Patent Publication Number: US-2015076395-A1

Title: Themrally conductive  thermoplastic for light emitting diode fixture assembly

Description:
This application is a divisional of U.S. patent application Ser. No. 13/547,437, filed on Jul. 12, 2012, which claims the benefit of United States Provisional Patent Application Ser. No. 61/547,456, filed on Oct. 14, 2011. The teachings of U.S. patent application Ser. No. 13/547,437 and U.S. Provisional Patent Application Ser. No. 61/547,456 are incorporated herein by reference in their entirety. 
    
    
     BACKGROUND OF THE INVENTION 
     Light-emitting diodes (LEDs) based on solid state lighting technology are likely to replace incandescent and fluorescent bulbs in housing and commercial markets. The modules, bulbs, and fixtures made out of the LEDs/solid state lighting have distinct advantages such as, they are brighter, require less energy, and extend the light&#39;s lifetime. Some of the electricity in an LED becomes heat rather than light and if the heat is not removed, the LEDs run at high temperatures, which not only lowers their efficiency, but also makes the LED less reliable and cost effective alternate to current lighting industry. In order to solve the difficult problem in this field, the LED industry has developed many different methods and solutions in addressing key problems such as heat dissipation, shape, luminance, product life and cost. The high power LED illumination still faces a lot of technological challenges at present with regards to improving its efficiency in heat transfer. 
     The current solution in thermal management involves materials acting as a heat sink made from aluminum, although copper may be used as well. New classes of materials including thermoplastic compounds that are used when heat dissipation requirements are lower than normal or have a complex shape would offer improvements by molding and extrusion which would offer better thermal transfer than copper with a lower weight than aluminum. The improved thermoplastic composition further offers the advantage of being able to be formed into complex two-dimensional parts and can also be easily mass produced. 
     The present invention relates to a heat dissipating thermoplastic compound composition acting as a both external and internal heat sink which can be easily customized for any given shape and size via regular melt processing techniques in a LED part design. Such a composition can solve the problems of light decay, heat dissipation, and shape adoption in next generation high brightness LEDs. 
     Another aspect of the current invention is that the thermally conducting composition can be formulated to provide a superior surface finish which provides superior thermal radiation of heat especially at higher temperatures. This is particularly useful in cases where heat is dissipated by radiation and the thermally conductive composition is acting as a reflector. Moreover, a perfectly fused contact area or good interface allows the use of a thinner layer of thermal compound, which will reduce the thermal resistance between the heat sink and LED source. 
     The prior art in thermally conductive thermoplastic compounds uses boron nitride as a conductive filler. Thermally conductive fillers do not only have to be limited to boron nitride. The prior art also teaches that there are a variety of other fillers available for compounding with thermoplastics that will impart thermal conductivity to a polymer compound. These materials include but are not limited to metals and their alloys, such as copper, aluminum, bronze, gold, silver, iron, lead, stainless steel, titanium, brass, nickel coated fibers, aluminum coated fibers, and metal oxides, such as zinc oxide, aluminum oxide, beryllium oxide, magnesium oxide, iron oxide, and aluminum nitride. The use of ceramics and minerals as thermally conductive fillers is also described in the prior art. These thermally conductive materials include granite, silicon carbide, zirconium silicate, limestone, marble, quartz, and sandstone. Thermally conductive fillers that are known in the prior art also include carbon rich materials such as carbon fibers, carbon nanotubes, carbon nanofibers, diamond, natural and synthetic unexpanded graphite, natural and synthetic expanded graphite, carbon black, diamond powders (synthetic and natural), and graphene. 
     A limitation of some of the fillers known in the prior art, including boron nitrides, is that thermal conductivity is only realized uni-directionally and therefore through-plane thermal conductivity is delivered at a level which is less than that needed in some important commercial applications. However, prior art teaches that the thermal conductivity of thermoplastic compositions can be increased by the addition of another filler having a low aspect ratio. There is accordingly a need for a composition which can increase through plane thermal conductivity over the levels provided by boron nitride and other conventional thermally conductive fillers. 
     In addition to having thermal conductivity in some applications it is also critical for thermoplastic compound formulations to impart additional performance characteristics including electrical conductivity, electrical insulativity, processability and flame retardancy. In many cases, enhanced electrical conductivity facilitates electroplating, electroless plating, and primer free electrostatic painting of thermally conductive polymer parts. These plating/painting processes are typically performed by moving ions in an electrolytic solution by an electric field over a given conductive substrate in order to coat said substrate with a thin layer of the material, typically a metal. Thermoplastic material that can be electroplated yields also generally benefits by providing improved wear and mar resistance, lubricity, aesthetics, and corrosion resistance. 
     The improvement of electrical insulation characteristics also normally contributes to a higher break down voltage of thermally conductive polymer parts. This property is very desirable in numerous electrical and electronic applications. For example in LEDs, an electrically insulative and thermally conductive polymer compound can be used in place of electrically conductive aluminum for making housings, back plates, connectors and sleeves with better results. In these parts, a higher breakdown voltage is typically desired. 
     Flame retardant chemicals, compounds, and fillers can also be introduced into thermoplastic compounds to improve their flammability ratings. Introducing flame retardants into the thermally conductive thermoplastic compounds helps impart ignition resistance and inhibits or resists the spread of fire. This added property allows for the thermally conductive thermoplastic compound to be utilized safely where a potential for fire exists, meeting the requirements of Underwriter Labs UL-94 and the International Electrotechnical Commission (IEC) IEC 60707, IEC 60695-11-10, and IEC 60695-11-20. 
     Processability is a very important criterion in manufacturing most articles via conventional molding and extrusion techniques. Good processability is a beneficial characteristic for thermoplastics that are used in almost all applications ranging from conventional injection molding to complex techniques used in specialty applications. However, excellent processability can be critical in many complex molding applications that require a very fine balance of performance properties along with low temperature melting point and easy flow. 
     SUMMARY OF THE INVENTION 
     This invention relates to thermally conductive thermoplastic compounds. It is important for all thermoplastics to by easily processable via melt techniques, such as injection molding, extrusion, thermoforming and in some case compression molding and fiber spinning/extrusion. It is also, of course, important for the polymers used in over molding procedures to exhibit good processability. 
     In cases where fillers are added to thermoplastic elastomers processing can be more challenging. Introducing flow modifiers and the appropriate combination of additives helps us solve this problem and make the final composition easy to overmold at temperatures around 200° C. (which is required to protect the electronics on a circuit board on which the compound will be overmolded). Along with this comes surface properties and finish. 
     This invention discloses a thermoplastic compound that exhibits through plane thermal conductivity. The formulation of this invention comprises at least a primary thermally conductive filler and possibly a secondary and tertiary thermally conductive filler. Also, disclosed is the ability to add electrically insulative or electrically conductive properties to the disclosed thermoplastic thermally conductive compound via the use of a carbon based substances. It is further disclosed that flame retardant fillers or inherently flame retardant polymers can also be incorporated into the disclosed compound to impart flame retardant properties into the thermally conductive thermoplastic compound. 
     The present invention more specifically discloses a light emitting diode fixture having a thermally conductive thermoplastic housing therein which is comprised of (1) at least one light emitting diode, (2) a lens covering a portion of the light emitting diode, (3) a back plate to which the light emitting diode is affixed, (4) the thermally conductive thermoplastic housing for the light emitting diode and the base plate, wherein the housing is comprised of a thermally conductive thermoplastic composition which is comprised of at least one thermoplastic polymer, and at least one thermally conductive filler, and (5) electrical connectors which are in electrical communication with the light emitting diode and an electrical supply source. 
     The present invention further discloses a light emitting diode fixture having a thermally conductive thermoplastic power supply cup therein which is comprised of (1) at least one light emitting diode, (2) a lens covering a portion of the light emitting diode, (3) a back plate to which the light emitting diode is affixed, (4) a housing for the light emitting diode and the base plate, (5) electrical connectors which are in electrical communication with the light emitting diode and an electrical supply source, and (6) the electrical power supply cup, wherein the electrical power supply cup is comprised of a thermally conductive thermoplastic composition which is comprised of at least one thermoplastic polymer, and a thermally conductive filler. 
     A light emitting diode fixture having a thermally conductive thermoplastic back plate therein which is comprised of (1) at least one light emitting diode, (2) a lens covering a portion of the light emitting diode, (3) at least one heat spreader wherein the heat spreader is comprised of a thermally conductive thermoplastic composition which is comprised of at least one thermoplastic polymer, and at least one thermally conductive filler, (4) a back plate which is affixed to the heat spreader, wherein the back plate is comprised of an electrically conductive metal, (5) a housing for the light emitting diode and the back plate, and (6) electrical connectors which are in electrical communication with the back plate and an electrical supply source. 
     The present invention further reveals discloses a light emitting diode fixture having an overmolded housing comprising (1) a back plate, (2) a circuit board which is affixed to the back plate, (3) a light emitting diode which is affixed to the back plate and which is in electrical communication with the circuit board, (4) electrical connectors which are in electrical communication with the circuit board, (5) a lens which covers at least a portion of the light emitting diode, and (6) a housing which is overmolded onto the back plate, wherein said housing is comprised of a thermoplastic composition which includes a thermoplastic polymer having a melting point of less than 220° C., and at least one thermally conductive filler 
     The subject invention also discloses a thermally conductive polymeric composition having flame retardancy which is comprised of (1) at least one thermoplastic polymer, (2) at least one thermally conductive filler, (3) at least one flame retardant system, (4) at least one impact modifier, and (5) a surface active agent. 
     Further the subject invention also discloses a thermally conductive polymeric composition having flame retardancy which is comprised of (1) at least one inherently flame retardant thermoplastic polymer, (2) at least one thermally conductive filler, (3) at least one impact modifier, and (4) a surface active agent. 
    
    
     
       BRIEF DESCRIPTION OF DRAWINGS 
         FIG. 1  is a perspective view of a light emitting diode fixture for utilization as a replacement for conventional light bulbs of virtually all types into which the thermally conductive thermoplastic of this invention can be incorporated. Such light emitting diode fixtures are commonly utilized as spotlight bulbs (MR16), candle lights (candelabra bulbs), A series bulbs, and PAR series bulbs (such as PAR 20 of 7 watts, PAR 30 of 13 to 15 watts, and beyond). 
         FIG. 1   a  is schematic exploded diagram of a light emitting diode fixture into which the thermally conductive thermoplastic of this invention can be incorporated. 
         FIG. 2  is a schematic drawing of a second type of light emitting diode fixture which can include component parts which are made of the thermally conductive thermoplastic of this invention. This type of light emitting diode fixture is typically used in office lighting, parking lot lights, street lights and custom design fixtures. 
         FIG. 3  is a schematic diagram of a device that can be used as a thermal conductivity meter. 
     
    
    
     REFERENCE NUMERALS USED IN FIGURES 
     The reference numerals used in the drawings to identify various parts or elements of the light emitting diode fixtures of this invention and the thermal conductivity meter used in the practice of this invention are as follows:
           1 . light emitting diode fixture     2 . light emitting diode     3 . lens     4 . back plate     5 . heat sink     6 . electrical connector     7 . electrical power supply cup     8 . connecting part     9 . connection part     10 . driver     11 . heat spreader     12 . heat spreader     13 . screws     14 . cover plate lens     15 . fixture body     16 . thermal conductivity meter     17 . aluminum block     18 . first thermocouple     19 . test sample     20 . heat source     21 . support base     22 . second thermocouple     23 . first digital temperature readout meter     24 . wires     25 . second digital temperature readout meter       

