Patent Publication Number: US-2020277283-A1

Title: Organic electroluminescent materials and devices

Description:
This application claims the benefit of Chinese Application No. 201910149767.3 filed on Feb. 28, 2019 to the China National Intellectual Property Administration, the entire content of which is incorporated herein by reference. 
     TECHNICAL FIELD 
     The present disclosure relates to compounds for organic electronic device, such as organic electroluminescent device. More specifically, it relates to novel carbazole compounds, and organic electroluminescent devices and a compound formulation comprising the same. 
     BACKGROUND 
     Organic electronic devices include, but are not limited to, the following types: organic light-emitting diodes (OLEDs), organic field-effect transistors (O-FETs), organic light-emitting transistors (OLETs), organic photovoltaic devices (OPVs), dye-sensitized solar cells (DSSCs), organic optical detectors, organic photoreceptors, organic field-quench devices (OFQDs), light-emitting electrochemical cells (LECs), organic laser diodes and organic plasmon emitting devices. Among them, OLEDs are becoming more and more popular for their unique superior properties, such as having a wide color gamut, almost infinitely high contrast, extremely high response speed, flexibility, energy saving and etc. 
     OLED can be categorized as three different types according to its emitting mechanism. The OLED invented by Tang and van Slyke is a fluorescent OLED. It only utilizes singlet emission. The triplets generated in the device are wasted through nonradiative decay channels. Therefore, the internal quantum efficiency (IQE) of a fluorescent OLED is only 25%. This limitation hindered the commercialization of OLED. In 1997, Forrest and Thompson reported phosphorescent OLED, which uses triplet emission from heave metal containing complexes as the emitter. As a result, both singlet and triplets can be harvested, achieving 100% IQE. The discovery and development of phosphorescent OLED contributed directly to the commercialization of active-matrix OLED (AMOLED) due to its high efficiency. Recently, Adachi achieved high efficiency through thermally activated delayed fluorescence (TADF) of organic compounds. These emitters have small singlet-triplet gap that makes the transition from triplet back to singlet possible. In the TADF device, the triplet excitons can go through reverse intersystem crossing to generate singlet excitons, resulting in high IQE. 
     The emitting color of an OLED can be achieved by emitter structural design. An OLED may comprise one emitting layer or a plurality of emitting layers to achieve desired spectrum. In the case of green, yellow, and red OLEDs, phosphorescent emitters have successfully reached commercialization. Blue phosphorescent device still suffers from non-saturated blue color, short device lifetime, and high operating voltage. Commercial full-color OLED displays normally adopt a hybrid strategy, using fluorescent blue and phosphorescent yellow, or red and green. At present, efficiency roll-off of phosphorescent OLEDs at high brightness remains a problem. In addition, it is desirable to have more saturated emitting color, higher efficiency, and longer device lifetime. 
     The carbazole-based organic semiconductor materials have a wide range of application in optoelectronic devices due to their superior optoelectronic properties, redox properties, stability and etc. 
     WO2013100538A1 disclosed carbazole compounds of the following structure 
     
       
         
         
             
             
         
       
     
     especially 
     
       
         
         
             
             
         
       
     
     The inventor of this application noticed various advantages of the compound obtained by combining carbazole with an aza six-membered aromatic ring such as pyridine, pyrimidine, and triazine, but it did not explicitly recognize the unique advantages of the triazine structure. In addition, in the choice of the position where the triazine is connected to the carbazole ring, it is not aware of the advantages of substitution positions on the carbazole ring other than the 3-position explicitly disclosed in this invention, especially the 2-position substitution. 
     KR1020180060474A, EP2991128A1 and US20150228908A1 all have disclosed compounds in which the aza-ring structure such as triazine is connected to the 4-position of the carbazole ring through a single bond or a (hetero) arylene-based linking group. However, KR1020180060474A requires that a carbazole group further be connected to the carbazole unit, which may lead to unfavorable results of excessively enhanced hole transporting capabilities. EP2991128A1 mainly focuses on the combination use of a compound having a triazine substitution at the 4-position of carbazole and a specific second host compound having a bicarbazole and a benzothienopyrimidine or benzofuropyrimidine structure. US20150228908A1 also noticed the advantage of introducing an aza-aromatic ring at the 4-position of carbazole. It uses a series of aza-aromatic ring structures such as triazine, pyrimidine, quinoxaline, pyrimidopyrimidine, and pyrazinoimidazole. It is also unconscious about the advantages of substitution to other positions on the carbazole ring, especially the 2-position. 
     US20120223276A1 disclosed the following structure: 
     
       
         
         
             
             
         
       
     
     those two compounds containing carbazole or phosphofluorene structural units. In this application, the advantages of introducing an aza-aromatic ring structure on the carbazole ring are noted, but the position of introducing an aza-aromatic ring is variable, involving the 2-, 3- and 9-positions (on the nitrogen atom of carbazole) substituted compounds, and it does not realize the special advantage of fixing the triazine group at a specific position of the carbazole ring for substitution. 
     However, carbazole-based organic semiconductor materials reported currently have certain limitations in optoelectronic devices such as carrier transporting capabilities, efficiency, and lifetime. Therefore, the application potential of such materials deserves further research and development. The present invention discloses a new carbazole compound, which can improve the lifetime of a device and provide better device performance. 
     SUMMARY 
     The present disclosure aims to provide a series of compounds with novel carbazole structure to solve at least part of the above problems. The compound can be used as host material, hole blocking material in an organic electroluminescent device. These new compounds can provide better device performance, such as device performance of very low driving voltage, high efficiency, and long lifetime. 
     According to an embodiment of the present disclosure, a compound having the structure of Formula 1 is disclosed: 
     
       
         
         
             
             
         
       
     
     wherein 
     R a  is selected from biphenyl, terphenyl, naphthyl, phenanthryl, triphenylene, fluorenyl, dibenzofuranyl; 
     n is the number of R b , n is selected from 1, 2, 3 or 4; when n≥2, the R b  is selected from the same or different structures, each of R b  is independently selected from the group consisting of: hydrogen, deuterium, phenyl, biphenyl and terphenyl; 
     R c , R d  and R e  are each independently selected from the group consisting of hydrogen, deuterium, halogen, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted heteroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted arylalkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 20 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 20 carbon atoms, and combinations thereof; 
     and, wherein R 1  has the structure of Formula 2: 
     
