Patent Publication Number: US-4581422-A

Title: Epoxy resin composition containing a curing agent which is a reaction product of cyanoguanidine, formaldehyde and an amine

Description:
BACKGROUND OF THE INVENTION 
     1. Field of the Invention 
     This invention relates to curable epoxy resins, and more particularly to epoxy resins cured with a reaction product of cyanoguanidine, amine and formaldehyde. 
     2. Related Publications 
     Cyanoguanidine is a widely used epoxy curing agent. However, it is a solid material and, therefore, difficult to use conveniently when curing liquid epoxy systems. Polyoxyalkylene amines and polyoxyalkylene polyamines are also known as epxoy curing agents. The use of cyanoguanidine (dicyandiamide) is disclosed in a technical report from American Hoechst Corporation entitled, &#34;Dycyandiamide&#34;. 
     Polyoxyalkylene amines have been disclosed in many patents and publications as curing agents for epoxy resins. For example, U.S. Pat. Nos. 4,115,360; 4,141,885; 4,115,361; 4,146,700 and 4,169,177. 
     In the present invention it has been discovered that a reaction product of cyanoguanidine, formaldehyde and an amine, especially a polyoxyalkylene amine, provide, in most cases, a fluid, viscous liquid which is easily dispersed uniformly into epoxy resins thereby providing a new and useful epoxy resin curing agent and permits the use of cyanoguanidine in a much more usable form. 
     SUMMARY OF THE INVENTION 
     The invention is an epoxy resin composition comprising a vicinal polyepoxide having an epoxide equivalency of greater than about 1.8 and a curing amount of the reaction product of cyanoguanidine, formaldehyde and a primary or secondary amine, especially a polyoxyalkylene amine. 
     DESCRIPTION OF THE PREFERRED EMBODIMENTS 
     According to the instant inventive concept, a new epoxy resin curing composition is provided which is the reaction product of cyanoguanidine, formaldehyde and a primary or secondary amine. This reaction product is mixed in a curing amount with a vicinal polyepoxide having an epoxide equivalency of greater than about 1.8 to provide a cured epoxy material. 
     The epoxy resin curing agent is prepared from a reaction product of cyanoguanidine, formaldehyde and amines of the following description. 
     The amine terminated polyethers (polyoxyalkylene amines) useful in this invention are polyethers of about 350 molecular weight or more made from an appropriate initiator to which lower alkylene oxides such as ethylene oxide, propylene oxide, butylene oxide or mixtures thereof are added with the resulting hydroxyl terminated polyol then being aminated. When two or more oxides are used, they may be present as random mixtures or as blocks of one or the other polyether. 
     In the amination step it is highly desirable that the terminal hydroxyl groups in the polyol be essentially all secondary hydroxyl groups for ease of amination. Normally, the amination step does not completely replace all of the hydroxyl groups. However, the majority of hydroxyl groups are replaced by amine groups. Therefore, the amine terminated polyether resins useful in this invention have greater than 50% of their active hydrogens in the form of amine hydrogens. If ethylene oxide is used it is desirable to cap the hydroxyl terminated polyol with a small amount of higher alkylene oxide to ensure that the terminal hydroxyl groups are essentially all secondary hydroxyl groups. The polyols so prepared are then reductively aminated as outlined, for example, in U.S. Pat. No. 3,654,370 and other prior art techniques. 
     Polyoxyalkylene polyamines having the structure ##STR1## wherein Y is hydrogen, a methyl radical or an ethyl radical, Z is a hydrocarbon radical of 2-5 carbon atoms, n is a number sufficient to impart a molecular weight of about 350-2000 to the molecule and r is a number 2 or greater are useful. 
     Other useful amines include the JEFFAMINE® M-series which are mono functional amines represented by the general structure ##STR2## where R and R&#39; are alkyl groups and n is a number of 1 or more. 
     Examples of useful amines of this type are as follows: 
     JEFFAMINE M-1000--CH 3  O(C 2  H 4  O) 18 .6 [CH 2  CH(CH 3 )O] 1 .6 CH 2  CH(CH 3 )NH 2   
     JEFFAMINE M-600--CH 3  OC 2  H 4  [CH 2  CH(CH 3 )O] 8  CH 2  CH(CH 3 )NH 2   
     JEFFAMINE M-360--CH 3  OC 4  H 9  (OCH 2  CH 2 ) 4  OCH 2  CH(CH 3 )OCH 2  CH(CH 3 )NH 2   
     Another example of a suitable amine to be used in accordance with the present invention is a polyoxyethylenediamine such as one having the formula ##STR3## 
     Examples of suitable polyoxyethylenediamines having this formula are as follows: 
     
