then 
     cooling the coated steel sheet to 250° C. or below at a cooling rate of not less than 5° C./sec. 
    
    
     DETAILED DESCRIPTION OF THE INVENTION 
     (a) Steel Sheet Substrate 
     In the steel sheet substrate according to the present invention, the chemical composition is limited from the viewpoint of providing high strength hot-dip galvanized or galvannealed steel sheets possessing good press formability and good plating adhesion. The reasons for the limitation of the chemical composition will be described in detail. 
     Basic Constituents 
     Carbon (C) is an austenite stabilizer. In the intercritical temperature range and in the bainite transformation temperature range, carbon migrates from ferrite and is enriched in austenite. As a result, even after cooling to room temperature, 2 to 20% of chemically stabilized austenite is present and improves formability through transformation induced plasticity. If the content of carbon is less than 0.05%, then it is difficult to ensure not less than 2% of retained austenite, making it impossible to attain the contemplated effect. On the other hand, a carbon content exceeding 0.2% should be avoided, because the weldability is deteriorated. 
     Silicon (Si) does not dissolve in cementite and suppresses the precipitation of cementite. By virtue of this action, the transformation from austenite to cementite at 350 to 600° C. is delayed, during which time the enrichment of carbon in austenite is promoted. This can enhance the chemical stability of austenite, causes transformation induced plasticity, and thus enables retained austenite, which can improve the formability, to be ensured. If the content of silicon is less than 0.2%, then the effect of silicon cannot be attained. On the other hand, when the silicon content is excessively high, the suitability for coating is deteriorated. Therefore, the silicon content should be not more than 2.0%. 
     Manganese (Mn) is an austenite former. Further, manganese can prevent the decomposition of austenite to pearlite in the course of cooling to 350 to 600° C. after annealing in the intercritical temperature range. Therefore, manganese acts so that retained austenite is contained in the metallurgical structure after cooling to room temperature. When the content of manganese is less than 0.2%, in order to prevent the decomposition of austenite to pearlite, the cooling rate should be increased to such a level that could not be controlled on a commercial scale. This is disadvantageous. On the other hand, when the manganese content exceeds 2.5%, the formation of a banded structure is significant, resulting in deteriorated properties of the steel sheet. Further, in this case, upon spot welding, the spot weld zone is disadvantageously likely to be broken within the nugget. Furthermore, increasing the manganese content deteriorates the suitability for coating. 
     Aluminum (Al) is used as a deoxidizer. At the same time, as with silicon, aluminum does not dissolve in cementite and, in holding the steel sheet at 350 to 600° C., suppresses the precipitation of cementite and delays the transformation from austenite to cementite. Since, however, aluminum has higher ferrite forming ability than silicon, the transformation starts in an earlier stage. In this case, even when the holding time is very short, carbon is enriched in austenite from the start of annealing in the intercritical temperature range. This can enhance the chemical stability, and thus, the amount of martensite, which deteriorates the formability, present in the metallurgical structure after cooling to room temperature is very small. Therefore, the coexistence of aluminum and silicon can reduce a change in strength and elongation depending upon conditions for holding at 350 to 600° C., and steel sheets having a combination of high strength with good press formability can be easily provided. For attaining the above effect, the addition of aluminum in an amount of not less than 0.01% is necessary. The addition of aluminum in an amount of not less than 0.1% is preferred. In addition, aluminum, together with silicon, should be added so that the content of “Si+0.8Al” is not less than 0.4%. On the other hand, as with the case of silicon, an aluminum content exceeding 1.5% deteriorates plating adhesion and thus should be avoided. Furthermore, from the viewpoint of ensuring the plating adhesion, aluminum, together with silicon, should be added so that the content of “Si+0.8Al” is not more than 2.0%. 
     Selective Basic Constituents 
     Tin (Sn), antimony (Sb), bismuth (Bi), selenium (Se), beryllium (Be), magnesium (Mg), calcium (Ca), zirconium (Zr), scandium (Sc), yttrium (Y), lanthanum (La), and cerium (Ce) are elements which are most important to the present invention. The addition of at least one of these elements can improve the wettability and the plating adhesion of the steel sheet by hot-dip galvanizing or galvannealing. As a result, steel sheets having excellent suitability for coating and formability can be produced. 
     In steel sheets containing silicon and aluminum, when coated steel sheets are produced in a continuous hot-dip galvanizing line, oxides of silicon and aluminum are formed on the surface of the steel sheets, resulting in deteriorated plating adhesion. However, the addition of at least one of the above elements can improve the suitability of the steel sheets for coating. 
     In a preferred embodiment of the present invention, tin is added in an amount of 0.003 to 1.0%. In steel sheets containing silicon and aluminum, when coated steel sheets are produced in a continuous hot-dip galvanizing line, oxides of silicon and aluminum are formed on the surface of the steel sheets and deteriorate the plating adhesion to the steel sheets. However, since tin is an element which is less likely to be oxidized than iron and, at the same time, is likely to segregate on the surface of steel sheets, tin is enriched in the surface layer of the steel sheets to suppress the formation of oxides of silicon and aluminum, whereby the deterioration in plating adhesion is prevented. When the content of tin is less than 0.003%, satisfactory plating adhesion cannot be provided in the steel of the present invention. When more significant development of the above effect is desired, the addition of tin in an amount of not less than 0.005% is preferred. The amount of tin added is more preferably not less than 0.008%. On the other hand, when tin is added in an amount of more than 1.0%, cracking disadvantageously occurs at the time of hot rolling. As a result, good appearance of coating cannot be ensured. When better appearance of coating is desired, the addition of tin in an amount of not more than 0.5% is preferred. 
     In another preferred embodiment of the present invention, 0.005 to 1.0% in total of at least one of antimony, bismuth, and selenium is added. Antimony, bismuth, and selenium are likely to cause surface segregation and thus are enriched in the surface layer of the steel sheet to suppress the formation of oxides of silicon and aluminum. Consequently, even in the case of high-silicon and/or high-aluminum steel, the deterioration in plating adhesion can be prevented. This effect can be attained by adding at least one of antimony, bismuth, and selenium. When the total amount of antimony, bismuth, and selenium is not less than 0.005%, satisfactory plating adhesion can be provided. When a further improved effect is desired, the addition of at least two of these elements in a total amount of not less than 0.008% is preferred. The addition of more than 1.0% in total of at least one of antimony, bismuth, and selenium causes surface segregation of these elements in an excessive amount. As a result, good appearance of coating cannot be ensured. In order to maintain good appearance of coating, the addition of not more than 0.5% in total of at least one of antimony, bismuth, and selenium is preferred. 
     As with antimony, bismuth, and selenium, arsenic (As) tellurium (Te), polonium (Po), and germanium (Ge) can improve suitability of the steel sheet for coating. Since, however, arsenic (As), tellurium (Te), polonium (Po), and germanium (Ge) are toxic elements and are very high in cost, these elements are excluded from the additive elements in the present invention. 
     In still another preferred embodiment of the present invention, 0.005 to 1.0% in total of at least one of beryllium (Be), magnesium (Mg), calcium (Ca), and zirconium (Zr) is added. Since beryllium (Be), magnesium (Mg), calcium (Ca), and zirconium (Zr) are very likely to form oxides, they can suppress the formation of silicon oxide and/or aluminum oxide which deteriorate suitability of high-silicon steel and/or high-aluminum steel for coating. This contributes to an improvement in suitability for coating. This effect can be attained by adding at least one of beryllium (Be), magnesium (Mg), calcium (Ca), and zirconium (Zr). The addition of not less than 0.005% in total of at least one of beryllium (Be), magnesium (Mg), calcium (Ca), and zirconium (Zr) can provide satisfactory plating adhesion. When a further improved effect is desired, the addition of at least two of these elements in a total amount of not less than 0.008% is preferred. The addition of more than 1.0% in total of at least one of beryllium (Be), magnesium (Mg), calcium (Ca), and zirconium (Zr) results in an increased amount of the formation of oxides of these elements and consequently makes it impossible to ensure good appearance of coating. 
     In a further preferred embodiment of the present invention, 0.005 to 1.0% in total of at least one of scandium (Sc), yttrium (Y), lanthanum (La), and cerium (Ce) is added. Since scandium (Sc), yttrium (Y), lanthanum (La), and cerium (Ce) are also likely to form oxides, they can suppress the formation of silicon oxide and/or aluminum oxide which deteriorate suitability of high-silicon steel and/or high-aluminum steel for coating. This contributes to an improvement in suitability for coating. Further, at the time of oxidation, scandium (Sc), yttrium (Y), lanthanum (La), and cerium (Ce) vigorously act on surface irregularities of the steel sheet. This contributes to improved plating adhesion. This effect can be attained by adding at least one of scandium (Sc), yttrium (Y), lanthanum (La), and cerium (Ce). The addition of not less than 0.005% in total of at least one of scandium (Sc), yttrium (Y), lanthanum (La), and cerium (Ce) can provide satisfactory plating adhesion. When a further improved effect is desired, the addition of at least two of these elements in a total amount of not less than 0.008% is preferred. The addition of more than 1.0% in total of at least one of scandium (Sc), yttrium (Y), lanthanum (La), and cerium (Ce) results in the formation of an increased amount of oxides of these elements and consequently makes it impossible to ensure good appearance of coating. 
     As with scandium (Sc), yttrium (Y), lanthanum (La), and cerium (Ce), rare earth elements such as neodymium (Nd), gadolinium (Gd), and dysprosium (Dy) can improve the suitability for coating. These elements, however, are very high in cost and thus are excluded from additive elements in the present invention. 
     Further, the addition of a combination of two or more members, which are different from each other or one another in effect, selected from the group consisting of (i) tin (Sn), (ii) at least one member selected from antimony (Sb), bismuth (Bi), and selenium (Se), (iii) at least one member selected from beryllium (Be), magnesium (Mg), calcium (Ca), and zirconium (Zr), and (iv) at least one member selected from scandium (Sc), yttrium (Y), lanthanum (La), and cerium (Ce) can ensure better suitability for coating. 
     The addition of not less than 0.005% in total of at least one of these elements can provide satisfactory plating adhesion. When the total amount of at least one of these elements exceeds 1.0%, good appearance of coating cannot be ensured. 
     Optional Constituents 
     In the steel sheet according to the present invention, the above-described elements constitute basic constituents. In addition to these elements and iron, for example, at least one of nickel (Ni), copper (Cu), and cobalt (Co), which are austenite formers and, at the same time, can improve strength and plating adhesion, may be added. Also, at least one of molybdenum (Mo), chromium (Cr), vanadium (V), boron (B), titanium (Ti), niobium (Nb), and boron (B), which are hardenability improving elements (constituent (a) group), and/or at least one of REM (rare earth metal), calcium (Ca) zirconium (Zr), and magnesium (Mg), which reduce inclusions (constituent (b) group), may be added optionally together with at least one of the above-described elements, that is, nickel, copper, and cobalt, to the above basic constituents. 
     The reasons for the limitation of the contents of the above elements in the steel sheet will be described in detail. 
     Nickel (Ni), copper (Cu), and cobalt (Co), as with tin (Sn), are less likely to be oxidized than iron and thus are enriched on the surface of the steel sheet at the time of annealing to suppress the formation of oxides of silicon (Si), aluminum (Al) and the like which inhibit plating adhesion. Further, nickel (Ni), copper (Cu), and cobalt (Co), as with manganese (Mn), are austenite formers and, at the same time, as with silicon (Si) and aluminum (Al), do not dissolve in cementite. Therefore, in holding the steel sheet at 350 to 600° C., nickel (Ni), copper (Cu), and cobalt (Co) suppress the precipitation of cementite and delay the progress of transformation. Therefore, the addition of at least one of nickel (Ni), copper (Cu), and cobalt (Co) can provide better steel sheets. When nickel is added in an amount exceeding 2.0%, the contemplated effect is saturated. For this reason, the upper limit of the nickel content is 2.0%. When copper (Cu) is added in an amount exceeding 2.0%, the quality of the steel sheet is deteriorated as a result of precipitation of copper (Cu). For this reason, the upper limit of the copper content is 2.0%. Since cobalt (Co) is an expensive metal, the upper limit of the cobalt content is 0.3%. When tin and copper (Co) are added in combination, preferably, tin and copper satisfy a mutual relationship represented by formula “Sn(%)+Cu(%)&lt;3×Ni(%)” from the viewpoint of preventing hot cracking caused by tin and copper. 
     Molybdenum (Mo), chromium (Cr), vanadium (V), titanium (Ti), niobium (Ni), and boron (B) are strength improving elements, and REM, calcium (Ca), zirconium (Zr), and magnesium (Mg) are elements which combine with sulfur in the steel to reduce inclusions, thereby ensuring good elongation of the steel. Preferably, the steel sheet substrate further comprises molybdenum (Mo): less than 0.5%, chromium (Cr): less than 1.0%, vanadium (V): less than 0.3%, titanium (Ti): less than 0.06%, niobium (Nb): less than 0.06%, and boron (B): less than 0.01%. The effect of these elements is saturated when these elements are added in the upper limit amount. When the above elements are added in an amount exceeding the upper limit, the cost is increased. Therefore, when these elements are added, the amounts of the elements added should be not more than the above respective upper limits. 
     When phosphorus (P), sulfur (S), nitrogen (N), oxygen (O) and other elements, which are unavoidably included in general steels, are contained as steel constituents, the effect of the present invention is not deteriorated at all. 
     Further, in the coated steel sheet according to the present invention, in addition to the above elements and unavoidable impurities, elements, which are generally incidentally present in steels, maybe contained as incidental constituents in such an amount that does not sacrifice the properties of the coated steel sheet. 
     The ductility of the steel sheet of the present invention as the final product varies depending upon the volume fraction of retained austenite contained in the product. The retained austenite contained in the metallurgical structure is stably present when the steel sheet does not undergo any deformation. Upon the application of deformation, however, the retained austenite is transformed to martensite to develop transformation induced plasticity. Therefore, in the steel sheet containing retained austenite in the metallurgical structure, good formability can be realized while enjoying high strength. 
     When the volume fraction of retained austenite is less than 2%, the above effect is not significantly attained. On the other hand, when the volume fraction of retained austenite exceeds 20%, there is a possibility that forming under extremely severe conditions provides a press formed product containing a large amount of marten site. As a result, problems associated with secondary formability and impact resistance sometimes occur. For the above reason, in the present invention, the volume fraction of retained austenite is limited to not more than 20%. 
     The ductility of the steel sheet of the present invention as the final product varies depending upon the volume fraction of retained austenite contained in the steel sheet as the final product. The retained austenite remaining in the metallurgical structure is stably present when the steel sheet does not undergo any deformation. Upon the application of deformation, however, the retained austenite is transformed to martensite to develop transformation induced plasticity. Therefore, good formability can be realized while enjoying high strength. 
     When the volume fraction of retained austenite is less than 2%, the effect of improving the formability is not significant. On the other hand, when the volume fraction of retained austenite exceeds 20%, there is a possibility that forming under extremely severe conditions provides a formed product containing a large amount of martensite. The presence of the martensite sometimes causes problems associated with secondary formability and impact resistance. For the above reason, in the present invention, the volume fraction of retained austenite is limited to not more than 20%. 
     (b) Zinc Coated Layer 
     In the steel sheet according to the present invention, a zinc coated layer is provided on the steel sheet substrate. The zinc coated layer according to the present invention may be either a galvanized layer or a galvannealed layer. The galvanized layer and the galvannealed layer will be described in detail. 
     The galvanized layer comprises zinc: not less than 80% and aluminum: not more than 1% with the balance consisting of zinc and unavoidable impurities. The reason why the content of zinc in the galvanized layer is limited to not less than 80% is that, when the zinc content is less than 80%, the coated layer is hard and is disadvantageously cracked at the time of forming. The reason why the content of aluminum in the galvanized layer is limited to not more than 1% is that, when the aluminum content exceeds 1%, aluminum segregated during coating constitutes a local battery which deteriorates corrosion resistance. 
     The galvannealed layer is useful particularly for improving spot weldability. The galvannealed layer comprises zinc: 80 to 91%, iron: 8 to 15%, and aluminum: not more than 1% with the balance consisting of zinc and unavoidable impurities. The reason why the content of zinc in the galvannealed layer is limited to not less than 80% is that, when the zinc content is less than 80%, the coated layer is hard and is disadvantageously cracked at the time of forming. The reason why the upper limit of the content of zinc in the galvannealed layer is 91% is that, when the zinc content exceeds 91%, the spot weldability is disadvantageously deteriorated making it impossible to attain the object of the present invention. 
     The reason why the content of iron in the galvannealed layer is limited to not less than 8% is that, when the iron content is less than 8%, the suitability for conversion treatment (phosphate treatment) and the plating adhesion cannot be ensured. The reason why the upper limit of the content of iron in the coating layer is 15% is that, when the iron content exceeds 15%, overalloying occurs and, consequently, plating adhesion in the worked part is deteriorated. 
     The reason why the content of aluminum in the galvannealed layer is limited to not more than 1% is that, when the aluminum content exceeds 1%, aluminum segregated during coating constitutes a local battery and, consequently, the corrosion resistance of the steel sheet is deteriorated. 
     The galvanized layer and the galvannealed layer in the steel sheet according to the present invention are as described above. In addition to the above constituents, elements such as manganese (Mn), lead (Pb), antimony (Sb), calcium (Ca), and magnesium (Mg) maybe contained as unavoidable impurities. Further, very small amounts of other elements may be contained as incidental constituents. 
     The thickness of the galvanized layer and the galvannealed layer is not particularly limited. Preferably, however, the thickness is not less than 0.1 μm from the viewpoint of ensuring corrosion resistance, and is not more than 15 μm from the viewpoint of ensuring workability. 
     Production Process 
     Next, the process for producing the hot-dip galvanized or galvannealed steel sheet according to the present invention will be described. 
     The hot-dip galvanized steel sheet according to the present invention is produced by annealing a cold rolled steel sheet having the above-described chemical composition for 10 sec to 6 min in the intercritical temperature range of 650 to 900° C., then cooling the annealed steel sheet to 350 to 500° C. at a cooling rate of 2 to 200° C./sec, optionally further holding the cooled steel sheet in said cooling temperature range for not more than 10 min, then subjecting the cooled steel sheet to hot-dip galvanizing, and then cooling the coated steel sheet to 250° C. or below at a cooling rate of not less than 5° C./sec. 
     The hot-dip galvannealed steel sheet according to the present invention is produced by annealing a cold rolled steel sheet having the above-described chemical composition for 10 sec to 6 min in the intercritical temperature range of 650 to 900° C., then cooling the annealed steel sheet to 350 to 500° C. at a cooling rate of 2 to 200° C./sec, optionally further holding the cooled steel sheet in said cooling temperature range for not more than 10 min, then subjecting the cooled steel sheet to hot-dip galvannealing process, holding the coated steel sheet in the temperature region of 450 to 600° C. for 5 sec to 2 min, and then cooling the coated steel sheet to 250° C. or below at a cooling rate of not less than 5° C./sec. 
     In continuous annealing of the cold rolled steel sheet after cold rolling, the cold rolled steel sheet is first heated to the temperature range of Ac 1  transformation point to Ac 3  transformation point to form a two-phase structure of [ferrite+austenite]. At that time, when the heating temperature is below 650° C., a lot of time is required for the redissolution of cementite to form a solid solution, and the existing amount of austenite is very small. For this reason, the lower limit of the heating temperature is 650° C. 
     On the other hand, when the heating temperature is excessively high, the volume fraction of austenite is so large that the content of carbon in austenite is lowered. For the above reason, the upper limit of the heating temperature is 900° C. When the holding time in this temperature range is excessively short, the possibility of presence of undissolved carbides is high and, consequently, the existing amount of austenite is small. On the other hand, when the holding time is long, grains become coarse and, as a result, the amount of austenite, which is finally present, is reduced, resulting in deteriorated strength-ductility balance. For the above reason, in the present invention, the holding time is limited to 10 sec to 6 min. 
     After the equation of heat, the steel sheet is cooled to 350 to 500° C. at a cooling rate of 2 to 200° C./sec. The object of this step is as follows. In this step, austenite formed by heating in the two-phase region is carried forward to a bainite transformation region without transformation to pearlite, and subsequent treatment permits retained austenite and bainite to exist at room temperature, whereby predetermined properties are provided. In this case, when the cooling rate is less than 2° C./sec, a major part of austenite disadvantageously causes pearlite transformation during cooling. As a result, retained austenite cannot be ensured. On the other hand, when the cooling rate exceeds 200° C./sec, the cooling termination temperature significantly deviates from a predetermined value in the widthwise direction and longitudinal direction. This makes it impossible to produce a steel sheet having homogeneous quality. 
     The termination temperature of cooling from the two-phase region is determined from the viewpoint of the suitability for hot-dip galvanizing. When the hot-dip galvanizing temperature is excessively low, the wettability of the steel sheet by coating is lowered and, consequently, plating adhesion is deteriorated. On the other hand, when the hot-dip galvanizing temperature is excessively high, an alloying reaction of iron with zinc proceeds in a zinc bath and, consequently, the concentration of iron in the coating is increased. For the above reason, in the present invention, the termination temperature of cooling from the two-phase region and the hot-dip zinc coating temperature are limited to 350 to 500° C. 
     Further, before hot-dip galvanizing, if necessary, the steel sheet is held in the temperature range of 350 to 500° C. for not more than 10 min. Holding the temperature of the steel sheet before hot-dip galvanizing allows bainite transformation to proceed, and carbon-enriched retained austenite can be stabilized. As a result, steel sheets having a combination of good strength with good elongation can be more stably produced. 
     When the termination temperature of cooling from the two-phase region exceeds 500° C., austenite is decomposed to carbides during subsequent temperature holding, and it is difficult for austenite to remain undecomposed. On the other hand, when the cooling termination temperature is below 350° C., a major part of austenite is transformed to martensite. As a result, the press formability is likely to be deteriorated, although the strength is enhanced. Further, in this case, at the time of galvanizing, the steel sheet temperature should be raised. This is ineffective from the viewpoint of thermal energy. 
     For the above reason, the holding temperature is limited to 350 to 500° C. When the temperature holding time exceeds 10 min, upon heating after zinc coating, the precipitation of carbides and the disappearance of untransformed austenite take place. As a result, both the strength and the press formability are likely to be deteriorated. For the above reason, when the temperature is held, the temperature holding time is limited to not more than 10 min. 
     In producing the hot-dip galvanized steel sheet, after hot-dip galvanizing process, the coated steel sheet is cooled to 250° C. or below at a cooling rate of not less than 5° C./sec. Here at the time of galvanizing, bainite transformation is allowed to proceed to develop a mixed structure. The mixed structure comprises bainite, which is substantially free from carbides, retained austenite, which has been enriched with carbon scavenged from that portion and has an Ms point lowered to room temperature or below, and ferrite, which has been further cleaned during heating in the two-phase region. This structure can simultaneously realize high strength and good formability. 
     In this case, when the cooling rate after temperature holding is less than 5° C./sec or when the cooling termination temperature is above 250° C., austenite, which has been enriched with carbon during cooling, also causes carbide precipitation and is decomposed to bainite. This disadvantageously reduces the amount of retained austenite which improves workability through transformation induced plasticity. As a result, the object of the present invention cannot be attained. In order to increase the amount of the retained austenite remaining untransformed, preferably, the holding temperature after hot-dip galvanizing process is 350 to 400° C., and the holding time is not more than 5 min. 
     Further, in producing the hot-dip galvannealed steel sheet, after hot-dip galvannealing process, the coated steel sheet is held in the temperature range of 450 to 600° C. for 5 sec to 2 min and is then cooled to 250° C. or below at a cooling rate of not less than 5° C./sec. The above conditions are determined from the viewpoints of the alloying reaction of iron with zinc and the optimization of the structure of the steel sheet. 
     In the steel according to the present invention, silicon and aluminum are contained, and through the utilization of two-stage transformation from austenite to bainite, a mixed structure is developed which is composed of bainite, retained austenite, and ferrite. This bainite is substantially free from carbides. The austenite has been enriched with carbon scavenged from that portion and has an Ms point lowered to room temperature or below. The ferrite has been further cleaned during heating in the two-phase region. The development of the mixed structure can simultaneously realize high strength and good formability. When the holding temperature is above 600° C., pearlite is formed and the retained austenite is not contained in the steel sheet. Further, in this case, the alloying reaction excessively proceeds. Consequently, the concentration of iron in the coating disadvantageously exceeds 12%. 
     On the other hand, when the heating temperature is 450° C. or below, the alloying reaction rate of the coating is lowered and, consequently, the concentration of iron in the coating is lowered. 
     When the holding time is not more than 5 sec, bainite is not satisfactorily formed and the enrichment of untransformed austenite with carbon is also unsatisfactory. In this case, during cooling, martensite is formed, resulting in deteriorated formability. At the same time, the galvannealing reaction is unsatisfactory. 
     On the other hand, when the holding time is not less than 2 min, overalloying of the coating occurs and, at the time of forming, coating separation or the like is disadvantageously likely to occur. When the cooling rate after the temperature holding is less than 5° C./sec or when the cooling termination temperature is above 250° C., bainite transformation further proceeds and austenite, which has been enriched with carbon in the preceding reaction, also causes carbide precipitation and is decomposed to bainite. This disadvantageously reduces the amount of retained austenite which improves workability through transformation induced plasticity. As a result, the object of the present invention cannot be attained. 
     The hot-dip galvanizing temperature is preferably between the melting point of the zinc bath and 500° C. When the hot-dip galvanizing temperature is above 500° C., a large amount of vapor is produced from the zinc bath and, consequently, the operating efficiency is deteriorated. The rate of heating to the holding temperature after the coating is not particularly limited. The heating rate, however, is preferably not less than 3° C./sec from the viewpoints of the coating structure and the metallurgical structure. 
     The temperature and the cooling temperature in the above-described individual steps are not necessarily constant so far as the temperature and the cooling temperature fall within the above-specified respective ranges. Even when the temperature or the cooling temperature fluctuates within the above-specified range, the properties of the final product are not deteriorated and, in some cases, are improved. The material used in the present invention may have been produced through refining, casting, hot rolling, and cold rolling steps in a conventional steelmaking process. Alternatively, the material used in the present invention may have been produced by a process wherein a part or the whole of these steps has been omitted. Conditions of these steps are also not particularly limited. 
     In order to further improve the plating adhesion, before annealing, the steel sheet may be coated with nickel, copper, cobalt, and iron, either alone or in combination. Another method usable for improving the plating adhesion is to properly regulate the atmosphere at the time of annealing of the steel sheet. For example, a method may be adopted wherein, before coating, the surface of the steel sheet is first oxidized in atmosphere and is then reduced to clean the surface of the steel sheet. Further, for plating adhesion improvement purposes, before annealing, pickling of the steel sheet or grinding of the steel sheet may be carried out to remove oxides on the surface of the steel sheet. This does not change the subject matter of the present invention. The above treatments can improve plating adhesion and further can accelerate alloying. 
     As described above, the present invention can efficiently produce high strength hot-dip galvanized or galvannealed steel sheets having good press formability and plating adhesion which can be used as automobile, building, electric or other members and other applications. 
     EXAMPLES 
     The following examples further illustrate but do not limit the present invention. 
     Example A1 
     Steels having chemical compositions shown in Table A1 were reheated to 1250° C., were then finish rolled at 900° C., and were coiled at 650° C. to prepare 4 mm-thick hot rolled steel sheets. Scale deposited on the surface of the hot rolled steel sheets was removed with hydrochloric acid, and the steel sheets were then cold rolled to prepare 1.4 mm-thick cold rolled steel sheets. The cold rolled steel sheets were annealed under conditions shown in Table A2 and Table A3 (continuation from Table A2), were coated, and were then temper rolled with a reduction of 0.5%. The steel sheets thus obtained were subjected to the following performance evaluation tests, that is, “tensile test,” “retained austenite measuring test,” “welding test,” “appearance of coating,” “plating adhesion,” and “measurement of concentration in coated layer.” In the coating in the above production of the steel sheets, both sides of the cold rolled steel sheets were coated at a coverage of coating of 50 g/m 2  per side. 
     In the “tensile test,” a JIS No. 5 tensile test piece was extracted in C-direction, and a cold tensile test was carried out under conditions of gauge thickness 50 mm and tensile speed 10 mm/min. 
     The “retained austenite measuring test” was carried out by a method called “5-peak” method. In this method, a quarter of the sheet thickness from the surface toward the inner side of the sheet was chemically polished, α-iron intensity and γ-iron intensity were then measured by X-ray diffractometry using an Mo bulb, and the volume fraction of retained austenite was determined based on the α-iron intensity and the γ-iron intensity. 
     The “welding test” was carried out by performing spot welding under welding conditions of welding current: 10 kA, applied pressure: 220 kg, welding time: 12 cycles, electrode diameter: 6 mm, electrode shape: domed, and tip: 6φ-40R, and counting the number of continuous spots provided until the welding reached the point at which the nugget diameter became below 4√{square root over (t)} wherein t represents sheet thickness. The counted number of continuous spots was evaluated according to the following criteria. ◯: more than 1,000 continuous spots, Δ: 500 to 1,000 continuous spots, and ×: less than 500 continuous spots. Here ◯ was regarded as acceptable, and Δ and × as unacceptable. 
     The “appearance of coating” was determined by visually inspecting the appearance of the coated steel sheet for noncoated sites and evaluating the results according to the following criteria. ◯: not more than 5/dm 2 , Δ: 6 to 15/dm 2 , and ×: not less than 16/dm 2 . Here ◯ was regarded as acceptable, and Δ and × as unacceptable. 
     The “plating adhesion” was determined by subjecting the coated steel sheet to a 60-degree V bending test, then performing a tape test, and evaluating the results according to the following criteria. 
     Blackening in tape test (%) 
     ⊚: 0 to 10 
     ◯: 10 to less than 20 
     Δ: 20 to less than 30 
     ×: not less than 30 
     (⊚ and ◯: acceptable, Δ and ×: unacceptable) 
     The “measurement of concentration in coated layer” was carried out by dissolving the coated layer in 5% hydrochloric acid containing an amine-based inhibitor and then analyzing the solution by ICP emission spectroscopy. 
     The results of the above performance evaluation tests are shown in Table A4 and Table A5 (continuation from Table A4). For all of samples 1 to 13 which are examples of the present invention, the total elongation was not less than 30% while ensuring a tensile strength of not less than 550 MPa, indicating that high strength and good press formability could be simultaneously realized. At the same time, for these samples, the plating adhesion was acceptable. 
     By contrast, samples 14 to 23, which are comparative examples, could not attain the object of the present invention, because, for sample 14, the content of carbon was lower than the carbon content range specified in the present invention; for sample 15, the content of carbon was higher than the carbon content range specified in the present invention; for sample 16, the content of silicon was lower than the silicon content range specified in the present invention; for sample 17, the content of silicon was higher than the silicon content range specified in the present invention; samples 18 and 19 failed to satisfy the relationship between silicon and aluminum specified in the present invention; for sample 20, the content of manganese was lower than the manganese content range specified in the present invention; for sample 21, the content of manganese was higher than the manganese content range specified in the present invention; for sample 22, the content of aluminum was higher than the aluminum content range specified in the present invention; and, for sample 23, the content of tin was lower than the tin content range specified in the present invention. 
     For samples 24 to 48 as comparative examples, although the chemical compositions of the steels fell within the scope of the present invention, any one of the treatment conditions was outside the scope of the present invention. These comparative samples suffered from poor strength-ductility balance or poor plating adhesion and thus could not attain the object of the present invention. 
     
