Patent Publication Number: US-2007123619-A1

Title: Method to produce reinforced halobutyl elastomer compounds

Description:
This application claims the benefit of Provisional Application No. 60/733,412 filed Nov. 4, 2005. 
    
    
     FIELD OF THE INVENTION  
      The present invention relates to halobutyl elastomer compounds containing a butyl elastomer, at least one additional elastomer, a mineral filler and a mixed modifier system of a silane compound and an additive derived from a compound containing at least one hydroxyl group and a functional group containing a basic amine.  
      The present invention also relates to a process of preparing a reinforced elastomer including admixing a halobutyl elastomer, at least one additional elastomer, a mineral filler and a mixed modifier system of a silane compound and an additive derived from a compound containing at least one hydroxyl group and a functional group containing a basic amine.  
     BACKGROUND OF THE INVENTION  
      Butyl rubber (IIR), a random copolymer of isobutylene and isoprene is well known for its excellent thermal stability, ozone resistance and desirable dampening characteristics. IIR is prepared commercially in a slurry process using methyl chloride as a vehicle and a Friedel-Crafts catalyst as the polymerization initiator. The methyl chloride offers the advantage that AlCl 3 , a relatively inexpensive Friedel-Crafts catalyst, is soluble in it, as are the isobutylene and isoprene comonomers. Additionally, the butyl rubber polymer is insoluble in the methyl chloride and precipitates out of solution as fine particles. The polymerization is generally carried out at temperatures of about −90° C. to −100° C. See U.S. Pat. No. 2,356,128 and  Ullmanns Encyclopedia of Industrial Chemistry , volume A 23,1993, pages 288-295. The low polymerization temperatures are required in order to achieve molecular weights which are sufficiently high for rubber applications.  
      The first major application of IIR was in tire inner tubes. Despite the low levels of backbone unsaturation (ca. 0.8-1.8 mol %), IIR possesses sufficient vulcanization activity for inner tube application. With the evolution of the tire inner liner, it became necessary to enhance the cure reactivity of IIR to levels typically found for conventional diene-based elastomers such as butadiene rubber (BR) or styrene-butadiene rubber (SBR). To this end, halogenated grades of butyl rubber were developed. The treatment of organic IIR solutions with elemental chlorine or bromine results in the isolation of halobutyl rubber (HIIR), such as chlorobutyl (CIIR) and bromobutyl (BIIR) rubber. These materials are marked by the presence of reactive allylic halides along the polymer main chain that permit co-vulcanization with other rubber compounds.  
      As automotive greenhouse gas emissions have come under increasing scrutiny, there has been a movement in the industry to reduce the weight and improve rolling resistance of tires. Since the tread is vulcanized to the tire carcass, a halobutyl rubber compound is preferred over nonhalogenated Butyls for its cure reactivity. Halobutyl rubber compounds used in tire treads desirably exhibit low rolling resistance and high abrasion resistance. Although it is possible to provide both of these in a hard rubber compound, this has a negative impact on traction. The preferred butyl-rubber containing compound for use in tires therefore exhibits a combination of dynamic properties including low rolling resistance, abrasion resistance at least equivalent to existing tread compounds, and wet traction characteristics. However, obtaining the desired properties has proven difficult in practice and no commercial halobutyl tread compounds currently exist.  
      It is known in the art that BIIR-based tread formulations prepared with the use of additives such as DMAE possess certain enhanced dynamic properties. Resendes, R; Hopkins, W; Niziolek, T; Braubach, W “Cost Effective Modifiers for the Preparation of BIIR Based Tire Tread Formulations.”  Rubber World, September,  2003, pp. 46-51. However, the use of silanes in conjunction with DMAE has been left largely unexplored and it is unclear whether or not a synergistic effect might exist that could provide the combination of dynamic properties desirable in tread formulations.  
     SUMMARY OF THE INVENTION  
      The present invention relates to filled halobutyl elastomers, such as bromobutyl elastomers (BIIR). Surprisingly it has been discovered that a synergistic effect occurs in halobutyl elastomer compounds when a mixed modifier is utilized during compounding which results in a compound having unexpected superior properties.  
      The present invention relates is to halobutyl elastomer compounds containing a butyl elastomer, at least one additional elastomer, a mineral filler and a mixed modifier system of a silane compound and an additive derived from a compound containing at least one hydroxyl group and a functional group containing a basic amine.  
      The present invention also relates to a process of preparing a reinforced elastomer including admixing a halobutyl elastomer, at least one additional elastomer, a mineral filler and a mixed modifier system of a silane compound and an additive derived from a compound containing at least one hydroxyl group and a functional group containing a basic amine. 
    
