Patent Publication Number: US-2009227563-A1

Title: Herbicidal compositions having improved effect

Description:
The present invention concerns boosting the activity of crop protection materials comprising inhibitors of fatty acid biosynthesis, especially phenyl-substituted cyclic ketoenols, through the addition of ammonium salts or phosphonium salts and, if desired, penetrants, the corresponding materials, processes for preparing them, and their use in crop protection for preventing unwanted plant growth. 
     For 3-acylpyrrolidine-2,4-diones pharmaceutical properties have already been described (S. Suzuki et al. Chem. Pharm. Bull. 15 1120 (1967)). Additionally N-phenylpyrrolidine-2,4-diones have been synthesized, by R. Schmierer and H. Mildenberger (Liebigs Ann. Chem. 1985, 1095). No biological activity has been described for these compounds. 
     EP-A-0 262 399 and GB-A-2 266 888 disclose similarly structured compounds (3-arylpyrrolidine-2,4-diones) for which, however, no herbicidal, insecticidal or acaricidal activity has been made known. Compounds known with a herbicidal, insecticidal or acaricidal activity include unsubstituted, bicyclic 3-arylpyrrolidine-2,4-dione derivatives (EP-A-355 599, EP-A-415 211 and JP-A-12-053 670) and also substituted monocyclic 3-arylpyrrolidine-2,4-dione derivatives (EP-A-377 893 and EP-A-442 077). 
     Additionally known are polycyclic 3-arylpyrrolidine-2,4-dione derivatives (EP-A-442 073) and also 1H-arylpyrrolidinedione derivatives (EP-A-456 063, EP-A-521 334, EP-A-596 298, EP-A-613 884, EP-A-613 885, WO 95/01 997, WO 95/26 954, WO 95/20 572, EP-A-0 668 267, WO 96/25 395, WO 96/35 664, WO 97/01 535, WO 97/02 243, WO 97/36 868, WO 97/43275, WO 98/05638, WO 98/06721, WO 98/25928, WO 99/16748, WO 99/24437, WO 99/43649, WO 99/48869 and WO 99/55673, WO 01/17972, WO 01/23354, WO 01/74770, WO 03/013249, WO 04/007448, WO 04/024688, WO 04/065366, WO 04/080962, WO 04/111042, WO 05/044791, WO 05/044796, WO 05/048710, WO 05/049569, WO 05/066125, WO 05/092897, WO 06/000355, WO 06/029799, WO 06/056281, WO 06/056282, WO 06/089633). 
     It is known that certain substituted Δ 3 -dihydrofuran-2-one derivatives possess herbicidal properties (cf. DE-A-4 014 420). The synthesis of the tetronic acid derivatives used as starting compounds (such as 3-(2-methylphenyl)-4-hydroxy-5-(4-fluorophenyl)-Δ 3 -dihydrofuran-2-one) is likewise described in DE-A-4 014 420. Similarly structured compounds, without a report of an insecticidal and/or acaricidal activity, are known from the publication by Campbell et al., J. Chem. Soc., Perkin Trans. 1, 1985, (8) 1567-76. Moreover, 3-aryl-Δ 3 -dihydrofuranone derivatives having herbicidal, acaricidal and insecticidal properties are known from EP-A-528 156, EP-A-0 647 637, WO 95/26 345, WO 96/20 196, WO 96/25 395, WO 96/35 664, WO 97/01 535, WO 97/02 243, WO 97/36 868, WO 98/05638, WO 98/25928, WO 99/16748, WO 99/43649, WO 99/48869, WO 99/55673, WO 01/17972, WO 01/23354 and WO 01/74770, WO 03/013 249, WO 04/024 688, WO 04/080 962, WO 04/111 042, WO 05/092897, WO 06/000355, WO 06/029799 and WO 06/089633. As well 3-aryl-Δ 3 -dihydrothiophene-one derivatives are known (WO 95/26 345, 96/25 395, WO 97/01 535, WO 97/02 243, WO 97/36 868, WO 98/05638, WO 98/25928, WO 99/16748, WO 99/43649, WO 99/48869, WO 99/55673, WO 01/17972, WO 01/23354, WO 01/74770, WO 03/013249, WO 04/080 962, WO 04/111 042, WO 05/092897, WO 06/029799). 
     Certain phenylpyrone derivatives unsubstituted in the phenyl ring have already been disclosed (cf. A. M. Chirazi, T. Kappe and E. Ziegler, Arch. Pharm. 309, 558 (1976) and K.-H. Boltze and K. Heidenbluth, Chem. Ber. 91, 2849), no possible usefulness as pesticides being reported for these compounds. Phenylpyrone derivatives substituted in the phenyl ring and having herbicidal, acaricidal and insecticidal properties are described in EP-A-588 137, WO 96/25 395, WO 96/35 664, WO 97/01 535, WO 97/02 243, WO 97/16 436, WO 97/19 941, WO 97/36 868, WO 98/05638, WO 99/43649, WO 99/48869, WO 99/55673, WO 01/17972, WO 01/74770, WO 03/013249, WO 04/080 962, WO 04/111 042, WO 05/092897 and WO 06/029799. 
     Certain 5-phenyl-1,3-thiazine derivatives unsubstituted in the phenyl ring have already been disclosed (cf. E. Ziegler and E. Steiner, Monatsh. 95, 147 (1964), R. Ketcham, T. Kappe and E. Ziegler, J. Heterocycl. Chem. 10, 223 (1973)), no possible application as pesticides being reported for these compounds. 5-Phenyl-1,3-thiazine derivatives substituted in the phenyl ring and having a herbicidal, acaricidal and insecticidal activity are described in WO 94/14 785, WO 96/02 539, WO 96/35 664, WO 97/01 535, WO 97/02 243, WO 97/02 243, WO 97/36 868, WO 99/05638, WO 99/43649, WO 99/48869, WO 99/55673, WO 01/17972, WO 01/74770, WO 03/013249, WO 04/080 962, WO 04/111 042, WO 05/092897 and WO 06/029799. 
     It is known that certain substituted 2-arylcyclopentanediones have herbicidal, insecticidal and acaricidal properties (cf. e.g. U.S. Pat. Nos. 4,283,348; 4,338,122; 4,436,666; 4,526,723; 4,551,547; 4,632,698; WO 96/01 798; WO 96/03 366, WO 97/14 667 and also WO 98/39281, WO 99/43649, WO 99/48869, WO 99/55673, WO 01/17972, WO 01/74770, WO 03/013249, WO 04/080 962, WO 04/111 042, WO 05/092897 and WO 06/029799). Moreover, similarly substituted compounds are known: 3-hydroxy-5,5-dimethyl-2-phenylcyclopent-2-en-1-one, from the publication by Micklefield et al., Tetrahedron, (1992), 7519-26, and the natural substance Involutin, (−)-cis-5-(3,4-dihydroxyphenyl)-3,4-dihydroxy-2-(4-hydroxyphenyl)cyclopent-2-en-one, from the publication by Edwards et al., J. Chem. Soc. S, (1967), 405-9. No insecticidal or acaricidal activity is described. Furthermore, 2-(2,4,6-trimethylphenyl)-1,3-indanedione is known from the publication J. Economic Entomology, 66, (1973), 584 and from the laid-open specification DE-A 2 361 084, with reports of herbicidal and acaricidal activities. 
     It is known that certain substituted 2-arylcyclohexanediones possess herbicidal, insecticidal and acaricidal properties (U.S. Pat. Nos. 4,175,135, 4,209,432, 4,256,657, 4,256,658, 4,256,659, 4,257,858, 4,283,348, 4,303,669, 4,351,666, 4,409,153, 4,436,666, 4,526,723, 4,613,617, 4,659,372, DE-A 2 813 341, and also Wheeler, T. N., J. Org. Chem. 44, 4906 (1979)), WO 99/43649, WO 99/48869, WO 99/55673, WO 01/17972, WO 01/74770, WO 03/013249, WO 04/080 962, WO 04/111 042, WO 05/092897 and WO 06/029799). 
     It is known that certain substituted 4-arylpyrazolidine-3,5-diones possess acaricidal, insecticidal and herbicidal properties (cf. e.g. WO 92/16 510, EP-A-508 126, WO 96/11 574, WO 96/21 652, WO 99/47525, WO 01/17351, WO 01/17352, WO 01/17353, WO 01/17972, WO 01/17973, WO 03/028 466, WO 03/062 244, WO 04/080 962, WO 04/111 042, WO 05/005428, WO 05/016873, WO 05/092897 and WO 06/029799). 
     It is known that certain tetrahydropyridones possess herbicidal properties (JP 0832530). Moreover, specific 4-hydroxytetrahydropyridones with acaricidal, insecticidal and herbicidal properties are known (JP 11152273). Furthermore, 4-hydroxytetrahydropyridones have become known as pesticides and herbicides, in WO 01/79204. 
     It is known that certain 5,6-dihydropyrone derivatives have antiviral properties as protease inhibitors (WO 95/14012). Moreover, 4-phenyl-6-(2-phenethyl)-5,6-dihydropyrone is known from the synthesis of kavalactone derivatives (Kappe et al., Arch. Pharm. 309, 558-564 (1976)). Moreover, 5,6-dihydropyrone derivatives are known as intermediates (White, J. D., Brenner, J. B., Deinsdale, M. J., J. Amer. Chem. Soc. 93, 281-282 (1971)). 3-Phenyl-5,6-dihydropyrone derivatives with applications in crop protection are described in WO 01/98288. 
     All of the active ingredients present in the materials of the invention are already known and can be prepared by methods described in the prior art (see references cited above). Their activity is good, but not always entirely satisfactory, particularly at low application rates and concentrations. Moreover, the plant tolerance of these compounds is not always sufficient. There is therefore a need for a boost in activity of the crop protection materials comprising the compounds. 
     Descriptions have already been given in the literature to the effect that the activity of various active ingredients can be boosted through addition of ammonium salts. The salts in question, however, are salts with a detergent effect (e.g. WO 95/017817) and/or salts having relatively long alkyl and/or aryl substituents, which have a permeabilizing effect or which increase the solubility of the active ingredient (e.g. EP-A 0 453 086, EP-A 0 664 081, FR-A 2 600 494, U.S. Pat. No. 4,844,734, U.S. Pat. No. 5,462,912, U.S. Pat. No. 5,538,937, US-A 03/0224939, US-A 05/0009880, US-A 05/0096386). Furthermore, the prior art describes the activity only for certain active ingredients and/or certain applications of the materials in question. A boost in activity through ammonium sulphate, for example, is described for the herbicides glyphosate and phosphinothricin, for example (U.S. Pat. No. 6,645,914, EP-A2 0 036 106). 
     As well, the use of ammonium sulphate as a formulating assistant has been described for certain active ingredients and applications (WO 92/16108), but it is used there for the purpose of stabilizing the formulation, not for boosting activity. 
     It has now been found, entirely surprisingly, that the activity of herbicides from the class of the phenyl-substituted cyclic ketoenols can be boosted significantly through the addition of ammonium salts or phosphonium salts to the as-used solution or through the incorporation of these salts into a formulation comprising phenyl-substituted cyclic ketoenols. The present invention provides, therefore, for the use of ammonium salts or phosphonium salts to boost the activity of crop protection materials which comprise herbicidally active phenyl-substituted cyclic ketoenols as active ingredient. The invention likewise provides materials which comprise herbicidally active phenyl-substituted cyclic ketoenols and activity-boosting ammonium salts or phosphonium salts, specifically including not only formulated active ingredients but also application-ready materials (spray liquors). The invention further provides, finally, for the use of these materials for controlling unwanted plant growth. 
     Active ingredients of the invention from the class of the phenyl-substituted cyclic ketoenols whose activity can be boosted through the addition of ammonium salts or phosphonium salts to the formulated or application-ready active-ingredient preparations are defined by formula (I) 
     
       
         
         
             
             
         
       
         
         in which 
         W is hydrogen, alkyl, alkenyl, alkynyl, halogen, alkoxy, haloalkyl, haloalkoxy or cyano, 
         X is halogen, alkyl, alkenyl, alkynyl, alkoxy, alkoxy-alkoxy, haloalkyl, haloalkoxy or cyano, 
         Y is hydrogen, halogen, alkyl, alkenyl, alkynyl, alkoxy, cyano, haloalkyl, haloalkoxy or in each case optionally substituted phenyl or hetaryl, 
         Z is hydrogen, halogen, alkyl, haloalkyl, cyano, alkoxy or haloalkoxy, 
         CKE is one of the groups 
       
    
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
         
         
           
             in which 
             A is hydrogen, in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, saturated or unsaturated, optionally substituted cycloalkyl in which optionally at least one ring atom is replaced by a heteroatom, or in each case optionally halogen-, alkyl-, haloalkyl-, alkoxy-, haloalkoxy-, cyano- or nitro-substituted aryl, arylalkyl or hetaryl, 
             B is hydrogen, alkyl or alkoxyalkyl, or 
             A and B, together with the carbon atom to which they are attached, are a saturated or unsaturated, unsubstituted or substituted ring optionally containing at least one heteroatom, 
             D is hydrogen or an optionally substituted radical from the series alkyl, alkenyl, alkynyl, alkoxyalkyl, saturated or unsaturated cycloalkyl in which optionally one or more ring members are replaced by heteroatoms, or is arylalkyl, aryl, hetarylalkyl or hetaryl, or 
             A and D, together with the atoms to which they are attached, are a saturated or unsaturated ring which optionally contains at least one (in the case of CKE=8 one further) heteroatom and is substituted or unsubstituted in the A,D moiety, or 
             A and Q 1  together are alkenediyl or alkanediyl optionally substituted by hydroxyl or by in each case optionally substituted alkyl, alkoxy, alkylthio, cycloalkyl, benzyloxy or aryl, or 
             D and Q 1 , together with the atoms to which they are attached, are a saturated or unsaturated ring which optionally contains at least one heteroatom and is substituted or unsubstituted in the D, Q 1  moiety, 
             Q 1  is hydrogen, alkyl, alkoxyalkyl, optionally substituted cycloalkyl (in which optionally one methylene group is replaced by oxygen or sulphur) or optionally substituted phenyl, 
             Q 2 , Q 4 , Q 5  and Q 6  independently of one another are hydrogen or alkyl, 
             Q 3  is hydrogen, is optionally substituted alkyl, alkoxyalkyl, alkylthioalkyl, optionally substituted cycloalkyl (in which optionally one methylene group is replaced by oxygen or sulphur) or optionally substituted phenyl, or 
             Q 1  and Q 2 , together with the carbon atom to which they are attached, are a substituted or unsubstituted ring optionally containing a heteroatom, or 
             Q 3  and Q 4 , together with the carbon atom to which they are attached, are a saturated or unsaturated, unsubstituted or substituted ring optionally containing a heteroatom, 
             G is hydrogen (a) or is one of the groups 
           
         
       
    
     
       
         
         
             
             
         
       
         
         
           
             
               
                 in which 
                 E is one metal ion equivalent or an ammonium ion, 
                 L is oxygen or sulphur, 
                 M is oxygen or sulphur, 
                 R 1  is in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl or optionally halogen-, alkyl- or alkoxy-substituted cycloalkyl, which may be interrupted by at least one heteroatom, or is in each case optionally substituted phenyl, phenylalkyl, hetaryl, phenoxyalkyl or hetaryloxyalkyl, 
                 R 2  is in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl or is in each case optionally substituted cycloalkyl, phenyl or benzyl, 
                 R 3 , R 4  and R 5  independently of one another are in each case optionally halogen-substituted alkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkenylthio, cycloalkylthio or are in each case optionally substituted phenyl, benzyl, phenoxy or phenylthio, 
                 R 6  and R 7  independently of one another are hydrogen, in each case optionally halogen-substituted alkyl, cycloalkyl, alkenyl, alkoxy, alkoxyalkyl, are optionally substituted phenyl, are optionally substituted benzyl, or, together with the N atom to which they are attached, are a ring which is optionally interrupted by oxygen or sulphur. 
               
             
           
         
       
    
     Depending on factors including the nature of the substituents, the compounds of formula (I) may be present in the form of geometrical and/or optical isomers or isomer mixtures, in different compositions, which can optionally be separated in a customary way. Not only the pure isomers but also the isomer mixtures can be used in materials of the invention and can be boosted in their activity through ammonium salts or phosphonium salts of the invention. Reference below is always, for the sake of simplicity to compounds of the formula (I), although what are meant are not only the pure compounds but also, where appropriate, mixtures containing different fractions of isomeric compounds. 
     Including the definitions (1) to (10) of the group CKE produces the following principal structures (I-1) to (I-10): 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     in which
 
A, B, D, G, Q 1 , Q 2 , Q 3 , Q 4 , Q 5 , Q 6 , W, X, Y and Z are as defined above.
 
     Including the various definitions (a), (b), (c), (d), (e), (f) and (g) of the group G produces the following principal structures (I-1-a) to (I-1-g) if CKE is the group (1): 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     in which
 
A, B, D, E, L, M, W, X, Y, Z, R 1 , R 2 , R 3 , R 4 , R 5 , R 6  and R 7  are as defined above.
 
     Including the various definitions (a), (b), (c), (d), (e), (f) and (g) of the group G produces the following principal structures (I-2-a) to (I-2-g) if CKE is the group (2): 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     in which
 
A, B, E, L, M, W, X, Y, Z, R 1 , R 2 , R 3 , R 4 , R 5 , R 6  and R 7  are as defined above.
 
     Including the various definitions (a), (b), (c), (d), (e), (f) and (g) of the group G produces the following principal structures (I-3-a) to (I-3-g) if CKE is the group (3): 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     in which
 
A, B, E, L, M, W, X, Y, Z, R 1 , R 2 , R 3 , R 4 , R 5 , R 6  and R 7  are as defined above.
 
     Depending on the position of the substituent G the compounds of the formula (I-4) may be present in the two isomeric forms of the formulae (I-4-A) and (I-4-B) 
     
       
         
         
             
             
         
       
     
     which the dashed line in the formula (I-4) is intended to express. 
     The compounds of the formula (I-4-A) and (I-4-B) may be present both as mixtures and in the form of their pure isomers. Mixtures of the compounds of the formulae (I-4-A) and (I-4-B) can be separated where appropriate in conventional manner by means of physical methods, such as by chromatographic methods, for example. 
     For reasons of greater clarity in each case only one of the possible isomers is set out below. This does not rule out the possibility of the compounds being present where appropriate in the form of the isomer mixtures or in the respective other isomeric form. 
     Including the various definitions (a), (b), (c), (d), (e), (f) and (g) of the group G produces the following principal structures (I-4-a) to (I-4-g) if CKE is the group (4): 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     in which
 
A, D, E, L, M, W, X, Y, Z, R 1 , R 2 , R 3 , R 4 , R 5 , R 6  and R 7  are as defined above.
 
     Including the various definitions (a), (b), (c), (d), (e), (f) and (g) of the group G produces the following principal structures (I-5-a) to (I-5-g) if CKE is the group (5): 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     in which
 
A, E, L, M, W, X, Y, Z, R 1 , R 2 , R 3 , R 4 , R 5 , R 6  and R 7  are as defined above.
 
     Depending on the position of the substituent G the compounds of the formula (I-6) may be present in the two isomeric forms of the formulae (I-6-A) and (I-6-B) 
     
       
         
         
             
             
         
       
     
     which the dashed line in the formula (I) is intended to express. 
     The compounds of the formulae (I-6-A) and (I-6-B) may be present both as mixtures and in the form of their pure isomers. Mixtures of the compounds of the formulae (I-6-A) and (I-6-B) can be separated where appropriate by means of physical methods, such as by chromatographic methods, for example. 
     For reasons of greater clarity in each case only one of the possible isomers is set out below. This does not rule out the possibility of the compounds being present where appropriate in the form of the isomer mixtures or in the respective other isomeric form. 
     Including the various definitions (a), (b), (c), (d), (e), (f) and (g) of the group G produces the following principal structures (I-6-a) to (I-6-g): 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     in which
 
A, B, Q 1 , Q 2 , E, L, M, W, X, Y, Z, R 1 , R 2 , R 3 , R 4 , R 5 , R 6  and R 7  are as defined above.
 
     Depending on the position of the substituent G the compounds of the formula (I-7) may be present in the two isomeric forms of the formulae (I-7-A) and (I-7-B) which the dashed line in the formula (I-7) is intended to express: 
     
       
         
         
             
             
         
       
     
     The compounds of the formulae (I-7-A) and (I-7-B) may be present both as mixtures and in the form of their pure isomers. Mixtures of the compounds of the formulae (I-7-A) and (I-7-B) can be separated where appropriate by means of physical methods, such as by chromatographic methods, for example. 
     For reasons of greater clarity in each case only one of the possible isomers is set out below. This does not rule out the possibility of the relevant compound being present where appropriate as isomer mixtures or in the respective other isomeric form. 
     Including the various definitions (a), (b), (c), (d), (e), (f) and (g) of the group G produces the following principal structures (I-7-a) to (I-7-g): 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     in which
 
A, B, E, L, M, Q 3 , Q 4 , Q 5 , Q 6 , W, X, Y, Z, R 1 , R 2 , R 3 , R 4 , R 5 , R 6  and R 7  are as defined above.
 
     Depending on the position of the substituent G the compounds of the formula (I-8) can be present in the two isomeric formulae (I-8-A) and (I-8-B) 
     
       
         
         
             
             
         
       
     
     which the dashed line in the formulae (I-8) is intended to express. 
     The compounds of the formulae (I-8-A) and (I-8-B) may be present both as mixtures and in the form of their pure isomers. Mixtures of the compounds of the formulae (I-8-A) and (I-8-B) can be separated where appropriate in conventional manner by means of physical methods, such as by chromatographic methods, for example. 
     For reasons of greater clarity in each case only one of the possible isomers is set out below. This does not rule out the possibility of the compounds being present where appropriate in the form of the isomer mixtures or in the respective other isomeric form. 
     Including the various definitions (a), (b), (c), (d), (e), (f) and (g) of the group G produces the following principal structures (I-8-a) to (I-8-g) if Het is the group (8): 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     in which
 
A, D, E, L, M, W, X, Y, Z, R 1 , R 2 , R 3 , R 4 , R 5 , R 6  and R 7  are as defined above.
 
     Depending on the position of the substituent G the compounds of the formulae (I-9) may be present in the two isomeric forms of the formulae (I-9-A) and (I-9-B) which the dashed line in the formula (I-9) is intended to express. 
     