       
         
           
               
               
               
             
               
                   
                 TABLE A1 
               
             
            
               
                   
                   
               
               
                   
                 Chemical composition, weight % 
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Steel 
                 C 
                 Si 
                 Mn 
                 P 
                 S 
                 Al 
                 Sn 
                 Ni 
                 Cu 
                 Co 
                 Others 
                 Si + 0.8 Al 
                 Remarks 
               
               
                   
               
               
                 a 
                 0.08 
                 1.21 
                 1.55 
                 0.004 
                 0.005 
                 0.25 
                 0.056 
                 0.02 
                 0.01 
                 — 
                 — 
                 1.41  
                 Ex. of inv. 
               
               
                 b 
                 0.12 
                 0.24 
                 2.21 
                 0.014 
                 0.003 
                 0.73 
                 0.015 
                 0.05 
                 0.04 
                 0.02 
                 Mo: 0.11, Ca: 0.02 
                 0.824 
                 Ex. of inv. 
               
               
                 c 
                 0.16 
                 1.30 
                 1.40 
                 0.008 
                 0.004 
                 0.02 
                 0.720 
                 0.03 
                 0.20 
                 — 
                 Cr: 0.22 
                 1.316 
                 Ex. of inv. 
               
               
                 d 
                 0.13 
                 0.65 
                 1.00 
                 0.009 
                 0.006 
                 0.74 
                 0.132 
                 0.87 
                 1.30 
                 — 
                 Sb: 0.12 
                 1.242 
                 Ex. of inv. 
               
               
                 e 
                 0.04 
                 1.30 
                 2.40 
                 0.015 
                 0.002 
                 0.21 
                 0.082 
                 0.06 
                 0.02 
                 — 
                 Ce (REM): 0.002, Nb: 0.03 
                 1.468 
                 Ex. of inv. 
               
               
                 f 
                 0.07 
                 0.34 
                 0.90 
                 0.012 
                 0.012 
                 0.65 
                 0.008 
                 1.60 
                 0.20 
                 0.23 
                 Ti: 0.02, Zr: 0.05 
                 0.86  
                 Ex. of inv. 
               
               
                 g 
                 0.17 
                 1.70 
                 1.50 
                 0.005 
                 0.008 
                 0.23 
                 0.432 
                 0.20 
                 0.10 
                 — 
                 Mg: 0.003 
                 1.884 
                 Ex. of inv. 
               
               
                 h 
                 0.09 
                 0.82 
                 1.40 
                 0.005 
                 0.004 
                 0.34 
                 0.187 
                 0.67 
                 0.92 
                 — 
                 — 
                 1.092 
                 Ex. of inv. 
               
               
                 i 
                 0.11 
                 0.46 
                 1.60 
                 0.012 
                 0.011 
                 0.95 
                 0.861 
                 0.11 
                 0.02 
                 — 
                 Y (REM): 0.07, Ca: 0.01 
                 1.22  
                 Ex. of inv. 
               
               
                 j 
                 0.07 
                 1.12 
                 1.30 
                 0.004 
                 0.005 
                 0.02 
                 0.006 
                 1.12 
                 0.65 
                 0.01 
                 — 
                 1.136 
                 Ex. of inv. 
               
               
                 k 
                 0.18 
                 0.93 
                 1.6  
                 0.008 
                 0.009 
                 0.14 
                 0.229 
                 0.23 
                 0.06 
                 0.01 
                 Mo: 0.04, Ti: 0.01, 
                 1.042 
                 Ex. of inv. 
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 Mg: 0.02 
               
               
                 l 
                 0.08 
                 0.82 
                 1.70 
                 0.004 
                 0.005 
                 0.13 
                 0.046 
                 0.02 
                 0.01 
                 0.02 
                 — 
                 0.924 
                 Ex. of inv. 
               
               
                 m 
                 0.17 
                 1.40 
                 1.70 
                 0.005 
                 0.008 
                 0.23 
                 0.079 
                 0.20 
                 0.10 
                 — 
                 Mg: 0.02 
                 1.584  
                 Ex. of inv. 
               
               
                 n 
                 
                   0.01 
                 
                 0.34 
                 1.03 
                 0.003 
                 0.005 
                 0.55 
                 0.028 
                 0.01 
                 0.03 
                 — 
                 — 
                 0.78  
                 Comp. Ex. 
               
               
                 o 
                 
                   0.22 
                 
                 0.62 
                 1.82 
                 0.013 
                 0.002 
                 0.22 
                 0.102 
                 0.02 
                 0.02 
                 — 
                 Bi: 0.05 
                 0.796 
                 Comp. Ex. 
               
               
                 p 
                 0.13 
                 
                   0.13 
                 
                 1.34 
                 0.007 
                 0.003 
                 0.39 
                 0.043 
                 0.02 
                 0.02 
                 0.12 
                 Ce (REM): 0.2 
                 0.442 
                 Comp. Ex. 
               
               
                 q 
                 0.16 
                 
                   1.92 
                 
                 0.97 
                 0.008 
                 0.002 
                 0.24 
                 0.081 
                 1.20 
                 0.10 
                 — 
                 — 
                 2.112 
                 Comp. Ex. 
               
               
                 r 
                 0.15 
                   *0.22   
                 0.58 
                 0.004 
                 0.007 
                   *0.12   
                 0.210 
                 0.02 
                 0.23 
                 0.04 
                 V: 0.01, Zr: 0.02 
                 
                   0.316 
                 
                 Comp. Ex. 
               
               
                 s 
                 0.12 
                   *1.55   
                 1.52 
                 0.005 
                 0.003 
                   *0.73   
                 0.192 
                 0.08 
                 0.13 
                 — 
                 — 
                 
                   2.134 
                 
                 Comp. Ex. 
               
               
                 t 
                 0.06 
                 0.36 
                 
                   0.18 
                 
                 0.008 
                 0.003 
                 0.22 
                 0.062 
                 0.66 
                 0.22 
                 — 
                 Sb: 0.22, Ca: 0.21 
                 0.536 
                 Comp. Ex. 
               
               
                 u 
                 0.14 
                 0.73 
                 
                   2.65 
                 
                 0.009 
                 0.005 
                 0.54 
                 0.009 
                 0.23 
                 0.15 
                 — 
                 Cr: 0.23, Mo: 0.09 
                 1.162 
                 Comp. Ex. 
               
               
                 v 
                 0.12 
                 0.54 
                 0.85 
                 0.005 
                 0.006 
                   1.63   
                 0.008 
                 0.01 
                 1.10 
                 0.12 
                 — 
                 1.844 
                 Comp. Ex. 
               
               
                 w 
                 0.09 
                 0.62 
                 1.22 
                 0.012 
                 0.002 
                 0.32 
                 
                   0.001 
                 
                 0.32 
                 0.03 
                 — 
                 Ti: 0.03, Nb: 0.03 
                 0.876 
                 Comp. Ex. 
               
               
                   
               
               
                 Note)  
               
               
                 Mark        indicates that the value is outside the scope of the present invention.  
               
               
                 Mark * indicates that the value does not satisfy the relationship between Al and Si specified in the present invention.  
               