     DETAILED DESCRIPTION OF THE INVENTION 
     A light emitting diode fixture  1  of the present invention is depicted in  FIG. 1 . Such a light emitting diode fixture includes at least one light emitting diode  2  and typically includes a plurality of light emitting diodes. The light emitting diode fixture also includes a lens  3  covering at least a portion of the light emitting diode or diodes  2 . A back plate  4  supports the LED assembly to a heat sink  5  (body of the fixture or housing) which dissipates heat generated by the light emitting diode(s) from the fixture to its surroundings. The heat sink  5  also typically provides a major component of the body of the fixture. The heat sink  5  typically has a lens  3  attached to one side thereof with an electrical connector  6  which may be in a socket assembly at the other end. The electrical connector  6  is adapted to connect to a power source such as a household or AC power circuit or to a battery supply. The socket assembly typically includes the electrical connector  6 , electrical power supply cup  7  (also known as a sleeve), and optionally other connecting parts  8  and  9 , and an electrical driver  10  which is typically a circuit board that gives power to the light emitting diodes. The electrical driver  10  typically converts the current supply from alternating current to direct current and preferably provides constant current supply to each light emitting diode in the fixture, and optionally the driver controls current to the light emitting diodes to provide control over lumen output. Optionally, one or more heat spreaders  11  and  12  are used to facilitate rapid dissipation of heat from the light emitting diode to the heat sink, back plate and other components of the fixture assembly. Such heat spreaders help to protect the light emitting diodes from thermal shock and thermal degradation which can result in lower lumens output over time. Optionally, the light emitting diodes can be affixed to the optional heat spreaders  11  and  12  and to the back plate  4  and to connectors such as screws  13 . 
       FIG. 2  illustrates another light emitting diode fixture  1  which includes a plurality of light emitting diodes  2 , a cover plate lens  14 , a back plate  4 , a heat sink  5 , and a fixture body  15 . In this type of light emitting diode fixture, the electrical driver can be located at a position in the fixture body or in a remote external position. For instance, in street and parking lot light applications, it is frequently convention to position the electrical driver on a light pole or in some other position external to the light emitting diode fixture itself. Utilizing external positioning of the electrical driver can prove to be beneficial in some applications because it removes the driver from proximity to the LED heat source and also can provide added flexibility in current control to provide for increasing or decreasing the lumens provided (allows for dimming). It also facilitates replacement of component parts without the need for replacing the entire light emitting diode fixture. For instance, individual LEDs can be replaced without replacing the driver and the driver can be replaced without the need to replace the LEDs. It should be understood that the fixture body  15  and other component parts of the fixture can be designed to be of virtually any desired geometric shape, for instance, it can be rectangular (as shown in  FIG. 2 ), round, square, hexagonal, octagonal, etc. The light emitting diode fixture will typically also include heat spreaders. 
     The compositions claimed in this specification comprise of at least one primary thermally conductive filler and possibly a secondary and tertiary thermally conductive filler. This composition when added to a thermoplastic, as shown in the examples, imparts thermal conductive properties to the thermoplastic, in particular increases in the through plane and in-plane thermal conductivity. 
     The thermally conductive filler system that may be utilized in the claimed composition include but are not limited to metals and their alloys, such as copper, aluminum, bronze, gold, silver, iron, lead, stainless steel, titanium, brass, aluminum nitride, aluminum coated fibers, copper coated fibers, and metal oxides, such as zinc oxide, aluminum oxide, beryllium oxide, magnesium oxide, and ceramics and minerals including granite, boron nitride, silicon carbide, zirconium silicate, limestone, marble, quartz, sandstone. Also included in thermally conductive fillers are carbon rich materials such as carbon fibers, carbon nanotubes, carbon nanofibers, diamond, natural and synthetic unexpanded graphite, natural and synthetic expanded graphite, and graphene. 
     Boron nitrides useful in this composition are generally found in particle form or agglomerate form. When in particle form, the boron nitride appears as platelets having a mean particle size of 35 microns, 12-13 microns and a surface area of 0.1 to 1.0 square meters/gram. These boron nitrides are available from Momentive Performance Materials, Strongsville, Ohio USA, previously known as Advanced Ceramics, Cleveland, Ohio, USA as POLARTHERM® 110 and 220 respectively. In practicing the subject invention it is typically advantageous for the thermally conductive composition utilized in LED fixtures to be void of boron nitrides. 
     Boron nitride is also available in highly crystalline powdered form. This boron nitride form is typically a very high purity mix of platelets and small to medium agglomerates having a mean particle size of 20-60 and 15-25 microns with a high surface area of 3-5 square meters/gram. These boron nitrides are available from Momentive Performance Materials, Strongsville, Ohio, USA, previously known as Advanced Ceramics, Cleveland Ohio, USA as CoolFlow CF400 and CoolFlow CF300 respectively. 
     Boron nitride is also available in agglomerates approximating a sphere, or spherical. These agglomerates have a mean particle size which is within the range of 55 to 65 microns and a nominal surface area of 5.5 square meters/gm. These boron nitride agglomerates are available as POLARTHERM® XLR 60. 
     Aluminum nitride is believed to be a good substitute for boron nitride with mixtures of the boron and aluminum nitride contemplated as well. Effective amounts of boron nitride, aluminum nitride or mixture of boron nitride and aluminum nitride when used in combination with a thermoplastic are in the range of 25 to 55 percent by weight of the total composition, with 30 to 50 percent being more effective and 30 to 45 percent being even more effective and 33 to 38 percent being the most effective. 
     Aluminum oxide has been found to be useful as a thermally conductive filler for thermoplastics, specifically white aluminum oxide. The white aluminum oxide used is a pure, clear white aluminum oxide with low soda and silica content. An ideal average particle size is between 50-100 microns, more specifically 80 microns. The particles of white aluminum oxide tend to be blocky with sharp edges with an alpha alumina, in the hexagonal crystal system structure. This grade of aluminum oxide is available from Washington Mills, North Grafton, Mass., USA as Duralum Special White. 
     Zinc oxides are believed to also impart high through plane thermal conductivity to thermoplastic compounds. The zinc oxide used is very high purity. The zinc oxide has a particle size of 0.25-0.33 microns, more specifically 0.31 microns and an average surface area of 3.5 square meters/gram. The bulk density of zinc oxide is approximately 50 pounds/cubic foot. This grade of zinc oxide is available from Zochem Inc., Brampton, Ontario, Canada as Zoco 103. 
     Copper powders are also available as thermally conductive fillers. A purity level of at least 99% is required. A mean particle size should be approximately 30-80 microns, more specifically 40-60 microns. Copper powders are commercially available from a number of suppliers. 
     The graphite and carbon fibers typically used preferably have an average length which is within the range of about 75 microns to about 250 microns. Such fibers will frequently have a length of about 100 microns (which is within the range of about 75 microns to about 125 microns) and preferably have a length of about 150 micron (which is within the range of 125 microns to 175 microns). Alternative the fibers can be potassium and/or ceramic whiskers. Carbon fibers are derived from primarily two sources: polyacrylonitrile (PAN) and pitch (petroleum based). The PAN based fiber has approximately 55% carbon content and is available from a multitude of sources. The thermal conductivity of PAN based fibers is approximately 200 to 350 W/mK (Watt/meter-Kelvin). Pitch based fibers have approximately 85% carbon content and approach the properties of graphite and are therefore called graphite fibers due to their high carbon content. To be a graphite fiber, the fiber should have more than 80% carbon content. The thermal conductivity of graphite fibers (pitch based fibers) is approximately 900 W/mK. 
     The expanded graphite can be manufactured by a thermal expansion process. In this process, certain compounds are chemically inserted between the graphite planes and exposed to heat. The chemicals inside the graphite decompose, forcing the graphite layers apart. The expanded graphite has a worm like appearance with an apparent density of about 0.003 g/cc as compared to the theoretical density of 2.6 g/cc for unexpanded graphite. Additionally, expanded graphite can be compressed from 0.003 g/cc to densities up to 1.75 g/cc and greater. U.S. Pat. No. 3,404,061 describes how to make expanded graphite in a continuous process. The teachings of U.S. Pat. No. 3,404,061 are incorporated herein by reference for the purpose of teaching a satisfactory method for producing expanded graphite which can be utilized in accordance with this invention. 
     The aspect ratio of the expanded graphite is believed to lie in the range of 200 to 300. This is in contrast to the carbon fibers which have a much smaller aspect ratio which is typically within the range of 5 to 50 and which is frequently approximately 10. 
     The carbon containing substance is effective when present at a level of 5 to 35% by weight of the total composition, more effective at 10 to 30 weight percent of the total composition, with even better results believed obtained at 14 to 26 weight percent and 16 to 24 weight percent of the total composition. 
     The thermally conductive composition can be mixed with virtually any thermoplastic or composite to make the resultant composition thermally conductive. This composition finds utility when added to a single thermoplastic polymer or blend/alloy. Typically this thermoplastic polymer system will be chosen from the list of polymer systems such as: polyethylene, polypropylene, polyether block polyamides, PEI, polyester block co-polymers, styrenic block co-polymers, styrene based co and ter polymers (such as ABS, HIPS, ASA, SIBS, SEBS, SBS, etc,), polyesters (such as PET, PTT, PETG, PBT, CBT), polycarbonates, polyetheretherketones, PAEK, PEK, polyphylene sulfide, polysulfones, liquid crystalline polymers, thermoplastic elastomers, polyamides, semi-aromatic polyamides (PPA), acrylate polymers (specifically ethylene methacrylate), thermoplastic urethanes and their blends/alloys thereof. Additionally the polymer systems may contain polymeric modifiers, stabilizers, and other additives. 
     The dicarboxylic acid which can be used in the hard polyesters that are useful in the practice of this invention are typically selected from the group consisting of terephthalic acid, isophthalic acid, naphthalenedicarboxylic acid, diphenyldicarboxylic acid or a mixture of 2 or more thereof. The diol used for the polyester is typically an alkylene glycol that contains 2-10 carbon atoms, 1,6-cyclohexanediol, 1,6-dimethanolcyclohexane or a mixture of two or more thereof. In general, it is preferred that a polyester having a more crystalline structure be used. These polyesters include poly (butylenes terephthalate) (PBT), poly (ethylene terephthalate) (PET), poly (trimethylene terephthalate) (PTT), poly (butylenes isophthalate) (PBI), poly (cyclohexylene-dimethylene terephthalate) (PCT), poly (ethylene naphthalate) (PEN), poly (trimethylene naphthalate) (PTN), and poly (butylenes naphthalate) (PBN). 
     The polyurethanes that are useful in the practice of this invention will typically consist of prepolymers and/or the thermoplastic polyurethanes (TPU) of the formula of —R 1 OCONHR 2 —NHCOO— as hard segments, where R 1  is an alkylene group containing 2-6 carbon atoms and R 2  is an aromatic group, and the soft segments having polyalkylene oxide, polyester, polycaprolactone or a copolymer of two or more thereof. The preference is MDI-based polyether, polyester, polycaprolactone, ether-ester and ester-polycaprolactone TPU. The copolyester is polyether-polyester multiblock copolymer, where polyester is aromatic dicarboxylic acid incorporating with alkylene glycols having 2-6 carbon atoms. The preferred copolyester is using polytetrahydrofuran as soft segments and poly (butylenes terephthalate) as hard segments. 
     Another optional agreement is CBT®100 low molecular weight thermoplastic resin from Cyclics Corporation of Schenectady, N.Y. This low molecular weight thermoplastic resin is a blend of polybutylene terephthalate oligomers which does not include a polymerization catalyst. It melts into a low viscosity liquid and is not believed to further polymerize into the polybutylene terephthalate polymer (PBT) of higher molecular weight. 
     To increase cold temperature impact characteristics it can be advantageous in one embodiment of this invention for the composition to contain a rubbery impact modifier composition component which could be one or more rubbery impact modifiers. The type of rubber impact modifier is a polymeric material which, at room temperature, is capable of recovering substantially in shape and size after removal of a force. However, the rubbery impact modifier should have a glass transition temperature of less than 0° C. Better performance is normally attained when the glass transition temperature (Tg) is less than −5° C., −10° C., or −15° C., with a Tg of less than −30° C. being even better. The Lotader® resins from Arkema, Corporation (France) are some representative examples of such rubbery impact modifiers that can be included in one embodiment of this invention. These particular impact modifiers are functionalized polyolefin ethylene-acrylate terpolymers, such as ethylene-acrylic esters-maleic anhydride (MAH) or glycidyl methacrylate (GMA). 
     The rubbery impact modifier composition which can optionally be used is preferably a functionalized rubbery impact modifier and can be an ethylene copolymer that functions as a compatibilizing agent or surfactant, in that it forms a covalent bond and/or physical interaction with at least one polyester component and compatibly blends with the polyester component. In most cases, to get the high level of compatibility and physical properties, such as low temperature impact strength, a covalent bond will form between the polyester component and the functionalized rubbery impact modifier. The functionalized rubbery impact modifier component of the thermoplastic resin composition will normally represent from 2.0 weight percent to 50 weight percent of the composition, with 10 to 45 weight percent more preferable and 15 to 40 percent most preferable. The functionalized rubbery impact modifier is preferably present in the composition at a level which is within the range of 10 weight percent to 40 weight percent. 
     The functionalized rubbery impact modifier will often be a compatibilizing ethylene copolymer of the formula E/X/Y, where E is about 55-75%, X is about 15-35%, and Y is about 2-15% by weight of the compatibilizing ethylene copolymer, and E is ethylene. X is an α,β-ethylenically unsaturated monomer derived from at least one of alkylacrylate, alkylmethacrylate, alkyl vinyl ether, carbon dioxide, sulfur dioxide, or mixtures thereof, where the alkyl groups contain 1-12 carbon atoms, such as vinyl acetate, methylacrylate, butylacrylate, and methyl vinyl ether. X can, for example, be a moiety derived from at least one of alkyl acrylate, alkyl methacrylate, alkyl vinyl ether, carbon monoxide, sulfur dioxide, or mixtures thereof. More specifically, X can, for example, contain up to about 35 weight percent of a moiety derived from at least one alkyl acrylate, alkyl methacrylate, or mixtures thereof where the alkyl groups contain 1-8 carbon atoms. 
     Y is an α,β-ethylenically unsaturated monomer containing a reactive group, such as epoxide, maleic anhydride, isocyanate, or oxazoline, for example. In one embodiment, Y is selected from the group consisting of glycidyl methacrylate and glycidyl acrylate, maleic anhydride, and isocyanato-ethylmethacrylate. 
     The functionalized rubbery polymer will typically contain repeat units that are derived from an acrylate monomer of the structural formula: 
     
       
         
         
             
             
         
       
     
     wherein R represents a hydrogen atom, an alkyl group containing from 1 to about 8 carbon atoms, or a moiety containing an epoxy group, and wherein R 1  represents a hydrogen atom or an alkyl group containing from 1 to about 8 carbon atoms. Some representative examples of monomers that can be used include methyl methacrylate, butyl acrylate, dimethylsiloxane. In many cases, R will represent an alkyl group containing from 1 to 4 carbon atoms. The moiety containing an epoxy group will typically be of the structural formula: 
     
       
         
         
             
             
         
