Patent Publication Number: US-4730021-A

Title: Process for preparing aqueous dispersions of acrylic-urethane graft copolymers

Description:
This application is a continuation of application Ser. No. 733,528, filed May 13, 1985, now abandoned. 
    
    
     The present invention relates to a process for preparing aqueous dispersions of urethane-acrylate graft-copolymers and to the thus obtained stable aqueous dispersions, which may be used in waterborne coatings, printing inks, and related applications. 
     Until recently almost all coatings were applied as a solution in an organic solvent, which after evaporation left behind the dried coating on the article to be coated like solvent based acrylates and urethanes. In addition other systems were developed, which are in essence reactive compositions, being essentially free of volatile solvents and containing reactive diluents, which react during the curing process to become part of the coating itself like e.g. unsaturated polyesters. 
     Since the harmfulness of some compounds in these systems (e.g. solvents, reactive diluents, free isocyanates) and their deleterious environmental effects when evaporated became better understood and also the price of organic solvents increased, these systems met with increasing disfavour. 
     In response, those skilled in the art endeavoured to develop coating systems wherein the use of the harmful compounds mentioned before is avoided. Among the most successful systems are the colloidal and aqueous dispersions, containing only a small amount of solvent or no solvent at all. Very interesting types in this field are the acrylate and urethane based dispersions. Acrylates are known to have e.g. good adhesion on a great variety of substrates, a very good weathering resistance, dependent on the composition also a good resistance to chemicals and hydrolysis, a great variety in raw materials and a good compatibility with various cobinders. 
     Drawbacks of the acrylates are for example a rather low solids content in application formulas in view of the viscosity correlation and, with respect to the physically drying types, a rather thermoplastic nature which may induce blocking problems. 
     The urethanes are well-known because of their good mechanical resistance (abrasion, mar, scratch), elasticity/tensile strength, less thermoplastic behaviour than the acrylates, a higher solvent resistance and in the case of two component systems, a higher solids content at lower viscosities in application formulas. 
     As drawbacks can be mentioned a poorer resistance to weathering (yellowing by UV), hydrolysis and alkaline attack. Urethanes generally are more expensive than acrylates are. 
     Although many activities were unfolded in the field of urethane-acrylate combinations such as the 2-component and UV-curing systems in view of possible synergetic effects (combining advantages and concurrently reducing the drawbacks), in these systems still disadvantages as solvent emission, limited potlife and the presence of harmful or toxic reactive diluents remain. 
     Physical combinations of aqueous or colloidal dispersions of both types often will result in unstable formulas. 
     Objective of the present invention is to provide a process for preparing storage stable, gel free, one component aqueous dispersions of urethane-acrylate graftcopolymers (or related reticulate polymers) coming up to the outstanding properties of the 2-component systems, free of toxic volatile compounds, which can be used in coatings, printing inks and related applications. 
     The process according to the invention is therefore characterized in that 
     a. a monoacrylated adduct is prepared by reaction of a polymerizable acrylate containing at least one active hydrogen atom with a diisocyanate to produce an essentially monoacrylated diisocyanate adduct in the presence of excess diisocyanate, the NCO/OH equivalent ratio to produce the adduct is 2:1, 
     b. the thus obtained adduct together with other polyisocyanates is reacted with an organic compound containing at least one active hydrogen atom and an organic compound containing at least one active hydrogen atom and a group capable of forming a salt group, said organic compounds having an average isocyanate-reactive functionality of 2, 
     c. the thus obtained prepolymer is neutralized and is dispersed in water, immediately followed by the addition of a chain extender under obtaining a chain-extended acrylated urethane polymer dispersion, and 
     d. the thus obtained dispersion is used in an emulsionpolymerization under obtaining a stable aqueous dispersion of urethane-acrylate graftcopolymer. 
     The process according to the invention for preparing storage stable aqueous dispersions of urethane-acrylate graftcopolymers has four steps. 
     In the first step essentially a mono-acrylated adduct is prepared. This preparation is usually carried out in a dry atmosphere by reacting an excess of diisocyanate with a hydroxy-acrylate in an equivalent ratio NCO:OH from 2:1, preferably 10:1 to 30:1 at a temperature of about 0°-130° C., preferably 20°-100° C. Preferably no catalyst is used. 
     In the second step the adduct (a selectively prepared mono-acrylated diisocyanate compound), prepared in the first step, also in a dry atmosphere together with other polyisocyanates, consisting of the excess and/or additional, whether or not identical polyisocyanate, is reacted with active hydrogen atoms containing compounds, such as polyoles and polyamines, and with compounds having at least one active hydrogen atom and at least one group capable of salt formation in an equivalent ratio of NCO:OH of 1,2:1 to 2,5:1, preferably 1,6:1 to 2,3:1, at a temperature of about 50°-130° C., preferably 80°-95° C. The salt group equivalent weight should be less than 6000, preferably 200-5000, in order to obtain stable dispersions. 
     To carry out this reaction one may use any of the known catalysts, such as an amine or an organo metal compound, usually a tin compound. The catalyst, if present, is present in any of the conventional and known catalytically effective amounts, sufficient to carry out the urethane synthesis, preferably from 0,001 to 0,1%, by weight. 
     If required, in the third step the partly acrylated urethane prepolymer, prepared in the second step, is diluted with polymerizable compounds, like acrylate monomers, in order to reduce the viscosity. 
     For further handling a prepolymer viscosity of about 10-10.000 mPa.s is preferred to achieve a smooth emulsion polymerization as to be described in the fourth step. Thereafter the prepolymer is converted in a salt form by means of a neutralizing agent, preferably a tertiary amine, at a neutralization percentage of about 50-130% on equivalent base. The neutralization is carried out directly in the prepolymer, followed by dispersion in water, or during the dispersion of the prepolymer in a solution of the neutralization agent in water. Immediately thereafter the chainextension occurs according to conventional procedures. The chain extenders to be used may be defined as active hydrogen atoms containing compounds having at least two active hydrogen atom which are more reactive with NCO-groups than with water, preferably primary and secondary organic amines. Also ammonia may be used. 
     The equivalent ratio between the NCO-groups in the mono-acrylated urethane prepolymer and the active hydrogen atoms in the chain extender should be less than 2:1, preferably 1,0:1 to 1,8:1, to obtain gel-free products. The final chain extended acrylated urethane polymer dispersions should have a solids content of about 20-80%, by weight, preferably 30-40%, by weight. 
     In the fourth step the mono-acrylated urethane dispersion, which is obtained in the third step, is subjected to an emulsion polymerization with acrylate and/or related monomers, to yield a stable urethane-acrylate graft-copolymer. The choice of the solids ratio between the acrylate and the urethane part in this embodiment is arbitrary, for instance ranging from 95:5 to 5:95. 
     The final copolymeer dispersion should have a solids content of 30-70%, by weight, preferably 40%, by weight. The emulsion polymerization techniques to be used according to the invention are also well known techniques, wherein the emulsion polymerization is carried out with or without pressure and in an inert or not inert atmosphere. 
