Patent Publication Number: US-2021163252-A1

Title: Collection device and preparation system

Description:
TECHNICAL FIELD 
     The present disclosure relates to the technical field of carbon nanotube material preparation, in particular to a collection device and a preparation system. 
     BACKGROUND 
     Carbon nanotubes (CNTs) are one-dimensional tubular nanomaterial formed by single- or multi-layer graphene crimping. The unique structure thereof brings excellent mechanical, thermal and electrical properties. CNTs have theoretically good mechanical, electrical conductive and thermal conductive properties, and hence have a very large application prospect. Carbon nanotube films and carbon nanotube fibers formed by carbon nanotubes intertwined with one another are common carbon nanotube macroscopic bodies, and can exert excellent performance of carbon nanotubes and have a wide range of application prospects in the fields of electromagnetic shielding, composite materials, electric heating, etc. However, the actual orientation and uniformity of the prepared carbon nanotube macroscopic bodies are poor, that affects various properties of the final macroscopic bodies. 
     SUMMARY 
     Based on the above, it is necessary to provide a collection device and a preparation system for addressing at least one of the above technical problems. 
     The present disclosure provides a collection device for the collection of carbon nanotube films or carbon nanotube fibers, the collection device including: 
     a pre-adjustment mechanism for adjusting the orientation of at least one bundle of carbon nanotube aggregates, the pre-adjustment mechanism including a first pre-adjustment sub-mechanism and a second pre-adjustment sub-mechanism, the first pre-adjustment sub-mechanism including at least a first wheel body and a second wheel body rotatably arranged in a first direction for prepressing both sides of the carbon nanotube aggregates; the second pre-adjustment sub-mechanism including at least a third wheel body for drawing the carbon nanotube aggregates; 
     a winding mechanism for winding and collecting the carbon nanotube aggregates drawn from the pre-adjustment mechanism. 
     The above collection device, by adding the first pre-adjustment sub-mechanism and the second pre-adjustment sub-mechanism, both of which adjust the orientation of at least one bundle of carbon nanotube aggregates, improves not only the internal structure of the carbon nanotubes but also the orientation and the uniformity thereof, achieving the control of the mechanical, electrical and thermal properties of the carbon nanotube materials collected, and contributing to the large-scale production of carbon nanotube films or carbon nanotube fibers of carbon nanotube materials with different properties. 
     In one embodiment, the third wheel body is rotatable and surrounded by a plurality of first annular protrusions provided thereon for adjusting the orientation of the carbon nanotube aggregates. 
     In one embodiment, the first annular protrusion has a width of no greater than 10 μm, and the adjacent first annular protrusions are spaced from each other by no greater than 100 μm. 
     In one embodiment, the collection device further includes a first heating mechanism for adjustment the temperature of a contact surface of the first pre-adjustment mechanism and/or the second pre-adjustment mechanism for contacting the carbon nanotube aggregates. 
     In one embodiment, annular position-limiting slots capable of accommodating carbon nanotube aggregates are provided in the contact surface of the first wheel body and/or the second wheel body for contacting the carbon nanotube aggregates. 
     In one embodiment, the second pre-adjustment sub-mechanism further includes a fourth wheel body, wherein the fourth wheel body and the third wheel body are spaced and staggered in a second direction and both of them are capable of drawing the carbon nanotube aggregates along the collecting direction. 
     In one embodiment, the fourth wheel body is rotatable and surrounded by a plurality of second annular protrusions provided thereon for adjusting the orientation of the carbon nanotube aggregates. 
     In one embodiment, the second annular protrusion has a width of no greater than 10 μm and the adjacent second annular protrusions are spaced from each other by no greater than 100 μm. 
     In one embodiment, the first wheel body and the second wheel body are rotated facing towards or away from each other, and the rotation speeds of the third wheel body and the fourth wheel body are not equal. 
     In one embodiment, the first direction and the second direction are perpendicular to each other. 
     In one embodiment, the winding mechanism includes a rotary drum being retractable in an axial direction and capable of reciprocating in a direction that is not perpendicular to the axial direction of the rotary drum. 
     In one embodiment, the winding mechanism includes a first rotating wheel, a second rotating wheel and a collection belt tensioned therebetween; or 
     the winding mechanism includes a first rotating wheel, a second rotating wheel and a collection plate disposed therebetween and capable of rotating toward the pre-adjustment mechanism. 