       
         
         
             
             
         
       
     
     L is a single bond, or a substituted or unsubstituted arylene having 6 to 60 carbon atoms; 
     R 2  and R 3  are each independently selected from the group consisting of hydrogen, deuterium, halogen, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted heteroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted arylalkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 20 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 20 carbon atoms, and combinations thereof; 
     when R 2  and R 3  are selected from a substituted group in the group, the substitution in the substituted group is selected from deuterium, halogen, an unsubstituted alkyl group having 1 to 20 carbon atoms, an unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, an unsubstituted heteroalkyl group having 1 to 20 carbon atoms, an unsubstituted arylalkyl group having 7 to 30 carbon atoms, an unsubstituted alkoxy group having 1 to 20 carbon atoms, an unsubstituted aryl group having 6 to 30 carbon atoms, and combinations thereof. 
     According to another embodiment of the present disclosure, an electroluminescent device is also disclosed, which comprises an anode, a cathode, and an organic layer disposed between the anode and the cathode, wherein the organic layer comprising the compound having the structure of Formula 1 described above. 
     According to another embodiment of the present disclosure, a compound formulation comprising the compound having the structure of Formula 1 described above is also disclosed. 
     The compound having a novel carbazole structure disclosed in the present disclosure can be used as host material, hole blocking material in an organic electroluminescent device. Compared with existing compounds, these new compounds can provide better device performance, such as very low drive voltage, high efficiency, and long lifetime. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1  schematically shows an organic light emitting device that can incorporate the compound and compound formulation disclosed herein. 
         FIG. 2  schematically shows another organic light emitting device that can incorporate the compound and compound formulation disclosed herein. 
         FIG. 3  shows the Structural Formula 1 of the compound disclosed herein. 
     
    
    