    
     BRIEF DESCRIPTION OF THE INVENTION  
       FIG. 1  illustrates the tan δ response versus temperature of filled butyl elastomer compounds.  
       FIG. 2  illustrates the tan δ response versus temperature of filled butyl elastomer compounds. 
    
    
     DETAILED DESCRIPTION OF THE INVENTION  
      The phrase “halobutyl elastomer(s)” as used herein refers to a chlorinated or brominated butyl elastomer. Brominated butyl elastomers are preferred, and the present invention is illustrated, by way of example, with reference to bromobutyl elastomers. It should be understood, however, that the present invention extends to the use of chlorinated butyl elastomers.  
      Halobutyl elastomers suitable for use in the present invention include, but are not limited to, brominated butyl elastomers. Such elastomers may be obtained by bromination of butyl rubber, which is a copolymer of an isoolefin, usually isobutylene and a co-monomer that is usually a C4 to C6 conjugated diolefin, preferably isoprene and brominated isobutene-isoprene-copolymers (BIIR). Co-monomers other than conjugated diolefins can be used, such as alkyl-substituted vinyl aromatic co-monomers which includes C1-C4-alkyl substituted styrene. An example of a halobutyl elastomer which is commercially available is brominated isobutylene methylstyrene copolymer (BIMS) in which the co-monomer is p-methylstyrene.  
      Brominated butyl elastomers typically contain in the range of from 0.1 to 10 weight percent, preferably 0.5 to 5 weight percent of repeating units derived from diolefin, preferably isoprene, and in the range of from 90 to 99.9 weight percent, preferably 95 to 99.5 weight percent of repeating units derived from isoolefin, preferably isobutylene, based upon the hydrocarbon content of the polymer, and in the range of from 0.1 to 9 weight percent, preferably 0.75 to 2.3 weight percent and more preferably from 0.75 to 2.3 weight percent bromine, based upon the bromobutyl polymer. A typical bromobutyl polymer has a molecular weight, expressed as the Mooney viscosity according to DIN 53 523 (ML 1+8 at 125° C.), in the range of from 25 to 60.  
      A stabilizer may be added to the brominated butyl elastomer. Suitable stabilizers include calcium stearate and epoxidized soy bean oil, preferably used in an amount in the range of from 0.5 to 5 parts by weight per 100 parts by weight of the brominated butyl rubber (phr).  
      Examples of suitable brominated butyl elastomers include Bayer Bromobutyl 2030, Bayer Bromobutyl 2040 (BB2040), and Bayer Bromobutyl X2 commercially available from Bayer Corporation. Bayer BB2040 has a Mooney viscosity (ML 1+8 @ 125° C.) of 39±4, a bromine content of 2.0±0.3 wt % and an approximate molecular weight of 500,000 grams per mole.  
      The brominated butyl elastomer used in the process of the present invention may also be a graft copolymer of a brominated butyl rubber and a polymer based upon a conjugated diolefin monomer. Co-pending Canadian Patent Application 2,279,085 is directed towards a process for preparing such graft copolymers by mixing solid brominated butyl rubber with a solid polymer based on a conjugated diolefin monomer which also includes some C—S—(S)n-C bonds, where n is an integer from 1 to 7, the mixing being carried out at a temperature greater than 50° C. and for a time sufficient to cause grafting. The bromobutyl elastomer of the graft copolymer can be any of those described above. The conjugated diolefins that can be incorporated in the graft copolymer generally have the structural formula:  
                 