     For the case of description of the subject of the present invention some simplifications have been made, but are not meant as a restriction of the present specification and claims: 
     The term acrylate is meant as being part of the group acrylates, methacrylates and related polymerizable compounds. 
     In the equivalent reaction ratios the OH-group is mentioned as NCO-reactive group. Generally this group is meant as being part of the groups containing active hydrogens according to the Zerewitinoff test. Accordingly active hydrogens include hydrogen atoms attached to oxygen, nitrogen or sulfur and thus useful compounds will include those having at least one of these groups: --OH, --SH, &gt;NH, --NH 2 . 
     Finally for the active hydrogen containing polymerizable vinyl compounds is read (but not limited to) a hydroxy-functional (meth) acrylate. 
     In the first step almost selectively a monoacrylated diisocyanate is obtained. Although not limited thereto, it is according to the invention started from aliphatic diisocyanates, since these compounds perform better in coating compositions in e.g. U.V. stability than the aromatic ones do. 
     For example an adduct based on isophorone diisocyanate (IPDI) and 2-hydroxy-ethyl methacrylate (2-HEMA) showed no free hydroxy-acrylate and only a small amount of diacrylated diisocyanate: generally less than 5% of the total amount of acrylated diisocyanates: ##STR1## 
     Although in the European Patent Application No. 015.593 was claimed that only at low temperatures and low catalyst concentrations mono-acrylated diisocyanates can be made selectively, according to the invention surprisingly a high degree of selectivity is observed, within a reasonable short reaction time. 
     In the patent application mentioned was stated that formation of mono-acrylated diisocyanates can be achieved only if diisocyanates are applied showing different reactivities between NCO-groups, the so called &#34;asymmetrical&#34; diisocyanates like IPDI. 
     Contrary to this statement the inventors surprisingly also succeeded in making mono-acrylated diisocyanates rather selectively by the present procedure; for example with 4,4&#39;-methylene bis (cyclohexylene diisocynate), available from Bayer under the trademark Desmodur W® and 2--HEMA an adduct was made free from monomeric 2--HEMA and containing no more than 10% of the diacrylated compound on the total amount of acrylated diisocyanates. 
     In the light of the emulsion polymerization in step four of the present process, this low content of di-acrylated diisocyanates is necessary in order to avoid as many as possible crosslinking reactions during the polymerization reaction, as well as to avoid possible instabilities because of gel formation due to the mentioned crosslinking reactions. 
     Based on the obtained results a wide variety of diisocyanates may be used. 
     In this respect it should be noted that in the adduct preparation according to the invention preferably diisocyanates should be used. In the use of higher polyisocyanates finally polyurethane chains are formed with random vinyl groups, which may cause gelling because of the cross-linking reactions in the emulsion polymerization step, if the urethane chains contain more than two vinyl groups per chain. 
     The application of commercially available active hydrogen atoms containing polymerizable compounds in the stable aqueous dispersions of the invention is limited to vinyl compounds which are monofunctional with respect to the NCO reactive group like hydroxyacrylates, the mono-acrylic acid esters of glycols, like ethylene glycol monomethacrylate (USSR Pat. No. 933,667), or the mono-esters of 2-methylpropylene glycol (Japanese Patent No. (U) 58/049,339). Difunctional compounds like the mono(meth)acrylic acid ester of a trihydric alcohol as 2,3-dihydroxy propylacrylate (U.S. Pat. No. 4,366,301) and cis-2-butene-1,4 diol (J. Pol. Sci., Pol. Chem. 1982, Vol. 20, No. 10, 2879) may be less appropriate since polyurethane chains will result with statistically distributed vinyl groups, having the above-mentioned disadvantages of an increased chance of gellation due to cross-linking reactions in the emulsion polymerization. 
     The functionality of the reactants in the second and third step is very important for the properties of the acrylated urethane prepolymer and -polymer. If either or both of the reactant types in the prepolymer preparation have a functionality of greater than 2.0 the prepolymer in most instances will be a gel and not be dispersible at all. However, if the average functionality is reduced by using only difunctional reactants or by introducing monofunctional ingredients and in addition the reaction conditions are controlled to limit the molecular weight, a readily dispersible prepolymer will result. 
     Also in the extension step a chain extender, having an average functionality of greater than 2.0 would probably gel such a high molecular weight product, if used in a stoichiometric amount with the unreacted NCO groups in the acrylated urethane prepolymer. Reducing the average functionality e.g. via introducing monofunctional compounds (to a value ≦2.0) gelling can probably be avoided. 
     The chain extenders are preferably water-soluble, although water-dispersible materials may be used. Water-soluble chain extenders are preferred because if the prepolymer is only marginally dispersible, a water-soluble chain extender will enhance the water-dispersibility of the final acrylated urethane polymer. 
     The structure of the extended prepolymer, obtained in step 3., can possess one or two ethylenically unsaturated groups dependent on the reaction conditions, for example when starting from: ##STR2## where: U=a repeating unit consisting of reaction products of the diisocyanate with the chain extender or other active hydrogens containing compounds being present during the prepolymer preparation. 
     n=the degree of polyaddition of the urethane polymer, being equal to zero, unity or a whole number greater than unity. 
     1=a mono-acrylated urethane polymer, terminated by a chain extender. 
     2=a mono-acrylated urethane polymer, but terminated by the reaction of NCO with water, yielding an amine group. 
     3=a diacrylated urethane polymer. 
     From the mono-acrylated urethane polymers urethane-acrylate graftcopolymers may be formed during the emulsion polymerization (step 4), from the diacrylated urethane polymers urethan-acrylate reticulate copolymers. 
     Since both the mono- and diacrylated urethane polymers may be expected to be present in practice, a combination of both types of copolymers will result in step 4. 
     Dissolving the acrylated urethane prepolymer in acrylate monomers, as described in the third step of the procedure of the invention, can be an essential step before carrying out the emulsion polymerization. 
     Omitting this step in the given procedure may result in unstable aqueous dispersion, containing a considerable amount of gel. Also recommendable in this step is the introduction of a small amount of emulsifier, preferably to be added to the water phase before starting dispersing the acrylated urethane prepolymer into the water phase. 
     Introduction in a later stage, e.g. between the extension and the emulsion polymerization, may influence the processing negatively. In addition anionic emulsifiers, such as sodium lauryl sulphate, perform better than non-ionic types or combinations of anionic and non-ionic types do. 
     The process according to the invention results in a smooth processing, thereby yielding low viscous polymer dispersions showing a high degree of acrylate/urethane grafting (i.e. in the form of both graft- and reticulate copolymers): over 90% of the acrylate monomers appeared to be coupled to the acrylated urethane polymer. The grafting efficiency was checked by a soxhlet extraction wherein the graft and/or reticulate copolymers, finally obtained, were subjected to a 24 hours extraction with tetrahydrofuran or isopropylalcohol. 
     A reference sample consisting of a physical blend of vinyl terminated urethane (polymer dispersion) and an acrylate polymer dispersion with the same overall composition as the grafted copolymer was extracted completely during this cycle. 