     DETAILED DESCRIPTION 
     OLEDs may be fabricated on various types of substrates such as glass, plastic, and metal foil.  FIG. 1  schematically shows the organic light emitting device  100  without limitation. The figures are not necessarily drawn to scale. Some of the layers in the figures may also be omitted as needed. Device  100  may include a substrate  101 , an anode  110 , a hole injection layer  120 , a hole transport layer  130 , an electron blocking layer  140 , an emissive layer  150 , a hole blocking layer  160 , an electron transport layer  170 , an electron injection layer  180  and a cathode  190 . Device  100  may be fabricated by depositing the layers described in order. The properties and functions of these various layers, as well as example materials, are described in more detail in U.S. Pat. No. 7,279,704 at cols. 6-10, the contents of which are incorporated by reference herein in its entirety. 
     More examples for each of these layers are available. For example, a flexible and transparent substrate-anode combination is disclosed in U.S. Pat. No. 5,844,363, which is incorporated by reference herein in its entirety. An example of a p-doped hole transport layer is m-MTDATA doped with F 4 -TCNQ at a molar ratio of 50:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference herein in its entirety. Examples of host materials are disclosed in U.S. Pat. No. 6,303,238 to Thompson et al., which is incorporated by reference herein in its entirety. An example of an n-doped electron transport layer is BPhen doped with Li at a molar ratio of 1:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference herein in its entirety. U.S. Pat. Nos. 5,703,436 and 5,707,745, which are incorporated by reference herein in their entireties, disclose examples of cathodes including composite cathodes having a thin layer of metal such as Mg:Ag with an overlying transparent, electrically-conductive, sputter-deposited ITO layer. The theory and use of blocking layers is described in more detail in U.S. Pat. No. 6,097,147 and U.S. Patent Application Publication No. 2003/0230980, which are incorporated by reference herein in their entireties. Examples of injection layers are provided in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference herein in its entirety. A description of protective layers may be found in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference herein in its entirety. 
     The layered structure described above is provided by way of non-limiting example. Functional OLEDs may be achieved by combining the various layers described in different ways, or layers may be omitted entirely. It may also include other layers not specifically described. Within each layer, a single material or a mixture of multiple materials may be used to achieve optimum performance. Any functional layer may include several sublayers. For example, the emissive layer may have two layers of different emitting materials to achieve desired emission spectrum. 
     In one embodiment, an OLED may be described as having an “organic layer” disposed between a cathode and an anode. This organic layer may comprise a single layer or multiple layers. 
     An OLED may be encapsulated by a barrier layer.  FIG. 2  schematically shows the organic light emitting device  200  without limitation.  FIG. 2  differs from  FIG. 1  in that the organic light emitting device include a barrier layer  102 , which is above the cathode  190 , to protect it from harmful species from the environment such as moisture and oxygen. Any material that may provide the barrier function may be used as the barrier layer such as glass and organic-inorganic hybrid layers. The barrier layer should be placed directly or indirectly outside of the OLED device. Multilayer thin film encapsulation was described in U.S. Pat. No. 7,968,146, which is herein incorporated by reference in its entirety. 
     Devices fabricated in accordance with embodiments of the present disclosure may be incorporated into a wide variety of consumer products that have one or more of the electronic component modules (or units) incorporated therein. Some examples of such consumer products include flat panel displays, monitors, medical monitors, televisions, billboards, lights for interior or exterior illumination and/or signaling, heads-up displays, fully or partially transparent displays, flexible displays, smart phones, tablets, phablets, wearable devices, smart watches, laptop computers, digital cameras, camcorders, viewfinders, micro-displays, 3-D displays, vehicles displays, and vehicle tail lights. 
     The materials and structures described herein may be used in other organic electronic devices listed above. 
     As used herein, “top” means furthest away from the substrate, while “bottom” means closest to the substrate. Where a first layer is described as “disposed over” a second layer, the first layer is disposed further away from substrate. There may be other layers between the first and second layer, unless it is specified that the first layer is “in contact with” the second layer. For example, a cathode may be described as “disposed over” an anode, even though there are various organic layers in between. 
     As used herein, “solution processable” means capable of being dissolved, dispersed, or transported in and/or deposited from a liquid medium, either in solution or suspension form. 
     A ligand may be referred to as “photoactive” when it is believed that the ligand directly contributes to the photoactive properties of an emissive material. A ligand may be referred to as “ancillary” when it is believed that the ligand does not contribute to the photoactive properties of an emissive material, although an ancillary ligand may alter the properties of a photoactive ligand. 
     It is believed that the internal quantum efficiency (IQE) of fluorescent OLEDs may exceed the 25% spin statistics limit through delayed fluorescence. As used herein, there are two types of delayed fluorescence, i.e. P-type delayed fluorescence and E-type delayed fluorescence. P-type delayed fluorescence is generated from triplet-triplet annihilation (TTA). 
     On the other hand, E-type delayed fluorescence does not rely on the collision of two triplets, but rather on the transition between the triplet states and the singlet excited states. Compounds that are capable of generating E-type delayed fluorescence are required to have very small singlet-triplet gaps to convert between energy states. Thermal energy may activate the transition from the triplet state back to the singlet state. This type of delayed fluorescence is also known as thermally activated delayed fluorescence (TADF). A distinctive feature of TADF is that the delayed component increases as temperature rises. If the reverse intersystem crossing rate is fast enough to minimize the non-radiative decay from the triplet state, the fraction of back populated singlet excited states may potentially reach 75%. The total singlet fraction may be 100%, far exceeding 25% of the spin statistics limit for electrically generated excitons. 
     E-type delayed fluorescence characteristics may be found in an exciplex system or in a single compound. Without being bound by theory, it is believed that E-type delayed fluorescence requires the luminescent material to have a small singlet-triplet energy gap (ΔE S-T ). Organic, non-metal containing, donor-acceptor luminescent materials may be able to achieve this. The emission in these materials is often characterized as a donor-acceptor charge-transfer (CT) type emission. The spatial separation of the HOMO and LUMO in these donor-acceptor type compounds often results in small ΔE S-T . These states may involve CT states. Often, donor-acceptor luminescent materials are constructed by connecting an electron donor moiety such as amino- or carbazole-derivatives and an electron acceptor moiety such as N-containing six-membered aromatic rings. 
     Definition of Terms of Substituents 
     Halogen or halide—as used herein includes fluorine, chlorine, bromine, and iodine. 
     Alkyl—contemplates both straight and branched chain alkyl groups. Examples of the alkyl group include methyl group, ethyl group, propyl group, isopropyl group, n-butyl group, s-butyl group, isobutyl group, t-butyl group, n-pentyl group, n-hexyl group, n-heptyl group, n-octyl group, n-nonyl group, n-decyl group, n-undecyl group, n-dodecyl group, n-tridecyl group, n-tetradecyl group, n-pentadecyl group, n-hexadecyl group, n-heptadecyl group, n-octadecyl group, neopentyl group, 1-methylpentyl group, 2-methylpentyl group, 1-pentylhexyl group, 1-butylpentyl group, 1-heptyloctyl group, and 3-methylpentyl group. Additionally, the alkyl group may be optionally substituted. The carbons in the alkyl chain may be replaced by other hetero atoms. Of the above, preferred are methyl group, ethyl group, propyl group, isopropyl group, n-butyl group, s-butyl group, isobutyl group, t-butyl group, n-pentyl group, and neopentyl group. 