     In one embodiment, the spacing between the first wheel and the second wheel can be adjusted. 
     The present disclosure also provides a preparation system for the preparation of carbon nanotube film material or carbon nanotube fiber material, the preparation system including: 
     a synthesis device for floating catalytic synthesis of carbon nanotube aggregates, including a reactor having at least one growth tube; and 
     a collection device which is any one of the collection devices described above and located on an outlet end side of the synthesis device for collecting the carbon nanotube aggregates prepared by the synthesis device. 
     In one embodiment, the end of the growth tube near the collection device is trumpet-shaped or cylindrical. 
     In one of the embodiments, the growth tube is square shaped. 
     In one of the embodiments, the preparation system further includes: 
     a feeding device for providing reaction raw materials and communicating with an inlet end of the synthesis device, the feeding device including at least one injection mechanism and at least one feeding pipe with one end communicating with the injection mechanism and the other end communicating with the growth tube. 
     In one embodiment, the synthesis device includes a reactor having a plurality of growth tubes which are arranged in a circular distribution or a matrix distribution. 
     In one embodiment, the synthesis device further includes a second heating mechanism for adjusting the temperature distribution of respective regions of the inlet ends of the plurality of growth tubes. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1  is a schematic structural diagram of a collection device according to an embodiment of the present disclosure; 
         FIG. 2  is a schematic structural diagram of a collection device according to another embodiment of the present disclosure; 
         FIG. 3  is a sectional view of the third wheel body in  FIG. 2 ; 
         FIG. 4  is a sectional view of the fourth wheel body in  FIG. 2 ; 
         FIG. 5  is a side view of the first pre-adjustment sub-mechanism of  FIG. 2 ; 
         FIG. 6  is a schematic structural diagram of a winding mechanism according to an embodiment of the present disclosure; 
         FIG. 7  is a schematic structural diagram of a collection device according to another embodiment of the present disclosure; 
         FIG. 8  is a schematic structural diagram of a collection device according to an embodiment of the present disclosure; 
         FIG. 9  is a side view of a partial structure of a synthesis device according to an embodiment of the present disclosure; 
         FIG. 10  is an SEM image of Sample  1  of a carbon nanotube film product prepared by a preparation system according to an embodiment of the present disclosure. 
         FIG. 11  is an SEM image of Sample  2  of a carbon nanotube film product prepared by a comparative preparation system; 
         FIG. 12  is a graph showing the tensile stress—breaking elongation curves of the two carbon nanotube film products; 
         FIG. 13  is a schematic structural diagram of a preparation system according to another embodiment of the present disclosure. 
     
    
    
     Reference signs: 
       100 : collection device,  110 : First pre-adjustment sub-mechanism,  111 : First wheel body,  112 : Second wheel body,  120 : Second pre-adjustment sub-mechanism,  121 : Third wheel body,  122 : Fourth wheel body,  130 : Winding mechanism,  131 : First rotating wheel,  132 : Second rotating wheel,  133 : Collection plate,  140 : First annular protrusion,  150 : Second annular protrusion,  160 : Annular position-limiting slot; 
       200 : Synthesis device,  210 : Reactor,  211 : Growth tube,  212 : Second heating mechanism; 
       300 : Feeding device,  310 : Injection mechanism,  320 : Feeding tube,  400 : Carbon nanotube aggregates. 
     DETAILED DESCRIPTION OF EMBODIMENTS 
     Reference will now be made to the drawings to describe embodiments of the present disclosure in detail, so that the above objects, features and advantages of the present disclosure can be more apparent and understandable. In the following description, numerous specific details are set forth in order to provide a thorough understanding of the present disclosure. However, the present disclosure can be implemented through various other means different from those described herein, and those skilled in the art can make similar improvements without departing from the essence of the present disclosure. Therefore, the present disclosure is not intended to be limited by the specific embodiments disclosed below. 
     Unless otherwise defined, all terms (including technical and scientific terms) used herein have the same meaning as commonly understood by skilled person in the art to which this disclosure belongs. The terms used herein is for the purpose of describing embodiments only and is not intended to limit the present disclosure. As used herein, the term “and/or” includes any and all combinations of one or more of the associated listed items. 