     The preparation of an adduct, consisting of an essentially mono-acrylated diisocyanate, is very essential to obtain a high grafting efficiency between the acrylate and urethane chains. First making a urethane prepolymer and then coupling to a hydroxy-acrylate monomer (or related NCO reactive monomers) appeared to be less effective. Possibly one may use a suitable adduct, which is not prepared in situ. 
     Since a urethane prepolymer usually contains monomeric diisocyanates--for instance when starting from a NCO:OH equivalent ratio of 2:1, a free diisocyanate content up to 7%, by weight, based on prepolymer, was found--coupling thereof with hydroxy-acrylates will possibly result in a preferred reaction between the free diisocyanate, which shows a higher reactivity. So either the hydroxy-acrylate monomer is coupled to the free NCO-groups of the urethane prepolymer or to the free diisocyanates, in which case the NCO:OH equivalent ratio is very unfavourable: diacrylated diisocyanate may be formed to a larger extent, which can not be incorporated into the urethane chain in the extension step. 
     In addition these low molecular weight compounds will promote crosslinking reactions during the emulsion polymerization because of their bifunctional unsaturation. Besides, these compounds will detract the film formation. 
     Testing the procedure, where the hydroxy-acrylate monomer is added to the urethane prepolymer, in a reference sample, however, neither gellation tendencies nor a higher gel content was found, but the grafting efficiency appeared to be poor: less than about 50% of the acrylate monomers was coupled to the acrylated urethane chain. 
     Also the film formation of this dispersion was poor. 
     The graft and reticulate copolymers, prepared by the process of the invention, show a good storage stability (tested under various conditions), an excellent resistance to hydrolysis in alkaline medium and a good water and solvent repellancy. 
     Polymerizable vinyl compounds having a single reactive hydrogen atom (defined according to the Zerewitinoff test), useful in the process of the present invention, are well-known to those, skilled in the art. Illustrative for these compounds one can name hydroxy-functional acrylates, defined by the formula ##STR3## where X is hydrogen or methyl and R is a divalent alkylene having 2 to 6 carbon atoms. 
     It also includes products such as acrylamides, methacrylamide, N-hydroxymethylacrylamide, N-hydroxymethylmethacrylamide, diethylene glycolacrylate, diethylene glycolmethacrylate and the like, primary and secondary amino group containing acrylate and methacrylate acid esters of the formula: ##STR4## where X is hydrogen or methyl, R 1  is a divalent alkylene having 2 to 6 carbon atoms, R 2  is hydrogen, methyl or a higher alkyl group, and the like. 
     The polyisocyanates useful in the process of the invention can be aliphatic, cycloaliphatic and aromatic or mixtures thereof. Aliphatic c.q. cycloaliphatic polyisocyanates are preferred because of a better UV-/weathering resistance in the final application. 
     In addition, diisocyanates are preferred although also higher polyisocyanates can be used in place of, or in combination with diisocyanates and/or monoisocyanates to achieve an average functionality of 2 in view of possible gel problems when preparing the urethane polymer as described before. 
     Examples of suitable monisocyanates are cyclohexyl isocyanate, phenylisocyanate, toluene isocyanate, isocyanate-ethylmethacrylate and α,α-dimethyl-meta-isopropenyl benzylisocyanate. Examples of suitable (cyclo-)aliphatic diisocyanates are 2,2,4-trimethyl hexamethylene diisocyanate (TMDI), 1,4-tetramethylene diisocyanate, 1,6-hexamethylene diisocyanate (HDI), isophoronediisocyanate (IPDI), 4,4&#39;-methylene-bis-(cyclohexylene diisocyanate), α,α&#39;-xylylene diisocyanate. Examples of suitable aromatic diisocyanates are toluene diisocyanate, 1,4-phenylene diisocyanate, 4,4&#39;-diphenylmethane diisocyanate, meta or para tetramethylxylene diisocyanates. 
     Examples of suitable higher polyisocyanates are 2,4,6-triisocyanate toluene, 4,4&#39;,4&#34;-triisocyanate triphenyl methane, 1,2,4-benzene triisocyanate, biurets of the diisocyanates and the like. 
     The active hydrogen atoms containing organic compounds, defined according to the Zerewitinoff test, suitable in the process of the present invention can be aliphatic, cycloaliphatic, aromatic or mixtures thereof. Functional groups according to the Zerewitinoff test are --OH, --SH, &lt;NH and --NH 2 . 
     The average functionality is, as mentioned before, important in controlling the tendency of the polymer to gel and should be adjusted to a value of 2, when using higher functional compounds, by monofunctional ones. Examples of suitable compounds include polyols, polyamines, amino alcohols, mercapto terminated derivatives, and the like. The polyols, useful in the process of this invention have an average molecular weight from 60 to 6,000, preferably 2 hydroxyl groups and a hydroxyl number of about 20 to 1,000 mg KOH/g. 
     Illustrative of such polyols are: 
     1. aliphatic diols such as ethylene glycol, propane diol, neopentyl glycol, butane diol, hexane diol and the bivalent alcohols with 1,2-alkylene oxide, like ethylene oxide and propylene oxide. 
     2. cycloaliphatic diols, like 1,4-cyclohexane diol, and 4,4&#39;-dihydroxy cyclohexyl 2,2-propane. 
     3. araliphatic bivalent alcohols, containing 1 to 2 etheroxy atoms like bis(ethoxylated) Bisphenol A and bis(propoxylated) Bisphenol A. 
     4. polyether diols, like polyethylene oxide diols, polyethylene oxide propylene oxide diols, polypropylene oxide diols and polytetramethylene oxide diols. 
     5. polyester diols from the alcohols, mentioned under 1, 2 and 3 and polycarboxylic (preferably dicarboxylic) acids and anhydrides thereof, like maleic acid, fumaric acid, mesaconic acid, citraconic acid, itaconic acid, glutaric acid, adipic acid, isophtalic acid and terephtalic acid. 
     6. polyols, based on polycarbonates and polycaprolactones. 
     As suitable polyamines one can mention for instance ethylene diamine, 1,2-propylene diamine, 1,8-methane diamine, isophorone diamine, propane 2,2-cyclohexylamine, N,N&#39;-dimethyl-o-phenylene diamine, N,N&#39;-di-p-tolyl-m-phenylene diamine, p-aminodiphenylamine. 
     Suitable amino-alcohols and mercapto terminated derivatives are e.g. monoethanolamine, 2-hydroxypropylamine, N,N-bis(3-aminopropyl)ethanolamine, p-aminophenol, β-mercapto ethanol and the like. 
     The acrylated urethane prepolymer also contains salt groups, such as acid salt groups, which can be selected from the class consisting of OSO 3   - , --OPO 3 .sup.═, COO - , SO 2  O - , POO -  and PO 3 .sup.═. 
     The prepolymer can be prepared from reactants containing the salt group, or as is more normally the case, the free acid groups, which can be subsequently neutralized after prepolymer formation. 
     Suitable materials for introducing acid groups, when preparing the prepolymer, are organic compounds having at least one active hydrogen atom and at least one group capable of salt formation. Specific examples of these compounds are hydroxy, aminohydroxy, amino and mercaptocarboxylic acids, sulphonic acids, hydroxy and amino sulphonic acids such as dimetylol propionic acid, oxaluric acid, anilido acetic acid, hydroxyethyl propionic acid, dihydroxy maleic acid, dihydroxy tartaric acid, 2,6-dihydroxybenzoic acid, glycollic acid, thioglycollic acid, glycine, alpha alanine, 6-amino caproic acid, 2-hydroxyethane sulphonic acid, 4,6-diamino benzene, 1,3-disulphonic acid, 2-amino diphenylamino sulphonic acid, and the like. 
     Suitable salt forming agents for acid groups containing compounds include inorganic and organic bases such as sodium hydroxides, potassium hydroxide, ammonia and tertiary amines. 