         ______________________________________                                    
                 Approximate Value                                        
                 b      a + c                                             
______________________________________                                    
JEFFAMINE ED-600   13.5     3.5                                           
JEFFAMINE ED-900   20.5     3.5                                           
JEFFAMINE ED-2001  45.5     3.5                                           
______________________________________                                    
 
    
     We believe the reaction to prepare the curing agents of this invention proceeds as follows: ##STR4## The reaction is preferably carried out at about 90° C. for about four hours. Thereafter the water of condensation and the water in any reactants is removed at about 90°-120° C. and pressures of about 10-50 mm. The preferred ratios are 1:1:1 for the reactants; however, an excess of the amine or cyanoguanidine may generally be used. With selected amines less than one mole may also be useful as the following examples will show. 
     The exact useful ratios for particular reactants are easily determined by one skilled in the art using the teachings herein. A satisfactory ratio should provide a product viscosity suitable for various applications such as molding, casting, encapsulating or spraying or brushing to form a coating. 
     Generally, the amine cured vicinal polyepoxide containing compositions are organic materials having an average of at least 1.8 reactive 1,2-epoxy groups per molecule. These polyepoxide materials can be monomeric or polymeric, saturated or unsaturated, aliphatic, cycloaliphatic, aromatic or heterocyclic, and may be substituted if desired with other substituents besides the epoxy groups; e.g., hydroxyl groups, ether radicals, aromatic halogen atoms and the like. 
     Preferred polyepoxides are those of glycidyl ethers prepared by epoxidizing the corresponding allyl ethers or reacting, by known procedures, a molar excess of epichlorohydrin and an aromatic polyhydroxy compound; i.e., isopropylidene bisphenol, novolak, resorcinol, etc. The epoxy derivatives of methylene or isopropylidene bisphenols are especially preferred. 
     A widely used class of polyepoxides which are useful according to the instant invention includes the resinous epoxy polyethers obtained by reacting an epihalohydrin, such as epichlorohydrin, and the like, with either a polyhydric phenol or a polyhydric alcohol. An illustration, but by no means exhaustive, lising of suitable dihydric phenols includes 4,4&#39;-isopropylidene bisphenol, 2,4&#39;-dihydroxydiphenylethylmethane, 3,3&#39;-dihydroxydiphenyldiethylmethane, 3,4&#39;dihydroxydiphenylmethylpropylmethane, 2,3&#39;-dihydroxydiphenylethylphenylmethane, 4,4&#39;-dihydroxydiphenylpropylphenylmethane, 4,4&#39;-dihydroxydiphenylbutylphenylmethane, 2,2&#39;-dihydroxydiphenylditolylmethane, 4,4&#39;-dihydroxydiphenyltolylmethylmethane and the like. Other polyhydric phenols which may also be co-reacted with an epihalohydrin to provide these epoxy polyethers are such compounds as resorcinol, hydroquinone, substituted hydroquinones; e.g., methylhydroquinone, and the like. 
     Among the polyhydric alcohols which can be co-reacted with an epihalohydrin to provide these resinous epoxy polyethers are such compounds as ethylene glycol, propylene glycols, butylene glycols, pentane diols, bis(4-hydroxycyclohexyl)dimethylmethane, 1,4-dimethylolbenzene, glycerol, 1,2,6-hexanetriol, trimethylolpropane, manniatol, sorbitol, erythritol, pentaerythritol, their dimers, trimers and higher polymers; e.g., polyethylene glycols, polypropylene glycols, triglycerol, dipentaerythritol and the like, polyallyl alcohol, polyhydric thioethers, such as 2,2&#39;-, 3,3&#39;-tetrahydroxydipropylsulfide and the like, mercapto alcohols such as monothioglycerol, dithioglycerol, and the like, polyhydric alcohol partial esters, such as monostearin, pentaerythritol monoacetate, and the like, and halogenated polyhydric alcohols such as the monochlorohydrins of glycerol, sorbitol, pentaerythritol and the like. 
     Another class of polymeric polyepoxides which can be amine cured and are in accordance with the instant invention includes the epoxy novolak resins obtained by reacting, preferably in the presence of a basic catalyst; e.g., sodium or potassium hydroxide, an epihalohydrin, such as epichlorohydrin, with the resinous condensate of an aldehyde; e.g., formaldehyde, and either a monohydric phenol; e.g., phenol itself, or a polyhydric phenol. Further details concerning the nature and preparation of these epoxy novolak resins can be obtained in Lee, H. and Neville, K., Handbook of Epoxy Resins, McGraw-Hill Book Co., New York, 1967. 
     Other polyepoxides known to those skilled in the art may be useful in this invention. 
     Optionally, the epoxy resin formulations of the instant invention can include an &#34;accelerator&#34; to speed the amine cure of the epoxy resin, especially at ambient temperatures. In several applications, such acceleration is beneficial, especially when an epoxy resin is used as an adhesive in flammable environment, thus making elevated temperature cure inconvenient or even hazardous. Lee, H. and Neville, K., Handbook of Epoxy Resins, pp. 7-14 describes the use of certain amine-containing compounds as epoxy curing agent-accelerators. 
     Many accelerators are known in the art which can be utilized in accordance with the instant invention. Examples include salts of phenols, salicyclic acids, amine salts of fatty acids, such as those disclosed in U.S. Pat. No. 2,681,901, and tertiary amines such as those disclosed in U.S. Pat. NO. 2,839,480. Preferred accelerators in accordance with the instant invention are disclosed in U.S. Pat. Nos. 3,875,072 and 4,195,153. 
     It will further be realized that various conveniently employed additives can be admixed with the polyepoxide containing composition of the instant invention prior to final cure. For example, in certain instances it may be desired to add minor amounts of other polyalkyleneamine co-catalysts as herein described, or hardeners along with various other accelerators and curing agent systems well known in the art. 
     Additionally, conventional pigments, dyes, fillers, flame retarding agents and the like which are compatible; natural or synthetic resins can be added. Furthermore, although not preferred, known solvents for polyepoxide materials such as toluene, benzene, xylene, dioxane, ethylene glycol monomethyl ether and the like can be used. The compositions of the instant invention can be used as impregnants, surface coatings, encapsulating compositions, laminants and, particularly and most importantly, as adhesives for bonding metallic elements or structures permanently together. 
     The following examples illustrate the nature of the instant invention but are not intended to be limitative thereof. 
    