       FIG. 1  illustrates the collection device  100  of the present disclosure. The collection device  100  is used for collecting carbon nanotube films or carbon nanotube fibers. The collection device  100  includes a housing that communicates with an outlet end of a synthesis device  200 , and a pre-adjustment mechanism and a winding mechanism  130  provided inside the housing. 
     The pre-adjustment mechanism is disposed within the housing and serves to adjust the orientation of at least one bundle of carbon nanotube aggregates  400 . Specifically, the pre-adjustment mechanism is used to adjust the orientation of a bundle of carbon nanotube aggregates and also can be used to adjust the orientations of two or more bundles of carbon nanotube aggregates. 
     The pre-adjustment mechanism includes a first pre-adjustment sub-mechanism  110  and a second pre-adjustment sub-mechanism  120 . 
     The first pre-adjustment sub-mechanism  110  includes at least a first wheel body  111  and a second wheel body  112  that are rotatable and arranged in a first direction for prepressing both sides of the carbon nanotube aggregates. The second pre-adjustment sub-mechanism  120  includes at least a third wheel  121  for drawing the carbon nanotube aggregates. The first wheel body  111 , the second wheel body  112 , and the third wheel body  121  each may be rotatable roller or roll wheel structure, and has a size matching the carbon nanotube aggregates. In this embodiment, the carbon nanotube aggregates firstly undergo a first orientation adjustment via the first pre-adjustment mechanism  110 , and then undergo a second orientation adjustment via the second pre-adjustment sub-mechanism  120 . 
     The winding mechanism  130  is used for winding and collecting the carbon nanotube aggregates drawn from the pre-adjustment mechanism. 
     The above collection device  100 , by adding the first pre-adjustment sub-mechanism  110  and the second pre-adjustment sub-mechanism  120 , both of which adjust the orientation of at least one bundle of carbon nanotube aggregates respectively, improves not only the internal structure of the carbon nanotubes but also the orientation and the uniformity thereof, achieving the control of the mechanical, electrical and thermal properties of the carbon nanotube material collected, and contributing to the large-scale production of carbon nanotube films or carbon nanotube fibers with different properties. 
     Referring to  FIG. 1 , a direction of the connection line from the outlet end to the collection mechanism is defined as direction M, an end in the direction M near the outlet end side is defined as a rear end, and an end far away from the outlet end side is defined as a front end. Also right and left ends and upper and lower ends of the direction M are defined correspondingly as left, right and upper, lower sides, respectively. 
     EXAMPLE 1 
       FIG. 2  shows a collection device  100  for a horizontal furnace. The collection device  100  is adapted to collect carbon nanotube films or carbon nanotube fibers. The collection device  100  includes a housing, a pre-adjustment mechanism and a winding mechanism  130 , wherein, the pre-adjustment mechanism includes a first pre-adjustment sub-mechanism  110  and a second pre-adjustment sub-mechanism  120  and is adapted to adjust multiple bundles of carbon nanotube aggregates. 
     The first adjustment sub-mechanism  110  is disposed near the outlet end, and the second pre-adjustment sub-mechanism  120  is disposed between the first adjustment sub-mechanism  110  and the winding mechanism  130 . The first wheel body  111  and the second wheel body  112  are preferably arranged on the left and right sides of the direction M respectively, that is, the first wheel body  111  and the second wheel body  112  are arranged on the left and right sides of the carbon nanotube aggregates respectively. 
     Since the carbon nanotube aggregates are mostly in multiple bundles in most cases and the drawn direction of each bundle of carbon nanotube aggregates is inconsistent with the axial direction of the carbon nanotubes, it is difficult to achieve uniform collection of multiple bundles of carbon nanotube aggregates. However, the internal structure of the carbon nanotube material has a great impact on various properties, thus, the overall performance of the carbon nanotube material will be affected. By arranging the first wheel body  111  and the second wheel body  112  disposed on the left and right sides respectively, multiple bundles of carbon nanotube aggregates can be integrated into one bundle so that the integrated carbon nanotube aggregates can be collected in a complete shape, thereby optimizing the uniformity of the collected carbon nanotube aggregate material. Similarly, by adjusting the rotation speeds of the first wheel body  111  and the second wheel body  112 , the positive pressure exerted by the first wheel body  111  and the second wheel body  112  onto the carbon nanotube aggregates can be changed to achieve different bundling and drawing effects, so as to adjust the orientation of the carbon nanotube aggregates, and therefore various properties of the carbon nanotube material can be controlled. At this time, the spacing between the first wheel body  111  and the second wheel body  112 , and the rotation speeds and positions thereof, can be adjusted according to the yield and output rate of the carbon nanotube aggregates so as to achieve the best pre-adjustment effect. It should be noted that in this case, the number of the wheel bodies disposed in the first direction may be always 2, that is, there are only the first wheel body  111  and the second wheel body  112 . Of course, the number of the wheel bodies disposed in the first direction may be multiple other than 2, and preferably may be the number matching with the multiple bundles of carbon nanotube aggregates. 