     Suitable chain extenders having at least two active hydrogen atom more reactive with NCO-groups than water are for instance ammonia, primary and secondary amines, preferably diamines, and certain organic polyols, preferably diols. Examplary for these compounds are hydrazine, substituted hydrazines, e.g. dimethylhydrazine, 1,6-hexamethylene bishydrazine, hydrazides of dicarboxylic and disulphonic acids, reaction products of hydrazine with lactones and glycols, ethylene diamine, hexamethylene diamine, isophorone diamine, diaminophenyl methane, ethylene glycol, di-, tri- and tetraethylene glycol, propane 1,2-diol, propane 1,3-diol, neopentyl glycol. Also amino-alcohols and water may be used. 
     During the preparation of the acrylated urethane prepolymer one can have present any of the known catalysts, such as amines and organometal compounds for the urethane reaction. These catalysts are well-known and include triethylene diamine, morpholine, N-ethyl-morpholine, piperazine, triethanolamine, triethylamine, dibutyltin dilaurate, stannous octoate, dioctyltin diacetate, lead octoate, stannous oleate, stannous tallate, dibutyltin oxide, and the like. 
     The acrylated (i.e. acryl terminated) aqueous polyurethane dispersions, finally obtained via the route and based on the ingredients described before, are subjected to an emulsion polymerization. 
     The procedures, used to prepare the emulsion polymers are well-known in the art and generally involve admixing under rapid stirring the comonomer charge with water, surfactants, or emulsifying agents, a polymerization catalyst or initiator and eventually a chain transfer agent. 
     The mixture is then heated to polymerization temperature for the time required to substantially complete the emulsion polymer formation. 
     The polymerization can be carried out in equipment heretofore employed for emulsion polymerization whether or not under pressure, usually in an atmosphere of N 2 , CO 2 , inert gas and the like. 
     Many variations of the general preparative procedure are used to obtain for example lower viscosity, high solids content, improved freeze-thaw stability, etc. 
     The variations include for example the use of the pre-emulsion technique in which the monomer charge is first  emulsified in water using a surfactant and then this pre-emulsion is added to the reaction mixture, which contains the remaining reactants. This procedure is the so-called &#34;feed-addition&#34; system. A variant in this procedure may consist therein, that a part of the monomer is seeded to start the reaction, after a certain reaction period followed by the feed-addition. 
     In this system the polymerization of the monomers is effected by the free radical catalysts (free radical formers or free radical forming systems), of which the half life time is dependent on the temperature. 
     Some well-known catalysts for example become active or decompose at the temperature used during the polymerization (thermal decomposition), others--especially those having a rather long half life time--are activated by means of a reducing agent (chemical decomposition) which, in the absence of oxygen, immediately produces free radicals. These redox couples can be used in feed-addition systems by adding the catalyst to the reaction mixture, being present in the reactor phase, and feeding the reducing agent simultaneously with the (whether or not pre-emulsified) monomer blend to achieve a better control of the polymerization reaction. 
     Other redox systems are based on free radical catalysts in combination with an, eventually chelatable, metal reducing agent, which effect the polymerization reaction already at low temperatures. These systems usually show a reaction exotherm even up to 70° C. or more, during which the polymerization is almost completed. 
     Generally, temperatures used during the polymerization should be sufficient to effect polymerization by activation of the catalyst and double bonds of the monomers. These temperatures should not be too high to cause a run-away reaction and not too low to retard polymerization. 
     In general redox systems perform well at temperatures already from 10° C. and feed-addition systems at temperatures from 50° C. to about 110° C. 
     When applying these emulsion polymerization techniques in the present invention (step 4), the acrylated aqueous polyurethane dispersion is introduced into the reactor phase. 
     The pre-emulsified monomers, if present, being present in the urethane dispersion, can be considered as the seeded part of the monomer feed when applying the seeding/feeding technique. During the emulsion polymerization reaction the acrylated aqueous polyurethane dispersion surprisingly appears to function as a conventional monomer: extraction tests, carried out as described before, indicate that this compound for the greater part is incorporated in the growing acrylate polymer chain. 
     The polymerizable vinyl monomers, useful in the process of the invention, can be nitrile like acrylonitrile, methacrylonitrile; an amide like acrylamide, methacrylamide, n-methylolacrylamide, ethacrylamide; an acrylate like methylacrylate, ethylacrylate, butylacrylate, 2-ethyl hexylacrylate; an alkyl acrylate like methyl methacrylate, ethyl methacrylate, butyl methacrylate; an acid like acrylic acid, methacrylic acid, maleic acid, malonic acid, itaconic acid; an aromatic like styrene, vinyl toluene, α-methyl styrene, methyl vinyl toluene; a pyridine like 2- or 4-vinyl pyridine, 2-methyl-5-pyridine and 5-ethyl-2-vinyl pyridine, and the like and mixtures thereof. 
     It is known that the introduction of small quantities of multifunctional acrylate monomer into the copolymer sometimes improves the properties of coatings resins. Examplary preferred multifunctional acrylate compounds include ethylene glycol diacrylate, glycerol diacrylate, 1,4-cyclohexane-diol-diacrylate, 1,4-benzene-diol dimethacrylate, pentaerythritol triacrylate and the like and mixtures thereof. See for both types of monomers also &#34;Polymer Handbook&#34; second edition, published by John Wiley &amp; Sons, New York, 1974, pages II-105 and II-387. 
     Suitable free radical catalysts are ammonium, sodium and potassium persulphate, bis(2-ethylhexyl)peroxydicarbonate, di-n butyl peroxy-dicarbonate, t-butyl perpivalate, t-butyl hydroperoxide, cumene hydroperoxide, dibenzoyl peroxide, dilauroyl peroxide, 2,2&#39;-azo-bis isobutyronitrile, 2,2&#39;-azobis-2-methylbutyronitrile and the like and mixtures of the same. See also the free radical catalysts as described in p.e. &#34;Polymer Handbook&#34;, mentioned before, and in the Encyclopedia of Polymer Science and Technology&#34;, Interscience Publishers, a division of John Wiley &amp; Sons, Inc., New York, Vol. 2 (1965), Vol. 3 (1965), Vol. 7 (1967) and Vol. 9 (1968). 
     Suitable reducing agents, most commonly used, are for example ascorbic acid, sodium sulphoxylate formaldehyde, thiosulphates, bisulphates, hydrosulphates, water-soluble amines, such as diethylene triamine, triethylene tetramine, and tetraethylene pentamine, and reducing salts as the sulphates of metals, which are capable of existing in more than one valence state like cobalt, iron, nickel, copper, etc. 
     From the many types of chain transfer agents or modifiers been proposed, it is preferred to use the alkyl and/or aralkyl mercaptans having from 8 to 18 carbon atoms, such as n-octyl mercaptan, t-dodecyl mercaptan and so forth and mixtures thereof. 
     Emulsifiers such as soaps, surfactants or dispersing agents, being useful in the process of the invention, are used in amounts sufficient to obtain a stable aqueous dispersion of the water and the monomers together with the dispersed acrylated urethane polymer and can be of the anionic or non-ionic types, commonly employed, as well as mixtures thereof. Generally, the anionic types perform better than the non-ionic types do. 
     Examples of the anionic types are potassium laurate, potassium stearate, potassium oleate, sodium dodecyl sulphate, sodium decyl sulphate, sodium rozinate and the like. 
     Examples of the non-ionic types are ethylene oxide and propylene oxide condensates in general, e.g. straight and branched chain alkyl and alkylaryl polyethylene glycol and polypropylene glycolethers and thioethers. Also substances which are members of a homologous series of alkylphenoxypoly(ethyleneoxy) ethanols and the like approved to be suitable. 
     See also &#34;McCutcheon&#39;s Detergents &amp; Emulsifiers&#34;, 1974, North American Edition, published by McCutcheon&#39;s Division, Allured Publishing Corporation, New Jersey. 
    