     Cycloalkyl—as used herein contemplates cyclic alkyl groups. Preferred cycloalkyl groups are those containing 4 to 10 ring carbon atoms and includes cyclobutyl, cyclopentyl, cyclohexyl, 4-methylcyclohexyl, 4,4-dimethylcylcohexyl, 1-adamantyl, 2-adamantyl, 1-norbornyl, 2-norbornyl and the like. Additionally, the cycloalkyl group may be optionally substituted. The carbons in the ring can be replaced by other hetero atoms. 
     Alkenyl—as used herein contemplates both straight and branched chain alkene groups. Preferred alkenyl groups are those containing 2 to 15 carbon atoms. Examples of the alkenyl group include vinyl group, allyl group, 1-butenyl group, 2-butenyl group, 3-butenyl group, 1,3-butandienyl group, 1-methylvinyl group, styryl group, 2,2-diphenylvinyl group, 1,2-diphenylvinyl group, 1-methylallyl group, 1,1-dimethylallyl group, 2-methylallyl group, 1-phenylallyl group, 2-phenylallyl group, 3-phenylallyl group, 3,3-diphenylallyl group, 1,2-dimethylallyl group, 1-phenyl 1-butenyl group, and 3-phenyl-1-butenyl group. Additionally, the alkenyl group may be optionally substituted. 
     Alkynyl—as used herein contemplates both straight and branched chain alkyne groups. Preferred alkynyl groups are those containing 2 to 15 carbon atoms. Additionally, the alkynyl group may be optionally substituted. 
     Aryl or aromatic group—as used herein includes noncondensed and condensed systems. Preferred aryl groups are those containing six to sixty carbon atoms, preferably six to twenty carbon atoms, more preferably six to twelve carbon atoms. Examples of the aryl group include phenyl, biphenyl, terphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene, preferably phenyl, biphenyl, terphenyl, triphenylene, fluorene, and naphthalene. Additionally, the aryl group may be optionally substituted. Examples of the non-condensed aryl group include phenyl group, biphenyl-2-yl group, biphenyl-3-yl group, biphenyl-4-yl group, p-terphenyl-4-yl group, p-terphenyl-3-yl group, p-terphenyl-2-yl group, m-terphenyl-4-yl group, m-terphenyl-3-yl group, m-terphenyl-2-yl group, o-tolyl group, m-tolyl group, p-tolyl group, p-t-butylphenyl group, p-(2-phenylpropyl)phenyl group, 4′-methylbiphenylyl group, 4″-t-butyl p-terphenyl-4-yl group, o-cumenyl group, m-cumenyl group, p-cumenyl group, 2,3-xylyl group, 3,4-xylyl group, 2,5-xylyl group, mesityl group, and m-quarterphenyl group. 
     Heterocyclic group or heterocycle—as used herein includes aromatic and non-aromatic cyclic groups. Hetero-aromatic also means heteroaryl. Preferred non-aromatic heterocyclic groups are those containing 3 to 7 ring atoms which include at least one hetero atom such as nitrogen, oxygen, and sulfur. The heterocyclic group may also be an aromatic heterocyclic group having at least one heteroatom selected from nitrogen atom, oxygen atom, sulfur atom, and selenium atom. 
     Heteroaryl—as used herein includes noncondensed and condensed hetero-aromatic groups that may include from one to five heteroatoms. Preferred heteroaryl groups are those containing three to thirty carbon atoms, preferably three to twenty carbon atoms, more preferably three to twelve carbon atoms. Suitable heteroaryl groups include dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine, preferably dibenzothiophene, dibenzofuran, dibenzoselenophene, carbazole, indolocarbazole, imidazole, pyridine, triazine, benzimidazole, 1,2-azaborine, 1,3-azaborine, 1,4-azaborine, borazine, and aza-analogs thereof. Additionally, the heteroaryl group may be optionally substituted. 
     Alkoxy—it is represented by —O-Alkyl. Examples and preferred examples thereof are the same as those described above. Examples of the alkoxy group having 1 to 20 carbon atoms, preferably 1 to 6 carbon atoms include methoxy group, ethoxy group, propoxy group, butoxy group, pentyloxy group, and hexyloxy group. The alkoxy group having 3 or more carbon atoms may be linear, cyclic or branched. 
     Aryloxy—it is represented by —O-Aryl or —O-heteroaryl. Examples and preferred examples thereof are the same as those described above. Examples of the aryloxy group having 6 to 40 carbon atoms include phenoxy group and biphenyloxy group. 
     Arylalkyl—as used herein contemplates an alkyl group that has an aryl substituent. Additionally, the arylalkyl group may be optionally substituted. Examples of the arylalkyl group include benzyl group, 1-phenylethyl group, 2-phenylethyl group, 1-phenylisopropyl group, 2-phenylisopropyl group, phenyl-t-butyl group, alpha.-naphthylmethyl group, 1-alpha.-naphthylethyl group, 2-alpha-naphthylethyl group, 1-alpha-naphthylisopropyl group, 2-alpha-naphthylisopropyl group, beta-naphthylmethyl group, 1-beta-naphthylethyl group, 2-beta-naphthylethyl group, 1-beta-naphthylisopropyl group, 2-beta-naphthylisopropyl group, p-methylbenzyl group, m-methylbenzyl group, o-methylbenzyl group, p-chlorobenzyl group, m-chlorobenzyl group, o-chlorobenzyl group, p-bromobenzyl group, m-bromobenzyl group, o-bromobenzyl group, p-iodobenzyl group, m-iodobenzyl group, o-iodobenzyl group, p-hydroxybenzyl group, m-hydroxybenzyl group, o-hydroxybenzyl group, p-aminobenzyl group, m-aminobenzyl group, o-aminobenzyl group, p-nitrobenzyl group, m-nitrobenzyl group, o-nitrobenzyl group, p-cyanobenzyl group, m-cyanobenzyl group, o-cyanobenzyl group, 1-hydroxy-2-phenylisopropyl group, and 1-chloro-2-phenylisopropyl group. Of the above, preferred are benzyl group, p-cyanobenzyl group, m-cyanobenzyl group, o-cyanobenzyl group, 1-phenylethyl group, 2-phenylethyl group, 1-phenylisopropyl group, and 2-phenylisopropyl group. 
     The term “aza” in azadibenzofuran, aza-dibenzothiophene, etc. means that one or more of the C—H groups in the respective aromatic fragment are replaced by a nitrogen atom. For example, azatriphenylene encompasses dibenzo[f,h]quinoxaline, dibenzo[f,h]quinoline and other analogues with two or more nitrogens in the ring system. One of ordinary skill in the art may readily envision other nitrogen analogs of the aza-derivatives described above, and all such analogs are intended to be encompassed by the terms as set forth herein. 
     In this disclosure, unless defined otherwise, when using any one of the terms of the group consisting of substituted alkyl, substituted cycloalkyl, substituted heteroalkyl, substituted aralkyl, substituted alkoxy, substituted aryloxy, substituted alkenyl, substituted aryl, substituted heteroaryl, substituted alkylsilyl, substituted arylsilyl, substituted amine, substituted acyl, substituted carbonyl, substituted carboxylic acid, substituted ester, substituted nitrile, substituted isonitrile, substituted thioalkyl, substituted sulfinyl, substituted sulfonyl, substituted phosphino refers to any one of alkyl, cycloalkyl, heteroalkyl, aralkyl, alkoxy, aryloxy, alkenyl, aromatic group, heteroaryl, alkylsilyl, arylsilyl, amine, acyl, carbonyl, carboxylic acid, ester, nitrile, isonitrile, thioalkyl, sulfinyl, sulfonyl, and phosphino may be substituted with one or more substituents selected from the group consisting of deuterium, an unsubstituted alkyl group having 1 to 20 carbon atoms, an unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, an unsubstituted heteroalkyl group having 1 to 20 carbon atoms, an unsubstituted arylalkyl group having 7 to 30 carbon atoms, an unsubstituted alkoxy group having 1 to 20 carbon atoms, an unsubstituted aryloxy group having 6 to 30 carbon atoms, an unsubstituted alkenyl group having 2 to 20 carbon atoms, an unsubstituted aryl group having 6 to 30 carbon atoms, an unsubstituted heteroaryl group having 3 to 30 carbon atoms, an unsubstituted alkylsilyl group having 3 to 20 carbon atoms, an unsubstituted arylsilyl group having 6 to 20 carbon atoms, an unsubstituted amino group having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a nitrile group, an isonitrile group, a thioalkyl group, a sulfinyl group, a sulfonyl group, a phosphino group, and combinations thereof. 
     It is to be understood that when a molecular fragment is described as being a substituent or otherwise attached to another moiety, its name may be written as if it were a fragment (e.g. phenyl, phenylene, naphthyl, dibenzofuryl) or as if it were the whole molecule (e.g. benzene, naphthalene, dibenzofuran). As used herein, these different ways of designating a substituent or attached fragment are considered to be equivalent. 
     In the compounds mentioned in this disclosure, the hydrogen atoms may be partially or fully replaced by deuterium. Other atoms such as carbon and nitrogen, may also be replaced by their other stable isotopes. The replacement by other stable isotopes in the compounds may be preferred due to its enhancements of device efficiency and stability. 
     In the compounds mentioned in this disclosure, multiple substitutions refer to a range that includes a double substitution, up to the maximum available substitutions. When a substituent in a compound mentioned in this disclosure represents a multi-substitution (including di-, tri-, tetra-, etc.), it means that the substituent may exist at multiple available substitution positions on its linking structure, the substituents present at multiple available substitution positions may be the same or different structures. 
     According to an embodiment of the present disclosure, a compound having the structure of Formula 1 is disclosed: 
     