       
         
         
             
             
         
       
     
     The compounds of the formula (I-9-A) and (I-9-B) may be present both as mixtures and in the form of their pure isomers. Mixtures of the compounds of the formulae (I-9-A) and (I-9-B) can be separated where appropriate in conventional manner by means of physical methods, such as by chromatographic methods, for example. 
     For reasons of greater clarity in each case only one of the possible isomers is set out below. This does not rule out the possibility of the compounds being present where appropriate in the form of the isomer mixtures or in the respective other isomeric form. 
     Including the various definitions (a), (b), (c), (d), (e), (f) and (g) of the group G produces the following principal structures (I-9-a) to (I-9-g) if CKE is the group (9): 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     in which
 
A, B, D, E, L, M, Q 1 , Q 2 , W, X, Y, Z, R 1 , R 2 , R 3 , R 4 , R 5 , R 6  and R 7  are as defined above.
 
     Depending on the position of the substituent G the compounds of the formula (I-10) may be present in the two isomeric forms of the formulae (I-10-A) and (I-10-B) 
     
       
         
         
             
             
         
       
     
     which the dashed line in the formula (I-10) is intended to express. 
     The compounds of the formulae (I-10-A) and (I-10-B) may be present both as mixtures and in the form of their pure isomers. Mixtures of the compounds of the formulae (I-10-A) and (I-10-B) can be separated where appropriate in conventional manner by means of physical methods, such as by chromatographic methods, for example. 
     For reasons of greater clarity in each case only one of the possible isomers is set out below. This does not rule out the possibility of the compounds being present where appropriate in the form of the isomer mixtures or in the respective other isomeric form. 
     Including the various definitions (a), (b), (c), (d), (e), (f) and (g) of the group G produces the following principal structures (I-10-a) to (I-10-g) if CKE is the group (10): 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     in which
 
A, B, D, E, L, M, Q 1 , Q 2 , W, X, Y, Z, R 1 , R 2 , R 3 , R 4 , R 5 , R 6  and R 7  are as defined above.
 
     A general definition of the compounds of the invention is given by the formula (I). Preferred substituents and/or ranges of the radicals listed in the formulae mentioned above and below are elucidated in the following text:
     W is preferably hydrogen, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, halogen, C 1 -C 6 -alkoxy, C 1 -C 4 -haloalkyl, C 1 -C 4 -haloalkoxy or cyano,   X is preferably halogen, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 1 -C 6 -alkoxy, C 1 -C 6 -alkoxy-C 1 -C 4 -alkoxy, C 1 -C 4 -haloalkyl, C 1 -C 4 -haloalkoxy or cyano,   Y is preferably hydrogen, halogen, C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 1 -C 6 -alkoxy, cyano, C 1 -C 4 -haloalkyl, haloalkoxy, or is V 1 - and V 2 -substituted phenyl or pyridyl,   V 1  is preferably halogen, C 1 -C 12 -alkyl, C 1 -C 6 -alkoxy, C 1 -C 4 -haloalkyl, C 1 -C 4 -haloalkoxy, cyano or nitro.   V 2  is preferably hydrogen, halogen, C 1 -C 6 -alkyl, C 1 -C 6 -alkoxy or C 1 -C 4 -haloalkyl,   V 1  and V 2  are preferably together C 3 -C 4 -alkanediyl which optionally can be substituted by halogen and/or C 1 -C 2 -alkyl and which optionally can be interrupted by one or two oxygen atoms.   Z is preferably hydrogen, halogen, C 1 -C 6 -alkyl, C 1 -C 4 -haloalkyl, cyano, C 1 -C 6 -alkoxy or C 1 -C 4 -haloalkoxy.   CKE is preferably one of the groups   

     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
         
         A is preferably hydrogen or in each case optionally halogen-substituted C 1 -C 12 -alkyl, C 3 -C 8 -alkenyl, C 1 -C 10 -alkoxy-C 1 -C 8 -alkyl, C 1 -C 10 -alkylthio-C 1 -C 6 -alkyl, optionally halogen-, C 1 -C 6 -alkyl- or C 1 -C 6 -alkoxy-substituted C 3 -C 8 -cycloalkyl in which optionally one or two ring members not directly adjacent are replaced by oxygen and/or sulphur, or is in each case optionally halogen-, C 1 -C 6 -alkyl-, C 1 -C 6 -haloalkyl-, C 1 -C 6 -alkoxy-, C 1 -C 6 -haloalkoxy-, cyano- or nitro-substituted phenyl, naphthyl, hetaryl having 5 to 6 ring atoms (for example furanyl, pyridyl, imidazolyl, triazolyl, pyrazolyl, pyrimidyl, thiazolyl or thienyl), phenyl-C 1 -C 6 -alkyl or naphthyl-C 1 -C 6 -alkyl, 
         B is preferably hydrogen, C 1 -C 12 -alkyl or C 1 -C 8 -alkoxy-C 1 -C 6 -alkyl or 
         A, B and the carbon atom to which they are attached are preferably saturated C 3 -C 10 -cycloalkyl or unsaturated C 5 -C 10 -cycloalkyl, in which optionally one ring member is replaced by oxygen or sulphur and which optionally are singly or doubly substituted by C 1 -C 8 -alkyl, C 1 -C 6 -alkoxy-C 1 -C 6 -alkyl, C 3 -C 6 -cycloalkyl-C 1 -C 2 -alkoxy, C 3 -C 10 -cycloalkyl, C 1 -C 8 -haloalkyl, C 1 -C 8 -alkoxy, C 1 -C 6 -alkoxy-C 1 -C 4 -alkoxy, C 1 -C 8 -alkylthio, halogen or phenyl, or 
         A, B and the carbon atom to which they are attached are preferably C 3 -C 6 -cycloalkyl which is substituted by an alkylenediyl group which is optionally substituted by C 1 -C 4 -alkyl and optionally contains one or two oxygen and/or sulphur atoms not directly adjacent, or by an alkylenedioxyl group or by an alkylenedithioyl group, which with the carbon atom to which it is attached forms a further five- to eight-membered ring, or 
         A, B and the carbon atom to which they are attached are preferably C 3 -C 8 -cycloalkyl or C 5 -C 8 -cycloalkenyl in which two substituents, together with the carbon atoms to which they are attached, are in each case optionally C 1 -C 6 -alkyl-, C 1 -C 6 -alkoxy- or halogen-substituted C 2 -C 6 -alkanediyl, C 2 -C 6 -alkenediyl or C 4 -C 6 -alkanedienediyl, in which optionally one methylene group is replaced by oxygen or sulphur, 
         D is preferably hydrogen, in each case optionally halogen-substituted C 1 -C 12 -alkyl, C 3 -C 8 -alkenyl, C 3 -C 8 -alkynyl, C 1 -C 10 -alkoxy-C 2 -C 8 -alkyl, optionally halogen-, C 1 -C 4 -alkyl-, C 1 -C 4 -alkoxy- or C 1 -C 4 -haloalkyl-substituted C 3 -C 8 -cycloalkyl in which optionally one ring member is replaced by oxygen or sulphur, or is in each case optionally halogen-, C 1 -C 6 -alkyl-, C 1 -C 6 -haloalkyl-, C 1 -C 6 -alkoxy-, C 1 -C 6 -haloalkoxy-, cyano- or nitro-substituted phenyl, hetaryl having 5 or 6 ring atoms (for example furanyl, imidazolyl, pyridyl, thiazolyl, pyrazolyl, pyrimidyl, pyrrolyl, thienyl or triazolyl), phenyl-C 1 -C 6 -alkyl or hetaryl-C 1 -C 6 -alkyl having 5 or 6 ring atoms (for example furanyl, imidazolyl, pyridyl, thiazolyl, pyrazolyl, pyrimidyl, pyrrolyl, thienyl or triazolyl) or 
         A and D are preferably together in each case optionally substituted C 3 -C 6 -alkanediyl or C 3 -C 6 -alkenediyl, in which optionally one methylene group is replaced by a carbonyl group, oxygen or sulphur, and
       suitable substituents are in each case as follows:   halogen, hydroxyl, mercapto or in each case optionally halogen-substituted C 1 -C 10 -alkyl, C 1 -C 6 -alkoxy, C 1 -C 6 -alkylthio, C 3 -C 7 -cycloalkyl, phenyl or benzyloxy, or a further C 3 -C 6 -alkanediyl moiety, C 3 -C 6 -alkenediyl moiety or a butadienyl moiety, which is optionally substituted by C 1 -C 6 -alkyl or in which optionally two adjacent substituents, with the carbon atoms to which they are attached, form a further saturated or unsaturated ring having 5 or 6 ring atoms (in the case of the compound of the formula (I-1) A and D, together with the atoms to which they are attached, then are, for example, the groups AD-1 to AD-10 specified later on below), which can contain oxygen or sulphur, or in which optionally one of the following groups   
     
       
    
     
       
         
         
             
             
         
       
     
     is present, or
     A and Q 1  are together preferably C 4 -C 6 -alkenediyl or C 3 -C 6 -alkanediyl which are in each case optionally substituted one or two times by identical or different substituents selected from halogen, hydroxyl, C 3 -C 7 -cycloalkyl, C 1 -C 6 -alkylthio, C 1 -C 6 -alkoxy or C 1 -C 10 -alkyl in each case optionally substituted one to three times by identical or different halogen substituents, and phenyl or benzyloxy in each case optionally substituted one to three times by identical or different halogen, C 1 -C 6 -alkyl or C 1 -C 6 -alkoxy substituents, and which, moreover, optionally contains one of the following groups   

     
       
         
         
             
             
         
       
     
     or is bridged by a C 1 -C 2 -alkanediyl group or by an oxygen atom, or
     D and Q 1  are preferably together C 3 -C 6 -alkanediyl which is in each case optionally substituted one or two times by identical or different substituents selected from C 1 -C 4 -alkyl and C 1 -C 4 -alkoxy.   Q 1  is preferably hydrogen, C 1 -C 6 -alkyl, C 1 -C 6 -alkoxy-C 1 -C 2 -alkyl, optionally fluorine-, chlorine-, C 1 -C 4 -alkyl-, C 1 -C 2 -haloalkyl- or C 1 -C 4 -alkoxy-substituted C 3 -C 8 -cycloalkyl, in which optionally one methylene group is replaced by oxygen or sulphur, or is optionally halogen-, C 1 -C 4 -alkyl-, C 1 -C 4 -alkoxy-, C 1 -C 2 -haloalkyl-, C 1 -C 2 -haloalkoxy-, cyano- or nitro-substituted phenyl, or   Q 2 , Q 4 , Q 5  and Q 6  independently of one another are preferably hydrogen or C 1 -C 4 -alkyl,   Q 3  is preferably hydrogen, C 1 -C 6 -alkyl, C 1 -C 6 -alkoxy-C 1 -C 2 -alkyl, C 1 -C 6 -alkylthio-C 1 -C 2 -alkyl, optionally C 1 -C 4 -alkyl- or C 1 -C 4 -alkoxy-substituted C 3 -C 8 -cycloalkyl, in which optionally one methylene group is replaced by oxygen or sulphur, or is optionally halogen-, C 1 -C 4 -alkyl-, C 1 -C 4 -alkoxy-, C 1 -C 2 -haloalkyl-, C 1 -C 2 -haloalkoxy-, cyano- or nitro-substituted phenyl.   Q1 and Q2, with the carbon atom to which they are attached, are preferably optionally C 1 -C 6 -alkyl-, C 1 -C 6 -alkoxy- or C 1 -C 2 -haloalkyl-substituted C 3 -C 7  ring in which optionally one ring member is replaced by oxygen or sulphur,   Q 3  and Q 4 , together with the carbon atom to which they are attached, are preferably an optionally C 1 -C 4 -alkyl-, C 1 -C 4 -alkoxy- or C 1 -C 2 -haloalkyl-substituted C 3 -C 7  ring in which optionally one ring member is replaced by oxygen or sulphur,   G is preferably hydrogen (a) or is one of the groups   

     
       
         
         
             
             
         
       
     
     in particular is (a), (b), (c) or (g)
         in which   E is one metal ion equivalent or ammonium ion,   L is oxygen or sulphur and   M is oxygen or sulphur.       R 1  is preferably in each case optionally halogen-substituted C 1 -C 20 -alkyl, C 2 -C 20 -alkenyl, C 1 -C 8 -alkoxy-C 1 -C 8 -alkyl, C 1 -C 8 -alkylthio-C 1 -C 8 -alkyl, poly-C 1 -C 8 -alkoxy-C 1 -C 8 -alkyl or optionally halogen-, C 1 -C 6 -alkyl- or C 1 -C 6 -alkoxy-substituted C 3 -C 8 -cycloalkyl in which optionally one or more (preferably not more than two) ring members not directly adjacent are replaced by oxygen and/or sulphur,
       is optionally halogen-, cyano-, nitro-, C 1 -C 6 -alkyl-, C 1 -C 6 -alkoxy-, C 1 -C 6 -haloalkyl-, C 1 -C 6 -haloalkoxy-, C 1 -C 6 -alkylthio- or C 1 -C 6 -alkylsulphonyl-substituted phenyl,   is optionally halogen-, nitro-, cyano-, C 1 -C 6 -alkyl-, C 1 -C 6 -alkoxy-, C 1 -C 6 -haloalkyl- or C 1 -C 6 -haloalkoxy-substituted phenyl-C 1 -C 6 -alkyl,   is optionally halogen- or C 1 -C 6 -alkyl-substituted 5- or 6-membered hetaryl (for example pyrazolyl, thiazolyl, pyridyl, pyrimidyl, furanyl or thienyl),   is optionally halogen- or C 1 -C 6 -alkyl-substituted phenoxy-C 1 -C 6 -alkyl or   is optionally halogen-, amino- or C 1 -C 6 -alkyl-substituted 5- or 6-membered hetaryloxy-C 1 -C 6 -alkyl (for example pyridyloxy-C 1 -C 6 -alkyl, pyrimidyloxy-C 1 -C 6 -alkyl or thiazolyloxy-C 1 -C 6 -alkyl),   
       R 2  is preferably in each case optionally halogen-substituted C 1 -C 20 -alkyl, C 2 -C 20 -alkenyl, C 1 -C 8 -alkoxy-C 2 -C 8 -alkyl, poly-C 1 -C 8 -alkoxy-C 2 -C 8 -alkyl,
       is optionally halogen-, C 1 -C 6 -alkyl- or C 1 -C 6 -alkoxy-substituted C 3 -C 8 -cycloalkyl or   is in each case optionally halogen-, cyano-, nitro-, C 1 -C 6 -alkyl-, C 1 -C 6 -alkoxy-, C 1 -C 6 -haloalkyl- or C 1 -C 6 -haloalkoxy-substituted phenyl or benzyl,   
       R 3  is preferably optionally halogen-substituted C 1 -C 8 -alkyl or is in each case optionally halogen-, C 1 -C 6 -alkyl-, C 1 -C 6 -alkoxy-, C 1 -C 4 -haloalkyl-, C 1 -C 4 -haloalkoxy-, cyano- or nitro-substituted phenyl or benzyl,   R 4  and R 5  independently of one another are preferably in each case optionally halogen-substituted C 1 -C 8 -alkyl, C 1 -C 8 -alkoxy, C 1 -C 8 -alkylamino, di-(C 1 -C 8 -alkyl)amino, C 1 -C 8 -alkylthio, C 2 -C 8 -alkenylthio, C 3 -C 7 -cycloalkylthio or are in each case optionally halogen-, nitro-, cyano-, C 1 -C 4 -alkoxy-, C 1 -C 4 -haloalkoxy-, C 1 -C 4 -alkylthio-, C 1 -C 4 -haloalkylthio-, C 1 -C 4 -alkyl- or C 1 -C 4 -haloalkyl-substituted phenyl, phenoxy or phenylthio,   R 6  and R 7  are preferably independently of one another hydrogen, are in each case optionally halogen-substituted C 1 -C 8 -alkyl, C 3 -C 8 -cycloalkyl, C 1 -C 8 -alkoxy, C 3 -C 8 -alkenyl, C 1 -C 8 -alkoxy-C 1 -C 8 -alkyl, are optionally halogen-, C 1 -C 8 -haloalkyl-, C 1 -C 8 -alkyl- or C 1 -C 8 -alkoxy-substituted phenyl, optionally halogen-, C 1 -C 8 -alkyl-, C 1 -C 8 -haloalkyl- or C 1 -C 8 -alkoxy-substituted benzyl or together are an optionally C 1 -C 4 -alkyl-substituted C 3 -C 6 -alkylene radical in which optionally one carbon atom is replaced by oxygen or sulphur,   R 13  is preferably hydrogen, is in each case optionally halogen-substituted C 1 -C 8 -alkyl or C 1 -C 8 -alkoxy, is optionally halogen-, C 1 -C 4 -alkyl- or C 1 -C 4 -alkoxy-substituted C 3 -C 8 -cycloalkyl in which optionally one methylene group is replaced by oxygen or sulphur, or is in each case optionally halogen-, C 1 -C 6 -alkyl-, C 1 -C 6 -alkoxy-, C 1 -C 4 -haloalkyl-, C 1 -C 4 -haloalkoxy-, nitro- or cyano-substituted phenyl, phenyl-C 1 -C 4 -alkyl or phenyl-C 1 -C 4 -alkoxy,   R 14a  is preferably hydrogen or C 1 -C 8 -alkyl or   R 13  and R 14a  are preferably together C 4 -C 6 -alkanediyl,   R 15a  and R 16a  are alike or different and are preferably C 1 -C 6 -alkyl or   R 15a  and R 16a  are preferably together a C 2 -C 4 -alkanediyl radical which is optionally substituted by C 1 -C 6 -alkyl, C 1 -C 6 -haloalkyl or by optionally halogen-, C 1 -C 6 -alkyl-, C 1 -C 4 -haloalkyl-, C 1 -C 6 -alkoxy-, C 1 -C 4 -haloalkoxy-, nitro- or cyano-substituted phenyl,   R 17a  and R 18a  are preferably independently of one another hydrogen, are optionally halogen-substituted C 1 -C 8 -alkyl or are optionally halogen-, C 1 -C 6 -alkyl-, C 1 -C 6 -alkoxy-, C 1 -C 4 -haloalkyl-, C 1 -C 4 -haloalkoxy-, nitro- or cyano-substituted phenyl or   R 17a  and R 18a , together with the carbon atom to which they are attached, are preferably a carbonyl group or are optionally halogen-, C 1 -C 4 -alkyl- or C 1 -C 4 -alkoxy-substituted C 5 -C 7 -cycloalkyl in which optionally one methylene group is replaced by oxygen or sulphur,   R 19a  and R 20a  are preferably independently of one another C 1 -C 10 -alkyl, C 2 -C 10 -alkenyl, C 1 -C 10 -alkoxy, C 1 -C 10 -alkylamino, C 3 -C 10 -alkenylamino, di-(C 1 -C 10 -alkyl)amino or di-(C 3 -C 10 -alkenyl)amino.   

     In the radical definitions qualified by “preferably” halogen or halo is fluorine, chlorine, bromine and iodine, in particular fluorine, chlorine and bromine.
     W is with particular preference hydrogen, fluorine, chlorine, bromine, C 1 -C 4 -alkyl, C 2 -C 4 -alkenyl, C 2 -C 4 -alkynyl, C 1 -C 4 -alkoxy, C 1 -C 2 -haloalkyl or C 1 -C 2 -haloalkoxy,   X is with particular preference chlorine, bromine, iodine, C 1 -C 4 -alkyl, C 2 -C 4 -alkenyl, C 2 -C 4 -alkynyl, C 1 -C 4 -alkoxy, C 1 -C 4 -alkoxy-C 1 -C 3 -alkoxy, C 1 -C 2 -haloalkyl, C 1 -C 2 -haloalkoxy or cyano,   Y is with particular preference in position 4 hydrogen, fluorine, chlorine, bromine, iodine, methoxy, ethoxy, cyano, trifluoromethyl, difluoromethoxy or trifluoromethoxy,   Z is with particular preference hydrogen.   W is with particular preference also hydrogen, fluorine, chlorine, bromine or C 1 -C 4 -alkyl,   X is with particular preference also chlorine, bromine, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 1 -C 2 -haloalkyl, C 1 -C 2 -haloalkoxy or cyano,   Y is with particular preference also in position 4 C 2 -C 4 -alkenyl, C 2 -C 4 -alkynyl or the radical   

     
       
         
         
             
             
         
       
         
         Z is with particular preference also hydrogen, 
         V 1  is with particular preference also fluorine, chlorine, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 1 -C 2 -haloalkyl or C 1 -C 2 -haloalkoxy, cyano or nitro, 
         V 2  is with particular preference also hydrogen, fluorine, chlorine, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy or C 1 -C 2 -haloalkyl, 
         V 1  and V 2  together are with particular preference also —O—CH 2 —O— and —O—CF 2 —O—. 
         W is with particular preference likewise hydrogen, fluorine, chlorine, bromine or C 1 -C 4 -alkyl, 
         X is with particular preference likewise chlorine, bromine, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 1 -C 2 -haloalkyl, C 1 -C 2 -haloalkoxy or cyano, 
         Y is with particular preference likewise in position 5 C 2 -C 4 -alkenyl, C 2 -C 4 -alkynyl or the radical 
       
    
     
       
         
         
             
             
         
       
         
         Z is with particular preference likewise in position 4 hydrogen, C 1 -C 4 -alkyl or chlorine, 
         V 1  is with particular preference likewise fluorine, chlorine, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 1 -C 2 -haloalkyl or C 1 -C 2 -haloalkoxy, cyano or nitro, 
         V 2  is with particular preference likewise hydrogen, fluorine, chlorine, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy or C 1 -C 2 -haloalkyl, 
         V 1  and V 2  together are with particular preference likewise —O—CH 2 —O— and —O—CF 2 —O—. 
         W moreover is with particular preference hydrogen, C 1 -C 4 -alkyl, C 2 -C 4 -alkenyl, C 2 -C 4 -alkynyl, C 1 -C 4 -alkoxy, fluorine, chlorine, bromine or trifluoromethyl, 
         X moreover is with particular preference fluorine, chlorine, bromine, iodine, C 1 -C 4 -alkyl, C 2 -C 4 -alkenyl, C 2 -C 4 -alkynyl, C 1 -C 4 -alkoxy, C 1 -C 4 -alkoxy-C 1 -C 3 -alkoxy, C 1 -C 2 -haloalkyl, C 1 -C 2 -haloalkoxy or cyano, 
         Y moreover in position 4 is with particular preference C 1 -C 4 -alkyl, 
         Z moreover is with particular preference hydrogen. 
         W additionally is with particular preference hydrogen, fluorine, chlorine, bromine, C 1 -C 4 -alkyl or C 1 -C 4 -alkoxy, 
         X additionally is with particular preference chlorine, bromine, iodine, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 1 -C 2 -haloalkyl, C 1 -C 2 -haloalkoxy or cyano, 
         Y additionally in position 4 is with particular preference hydrogen, chlorine, bromine, iodine, C 1 -C 4 -alkyl, C 1 -C 2 -haloalkyl or C 1 -C 2 -haloalkoxy, 
         Z additionally in position 3 or 5 is with particular preference fluorine, chlorine, bromine, iodine, C 1 -C 4 -alkyl, C 1 -C 2 -haloalkyl, C 1 -C 4 -alkoxy or C 1 -C 2 -haloalkoxy. 
         CKE stands with particular preference for one of the groups 
       