    
     The process of the invention is illustrated in more detail by means of the following examples, however, without any limitation thereto. 
     Unless otherwise noted all amounts are indicated in parts by weight. 
     The given equivalent data are gram-equivalents. 
     EXAMPLE I 
     (Comparative example) 
     This example concerns the preparation of an aqueous dispersion of an acrylate/urethane graft/copolymer, where the HEMA is introduced in the reaction mixture after finishing the preparation of the urethane prepolymer. 
     There were charged to a two liter fourneck round bottom flask, equipped with a thermometer, mechanical stirrer, air condenser, dry air or nitrogen blanket, dropping funnel and heating mantle 547.6 grams of 4,4&#39;-methylene bis(cyclohexyl)diisocyanate, 597 grams of a polypropylene glycol having a hydroxyl number of 55.6 mg KOH/g, 338.4 grams of a polypropylene glycol having a hydroxyl number of 111.4 mg KOH/g and 55.4 grams of dimethylol propionic acid. 
     The mixture was mixed during 10 minutes, whereafter 0.2 g dibutyltin dilaurate as catalyst was added. Thereafter the reaction mixture was heated to 55°-65° C., which temperature was increased by the exothermic reaction to 95° C., kept at 95° C. for one hour to complete the reaction and subsequently cooled to about 60° C. At this temperature, while stirring the reaction mixture, 20.4 g of 2-hydroxyethyl methacrylate was added dropwise. The reaction mixture was then stirred and heated at a temperature of 60° C. (±2° C.) for 2 hours. 
     To this mixture were charged 41 g of triethylamine, as neutralizing agent, dissolved in a monomer blend of 100 g of methyl methacrylate and 300 g of N-butylacrylate and reacted for half an hour. After this reaction the acrylate terminated urethane prepolymer, thus obtained, was cooled to about 30°-40° C. 
     In a comparable equipment under a nitrogen blanket (or other inert gas) 296.1 g of the prepolymer, thus obtained, was added over a period of one hour to a reaction mixture containing 619.6 g of demineralized water and 67.3 g of sodium lauryl sulphate (solids content 32%) at ambient temperature. Immediately after finishing the prepolymer feeding 6.5 g of hydrazine monohydrate was added to the obtained dispersion. This mixture was reacted for half an hour, whereafter 2.1 g of potassium persulphate and 2.7 g of sodium bicarbonate, dissolved in 526.3 g of demineralized water, were charged. 
     The reaction mixture, thus obtained, was heated to about 90° C., at which temperature a monomer blend of 119.9 g of methyl methacrylate and 359.9 g of N-butyl methacrylate were added over a period of one hour, whereafter the temperature was maintained at 90° C. for another half an hour. The aqueous acrylate urethane graftcopolymer dispersion, thus obtained, showed the following specifications: 
     