    
     EXAMPLE 1 
     
         __________________________________________________________________________
Glass Transition Temperatures (Tg, °C.) of Epoxy Resins            
Cured With Amine, Cyanoguanidine and Formaldehyde Condensates             
                          Mole Ratio                                      
                                Optimum                                   
                                     Concentration.sup.1                  
No.                                                                       
   Condensate Composition Condensate                                      
                                Tg, °C.                            
                                     phr                                  
__________________________________________________________________________
1  JEFFAMINE ® D-400.Cyanoguanidine.CH.sub.2 O                        
                          1:1:1 94.9 25                                   
2  JEFFAMINE T-403.Cyanoguanidine.CH.sub.2 O                              
                          0.7:1:1                                         
                                94.2 25                                   
3  JEFFAMINE D-400.Cyanoguanidine.CH.sub.2 O                              
                          1:2:2 102.4                                     
                                     18                                   
4  JEFFAMINE D-230.Cyanoguanidine.CH.sub.2 O                              
                          1:1:1 112.1                                     
                                     16                                   
5  JEFFAMINE M-360.Cyanoguanidine.CH.sub.2 O                              
                          1:1:1 80.4 24                                   
6  JEFFAMINE M-360.Cyanoguanidine.CH.sub.2 O                              
                          0.67:1:1                                        
                                89.2 22                                   
7  JEFFAMINE ED-600.Cyanoguanidine.CH.sub.2 O                             
                          1:2:2 96.4 24                                   
.sup. 8.sup.2                                                             
   Dipropylenetriamine.sup.3.Cyanoguanidine.CH.sub.2 O                    
                          1:1:1 132.9                                     
                                     16                                   
__________________________________________________________________________
 .sup.1 Concentration in parts per hundred of liquid epoxy resin of       
 equivalent weight ˜185.                                            
 .sup.2 Comparative example. Not suitable.                                
 ##STR5##                                                                 
 