    
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
         
         A is with particular preference hydrogen, in each case optionally mono- to tri-fluorine- or -chlorine-substituted C 1 -C 6 -alkyl, C 1 -C 4 -alkoxy-C 1 -C 2 -alkyl, optionally singly to doubly C 1 -C 2 -alkyl- or C 1 -C 2 -alkoxy-substituted C 3 -C 6 -cycloalkyl or (but not in the case of the compounds of the formulae (I-3), (I-4), (I-6) and (I-7)) in each case optionally singly to doubly fluorine-, chlorine-, bromine-, C 1 -C 4 -alkyl-, C 1 -C 2 -haloalkyl-, C 1 -C 4 -alkoxy-, C 1 -C 2 -haloalkoxy-, cyano- or nitro-substituted phenyl or benzyl, 
         B is with particular preference hydrogen, C 1 -C 4 -alkyl or C 1 -C 2 -alkoxy-C 1 -C 2 -alkyl, or 
         A, B and the carbon atoms to which they are attached are with particular preference saturated or unsaturated C 3 -C 7 -cycloalkyl in which optionally one ring member is replaced by oxygen or sulphur and which is optionally singly to doubly substituted by C 1 -C 6 -alkyl, C 1 -C 4 -alkoxy-C 1 -C 2 -alkyl, trifluoromethyl, C 1 -C 6 -alkoxy, C 1 -C 3 -alkoxy-C 1 -C 3 -alkoxy or C 3 -C 6 -cycloalkylmethoxy, with the proviso that in that case Q 3  is with particular preference hydrogen or methyl, or 
         A, B and the carbon atom to which they are attached are with particular preference C 5 -C 6 -cycloalkyl which is substituted by an alkylenedithiol group or by an alkylenedioxyl group or by an alkylenediyl group which is optionally substituted by methyl or ethyl and optionally contains one or two oxygen or sulphur atoms not directly adjacent, and which, with the carbon atom to which it is attached, forms a further five- or six-membered ring, with the proviso that in that case Q 3  is with particular preference hydrogen or methyl, or 
         A, B and the carbon atom to which they are attached are with particular preference C 3 -C 6 -cycloalkyl or C 5 -C 6 -cycloalkenyl in which two substituents, together with the carbon atoms to which they are attached, are in each case optionally C 1 -C 2 -alkyl- or C 1 -C 2 -alkoxy-substituted C 2 -C 4 -alkanediyl, C 2 -C 4 -alkenediyl or butadienediyl, with the proviso that in that case Q 3  is with particular preference hydrogen or methyl, 
         D is with particular preference hydrogen, is in each case optionally mono- to tri-fluoro-substituted C 1 -C 6 -alkyl, C 3 -C 6 -alkenyl, C 1 -C 4 -alkoxy-C 2 -C 3 -alkyl, is optionally C 3 -C 6 -cycloalkyl which is singly to doubly substituted by C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy or C 1 -C 2 -haloalkyl and in which optionally one methylene group is replaced by oxygen, or (but not in the case of the compounds of the formulae (I-1)) is pyridyl or phenyl in each case optionally substituted singly to doubly by fluorine, chlorine, bromine, C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl, C 1 -C 4 -alkoxy or C 1 -C 4 -haloalkoxy, or 
         A and D together are with particular preference optionally singly to doubly substituted C 3 -C 5 -alkanediyl in which one methylene group can be replaced by a carbonyl group (but not in the case of the compounds of the formula (I-1)), oxygen or sulphur, suitable substituents being C 1 -C 2 -alkyl or C 1 -C 2 -alkoxy, or 
         A and D (in the case of the compounds of the formula (I-1)), together with the atoms to which they are attached, are one of the groups AD-1 to AD-10: 
       
    
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     or
     A and Q 1  together are with particular preference C 3 -C 4 -alkanediyl in each case optionally substituted singly or doubly by identical or different substituents selected from C 1 -C 2 -alkyl or C 1 -C 2 -alkoxy, or   D and Q 1  together are with particular preference C 3 -C 4 -alkanediyl, or   Q 1  is with particular preference hydrogen, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy-C 1 -C 2 -alkyl, or optionally methyl- or methoxy-substituted C 3 -C 6 -cycloalkyl in which optionally one methylene group is replaced by oxygen,   Q 2  is with particular preference hydrogen, methyl or ethyl,   Q 4 , Q 5  and Q 6  independently of one another are with particular preference hydrogen or C 1 -C 3 -alkyl,   Q 3  is with particular preference hydrogen, C 1 -C 4 -alkyl, or optionally singly to doubly methyl- or methoxy-substituted C 3 -C 6 -cycloalkyl, or   Q 1  and Q 2  are with particular preference hydrogen, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy-C 1 -C 2 -alkyl, or optionally methyl- or methoxy-substituted C 3 -C 6 -cycloalkyl in which optionally one methylene group is replaced by oxygen, or   Q 3  and Q 4 , together with the carbon to which they are attached, are with particular preference an optionally C 1 -C 2 -alkyl- or C 1 -C 2 -alkoxy-substituted saturated C 5 -C 6  ring in which optionally one ring member is replaced by oxygen or sulphur, with the proviso that in that case A is with particular preference is hydrogen or methyl,   G is with particular preference hydrogen (a) or is one of the groups   

     
       
         
         
             
             
         
       
     
     in particular is (a), (b) or (c),
         in which   E is one metal ion equivalent or an ammonium ion,   L is oxygen or sulphur and   M is oxygen or sulphur,       R 1  is with particular preference in each case optionally mono- to tri-fluorine- or -chlorine-substituted C 1 -C 8 -alkyl, C 2 -C 18 -alkenyl, C 1 -C 4 -alkoxy-C 1 -C 2 -alkyl, C 1 -C 4 -alkylthio-C 1 -C 2 -alkyl or optionally singly- to doubly fluorine-, chlorine-, C 1 -C 2 -alkyl- or C 1 -C 2 -alkoxy-substituted C 3 -C 6 -cycloalkyl in which optionally one or two ring members not directly adjacent are replaced by oxygen,
       is phenyl optionally substituted by fluorine, chlorine, bromine, cyano, nitro, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 1 -C 2 -haloalkyl or C 1 -C 2 -haloalkoxy,   
       R 2  is in each case optionally mono- to tri-fluorine-substituted C 1 -C 8 -alkyl, C 2 -C 8 -alkenyl or C 1 -C 4 -alkoxy-C 2 -C 4 -alkyl,
       is optionally mono-C 1 -C 2 -alkyl- or —C 1 -C 2 -alkoxy-substituted C 3 -C 6 -cycloalkyl or   is benzyl or phenyl in each case optionally substituted singly to doubly by fluorine, chlorine, bromine, cyano, nitro, C 1 -C 4 -alkyl, C 1 -C 3 -alkoxy, trifluoromethyl or trifluoromethoxy,   
       R 3  is with particular preference C 1 -C 6 -alkyl optionally substituted one to three times by fluorine or is phenyl optionally substituted once by fluorine, chlorine, bromine, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, trifluoromethyl, trifluoromethoxy, cyano or nitro,   R 4  is with particular preference C 1 -C 6 -alkyl, C 1 -C 6 -alkoxy, C 1 -C 6 -alkylamino, di-(C 1 -C 6 -alkyl)amino, C 1 -C 6 -alkylthio, C 3 -C 4 -alkenylthio, C 3 -C 6 -cycloalkylthio or is phenylthio, phenoxy or phenyl in each case optionally substituted once by fluorine, chlorine, bromine, nitro, cyano, C 1 -C 3 -alkoxy, C 1 -C 3 -haloalkoxy, C 1 -C 3 -alkylthio, C 1 -C 3 -haloalkylthio, C 1 -C 3 -alkyl or trifluoromethyl,   R 5  is with particular preference C 1 -C 6 -alkoxy or C 1 -C 6 -alkylthio,   R 6  is with particular preference hydrogen, C 1 -C 6 -alkyl, C 3 -C 6 -cycloalkyl, C 1 -C 6 -alkoxy, C 3 -C 6 -alkenyl, C 1 -C 6 -alkoxy-C 1 -C 4 -alkyl, is phenyl optionally substituted once by fluorine, chlorine, bromine, trifluoromethyl, C 1 -C 4 -alkyl or C 1 -C 4 -alkoxy, or is benzyl optionally substituted once by fluorine, chlorine, bromine, C 1 -C 4 -alkyl, trifluoromethyl or C 1 -C 4 -alkoxy,   R 7  is with particular preference C 1 -C 6 -alkyl, C 3 -C 6 -alkenyl or C 1 -C 6 -alkoxy-C 1 -C 4 -alkyl,   R 6  and R 7  together are with particular preference an optionally methyl- or ethyl-substituted C 4 -C 5 -alkylene radical in which optionally one methylene group is replaced by oxygen or sulphur.   

     In the radical definitions qualified by “with particular preference” halogen or halo is fluorine, chlorine and bromine, especially fluorine and chlorine.
     W is with very particular preference hydrogen, methyl, chlorine, bromine, ethyl, methoxy, ethoxy or trifluoromethyl,   X is with very particular preference chlorine, bromine, iodine, methyl, ethyl, propyl, methoxy, ethoxy, propoxy, methoxy-ethoxy, ethoxy-ethoxy, trifluoromethyl, difluoromethoxy, trifluoromethoxy or cyano,   Y is with very particular preference in position 4 hydrogen, chlorine, bromine, iodine, trifluoromethyl or trifluoromethoxy,   Z is with very particular preference hydrogen.   W is with very particular preference also hydrogen, chlorine, bromine, methyl or ethyl,   X is with very particular preference also chlorine, bromine, methyl, ethyl, propyl, methoxy, trifluoromethyl, difluoromethoxy, trifluoromethoxy or cyano,   Y is with very particular preference also in position 4 the radical   

     
       
         
         
             
             
         
       
         
         Z is with very particular preference also hydrogen, 
         V 1  is with very particular preference also fluorine, chlorine, methyl, methoxy, trifluoromethyl, trifluoromethoxy or cyano, 
         V 2  is with very particular preference also hydrogen, fluorine, chlorine, methyl, methoxy or trifluoromethyl. 
         W is with very particular preference likewise hydrogen, chlorine or methyl, 
         X is with very particular preference likewise chlorine, methyl, trifluoromethyl, methoxy, difluoromethoxy, trifluoromethoxy or cyano, 
         Y is with very particular preference likewise in position 5 the radical 
       
    
     
       
         
         
             
             
         
       
         
         Z is with very particular preference likewise in position 4 hydrogen or methyl, 
         V 1  is with very particular preference likewise fluorine, chlorine, methyl, methoxy, trifluoromethyl, trifluoromethoxy or cyano, 
         V 2  is with very particular preference likewise hydrogen, fluorine, chlorine, methyl, methoxy or trifluoromethyl. 
         W is moreover with very particular preference hydrogen, methyl, ethyl, methoxy, ethoxy, chlorine or bromine, 
         X is moreover with very particular preference chlorine, bromine, iodine, methyl, ethyl, propyl, methoxy, ethoxy, propoxy, methoxy-ethoxy, ethoxy-ethoxy, trifluoromethyl, difluoromethoxy, trifluoromethoxy or cyano, 
         Y is moreover with very particular preference in position 4 methyl or ethyl, 
         Z is moreover with very particular preference hydrogen. 
         W is with very particular preference additionally hydrogen, chlorine, bromine, methyl or ethyl, 
         X is with very particular preference additionally chlorine, bromine, iodine, methyl, ethyl, methoxy, trifluoromethyl, difluoromethoxy or trifluoromethoxy, 
         Y is with very particular preference additionally in position 4 hydrogen, chlorine, bromine, methyl or ethyl, 
         Z is with very particular preference additionally in position 3 or 5 fluorine, chlorine, bromine, iodine, methyl, ethyl, trifluoromethyl or trifluoromethoxy. 
         CKE stands with very particular preference for one of the groups 
       
    
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
         
         A is with very particular preference hydrogen, in each case optionally mono- to tri-fluorine-substituted C 1 -C 4 -alkyl, C 1 -C 2 -alkoxy-C 1 -C 2 -alkyl, is cyclopropyl, cyclopentyl or cyclohexyl and only in the case of the compounds of the formula (I-5) is phenyl optionally substituted singly to doubly by fluorine, chlorine, bromine, methyl, ethyl, n-propyl, isopropyl, methoxy, ethoxy, trifluoromethyl, trifluoromethoxy, cyano or nitro, 
         B is with very particular preference hydrogen, methyl or ethyl, or 
         A, B and the carbon atom to which they are attached are with very particular preference saturated C 5 -C 6 -cycloalkyl in which optionally one ring member is replaced by oxygen or sulphur and which is optionally substituted once by methyl, ethyl, propyl, isopropyl, methoxymethyl, ethoxymethyl, propoxymethyl, methoxyethyl, ethoxyethyl, trifluoromethyl, methoxy, ethoxy, propoxy, methoxyethoxy, butoxy, ethoxyethoxy or cyclopropylmethoxy, with the proviso that in that case Q 3  is with very particular preference hydrogen, or 
         A, B and the carbon atom to which they are attached are with very particular preference C 6 -cycloalkyl which is optionally substituted by an alkylenedioxyl group which contains two oxygen atoms not directly adjacent, with the proviso that in that case Q 3  is with very particular preference hydrogen, or 
         A, B and the carbon atom to which they are attached are with very particular preference C 5 -C 6 -cycloalkyl or C 5 -C 6 -cycloalkenyl, in which two substituents, together with the carbon atoms to which they are attached, are C 2 -C 4 -alkanediyl or C 2 -C 4 -alkenediyl or butadienediyl, with the proviso that in that case Q 3  is with very particular preference hydrogen, 
         D is with very particular preference hydrogen, is in each case optionally mono- to tri-fluoro-substituted C 1 -C 4 -alkyl, C 3 -C 4 -alkenyl, C 1 -C 4 -alkoxy-C 2 -C 3 -alkyl, is cyclopropyl, cyclopentyl or cyclohexyl or (but not in the case of the compounds of the formulae (I-1)) is pyridyl or phenyl in each case optionally substituted once by fluorine, chlorine, methyl, ethyl, n-propyl, isopropyl, methoxy, ethoxy or trifluoromethyl, 
         or 
         A and D together are with very particular preference C 3 -C 5 -alkanediyl which is optionally substituted once by methyl or methoxy and in which optionally one carbon atom is replaced by oxygen or sulphur, or is the group AD-1, or 
         A and Q 1  are together with very particular preference C 3 -C 4 -alkanediyl optionally substituted singly to doubly by methyl or methoxy, or 
         D and Q 1  are together with very particular preference C 3 -C 4 -alkanediyl, or 
         Q 1  is with very particular preference hydrogen, methyl, ethyl, propyl, isopropyl, cyclopropyl, cyclopentyl or cyclohexyl, 
         Q 2  is with very particular preference hydrogen, methyl or ethyl, 
         Q 4 , Q 5  and Q 6  are with very particular preference independently of one another hydrogen or methyl, 
         Q 3  is with very particular preference hydrogen, methyl, ethyl or propyl, or 
         Q 3  and Q 4 , are with very particular preference, together with the carbon to which they are attached, an optionally mono-methyl- or -methoxy-substituted saturated C 5 -C 6  ring, with the proviso that in that case A is with very particular preference hydrogen, 
         G is with very particular preference hydrogen (a) or is one of the groups 
       
    
     
       
         
         
             
             
         
       
         
         
           
             in which 
             L is oxygen or sulphur, 
             M is oxygen or sulphur and 
             E is an ammonium ion, 
           
         
         R 1  is with very particular preference in each case optionally mono-chloro-substituted C 1 -C 6 -alkyl, C 2 -C 17 -alkenyl, C 1 -C 2 -alkoxy-C 1 -alkyl, C 1 -C 2 -alkylthio-C 1 -alkyl or in each case optionally mono-fluorine-, -chlorine-, -methyl- or -methoxy-substituted cyclopropyl or cyclohexyl,
       is phenyl optionally substituted once by fluorine, chlorine, bromine, cyano, nitro, methyl, methoxy, trifluoromethyl or trifluoromethoxy,   
     
         R 2  is with very particular preference in each case optionally mono-fluoro-substituted C 1 -C 8 -alkyl, C 2 -C 6 -alkenyl or C 1 -C 4 -alkoxy-C 2 -C 3 -alkyl, phenyl or benzyl, 
         R 3  is with very particular preference C 1 -C 8 -alkyl. 
       
    
     Specifically mention may be made, apart from the compounds specified in the examples, of the following compounds: 
     
       
         
           
               
             
               
                 TABLE 1 
               
             
            
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
            
           
           
               
               
               
               
               
            
               
                   
                 X 
                 W 
                 Y 
                 Z 
               
               
                   
                   
               
               
                   
                 CH 3   
                 H 
                 H 
                 H 
               
               
                   
                 Br 
                 H 
                 H 
                 H 
               
               
                   
                 Cl 
                 H 
                 H 
                 H 
               
               
                   
                 CF 3   
                 H 
                 H 
                 H 
               
               
                   
                 OCH 3   
                 H 
                 H 
                 H 
               
               
                   
                 Br 
                 H 
                 4-Cl 
                 H 
               
               
                   
                 Cl 
                 H 
                 4-Br 
                 H 
               
               
                   
                 Cl 
                 H 
                 4-Cl 
                 H 
               
               
                   
                 Cl 
                 H 
                 4-CH 3   
                 H 
               
               
                   
                 CH 3   
                 H 
                 4-Cl 
                 H 
               
               
                   
                 CH 3   
                 H 
                 4-CH 3   
                 H 
               
               
                   
                 Cl 
                 Cl 
                 H 
                 H 
               
               
                   
                 Cl 
                 OCH 3   
                 H 
                 H 
               
               
                   
                 Cl 
                 CH 3   
                 H 
                 H 
               
               
                   
                 Cl 
                 OC 2 H 5   
                 H 
                 H 
               
               
                   
                 OCH 3   
                 OCH 3   
                 H 
                 H 
               
               
                   
                 CH 3   
                 CH 3   
                 H 
                 H 
               
               
                   
                 Br 
                 CH 3   
                 4-Br 
                 H 
               
               
                   
                 Cl 
                 Cl 
                 4-CH 3   
                 H 
               
               
                   
                 CH 3   
                 Br 
                 4-CH 3   
                 H 
               
               
                   
                 CH 3   
                 Cl 
                 4-CH 3   
                 H 
               
               
                   
                 OCH 3   
                 CH 3   
                 4-CH 3   
                 H 
               
               
                   
                 OC 2 H 5   
                 CH 3   
                 4-CH 3   
                 H 
               
               
                   
                 OC 3 H 7   
                 CH 3   
                 4-CH 3   
                 H 
               
               
                   
                 CH 3   
                 CH 3   
                 4-CH 3   
                 H 
               
               
                   
                 Br 
                 Br 
                 4-CH 3   
                 H 
               
               
                   
                 CH 3   
                 CH 3   
                 4-Br 
                 H 
               
               
                   
                 C 2 H 5   
                 CH 3   
                 H 
                 H 
               
               
                   
                 C 2 H 5   
                 C 2 H 5   
                 H 
                 H 
               
               
                   
                 OCH 3   
                 C 2 H 5   
                 4-CH 3   
                 H 
               
               
                   
                 CH 3   
                 CH 3   
                 4-OCH 3   
                 H 
               
               
                   
                 Br 
                 Cl 
                 4-CH 3   
                 H 
               
               
                   
                 Br 
                 CH 3   
                 4-Cl 
                 H 
               
               
                   
                 Cl 
                 CH 3   
                 4-Br 
                 H 
               
               
                   
                 CH 3   
                 CH 3   
                 4-Cl 
                 H 
               
               
                   
                 C 2 H 5   
                 CH 3   
                 4-CH 3   
                 H 
               
               
                   
                 C 2 H 5   
                 CH 3   
                 4-C 2 H 5   
                 H 
               
               
                   
                 C 2 H 5   
                 C 2 H 5   
                 4-CH 3   
                 H 
               
               
                   
                 C 2 H 5   
                 C 2 H 5   
                 4-C 2 H 5   
                 H 
               
               
                   
                 C 2 H 5   
                 CH 3   
                 4-Cl 
                 H 
               
               
                   
                 C 2 H 5   
                 C 2 H 5   
                 4-Cl 
                 H 
               
               
                   
                 C 2 H 5   
                 CH 3   
                 4-Br 
                 H 
               
               
                   
                 C 2 H 5   
                 C 2 H 5   
                 4-Br 
                 H 
               
               
                   
                 C 2 H 5   
                 Cl 
                 4-CH 3   
                 H 
               
               
                   
                 C 2 H 5   
                 Br 
                 4-CH 3   
                 H 
               
               
                   
                 C 2 H 5   
                 Cl 
                 4-Cl 
                 H 
               
               
                   
                 C 2 H 5   
                 Br 
                 4-Br 
                 H 
               
               
                   
                 C 2 H 5   
                 Cl 
                 4-Br 
                 H 
               
               
                   
                 C 2 H 5   
                 Br 
                 4-Cl 
                 H 
               
               
                   
                 OCH 3   
                 CH 3   
                 4-Cl 
                 H 
               
               
                   
                 OCH 3   
                 C 2 H 5   
                 4-Cl 
                 H 
               
               
                   
                 OC 2 H 5   
                 CH 3   
                 4-Cl 
                 H 
               
               
                   