       
     
     wherein n represents an integer from 1 to about 6. In most cases, n will represent 1. The functionalized rubbery polymer will generally also contain repeat units that are derived from a conjugated diolefin monomer, such as 1,3-butadiene or isoprene, a vinyl aromatic monomer, such as styrene or α-methyl styrene, a monoolefin monomer, such as ethylene or propylene, and/or a dialkylsiloxane monomer, such as dimethylsiloxane. 
     The functionalized rubbery polymer can optionally contain repeat units in its backbone which are derived from an anhydride group containing monomer, such as maleic anhydride. In another scenario, the functionalized rubbery polymer can contain anhydride moieties which are grafted onto the polymer in a post polymerization step. 
     In addition, reinforcing fibers and fillers may be incorporated into the thermoplastic elastomers according to the invention. The reinforcing fibers include those of glass, carbon, aromatic polyamide, and thermotropic liquid crystalline polymers. The fillers include talc, glass beads, calcium carbonate, carbon black, minerals, silicates and nano-fillers. Further, polyfluorocarbon compounds such as PTFE may be incorporated into the present elastomers, as well as pigments, thermal stabilizers, UV stabilizers, antioxidants, flame retardants and conductive materials (organic or/and inorganic). 
     Another class of rubbery impact modifiers that can be utilized in the practice of this invention are polyolefins which are grafted with maleic anhydride. One example of such an impact modifier is Polybond® 3200 polypropylene with 1% maleic anhydride from Crompton Corporation. 
     Various stabilizer packages are used in polymers for preventing oxidation, chain scission and uncontrolled reactions/recombinations and crosslinking reactions that are caused by photo-oxidation of polymers. Polymers are considered to get weathered or degraded due to the direct or indirect impact of heat and ultraviolet light. The effectiveness of the stabilizers against weathering depends on solubility, ability to stabilize in different polymer matrix, the distribution in matrix, evaporation loss during processing and use. The effect on the viscosity is also an important concern for processing. Various types of stabilizer that are commonly used in polymers are:
         Anti-oxidants (primary and secondary)—these are mainly phenolic and phosphite based.   HALS—Hindered amine light stabilizers   UV Absorbers—typical are oxanilides, benxophenones, benxotriazoles and hydroxyphenyltriazines.   Organosulfur compounds—prevents decomposition.   Antiozonants—prevent ozone cracking       

     Various surface active agents have been used in the experiments. This surface active agent has dual purpose:
         Viscosity modifier—allows the polymer compound melt to flow easily into the mold or extrude. Here the main purpose is to drop the viscosity so that the material can flow into thin sections and thru thin channels while being processed via injection molding or profile extrusion.   Surface enhancer—provides a smooth scratch resistant surface to the final molded part.       

     Ideally a low to medium molecular weight polyolefin, silicon oils, plasticizers, lubricants, polydimethylsiloxane (PDMS), acid amides, acid esters, fatty acids, hydrocarbon waxes, metallic soaps (various stearates, stearic acids), etc and the master batch forms of these additives are used as surface active agents. 
     Electrically conductive additives can also be added to the thermally conductive composite explained above in order to impart electrical conductivity to the end product which is required to facilitate electroplating, electroless plating, and primer free electrostatic painting of the thermally conductive polymer part. This property can be achieved by the use of various functional fillers including: carbon black powder, multiwall carbon nanotubes, single-wall carbon nanotubes, carbon fiber, carbon nanofibers, graphite, graphene, graphite fiber, metal nanoparticles (gold, silver, tungsten, and copper nano particles), metal coated carbon fibers, metal or nano-particle coated organic and inorganic fillers and other conductive type fillers. The current invention uses a single functional filler or a combination of two or more fillers from the above list. In a typical example, the resulting composite material of this invention consists of 0.1-35% loading of one or multiple conductive fillers as listed above. 
     
       
         
           
               
             
               
                 TABLE 1 
               
             
            
               
                   
               
               
                 Electrical Conductivity of additives and their composite properties. 
               
            
           
           
               
               
               
            
               
                 Additives 
                 Volume Resistivity 
                 Properties of Composites 
               
               
                   
               
            
           
           
               
               
               
               
            
               
                 Antistatic agents 
                 ~10 11   
                 Ω · cm 
                 Isotropic shrinkage 
               
               
                   
                   
                   
                 Non-sloughing 
               
               
                   
                   
                   
                 Moderate elongation 
               
               
                   
                   
                   
                 Colorable 
               
               
                   
                   
                   
                 Transparent grade 
               
               
                 Inherently dissipative polymers 
                 ~10 9 ~10 12   
                 Ω · cm 
                 Isotropic shrinkage 
               
               
                   
                   
                   
                 Colorable 
               
               
                   
                   
                   
                 Moderate elongation 
               
               
                 Inherently conductive polymers 
                 ~10 2 ~10 4   
                 Ω · cm 
                 Isotropic shrinkage 
               
               
                   
                   
                   
                 Colorable 
               
               
                   
                   
                   
                 Moderate elongation 
               
               
                   
                   
                   
                 EMI/RFI shielding capability 
               
               
                 Carbon black 
                 ~10 2   
                 Ω · cm 
                 Isotropic shrinkage 
               
               
                   
                   
                   
                 Strength/stiffness unchanged 
               
               
                   
                   
                   
                 Moderate elongation 
               
               
                   
                   
                   
                 Sloughing 
               
               
                   
                   
                   
                 High percolation threshold 
               
               
                   
                   
                   
                 EMI/RFI shielding capability 
               
               
                 Carbon fiber 
                 ~10~10 2   
                 Ω · cm 
                 Anisotropic shrinkage 
               
               
                   
                   
                   
                 Increase Strength/stiffness 
               
               
                   
                   
                   
                 Low elongation 
               
               
                   
                   
                   
                 Color option 
               
               
                   
                   
                   
                 Medium percolation threshold 
               
               
                   
                   
                   
                 EMI/RFI shielding capability 
               
               
                 Carbon Nanotubes- MWNT, 
                 ~10~10 2   
                 Ω · cm 
                 Increase Strength/stiffness 
               
               
                 SWNT, SMWNT 
                   
                   
                 Low percolation threshold 
               
               
                   
                   
                   
                 EMI/RFI shielding capability 
               
               
                 Stainless steel fiber 
                 ~0.10 
                 Ω · cm 
                 Isotropic shrinkage 
               
               
                   
                   
                   
                 Strength/stiffness unchanged 
               
               
                   
                   
                   
                 FDA compliant 
               
               
                   
                   
                   
                 Moderate elongation 
               
               
                   
                   
                   
                 EMI/RFI shielding capability 
               
               
                 Graphite (Various Micron size 
                 ~10 
                 Ω · cm 
                 Increase Strength/stiffness 
               
               
                 particles) 
                   
                   
                 Medium percolation threshold 
               
               
                 Nickel-coated graphite 
                 ~10 
                 Ω · cm 
                 Anisotropic shrinkage 
               
               
                   
                   
                   
                 Increase Strength/stiffness 
               
               
                   
                   
                   
                 Low percolation threshold 
               
               
                   
                   
                   
                 EMI/RFI shielding capability 
               
               
                 Nickel-coated Carbon Nanotube 
                 ~10~10 2   
                 Ω · cm 
                 Increase Strength/stiffness 
               
               
                   
                   
                   
                 Low percolation threshold 
               
               
                   
                   
                   
                 EMI/RFI shielding capability 
               
               
                 Graphene (Various Micron size 
                 ~0.01 
                 Ω · cm 
                 Increase Strength/stiffness 
               
               
                 particles) 
                   
                   
                 Medium percolation threshold 
               
               
                   
               
            
           
         
       
     
     The carbon nanotubes used in making the thermoplastic polymer compositions of this invention normally have a diameter which is within the range of 5 to 20 nanometers and have a length which is within the range of 1 to 5 microns. The carbon nanotubes used in making the thermoplastic polymer composition of this invention more typically have a diameter which is within the range of 7 to 15 nanometers and have a length which is within the range of 1 to 3 microns. The carbon nanotubes used in making the thermoplastic polymer compositions of this invention preferably have a diameter which is within the range of 9 to 10 nanometers and have an aspect ratio which is within the range of 80 to 180 and more typically have an aspect ratio which is within the range of 90 to 150. The carbon nanotubes used in making the thermoplastic polymer composition of this invention preferably have an aspect ratio which is within the range of 95 to 120. 
     Specialty carbon nanotubes are also used in making the thermoplastic polymer compositions of this invention normally have a diameter which is within the range of 4 to 12 nanometers and have a length which is within the range of 1 to 5 microns. The specialty multiwall carbon nanotubes used in making the thermoplastic polymer composition of this invention more typically have a diameter which is within the range of 6 to 9 nanometers and have a length which is within the range of 1 to 3 microns. The specialty carbon nanotubes typically have 2 to 10 walls and more typically have 3 to 6 walls. The specialty carbon nanotubes used in making the thermoplastic polymer compositions of this invention typically has an aspect ratio of approximately 1,000 (for instance within the range of 800 to 1200). 
     Carbon black is one of the most popular fillers used in conductive polymers because of its low cost. Since its aspect ratio (ratio of length to diameter) is very small due to the particulate shape, and its percolation threshold is very high, the particles can be interconnected to be conductive. The conductive carbon black used in making the thermoplastic polymer compositions of this invention has an average particle size of 30 to 90 microns. More typically, the conductive carbon black used in making the thermoplastic polymer compositions of this invention has an average particle size of 40 to 60 microns. 
     A combination of various conductive fillers can have a synergistic effect on the conductivity of polymer composites. For example, the combination of graphite with regular carbon fiber had higher conductivity than any one of them with the same amount of loading. The combination of carbon black, regular carbon fiber, and graphite also has better EMI shielding effectiveness than any one of them or two of them. The synergistic effects have been also found from the incorporation of ICP (inherently conductive polymers) with conductive fibers. 
     Flame retardant chemicals, compounds, and fillers can also be introduced into thermoplastic compounds to improve their flammability ratings. Introducing flame retardants into the thermally conductive thermoplastic compounds helps impart ignition resistance and inhibits or resists the spread of fire. This added property allows for the thermally conductive thermoplastic compound to be utilized safely where a potential for fire exists. Depending on which base thermoplastic resin is chosen for the composite, will determine which flame retardant is needed. 
     Typical flame retardants utilized in the thermoplastic industry include: bisphenol-A, disphenylphosphate, 1,2-bis(tribromophenoxy)ethane, brominated epoxy oligomers, brominated polystyrene, chlorendic anhydride, chlorinated paraffins, decabromobiphenyl, decabromodiphenylethane, decabromodiphenyloxide, dechlorane plus, dibromoneopentylglycol, ethylene-bis(5,6-dibromonorbornane-2,30dicarboximide), ethylene-bis(tetrabromophthalimide), halogenated polyetherpolyols, hexabromocyclododecane, octabromodiphenyloxide, octabromotrimethylphenylindane, pentabromodiphenyloxide, poly(dibromostyrene), poly(pentabromobenzylacrylate), resorcinol diphenylphospate, tetrabromo-bisphenol-A, tetrabromo-bisphenol-A,bis(2,3-dibromopropyl ether), tetrabromo-bisphenol-A, carbonate oligomers, tetrabromophthalate diols, tetrabromophthalic anhydride, and triphenylphosphate. 
     With some of the flame retardants listed above it is beneficial and necessary to use a synergist. Typically, antimony dioxide is the synergist of choice, however, others can include: sodium antimonite, iron oxide, zinc borate, zinc phosphate, and zinc stannate. 
     After the correct amounts of thermally conductive, electrically conductive, flame retardant fillers and/or stabilizers, modifiers, and other additives are added to the composition, the amount of thermoplastic in the composition makes up the remaining amount. The thermoplastic compound may be present at 10 to 60 percent by weight of the total composition, with 15 to 55 weight percent being more preferred, and 20 to 45 weight percent being even more preferred. 
     In one embodiment of this invention the thermally conductive thermoplastic polymeric composition employed in making the heat sink fixture/housing and/or sleeve is comprised of a medium viscosity polyamide polymer, a thermally conductive filler system, an impact modifier, a flame retardant system and a surface active agent, wherein:
         the polyamide polymer is present in the composition at a level which is within the range of 10 weight percent to 50 weight percent, more preferably in the range of 20 weight percent to 30 weight percent;   the thermally conductive filler system is present in the composition at a level which is within the range of 30 weight percent to 70 weight percent, more preferably in the range of 40 weight percent to 55 weight percent;   the impact modifier is present in the composition at a level which is within the range of 1 weight percent to 15 weight percent, more preferably in the range of 2 weight percent to 5 weight percent;   the flame retardant system is present in the composition at a level which is within the range of 10 weight percent to 20 weight percent, more preferably in the range of 12 weight percent to 16 weight percent; and   the surface active agent is present as an mixture of 2 surface active agents in the composition at a level which is within the range of 0.1 weight percent to 5 weight percent, more preferably in the range of 0.5 weight percent to 3.0 weight percent       

     In such compositions the polyamide polymer can be selected from the group consisting of polyamide 6, polyamide 66, polyamide 46, polyamide 12, polyamide 11, semi-aromatic polyamides (PPA), co-polyamides and mixtures thereof. Further in such combinations, the thermally conductive filler system is selected from the various particles such as graphites, metal oxides, ceramics and carbon blacks or fibers. In one such example this thermally conductive filler system comprises of natural or synthetic graphite particles (platelet type) and zinc oxide. In another example, it can consist of only one type of graphite particle or a combination of various grades of graphites. In another example (for electrically insulative grades of compound for sleeve), this filler combination consists of only zinc oxides or zinc oxides combined with aluminium oxides or any metal oxides with ceramic particles. 
     The impact modifier is typically a meleated polyolefin, such as like maleic anhydride grafted polyethylene, maleic anhydride grafted polypropylene, maleic anhydride grafted ethylene copolymers and combinations thereof. 
     The flame retardant system is typically selected to include a combination of primary flame retardant and a synergist in the preferred ratio range of 5:1 to 3:1. The primary flame retardants are brominated epoxy oligomers, brominated polystyrene, chlorendic anhydride, chlorinated paraffins, decabromobiphenyl, decabromodiphenylethane, decabromodiphenyloxide, dechlorane plus, dibromoneopentylglycol, ethylene-bis(5,6-dibromonorbornane-2,30-dicarboximide), and the synergist is typically antimony trioxide, antimony dioxide or zinc borate. The surface active agent mixture is typically comprising of a polyethylene based polymer and a Polydimethylsiloxane (PDMS) in its original form or as a master batch. 
     In another embodiment of this invention the thermally conductive thermoplastic polymeric composition employed in making the high temperature resistant heat sink fixture, housing, sleeve, or back plate is comprised of an high performance polymer, a thermally conductive filler system, an impact modifier, and a surface active agent, wherein:
         the high performance polymer is present in the composition at a level which is within the range of 10 weight percent to 60 weight percent, more preferably in the range of 30 weight percent to 50 weight percent and most preferably in the range of 35 weight percent to 45 weight percent;   the thermally conductive filler system is present in the composition at a level which is within the range of 30 weight percent to 70 weight percent, more preferably in the range of 40 weight percent to 55 weight percent;   the impact modifier is present in the composition at a level which is within the range of 1 weight percent to 15 weight percent, more preferably in the range of 2 weight percent to 5 weight percent; and   the surface active agent is present as an mixture of 2 surface active agents in the composition at a level which is within the range of 0.1 weight percent to 5 weight percent, more preferably in the range of 0.5 weight percent to 3.0 weight percent.       

