Patent Publication Number: US-2022231385-A1

Title: Solid-state battery

Description:
This application is based on and claims the benefit of priority from Japanese Patent Application No. 2021-007085, filed on 20 Jan. 2021, the content of which is incorporated herein by reference. 
     BACKGROUND OF THE INVENTION 
     Field of the Invention 
     The present invention relates to a solid-state battery. 
     Related Art 
     Conventionally, lithium ion secondary batteries have been becoming widespread as secondary batteries having high energy density. A lithium ion secondary battery has a structure including a positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode, and a liquid electrolyte being filled therein. 
     Since an electrolytic solution in the lithium ion secondary battery is usually a flammable organic solvent, in particular, safety against heat has often been a problem. Then, a solid-state battery using an inorganic-based solid electrolyte instead of an organic-based liquid electrolyte has been proposed (see Patent Document 1).
     Patent Document 1: Japanese Unexamined Patent Application, Publication No. 2000-106154   

     SUMMARY OF THE INVENTION 
     In conventional secondary batteries such as a lithium ion secondary battery including a liquid electrolyte, a battery cell having a columnar shape and having a large capacity can be produced by stacking and winding a pair of electrodes composed of a positive electrode and a negative electrode coated with an active material, and filling the inside of the obtained cylindrical-shaped wound body with an electrolytic solution. 
     A solid-state battery housed in a cylindrical outer body has an advantage that stress is not concentrated on the corner portion, and, therefore, restraining pressure can be uniformly applied as compared with, for example, a solid-state battery housed in an outer body having a rectangular tube shape. In a case of a solid-state battery, it is difficult to produce a wound body because an electrode is hard and fragile. Therefore, when a multilayer body including a plurality of electrodes is housed in a cylindrical-shaped outer body, it is required to have a structure of series connection. Therefore, since the cell has a high voltage and a small capacity, it is necessary to provide an insulating component accompanying the increase in voltage. Furthermore, in order to increase the capacity by connecting a plurality of cells in parallel, it is necessary to install connectors or the like in parallel in number of parallel connections. Therefore, there has been a problem that the number of components is increased, resulting in lowering the energy density per module unit. 
     The present invention has been made in view of the above, and has an object to provide a solid-state battery capable of achieving high capacity. 
     (1) The present invention relates to a solid-state battery including a multilayer body including a stack of a plurality of electrode layers including positive electrode layers and negative electrode layers and solid electrolyte layers each disposed between the electrode layers, the multilayer body having a columnar shape; and the solid-state battery including a positive electrode terminal and a negative electrode terminal disposed at both end portions of the multilayer body; a positive electrode tab electrically connected to the positive electrode layer and the positive electrode terminal; and a negative electrode tab electrically connected to the negative electrode layer and the negative electrode terminal, in which the positive electrode tab and the negative electrode tab are spirally wound on an outer peripheral surface of the multilayer body. 
     The invention of (1) can provide a solid-state battery capable of achieving high capacity. 
     (2) The solid-state battery described in (1), wherein the positive electrode tab and the negative electrode tab have an at least partially insulated surface or a surface at least partially covered with an insulator. 
     The invention of (2) can prevent short-circuit of a solid-state battery, and can improve the safety of the solid-state battery. 
     (3) The solid-state battery described in (1) or (2), wherein the positive electrode layer and the negative electrode layer include a current collector made of a metal porous body. 
     The invention of (3) makes it possible to easily connect the electrode tab to each electrode layer by welding. 
     (4) The solid-state battery described in (3), wherein the positive electrode tab and the negative electrode tab are welded to the current collector. 
     The invention of (4) makes it possible to easily and strongly connect the electrode tab to each electrode layer. 
     (5) The solid-state battery described in (4), wherein a material mixture unfilled portion, in which the current collector is not filled with an electrode material mixture, is provided in the outer periphery in the diameter direction of the electrode layers, and the positive electrode tab and the negative electrode tab are welded to the current collector in the material mixture unfilled portion. 