                 OC 2 H 5   
                 C 2 H 5   
                 4-Cl 
                 H 
               
               
                   
                 Cl 
                 OCH 3   
                 4-CH 3   
                 H 
               
               
                   
                 Cl 
                 OC 2 H 5   
                 4-CH 3   
                 H 
               
               
                   
                 Cl 
                 Cl 
                 4-Cl 
                 H 
               
               
                   
                 Cl 
                 H 
                 4-Cl 
                 5-Cl 
               
               
                   
                 CH 3   
                 H 
                 4-CH 3   
                 5-CH 3   
               
               
                   
                 CH 3   
                 H 
                 4-Cl 
                 5-CH 3   
               
               
                   
                 Br 
                 H 
                 4-Cl 
                 5-CH 3   
               
               
                   
                 Br 
                 H 
                 4-CH 3   
                 5-CH 3   
               
               
                   
                 Cl 
                 H 
                 4-Br 
                 5-CH 3   
               
               
                   
                 Cl 
                 H 
                 4-Cl 
                 5-CH 3   
               
               
                   
                 CH 3   
                 H 
                 4-Br 
                 5-CH 3   
               
               
                   
                 Cl 
                 H 
                 4-CH 3   
                 5-Cl 
               
               
                   
                 CH 3   
                 H 
                 H 
                 5-CH 3   
               
               
                   
                 Cl 
                 H 
                 H 
                 5-CH 3   
               
               
                   
                 Br 
                 H 
                 H 
                 5-CH 3   
               
               
                   
                 CH 3   
                 H 
                 H 
                 5-Cl 
               
               
                   
                 CH 3   
                 H 
                 H 
                 5-Br 
               
               
                   
                 CH 3   
                 CH 3   
                 4-CH 3   
                 5-CH 3   
               
               
                   
                 CH 3   
                 CH 3   
                 4-CH 3   
                 5-Cl 
               
               
                   
                 CH 3   
                 CH 3   
                 4-CH 3   
                 5-Br 
               
               
                   
                 CH 3   
                 CH 3   
                 H 
                 3-Cl 
               
               
                   
                 CH 3   
                 CH 3   
                 H 
                 3-Br 
               
               
                   
                 Cl 
                 Cl 
                 H 
                 3-Br 
               
               
                   
                 CH 3   
                 CH 3   
                 4-(4-Cl—C 6 H 4 ) 
                 H 
               
               
                   
                 C 2 H 5   
                 CH 3   
                 4-(4-Cl—C 6 H 4 ) 
                 H 
               
               
                   
                 C 2 H 5   
                 C 2 H 5   
                 4-(4-Cl—C 6 H 4 ) 
                 H 
               
               
                   
                 Cl 
                 CH 3   
                 4-(4-Cl—C 6 H 4 ) 
                 H 
               
               
                   
                 Cl 
                 C 2 H 5   
                 4-(4-Cl—C 6 H 4 ) 
                 H 
               
               
                   
                 CH 3   
                 H 
                 5-(4-Cl—C 6 H 4 ) 
                 H 
               
               
                   
                 CH 3   
                 CH 3   
                 5-(4-Cl—C 6 H 4 ) 
                 H 
               
               
                   
                 CH 3   
                 H 
                 5-(4-C1—C 6 H 4 ) 
                 4-CH 3   
               
               
                   
                 CH 3   
                 CH 3   
                 5-(4-Cl—C 6 H 4 ) 
                 4-CH 3   
               
               
                   
                 Cl 
                 H 
                 5-(4-Cl—C 6 H 4 ) 
                 H 
               
               
                   
                 I 
                 H 
                 H 
                 H 
               
               
                   
                 I 
                 H 
                 4-CH 3   
                 H 
               
               
                   
                 I 
                 CH 3   
                 H 
                 H 
               
               
                   
                 I 
                 C 2 H 5   
                 H 
                 H 
               
               
                   
                 CH 3   
                 H 
                 H 
                 5-I 
               
               
                   
                 CH 3   
                 H 
                 4-CH 3   
                 5-I 
               
               
                   
                 I 
                 CH 3   
                 4-CH 3   
                 H 
               
               
                   
                 I 
                 C 2 H 5   
                 4-CH 3   
                 H 
               
               
                   
                 I 
                 CH 3   
                 4-Cl 
                 H 
               
               
                   
                 I 
                 C 2 H 5   
                 4-Cl 
                 H 
               
               
                   
                 I 
                 Cl 
                 4-CH 3   
                 H 
               
               
                   
                 I 
                 H 
                 4-CH 3   
                 5-CH 3   
               
               
                   
                 CH 3   
                 H 
                 4-I 
                 H 
               
               
                   
                 C 2 H 5   
                 H 
                 4-I 
                 H 
               
               
                   
                 CH 3   
                 CH 3   
                 4-I 
                 H 
               
               
                   
                 C 2 H 5   
                 CH 3   
                 4-I 
                 H 
               
               
                   
                 C 2 H 5   
                 C 2 H 5   
                 4-I 
                 H 
               
               
                   
                 Cl 
                 CH 3   
                 4-I 
                 H 
               
               
                   
                 Cl 
                 C 2 H 5   
                 4-I 
                 H 
               
               
                   
                 CH 3   
                 H 
                 4-I 
                 5-CH 3   
               
               
                   
                 CH 3   
                 CH 3   
                 H 
                 3-I 
               
               
                   
                 I 
                 H 
                 H 
                 5-CH 3   
               
               
                   
                   
               
            
           
         
       
     
     Compounds suitable with particular preference as active ingredients of the invention are compounds having the radical combinations specified in Table 1 for W, X, Y and Z and the radical combinations specified in Tables 2a and 2b for A, B and D. 
     
       
         
           
               
             
               
                 TABLE 2a 
               
             
            
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
            
           
           
               
               
               
            
               
                 A 
                 B 
                 D 
               
               
                   
               
               
                 CH 3   
                 H 
                 H 
               
               
                 C 2 H 5   
                 H 
                 H 
               
               
                 C 3 H 7   
                 H 
                 H 
               
               
                 i-C 3 H 7   
                 H 
                 H 
               
               
                 C 4 H 9   
                 H 
                 H 
               
               
                 i-C 4 H 9   
                 H 
                 H 
               
               
                 s-C 4 H 9   
                 H 
                 H 
               
               
                 t-C 4 H 9   
                 H 
                 H 
               
               
                 CH 3   
                 CH 3   
                 H 
               
               
                 C 2 H 5   
                 CH 3   
                 H 
               
               
                 C 3 H 7   
                 CH 3   
                 H 
               
               
                 i-C 3 H 7   
                 CH 3   
                 H 
               
               
                 C 4 H 9   
                 CH 3   
                 H 
               
               
                 i-C 4 H 9   
                 CH 3   
                 H 
               
               
                 s-C 4 H 9   
                 CH 3   
                 H 
               
               
                 t-C 4 H 9   
                 CH 3   
                 H 
               
               
                 C 2 H 5   
                 C 2 H 5   
                 H 
               
               
                 C 3 H 7   
                 C 3 H 7   
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 CH 3   
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 CH 3   
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 CH 3   
                 H 
               
               
                   
               
            
           
           
               
               
            
               
                 —(CH 2 ) 2 — 
                 H 
               
               
                 —(CH 2 ) 4 — 
                 H 
               
               
                 —(CH 2 ) 5 — 
                 H 
               
               
                 —(CH 2 ) 6 — 
                 H 
               
               
                 —(CH 2 ) 7 — 
                 H 
               
               
                 —(CH 2 ) 2 —O—(CH 2 ) 2 — 
                 H 
               
               
                 —CH 2 —O—(CH 2 ) 3 — 
                 H 
               
               
                 —(CH 2 ) 2 —S—(CH 2 ) 2 — 
                 H 
               
               
                 —CH 2 —CHCH 3 —(CH 2 ) 3 — 
                 H 
               
               
                 —CH 2 —CHOCH 3 —(CH 2 ) 2 — 
                 H 
               
               
                 —CH 2 —CHOC 2 H 5 —(CH 2 ) 2 — 
                 H 
               
               
                 —CH 2 —CHOC 3 H 7 —(CH 2 ) 2 — 
                 H 
               
               
                 —CH 2 —CHOC 4 H 9 —(CH 2 ) 2 — 
                 H 
               
               
                 —CH 2 —CHO(CH 2 ) 2 OCH 3 —(CH 2 ) 2 — 
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 —CH 2 —CHOCH 3 —(CH 2 ) 3 — 
                 H 
               
               
                 —CH 2 —CHOC 2 H 5 —(CH 2 ) 3 — 
                 H 
               
               
                 —CH 2 —CHOC 3 H 7 —(CH 2 ) 3 — 
                 H 
               
               
                 —CH 2 —CHOC 4 H 9 —(CH 2 ) 3 — 
                 H 
               
               
                 —CH 2 —CHO(CH 2 ) 2 OCH 3 —(CH 2 ) 3 — 
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 —(CH 2 ) 2 —CHCH 3 —(CH 2 ) 2 — 
                 H 
               
               
                 —(CH 2 ) 2 —CHC 2 H 5 —(CH 2 ) 2 — 
                 H 
               
               
                 —(CH 2 ) 2 —CHC 3 H 7 —(CH 2 ) 2 — 
                 H 
               
               
                 —(CH 2 ) 2 —CHi-C 3 H 7 —(CH 2 ) 2 — 
                 H 
               
               
                 —(CH 2 ) 2 —CHOCH 3 —(CH 2 ) 2 — 
                 H 
               
               
                 —(CH 2 ) 2 —CHOC 2 H 5 —(CH 2 ) 2 — 
                 H 
               
               
                 —(CH 2 ) 2 —CHOC 3 H 7 —(CH 2 ) 2 — 
                 H 
               
               
                 —(CH 2 ) 2 —CHO-i-C 3 H 7 —(CH 2 ) 2 — 
                 H 
               
               
                 —(CH 2 ) 2 —C(CH 3 ) 2 —(CH 2 ) 2 — 
                 H 
               
               
                 —CH 2 —(CHCH 3 ) 2 —(CH 2 ) 2 — 
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
             
               
                 TABLE 2b 
               
               
                   
               
               
                 A 
                 D 
                 B 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
            
               
                 —(CH 2 ) 3 — 
                 H 
               
               
                 —(CH 2 ) 4 — 
                 H 
               
               
                 —CH 2 —CHCH 3 —CH 2 — 
                 H 
               
               
                 —CH 2 —CH 2 —CHCH 3 — 
                 H 
               
               
                 —CH 2 —CHCH 3 —CHCH 3 — 
                 H 
               
               
                 —CH 2 —CH(OCH 3 )—CH 2 — 
                 H 
               
               
                 —CH 2 —CH═CH—CH 2 — 
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 —CH 2 —S—CH 2 — 
                 H 
               
               
                 —CH 2 —S—(CH 2 ) 2 — 
                 H 
               
               
                 —(CH 2 ) 2 —S—CH 2 — 
                 H 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
            
           
           
               
               
               
            
               
                 H 
                 CH 3   
                 H 
               
               
                 H 
                 C 2 H 5   
                 H 
               
               
                 H 
                 C 3 H 7   
                 H 
               
               
                 H 
                 i-C 3 H 7   
                 H 
               
               
                   
               
               
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 CH 3   
                 CH 3   
                 H 
               
               
                 CH 3   
                 C 2 H 5   
                 H 
               
               
                 CH 3   
                 C 3 H 7   
                 H 
               
               
                 CH 3   
                 i-C 3 H 7   
                 H 
               
               
                   
               
               
                 CH 3   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 CH 3   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 CH 3   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 C 2 H 5   
                 CH 3   
                 H 
               
               
                 C 2 H 5   
                 C 2 H 5   
                 H 
               
               
                   
               
            
           
         
       
     
     Compounds emphasized as active ingredients are, in particular, preferred compounds having the radical combinations specified in Table 1 for W, X and Y and the radical combinations specified in Tables 2a and 2b for A, B and D, in which W, X and Y represent a phenyl ring substituted in position 2, disubstituted in positions 2, 4 or 2,6, or trisubstituted in positions 2,4,6. 
     Compounds suitable as active ingredients of the invention are, with particular preference, compounds having the radical combinations specified in Table 1 for W, X, Y and Z and the radical combinations specified in Table 3 for A and B. 
     
       
         
           
               
             
               
                 TABLE 3 
               
             
            
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
            
           
           
               
               
               
            
               
                   
                 A 
                 B 
               
               
                   
                   
               
               
                   
                 CH 3   
                 H 
               
               
                   
                 C 2 H 5   
                 H 
               
               
                   
                 C 3 H 7   
                 H 
               
               
                   
                 i-C 3 H 7   
                 H 
               
               
                   
                 C 4 H 9   
                 H 
               
               
                   
                 i-C 4 H 9   
                 H 
               
               
                   
                 s-C 4 H 9   
                 H 
               
               
                   
                 t-C 4 H 9   
                 H 
               
               
                   
                 CH 3   
                 CH 3   
               
               
                   
                 C 2 H 5   
                 CH 3   
               
               
                   
                 C 3 H 7   
                 CH 3   
               
               
                   
                 i-C 3 H 7   
                 CH 3   
               
               
                   
                 C 4 H 9   
                 CH 3   
               
               
                   
                 i-C 4 H 9   
                 CH 3   
               
               
                   
                 s-C 4 H 9   
                 CH 3   
               
               
                   
                 t-C 4 H 9   
                 CH 3   
               
               
                   
                 C 2 H 5   
                 C 2 H 5   
               
               
                   
                 C 3 H 7   
                 C 3 H 7   
               
               
                   
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 CH 3   
               
               
                   
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 CH 3   
               
               
                   
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 CH 3   
               
               
                   
                   
               
            
           
           
               
            
               
                 —(CH 2 ) 2 — 
               
               
                 —(CH 2 ) 4 — 
               
               
                 —(CH 2 ) 5 — 
               
               
                 —(CH 2 ) 6 — 
               
               
                 —(CH 2 ) 7 — 
               
               
                 —(CH 2 ) 2 —O—(CH 2 ) 2 — 
               
               
                 —CH 2 —O—(CH 2 ) 3 — 
               
               
                 —(CH 2 ) 2 —S—(CH 2 ) 2 — 
               
               
                 —CH 2 —CHCH 3 —(CH 2 ) 3 — 
               
               
                 —CH 2 —CHOCH 3 —(CH 2 ) 3 — 
               
               
                 —CH 2 —CHOC 2 H 5 —(CH 2 ) 3 — 
               
               
                 —CH 2 —CHOC 3 H 7 —(CH 2 ) 3 — 
               
               
                 —CH 2 —CHOC 4 H 9 —(CH 2 ) 3 — 
               
               
                 —CH 2 —CHO(CH 2 ) 2 OCH 3 —(CH 2 ) 3 — 
               
               
                 —(CH 2 ) 2 —CHCH 3 —(CH 2 ) 2 — 
               
               
                 —(CH 2 ) 2 —CHC 2 H 5 —(CH 2 ) 2 — 
               
               
                 —(CH 2 ) 2 —CHC 3 H 7 —(CH 2 ) 2 — 
               
               
                 —(CH 2 ) 2 —CHi-C 3 H 7 —(CH 2 ) 2 — 
               
               
                 —(CH 2 ) 2 —CHOCH 3 —(CH 2 ) 2 — 
               
               
                 —(CH 2 ) 2 —CHOC 2 H 5 —(CH 2 ) 2 — 
               
               
                 —(CH 2 ) 2 —CHOC 3 H 7 —(CH 2 ) 2 — 
               
               
                 —(CH 2 ) 2 —CHO-i-C 3 H 7 —(CH 2 ) 2 — 
               
               
                 —(CH 2 ) 2 —C(CH 3 ) 2 —(CH 2 ) 2 — 
               
               
                 —CH 2 —(CHCH 3 ) 2 —(CH 2 ) 2 — 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
            
           
         
       
     
     Compounds emphasized as active ingredients are, in particular, preferred compounds having the radical combinations specified in Table 1 for W, X and Y and the radical combinations specified in Table 3 for A and B, in which W, X and Y represent a phenyl ring substituted in position 2, disubstituted in positions 2, 4 or 2,6 or trisubstituted in positions 2,4,6. 
     Emphasis may be given to the following compounds: 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     The compounds of the formula (I) possess a herbicidal activity, but individually the activity and/or tolerance leaves something to be desired. 
     The active ingredients can be used in the compositions of the invention in a broad concentration range. The concentration of the active ingredients in the formulation is typically 0.1%-50% by weight. 
     Ammonium salts and phosphonium salts which inventively boost the activity of crop protection materials comprising fatty acid biosynthesis inhibitors are defined by formula (II) 
     
       
         
         
             
             
         
       
         
         in which 
         D is nitrogen or phosphorus, 
         D is preferably nitrogen, 
         R 26 , R 27 , R 28  and R 29  independently of one another are hydrogen or in each case optionally substituted C 1 -C 8 -alkyl or singly or multiply unsaturated, optionally substituted C 1 -C 8 -alkylene, the substituents being selectable from halogen, nitro and cyano, 
         R 26 , R 27 , R 28  and R 29  are preferably independently of one another hydrogen or in each case optionally substituted C 1 -C 4 -alkyl, the substituents being selectable from halogen, nitro and cyano, 
         R 26 , R 27 , R 28  and R 29  are with particular preference independently of one another hydrogen, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl or tert-butyl, 
         R 26 , R 27 , R 21  and R 29  with very particular preference are hydrogen, 
         R 26 , R 27 , R 28  and R 29 , additionally, with very particular preference simultaneously are methyl or simultaneously are ethyl, 
         n is 1, 2, 3 or 4, 
         n preferably is 1 or 2, 
         R 30  is an organic or inorganic anion, 
         R 30  preferably is hydrogencarbonate, tetraborate, fluoride, bromide, iodide, chloride, monohydrogenphosphate, dihydrogenphosphate, hydrogensulphate, tartrate, sulphate, nitrate, thiosulphate, thiocyanate, formate, lactate, acetate, propionate, butyrate, pentanoate, citrate or oxalate, 
         R 30  additionally preferably is carbonate, pentaborate, sulphite, benzoate, hydrogenoxalate, hydrogencitrate, methylsulphate or tetrafluoroborate, 
         R 30  with particular preference is lactate, sulphate, nitrate, thiosulphate, thiocyanate, citrate, oxalate or formate, 
         R 30  moreover with particular preference is acetate, monohydrogenphosphate or dihydrogenphosphate, and 
         R 30  with very particular preference is sulphate, thiocyanate, dihydrogenphosphate or monohydrogenphosphate. 
       
    
     The ammonium salts and phosphonium salts of the formula (II) can be used in a broad concentration range to boost the activity of crop protection materials comprising ketoenols. In general the ammonium salts or phosphonium salts are used in the application-ready crop protection material in a concentration of 0.5 to 80 mmol/l, preferably 0.75 to 37.5 mmol/l, more preferably 1.5 to 25 mmol/l. In the case of the formulated product the ammonium salt and/or phosphonium salt concentration in the formulation is chosen such that it is within these stated general, preferred or particularly preferred ranges after the formulation has been diluted to the desired active-ingredient concentration. The concentration of the salt in the formulation is typically 1%-50% by weight. 
     In one preferred embodiment of the invention the activity is boosted by adding to the crop protection materials not only an ammonium salt and/or phosphonium salt but also, additionally, a penetrant. It is considered entirely surprising that even in these cases an even greater boost to activity is observed. The present invention therefore likewise provides for the use of a combination of penetrant and ammonium salts and/or phosphonium salts to boost the activity crop protection materials which comprise herbicidally active phenyl-substituted cyclic ketoenols as active ingredient. The invention likewise provides materials which comprise herbicidally active phenyl-substituted cyclic ketoenols, penetrants and ammonium salts and/or phosphonium salts, including specifically not only formulated active ingredients but also application-ready materials (spray liquors). The invention additionally provides, finally, for the use of these materials for controlling unwanted plant growth. 
     Suitable penetrants in the present context include all those substances which are typically used to enhance the penetration of active agrochemical ingredients into plants. Penetrants are defined in this context by their ability to penetrate from the aqueous spray liquor and/or from the spray coating into the cuticle of the plant and thereby to increase the mobility of active ingredients in the cuticle. The method described in the literature (Baur et al., 1997 , Pesticide Science  51, 131-152) can be used in order to determine this property. 
     Examples of suitable penetrants include alkanol alkoxylates. Penetrants of the invention are alkanol alkoxylates of the formula 
       R—O-(-AO) v —R′  (III) 
     in which
         R is linear or branched alkyl having 4 to 20 carbon atoms,   R′ is hydrogen, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, n-pentyl or n-hexyl,   AO is an ethylene oxide radical, a propylene oxide radical, a butylene oxide radical or is mixtures of ethylene oxide and propylene oxide radicals or butylene oxide radicals, and   v is a number from 2 to 30.       

     Alkanol alkoxylates of the kind in which R′ is hydrogen are referred to as “open” alkanol alkoxylates. One preferred group of penetrants are alkanol alkoxylates of the formula 
       R—O-(-EO—) n —R′  (III-a) 
     in which
         R is as defined above,   R′ is as defined above,   EO is —CH 2 —CH 2 —O—, and   n is a number from 2 to 20.       

     A further preferred group of penetrants are alkanol alkoxylates of the formula 
       R—O-(-EO—) p —(—PO—) q —R′  (III-b) 
     in which
         R is as defined above,   R′ is as defined above,   EO is —CH 2 —CH 2 —O—,   PO is       

     
       
         
         
             
             
         
       
         
         
           
             p is a number from 1 to 10, and 
             q is a number from 1 to 10. 
           
         
       
    
     A further preferred group of penetrants are alkanol alkoxylates of the formula 
       R—O—(—PO—) r -(EO—) s —R′  (III-c) 
     in which
         R is as defined above,   R′ is as defined above,   EO is —CH 2 —CH 2 —O—,   PO is       

     
       
         
         
             
             
         
       
         
         
           
             r is a number from 1 to 10, and 
             s is a number from 1 to 10. 
           
         
       
    
     A further preferred group of penetrants are alkanol alkoxylates of the formula 
       R—O-(-EO—) p —(—BO—) q —R′  (III-d) 
     in which
         R and R′ are as defined above,   EO is CH 2 —CH 2 —O—,       

     BO is 
     
       
         
         
             
             
         
       
         
         
           
             p is a number from 1 to 10 and 
             q is a number from 1 to 10. 
           