    
     EXAMPLE 2 
     
         ______________________________________                                    
Storage Stability of Amine, Cyanoguanidine                                
and Formaldehyde Condensates After Combination                            
With a Liquid Epoxy Resin                                                 
Formulation                                                               
         A      B      C    D    E    F-   G    H                         
______________________________________                                    
EPON ® 828                                                            
         100    100    100  100  100  100  100  100                       
Conden-   25    --     --   --   --   --   --   --                        
sate 1.sup.1                                                              
Condensate 2                                                              
         --      25    --   --   --   --   --   --                        
Condensate 3                                                              
         --     --      18  --   --   --   --   --                        
Condensate 4                                                              
         --     --     --    16  --   --   --   --                        
Condensate 5                                                              
         --     --     --   --    24  --   --   --                        
Condensate 6                                                              
         --     --     --   --   --    22  --   --                        
Condensate 7                                                              
         --     --     --   --   --   --    24  --                        
Condensate 8                                                              
         --     --     --   --   --   --   --    16                       
Storage Sta-                                                              
bility, days                                                              
to solidify                                                               
@ 25° C.                                                           
          8     &lt;1     .sup.4                                             
                            .sup.4                                        
                                 &gt;14  &lt;14  14.sup.5                       
                                                .sup.4                    
@ 40° C.                                                           
          4     &lt;1     .sup.4                                             
                            .sup.4                                        
                                  10   9   6.sup.2,3                      
                                                .sup.4                    
______________________________________                                    
 .sup.1 From Example 1.                                                   
 .sup.2 Liquid after 48 hours but gel particles formed throughout.        
 .sup.3 Near gel after 5 days; phase separation of gelliquid.             
 .sup.4 Non-homogeneous after mixing; gellike particles in liquid.        
 .sup.5 Near gel; nonhomogeneous.                                         
 
    
     EXAMPLE 3 
     This experiment will describe the technique used to make the runs described in Table I. To a 500 ml three-necked flask equipped with a stirrer, thermometer and Dean-Stark trap was added 43 g (0.5 moles) of cyanoguanidine and 200 g of JEFFAMINE D-400 amine (0.5 moles). With stirring and under nitrogen, the mixture was heated to 50° C. The mixture has a turbid appearance and was cooled to 25° C. Then 40.5 g of formalin (37% formaldehyde; 0.5 moles) was added over a 15-minute period. The reactants were heated to 90° C. and held at 90°-110° C. for three hours. About 8 ml of water was collected. Finally, the product was heated for two hours at 90° C. and 20 mm pressure. The product was a viscous almost colorless liquid. 
     
                                           TABLE I                                 
__________________________________________________________________________
Reactions of Cyanoguanidine, Formalin and Amines                          
Cyanoguanidine                                                            
           37% Formalin                                                   
                   JEFFAMINE ® Product                                
No.                                                                       
   Grams                                                                  
       Moles                                                              
           Grams                                                          
               Moles                                                      
                   or Amine Grams/Moles                                   
                                   Weight, g                              
__________________________________________________________________________
1  43  0.5 40.5                                                           
               0.5 D-400    200                                           
                               0.5 248                                    
2  8.4 0.1 8.1 0.1 ED-900   90 0.1 99.0                                   
3  8.4 0.1 8.1 0.1 T-5000   680                                           
                               0.272                                      
                                   681.5                                  
4  42  0.5 42  0.5 T-403    139.5                                         
                               0.35                                       
                                   325                                    
5  16.8                                                                   
       0.2 16.8                                                           
               0.2 DPTA     25.4                                          
                               0.2 42.2                                   
6  8.4 0.1 8.1 0.1 D-2000   200                                           
                               0.1 208.3                                  
7  33.6                                                                   
       0.4 32.4                                                           
               0.4 D-400    80 0.2 117.5                                  
8  16.8                                                                   
       0.2 16.2                                                           
               0.2 D-2000   400                                           
                               0.2 457.6                                  
9  33.6                                                                   
       0.4 32.4                                                           
               0.4 D-230    72 0.4 126.8                                  
10 42  0.5 41  0.5 D-230    57.5                                          
                               0.25                                       
                                   104.2                                  
11 43  0.5 41  0.5 M-360    180                                           
                               0.5 227.0                                  
12 42  0.5 41  0.5 M-360    120                                           
                               0.33                                       
                                   167.6                                  
13 42  0.5 41  0.5 ED-600   150                                           
                               0.25                                       
                                   197.7                                  
14 102 1.2 97.2                                                           
               1.2 D-400    240                                           
                               0.6 355.4                                  
15 33.6                                                                   
       0.4 32.4                                                           
               0.4 D-230    72 0.4 107.5                                  
16 42  0.5 41  0.5 N--butyl 37 0.5 --                                     
                   amine                                                  
17 84  1.0 81  1.0 Methoxy- 89 1.0 163                                    
                   propylamine                                            
__________________________________________________________________________
 Product Appearance                                                       
 .sup.1 Viscous, almost colorless liquid                                  
 .sup.2 Nice fluid, light yellow liquid                                   
 .sup.3 Homogeneous white dispersion                                      
 .sup.4 Viscous, light colored material                                   
 .sup.5 Reddish orange color, nonpourable                                 
 .sup.6 Creamy-turbid                                                     
 .sup.7 Very viscous yellow liquid                                        
 .sup.8 Cream colored, slightly viscous                                   
 .sup.9 Gold colored clear liquid                                         
 .sup.10 Amber colored, slightly turbid solid                             
 .sup.11 Clear amber liquid at room temp.                                 
 .sup.12 Light yellow, slightly turbid and                                
 .sup.13 Light yellow with slight haze to product. Water soluble, slightly
 pourable at room temperature                                             
 .sup.14 Light yellow slightly turbid solid at room temperature           
 .sup.15 Light yellow, slightly hazy solid at room temperature            
 .sup.16 Solid gel, light yellow and taffylike when warm                  
 .sup.17 White, brittle solid                                             
 