 
 wherein R is a hydrogen atom or an alkyl group containing from 1 to 8 carbon atoms and wherein R1 and R11 can be the same or different and are selected from hydrogen atoms or alkyl groups containing from 1 to 4 carbon atoms. Suitable conjugated diolefins include 1,3-butadiene, isoprene, 2-methyl-1,3-pentadiene, 4-butyl-1,3-pentadiene, 2,3-dimethyl-1,3-pentadiene 1,3-hexadiene, 1,3-octadiene, 2,3-dibutyl-1,3-pentadiene, 2-ethyl-1,3-pentadiene, 2-ethyl-1,3-butadiene and the like. Conjugated diolefin monomers containing from 4 to 8 carbon atoms are preferred, 1,3-butadiene and isoprene being more preferred. 
 
      The polymer based on a conjugated diene monomer can be a homopolymer, or a copolymer of two or more conjugated diene monomers, or a copolymer with a vinyl aromatic monomer.  
      The vinyl aromatic monomers, which can optionally be used, should be copolymerizable with the conjugated diolefin monomers being employed. Generally, any vinyl aromatic monomer, which is known to polymerize with organo alkali metal initiators, can be used. Such vinyl aromatic monomers usually contain in the range of from 8 to 20 carbon atoms, preferably from 8 to 14 carbon atoms. Examples of suitable vinyl aromatic monomers include styrene, alpha-methyl styrene, various alkyl styrenes including p-methylstyrene, p-methoxy styrene, 1-vinylnaphthalene, 2-vinyl naphthalene, 4-vinyl toluene and the like. Styrene is preferred for copolymerization with 1,3-butadiene alone or for terpolymerization with both 1,3-butadiene and isoprene.  
      According to the present invention, the halobutyl elastomer is used in combination with another elastomer. Suitable elastomers include diene based elastomers such as BR, SBR and NR.  
      According to the present invention the halobutyl elastomer compound is reinforced with a filler. Suitable fillers according to the present invention are composed of particles of a mineral, suitable fillers include silica, silicates, clay (such as ventonite) gypsum, alumina, titanium dioxide, talc and the like, as well as mixtures thereof.  
      Further examples of suitable fillers include: 
          natural clays, such as montmorillonite and other naturally occurring clays;     organophilically modified clays such as organophilically modified montmorillonite clays (e.g. Cloisite® Nanoclays available from Southern Clay Products) and other organophilically modified naturally occurring clays;     highly disperse silicas, prepared e.g. by the precipitation of silicate solutions or the flame hydrolysis of silicon halides, with specific surface areas of 5 to 1000, preferably 20 to 400 m2/g (BET specific surface area), and with primary particle sizes of 10 to 400 nm; the silicas can optionally also be present as mixed oxides with other metal oxides such as Al, Mg, Ca, Ba, Zn, Zr and Ti;     synthetic silicates, such as aluminum silicate and alkaline earth metal silicate;     magnesium silicate or calcium silicate, with BET specific surface areas of 20 to 400 m 2 /g and primary particle diameters of 10 to 400 nm;     natural silicates, such as kaolin and other naturally occurring silica;     glass fibers and glass fiber products (mafting, extrudates) or glass microspheres;     metal oxides, such as zinc oxide, calcium oxide, magnesium oxide and aluminum oxide;     metal carbonates, such as magnesium carbonate, calcium carbonate and zinc carbonate;     metal hydroxides, e.g. aluminum hydroxide and magnesium hydroxide or combinations thereof.        

