Patent Publication Number: US-2023151235-A1

Title: Formulation of an organic functional material

Description:
TECHNICAL FIELD 
     The present invention relates to a formulation containing at least one organic functional material and a mixture of three different organic solvents, a first organic solvent A, a second organic solvent B and a third organic solvent C, characterized in that
         the first organic solvent A has a boiling point in the range from 250 to 350° C. and a viscosity of 10 mPas,   the second organic solvent B has a boiling point in the range from 200 to 350° C. and a viscosity in the range from 2 to 5 mPas, and   the third organic solvent C has a boiling point in the range from 100 to 300° C. and a viscosity of 3 mPas,   the solubility of the at least one organic functional material in the second organic solvent B is 5 g/l, and   the boiling point of the first organic solvent A is at least 10° C. higher than the boiling point of the second organic solvent B;       

     as well as to electroluminescent devices prepared by using these formulations. 
     BACKGROUND ART 
     Organic Light Emitting Devices (OLEDs) have been fabricated for a long time by vacuum deposition processes. Other techniques such as inkjet printing have been recently thoroughly investigated because of their advantages such as cost savings and scale-up possibilities. One of the main challenges in multi-layer printing is to identify the relevant parameters to obtain a homogeneous deposition of inks on the substrate. To trigger these parameters, such as surface tension, viscosity or boiling point, some additives can be added to the formulation. 
     Technical Problem and Object of the Invention 
     Many solvents have been proposed in organic electronic devices for inkjet printing. However, the number of important parameters playing a role during deposition and drying process makes the choice of the solvent very challenging. Thus, formulations containing organic semiconductors used for deposition by inkjet printing still need to be improved. One object of the present invention is to provide a formulation of an organic semiconductor which allows a controlled deposition to form organic semiconductor layers having good layer properties and efficient performance. A further object of the present invention is to provide a formulation of an organic semiconductor which allows an excellent film uniformity when deposited and dried on a substrate using e.g. an inkjet printing method thereby giving good layer properties and efficient performance. 
     In JP 201 5/1 91 792 A2 a solute is disclosed, composed of the constituent material or its precursor of the functional layer, dissolved in a first and second solvent, wherein the first solvent has a first solubility parameter and a first boiling point and the second solvent has a smaller second solubility parameter than the first solubility parameter and a second lower boiling point than the first boiling point, the first boiling point is 250° C. and the second boiling point is 170° C., the difference between the second and the first boiling point is 40° C. and the second solubility parameter is 9.0 (cal/cm 3 ) 1/2  or less. 
     In EP 2924083 A1 an ink for functional layer formation is disclosed, comprising a first component that is a solute, a second component that has a boiling point in the range from 280 to 350° C., is a good solvent for the first component, and is at least one type selected from the group consisting of an aromatic hydrocarbon including at least two aromatic rings, aromatic glycol ether, aliphatic glycol ether, aliphatic acetate, and aliphatic ester, and a third component that has a boiling point in the range from 200 to 300° C., is a good solvent for the first component, and is at least one type selected from the group consisting of an aromatic hydrocarbon, an aromatic ether, and an aliphatic ether, wherein the proportion of the second component in a mixed solvent including the second component and the third component is 10 wt % or greater. 
     In US 2013/256636 A1 a function layer ink for forming a functional layer by a liquid coating method is disclosed, wherein the function layer material contains a macromolecular or low-molecular-weight material, and a mixed solvent containing 0.1% by weight or more of solvent A having a viscosity in the range from 0.01 to 0.05 Pas, and solvent B having a viscosity of less than 0.01 Pas and a lower boiling point than the solvent A, the mixed solvent has a viscosity of less than 0.02 Pas and a boiling point in the range from 200 to 350° C. 
     In WO 2005/083814 A1, solutions of at least one organic semiconductor containing at least one high-molecular weight constituent in a solvent mixture of at least three different solvents A, B and C are disclosed. Solvents A and B are good solvents for the organic semiconductor, the solvent C is a bad solvent for the organic semiconductor. 
     In WO 2005/112145 A1 single-phase, liquid compositions (solutions) are disclosed comprising at least one organic semiconductor which comprises at least one high-molecular-weight component, and at least one organic solvent A which is a good solvent for the organic semiconductor, and at least one organic solvent B which is a poor solvent for the organic semi-conductor, characterised in that the following applies to the boiling points (b.p.) of solvents A and B: b.p.(A)&gt;b.p.(B). 
     Solution to Problem 
     The above objects of the present invention are solved by providing a formulation containing at least one organic functional material and a mixture of three different organic solvents, a first organic solvent A, a second organic solvent B and a third organic solvent C, characterized in that the first organic solvent A has a boiling point in the range from 250 to 350° C. and a viscosity of 10 mPas, the second organic solvent B has a boiling point in the range from 200 to 350° C. and a viscosity in the range from 2 to 5 mPas, and the third organic solvent C has a boiling point in the range from 100 to 300° C. and a viscosity of 3 mPas, the solubility of the at least one organic functional material in the second organic solvent B is 5 g/l, and the boiling point of the first organic solvent A is at least 10° C. higher than the boiling point of the second organic solvent B. 
     Advantageous Effects of Invention 
     The inventors have surprisingly found that the use of the formulation of the present invention allows an effective ink deposition to form uniform and well-defined organic layers of functional materials which have good layer properties and performance. 
    
    
     
       BRIEF DESCRIPTION OF DRAWINGS 
         FIG.  1    shows a typical layer structure of a device containing a substrate, an ITO anode, a hole-injection layer (HIL), a hole-transport layer (HTL), a green-emissive layer (G-EML), a hole blocking layer (HBL), an electron-transport layer (ETL) and an Al cathode. 
         FIGS.  2  to  7    show the film profiles of the films prepared in comparative example 1 as well as in working examples 2 to 6. 
     
    
    
     DESCRIPTION OF EMBODIMENTS 
     The present invention relates to a formulation containing at least one organic functional material and a mixture of three different organic solvents, a first organic solvent A, a second organic solvent B and a third organic solvent C, characterized in that the first organic solvent A has a boiling point in the range from 250 to 350° C. and a viscosity of 10 mPas, the second organic solvent B has a boiling point in the range from 200 to 350° C. and a viscosity in the range from 3 to 5 mPas and the third organic solvent C has a boiling point in the range from 100 to 300° C. and a viscosity of 3 mPas, the solubility of the at least one organic functional material in the second organic solvent B is 5 g/l, and the boiling point of the first organic solvent A is at least 10° C. higher than the boiling point of the second organic solvent B. 
     PREFERRED EMBODIMENTS 
     In a first preferred embodiment of the present invention, the formulation contains at least one organic functional material and a solvent mixture, wherein the solvent mixture consists of three different organic solvents, a first organic solvent A, a second organic solvent B and a third organic solvent C, characterized in that the first organic solvent A has a boiling point in the range from 250 to 350° C. and a viscosity of ≥10 mPas, the second organic solvent B has a boiling point in the range from 200 to 350° C. and a viscosity in the range from 2 to 5 mPas and the third organic solvent C has a boiling point in the range from 100 to 300° C. and a viscosity of ≤3 mPas, the solubility of the at least one organic functional material in the second organic solvent B is ≥5 g/l, and the boiling point of the first organic solvent A is at least 10° C. higher than the boiling point of the second organic solvent B. 
     The content of the first organic solvent A is from 0.1 to 50 vol.-%, more preferably from 0.1 to 25 vol.-%, more preferably from 0.1 to 10 vol.-% and most preferably from 0.1 to 5 vol.-%, based on the total amount of organic solvents in the formulation. 
     In a further preferred embodiment, the formulation is characterized in that the first organic solvent A is selected from naphthalene derivatives, partially hydrogenated naphthalene derivatives, e.g. tetrahydronaphthalene derivatives, fully hydrogenated naphthalene derivatives, e.g. decahydronaphthalene derivatives, indane derivatives and fully hydrogenated anthracene derivatives. 
     The expression “derivatives” as used above and below in the present application means that the core structure, e.g. the naphthalene core or the partially/fully hydrogenated naphthalene core, is at least mono- or polysubstituted by a substituent R. 
     R is identical or different at each occurrence, either
         a straight-chain alkyl group having from 1 to 12 carbon atoms or a branched or cyclic alkyl group having from 3 to 12 carbon atoms, in which one or more non-adjacent CH 2  groups may be replaced by —O—, —S—, —NR 1 —, —CO—O—, —O═O—, —CH═CH— or —C═C—, and in which one or more hydrogen atoms may be replaced by F or an aryl or heteroaryl group which has from 4 to 14 carbon atoms and may be substituted by one or more nonaromatic R 1  radicals, and a plurality of substituents R 1 , either on the same ring or on the two different rings, may together in turn form a mono- or polycyclic, aliphatic, aromatic or heteroaromatic ring system, which may be substituted by a plurality of substituents R 1 , or two R may together in turn form a mono- or polycyclic, aliphatic, aromatic or heteroaromatic rings system having from 4 to 14 carbon atoms, which may be substituted by a plurality of substituents R 1 , or   an aryl or heteroaryl group which has from 4 to 14 carbon atoms and may be substituted by one or more nonaromatic R 1  radicals, and a plurality of substituents R 1 , either on the same ring or on the two different rings, may together in turn form a mono- or polycyclic, aliphatic, aromatic or heteroaromatic ring system, which may be substituted by a plurality of substituents R 1 , or two R may together in turn form a mono- or polycyclic, aliphatic, aromatic or heteroaromatic rings system having from 4 to 14 carbon atoms, which may be substituted by a plurality of substituents R 1 .       

     In a more preferred embodiment, the formulation is characterized in that the first organic solvent A is selected from naphthalene derivatives, tetrahydronaphthalene derivatives and decahydronaphthalene derivatives. 
     If the first organic solvent A is a naphthalene derivative, it is preferably a solvent according to general formula (I) 
     
       
         
         
             
             
         
       
     
     wherein 
     R is either
         a straight-chain alkyl group having from 1 to 12 carbon atoms or a branched or cyclic alkyl group having from 3 to 12 carbon atoms, in which one or more non-adjacent CH 2  groups may be replaced by —O—, —S—, —NR 1 —, —CO—O—, —O═O—, —CH═CH— or —C≡C—, and in which one or more hydrogen atoms may be replaced by F or an aryl or heteroaryl group which has from 4 to 14 carbon atoms and may be substituted by one or more nonaromatic R 1  radicals, and a plurality of substituents R 1 , either on the same ring or on the two different rings, may together in turn form a mono- or polycyclic, aliphatic, aromatic or heteroaromatic ring system, which may be substituted by a plurality of substituents R 1 , or   an aryl or heteroaryl group which has from 4 to 14 carbon atoms and may be substituted by one or more nonaromatic R 1  radicals, and a plurality of substituents R 1 , either on the same ring or on the two different rings, may together in turn form a mono- or polycyclic, aliphatic, aromatic or heteroaromatic ring system, which may be substituted by a plurality of substituents R 1 , or two R may together in turn form a mono- or polycyclic, aliphatic, aromatic or heteroaromatic rings system having from 4 to 14 carbon atoms, which may be substituted by a plurality of substituents R 1 , and       

     R 1  is identical or different at each instance, and is a straight-chain alkyl or alkoxy group having from 1 to 12 carbon atoms or a branched or cyclic alkyl or alkoxy group having from 3 to 20 carbon atoms, in which one or more non-adjacent CH 2  groups may be replaced by —O—, —S—, —CO—O—, —O═O—, —CH═CH— or —C≡C—. 
     Preferably, R is a cyclic alkyl group having from 6 to 10 carbon atoms, in which one or more non-adjacent CH 2  groups may be replaced by —O—, —S—, —NR 1 —, —CO—O—, —O═O—, —CH═CH— or —C≡C—, or an aryl or heteroaryl group which has from 6 to 10 carbon atoms and may be substituted by one or more substituents R 1 , and a plurality of substituents R 1 , either on the same ring or on the two different rings, may together in turn form a mono- or polycyclic, aliphatic, aromatic or heteroaromatic ring system, which may be substituted by a plurality of substituents R 1 . 
     In a first most preferred embodiment, the naphthalene derivative is either 1-cyclohexyl-naphthalene or 1-phenyl-naphthalene. 
     If the first organic solvent A is a tetrahydronaphthalene derivative, it is preferably a solvent according to general formula (II) or (III) 
     
       
         
         
             
             
         
       
     
     wherein R can have the meanings as given above with respect to formula (I). 
     In a second most preferred embodiment, the tetrahydronaphthalene derivative is 1-phenyl-1,2,3,4-tetrahydronaphthalene. 
     If the first organic solvent A is a decahydronaphthalene derivative, it is preferably a solvent according to general formula (IV) 
     
       
         
         
             
             
         
       
     
     wherein R can have the meanings as given above with respect to formula (I). 
     In a third most preferred embodiment, the decahydronaphthalene derivative is either 1-cyclohexyl-decahydronaphthalene or 1-phenyl-decahydronaphthalene. 
     The first organic solvent A has a boiling point in the range from 250 to 350° C., preferably in the range from 260 to 340° C. and most preferably in the range from 270 to 330° C. 
     The first organic solvent A has a melting point preferably below 25° C., which means that the first organic solvent A is liquid at room temperature. 
     The viscosity of the first organic solvent A is 10 mPas, preferably 15 mPas, more preferably 25 mPas and most preferably 50 mPas. 
     The at least one organic functional material has a solubility in the first organic solvent A which is 5 g/l. 
     Examples of preferred first organic solvents A and their boiling points (BP) and melting points (MP) are shown in the following Table 1. 
     
       
         
           
               
             
               
                 TABLE 1 
               
             
            
               
                   
               
               
                 Preferred first organic solvents A and their boiling  
               
               
                 points (BP) and melting points (MP). 
               
            
           
           
               
               
               
               
            
               
                   
                 Solvent A 
                 BP (° C.) 
                 MP(° C.) 
               