     In such compositions the high performance polymer can be selected from the group consisting of polyphylene sulphide (PPS), semi-aromatic polyamides (PPA), polyetheretherketones (PEEK), liquid crystal polymers (LCP) and sulfone polymers (PSU, PES, PPSU) Further in such combinations, the thermally conductive filler system is selected from the various particles such as graphites, metal oxides, ceramics and carbon blacks or fibers. In one such example this thermally conductive filler system comprises of natural or synthetic graphite particles (platelet type) and zinc oxide. In another example, it can consist of only one type of graphite particle or a combination of various grades of graphites. In another example (for electrically insulative grades of compound for sleeve), this filler combination consists of only zinc oxides or zinc oxides combined with aluminium oxides or any metal oxides with ceramic particles. 
     The impact modifier is typically a meleated polyolefin such as maleic anhydride grafted polyethylene, maleic anhydride grafted polypropylene, maleic anhydride grafted ethylene copolymers and their combinations. The surface active agent mixture is typically comprising of a polyethylene based polymer and a polydimethylsiloxane (PDMS) in its original form or as a master batch. 
     In a further embodiment of this invention the thermally conductive thermoplastic polymeric composition employed in making the high thermally conductive sheets, films, plates is comprised of an polymer system, and a thermally conductive filler system, wherein the polymer is present in the composition at a level which is within the range of 10 weight percent to 50 weight percent, more preferably in the range of 12 weight percent to 40 weight percent and most preferably in the range of 15 weight percent to 25 weight percent; and wherein the thermally conductive filler system is present in the composition at a level which is within the range of 40 weight percent to 90 weight percent, more preferably in the range of 50 weight percent to 75 weight percent. 
     In such compositions the polymer systems can be selected from any of the base polymers and mixtures thereof. Further in such combinations, the thermally conductive filler system is selected from the various types of graphites, and mixtures thereof. 
     This invention is illustrated by the following examples that are merely for the purpose of illustration and are not to be regarded as limiting the scope of the invention or the manner in which it can be practiced. Unless specifically indicated otherwise, parts and percentages are given by weight. 
     The above defined composite systems can be prepared by using a co-rotating twin screw extruder; such as a 25 mm diameter (D) twin-screw extruder from Berstorff, GmbH which was used in making various test formulations. The components of the formulations were fed in two schemes; (i.) all from the throat of the extruder, passing it through a length of 44D and (ii.) the conductive filler only fed from the side-feeder, with the other components from the throat. The system was typically degassed by vacuum. A twin screw extruder can beneficially be utilized in processing the above defined composite material. Pellets were collected by running the strands through a strand-pelletizer. Other melt blending/compounding techniques such as single screw extruders and banbury mixers can also be used. 
     The amount of shear applied during melt mixing should be the amount required for dispersion while still maintaining the structure of the thermal fillers. The amount of shear and how to increase or decrease the shear is dependent upon the attributes of a given composition and the mixing device and the mixing parameters such as screw design, back pressure, horsepower, and rpms of the screw relative to the output. These are all well-established independent variables commonly used to introduce shear into a mixing device such as an extruder. 
     Test Methods 
     Using basic steady state heat transfer equations, a cost-effective apparatus that would measure through plane thermal conductivity was modeled and designed. The thermal conductivity meter developed is based on a hot plate testing method. A schematic diagram of such a thermal conductivity meter is illustrated in  FIG. 3 . The thermal conductivity meter  16  includes an aluminum block  17  with a polymeric test sample  19  being positioned above the aluminum block  17 . The aluminum block  17  is positioned above a heat source  20  such as a hot plate, which is positioned above a base support  21 . A first thermocouple  18  is connected to the surface of polymeric test sample  19  and a second thermocouple  22  is connected to the surface of the aluminum block  17  as illustrated in  FIG. 3 . The first thermocouple  18  is connected to a first digital temperature readout meter  23  via electrically insulated wires  24  and the second thermocouple  22  is connected to a second digital temperature readout meter  25  with electrically insulated wires  24 . 
     As heat is transferred though a medium normal to its surface, temperature is reduced through the resistance of the material. This resistance is related to the thermal conductivity of the material. Using this relationship, thermal conductivity of the sample can be realized. A few assumptions are also made during the measurement and calculation of thermal conductivity when made via a thermal conductivity meter. The assumptions made include:
         a. Steady state   b. Apparatus is adiabatic with surroundings   c. Constant properties   d. Thickness of sample is much less than the length of the sample   e. Thermal conductivity of aluminum is much greater than the thermal conductivity of the sample   f. The sample covers the total area of the aluminum block       

     The thermal conductivity data collected was comparable to data attained from a laser flash type thermal conductivity meter. 
     The volume resistivity of a molded specimen was measured by direct-current (DC) resistance along the length direction around 40 mm at room temperature. The resistivity was converted to volume resistivity, ρ v  as ρ v =WDR v /L, where W is the width, D the thickness, L the length of the specimen, and R v  is the measured resistance. The data was the average of 10 specimens with standard deviation to the mean less than 5%. 
     Electrical conductivity was calculated by the following formula: 
     
       
         
           
             σ 
             = 
             
               
                 ( 
                 
                   
                     V 
                     I 
                   
                   × 
                   
                     π 
                     
                       ln 
                        
                       
                           
                       
                        
                       2 
                     
                   
                   × 
                   t 
                 
                 ) 
               
               
                 - 
                 1 
               
             
           
         
       
     
     wherein σ is electrical conductivity, V, I and t are current, voltage, and thickness of the sample, respectively. It should be noted that the thickness is not much smaller than the distance between the probes so that electrical conductivity obtained is not real surface conductivity. The average conductivity of each specimen will be obtained from measurements at four different locations. 
     The thermal properties will be characterized by thermogravimetric analyzer (TGA), and differential scanning calorimetry, DSC. The mechanical properties (i.e. tensile strength, tensile modulus, elongation, toughness) will be tested by Instron. The heat distortion temperature (HDT) is determined by HDT tester. 
     EXPERIMENTAL 
       
     
       
         
           
               
             
               
                 TABLE 2 
               
             
            
               
                   
               
               
                 Details of Ingredients used in the experiments are listed in below table: 
               
            
           
           
               
               
               
               
            
               
                 MATERIAL 
                 SUPPLIER 
                 GRADE 
                 SPECIFICATIONS 
               
               
                   
               
               
                 ABS 
                 CHI MEI Corporation 
                 Polyac PA757 
                 General purpose acrylonitrile 
               
               
                   
                 Sabic Innovative Plastics 
                 Cycolac MG94 
                 butadiene styrene. Melt flow 
               
               
                   
                   
                   
                 rate = 1.8 g/10 min. 
               
               
                 HDPE 
                 Ashland Distribution 
                 Hival 511051 
                 High flow HDPE grade 
               
               
                 PP copoly 
                 Ashland Distribution 
                 Hival PP CP 2620 NAT 
                 General purpose PP copolymer 
               
               
                 PP 
                 Ashland Distribution 
                 Hival PP HO 2420NA NAT 
                 A homopolymer resin designed 
               
               
                   
                 ExxonMobil Chemical 
                 ExxonMobil ™ PP3155 
                 for spunbond nonwovens. 
               
               
                   
                   
                   
                 Particularly suited for excellent 
               
               
                   
                   
                   
                 spinning for uniform, high 
               
               
                   
                   
                   
                 quality fabrics. Melt flow rate = 
               
               
                   
                   
                   
                 36 g/10 min. 
               
               
                 LDPE 
                 Ashland Distribution 
                 Petrothane NA870252 LDPE 
                 Linear low density polyethylene 
               
               
                   
                 Westlake Polymer LLC 
                 LLDPE HIFOR GT4157 
                 with a melt flow rate = 0.8 
               
               
                   
                   
                 LF2018AB 
                 g/10 min and density = 0.924. 
               
               
                   
                   
                   
                 Ideal for sheet and tubing. 
               
               
                 Nylon 6,6 
                 BASF 
                 Ultramid A34 
                 General purpose Polyamide 66 
               
               
                 Nylon 4,6 
                 DSM corporation 
                 Stanyl TW341 
               
               
                 PC 
                 Bayer Materials 
                 Makrolon 2408 
                 General purpose PC resin - 20- 
               
               
                   
                 Teijin 
                 Powder PC Panlite 1225 WX 
                 24 MFI 
               
               
                 PBT 
                 Dupont 
                 Crastin 6131 - PBT 
                 High Flow PBT 
               
               
                 PBT Cyclized 
                 Cyclics Corporation 
                 CBT 100 or 500 
                 Cyclic butylene terepthalate 
               
               
                 PTFE 
                 Daikin 
                 PTFE L-5F 
                 Surface active PTFE 
               
               
                 EMA 
                 ExxonMobil Chemical 
                 Optema ™ TC120 ot TC141 
                 Ethylene methyl acrylate 
               
               
                   
                   
                   
                 copolymer intended for 
               
               
                   
                   
                   
                 extrustion coating, coextrusion 
               
               
                   
                   
                   
                 coating and extrusion 
               
               
                   
                   
                   
                 lamination. Melt flow rate = 6 
               
               
                   
                   
                   
                 g/10 min. 
               
               
                 PET 
                 generic 
                 PET 
                 General purpose PET 
               
               
                 PETG 
                 SK Chemicals 
                 Skygreen ® S2008 
                 General purpose polyethylene 
               
               
                   
                   
                   
                 terephthalate glycol. 
               
               
                 PPS 
                 Ticona 
                 Fortran 0205 PPS 
                 Compounding grade 
               
               
                   
                   
                   
                 Polyphylene Sulphide 
               
               
                 LCP 
                 Ticona 
                 Vectra LCP E950 
                 High strenght, electrcial grade 
               
               
                   
                   
                   
                 Liquid Crystal Polymer 
               
               
                 SEBS (TPE) 
                 Kraton Corporation 
                 Kraton 1901X 
                 Maleated SEBS 
               
               
                 TPU 
                 Merquinsa 
                 PearlThane ® 11T93 
                 A polycaprolactone copolyester 
               
               
                   
                   
                   
                 based thermoplastic 
               
               
                   
                   
                   
                 polyurethane with a shore 
               
               
                   
                   
                   
                 hardness = 93A. 
               
               
                 TPU 
                 Merquinsa 
                 PearlThane ® 15N70 
                 A polyether copolymer-based 
               
               
                   
                   
                   
                 thermoplastic polyurethane 
               
               
                   
                   
                   
                 with a shore hardness = 72A. 
               
               
                 TPU 
                 Merquinsa 
                 PearlThane ® D15N80 
                 A polyether-based 
               
               
                   
                   
                   
                 thermoplastic polyurethane 
               
               
                   
                   
                   
                 with a shore hardness = 81A. 
               
               
                 Carbon 
                 Arkema 
                 Graphistrength ™ C100 
                 Multi-walled carbon nanotubes 
               
               
                 Nanotubes 
                   
                   
                 with a mean number of walls = 
               
               
                 (C100) 
                   
                   
                 5-15, outer mean diameter = 
               
               
                   
                   
                   
                 10-15 nm, and length = 0.1- 
               
               
                   
                   
                   
                 10 μm. 
               
               
                 Carbon 
                 Bayer Materials 
                 Baytubes ® 150HP 
                 Multi-walled carbon nanotubes 
               
               
                 Nanotubes 
                   
                   
                 with a mean number of walls = 
               
               
                 (Baytubes) 
                   
                   
                 3-15, outer mean diameter = 
               
               
                   
                   
                   
                 13-16 nm, and length = 1−&gt;10 μm. 
               