               
                 Mark — indicates that the constituent is not contained.  
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE A2 
               
               
                   
               
               
                   
                   
                 Anneal- 
                 Anneal- 
                   
                   
                   
                   
                   
                 Al 
                 Alloy- 
                   
                   
                   
                   
               
               
                   
                   
                 ing 
                 ing 
                 Cooling 
                 Cooling 
                 Holding 
                 Holding 
                 Coating 
                 content 
                 ing 
                 Alloying 
                 Cooling 
                 Cooling 
                   
               
               
                 Sam- 
                   
                 temp., 
                 time, 
                 rate, 
                 termination 
                 temp. before 
                 time, 
                 temp., 
                 of zinc 
                 temp., 
                 time, 
                 rate, 
                 temp., 
                 Re- 
               
               
                 ple 
                 Steel 
                 ° C. 
                 sec 
                 ° C./sec 
                 temp., ° C. 
                 coating, ° C. 
                 sec 
                 ° C. 
                 bath, % 
                 ° C. 
                 sec 
                 ° C./sec 
                 ° C. 
                 marks 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1 
                 a 
                 800 
                 150 
                 10 
                 400 
                 400-450 
                  60 
                 450 
                 0.11 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 2 
                 b 
                 750 
                 90 
                 20 
                 400 
                 — 
                 — 
                 450 
                 0.14 
                 520 
                 30 
                 15 
                 150 
                 GA 
               
               
                 3 
                 c 
                 800 
                 100 
                 40 
                 420 
                 360-400 
                 420 
                 470 
                 0.16 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 4 
                 d 
                 750 
                 90 
                 150 
                 380 
                 — 
                 — 
                 450 
                 0.10 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 5 
                 e 
                 780 
                 150 
                 3 
                 370 
                 350-380 
                 300 
                 440 
                 0.12 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 6 
                 f 
                 800 
                 90 
                 20 
                 480 
                 — 
                 — 
                 450 
                 0.15 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 7 
                 g 
                 750 
                 200 
                 20 
                 410 
                 — 
                 — 
                 450 
                 0.15 
                 500 
                 30 
                 10 
                 180 
                 GA 
               
               
                 8 
                 h 
                 850 
                 85 
                 7 
                 440 
                 400-470 
                  40 
                 450 
                 0.20 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 9 
                 i 
                 750 
                 150 
                 10 
                 360 
                 360-440 
                 200 
                 450 
                 0.11 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 10 
                 j 
                 800 
                 90 
                 20 
                 480 
                 400-500 
                 100 
                 450 
                 0.15 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 11 
                 k 
                 750 
                 110 
                 5 
                 440 
                 — 
                 — 
                 450 
                 0.20 
                 500 
                 30 
                 10 
                 180 
                 GA 
               
               
                 12 
                 l 
                 700 
                 120 
                 10 
                 400 
                 360-440 
                  60 
                 450 
                 0.18 
                 550 
                 10 
                 10 
                 180 
                 GA 
               
               
                 13 
                 m 
                 800 
                 200 
                 15 
                 430 
                 — 
                 — 
                 460 
                 0.20 
                 — 
                 — 
                 10 
                 200 
                 GI 
               
               
                 14 
                 n 
                 830 
                 90 
                 20 
                 410 
                 400-470 
                  30 
                 450 
                 0.15 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 15 
                 o 
                 800 
                 120 
                 6 
                 420 
                 — 
                 — 
                 460 
                 0.14 
                 520 
                 15 
                 10 
                 180 
                 GA 
               
               
                 16 
                 p 
                 750 
                 110 
                 10 
                 370 
                 — 
                 — 
                 450 
                 0.10 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 17 
                 q 
                 820 
                 90 
                 20 
                 480 
                 430-500 
                  30 
                 450 
                 0.09 
                 580 
                 30 
                 10 
                 180 
                 GA 
               
               
                 18 
                 r 
                 750 
                 90 
                 20 
                 410 
                 — 
                 — 
                 450 
                 0.16 
                 500 
                 20 
                 10 
                 180 
                 GA 
               
               
                 19 
                 s 
                 870 
                 150 
                 9 
                 440 
                 370-440 
                 300 
                 450 
                 0.13 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 20 
                 t 
                 750 
                 70 
                 20 
                 420 
                 — 
                 — 
                 450 
                 0.18 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 21 
                 u 
                 830 
                 90 
                 10 
                 480 
                 400-490 
                  30 
                 450 
                 0.17 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 22 
                 v 
                 750 
                 200 
                 20 
                 490 
                 400-470 
                  80 
                 450 
                 0.09 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 23 
                 w 
                 800 
                 120 
                 5 
                 400 
                 — 
                 — 
                 440 
                 0.14 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 24 
                 a 
                 
                   600 
                 
                 90 
                 20 
                 360 
                 — 
                 — 
                 470 
                 0.08 
                 500 
                 30 
                 10 
                 180 
                 GA 
               
               
                   
               
               
                 Note)  
               
               
                 Mark      indicates that the value is outside the scope of the present invention. The heating rate after coating was constant and 10° C./sec.  
               
               
                 GA represents a hot-dip galvannealed steel sheet.  
               
               
                 GI represents a hot-dip galvanized steel sheet.  
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE A3 
               
             
            
               
                   
               
               
                 (continuation from TABLE A2) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                 Anneal- 
                 Anneal- 
                   
                   
                   
                   
                   
                 Al 
                 Alloy- 
                   
                   
                   
                   
               
               
                   
                   
                 ing 
                 ing 
                 Cooling 
                 Cooling 
                 Holding 
                 Holding 
                 Coating 
                 content 
                 ing 
                 Alloying 
                 Cooling 
                 Cooling 
                   
               
               
                 Sam- 
                   
                 temp., 
                 time, 
                 rate, 
                 termination 
                 temp. before 
                 time, 
                 temp., 
                 of zinc 
                 temp., 
                 time, 
                 rate, 
                 temp., 
                 Re- 
               
               
                 ple 
                 Steel 
                 ° C. 
                 sec 
                 ° C./sec 
                 temp., ° C. 
                 coating, ° C. 
                 sec 
                 ° C. 
                 bath, % 
                 ° C. 
                 sec 
                 ° C./sec 
                 ° C. 
                 marks 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 25 
                 a 
                 
                   950 
                 
                 90 
                 80 
                 480 
                 400-500 
                  60 
                 450 
                 0.11 
                 480 
                 50 
                 10 
                 180 
                 GA 
               
               
                 26 
                 a 
                 750 
                 
                    5 
                 
                 20 
                 440 
                 430-500 
                  20 
                 450 
                 0.20 
                 500 
                 30 
                 10 
                 180 
                 GA 
               
               
                 27 
                 a 
                 800 
                   400   
                 20 
                 410 
                 — 
                 — 
                 480 
                 0.17 
                 500 
                 40 
                 20 
                 220 
                 GA 
               
               
                 28 
                 a 
                 750 
                 90 
                 
                    1 
                 
                 370 
                 430-500 
                  30 
                 450 
                 0.13 
                 510 
                 30 
                 10 
                 180 
                 GA 
               
               
                 29 
                 a 
                 800 
                 110  
                 10 
                 
                   300 
                 
                 370-440 
                 300 
                 450 
                 0.09 
                 480 
                 50 
                 10 
                 180 
                 GA 
               
               
                 30 
                 a 
                 770 
                 90 
                 70 
                 
                   520 
                 
                 370-440 
                 300 
                 450 
                 0.14 
                 500 
                 30 
                 10 
                 180 
                 GA 
               
               
                 31 
                 a 
                 830 
                 150  
                 10 
                 420 
                 400-490 
                 
                   650 
                 
                 480 
                 0.18 
                 500 
                 30 
                 10 
                 180 
                 GA 
               
               
                 32 
                 a 
                 800 
                 70 
                 20 
                 410 
                 400-470 
                  80 
                 430 
                 0.11 
                 
                   430 
                 
                 40 
                 15 
                 180 
                 GA 
               
               
                 33 
                 a 
                 750 
                 90 
                 25 
                 440 
                 370-440 
                 140 
                 480 
                 0.16 
                 
                   620 
                 
                 20 
                 10 
                 100 
                 GA 
               
               
                 34 
                 a 
                 850 
                 60 
                 20 
                 420 
                 — 
                 — 
                 450 
                 0.20 
                 500 
                   3   
                 8 
                 180 
                 GA 
               
               
                 35 
                 a 
                 750 
                 90 
                 80 
                 480 
                 — 
                 — 
                 450 
                 0.12 
                 500 
                   130   
                 10 
                 180 
                 GA 
               
               
                 36 
                 a 
                 820 
                 70 
                 50 
                 490 
                 400-470 
                 250 
                 440 
                 0.10 
                 500 
                 25 
                 
                    3 
                 
                 180 
                 GA 
               
               
                 37 
                 a 
                 750 
                 100  
                 20 
                 360 
                 — 
                 — 
                 450 
                 0.08 
                 500 
                 30 
                 10 
                 
                   300 
                 
                 GA 
               
               
                 38 
                 a 
                 830 
                 90 
                 20 
                 480 
                 400-500 
                   60 
                 450 
                 
                   0.82 
                 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 39 
                 a 
                 
                   600 
                 
                 90 
                 20 
                 360 
                 — 
                 — 
                 470 
                 0.08 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 40 
                 a 
                 
                   950 
                 
                 90 
                 80 
                 480 
                 400-500 
                  60 
                 450 
                 0.11 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 41 
                 a 
                 750 
                 
                    5 
                 
                 20 
                 440 
                 430-500 
                  20 
                 450 
                 0.20 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 42 
                 a 
                 800 
                   420   
                 20 
                 410 
                 — 
                 — 
                 480 
                 0.17 
                 — 
                 — 
                 20 
                 220 
                 GI 
               
               
                 43 
                 a 
                 750 
                 90 
                 
                    1 
                 
                 370 
                 430-500 
                  30 
                 450 
                 0.13 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 44 
                 a 
                 800 
                 110  
                 10 
                 
                   300 
                 
                 370-440 
                 300 
                 450 
                 0.09 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 45 
                 a 
                 830 
                 150  
                 10 
                 420 
                 400-490 
                 
                   720 
                 
                 480 
                 0.18 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 46 
                 a 
                 820 
                 70 
                 50 
                 490 
                 400-470 
                 250 
                 440 
                 0.10 
                 — 
                 — 
                 
                    3 
                 
                 180 
                 GI 
               
               
                 47 
                 a 
                 750 
                 100  
                 20 
                 360 
                 — 
                 — 
                 450 
                 0.08 
                 — 
                 — 
                 10 
                 
                   300 
                 
                 GI 
               
               
                 48 
                 a 
                 830 
                 90 
                 20 
                 480 
                 400-500 
                  60 
                 450 
                 
                   0.82 
                 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                   
               
               
                 Note)  
               
               
                 Mark      indicates that the value is outside the scope of the present invention. The heating rate after coating was constant and 10° C./sec.  
               
               
                 GA represents a hot-dip galvannealed steel sheet.  
               
               
                 GI represents a hot-dip galvanized steel sheet.  
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE A4 
               
               
                   
               
               
                   
                   
                   
                 Retained 
                 Fe content of 
                 Al content of 
                 Appearance 
                 Plating 
                   
                   
               
               
                 Sample 
                 TS, MPa 
                 El, % 
                 γ, % 
                 coating, % 
                 coating, % 
                 of coating 
                 adhesion 
                 Weldability 
                 Remarks 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
            
               
                 1 
                 630 
                 36 
                 8 
                 10 
                 0.22 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Ex. of inv. 
               
               
                 2 
                 660 
                 34 
                 10 
                 10  
                 0.18 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Ex. of inv. 
               
               
                 3 
                 720 
                 34 
                 13  
                 — 
                 0.28 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Ex. of inv. 
               
               
                 4 
                 640 
                 31 
                 11  
                 11 
                 0.16 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Ex. of inv. 
               
               
                 5 
                 780 
                 30 
                 3 
                 — 
                 0.18 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Ex. of inv. 
               
               
                 6 
                 580 
                 36 
                 9 
                 10 
                 0.82 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Ex. of inv. 
               
               
                 7 
                 840 
                 31 
                 15  
                 10 
                 0.13 
                 ◯ 
                 ◯ 
                 ◯ 
                 Ex. of inv. 
               
               
                 8 
                 640 
                 36 
                 8 
                 12 
                 0.16 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Ex. of inv. 
               
               
                 9 
                 630 
                 35 
                 10  
                 — 
                 0.25 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Ex. of inv. 
               
               
                 10 
                 620 
                 36 
                 7 
                 10 
                 0.17 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Ex. of inv. 
               
               
                 11 
                 810 
                 31 
                 18  
                 10 
                 0.23 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Ex. of inv. 
               
               
                 12 
                 610 
                 35 
                 4 
                 11 
                 0.32 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Ex. of inv. 
               
               
                 13 
                 830 
                 32 
                 15  
                 — 
                 0.18 
                 ◯ 
                 ◯ 
                 ◯ 
                 Ex. of inv. 
               
               
                 14 
                 540 
                 28 
                 1 
                 — 
                 0.20 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 15 
                 810 
                 25 
                   22   
                 10 
                 0.21 
                 ◯ 
                 ⊚ 
                 
                   X 
                 
                 Comp. Ex. 
               
               
                 16 
                 570 
                 28 
                 
                   1 
                 
                 10 
                 0.16 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 17 
                 710 
                 30 
                 8 
                   6   
                 0.32 
                 
                   X 
                 
                 
                   X 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 18 
                 550 
                 29 
                 1 
                 10 
                 0.13 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 19 
                 620 
                 33 
                 6 
                 10 
                 0.19 
                 
                   X 
                 
                 
                   X 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 20 
                 560 
                 20 
                 1 
                  9 
                 0.23 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 21 
                 700 
                 34 
                 7 
                 10 
                 0.28 
                 
                   Δ 
                 
                 
                   Δ 
                 
                 X 
                 Comp. Ex. 
               
               
                 22 
                 640 
                 33 
                 6 
                 — 
                 0.32 
                 
                   X 
                 
                 
                   X 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 23 
                 660 
                 33 
                 5 
                 — 
                 0.28 
                 
                   X 
                 
                 
                   X 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 24 
                 550 
                 24 
                 1 
                 10 
                 0.41 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                   
               
               
                 Note)  
               
               
                 Mark      indicates that the value is outside the scope of the present invention.  
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE A5 
               
             
            
               
                   
               
               
                 (continuation from TABLE A4) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                   
                 Retained 
                 Fe content of 
                 Al content of 
                 Appearance 
                 Plating 
                   
                   
               
               
                 Sample 
                 TS, MPa 
                 El, % 
                 γ, % 
                 coating, % 
                 coating, % 
                 of coating 
                 adhesion 
                 Weldability 
                 Remarks 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
            
               
                 25 
                 600 
                 26 
                 1 
                 10 
                 0.21 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 26 
                 620 
                 20 
                 1 
                 9 
                 0.23 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 27 
                 580 
                 22 
                 
                   1 
                 
                 10 
                 0.63 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 28 
                 550 
                 26 
                 1 
                 10 
                 0.27 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 29 
                 650 
                 24 
                 1 
                 11 
                 0.34 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 30 
                 610 
                 34 
                 6 
                 15 
                 0.28 
                 ◯ 
                 
                   Δ 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 27 
                 580 
                 22 
                 
                   1 
                 
                 10 
                 0.63 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 31 
                 600 
                 29 
                 1 
                 10 
                 0.41 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 32 
                 610 
                 35 
                 5 
                 5 
                 0.23 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 27 
                 580 
                 22 
                 
                   1 
                 
                 10 
                 0.63 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 33 
                 570 
                 29 
                 1 
                 15 
                 0.23 
                 ◯ 
                 
                   Δ 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 34 
                 630 
                 35 
                 6 
                 7 
                 0.23 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 35 
                 580 
                 28 
                 
                   1 
                 
                 15 
                 0.32 
                 ◯ 
                 
                   Δ 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 36 
                 580 
                 26 
                 
                   1 
                 
                 10 
                 0.23 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 37 
                 560 
                 23 
                 1 
                 10 
                 0.32 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 38 
                 630 
                 35 
                 7 
                 10 
                 1.23 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 39 
                 550 
                 24 
                 
                   1 
                 
                 10 
                 0.41 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 40 
                 600 
                 26 
                 1 
                 10 
                 0.21 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 41 
                 620 
                 20 
                 
                   1 
                 
                 9 
                 0.23 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 42 
                 580 
                 22 
                 1 
                 10 
                 0.63 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 43 
                 550 
                 26 
                 
                   1 
                 
                 10 
                 0.27 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 44 
                 650 
                 24 
                 
                   1 
                 
                 11 
                 0.34 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 45 
                 600 
                 29 
                 
                   1 
                 
                 10 
                 0.41 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 46 
                 580 
                 26 
                 
                   1 
                 
                 10 
                 0.23 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 47 
                 560 
                 23 
                 
                   1 
                 
                 10 
                 0.32 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 48 
                 630 
                 35 
                 7 
                 10 
                 1.23 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                   
               
               
                 Note)  
               
               
                 Mark      indicates that the value is outside the scope of the present invention.  
               
            
           
         
       
     
     Example B1 
     Steels having chemical compositions shown in Table B1 and Table B2 (continuation from Table B1) were reheated to 1250° C., were then finish rolled at 900° C., and were coiled at 650° C. to prepare 4 mm-thick hot rolled steel sheets. Scale deposited on the surface of the hot rolled steel sheets was removed with hydrochloric acid, and the steel sheets were then cold rolled to prepare 1.4 mm-thick cold rolled steel sheets. The cold rolled steel sheets were annealed under conditions shown in Table B3 and Table B4 (continuation from Table B3), were coated, and were then temper rolled with a reduction of 0.5%. The steel sheets thus obtained were subjected to the following performance evaluation tests, that is, “tensile test,” “retained austenite measuring test,” “welding test,” “appearance of coating,” “plating adhesion,” and “measurement of concentration in coated layer.” In the coating in the above production of the steel sheets, both sides of the cold rolled steel sheets were coated at a coverage of coating of 50 g/m 2  per side. 
     In the “tensile test,” a JIS No. 5 tensile test piece was extracted in C-direction, and a cold tensile test was carried out under conditions of gauge thickness 50 mm and tensile speed 10 mm/min. 
     The “retained austenite measuring test” was carried out by a method called “5-peak” method. In this method, a quarter of the sheet thickness from the surface toward the inner side of the sheet was chemically polished, (α-iron intensity and γ-iron intensity were then measured by X-ray diffractometry using an Mo bulb, and the volume fraction of retained austenite was determined based on the (α-iron intensity and the γ-iron intensity. 
     The “welding test” was carried out by performing spot welding under welding conditions of welding current: 10 kA, applied pressure: 220 kg, welding time: 12 cycles, electrode diameter: 6 mm, electrode shape: domed, and tip: 6φ-40R, and counting the number of continuous spots provided until the welding reached the point at which the nugget diameter became below 4√{square root over (t)} wherein t represents sheet thickness. The counted number of continuous spots was evaluated according to the following criteria. ⊚: more than 2,000 continuous spots, ◯: more than 1,000 continuous spots, Δ: 500 to 1,000 continuous spots, and ×: less than 500 continuous spots. Here ⊚ and ◯ were regarded as acceptable, and Δ and × as unacceptable. 
     The “appearance of coating” was determined by visually inspecting the appearance of the coated steel sheet for non-coated sites and evaluating the results according to the following criteria. 
     ◯: not more than 5/dm 2 , Δ: 6 to 15/dm 2 , and ×: not less than 16/dm 2 . 
     Here ◯ was regarded as acceptable, and Δ and × as unacceptable. 
     The “plating adhesion” was determined by subjecting the coated steel sheet to a 60-degree V bending test, then performing a tape test, and evaluating the results according to the following criteria. 
     Blackening in tape test (%) 
     ⊚: 0 to 10 
     ◯: 10 to less than 20 
     Δ: 20 to less than 30 
     ×: not less than 30 
     (⊚ and ◯: acceptable, Δ and ×: unacceptable) 
     The “measurement of concentration in coated layer” was carried out by dissolving the coated layer in 5% hydrochloric acid containing an amine-based inhibitor and then analyzing the solution by ICP emission spectroscopy. 
     The results of the above performance evaluation tests are shown in Table B5 and Table B6 (continuation from Table B5). For all of samples 1 to 13 which are examples of the present invention, the total elongation was not less than 30% while ensuring a tensile strength of not less than 550 MPa, indicating that high strength and good press formability could be simultaneously realized. At the same time, for these samples, the plating adhesion was acceptable. 
     By contrast, samples 14 to 26, which are comparative examples, could not attain the object of the present invention due to poor strength-ductility balance or poor plating adhesion, because, for sample 14, the content of carbon (C) was lower than the carbon (C) content range specified in the present invention; for sample 15, the content of carbon (C) was higher than the carbon (C) content range specified in the present invention; for sample 16, the content of silicon (Si) was lower than the silicon (Si) content range specified in the present invention; for sample 17, the content of silicon (Si) was higher than the silicon (Si) content range specified in the present invention; samples 18 and 19 failed to satisfy the relationship between silicon (Si) and aluminum (Al) specified in the present invention; for sample 20, the content of manganese (Mn) was lower than the manganese (Mn) content range specified in the present invention; for sample 21, the content of manganese (Mn) was higher than the manganese (Mn) content range specified in the present invention; for sample 22, the content of aluminum (Al) was higher than the aluminum (Al) content range specified in the present invention; for samples 23, 24, and 25, the content of selenium (Se)+bismuth (Bi)+antimony (Sb) was lower than the selenium+bismuth+antimony content range specified in the present invention; and, for sample 26, the content of selenium (Se)+bismuth (Bi)+antimony (Sb) was higher than the selenium+bismuth+antimony content range specified in the present invention. 
     For samples 27 to 51 (see Table B6) as comparative examples, although the chemical compositions of the steel sheets fell within the scope of the present invention, any one of the treatment conditions was outside the scope of the present invention. These comparative samples suffered from poor strength-ductility balance or poor plating adhesion and thus could not attain the object of the present invention. 
     