               
                   
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 324 
                 Liquid at RT 
               
               
                   
                   
               
               
                   
                 CAS 605-02-7 
                   
                   
               
               
                   
                 1-Phenylnaphthalene 
                   
                   
               
               
                   
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 301 
                 Liquid at RT 
               
               
                   
                   
               
               
                   
                 CAS 858198-92-2 
                   
                   
               
               
                   
                 1-phenyl decahydronaphthalene 
                   
                   
               
               
                   
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 301 
                 Liquid at RT 
               
               
                   
                   
               
               
                   
                 CAS 22236-62-0 
                   
                   
               
               
                   
                 1-cyclohexyl decahydronaphthalene 
                   
                   
               
               
                   
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 300 
                 Liquid at RT 
               
               
                   
                   
               
               
                   
                 CAS 3042-69-1 
                   
                   
               
               
                   
                 Cycyclohexylaphthalene 
                   
                   
               
               
                   
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 341  
                 Liquid at RT 
               
               
                   
                   
               
               
                   
                 CAS 90501-15-8  
                   
                   
               
               
                   
                 5-cyclohexyl-1,2,3,4-  
                   
                   
               
               
                   
                 tetrahydro-naphthalene 
                   
                   
               
               
                   
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 322 
                 Liquid at RT 
               
               
                   
                   
               
               
                   
                 CAS 80039-48-1 
                   
                   
               
               
                   
                 1-cyclohexyl-1,2,3,4-  
                   
                   
               
               
                   
                 tetrahydro-naphthalene 
                   
                   
               
               
                   
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 320 
                 Liquid at RT 
               
               
                   
                   
               
               
                   
                 CAS 3018-20-0 
                   
                   
               
               
                   
                 1-phenyl-1,2,3,4- 
                   
                   
               
               
                   
                 tetrahydro-naphthalene 
               
               
                   
                   
               
            
           
         
       
     
     The formulations of the present application comprise a second organic solvent B which is different from the first organic solvent A and the third organic solvent C. The second organic solvent B is employed together with the first organic solvent A and the third organic solvent C. 
     The content of the second organic solvent B is preferably in the range from 20 to 85 vol.-%, more preferably in the range from 30 to 80 vol.-%, and most preferably in the range from 40 to 75 vol.-%, based on the total amount of organic solvents in the formulation. 
     Suitable second organic solvents B are preferably organic solvents which include inter alia, ketones, ethers, esters, amides such as di-C 1-2 -alkylformamides, sulfur compounds, nitro compounds, hydrocarbons, halogenated hydrocarbons (e.g. chlorinated hydrocarbons), aromatic or heteroaromatic hydrocarbons (e.g. naphthalene derivatives) and halogenated aromatic or heteroaromatic hydrocarbons. 
     Preferably, the second organic solvent B can be chosen from one of the following groups: substituted and non-substituted aromatic or linear ethers such as 3-phenoxytoluene or anisole; substituted or non-substituted arene derivatives such as cyclohexylbenzene, substituted or non-substituted indanes such as hexamethylindane; substituted and non-substituted aromatic or linear ketones such as dicyclohexylmethanone; substituted and non-substituted heterocycles such as pyrrolidinones, pyridines, pyrazines; other fluorinated or chlorinated aromatic hydrocarbons, substituted or non-substituted naphthalenes such as alkyl substituted naphthalenes, such as 1-ethyl naphthalene. 
     Particularly preferred second organic solvents B are, for example, 1-ethyl-naphthalene, 2-ethylnaphthalene, 2-propylnaphthalene, 2-(1-methylethyl)-naphthalene, 1-(1-methylethyl)-naphthalene, 2-butylnaphthalene, 1,6-dimethylnaphthalene, 2,2′-dimethylbiphenyl, 3,3″-dimethylbiphenyl, 1-acetylnaphthalene,1,2,3,4-tetramethylbenzene, 1,2,3,5-tetramethyl-benzene, 1,2,4,5-tetramethylbenzene, 1,2,4-trichlorobenzene, 1,2-dihydronaphthalene, 1,2-dimethylnaphthalene, 1,3-benzodioxole, 1,3-diisopropylbenzene, 1,3-dimethylnaphthalene, 1,4-benzodioxane, 1,4-diisopropylbenzene, 1,4-dimethylnaphthalene, 1,5-dimethyltetralin, 1-benzothiophene, thianaphthalene, 1-bromonaphthalene, 1-chloro-methylnaphthalene, 1-methoxynaphthalene, 1-methylnaphthalene, 2-bromo-3-bromomethylnaphthalene, 2-bromomethyl-naphthalene, 2-bromonaphthalene, 2-ethoxynaphthalene, 2-isopropyl-anisole, 3,5-dimethyl-anisole, 5-methoxyindane, 5-methoxyindole, 5-tert-butyl-m-xylene, 6-methylquinoline, 8-methylquinoline, acetophenone, benzothiazole, benzylacetate, butylphenylether, cyclohexylbenzene, decahydronaphthol, dimethoxytoluene, 3-phenoxytoluene, diphenylether, propiophenone, hexylbenzene, hexamethylindane, isochromane, phenylacetate, propio-phenone, veratrol, pyrrolidinone, N,N-dibutylaniline, cyclohexyl hexanoate, menthyl isovalerate, dicyclohexyl methanone, ethyl laurate, ethyl decanoate. 
     The second organic solvent B has a boiling point in the range from 200 to 350° C., preferably in the range from 225 to 325° C. and most preferably in the range from 250 to 300° C. 
     The viscosity of the second organic solvent B is in the range from 2 to 5 mPas, preferably in the range from 2.5 to 5 mPas, more preferably in the range from 3 to 5 mPas and most preferably in the range from &gt;3 to 5 mPas. 
     The at least one organic functional material has a solubility in the second organic solvent B which is 5 g/l, preferably 10 g/l. 
     Examples of preferred second organic solvents B and their boiling points (BP) and melting points (MP) are shown in the following Table 2. 
     
       
         
           
               
             
               
                 TABLE 2 
               
             
            
               
                   
               
               
                 Preferred second organic solvents B and their  
               
               
                 boiling points (BP) and melting points (MP). 
               
            
           
           
               
               
               
            
               
                 Solvent B 
                 BP (° C.) 
                 MP(° C.) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 271 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 3586-14-9 
                   
                   
               
               
                 3-Phenoxytoluene 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 249 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 136-60-7 
                   
                   
               
               
                 Butylbenzoate 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 239 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 827-52-1 
                   
                   
               
               
                 Cyclohexylbenzene 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 258 
                 −15 
               
               
                   
               
               
                 CAS 1127-76-0 
                   
                   
               
               
                 1-Ethylnaphthalene 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 223 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 7774-44-9 
                   
                   
               
               
                 Cyclohexylisovalerate 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 270 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 16409-46-4 
                   
                   
               
               
                 Menthylisovalerate 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 255 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 6243-10-3 
                   
                   
               
               
                 Cyclohexylhexanoate 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 237 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 103-93-5 
                   
                   
               
               
                 p-Tolylisobutyrate 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 259 
                 18 
               
               
                   
               
               
                 CAS 605-39-0 
                   
                   
               
               
                 2,2′-Dimethylbiphenyl 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 267 
                 −18 
               
               
                   
               
               
                 CAS 571-58-4 
                   
                   
               
               
                 1,4-Dimethylnaphthalene 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 279 
                 5-7 
               
               
                   
               
               
                 CAS 612-75-9 
                   
                   
               
               
                 3,3′-Dimethylbipheny 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 302 
                 10.5 
               
               
                   
               
               
                 CAS 941-98-0 
                   
                   
               
               
                 1-Acetylnaphthalene 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 275 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 613-29-6 
                   
                   
               
               
                 N, N-dibutylaniline 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 266 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 119-60-8 
                   
                   
               
               
                 Dicyclohexyl methanone 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 232 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 94-08-6 
                   
                   
               
               
                 Ethyl p-toluate 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 211 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 2315-68-6 
                   
                   
               
               
                 Propyl benzoate 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 240 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 32357-25-8 
                   
                   
               
               
                 Propyl 2-methylbenzoate 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 268 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 6640-77-3 
                   
                   
               
               
                 Butyl m-toluate 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 227 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 87-24-1 
                   
                   
               
               
                 Ethyl o-toluate 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 234 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 120-33-2 
                   
                   
               
               
                 Ethyl m-toluate 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 207 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 119-64-2 
                   
                   
               
               
                 Tetralin 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 255 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 643-58-3 
                   
                   
               
               
                 2-methyl biphenyl 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 297 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 20115-23-5 
                   
                   
               
               
                 Phenyl pentanoate 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 225 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 4346-18-3 
                   
                   
               
               
                 Phenyl butanoate 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 244 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 14617-92-6 
                   
                   
               
               
                 4-methylphenyl butanoate 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 243 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 90-12-0 
                   
                   
               
               
                 1-methyl naphthalene 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 229 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 1680-51-9 
                   
                   
               
               
                 6-methyltetralin 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 234 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 2809-64-5 
                   
                   
               
               
                 5-methyltetralin 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 239 
                 — 
               
               
                   
               
               
                 CAS 21564-91-0 
                   
                   
               
               
                 1,5-dimethyltetralin 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 244 
                 — 
               
               
                   
               
               
                 CAS 22531-20-0 
                   
                   
               
               
                 6-ethyltetralin 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 258 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 939-27-5 
                   
                   
               
               
                 2-ethyl naphthalene 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 256 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 622-08-2 
                   
                   
               
               
                 2-(phenylmethoxy) ethanol 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 221 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 80-73-9 
                   
                   
               
               
                 1,3-dimethyl-2-imidazolidinone 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 212 
                 −34 
               
               
                   
               
               
                 CAS 93-89-0 
                   
                   
               
               
                 Ethyl benzoate 
               
               
                   
               
            
           
         
       
     
     The formulations of the present application comprise a third organic solvent C which is different from the first organic solvent A and the second organic solvent B. The third organic solvent C is employed together with the first organic solvent A and the second organic solvent B. 
     The content of the third organic solvent C is preferably in the range from 10 to 70 vol.-%, more preferably in the range from 15 to 60 vol.-%, and most preferably in the range from 20 to 50 vol.-%, based on the total amount of organic solvents in the formulation. 
     Suitable third organic solvents C are preferably organic solvents which include inter alia, ketones, substituted and non-substituted aromatic, alicyclic or linear ethers, esters, amides, aromatic amines, sulfur compounds, nitro compounds, hydrocarbons, halogenated hydrocarbons (e.g. chlorinated hydrocarbons), aromatic or heteroaromatic hydrocarbons (e.g. naphthalene derivatives, pyrrolidinones, pyridines, pyrazines), indane derivatives and halogenated aromatic or heteroaromatic hydrocarbons. 
     Preferably, the third organic solvent C can be chosen from one of the following groups: aliphatic hydrocarbons, alkylbenzenes, cycloalkyl-benzenes, aromatic ethers, aromatic and non-aromatic esters, cyclic esters. 
     The third organic solvent C has a boiling point in the range from 100 to 300° C., preferably in the range from 125 to 275° C. and most preferably in the range from 150 to 250° C. Furthermore, the boiling point of the third organic solvent C is at least 10° C. lower, preferably at least 20° C. lower and more preferably at least 30° C. lower than the boiling point of the second organic solvent B. 
     The viscosity of the third organic solvent C is 3 mPas, preferably 2.5 mPas and more preferably 2 mPas. 
     The at least one organic functional material has a solubility in the second organic solvent B which is 5 g/l, preferably 10 g/l. 
     Examples of particular preferred third organic solvents C and their boiling points (BP) and melting points (MP) are shown in the following Table 3. 
     
       
         
           
               
             
               
                 TABLE 3 
               
             
            
               
                   
               
               
                 Preferred third organic solvents C and their boiling  
               
               
                 points (BP) and melting points (MP). 
               
            
           
           
               
               
               
            
               
                 Solvent C 
                 BP (° C.) 
                 MP(° C.) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 216 
                 −10 
               
               
                   
               
               
                 CAS 112-40-3 
                   
                   
               
               
                 Dodecane 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 174 
                 −29 
               
               
                   
               
               
                 CAS 124-18-5 
                   
                   
               
               
                 Decane 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 261 
                 −36 
               
               
                   
               
               
                 CAS 2189-60-8 
                   
                   
               
               
                 1-Phenyloctane 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 230 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 1078-71-3 
                   
                   
               
               
                 1-Phenylheptane 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 205 
                 −75 
               
               
                   
               
               
                 CAS 538-68-1 
                   
                   
               
               
                 Pentylbenzene 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 175 
                 −50 
               
               
                   
               
               
                 CAS 104-93-8 
                   
                   
               
               
                 4-Methylanisole 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 200 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 4685-47-6 
                   
                   
               
               
                 3,4-Dimethylanisole 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 198 
                 −12 
               
               
                   
               
               
                 CAS 93-58-3 
                   
                   
               
               
                 Methylbenzoate 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 212 
                 −34 
               
               
                   
               
               
                 CAS 93-89-0 
                   
                   
               
               
                 Ethylbenzoate 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 206 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 106-32-1 
                   
                   
               
               
                 Ethyl octanoate 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 227 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 87-24-1 
                   
                   
               
               
                 Ethyl o-Toluate 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 235 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 94-08-6 
                   
                   
               
               
                 Ethyl p-Toluate 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 237 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 103-93-5 
                   
                   
               
               
                 Isobutyric acid p-tolyl ester 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 240 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 108-32-7 
                   
                   
               
               
                 Propylene carbonate 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 240 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 827-52-1 
                   
                   
               
               
                 Cyclohexylbenzene 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 250 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 136-60-7 
                   
                   
               
               
                 Butylbenzoate 
                   
                   
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 211 
                 Liquid at RT 
               
               
                   
               
               
                 CAS 7382-32-3 
                   
                   
               
               
                 Diethylene Glycol Butyl Methyl Ether 
               
               
                   
               
            
           
         
       
     
     In a second preferred embodiment of the present invention, the formulation does not contain a solvent comprising a group, which is capable of receiving or giving a hydrogen bonding. This means, that in a preferred embodiment, the formulation of the present invention is free of solvents, comprising groups which are capable of receiving or giving a hydrogen bonding. 
     The content of the at least one organic functional material in the formulation is in the range from 0.001 to 20 weight-%, preferably in the range from 0.01 to 10 weight-%, more preferably in the range from 0.1 to 5 weight-% and most preferably in the range from 0.3 to 5 weight-%, based on the total weight of the formulation. 
     Furthermore, the formulation of the present invention has a viscosity preferably in the range from 0.8 to 50 mPas, more preferably in the range from 1 to 40 mPas, and most preferably in the range from 2 to 15 mPas. 
     The viscosity of the formulations and solvents according to the present invention is measured with a 1° cone-plate rotational rheometer of the type Discovery AR3 (Thermo Scientific). The equipment allows a precise control of the temperature and sheer rate. The measurement of the viscosity is carried out at a temperature of 25.0° C. (+/−0.2° C.) and a sheer rate of 500 s −1 . Each sample is measured three times and the obtained measured values are averaged. 
     The formulation of the present invention has a surface tension preferably in the range from 10 to 70 mN/m, more preferably in the range from 15 to 50 mN/m and most preferably in the range from 20 to 40 mN/m. 
     Preferably, the organic solvent blend comprises a surface tension in the range from 10 to 70 mN/m, more preferably in the range from 15 to 50 mN/m and most preferably in the range from 20 to 40 mN/m. 
     The surface tension can be measured using a FTA (First Ten Angstrom) 1000 contact angle goniometer at 20° C. Details of the method are available from First Ten Angstrom as published by Roger P. Woodward, Ph.D. “Surface Tension Measurements Using the Drop Shape Method”. Preferably, the pendant drop method can be used to determine the surface tension. This measurement technique dispenses a drop from a needle in a bulk liquid or gaseous phase. The shape of the drop results from the relationship between the surface-tension, gravity and density differences. Using the pendant drop method, the surface tension is calculated from the shadow image of a pendant drop using http://www.kruss.de/services/education-theory/glossary/drop-shape-analysis. A commonly used and commercially available high precision drop shape analysis tool, namely FTA1000 from First Ten Ångstrom, was used to perform all surface tension measurements. The surface tension is determined by the software FTA1000. All measurements were performed at room temperature which is in the range between 20° C. and 25° C. The standard operating procedure includes the determination of the surface tension of each formulation using a fresh disposable drop dispensing system (syringe and needle). Each drop is measured over the duration of one minute with sixty measurements which are later on averaged. For each formulation three drops are measured. The final value is averaged over said measurements. The tool is regularly cross-checked against various liquids having well known surface tensions. 
     The formulation according to the present invention comprises at least one organic functional material which can be employed for the production of functional layers of electronic devices. Functional materials are generally the organic materials which are introduced between the anode and the cathode of an electronic device. 
     The term organic functional material denotes, inter alia, organic conductors, organic semiconductors, organic fluorescent compounds, organic phosphorescent compounds, organic light-absorbent compounds, organic light-sensitive compounds, organic photosensitisation agents and other organic photoactive compounds. The term organic functional material furthermore encompasses organometallic complexes of transition metals, rare earths, lanthanides and actinides. 
     The organic functional material is preferably an organic semiconductor selected from the group consisting of fluorescent emitters, phosphorescent emitters, host materials, matrix materials, exciton-blocking materials, electron-transport materials, electron-injection materials, hole-transport materials, hole-injection materials, n-dopants, p-dopants, wide-band-gap materials, electron-blocking materials and hole-blocking materials. 
     Preferred embodiments of organic functional materials are disclosed in detail in WO 2011/076314 A1, where this document is incorporated into the present application by way of reference. 
     In a more preferred embodiment, the organic semiconductor is an emitting material selected from the group consisting of fluorescent emitters and phosphorescent emitters. 
     The organic functional material can be a compound having a low molecular weight, a polymer, an oligomer or a dendrimer, where the organic functional material may also be in the form of a mixture. Thus, the formulations according to the present invention may comprise two or more different compounds having a low molecular weight, one compound having a low molecular weight and one polymer or two polymers (blend). 
     If the organic functional material is a low molecular weight compound, it has preferably a molecular weight of 3,000 g/mol, more preferably of 2,000 g/mol and most preferably of 1,000 g/mol. 
     If the organic functional material is a polymeric compound, it has preferably a molecular weight M w  of 10,000 g/mol, more preferably of 20,000 g/mol and most preferably of 40,000 g/mol. 
     The molecular weight M w  of the polymers here is preferably in the range from 10,000 to 2,000,000 g/mol, more preferably in the range from 20,000 to 1,000,000 g/mol and most preferably in the range from 40,000 to 300,000 g/mol. The molecular weight M w  is determined by means of GPC (=gel permeation chromatography) against an internal polystyrene standard. 
     In a third preferred embodiment of the present invention, the at least one organic functional material in the formulation of the present application, is a low molecular weight compound. Preferably, all organic functional materials in the formulation of the present application are low molecular weight compounds. 
     In a further preferred embodiment, the at least one emitting material is a mixture of two or more different compounds having a low molecular weight. 
     Organic functional materials are frequently described via the properties of the frontier orbitals, which are described in greater detail below. Molecular orbitals, in particular also the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO), their energy levels and the energy of the lowest triplet state T 1  or of the lowest excited singlet state Si of the materials can be estimated based on quantum-chemical calculations. In order to calculate these properties for organic substances without metals, firstly a geometry optimisation is carried out using the “Ground State/Semi-empirical/Default Spin/AM1/Charge 0/Spin Singlet” method. An energy calculation is subsequently carried out on the basis of the optimised geometry. The “TD-SCF/DFT/Default Spin/B3PW91” method with the “6-31G(d)” base set (charge 0, spin singlet) is used here. For metal-containing compounds, the geometry is optimised via the “Ground State/Hartree-Fock/Default Spin/LanL2 MB/Charge 0/Spin Singlet” method. The energy calculation is carried out analogously to the above-described method for the organic substances, with the difference that the “LanL2DZ” base set is used for the metal atom and the “6-31G(d)” base set is used for the ligands. The energy calculation gives the HOMO energy level HEh or LUMO energy level LEh in hartree units. The HOMO and LUMO energy levels in electron volts calibrated with reference to cyclic voltammetry measurements are determined therefrom as follows: 
       HOMO(eV)=(( HEh* 27.212)−0.9899)/1.1206
 