       
         
         
             
             
         
       
     
     wherein 
     R a  is selected from biphenyl, terphenyl, naphthyl, phenanthryl, triphenylene, fluorenyl, dibenzofuranyl; 
     n is the number of R b , n is selected from 1, 2, 3 or 4; when n≥2, the R b  is selected from the same or different structures; each of R b  is independently selected from the group consisting of: hydrogen, deuterium, phenyl, biphenyl and terphenyl; 
     R c , R d  and R e  are each independently selected from the group consisting of hydrogen, deuterium, halogen, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted heteroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted arylalkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 20 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 20 carbon atoms, and combinations thereof; 
     and R 1  has the structure of Formula 2: 
     
       
         
         
             
             
         
       
     
     L is a single bond, or a substituted or unsubstituted arylene having 6 to 60 carbon atoms; 
     R 2  and R 3  are each independently selected from the group consisting of hydrogen, deuterium, halogen, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted heteroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted arylalkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 20 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 20 carbon atoms, and combinations thereof; 
     when R 2  and R 3  are selected from a substituted group in the group, the substitution in the substituted group is selected from deuterium, halogen, an unsubstituted alkyl group having 1 to 20 carbon atoms, an unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, an unsubstituted heteroalkyl group having 1 to 20 carbon atoms, an unsubstituted arylalkyl group having 7 to 30 carbon atoms, an unsubstituted alkoxy group having 1 to 20 carbon atoms, an unsubstituted aryl group having 6 to 30 carbon atoms, and combinations thereof. 
     According to an embodiment of the present disclosure, wherein R 2  and R 3  are unsubstituted aryl groups having 6 to 30 carbon atoms. 
     According to a preferred embodiment of the present disclosure, wherein R 2  and R 3  are each independently selected from phenyl, biphenyl or terphenyl. 
     According to another preferred embodiment of the present disclosure, wherein at least one of R 2  and R 3  is biphenyl or terphenyl. 
     According to an embodiment of the present disclosure, wherein L is selected from a substituted or unsubstituted arylene having 6 to 30 carbon atoms; further, L is selected from a substituted or unsubstituted arylene having 6 to 20 carbon atoms. 
     According to an embodiment of the present disclosure, wherein L is a single bond. 
     According to an embodiment of the present disclosure, wherein R b  is hydrogen. 
     According to an embodiment of the present disclosure, wherein R c , R d  and R e  is hydrogen. 
     According to an embodiment of the present disclosure, wherein the compound is selected from the group consisting of: 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     According to an embodiment of the present disclosure, wherein the hydrogen in the above-mentioned Compound 1 to Compound 270 can be partially or completely replaced by deuterium. 
     According to an embodiment of the present disclosure, an electroluminescent device is also disclosed, which comprises: 
     an anode, 
     a cathode, 
     and an organic layer disposed between the anode and the cathode, wherein the organic layer comprising the compound having the structure of Formula 1: 
     
       
         
         
             
             
         
       
     
     wherein 
     R a  is selected from biphenyl, terphenyl, naphthyl, phenanthryl, triphenylene, fluorenyl, dibenzofuranyl; 
     n is the number of R b , n is selected from 1, 2, 3 or 4; when n≥2, the R b  is selected from the same or different structures; each of R b  is independently selected from the group consisting of: hydrogen, deuterium, phenyl, biphenyl and terphenyl; 
     R c , R d  and R e  are each independently selected from the group consisting of hydrogen, deuterium, halogen, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted heteroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted arylalkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 20 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 20 carbon atoms, and combinations thereof; 
     and R 1  has the structure of Formula 2: 
     
       
         
         
             
             
         
       
     
     L is selected from a single bond, or a substituted or unsubstituted arylene having 6 to 60 carbon atoms; 
     R 2  and R 3  are each independently selected from the group consisting of hydrogen, deuterium, halogen, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted heteroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted arylalkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 20 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 20 carbon atoms, and combinations thereof; 
     when R 2  and R 3  are selected from a substituted group in the group, the substitution in the substituted group is selected from deuterium, halogen, an unsubstituted alkyl group having 1 to 20 carbon atoms, an unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, an unsubstituted heteroalkyl group having 1 to 20 carbon atoms, an unsubstituted arylalkyl group having 7 to 30 carbon atoms, an unsubstituted alkoxy group having 1 to 20 carbon atoms, an unsubstituted aryl group having 6 to 30 carbon atoms, and combinations thereof. 
     According to an embodiment of the present disclosure, wherein in the device, the organic layer is a light emitting layer, and the compound is a host material. 
     According to an embodiment of the present disclosure, wherein in the device, the organic layer is a hole blocking layer, and the compound is a hole blocking material. 
     According to an embodiment of the present disclosure, wherein in the device, the light emitting layer further comprises at least one host material different from the compound having Formula 1. 
     According to an embodiment of the present disclosure, wherein in the device, the light emitting layer further comprises phosphorescent material. 
     According to an embodiment of the present disclosure, wherein the phosphorescent material is a metal complex, the metal complex comprises at least one ligand, and the ligand comprises any one of the following structures: 
     
       
         
         
             
             
         