       
         
           
               
               
               
             
               
                   
                 TABLE B1 
               
             
            
               
                   
                   
               
               
                   
                 Chemical composition, weight % 
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Steel 
                 C 
                 Si 
                 Mn 
                 P 
                 S 
                 Al 
                 Sb 
                 Bi 
                 Se 
                 Sb + Bi + Se 
                 Others 
                 Si + 0.8 Al 
                 Remarks 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 a 
                 0.08 
                 1.21 
                 1.55 
                 0.004 
                 0.005 
                 0.25 
                 0.056 
                 0 
                 0 
                 0.056 
                 — 
                 1.41 
                 Ex. of inv. 
               
               
                 b 
                 0.12 
                 0.24 
                 2.21 
                 0.014 
                 0.003 
                 0.73 
                 0 
                 0.050 
                 0 
                 0.050 
                 Mo: 0.11, Ca: 0.02 
                 0.824 
                 Ex. of inv. 
               
               
                 c 
                 0.16 
                 1.30 
                 1.40 
                 0.008 
                 0.004 
                 0.02 
                 0 
                 0 
                 0.022 
                 0.022 
                 Sn: 0.05, Cr: 0.22 
                 1.316 
                 Ex. of inv. 
               
               
                 d 
                 0.13 
                 0.65 
                 1.00 
                 0.009 
                 0.006 
                 0.74 
                 0.132 
                 0.230 
                 0.120 
                 0.482 
                 Ni: 0.12 
                 1.242 
                 Ex. of inv. 
               
               
                 e 
                 0.04 
                 1.30 
                 2.40 
                 0.015 
                 0.002 
                 0.21 
                 0.082 
                 0.060 
                 0.020 
                 0.162 
                 Ce (REM): 0.002, Nb: 0.03 
                 1.468 
                 Ex. of inv. 
               
               
                 f 
                 0.07 
                 0.34 
                 0.90 
                 0.012 
                 0.012 
                 0.65 
                 0.008 
                 0.002 
                 0.001 
                 0.011 
                 Ti: 0.02, Zr: 0.05 
                 0.86 
                 Ex. of inv. 
               
               
                 g 
                 0.17 
                 1.70 
                 1.50 
                 0.005 
                 0.008 
                 0.23 
                 0.112 
                 0.200 
                 0.100 
                 0.412 
                 Mg: 0.003 
                 1.884 
                 Ex. of inv. 
               
               
                 h 
                 0.09 
                 0.82 
                 1.40 
                 0.005 
                 0.004 
                 0.34 
                 0.187 
                 0 
                 0.030 
                 0.217 
                 — 
                 1.092 
                 Ex. of inv. 
               
               
                 i 
                 0.11 
                 0.46 
                 1.60 
                 0.012 
                 0.011 
                 0.95 
                 0.742 
                 0.110 
                 0.020 
                 0.872 
                 Y (REM): 0.07, Ca: 0.01 
                 1.22 
                 Ex. of inv. 
               
               
                 j 
                 0.07 
                 1.12 
                 1.30 
                 0.004 
                 0.005 
                 0.02 
                 0.006 
                 0.320 
                 0 
                 0.326 
                 — 
                 1.136 
                 Ex. of inv. 
               
               
                 k 
                 0.18 
                 0.93 
                 1.6  
                 0.008 
                 0.009 
                 0.14 
                 0.229 
                 0.230 
                 0.060 
                 0.519 
                 Mo: 0.04, Ti: 0.01, 
                 1.042 
                 Ex. of inv. 
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 Mg: 0.02 
               
               
                 l 
                 0.08 
                 0.82 
                 1.70 
                 0.004 
                 0.005 
                 0.13 
                 0.046 
                 0.020 
                 0.010 
                 0.076 
                 — 
                 0.924 
                 Ex. of inv. 
               
               
                 m 
                 0.17 
                 1.40 
                 1.70 
                 0.005 
                 0.008 
                 0.23 
                 0 
                 0.200 
                 0.100 
                 0.300 
                 Mg: 0.02, Co: 0.05 
                 1.584 
                 Ex. of inv. 
               
               
                   
               
               
                 Note)  
               
               
                 In the table, mark      indicates that the value is outside the scope of the present invention;  
               
               
                 mark * indicates that the value does not satisfy the relationship between Al and Si specified in the present invention; and  
               
               
                 mark — indicates that the constituent is not contained.  
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE B2 
               
             
            
               
                   
               
               
                 (continuation from TABLE B1) 
               
            
           
           
               
               
               
            
               
                   
                 Chemical composition, weight % 
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Steel 
                 C 
                 Si 
                 Mn 
                 P 
                 S 
                 Al 
                 Sb 
                 Bi 
                 Se 
                 Sb + Bi + Se 
                 Others 
                 Si + 0.8 Al 
                 Remarks 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 n 
                 
                   0.01 
                 
                 0.34 
                 1.03 
                 0.003 
                 0.005 
                 0.55 
                 0.028 
                 0.010 
                 0.030 
                 0.068 
                 — 
                 0.78  
                 Comp. Ex. 
               
               
                 o 
                 
                   0.22 
                 
                 0.62 
                 1.82 
                 0.013 
                 0.002 
                 0.22 
                 0.102 
                 0.020 
                 0.020 
                 0.142 
                 Sn: 0.05 
                 0.796 
                 Comp. Ex. 
               
               
                 p 
                 0.13 
                 
                   0.13 
                 
                 1.34 
                 0.007 
                 0.003 
                 0.39 
                 0.043 
                 0.020 
                 0 
                 0.063 
                 Ce (REM): 0.2 
                 0.442 
                 Comp. Ex. 
               
               
                 q 
                 0.16 
                 
                   1.92 
                 
                 0.97 
                 0.008 
                 0.002 
                 0.24 
                 0.004 
                 0.002 
                 0.002 
                 0.008 
                 — 
                 2.112 
                 Comp. Ex. 
               
               
                 r 
                 0.15 
                 
                   *0.22 
                 
                 0.58 
                 0.004 
                 0.007 
                 
                   *0.12 
                 
                 0.210 
                 0.020 
                 0.230 
                 0.460 
                 V: 0.01, Zr: 0.02 
                 
                   0.316 
                 
                 Comp. Ex. 
               
               
                 s 
                 0.12 
                 
                   *1.55 
                 
                 1.52 
                 0.005 
                 0.003 
                 
                   *0.73 
                 
                 0.192 
                 0.080 
                 0.130 
                 0.402 
                 — 
                 
                   2.134 
                 
                 Comp. Ex. 
               
               
                 t 
                 0.06 
                 0.36 
                 
                   0.18 
                 
                 0.008 
                 0.003 
                 0.22 
                 0.062 
                 0.042 
                 0.220 
                 0.324 
                 Cu: 0.22, Ca: 0.21 
                 0.536 
                 Comp. Ex. 
               
               
                 u 
                 0.14 
                 0.73 
                 
                   2.65 
                 
                 0.009 
                 0.005 
                 0.54 
                 0 
                 0.230 
                 0.150 
                 0.380 
                 Cr: 0.23, Mo: 0.09 
                 1.162 
                 Comp. Ex. 
               
               
                 v 
                 0.12 
                 0.54 
                 0.85 
                 0.005 
                 0.006 
                 
                   1.63 
                 
                 0.008 
                 0.010 
                 0.023 
                 0.041 
                 — 
                 1.844 
                 Comp. Ex. 
               
               
                 w 
                 0.09 
                 0.62 
                 1.22 
                 0.012 
                 0.002 
                 0.32 
                 
                   0.001 
                 
                 0 
                 0 
                 
                   0.001 
                 
                 Ti: 0.03, Nb: 0.03 
                 0.876 
                 Comp. Ex. 
               
               
                 x 
                 0.09 
                 0.62 
                 1.22 
                 0.012 
                 0.002 
                 0.32 
                 0 
                 
                   0.002 
                 
                 0 
                 
                   0.002 
                 
                 Ni: 0.11, Mg: 0.02 
                 0.876 
                 Comp. Ex. 
               
               
                 y 
                 0.09 
                 0.62 
                 1.22 
                 0.012 
                 0.002 
                 0.32 
                 
                   0.001 
                 
                 0 
                 
                   0.001 
                 
                 
                   0.002 
                 
                 Sn: 0.04 
                 0.876 
                 Comp. Ex. 
               
               
                 z 
                 0.09 
                 0.62 
                 1.22 
                 0.012 
                 0.002 
                 0.32 
                 
                   0.861 
                 
                 
                   0.200 
                 
                 
                   0.229 
                 
                 
                   1.290 
                 
                   
                 0.876 
                 Comp. Ex 
               
               
                   
               
               
                 Note)  
               
               
                 In the table, mark      indicates that the value is outside the scope of the present invention;  
               
               
                 mark * indicates that the value does not satisfy the relationship between Al and Si specified in the present invention; and  
               
               
                 mark — indicates that the constituent is not contained.  
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE B3 
               
               
                   
               
               
                   
                   
                 Anneal- 
                 Anneal- 
                   
                   
                   
                   
                   
                 Al 
                 Alloy- 
                   
                   
                   
                   
               
               
                   
                   
                 ing 
                 ing 
                 Cooling 
                 Cooling 
                 Holding 
                 Holding 
                 Coating 
                 content 
                 ing 
                 Alloying 
                 Cooling 
                 Cooling 
                   
               
               
                 Sam- 
                   
                 temp., 
                 time, 
                 rate, 
                 termination 
                 temp. before 
                 time, 
                 temp., 
                 of zinc 
                 temp., 
                 time, 
                 rate, 
                 temp., 
                 Re- 
               
               
                 ple 
                 Steel 
                 ° C. 
                 sec 
                 ° C./sec 
                 temp., ° C. 
                 coating, ° C. 
                 sec 
                 ° C. 
                 bath, % 
                 ° C. 
                 sec 
                 ° C./sec 
                 ° C. 
                 marks 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1 
                 a 
                 800 
                 150 
                 10 
                 400 
                 400-450 
                  60 
                 450 
                 0.11 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 2 
                 b 
                 750 
                 90 
                 20 
                 400 
                 — 
                 — 
                 450 
                 0.14 
                 520 
                 30 
                 15 
                 150 
                 GA 
               
               
                 3 
                 c 
                 800 
                 100 
                 40 
                 420 
                 360-400 
                 420 
                 470 
                 0.16 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 4 
                 d 
                 750 
                 90 
                 150 
                 380 
                 — 
                 — 
                 450 
                 0.10 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 5 
                 e 
                 780 
                 150 
                 3 
                 370 
                 350-380 
                 300 
                 440 
                 0.12 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 6 
                 f 
                 800 
                 90 
                 20 
                 480 
                 — 
                 — 
                 450 
                 0.15 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 7 
                 g 
                 750 
                 200 
                 20 
                 410 
                 — 
                 — 
                 450 
                 0.15 
                 500 
                 30 
                 10 
                 180 
                 GA 
               
               
                 8 
                 h 
                 850 
                 85 
                 7 
                 440 
                 400-470 
                  40 
                 450 
                 0.20 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 9 
                 i 
                 750 
                 150 
                 10 
                 360 
                 360-440 
                 200 
                 450 
                 0.11 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 10 
                 j 
                 800 
                 90 
                 20 
                 480 
                 400-500 
                 100 
                 450 
                 0.15 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 11 
                 k 
                 750 
                 110 
                 5 
                 440 
                 — 
                 — 
                 450 
                 0.20 
                 500 
                 30 
                 10 
                 180 
                 GA 
               
               
                 12 
                 l 
                 700 
                 120 
                 10 
                 400 
                 360-440 
                  60 
                 450 
                 0.18 
                 550 
                 10 
                 10 
                 180 
                 GA 
               
               
                 13 
                 m 
                 800 
                 200 
                 15 
                 430 
                 — 
                 — 
                 460 
                 0.20 
                 — 
                 — 
                 10 
                 200 
                 GI 
               
               
                 14 
                 n 
                 830 
                 90 
                 20 
                 410 
                 400-470 
                  30 
                 450 
                 0.15 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 15 
                 o 
                 800 
                 120 
                 6 
                 420 
                 — 
                 — 
                 460 
                 0.14 
                 520 
                 15 
                 10 
                 180 
                 GA 
               
               
                 16 
                 p 
                 750 
                 110 
                 10 
                 370 
                 — 
                 — 
                 450 
                 0.10 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 17 
                 q 
                 820 
                 90 
                 20 
                 480 
                 430-500 
                  30 
                 450 
                 0.09 
                 580 
                 30 
                 10 
                 180 
                 GA 
               
               
                 18 
                 r 
                 750 
                 90 
                 20 
                 410 
                 — 
                 — 
                 450 
                 0.16 
                 500 
                 20 
                 10 
                 180 
                 GA 
               
               
                 19 
                 s 
                 870 
                 150 
                 9 
                 440 
                 370-440 
                 300 
                 450 
                 0.13 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 20 
                 t 
                 750 
                 70 
                 20 
                 420 
                 — 
                 — 
                 450 
                 0.18 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 21 
                 u 
                 830 
                 90 
                 10 
                 480 
                 400-490 
                  30 
                 450 
                 0.17 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 22 
                 v 
                 750 
                 200 
                 20 
                 490 
                 400-470 
                  80 
                 450 
                 0.09 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 23 
                 w 
                 800 
                 120 
                 5 
                 400 
                 — 
                 — 
                 440 
                 0.14 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 24 
                 x 
                 750 
                 110 
                 10 
                 400 
                 — 
                 — 
                 440 
                 0.14 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 25 
                 y 
                 800 
                 120 
                 5 
                 400 
                 400-470 
                  80 
                 440 
                 0.14 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 26 
                 z 
                 800 
                 70 
                 20 
                 440 
                 — 
                 — 
                 440 
                 0.14 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                   
               
               
                 Note)  
               
               
                 In the table, mark      indicates that the value is outside the scope of the present invention; the heating rate after coating was constant and 10° C./sec; and  
               
               
                 GA represents a hot-dip galvannealed steel sheet, and  
               
               
                 GI represents a hot-dip galvanized steel sheet.  
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE B4 
               
             
            
               
                   
               
               
                 (continuation from TABLE B3) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                 Anneal- 
                 Anneal- 
                   
                   
                   
                   
                   
                 Al 
                 Alloy- 
                   
                   
                   
                   
               
               
                   
                   
                 ing 
                 ing 
                 Cooling 
                 Cooling 
                 Holding 
                 Holding 
                 Coating 
                 content 
                 ing 
                 Alloying 
                 Cooling 
                 Cooling 
                   
               
               
                 Sam- 
                   
                 temp., 
                 time, 
                 rate, 
                 termination 
                 temp. before 
                 time, 
                 temp., 
                 of zinc 
                 temp., 
                 time, 
                 rate, 
                 temp., 
                 Re- 
               
               
                 ple 
                 Steel 
                 ° C. 
                 sec 
                 ° C./sec 
                 temp., ° C. 
                 coating, ° C. 
                 sec 
                 ° C. 
                 bath, % 
                 ° C. 
                 sec 
                 ° C./sec 
                 ° C. 
                 marks 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 27 
                 a 
                 
                   600 
                 
                 90 
                 20 
                 360 
                 — 
                 — 
                 470 
                 0.08 
                 500 
                 30 
                 10 
                 180 
                 GA 
               
               
                 28 
                 a 
                 
                   950 
                 
                 90 
                 80 
                 480 
                 400-500 
                  60 
                 450 
                 0.11 
                 480 
                 50 
                 10 
                 180 
                 GA 
               
               
                 29 
                 a 
                 750 
                   5   
                 20 
                 440 
                 430-500 
                  20 
                 450 
                 0.20 
                 500 
                 30 
                 10 
                 180 
                 GA 
               
               
                 30 
                 a 
                 800 
                 
                   400 
                 
                 20 
                 410 
                 — 
                 — 
                 480 
                 0.17 
                 500 
                 40 
                 20 
                 220 
                 GA 
               
               
                 31 
                 a 
                 750 
                 90 
                 
                   1 
                 
                 370 
                 430-500 
                  30 
                 450 
                 0.13 
                 510 
                 30 
                 10 
                 180 
                 GA 
               
               
                 32 
                 a 
                 800 
                 110 
                 10 
                 
                   300 
                 
                 370-440 
                 300 
                 450 
                 0.09 
                 480 
                 50 
                 10 
                 180 
                 GA 
               
               
                 33 
                 a 
                 770 
                 90 
                 70 
                 
                   520 
                 
                 370-440 
                 300 
                 450 
                 0.14 
                 500 
                 30 
                 10 
                 180 
                 GA 
               
               
                 34 
                 a 
                 830 
                 150 
                 10 
                 420 
                 400-490 
                 
                   650 
                 
                 480 
                 0.18 
                 500 
                 30 
                 10 
                 180 
                 GA 
               
               
                 35 
                 a 
                 800 
                 70 
                 20 
                 410 
                 400-470 
                  80 
                 430 
                 0.11 
                 
                   430 
                 
                 40 
                 15 
                 180 
                 GA 
               
               
                 36 
                 a 
                 750 
                 90 
                 25 
                 440 
                 370-440 
                 140 
                 480 
                 0.16 
                 
                   620 
                 
                 20 
                 10 
                 100 
                 GA 
               
               
                 37 
                 a 
                 850 
                 60 
                 20 
                 420 
                 — 
                 — 
                 450 
                 0.20 
                 500 
                   3   
                 8 
                 180 
                 GA 
               