     The invention of (5) makes it possible to easily and reliably connect the electrode tab to each electrode layer by welding. 
     (6) The solid-state battery described in any one of (1) to (5), wherein an insulator is disposed on at least an outer peripheral surface of the multilayer body, in which the positive electrode tab and the negative electrode tab are not disposed. 
     The invention of (6) can prevent the positive electrode tab and the negative electrode tab from being brought into contact with each other and being short-circuited, and can apply uniform restraining pressure to the multilayer body. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1  is a perspective view showing a solid-state battery in accordance with a first embodiment of the present invention; 
         FIG. 2  is an exploded perspective view showing the solid-state battery in accordance with the first embodiment of the present invention; 
         FIG. 3A  is sectional views showing an electrode layer in accordance with an embodiment of the present invention; 
         FIG. 3B  is sectional views showing an electrode layer in accordance with an embodiment of the present invention; 
         FIG. 4  is a perspective view showing a solid-state battery in accordance with a second embodiment of the present invention; 
         FIG. 5  is a sectional view showing a solid-state battery in accordance with the second embodiment of the present invention; 
         FIG. 6  is a sectional view showing a solid-state battery in accordance with the second embodiment of the present invention; and 
         FIG. 7  is a sectional view showing a solid-state battery in accordance with the second embodiment of the present invention. 
     
    
    
     DETAILED DESCRIPTION OF THE INVENTION 
     Hereinafter, embodiments of the present invention will be described with reference to the drawings. However, the embodiments shown below are to exemplify the present invention, and the present invention is not to be limited to the following description. 
     First Embodiment 
     &lt;Solid-State Battery&gt; 
     A solid-state battery  10  in accordance with this embodiment, as shown in  FIG. 1 , includes a multilayer body  1  having a columnar shape, a positive electrode tab  21  and a negative electrode tab  31  spirally wound on an outer peripheral surface of the multilayer body  1 , and a positive electrode terminal  22  and a negative electrode terminal  32  disposed at both end portions of the multilayer body  1 . These are housed in a cylindrical-shape outer body (not shown). In this embodiment, the solid-state battery  10  is a solid-state lithium ion secondary battery capable of being charged and discharged by absorbing and releasing lithium ions and electrons. 
     (Multilayer Body) 
     A multilayer body  1 , as shown in  FIG. 2 , is formed by laminating a positive electrode layer  20 , a negative electrode layer  30 , and a solid electrolyte layer  40  disposed between the positive electrode layer  20  and the negative electrode layer  30  each having a columnar shape. In this embodiment, the positive electrode layer  20  is disposed on one laminate end portion of the multilayer body  1 , and the negative electrode layer  30  is disposed on the other laminate end portion of the multilayer body  1 . 
     [Electrode Layer] 
     Electrode layers including a positive electrode layer  20  and a negative electrode layer  30  have a columnar shape, and is formed by filling at least a part of a current collector made of a metal porous body with an electrode material mixture. Hereinafter, the positive electrode layer  20  is described as an example, but the same is true to the negative electrode layer  30  having the same configuration.  FIG. 3A  and  FIG. 3B  are sectional views showing the positive electrode layer  20  as the electrode layer.  FIG. 3A  is a sectional view of the positive electrode layer  20  in the diameter direction, and  FIG. 3B  is a sectional view of the positive electrode layer  20  in the axial direction. As shown in  FIG. 3A  and  FIG. 3B , the positive electrode layer  20  includes a material mixture filled portion  20   a  having a current collector filled with an electrode material mixture in the center portion of the diameter direction. Furthermore, the positive electrode layer  20  includes a material mixture unfilled portion  20   b  in which the current collector is not filled with an electrode material mixture in the outer periphery in the diameter direction. A part of the material mixture unfilled portion  20   b  is provided with a welded portion  20   c  welded to a positive electrode tab  21 . By providing the material mixture unfilled portion  20   b  with the welded portion  20   c , the positive electrode tab  21  and the positive electrode layer  20  can be welded easily and reliably. Note here that when the electrode layer does not include a material mixture unfilled portion, a welded portion to a tab may be provided in the material mixture filled portion. 