       
     
     wherein 
     R x , R y , and R z  can represent mono substitution, multiple substitutions or no substitution; 
     R x , R y , and R z  are each independently selected from the group consisting of hydrogen, deuterium, halogen, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted heteroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted arylalkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 20 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 20 carbon atoms, a substituted or unsubstituted amino group having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a nitrile group, an isonitrile group, a thiol group, a sulfinyl group, a sulfonyl group, a phosphino group, and combinations thereof; 
     X b  is selected from the group consisting of O, S, Se, NR N1 , CR 1 R C2 ; 
     R N1 , R C1  and R C2  are each independently selected from the group consisting of hydrogen, deuterium, halogen, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted heteroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted arylalkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 20 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 20 carbon atoms, a substituted or unsubstituted amino group having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a nitrile group, an isonitrile group, a thioalkyl group, a sulfinyl group, a sulfonyl group, a phosphino group, and combinations thereof. 
     According to another embodiment of the present disclosure, a compound formulation comprising the compound represented by Formula 1 is further disclosed, the specific structure of the compound is described in any one of the embodiments aforementioned. 
     Combination with Other Materials 
     The materials described in the present disclosure for a particular layer in an organic light emitting device may be used in combination with various other materials present in the device. The combinations of these materials are described in more detail in U.S. Pat. App. No. 20160359122A1 at paragraphs 0132-0161, which is incorporated by reference herein in its entirety. The materials described or referred to the disclosure are non-limiting examples of materials that may be useful in combination with the materials disclosed herein, and one of skill in the art may readily consult the literature to identify other materials that may be useful in combination. 
     The materials described herein as useful for a particular layer in an organic light emitting device may be used in combination with a variety of other materials present in the device. For example, the compounds disclosed herein may be used in combination with a wide variety of emitting dopants, hosts, transporting layers, blocking layers, injection layers, electrodes and other layers that may be present. The combination of these materials is described in detail in paragraphs 0080-0101 of U.S. Pat. App. No. 20150349273, which is incorporated by reference herein in its entirety. The materials described or referred to the disclosure are non-limiting examples of materials that may be useful in combination with the materials disclosed herein, and one of skill in the art may readily consult the literature to identify other materials that may be useful in combination. 
     In the embodiments of material synthesis, all reactions were performed under nitrogen protection unless otherwise stated. All reaction solvents were anhydrous and used as received from commercial sources. Synthetic products were structurally confirmed and tested for properties using one or more conventional equipment in the art (including, but not limited to, nuclear magnetic resonance instrument produced by BRUKER, liquid chromatograph produced by SHIMADZU, liquid chromatography-mass spectrometer produced by SHIMADZU, gas chromatography-mass spectrometer produced by SHIMADZU, differential Scanning calorimeters produced by SHIMADZU, fluorescence spectrophotometer produced by SHANGHAI LENGGUANG TECH., electrochemical workstation produced by WUHAN CORRTEST, and sublimation apparatus produced by ANHUI BEQ, etc.) by methods well known to the persons skilled in the art. In the embodiments of the device, the characteristics of the device were also tested using conventional equipment in the art (including, but not limited to, evaporator produced by ANGSTROM ENGINEERING, optical testing system produced by SUZHOU FATAR, life testing system produced by SUZHOU FATAR, and ellipsometer produced by BEIING ELLITOP, etc.) by methods well known to the persons skilled in the art. As the persons skilled in the art are aware of the above-mentioned equipment use, test methods and other related contents, the inherent data of the sample can be obtained with certainty and without influence, so the above related contents are not further described in this disclosure. 
     Synthesis Examples 
     The method for preparing the compound of the present invention is not limited. The following compounds are exemplified as a typical but non-limiting example, and the synthesis route and preparation method are as follows: 
     Synthesis Example 1: Synthesis of Compound 16 
     Step 1: Synthesis of Intermediate B 
     
       
         
         
             
             
         
       
     
     2-Bromo-carbazole (9.0 g, 36.57 mmol), 4-iodo-biphenyl (13.3 g, 47.54 mmol), CuCl (0.36 g, 3.66 mmol), 18-crown-6 (0.96 g, 3.66 mmol), 1,10-o-phenanthroline (0.66 g, 3.66 mmol), K 2 CO 3  (12.63 g, 91.43 mmol) were added to N-methyl pyrrolidone (200 mL) in a three-necked round-bottomed flask, protected by nitrogen, and heated to 180° C., reacted overnight. The reaction solution was filtrated through celite, the filtrate was poured into a large amount of water, and extracted with DCM several times, dried over anhydrous Na 2 SO 4 , filtered, and rotary evaporated to dryness. Purified via silica gel column chromatography (PE/DCM=40:1) to give intermediate B (9.7 g, 24.36 mmol) as a white solid with a yield of 66.6%. 
     Step 2: Synthesis of Intermediate C 
     
       
         
         
             
             
         
       
     
     Intermediate B (9.7 g, 24.36 mmol), bis(pinacolato)diboron (12.37 g, 48.72 mmol), Pd(dppf)Cl 2  (0.53 g, 0.73 mmol), KOAc (4.68 g, 48.72 mmol) were added to 1,4-dioxane (120 mL) in a three-necked round bottom flask, protected by nitrogen, and heated to reflux overnight. Heating was stopped, the reaction was cooled to room temperature, filtered through celite, and the filtrate was rotary evaporated to dryness. The residue was purified via silica gel column chromatography (PE/DCM=2:1) to obtain a white solid intermediate C (6.1 g, 13.70 mmol) with a yield of 56.2%. 
     Step 3: Synthesis of Compound 16 
     
       
         
         
             
             
         
       
     
     Intermediate C (4.6 g, 10.33 mmol), intermediate D (3.91 g, 11.36 mmol), Pd(PPh 3 ) 4  (0.60 g, 0.52 mmol), K 2 CO 3  (2.86 g, 20.66 mmol) were added to toluene (48 mL), EtOH (12 mL), H 2 O (12 mL) in a three-necked round bottom flask, protected by nitrogen, and heated to reflux overnight. Heating was stopped and the reaction was cooled to room temperature. The reaction was suctioned under reduced pressure, and the solid was sequentially washed with water and methanol several times. The solid was recrystallized from toluene to obtain Compound 16 (5.5 g, 8.78 mmol) as a white solid in a yield of 84.9%. The product was identified as the target product with a molecular weight of 627. 
     Synthesis Example 2: Synthesis of Compound 19 
     Step 1: Synthesis of Intermediate F 
     
       
         
         
             
             
         
       
     
     2-Bromo-carbazole (8.24 g, 33.46 mmol), 2-iodo-naphthalene (11.05 g, 43.5 mmol), CuCl (0.33 g, 3.35 mmol), 18-crown-6 (0.88 g, 3.35 mmol), 1,10-o-phenanthroline (0.60 g, 3.35 mmol), K 2 CO 3  (11.56 g, 83.65 mmol) were added to N-methyl pyrrolidone (190 mL) in a three-neck round bottom flask, protected by nitrogen, heated to 180° C., and reacted overnight. Heating was stopped and the reaction was cooled to room temperature. The reaction solution was filtered through celite. The filtrate was poured into a large amount of water, extracted with DCM several times, dried over anhydrous Na 2 SO 4 , filtered and rotary evaporated to dryness. Purified via silica gel column chromatography (PE/DCM=50:1) to give intermediate F (11.0 g, 29.55 mmol) as a white solid with a yield of 88.3%. 
     Step 2: Synthesis of Intermediate G 
     