               
                 38 
                 a 
                 750 
                 90 
                 80 
                 480 
                 — 
                 — 
                 450 
                 0.12 
                 500 
                   130   
                 10 
                 180 
                 GA 
               
               
                 39 
                 a 
                 820 
                 70 
                 50 
                 490 
                 400-470 
                 250 
                 440 
                 0.10 
                 500 
                 25 
                   3   
                 180 
                 GA 
               
               
                 40 
                 a 
                 750 
                 100 
                 20 
                 360 
                 — 
                 — 
                 450 
                 0.08 
                 500 
                 30 
                 10 
                 
                   300 
                 
                 GA 
               
               
                 41 
                 a 
                 830 
                 90 
                 20 
                 480 
                 400-500 
                  60 
                 450 
                 
                   0.82 
                 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 42 
                 a 
                 
                   600 
                 
                 90 
                 20 
                 360 
                 — 
                 — 
                 470 
                 0.08 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 43 
                 a 
                 
                   950 
                 
                 90 
                 80 
                 480 
                 400-500 
                  60 
                 450 
                 0.11 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 44 
                 a 
                 750 
                   5   
                 20 
                 440 
                 430-500 
                  20 
                 450 
                 0.20 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 45 
                 a 
                 800 
                 
                   420 
                 
                 20 
                 410 
                 — 
                 — 
                 480 
                 0.17 
                 — 
                 — 
                 20 
                 220 
                 GI 
               
               
                 46 
                 a 
                 750 
                 90 
                 
                   1 
                 
                 370 
                 430-500 
                  30 
                 450 
                 0.13 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 47 
                 a 
                 800 
                 110 
                 10 
                 
                   300 
                 
                 370-440 
                 300 
                 450 
                 0.09 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 48 
                 a 
                 830 
                 150 
                 10 
                 420 
                 400-490 
                 
                   720 
                 
                 480 
                 0.18 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 49 
                 a 
                 820 
                 70 
                 50 
                 490 
                 400-470 
                 250 
                 440 
                 0.10 
                 — 
                 — 
                   3   
                 180 
                 GI 
               
               
                 50 
                 a 
                 750 
                 100 
                 20 
                 360 
                 — 
                 — 
                 450 
                 0.08 
                 — 
                 — 
                 10 
                 
                   300 
                 
                 GI 
               
               
                 51 
                 a 
                 830 
                 90 
                 20 
                 480 
                 400-500 
                  60 
                 450 
                 
                   0.82 
                 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                   
               
               
                 Note)  
               
               
                 In the table, mark      indicates that the value is outside the scope of the present invention; the heating rate after coating was constant and 10° C./sec; and  
               
               
                 GA represents a hot-dip galvannealed steel sheet, and  
               
               
                 GI represents a hot-dip galvanized steel sheet.  
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE B5 
               
               
                   
               
               
                   
                   
                   
                 Retained 
                 Zn content of 
                 Fe content of 
                 Al content of 
                 Appearance 
                 Plating 
                   
                   
               
               
                 Sample 
                 TS, MPa 
                 El, % 
                 γ, % 
                 coating, % 
                 coating, % 
                 coating, % 
                 of coating 
                 adhesion 
                 Weldability 
                 Remarks 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1 
                 630 
                 36 
                  8 
                 89 
                 10 
                 0.22 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Ex. of inv. 
               
               
                 2 
                 660 
                 34 
                 10 
                 89 
                 10 
                 0.18 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Ex. of inv. 
               
               
                 3 
                 720 
                 34 
                 13 
                 98 
                 — 
                 0.28 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Ex. of inv. 
               
               
                 4 
                 640 
                 31 
                 11 
                 88 
                 11 
                 0.16 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Ex. of inv. 
               
               
                 5 
                 780 
                 30 
                  3 
                 94 
                 — 
                 0.18 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Ex. of inv. 
               
               
                 6 
                 580 
                 36 
                  9 
                 89 
                 10 
                 0.82 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Ex. of inv. 
               
               
                 7 
                 840 
                 31 
                 15 
                 89 
                 10 
                 0.13 
                 ◯ 
                 ◯ 
                 ⊚ 
                 Ex. of inv. 
               
               
                 8 
                 640 
                 36 
                  8 
                 87 
                 12 
                 0.16 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Ex. of inv. 
               
               
                 9 
                 630 
                 35 
                 10 
                 99 
                 — 
                 0.25 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Ex. of inv. 
               
               
                 10 
                 620 
                 36 
                  7 
                 89 
                 10 
                 0.17 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Ex. of inv. 
               
               
                 11 
                 810 
                 31 
                 18 
                 89 
                 10 
                 0.23 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Ex. of inv. 
               
               
                 12 
                 610 
                 35 
                  4 
                 88 
                 11 
                 0.32 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Ex. of inv. 
               
               
                 13 
                 830 
                 32 
                 15 
                 99 
                 — 
                 0.18 
                 ◯ 
                 ◯ 
                 ◯ 
                 Ex. of inv. 
               
               
                 14 
                 540 
                 28 
                   1   
                 93 
                 — 
                 0.20 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 15 
                 810 
                 25 
                 
                   22 
                 
                 89 
                 10 
                 0.21 
                 ◯ 
                 ⊚ 
                 
                   X 
                 
                 Comp. Ex. 
               
               
                 16 
                 570 
                 28 
                   1   
                 89 
                 10 
                 0.16 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 17 
                 710 
                 30 
                  8 
                 
                   93 
                 
                   6   
                 0.32 
                 
                   X 
                 
                 
                   X 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 18 
                 550 
                 29 
                   1   
                 89 
                 10 
                 0.13 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 19 
                 620 
                 33 
                  6 
                 89 
                 10 
                 0.19 
                 
                   X 
                 
                 
                   X 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 20 
                 560 
                 20 
                   1   
                 90 
                  9 
                 0.23 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 21 
                 700 
                 34 
                  7 
                 89 
                 10 
                 0.28 
                 
                   Δ 
                 
                 
                   Δ 
                 
                 X 
                 Comp. Ex. 
               
               
                 22 
                 640 
                 33 
                  6 
                 99 
                 — 
                 0.32 
                 
                   X 
                 
                 
                   X 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 23 
                 660 
                 33 
                  5 
                 94 
                 — 
                 0.28 
                 
                   X 
                 
                 
                   X 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 24 
                 650 
                 33 
                  4 
                 90 
                  9 
                 0.32 
                 
                   X 
                 
                 
                   X 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 25 
                 665 
                 33 
                  5 
                 96 
                 — 
                 0.29 
                 
                   X 
                 
                 
                   X 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 26 
                 670 
                 32 
                  5 
                 88 
                 11 
                 0.33 
                 
                   X 
                 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                   
               
               
                 Note)  
               
               
                 In the table, mark       indicates that the value is outside the scope of the present invention.  
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE B6 
               
             
            
               
                   
               
               
                 (continuation from TABLE B5) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                   
                 Retained 
                 Zn content of 
                 Fe content of 
                 Al content of 
                 Appearance 
                 Plating 
                   
                   
               
               
                 Sample 
                 TS, MPa 
                 El, % 
                 γ, % 
                 coating, % 
                 coating, % 
                 coating, % 
                 of coating 
                 adhesion 
                 Weldability 
                 Remarks 
               
               
                   
               
               
                 27 
                 550 
                 24 
                 
                   1 
                 
                 89 
                 10 
                 0.41 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp.Ex 
               
               
                 28 
                 600 
                 26 
                 
                   1 
                 
                 89 
                 10 
                 0.21 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 29 
                 620 
                 20 
                 
                   1 
                 
                 90 
                  9 
                 0.23 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 30 
                 580 
                 22 
                 1 
                 89 
                 10 
                 0.63 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 31 
                 550 
                 26 
                 
                   1 
                 
                 89 
                 10 
                 0.27 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 32 
                 650 
                 24 
                 
                   1 
                 
                 88 
                 11 
                 0.34 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 33 
                 610 
                 34 
                 6 
                 84 
                 
                   15 
                 
                 0.28 
                 ◯ 
                 
                   Δ 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 34 
                 600 
                 29 
                 
                   1 
                 
                 89 
                 10 
                 0.41 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 35 
                 610 
                 35 
                 5 
                 
                   94 
                 
                 5 
                 0.23 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 36 
                 570 
                 29 
                 1 
                 84 
                 
                   15 
                 
                 0.23 
                 ◯ 
                 
                   Δ 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 37 
                 630 
                 35 
                 6 
                 
                   92 
                 
                   7   
                 0.23 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 38 
                 580 
                 28 
                 
                   1 
                 
                 84 
                 
                   15 
                 
                 0.32 
                 ◯ 
                 
                   Δ 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 39 
                 580 
                 26 
                 
                   1 
                 
                 89 
                 10 
                 0.23 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 40 
                 560 
                 23 
                 
                   1 
                 
                 89 
                 10 
                 0.32 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 41 
                 630 
                 35 
                 7 
                 88 
                 10 
                 
                   1.23 
                 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 42 
                 550 
                 24 
                 
                   1 
                 
                 89 
                 10 
                 0.41 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 43 
                 600 
                 26 
                 
                   1 
                 
                 89 
                 10 
                 0.21 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 44 
                 620 
                 20 
                 
                   1 
                 
                 90 
                 9 
                 0.23 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 45 
                 580 
                 22 
                 1 
                 89 
                 10 
                 0.63 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 46 
                 550 
                 26 
                 
                   1 
                 
                 89 
                 10 
                 0.27 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 47 
                 650 
                 24 
                 
                   1 
                 
                 88 
                 11 
                 0.34 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 48 
                 600 
                 29 
                 
                   1 
                 
                 89 
                 10 
                 0.41 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 49 
                 580 
                 26 
                 
                   1 
                 
                 89 
                 10 
                 0.23 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 50 
                 560 
                 23 
                 
                   1 
                 
                 89 
                 10 
                 0.32 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 51 
                 630 
                 35 
                 7 
                 88 
                 10 
                 
                   1.23 
                 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                   
               
               
                 Note)  
               
               
                 In the table, mark      indicates that the value is outside the scope of the present invention.  
               
            
           
         
       
     
     Example B2 
     Steels having chemical compositions shown in Table B7 and Table B8 (continuation from Table B7) were reheated to 1250° C., were then finish rolled at 900° C., and were coiled at 650° C. to prepare 4 mm-thick hot rolled steel sheets. Scale deposited on the surface of the hot rolled steel sheets was removed with hydrochloric acid, and the steel sheets were then cold rolled to prepare 1.4 mm-thick cold rolled steel sheets. The cold rolled steel sheets were annealed under conditions shown in Table B9 and Table B10 (continuation from Table B9), were coated, and were then temper rolled with a reduction of 0.5%. The steel sheets thus obtained were subjected to the following performance evaluation tests, that is, “tensile test,” “retained austenite measuring test,” “welding test,” “appearance of coating,” “plating adhesion,” and “measurement of concentration in coated layer.” In the coating in the above production of the steel sheets, both sides of the cold rolled steel sheets were coated at a coverage of coating of 50 g/m 2  per side. 
     In the “tensile test,” a JIS No. 5 tensile test piece was extracted in C-direction, and a cold tensile test was carried out under conditions of gauge thickness 50 mm and tensile speed 10 mm/min. 
     The “retained austenite measuring test” was carried out by a method called “5-peak” method. In this method, a quarter of the sheet thickness from the surface toward the inner side of the sheet was chemically polished, α-iron intensity and γ-iron intensity were then measured by X-ray diffractometry using an Mo bulb, and the volume fraction of retained austenite was determined based on the α-iron intensity and the γ-iron intensity. 
     The “welding test” was carried out by performing spot welding under welding conditions of welding current: 10 kA, applied pressure: 220 kg, welding time: 12 cycles, electrode diameter: 6 mm, electrode shape: domed, and tip: 6φ-40R, and counting the number of continuous spots provided until the welding reached the point at which the nugget diameter became below 4√{square root over (t)} wherein t represents sheet thickness. The counted number of continuous spots was evaluated according to the following criteria. ⊚: more than 2,000 continuous spots, ◯: more than 1,000 continuous spots, Δ: 500 to 1,000 continuous spots, and ×: less than 500 continuous spots. Here ⊚ and ◯ were regarded as acceptable, and A and × as unacceptable. 
     The “appearance of coating” was determined by visually inspecting the appearance of the coated steel sheet for noncoated sites and evaluating the results according to the following criteria. 
     ◯: not more than 5/dm 2 , Δ: 6 to 15/dm 2 , and ×: not less than 16/dm 2 . 
     Here ◯ was regarded as acceptable, and Δ and × as unacceptable. 
     The “plating adhesion” was determined by subjecting the coated steel sheet to a 60-degree V bending test, then performing a tape test, and evaluating the results according to the following criteria. 
     Blackening in tape test (%) 
     ⊚: 0 to 10 
     ◯: 10 to less than 20 
     Δ: 20 to less than 30 
     ×: not less than 30 
     (⊚ and ◯: acceptable, Δ and ×: unacceptable) 
     The “measurement of concentration in coated layer” was carried out by dissolving the coated layer in 5% hydrochloric acid containing an amine-based inhibitor and then analyzing the solution by ICP emission spectroscopy. 
     The results of the above performance evaluation tests are shown in Table B11 and Table B12 (continuation from Table B11). For all of samples 52 to 64 which are examples of the present invention, the total elongation was not less than 30% while ensuring a tensile strength of not less than 550 MPa, indicating that high strength and good press formability could be simultaneously realized. At the same time, for these samples, the plating adhesion was acceptable. 
     By contrast, samples 65 to 77, which are comparative examples, could not attain the object of the present invention due to poor strength-ductility balance or poor plating adhesion, because, for sample 65, the content of carbon (C) was lower than the carbon (C) content range specified in the present invention; for sample 66, the content of carbon (C) was higher than the carbon (C) content range specified in the present invention; for sample 67, the content of silicon (Si) was lower than the silicon (Si) content range specified in the present invention; for sample 68, the content of silicon (Si) was higher than the silicon (Si) content range specified in the present invention; samples 69 and 70 failed to satisfy the relationship between silicon (Si) and aluminum (Al) specified in the present invention; for sample 71, the content of manganese (Mn) was lower than the manganese (Mn) content range specified in the present invention; for sample 72, the content of manganese (Mn) was higher than the manganese (Mn) content range specified in the present invention; for sample 73, the content of aluminum (Al) was higher than the aluminum (Al) content range specified in the present invention; for samples 74, 75, and 76, the content of beryllium (Be)+calcium (Ca)+magnesium (Mg)+zirconium (Zr) was lower than the beryllium (Be)+calcium (Ca)+magnesium (Mg)+zirconium (Zr) content range specified in the present invention; and, for sample 77, the content of beryllium (Be)+calcium (Ca)+magnesium (Mg)+zirconium (Zr) was higher than the beryllium (Be)+calcium (Ca)+magnesium (Mg)+zirconium (Zr) content range specified in the present invention. 
     For samples 78 to 102 as comparative examples, although the chemical compositions of the steels fell within the scope of the present invention, any one of the treatment conditions was outside the scope of the present invention. These comparative samples suffered from poor strength-ductility balance or poor plating adhesion and thus could not attain the object of the present invention. 
     
       
         
           
               
               
               
             
               
                   
                 TABLE B7 
               
             
            
               
                   
                   
               
               
                   
                 Chemical composition, weight % 
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Steel 
                 C 
                 Si 
                 Mn 
                 P 
                 S 
                 Al 
                 Be 
                 Ca 
                 Mg 
                 Zr 
                 Be + Ca + Mg + Zr 
                 Others 
                 Si + 0.8 Al 
                 Remarks 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 aa 
                 0.08 
                 1.21 
                 1.55 
                 0.004 
                 0.005 
                 0.25 
                 0.056 
                 0 
                 0 
                 0 
                 0.056 
                 — 
                 1.41 
                 Ex. of inv. 
               
               
                 ab 
                 0.12 
                 0.24 
                 2.21 
                 0.014 
                 0.003 
                 0.73 
                 0 
                 0.050 
                 0 
                 0 
                 0.050 
                 Mo: 0.11, Bi: 0.02 
                 0.824 
                 Ex. of inv. 
               
               
                 ac 
                 0.16 
                 1.30 
                 1.40 
                 0.008 
                 0.004 
                 0.02 
                 0 
                 0 
                 0.022 
                 0.022 
                 0.044 
                 Sn: 0.05, Cr: 0.22 
                 1.316 
                 Ex. of inv. 
               
               
                 ad 
                 0.13 
                 0.65 
                 1.00 
                 0.009 
                 0.006 
                 0.74 
                 0 
                 0 
                 0 
                 0.120 
                 0.120 
                 Ni: 0.12 
                 1.242 
                 Ex. of inv. 
               
               
                 ae 
                 0.04 
                 1.30 
                 2.40 
                 0.015 
                 0.002 
                 0.21 
                 0.082 
                 0.060 
                 0.043 
                 0.020 
                 0.205 
                 Ce: 0.002, Nb: 0.03 
                 1.468 
                 Ex. of inv. 
               
               
                 af 
                 0.07 
                 0.34 
                 0.90 
                 0.012 
                 0.012 
                 0.65 
                 0.008 
                 0.002 
                 0.008 
                 0.001 
                 0.019 
                 Ti: 0.02, Zr: 0.05 
                 0.86 
                 Ex. of inv. 
               
               
                 ag 
                 0.17 
                 1.70 
                 1.50 
                 0.005 
                 0.008 
                 0.23 
                 0.112 
                 0.200 
                 0.100 
                 0.100 
                 0.512 
                 Sb: 0.003 
                 1.884 
                 Ex. of inv. 
               
               
                 ah 
                 0.09 
                 0.82 
                 1.40 
                 0.005 
                 0.004 
                 0.34 
                 0.187 
                 0 
                 0.742 
                 0.030 
                 0.959 
                 — 
                 1.092 
                 Ex. of inv. 
               
               
                 ai 
                 0.11 
                 0.46 
                 1.60 
                 0.012 
                 0.011 
                 0.95 
                 0.742 
                 0.110 
                 0.046 
                 0.020 
                 0.918 
                 Y: 0.07, Se: 0.01 
                 1.22 
                 Ex. of inv. 
               
               
                 aj 
                 0.07 
                 1.12 
                 1.30 
                 0.004 
                 0.005 
                 0.02 
                 0.006 
                 0.320 
                 0.100 
                 0 
                 0.426 
                 — 
                 1.136 
                 Ex. of inv. 
               
               
                 ak 
                 0.18 
                 0.93 
                 1.6  
                 0.008 
                 0.009 
                 0.14 
                 0 
                 0.230 
                 0.230 
                 0.060 
                 0.520 
                 Mo: 0.04, Ti: 0.01, Sb: 
                 1.042 
                 Ex. of inv. 
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 0.02 
               
               
                 al 
                 0.08 
                 0.82 
                 1.70 
                 0.004 
                 0.005 
                 0.13 
                 0.046 
                 0.020 
                 0 
                 0.010 
                 0.076 
                 — 
                 0.924 
                 Ex. of inv. 
               
               
                 am 
                 0.17 
                 1.40 
                 1.70 
                 0.005 
                 0.008 
                 0.23 
                 0 
                 0.200 
                 0.102 
                 0.100 
                 0.402 
                 Co: 0.05 
                 1.584 
                 Ex. of inv. 
               