         
       
    
     A further preferred group of penetrants are alkanol alkoxylates of the formula 
       R—O—(—BO—) r -(-EO—) s —R′  (III-e) 
     in which
         R and R′ are as defined above,   BO is       

     
       
         
         
             
             
         
       
         
         
           
             EO is CH 2 —CH 2 —O—, 
             r is a number from 1 to 10 and 
             s is a number from 1 to 10. 
           
         
       
    
     A further preferred group of penetrants are alkanol alkoxylates of the formula 
       CH 3 —(CH 2 ) t —CH 2 —O—(—CH 2 —CH 2 —O—) u —R′  (III-f) 
     in which
         R′ is as defined above,   t is a number from 8 to 13,   u is a number from 6 to 17.       

     In the formulae indicated above,
     R is preferably butyl, isobutyl, n-pentyl, isopentyl, neopentyl, n-hexyl, isohexyl, n-octyl, isooctyl, 2-ethylhexyl, nonyl, isononyl, decyl, n-dodecyl, isododecyl, lauryl, myristyl, isotridecyl, trimethylnonyl, palmityl, stearyl or eicosyl.   

     As an example of an alkanol alkoxylate of the formula (III-c) mention may be made of 2-ethylhexyl alkoxylate of the formula 
     
       
         
         
             
             
         
       
     
     in which
         EO is —CH 2 —CH 2 —O—,   PO is       

     
       
         
         
             
             
         
       
     
     and
 
the numbers 8 and 6 represent average values.
 
     As an example of an alkanol alkoxylate of the formula (III-d) mention may be made of the formula 
       CH 3 —(CH 2 ) 10 —O-(-EO—) 6 —(—BO—) 2 —CH 3   (III-d-1) 
     in which
         EO is CH 2 —CH 2 —O—,   BO is       

     
       
         
         
             
             
         
       
     
     and
         the numbers 10, 6 and 2 represent average values.       

     Particularly preferred alkanol alkoxylates of the formula (III-f) are compounds of this formula in which
         t is a number from 9 to 12 and   u is a number from 7 to 9.       

     Mention may be made with very particular preference of alkanol alkoxylate of the formula (III-f-1) 
       CH 3 —(CH 2 ) t —CH 2 —O—(—CH 2 —CH 2 —O—) u —H  (III-f-1) 
     in which
         t stands for the average value 10.5 and   u stands for the average value 8.4.       

     A general definition of the alkanol alkoxylates is given by the formulae above. These substances are mixtures of substances of the stated type with different chain lengths. The indices therefore have average values which may also deviate from whole numbers. 
     The alkanol alkoxylates of the formulae stated are known and in some cases are available commercially or can be prepared by known methods (cf. WO 98-35 553, WO 00-35 278 and EP-A 0 681 865). 
     Suitable penetrants also include, for example, substances which promote the availability of the compounds of the formula (I) in the spray coating. These include, for example, mineral or vegetable oils. Suitable oils are all mineral or vegetable oils—modified or otherwise—which can typically be used in agrochemical compositions. Mention may be made by way of example of sunflower oil, rapeseed oil, olive oil, castor oil, colza oil, maize seed oil, cotton seed oil and soybean oil, or the esters of said oils. Preference is given to rapeseed oil, sunflower oil and their methyl or ethyl esters. 
     The concentration of penetrant in the materials of the invention can be varied within a wide range. In the case of a formulated crop protection material it is in general 1% to 95%, preferably 1% to 55%, more preferably 15%-40% by weight. In the application-ready materials (spray liquors) the concentrations are generally between 0.1 and 10 g/l, preferably between 0.5 and 5 g/l. 
     Inventively emphasized combinations of active ingredient, salt and penetrant are listed in the table below. “as per test” means here that any compound that acts as a penetrant in the cuticle penetration test (Baur et al., 1997 , Pesticide Science  51, 131-152) is suitable. 
     
       
         
           
               
               
               
               
             
               
                   
               
               
                   
                 Active 
                   
                   
               
               
                 # 
                 ingredient 
                 Salt 
                 Penetrant 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
            
               
                 1 
                 (I-1-a-1) 
                 ammonium sulphate 
                 as per test 
               
               
                 2 
                 (I-1-a-1) 
                 ammonium lactate 
                 as per test 
               
               
                 3 
                 (I-1-a-1) 
                 ammonium nitrate 
                 as per test 
               
               
                 4 
                 (I-1-a-1) 
                 ammonium thiosulphate 
                 as per test 
               
               
                 5 
                 (I-1-a-1) 
                 ammonium thiocyanate 
                 as per test 
               
               
                 6 
                 (I-1-a-1) 
                 ammonium citrate 
                 as per test 
               
               
                 7 
                 (I-1-a-1) 
                 ammonium oxalate 
                 as per test 
               
               
                 8 
                 (I-1-a-1) 
                 ammonium formate 
                 as per test 
               
               
                 9 
                 (I-1-a-1) 
                 ammonium hydrogenphosphate 
                 as per test 
               
               
                 10 
                 (I-1-a-1) 
                 ammonium dihydrogenphosphate 
                 as per test 
               
               
                 11 
                 (I-1-a-1) 
                 ammonium carbonate 
                 as per test 
               
               
                 12 
                 (I-1-a-1) 
                 ammonium benzoate 
                 as per test 
               
               
                 13 
                 (I-1-a-1) 
                 ammonium sulphite 
                 as per test 
               
               
                 14 
                 (I-1-a-1) 
                 ammonium benzoate 
                 as per test 
               
               
                 15 
                 (I-1-a-1) 
                 ammonium hydrogenoxalate 
                 as per test 
               
               
                 16 
                 (I-1-a-1) 
                 ammonium hydrogencitrate 
                 as per test 
               
               
                 17 
                 (I-1-a-1) 
                 ammonium acetate 
                 as per test 
               
               
                 18 
                 (I-1-a-1) 
                 tetramethylammonium sulphate 
                 as per test 
               
               
                 19 
                 (I-1-a-1) 
                 tetramethylammonium lactate 
                 as per test 
               
               
                 20 
                 (I-1-a-1) 
                 tetramethylammonium nitrate 
                 as per test 
               
               
                 21 
                 (I-1-a-1) 
                 tetramethylammonium thiosulphate 
                 as per test 
               
               
                 22 
                 (I-1-a-1) 
                 tetramethylammonium thiocyanate 
                 as per test 
               
               
                 23 
                 (I-1-a-1) 
                 tetramethylammonium citrate 
                 as per test 
               
               
                 24 
                 (I-1-a-1) 
                 tetramethylammonium oxalate 
                 as per test 
               
               
                 25 
                 (I-1-a-1) 
                 tetramethylammonium formate 
                 as per test 
               
               
                 26 
                 (I-1-a-1) 
                 tetramethylammonium hydrogenphosphate 
                 as per test 
               
               
                 27 
                 (I-1-a-1) 
                 tetramethylammonium 
                 as per test 
               
               
                   
                   
                 dihydrogenphosphate 
               
               
                 28 
                 (I-1-a-1) 
                 tetraethylammonium sulphate 
                 as per test 
               
               
                 29 
                 (I-1-a-1) 
                 tetraethylammonium lactate 
                 as per test 
               
               
                 30 
                 (I-1-a-1) 
                 tetraethylammonium nitrate 
                 as per test 
               
               
                 31 
                 (I-1-a-1) 
                 tetraethylammonium thiosulphate 
                 as per test 
               
               
                 32 
                 (I-1-a-1) 
                 tetraethylammonium thiocyanate 
                 as per test 
               
               
                 33 
                 (I-1-a-1) 
                 tetraethylammonium citrate 
                 as per test 
               
               
                 34 
                 (I-1-a-1) 
                 tetraethylammonium oxalate 
                 as per test 
               
               
                 35 
                 (I-1-a-1) 
                 tetraethylammonium formate 
                 as per test 
               
               
                 36 
                 (I-1-a-1) 
                 tetraethylammonium hydrogenphosphate 
                 as per test 
               
               
                 37 
                 (I-1-a-1) 
                 tetraethylammonium dihydrogenphosphate 
                 as per test 
               
               
                 38 
                 (I-1-a-2) 
                 ammonium sulphate 
                 as per test 
               
               
                 39 
                 (I-1-a-2) 
                 ammonium lactate 
                 as per test 
               
               
                 40 
                 (I-1-a-2) 
                 ammonium nitrate 
                 as per test 
               
               
                 41 
                 (I-1-a-2) 
                 ammonium thiosulphate 
                 as per test 
               
               
                 42 
                 (I-1-a-2) 
                 ammonium thiocyanate 
                 as per test 
               
               
                 43 
                 (I-1-a-2) 
                 ammonium citrate 
                 as per test 
               
               
                 44 
                 (I-1-a-2) 
                 ammonium oxalate 
                 as per test 
               
               
                 45 
                 (I-1-a-2) 
                 ammonium formate 
                 as per test 
               
               
                 46 
                 (I-1-a-2) 
                 ammonium hydrogenphosphate 
                 as per test 
               
               
                 47 
                 (I-1-a-2) 
                 ammonium dihydrogenphosphate 
                 as per test 
               
               
                 48 
                 (I-1-a-2) 
                 ammonium carbonate 
                 as per test 
               
               
                 49 
                 (I-1-a-2) 
                 ammonium benzoate 
                 as per test 
               
               
                 50 
                 (I-1-a-2) 
                 ammonium sulphite 
                 as per test 
               
               
                 51 
                 (I-1-a-2) 
                 ammonium benzoate 
                 as per test 
               
               
                 52 
                 (I-1-a-2) 
                 ammonium hydrogenoxalate 
                 as per test 
               
               
                 53 
                 (I-1-a-2) 
                 ammonium hydrogencitrate 
                 as per test 
               
               
                 54 
                 (I-1-a-2) 
                 ammonium acetate 
                 as per test 
               
               
                 55 
                 (I-1-a-2) 
                 tetramethylammonium sulphate 
                 as per test 
               
               
                 56 
                 (I-1-a-2) 
                 tetramethylammonium lactate 
                 as per test 
               
               
                 57 
                 (I-1-a-2) 
                 tetramethylammonium nitrate 
                 as per test 
               
               
                 58 
                 (I-1-a-2) 
                 tetramethylammonium thiosulphate 
                 as per test 
               
               
                 59 
                 (I-1-a-2) 
                 tetramethylammonium thiocyanate 
                 as per test 
               
               
                 60 
                 (I-1-a-2) 
                 tetramethylammonium citrate 
                 as per test 
               
               
                 61 
                 (I-1-a-2) 
                 tetramethylammonium oxalate 
                 as per test 
               
               
                 62 
                 (I-1-a-2) 
                 tetramethylammonium formate 
                 as per test 
               
               
                 63 
                 (I-1-a-2) 
                 tetramethylammonium hydrogenphosphate 
                 as per test 
               
               
                 64 
                 (I-1-a-2) 
                 tetramethylammonium 
                 as per test 
               
               
                   
                   
                 dihydrogenphosphate 
               
               
                 65 
                 (I-1-a-2) 
                 tetraethylammonium sulphate 
                 as per test 
               
               
                 66 
                 (I-1-a-2) 
                 tetraethylammonium lactate 
                 as per test 
               
               
                 67 
                 (I-1-a-2) 
                 tetraethylammonium nitrate 
                 as per test 
               
               
                 68 
                 (I-1-a-2) 
                 tetraethylammonium thiosulphate 
                 as per test 
               
               
                 69 
                 (I-1-a-2) 
                 tetraethylammonium thiocyanate 
                 as per test 
               
               
                 70 
                 (I-1-a-2) 
                 tetraethylammonium citrate 
                 as per test 
               
               
                 71 
                 (I-1-a-2) 
                 tetraethylammonium oxalate 
                 as per test 
               
               
                 72 
                 (I-1-a-2) 
                 tetraethylammonium formate 
                 as per test 
               
               
                 73 
                 (I-1-a-2) 
                 tetraethylammonium hydrogenphosphate 
                 as per test 
               
               
                 74 
                 (I-1-a-2) 
                 tetraethylammonium dihydrogenphosphate 
                 as per test 
               
               
                 75 
                 (I-1-a-3) 
                 ammonium sulphate 
                 as per test 
               
               
                 76 
                 (I-1-a-3) 
                 ammonium lactate 
                 as per test 
               
               
                 77 
                 (I-1-a-3) 
                 ammonium nitrate 
                 as per test 
               
               
                 78 
                 (I-1-a-3) 
                 ammonium thiosulphate 
                 as per test 
               
               
                 79 
                 (I-1-a-3) 
                 ammonium thiocyanate 
                 as per test 
               
               
                 80 
                 (I-1-a-3) 
                 ammonium citrate 
                 as per test 
               
               
                 81 
                 (I-1-a-3) 
                 ammonium oxalate 
                 as per test 
               
               
                 82 
                 (I-1-a-3) 
                 ammonium formate 
                 as per test 
               
               
                 83 
                 (I-1-a-3) 
                 ammonium hydrogenphosphate 
                 as per test 
               
               
                 84 
                 (I-1-a-3) 
                 ammonium dihydrogenphosphate 
                 as per test 
               
               
                 85 
                 (I-1-a-3) 
                 ammonium carbonate 
                 as per test 
               
               
                 86 
                 (I-1-a-3) 
                 ammonium benzoate 
                 as per test 
               
               
                 87 
                 (I-1-a-3) 
                 ammonium sulphite 
                 as per test 
               
               
                 88 
                 (I-1-a-3) 
                 ammonium benzoate 
                 as per test 
               
               
                 89 
                 (I-1-a-3) 
                 ammonium hydrogenoxalate 
                 as per test 
               
               
                 90 
                 (I-1-a-3) 
                 ammonium hydrogencitrate 
                 as per test 
               
               
                 91 
                 (I-1-a-3) 
                 ammonium acetate 
                 as per test 
               
               
                 92 
                 (I-1-a-3) 
                 tetramethylammonium sulphate 
                 as per test 
               
               
                 93 
                 (I-1-a-3) 
                 tetramethylammonium lactate 
                 as per test 
               
               
                 94 
                 (I-1-a-3) 
                 tetramethylammonium nitrate 
                 as per test 
               
               
                 95 
                 (I-1-a-3) 
                 tetramethylammonium thiosulphate 
                 as per test 
               
               
                 96 
                 (I-1-a-3) 
                 tetramethylammonium thiocyanate 
                 as per test 
               
               
                 97 
                 (I-1-a-3) 
                 tetramethylammonium citrate 
                 as per test 
               
               
                 98 
                 (I-1-a-3) 
                 tetramethylammonium oxalate 
                 as per test 
               
               
                 99 
                 (I-1-a-3) 
                 tetramethylammonium formate 
                 as per test 
               
               
                 100 
                 (I-1-a-3) 
                 tetramethylammonium hydrogenphosphate 
                 as per test 
               
               
                 101 
                 (I-1-a-3) 
                 tetramethylammonium 
                 as per test 
               
               
                   
                   
                 dihydrogenphosphate 
               
               
                 102 
                 (I-1-a-3) 
                 tetraethylammonium sulphate 
                 as per test 
               
               
                 103 
                 (I-1-a-3) 
                 tetraethylammonium lactate 
                 as per test 
               
               
                 104 
                 (I-1-a-3) 
                 tetraethylammonium nitrate 
                 as per test 
               
               
                 105 
                 (I-1-a-3) 
                 tetraethylammonium thiosulphate 
                 as per test 
               
               
                 106 
                 (I-1-a-3) 
                 tetraethylammonium thiocyanate 
                 as per test 
               
               
                 107 
                 (I-1-a-3) 
                 tetraethylammonium citrate 
                 as per test 
               
               
                 108 
                 (I-1-a-3) 
                 tetraethylammonium oxalate 
                 as per test 
               
               
                 109 
                 (I-1-a-3) 
                 tetraethylammonium formate 
                 as per test 
               
               
                 110 
                 (I-1-a-3) 
                 tetraethylammonium hydrogenphosphate 
                 as per test 
               
               
                 111 
                 (I-1-a-3) 
                 tetraethylammonium dihydrogenphosphate 
                 as per test 
               
               
                 112 
                 (I-1-a-4) 
                 ammonium sulphate 
                 as per test 
               
               
                 113 
                 (I-1-a-4) 
                 ammonium lactate 
                 as per test 
               
               
                 114 
                 (I-1-a-4) 
                 ammonium nitrate 
                 as per test 
               
               
                 115 
                 (I-1-a-4) 
                 ammonium thiosulphate 
                 as per test 
               
               
                 116 
                 (I-1-a-4) 
                 ammonium thiocyanate 
                 as per test 
               
               
                 117 
                 (I-1-a-4) 
                 ammonium citrate 
                 as per test 
               
               
                 118 
                 (I-1-a-4) 
                 ammonium oxalate 
                 as per test 
               
               
                 119 
                 (I-1-a-4) 
                 ammonium formate 
                 as per test 
               
               
                 120 
                 (I-1-a-4) 
                 ammonium hydrogenphosphate 
                 as per test 
               
               
                 121 
                 (I-1-a-4) 
                 ammonium dihydrogenphosphate 
                 as per test 
               
               
                 122 
                 (I-1-a-4) 
                 ammonium carbonate 
                 as per test 
               
               
                 123 
                 (I-1-a-4) 
                 ammonium benzoate 
                 as per test 
               
               
                 124 
                 (I-1-a-4) 
                 ammonium sulphite 
                 as per test 
               
               
                 125 
                 (I-1-a-4) 
                 ammonium benzoate 
                 as per test 
               
               
                 126 
                 (I-1-a-4) 
                 ammonium hydrogenoxalate 
                 as per test 
               
               
                 127 
                 (I-1-a-4) 
                 ammonium hydrogencitrate 
                 as per test 
               
               
                 128 
                 (I-1-a-4) 
                 ammonium acetate 
                 as per test 
               
               
                 129 
                 (I-1-a-4) 
                 tetramethylammonium sulphate 
                 as per test 
               
               
                 130 
                 (I-1-a-4) 
                 tetramethylammonium lactate 
                 as per test 
               
               
                 131 
                 (I-1-a-4) 
                 tetramethylammonium nitrate 
                 as per test 
               
               
                 132 
                 (I-1-a-4) 
                 tetramethylammonium thiosulphate 
                 as per test 
               
               
                 133 
                 (I-1-a-4) 
                 tetramethylammonium thiocyanate 
                 as per test 
               
               
                 134 
                 (I-1-a-4) 
                 tetramethylammonium citrate 
                 as per test 
               
               
                 135 
                 (I-1-a-4) 
                 tetramethylammonium oxalate 
                 as per test 
               
               
                 136 
                 (I-1-a-4) 
                 tetramethylammonium formate 
                 as per test 
               
               
                 137 
                 (I-1-a-4) 
                 tetramethylammonium hydrogenphosphate 
                 as per test 
               
               
                 138 
                 (I-1-a-4) 
                 tetramethylammonium 
                 as per test 
               
               
                   
                   
                 dihydrogenphosphate 
               
               
                 139 
                 (I-1-a-4) 
                 tetraethylammonium sulphate 
                 as per test 
               
               
                 140 
                 (I-1-a-4) 
                 tetraethylammonium lactate 
                 as per test 
               
               
                 141 
                 (I-1-a-4) 
                 tetraethylammonium nitrate 
                 as per test 
               
               
                 142 
                 (I-1-a-4) 
                 tetraethylammonium thiosulphate 
                 as per test 
               
               
                 143 
                 (I-1-a-4) 
                 tetraethylammonium thiocyanate 
                 as per test 
               
               
                 144 
                 (I-1-a-4) 
                 tetraethylammonium citrate 
                 as per test 
               
               
                 145 
                 (I-1-a-4) 
                 tetraethylammonium oxalate 
                 as per test 
               
               
                 146 
                 (I-1-a-4) 
                 tetraethylammonium formate 
                 as per test 
               
               
                 147 
                 (I-1-a-4) 
                 tetraethylammonium hydrogenphosphate 
                 as per test 
               
               
                 148 
                 (I-1-a-4) 
                 tetraethylammonium dihydrogenphosphate 
                 as per test 
               
               
                 149 
                 (I-1-a-5) 
                 ammonium sulphate 
                 as per test 
               
               
                 150 
                 (I-1-a-5) 
                 ammonium lactate 
                 as per test 
               
               
                 151 
                 (I-1-a-5) 
                 ammonium nitrate 
                 as per test 
               
               
                 152 
                 (I-1-a-5) 
                 ammonium thiosulphate 
                 as per test 
               
               
                 153 
                 (I-1-a-5) 
                 ammonium thiocyanate 
                 as per test 
               
               
                 154 
                 (I-1-a-5) 
                 ammonium citrate 
                 as per test 
               
               
                 155 
                 (I-1-a-5) 
                 ammonium oxalate 
                 as per test 
               
               
                 156 
                 (I-1-a-5) 
                 ammonium formate 
                 as per test 
               
               
                 157 
                 (I-1-a-5) 
                 ammonium hydrogenphosphate 
                 as per test 
               
               
                 158 
                 (I-1-a-5) 
                 ammonium dihydrogenphosphate 
                 as per test 
               
               
                 159 
                 (I-1-a-5) 
                 ammonium carbonate 
                 as per test 
               
               
                 160 
                 (I-1-a-5) 
                 ammonium benzoate 
                 as per test 
               
               
                 161 
                 (I-1-a-5) 
                 ammonium sulphite 
                 as per test 
               
               
                 162 
                 (I-1-a-5) 
                 ammonium benzoate 
                 as per test 
               
               
                 163 
                 (I-1-a-5) 
                 ammonium hydrogenoxalate 
                 as per test 
               
               
                 164 
                 (I-1-a-5) 
                 ammonium hydrogencitrate 
                 as per test 
               
               
                 165 
                 (I-1-a-5) 
                 ammonium acetate 
                 as per test 
               
               
                 166 
                 (I-1-a-5) 
                 tetramethylammonium sulphate 
                 as per test 
               
               
                 167 
                 (I-1-a-5) 
                 tetramethylammonium lactate 
                 as per test 
               
               
                 168 
                 (I-1-a-5) 
                 tetramethylammonium nitrate 
                 as per test 
               
               
                 169 
                 (I-1-a-5) 
                 tetramethylammonium thiosulphate 
                 as per test 
               
               
                 170 
                 (I-1-a-5) 
                 tetramethylammonium thiocyanate 
                 as per test 
               
               
                 171 
                 (I-1-a-5) 
                 tetramethylammonium citrate 
                 as per test 
               