       LUMO(eV)=(( LEh* 27.212)−2.0041)/1.385
 
     For the purposes of the present application, these values are to be regarded as HOMO and LUMO energy levels respectively of the materials. 
     The lowest triplet state Ti is defined as the energy of the triplet state having the lowest energy which arises from the quantum-chemical calculation described. 
     The lowest excited singlet state Si is defined as the energy of the excited singlet state having the lowest energy which arises from the quantum-chemical calculation described. 
     The method described herein is independent of the software package used and always gives the same results. Examples of frequently used programs for this purpose are “Gaussian09W” (Gaussian Inc.) and Q-Chem 4.1 (Q-Chem, Inc.). 
     Compounds having hole-injection properties, also called hole-injection materials herein, simplify or facilitate the transfer of holes, i.e. positive charges, from the anode into an organic layer. In general, a hole-injection material has an HOMO level which is in the region of or above the level of the anode, i.e. in general is at least −5.3 eV. 
     Compounds having hole-transport properties, also called hole-transport materials herein, are capable of transporting holes, i.e. positive charges, which are generally injected from the anode or an adjacent layer, for example a hole-injection layer. A hole-transport material generally has a high HOMO level of preferably at least −5.4 eV. Depending on the structure of an electronic device, it may also be possible to employ a hole-transport material as hole-injection material. 
     The preferred compounds which have hole-injection and/or hole-transport properties include, for example, triarylamines, benzidines, tetraaryl-para-phenylenediamines, triarylphosphines, phenothiazines, phenoxazines, dihydrophenazines, thianthrenes, dibenzo-para-dioxins, phenoxathiynes, carbazoles, azulenes, thiophenes, pyrroles and furans as well as their derivatives and further O-, S- or N-containing heterocycles having a high HOMO (HOMO=highest occupied molecular orbital). 
     Compounds which have electron-injection and/or electron-transport properties are, for example, pyridines, pyrimidines, pyridazines, pyrazines, oxadiazoles, quinolines, quinoxalines, anthracenes, benzanthracenes, pyrenes, perylenes, benzimidazoles, triazines, ketones, phosphine oxides and phenazines and derivatives thereof, but also triarylboranes and further O—, S- or N-containing heterocycles having a low LUMO (LUMO=lowest unoccupied molecular orbital). 
     The formulations of the present invention preferably comprise emitters. The term emitter denotes a material which, after excitation, which can take place by transfer of any type of energy, allows a radiative transition into a ground state with emission of light. In general, two classes of emitter are known, namely fluorescent and phosphorescent emitters. The term fluorescent emitter denotes materials or compounds in which a radiative transition from an excited singlet state into the ground state takes place. The term phosphorescent emitter preferably denotes luminescent materials or compounds which contain transition metals. 
     Emitters are frequently also called dopants if the dopants cause the properties described above in a system. A dopant in a system comprising a matrix material and a dopant is taken to mean the component whose proportion in the mixture is the smaller. Correspondingly, a matrix material in a system comprising a matrix material and a dopant is taken to mean the component whose proportion in the mixture is the greater. Accordingly, the term phosphorescent emitter can also be taken to mean, for example, phosphorescent dopant. 
     Compounds which are able to emit light include, inter alia, fluorescent emitters and phosphorescent emitters. These include, inter alia, compounds containing stilbene, stilbenamine, styrylamine, coumarine, rubrene, rhodamine, thiazole, thiadiazole, cyanine, thiophene, paraphenylene, perylene, phtalocyanine, porphyrin, ketone, quinoline, imine, anthracene and/or pyrene structures. Particular preference is given to compounds which are able to emit light from the triplet state with high efficiency, even at room temperature, i.e. exhibit electrophosphorescence instead of electro-fluorescence, which frequently causes an increase in the energy efficiency. Suitable for this purpose are firstly compounds which contain heavy atoms having an atomic number of greater than 36. Preference is given to compounds which contain d- or f-transition metals which satisfy the above-mentioned condition. Particular preference is given here to corresponding compounds which contain elements from group 8 to 10 (Ru, Os, Rh, Ir, Pd, Pt). Suitable functional compounds here are, for example, various complexes, as described, for example, in WO 02/068435 A1, WO 02/081488 A1, EP 1239526 A2 and WO 2004/026886 A2. 
     Preferred compounds which can serve as fluorescent emitters are described by way of example below. Preferred fluorescent emitters are selected from the class of the monostyrylamines, the distyrylamines, the tristyrylamines, the tetrastyrylamines, the styrylphosphines, the styryl ethers and the arylamines. 
     A monostyrylamine is taken to mean a compound which contains one substituted or unsubstituted styryl group and at least one, preferably aromatic, amine. A distyrylamine is taken to mean a compound which contains two substituted or unsubstituted styryl groups and at least one, preferably aromatic, amine. A tristyrylamine is taken to mean a compound which contains three substituted or unsubstituted styryl groups and at least one, preferably aromatic, amine. A tetrastyrylamine is taken to mean a compound which contains four substituted or unsubstituted styryl groups and at least one, preferably aromatic, amine. The styryl groups are particularly preferably stilbenes, which may also be further substituted. Corresponding phosphines and ethers are defined analogously to the amines. An arylamine or an aromatic amine in the sense of the present invention is taken to mean a compound which contains three substituted or unsubstituted aromatic or heteroaromatic ring systems bonded directly to the nitrogen. At least one of these aromatic or heteroaromatic ring systems is preferably a condensed ring system, preferably having at least 14 aromatic ring atoms. Preferred examples thereof are aromatic anthracenamines, aromatic anthracene-diamines, aromatic pyrenamines, aromatic pyrenediamines, aromatic chrysenamines or aromatic chrysenediamines. An aromatic anthracen-amine is taken to mean a compound in which one diarylamino group is bonded directly to an anthracene group, preferably in the 9-position. An aromatic anthracenediamine is taken to mean a compound in which two diarylamino groups are bonded directly to an anthracene group, preferably in the 2,6- or 9,10-position. Aromatic pyrenamines, pyrenediamines, chrysenamines and chrysenediamines are defined analogously thereto, where the diarylamino groups are preferably bonded to the pyrene in the 1-position or in the 1,6-position. 
     Further preferred fluorescent emitters are selected from indenofluorenamines or indenofluorenediamines, which are described, inter alia, in WO 2006/122630; benzoindenofluorenamines or benzoindenofluorenediamines, which are described, inter alia, in WO 2008/006449; and dibenzo-indenofluorenamines or dibenzoindenofluorenediamines, which are described, inter alia, in WO 2007/140847. 
     Examples of compounds from the class of the styrylamines which can be employed as fluorescent emitters are substituted or unsubstituted tristilbenamines or the dopants described in WO 2006/000388, WO 2006/058737, WO 2006/000389, WO 2007/065549 and WO 2007/115610. Distyryl-benzene and distyrylbiphenyl derivatives are described in U.S. Pat. No. 5,121,029. Further styrylamines can be found in US 2007/0122656 A1. 
     Particularly preferred styrylamine compounds are the compounds of the formula EM-1 described in U.S. Pat. No. 7,250,532 B2 and the compounds of the formula EM-2 described in DE 10 2005 058557 A1: 
     
       
         
         
             
             
         
       
     
     Particularly preferred triarylamine compounds are compounds of the formulae EM-3 to EM-15 disclosed in CN 1583691 A, JP 08/053397 A and U.S. Pat. No. 6,251,531 B1, EP 1957606 A1, US 2008/0113101 A1, US 2006/210830 A, WO 2008/006449 and DE 102008035413 and derivatives thereof: 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     Further preferred compounds which can be employed as fluorescent emitters are selected from derivatives of naphthalene, anthracene, tetracene, benzanthracene, benzophenanthrene (DE 10 2009 005746), fluorene, fluoranthene, periflanthene, indenoperylene, phenanthrene, perylene (US 2007/0252517 A1), pyrene, chrysene, decacyclene, coronene, tetra-phenylcyclopentadiene, pentaphenylcyclopentadiene, fluorene, spiro-fluorene, rubrene, coumarine (U.S. Pat. Nos. 4,769,292, 6,020,078, US 2007/0252517 A1), pyran, oxazole, benzoxazole, benzothiazole, benzimidazole, pyrazine, cinnamic acid esters, diketopyrrolopyrrole, acridone and quinacridone (US 2007/0252517 A1). 
     Of the anthracene compounds, particular preference is given to 9,10-substituted anthracenes, such as, for example, 9,10-diphenylanthracene and 9,10-bis(phenylethynyl)anthracene. 1,4-Bis(9′-ethynylanthracenyl)-benzene is also a preferred dopant. 
     Preference is likewise given to derivatives of rubrene, coumarine, rhodamine, quinacridone, such as, for example, DMQA (═N,N′-dimethylquinacridone), dicyanomethylenepyran, such as, for example, DCM (=4-(dicyano-ethylene)-6-(4-dimethylaminostyryl-2-methyl)-4H-pyran), thiopyran, poly-methine, pyrylium and thiapyrylium salts, periflanthene and indenoperylene. 
     Blue fluorescent emitters are preferably polyaromatic compounds, such as, for example, 9,10-di(2-naphthylanthracene) and other anthracene derivatives, derivatives of tetracene, xanthene, perylene, such as, for example, 2,5,8,11-tetra-t-butylperylene, phenylene, for example 4,4′-bis(9-ethyl-3-carbazovinylene)-1,1′-biphenyl, fluorene, fluoranthene, arylpyrenes (US 2006/0222886 A1), arylenevinylenes (U.S. Pat. Nos. 5,121,029, 5,130,603), bis-(azinyl)imine-boron compounds (US 2007/0092753 A1), bis(azinyl)methene compounds and carbostyryl compounds. 
     Further preferred blue fluorescent emitters are described in C. H. Chen et al.: “Recent developments in organic electroluminescent materials” Macro-mol. Symp. 125, (1997) 1-48 and “Recent progress of molecular organic electroluminescent materials and devices” Mat. Sci. and Eng. R, 39 (2002), 
     Further preferred blue-fluorescent emitters are the hydrocarbons of the following formula (1) as disclosed in WO 2010/012328 A1. 
     
       
         
         
             
             
         
       
     
     where the following applies to the symbols and indices used:
     Ar 1 , Ar 2 , Ar 3  are on each occurrence, identically or differently, an aryl or heteroaryl group having 5 to 30 aromatic ring atoms, which may be substituted by one or more radicals R 1 , with the proviso that Ar 2  does not stand for anthracene, naphthacene or pentacene;   X is on each occurrence, identically or differently, a group selected from BR 2 , C(R 2 ) 2 , Si(R 2 ) 2 , C═O, C═NR 2 , C═C(R 2 ) 2 O, S, S═O, SO 2 , NR 2 , PR 2 , P(═O)R 2  and P(═S)R 2 ;   R 1 , R 2  are on each occurrence, identically or differently, H, D, F, Cl, Br, I, N(Ar 4 ) 2 , C(═O)Ar 4 , P(═O)(Ar 4 ) 2 , S(═O)Ar 4 , S(═O) 2 Ar 4 , CR 2 ═CR 2 Ar 4 , CHO, CR 3 ═C(R 3 ) 2 , CN, NO 2 , Si(R 3 ) 3 , B(OR 3 ) 2 , B(R 3 ) 2 , B(N(R 3 ) 2 ) 2 , OSO 2 R 3 , a straight-chain alkyl, alkoxy or thioalkoxy group having 1 to 40 C atoms or a straight-chain alkenyl or alkynyl group having 2 to 40 C atoms or a branched or cyclic alkyl, alkenyl, alkynyl, alkoxy or thioalkoxy group having 3 to 40 C atoms, each of which may be substituted by one or more radicals R 3 , where in each case one or more non-adjacent CH 2  groups may be replaced by R 3 C═CR 3 , C≡C, Si(R 3 ) 2 , Ge(R 3 ) 2 , Sn(R 3 ) 2 , C═O, C═S, C═Se, C═NR 3 , P(═O)R 3 , SO, SO 2 , NR 3 , O, S or CONR 3  and where one or more H atoms may be replaced by F, Cl, Br, I, CN or NO 2 , or an aromatic or heteroaromatic ring system having 5 to 60 aromatic ring atoms, which may in each case be substituted by one or more radicals R 3 , or a combination of these systems; two or more substituents R 1  or R 2  here may also form a mono- or polycyclic, aliphatic or aromatic ring system with one another;   R 3  is on each occurrence, identically or differently, H, D or an aliphatic or aromatic hydrocarbon radical having 1 to 20 C atoms;   Ar 4  is on each occurrence, identically or differently, an aromatic or heteroaromatic ring system having 5-30 aromatic ring atoms, which may be substituted by one or more non-aromatic radicals R 1 ; two radicals Ar on the same nitrogen or phosphorus atom may also be linked to one another here by a single bond or a bridge X;   m, n are 0 or 1, with the proviso that m+n=1;   p is 1, 2, 3, 4, 5 or 6;   

     Ar 1 , Ar 2  and X here together form a five-membered ring or a six-membered ring, and Ar 2 , Ar 3  and X together form a five-membered ring or a six-membered ring, with the proviso that either all symbols X in the compound of the formula (1) are bound in a five-membered ring or all symbols X in the compound of the formula (1) are bound in a six-membered ring; 
     characterised in that the sum of all π electrons in groups Ar 1 , Ar 2  and Ar 3  is at least 28 if p=1 and is at least 34 if p=2 and is at least 40 if p=3 and is at least 46 if p=4 and is at least 52 if p=5 and is at least 58 if p=6; 
     n=0 or m=0 here means that the corresponding group X is not present and that instead hydrogen or a substituent R 1  is bonded to the corresponding positions of Ar 2  and Ar 3 . 
     Further preferred blue-fluorescent emitters are the hydrocarbons of the following formula (2) as disclosed in WO 2014/111269 A2. 
     