     The second pre-adjustment sub-mechanism  120  includes a third wheel body  121  disposed on the lower side of the direction M, that is, the third wheel body  121  is disposed on the lower side of the carbon nanotube aggregates. The third wheel body  121  is rotatable and surrounded by a plurality of first annular protrusions  140  provided thereon for adjusting the orientation of the carbon nanotube aggregates. 
     Referring to  FIG. 3 , a plurality of first annular protrusions  140  are disposed on a contact surface of the third wheel body  121  for contacting the carbon nanotube aggregates, and the plurality of first annular protrusions  140  are arranged as surrounding the axial direction of the third wheel body  121 . The width of the first annular protrusion  140  is no greater than 10 μm, and the spacing between the adjacent first annular protrusions  140  is no greater than 100 μm. The first wheel body  111  and the second wheel body  112  are rotatable and their rotation directions can be the same or different. Preferably, the first wheel body  111  and the second wheel body  112  have rotation directions being opposite, and further preferably, they can rotate facing towards or away from each other. 
     The width of the first annular protrusion  140  is no greater than 10 μm, and the spacing between the adjacent first annular protrusions  140  is no greater than 100 μm. Preferably, the width of the first annular protrusion  140  is 0.2 to 5 μm, and the spacing between the adjacent first annular protrusions  140  is 50 to 90 μm. The height of the first annular protrusion  140  is 1 to 10 mm. Further, the first annular protrusion  140  may be integrally formed with the third wheel body  121 , or may be separately formed and detachably mounted on the third wheel body  121 . The first annular protrusion  140  can be prepared by laser etching or chemical etching or printing, etc. 
     As the third wheel body  121  rotates, the third wheel body  121  brings the corresponding first annular protrusion  140  to rotate. A plurality of spaced first annular protrusions  140  can exert a force along the tangential direction on the carbon nanotube aggregates to help regulate the internal structure of the carbon nanotube aggregates along the tangential direction. In addition, the first annular protrusions  140  each can also exert a certain positive pressure on the carbon nanotube aggregates, and by adjusting the rotation speed of the third wheel  121 , the third wheel  121  can apply different positive pressures on the carbon nanotube aggregates to achieve the drawing of the carbon nanotube aggregates to adjust the orientation of the carbon nanotube aggregates so that various properties of the carbon nanotube material can be controlled. 
     Referring to  FIG. 2 , in this embodiment, the second pre-adjustment sub-mechanism  120  further includes at least a rotatable fourth wheel body  122 . The fourth wheel body  122  and the third wheel body  121  are spaced and staggered in the second direction and each of them is capable of drawing the carbon nanotube aggregates along the collecting direction. The second direction is different from the first direction. Preferably, the second direction and the first direction are perpendicular to each other. Of course, the second direction and the first direction may also be other cases. 
     Further, the fourth wheel body  122  and the third wheel body  121  are disposed on the upper and lower sides or the left and right sides of the Direction M, and the disposing positions of the two wheel bodies may be adjusted correspondingly according to the disposal of the first wheel body  111  and the second wheel body  112 . Since the fourth wheel body  122  is added, by adjusting the rotation speeds of the fourth wheel body  122  and the third wheel body  121  to be different, the positive pressure along the second direction applied by the third wheel body  121  and the fourth wheel body  122  on the carbon nanotube aggregates can be changed to achieve further drafting of the carbon nanotube aggregates and further adjusting the orientation of the carbon nanotube aggregates so as to realize the controllable adjustment of various properties of the carbon nanotube material. In this embodiment, the number of the third wheel body  121  and that of the fourth wheel body  122  are the same and both are one. In other embodiments, the number of the third wheel body  121  and the fourth wheel body  122  may be two or more. In this way, various degree of drawing of the carbon nanotube aggregates is performed by adding a plurality of wheel bodies to further adjust the microstructure of the carbon nanotube aggregates and to improve the orientation of the carbon nanotube aggregates. 