               
                 172 
                 (I-1-a-5) 
                 tetramethylammonium oxalate 
                 as per test 
               
               
                 173 
                 (I-1-a-5) 
                 tetramethylammonium formate 
                 as per test 
               
               
                 174 
                 (I-1-a-5) 
                 tetramethylammonium hydrogenphosphate 
                 as per test 
               
               
                 175 
                 (I-1-a-5) 
                 tetramethylammonium 
                 as per test 
               
               
                   
                   
                 dihydrogenphosphate 
               
               
                 176 
                 (I-1-a-5) 
                 tetraethylammonium sulphate 
                 as per test 
               
               
                 177 
                 (I-1-a-5) 
                 tetraethylammonium lactate 
                 as per test 
               
               
                 178 
                 (I-1-a-5) 
                 tetraethylammonium nitrate 
                 as per test 
               
               
                 179 
                 (I-1-a-5) 
                 tetraethylammonium thiosulphate 
                 as per test 
               
               
                 180 
                 (I-1-a-5) 
                 tetraethylammonium thiocyanate 
                 as per test 
               
               
                 181 
                 (I-1-a-5) 
                 tetraethylammonium citrate 
                 as per test 
               
               
                 182 
                 (I-1-a-5) 
                 tetraethylammonium oxalate 
                 as per test 
               
               
                 183 
                 (I-1-a-5) 
                 tetraethylammonium formate 
                 as per test 
               
               
                 184 
                 (I-1-a-5) 
                 tetraethylammonium hydrogenphosphate 
                 as per test 
               
               
                 185 
                 (I-1-a-5) 
                 tetraethylammonium dihydrogenphosphate 
                 as per test 
               
               
                 186 
                 (I-1-a-6) 
                 ammonium sulphate 
                 as per test 
               
               
                 187 
                 (I-1-a-6) 
                 ammonium lactate 
                 as per test 
               
               
                 188 
                 (I-1-a-6) 
                 ammonium nitrate 
                 as per test 
               
               
                 189 
                 (I-1-a-6) 
                 ammonium thiosulphate 
                 as per test 
               
               
                 190 
                 (I-1-a-6) 
                 ammonium thiocyanate 
                 as per test 
               
               
                 191 
                 (I-1-a-6) 
                 ammonium citrate 
                 as per test 
               
               
                 192 
                 (I-1-a-6) 
                 ammonium oxalate 
                 as per test 
               
               
                 193 
                 (I-1-a-6) 
                 ammonium formate 
                 as per test 
               
               
                 194 
                 (I-1-a-6) 
                 ammonium hydrogenphosphate 
                 as per test 
               
               
                 195 
                 (I-1-a-6) 
                 ammonium dihydrogenphosphate 
                 as per test 
               
               
                 196 
                 (I-1-a-6) 
                 ammonium carbonate 
                 as per test 
               
               
                 197 
                 (I-1-a-6) 
                 ammonium benzoate 
                 as per test 
               
               
                 198 
                 (I-1-a-6) 
                 ammonium sulphite 
                 as per test 
               
               
                 199 
                 (I-1-a-6) 
                 ammonium benzoate 
                 as per test 
               
               
                 200 
                 (I-1-a-6) 
                 ammonium hydrogenoxalate 
                 as per test 
               
               
                 201 
                 (I-1-a-6) 
                 ammonium hydrogencitrate 
                 as per test 
               
               
                 202 
                 (I-1-a-6) 
                 ammonium acetate 
                 as per test 
               
               
                 203 
                 (I-1-a-6) 
                 tetramethylammonium sulphate 
                 as per test 
               
               
                 204 
                 (I-1-a-6) 
                 tetramethylammonium lactate 
                 as per test 
               
               
                 205 
                 (I-1-a-6) 
                 tetramethylammonium nitrate 
                 as per test 
               
               
                 206 
                 (I-1-a-6) 
                 tetramethylammonium thiosulphate 
                 as per test 
               
               
                 207 
                 (I-1-a-6) 
                 tetramethylammonium thiocyanate 
                 as per test 
               
               
                 208 
                 (I-1-a-6) 
                 tetramethylammonium citrate 
                 as per test 
               
               
                 209 
                 (I-1-a-6) 
                 tetramethylammonium oxalate 
                 as per test 
               
               
                 210 
                 (I-1-a-6) 
                 tetramethylammonium formate 
                 as per test 
               
               
                 211 
                 (I-1-a-6) 
                 tetramethylammonium hydrogenphosphate 
                 as per test 
               
               
                 212 
                 (I-1-a-6) 
                 tetramethylammonium 
                 as per test 
               
               
                   
                   
                 dihydrogenphosphate 
               
               
                 213 
                 (I-1-a-6) 
                 tetraethylammonium sulphate 
                 as per test 
               
               
                 214 
                 (I-1-a-6) 
                 tetraethylammonium lactate 
                 as per test 
               
               
                 215 
                 (I-1-a-6) 
                 tetraethylammonium nitrate 
                 as per test 
               
               
                 216 
                 (I-1-a-6) 
                 tetraethylammonium thiosulphate 
                 as per test 
               
               
                 217 
                 (I-1-a-6) 
                 tetraethylammonium thiocyanate 
                 as per test 
               
               
                 218 
                 (I-1-a-6) 
                 tetraethylammonium citrate 
                 as per test 
               
               
                 219 
                 (I-1-a-6) 
                 tetraethylammonium oxalate 
                 as per test 
               
               
                 220 
                 (I-1-a-6) 
                 tetraethylammonium formate 
                 as per test 
               
               
                 221 
                 (I-1-a-6) 
                 tetraethylammonium hydrogenphosphate 
                 as per test 
               
               
                 222 
                 (I-1-a-6) 
                 tetraethylammonium dihydrogenphosphate 
                 as per test 
               
               
                 223 
                 (I-1-b-1) 
                 ammonium sulphate 
                 as per test 
               
               
                 224 
                 (I-1-b-1) 
                 ammonium lactate 
                 as per test 
               
               
                 225 
                 (I-1-b-1) 
                 ammonium nitrate 
                 as per test 
               
               
                 226 
                 (I-1-b-1) 
                 ammonium thiosulphate 
                 as per test 
               
               
                 227 
                 (I-1-b-1) 
                 ammonium thiocyanate 
                 as per test 
               
               
                 228 
                 (I-1-b-1) 
                 ammonium citrate 
                 as per test 
               
               
                 229 
                 (I-1-b-1) 
                 ammonium oxalate 
                 as per test 
               
               
                 230 
                 (I-1-b-1) 
                 ammonium formate 
                 as per test 
               
               
                 231 
                 (I-1-b-1) 
                 ammonium hydrogenphosphate 
                 as per test 
               
               
                 232 
                 (I-1-b-1) 
                 ammonium dihydrogenphosphate 
                 as per test 
               
               
                 233 
                 (I-1-b-1) 
                 ammonium carbonate 
                 as per test 
               
               
                 234 
                 (I-1-b-1) 
                 ammonium benzoate 
                 as per test 
               
               
                 235 
                 (I-1-b-1) 
                 ammonium sulphite 
                 as per test 
               
               
                 236 
                 (I-1-b-1) 
                 ammonium benzoate 
                 as per test 
               
               
                 237 
                 (I-1-b-1) 
                 ammonium hydrogenoxalate 
                 as per test 
               
               
                 238 
                 (I-1-b-1) 
                 ammonium hydrogencitrate 
                 as per test 
               
               
                 239 
                 (I-1-b-1) 
                 ammonium acetate 
                 as per test 
               
               
                 240 
                 (I-1-b-1) 
                 tetramethylammonium sulphate 
                 as per test 
               
               
                 241 
                 (I-1-b-1) 
                 tetramethylammonium lactate 
                 as per test 
               
               
                 242 
                 (I-1-b-1) 
                 tetramethylammonium nitrate 
                 as per test 
               
               
                 243 
                 (I-1-b-1) 
                 tetramethylammonium thiosulphate 
                 as per test 
               
               
                 244 
                 (I-1-b-1) 
                 tetramethylammonium thiocyanate 
                 as per test 
               
               
                 245 
                 (I-1-b-1) 
                 tetramethylammonium citrate 
                 as per test 
               
               
                 246 
                 (I-1-b-1) 
                 tetramethylammonium oxalate 
                 as per test 
               
               
                 247 
                 (I-1-b-1) 
                 tetramethylammonium formate 
                 as per test 
               
               
                 248 
                 (I-1-b-1) 
                 tetramethylammonium hydrogenphosphate 
                 as per test 
               
               
                 249 
                 (I-1-b-1) 
                 tetramethylammonium 
                 as per test 
               
               
                   
                   
                 dihydrogenphosphate 
               
               
                 250 
                 (I-1-b-1) 
                 tetraethylammonium sulphate 
                 as per test 
               
               
                 251 
                 (I-1-b-1) 
                 tetraethylammonium lactate 
                 as per test 
               
               
                 252 
                 (I-1-b-1) 
                 tetraethylammonium nitrate 
                 as per test 
               
               
                 253 
                 (I-1-b-1) 
                 tetraethylammonium thiosulphate 
                 as per test 
               
               
                 254 
                 (I-1-b-1) 
                 tetraethylammonium thiocyanate 
                 as per test 
               
               
                 255 
                 (I-1-b-1) 
                 tetraethylammonium citrate 
                 as per test 
               
               
                 256 
                 (I-1-b-1) 
                 tetraethylammonium oxalate 
                 as per test 
               
               
                 257 
                 (I-1-b-1) 
                 tetraethylammonium formate 
                 as per test 
               
               
                 258 
                 (I-1-b-1) 
                 tetraethylammonium hydrogenphosphate 
                 as per test 
               
               
                 259 
                 (I-1-b-1) 
                 tetraethylammonium dihydrogenphosphate 
                 as per test 
               
               
                 260 
                 (I-1-c-1) 
                 ammonium sulphate 
                 as per test 
               
               
                 261 
                 (I-1-c-1) 
                 ammonium lactate 
                 as per test 
               
               
                 262 
                 (I-1-c-1) 
                 ammonium nitrate 
                 as per test 
               
               
                 263 
                 (I-1-c-1) 
                 ammonium thiosulphate 
                 as per test 
               
               
                 264 
                 (I-1-c-1) 
                 ammonium thiocyanate 
                 as per test 
               
               
                 265 
                 (I-1-c-1) 
                 ammonium citrate 
                 as per test 
               
               
                 266 
                 (I-1-c-1) 
                 ammonium oxalate 
                 as per test 
               
               
                 267 
                 (I-1-c-1) 
                 ammonium formate 
                 as per test 
               
               
                 268 
                 (I-1-c-1) 
                 ammonium hydrogenphosphate 
                 as per test 
               
               
                 269 
                 (I-1-c-1) 
                 ammonium dihydrogenphosphate 
                 as per test 
               
               
                 270 
                 (I-1-c-1) 
                 ammonium carbonate 
                 as per test 
               
               
                 271 
                 (I-1-c-1) 
                 ammonium benzoate 
                 as per test 
               
               
                 272 
                 (I-1-c-1) 
                 ammonium sulphite 
                 as per test 
               
               
                 273 
                 (I-1-c-1) 
                 ammonium benzoate 
                 as per test 
               
               
                 274 
                 (I-1-c-1) 
                 ammonium hydrogenoxalate 
                 as per test 
               
               
                 275 
                 (I-1-c-1) 
                 ammonium hydrogencitrate 
                 as per test 
               
               
                 276 
                 (I-1-c-1) 
                 ammonium acetate 
                 as per test 
               
               
                 277 
                 (I-1-c-1) 
                 tetramethylammonium sulphate 
                 as per test 
               
               
                 278 
                 (I-1-c-1) 
                 tetramethylammonium lactate 
                 as per test 
               
               
                 279 
                 (I-1-c-1) 
                 tetramethylammonium nitrate 
                 as per test 
               
               
                 280 
                 (I-1-c-1) 
                 tetramethylammonium thiosulphate 
                 as per test 
               
               
                 281 
                 (I-1-c-1) 
                 tetramethylammonium thiocyanate 
                 as per test 
               
               
                 282 
                 (I-1-c-1) 
                 tetramethylammonium citrate 
                 as per test 
               
               
                 283 
                 (I-1-c-1) 
                 tetramethylammonium oxalate 
                 as per test 
               
               
                 284 
                 (I-1-c-1) 
                 tetramethylammonium formate 
                 as per test 
               
               
                 285 
                 (I-1-c-1) 
                 tetramethylammonium hydrogenphosphate 
                 as per test 
               
               
                 286 
                 (I-1-c-1) 
                 tetramethylammonium 
                 as per test 
               
               
                   
                   
                 dihydrogenphosphate 
               
               
                 287 
                 (I-1-c-1) 
                 tetraethylammonium sulphate 
                 as per test 
               
               
                 288 
                 (I-1-c-1) 
                 tetraethylammonium lactate 
                 as per test 
               
               
                 289 
                 (I-1-c-1) 
                 tetraethylammonium nitrate 
                 as per test 
               
               
                 290 
                 (I-1-c-1) 
                 tetraethylammonium thiosulphate 
                 as per test 
               
               
                 291 
                 (I-1-c-1) 
                 tetraethylammonium thiocyanate 
                 as per test 
               
               
                 292 
                 (I-1-c-1) 
                 tetraethylammonium citrate 
                 as per test 
               
               
                 293 
                 (I-1-c-1) 
                 tetraethylammonium oxalate 
                 as per test 
               
               
                 294 
                 (I-1-c-1) 
                 tetraethylammonium formate 
                 as per test 
               
               
                 295 
                 (I-1-c-1) 
                 tetraethylammonium hydrogenphosphate 
                 as per test 
               
               
                 296 
                 (I-1-c-1) 
                 tetraethylammonium dihydrogenphosphate 
                 as per test 
               
               
                 297 
                 (I-2-a-1) 
                 ammonium sulphate 
                 as per test 
               
               
                 298 
                 (I-2-a-1) 
                 ammonium lactate 
                 as per test 
               
               
                 299 
                 (I-2-a-1) 
                 ammonium nitrate 
                 as per test 
               
               
                 300 
                 (I-2-a-1) 
                 ammonium thiosulphate 
                 as per test 
               
               
                 301 
                 (I-2-a-1) 
                 ammonium thiocyanate 
                 as per test 
               
               
                 302 
                 (I-2-a-1) 
                 ammonium citrate 
                 as per test 
               
               
                 303 
                 (I-2-a-1) 
                 ammonium oxalate 
                 as per test 
               
               
                 304 
                 (I-2-a-1) 
                 ammonium formate 
                 as per test 
               
               
                 305 
                 (I-2-a-1) 
                 ammonium hydrogenphosphate 
                 as per test 
               
               
                 306 
                 (I-2-a-1) 
                 ammonium dihydrogenphosphate 
                 as per test 
               
               
                 307 
                 (I-2-a-1) 
                 ammonium carbonate 
                 as per test 
               
               
                 308 
                 (I-2-a-1) 
                 ammonium benzoate 
                 as per test 
               
               
                 309 
                 (I-2-a-1) 
                 ammonium sulphite 
                 as per test 
               
               
                 310 
                 (I-2-a-1) 
                 ammonium benzoate 
                 as per test 
               
               
                 311 
                 (I-2-a-1) 
                 ammonium hydrogenoxalate 
                 as per test 
               
               
                 312 
                 (I-2-a-1) 
                 ammonium hydrogencitrate 
                 as per test 
               
               
                 313 
                 (I-2-a-1) 
                 ammonium acetate 
                 as per test 
               
               
                 314 
                 (I-2-a-1) 
                 tetramethylammonium sulphate 
                 as per test 
               
               
                 315 
                 (I-2-a-1) 
                 tetramethylammonium lactate 
                 as per test 
               
               
                 316 
                 (I-2-a-1) 
                 tetramethylammonium nitrate 
                 as per test 
               
               
                 317 
                 (I-2-a-1) 
                 tetramethylammonium thiosulphate 
                 as per test 
               
               
                 318 
                 (I-2-a-1) 
                 tetramethylammonium thiocyanate 
                 as per test 
               
               
                 319 
                 (I-2-a-1) 
                 tetramethylammonium citrate 
                 as per test 
               
               
                 320 
                 (I-2-a-1) 
                 tetramethylammonium oxalate 
                 as per test 
               
               
                 321 
                 (I-2-a-1) 
                 tetramethylammonium formate 
                 as per test 
               
               
                 322 
                 (I-2-a-1) 
                 tetramethylammonium hydrogenphosphate 
                 as per test 
               
               
                 323 
                 (I-2-a-1) 
                 tetramethylammonium 
                 as per test 
               
               
                   
                   
                 dihydrogenphosphate 
               
               
                 324 
                 (I-2-a-1) 
                 tetraethylammonium sulphate 
                 as per test 
               
               
                 325 
                 (I-2-a-1) 
                 tetraethylammonium lactate 
                 as per test 
               
               
                 326 
                 (I-2-a-1) 
                 tetraethylammonium nitrate 
                 as per test 
               
               
                 327 
                 (I-2-a-1) 
                 tetraethylammonium thiosulphate 
                 as per test 
               
               
                 328 
                 (I-2-a-1) 
                 tetraethylammonium thiocyanate 
                 as per test 
               
               
                 329 
                 (I-2-a-1) 
                 tetraethylammonium citrate 
                 as per test 
               
               
                 330 
                 (I-2-a-1) 
                 tetraethylammonium oxalate 
                 as per test 
               
               
                 331 
                 (I-2-a-1) 
                 tetraethylammonium formate 
                 as per test 
               
               
                 332 
                 (I-2-a-1) 
                 tetraethylammonium hydrogenphosphate 
                 as per test 
               
               
                 333 
                 (I-2-a-1) 
                 tetraethylammonium dihydrogenphosphate 
                 as per test 
               
               
                 334 
                 (I-4-a-1) 
                 ammonium sulphate 
                 as per test 
               
               
                 335 
                 (I-4-a-1) 
                 ammonium lactate 
                 as per test 
               
               
                 336 
                 (I-4-a-1) 
                 ammonium nitrate 
                 as per test 
               
               
                 337 
                 (I-4-a-1) 
                 ammonium thiosulphate 
                 as per test 
               
               
                 338 
                 (I-4-a-1) 
                 ammonium thiocyanate 
                 as per test 
               
               
                 339 
                 (I-4-a-1) 
                 ammonium citrate 
                 as per test 
               
               
                 340 
                 (I-4-a-1) 
                 ammonium oxalate 
                 as per test 
               
               
                 341 
                 (I-4-a-1) 
                 ammonium formate 
                 as per test 
               
               
                 342 
                 (I-4-a-1) 
                 ammonium hydrogenphosphate 
                 as per test 
               
               
                 343 
                 (I-4-a-1) 
                 ammonium dihydrogenphosphate 
                 as per test 
               
               
                 344 
                 (I-4-a-1) 
                 ammonium carbonate 
                 as per test 
               
               
                 345 
                 (I-4-a-1) 
                 ammonium benzoate 
                 as per test 
               
               
                 346 
                 (I-4-a-1) 
                 ammonium sulphite 
                 as per test 
               
               
                 347 
                 (I-4-a-1) 
                 ammonium benzoate 
                 as per test 
               
               
                 348 
                 (I-4-a-1) 
                 ammonium hydrogenoxalate 
                 as per test 
               
               
                 349 
                 (I-4-a-1) 
                 ammonium hydrogencitrate 
                 as per test 
               
               
                 350 
                 (I-4-a-1) 
                 ammonium acetate 
                 as per test 
               
               
                 351 
                 (I-4-a-1) 
                 tetramethylammonium sulphate 
                 as per test 
               
               
                 352 
                 (I-4-a-1) 
                 tetramethylammonium lactate 
                 as per test 
               
               
                 353 
                 (I-4-a-1) 
                 tetramethylammonium nitrate 
                 as per test 
               
               
                 354 
                 (I-4-a-1) 
                 tetramethylammonium thiosulphate 
                 as per test 
               
               
                 355 
                 (I-4-a-1) 
                 tetramethylammonium thiocyanate 
                 as per test 
               
               
                 356 
                 (I-4-a-1) 
                 tetramethylammonium citrate 
                 as per test 
               
               
                 357 
                 (I-4-a-1) 
                 tetramethylammonium oxalate 
                 as per test 
               
               
                 358 
                 (I-4-a-1) 
                 tetramethylammonium formate 
                 as per test 
               
               
                 359 
                 (I-4-a-1) 
                 tetramethylammonium hydrogenphosphate 
                 as per test 
               
               
                 360 
                 (I-4-a-1) 
                 tetramethylammonium 
                 as per test 
               
               
                   
                   
                 dihydrogenphosphate 
               
               
                 361 
                 (I-4-a-1) 
                 tetraethylammonium sulphate 
                 as per test 
               
               
                 362 
                 (I-4-a-1) 
                 tetraethylammonium lactate 
                 as per test 
               
               
                 363 
                 (I-4-a-1) 
                 tetraethylammonium nitrate 
                 as per test 
               
               
                 364 
                 (I-4-a-1) 
                 tetraethylammonium thiosulphate 
                 as per test 
               
               
                 365 
                 (I-4-a-1) 
                 tetraethylammonium thiocyanate 
                 as per test 
               
               
                 366 
                 (I-4-a-1) 
                 tetraethylammonium citrate 
                 as per test 
               
               
                 367 
                 (I-4-a-1) 
                 tetraethylammonium oxalate 
                 as per test 
               
               
                 368 
                 (I-4-a-1) 
                 tetraethylammonium formate 
                 as per test 
               
               
                 369 
                 (I-4-a-1) 
                 tetraethylammonium hydrogenphosphate 
                 as per test 
               
               
                 370 
                 (I-4-a-1) 
                 tetraethylammonium dihydrogenphosphate 
                 as per test 
               
               
                 371 
                 (I-6-a-1) 
                 ammonium sulphate 
                 as per test 
               
               
                 372 
                 (I-6-a-1) 
                 ammonium lactate 
                 as per test 
               
               
                 373 
                 (I-6-a-1) 
                 ammonium nitrate 
                 as per test 
               
               
                 374 
                 (I-6-a-1) 
                 ammonium thiosulphate 
                 as per test 
               
               
                 375 
                 (I-6-a-1) 
                 ammonium thiocyanate 
                 as per test 
               
               
                 376 
                 (I-6-a-1) 
                 ammonium citrate 
                 as per test 
               