       
         
         
             
             
         
       
     
     where:
     Ar 1  is on each occurrence, identically or differently, an aryl or heteroaryl group having 6 to 18 aromatic ring atoms, which may be substituted by one or more radicals R 1 ;   Ar 2  is on each occurrence, identically or differently, an aryl or heteroaryl group having 6 aromatic ring atoms, which may be substituted by one or more radicals R 2 ;   X 1  is on each occurrence, identically or differently, BR 3 , C(R 3 ) 2 , —C(R 3 ) 2 —C(R 3 ) 2 —, —C(R 3 ) 2 —O—, —C(R 3 ) 2 —S—, —R 3 C═CR 3 —, —R 3 C═N—, Si(R 3 ) 2 , —Si(R 3 ) 2 —Si(R 3 ) 2 —, C═O, O, S, S═O, SO 2 , NR 3 , PR 3  or P(═O)R 3 ;   R 1 , R 2 , R 3  are on each occurrence, identically or differently, H, D, F, Cl, Br, I, C(═O)R 4 , CN, Si(R 4 ) 3 , N(R 4 ) 2 , P(═O)(R 4 ) 2 , OR 4 , S(═O)R 4 , S(═O) 2 R 4 , a straight-chain alkyl or alkoxy group having 1 to 20 C atoms or a branched or cyclic alkyl or alkoxy group having 3 to 20 C atoms or an alkenyl or alkynyl group having 2 to 20 C atoms, where the above-mentioned groups may each be substituted by one or more radicals R 4  and where one or more CH 2  groups in the above-mentioned groups may be replaced by —R 4 C═CR 4 —, —C≡C—, Si(R 4 ) 2 , C═O, C═NR 4 , —C(═O)O—, —C(═O)NR 4 —, NR 4 , P(═O)(R 4 ), —O—, —S—, SO or SO 2 , or an aromatic or heteroaromatic ring system having 5 to 30 aromatic ring atoms, which may in each case be substituted by one or more radicals R 4 , where two or more radicals R 3  may be linked to one another and may form a ring;   R 4  is on each occurrence, identically or differently, H, D, F, Cl, Br, I, C(═O)R 5 , CN, Si(R 5 ) 3 , N(R 5 ) 2 , P(═O)(R 5 ) 2 , OR 5 , S(═O)R 5 , S(═O) 2 R 5 , a straight-chain alkyl or alkoxy group having 1 to 20 C atoms or a branched or cyclic alkyl or alkoxy group having 3 to 20 C atoms or an alkenyl or alkynyl group having 2 to 20 C atoms, where the above-mentioned groups may each be substituted by one or more radicals R 5  and where one or more CH 2  groups in the above-mentioned groups may be replaced by —R 5 C═CR 5 —, —C≡C—, Si(R 5 ) 2 , C═O, C═NR 5 , —C(═O)O—, —C(═O)NR 5 —, NR 5 , P(═O)(R 5 ), —O—, —S—, SO or SO 2 , or an aromatic or heteroaromatic ring system having 5 to 30 aromatic ring atoms, which may in each case be substituted by one or more radicals R 5 , where two or more radicals R 4  may be linked to one another and may form a ring;   R 5  is on each occurrence, identically or differently, H, D, F or an aliphatic, aromatic or heteroaromatic organic radical having 1 to 20 C atoms, in which, in addition, one or more H atoms may be replaced by D or F; two or more substituents R 5  here may be linked to one another and may form a ring;   

     where at least one of the two groups Ar 1  must contain 10 or more aromatic ring atoms; and 
     where, if one of the two groups Ar 1  is a phenyl group, the other of the two groups Ar 1  must not contain more than 14 aromatic ring atoms. 
     Further preferred blue-fluorescent emitters are the hydrocarbons of the following formula (3) as disclosed in PCT/EP2017/066712. 
     
       
         
         
             
             
         
       
     
     where the following applies to the symbols and indices used: 
     Ar 1  stands on each occurrence, identically or differently, for an aryl or heteroaryl group having 6 to 18 aromatic ring atoms, which may in each case be substituted by one or more radicals R 1 , wherein at least one of the group Ar 1  in formula (1) has 10 or more aromatic ring atoms; 
     Ar 2  stands on each occurrence, identically or differently, for an aryl or heteroaryl group having 6 aromatic ring atoms, which may in each case be substituted by one or more radicals R 1 ; 
     Ar 3 , Ar 4  stand on each occurrence, identically or differently, for an aromatic or heteroaromatic ring systems having 5 to 25 aromatic ring atoms, which may in each case be substituted by one or more radicals R 1 ; 
     E is identically or differently on each occurrence, selected from —BR 0 —, —C(R 0 ) 2 —, —C(R 0 ) 2 —C(R 0 ) 2 —, —C(R 0 ) 2 —O—, —C(R 0 ) 2 —S—, —R 0 C═CR 0 —, —R 0 C═N—, Si(R 0 ) 2 , —Si(R 0 ) 2 —Si(R 0 ) 2 —, —C(═O)—, —C(═NR 0 )—, —C(═C(R 0 ) 2 )—, —O—, —S—, —S(═O)—, —SO 2 —, —N(R 0 )—, —P(R 0 )— and —P((═O)R 0 )—, and two groups E may be in a cis- or trans-position relative to each other; 
     R 0 , R 1  stand on each occurrence, identically or differently, for H, D, F, Cl, Br, I, CHO, CN, N(Ar 5 ) 2 , C(═O)Ar 5 , P(═O)(Ar 5 ) 2 , S(═O)Ar 5 , S(═O) 2 Ar 5 , NO 2 , Si(R 2 ) 3 , B(OR 2 ) 2 , OSO 2 R 2 , a straight-chain alkyl, alkoxy or thioalkyl groups having 1 to 40 C atoms or branched or a cyclic alkyl, alkoxy or thioalkyl groups having 3 to 40 C atoms, each of which may be substituted by one or more radicals R 2 , where in each case one or more non-adjacent CH 2  groups may be replaced by R 2 C═CR 2 , CC, Si(R 2 ) 2 , Ge(R 2 ) 2 , Sn(R 2 ) 2 , C═O, C═S, C═Se, P(═O)(R 2 ), SO, SO 2 , O, S or CONR 2  and where one or more H atoms may be replaced by D, F, Cl, Br, I, CN or NO 2 , an aromatic or heteroaromatic ring systems having 5 to 60 aromatic ring atoms, which may in each case be substituted by one or more radicals R 2 , or an aryloxy groups having 5 to 40 aromatic ring atoms, which may be substituted by one or more radicals R 2 , where two adjacent substituents R 0  and/or two adjacent substituents R 1  may form a mono- or polycyclic, aliphatic ring system or aromatic ring system, which may be substituted by one or more radicals R 2 ; 
     R 2  stands on each occurrence, identically or differently, for H, D, F, Cl, Br, I, CHO, CN, N(Ar 5 ) 2 , C(═O)Ar 5 , P(═O)(Ar 5 ) 2 , S(═O)Ar 5 , S(═O) 2 Ar 5 , NO 2 , Si(R 3 ) 3 , B(OR 3 ) 2 , OSO 2 R 3 , a straight-chain alkyl, alkoxy or thioalkyl groups having 1 to 40 C atoms or branched or cyclic alkyl, alkoxy or thioalkyl groups having 3 to 40 C atoms, each of which may be substituted by one or more radicals R 3 , where in each case one or more non-adjacent CH 2  groups may be replaced by R 3 C═CR 3 , CC, Si(R 3 ) 2 , Ge(R 3 ) 2 , Sn(R 3 ) 2 , C═O, C═S, C═Se, P(═O)(R 3 ), SO, SO 2 , O, S or CONR 3  and where one or more H atoms may be replaced by D, F, Cl, Br, I, CN or NO 2 , an aromatic or heteroaromatic ring systems having 5 to 60 aromatic ring atoms, which may in each case be substituted by one or more radicals R 3 , or an aryloxy group having 5 to 60 aromatic ring atoms, which may be substituted by one or more radicals R 3 , where two adjacent substituents R 2  may form a mono- or polycyclic, aliphatic ring system or aromatic ring system, which may be substituted by one or more radicals R 3 ; 
     R 3  stands on each occurrence, identically or differently, for H, D, F, Cl, Br, I, CN, a straight-chain alkyl, alkoxy or thioalkyl groups having 1 to 20 C atoms or branched or cyclic alkyl, alkoxy or thioalkyl groups having 3 to 20 C atoms, where in each case one or more non-adjacent CH 2  groups may be replaced by SO, SO 2 , O, S and where one or more H atoms may be replaced by D, F, Cl, Br or I, or an aromatic or heteroaromatic ring system having 5 to 24 C atoms; 
     Ar 5  is an aromatic or heteroaromatic ring system having 5 to 24 aromatic ring atoms, preferably 5 to 18 aromatic ring atoms, which may in each case also be substituted by one or more radicals R 3 ; 
     n is an integer from 1 to 20; 
     wherein if n is equal to 1 and at least one of the group Ar 3  or Ar 4  stands for a phenyl group, then the compound of formula (1) bears at least one group R 0  or R 1 , which stands for a straight-chain alkyl group having 2 to 40 C atoms or a branched or cyclic alkyl group having 3 to 40 C atoms, each of which may be substituted by one or more radicals R 2 . 
     Preferred compounds which can serve as phosphorescent emitters are described below by way of example. 
     Examples of phosphorescent emitters are revealed by WO 00/70655, WO 01/41512, WO 02/02714, WO 02/15645, EP 1191613, EP 1191612, EP 1191614 and WO 2005/033244. In general, all phosphorescent complexes as are used in accordance with the prior art for phosphorescent OLEDs and as are known to the person skilled in the art in the area of organic electroluminescence are suitable, and the person skilled in the art will be able to use further phosphorescent complexes without inventive step. 
     Phosphorescent metal complexes preferably contain Ir, Ru, Pd, Pt, Os or Re, more preferably Ir. 
     Preferred ligands are 2-phenylpyridine derivatives, 7,8-benzoquinoline derivatives, 2-(2-thienyl)pyridine derivatives, 2-(1-naphthyl)pyridine derivatives, 1-phenylisoquinoline derivatives, 3-phenylisoquinoline derivatives or 2-phenylquinoline derivatives. All these compounds may be substituted, for example by fluoro, cyano and/or trifluoromethyl substituents for blue. Auxiliary ligands are preferably acetylacetonate or picolinic acid. 
     In particular, complexes of Pt or Pd with tetradentate ligands of the formula EM-16 are suitable 
     
       
         
         
             
             
         
       
     
     The compounds of the formula EM-16 are described in greater detail in US 2007/0087219 A1, where, for an explanation of the substituents and indices in the above formula, reference is made to this specification for disclosure purposes. Furthermore, Pt-porphyrin complexes having an enlarged ring system (US 2009/0061681 A1) and Ir complexes, for example 2,3,7,8,12,13,17,18-octaethyl-21H, 23H-porphyrin-Pt(II), tetraphenyl-Pt(II) tetrabenzoporphyrin (US 2009/0061681 A1), cis-bis(2-phenylpyridinato-N,C 2 ′)Pt(II), cis-bis(2-(2′-thienyl)pyridinato-N,C 3 ′)Pt(II), cis-bis(2-(2′-thienyl)-quinolinato-N,C 5 ′)Pt(II), (2-(4,6-difluorophenyl)pyridinato-N,C 2 ′)Pt(II) (acetyl-acetonate), or tris(2-phenylpyridinato-N,C 2 ′)lr(III) (=Ir(ppy) 3 , green), bis(2-phenylpyridinato-N,C 2 )lr(III) (acetylacetonate) (=Ir(ppy) 2  acetylacetonate, green, US 2001/0053462 A1, Baldo, Thompson et al.  Nature  403, (2000), 750-753), bis(1-phenylisoquinolinato-N,C 2 ′)(2-phenylpyridinato-N,C 2 ′)-iridium(III), bis(2-phenylpyridinato-N,C 2 ′)(1-phenylisoquinolinato-N,C 2 ′)-iridium(III), bis(2-(2′-benzothienyl)pyridinato-N,C 3 ′)iridium(III) (acetyl-acetonate), bis(2-(4′,6′-difluorophenyl)pyridinato-N,C 2 ′)iridium(III) (picco-linate) (Flrpic, blue), bis(2-(4′,6′-difluorophenyl)pyridinato-N,C 2 ′)lr(II) (tetrakis(1-pyrazolyl)borate), tris(2-(biphenyl-3-yl)-4-tert-butylpyridine)-iridium(III), (ppz) 2 lr(5phdpym) (US 2009/0061681 A1), (45ooppz) 2 -Ir(5phdpym) (US 2009/0061681 A1), derivatives of 2-phenylpyridine-Ir complexes, such as, for example, PQIr (=iridium(III) bis(2-phenylquinolyl-N,C 2 ′)acetylacetonate), tris(2-phenylisoquinolinato-N,C)lr(III) (red), bis(2-(2′-benzo[4,5-a]thienyl)pyridinato-N,C 3 )lr (acetylacetonate) ([Btp 2 lr(acac)], red, Adachi et al.  Appl. Phys. Lett.  78 (2001), 1622-1624). 
     Likewise suitable are complexes of trivalent lanthanides, such as, for example, Tb 3+  and Eu 3+  (J. Kido et al.  Appl. Phys. Lett.  65 (1994), 2124, Kido et al. Chem. Lett. 657, 1990, US 2007/0252517 A1), or phosphorescent complexes of Pt(II), Ir(I), Rh(I) with maleonitrile dithiolate (Johnson et al.,  JACS  105, 1983, 1795), Re(I) tricarbonyl-diimine complexes (Wrighton,  JACS  96, 1974, 998, inter alia), Os(II) complexes with cyano ligands and bipyridyl or phenanthroline ligands (Ma et al.,  Synth. Metals  94, 1998, 245). 
     Further phosphorescent emitters having tridentate ligands are described in U.S. Pat. No. 6,824,895 and U.S. Ser. No. 10/729,238. Red-emitting phosphorescent complexes are found in U.S. Pat. Nos. 6,835,469 and 6,830,828. 
     Particularly preferred compounds which are used as phosphorescent dopants are, inter alia, the compounds of the formula EM-17 described, inter alia, in US 2001/0053462 A1 and  Inorg. Chem.  2001, 40(7), 1704-1711, JACS 2001, 123(18), 4304-4312, and derivatives thereof. 
     
       
         
         
             
             
         
       
     
     Derivatives are described in U.S. Pat. No. 7,378,162 B2, U.S. Pat. No. 6,835,469 B2 and JP 2003/253145 A. 
     Furthermore, the compounds of the formulae EM-18 to EM-21 described in U.S. Pat. No. 7,238,437 B2, US 2009/008607 A1 and EP 1348711, and derivatives thereof, can be employed as emitters. 
     