      Because these mineral particles have hydroxyl groups on their surface, rendering them hydrophilic and oleophobic, it is difficult to achieve good interaction between the filler particles and the butyl elastomer. For many purposes, the preferred mineral is silica, especially silica prepared by the carbon dioxide precipitation of sodium silicate.  
      Dried amorphous silica particles suitable for use as mineral fillers in accordance with the present invention have a mean agglomerate particle size in the range of from 1 to 100 microns, preferably between 10 and 50 microns and more preferably between 10 and 25 microns. It is preferred that less than 10 percent by volume of the agglomerate particles are below 5 microns or over 50 microns in size. A suitable amorphous dried silica has a BET surface area, measured in accordance with DIN (Deutsche Industrie Norm) 66131, of between 50 and 450 square meters per gram and a DBP absorption, as measured in accordance with DIN 53601, of between 150 and 400 grams per 100 grams of silica, and a drying loss, as measured according to DIN ISO 787/11, of from 0 to 10 percent by weight. Suitable silica fillers are commercially available under the trademarks HiSil 210, HiSil 233 and HiSil 243 available from PPG Industries Inc. Also suitable are Vulkasil S and Vulkasil N, commercially available from Bayer AG.  
      Mineral fillers can also be used in combination with known non-mineral fillers, such as 
          carbon blacks; suitable carbon blacks are preferably prepared by the lamp black, furnace black or gas black process and have BET specific surface areas of 20 to 200 m2/g, for example, SAF, ISAF, HAF, FEF or GPF carbon blacks; or     rubber gels, preferably those based on polybutadiene, butadiene/styrene copolymers, butadiene/acrylonitrile copolymers and polychloroprene.        

      Non-mineral fillers are not normally used as filler in the halobutyl elastomer compositions of the present invention, but in some embodiments they may be present in an amount up to 60 phr. It is preferred that the mineral filler should constitute at least 35% by weight of the total amount of filler. If the halobutyl elastomer composition of the present invention is blended with another elastomeric composition, that other composition may contain mineral and/or non-mineral fillers. The mixed modifier system of the present invention includes a silane compound. The silane compound useful in the mixed modifier of the present invention is preferably a sulfur-containing silane. The silane compound may be a sulfur-containing silane compound. Suitable sulfur-containing silanes include those described in U.S. Pat. No. 4,704,414, in published European patent application 0,670,347 A1 and in published German patent application 4435311 A1, which are all incorporated herein by reference. One suitable compound is a mixture of bis[3-(triethoxysilyl)propyl]-monosulfane, bis[3(triethoxysilyl)propyl]disulfane, bis[3-(triethoxysilyl)propyl]trisulfane and bis[3(triethoxysilyl)propyl]tetrasulfane and higher sulfane homologues available under the trademarks Si-69 (average sulfane 3.5), Silquest™ A-1589 (from CK Witco) or Si-75 (from Degussa) (average sulfane 2.0). Another example is bis[2-(triethoxysilyl)ethyl]-tetrasulfane, available under the trade-mark Silquest™ RC-2.  
      Examples of suitable sulfur-containing silanes include compounds of formula
 
R 7 R 8 R 9 SiR 10 
 
 in which at least one of R 7 , R 8  and R 9 , preferably two of R 7 , R 8  and R 9  and most preferably three of R 7 , R 8  and R 9 , are hydroxyl or hydrolysable groups. The groups R 7 , R 8  and R 9  are bound to the silicon atom. The group R 7  may be hydroxyl or OC p H 2p +1 where p is from 1 to 10 and the carbon chain may be interrupted by oxygen atoms, to give groups, for example of formula CH 3 OCH 2 O—, CH 3 OCH 2 OCH 2 O—, CH 3 (OCH 2 ) 4 O—, CH 3 OCH 2 CH 2 O—, C 2 H 5 OCH 2 O—, C 2 H 5 OCH 2 OCH 2 O—, or C 2 H 5 OCH 2 CH 2 O—. Alternatively, R 7  may be phenoxy. The group R 8  may be the same as R 7 . R 8  may also be a C 1-10  alkyl group, or a C 2-10  mono- or diunsaturated alkenyl group. Further, R 8  may be the same as the group R 10  described below. 
 
      R 9  may be the same as R 7 , but it is preferred that R 7 , R 8  and R 9  are not all hydroxyl. R 9  may also be C 1-10  alkyl, phenyl, C 2-10  mono-or diunsaturated alkenyl. Further, R 9  may be the same as the group R 10  described below.  
      The group R 10  attached to the silicon atom is such that it may participate in a crosslinking reaction with unsaturated polymers by contributing to the formation of crosslinks or by otherwise participating in crosslinking. R 10  may have the following structure:
 