         ______________________________________                                    
solids content         40.20%                                             
pH                     8.23                                               
Brookfield viscosity (25° C.)                                      
                       88 m.Pa.s.                                         
free monomer content   0.50%                                              
coagulum content       0.15%                                              
______________________________________                                    
 
    
     Soxhlet extraction of the dried polymer with tetrahydrofuran over a period of 24 hours left about 62% of not extracted material. Converting this value to a percentage not extracted acrylate compounds on total input of acrylate monomers a value of about 50% was found. So about 50% of the acrylate monomers approved to be coupled to the acrylate terminated urethane polymer. 
     Storage stability: 
     
         ______________________________________                                    
Freeze-thaw             very bad                                          
(7 cycles 8 hours -20° C.                                          
and 16 hours 20° C.)                                               
at 4° C.         bad                                               
(7 cycles of 16 hours 4° C.                                        
and 8 hours 20° C.)                                                
at room temperature (4 weeks)                                             
                        good                                              
at 52° C. (4 weeks                                                 
                        good                                              
______________________________________                                    
 
    
     Because of a bad film formation the film properties could not be determined. 
     EXAMPLE II 
     (Comparative example) 
     Herein the polyurethane dispersion and the acrylate polymer are prepared independently and then they are mixed. 
     The procedure of this preparation is more or less comparable with comparative example I. 
     There are the following modifications: 
     diisocyanate: isophorone diisocyanate 
     the urethane prepolymer was diluted with N-methylpyrrolidone 
     the urethane prepolymer was dispersed without an emulsifier. 
     Components for the urethane prepolymer preparation: 
     
         ______________________________________                                    
N--methypyrrolidone   200.0                                               
isophorone diisocyanate                                                   
                      708.5                                               
polypropylene glycol (OH = 56.0)                                          
                      768.5                                               
polypropylene glycol (OH = 110.0)                                         
                      442.2                                               
dimethylol propionic acid                                                 
                      80.6                                                
dibutyltin dilaurate  0.2                                                 
                      2200.0     g                                        
______________________________________                                    
 
    
     To 2,200.0 g prepolymer are added 33.3 g of 2-hydroxyethyl methacrylate and heated to 50°-60° C., followed by cooling of the acrylated prepolymer after 2 hours reaction. 
     Components for dispersion and extension: 
     
         ______________________________________                                    
prepolymer        876.4                                                   
triethylamine     23.8                                                    
hydrazine monohydrate                                                     
                  28.1                                                    
demineralized water                                                       
                  1071.7                                                  
                  2000.0       g                                          
______________________________________                                    
 
    
     Components acrylate polymer preparation: 
     
         ______________________________________                                    
demineralized water 1064.3                                                
ammonium persulphate                                                      
                    1.7                                                   
sodium laurylsulphate (32%)                                               
                    54.4                                                  
N--butyl methacrylate                                                     
                    650.7                                                 
methyl methacrylate 228.9                                                 
                    2000.0     g                                          
______________________________________                                    
 
    
     Components for mixing the PUR-dispersion with the acrylate polymer: 
     
         ______________________________________                                    
PUR-dispersion   499.8                                                    
acrylate polymer 1084.9                                                   
demineralized water                                                       
                 415.3                                                    
                 2000.0       g                                           
______________________________________                                    
 
    
     Specifications PUR-polyacrylate physical mixture: 
     
         ______________________________________                                    
solids content         35.5%                                              
pH                     8.4                                                
Brookfield viscosity (25° C.)                                      
                       15.0 m.Pa.s.                                       
free monomers content  0.05%                                              
sediment content       0.03%                                              
Soxhlet extraction     3% residue                                         
                       on total input.                                    
______________________________________                                    
 
    
     Film formation: 
     
         ______________________________________                                    
minimum film formation temperature                                        
                         20° C.                                    
appearance               clear,                                           
                         colourless,                                      
                         smooth                                           
______________________________________                                    
 
    
     Film properties: 
     
         ______________________________________                                    
structure            brittle/                                             
                     very breakable                                       
Konig hardness       93 sec                                               
Resistances:                                                              
water                moderate                                             
toluene              bad                                                  
acetone              very bad                                             
ethanol              very bad                                             
N--methylpyrrolidone very bad                                             
Storage stabilities:                                                      
Freeze-thaw          very bad                                             
at 4° C.      bad                                                  
at room temperature  good                                                 
at 52° C.     moderate                                             
______________________________________                                    
 
    
     EXAMPLE III 
     There were charged to a two liter fourneck round bottom flask, equipped with a thermometer, mechanical stirrer, air condenser, dry air or nitrogen blanket, dropping funnel and heating mantle, 557.8 g of 4,4&#39;-methylene bis(cyclohexyl) diisocyanate (Desmodur W®). The reactor phase was then heated to 95° C. at which temperature 18.5 g of 2-hydroxyethyl methacrylate were added dropwise over a period of one hour, which mixture was kept at this temperature for another half an hour and subsequently cooled down to 60° C. The Desmodur W®--HEMA adduct had the following composition (GPC peak area ratio): Desmodur W®/HEMA:HEMA/Desmodur W®/HEMA=90:10. 
     To this mixture were then charged 603.9 g of a polypropylene glycol having a hydroxyl number of 55.6 mg KOH/g, 340 g of a polypropylene glycol having a hydroxyl number of 111.4 mg KOH/g and 62.8 g of dimethylol propionic acid. The mixture was mixed during 10 minutes, whereafter 0.8 g of dibutyltin dilaurate as catalyst was added. 
     Thereafter the reaction mixture was heated to 55°-65° C., which temperature was increased by the exothermic reaction to 95° C., kept at 95° C. for one hour to complete the reaction and subsequently cooled to 60° C. 
     To this mixture were charged 46.5 g of triethylamine, as neutralizing agent, dissolved in a monomer blend of 92.4 g of methyl methacrylate and 277.2 g of N-butyl methacrylate, which mixture was reacted for half an hour and subsequently cooled down to 30°-40° C. 
     In a comparable equipment under a nitrogen (or other inert gas) blanket 316.3 g of the prepolymer, thus obtained, were added over a period of one hour to a reaction mixture containing 530 g of demineralized water and 52.5 g of sodium laurylsulphate (solids content 32%) at ambient temperature. Immediately after finishing the prepolymer feeding 6.8 g of hydrazine monohydrate were added to the obtained dispersion. This mixture was reacted for half an hour, whereafter 2.3 g of potassium persulphate, dissolved in 624.6 g of demineralized water, were charged. 
     The reaction mixture, thus obtained, was heated to about 90° C. under nitrogen (or another inert gas) atmosphere,  sphere, at which temperature a monomer blend of 116.9 g of methyl methacrylate and 350.6 g of N-butyl methacrylate were added over a period of one hour, whereafter the temperature was maintained at 90° C. for another half an hour. The aqueous acrylate urethane graftcopolymer dispersion, thus obtained, showed the following specifications: 
     
         ______________________________________                                    
solids content       39.6%                                                
pH                   7.47                                                 
Brookfield viscosity (25° C.)                                      
                     86 m.Pa.s.                                           
free monomer content 0.20%                                                
coagulum content     0.04%                                                
Soxhlet extraction   76% residue on                                       
                     total output,                                        
                     (corresponding                                       
                     with 76% acrylate                                    
                     on acrylate input)                                   
______________________________________                                    
 
    
     Storage stabilities: 
     