       
         
         
             
             
         
       
     
     Quantum dots can likewise be employed as emitters, these materials being disclosed in detail in WO 2011/076314 A1. 
     Compounds which are employed as host materials, in particular together with emitting compounds, include materials from various classes of substances. 
     Host materials generally have larger band gaps between HOMO and LUMO than the emitter materials employed. In addition, preferred host materials exhibit properties of either a hole- or electron-transport material. Furthermore, host materials can have both electron- and hole-transport properties. 
     Host materials are in some cases also called matrix material, in particular if the host material is employed in combination with a phosphorescent emitter in an OLED. 
     Preferred host materials or co-host materials, which are employed, in particular, together with fluorescent dopants, are selected from the classes of the oligoarylenes (for example 2,2′,7,7′-tetraphenylspirobifluorene in accordance with EP 676461 or dinaphthylanthracene), in particular the oligoarylenes containing condensed aromatic groups, such as, for example, anthracene, benzanthracene, benzophenanthrene (DE 10 2009 005746, WO 2009/069566), phenanthrene, tetracene, coronene, chrysene, fluorene, spirofluorene, perylene, phthaloperylene, naphthaloperylene, decacyclene, rubrene, the oligoarylenevinylenes (for example DPVBi=4,4′-bis(2,2-diphenylethenyl)-1,1′-biphenyl or spiro-DPVBi in accordance with EP 676461), the polypodal metal complexes (for example in accordance with WO 04/081017), in particular metal complexes of 8-hydroxyquinoline, for example AIQ3 (=aluminium(III) tris(8-hydroxyquinoline)) or bis(2-methyl-8-quinolinolato)-4-(phenylphenolinolato)aluminium, also with imidazole chelate (US 2007/0092753 A1) and the quinoline-metal complexes, amino-quinoline-metal complexes, benzoquinoline-metal complexes, the hole-conducting compounds (for example in accordance with WO 2004/058911), the electron-conducting compounds, in particular ketones, phosphine oxides, sulfoxides, etc. (for example in accordance with WO 2005/084081 and WO 2005/084082), the atropisomers (for example in accordance with WO 2006/048268), the boronic acid derivatives (for example in accordance with WO 2006/117052) or the benzanthracenes (for example in accordance with WO 2008/145239). 
     Particularly preferred compounds which can serve as host materials or co-host materials are selected from the classes of the oligoarylenes, comprising anthracene, benzanthracene and/or pyrene, or atropisomers of these compounds. An oligoarylene in the sense of the present invention is intended to be taken to mean a compound in which at least three aryl or arylene groups are bonded to one another. 
     Preferred host materials are selected, in particular, from compounds of the formula (H-1) 
       Ar 4 —(Ar 5 ) p —Ar 6   (H-1)
 
     where Ar 4 , Ar 5 , Ar 6  are on each occurrence, identically or differently, an aryl or heteroaryl group having 5 to 30 aromatic ring atoms, which may optionally be substituted, and p represents an integer in the range from 1 to 5; the sum of the π electrons in Ar 4 , Ar 5  and Ar 6  is at least 30 if p=1 and at least 36 if p=2 and at least 42 if p=3. 
     In the compounds of the formula (H-1), the group Ar 5  particularly preferably stands for anthracene, and the groups Ar 4  and Ar 6  are bonded in the 9- and 10-position, where these groups may optionally be substituted. Very particularly preferably, at least one of the groups Ar 4  and/or Ar 6  is a condensed aryl group selected from 1- or 2-naphthyl, 2-, 3- or 9-phenanthrenyl or 2-, 3-, 4-, 5-, 6- or 7-benzanthracenyl. Anthracene-based compounds are described in US 2007/0092753 A1 and US 2007/0252517 A1, for example 2-(4-methylphenyl)-9,10-di-(2-naphthyl)anthracene, 9-(2-naphthyl)-10-(1,1′-biphenyl)anthracene and 9,10-bis[4-(2,2-diphenylethenyl)phenyl]anthracene, 9,10-diphenylanthracene, 9,10-bis(phenylethynyl)anthracene and 1,4-bis(9′-ethynylanthracenyl)benzene. Preference is also given to compounds containing two anthracene units (US 2008/0193796 A1), for example 10,10′-bis[1,1′,4′,1″ ]terphenyl-2-yl-9,9′-bisanthracenyl. 
     Further preferred compounds are derivatives of arylamine, styrylamine, fluorescein, diphenylbutadiene, tetraphenylbutadiene, cyclopentadiene, tetraphenylcyclopentadiene, pentaphenylcyclopentadiene, coumarine, oxadiazole, bisbenzoxazoline, oxazole, pyridine, pyrazine, imine, benzo-thiazole, benzoxazole, benzimidazole (US 2007/0092753 A1), for example 2,2′,2″-(1,3,5-phenylene)tris[1-phenyl-1H-benzimidazole], aldazine, stilbene, styrylarylene derivatives, for example 9,10-bis[4-(2,2-diphenyl-ethenyl)phenyl]anthracene, and distyrylarylene derivatives (U.S. Pat. No. 5,121,029), diphenylethylene, vinylanthracene, diaminocarbazole, pyran, thiopyran, diketopyrrolopyrrole, polymethine, cinnamic acid esters and fluorescent dyes. 
     Particular preference is given to derivatives of arylamine and styrylamine, for example TNB (=4,4′-bis[N—(1-naphthyl)-N—(2-naphthyl)amino]biphenyl). Metal-oxinoid complexes, such as LiQ or AIQ3, can be used as co-hosts. 
     Preferred compounds with oligoarylene as matrix are disclosed in US 2003/0027016 A1, U.S. Pat. No. 7,326,371 B2, US 2006/043858 A, WO 2007/114358, WO 2008/145239, JP 3148176 B2, EP 1009044, US 2004/018383, WO 2005/061656 A1, EP 0681019B1, WO 2004/013073A1, U.S. Pat. No. 5,077,142, WO 2007/065678 and DE 102009005746, where particularly preferred compounds are described by the formulae H-2 to H-8. 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     Furthermore, compounds which can be employed as host or matrix include materials which are employed together with phosphorescent emitters. These compounds, which can also be employed as structural elements in polymers, include CBP (N,N-biscarbazolylbiphenyl), carbazole derivatives (for example in accordance with WO 2005/039246, US 2005/0069729, JP 2004/288381, EP 1205527 or WO 2008/086851), azacarbazoles (for example in accordance with EP 1617710, EP 1617711, EP 1731584 or JP 2005/347160), ketones (for example in accordance with WO 2004/093207 or in accordance with DE 102008033943), phosphine oxides, sulfoxides and sulfones (for example in accordance with WO 2005/003253), oligophenylenes, aromatic amines (for example in accordance with US 2005/0069729), bipolar matrix materials (for example in accordance with WO 2007/137725), silanes (for example in accordance with WO 2005/111172), 9,9-diarylfluorene derivatives (for example in accordance with DE 102008017591), azaboroles or boronic esters (for example in accordance with WO 2006/117052), triazine derivatives (for example in accordance with DE 102008036982), indolocarbazole derivatives (for example in accordance with WO 2007/063754 or WO 2008/056746), indenocarbazole derivatives (for example in accordance with DE 102009023155 and DE 102009031021), diazaphosphole derivatives (for example in accordance with DE 102009022858), triazole derivatives, oxazoles and oxazole derivatives, imidazole derivatives, polyarylalkane derivatives, pyrazoline derivatives, pyrazolone derivatives, distyrylpyrazine derivatives, thiopyran dioxide derivatives, phenylenediamine derivatives, tertiary aromatic amines, styrylamines, amino-substituted chalcone derivatives, indoles, hydrazone derivatives, stilbene derivatives, silazane derivatives, aromatic dimethylidene compounds, carbodiimide derivatives, metal complexes of 8-hydroxy-quinoline derivatives, such as, for example, AIQ3, which may also contain triarylaminophenol ligands (US 2007/0134514 A1), metal complex/poly-silane compounds, and thiophene, benzothiophene and dibenzothiophene derivatives. 
     Examples of preferred carbazole derivatives are mCP (=1,3-N,N-di-carbazolylbenzene (=9,9′-(1,3-phenylene)bis-9H-carbazole)) (formula H-9), CDBP (=9,9′-(2,2′-dimethyl[1,1′-biphenyl]-4,4′-diyl)bis-9H-carbazole), 1,3-bis(N,N′-dicarbazolyl)benzene (=1,3-bis(carbazol-9-yl)benzene), PVK (polyvinylcarbazole), 3,5-di(9H-carbazol-9-yl)biphenyl and CMTTP (formula H-10). Particularly referred compounds are disclosed in US 2007/0128467 A1 and US 2005/0249976 A1 (formulae H-11 and H-13). 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     Preferred tetraaryl-Si compounds are disclosed, for example, in US 2004/0209115, US 2004/0209116, US 2007/0087219 A1 and in H. Gilman, E. A. Zuech, Chemistry &amp; Industry (London, United Kingdom), 1960, 120. Particularly preferred tetraaryl-Si compounds are described by the formulae H-14 to H-21. 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     Particularly preferred compounds from group 4 for the preparation of the matrix for phosphorescent dopants are disclosed, inter alia, in DE 102009022858, DE 102009023155, EP 652273 B1, WO 2007/063754 and WO 2008/056746, where particularly preferred compounds are described by the formulae H-22 to H-25. 
     
       
         
         
             
             
         
       
     
     With respect to the functional compounds which can be employed in accordance with the invention and which can serve as host material, especial preference is given to substances which contain at least one nitrogen atom. These preferably include aromatic amines, triazine derivatives and carbazole derivatives. Thus, carbazole derivatives in particular exhibit surprisingly high efficiency. Triazine derivatives result in unexpectedly long lifetimes of the electronic devices. 
     It may also be preferred to employ a plurality of different matrix materials as a mixture, in particular at least one electron-conducting matrix material and at least one hole-conducting matrix material. Preference is likewise given to the use of a mixture of a charge-transporting matrix material and an electrically inert matrix material which is not in involved in the charge transport to a significant extent, if at all, as described, for example, in WO 2010/108579. 
     It is furthermore possible to employ compounds which improve the transition from the singlet state to the triplet state and which, employed in support of the functional compounds having emitter properties, improve the phosphorescence properties of these compounds. Suitable for this purpose are, in particular, carbazole and bridged carbazole dimer units, as described, for example, in WO 2004/070772 A2 and WO 2004/113468 A1. Also suitable for this purpose are ketones, phosphine oxides, sulfoxides, sulfones, silane derivatives and similar compounds, as described, for example, in WO 2005/040302 A1. 
     n-Dopants herein are taken to mean reducing agents, i.e. electron donors. Preferred examples of n-dopants are W(hpp) 4  and other electron-rich metal complexes in accordance with WO 2005/086251 A2, P═N compounds (for example WO 2012/175535 A1, WO 2012/175219 A1), naphthylenecarbo-diimides (for example WO 2012/168358 A1), fluorenes (for example WO 2012/031735 A1), free radicals and diradicals (for example EP 1837926 A1, WO 2007/107306 A1), pyridines (for example EP 2452946 A1, EP 2463927 A1), N-heterocyclic compounds (for example WO 2009/000237 A1) and acridines as well as phenazines (for example US 2007/145355 A1). 
     Furthermore, the formulations may comprise a wide-band-gap material as functional material. Wide-band-gap material is taken to mean a material in the sense of the disclosure content of U.S. Pat. No. 7,294,849. These systems exhibit particularly advantageous performance data in electroluminescent devices. 
     The compound employed as wide-band-gap material can preferably have a band gap of 2.5 eV or more, preferably 3.0 eV or more, particularly preferably 3.5 eV or more. The band gap can be calculated, inter alia, by means of the energy levels of the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO). 
     Furthermore, the formulations may comprise a hole-blocking material (HBM) as functional material. A hole-blocking material denotes a material which prevents or minimises the transmission of holes (positive charges) in a multilayer system, in particular if this material is arranged in the form of a layer adjacent to an emission layer or a hole-conducting layer. In general, a hole-blocking material has a lower HOMO level than the hole-transport material in the adjacent layer. Hole-blocking layers are frequently arranged between the light-emitting layer and the electron-transport layer in OLEDs. 
     It is basically possible to employ any known hole-blocking material. In addition to other hole-blocking materials described elsewhere in the present application, advantageous hole-blocking materials are metal complexes (US 2003/0068528), such as, for example, bis(2-methyl-8-quinolinolato)(4-phenylphenolato)aluminium(III) (BAIQ). Fac-tris(1-phenylpyrazolato-N,C2)-iridium(III) (lr(ppz) 3 ) is likewise employed for this purpose (US 2003/0175553 A1). Phenanthroline derivatives, such as, for example, BCP, or phthalimides, such as, for example, TMPP, can likewise be employed. 
     Furthermore, advantageous hole-blocking materials are described in WO 00/70655 A2, WO 01/41512 and WO 01/93642 A1. 
     Furthermore, the formulations may comprise an electron-blocking material (EBM) as functional material. An electron-blocking material denotes a material which prevents or minimises the transmission of electrons in a multilayer system, in particular if this material is arranged in the form of a layer adjacent to an emission layer or an electron-conducting layer. In general, an electron-blocking material has a higher LUMO level than the electron-transport material in the adjacent layer. 
     It is basically possible to employ any known electron-blocking material. In addition to other electron-blocking materials described elsewhere in the present application, advantageous electron-blocking materials are transition-metal complexes, such as, for example, Ir(ppz) 3  (US 2003/0175553). 
     The electron-blocking material can preferably be selected from amines, triarylamines and derivatives thereof. 
     Furthermore, the functional compounds which can be employed as organic functional materials in the formulations preferably have, if they are low-molecular-weight compounds, a molecular weight of ≤3,000 g/mol, more preferably ≤2,000 g/mol and most preferably ≤1,000 g/mol. 
     Of particular interest are furthermore functional compounds which are distinguished by a high glass-transition temperature. In this connection, particularly preferred functional compounds which can be employed as organic functional material in the formulations are those which have a glass-transition temperature of ≥70° C., preferably ≥100° C., more preferably ≥125° C. and most preferably ≥150° C., determined in accordance with DIN 51005. 
     The formulations may also comprise polymers as organic functional materials. The compounds described above as organic functional materials, which frequently have a relatively low molecular weight, can also be mixed with a polymer. It is likewise possible to incorporate these compounds covalently into a polymer. This is possible, in particular, with compounds which are substituted by reactive leaving groups, such as bromine, iodine, chlorine, boronic acid or boronic acid ester, or by reactive, polymerisable groups, such as olefins or oxetanes. These can be used as monomers for the production of corresponding oligomers, dendrimers or polymers. The oligomerisation or polymerisation here preferably takes place via the halogen functionality or the boronic acid functionality or via the polymerisable group. It is furthermore possible to crosslink the polymers via groups of this type. The compounds and polymers according to the invention can be employed as crosslinked or uncrosslinked layer. 
     Polymers which can be employed as organic functional materials frequently contain units or structural elements which have been described in the con-text of the compounds described above, inter alia those as disclosed and extensively listed in WO 02/077060 A1, in WO 2005/014689 A2 and in WO 2011/076314 A1. These are incorporated into the present application by way of reference. The functional materials can originate, for example, from the following classes:
     Group 1: structural elements which are able to generate hole-injection and/or hole-transport properties;   Group 2: structural elements which are able to generate electron-injection and/or electron-transport properties;   Group 3: structural elements which combine the properties described in relation to groups 1 and 2;   Group 4: structural elements which have light-emitting properties, in particular phosphorescent groups;   Group 5: structural elements which improve the transition from the so-called singlet state to the triplet state;   Group 6: structural elements which influence the morphology or also the emission colour of the resultant polymers;   Group 7: structural elements which are typically used as backbone.   