               
                 377 
                 (I-6-a-1) 
                 ammonium oxalate 
                 as per test 
               
               
                 378 
                 (I-6-a-1) 
                 ammonium formate 
                 as per test 
               
               
                 379 
                 (I-6-a-1) 
                 ammonium hydrogenphosphate 
                 as per test 
               
               
                 380 
                 (I-6-a-1) 
                 ammonium dihydrogenphosphate 
                 as per test 
               
               
                 381 
                 (I-6-a-1) 
                 ammonium carbonate 
                 as per test 
               
               
                 382 
                 (I-6-a-1) 
                 ammonium benzoate 
                 as per test 
               
               
                 383 
                 (I-6-a-1) 
                 ammonium sulphite 
                 as per test 
               
               
                 384 
                 (I-6-a-1) 
                 ammonium benzoate 
                 as per test 
               
               
                 385 
                 (I-6-a-1) 
                 ammonium hydrogenoxalate 
                 as per test 
               
               
                 386 
                 (I-6-a-1) 
                 ammonium hydrogencitrate 
                 as per test 
               
               
                 387 
                 (I-6-a-1) 
                 ammonium acetate 
                 as per test 
               
               
                 388 
                 (I-6-a-1) 
                 tetramethylammonium sulphate 
                 as per test 
               
               
                 389 
                 (I-6-a-1) 
                 tetramethylammonium lactate 
                 as per test 
               
               
                 390 
                 (I-6-a-1) 
                 tetramethylammonium nitrate 
                 as per test 
               
               
                 391 
                 (I-6-a-1) 
                 tetramethylammonium thiosulphate 
                 as per test 
               
               
                 392 
                 (I-6-a-1) 
                 tetramethylammonium thiocyanate 
                 as per test 
               
               
                 393 
                 (I-6-a-1) 
                 tetramethylammonium citrate 
                 as per test 
               
               
                 394 
                 (I-6-a-1) 
                 tetramethylammonium oxalate 
                 as per test 
               
               
                 395 
                 (I-6-a-1) 
                 tetramethylammonium formate 
                 as per test 
               
               
                 396 
                 (I-6-a-1) 
                 tetramethylammonium hydrogenphosphate 
                 as per test 
               
               
                 397 
                 (I-6-a-1) 
                 tetramethylammonium 
                 as per test 
               
               
                   
                   
                 dihydrogenphosphate 
               
               
                 398 
                 (I-6-a-1) 
                 tetraethylammonium sulphate 
                 as per test 
               
               
                 399 
                 (I-6-a-1) 
                 tetraethylammonium lactate 
                 as per test 
               
               
                 400 
                 (I-6-a-1) 
                 tetraethylammonium nitrate 
                 as per test 
               
               
                 401 
                 (I-6-a-1) 
                 tetraethylammonium thiosulphate 
                 as per test 
               
               
                 402 
                 (I-6-a-1) 
                 tetraethylammonium thiocyanate 
                 as per test 
               
               
                 403 
                 (I-6-a-1) 
                 tetraethylammonium citrate 
                 as per test 
               
               
                 404 
                 (I-6-a-1) 
                 tetraethylammonium oxalate 
                 as per test 
               
               
                 405 
                 (I-6-a-1) 
                 tetraethylammonium formate 
                 as per test 
               
               
                 406 
                 (I-6-a-1) 
                 tetraethylammonium hydrogenphosphate 
                 as per test 
               
               
                 407 
                 (I-6-a-1) 
                 tetraethylammonium dihydrogenphosphate 
                 as per test 
               
               
                 408 
                 (I-6-a-2) 
                 ammonium sulphate 
                 as per test 
               
               
                 409 
                 (I-6-a-2) 
                 ammonium lactate 
                 as per test 
               
               
                 410 
                 (I-6-a-2) 
                 ammonium nitrate 
                 as per test 
               
               
                 411 
                 (I-6-a-2) 
                 ammonium thiosulphate 
                 as per test 
               
               
                 412 
                 (I-6-a-2) 
                 ammonium thiocyanate 
                 as per test 
               
               
                 413 
                 (I-6-a-2) 
                 ammonium citrate 
                 as per test 
               
               
                 414 
                 (I-6-a-2) 
                 ammonium oxalate 
                 as per test 
               
               
                 415 
                 (I-6-a-2) 
                 ammonium formate 
                 as per test 
               
               
                 416 
                 (I-6-a-2) 
                 ammonium hydrogenphosphate 
                 as per test 
               
               
                 417 
                 (I-6-a-2) 
                 ammonium dihydrogenphosphate 
                 as per test 
               
               
                 418 
                 (I-6-a-2) 
                 ammonium carbonate 
                 as per test 
               
               
                 419 
                 (I-6-a-2) 
                 ammonium benzoate 
                 as per test 
               
               
                 420 
                 (I-6-a-2) 
                 ammonium sulphite 
                 as per test 
               
               
                 421 
                 (I-6-a-2) 
                 ammonium benzoate 
                 as per test 
               
               
                 422 
                 (I-6-a-2) 
                 ammonium hydrogenoxalate 
                 as per test 
               
               
                 423 
                 (I-6-a-2) 
                 ammonium hydrogencitrate 
                 as per test 
               
               
                 424 
                 (I-6-a-2) 
                 ammonium acetate 
                 as per test 
               
               
                 425 
                 (I-6-a-2) 
                 tetramethylammonium sulphate 
                 as per test 
               
               
                 426 
                 (I-6-a-2) 
                 tetramethylammonium lactate 
                 as per test 
               
               
                 427 
                 (I-6-a-2) 
                 tetramethylammonium nitrate 
                 as per test 
               
               
                 428 
                 (I-6-a-2) 
                 tetramethylammonium thiosulphate 
                 as per test 
               
               
                 429 
                 (I-6-a-2) 
                 tetramethylammonium thiocyanate 
                 as per test 
               
               
                 430 
                 (I-6-a-2) 
                 tetramethylammonium citrate 
                 as per test 
               
               
                 431 
                 (I-6-a-2) 
                 tetramethylammonium oxalate 
                 as per test 
               
               
                 432 
                 (I-6-a-2) 
                 tetramethylammonium formate 
                 as per test 
               
               
                 433 
                 (I-6-a-2) 
                 tetramethylammonium hydrogenphosphate 
                 as per test 
               
               
                 434 
                 (I-6-a-2) 
                 tetramethylammonium 
                 as per test 
               
               
                   
                   
                 dihydrogenphosphate 
               
               
                 435 
                 (I-6-a-2) 
                 tetraethylammonium sulphate 
                 as per test 
               
               
                 436 
                 (I-6-a-2) 
                 tetraethylammonium lactate 
                 as per test 
               
               
                 437 
                 (I-6-a-2) 
                 tetraethylammonium nitrate 
                 as per test 
               
               
                 438 
                 (I-6-a-2) 
                 tetraethylammonium thiosulphate 
                 as per test 
               
               
                 439 
                 (I-6-a-2) 
                 tetraethylammonium thiocyanate 
                 as per test 
               
               
                 440 
                 (I-6-a-2) 
                 tetraethylammonium citrate 
                 as per test 
               
               
                 441 
                 (I-6-a-2) 
                 tetraethylammonium oxalate 
                 as per test 
               
               
                 442 
                 (I-6-a-2) 
                 tetraethylammonium formate 
                 as per test 
               
               
                 443 
                 (I-6-a-2) 
                 tetraethylammonium hydrogenphosphate 
                 as per test 
               
               
                 444 
                 (I-6-a-2) 
                 tetraethylammonium dihydrogenphosphate 
                 as per test 
               
               
                 445 
                 (I-8-a-1) 
                 ammonium sulphate 
                 as per test 
               
               
                 446 
                 (I-8-a-1) 
                 ammonium lactate 
                 as per test 
               
               
                 447 
                 (I-8-a-1) 
                 ammonium nitrate 
                 as per test 
               
               
                 448 
                 (I-8-a-1) 
                 ammonium thiosulphate 
                 as per test 
               
               
                 449 
                 (I-8-a-1) 
                 ammonium thiocyanate 
                 as per test 
               
               
                 450 
                 (I-8-a-1) 
                 ammonium citrate 
                 as per test 
               
               
                 451 
                 (I-8-a-1) 
                 ammonium oxalate 
                 as per test 
               
               
                 452 
                 (I-8-a-1) 
                 ammonium formate 
                 as per test 
               
               
                 453 
                 (I-8-a-1) 
                 ammonium hydrogenphosphate 
                 as per test 
               
               
                 454 
                 (I-8-a-1) 
                 ammonium dihydrogenphosphate 
                 as per test 
               
               
                 455 
                 (I-8-a-1) 
                 ammonium carbonate 
                 as per test 
               
               
                 456 
                 (I-8-a-1) 
                 ammonium benzoate 
                 as per test 
               
               
                 457 
                 (I-8-a-1) 
                 ammonium sulphite 
                 as per test 
               
               
                 458 
                 (I-8-a-1) 
                 ammonium benzoate 
                 as per test 
               
               
                 459 
                 (I-8-a-1) 
                 ammonium hydrogenoxalate 
                 as per test 
               
               
                 460 
                 (I-8-a-1) 
                 ammonium hydrogencitrate 
                 as per test 
               
               
                 461 
                 (I-8-a-1) 
                 ammonium acetate 
                 as per test 
               
               
                 462 
                 (I-8-a-1) 
                 tetramethylammonium sulphate 
                 as per test 
               
               
                 463 
                 (I-8-a-1) 
                 tetramethylammonium lactate 
                 as per test 
               
               
                 464 
                 (I-8-a-1) 
                 tetramethylammonium nitrate 
                 as per test 
               
               
                 465 
                 (I-8-a-1) 
                 tetramethylammonium thiosulphate 
                 as per test 
               
               
                 466 
                 (I-8-a-1) 
                 tetramethylammonium thiocyanate 
                 as per test 
               
               
                 467 
                 (I-8-a-1) 
                 tetramethylammonium citrate 
                 as per test 
               
               
                 468 
                 (I-8-a-1) 
                 tetramethylammonium oxalate 
                 as per test 
               
               
                 469 
                 (I-8-a-1) 
                 tetramethylammonium formate 
                 as per test 
               
               
                 470 
                 (I-8-a-1) 
                 tetramethylammonium hydrogenphosphate 
                 as per test 
               
               
                 471 
                 (I-8-a-1) 
                 tetramethylammonium 
                 as per test 
               
               
                   
                   
                 dihydrogenphosphate 
               
               
                 472 
                 (I-8-a-1) 
                 tetraethylammonium sulphate 
                 as per test 
               
               
                 473 
                 (I-8-a-1) 
                 tetraethylammonium lactate 
                 as per test 
               
               
                 474 
                 (I-8-a-1) 
                 tetraethylammonium nitrate 
                 as per test 
               
               
                 475 
                 (I-8-a-1) 
                 tetraethylammonium thiosulphate 
                 as per test 
               
               
                 476 
                 (I-8-a-1) 
                 tetraethylammonium thiocyanate 
                 as per test 
               
               
                 477 
                 (I-8-a-1) 
                 tetraethylammonium citrate 
                 as per test 
               
               
                 478 
                 (I-8-a-1) 
                 tetraethylammonium oxalate 
                 as per test 
               
               
                 479 
                 (I-8-a-1) 
                 tetraethylammonium formate 
                 as per test 
               
               
                 480 
                 (I-8-a-1) 
                 tetraethylammonium hydrogenphosphate 
                 as per test 
               
               
                 481 
                 (I-8-a-1) 
                 tetraethylammonium dihydrogenphosphate 
                 as per test 
               
               
                 482 
                 (I-8-b-1) 
                 ammonium sulphate 
                 as per test 
               
               
                 483 
                 (I-8-b-1) 
                 ammonium lactate 
                 as per test 
               
               
                 484 
                 (I-8-b-1) 
                 ammonium nitrate 
                 as per test 
               
               
                 485 
                 (I-8-b-1) 
                 ammonium thiosulphate 
                 as per test 
               
               
                 486 
                 (I-8-b-1) 
                 ammonium thiocyanate 
                 as per test 
               
               
                 487 
                 (I-8-b-1) 
                 ammonium citrate 
                 as per test 
               
               
                 488 
                 (I-8-b-1) 
                 ammonium oxalate 
                 as per test 
               
               
                 489 
                 (I-8-b-1) 
                 ammonium formate 
                 as per test 
               
               
                 490 
                 (I-8-b-1) 
                 ammonium hydrogenphosphate 
                 as per test 
               
               
                 491 
                 (I-8-b-1) 
                 ammonium dihydrogenphosphate 
                 as per test 
               
               
                 492 
                 (I-8-b-1) 
                 ammonium carbonate 
                 as per test 
               
               
                 493 
                 (I-8-b-1) 
                 ammonium benzoate 
                 as per test 
               
               
                 494 
                 (I-8-b-1) 
                 ammonium sulphite 
                 as per test 
               
               
                 495 
                 (I-8-b-1) 
                 ammonium benzoate 
                 as per test 
               
               
                 496 
                 (I-8-b-1) 
                 ammonium hydrogenoxalate 
                 as per test 
               
               
                 497 
                 (I-8-b-1) 
                 ammonium hydrogencitrate 
                 as per test 
               
               
                 498 
                 (I-8-b-1) 
                 ammonium acetate 
                 as per test 
               
               
                 499 
                 (I-8-b-1) 
                 tetramethylammonium sulphate 
                 as per test 
               
               
                 500 
                 (I-8-b-1) 
                 tetramethylammonium lactate 
                 as per test 
               
               
                 501 
                 (I-8-b-1) 
                 tetramethylammonium nitrate 
                 as per test 
               
               
                 502 
                 (I-8-b-1) 
                 tetramethylammonium thiosulphate 
                 as per test 
               
               
                 503 
                 (I-8-b-1) 
                 tetramethylammonium thiocyanate 
                 as per test 
               
               
                 504 
                 (I-8-b-1) 
                 tetramethylammonium citrate 
                 as per test 
               
               
                 505 
                 (I-8-b-1) 
                 tetramethylammonium oxalate 
                 as per test 
               
               
                 506 
                 (I-8-b-1) 
                 tetramethylammonium formate 
                 as per test 
               
               
                 507 
                 (I-8-b-1) 
                 tetramethylammonium hydrogenphosphate 
                 as per test 
               
               
                 508 
                 (I-8-b-1) 
                 tetramethylammonium 
                 as per test 
               
               
                   
                   
                 dihydrogenphosphate 
               
               
                 509 
                 (I-8-b-1) 
                 tetraethylammonium sulphate 
                 as per test 
               
               
                 510 
                 (I-8-b-1) 
                 tetraethylammonium lactate 
                 as per test 
               
               
                 511 
                 (I-8-b-1) 
                 tetraethylammonium nitrate 
                 as per test 
               
               
                 512 
                 (I-8-b-1) 
                 tetraethylammonium thiosulphate 
                 as per test 
               
               
                 513 
                 (I-8-b-1) 
                 tetraethylammonium thiocyanate 
                 as per test 
               
               
                 514 
                 (I-8-b-1) 
                 tetraethylammonium citrate 
                 as per test 
               
               
                 515 
                 (I-8-b-1) 
                 tetraethylammonium oxalate 
                 as per test 
               
               
                 516 
                 (I-8-b-1) 
                 tetraethylammonium formate 
                 as per test 
               
               
                 517 
                 (I-8-b-1) 
                 tetraethylammonium hydrogenphosphate 
                 as per test 
               
               
                 518 
                 (I-8-b-1) 
                 tetraethylammonium dihydrogenphosphate 
                 as per test 
               
               
                   
               
            
           
         
       
     
     Crop protection materials of the invention may also comprise further components, examples being surfactants and/or dispersing assistants or emulsifiers. 
     Suitable nonionic surfactants and/or dispersing assistants include all substances of this type that can typically be used in agrochemical compositions. Preferably mention may be made of polyethylene oxide-polypropylene oxide block copolymers, polyethylene glycol ethers of linear alcohols, reaction products of fatty acids with ethylene oxide and/or propylene oxide, and also polyvinyl alcohol, polyvinylpyrrolidone, copolymers of polyvinyl alcohol and polyvinylpyrrolidone, and copolymers of (meth)acrylic acid and (meth)acrylic esters, and additionally alkyl ethoxylates and alkylaryl ethoxylates, which optionally may be phosphated and optionally may be neutralized with bases, mention being made, by way of example, of sorbitol ethoxylates, and, as well, polyoxyalkylenamine derivatives. 
     Suitable anionic surfactants include all substances of this type that can typically be used in agrochemical compositions. Preference is given to alkali metal salts and alkaline earth metal salts of alkylsulphonic acids or alkylarylsulphonic acids. 
     A further preferred group of anionic surfactants and/or dispersing assistants are the following salts that are of low solubility in plant oil: salts of polystyrenesulphonic acids, salts of polyvinylsulphonic acids, salts of naphthalenesulphonic acid-formaldehyde condensation products, salts of condensation products of naphthalenesulphonic acid, phenolsulphonic acid and formaldehyde, and salts of ligninsulphonic acid. 
     Suitable additives which may be included in the formulations of the invention are emulsifiers, foam inhibitors, preservatives, antioxidants, colorants and inert filling materials. 
     Preferred emulsifiers are ethoxylated nonylphenols, reaction products of alkylphenols with ethylene oxide and/or propylene oxide, ethoxylated arylalkylphenols, and also ethoxylated and propoxylated arylalkylphenols, and also sulphated or phosphated arylalkyl ethoxylates and/or arylalkyl ethoxy-propoxylates, mention being made by way of example of sorbitan derivatives, such as polyethylene oxide-sorbitan fatty acid esters, and sorbitan fatty acid esters. 
     Compositions of the invention may further comprise, as well as at least one compound of the formula (I), at least one further active herbicidal ingredient, preferably from the group consisting of acetochlor, acifluorfen (-sodium), aclonifen, alachlor, alloxydim (-sodium), ametryne, ami-carbazone, amidochlor, amidosulfuron, aminopyralid, anilofos, asulam, atrazine, azafenidin, azimsulfuron, beflubutamid, benazolin (-ethyl), benfuresate, bensulfuron (-methyl), bentazon, bencarbazone, benzfendizone, benzobicyclon, benzofenap, benzoylprop (-ethyl), bialaphos, bifenox, bispyribac (-sodium), bromobutide, bromofenoxim, bromoxynil, butachlor, butafenacil (-allyl), butroxydim, butylate, cafenstrole, caloxydim, carbetamide, carfentrazone (-ethyl), chlomethoxyfen, chloramben, chloridazon, chlorimuron (-ethyl), chlornitrofen, chlorsulfuron, chlortoluron, cinidon (-ethyl), cinmethylin, cinosulfuron, clefoxydim, clethodim, clodinafop (-propargyl), clomazone, clomeprop, clopyralid, clopyrasulfuron (-methyl), cloransulam (-methyl), cumyluron, cyanazine, cybutryne, cycloate, cyclosulfamuron, cycloxydim, cyhalofop (-butyl), 2,4-D, 2,4-DB, desmedipham, diallate, dicamba, dichlorprop (—P), diclofop (-methyl), diclosulam, diethatyl (-ethyl), difenzoquat, diflufenican, diflufenzopyr, dimefuron, dimepiperate, dimethachlor, dimethametryn, dimethenamid, dimexyflam, dinitramine, diphenamid, diquat, dithiopyr, diuron, dymron, epropodan, EPTC, esprocarb, ethalfluralin, ethametsulfuron (-methyl), ethofumesate, ethoxyfen, ethoxysulfuron, etobenzanid, fenoxaprop (—P-ethyl), fentrazamide, flamprop (-isopropyl, -isopropyl-L, -methyl), flazasulfuron, florasulam, fluazifop (—P-butyl), fluazolate, flucarbazone (-sodium), flufenacet, flumetsulam, flumiclorac (-pentyl), flumioxazin, flumipropyn, flumetsulam, fluometuron, fluorochloridone, fluoroglycofen (-ethyl), flupoxam, flupropacil, flurpyrsulfuron (-methyl, -sodium), flurenol (-butyl), fluridone, fluoroxypyr (-butoxypropyl, -meptyl), flurprimidol, flurtamone, fluthiacet (-methyl), fluthiamide, fomesafen, foramsulfuron, glufosinate (-ammonium), glyphosate (-isopropylammonium), halosafen, haloxyfop (-ethoxyethyl, —P-methyl), hexazinone, HOK-201, imazamethabenz (-methyl), imazamethapyr, imazamox, imazapic, imazapyr, imazaquin, imazethapyr, imazosulfuron, iodosulfuron (-methyl, -sodium), ioxynil, isopropalin, isoproturon, isouron, isoxaben, isoxachlortole, isoxaflutole, isoxapyrifop, lactofen, lenacil, linuron, MCPA, mecoprop, mefenacet, mesosulfurone, mesotrione, metamifop, metamitron, metazachlor, methabenzthiazuron, metobenzuron, metobromuron, (alpha-) metolachlor, metosulam, metoxuron, metribuzin, metsulfuron (-methyl), molinate, monolinuron, naproanilide, napropamide, neburon, nicosulfuron, norflurazon, orbencarb, orthosulfamuron, oryzalin, oxadiargyl, oxadiazon, oxasulfuron, oxaziclomefone, oxyfluorfen, paraquat, pelargonic acid, pendimethalin, pendralin, penoxsulam, pentoxazone, phenmedipham, picolinafen, pinoxaden, piperophos, pretilachlor, primisulfuron (-methyl), profluazol, prometryn, propachlor, propanil, propaquizafop, propisochlor, propoxycarbazone (-sodium), propyzamide, prosulfocarb, prosulfuron, pyraflufen (-ethyl), pyrasulfotole, pyrazogyl, pyrazolate, pyrazosulfuron (-ethyl), pyrazoxyfen, pyribenzoxim, pyributicarb, pyridate, pyridatol, pyriftalid, pyriminobac (-methyl), pyrimisulfan, pyrithiobac (-sodium), pyroxasulfone, quinchlorac, quinmerac, quinoclamine, quizalofop (—P-ethyl, —P-tefuryl), rimsulfuron, sethoxydim, simazine, simetryn, sulcotrione, sulfentrazone, sulfometuron (-methyl), sulfosate, sulfosulfuron, tebutam, tebuthiuron, tembotrione, tepraloxydim, terbuthylazine, terbutryn, thenylchlor, thiafluamide, thiazopyr, thidiazimin, thifensulfuron (-methyl), thiobencarb, tiocarbazil, topramezone, tralkoxydim, triallate, triasulfuron, tribenuron (-methyl), triclopyr, tridiphane, trifluralin, trifloxysulfuron, triflusulfuron (-methyl), tritosulfuron and the following four compounds 
     
       
         
         
             
             
         
       
     
     The examples which follow serve to illustrate the invention and should in no way be interpreted as being restrictive. 
     Glasshouse Trials on Activity Boost Through Ammonium/Phosphonium Salts 
     Seeds of monocot and dicot weeds and crop plants are sown in sandy loam soil in wood fibre pots or in plastic pots, and are covered with soil and cultivated under good growth conditions in the glasshouse and also, during the vegetation period, outdoors outside the glasshouse. 2-3 weeks after sowing, the trial plants are treated at the one- to three-leaf stage. The test compounds, formulated as wettable powders (WP) or liquids (EC), are applied by spraying to the plants and the soil surface in various doses, with a water application rate of 300 l/ha (converted) and with the addition of penetrants (0.2% to 0.4%) and where appropriate an ammonium salt. After the trial plants had stood in the glasshouse for about 3 to 4 weeks under optimum growth conditions, the activity of the products was rated visually in comparison to untreated controls (activity in %, i.e. 0%=no activity or as control, 100%=all plants died). 
     For rapeseed oil methyl ester (RME) the following tables specify concentration in % a.i. by volume for ammonium sulphate (AMS) in g/l in the spray liquor. 
    