         ______________________________________                                    
Freeze-thaw             very bad                                          
(7 cycles of 8 hours -20° C.                                       
and 16 hours 20° C.)                                               
at 4° C.         bad                                               
(7 cycles of 16 hours 4° C.                                        
and 8 hours 20° C.)                                                
at room temperature (4 weeks)                                             
                        good                                              
at 52° C. (4 weeks)                                                
                        very good                                         
______________________________________                                    
 
    
     Film formation: 
     
         ______________________________________                                    
minimum film formation temperature                                        
                         &lt;18° C.                                   
appearance               clear,                                           
                         smooth,                                          
                         colourless.                                      
______________________________________                                    
 
    
     Film properties: 
     
         ______________________________________                                    
structure             tough,                                              
                      flexible,                                           
                      not elastic                                         
Konig hardness        60 sec                                              
Resistances:                                                              
water                 bad                                                 
toluene               bad                                                 
acetone               moderate                                            
ethanol               good                                                
N--methylpyrrolidone  bad.                                                
______________________________________                                    
 
    
     EXAMPLE IV 
     The procedure was identical to example III; the urethane polymer, however, was based on isophorone diisocyanate. 
     Components for the partially acrylated urethane prepolymer (given in grams): 
     
         ______________________________________                                    
isophorone diisocyanate                                                   
                    486.7                                                 
2-hydroxy ethyl methacrylate                                              
                    18.9                                                  
polypropylene glycol                                                      
                    648.8                                                 
(OH = 55.6 mg KOH/g)                                                      
polypropylene glycol                                                      
                    391.7                                                 
(OH = 108.7 mg KOH/g)                                                     
dimethylol propionic acid                                                 
                    69.1                                                  
dibutyltin dilaurate                                                      
                    0.8                                                   
triethylamine       7.4                                                   
methyl methacrylate 94.2                                                  
N--butyl methacrylate                                                     
                    282.4                                                 
                    2000.0     g                                          
______________________________________                                    
 
    
     The isophorone diisocyanate-HEMA adduct had the following composition (GPC peak area ratio): IPDI/HEMA:HEMA/IPDI/HEMA=95:5. 
     The prepolymer thus obtained was dispersed and extended comparably to example III. 
     Components (in grams): 
     
         ______________________________________                                    
prepolymer          295.6                                                 
hydrazine monohydrate                                                     
                    5.5                                                   
sodium laurylsulphate (32%)                                               
                    48.9                                                  
demineralized water 492.3                                                 
                    842.3      g                                          
______________________________________                                    
 
    
     Also according to the procedure, described in example III, this aqueous acrylate terminated polyurethane dispersion was copolymerized with acrylate monomers, components (in grams): 
     
         ______________________________________                                    
acrylated PU-dispersion                                                   
                  842.3                                                   
methyl methacrylate                                                       
                  122.6                                                   
N--butyl methacrylate                                                     
                  367.7                                                   
potassium persulphate                                                     
                  2.7                                                     
demineralized water                                                       
                  664.7                                                   
                  2000.0       g                                          
______________________________________                                    
 
    
     The aqueous acrylate urethane graftcopolymer dispersion, finally obtained, showed the following specifications: 
     
         ______________________________________                                    
solids content       39.6%                                                
pH                   7.6                                                  
Brookfield viscosity (25° C.)                                      
                     28 m.Pa.s.                                           
free monomer content 0.15%                                                
coagulum content     &lt;0.02%                                               
Soxhlet extraction   88% residue                                          
                     on total input,                                      
                     (corresponding                                       
                     with 88% acrylates                                   
                     on acrylate input).                                  
______________________________________                                    
 
    
     Storage stabilities: 
     
         ______________________________________                                    
Freeze-thaw           very good                                           
at 4° C.       very good                                           
at room temperature   very good                                           
at 52° C.      very good                                           
______________________________________                                    
 
    
     Film formation: 
     
         ______________________________________                                    
minimum film formation temperature range                                  
                          23-25° C.                                
appearance                clear,                                          
                          colourless,                                     
                          smooth.                                         
______________________________________                                    
 
    
     Film properties: 
     
         ______________________________________                                    
Structure             tough,                                              
                      flexible,                                           
                      not elastic                                         
Konig hardness        86 sec                                              
Resistances                                                               
water                 good                                                
toluene               good                                                
acetone               good                                                
ethanol               good                                                
N--methylpyrrolidone  good                                                
______________________________________                                    
 
    
     EXAMPLE V 
     The procedure was comparable with example III. The following modifications are introduced: 
     Diisocyanate: isophorone diisocyanate 
     In the acrylic part acid fuctionality was incorporated via copolymerization of a slight amount of methacrylic acid: 5%, by weight, on the total amount of monomers. 
     The copolymerization was initiated by the addition of ammonium persulphate to the acrylated PU-dispersion, cumene hydroperoxide to the acrylate monomers to be introduced and by use of an independent reductor feed of i-ascorbinic acid. 
     The acrylate monomers were metered in one hour at 70°-75° C., followed by a post-reaction of half an hour at 75°-80° C. 
     For the copolymerization an additional emulsifier was added; alkylphenoxy poly(ethylene-oxy) ethyl mono- and di-esters of phosphoric acid, commercially available under the name Gafac RE-610®. 
     After the copolymerization the pH was increased to a value of about 8 by means of diluted ammonia. 
     Components for the acrylated urethane prepolymer (in grams): 
     
         ______________________________________                                    
isophorone diisocyanate                                                   
                    486.7                                                 
2-hydroxy ethyl methacrylate                                              
                    18.9                                                  
polypropylene glycol                                                      
                    648.8                                                 
(OH = 55.6 mg KOH/g)                                                      
polypropylene glycol                                                      
                    391.7                                                 
(OH = 108.7 mg KOH/g)                                                     
dimethylol propionic acid                                                 
                    69.1                                                  
dibutyltin dilaurate                                                      
                    0.8                                                   
triethylamine       7.4                                                   
methyl methacrylate 94.2                                                  
N--butyl methacrylate                                                     
                    282.4                                                 
                    2000.0     g                                          
______________________________________                                    
 
    
     The prepolymer, thus obtained, was dispersed and extended comparably to example III. 
     Components (in grams): 
     
         ______________________________________                                    
prepolymer          295.6                                                 
hydrazine monohydrate                                                     
                    5.5                                                   
sodium laurylsulphate (32%)                                               
                    48.9                                                  
demineralized water 492.3                                                 
                    842.3      g                                          
______________________________________                                    
 
    
     To the acrylated PU-dispersion there was added, according to the following components, ammonium persulphate, Gafac RE-610 and demineralized water. After heating the reaction mixture to 70° C. the mixture of N-butyl methacrylate, methyl methacrylate, methacrylic acid and cumene hydroperoxide is added at 70°-75° C. during one hour. Simultaneously, a 1% solution of iso-ascorbic acid is added separately. 
     Hereafter a post-reaction of half an hour was carried out at 75°-80° C. 
     Components (in grams): 
     