     The structural elements here may also have various functions, so that a clear assignment need not be advantageous. For example, a structural element of group 1 may likewise serve as backbone. 
     The polymer having hole-transport or hole-injection properties employed as organic functional material, containing structural elements from group 1, may preferably contain units which correspond to the hole-transport or hole-injection materials described above. 
     Further preferred structural elements of group 1 are, for example, triarylamines, benzidines, tetraaryl-para-phenylenediamines, carbazoles, azulenes, thiophenes, pyrroles and furanes and derivatives thereof and further O—, S- or N-containing heterocycles having a high HOMO. These arylamines and heterocycles preferably have an HOMO of above −5.8 eV (against vacuum level), particularly preferably above −5.5 eV. 
     Preference is given, inter alia, to polymers having hole-transport or hole-injection properties, containing at least one of the following recurring units of the formula HTP-1: 
     
       
         
         
             
             
         
       
     
     in which the symbols have the following meaning:
     Ar 1  is, in each case identically or differently for different recurring units, a single bond or a monocyclic or polycyclic aryl group, which may optionally be substituted;   Ar 2  is, in each case identically or differently for different recurring units, a monocyclic or polycyclic aryl group, which may optionally be substituted;   Ar 3  is, in each case identically or differently for different recurring units, a monocyclic or polycyclic aryl group, which may optionally be substituted;   m is 1, 2 or 3.   

     Particular preference is given to recurring units of the formula HTP-1 which are selected from the group consisting of units of the formulae HTP-1A to HTP-1C: 
     
       
         
         
             
             
         
       
     
     in which the symbols have the following meaning:
     R a  is on each occurrence, identically or differently, H, a substituted or unsubstituted aromatic or heteroaromatic group, an alkyl, cycloalkyl, alkoxy, aralkyl, aryloxy, arylthio, alkoxycarbonyl, silyl or carboxyl group, a halogen atom, a cyano group, a nitro group or a hydroxyl group;   r is 0, 1, 2, 3 or 4, and   s is 0, 1, 2, 3, 4 or 5.   

     Preference is given, inter alia, to polymers having hole-transport or hole-injection properties, containing at least one of the following recurring units of the formula HTP-2: 
       -(T) c -(Ar 7 ) d -(T 2 ) e -(Ar 8 ) f -  HTP-2
 
     in which the symbols have the following meaning: 
     T 1  and T 2  are selected independently from thiophene, selenophene, thieno-[2,3-b]thiophene, thieno[3,2-b]thiophene, dithienothiophene, pyrrole and aniline, where these groups may be substituted by one or more radicals R b ; 
     R b  is selected independently on each occurrence from halogen, —CN, —NC, —NCO, —NCS, —OCN, —SCN, —C(═O)NR 0 R 00 , —C(═O)X, —C(═O)R 0 , —NH 2 , —NR 0 R 00 , —SH, —SRO, —SO 3 H, —SO 2 R 0 , —OH, —NO 2 , —CF 3 , —SF 5 , an optionally substituted silyl, carbyl or hydrocarbyl group having 1 to 40 carbon atoms, which may optionally be substituted and may optionally contain one or more heteroatoms; 
     R 0  and R 00  are each independently H or an optionally substituted carbyl or hydrocarbyl group having 1 to 40 carbon atoms, which may optionally be substituted and may optionally contain one or more heteroatoms; 
     Ar 7  and Ar 8  represent, independently of one another, a monocyclic or polycyclic aryl or heteroaryl group, which may optionally be substituted and may optionally be bonded to the 2,3-position of one or both adjacent thiophene or selenophene groups; 
     c and e are, independently of one another, 0, 1, 2, 3 or 4, where 
     1&lt;c+e 6; 
     d and f are, independently of one another, 0, 1, 2, 3 or 4. 
     Preferred examples of polymers having hole-transport or hole-injection properties are described, inter alia, in WO 2007/131582 A1 and WO 2008/009343 A1. 
     The polymer having electron-injection and/or electron-transport properties employed as organic functional material, containing structural elements from group 2, may preferably contain units which correspond to the electron-injection and/or electron-transport materials described above. 
     Further preferred structural elements of group 2 which have electron-injection and/or electron-transport properties are derived, for example, from pyridines, pyrimidines, pyridazines, pyrazines, oxadiazoles, quinolines, quinoxalines and phenazines and derivatives thereof, but also triarylboranes or further O-, S- or N-containing heterocycles having a low LUMO level. These structural elements of group 2 preferably have an LUMO of below −2.7 eV (against vacuum level), particularly preferably below −2.8 eV. 
     The organic functional material can preferably be a polymer which contains structural elements from group 3, where structural elements which improve the hole and electron mobility (i.e. structural elements from groups 1 and 2) are connected directly to one another. Some of these structural elements can serve as emitters here, where the emission colours may be shifted, for example, into the green, red or yellow. Their use is therefore advantageous, for example, for the generation of other emission colours or a broad-band emission by polymers which originally emit in blue. 
     The polymer having light-emitting properties employed as organic functional material, containing structural elements from group 4, may preferably contain units which correspond to the emitter materials described above. Preference is given here to polymers containing phosphorescent groups, in particular the emitting metal complexes described above which contain corresponding units containing elements from groups 8 to 10 (Ru, Os, Rh, Ir, Pd, Pt). 
     The polymer employed as organic functional material containing units of group 5 which improve the transition from the so-called singlet state to the triplet state can preferably be employed in support of phosphorescent compounds, preferably the polymers containing structural elements of group 4 described above. A polymeric triplet matrix can be used here. 
     Suitable for this purpose are, in particular, carbazole and connected carbazole dimer units, as described, for example, in DE 10304819 A1 and DE 10328627 A1. Also suitable for this purpose are ketone, phosphine oxide, sulfoxide, sulfone and silane derivatives and similar compounds, as described, for example, in DE 10349033 A1. Furthermore, preferred structural units can be derived from compounds which have been described above in connection with the matrix materials employed together with phosphorescent compounds. 
     The further organic functional material is preferably a polymer containing units of group 6 which influence the morphology and/or the emission colour of the polymers. Besides the polymers mentioned above, these are those which have at least one further aromatic or another conjugated structure which do not count amongst the above-mentioned groups. These groups accordingly have only little or no effect on the charge-carrier mobilities, the non-organometallic complexes or the singlet-triplet transition. 
     Structural units of this type are able to influence the morphology and/or the emission colour of the resultant polymers. Depending on the structural unit, these polymers can therefore also be used as emitters. 
     In the case of fluorescent OLEDs, preference is therefore given to aromatic structural elements having 6 to 40 C atoms or also tolan, stilbene or bis-styrylarylene derivative units, each of which may be substituted by one or more radicals. Particular preference is given here to the use of groups derived from 1,4-phenylene, 1,4-naphthylene, 1,4- or 9,10-anthrylene, 1,6-, 2,7- or 4,9-pyrenylene, 3,9- or 3,10-perylenylene, 4,4′-biphenylene, 4,4″-terphenylylene, 4,4′-bi-1,1′-naphthylylene, 4,4′-tolanylene, 4,4′-stilbenylene or 4,4″-bisstyrylarylene derivatives. 
     The polymer employed as organic functional material preferably contains units of group 7, which preferably contain aromatic structures having 6 to 40 C atoms which are frequently used as backbone. 
     These include, inter alia, 4,5-dihydropyrene derivatives, 4,5,9,10-tetra-hydropyrene derivatives, fluorene derivatives, which are disclosed, for example, in U.S. Pat. No. 5,962,631, WO 2006/052457 A2 and WO 2006/118345 A1, 9,9-spirobifluorene derivatives, which are disclosed, for example, in WO 2003/020790 A1, 9,10-phenanthrene derivatives, which are disclosed, for example, in WO 2005/104264 A1, 9,10-dihydrophenanthrene derivatives, which are disclosed, for example, in WO 2005/014689 A2, 5,7-dihydrodibenzoxepine derivatives and cis- and trans-indenofluorene derivatives, which are disclosed, for example, in WO 2004/041901 A1 and WO 2004/113412 A2, and binaphthylene derivatives, which are disclosed, for example, in WO 2006/063852 A1, and further units which are disclosed, for example, in WO 2005/056633 A1, EP 1344788 A1, WO 2007/043495 A1, WO 2005/033174 A1, WO 2003/099901 A1 and DE 102006003710. 
     Particular preference is given to structural units of group 7 which are selected from fluorene derivatives, which are disclosed, for example, in U.S. Pat. No. 5,962,631, WO 2006/052457 A2 and WO 2006/118345 A1, spiro-bifluorene derivatives, which are disclosed, for example, in WO 2003/020790 A1, benzofluorene, dibenzofluorene, benzothiophene and dibenzo-fluorene groups and derivatives thereof, which are disclosed, for example, in WO 2005/056633 A1, EP 1344788 A1 and WO 2007/043495 A1. 
     For carrying out the present invention, preference is given to polymers which contain more than one of the structural elements of groups 1 to 7 described above. It may furthermore be provided that the polymers preferably contain more than one of the structural elements from one group described above, i.e. comprise mixtures of structural elements selected from one group. 
     Particular preference is given, in particular, to polymers which, besides at least one structural element which has light-emitting properties (group 4), preferably at least one phosphorescent group, additionally contain at least one further structural element of groups 1 to 3, 5 or 6 described above, where these are preferably selected from groups 1 to 3. 
     The proportion of the various classes of groups, if present in the polymer, can be in broad ranges, where these are known to the person skilled in the art. Surprising advantages can be achieved if the proportion of one class present in a polymer, which is in each case selected from the structural elements of groups 1 to 7 described above, is preferably in each case 5 mol %, particularly preferably in each case 10 mol %. 
     The preparation of white-emitting copolymers is described in detail, inter alia, in DE 10343606 A1. 
     In order to improve the solubility, the polymers may contain corresponding groups. It may preferably be provided that the polymers contain substituents, so that on average at least 2 non-aromatic carbon atoms, particularly preferably at least 4 and especially preferably at least 8 non-aromatic carbon atoms are present per recurring unit, where the average relates to the number average. Individual carbon atoms here may be replaced, for example, by O or S. However, it is possible for a certain proportion, optionally all recurring units, to contain no substituents which contain non-aromatic carbon atoms. Short-chain substituents are preferred here, since long-chain substituents can have adverse effects on layers which can be obtained using organic functional materials. The substituents preferably contain at most 12 carbon atoms, preferably at most 8 carbon atoms and particularly preferably at most 6 carbon atoms in a linear chain. 
     The polymer employed in accordance with the invention as organic functional material can be a random, alternating or regioregular copolymer, a block copolymer or a combination of these copolymer forms. 
     In a further embodiment, the polymer employed as organic functional material can be a non-conjugated polymer having side chains, where this embodiment is particularly important for phosphorescent OLEDs based on polymers. In general, phosphorescent polymers can be obtained by free-radical copolymerisation of vinyl compounds, where these vinyl compounds contain at least one unit having a phosphorescent emitter and/or at least one charge-transport unit, as is disclosed, inter alia, in U.S. Pat. No. 7,250,226 B2. 
     Further phosphorescent polymers are described, inter alia, in JP 2007/211243 A2, JP 2007/197574 A2, U.S. Pat. No. 7,250,226 B2 and JP 2007/059939 A. 
     In a further preferred embodiment, the non-conjugated polymers contain backbone units, which are connected to one another by spacer units. 
     Examples of such triplet emitters which are based on non-conjugated polymers based on backbone units are disclosed, for example, in DE 102009023154. 
     In a further preferred embodiment, the non-conjugated polymer can be designed as fluorescent emitter. Preferred fluorescent emitters which are based on non-conjugated polymers having side chains contain anthracene or benzanthracene groups or derivatives of these groups in the side chain, where these polymers are disclosed, for example, in JP 2005/108556, JP 2005/285661 and JP 2003/338375. 
     These polymers can frequently be employed as electron- or hole-transport materials, where these polymers are preferably designed as non-conjugated polymers. 
     Furthermore, the functional compounds employed as organic functional materials in the formulations preferably have, in the case of polymeric compounds, a molecular weight M w  of ≥10,000 g/mol, particularly preferably ≥20,000 g/mol and especially preferably ≥40,000 g/mol. 
     The molecular weight M w  of the polymers here is preferably in the range from 10,000 to 2,000,000 g/mol, particularly preferably in the range from 20,000 to 1,000,000 g/mol and very particularly preferably in the range from 40,000 to 300,000 g/mol. The molecular weight M w  is determined by means of GPC(=gel permeation chromatography) against an internal polystyrene standard. 
     The publications cited above for description of the functional compounds are incorporated into the present application by way of reference for disclosure purposes. 
     The formulations according to the invention may comprise all organic functional materials which are necessary for the production of the respective functional layer of the electronic device. If, for example, a hole-transport, hole-injection, electron-transport or electron-injection layer is built up precisely from one functional compound, the formulation comprises precisely this compound as organic functional material. If an emission layer comprises, for example, an emitter in combination with a matrix or host material, the formulation comprises, as organic functional material, precisely the mixture of emitter and matrix or host material, as described in greater detail elsewhere in the present application. 
     Besides the said components, the formulation according to the invention may comprise further additives and processing assistants. These include, inter alia, surface-active substances (surfactants), lubricants and greases, additives which modify the viscosity, additives which increase the conductivity, dispersants, hydrophobicising agents, adhesion promoters, flow improvers, antifoams, deaerating agents, diluents, which may be reactive or unreactive, fillers, assistants, processing assistants, dyes, pigments, stabilisers, sensitisers, nanoparticles and inhibitors. 
     The present invention furthermore relates to a process for the preparation of a formulation according to the present invention, wherein the at least one organic functional material, which can be employed for the production of functional layers of electronic devices, and the three different organic solvents A, B and C are mixed. 
     A formulation in accordance with the present invention can be employed for the production of a layer or multilayered structure in which the organic functional materials are present in layers, as are required for the production of preferred electronic or opto-electronic components, such as OLEDs. 
     The formulation of the present invention can preferably be employed for the formation of functional layers on a substrate or one of the layers applied to the substrate. The substrates can either have bank structures or not. 
     The present invention likewise relates to a process for the preparation of an electronic device, preferably an electroluminescent device, in which at least one layer of the electronic, preferably electroluminescent device, is prepared in that a formulation according to the present invention is deposited, preferably printed, more preferably ink-jet printed, on a surface and subsequently dried. 
     The functional layers can be produced, for example, by flood coating, dip coating, spray coating, spin coating, screen printing, relief printing, gravure printing, rotary printing, roller coating, flexographic printing, offset printing or nozzle printing, preferably ink-jet printing on a substrate or one of the layers applied to the substrate. 
     After the application of a formulation according to the present invention to a substrate or a functional layer already applied, a drying step can be carried out in order to remove the solvents from the continuous phase described above. The drying can preferably be carried out at relatively low temperature and over a relatively long period in order to avoid bubble formation and to obtain a uniform coating. The drying can preferably be carried out at a temperature in the range from 80 to 300° C., more preferably 150 to 250° C. and most preferably 160 to 200° C. The drying here can preferably be carried out at a pressure in the range from 10 −6  mbar to 2 bar, more preferably in the range from 10 −2  mbar to 1 bar and most preferably in the range from 10 −1  mbar to 100 mbar. During the drying process, the temperature of the substrates can be vary from −15° C. to 250° C. The duration of the drying depends on the degree of drying to be achieved, where small amounts of water can optionally be removed at relatively high temperature and in combination with sintering, which is preferably to be carried out. 
     It may furthermore be provided that the process is repeated a number of times, with formation of different or identical functional layers. Crosslinking of the functional layer formed can take place here in order to prevent dissolution thereof, as is disclosed, for example, in EP 0637899 A1. 
     The present invention also relates to an electronic device obtainable by a process for the production of an electronic device. 
     The present invention also relates to an electronic device, preferably an electroluminescent device, characterized in that at least one layer is prepared in that a formulation according to the present invention is deposited, preferably printed, more preferably ink-jet printed, on a surface and subsequently dried. 
     The present invention furthermore relates to an electronic device having at least one functional layer comprising at least one organic functional material which is obtainable by the above-mentioned process for the production of an electronic device. 
     An electronic device is taken to mean a device which comprises anode, cathode and at least one functional layer in between, where this functional layer comprises at least one organic or organometallic compound. 
     The organic electronic device is preferably an organic electroluminescent device (OLED), a polymeric electroluminescent device (PLED), an organic integrated circuit (O-IC), an organic field-effect transistor (O-FET), an organic thin-film transistor (O-TFT), an organic, light-emitting transistor (O-LET), an organic solar cell (O-SC), an organic photovoltaic (OPV) cell, an organic, optical detector, an organic photoreceptor, an organic field-quench device (O-FQD), an organic electrical sensor, a light-emitting electrochemical cell (LEC) or an organic laser diode (O-laser), more preferably an organic electroluminescent device (OLED) or a polymeric electroluminescent device (PLED). 
     Active components are generally the organic or inorganic materials which are introduced between the anode and the cathode, where these active components effect, maintain and/or improve the properties of the electronic device, for example its performance and/or its lifetime, for example charge-injection, charge-transport or charge-blocking materials, but in particular emission materials and matrix materials. The organic functional material which can be employed for the production of functional layers of electronic devices accordingly preferably comprises an active component of the electronic device. 
     Organic electroluminescent devices are a preferred embodiment of the present invention. The organic electroluminescent device comprises a cathode, an anode and at least one emitting layer. 
     It is furthermore preferred to employ a mixture of two or more triplet emitters together with a matrix. The triplet emitter having the shorter-wave emission spectrum serves as co-matrix here for the triplet emitter having the longer-wave emission spectrum. 
     The proportion of the matrix material in the emitting layer in this case is preferably between 50 and 99.9% by vol., more preferably between 80 and 99.5% by vol. and most preferably between 92 and 99.5% by vol. for fluorescent emitting layers and between 85 and 97% by vol. for phosphorescent emitting layers. 
     Correspondingly, the proportion of the dopant is preferably between 0.1 and 50% by vol., more preferably between 0.5 and 20% by vol. and most preferably between 0.5 and 8% by vol. for fluorescent emitting layers and between 3 and 15% by vol. for phosphorescent emitting layers. 
     An emitting layer of an organic electroluminescent device may also encompass systems which comprise a plurality of matrix materials (mixed-matrix systems) and/or a plurality of dopants. In this case too, the dopants are generally the materials whose proportion in the system is the smaller and the matrix materials are the materials whose proportion in the system is the greater. In individual cases, however, the proportion of an individual matrix material in the system may be smaller than the proportion of an individual dopant. 
     The mixed-matrix systems preferably comprise two or three different matrix materials, more preferably two different matrix materials. One of the two materials here is preferably a material having hole-transporting properties and the other material is a material having electron-transporting properties. However, the desired electron-transporting and hole-transporting properties of the mixed-matrix components may also be combined principally or completely in a single mixed-matrix component, where the further mixed-matrix component(s) fulfil(s) other functions. The two different matrix materials may be present here in a ratio of 1:50 to 1:1, preferably 1:20 to 1:1, more preferably 1:10 to 1:1 and most preferably 1:4 to 1:1. Mixed-matrix systems are preferably employed in phosphorescent organic electroluminescent devices. Further details on mixed-matrix systems can be found, for example, in WO 2010/108579. 
     Apart from these layers, an organic electroluminescent device may also comprise further layers, for example in each case one or more hole-injection layers, hole-transport layers, hole-blocking layers, electron-transport layers, electron-injection layers, exciton-blocking layers, electron-blocking layers, charge-generation layers (IDMC 2003, Taiwan, Session 21 OLED (5), T. Matsumoto, T. Nakada, J. Endo, K. Mori, N. Kawamura, A. Yokoi, J. Kido,  Multiphoton Organic EL Device Having Charge Generation Layer ) and/or organic or inorganic p/n junctions. It is possible here for one or more hole-transport layers to be p-doped, for example with metal oxides, such as MoO 3  or WO 3 , or with (per)fluorinated electron-deficient aromatic compounds, and/or for one or more electron-transport layers to be n-doped. 
     It is likewise possible for interlayers, which have, for example, an exciton-blocking function and/or control the charge balance in the electro-luminescent device, to be introduced between two emitting layers. However, it should be pointed out that each of these layers does not necessarily have to be present. These layers may likewise be present on use of the formulations according to the invention, as defined above. 
     In a further embodiment of the present invention, the device comprises a plurality of layers. The formulation according to the present invention can preferably be employed here for the production of a hole-transport, hole-injection, electron-transport, electron-injection and/or emission layer. 
     The present invention accordingly also relates to an electronic device which comprises at least three layers, but in a preferred embodiment all said layers, from hole-injection, hole-transport, emission, electron-transport, electron-injection, charge-blocking and/or charge-generation layer and in which at least one layer has been obtained by means of a formulation to be employed in accordance with the present invention. The thickness of the layers, for example the hole-transport and/or hole-injection layer, can preferably be in the range from 1 to 500 nm, more preferably in the range from 2 to 200 nm. 
     The device may furthermore comprise layers built up from further low-molecular-weight compounds or polymers which have not been applied by the use of formulations according to the present invention. These can also be produced by evaporation of low-molecular-weight compounds in a high vacuum. 
     It may additionally be preferred to use the compounds to be employed not as the pure substance, but instead as a mixture (blend) together with further polymeric, oligomeric, dendritic or low-molecular-weight substances of any desired type. These may, for example, improve the electronic properties or themselves emit. 
     In a preferred embodiment of the present invention, the formulations according to the invention comprise organic functional materials which are employed as host materials or matrix materials in an emitting layer. The formulation here may comprise the emitters described above in addition to the host materials or matrix materials. The organic electroluminescent device here may comprise one or more emitting layers. If a plurality of emission layers are present, these preferably have a plurality of emission maxima between 380 nm and 750 nm, resulting overall in white emission, i.e. various emitting compounds which are able to fluoresce or phosphoresce are used in the emitting layers. Very particular preference is given to three-layer systems, where the three layers exhibit blue, green and orange or red emission (for the basic structure see, for example, WO 2005/011013). White-emitting devices are suitable, for example, as backlighting of LCD displays or for general lighting applications. 
     It is also possible for a plurality of OLEDs to be arranged one above the other, enabling a further increase in efficiency with respect to the light yield to be achieved. 
     In order to improve the coupling-out of light, the final organic layer on the light-exit side in OLEDs can, for example, also be in the form of a nano-foam, resulting in a reduction in the proportion of total reflection. 
     Preference is furthermore given to an organic electroluminescent device in which one or more layers are applied by means of a sublimation process, in which the materials are applied by vapour deposition in vacuum sublimation units at a pressure below 10 −5  mbar, preferably below 10 −6  mbar, more preferably below 10 −7  mbar. 
     It may furthermore be provided that one or more layers of an electronic device according to the present invention are applied by means of the OVPD (organic vapour phase deposition) process or with the aid of carrier-gas sublimation, in which the materials are applied at a pressure between 10 −5  mbar and 1 bar. 
     It may furthermore be provided that one or more layers of an electronic device according to the present invention are produced from solution, such as, for example, by spin coating, or by means of any desired printing process, such as, for example, screen printing, flexographic printing or offset printing, but particularly preferably LITI (light induced thermal imaging, thermal transfer printing) or ink-jet printing. 
     The device usually comprises a cathode and an anode (electrodes). The electrodes (cathode, anode) are selected for the purposes of the present invention in such a way that their band energies correspond as closely as possible to those of the adjacent, organic layers in order to ensure highly efficient electron or hole injection. 
     The cathode preferably comprises metal complexes, metals having a low work function, metal alloys or multilayered structures comprising various metals, such as, for example, alkaline-earth metals, alkali metals, main-group metals or lanthanoids (for example Ca, Ba, Mg, Al, In, Mg, Yb, Sm, etc.). In the case of multilayered structures, further metals which have a relatively high work function, such as, for example, Ag and Ag nanowire (Ag NW) can also be used in addition to the said metals, in which case combinations of the metals, such as, for example, Ca/Ag or Ba/Ag, are generally used. It may also be preferred to introduce a thin interlayer of a material having a high dielectric constant between a metallic cathode and the organic semiconductor. Suitable for this purpose are, for example, alkali-metal or alkaline-earth metal fluorides, but also the corresponding oxides (for example LiF, Li 2 O, BaF 2 , MgO, NaF, etc.). The layer thickness of this layer is preferably between 0.1 and 10 nm, more preferably between 0.2 and 8 nm, and most preferably between 0.5 and 5 nm. 
     The anode preferably comprises materials having a high work function. The anode preferably has a potential greater than 4.5 eV vs. vacuum. Suitable for this purpose are on the one hand metals having a high redox potential, such as, for example, Ag, Pt or Au. On the other hand, metal/metal oxide electrodes (for example Al/Ni/NiO x , Al/PtO x ) may also be preferred. For some applications, at least one of the electrodes must be transparent in order to facilitate either irradiation of the organic material (O-SCs) or the coupling-out of light (OLEDs/PLEDs, O-lasers). A preferred structure uses a transparent anode. Preferred anode materials here are conductive, mixed metal oxides. Particular preference is given to indium tin oxide (ITO) or indium zinc oxide (IZO). Preference is furthermore given to conductive, doped organic materials, in particular conductive, doped polymers, such as, for example, poly(ethylenedioxythiophene) (PEDOT) and polyaniline (PANI) or derivatives of these polymers. It is furthermore preferred for a p-doped hole-transport material to be applied as hole-injection layer to the anode, where suitable p-dopants are metal oxides, for example MoO 3  or WO 3 , or (per)fluorinated electron-deficient aromatic compounds. Further suitable p-dopants are HAT-CN (hexacyanohexaazatriphenylene) or the compound NDP9 from Novaled. A layer of this type simplifies hole injection in materials having a low HOMO, i.e. an HOMO with a large value. 
     In general, all materials as are used for the layers in accordance with the prior art can be used in the further layers, and the person skilled in the art will be able to combine each of these materials with the materials according to the invention in an electronic device without inventive step. 
     The device is correspondingly structured in a manner known per se, depending on the application, provided with contacts and finally hermeti-cally sealed, since the lifetime of such devices is drastically shortened in the presence of water and/or air. 
     The formulations according to the invention and the electronic devices, in particular organic electroluminescent devices, obtainable therefrom are distinguished over the prior art by one or more of the following surprising advantages:
     1. The electronic devices obtainable using the formulations according to the invention exhibit very high stability and a very long lifetime com-pared with electronic devices obtained using conventional methods.   2. The formulations according to the invention can be processed using conventional methods, so that cost advantages can also be achieved thereby.   3. The organic functional materials employed in the formulations according to the invention are not subject to any particular restrictions, enabling the process of the present invention to be employed comprehensively.   4. The coatings obtainable using the formulations of the present invention exhibit excellent quality, in particular with respect to the uniformity of the coating.   