               
                   
               
               
                 Note)  
               
               
                 In the table, mark      indicates that the value is outside the scope of the present invention;  
               
               
                 mark * indicates that the value does not satisfy the relationship between Al and Si specified in the present invention; and  
               
               
                 mark — indicates that the constituent is not contained.  
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE B8 
               
             
            
               
                   
               
               
                 (continuation from TABLE 7) 
               
            
           
           
               
               
               
            
               
                   
                 Chemical composition, weight % 
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Steel 
                 C 
                 Si 
                 Mn 
                 P 
                 S 
                 Al 
                 Be 
                 Ca 
                 Mg 
                 Zr 
                 Be + Ca + Mg + Zr 
                 Others 
                 Si + 0.8 Al 
                 Remarks 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 an 
                 
                   0.01 
                 
                 0.34 
                 1.03 
                 0.003 
                 0.005 
                 0.55 
                 0.028 
                 0.010 
                 0.020 
                 0.030 
                 0.088 
                 — 
                 0.78 
                 Comp. Ex. 
               
               
                 ao 
                 
                   0.22 
                 
                 0.62 
                 1.82 
                 0.013 
                 0.002 
                 0.22 
                 0.102 
                 0.020 
                 0.112 
                 0.020 
                 0.254 
                 Sn: 0.05 
                 0.796 
                 Comp. Ex. 
               
               
                 ap 
                 0.13 
                 
                   0.13 
                 
                 1.34 
                 0.007 
                 0.003 
                 0.39 
                 0.043 
                 0.020 
                 0.010 
                 0 
                 0.073 
                 Ce: 0.2 
                 0.442 
                 Comp. Ex. 
               
               
                 aq 
                 0.16 
                 
                   1.92 
                 
                 0.97 
                 0.008 
                 0.002 
                 0.24 
                 0 
                 0.002 
                 0.030 
                 0.002 
                 0.034 
                 — 
                 2.112 
                 Comp. Ex. 
               
               
                 ar 
                 0.15 
                 
                   *0.22 
                 
                 0.58 
                 0.004 
                 0.007 
                 
                   *0.12 
                 
                 0.210 
                 0.020 
                 0.112 
                 0.230 
                 0.572 
                 V: 0.01, Zr: 0.02 
                 
                   0.316 
                 
                 Comp. Ex. 
               
               
                 as 
                 0.12 
                 
                   *1.55 
                 
                 1.52 
                 0.005 
                 0.003 
                 
                   *0.73 
                 
                 0.192 
                 0.080 
                 0 
                 0.130 
                 0.402 
                 — 
                 
                   2.134 
                 
                 Comp. Ex. 
               
               
                 at 
                 0.06 
                 0.36 
                 
                   0.18 
                 
                 0.008 
                 0.003 
                 0.22 
                 0.062 
                 0.042 
                 0.008 
                 0.220 
                 0.332 
                 Cu: 0.22, Bi: 0.021 
                 0.536 
                 Comp. Ex. 
               
               
                 au 
                 0.14 
                 0.73 
                 
                   2.65 
                 
                 0.009 
                 0.005 
                 0.54 
                 0 
                 0.230 
                 0.130 
                 0 
                 0.360 
                 Cr: 0.23, Mo: 0.09 
                 1.162 
                 Comp. Ex. 
               
               
                 av 
                 0.12 
                 0.54 
                 0.85 
                 0.005 
                 0.006 
                 
                   1.63 
                 
                 0.008 
                 0.010 
                 0.010 
                 0.023 
                 0.051 
                 — 
                 1.844 
                 Comp. Ex. 
               
               
                 aw 
                 0.09 
                 0.62 
                 1.22 
                 0.012 
                 0.002 
                 0.32 
                 
                   0.001 
                 
                 0 
                 0 
                 0 
                 
                   0.001 
                 
                 Ti: 0.03, Nb: 0.03 
                 0.876 
                 Comp. Ex. 
               
               
                 ax 
                 0.09 
                 0.62 
                 1.22 
                 0.012 
                 0.002 
                 0.32 
                 0 
                 
                   0.002 
                 
                 0.001 
                 0 
                 
                   0.003 
                 
                 Ni: 0.11, Sb: 0.02 
                 0.876 
                 Comp. Ex. 
               
               
                 ay 
                 0.09 
                 0.62 
                 1.22 
                 0.012 
                 0.002 
                 0.32 
                 
                   0.001 
                 
                 0 
                 0 
                 
                   0.001 
                 
                 
                   0.002 
                 
                 Sn: 0.04 
                 0.876 
                 Comp. Ex. 
               
               
                 az 
                 0.09 
                 0.62 
                 1.22 
                 0.012 
                 0.002 
                 0.32 
                 
                   0.861 
                 
                 
                   0.200 
                 
                 
                   0.112 
                 
                 
                   0.229 
                 
                 
                   1.402 
                 
                   
                 0.876 
                 Comp. Ex. 
               
               
                   
               
               
                 Note)  
               
               
                 In the table, mark      indicates that the value is outside the scope of the present invention;  
               
               
                 mark * indicates that the value does not satisfy the relationship between Al and Si specified in the present invention; and  
               
               
                 mark — indicates that the constituent is not contained.  
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE B9 
               
               
                   
               
               
                   
                   
                 Anneal- 
                 Anneal- 
                   
                   
                   
                   
                   
                 Al 
                 Alloy- 
                   
                   
                   
                   
               
               
                   
                   
                 ing 
                 ing 
                 Cooling 
                 Cooling 
                 Holding 
                 Holding 
                 Coating 
                 content 
                 ing 
                 Alloying 
                 Cooling 
                 Cooling 
                   
               
               
                 Sam- 
                   
                 temp.,  
                 time, 
                 rate, 
                 termination 
                 temp. before 
                 time, 
                 temp., 
                 of zinc 
                 temp., 
                 time, 
                 rate, 
                 temp., 
                 Re- 
               
               
                 ple 
                 Steel 
                 ° C. 
                 sec 
                 ° C./sec 
                 temp., ° C. 
                 coating, ° C. 
                 sec 
                 ° C. 
                 bath, % 
                 ° C. 
                 sec 
                 ° C./sec 
                 ° C. 
                 marks 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 52 
                 aa 
                 800 
                 150 
                 10 
                 400 
                 400-450 
                  60 
                 450 
                 0.11 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 53 
                 ab 
                 750 
                 90 
                 20 
                 400 
                 — 
                 — 
                 450 
                 0.14 
                 520 
                 30 
                 15 
                 150 
                 GA 
               
               
                 54 
                 ac 
                 800 
                 100 
                 40 
                 420 
                 360-400 
                 420 
                 470 
                 0.16 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 55 
                 ad 
                 750 
                 90 
                 150 
                 380 
                 — 
                 — 
                 450 
                 0.10 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 56 
                 ae 
                 780 
                 150 
                 3 
                 370 
                 350-380 
                 300 
                 440 
                 0.12 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 57 
                 af 
                 800 
                 90 
                 20 
                 480 
                 — 
                 — 
                 450 
                 0.15 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 58 
                 ag 
                 750 
                 200 
                 20 
                 410 
                 — 
                 — 
                 450 
                 0.15 
                 500 
                 30 
                 10 
                 180 
                 GA 
               
               
                 59 
                 ah 
                 850 
                 85 
                 7 
                 440 
                 400-470 
                  40 
                 450 
                 0.20 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 60 
                 ai 
                 750 
                 150 
                 10 
                 360 
                 360-440 
                 200 
                 450 
                 0.11 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 61 
                 aj 
                 800 
                 90 
                 20 
                 480 
                 400-500 
                 100 
                 450 
                 0.15 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 62 
                 ak 
                 750 
                 110 
                 5 
                 440 
                 — 
                 — 
                 450 
                 0.20 
                 500 
                 30 
                 10 
                 180 
                 GA 
               
               
                 63 
                 al 
                 700 
                 120 
                 10 
                 400 
                 360-440 
                  60 
                 450 
                 0.18 
                 550 
                 10 
                 10 
                 180 
                 GA 
               
               
                 64 
                 am 
                 800 
                 200 
                 15 
                 430 
                 — 
                 — 
                 460 
                 0.20 
                 — 
                 — 
                 10 
                 200 
                 GI 
               
               
                 65 
                 an 
                 830 
                 90 
                 20 
                 410 
                 400-470 
                  30 
                 450 
                 0.15 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 66 
                 ao 
                 800 
                 120 
                 6 
                 420 
                 — 
                 — 
                 460 
                 0.14 
                 520 
                 15 
                 10 
                 180 
                 GA 
               
               
                 67 
                 ap 
                 750 
                 110 
                 10 
                 370 
                 — 
                 — 
                 450 
                 0.10 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 68 
                 aq 
                 820 
                 90 
                 20 
                 480 
                 430-500 
                  30 
                 450 
                 0.09 
                 580 
                 30 
                 10 
                 180 
                 GA 
               
               
                 69 
                 ar 
                 750 
                 90 
                 20 
                 410 
                 — 
                 — 
                 450 
                 0.16 
                 500 
                 20 
                 10 
                 180 
                 GA 
               
               
                 70 
                 as 
                 870 
                 150 
                 9 
                 440 
                 370-440 
                 300 
                 450 
                 0.13 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 71 
                 at 
                 750 
                 70 
                 20 
                 420 
                 — 
                 — 
                 450 
                 0.18 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 72 
                 au 
                 830 
                 90 
                 10 
                 480 
                 400-490 
                  30 
                 450 
                 0.17 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 73 
                 av 
                 750 
                 200 
                 20 
                 490 
                 400-470 
                  80 
                 450 
                 0.09 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 74 
                 aw 
                 800 
                 120 
                 5 
                 400 
                 — 
                 — 
                 440 
                 0.14 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 75 
                 ax 
                 750 
                 110 
                 10 
                 400 
                 — 
                 — 
                 440 
                 0.14 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 76 
                 ay 
                 800 
                 120 
                 5 
                 400 
                 400-470 
                  80 
                 440 
                 0.14 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 77 
                 az 
                 800 
                 70 
                 20 
                 440 
                 — 
                 — 
                 440 
                 0.14 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                   
               
               
                 Note)  
               
               
                 In the table, mark      indicates that the value is outside the scope of the present invention; the heating rate after coating was constant and 10° C./sec; and  
               
               
                 GA represents a hot-dip galvannealed steel sheet, and  
               
               
                 GI represents a hot-dip galvanized steel sheet.  
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE B10 
               
             
            
               
                   
               
               
                 (continuation from TABLE B9) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                 Anneal- 
                 Anneal- 
                   
                   
                   
                   
                   
                 Al 
                 Alloy- 
                   
                   
                   
                   
               
               
                   
                   
                 ing 
                 ing 
                 Cooling 
                 Cooling 
                 Holding 
                 Holding 
                 Coating 
                 content 
                 ing 
                 Alloying 
                 Cooling 
                 Cooling 
                   
               
               
                 Sam- 
                   
                 temp.,  
                 time, 
                 rate, 
                 termination 
                 temp. before 
                 time, 
                 temp., 
                 of zinc 
                 temp., 
                 time, 
                 rate, 
                 temp., 
                 Re- 
               
               
                 ple 
                 Steel 
                 ° C. 
                 sec 
                 ° C./sec 
                 temp., ° C. 
                 coating, ° C. 
                 sec 
                 ° C. 
                 bath, % 
                 ° C. 
                 sec 
                 ° C./sec 
                 ° C. 
                 marks 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 78 
                 aa 
                 
                   600 
                 
                 90 
                 20 
                 360 
                 — 
                 — 
                 470 
                 0.08 
                 500 
                 30 
                 10 
                 180 
                 GA 
               
               
                 79 
                 aa 
                 
                   950 
                 
                 90 
                 80 
                 480 
                 400-500 
                  60 
                 450 
                 0.11 
                 480 
                 50 
                 10 
                 180 
                 GA 
               
               
                 80 
                 aa 
                 750 
                   5   
                 20 
                 440 
                 430-500 
                  20 
                 450 
                 0.20 
                 500 
                 30 
                 10 
                 180 
                 GA 
               
               
                 81 
                 aa 
                 800 
                   400   
                 20 
                 410 
                 — 
                 — 
                 480 
                 0.17 
                 500 
                 40 
                 20 
                 220 
                 GA 
               
               
                 82 
                 aa 
                 750 
                 90 
                   1   
                 370 
                 430-500 
                  30 
                 450 
                 0.13 
                 510 
                 30 
                 10 
                 180 
                 GA 
               
               
                 83 
                 aa 
                 800 
                 110  
                 10 
                 
                   300 
                 
                 370-440 
                 300 
                 450 
                 0.09 
                 480 
                 50 
                 10 
                 180 
                 GA 
               
               
                 84 
                 aa 
                 770 
                 90 
                 70 
                 
                   520 
                 
                 370-440 
                 300 
                 450 
                 0.14 
                 500 
                 30 
                 10 
                 180 
                 GA 
               
               
                 85 
                 aa 
                 830 
                 150  
                 10 
                 420 
                 400-490 
                 
                   650 
                 
                 480 
                 0.18 
                 500 
                 30 
                 10 
                 180 
                 GA 
               
               
                 86 
                 aa 
                 800 
                 70 
                 20 
                 410 
                 400-470 
                  80 
                 430 
                 0.11 
                 430 
                 40 
                 15 
                 180 
                 GA 
               
               
                 87 
                 aa 
                 750 
                 90 
                 25 
                 440 
                 370-440 
                 140 
                 480 
                 0.16 
                 
                   620 
                 
                 20 
                 10 
                 100 
                 GA 
               
               
                 88 
                 aa 
                 850 
                 60 
                 20 
                 420 
                 — 
                 — 
                 450 
                 0.20 
                 500 
                   3   
                 8 
                 180 
                 GA 
               
               
                 89 
                 aa 
                 750 
                 90 
                 80 
                 480 
                 — 
                 — 
                 450 
                 0.12 
                 500 
                   130   
                 10 
                 180 
                 GA 
               
               
                 90 
                 aa 
                 820 
                 70 
                 50 
                 490 
                 400-470 
                 250 
                 440 
                 0.10 
                 500 
                 25 
                   3   
                 180 
                 GA 
               
               
                 91 
                 aa 
                 750 
                 100  
                 20 
                 360 
                 — 
                 — 
                 450 
                 0.08 
                 500 
                 30 
                 10 
                 
                   300 
                 
                 GA 
               
               
                 92 
                 aa 
                 830 
                 90 
                 20 
                 480 
                 400-500 
                  60 
                 450 
                 
                   0.82 
                 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 93 
                 aa 
                 
                   600 
                 
                 90 
                 20 
                 360 
                 — 
                 — 
                 470 
                 0.08 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 94 
                 aa 
                 
                   950 
                 
                 90 
                 80 
                 480 
                 400-500 
                  60 
                 450 
                 0.11 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 95 
                 aa 
                 750 
                   5   
                 20 
                 440 
                 430-500 
                  20 
                 450 
                 0.20 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 96 
                 aa 
                 800 
                   420   
                 20 
                 410 
                 — 
                 — 
                 480 
                 0.17 
                 — 
                 — 
                 20 
                 220 
                 GI 
               
               
                 97 
                 as 
                 750 
                 90 
                   1   
                 370 
                 430-500 
                  30 
                 450 
                 0.13 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 98 
                 aa 
                 800 
                 110  
                 10 
                 
                   300 
                 
                 370-440 
                 300 
                 450 
                 0.09 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 99 
                 aa 
                 830 
                 150  
                 10 
                 420 
                 400-490 
                 
                   720 
                 
                 480 
                 0.18 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 100 
                 aa 
                 820 
                 70 
                 50 
                 490 
                 400-470 
                 250 
                 440 
                 0.10 
                 — 
                 — 
                 
                   3 
                 
                 180 
                 GI 
               
               
                 101 
                 aa 
                 750 
                 100  
                 20 
                 360 
                 — 
                 — 
                 450 
                 0.08 
                 — 
                 — 
                 10 
                 
                   300 
                 
                 GI 
               
               
                 102 
                 aa 
                 830 
                 90 
                 20 
                 480 
                 400-500 
                  60 
                 450 
                 
                   0.82 
                 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                   
               
               
                 Note)  
               
               
                 In the table, mark      indicates that the value is outside the scope of the present invention; the heating rate after coating was constant and 10° C./sec; and  
               
               
                 GA represents a hot-dip galvannealed steel sheet, and  
               
               
                 GI represents a hot-dip galvanized steel sheet.  
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE B11 
               
               
                   
               
               
                   
                   
                   
                 Retained 
                 Zn content of 
                 Fe content of 
                 Al content of 
                 Appearance 
                 Plating 
                   
                   
               
               
                 Sample 
                 TS, MPa 
                 El, % 
                 γ, % 
                 coating, % 
                 coating, % 
                 coating, % 
                 of coating 
                 adhesion 
                 Weldability 
                 Remarks 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                 52 
                 630 
                 36 
                  8 
                 89 
                 10 
                 0.22 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Ex. of inv. 
               
               
                 53 
                 660 
                 34 
                 10 
                 89 
                 10 
                 0.18 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Ex. of inv. 
               
               
                 54 
                 720 
                 34 
                 13 
                 98 
                 — 
                 0.28 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Ex. of inv. 
               
               
                 55 
                 640 
                 31 
                 11 
                 88 
                 11 
                 0.16 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Ex. of inv. 
               
               
                 56 
                 780 
                 30 
                  3 
                 94 
                 — 
                 0.18 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Ex. of inv. 
               
               
                 57 
                 580 
                 36 
                  9 
                 89 
                 10 
                 0.82 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Ex. of inv. 
               
               
                 58 
                 840 
                 31 
                 15 
                 89 
                 10 
                 0.13 
                 ◯ 
                 ◯ 
                 ⊚ 
                 Ex. of inv. 
               
               
                 59 
                 640 
                 36 
                  8 
                 87 
                 12 
                 0.16 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Ex. of inv. 
               
               
                 60 
                 630 
                 35 
                 10 
                 99 
                 — 
                 0.25 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Ex. of inv. 
               
               
                 61 
                 620 
                 36 
                  7 
                 89 
                 10 
                 0.17 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Ex. of inv. 
               
               
                 62 
                 810 
                 31 
                 18 
                 89 
                 10 
                 0.23 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Ex. of inv. 
               
               
                 63 
                 610 
                 35 
                  4 
                 88 
                 11 
                 0.32 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Ex. of inv. 
               
               
                 64 
                 830 
                 32 
                 15 
                 99 
                 — 
                 0.18 
                 ◯ 
                 ◯ 
                 ◯ 
                 Ex. of inv. 
               
               
                 65 
                 540 
                 28 
                   1   
                 93 
                 — 
                 0.20 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 66 
                 810 
                 25 
                 
                   22 
                 
                 89 
                 10 
                 0.21 
                 ◯ 
                 ⊚ 
                 
                   X 
                 
                 Comp. Ex. 
               
               
                 67 
                 570 
                 28 
                   1   
                 89 
                 10 
                 0.16 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 68 
                 710 
                 30 
                  8 
                 
                   93 
                 
                   6   
                 0.32 
                 
                   X 
                 
                 
                   X 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 69 
                 550 
                 29 
                   1   
                 89 
                 10 
                 0.13 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 70 
                 620 
                 33 
                  6 
                 89 
                 10 
                 0.19 
                 
                   X 
                 
                 
                   X 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 71 
                 560 
                 20 
                   1   
                 90 
                  9 
                 0.23 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 72 
                 700 
                 34 
                  7 
                 89 
                 10 
                 0.28 
                 
                   Δ 
                 
                 
                   Δ 
                 
                 X 
                 Comp. Ex. 
               