    
     EXAMPLE 4 
     According to the general procedure of Example 3, the following epoxy resins were mixed with curatives and a casting was made where possible. 
     
         ______________________________________                                    
                 A     B       C      D                                   
______________________________________                                    
Formulation                                                               
Liquid epoxy resin (EEW˜185)                                        
                   100     100     100  100                               
JEFFAMINE          25      --      --   --                                
D-400.DICY.CH.sub.2 O Cond.                                               
(0.5.0.5.0.5 molar)                                                       
JEFFAMINE          --      25      --   --                                
T-403.DICY.CH.sub.2 O Cond.                                               
(0.5.0.5.0.5 molar)                                                       
JEFFAMINE          --      --      18   --                                
D-400.DICY.CH.sub.2 O Cond.                                               
(1.0.2.0.0.2.0 molar)                                                     
JEFFAMINE          --      --      --   16                                
D-230.DICY.CH.sub.2 O Cond.                                               
Storage stability, days to solidify                                       
@˜25° C.                                                     
                   8.sup.3 &lt;1.sup.4                                       
                                   5    5                                 
@40° C.     4.sup.3 &lt;1.sup.4                                       
                                   5    5                                 
                                   6    7                                 
Properties of Cured 1/8 in Castings.sup.1                                 
Izod impact strength, ft/lbs/in                                           
                   0.12    0.14                                           
Tensile strength, psi                                                     
                   10450   10600                                          
Tensile modulus, psi                                                      
                   449000  473000                                         
Elongation at break, %                                                    
                   5.2     6.5                                            
Flexural strength, psi                                                    
                   17950   16600                                          
Flexural modulus, psi                                                     
                   482000  448000                                         
HDT, °C., 264 psi/66 psi                                           
                   63/72   86/91                                          
Shore D hardness, 0-10 sec                                                
                   77-74   76-74                                          
Compression strength at yield, psi                                        
                   12400   13500   --                                     
at failure, psi    42400   40100   6100                                   
% weight gain, 24 hour water boil                                         
                   5.0     3.5                                            
% weight gain, 3 hour acetone boil                                        
                   10.5    7.0                                            
Adhesive Properties.sup.2                                                 
Tensile shear strength, psi                                               
                   4000    3400    3900                                   
T-peel strength, pli                                                      
                   3.3     2.7     2.4                                    
______________________________________                                    
 .sup.1 Cured 2 hrs at 100° C., 3 hrs at 150° C.            
 .sup.2 Cured 1 hr at 150° C., 3 hrs at 150° C.             
 .sup.3 Viscous after 24 hours.                                           
 .sup.4 Brittle solid after 24 hours.                                     
 .sup.5 Non-homogeneous-solids in liquid immediately after mixing.        
 .sup.6 Could not prepare satisfactory panel for testing.                 
 .sup.7 Viscous gel formed on mixing; could not pour into mold.           
 