     Further, referring to  FIG. 4 , the fourth wheel body is surrounded by a plurality of second annular protrusions  150  provided thereon for adjusting the orientation of the carbon nanotube aggregates. Specifically, a plurality of second annular protrusions  150  can be disposed on a contact surface of the fourth wheel body  122  for contacting the carbon nanotube aggregates and those protrusions  150  may be provided as surrounding the axial direction of the fourth wheel body  122 . 
     The width of the second annular protrusion  150  is no greater than 10 μm, and the spacing between the adjacent second annular protrusions  150  is no greater than 100 μm. Similar to the first annular protrusion  140 , preferably, the width of the second annular protrusion  150  is 0.2 to 5 μm, and the spacing between the adjacent second annular protrusions  150  is 1 to 80 μm. The height of the second annular protrusion  150  is 1 to 10 mm. Further, the second annular protrusion  150  may be integrally formed with the fourth wheel body  122 , or may be separately formed and detachably mounted on the fourth wheel body  122 . The second annular protrusion  150  can be prepared by laser etching or chemical etching or printing, etc. 
     In one embodiment, the first annular protrusions  140  and the second annular protrusions  150  may be disposed symmetrically or may be staggered. 
     As the third wheel body  121  and the fourth wheel body  122  rotate, the third wheel body  121  and the fourth wheel body  122  bring the corresponding first annular protrusion  140  and second annular protrusions  150  to rotate. A plurality of spaced annular protrusions can exert a force along the tangential direction on the carbon nanotube aggregates to help adjust the internal structure of the carbon nanotube aggregates along the tangential direction, optimizing the adjustment effect of orientation. In addition, the first annular protrusions  140  and the second annular protrusions  150  each can also exert a certain positive pressure on the carbon nanotube aggregates; and by adjusting the rotation speeds of the third wheel  121  and the fourth wheel body  122  to be different, different positive pressures along the first direction will be applied by the third wheel  121  and the fourth wheel body  122  on the carbon nanotube aggregates, so as to achieve the drawing of the carbon nanotube aggregates to adjust the orientation of the carbon nanotube aggregates, and therefore various properties of the carbon nanotube material can be controlled. 
     In one embodiment, the respective widths and spacings of the first annular protrusions  140  and the second annular protrusions  150  may be the same or different. When the respective widths and the spacings of the first annular protrusions  140  and second annular protrusions  150  are different, the distribution density of the respective protrusions can be adjusted so as to achieve different orientation adjustment effects. 
     In one embodiment, referring to  FIG. 5 , an annular position-limiting slot  160  capable of accommodating carbon nanotube aggregates is provided in the contact surface of the first wheel body  111  and/or the second wheel body  112  for contacting the carbon nanotube aggregates. 
     The annular position-limiting slot  160  has a slot span matching the size of the carbon nanotube aggregates to be accommodated. In this embodiment, the shape of the cross-section of the annular position-limiting slot  160  in the axial direction may be a symmetrical triangle. In another embodiment, the shape of the cross-section of the annular position-limiting slot  160  in the axial direction may be a symmetrical arc. In other embodiments, the annular position-limiting slot  160  may be other shapes. 
     Providing the annular position-limiting slot  160  can not only fix and limit the position of the carbon nanotube aggregates to prevent the carbon nanotube aggregates from moving up and down when being pre-pressed by the first pre-adjustment sub-mechanism  110 , but also effectively gathers the carbon nanotube aggregates in the annular position-limiting slot  160  to further ensure uniform collection and improve the orientation of the collected carbon nanotube aggregates. 
     In one embodiment, the collection device  100  further includes a first heating mechanism (not shown in the figures) which is disposed in the housing and configured to adjust the temperature of the contact surface of the first pre-adjustment mechanism  110  and/or the second pre-adjustment mechanism for contacting the carbon nanotube aggregates. 
     In one embodiment, the first heating mechanism includes a heating resistance wire and a controller. The heating resistance wire is arranged in the end or inside of the first pre-adjustment sub-mechanism  110  and/or the second pre-adjustment sub-mechanism  120 . The controller is arranged inside the housing and configured to control the heat generated by the heating resistance wire. The first heating mechanism may also include a thermocouple or a thermodetector that measures the temperature of the corresponding contact surface of the pre-adjustment mechanism. 