     The material mixture unfilled portion  20   b  may be formed in a part of the outer periphery in the diameter direction of the positive electrode layer  20 , but the material mixture unfilled portion  20   b  is preferably formed over the entire circumference of the outer periphery in the diameter direction of the positive electrode layer  20 . Thus, when the multilayer body  1  is housed in the outer body, pressure can be uniformly applied to the positive electrode layer  20  from the side surface in the circumferential direction. The material mixture unfilled portion  20   b  has a metal density being preferably higher than that of the material mixture filled portion  20   a . Furthermore, the material mixture unfilled portion  20   b  may be filled with any one of an insulating material, a solid electrolyte, and a heat conductive material. When the material mixture unfilled portion  20   b  is filled with an insulating material or a solid electrolyte, an internal short circuit of the solid-state battery  10  can be prevented. Furthermore, when the material mixture unfilled portion  20   b  is filled with a heat conductive material, the dissipation efficiency of heat generated in the electrode layers to the outside can be improved. 
     Examples of the insulating material capable of being filled into the material mixture unfilled portion  20   b  include a synthetic resin, and the like. The synthetic resin is not particularly limited, and examples thereof include a thermosetting resin such as a polyimide resin, an epoxy resin, a silicone resin, a polyurethane resin, and the like; a thermoplastic resin such as a polyolefin resin, a polystyrene resin, a fluorine resin, a polyvinyl chloride resin, a polymethacrylic acid resin, a polyurethane resin, and the like; and a photocurable resin such as a silicone resin, a polymethacrylic acid resin, a polyester resin, and the like. As the solid electrolyte, the same materials as the solid electrolyte materials to be used for the below-mentioned solid electrolyte layer  40  are used. Examples of the heat conductive material include high-thermal conductive PC (polycarbonate) resin, high-thermal conductive polybutylene terephthalate (PBT) resin, a high-thermal conductive polyamide (PA) resin, a polyphenylene sulfide (PPS) resin, and the like, and further examples include high-thermal conductive resin materials such as a high-thermal conductive silicone materials having thermal conductivity of 30 W/mK or more. 
     Both the positive electrode layer  20  and the negative electrode layer  30  may have a material mixture unfilled portion. Furthermore, only one of the positive electrode layer  20  and the negative electrode layer  30  may have a material mixture unfilled portion. When only one of the positive electrode layer  20  and the negative electrode layer  30  has a material mixture unfilled portion, it is preferable that the positive electrode layer  20  has a material mixture unfilled portion. Thus, since the material mixture filled portion of the positive electrode layer  20  is smaller than the material mixture filled portion of the negative electrode layer  30 , it is possible to suppress precipitation of lithium due to concentration of electric current on the end portion of the negative electrode layer  30 . 
     [Current Collector] 
     A current collector constituting the positive electrode layer  20  and the negative electrode layer  30  is made of a metal porous body. The metal porous body includes mutually continuous pores. The inside of the pores can be filled with an electrode material mixture including an electrode active material. The above-mentioned metal porous body is not particularly limited as long as it includes mutually continuous pores, and examples thereof include foam metals having pores, metal mesh, expanded metal, a punched metal, a metal nonwoven fabric, and the like, having pores formed by foaming. Examples of metal to be used for the metal porous body is not particularly limited as long as it has conductivity, and examples thereof include nickel, aluminum, stainless steel, titanium, copper, silver, and the like. Among them, foamed aluminum, foamed nickel, and foamed stainless steel are preferably used as the current collector constituting the positive electrode, and foamed copper and foamed stainless steel are preferably used as the current collector constituting the negative electrode. 