               
                 Carbon 
                 NANOCYL S.A. 
                 Nanocyl ™ NC 7000 
                 Multi-walled carbon nanotubes 
               
               
                 Nanotubes 
                   
                   
                 with an aspect ratio &gt;150. 
               
               
                 (Nanocyl) 
               
               
                 Carbon 
                 SouthWest 
                 SWeNT ® SMW-100 
                 Specialty Multiwalled carbon 
               
               
                 Nanotbues 
                 NanoTechnologies 
                   
                 nanotbues with a mean 
               
               
                 (SWeNT) 
                   
                   
                 number of walls = 3-6, a mean 
               
               
                   
                   
                   
                 diameter = 6.6 nm, and an 
               
               
                   
                   
                   
                 aspect ratio ~1,000. 
               
               
                 Carbon 
                 Cnano Technology Limited 
                 Flotubes ™ 9000 
                 Multi-walled carbon nanotubes 
               
               
                 Nanotubes 
                   
                   
                 with an average diameter = 
               
               
                 (Cnano) 
                   
                   
                 11 nm, and an average length = 
               
               
                   
                   
                   
                 10 μm. 
               
               
                 Flame 
                 Akzo Nobel 
                 Perkalite FR100 
                 Various FR&#39;s used ranging form 
               
               
                 Retardants 
                 Albemarle 
                 Saytex 120 
                 brominated materials to non- 
               
               
                   
                 BASF 
                 Saytex 8010 
                 hals 
               
               
                   
                 Bright Sun/Albemarle 
                 Saytex HP 3010 
               
               
                   
                 CHEMPOINT 
                 Melapur 200 
               
               
                   
                 Clariant Corporation 
                 Antimony Trioxide 
               
               
                   
                 ICL Corporation 
                 DE-83R 
               
               
                   
                   
                 Exolit OP 1230 
               
               
                   
                   
                 ICL FR 1025 
               
               
                 Antioxidant 
                 Amfine 
                 AO-412S 
                 High molecular weight 
               
               
                   
                 Maroon Chemical 
                 Sunox 626 
                 thioether antioxidant 
               
               
                   
                 HM Royal 
                 Ethanox ® 310 
                 Phosphate antioxidant 
               
               
                   
                   
                   
                 Tin-free antioxidant 
               
               
                 Modifier 
                 Arkema 
                 Lotader 8900 
                 A random terpolymer of 
               
               
                   
                   
                   
                 ethylene, acrylic ester and 
               
               
                   
                   
                   
                 glycidyl metacrylate with a 
               
               
                   
                   
                   
                 melt flow rate = 6 g/10 min. 
               
               
                 Modifier 
                 Arkema 
                 Lotader ® 4700 
                 A random terpolymer of 
               
               
                   
                   
                   
                 ethylene, acrylic ester and 
               
               
                   
                   
                   
                 maleic anhydride with a melt 
               
               
                   
                   
                   
                 flow rate = 7 g/10 min. 
               
               
                 Modifier 
                 Clariant Corporation 
                 Licocene ® PE 4351 
                 Maleic-anhydride-modified 
               
               
                   
                   
                   
                 polyethylene 
               
               
                 Modifier 
                 Kraton Polymers LLC 
                 Kraton ® FG 1901G 
                 A linear triblock copolymer 
               
               
                   
                   
                   
                 based on styrene and 
               
               
                   
                   
                   
                 ethylene/butylene with a 
               
               
                   
                   
                   
                 polystyrene content of 30%. 
               
               
                   
                   
                   
                 Melt flow rate = 14-28 g/10 min 
               
               
                   
                   
                   
                 and shore hardness = 71A. 
               
               
                 Modifier 
                 Polyram Ram-On 
                 Bondyram ® 6000 
                 Maleic anhydride modified 
               
               
                   
                 Industries 
                   
                 ABS. Compatibilizer and 
               
               
                   
                   
                   
                 coupling agent for styrene 
               
               
                   
                   
                   
                 compounds with a mass flow 
               
               
                   
                   
                   
                 rate of 8 g/10 min. 
               
               
                 Carbon Black 
                 Cabot Corporation 
                 Volcan ® XC-72 
                 High surface area conductive 
               
               
                   
                   
                   
                 carbon black 
               
               
                 Coupling 
                 Chemtura 
                 Polybond ® 3200 
                 Maleic anhydride modified 
               
               
                 Agent 
                   
                   
                 homopolymers polypropylene 
               
               
                   
                   
                   
                 used as a coupling agent. 
               
               
                 CBT 
                 Cyclics Corporation 
                 CBT 100 
                 Melts to water-like viscosity 
               
               
                   
                   
                   
                 when heated, then polymerizes 
               
               
                   
                   
                   
                 into the engineering 
               
               
                   
                   
                   
                 thermoplastic polybutylene 
               
               
                   
                   
                   
                 terephthalate. 
               
               
                 Lubricants and 
                 Dupont 
                 Fusabond E MB-226DE 
                 standard and generic versions 
               
               
                 Flow/Rheology 
                 Elastocon TPE 
                 Fusabond N493D 
                 of various additives. 
               
               
                 Modifiers 
                 Technologies, Inc. 
                 Elastocon 2810 
               
               
                   
                 Wacker Silicones 
                 ZN Stearate 
               
               
                   
                   
                 Genioplast Pellet S 
               
               
                 Lubricant 
                 Harwick Standard 
                 Stan-Lube 6056 Mineral 
                 Processing oil lubricant 
               
               
                 Hytrel 
                 DuPont 
                 Hytrel ® 4069 
                 Low modulus grade with a 
               
               
                   
                   
                   
                 nominal hardness of 40D and 
               
               
                   
                   
                   
                 melt flow of 8.5 g/10 min. 
               
               
                 Pigments 
                 Dupont 
                 Tipure R104 
                 Basic titanium dioxide for white 
               
               
                   
                 Mayzo 
                 Benetex OB-1 
                 color and generic optical 
               
               
                   
                   
                   
                 brightners 
               
               
                 PPA 
                 Evonik 
                 Vestamid Htplus M3000 
                 These are Semi-Aromatic 
               
               
                   
                 Solvay Advanced 
                 Amodel A-1006 
                 Polyamides - PPA&#39;s 
               
               
                   
                 Polymers, LLC 
               
               
                 Pebax 
                 Arkema 
                 Pebax MH1637 
                 Polyether block amides, 
               
               
                   
                   
                   
                 plasticizer-free, thermoplastic 
               
               
                   
                   
                   
                 elastomers 
               
               
                 Thermoplastic 
                 Kaneka Corporation 
                 Sibstar ® 073T 
                 Thermoplastic elastomer with a 
               
               
                 Elastomer 
                   
                   
                 shore hardness = 45A and melt 
               
               
                   
                   
                   
                 flow rate = 7 g/10 min. 
               
               
                 Thermoplastic 
                 Kaneka Corporation 
                 Sibstar ® 103T 
                 Thermoplastic elastomer with a 
               
               
                 Elastomer 
                   
                   
                 shore hardness = 46A and a 
               
               
                   
                   
                   
                 melt flow rate = 0.10 g/10 min. 
               
               
                 Coupling 
                 Kenrich Petrochemicals 
                 Kenrich ® Capow L38 
                 Titanate coupling agent 
               
               
                 Agent 
               
               
                 Other Filler 
                 Momentive Performance 
                 Cool Flow CF 300/Polar 
                 Boron Nitrides - Various Grades - 
               
               
                   
                 Materials 
                 therm 110 and PTX 60 
                 Platelets to loosely attached 
               
               
                   
                   
                 Cool Flow CF400 
                 aglomarates 
               
               
                 Siloxane 
                 Multibase, A Dow Corning 
                 Siloxane Masterbatch 
                 Masterbatch consisting of 50% 
               
               
                   
                 Company 
                 MB50-001 
                 ultra-high molecular weight 
               
               
                   
                   
                   
                 siloxane polymer dispersed in 
               
               
                   
                   
                   
                 polypropylene homopolymer. 
               
               
                 Ketone 
                 Victrex, Evonik, Gharda 
                 Various grades of Victrex 
                 Various types of Ketone 
               
               
                 Polymers 
                   
                 PEEK, Vestakeep and 
                 polymers for high temp 
               
               
                   
                   
                 Gharda&#39;s PAEK 
                 applications. 
               
               
                 Synthetic 
                 Hyprez MA Diamond PDR 
                 Hyprez MA Diamond PDR 
                 Diamond Powder 
               
               
                 Diamond 
               
               
                 Carbon Fiber 
                 SGL carbons 
                 Sigrafil C30 
                 Generic carbon and graphite 
               
               
                   
                 Toho Tenax 
                 Tenax C493 
                 fibers 
               
               
                   
                 Teijin 
                 Rehema A201 
               
               
                 Other 
                 Unitex 
                 Uniplex 214 
                 BBSA type plasticizer for 
               
               
                 Additives 
                   
                   
                 Polyamides 
               
               
                 Graphite Filler 
                 SGL carbons 
                 GFG 200/500 
                 Various Graphites: thermally 
               
               
                   
                 Superior Graphites 
                 Superior 2025 Graphite 
                 expanded graphites, natural 
               
               
                   
                 XG Sciences 
                 Superior 8224 Graphite 
                 flakes, synthetic graphites, 
               
               
                   
                   
                 xGnP-M-15 
                 graphenes, etc. 
               
               
                   
                   
                 xGnP-M-25 
               
               
                 Thermal Filler 
                 Washington Mills Duralum 
                 Duralum Special White 
                 Various Fillers: Metal oxides to 
               
               
                   
                 Special White 
                 Al2O3 180 
                 ceramics to metal fibers and 
               
               
                   
                 Zochem 
                 Zoco 103 
                 powders 
               
               
                   
                 Zircocem (Jyoti Ceramic) 
                 Zircocem-1 
               
               
                   
                 SCM Metal Products 
                 500RL Copper Fibers 
               
               
                   
               
            
           
         
       
     
     Tables 3 through 13 list the resin compositions (Experiments 1-45). The compositions were made by reactive extrusion to make engineering thermoplastics. This was normally done by adding a dry blend mixture of the polymers, modifiers, stabilizers, processing aids, and fillers as a single feed into the feed hopper of a twin screw extruder with controlled specific energy input via control of feed rate (15 to 95% torque), RPM (60 to 900 rpm), process temperature (as per the base polymer system) and residence time distribution in various extruder stages. The specific energy input was typically within the range of 0.2 to 0.5 kilowatt hours per kilogram and was more commonly within the range of 0.25 to 0.35 kilowatt hours per kilogram. It should be noted that some compositions can be prepared employing other suitable mixing devices for melt blending, such as a single screw extruder or a multiple single screw extruder or a combination of internal mixers such as banbury and single or twin screw extruders or similar mixing devices. In practicing this invention any mixing equipment and techniques which result in an essentially homogenous dispersion of components can be used to obtain the desired results. 
     In an alternative method/procedure used, the thermoplastic thermally conductive compound material was made by charging the main feeder of a Berstorff ZE-25 twin screw extruder (L/D=44) with the ingredients. In another of the procedures used, a thermoplastic thermally conductive compound was made by a reactive blending/extrusion process using split-feed technology, wherein in a twin screw extruder (extruder length of 36D to 52D, wherein D is the diameter of the extruder screw), the select ingredient (mainly dispersion polymeric resin or mixture of resins and additives and thereof) was premixed and charged from the main feeder and the dispersed phase thermally conductive additives were introduced into the melt at a downstream feed port location at a distance of 8D to 30D, from the main feed throat of the extruder. 
     The operating conditions for the reactive extrusions used a screw speed of 200 to 600 RPM, a temperature profile of 30-45° C. (feed), 150-360° C. (Zone 2), 160-385° C. (Zone 3), 160-390° C. (Zone 4), 170-400° C. (Zone 5), 170-400° C. (Zone 6), 170-400° C. (Zone 7), 160-405° C. (Zone 8), and 160-400° C. (die). The specific barrel and die temperatures are based on the base polymer and additive system used. The product was pelletized and dried between 60-120° C. for 2-4 hours to a moisture content of less than 0.05% by weight. Then, test specimens (as per ASTM and ISO) were made by injection molding and were allowed to condition at a temperature of 23° C. for at least 24 hours before testing. The thermal, electrical and mechanical properties of these compounded materials are listed in the same tables below the respective compositions. 
     