     In one embodiment, the temperature of the first heating mechanism may be set in the range of 100 to 500° C. Further, the temperature of the first heating mechanism may be set in the range of 200 to 400° C. It should be noted that there is preferably an inert environment inside the housing of the collection device  100 . 
     By providing the first heating mechanism, the gas inside the carbon nanotube aggregates can be expelled via proper heating, and the denseness of the collected carbon nanotube product can be improved accordingly. In addition, the temperature of the contact surface contacting the carbon nanotube aggregates can also be controlled, thereby helping to improve the adjustment effect of the pre-adjustment mechanism on the internal structure of the carbon nanotube aggregates, and improve the orientation and uniformity of the carbon nanotubes, and then achieving the regulation of the various properties of the carbon nanotube material. 
     In this embodiment, the winding mechanism  130  may be a roller that can rotate to collect the carbon nanotube aggregates. Since carbon nanotube aggregates usually contain a trace amount of iron, the roller can be made of a micro-magnetic material, which can facilitate the adsorption and collection of the carbon nanotube aggregates. 
     In one embodiment, the winding mechanism  130  may be a rotary drum (not shown in the figures) that is retractable in the axial direction. When the collected carbon nanotube aggregates are carbon nanotube fibers, the rotary drum may need not to move; and when the collected carbon nanotube aggregates are carbon nanotube films, the rotary drum may perform a one-way motion or a reciprocating motion so that a certain area of carbon nanotube film can be collected. The directions of the reciprocating motion are not perpendicular to the axial direction of the rotary drum. Preferably, the directions of the reciprocating motion are parallel to the axial direction of the rotary drum. Of course, the directions of the reciprocating motion may be angled with respect to the axial direction of the rotary drum to achieve the collection of the carbon nanotube film. The provided rotary drum can be retractable along the axial direction, so that the area of the collected carbon nanotube film can be further changed, and the thickness of the prepared carbon nanotube film can be controlled, thereby obtaining carbon nanotube film materials with different performances. 
     In another embodiment, the winding mechanism  130  may include a first rotating wheel, a second rotating wheel, and a collection belt (not shown in the figures) tensioned between the first rotating wheel and the second rotating wheel. The axial direction of the first rotating wheel and the second rotating wheel is perpendicular to the extension line direction of the outlet end. 
     In one embodiment, the spacing between the first rotating wheel and the second rotating wheel can be adjusted. Therefore, by adjusting the spacing between the first rotating wheel and the second rotating wheel, the size in its width direction of the collected carbon nanotube aggregate film can be adjusted so as to adjust the area of the carbon nanotube film. 
     In yet another embodiment, referring to  FIG. 6 , the winding mechanism  130  may include a first rotating wheel  131 , a second rotating wheel  132  and a collection plate  133  disposed therebetween and being capable of rotating towards the pre-adjustment mechanism. The collection plate  133  may be a plate that is slightly magnetic and has a certain thickness. In one embodiment, the spacing between the first rotating wheel  131  and the second rotating wheel  132  can be adjusted. Correspondingly, the collection plate  133  can be provided as a retractable plate, then by adjusting the spacing between the first rotating wheel  131  and the second rotating wheel  132 , the size in its length direction of the collected carbon nanotube aggregate film can be adjusted so as to adjust the area of the carbon nanotube film. 
     EXAMPLE 2 
       FIG. 7  shows a collection device  100  for a vertical furnace. The collection device  100  is configured to collect carbon nanotube films or carbon nanotube fibers. The collection device  100  includes a housing that communicates with the outlet end of the synthesis device  200 , and a pre-adjustment mechanism and a winding mechanism  130  both disposed in the housing. The pre-adjustment mechanism includes a first pre-adjustment sub-mechanism  110  and a second pre-adjustment sub-mechanism  120 , and is configured to adjust the orientation of a bundle of carbon nanotube aggregates. 
     In addition to being adaptable to collect the carbon nanotube films or the carbon nanotube fibers grown by the vertical furnace, this example further differs from Example 1 in that the second pre-adjustment sub-mechanism  120  is disposed close to the outlet end of the synthesis device  200  and that the first pre-adjustment sub-mechanism  110  is disposed between the second pre-adjustment sub-mechanism  120  and the winding mechanism  130 . 