               
                 73 
                 640 
                 33 
                  6 
                 99 
                 — 
                 0.32 
                 
                   X 
                 
                 
                   X 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 74 
                 660 
                 33 
                  5 
                 94 
                 — 
                 0.28 
                 
                   X 
                 
                 
                   X 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 75 
                 650 
                 33 
                  4 
                 90 
                  9 
                 0.32 
                 
                   X 
                 
                 
                   X 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 76 
                 665 
                 33 
                  5 
                 96 
                 — 
                 0.29 
                 
                   X 
                 
                 
                   X 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 77 
                 670 
                 32 
                  5 
                 88 
                 11 
                 0.33 
                 
                   X 
                 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                   
               
               
                 Note)  
               
               
                 In the table, mark      indicates that the value is outside the scope of the present invention.  
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE B12 
               
             
            
               
                   
               
               
                 (continuation from TABLE B11) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                   
                 Retained 
                 Zn content of 
                 Fe content of 
                 Al content of 
                 Appearance 
                 Plating 
                   
                   
               
               
                 Sample 
                 TS, MPa 
                 El, % 
                 γ, % 
                 coating, % 
                 coating, % 
                 coating, % 
                 of coating 
                 adhesion 
                 Weldability 
                 Remarks 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                 78 
                 550 
                 24 
                 
                   1 
                 
                 89 
                 10 
                 0.41 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 79 
                 600 
                 26 
                 
                   1 
                 
                 89 
                 10 
                 0.21 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 80 
                 620 
                 20 
                 
                   1 
                 
                 90 
                 9 
                 0.23 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 81 
                 580 
                 22 
                 1 
                 89 
                 10 
                 0.63 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 82 
                 550 
                 26 
                 
                   1 
                 
                 89 
                 10 
                 0.27 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 83 
                 650 
                 24 
                 
                   1 
                 
                 88 
                 11 
                 0.34 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 84 
                 610 
                 34 
                 6 
                 84 
                 
                   15 
                 
                 0.28 
                 ◯ 
                 
                   Δ 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 85 
                 600 
                 29 
                 
                   1 
                 
                 89 
                 10 
                 0.41 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 86 
                 610 
                 35 
                 5 
                 
                   94 
                 
                 5 
                 0.23 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 87 
                 570 
                 29 
                 1 
                 84 
                 
                   15 
                 
                 0.23 
                 ◯ 
                 
                   Δ 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 88 
                 630 
                 35 
                 6 
                 
                   92 
                 
                 
                   7 
                 
                 0.23 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 89 
                 580 
                 28 
                 
                   1 
                 
                 84 
                 
                   15 
                 
                 0.32 
                 ◯ 
                 
                   Δ 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 90 
                 580 
                 26 
                 
                   1 
                 
                 89 
                 10 
                 0.23 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 91 
                 560 
                 23 
                 
                   1 
                 
                 89 
                 10 
                 0.32 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 92 
                 630 
                 35 
                 7 
                 88 
                 10 
                 
                   1.23 
                 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 93 
                 550 
                 24 
                 
                   1 
                 
                 89 
                 10 
                 0.41 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 94 
                 600 
                 26 
                 
                   1 
                 
                 89 
                 10 
                 0.21 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 95 
                 620 
                 20 
                 
                   1 
                 
                 90 
                 9 
                 0.23 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 96 
                 580 
                 22 
                 1 
                 89 
                 10 
                 0.63 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 97 
                 550 
                 26 
                 
                   1 
                 
                 89 
                 10 
                 0.27 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 98 
                 650 
                 24 
                 
                   1 
                 
                 88 
                 11 
                 0.34 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 99 
                 600 
                 29 
                 
                   1 
                 
                 89 
                 10 
                 0.41 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 100 
                 580 
                 26 
                 
                   1 
                 
                 89 
                 10 
                 0.23 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 101 
                 560 
                 23 
                 
                   1 
                 
                 89 
                 10 
                 0.32 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 102 
                 630 
                 35 
                 7 
                 88 
                 10 
                 
                   1.23 
                 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                   
               
               
                 Note)  
               
               
                 In the table, mark       indicates that  the value is outside the scope of the present invention.  
               
            
           
         
       
     
     Example B3 
     Steels having chemical compositions shown in Table B13 and Table B14 (continuation from Table B13) were reheated to 1250° C., were then finish rolled at 900° C., and were coiled at 650° C. to prepare 4 mm-thick hot rolled steel sheets. Scale deposited on the surface of the hot rolled steel sheets was removed with hydrochloric acid, and the steel sheets were then cold rolled to prepare 1.4 mm-thick cold rolled steel sheets. The cold rolled steel sheets were annealed under conditions shown in Table B15 and Table B16 (continuation from Table B15), were coated, and were then temper rolled with a reduction of 0.5%. The steel sheets thus obtained were subjected to the following performance evaluation tests, that is, “tensile test,” “retained austenite measuring test,” “welding test,” “appearance of coating,” “plating adhesion,” and “measurement of concentration in coated layer.” In the coating in the above production of the steel sheets, both sides of the cold rolled steel sheets were coated at a coverage of coating of 50 g/m 2  per side. 
     In the “tensile test,” a JIS No. 5 tensile test piece was extracted in C-direction, and a cold tensile test was carried out under conditions of gauge thickness 50 mm and tensile speed 10 mm/min. 
     The “retained austenite measuring test” was carried out by a method called “5-peak” method. In this method,a quarter of the sheet thickness from the surface toward the inner side of the sheet was chemically polished, α-iron intensity and γ-iron intensity were then measured by X-ray diffractometry using an Mo bulb, and the volume fraction of retained austenite was determined based on the α-iron intensity and the γ-iron intensity. 
     The “welding test” was carried out by performing spot welding under welding conditions of welding current: 10 kA, applied pressure: 220 kg, welding time: 12 cycles, electrode diameter: 6 mm, electrode shape: domed, and tip: 6φ-40R, and counting the number of continuous spots provided until the welding reached the point at which the nugget diameter became below 4√{square root over (t)} wherein t represents sheet thickness. The counted number of continuous spots was evaluated according to the following criteria. ⊚: more than 2,000 continuous spots, ◯: more than 1,000 continuous spots, Δ: 500 to 1,000 continuous spots, and ×: less than 500 continuous spots. Here ⊚ and ◯ were regarded as acceptable, and Δ and × as unacceptable. 
     The “appearance of coating” was determined by visually inspecting the appearance of the coated steel sheet for noncoated sites and evaluating the results according to the following criteria. 
     ◯: not more than 5/dm 2 , Δ: 6 to 15/dm 2 , and ×: not less than 16/dm 2 . 
     Here ◯ was regarded as acceptable, and Δ and × as unacceptable. 
     The “plating adhesion” was determined by subjecting the plated steel sheet to a 60-degree V bending test, then performing a tape test, and evaluating the results according to the following criteria. 
     Blackening in tape test (%) 
     ⊚: 0 to 10 
     ◯: 10 to less than 20 
     Δ: 20 to less than 30 
     ×: not less than 30 
     (⊚ and ◯: acceptable, Δand ×: unacceptable) 
     The “measurement of concentration in coated layer” was carried out by dissolving the coating layer in 5% hydrochloric acid containing an amine-based inhibitor and then analyzing the solution by ICP emission spectroscopy. 
     The results of the above performance evaluation tests are shown in Table B17 and Table B18 (continuation from Table B17). For all of samples 103 to 115 which are examples of the present invention, the total elongation was not less than 30% while ensuring a tensile strength of not less than 550 MPa, indicating that high strength and good press formability could be simultaneously realized. At the same time, for these samples, the plating adhesion was acceptable. 
     By contrast, samples 116 to 128, which are comparative examples, could not attain the object of the present invention due to poor strength-ductility balance or poor plating adhesion, because, for sample 116, the content of carbon (C) was lower than the carbon (C) content range specified in the present invention; for sample 117, the content of carbon (C) was higher than the carbon (C) content range specified in the present invention; for sample 118, the content of silicon (Si) was lower than the silicon (Si) content range specified in the present invention; for sample 119, the content of silicon (Si) was higher than the silicon (Si) content range specified in the present invention; samples 120 and 121 failed to satisfy the relationship between silicon (Si) and aluminum (Al) specified in the present invention; for sample 122, the content of manganese (Mn) was lower than the manganese (Mn) content range specified in the present invention; for sample 123, the content of manganese (Mn) was higher than the manganese (Mn) content range specified in the present invention; for sample 124, the content of aluminum (Al) was higher than the aluminum (Al) content range specified in the present invention; for samples 125, 126, and 127, the content of scandium (Sc)+yttrium (Y)+lanthanum (La)+cerium (Ce) was lower than the scandium (Sc)+yttrium (Y)+lanthanum (La)+cerium (Ce) content range specified in the present invention; and, for sample 128, the content of scandium+yttrium+lanthanum+cerium was higher than the scandium +yttrium+lanthanum+cerium content range specified in the present invention. 
     For samples 129 to 153 (see Table B18) as comparative examples, although the chemical compositions of the steels fell within the scope of the present invention, any one of the treatment conditions was outside the scope of the present invention. These comparative samples suffered from poor strength-ductility balance or poor plating adhesion and thus could not attain the object of the present invention. 
     
       
         
           
               
               
               
             
               
                   
                 TABLE B13 
               
             
            
               
                   
                   
               
               
                   
                 Chemical composition, weight % 
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Steel 
                 C 
                 Si 
                 Mn 
                 P 
                 S 
                 Al 
                 Sc 
                 Y 
                 La 
                 Ce 
                 Sc + Y + La + Ce 
                 Others 
                 Si + 0.8 Al 
                 Remarks 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 ba 
                 0.08 
                 1.21 
                 1.55 
                 0.004 
                 0.005 
                 0.25 
                 0.056 
                 0 
                 0 
                 0 
                 0.056 
                 — 
                 1.41 
                 Ex. of inv. 
               
               
                 bb 
                 0.12 
                 0.24 
                 2.21 
                 0.014 
                 0.003 
                 0.73 
                 0 
                 0.050 
                 0 
                 0 
                 0.050 
                 Mo: 0.11, Ca: 0.02 
                 0.824 
                 Ex. of inv. 
               
               
                 bc 
                 0.16 
                 1.30 
                 1.40 
                 0.008 
                 0.004 
                 0.02 
                 0 
                 0 
                 0.022 
                 0.022 
                 0.044 
                 Sn: 0.05, Cr: 0.22 
                 1.316 
                 Ex. of inv. 
               
               
                 bd 
                 0.13 
                 0.65 
                 1.00 
                 0.009 
                 0.006 
                 0.74 
                 0 
                 0 
                 0 
                 0.120 
                 0.120 
                 Ni: 0.12 
                 1.242 
                 Ex. of inv. 
               
               
                 be 
                 0.04 
                 1.30 
                 2.40 
                 0.015 
                 0.002 
                 0.21 
                 0.082 
                 0.060 
                 0.043 
                 0.020 
                 0.205 
                 Sb: 0.002, Nb: 0.03 
                 1.468 
                 Ex. of inv. 
               
               
                 bf 
                 0.07 
                 0.34 
                 0.90 
                 0.012 
                 0.012 
                 0.65 
                 0.008 
                 0.002 
                 0.008 
                 0.001 
                 0.019 
                 Ti: 0.02, Zr: 0.05 
                 0.86 
                 Ex. of inv. 
               
               
                 bg 
                 0.17 
                 1.70 
                 1.50 
                 0.005 
                 0.008 
                 0.23 
                 0.112 
                 0.200 
                 0.100 
                 0.100 
                 0.512 
                 Mg: 0.003 
                 1.884 
                 Ex. of inv. 
               
               
                 bh 
                 0.09 
                 0.82 
                 1.40 
                 0.005 
                 0.004 
                 0.34 
                 0.187 
                 0 
                 0.742 
                 0.030 
                 0.959 
                 — 
                 1.092 
                 Ex. of inv. 
               
               
                 bi 
                 0.11 
                 0.46 
                 1.60 
                 0.012 
                 0.011 
                 0.95 
                 0.742 
                 0.110 
                 0.046 
                 0.020 
                 0.918 
                 Bi: 0.07, Ca: 0.01 
                 1.22 
                 Ex. of inv. 
               
               
                 bj 
                 0.07 
                 1.12 
                 1.30 
                 0.004 
                 0.005 
                 0.02 
                 0.006 
                 0.320 
                 0.100 
                 0 
                 0.426 
                 — 
                 1.136 
                 Ex. of inv. 
               
               
                 bk 
                 0.18 
                 0.93 
                 1.6  
                 0.008 
                 0.009 
                 0.14 
                 0 
                 0.230 
                 0.230 
                 0.060 
                 0.520 
                 Mo: 0.04, Ti: 0.01, 
                 1.042 
                 Ex. of inv. 
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 Mg: 0.02 
               
               
                 bl 
                 0.08 
                 0.82 
                 1.70 
                 0.004 
                 0.005 
                 0.13 
                 0.046 
                 0.020 
                 0 
                 0.010 
                 0.076 
                 — 
                 0.924 
                 Ex. of inv. 
               
               
                 bm 
                 0.17 
                 1.40 
                 1.70 
                 0.005 
                 0.008 
                 0.23 
                 0 
                 0.200 
                 0.102 
                 0.100 
                 0.402 
                 Mg: 0.02, Co: 0.05 
                 1.584 
                 Ex. of inv. 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE B14 
               
             
            
               
                   
               
               
                 (continuation from TABLE B13) 
               
            
           
           
               
               
               
            
               
                   
                 Chemical composition, weight % 
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Steel 
                 C 
                 Si 
                 Mn 
                 P 
                 S 
                 Al 
                 Sc 
                 Y 
                 La 
                 Ce 
                 Sc + Y + La + Ce 
                 Others 
                 Si + 0.8 Al 
                 Remarks 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 bn 
                 
                   0.01 
                 
                 0.34 
                 1.03 
                 0.003 
                 0.005 
                 0.55 
                 0.028 
                 0.010 
                 0.020 
                 0.030 
                 0.088 
                 — 
                 0.78 
                 Comp. Ex. 
               
               
                 bo 
                 
                   0.22 
                 
                 0.62 
                 1.82 
                 0.013 
                 0.002 
                 0.22 
                 0.102 
                 0.020 
                 0.112 
                 0.020 
                 0.254 
                 Sn: 0.05 
                 0.796 
                 Comp. Ex. 
               
               
                 bp 
                 0.13 
                 
                   0.13 
                 
                 1.34 
                 0.007 
                 0.003 
                 0.39 
                 0.043 
                 0.020 
                 0.010 
                 0 
                 0.073 
                 Se: 0.2 
                 0.442 
                 Comp. Ex. 
               
               
                 bq 
                 0.16 
                 
                   1.92 
                 
                 0.97 
                 0.008 
                 0.002 
                 0.24 
                 0 
                 0.002 
                 0.030 
                 0.002 
                 0.034 
                 — 
                 2.112 
                 Comp. Ex. 
               
               
                 br 
                 0.15 
                 
                   *0.22 
                 
                 0.58 
                 0.004 
                 0.007 
                 
                   *0.12 
                 
                 0.210 
                 0.020 
                 0.112 
                 0.230 
                 0.572 
                 V: 0.01, Zr: 0.02 
                 
                   0.316 
                 
                 Comp. Ex. 
               
               
                 bs 
                 0.12 
                 
                   *1.55 
                 
                 1.52 
                 0.005 
                 0.003 
                 
                   *0.73 
                 
                 0.192 
                 0.080 
                 0 
                 0.130 
                 0.402 
                 — 
                 
                   2.134 
                 
                 Comp. Ex. 
               
               
                 bt 
                 0.06 
                 0.36 
                 
                   0.18 
                 
                 0.008 
                 0.003 
                 0.22 
                 0.062 
                 0.042 
                 0.008 
                 0.220 
                 0.332 
                 Cu: 0.22, Ca: 0.021 
                 0.536 
                 Comp. Ex. 
               
               
                 bu 
                 0.14 
                 0.73 
                 
                   2.65 
                 
                 0.009 
                 0.005 
                 0.54 
                 0 
                 0.230 
                 0.130 
                 0 
                 0.360 
                 Cr: 0.23, Mo: 0.09 
                 1.162 
                 Comp. Ex. 
               
               
                 bv 
                 0.12 
                 0.54 
                 0.85 
                 0.005 
                 0.006 
                 
                   1.63 
                 
                 0.008 
                 0.010 
                 0.010 
                 0.023 
                 0.051 
                 — 
                 1.844 
                 Comp. Ex. 
               
               
                 bw 
                 0.09 
                 0.62 
                 1.22 
                 0.012 
                 0.002 
                 0.32 
                 
                   0.001 
                 
                 0 
                 0 
                 0 
                 
                   0.001 
                 
                 Ti: 0.03, Nb: 0.03 
                 0.876 
                 Comp. Ex. 
               
               
                 bx 
                 0.09 
                 0.62 
                 1.22 
                 0.012 
                 0.002 
                 0.32 
                 0 
                 
                   0.002 
                 
                 0.001 
                 0 
                 
                   0.003 
                 
                 Ni: 0.11, Mg: 0.02 
                 0.876 
                 Comp. Ex. 
               
               
                 by 
                 0.09 
                 0.62 
                 1.22 
                 0.012 
                 0.002 
                 0.32 
                 
                   0.001 
                 
                 0 
                 0 
                 
                   0.001 
                 
                 
                   0.002 
                 
                 Sn: 0.04 
                 0.876 
                 Comp. Ex. 
               
               
                 bz 
                 0.09 
                 0.62 
                 1.22 
                 0.012 
                 0.002 
                 0.32 
                 
                   0.861 
                 
                 
                   0.200 
                 
                 
                   0.112 
                 
                 
                   0.229 
                 
                 
                   1.402 
                 
                   
                 0.876 
                 Comp. Ex. 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE B15 
               
               
                   
               
               
                   
                   
                   
                   
                 Cool- 
                 Cooling 
                 Holding 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                   
                   
                 Anneal- 
                 Anneal- 
                 ing 
                 termi- 
                 temp. 
               