-(alk) e (Ar) f S i (alk) g (Ar) h SiR 7 R 8 R 9 
 
 where R 7 , R 8  and R 9  are the same as previously defined, alk is a divalent straight hydrocarbon group having between 1 and 6 carbon atoms or a branched hydrocarbon group having between 2 and 6 carbon atoms, Ar is either a phenylene —C 6 H 4 —, biphenylene —C 6 H 4 —C 6 H 4 — or —C 6 H 4 —OC 6 H 4 -group and e, f, g and h are either 0, 1 or 2 and i is an integer from 2 to 8 inclusive with the provisos that the sum of e and f is always 1 or greater than 1 and that the sum of g and h is also always 1 or greater than 1. Alternately, R 10  may be represented by the structures (alk) e (Ar) f SH or (alk) e (Ar) f SCN where e and f are as defined previously. 
 
      Preferably, R 7 , R 8  and R 9  are all either OCH 3 , OC 2 H 5  or OC 3 H 8  groups and most preferably all are OCH 3  or OC 2 H 5  groups. In one embodiment, the sulfur-containing silane is bis[3-(trimethoxysilyl)propyl]-tetrasulfane (Si-168).  
      Non-limiting illustrative examples of other sulfur-containing silanes include the following:  
      3-octanoylthio-1-propyltriethoxysilane (Silane™ NXT)  
      bis[3-(triethoxysilyl)propyl]disulfane,  
      bis[2-(trimethoxysilyl)ethyl]tetrasulfane,  
      bis[2-(triethoxysilyl)ethyl]trisulfane,  
      bis[3-(trimethoxysilyl)propyl]disulfane,  
      3-mercaptopropyltrimethoxysilane,  
      3-mercaptopropylmethyidiethoxysilane, and  
      3-mercaptoethylpropylethoxymethoxysilane.  
      Other preferred sulfur-containing silanes include those disclosed in published German patent application 44 35 311 A1, (pages 2 and 3), which discloses oligomers and polymers of sulphur containing organooxysilanes of the general formula:  
                 
 
 in which R 11  is a saturated or unsaturated, branched or unbranched, substituted or unsubstituted hydrocarbon group that is at least trivalent and has from 2 to 20 carbon atoms, provided that there are at least two carbon-sulphur bonds, R 12  and R 13 , independently of each other, are saturated or unsaturated, branched or unbranched, substituted or unsubstituted hydrocarbon groups with 1 to 20 carbon atoms, halogen, hydroxy or hydrogen, n is 1 to 3, m is 1 to 1000, p is 1 to 5, q is 1 to 3 and x is 1 to 8. 
 
      Other sulfur-containing silanes are of the general formula  
                 
 
 wherein R 12 , m and x have the meanings given above, and R 12  is preferably methyl or ethyl. Particularly preferred sulfur-containing silanes are those of the following general formulae: 
 
(RO) 3 SiCH 2 CH 2 CH 2 —[S x —CH 2 —CH 2 ] n —S x —CH 2 CH 2 CH 2 Si(OR) 3 
 
 in which R=—CH 3  or —C 2 H 5 , x=1-6 and n=1-10;
 
(RO) 3 SiCH 2 CH 2 CH 2 —[S x —CH 2 CH(OH)—CH 2 ] n —S x —CH 2 CH 2 CH 2 Si(OR) 3 
 
 in which R=—CH 3  or —C 2 H 5 , x=1-6 and n=1-10;
 
(RO) 3 SiCH 2 CH 2 CH 2 —[S x —(CH 2 ) 6 ] n —S x —CH 2 CH 2 CH 2 —Si(OR) 3 
 
 in which R=—CH 3 , —C 2 H 5  or —C 3 H 7 , n=1-10 and x=1-6;
 
CH 3 —Si(RO) 2 —CH 2 CH 2 CH 2 —[(CH 2 ) 6 ] n —S x —CH 2 CH 2 CH 2 Si(OR) 2 —CH 3 
 
 in which R=—CH 3 , —C 2 H 5  or —C 3 H 7 , n=1-10 and x=1-6;
 
CH 3 —Si(RO) 2 —CH 2 —[S x —(CH 2 ) 6 ] n —S x —CH 2 —Si(OR) 2 —CH 3 
 
 in which R=—CH 3 , —C 2 H 5  or —C 3 H 7 , n=1-10 and x=1-6;
 