    
     EXAMPLE 1 
     The following compounds showed an activity boost with ammonium sulphate in a trial in the stated application rates against  Setaria viridis  (SETVI): 
     
       
         
           
               
               
               
               
               
             
               
                   
                 TABLE 1 
               
               
                   
                   
               
               
                   
                 Active 
                 Application 
                   
                   
               
               
                   
                 ingredient 
                 rate/g/ha 
                 Addition 
                 Activity/% 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
            
               
                   
                 I-1-a-1 
                 50 
                 RME (0.25%) 
                 40 
               
               
                   
                 I-1-a-1 
                 50 
                 RME (0.25%) 
                 50 
               
               
                   
                   
                   
                 AMS (3.3 g/l) 
               
               
                   
                 I-1-a-1 
                 25 
                 RME (0.25%) 
                 30 
               
               
                   
                 I-1-a-1 
                 25 
                 RME (0.25%) 
                 50 
               
               
                   
                   
                   
                 AMS (3.3 g/l) 
               
               
                   
                 I-1-a-2 
                 50 
                 RME (0.25%) 
                 50 
               
               
                   
                 I-1-a-2 
                 50 
                 RME (0.25%) 
                 93 
               
               
                   
                   
                   
                 AMS (3.3 g/l) 
               
               
                   
                 I-1-a-2 
                 25 
                 RME (0.25%) 
                 20 
               
               
                   
                 I-1-a-2 
                 25 
                 RME (0.25%) 
                 90 
               
               
                   
                   
                   
                 AMS (3.3 g/l) 
               
               
                   
                 I-1-a-2 
                 12.5 
                 RME (0.25%) 
                 5 
               
               
                   
                 I-1-a-2 
                 12.5 
                 RME (0.25%) 
                 60 
               
               
                   
                   
                   
                 AMS (3.3 g/l) 
               
               
                   
                 I-1-a-3 
                 100 
                 RME (0.25%) 
                 93 
               
               
                   
                 I-1-a-3 
                 100 
                 RME (0.25%) 
                 99 
               
               
                   
                   
                   
                 AMS (3.3 g/l) 
               
               
                   
                 I-1-a-3 
                 50 
                 RME (0.25%) 
                 93 
               
               
                   
                 I-1-a-3 
                 50 
                 RME (0.25%) 
                 95 
               
               
                   
                   
                   
                 AMS (3.3 g/l) 
               
               
                   
                 I-1-a-3 
                 25 
                 RME (0.25%) 
                 15 
               
               
                   
                 I-1-a-3 
                 25 
                 RME (0.25%) 
                 70 
               
               
                   
                   
                   
                 AMS (3.3 g/l) 
               
               
                   
                 I-4-a-1 
                 100 
                 RME (0.25%) 
                 0 
               
               
                   
                 I-4-a-1 
                 100 
                 RME (0.25%) 
                 90 
               
               
                   
                   
                   
                 AMS (3.3 g/l) 
               
               
                   
                 I-4-a-1 
                 50 
                 RME (0.25%) 
                 0 
               
               
                   
                 I-4-a-1 
                 50 
                 RME (0.25%) 
                 90 
               
               
                   
                   
                   
                 AMS (3.3 g/l) 
               
               
                   
                 I-4-a-1 
                 25 
                 RME (0.25%) 
                 0 
               
               
                   
                 I-4-a-1 
                 25 
                 RME (0.25%) 
                 20 
               
               
                   
                   
                   
                 AMS (3.3 g/l) 
               
               
                   
                 I-6-a-1 
                 50 
                 RME (0.25%) 
                 25 
               
               
                   
                 I-6-a-1 
                 50 
                 RME (0.25%) 
                 90 
               
               
                   
                   
                   
                 AMS (3.3 g/l) 
               
               
                   
                 I-6-a-1 
                 25 
                 RME (0.25%) 
                 15 
               
               
                   
                 I-6-a-1 
                 25 
                 RME (0.25%) 
                 90 
               
               
                   
                   
                   
                 AMS (3.3 g/l) 
               
               
                   
                 I-6-a-1 
                 12.5 
                 RME (0.25%) 
                 0 
               
               
                   
                 I-6-a-1 
                 12.5 
                 RME (0.25%) 
                 25 
               
               
                   
                   
                   
                 AMS (3.3 g/l) 
               
               
                   
                   
               
            
           
         
       
     
     EXAMPLE 2 
     The following compounds exhibited an activity boost in a trial with ammonium sulphate (AMS) against 
     ALOMY= Alopecurus myosuroides  
 
AVEFA= Avena fatua  
 
LOLMU= Lolium multiflorum  
 
LOLRI= Lolium rigidum 
 
     
       
         
           
               
               
               
               
               
             
               
                 TABLE 2 
               
               
                   
               
               
                 Active 
                 Application 
                   
                 Activity 
                   
               
               
                 ingredient 
                 rate/g/ha 
                 Addition 
                 against 
                 Activity/% 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
            
               
                 I-8-a-1 
                 25 
                 RME (0.25%) 
                 ALOMY 
                 50 
               
               
                 I-8-a-1 
                 25 
                 RME (0.25%) 
                 ALOMY 
                 70 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-8-a-1 
                 12.5 
                 RME (0.25%) 
                 ALOMY 
                 5 
               
               
                 I-8-a-1 
                 12.5 
                 RME (0.25%) 
                 ALOMY 
                 50 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-8-a-1 
                 25 
                 RME (0.25%) 
                 AVEFA 
                 40 
               
               
                 I-8-a-1 
                 25 
                 RME (0.25%) 
                 AVEFA 
                 80 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-8-a-1 
                 12.5 
                 RME (0.25%) 
                 AVEFA 
                 30 
               
               
                 I-8-a-1 
                 12.5 
                 RME (0.25%) 
                 AVEFA 
                 70 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-8-a-1 
                 25 
                 RME (0.25%) 
                 LOLMU 
                 80 
               
               
                 I-8-a-1 
                 25 
                 RME (0.25%) 
                 LOLMU 
                 95 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-8-a-1 
                 12.5 
                 RME (0.25%) 
                 LOLMU 
                 10 
               
               
                 I-8-a-1 
                 12.5 
                 RME (0.25%) 
                 LOLMU 
                 70 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-1-a-4 
                 50 
                 RME (0.25%) 
                 ALOMY 
                 5 
               
               
                 I-1-a-4 
                 50 
                 RME (0.25%) 
                 ALOMY 
                 70 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-1-a-4 
                 25 
                 RME (0.25%) 
                 ALOMY 
                 3 
               
               
                 I-1-a-4 
                 25 
                 RME (0.25%) 
                 ALOMY 
                 50 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-1-a-4 
                 50 
                 RME (0.25%) 
                 AVEFA 
                 5 
               
               
                 I-1-a-4 
                 50 
                 RME (0.25%) 
                 AVEFA 
                 30 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-1-a-4 
                 25 
                 RME (0.25%) 
                 AVEFA 
                 3 
               
               
                 I-1-a-4 
                 25 
                 RME (0.25%) 
                 AVEFA 
                 10 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-1-a-4 
                 50 
                 RME (0.25%) 
                 LOLMU 
                 5 
               
               
                 I-1-a-4 
                 50 
                 RME (0.25%) 
                 LOLMU 
                 90 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-1-a-4 
                 25 
                 RME (0.25%) 
                 LOLMU 
                 2 
               
               
                 I-1-a-4 
                 25 
                 RME (0.25%) 
                 LOLMU 
                 75 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-1-b-1 
                 50 
                 RME (0.25%) 
                 ALOMY 
                 20 
               
               
                 I-1-b-1 
                 50 
                 RME (0.25%) 
                 ALOMY 
                 75 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-1-b-1 
                 25 
                 RME (0.25%) 
                 ALOMY 
                 5 
               
               
                 I-1-b-1 
                 25 
                 RME (0.25%) 
                 ALOMY 
                 25 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-1-b-1 
                 50 
                 RME (0.25%) 
                 AVEFA 
                 50 
               
               
                 I-1-b-1 
                 50 
                 RME (0.25%) 
                 AVEFA 
                 60 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-1-b-1 
                 25 
                 RME (0.25%) 
                 AVEFA 
                 15 
               
               
                 I-1-b-1 
                 25 
                 RME (0.25%) 
                 AVEFA 
                 60 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-1-b-1 
                 50 
                 RME (0.25%) 
                 LOLMU 
                 10 
               
               
                 I-1-b-1 
                 50 
                 RME (0.25%) 
                 LOLMU 
                 75 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-1-b-1 
                 25 
                 RME (0.25%) 
                 LOLMU 
                 10 
               
               
                 I-1-b-1 
                 25 
                 RME (0.25%) 
                 LOLMU 
                 25 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-6-a-2 
                 25 
                 RME (0.25%) 
                 ALOMY 
                 30 
               
               
                 I-6-a-2 
                 25 
                 RME (0.25%) 
                 ALOMY 
                 93 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-6-a-2 
                 12.5 
                 RME (0.25%) 
                 ALOMY 
                 10 
               
               
                 I-6-a-2 
                 12.5 
                 RME (0.25%) 
                 ALOMY 
                 75 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-6-a-2 
                 25 
                 RME (0.25%) 
                 AVEFA 
                 35 
               
               
                 I-6-a-2 
                 25 
                 RME (0.25%) 
                 AVEFA 
                 99 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-6-a-2 
                 12.5 
                 RME (0.25%) 
                 AVEFA 
                 10 
               
               
                 I-6-a-2 
                 12.5 
                 RME (0.25%) 
                 AVEFA 
                 93 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-6-a-2 
                 25 
                 RME (0.25%) 
                 LOLMU 
                 20 
               
               
                 I-6-a-2 
                 25 
                 RME (0.25%) 
                 LOLMU 
                 100 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-6-a-2 
                 12.5 
                 RME (0.25%) 
                 LOLMU 
                 5 
               
               
                 I-6-a-2 
                 12.5 
                 RME (0.25%) 
                 LOLMU 
                 97 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-8-b-1 
                 50 
                 RME (0.25%) 
                 ALOMY 
                 90 
               
               
                 I-8-b-1 
                 50 
                 RME (0.25%) 
                 ALOMY 
                 95 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-8-b-1 
                 25 
                 RME (0.25%) 
                 ALOMY 
                 20 
               
               
                 I-8-b-1 
                 25 
                 RME (0.25%) 
                 ALOMY 
                 80 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-8-b-1 
                 50 
                 RME (0.25%) 
                 AVEFA 
                 70 
               
               
                 I-8-b-1 
                 50 
                 RME (0.25%) 
                 AVEFA 
                 97 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-8-b-1 
                 25 
                 RME (0.25%) 
                 AVEFA 
                 30 
               
               
                 I-8-b-1 
                 25 
                 RME (0.25%) 
                 AVEFA 
                 80 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-8-b-1 
                 50 
                 RME (0.25%) 
                 LOLMU 
                 97 
               
               
                 I-8-b-1 
                 50 
                 RME (0.25%) 
                 LOLMU 
                 100 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-8-b-1 
                 25 
                 RME (0.25%) 
                 LOLMU 
                 60 
               
               
                 I-8-b-1 
                 25 
                 RME (0.25%) 
                 LOLMU 
                 93 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-2-a-1 
                 100 
                 RME (0.25%) 
                 ALOMY 
                 30 
               
               
                 I-2-a-1 
                 100 
                 RME (0.25%) 
                 ALOMY 
                 70 
               
               
                   
                   
                 AMS (6.6 g/l) 
               
               
                 I-2-a-1 
                 50 
                 RME (0.25%) 
                 ALOMY 
                 30 
               
               
                 I-2-a-1 
                 50 
                 RME (0.25%) 
                 ALOMY 
                 70 
               
               
                   
                   
                 AMS (6.6 g/l) 
               
               
                 I-2-a-1 
                 50 
                 RME (0.25%) 
                 LOLMU 
                 70 
               
               
                 I-2-a-1 
                 50 
                 RME (0.25%) 
                 LOLMU 
                 98 
               
               
                   
                   
                 AMS (6.6 g/l) 
               
               
                 I-2-a-1 
                 25 
                 RME (0.25%) 
                 LOLMU 
                 30 
               
               
                 I-2-a-1 
                 50 
                 RME (0.25%) 
                 LOLMU 
                 80 
               
               
                   
                   
                 AMS (6.6 g/l) 
               
               
                 I-2-a-1 
                 50 
                 RME (0.25%) 
                 LOLRI 
                 40 
               
               
                 I-2-a-1 
                 50 
                 RME (0.25%) 
                 LOLRI 
                 80 
               
               
                   
                   
                 AMS (6.6 g/l) 
               
               
                 I-2-a-1 
                 25 
                 RME (0.25%) 
                 LOLRI 
                 20 
               
               
                 I-2-a-1 
                 50 
                 RME (0.25%) 
                 LOLRI 
                 40 
               
               
                   
                   
                 AMS (6.6 g/l) 
               
               
                   
               
            
           
         
       
     
     EXAMPLE 3 
     The following compounds showed activity boosts in a trial with graduated concentrations of ammonium sulphate: 
     ALOMY= Alopecurus myosuroides  
 
AVEFA= Avena fatua  
 
LOLMU= Lolium multiflorum  
 
SETVI= Setaria viridis 
 
     
       
         
           
               
               
               
               
               
             
               
                 TABLE 3 
               
               
                   
               
               
                 Active 
                 Application 
                   
                 Activity 
                   
               
               
                 ingredient 
                 rate/g/ha 
                 Addition 
                 against 
                 Activity/% 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
            
               
                 I-8-b-1 
                 50 
                 RME (0.25%) 
                 AVEFA 
                 70 
               
               
                 I-8-b-1 
                 50 
                 RME (0.25%) 
                 AVEFA 
                 90 
               
               
                   
                   
                 AMS (0.33 g/l) 
               
               
                 I-8-b-1 
                 50 
                 RME (0.25%) 
                 AVEFA 
                 95 
               
               
                   
                   
                 AMS (1 g/l) 
               
               
                 I-8-b-1 
                 50 
                 RME (0.25%) 
                 AVEFA 
                 97 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-8-b-1 
                 25 
                 RME (0.25%) 
                 ALOMY 
                 20 
               
               
                 I-8-b-1 
                 25 
                 RME (0.25%) 
                 ALOMY 
                 70 
               
               
                   
                   
                 AMS (0.33 g/l) 
               
               
                 I-8-b-1 
                 25 
                 RME (0.25%) 
                 ALOMY 
                 50 
               
               
                   
                   
                 AMS (1 g/l) 
               
               
                 I-8-b-1 
                 25 
                 RME (0.25%) 
                 ALOMY 
                 80 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-1-a-5 
                 50 
                 RME (0.25%) 
                 LOLMU 
                 5 
               
               
                 I-1-a-5 
                 50 
                 RME (0.25%) 
                 LOLMU 
                 60 
               
               
                   
                   
                 AMS (0.33 g/l) 
               
               
                 I-1-a-5 
                 50 
                 RME (0.25%) 
                 LOLMU 
                 93 
               
               
                   
                   
                 AMS (1 g/l) 
               
               
                 I-1-a-5 
                 50 
                 RME (0.25%) 
                 LOLMU 
                 95 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-1-a-5 
                 25 
                 RME (0.25%) 
                 ALOMY 
                 25 
               
               
                 I-1-a-5 
                 25 
                 RME (0.25%) 
                 ALOMY 
                 50 
               
               
                   
                   
                 AMS (0.33 g/l) 
               
               
                 I-1-a-5 
                 25 
                 RME (0.25%) 
                 ALOMY 
                 50 
               
               
                   
                   
                 AMS (1 g/l) 
               
               
                 I-1-a-5 
                 25 
                 RME (0.25%) 
                 ALOMY 
                 60 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-1-a-6 
                 12.5 
                 RME (0.25%) 
                 SETVI 
                 50 
               
               
                 I-1-a-6 
                 12.5 
                 RME (0.25%) 
                 SETVI 
                 65 
               
               
                   
                   
                 AMS (0.33 g/l) 
               
               
                 I-1-a-6 
                 12.5 
                 RME (0.25%) 
                 SETVI 
                 75 
               
               
                   
                   
                 AMS (1 g/l) 
               
               
                 I-1-a-6 
                 12.5 
                 RME (0.25%) 
                 SETVI 
                 90 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-1-a-6 
                 50 
                 RME (0.25%) 
                 LOLMU 
                 5 
               
               
                 I-1-a-6 
                 50 
                 RME (0.25%) 
                 LOLMU 
                 20 
               
               
                   
                   
                 AMS (0.33 g/l) 
               
               
                 I-1-a-6 
                 50 
                 RME (0.25%) 
                 LOLMU 
                 50 
               
               
                   
                   
                 AMS (1 g/l) 
               
               
                 I-1-a-6 
                 50 
                 RME (0.25%) 
                 LOLMU 
                 65 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                   
               
            
           
         
       
     
     EXAMPLE 4 
     The compound (I-1-c-1) showed an activity boost in a trial with ammonium sulphate against 
     ALOMY= Alopecurus myosuroides  
 
AVEFA= Avena fatua  
 
LOLMU= Lolium multiflorum  
 
SETVI= Setaria viridis  
 
BROER= Bromus erectus 
 
     
       
         
           
               
               
               
               
               
             
               
                 TABLE 4 
               
               
                   
               
               
                 Active 
                 Application 
                   
                 Activity 
                   
               
               
                 ingredient 
                 rate/g/ha 
                 Addition 
                 against 
                 Activity/% 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
            
               
                 I-1-c-1 
                 5 
                 Genapol LRO 
                 ALOMY 
                 73 
               
               
                   
                   
                 (0.33%) 
               
               
                 I-1-c-1 
                 5 
                 Genapol LRO 
                 ALOMY 
                 99 
               
               
                   
                   
                 (0.33%) 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-1-c-1 
                 5 
                 Genapol LRO 
                 APESV 
                 93 
               
               
                   
                   
                 (0.33%) 
               
               
                 I-1-c-1 
                 5 
                 Genapol LRO 
                 APESV 
                 97 
               
               
                   
                   
                 (0.33%) 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-1-c-1 
                 5 
                 Genapol LRO 
                 AVEFA 
                 75 
               
               
                   
                   
                 (0.33%) 
               
               
                 I-1-c-1 
                 5 
                 Genapol LRO 
                 AVEFA 
                 100 
               
               
                   
                   
                 (0.33%) 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-1-c-1 
                 5 
                 Genapol LRO 
                 BROER 
                 73 
               
               
                   
                   
                 (0.33%) 
               
               
                 I-1-c-1 
                 5 
                 Genapol LRO 
                 BROER 
                 97 
               
               
                   
                   
                 (0.33%) 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                 I-1-c-1 
                 5 
                 Genapol LRO 
                 LOLME 
                 86 
               
               
                   
                   
                 (0.33%) 
               
               
                 I-1-c-1 
                 5 
                 Genapol LRO 
                 LOLME 
                 97 
               
               
                   
                   
                 (0.33%) 
               
               
                   
                   
                 AMS (3.3 g/l) 
               
               
                   
               
            
           
         
       
     
     EXAMPLE 5 
     In plots measuring approximately 10 m 2 , in 9 trials, post-emergence treatments were carried out in 2-3 repetitions with compound (I-1-c-1). The weed population was the natural population and/or a sown population specifically geared to the objective. The active ingredient (I-1-c-1) was delivered as an EC formulation at the stated application rates with a penetrant of the formula (III-c-1) at a concentration of 0.3 g/l in 300 l of water, as a tank mix. In the elements of the trial with ammonium sulphate (AMS) the salt was added at 1 g/l to the spray liquor. Evaluation was made on the day of maximum activity. The activities reported in Table 5 are those obtained over the sum of all the trials. 
     AGRRE= Agropyron repens  
 
ALOMY= Alopecurus myosuroides  
 
AVEFA= Avena fatua 
 
     
       
         
           
               
               
               
               
               
             
               
                 TABLE 5 
               
               
                   
               
               
                 Active 
                 Application 
                   
                 Activity 
                   
               
               
                 ingredient 
                 rate/g/ha 
                 Addition 
                 against 
                 Activity/% 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
            
               
                 I-1-c-1 
                 5 
                 (III-c-1) (0.3 g/l) 
                 AGRRE 
                 80 
               
               
                 I-1-c-1 
                 5 
                 (III-c-1) (0.3 g/l) 
                 AGRRE 
                 90 
               
               
                   
                   
                 AMS (1 g/l) 
               
               
                 I-1-c-1 
                 5 
                 (III-c-1) (0.3 g/l) 
                 ALOMY 
                 67 
               
               
                 I-1-c-1 
                 5 
                 (III-c-1) (0.3 g/l) 
                 ALOMY 
                 72 
               
               
                   
                   
                 AMS (1 g/l) 
               
               
                 I-1-c-1 
                 5 
                 (III-c-1) (0.3 g/l) 
                 AVEFA 
                 80 
               
               
                 I-1-c-1 
                 5 
                 (III-c-1) (0.3 g/l) 
                 AVEFA 
                 90 
               
               
                   
                   
                 AMS (1 g/l)