     For other content in this example, reference may be made to the Example 1, and details are not described herein again. 
     The present disclosure also provides a preparation system for the preparation of carbon nanotube film material or carbon nanotube fiber material. The preparation system is described in detail with reference to the drawings. 
     EXAMPLE 3 
       FIG. 8  shows a preparation system including a horizontal furnace according to an embodiment of the present disclosure. The preparation system includes a synthesis device  200  and a collection device  100 . The synthesis device is adapted to floating catalytically synthesizing carbon nanotube aggregates. The synthesis device  200  includes a reactor  210  having at least one growth tube  211 . The collection device  100  is located at an outlet end side of the synthesis device  200 , and configured to collect the carbon nanotube aggregates prepared by the synthesis device  200 . The collection device  100  communicates with the outlet end side of the synthesis device  200 , for example, the collection device  100  can be sealingly connected to the synthesis device  200  via a flange (not shown in the figures). 
     In this embodiment, the reactor  210  may have a multi-tube horizontal structure, and the number of the growth tubes  211  is two. A plurality of growth tubes  211  are disposed inside the reactor  210  and share one reaction furnace. In this way, by providing multiple tubes, the output of carbon nanotubes can be greatly increased, and the quality of carbon nanotubes in each growth tube  211  can also be ensured, so that the performance of the entire carbon nanotube material can be improved. Of course, in other embodiments, the number of growth tubes  211  may be one or more other than two. 
     The reactor  210  may be horizontally disposed, but it may also have a multi-tube structure inclined at a certain angle certainly. The growth tube  211  may be made of quartz, corundum, or other materials commonly used in the art. In one embodiment, the shape of the growth tube  211  is square, so that the structure of the carbon nanotube aggregates generated in the growth tube  211  can be changed, thereby adjusting the uniformity of the collected carbon nanotube aggregates. Of course, in other embodiments, the growth tube  211  may has a commonly used hollow round tube structure. 
     In this embodiment, an end of the growth tube  211  near the collection device  100  is trumpet-shaped. Therefore, since it is necessary to introduce carrier gas into the process of the floating catalytic synthesis of carbon nanotube aggregates, turbulent flow will occur inside the growth tube  211  and the carbon nanotube aggregates will float upward and easily adhere to the inner wall of the growth tube  211 , resulting in collection interruption. By providing the distal end of the growth tube  211  in a trumpet shape, the probability of the carbon nanotube aggregates, adhering to the inner wall of the growth tube  211  can be reduced so as to increase the continuity of collection of the carbon nanotube aggregates. Of course, in other embodiments, the end of the growth tube  211  near the collection device  100  may have cylindrical or other conventional shapes. 
     The preparation system also includes a feeding device  300 , which is in communication with the inlet end of the synthesis device  200  for providing reaction raw materials. 
     Further, the feeding device  300  may include at least one injection mechanism  310  and at least one feeding pipe  320 . One end of the feeding pipe  320  communicates with the injection mechanism  310  and the other end communicates with the growth pipe  211 . The injection mechanism  310  may be one of a syringe pump, a liquid injector, and an ultrasonic atomization injection mechanism that can regulate the injection rate. 
     In this embodiment, the numbers of the feeding tube  320  and the injection mechanism  310  are all matching the number of the growth tubes  211 . In this case, the feeding tubes  320  can be connected in series or side-by-side. Therefore, the carbon nanotube material with different internal structures can be separately regulated by controlling the injection mechanism  310  so as to regulate the performance of the carbon nanotube material. 
     In one embodiment, the number of the feeding tube  320  and that of the injection mechanism  310  each may be one, which is simple structure and easy to operate. In another embodiment, there may be multiple feeding pipes  320  and one injection mechanism  310 . Such multiple feeding pipes  320  may share one injection mechanism  310 . Of course, the number of feeding tubes  320  and the injection mechanism  310  may also be other reasonable values. 
     It should be noted that multiple growth tubes  211  can be used to grow carbon nanotube aggregates to produce pure carbon nanotube materials. In addition, one or more of the growth tubes  211  can also be provided to prepare other materials to prepare a composite material containing carbon nanotubes so that the composite material will have different properties and the application field of the materials will be widened. 