     These above-mentioned advantages are not accompanied by an impairment of the other electronic properties. 
     It should be pointed out that variations of the embodiments described in the present invention fall within the scope of this invention. Each feature disclosed in the present invention can, unless this is explicitly excluded, be replaced by alternative features which serve the same, an equivalent or a similar purpose. Thus, each feature disclosed in the present invention is, unless stated otherwise, to be regarded as an example of a generic series or as an equivalent or similar feature. 
     All features of the present invention can be combined with one another in any way, unless certain features and/or steps are mutually exclusive. This applies, in particular, to preferred features of the present invention. Equally, features of non-essential combinations can be used separately (and not in combination). 
     It should furthermore be pointed out that many of the features, and in particular those of the preferred embodiments of the present invention, are themselves inventive and are not to be regarded merely as part of the embodiments of the present invention. For these features, independent protection can be sought in addition or as an alternative to each invention presently claimed. 
     The teaching on technical action disclosed with the present invention can be abstracted and combined with other examples. 
     The invention is explained in greater detail below with reference to working examples, but without being restricted thereby. 
     The person skilled in the art will be able to use the descriptions to produce further electronic devices according to the invention without the need to employ inventive skill and thus can carry out the invention throughout the range claimed. 
     WORKING EXAMPLES 
     A) Viscosity and Jettability 
     HTL inks were prepared and tested for viscosity and their suitability for inkjet printing. The compositions of the solvent blends used to prepare the inks consist of 1-Phenylnaphthalin (PNA), Cyclohexylhexanoat (CHH) and Pentylbenzol (PYB) and are shown in Table 1. As material for the hole-transport layer, HTM at a concentration of 7 g/l was used. The jetting performance was tested with a Dimatix DMP-2831 printer with a 10 pl Dimatix cartridge. The ligament length and the voltage was recorded for different droplet speeds while keeping the pulse width and the pulse shape constant. Also the maximum drop frequency with stable drop ejection was recorded. The information is collected in table 2. It is clearly visible that the inks have excellent properties for inkjet printing. 
     
       
         
           
               
             
               
                 TABLE 1 
               
             
            
               
                   
               
               
                 Solvent blend for ink preparation. 
               
            
           
           
               
               
               
               
               
            
               
                 Ink 
                 Solvent A 
                 Solvent B 
                 Solvent C 
                 Ratio 
               
               
                   
               
               
                 1 
                 PNA 
                 CHH 
                 PYB 
                 3/70/27 
               
               
                 2 
                 PNA 
                 CHH 
                 PYB 
                 3/50/47 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 2 
               
             
            
               
                   
               
               
                 Result of jetting inks with a Dimatix printhead. 
               
            
           
           
               
               
               
               
            
               
                   
                   
                 Ink 1 
                 Ink 2 
               
               
                   
                   
               
            
           
           
               
               
               
               
               
               
            
               
                   
                 Viscosity at 500 s −1   
                 4.27 
                 mPa*s 
                 3.45 
                 mPa*s 
               
               
                   
                 Voltage at 6 m/s 
                 19.2 
                 V 
                 19.2 
                 V 
               
               
                   
                 Ligament length at 6 m/s 
                 130 
                 μm 
                 110 
                 μm 
               
               
                   
                 Voltage at 8 m/s 
                 22.2 
                 V 
                 22.2 
                 V 
               
               
                   
                 Ligament length at 8 m/s 
                 180 
                 μm 
                 190 
                 μm 
               
               
                   
                 Voltage at 10 m/s 
                 25.7 
                 V 
                 26.5 
                 V 
               
               
                   
                 Ligament length at 10 m/s 
                 220 
                 μm 
                 250 
                 μm 
               
               
                   
                 Maximum jetting frequency 
                 11 
                 kHz 
                 15-16 
                 kHz 
               
               
                   
                   
               
            
           
         
       
     
     B) Film Formation 
     Six emissive layer (EML) inks were made as shown in Table 3. The materials used for green EML were H1, H2 and D1 in a relative ratio of 40/40/20 and for red EML were H1, H2, D1 and D2 in a ratio of 32/40/20/8 at a total concentration of 12 to 20 g/l. The inks were ink-jet printed and film profiles were measured after drying. The solvent 3-phenoxy toluene was chosen as a reference and showed a U-shape film profile ( FIG.  2   ). The film profile shows a significant improvement and a flat film can be achieved by adding 2 additional solvents to 3-phenoxy toluene. In example 2 and example 3, 1-Phenyl-naphthalene and pentylbenzene were added with different ratio, and flat films have been achieved. In example 4, flat red EML has been also achieved by applying red EML with the same solvent mixture as in example 3. It proves the solvent system can be used for various solid materials. 
     Furthermore, pentylbenzene was replaced by heptylbenzene, and a flat green EML has also been achieved, as shown in example 5. In example 6, a green EML with the solvent combination with 1-Ethyl-naphthalene, 1-Phenyl-naphthalene, and Diethylene glycol butyl methyl ether has been tested. As a result, a flat film has been achieved. The solvent combination, ratio for the above examples, and film flatness results were summarized in Table 3. The film flatness measurement and definition is described below. 
     A profile-meter Alpha-step D120 from KLA-Tencor Corporation with a 2 μm stylus was used to measure the film profiles. A flatness factor was calculated by the following formula and used to determine the flatness: 
     
       
         
           
             
               Flatness 
               ⁢ 
                   
               factor 
             
             = 
             
               
                 
                   
                     ❘ 
                     &#34;\[LeftBracketingBar]&#34; 
                   
                   
                     ( 
                     
                       
                         H 
                         edge 
                       
                       - 
                       
                         H 
                         center 
                       
                     
                     ) 
                   
                   
                     ❘ 
                     &#34;\[RightBracketingBar]&#34; 
                   
                 
                 
                   H 
                   center 
                 
               
               × 
               100 
               ⁢ 
               % 
             
           
         
       
     
     where 
     H edge  is the height of pixel edge, and H center  is the height of pixel center, measured across the short axis of the pixel. 
     The film is considered as flat when the flatness factor is equal or smaller than 10%. 
     