(RO) 3 Si—CH 2 CH 2 CH 2 —[S x —CH 2 CH 2 OCH 2 CH 2 )] n —S x —CH 2 CH 2 CH 2 —Si(OR) 3 
 
 in which R=—CH 3 , —C 2 H 5 , —C 3 H 7 , n=1-10 and x=1-6;  
                 
 
 in which R=—CH 3 , —C 2 H 5 , —C 3 H 7 , n=1-10 and x=1-6;
 
  
                 
 
 in which R=—CH 3 , —C 2 H 5  or —C 3 H 7 , R 1 =—CH 3 , —C 2 H 5 , —C 3 H 7 , —C 5 H 5 , —OCH 3 , —OC 2 H 5 , —OC 3 H 7  or —OC 5 H 5 , n=1-10 and x=1-8; and 
 
(RO) 3 Si—CH 2 CH 2 CH 2 —[S x —(CH 2 ) 6 ] r —[S x —(CH 2 ) 8 ] p —CH 2 CH 2 CH 2 —Si(OR) 3 
 
 in which R=—CH 3 , —C 2 H 5  or —C 3 H 7 , r+p=2-10 and x=1-6. 
 
      Also mentioned are sulfur-containing silanes of the formulae:
 
(RO) 3 SiCH 2 CH 2 CH 2 —[S x —(CH 2 CH 2 ) 6 ] n —S x —CH 2 CH 2 CH 2- Si(OR) 3 
 
(RO) 3 SiCH 2 CH 2 CH 2 —[S x —CH 2 CH(OH)—CH 2 ] n —S x —CH 2 CH 2 CH 2 Si(OR) 3 
 
 in which x is 1-6 and n is 1-4. 
 
      If the silane is a sulfur-containing silane it is preferred that it is bis[3-(triethoxysilyl)propyl]-tetrasulfane, of formula
 
(C 2 H 5 O) 3 Si—CH 2 —CH 2 —CH 2 —S—S—S—S—CH 2 —CH 2 —CH 2 —Si(OC 2 H 5 ) 3 .
 
      This compound is commercially available under the trade-mark Si-69. In fact Si-69 is a mixture of the above compound, i.e., the tetrasulfane, with bis[3-(triethoxysilyl)-propyl]monosulfane and bis[3-(triethoxysilyl)-propyl]trisulfane, average sulfane 3.5.  
      Another preferred sulfur-containing silane is available under the trade-mark Silquest™ 1589. The material available under this trade-mark is a mixture of sulfanes but the predominant component, about 75%, is similar in structure to the tetrasulfane Si-69, except that it is a disulfane, i.e., it has only
 
—S—S—
 
 where Si-69 has
 
—S—S—S—S—.
 