     The current collector as the metal porous body includes mutually continuous pores inside thereof, and has a larger surface area than that of a metal foil as a conventional current collector. Use of the above-mentioned metal porous body for the current collector makes it possible to fill the electrode material mixture including the electrode active material with the inside of the above-mentioned pores. Thus, the amount of active materials per unit area of the electrode layer can be increased, and as a result, the volumetric energy density of the solid-state battery can be improved. Furthermore, since the electrode material mixture can be fixed easily, unlike conventional electrodes using a metal foil for the current collector, it is not necessary to increase the viscosity of coating slurry forming an electrode material mixture layer for increasing a film thickness of the electrode material mixture layer. This can decrease a binding agent such as an organic polymer compound required for increasing viscosity. Therefore, it is possible to increase capacity per unit area of the electrode, and to achieve high capacity in a solid-state battery. Furthermore, use of the metal porous body for the current collector makes it possible to secure strength of the electrode layer. Therefore, the positive electrode tab and the negative electrode tab can be easily welded to each electrode layer, which has been difficult in a conventional electrode layer in which a current collecting foil is coated with an electrode material mixture. 
     [Electrode Material Mixture] 
     An electrode material mixture filled in a current collector as a metal porous body includes at least an electrode active material. The electrode material mixture that can be applied for this embodiment may include arbitrary other components as long as the electrode material mixture includes an electrode active material as an essential component. Other components are not particularly limited, and may use components that can be used for producing a solid-state battery can be used. For example, a solid electrolyte, a conductive auxiliary agent, a binding agent, and the like, can be included. 
     The positive electrode material mixture constituting the positive electrode layer  20  contains at least a positive electrode active material, and may contain other components such as a solid electrolyte, a conductive auxiliary agent, and a binding agent. The positive electrode active material is not particularly limited as long as it can absorb and release lithium ions. Examples thereof include LiCoO 2 , Li(Ni 5/10 Co 2/10 Mn 3/10 )O 2 , Li(Ni 6/10 Co 2/10 Mn 2/10 )O 2 , Li(Ni 8/10 Co 1/10 Mn 1/10 )O 2 , Li(Ni 0.8 Co 0.15 Al 0.05 )O 2 , Li(Ni 1/6 Co 4/6 Mn 1/6 )O 2 , Li(Ni 1/3 Co 1/3 Mn 1/3 )O 2 , LiCoO 4 , LiMn 2 O 4 , LiNiO 2 , LiFePO 4 , lithium sulfide, sulfur, and the like. 
     The negative electrode material mixture constituting the negative electrode layer  30  contains at least a negative electrode active material, and may contain other components such as a solid electrolyte, a conductive auxiliary agent, and a binding agent. The negative electrode active material is not particularly limited as long as it can absorb and release lithium ions, and examples thereof include metallic lithium, a lithium alloy, metal oxide, metal sulfide, metal nitride, Si, SiO, and carbon materials such as an artificial graphite, natural graphite, hard carbon, and soft carbon. 
     [Solid Electrolyte] 
     A solid electrolyte layer  40  is laminated between the positive electrode layer  20  and the negative electrode layer  30 . The solid electrolyte layer  40  is a layer containing at least a solid electrolyte material. Charge transfer between the positive electrode active material and the negative electrode active material can be carried out through the solid electrolyte material. The solid electrolyte is not particularly limited and well-known solid electrolyte that can be used for the solid-state battery can be used. Examples thereof include a sulfide solid electrolyte material, an oxide solid electrolyte material, a nitride solid electrolyte material, a halide solid electrolyte material, and the like. 