       
         
         
             
             
         
       
     
     Intermediate F (11.0 g, 29.54 mmol), bis(pinacolato)diboron (11.25 g, 44.31 mmol), Pd(dppf)Cl 2  (0.65 g, 0.89 mmol), KOAc (5.8 g, 59.08 mmol) were added to 1,4-dioxane (130 mL) in a three-neck round bottom flask, protected by nitrogen, and heated to reflux overnight. Heating was stopped, and the reaction was cooled to room temperature, filtered through celite, and the filtrate was rotary evaporated to dryness. The residue was purified via silica gel column chromatography (PE/DCM=2:1) to obtain white solid intermediate G (8.7 g, 20.75 mmol) with a yield of 70.2%. 
     Step 3: Synthesis of Compound 19 
     
       
         
         
             
             
         
       
     
     Intermediate G (5.87 g, 14.0 mmol), intermediate D (5.29 g, 15.4 mmol), Pd(PPh 3 ) 4  (0.65 g, 0.56 mmol), K 2 CO 3  (3.87 g, 28.0 mmol) were added to toluene (60 mL), EtOH (15 mL), H 2 O (15 mL) in a three-necked round bottom flask, protected by nitrogen, and heated to reflux overnight. Heating was stopped and the reaction was cooled to room temperature. The reaction was suctioned under reduced pressure, and the solid was sequentially washed with water and methanol several times. The solid was recrystallized from toluene to obtain Compound 19 (6.7 g, 11.15 mmol) as a white solid in a yield of 79.7%. The product was identified as the target product with a molecular weight of 601. 
     The persons skilled in the art should know that the above preparation method is only an illustrative example, and the persons skilled in the art can obtain the structure of other compounds of the present invention by modifying the above preparation method. 
     Device Example 1 
     A glass substrate with an 80 nm thick of indium tin oxide (ITO) electrode was cleaned and subjected to UV ozone and oxygen plasma treatment. After the treatments, the substrate was dried in a glovebox to remove moisture, the substrate was then mounted on a substrate holder and loaded into a vacuum chamber. The organic layers specified below were deposited in sequence by thermal vacuum deposition on the ITO anode at a rate of 0.2-2 Å/s under a vacuum degree of around 10 −8  torr. Compound HI was used as the hole injection layer (HIL). Compound HT was used as the hole transporting layer (HTL). Compound H1 was used as the electron blocking layer (EBL). Then the Compound GD was then doped in Compound H1 and Compound H2 be co-deposited as the emitting layer (EML). Compound 16 of the present disclosure was used as the hole blocking layer (HBL). On HBL, Compound ET and 8-hydroxyquinolinolato-lithium (Liq) were co-deposition as an electron transporting layer (ETL). Finally, 1 nm-thick 8-hydroxyquinolinolato-lithium (Liq) was deposited as the electron injection layer (EIL) and 120 nm of Al was deposited as the cathode. Then, the device was transferred back to the glovebox and encapsulated with a glass lid and a moisture getter to complete the device. 
     Device Example 2 
     Device Example 2 was fabricated in the same manner as in Device Example 1, except that using Compound 19 of the present disclosure instead of Compound 16 of the present disclosure as the hole blocking layer (HBL). 
     Comparative Example 1 
     Comparative Example 1 was fabricated in the same manner as in Device Example 1, except that using Compound H2 instead of Compound 16 of the present disclosure as the hole blocking layer (HBL). 
     Comparative Example 2 
     Comparative Example 2 was fabricated in the same manner as in Device Example 1, except that using Compound H3 instead of Compound 16 of the present disclosure as the hole blocking layer (HBL). 
     Comparative Example 3 
     Comparative Example 3 was fabricated in the same manner as in Device Example 1, except that using compound H4 instead of Compound 16 of the present disclosure as the hole blocking layer (HBL). 
     Device Example 3 
     Device Example 3 was fabricated in the same manner as in Comparative Example 1, except that using Compound 16 instead of Compound H2 in the emitting layer (EML). 
     Comparative Example 4 
     Comparative Example 4 was fabricated in the same manner as in Comparative Example 1, except that using the Compound H3 instead of Compound H2 in the emitting layer (EML). 
     Comparative Example 5 
     Comparative Example 5 was fabricated in the same manner as in Comparative Example 1, except that using the Compound H4 instead of Compound H2 in the emitting layer (EML). 
     The detailed partial structures of devices and thicknesses are shown in the following table. In the layers in which more than one material were used, they were obtained by doping different compounds in the weight ratios described therein. 
     
       
         
           
               
             
               
                 TABLE 1 
               
             
            
               
                   
               
               
                 Device Structure 
               
            
           
           
               
               
               
               
               
               
               
            
               
                 Device ID 
                 HIL 
                 HTL 
                 EBL 
                 EML 
                 HBL 
                 ETL 
               
               
                   
               
               
                 Device 
                 Compound 
                 Compound 
                 Compound 
                 Compound 
                 Compound 
                 Compound 
               
               
                 Example 1 
                 HI (100 Å) 
                 HT (350 Å) 
                 H1 (50 Å) 
                 H1:Compound 
                 16 (100 Å) 
                 ET:Liq 
               
               
                   
                   
                   
                   
                 H2:Compound GD 
                   
                 (40:60) 
               
               
                   
                   
                   
                   
                 (45:45:10) 
                   
                 (350 Å) 
               
               
                   
                   
                   
                   
                 (400 Å) 
               
               
                 Device 
                 Compound 
                 Compound 
                 Compound 
                 Compound 
                 Compound 
                 Compound 
               
               
                 Example 2 
                 HI (100 Å) 
                 HT (350 Å) 
                 H1 (50 Å) 
                 H1:Compound 
                 19 (100 Å) 
                 ET:Liq 
               
               
                   
                   
                   
                   
                 H2:Compound GD 
                   
                 (40:60) 
               
               
                   
                   
                   
                   
                 (45:45:10) 
                   