      The remainder of the mixture is composed of —S, to —S 7 — compounds. Silquest™ A-1589 is available from CK Witco. A similar material is available from Degussa under the trademark Si-75.  
      Yet another preferred sulfur-containing silane is bis[2-(triethoxysilyl)ethyl]tetrasulfane, available under the trade-mark Silquest™ RC-2.  
      The trimethoxy compounds corresponding to these triethoxy compounds can also be used.  
      The additive in the mixed modifier system contains at least one hydroxyl group and a functional group containing a basic amine and preferably also contains a primary alcohol group and an amine group separated by methylene bridges, which may be branched. Such compounds have the general formula HO—B—NR 14 R 15 ; wherein B is a C 1 —C 20  alkylene group which may be linear or branched and R 14  and R 15  are independently H, C 1 —C 11  alkyl or aryl groups. Preferably the number of methylene groups between the two functional groups should be in the range of from 1 to 4. Examples of preferred additives include monoethanolamine and N,N—dimethylaminoethanol.  
      The amount of filler to be incorporated into the halobutyl elastomer compound may vary between wide limits. Typical amounts of filler range from 20 parts to 250 parts, preferably 30 parts to 100 parts, more preferably from 40 to 80 parts per hundred parts of elastomer. For a compound containing about 30 phr mineral filler the amount of additive present in the mixed modifier is in the range from about 0.1 to 2.0 phr, more preferably from about 0.3 to 1.7 phr and even more preferably from about 0.5 to 1.5 phr and the amount of the silane compound in the mixed modifier is in the range from about 0.1 to 6.0 phr, more preferably from about 0.8 to 5.0 phr and even more preferably from about 1.6 to 4.2 phr. The amount of modifiers in the mixture will increase directly with the amount of silica in the compound. For example, if the amount of silica in the compound is doubled from 30 phr to 60 phr then the amount of the additive and silane in the mixed modifier may also double. For example, if additional mineral filler is increased, for example, 80 phr then the amount of additive and silane may need to be adjusted to, for example around 2 and 6 phr.  
      According to the present invention the elastomers, filler(s) and mixed modifier system containing a silane compound and a additive having at least one hydroxyl group and a functional containing a basic amine are mixed together, suitably at a temperature in the range of from 25 to 200° C. Normally the mixing time does not exceed one hour. The mixing can be carried out on a two-role mill mixer, a Banbury mixer or in a miniature internal mixer.  
     EXAMPLES  
      Testing  
      Hardness and Stress Strain Properties were determined with the use of an A- 2  type durometer following ASTM D-2240 requirements. The stress strain data was generated at 23° C. according to the requirements of ASTM D-412 Method A. Die C dumbbells cut from 2 mm thick tensile sheets (cured for tc90+5 minutes at 160° C.) were used. DIN abrasion resistance was determined according to test method DIN 53516. Sample buttons for DIN abrasion analysis were cured at 160° C. for tc90+10 minutes. GABO samples were cured at 160° C. for t90+5 minutes, and the dynamic response measured from −100° C. to +100° C. using a frequency of 10 Hz and a dynamic strain of 0.1%. Mooney scorch was measured at 130° C. with the use of an Alpha Technologies MV 2000 according to ASTM 1646. The tc90 times were determined according to ASTM D-5289 with the use of a Moving Die Rheometer (MDR 2000E) using a frequency of oscillation of 1.7 Hz and a 1° are at 170° C. for 30 minutes total run time. Curing was achieved with the use of an Electric Press equipped with an Allan-Bradley Programmable Controller.  
      Compounds were prepared using standard mixing practices. The examples were prepared, according to the formulations given in Table 1, with the use of a 1.5 L BR-82 Banbury internal mixer equipped with intermeshing rotors. The temperature was first allowed to stabilize at 30° C. With the rotor speed set at 77 rpm, ingredients 1A were introduced into the mixer followed by 1B after 0.5 min. After 3 minutes, ingredients 1C were added to the mixer. After 4 minutes, a sweep was performed. After 4.5 minutes, ingredients 1D were added to the mixer followed by a final sweep at 6.0 minutes. The compound was dumped after a total mix time of 7.0 minutes. The curatives (2A) were then added on a RT, two-roll mill.  
               TABLE 1                          Formulations of Compounds 1-7.                         Ingredients (phr)                                                         Comp.   Comp.                               Tag   Ex. 1   Ex. 2   Ex. 3   Ex. 4   Ex. 5   Ex. 6   Ex. 7                                                             BUNA ™ CB 25   1A   50   50   50   50   50   50   50       LANXESS ® BROMOBUTYL   1A   50   50   50   50   50   50   50       2030       SILANE SI-69 ®   1A   0   0   0.8   2.4   3.2   2.4   3.2       HI-SIL ™ 233   1B   30   30   30   30   30   30   30       N,N-DIMETHYL   1B   1.4   1.4   1.4   1.4   1.4   0.7   0.7       ETHANOLAMINE       Hexamethyldisilazane   1B   0   0.73   0   0   0   0   0       CARBON BLACK, N 234   1C   30   30   30   30   30   30   30       VULCAN 7       STEARIC ACID   1C   1   1   1   1   1   1   1       CALSOL 8240   1D   7.5   7.5   7.5   7.5   7.5   7.5   7.5       SUNOLITE 160 PRILLS   1D   0.75   0.75   0.75   0.75   0.75   0.75   0.75       VULKANOX ™ 4020 LG   1D   0.5   0.5   0.5   0.5   0.5   0.5   0.5       (6PPD)       VULKANOX ™ HS/LG   1D   0.5   0.5   0.5   0.5   0.5   0.5   0.5       (B)(R-463)       SULFUR NBS   2A   1   1   1   1   1   1   1       VULKACIT CZ/EGC   2A   1   1   1   1   1   1   1       ZINC OXIDE   2A   2   2   2   2   2   2   2                  
 