    
     EXAMPLE 5 
     As in Example 4, additional formulations were made into castings where possible. 
     
         ______________________________________                                    
                E     F       G       H                                   
______________________________________                                    
Formulation                                                               
Liquid epoxy resin (EEW˜185)                                        
                  100     100     100   100                               
JEFFAMINE         24      --      --    --                                
M-360.DICY.CH.sub.2 O Cond.                                               
(1.0.1.0.1.0 molar)                                                       
JEFFAMINE         --      22      --    --                                
M-360.DICY.CH.sub.2 O Cond.                                               
(0.67.1.0.1.0 molar)                                                      
JEFFAMINE         --      --      24    --                                
ED-600.DICY.CH.sub.2 O Cond.                                              
(0.5.1.0.1.0 molar)                                                       
DPTA.sup.1.DICY.CH.sub.2 O Cond.                                          
                  --      --      --    16                                
Storage stability, days to solidify                                       
@˜25° C.                                                     
                  ˜30                                               
                          ˜30                                       
                                  ˜21                               
                                        6                                 
@40° C.    10      9       6.sup.4,5                               
                                        6                                 
Properties of Cured 1/8 in Castings.sup.2                                 
Izod impact strength, ft/lbs/in                                           
                  0.12    0.14    0.14                                    
Tensile strength, psi                                                     
                  8100    8600    10000                                   
Tensile modulus, psi                                                      
                  472000  470000  471000                                  
Elongation at break, %                                                    
                  2.4     2.1     4.0                                     
Flexural strength, psi                                                    
                  14300   16400   17200                                   
Flexural modulus, psi                                                     
                  432000  471000  493000                                  
HDT, °C., 264 psi/66 psi                                           
                  42.5/44 51/57   47/51                                   
Shore D hardness, 0-10 sec                                                
                  75-71   77-74   75-72                                   
Compression strength at yield, psi                                        
                  12000   13700   12700                                   
to failure, psi   30700   28500   26800                                   
% weight gain, 24 hour water boil                                         
                  5.0     5.0     --                                      
% weight gain, 3 hour acetone boil                                        
                  28.9    16.5    --                                      
Adhesive Properties.sup.3                                                 
Tensile shear strength, psi                                               
                  1600    3600    3800                                    
T-peel strength, pli                                                      
                  1.5     1.9     2.7                                     
______________________________________                                    
 .sup.1 DPTA = dipropylenetriamine. Comparative example.                  
 .sup.2 Cured 2 hrs at 100° C., 3 hrs at 150° C.            
 .sup.3 Cured 1 hr at 100° C., 3 hrs at 150° C.             
 .sup.4 Liquid after 48 hrs but gel particles formed throughout liquid    
 material.                                                                
 .sup.5 Near gel after 5 days; phase separation of gel particles.         
 .sup.6 Gel-like particles formed immediately on mixing; no panel prepared
                                                                          
 
    
     GLOSSARY 
     JEFFAMINE® D-400--a polyoxyalkylene diamine of about 400 molecular weight. A product of Texaco Chemical Co. 
     JEFFAMINE T-403--a polyoxyalkylene triamine of about 400 molecular weight. A product of Texaco Chemical Co. 
     JEFFAMINE D-230--a polyoxyalkylene diamine of about 230 molecular weight. A product of Texaco Chemical Co. 
     JEFFAMINE M-360--a polyoxyalkylene monoamine of about 360 molecular weight. A product of Texaco Chemical Co. 
     JEFFAMINE ED-600--a water soluble polyoxyalkylene diamine of about 600 molecular weight. A product of Texaco Chemical Co. 
     EPON® 828--liquid epoxy resin--a diglycidyl ether of Bisphenol A of EEW˜185. EEW is epoxy equivalent weight. 
     JEFFAMINE T-5000--a polyoxyalkylene triamine of about 5000 molecular weight. A product of Texaco Chemical Co. 
     JEFFAMINE ED-900--a water soluble polyoxyalkylene diamine of about 900 molecular weight. A product of Texaco Chemical Co. 
     JEFFAMINE D-2000--a polyoxyalkylene diamine of about 2000 molecular weight. A product of Texaco Chemical Co.