               
                   
                   
                 ing 
                 ing 
                 rate 
                 nation 
                 before 
                 Holding 
                   
                   
                 Alloying 
                 Alloying 
                 Cooling 
                 Cooling 
               
               
                 Sam- 
                   
                 temp., 
                 time, 
                 ° C./ 
                 temp., 
                 coating, 
                 time, 
                 Coating 
                 Al content of 
                 temp., 
                 time, 
                 rate, 
                 temp., 
                 Re- 
               
               
                 ple 
                 Steel 
                 ° C. 
                 sec 
                 sec 
                 ° C. 
                 ° C. 
                 sec 
                 temp., ° C. 
                 zinc bath, % 
                 ° C. 
                 sec 
                 ° C./sec 
                 ° C. 
                 marks 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 103 
                 ba 
                 800 
                 150 
                 10 
                 400 
                 400- 
                 60 
                 450 
                 0.11 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                   
                   
                   
                   
                   
                   
                 450 
               
               
                 104 
                 bb 
                 750 
                 90 
                 20 
                 400 
                 — 
                 — 
                 450 
                 0.14 
                 520 
                 30 
                 15 
                 150 
                 GA 
               
               
                 105 
                 bc 
                 800 
                 100 
                 40 
                 420 
                 360- 
                 420  
                 470 
                 0.16 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                   
                   
                   
                   
                   
                   
                 400 
               
               
                 106 
                 bd 
                 750 
                 90 
                 150 
                 380 
                 — 
                 — 
                 450 
                 0.10 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 107 
                 be 
                 780 
                 150 
                 3 
                 370 
                 350- 
                 300  
                 440 
                 0.12 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                   
                   
                   
                   
                   
                   
                 380 
               
               
                 108 
                 bf 
                 800 
                 90 
                 20 
                 480 
                 — 
                 — 
                 450 
                 0.15 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 109 
                 bg 
                 750 
                 200 
                 20 
                 410 
                 — 
                 — 
                 450 
                 0.15 
                 500 
                 30 
                 10 
                 180 
                 GA 
               
               
                 110 
                 bh 
                 850 
                 85 
                 7 
                 440 
                 400- 
                 40 
                 450 
                 0.20 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                   
                   
                   
                   
                   
                   
                 470 
               
               
                 111 
                 bi 
                 750 
                 150 
                 10 
                 360 
                 360- 
                 200  
                 450 
                 0.11 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                   
                   
                   
                   
                   
                   
                 440 
               
               
                 112 
                 bj 
                 800 
                 90 
                 20 
                 480 
                 400- 
                 100  
                 450 
                 0.15 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                   
                   
                   
                   
                   
                   
                 500 
               
               
                 113 
                 bk 
                 750 
                 110 
                 5 
                 440 
                 — 
                 — 
                 450 
                 0.20 
                 500 
                 30 
                 10 
                 180 
                 GA 
               
               
                 114 
                 bl 
                 700 
                 120 
                 10 
                 400 
                 360- 
                 60 
                 450 
                 0.18 
                 550 
                 10 
                 10 
                 180 
                 GA 
               
               
                   
                   
                   
                   
                   
                   
                 440 
               
               
                 115 
                 bm 
                 800 
                 200 
                 15 
                 430 
                 — 
                 — 
                 460 
                 0.20 
                 — 
                 — 
                 10 
                 200 
                 GI 
               
               
                 116 
                 bn 
                 830 
                 90 
                 20 
                 410 
                 400- 
                 30 
                 450 
                 0.15 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                   
                   
                   
                   
                   
                   
                 470 
               
               
                 117 
                 bo 
                 800 
                 120 
                 6 
                 420 
                 — 
                 — 
                 460 
                 0.14 
                 520 
                 15 
                 10 
                 180 
                 GA 
               
               
                 118 
                 bp 
                 750 
                 110 
                 10 
                 370 
                 — 
                 — 
                 450 
                 0.10 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 119 
                 bq 
                 820 
                 90 
                 20 
                 480 
                 430- 
                 30 
                 450 
                 0.09 
                 580 
                 30 
                 10 
                 180 
                 GA 
               
               
                   
                   
                   
                   
                   
                   
                 500 
               
               
                 120 
                 br 
                 750 
                 90 
                 20 
                 410 
                 — 
                 — 
                 450 
                 0.16 
                 500 
                 20 
                 10 
                 180 
                 GA 
               
               
                 121 
                 bs 
                 870 
                 150 
                 9 
                 440 
                 370- 
                 300  
                 450 
                 0.13 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                   
                   
                   
                   
                   
                   
                 440 
               
               
                 122 
                 bt 
                 750 
                 70 
                 20 
                 420 
                 — 
                 — 
                 450 
                 0.18 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 123 
                 bu 
                 830 
                 90 
                 10 
                 480 
                 400- 
                 30 
                 450 
                 0.17 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                   
                   
                   
                   
                   
                   
                 490 
               
               
                 124 
                 bv 
                 750 
                 200 
                 20 
                 490 
                 400- 
                 80 
                 450 
                 0.09 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                   
                   
                   
                   
                   
                   
                 470 
               
               
                 125 
                 bw 
                 800 
                 120 
                 5 
                 400 
                 — 
                 — 
                 440 
                 0.14 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 126 
                 bx 
                 750 
                 110 
                 10 
                 400 
                 — 
                 — 
                 440 
                 0.14 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                 127 
                 by 
                 800 
                 120 
                 5 
                 400 
                 400- 
                 80 
                 440 
                 0.14 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                   
                   
                   
                   
                   
                   
                 470 
               
               
                 128 
                 bz 
                 800 
                 70 
                 20 
                 440 
                 — 
                 — 
                 440 
                 0.14 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                   
               
               
                 Note)  
               
               
                 In the table, mark_indicates that the value is outside the scope of the present invention; the heating rate after coating was constant and 10° C./sec; and  
               
               
                 GA represents a hot-dip galvannealed steel sheet, and  
               
               
                 GI represents a hot-dip galvanized steel sheet.  
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE B16 
               
             
            
               
                   
               
               
                 (continuation from Table B15) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                   
                   
                 Cool- 
                 Cooling 
                 Holding 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                   
                   
                 Anneal- 
                 Anneal- 
                 ing 
                 termi- 
                 temp. 
               
               
                   
                   
                 ing 
                 ing 
                 rate, 
                 nation 
                 before 
                 Holding 
                 Coating 
                 Al content 
                 Alloying 
                 Alloying 
                 Cooling 
                 Cooling 
               
               
                 Sam- 
                   
                 temp., 
                 time, 
                 ° C./ 
                 temp., 
                 coating, 
                 time, 
                 temp., 
                 of zinc 
                 temp., 
                 time, 
                 rate, 
                 temp., 
                 Re- 
               
               
                 ple 
                 Steel 
                 ° C. 
                 sec 
                 sec 
                 ° C. 
                 ° C. 
                 sec 
                 ° C. 
                 bath, % 
                 ° C. 
                 sec 
                 ° C./sec 
                 ° C. 
                 marks 
               
               
                   
               
               
                 129 
                 ba 
                 
                   600 
                 
                 90 
                 20 
                 360 
                 — 
                 — 
                 470 
                 0.08 
                 500 
                 30 
                 10 
                 180 
                 GA 
               
               
                 130 
                 ba 
                 
                   950 
                 
                 90 
                 80 
                 480 
                 400- 
                 60 
                 450 
                 0.11 
                 480 
                 50 
                 10 
                 180 
                 GA 
               
               
                   
                   
                   
                   
                   
                   
                 500 
               
               
                 131 
                 ba 
                 750 
                 
                    5 
                 
                 20 
                 440 
                 430- 
                 20 
                 450 
                 0.20 
                 500 
                 30 
                 10 
                 180 
                 GA 
               
               
                   
                   
                   
                   
                   
                   
                 500 
               
               
                 132 
                 ba 
                 800 
                 
                   400  
                 
                 20 
                 410 
                 — 
                 — 
                 480 
                 0.17 
                 500 
                 40 
                 20 
                 220 
                 GA 
               
               
                 133 
                 ba 
                 750 
                 90 
                 
                    1 
                 
                 370 
                 430- 
                 30 
                 450 
                 0.13 
                 510 
                 30 
                 10 
                 180 
                 GA 
               
               
                   
                   
                   
                   
                   
                   
                 500 
               
               
                 134 
                 ba 
                 800 
                 110  
                 10 
                 
                   300 
                 
                 370- 
                 300 
                 450 
                 0.09 
                 480 
                 50 
                 10 
                 180 
                 GA 
               
               
                   
                   
                   
                   
                   
                   
                 440 
               
               
                 135 
                 ba 
                 770 
                 90 
                 70 
                 
                   520 
                 
                 370- 
                 300 
                 450 
                 0.14 
                 500 
                 30 
                 10 
                 180 
                 GA 
               
               
                   
                   
                   
                   
                   
                   
                 440 
               
               
                 136 
                 ba 
                 830 
                 150  
                 10 
                 420 
                 400- 
                 
                   650 
                 
                 480 
                 0.18 
                 500 
                 30 
                 10 
                 180 
                 GA 
               
               
                   
                   
                   
                   
                   
                   
                 490 
               
               
                 137 
                 ba 
                 800 
                 70 
                 20 
                 410 
                 400- 
                 80 
                 430 
                 0.11 
                 
                   430 
                 
                 40 
                 15 
                 180 
                 GA 
               
               
                   
                   
                   
                   
                   
                   
                 470 
               
               
                 138 
                 ba 
                 750 
                 90 
                 25 
                 440 
                 370- 
                 140 
                 480 
                 0.16 
                 
                   620 
                 
                 20 
                 10 
                 100 
                 GA 
               
               
                   
                   
                   
                   
                   
                   
                 440 
               
               
                 139 
                 ba 
                 850 
                 60 
                 20 
                 420 
                 — 
                 — 
                 450 
                 0.20 
                 500 
                 
                    3 
                 
                 8 
                 180 
                 GA 
               
               
                 140 
                 ba 
                 750 
                 90 
                 80 
                 480 
                 — 
                 — 
                 450 
                 0.12 
                 500 
                 
                   130 
                 
                 10 
                 180 
                 GA 
               
               
                 141 
                 ba 
                 820 
                 70 
                 50 
                 490 
                 400- 
                 250 
                 440 
                 0.10 
                 500 
                 25 
                 
                    3 
                 
                 180 
                 GA 
               
               
                   
                   
                   
                   
                   
                   
                 470 
               
               
                 142 
                 ba 
                 750 
                 100  
                 20 
                 360 
                 — 
                 — 
                 450 
                 0.08 
                 500 
                 30 
                 10 
                 
                   300 
                 
                 GA 
               
               
                 143 
                 ba 
                 830 
                 90 
                 20 
                 480 
                 400- 
                 60 
                 450 
                 
                   0.82 
                 
                 500 
                 25 
                 10 
                 180 
                 GA 
               
               
                   
                   
                   
                   
                   
                   
                 500 
               
               
                 144 
                 ba 
                 
                   600 
                 
                 90 
                 20 
                 360 
                 — 
                 — 
                 470 
                 0.08 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                 145 
                 ba 
                 
                   950 
                 
                 90 
                 80 
                 480 
                 400- 
                 60 
                 450 
                 0.11 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                   
                   
                   
                   
                   
                   
                 500 
               
               
                 146 
                 ba 
                 750 
                 
                    5 
                 
                 20 
                 440 
                 430- 
                 20 
                 450 
                 0.20 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                   
                   
                   
                   
                   
                   
                 500 
               
               
                 147 
                 ba 
                 800 
                 
                   420  
                 
                 20 
                 410 
                 — 
                 — 
                 480 
                 0.17 
                 — 
                 — 
                 20 
                 220 
                 GI 
               
               
                 148 
                 ba 
                 750 
                 90 
                 
                    1 
                 
                 370 
                 430- 
                 30 
                 450 
                 0.13 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                   
                   
                   
                   
                   
                   
                 500 
               
               
                 149 
                 ba 
                 800 
                 110  
                 10 
                 
                   300 
                 
                 370- 
                 300 
                 450 
                 0.09 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                   
                   
                   
                   
                   
                   
                 440 
               
               
                 150 
                 ba 
                 830 
                 150  
                 10 
                 420 
                 400- 
                 
                   720 
                 
                 480 
                 0.18 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                   
                   
                   
                   
                   
                   
                 490 
               
               
                 151 
                 ba 
                 820 
                 70 
                 50 
                 490 
                 400- 
                 250 
                 440 
                 0.10 
                 — 
                 — 
                 
                    3 
                 
                 180 
                 GI 
               
               
                   
                   
                   
                   
                   
                   
                 470 
               
               
                 152 
                 ba 
                 750 
                 100 
                 20 
                 360 
                 — 
                 — 
                 450 
                 0.08 
                 — 
                 — 
                 10 
                 
                   300 
                 
                 GI 
               
               
                 153 
                 ba 
                 830 
                 90 
                 20 
                 480 
                 400- 
                 60 
                 450 
                 
                   0.82 
                 
                 — 
                 — 
                 10 
                 180 
                 GI 
               
               
                   
                   
                   
                   
                   
                   
                 500 
               
               
                   
               
               
                 Note)  
               
               
                 In the table, mark_indicates that the value is outside the scope of the present invention; the heating rate after coating was constant and 10° C./sec; and  
               
               
                 GA represents a hot-dip galvannealed steel sheet, and  
               
               
                 GI represents a hot-dip galvanized steel sheet.  
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE B17 
               
               
                   
               
               
                   
                   
                   
                 Retained 
                 Zn content of 
                 Fe content of 
                 Al content of 
                 Appearance 
                 Plating 
                   
                   
               
               
                 Sample 
                 TS, MPa 
                 El, % 
                 γ, % 
                 coating, % 
                 coating, % 
                 coating, % 
                 of coating 
                 adhesion 
                 Weldability 
                 Remarks 
               
               
                   
               
             
            
               
                 103 
                 630 
                 36 
                 8 
                 89 
                 10 
                 0.22 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Ex. of inv. 
               
               
                 104 
                 660 
                 34 
                 10  
                 89 
                 10 
                 0.18 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Ex. of inv. 
               
               
                 105 
                 720 
                 34 
                 13  
                 98 
                 — 
                 0.28 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Ex. of inv. 
               
               
                 106 
                 640 
                 31 
                 11  
                 88 
                 11 
                 0.16 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Ex. of inv. 
               
               
                 107 
                 780 
                 30 
                 3 
                 94 
                 — 
                 0.18 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Ex. of inv. 
               
               
                 108 
                 580 
                 36 
                 9 
                 89 
                 10 
                 0.82 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Ex. of inv. 
               
               
                 109 
                 840 
                 31 
                 15  
                 89 
                 10 
                 0.13 
                 ◯ 
                 ◯ 
                 ⊚ 
                 Ex. of inv. 
               
               
                 110 
                 640 
                 36 
                 8 
                 87 
                 12 
                 0.16 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Ex. of inv. 
               
               
                 111 
                 630 
                 35 
                 10  
                 99 
                 — 
                 0.25 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Ex. of inv. 
               
               
                 112 
                 620 
                 36 
                 7 
                 89 
                 10 
                 0.17 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Ex. of inv. 
               
               
                 113 
                 810 
                 31 
                 18  
                 89 
                 10 
                 0.23 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Ex. of inv. 
               
               
                 114 
                 610 
                 35 
                 4 
                 88 
                 11 
                 0.32 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Ex. of inv. 
               
               
                 115 
                 830 
                 32 
                 15  
                 99 
                 — 
                 0.18 
                 ◯ 
                 ◯ 
                 ◯ 
                 Ex. of inv. 
               
               
                 116 
                 540 
                 28 
                 
                   1 
                 
                 93 
                 — 
                 0.20 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 117 
                 810 
                 25 
                   22   
                 89 
                 10 
                 0.21 
                 ◯ 
                 ⊚ 
                 
                   X 
                 
                 Comp. Ex. 
               
               
                 118 
                 570 
                 28 
                 
                   1 
                 
                 89 
                 10 
                 0.16 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 119 
                 710 
                 30 
                 8 
                 
                   93 
                 
                   6   
                 0.32 
                 
                   X 
                 
                 
                   X 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 120 
                 550 
                 29 
                 
                   1 
                 
                 89 
                 10 
                 0.13 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 121 
                 620 
                 33 
                 6 
                 89 
                 10 
                 0.19 
                 
                   X 
                 
                 
                   X 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 122 
                 560 
                 20 
                 
                   1 
                 
                 90 
                  9 
                 0.23 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 123 
                 700 
                 34 
                 7 
                 89 
                 10 
                 0.28 
                 
                   Δ 
                 
                 
                   Δ 
                 
                 X 
                 Comp. Ex. 
               
               
                 124 
                 640 
                 33 
                 6 
                 99 
                 — 
                 0.32 
                 
                   X 
                 
                 
                   X 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 125 
                 660 
                 33 
                 5 
                 94 
                 — 
                 0.28 
                 
                   X 
                 
                 
                   X 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 126 
                 650 
                 33 
                 4 
                 90 
                  9 
                 0.32 
                 
                   X 
                 
                 
                   X 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 127 
                 665 
                 33 
                 5 
                 96 
                 — 
                 0.29 
                 
                   X 
                 
                 
                   X 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 128 
                 670 
                 32 
                 5 
                 88 
                 11 
                 0.33 
                 
                   X 
                 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                   
               
               
                 Note)  
               
               
                 In the table, mark_indicates that the value is outside the scope of the present invention.  
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE B18 
               
             
            
               
                   
               
               
                 (continuation from Table B17) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                   
                 Retained 
                 Zn content of 
                 Fe content of 
                 Al content of 
                 Appearance of 
                 Plating 
                   
                   
               
               
                 Sample 
                 TS, MPa 
                 El, % 
                 γ, % 
                 coating, % 
                 coating, % 
                 coating, % 
                 coating 
                 adhesion 
                 Weldability 
                 Remarks 
               
               
                   
               
               
                 129 
                 550 
                 24 
                 
                   1 
                 
                 89 
                 10 
                 0.41 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex 
               
               
                 130 
                 600 
                 26 
                 
                   1 
                 
                 89 
                 10 
                 0.21 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 131 
                 620 
                 20 
                 
                   1 
                 
                 90 
                  9 
                 0.23 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 132 
                 580 
                 22 
                 1 
                 89 
                 10 
                 0.63 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 133 
                 550 
                 26 
                 
                   1 
                 
                 89 
                 10 
                 0.27 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 134 
                 650 
                 24 
                 
                   1 
                 
                 88 
                 11 
                 0.34 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 135 
                 610 
                 34 
                 6 
                 84 
                 
                   15 
                 
                 0.28 
                 ◯ 
                 
                   Δ 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 136 
                 600 
                 29 
                 
                   1 
                 
                 89 
                 10 
                 0.41 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 137 
                 610 
                 35 
                 5 
                 
                   94 
                 
                   5   
                 0.23 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 138 
                 570 
                 29 
                 1 
                 84 
                 
                   15 
                 
                 0.23 
                 ◯ 
                 
                   Δ 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 139 
                 630 
                 35 
                 6 
                 
                   92 
                 
                   7   
                 0.23 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 140 
                 580 
                 28 
                 
                   1 
                 
                 84 
                 
                   15 
                 
                 0.32 
                 ◯ 
                 
                   Δ 
                 
                 ◯ 
                 Comp. Ex. 
               
               
                 141 
                 580 
                 26 
                 
                   1 
                 
                 89 
                 10 
                 0.23 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 142 
                 560 
                 23 
                 
                   1 
                 
                 89 
                 10 
                 0.32 
                 ◯ 
                 ⊚ 
                 ⊚ 
                 Comp. Ex. 
               
               
                 143 
                 630 
                 35 
                 7 
                 88 
                 10 
                 
                   1.23 
                 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 144 
                 550 
                 24 
                 
                   1 
                 
                 89 
                 10 
                 0.41 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 145 
                 600 
                 26 
                 
                   1 
                 
                 89 
                 10 
                 0.21 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 146 
                 620 
                 20 
                 
                   1 
                 
                 90 
                  9 
                 0.23 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 147 
                 580 
                 22 
                 1 
                 89 
                 10 
                 0.63 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 148 
                 550 
                 26 
                 
                   1 
                 
                 89 
                 10 
                 0.27 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 149 
                 650 
                 24 
                 
                   1 
                 
                 88 
                 11 
                 0.34 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 150 
                 600 
                 29 
                 
                   1 
                 
                 89 
                 10 
                 0.41 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 151 
                 580 
                 26 
                 
                   1 
                 
                 89 
                 10 
                 0.23 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 152 
                 560 
                 23 
                 
                   1 
                 
                 89 
                 10 
                 0.32 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                 153 
                 630 
                 35 
                 7 
                 88 
                 10 
                 
                   1.23 
                 
                 ◯ 
                 ⊚ 
                 ◯ 
                 Comp. Ex. 
               
               
                   
               
               
                 Note)  
               
               
                 In the table, mark_indicates that the value is outside the scope of the present invention.