       
         
           
               
             
               
                 TABLE 3 
               
             
            
               
                   
               
               
                 Solvent systems used and their corresponding profiles. 
               
            
           
           
               
               
               
               
               
            
               
                   
                   
                   
                 Film 
                   
               
               
                   
                   
                   
                 profile 
                 Flatness 
               
               
                   
                   
                 Ratio 
                 shown 
                 factor 
               
               
                   
                 Solvent(s) 
                 (Vol-%) 
                 in FIG. 
                 (%) 
               
               
                   
                   
               
            
           
           
               
               
               
               
               
            
               
                 Comparative 
                 3-phenoxy toluene 
                 100 
                 2 
                 43 (U- 
               
               
                 Example 1 
                   
                   
                   
                 shape) 
               
               
                 Example 2 
                 3-phenoxy toluene 
                 48 
                 3 
                 9 
               
               
                   
                 1-Phenyl-naphthalene 
                 3 
                   
                 (Flat) 
               
               
                   
                 Pentylbenzene 
                 49 
               
               
                 Example 3 
                 3-phenoxy toluene 
                 49 
                 4 
                 1 
               
               
                   
                 1-Phenyl-naphthalene 
                 2 
                   
                 (Flat) 
               
               
                   
                 Pentylbenzene 
                 49 
               
               
                 Example 4 
                 3-phenoxy toluene 
                 49 
                 5 
                 7 
               
               
                   
                 1-Phenyl naphthalene 
                 2 
                   
                 (flat) 
               
               
                   
                 Pentylbenzene 
                 49 
               
               
                 Example 5 
                 3-phenoxy toluene 
                 70 
                 6 
                 10 
               
               
                   
                 1-Phenyl-naphthalene 
                 2 
                   
                 (flat) 
               
               
                   
                 Heptylbenzene 
                 28 
               
               
                 Example 6 
                 1-Ethyl-naphthalene 
                 70 
                 7 
                 8 
               
               
                   
                 1-Phenyl-naphthalene 
                 3 
                   
                 (flat) 
               
               
                   
                 Diethylene Glycol 
                 27 
               
               
                   
                 Butyl Methyl Ether 
               
               
                   
               
            
           
         
       
     
     C) Solution Stability 
     To evaluate the suitability of the solvent blends towards their use for inks, inks were prepared and monitored under a series of conditions. The materials were weighed in according to the given weight percentages to allow the preparation of 5 ml ink. The solvents were purged with inert gas for 20 minutes and added to the solids. The solution was stirred until dissolution and then filtered. The clear solution were stored in glass bottles under argon in a freezer at 20° C. for two weeks and after letting the samples warm up to room temperature they were checked for visible precipitation. In a parallel experiment the samples were stored in a fridge (600) and in a third case the inks were stored at room temperature. In no case precipitation was observed. This demonstrates that the solvent blend according to the present invention is ideally suited to prepare long-term stable OLED inks. 
     
       
         
           
               
             
               
                 TABLE 4 
               
             
            
               
                   
               
               
                 Prepared inks for the solution stability study 
               
            
           
           
               
               
               
            
               
                 Materials (relative 
                 Concentration 
                 Solvents (relative 
               
               
                 amount in weight %) 
                 of solids (g/l) 
                 amount in Vol %) 
               
               
                   
               
               
                 H3 (99%); D3 (1%) 
                 10 
                 3-PT (80%); PYB (18%); PNA 
               
               
                   
                   
                 (2%) 
               
               
                 H2 (40%); H1 (35%); 
                 12 
                 3-PT (48%); PYB (49%); PNA 
               
               
                 D1 (17%); D2 (8%) 
                   
                 (3%) 
               
               
                 H2 (40%); H1 (40%); 
                 12 
                 3-PT (48%); CHB (49%); PNA 
               
               
                 D1 (20%) 
                   
                 (3%) 
               
               
                 H3 (99%); D3 (1%) 
                 15 
                 3-PT (70%); BB (28%); PNA 
               
               
                   
                   
                 (2%) 
               
               
                 H2 (40%); H1 (40%); 
                 20 
                 3-PT (48%); 4-MANIS (49%); 
               
               
                 D1 (20%) 
                   
                 PNA (3%) 
               
               
                 H2 (40%); H1 (40%); 
                 20 
                 3-PT (48%); PYB (49%); PNA 
               
               
                 D1 (20%) 
                   
                 (3%) 
               
               
                 H2 (40%); H1 (40%); 
                 20 
                 EOT (70%); 4-MANIS (27%); 
               
               
                 D1 (20%) 
                   
                 PNA (3%) 
               
               
                 H2 (40%); H1 (40%); 
                 20 
                 IBAPTE (68%); 4-MANIS 
               
               
                 D1 (20%) 
                   
                 (30%); PNA (2%) 
               
               
                 H2 (40%); H1 (40%); 
                 20 
                 ENA (58%); 4-MANIS (40%); 
               
               
                 D1 (20%) 
                   
                 PNA (2%) 
               
               
                 H2 (40%); H1 (35%); 
                 20 
                 3-PT (48%); 4-MANIS (49%); 
               
               
                 D1 (17%); D2 (8%) 
                   
                 PNA (3%) 
               
               
                 H2 (40%); H1 (35%); 
                 20 
                 3-PT (48%); PYB (49%); PNA 
               
               
                 D1 (17%); D2 (8%) 
                   
                 (3%) 
               
               
                 H2 (40%); H1 (35%); 
                 20 
                 EOT (70%); 4-MANIS (27%); 
               
               
                 D1 (17%); D2(8%) 
                   
                 PNA (3%) 
               
               
                 H2 (40%); H1 (35%); 
                 20 
                 IBAPTE (68%); 4-MANIS 
               
               
                 D1 (17%); D2 (8%) 
                   
                 (30%); PNA (2%) 
               
               
                 H2 (40%); H1 (35%); 
                 20 
                 ENA (58%); 4-MANIS (40%); 
               
               
                 D1 (17%); D2 (8%) 
                   
                 PNA (2%) 
               
               
                 H2 (40%); H1 (40%); 
                 20 
                 ENA (70%); 4-MANIS (29%); 
               
               
                 D1 (20%) 
                   
                 PNA (1%) 
               
               
                 H2 (40%); H1 (40%); 
                 20 
                 ENA (70%); PYB (29%); PNA 
               
               
                 D1 (20%) 
                   
                 (1%) 
               
               
                 H2 (30%); H1 (40%); 
                 20 
                 3-PT (80%); PYB (18%); PNA 
               
               
                 D1 (22%); D2 (8%) 
                   
                 (2%) 
               
               
                 H2 (20%); H1 (60%); 
                 20 
                 3-PT (80%); PYB (18%); PNA 
               
               
                 D1 (20%) 
                   
                 (2%) 
               
               
                 H2 (30%); H1 (40%); 
                 30 
                 3-PT (70%); BB (28%); PNA 
               
               
                 D1 (22%); D2 (8%) 
                   
                 (2%) 
               
               
                 H2 (20%); H1 (60%); 
                 30 
                 3-PT (70%); BB (28%);PNA 
               
               
                 D1 (20%) 
                   
                 (2%) 
               
               
                 H2 (40%); H1 (40%); 
                 50 
                 3-PT (48%); 4-MANIS (49%); 
               
               
                 D1 (20%) 
                   
                 PNA (3%) 
               
               
                 H2 (40%); H1 (40%); 
                 50 
                 3-PT (48%); PYB (48%); PNA 
               
               
                 D1 (20%) 
                   
                 (4%) 
               
               
                 H2 (40%); H1 (40%); 
                 50 
                 EOT (70%); 4-MANIS (26%); 
               
               
                 D1 (20%) 
                   
                 PNA (4%) 
               
               
                 H2 (40%); H1 (40%); 
                 50 
                 IBAPTE (68%); 4-MANIS 
               
               
                 D1 (20%) 
                   
                 (29%); PNA (3%) 
               
               
                 H2 (40%); H1 (40%); 
                 50 
                 ENA (58%); 4-MANIS (39%); 
               
               
                 D1 (20%) 
                   
                 PNA (3%) 
               
               
                 H2 (40%); H1 (35%); 
                 50 
                 3-PT (48%); 4-MANIS (49%); 
               
               
                 D1 (17%); D2 (8%) 
                   
                 PNA (3%) 
               
               
                 H2 (30%); H1 (40%); 
                 50 
                 3-PT (48%); 4-MANIS (49%); 
               
               
                 D1 (22%); D2 (8%) 
                   
                 PNA (3%) 
               
               
                 H2 (40%); H1 (35%); 
                 50 
                 3-PT (48%); PYB (49%); 
               
               
                 D1 (17%); D2 (8%) 
                   
                 PNA (3%) 
               
               
                 H2 (25%); H1 (55%); 
                 20 
                 ENA (70%); BDM (27%); 
               
               
                 D1 (20%) 
                   
                 PNA (3%) 
               
               
                 H2 (25%); H1 (55%); 
                 20 
                 ENA (49%); BB (49%); 
               
               
                 D1 (20%) 
                   
                 PNA (2%) 
               
               
                   
               
               
                 Abbreviations: 
               
               
                 3-PT: 3-Phenoxytoluene 
               
               
                 PNA: 1-Phenylnaphthalene 
               
               
                 BB: Butylbenzoat 
               
               
                 EOT: Ethyl-o-toluate 
               
               
                 ENA: 1-Ethylnaphthalene 
               
               
                 PYB: Pentylbenzene 
               
               
                 CHB: Cyclohexylbenzene 
               
               
                 4-MANIS: 4-Methylanisole 
               
               
                 IBAPTE: p-tolyl isobutyrate 
               
               
                 BDM: Butyl diethylene glycol methyl ether 
               
            
           
         
       
     
     D) Device Performance 
     Description of Fabrication Process: 
     Glass substrates covered with pre-structured ITO and bank material were cleaned using ultrasonication in isopropanol followed by de-ionized water, then dried using an air-gun and a subsequent annealing on a hot-plate at 230° C. for 2 hours. 
     The OLEDs have in principle the following layer structure:
         Substrate,   ITO (50 nm),   Hole injection layer (20 nm),   Hole transporting layer (20 nm),   Emissive layer (EML) (60 nm),   Hole blocking layer (HBL) (10 nm)   Electron transporting layer (ETL 50%, EIL 50%) (40 nm),   Electron injection layer (EIL) (1 nm),   Cathode.       

     The cathode was formed by an aluminium layer with a thickness of 100 nm. 
     A hole-injection layer (HIL) using a hole-transporting, cross-linkable polymer and a p-doping salt was inkjet-printed onto the substrate and dried in vacuum. Corresponding materials have been described, amongst others, in WO 2016/107668, WO 2013/081052 and EP 2325190. HIL inks were prepared at 7 g/l for each example using 1-Ethylnaphthalene: 1-Phenyl-naphthalene (99:1)). The HIL was then annealed at 200° C. for 30 minutes in air. 
     On top of the HIL, a hole-transport layer (HTL) was inkjet-printed, dried in vacuum and annealed at 225° C. for 30 minutes in nitrogen atmosphere. As material for the hole-transport layer, polymer HTM dissolved in 3-Phenoxytoluene: 1-Phenylnaphthalene (97:3) at a concentration of 7 g/l was used. Two green EML inks were made with solvent comparative example 1 and example 2 with 20 g/l (Table 5). The green EML was also inkjet-printed, vacuum dried and annealed at 150° C. for 10 minutes in nitrogen atmosphere. The inkjet printing process for HIL, HTL, and EML, was conducted with Dimatix Pixdro LD50 printer and Q-class printhead with 10 pL drop size. All inkjet printing processes were performed under yellow light and under ambient conditions. 
     
       
         
           
               
               
               
             
               
                 TABLE 5 
               
               
                   
               
               
                 Example 
                 Green EML 
                 Solvent System 
               
               
                   
               
             
            
               
                 Comp. device 
                 H1:H2:D1 (60:20:20) 
                 Comparative example 1 
               
               
                 example 1 
                   
                 (3-phenoxy toluene) 
               
               
                 device example 2 
                 H1:H2:D1 (60:20:20) 
                 Example 2 
               
               
                   
                   
                 (3-phenoxy toluene, 
               
               
                   
                   
                 1-Phenyl-naphthalene 
               
               
                   
                   
                 and pentylbenzene) 
               
               
                   
               
            
           
         
       
     
     The devices were then transferred into a vacuum deposition chamber where the deposition of a common hole blocking layer (HBL), an electron-transport layer (ETL), and a cathode (Al) were applied by thermal evaporation. The electron transport layer can be single electron transport molecule or as in the present case consist of two materials, which were admixed in a certain proportion by volume by co-evaporation. An expression such as ETM1:ETM2 (50%: 50%) here means that material ETM1 was present in the layer in a proportion by volume of 50%, whereas ETM2 was present in the layer in a proportion of 50%. 
     The chemical structure of the materials, including polymer HTM, and green EML, ETL, were presented in Table 6. 
     
       
         
           
               
             
               
                 TABLE 6 
               
               
                   
               
             
            
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 HTM 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 H1 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 H2 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 D1 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 D2 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 ETM1 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 ETM2 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 H3 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
               
                 D3 
               
               
                   
               
            
           
         
       
     
     The OLEDs were characterised by standard methods. For this purpose, the electroluminescence spectra, the current efficiency (measured in cd/A) and the external quantum efficiency (EQE, measured in % at 1000 cd/m 2 ) were determined from current/voltage/luminance characteristic lines (IVL characteristic lines) assuming a Lambertian emission profile. The electroluminescence (EL) spectra were recorded at a luminous density of 1000 cd/m 2  and the CIE 1931 x and y coordinates were then calculated from the EL spectrum. EQE @ 1000 cd/m 2  was defined as the external quantum efficiency at luminous density of 1000 cd/m 2 . For all experiments, the lifetime LT80 was determined. The lifetime LT80 (d 8000 cd/m 2  was defined as the time after which the initial luminous density of 8000 cd/m 2  has dropped by 20%. The device data of various OLEDs was summarized in Table 7. It can be seen that higher device performance and lifetime has been achieved by the Device example 2 using a solvent combination than the Device example 1 using the comparative solvent. It indicates that the improvement in device performance is mainly due to the novality of the solvent combination. 
     
       
         
           
               
             
               
                 TABLE 7 
               
             
            
               
                   
               
               
                 Device date of OLEDs 
               
            
           
           
               
               
               
               
               
            
               
                   
                   
                   
                 Lum. Eff. [cd/A] @ 
                 LT80 [h] @ 
               
               
                 Examples 
                 CIE x 
                 CIE y 
                 1000 cd/m 2   
                 8000 cd/m 2   
               
               
                   
               
            
           
           
               
               
               
               
               
            
               
                 Comp. Device 
                 0.31 
                 0.64 
                 59.0 
                 700 
               
               
                 example 1 
               
               
                 Device example 2 
                 0.31 
                 0.64 
                 66.9 
                 4500