     In one embodiment, referring to  FIG. 9 , the synthesis device  200  includes a reactor  210  having a plurality of growth tubes  211  which may be arranged in an annular manner. In other embodiments, the plurality of growth tubes  211  may be arranged in a side-by-side or a matrix manner. 
     Further, continuing to refer to  FIG. 8 , the synthesis device  200  further includes a second heating mechanism  212  for adjusting the temperature distribution of each region of the inlet ends of the plurality of growth tubes  211 . In this embodiment, the second heating mechanism  212  may be three spaced-apart heaters disposed on the inner wall of the reactor  210  to adjust the temperature of each area of the inlet ends of the growth tubes  211 , thereby controlling the growth of the carbon nanotube aggregates. 
     For details of the collection device  100 , reference may be made to the Example 1, and details are not described herein again. 
     The carbon nanotube film material can be prepared by the preparation system of this embodiment The preparation step includes: dissolving a catalyst and a growth promoter in a carbon source to prepare a reaction solution firstly; introducing the reaction solution and carrier gas into the growth tubes  211  in the reactor  210  through the feeding device  300  to conduct a catalytic cracking reaction to generate continuous carbon nanotube aggregates; and collecting the continuous carbon nanotube aggregates to obtain carbon nanotube films. Since the preparation process of the carbon nanotube film is relatively common, the raw material, the ratio and the technological condition in the above-mentioned preparation process may be those commonly used in the field, and will not be described here. 
     The carbon nanotube film product prepared by using the preparation system of the present embodiment (including a pre-adjustment mechanism) was labeled as Sample  1 . In order to explain the role played by the pre-adjustment mechanism, the pre-adjustment mechanism was removed from the preparation system in this embodiment while other mechanisms therein was maintained unchanged, then the obtained preparation system was used as a comparative preparation system (without a pre-adjustment mechanism) and a carbon nanotube material film product was prepared according to the technological conditions of the preparation of Sample  1 . The as-prepared product is labeled Sample  2 . 
       FIGS. 10 and 11  are SEM images of Sample  1  and Sample  2 , respectively. By comparison, the orientation of the carbon nanotube material film adjusted by the pre-adjustment mechanism (Sample  1 ) is better than the carbon nanotube material film without adjusting by the pre-adjustment mechanism (Sample  2 ). 
       FIG. 12  is a graph of tensile stress-breaking elongation for Samples  1  and  2 . By comparison, the mechanical properties of the carbon nanotube material film adjusted by the pre-adjustment mechanism (Sample  1 ) is better than the carbon nanotube material film without adjusting by the pre-adjustment mechanism (Sample  2 ). 
     EXAMPLE 4 
       FIG. 13  shows a preparation system including a vertical furnace according to another embodiment of the present disclosure. The preparation system includes a synthesis device  200  and a collection device  100 . The synthesis device  200  is used for the floating catalytic synthesis of carbon nanotube aggregates. The synthesis device  200  includes a reactor  210  having at least one growth tube  211 . The collection device  100  communicates with the outlet end of the synthesis device  200 , for collecting the carbon nanotube aggregates prepared by the synthesis device  200 . Specifically, the collection device  100  can be sealingly connected to the synthesis device  200  via a flange (not shown in the figures). 
     In this embodiment, the reactor  210  may have a single-tube vertical structure. In other embodiment, the reactor  210  may have a multi-tube vertical structure. The reactor  210  may be vertically disposed, but it may also have a structure inclined at a certain angle certainly. 
     For other details of the collection device  100 , reference may be made to the Example 2, and details are not described herein again. 
     For other content in this embodiment, reference may be made to the Example 3, and details are not described herein again. 
     The technical features of the above-described embodiments may be combined arbitrarily. To simplify the description, all the possible combinations of the technical features in the above embodiments are not described. However, all of the combinations of these technical features should be considered as within the scope of the disclosure, as long as such combinations do not contradict with each other. 
     The above embodiments merely represent several embodiments of the present disclosure, and the description thereof is more specific and detailed, but it should not be construed as limiting the scope of the present disclosure. It should be noted that, for those skilled in the art, several variations and improvements may be made without departing from the concept of the present disclosure, and these are all within the protection scope of the present disclosure. Therefore, the scope of protection of the present disclosure shall be subject to the appended claims.