                 (350 Å) 
               
               
                   
                   
                   
                   
                 (400 Å) 
               
               
                 Comparative 
                 Compound 
                 Compound 
                 Compound 
                 Compound 
                 Compound 
                 Compound 
               
               
                 Example 1 
                 HI (100 Å) 
                 HT (350 Å) 
                 H1 (50 Å) 
                 H1:Compound 
                 H2 (100 Å) 
                 ET:Liq 
               
               
                   
                   
                   
                   
                 H2:Compound GD 
                   
                 (40:60) 
               
               
                   
                   
                   
                   
                 (45:45:10) 
                   
                 (350 Å) 
               
               
                   
                   
                   
                   
                 (400 Å) 
               
               
                 Comparative 
                 Compound 
                 Compound 
                 Compound 
                 Compound 
                 Compound 
                 Compound 
               
               
                 Example 2 
                 HI (100 Å) 
                 HT (350 Å) 
                 H1 (50 Å) 
                 H1:Compound 
                 H3 (100 Å) 
                 ET:Liq 
               
               
                   
                   
                   
                   
                 H2:Compound GD 
                   
                 (40:60) 
               
               
                   
                   
                   
                   
                 (45:45:10) 
                   
                 (350 Å) 
               
               
                   
                   
                   
                   
                 (400 Å) 
               
               
                 Comparative 
                 Compound 
                 Compound 
                 Compound 
                 Compound 
                 Compound 
                 Compound 
               
               
                 Example 3 
                 HI 
                 HT (350 Å) 
                 H1 (50 Å) 
                 H1:Compound 
                 H4 (100 Å) 
                 ET:Liq 
               
               
                   
                 (100 Å) 
                   
                   
                 H2:Compound GD 
                   
                 (40:60) 
               
               
                   
                   
                   
                   
                 (45:45:10) 
                   
                 (350 Å) 
               
               
                   
                   
                   
                   
                 (400 Å) 
               
               
                 Device 
                 Compound 
                 Compound 
                 Compound 
                 Compound 
                 Compound 
                 Compound 
               
               
                 Example 3 
                 HI (100 Å) 
                 HT (350 Å) 
                 H1 (50 Å) 
                 H1:Compound 
                 H2 (100 Å) 
                 ET:Liq 
               
               
                   
                   
                   
                   
                 16:Compound GD 
                   
                 (40:60) 
               
               
                   
                   
                   
                   
                 (45:45:10) 
                   
                 (350 Å) 
               
               
                   
                   
                   
                   
                 (400 Å) 
               
               
                 Comparative 
                 Compound 
                 Compound 
                 Compound 
                 Compound 
                 Compound 
                 Compound 
               
               
                 Example 4 
                 HI (100 Å) 
                 HT (350 Å) 
                 H1 (50 Å) 
                 H1:Compound 
                 H2 (100 Å) 
                 ET:Liq 
               
               
                   
                   
                   
                   
                 H3:Compound GD 
                   
                 (40:60) 
               
               
                   
                   
                   
                   
                 (45:45:10) 
                   
                 (350 Å) 
               
               
                   
                   
                   
                   
                 (400 Å) 
               
               
                 Comparative 
                 Compound 
                 Compound 
                 Compound 
                 Compound 
                 Compound 
                 Compound 
               
               
                 Example 5 
                 HI (100 Å) 
                 HT (350 Å) 
                 H1 (50 Å) 
                 H1:Compound 
                 H2 (100 Å) 
                 ET: Liq 
               
               
                   
                   
                   
                   
                 H4:Compound GD 
                   
                 (40:60) 
               
               
                   
                   
                   
                   
                 (45:45:10) 
                   
                 (350 Å) 
               
               
                   
                   
                   
                   
                 (400 Å) 
               
               
                   
               
            
           
         
       
     
     Structure of the materials used in the devices are shown as below: 
     
       
         
         
             
             
         
       
     
     Device Examples 1-2 show the use of the material of the present disclosure in the hole blocking layer. At 1000 nits, the driving voltage of Device Example 1 was 2.78 V, the power efficiency was 103 lm/W, the maximum wavelength was 528 nm, and the CIE was 0.345, 0.627. The driving voltage of Example 2 was 2.81 V, the power efficiency was 103 lm/W, the maximum wavelength was 528 nm, and the CIE was 0.344, 0.628. The driving voltage of Comparative Example 1 was 2.94 V, the power efficiency was 95 lm/W, the maximum wavelength was 527 nm, and the CIE was 0.332 and 0.637. The driving voltage of Comparative Example 2 was 2.97 V, the power efficiency was 99 lm/W, the maximum wavelength was 528 nm, and the CIE was 0.344, 0.628. The driving voltage of Comparative Example 3 was 2.96 V, the power efficiency was 98 lm/W, the maximum wavelength was 528 nm, and the CIE was 0.342, 0.629. The above data shows that the emitting light of Device Examples 1-2 and Comparative Examples 1-3 are very close, but the power efficiency of Device Examples 1-2 are higher than that of Comparative Examples 1-3, and the driving voltage of Device Examples 1-2 are all lower than Examples 1-3. Especially in Device Example 1, the driving voltage is 2.78 V, which is very low. 
     Device Example 3 shows the use of the material of the present invention as a host material in the light emitting layer. The test was performed at a constant current of 15 mA/cm 2 . The efficiency and driving voltage of Device Example 3 and Comparative Example 1 and Comparative Examples 4-5 were basically equivalent, but the lifetime of LT97 were respectively 335 h, 310 h, 222.6 h, and 254.5 h. 
     The above data proves the structural characteristics of the compound of the present invention. The compound can be used as the hole blocking layer or a host material in the light-emitting layer by connecting a specific structure such as Formula 2 at a specific position of the carbazole ring in Formula 1, with specific selected substituents, which can improve the lifetime and efficiency of the device, reduce the driving voltage, and have important help to the industry. 
     It is understood that the various embodiments described herein are by way of example only, and are not intended to limit the scope of the disclosure. The present disclosure as claimed may therefore include variations from the particular examples and preferred embodiments described herein, as will be apparent to one of skill in the art. Many of the materials and structures described herein may be substituted with other materials and structures without deviating from the spirit of the present disclosure. It is understood that various theories as to why the disclosure works are not intended to be limiting.