       
         
           
               
             
               
                 TABLE 3 
               
             
            
               
                   
               
               
                 Experiments - Formulation and Test Results - 1 through 5 
               
            
           
           
               
               
            
               
                 Thermally Conductive + 
                 EXPERIMENT # 
               
            
           
           
               
               
               
               
               
               
            
               
                 Electrically Insulative 
                 1 
                 2 
                 3 
                 4 
                 5 
               
               
                   
               
            
           
           
               
               
               
               
               
               
            
               
                 MATERIALS 
                   
                   
                   
                   
                   
               
               
                 Vectra LCP E950 
                 48.70 
                 — 
                 — 
                 — 
                 — 
               
               
                 Hival PPCO 2620 
                 — 
                 48.70 
                 — 
                 — 
                 — 
               
               
                 Hival PP 2420 
                 — 
                 — 
                 80.00 
                 — 
                 — 
               
               
                 Ultramid A34 
                 — 
                 — 
                 — 
                 38.00 
                 60.00 
               
               
                 Fusabond N493D 
                 5.00 
                 — 
                 — 
                 4.00 
                 — 
               
               
                 HDPE 511051 
                 — 
                 — 
                 — 
                 6.00 
                 — 
               
               
                 Polybond 3200 
                 — 
                 3.00 
                 — 
                 — 
                 — 
               
               
                 PTFE L-5F 
                 — 
                 — 
                 — 
                 1.00 
                 — 
               
               
                 Ninor (PSNYL) 
                 — 
                 — 
                 — 
                 0.50 
                 — 
               
               
                 Genioplast Pellet S 
                 1.00 
                 — 
                 — 
                 0.50 
                 — 
               
               
                 Ethanox 310 
                 0.15 
                 0.15 
                 — 
                 — 
                 — 
               
               
                 Sunox 626 
                 0.15 
                 0.15 
                 — 
                 — 
                 — 
               
               
                 ZoChem 103 
                 35.00 
                 20.00 
                 — 
                 35.00 
                 — 
               
               
                 GFG 200 
                 2.00 
                 — 
                 — 
                 — 
                 — 
               
               
                 PolarTherm 110 
                 4.00 
                 28.00 
                 — 
                 10.00 
                 — 
               
               
                 Cool Flow CF 300 
                 4.00 
                 — 
                 — 
                 — 
                 — 
               
               
                 Graphite TC307 
                 — 
                 — 
                 20.00 
                 — 
                 — 
               
               
                 Barium Titanate 
                 — 
                 — 
                 — 
                 5.00 
                 — 
               
               
                 PTX60 
                 — 
                 — 
                 — 
                 — 
                 40.00 
               
               
                 Total 
                 100 
                 100 
                 100 
                 100 
                 100 
               
               
                 PROPERTIES 
               
               
                 Thermal Conductivity (W/mK) 
                 1.767 
                 1.174 
                 0.983 
                 1.402 
                 1.779 
               
               
                 Surface Resistance Plaque(ohms/sq) 
                 3.10E+12 
                 3.50E+12 
                 3.40E+11 
                 5.00E+12 
                 5.00E+12 
               
               
                 Tensile Modulus (MPa) 
                 4227.60 
                 4335.20 
                 2111.51 
                 3426.71 
                 9175.80 
               
               
                 Tensile Stress @ Yld (MPa) 
                 19.96 
                 21.50 
                 33.90 
                 35.32 
                 57.50 
               
               
                 Tensile Stress @ Break (MPa) 
                 19.93 
                 21.00 
                 32.47 
                 35.23 
                 56.50 
               
               
                 Tensile Strain @ Break (%) 
                 1.06 
                 3.50 
                 5.57 
                 4.01 
                 1.71 
               
               
                 Flexural Modulus (MPa) 
                 5235.35 
                 1632.60 
                 2205.41 
                 3598.26 
                 7399.90 
               
               
                 Flexural Stress @ Break (MPa) 
                 31.90 
                 37.40 
                 55.97 
                 66.25 
                 104.70 
               
               
                 Impact Strength (ft-lb/in) 
                 0.36 
                 0.93 
                 0.42 
                 1.11 
                 0.70 
               
               
                 Density 
                 1.8560 
                 1.3730 
                 1.0240 
                 1.7230 
                 1.4057 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 4 
               
             
            
               
                   
               
               
                 Experiments - Formulation and Test Results - 6 through 10 
               
            
           
           
               
               
            
               
                 Thermally Conductive + 
                 EXPERIMENT # 
               
            
           
           
               
               
               
               
               
               
            
               
                 Electrically Insulative 
                 6 
                 7 
                 8 
                 9 
                 10 
               
               
                   
               
            
           
           
               
               
               
               
               
               
            
               
                 MATERIALS 
                   
                   
                   
                   
                   
               
               
                 Ultramid A34 
                 24.00 
                 — 
                 — 
                 — 
                 — 
               
               
                 Fortran 0205 PPS 
                 — 
                 42.00 
                 42.00 
                 42.00 
                 44.70 
               
               
                 Cycolac MG94 
                 5.00 
                 — 
                 — 
                 — 
                 — 
               
               
                 Bondyram 6000 
                 5.00 
                 — 
                 — 
                 — 
                 — 
               
               
                 CBT 100 
                 — 
                 2.00 
                 2.00 
                 2.00 
                 2.00 
               
               
                 Genioplast Pellet S 
                 0.50 
                 1.00 
                 1.00 
                 1.00 
                 — 
               
               
                 Ninor (PSNYL) 
                 0.50 
                 — 
                 — 
                 — 
                 — 
               
               
                 HDPE 511051 
                 — 
                 3.00 
                 3.00 
                 3.00 
                 — 
               
               
                 Lotador 8900 
                 — 
                 2.00 
                 2.00 
                 2.00 
                 3.00 
               
               
                 Ethanox 310 
                 — 
                 — 
                 — 
                 — 
                 0.15 
               
               
                 Sunox 626 
                 — 
                 — 
                 — 
                 — 
                 0.15 
               
               
                 Duralum Special White Al2O3 180 
                 20.00 
                 — 
                 — 
                 — 
                 — 
               
               
                 Zochem 103 
                 45.00 
                 — 
                 — 
                 — 
                 — 
               
               
                 GFG 200 
                 — 
                 — 
                 20.00 
                 20.00 
                 — 
               
               
                 Cool Flow CF400 
                 — 
                 — 
                 30.00 
                 — 
                 — 
               
               
                 Zircocem-1 
                 — 
                 — 
                 — 
                 30.00 
                 — 
               
               
                 PTX60 
                 — 
                 30.00 
                 — 
                 — 
                 50.00 
               
               
                 Rahema A201 
                 — 
                 20.00 
                 — 
                 — 
                 — 
               
               
                 Total 
                 100 
                 100 
                 100 
                 100 
                 100 
               
               
                 PROPERTIES 
               
               
                 Thermal Conductivity (W/mK) 
                 1.579 
                 1.428 
                 1.884 
                 1.557 
                 1.441 
               
               
                 Surface Resistance Plaque(ohms/sq) 
                 4.20E+11 
                 2.10E+11 
                 1.80E+11 
                 4.60E+11 
                 5.90E+11 
               
               
                 Tensile Modulus (MPa) 
                 5428.13 
                 16888.80 
                 12233.10 
                 9147.70 
                 12280.60 
               
               
                 Tensile Stress @ Yld (MPa) 
                 45.22 
                 51.00 
                 30.60 
                 37.10 
                 46.50 
               
               
                 Tensile Stress @ Break (MPa) 
                 44.77 
                 51.70 
                 30.60 
                 37.10 
                 46.50 
               
               
                 Tensile Strain @ Break (%) 
                 1.64 
                 1.42 
                 0.71 
                 1.00 
                 1.18 
               
               
                 Flexural Modulus (MPa) 
                 7421.29 
                 8061.70 
                 4063.30 
                 3711.00 
                 7516.20 
               
               
                 Flexural Stress @ Break (MPa) 
                 75.40 
                 61.00 
                 43.40 
                 50.70 
                 11.10 
               
               
                 Impact Strength (ft-lb/in) 
                 0.43 
                 0.25 
                 0.24 
                 0.29 
                 0.44 
               
               
                 Density 
                 2.1533 
                 1.5703 
                 1.6057 
                 1.6542 
                 1.6120 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 5 
               
             
            
               
                   
               
               
                 Experiments - Formulation and Test Results - 11 through 13 
               
            
           
           
               
               
            
               
                 Thermally Conductive + 
                 EXPERIMENT # 
               
            
           
           
               
               
               
               
            
               
                 Electrically Insulative 
                 11 
                 12 
                 13 
               
               
                   
               
            
           
           
               
               
               
               
            
               
                 MATERIALS 
                   
                   
                   
               
               
                 Makrolon 2408 
                 21.57 
                 — 
                 — 
               
               
                 Powder PC Teijin 1225 WX 
                 — 
                 34.50 
                 — 
               
               
                 Petrothane NA870252 LDPE 
                 — 
                 — 
                 48.70 
               
               
                 Lotader 8900 
                 3.16 
                 2.00 
                 — 
               
               
                 Fusabond E MB-226DE 
                 — 
                 — 
                 5.00 
               
               
                 CBT 100 
                 1.83 
                 5.00 
                 — 
               
               
                 HDPE 511051 
                 0.92 
                 3.00 
                 — 
               
               
                 Geniplast Pellet S 
                 0.56 
                 — 
                 1.00 
               
               
                 Kenrich Capow L38/H 
                 — 
                 0.50 
                 — 
               
               
                 Ethanox 310 
                 — 
                 — 
                 0.15 
               
               
                 Sunox 626 
                 — 
                 — 
                 0.15 
               
               
                 Duralum Special White 
                 71.96 
                 — 
                 — 
               
               
                 Al2O3 180 
               
               
                 PolarTherm 110 
                 — 
                 — 
                 15.00 
               
               
                 PTX 60 
                 — 
                 35.00 
                 — 
               
               
                 GFG 200 
                 — 
                 20.00 
                 10.00 
               
               
                 ZoChem 103 
                 — 
                 — 
                 20.00 
               
               
                 Total 
                 100 
                 100 
                 100 
               
               
                 PROPERTIES 
               
               
                 Thermal Conductivity 
                 1.825 
                 2.266 
                 1.537 
               
               
                 (W/mK) 
               
               
                 Surface Resistance 
                 9.70E+13 
                 1.40E+11 
                 1.50E+11 
               
               
                 Plaque(ohms/sq) 
               
               
                 Tensile Modulus (MPa) 
                 4838.00 
                 3906.00 
                 1206.80 
               
               
                 Tensile Stress @ 
                 17.33 
                 28.30 
                 13.80 
               
               
                 Yld (MPa) 
               
               
                 Tensile Stress @ 
                 17.30 
                 27.70 
                 13.70 
               
               
                 Break (MPa) 
               
               
                 Tensile Strain @ 
                 1.55 
                 2.00 
                 6.65 
               
               
                 Break (%) 
               
               
                 Flexural Modulus (MPa) 
                 6339.47 
                 9251.20 
                 989.10 
               
               
                 Flexural Stress @ 
                 36.04 
                 38.80 
                 18.00 
               
               
                 Break (MPa) 
               
               
                 Impact Strength 
                 0.32 
                 0.31 
                 1.44 
               
               
                 (ft-lb/in) 
               
               
                 Density 
                 2.3277 
                 1.5227 
                 1.3433 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 6 
               
             
            
               
                   
               
               
                 Experiments - Formulation and Test Results - 14 through 18 
               
            
           
           
               
               
            
               
                 Thermally Conductive + 
                 EXPERIMENT # 
               
            
           
           
               
               
               
               
               
               
            
               
                 Electrically Conductive 
                 14 
                 15 
                 16 
                 17 
                 18 
               
               
                   
               
            
           
           
               
               
               
               
               
               
            
               
                 MATERIALS 
                   
                   
                   
                   
                   
               
               
                 Vectra E950 LCP 
                 53.50 
                 — 
                 — 
                 — 
                 — 
               
               
                 Hival PP 2420 
                 — 
                 50.00 
                 50.00 
                 — 
                 — 
               
               
                 Ultramid A34 
                 — 
                 — 
                 — 
                 56.00 
                 24.00 
               
               
                 LLDPE HIFOR GT4157 
                 1.00 
                 — 
                 — 
                 — 
                 — 
               
               
                 Cycolac MG94 
                 — 
                 — 
                 — 
                 — 
                 5.00 
               
               
                 Bondyram 6000 
                 — 
                 — 
                 — 
                 — 
                 5.00 
               
               
                 Genioplast Pellet S 
                 — 
                 — 
                 — 
                 — 
                 0.50 
               
               
                 Ninor (PSNYL) 
                 — 
                 — 
                 — 
                 — 
                 0.50 
               
               
                 Fusabond 493 
                 — 
                 — 
                 — 
                 2.00 
                 — 
               
               
                 Uniplex 214 
                 — 
                 — 
                 — 
                 1.50 
                 — 
               
               
                 ZN Stearate 
                 — 
                 — 
                 — 
                 0.30 
                 — 
               
               
                 Irganox B1171 
                 — 
                 — 
                 — 
                 0.20 
                 — 
               
               
                 Duralum Special White Al2O3 180 
                 — 
                 — 
                 — 
                 — 
                 15.00 
               
               
                 Graphite 958M 
                 — 
                 50.00 
                 — 
                 — 
                 — 
               
               
                 Superior 8224 Graphite 
                 10.00 
                 — 
                 50.00 
                 — 
                 — 
               
               
                 Tenax C493 
                 10.00 
                 — 
                 — 
                 — 
                 — 
               
               
                 ZoChem 103 
                 25.00 
                 — 
                 — 
                 — 
                 45.00 
               
               
                 GFG 200 
                 — 
                 — 
                 — 
                 — 
                 5.00 
               
               
                 xGnP-M-15 
                 — 
                 — 
                 — 
                 40.00 
                 — 
               
               
                 Graphistrength C100 
                 0.50 
                 — 
                 — 
                 — 
                 — 
               
               
                 Total 
                 100 
                 100 
                 100 
                 100 
                 100 
               
               
                 PROPERTIES 
               
               
                 Thermal Conductivity (W/mK) 
                 1.853 
                 1.150 
                 1.195 
                 2.410 
                 1.435 
               
               
                 Surface Resistance Plaque(ohms/sq) 
                 4.60E+02 
                 1.50E+06 
                 8.80E+02 
                 1.50E+04 
                 2.00E+06 
               
               
                 Tensile Modulus (MPa) 
                 9312.70 
                 3854.06 
                 6671.01 
                 6139.14 
                 6683.47 
               