     (Electrode Tab) 
     A positive electrode tab  21  and a negative electrode tab  31  as electrode tabs are a belt-like member spirally wound on the outer peripheral surface of a columnar-shaped multilayer body  1  as shown in  FIGS. 1 and 2 . The positive electrode tab  21  is welded and electrically connected to all the positive electrode layers  20  of the multilayer body  1  at a welded portion  20   c . Similarly, the negative electrode tab  31  is welded and electrically connected to all the negative electrode layers  30 . Furthermore, the positive electrode tab  21  is electrically connected to the positive electrode terminal  22 , and the negative electrode tab  31  is electrically connected to the negative electrode terminal  32 . As a result, the electrode layers constituting the multilayer body  1  are connected in parallel, so that a high-capacity solid-state battery can be obtained. In addition to the above, the multilayer body  1  having a columnar shape, and the positive electrode tabs  21  and the negative electrode tabs  31  can be constructed without providing extending portions of the electrode tabs, so that the above configuration can be housed in a cylindrical-shaped outer body with a space saved. As a result, the energy density of the solid-state battery can be improved, and restraining pressure can be uniformly applied to the electrode layers by the outer body. 
     Materials constituting the positive electrode tab  21  and the negative electrode tab  31  are not particularly limited, and the same metal materials constituting the positive current collector and the negative electrode current collector can be used, respectively. 
     Preferably, at least a part of the surface of the positive electrode tab  21  and the negative electrode tab  31  excluding a connection portion with respect to the electrode layer and the electrode terminal is insulation-processed or covered with an insulator. Thus, the short circuit of the solid-state battery  10  can be prevented. The method for insulation processing is not particularly limited, but examples thereof include a method of forming an insulating layer on the surface of the electrode tab by a metal oxide such as alumina or a solid electrolyte having insulating properties. The method for covering with an insulator is not particularly limited, and examples thereof include a method of covering the surface of the electrode tab with an insulating film. 
     (Electrode Terminal) 
     A positive electrode terminal  22  serving as an electrode terminal is disposed in contact with a positive electrode layer  20  disposed at one end portion of a multilayer body  1 . The positive electrode terminal  22  may be electrically connected to the positive electrode tab  21  by, for example, welding. Similarly, a negative electrode terminal  32  serving as an electrode terminal is disposed in contact with a negative electrode layer  30  disposed at the other end portion of the multilayer body  1 . The negative electrode terminal  32  may be electrically connected to the negative electrode tab  31  by, for example, welding. Materials of the positive electrode terminal  22  and a negative electrode terminal  32  are not particularly limited as long as they have conductivity, but from the viewpoint of facilitating welding, the positive electrode terminal  22  is formed of the same metals as the positive electrode tab  21 , and examples thereof include aluminum, stainless steel, and the like. Similarly, the negative electrode terminal  32  is preferably formed of the same metal as the negative electrode tab  31 , and examples thereof include copper, stainless steel, and the like. 
     (Outer Body) 
     An outer body is a cylindrical-shaped outer body that houses multilayer body  1  as well as the positive electrode tab  21  and the negative electrode tab  31 . The outer body is a sealing member for sealing the both end portions in the axial direction, and it may have a lid body. Materials for the outer body are not particularly limited, and, for example, a metal material can be used. When a metal material is used as the outer body, strong restraining pressure can be applied to the positive electrode layer  20  and the negative electrode layer  30 . The above-mentioned metal material is not particularly limited as long as it can be used as an outer body for batteries, and examples thereof include aluminum, stainless steel, and the like. As the materials for the outer body, in addition to the above metal materials, resin such as synthetic resin can be used. 