     
       
         
           
               
             
               
                 TABLE 2 
               
             
            
               
                   
               
               
                   
               
               
                 Selected Physical and Dynamic Properties of Compounds 1-7 
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                   
                 Ex. 1 
                 Ex. 2 
                 Ex. 3 
                 Ex. 4 
                 Ex. 5 
                 Ex. 6 
                 Ex. 7 
               
               
                   
                   
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                 Hardness Shore A (pts) 
                 61 
                 52 
                 61 
                 61 
                 62 
                 61 
                 62 
               
               
                 Modulus 300% 
                 8.3 
                 6.7 
                 11.0 
                 12.5 
                 14.6 
                 13.0 
                 14.9 
               
               
                 Ultimate Tensile 
                 16.7 
                 15.5 
                 16.2 
                 18.0 
                 17.3 
                 16.5 
                 16.0 
               
               
                 M300/M100 
                 3.3 
                 3.8 
                 3.4 
                 3.8 
                 3.7 
                 3.8 
                 3.4 
               
               
                 DIN Abrasion (mm 3 ) 
                 75 
                 85 
                 69 
                 67 
                 65 
                 61 
                 65 
               
               
                 Scorch Time, t3 
                 12.1 
                 14.1 
                 11.4 
                 9.7 
                 11.7 
                 11.4 
                 10.9 
               
               
                 Tan delta −20° C. 
                 0.463 
                 0.580 
                 0.485 
                 0.538 
                 0.564 
                 0.564 
                 0.549 
               
               
                 Tan delta 0° C. 
                 0.259 
                 0.350 
                 0.272 
                 0.301 
                 0.325 
                 0.309 
                 0.308 
               
               
                 Tan delta +60° C. 
                 0.132 
                 0.152 
                 0.126 
                 0.105 
                 0.101 
                 0.107 
                 0.102 
               
               
                   
               
            
           
         
       
     
      Examples 1 and 2 are comparative compounds. Example 1 utilizes only DMAE as a silica modifier for BIIR tread compounds while example 2 uses both DMAE and HMDZ modifiers, which serve to both improve filler dispersion and the level of reinforcement. Examples 3-7 use a combination of DMAE and Si-69 to obtain improved compound properties.  
      Analysis of the physical data for Examples 3-5 (see Table 2) indicates that the degree of reinforcement increases With the amount of Si-69 matching reinforcement of the DMAE/HMDZ compound. One important effect of this is that the compound hardness remains high relative to the control compound Example 2. Furthermore, the abrasion resistance appears to be improved as indicated by the DIN abrasion values for all compounds. Also, most importantly, the tan delta values at −20 and 0 C. (indicative of improved traction properties) are maintained in example 5 while significantly reducing the predicted rolling resistance by 50%. This effect is more pronounced in such a blend compound than either Si-69 or DMAE alone. Furthermore, if increased levels of DMAE are used in an effort to improve filler interaction, the resulting compound appears scorched and significant processing difficulties arise. The DMAE/Si-69 mixed modifier system increases the abrasion values relative to DMAE (/HMDZ) or Si-69 containing compounds with no such processing penalty (see  FIG. 1 ).  
      Although it may be speculated that increased modifier may be the root cause of such effects, here it is not the case. If one examines Example 6 it is clear that by using less than the molar equivalent of modifiers used in Example 2, that much improved dynamic as well as physical properties are observed (see  FIG. 2 , Table 2).  
      The above experimental data shows that a compound of the present invention comprising both a silane modifier and an additive derived from a compound comprising at least one hydroxyl group and a functional group containing a basic amine exhibits improved traction and reduced rolling resistance as compared with prior art compounds.