               
                 Tensile Stress @ Yld (MPa) 
                 57.50 
                 27.60 
                 34.61 
                 33.41 
                 45.40 
               
               
                 Tensile Stress @ Break (MPa) 
                 56.50 
                 26.45 
                 34.26 
                 33.38 
                 45.36 
               
               
                 Tensile Strain @ Break (%) 
                 1.71 
                 2.11 
                 1.68 
                 2.63 
                 2.08 
               
               
                 Flexural Modulus (MPa) 
                 7399.90 
                 4325.92 
                 8131.98 
                 8230.54 
                 8596.17 
               
               
                 Flexural Stress @ Break (MPa) 
                 104.70 
                 50.24 
                 55.87 
                 57.33 
                 70.24 
               
               
                 Impact Strength (ft-lb/in) 
                 0.70 
                 0.31 
                 0.46 
                 0.18 
                 0.47 
               
               
                 Density 
                 1.8083. 
                 1.2690 
                 1.2740 
                 1.3427 
                 2.1525 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 7 
               
             
            
               
                   
               
               
                 Experiments - Formulation and Test Results - 19 through 23 
               
            
           
           
               
               
            
               
                 Thermally Conductive + 
                 EXPERIMENT # 
               
            
           
           
               
               
               
               
               
               
            
               
                 Electrically Conductive 
                 19 
                 20 
                 21 
                 22 
                 23 
               
               
                   
               
            
           
           
               
               
               
               
               
               
            
               
                 MATERIALS 
                   
                   
                   
                   
                   
               
               
                 Fortran 0205 PPS 
                 48.70 
                 48.00 
                 — 
                 — 
                 — 
               
               
                 Makrolon 2408 
                 — 
                 — 
                 14.99 
                 35.20 
                 39.00 
               
               
                 Lotader 8900 
                 2.00 
                 2.00 
                 2.19 
                 3.00 
                 5.00 
               
               
                 Genioplast Pellet S 
                 1.00 
                 — 
                 0.39 
                 0.50 
                 1.00 
               
               
                 CBT 500 
                 — 
                 — 
                 — 
                 — 
                 3.00 
               
               
                 CBT 100 
                 3.00 
                 — 
                 1.27 
                 1.00 
                 — 
               
               
                 Ethanox 310 
                 0.15 
                 — 
                 — 
                 0.15 
                 — 
               
               
                 Sunox 626 
                 0.15 
                 — 
                 — 
                 0.15 
                 — 
               
               
                 HDPE 511051 
                 — 
                 — 
                 0.64 
                 — 
                 2.00 
               
               
                 Superior 8224 Graphite 
                 — 
                 50.00 
                 — 
                 — 
                 — 
               
               
                 Superior 2025 Graphite 
                 30.00 
                 — 
                 — 
                 — 
                 — 
               
               
                 GFG 200 
                 15.00 
                 — 
                 — 
                 10.00 
                 20.00 
               
               
                 Duralum Special White Al2O3 180 
                 — 
                 — 
                 — 
                 40.00 
                 — 
               
               
                 Zircocem-1 
                 — 
                 — 
                 — 
                 10.00 
                 — 
               
               
                 500RL Copper Fibers 
                 — 
                 — 
                 80.52 
                 — 
                 30.00 
               
               
                 Total 
                 100 
                 100 
                 100 
                 100 
                 100 
               
               
                 PROPERTIES 
               
               
                 Thermal Conductivity (W/mK) 
                 1.526 
                 1.366 
                 1.708 
                 1.784 
                 1.709 
               
               
                 Surface Resistance Plaque(ohms/sq) 
                 6.40E+05 
                 3.40E+04 
                 1.80E+08 
                 3.20E+06 
                 2.00E+05 
               
               
                 Tensile Modulus (MPa) 
                 10167.70 
                 7548.00 
                 3012.20 
                 5404.74 
                 4543.35 
               
               
                 Tensile Stress @ Yld (MPa) 
                 46.40 
                 64.30 
                 21.29 
                 32.02 
                 25.14 
               
               
                 Tensile Stress @ Break (MPa) 
                 46.30 
                 64.40 
                 21.28 
                 32.01 
                 26.93 
               
               
                 Tensile Strain @ Break (%) 
                 1.20 
                 2.30 
                 2.60 
                 2.00 
                 2.13 
               
               
                 Flexural Modulus (MPa) 
                 12058.80 
                 9794.40 
                 3763.08 
                 7389.80 
                 6689.23 
               
               
                 Flexural Stress @ Break (MPa) 
                 69.20 
                 96.40 
                 45.79 
                 53.32 
                 51.69 
               
               
                 Impact Strength (ft-lb/in) 
                 0.40 
                 0.48 
                 0.76 
                 0.74 
                 0.78 
               
               
                 Density 
                 1.5317 
                 1.7407 
                 3.7960 
                 1.9210 
                 1.7023 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 8 
               
             
            
               
                   
               
               
                 Experiments - Formulation and Test Results - 24 through 24 
               
            
           
           
               
               
               
               
            
               
                   
                 Thermally Conductive + 
                 EXPERIMENT # 
                   
               
            
           
           
               
               
               
               
            
               
                   
                 Electrically Conductive 
                 24 
                 25 
               
               
                   
                   
               
            
           
           
               
               
               
               
            
               
                   
                 MATERIALS 
                   
                   
               
               
                   
                 Stanyl TW341 
                 42.00 
                 — 
               
               
                   
                 PC/ABS FR2 7001 
                 — 
                 44.70 
               
               
                   
                 CBT500 
                 — 
                 5.00 
               
               
                   
                 CBT100 
                 2.00 
                 — 
               
               
                   
                 Fusabond 493 
                 5.00 
                 — 
               
               
                   
                 Genioplast Pellet S 
                 1.00 
                 — 
               
               
                   
                 Lotader 8900 
                 — 
                 3.00 
               
               
                   
                 HDPE 511051 
                 — 
                 2.00 
               
               
                   
                 Ethanox 310 
                 — 
                 0.15 
               
               
                   
                 Sunox 626 
                 — 
                 0.15 
               
               
                   
                 PTX 60 
                 30.00 
                 — 
               
               
                   
                 GFG 200 
                 20.00 
                 10.00 
               
               
                   
                 ZoChem 103 
                 — 
                 34.50 
               
               
                   
                 Graphistrength C100 
                 — 
                 0.50 
               
               
                   
                 Total 
                 100 
                 100 
               
               
                   
                 PROPERTIES 
               
               
                   
                 Thermal Conductivity (W/mK) 
                 2.567 
                 1.517 
               
               
                   
                 Surface Resistance Plaque(ohms/sq) 
                 9.50E+05 
                 4.30E+05 
               
               
                   
                 Tensile Modulus (MPa) 
                 4594.70 
                 4869.90 
               
               
                   
                 Tensile Stress @ Yld (MPa) 
                 20.60 
                 34.80 
               
               
                   
                 Tensile Stress @ Break (MPa) 
                 20.60 
                 32.60 
               
               
                   
                 Tensile Strain @ Break (%) 
                 1.11 
                 1.44 
               
               
                   
                 Flexural Modulus (MPa) 
                 3305.80 
                 3683.60 
               
               
                   
                 Flexural Stress @ Break (MPa) 
                 36.10 
                 57.10 
               
               
                   
                 Impact Strength (ft-lb/in) 
                 0.23 
                 0.36 
               
               
                   
                 Density 
                 1.4230 
                 1.7200 
               
               
                   
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 9 
               
             
            
               
                   
               
               
                 Experiments - Formulation and Test Results - 26 through 30 
               
            
           
           
               
               
            
               
                 Thermally Conductive + 
                 EXPERIMENT # 
               
            
           
           
               
               
               
               
               
               
            
               
                 Flame Retardant 
                 26 
                 27 
                 28 
                 29 
                 30 
               
               
                   
               
            
           
           
               
               
               
               
               
               
            
               
                 MATERIALS 
                   
                   
                   
                   
                   
               
               
                 Ultramid A34 
                 35.00 
                 37.75 
                 35.00 
                 35.00 
                 — 
               
               
                 Vectra A950 LCP 
                 — 
                 — 
                 — 
                 — 
                 45.00 
               
               
                 HDPE 511051 
                 1.00 
                 1.00 
                 1.00 
                 1.00 
                 — 
               
               
                 LLDPE HIFOR GT4157 
                 — 
                 — 
                 — 
                 — 
                 5.00 
               
               
                 Fusabond 493 
                 2.00 
                 2.00 
                 2.00 
                 2.00 
                 — 
               
               
                 PTFE L-5F 
                 1.00 
                 1.00 
                 1.00 
                 1.00 
                 — 
               
               
                 Ninor (PSNYL) 
                 0.50 
                 0.50 
                 0.50 
                 0.50 
                 — 
               
               
                 Genioplast Pellet S 
                 0.50 
                 0.50 
                 0.50 
                 0.50 
                 — 
               
               
                 Uniplex 214 
                 — 
                 0.25 
                 — 
                 — 
                 — 
               
               
                 DE-83R 
                 — 
                 — 
                 — 
                 8.00 
                 — 
               
               
                 Saytex 120 
                 8.00 
                 — 
                 — 
                 — 
                 — 
               
               
                 Perkalite FR100 
                 — 
                 10.00 
                 — 
                 — 
                 — 
               
               
                 Exolit OP1230 
                 — 
                 — 
                 10.00 
                 — 
                 — 
               
               
                 Melapur 200 
                 — 
                 3.00 
                 — 
                 — 
                 — 
               
               
                 Antimony Trioxide 
                 2.00 
                 2.00 
                 — 
                 2.00 
                 — 
               
               
                 Superior 8224 Graphite 
                 — 
                 — 
                 — 
                 — 
                 50.00 
               
               
                 Cool Flow CF400 
                 — 
                 — 
                 10.00 
                 — 
                 — 
               
               
                 ZoChem 103 
                 50.00 
                 42.00 
                 40.00 
                 50.00 
                 — 
               
               
                 Total 
                 100 
                 100 
                 100 
                 100 
                 100 
               
               
                 PROPERTIES 
               
               
                 Thermal Conductivity (W/mK) 
                   
                 1.184 
                 1.440 
                   
                 1.366 
               
               
                 Surface Resistance Plaque(ohms/sq) 
                   
                 2.00E+12 
                 2.80E+12 
                   
                 1.80E+02 
               
               
                 Flammability Rating (UL-94) 
                 V = 0 
                 Not FR 
                 V = 0 
                 NR 
                 NR 
               
               
                 Tensile Modulus (MPa) 
                 3885.79 
                 3310.71 
                 5466.54 
                 3195.85 
                 9288.90 
               
               
                 Tensile Stress @ Yld (MPa) 
                 44.98 
                 42.51 
                 44.01 
                 14.06 
                 91.40 
               
               
                 Tensile Stress @ Break (MPa) 
                 43.56 
                 43.19 
                 42.94 
                 14.04 
                 82.30 
               
               
                 Tensile Strain @ Break (%) 
                 1.78 
                 2.24 
                 1.80 
                 0.75 
                 4.18 
               
               
                 Flexural Modulus (MPa) 
                 4536.82 
                 3985.43 
                 6318.09 
                 4492.82 
                 7439.40 
               
               
                 Flexural Stress @ Break (MPa) 
                 89.69 
                 79.27 
                 72.64 
                 46.47 
                 93.60 
               
               
                 Impact Strength (ft-lb/in) 
                 0.52 
                 0.78 
                 0.63 
                 — 
                 1.27 
               
               
                 Density 
                 2.0607 
                 1.8847 
                 1.8230 
                 1.9517 
                 1.6183 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 10 
               
             
            
               
                   
               
               
                 Experiments - Formulation and Test Results - 31 through 34 
               
            
           
           
               
               
            
               
                 Thermally Conductive + 
                 EXPERIMENT # 
               
            
           
           
               
               
               
               
               
            
               
                 Flame Retardant 
                 31 
                 32 
                 33 
                 34 
               
               
                   
               
            
           
           
               
               
               
               
               
            
               
                 MATERIALS 
                   
                   
                   
                   
               
               
                 Vectra E950 LCP 
                 44.00 
                 — 
                 — 
                 — 
               
               
                 Fortran 0205 PPS 
                 — 
                 42.00 
                 42.00 
                 42.00 
               
               
                 Fusabond 493 
                 5.00 
                 — 
                 — 
                 — 
               
               
                 HDPE 511051 
                 — 
                 3.00 
                 3.00 
                 3.00 
               
               
                 CBT 100 
                 — 
                 2.00 
                 2.00 
                 2.00 
               
               
                 Lotader 8900 
                 — 
                 2.00 
                 2.00 
                 2.00 
               
               
                 Genioplast Pellet S 
                 1.00 
                 1.00 
                 1.00 
                 1.00 
               
               
                 Cool Flow CF300 
                 — 
                 — 
                 30.00 
                 — 
               
               
                 PTX60 
                 30.00 
                 30.00 
                 — 
                 30.00 
               
               
                 GFG 200 
                 20.00 
                 20.00 
                 20.00 
                 — 
               
               
                 xGnP-M-25 
                 — 
                 — 
                 — 
                 20.00 
               
               
                 Total 
                 100 
                 100 
                 100 
                 100 
               
               
                 PROPERTIES 
               
               
                 Thermal Conductivity (W/mK) 
                 2.360 
                 1.780 
                 1.813 
                 1.570 
               
               
                 Surface Resistance Plaque(ohms/sq) 
                 2.60E+04 
                 2.50E+11 
                 1.90E+11 
                 2.60E+11 
               