     The lid body is not particularly limited as long as it can seal both end portions in the axial direction of the outer body. The positive electrode terminal  22  and a negative electrode terminal  32  may be used as the lid body. Preferably, the lid body has a configuration capable of moving from the outer side in the axial direction of the cylindrical-shaped outer body toward the center portion of the solid-state battery  10 . When the lid body is moved as mentioned above, the positive electrode layer  20  and the negative electrode layer  30  are pressed via the lid body, so that a restraining pressure can be applied to the positive electrode layer  20  and the negative electrode layer  30 . The outer body has a cylindrical shape. When the restraining pressure is applied from the axial direction mentioned above, uniform restraining pressure can be applied to the both ends, which are in contact with the lid, of the positive electrode layer  20  and the negative electrode layer  30 . Therefore, even when the solid-state battery  10  is made into a module, a high restraining component is not required, and the energy density in the module unit can be improved. Furthermore, even at the side surfaces of the positive electrode layer  20  and the negative electrode layer  30 , which are in contact with the inner peripheral surface of the outer package, uniform restraining pressure can be applied. When the uniform restraining pressure is applied as mentioned above, the internal resistance of the solid-state battery  10  can be made uniform, and as a result, the reaction rate of the battery reaction generated inside the solid-state battery  10  can be made uniform. At a result, preferable battery performance can be obtained. Furthermore, when the side surfaces of the positive electrode layer  20  and the negative electrode layer  30  are restrained, in the use of the solid-state battery  10  as a vehicle-mounted battery, vibration at the time when it is mounted on a vehicle and the lamination displacement at the time of collision can be prevented, and the breakage of the multilayer body can be suppressed, so that the high durability and the high safety of the solid-state battery  10  can be obtained. 
     &lt;Method for Manufacturing Solid-State Battery  10 &gt; 
     A method for manufacturing a solid-state battery  10  is not particularly limited, but the method includes, for example, a filling step of filling a metal porous body with an electrode material mixture to form an electrode layer, and a welding step of welding an electrode tab to a multilayer body  1  obtained by laminating the electrode layer and a solid electrolyte layer and an electrode terminal. 
     The filling step is a step of impregnating pores of a metal porous body having a columnar shape with an electrode material mixture including an electrode active material, and forming an electrode layer. A method of filling the metal porous body with the electrode material mixture is not particularly limited, and examples of the method include a method for filling the inside of pores of the metal porous body with slurry including an electrode material mixture using a plunger-type die coater, while pressure is applied. In addition to the above, the inside of the metal porous body may be impregnated with an electrode material mixture by a dipping method. 
     The welding step is a step of winding the positive electrode tab  21  and the negative electrode tab  31  to the multilayer body  1  formed by laminating the electrode layer formed by the filling step and a solid electrolyte layer, and welding the electrode tabs and the electrode terminals disposed at both ends of each electrode layer and the multilayer body. The welding method is not particularly limited, and well-known methods can be used. 
     By housing the multilayer body  1  to which an electrode tab has been welded by the above-mentioned filling step and welding step in a cylindrical-shaped outer body, the solid-state battery  10  can be manufactured. A step of applying an appropriate restraining pressure to the multilayer body  1  housed in the cylindrical-shaped outer body from both end portions in the axial direction may be provided. 
     Hereinafter, another embodiment of the present invention is described. The same configuration as that of the above-mentioned first embodiment may be omitted. 
     Second Embodiment 
     A solid-state battery  10   a  in accordance with this embodiment, as shown in  FIG. 4 , includes a multilayer body  1  and an insulating film  5  as an insulator on the outer peripheral surface of the multilayer body  1 . The insulating film  5  is, for example, a belt-like member similar to a positive electrode tab  21  and a negative electrode tab  31 . It is preferable that the positive electrode tab  21 , the insulating film  5 , and the negative electrode tab  31  are spirally wound on the outer peripheral surface of the multilayer body  1  sequentially in this order. This can preferably prevent short-circuit of the solid-state battery  10   a . Furthermore, the insulating film  5  is preferably disposed on the outer peripheral surface in which the positive electrode tab  21  and the negative electrode tab  31  are not disposed in the outer peripheral surface of the multilayer body  1 , and the insulating film  5  preferably has the same thickness as the positive electrode tab  21  and the negative electrode tab  31 . This can reduce the level difference in the outer peripheral surface of the multilayer body  1 , which is generated by the positive electrode tab  21  and the negative electrode tab  31 , so that the outer body can apply uniform restraining pressure to the side surface portions of the positive electrode layer  20  and the negative electrode layer  30 . 
     Materials forming the insulating film  5  are not particularly limited, and examples thereof include synthetic resin and the like as an example of insulating material to be filled in the material mixture unfilled portion  20   b.    
     The insulating film  5  is only required to be disposed at least on the outer peripheral surface on which the positive electrode tab  21  and the negative electrode tab  31  are not disposed in the outer peripheral surface of the multilayer body  1 . For example, the insulating film  5  may be disposed so as to cover a portion excluding a welded portion to the positive electrode tab  21  and the negative electrode tab  31  in the outer peripheral surface of the multilayer body  1 . When the multilayer body  1  is wound on the positive electrode tab  21  and the negative electrode tab  31  after the multilayer body  1  has been covered with the insulating film  5  having the above-mentioned configuration and thereby, short circuit during manufacturing can be prevented. Alternatively, the positive electrode tab  21  and the negative electrode tab  31  are wound and welded to the multilayer body  1 , and then the entire part may be covered with the insulating film  5 . Thus, the manufacturing step can be simplified. 
       FIGS. 5, 6, and 7  are sectional views each showing an example in which the insulating film  5  is disposed on the outer peripheral surface of the multilayer body  1 .  FIG. 5  shows an example in which the insulating film  5  is disposed on the outer peripheral surface on which the positive electrode tab  21  and the negative electrode tab  31  are not disposed in the outer peripheral surface of the multilayer body  1 . In this case, in order to prevent short circuit from occurring between the positive electrode tab  21  and the negative electrode tab  31 , and the outer body  6 , an insulating layer I is preferably provided on a surface in which the positive electrode tab  21  and the negative electrode tab  31  are brought into contact with the outer body  6 . 
       FIG. 6  shows an example in which the insulating film  5  is disposed also between the positive electrode tab  21  and the negative electrode tab  31 , and the outer body  6  in addition to the outer peripheral surface in which the positive electrode tab  21  and the negative electrode tab  31  are not disposed in the outer peripheral surface of the multilayer body  1 . A configuration of  FIG. 6  need not perform insulation treatment with respect to the outer surface of the positive electrode tab  21  and the negative electrode tab  31 . The configuration of  FIG. 6  is obtained by winding the positive electrode tab  21  and the negative electrode tab  31  on the multilayer body  1 , and then covering the entire part with the insulating film  5 . 
     Similar to  FIG. 6 ,  FIG. 7  shows an example in which an insulating film is disposed also between the positive electrode tab  21  and the negative electrode tab  31 , and the outer body  6  in addition to the outer peripheral surface in which the positive electrode tab  21  and the negative electrode tab  31  are not disposed in the outer peripheral surface of the multilayer body  1 . The configuration of  FIG. 7  is divided into the insulating films  51  and  52 , and after the insulating film  51  is wound, the positive electrode tab  21  and the negative electrode tab  31  are wound, and thereby, short circuit during manufacturing can be prevented. Thereafter, the insulating film  52  is wound so as to cover the outer surfaces of the positive electrode tab  21  and the negative electrode tab  31 , so that it is not necessary to perform insulating treatment with respect to the outer surfaces of the positive electrode tab  21  and the negative electrode tab  31 . 
     In the above, the preferable embodiments of the present invention are described. The present invention is not necessarily limited to the above embodiments and can be appropriately modified. 
     EXPLANATION OF REFERENCE NUMERALS 
     
         
         
           
               10 ,  10   a  solid-state battery 
               1  multilayer body 
               20  positive electrode layer 
               21  positive electrode tab 
               22  positive electrode terminal 
               30  negative electrode layer 
               31  negative electrode tab 
               32  negative electrode terminal 
               40  solid electrolyte layer 
               5  insulating film (insulator)