               
                 Flammability Rating (UL-94) 
                 — 
                 — 
                 — 
                 — 
               
               
                 Tensile Modulus (MPa) 
                 6665.70 
                 12776.70 
                 10385.10 
                 8356.70 
               
               
                 Tensile Stress @ Yld (MPa) 
                 15.90 
                 30.50 
                 26.00 
                 32.30 
               
               
                 Tensile Stress @ Break (MPa) 
                 15.90 
                 24.50 
                 28.30 
                 33.00 
               
               
                 Tensile Strain @ Break (%) 
                 0.58 
                 1.48 
                 0.66 
                 0.86 
               
               
                 Flexural Modulus (MPa) 
                 5110.70 
                 3232.10 
                 4387.80 
                 3653.50 
               
               
                 Flexural Stress @ Break (MPa) 
                 30.50 
                 42.80 
                 44.70 
                 35.00 
               
               
                 Impact Strength (ft-lb/in) 
                 0.26 
                 0.24 
                 0.24 
                 0.24 
               
               
                 Density 
                 1.5540 
                 1.5747 
                 1.6140 
                 1.5177 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 11 
               
             
            
               
                   
               
               
                 Experiments - Formulation and Test Results - 35 through 39 
               
            
           
           
               
               
            
               
                 Thermally Conductive + 
                 EXPERIMENT # 
               
            
           
           
               
               
               
               
               
               
            
               
                 Whiteness Stability 
                 35 
                 36 
                 37 
                 38 
                 39 
               
               
                   
               
            
           
           
               
               
               
               
               
               
            
               
                 MATERIALS 
                   
                   
                   
                   
                   
               
               
                 Vestamid Htplus M3000 
                 41.60 
                 — 
                 33.50 
                 38.50 
                 44.20 
               
               
                 Ultramid A34 
                 — 
                 — 
                 10.00 
                 — 
                 — 
               
               
                 Amodel A-1006 
                 — 
                 42.20 
                 — 
                 — 
                 — 
               
               
                 Kraton 1901G 
                 — 
                 — 
                 2.00 
                 — 
                 — 
               
               
                 HDPE 511051 
                 — 
                 — 
                 1.00 
                 — 
                 — 
               
               
                 Genioplast Pellet S 
                 — 
                 — 
                 1.00 
                 — 
                 — 
               
               
                 Lotader 4700 
                 — 
                 2.00 
                 — 
                 — 
                 — 
               
               
                 Norac Calcium Stearate 
                 — 
                 0.50 
                 — 
                 — 
                 — 
               
               
                 Benetex OB-1 
                 — 
                 — 
                 0.10 
                 0.10 
                 — 
               
               
                 Polymist F284 
                 2.00 
                 — 
                 1.00 
                 5.00 
                 — 
               
               
                 Irganox 1098 
                 0.20 
                 0.15 
                 — 
                 0.20 
                 0.35 
               
               
                 Irgafos 168 
                 0.20 
                 0.15 
                 — 
                 0.20 
                 0.35 
               
               
                 Nylostab S-EED Pdr 
                 1.00 
                 — 
                 1.00 
                 1.00 
                 — 
               
               
                 Tipure R104 
                 — 
                 5.00 
                 — 
                 — 
                 — 
               
               
                 Weston TNPP 
                 — 
                 — 
                 0.40 
                 — 
                 — 
               
               
                 ZoChem 103 
                 55.00 
                 35.00 
                 50.00 
                 55.00 
                 55.00 
               
               
                 Cool Flow CF400 
                 — 
                 15.00 
                 — 
                 — 
                 — 
               
               
                 Total 
                 100 
                 100 
                 100 
                 100 
                 100 
               
               
                 PROPERTIES 
               
               
                 Thermal Conductivity (W/mK) 
                 1.52 
                 1.80 
                 1.390 
                 1.591 
                 1.53 
               
               
                 Surface Resistance Plaque(ohms/sq) 
                 — 
                 — 
                 3.70E+12 
                 2.70E+12 
                 4.00E+12 
               
               
                 Whiteness Index before heat aging 
                 54.44 
                 65.87 
                 77.31 
                 87.16 
                 66.28 
               
               
                 Tensile Modulus (MPa) 
                 3491.29 
                 5491.81 
                 3382.05 
                 — 
                 3737.52 
               
               
                 Tensile Stress @ Yld (MPa) 
                 29.56 
                 44.71 
                 30.12 
                 — 
                 20.92 
               
               
                 Tensile Stress @ Break (MPa) 
                 29.52 
                 54.46 
                 26.22 
                 — 
                 18.73 
               
               
                 Tensile Strain @ Break (%) 
                 1.22 
                 2.11 
                 1.12 
                 — 
                 0.78 
               
               
                 Flexural Modulus (MPa) 
                 4043.36 
                 6836.55 
                 3768.66 
                 — 
                 4146.80 
               
               
                 Flexural Stress @ Break (MPa) 
                 78.11 
                 102.24 
                 83.65 
                 — 
                 81.68 
               
               
                 Impact Strength (ft-lb/in) 
                 0.47 
                 0.63 
                 0.53 
                 — 
                 0.41 
               
               
                 Density 
                 1.9463 
                 1.8993 
                 1.8533 
                 2.0517 
                 1.9757 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 12 
               
             
            
               
                   
               
               
                 Experiments - Formulation and Test Results - 40 through 45 
               
            
           
           
               
               
               
               
               
               
               
            
               
                   
                 40 
                 41 
                 42 
                 43 
                 44 
                 45 
               
               
                   
                   
               
            
           
           
               
               
               
               
               
               
               
            
               
                 MATERIALS 
                   
                   
                   
                   
                   
                   
               
               
                 Fusabond 493 
                 2.00 
                 2.20 
                 1.80 
                 — 
                 3.89 
                 3.3 
               
               
                 Ultramid A34 
                 34.75 
                 31.08 
                 21.20 
                 — 
                 29.82 
                 26.4 
               
               
                 PTFE L-5F 
                 1.00 
                 0.55 
                 0.40 
                 — 
                 — 
                 — 
               
               
                 Uniplex 214 
                 0.25 
                 0.28 
                 0.20 
                 — 
                 0.21 
                 0.2 
               
               
                 HDPE 511051 
                 1.00 
                 1.10 
                 0.80 
                 1.75 
                 1.84 
                 2.8 
               
               
                 Genioplast Pellet S 
                 0.50 
                 0.28 
                 0.20 
                 1.75 
                 0.71 
                 0.7 
               
               
                 Ninor (PSNYL) 
                 0.50 
                 0.28 
                 0.20 
                 — 
                 — 
                 — 
               
               
                 Exolit OP 1230 
                 18.00 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 Saytex 120 
                 — 
                 13.75 
                 11.20 
                 — 
                 — 
                 — 
               
               
                 Al Oxide 
                 — 
                 — 
                 15.00 
                 — 
                 — 
                 12 
               
               
                 Antimony Trioxide 
                 — 
                 5.50 
                 4.00 
                 — 
                 2.52 
                 2.4 
               
               
                 GFG 200/500 
                 — 
                 — 
                 3.00 
                 13.50 
                 6 
                 — 
               
               
                 Lotader 8900 
                 — 
                 — 
                 — 
                 3.50 
                 — 
                 — 
               
               
                 PPS 
                 — 
                 — 
                 — 
                 50.33 
                 — 
                 — 
               
               
                 Ethanox 310 
                 — 
                 — 
                 — 
                 0.10 
                 0.205 
                 0.1 
               
               
                 Sunox 626 
                 — 
                 — 
                 — 
                 0.10 
                 0.205 
                 0.1 
               
               
                 8224 or 2025 
                 — 
                 — 
                 — 
                 18.75 
                 32 
                 — 
               
               
                 ZoChem 103 
                 42.00 
                 45.00 
                 42.00 
                 — 
                 10 
                 40 
               
               
                 CNT C100 
                 — 
                 — 
                 — 
                 3.20 
                 — 
                 — 
               
               
                 Sigrafil C30 
                 — 
                 — 
                 — 
                 7.00 
                 — 
                 — 
               
               
                 Saytex 8010 
                 — 
                 — 
                 — 
                 — 
                 12.6 
                 12 
               
               
                 Total 
                 100 
                 100 
                 100 
                 100 
                 100 
                 100 
               
               
                 PROPERTIES 
               
               
                 Thermal Conductivity (W/mK) 
                 1.4203 
                 1.0813 
                 2.3917 
                 1.7364 
                 2.579 
                 1.228 
               
               
                 Surface Resistance Plaque(ohms/sq) 
                 6.20E+11 
                 1.70E+13 
                 4.50E+10 
                 1.60E+03 
                 1.50E+05 
                 3.70E+12 
               
               
                 Flammability Rating (UL-94) @3.2 mm thickness 
                 V0 
                 V0 
                 V0 
                 V0 
                 V2 
                 V0 
               
               
                 Tensile Modulus (MPa) 
                 3160.67 
                 3912.29 
                 5073.63 
                 10488.44 
                 6564.05 
                 3978.19 
               
               
                 Tensile Stress @ Yld (MPa) 
                 30.46 
                 46.18 
                 30.54 
                 43.36 
                 35.88 
                 43.32 
               
               
                 Tensile Stress @ Break (MPa) 
                 28.96 
                 46.52 
                 32.1 
                 43.36 
                 35.79 
                 43.31 
               
               
                 Tensile Strain @ Break (%) 
                 2.8 
                 1.89 
                 1.28 
                 1.26 
                 1.29 
                 1.9 
               
               
                 Flexural Modulus (MPa) 
                 3505.25 
                 4539.3 
                 5266.43 
                 17364.7 
                 8073.38 
                 4543.2 
               
               
                 Flexural Stress @ Break (MPa) 
                 59.47 
                 77.25 
                 54.87 
                 106.44 
                 58.28 
                 73.8 
               
               
                 Impact Strength (ft-lb/in) 
                 0.51 
                 0.69 
                 0.46 
                 0.51 
                 0.53 
                 0.47 
               
               
                 Density 
                 1.7587 
                 2.0427 
                 2.338 
                 1.517 
                 1.7357 
                 2.152 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 13 
               
             
            
               
                   
               
               
                 Experiments - Formulations and Test Results - 46 through 51 
               
            
           
           
               
               
            
               
                   
                 EXPERIMENT # 
               
            
           
           
               
               
               
               
               
               
               
            
               
                 Thermally Conductive 
                 46 
                 47 
                 48 
                 49 
                 50 
                 51 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
            
               
                 MATERIALS 
                   
                   
                   
                   
                   
                   
               
               
                 Vixtrex 450P 
                 49.7 
               
               
                 PTX 60 
                 30 
               
               
                 BN-PT 110 
                 20 
                   
                   
                 35 
                 35 
                 40 
               
               
                 ELC 626 
                 0.15 
               
               
                 ELC 1010 (Antioxidant) 
                 0.15 
                   
                   
                 0.15 
                 0.15 
                 0.15 
               
               
                 Hyprez MA Diamond PDR 
                   
                 50 
               
               
                 Powder PC Tejin 1225 WX 
                   
                 44 
               
               
                 HDPE 
                   
                 2 
                 3 
               
               
                 CBT 100 
                   
                 3 
                 5 
               
               
                 PT 110 
                   
                   
                 40.5 
               
               
                 Zhutrex ETPE 60D 
                   
                   
                 49.5 
               
               
                 Makralon 
                   
                   
                   
                   
                   
                 5 
               
               
                 Victrex 
                   
                   
                   
                 64.7 
                 64.7 
               
               
                 Ultranox 626 
                   
                   
                   
                 0.15 
                 0.15 
                 0.15 
               
               
                 Gafone 3300 
                   
                   
                   
                   
                   
                 54.7 
               
               
                 Lotader 8900 
                   
                 1 
                 2 
                   
                   
                   
               
               
                 Total 
                 100 
                 100 
                 100 
                 100 
                 100 
                 100 
               
               
                 PROPERTIES 
               
               
                 Thermal Conductivity (W/mK) 
                 2.20 
                 1.86 
                 1.65 
                 1.38 
                 1.40 
                 1.45 
               
               
                 Tensile Modulus (MPa) 
                 — 
                 — 
                 — 
                 6587.7 
                 6252.1 
                 — 
               
               
                 Tensile Stress @ Yld (MPa) 
                 — 
                 — 
                 — 
                 71.3 
                 75.5 
                 — 
               
               
                 Tensile Stress @ Break (MPa) 
                 — 
                 — 
                 — 
                 71.3 
                 75.5 
                 — 
               
               
                 Tensile Strain @ Break (%) 
                 — 
                 — 
                 — 
                 2.43 
                 2.96 
                 — 
               
               
                 Flexural Modulus (MPa) 
                 — 
                 — 
                 — 
                 7530.6 
                 7054.9 
                 — 
               
               
                 Flexural Stress @ Break (MPa) 
                 — 
                 — 
                 — 
                 122.7 
                 138.2 
                 — 
               
               
                 Impact Strength (ft-lb/in) 
                 — 
                 — 
                 — 
                 0.59 
                 0.67 
                 — 
               
               
                 Density 
                 — 
                 — 
                 — 
                 1.5297 
                 1.5212 
                 1.4595 
               
               
                   
               
            
           
         
       
     
     While certain representative embodiments and details have been shown for the purpose of illustrating the subject invention, it will be apparent to those skilled in this art that various changes and modifications can be made therein without departing from the scope of the subject invention.