         ______________________________________                                    
acrylated PU-dispersion                                                   
                    808.7                                                 
ammonium persulphate                                                      
                    2.7                                                   
Gafac RE-610 (100%) 15.4                                                  
demineralized water 686.8                                                 
N--butyl methacrylate                                                     
                    366.5                                                 
methyl methacrylate 88.5                                                  
methacrylic acid    26.5                                                  
cumene hydroperoxide (80%)                                                
                    3.3                                                   
iso-ascorbic acid   1.6                                                   
                    2000.0     g                                          
______________________________________                                    
 
    
     The urethane acrylate graftcopolymer had the following specifications after adjusting the pH on about 8: 
     
         ______________________________________                                    
solids content        39.4%                                               
pH                    7.8                                                 
Brookfield viscosity (25° C.)                                      
                      15 m.Pa.s.                                          
free monomers content 0.16%                                               
coagulum content      0.02%                                               
Soxhlet extraction    89% residue on                                      
                      total input                                         
                      (corresponding                                      
                      with 89%                                            
                      acrylates on                                        
                      acrylate input)                                     
______________________________________                                    
 
    
     Storage stabilities: 
     
         ______________________________________                                    
Freeze-thaw           very good                                           
at 4° C.       very good                                           
at room temperature   good                                                
at 52° C.      very good                                           
______________________________________                                    
 
    
     Film formation: 
     
         ______________________________________                                    
minimum film formation temperature range                                  
                         24-26° C.                                 
appearance               clear, colour-                                   
                         less, smooth.                                    
______________________________________                                    
 
    
     Film properties: 
     
         ______________________________________                                    
structure            tough, flexible,                                     
                     not elastic                                          
Konig hardness       90 sec                                               
Resistances:                                                              
water                good                                                 
toluene              moderate                                             
acetone              good                                                 
ethanol              moderate                                             
N--methylpyrrolidone moderate.                                            
______________________________________                                    
 
    
     EXAMPLE VI 
     The procedure is comparable with example III. 
     The following modifications are introduced: 
     Diisocyanate: isophorone diisocyanate. 
     In the urethane prepolymer preparation it is started from a polyester instead of a polyether combination. 
     For the urethane prepolymer preparation 10% N-methylpyrrolidone was required in order to reduce the viscosity. 
     In the copolymerization the acid incorporation, initiation, reaction temperature, reaction time, the use of an additional emulsifier and the pH increase were the same as in example V. 
     The post-reaction was carried out with 17% of the cumene hydroperoxide and 25% of the i-ascorbic acid amount: half an hour at 75°-80° C. 
     Components acrylated urethane prepolymer preparation (in grams): 
     
         ______________________________________                                    
isophorone diisocyanate   394.6                                           
2-hydroxyethyl methacrylate                                               
                          15.4                                            
polyester (adipinic acid/1,6-hexanediol/                                  
                          1029.6                                          
neopentyl glycol OH &amp; Ac = 59.3)                                          
N--methylpyrrolidone      150.0                                           
dimethylol propionic acid 59.4                                            
dibutyltin dilaurate      0.7                                             
N--butyl methacrylate     262.5                                           
methyl methacrylate       87.5                                            
                          2000.0                                          
______________________________________                                    
 
    
     For the isophorone diisocyanate-HEMA adduct the following composition was found (GPC peak area ratio): IPDI/HEMA:HEMA/IPDI/HEMA=95:5. 
     The prepolymer was dispersed and extended according to example III. 
     Components (in grams): 
     
         ______________________________________                                    
prepolymer          300.8                                                 
triethylamine       6.6                                                   
hydrazine monohydrate                                                     
                    4.8                                                   
sodium laurylsulphate (32%)                                               
                    47.5                                                  
demineralized water 457.6                                                 
                    817.3      g                                          
______________________________________                                    
 
    
     Components copolymerization (in grams): 
     
         ______________________________________                                    
acrylated PU-dispersion                                                   
                    817.3                                                 
ammonium persulphate                                                      
                    1.1                                                   
N--butyl methacrylate                                                     
                    226.6                                                 
methyl methacrylate 223.4                                                 
methacrylic acid    26.5                                                  
cumene hydroperoxide (80%)                                                
                    4.0                                                   
iso-ascorbic acid   2.1                                                   
Gafac RE-610 (20%)  124.1                                                 
demineralized water 574.9                                                 
                    2000.0      g                                         
______________________________________                                    
 
    
     The urethane acrylate graftcopolymer had the following specifications after adjusting the pH on a value of about 8: 
     
         ______________________________________                                    
solids content        38.2%                                               
pH                    7.6                                                 
Brookfield viscosity (25° C.)                                      
                      12 m.Pa.s.                                          
free monomers content 0.40%                                               
coagulum content      0.02%                                               
Soxhlet extraction    87% residue on                                      
                      total input.                                        
______________________________________                                    
 
    
     Storage stabilities: 
     
         ______________________________________                                    
Freeze-thaw           good                                                
at 4° C.       good                                                
at room temperature   very good                                           
at 52° C.      very good                                           
______________________________________                                    
 
    
     Film formation: 
     
         ______________________________________                                    
minimum film formation temperature range                                  
                        39-44° C.                                  
appearance              clear, colour-                                    
                        less, moderate,                                   
                        pinholes.                                         
______________________________________                                    
 
    
     Film properties: 
     
         ______________________________________                                    
structure           slightly breakable                                    
Konig hardness      92 sec                                                
Resistances:                                                              
water               very good                                             
toluene             moderate                                              
acetone             good                                                  
ethanol             bad                                                   
N--methylpyrrolidone                                                      
                    moderate.                                             
______________________________________                                    
 
    
     EXAMPLE VII 
     The procedure is comparable with example III. 
     The following modifications are introduced: 
     Diisocyanate: isophorone diisocyanate. 
     Coupling agent: 2-hydroxyethyl acrylate 
     Reaction temperature adduct preparation: 50°-55° C. 
     The acrylate part was composed as follows: styrene/n-butylmethacrylate/methyl methacrylate/methacrylic acid=43.6/48.9/2.5/5.0 (in %, by weight). 
     For the copoplymerization an additional emusifier was added; alkylphenoxy poly(ethylene-oxy)ethyl mono- and diesters of phosphoric acid, commercially available under the name Gafac RE-610®. 
     After the copolymerization a post-reaction was carried out with cumene hydroperoxide and iso-ascorbic acid. Also an additional amount of sodium laurylsulphate was added. Reaction temperature of 60°-65° C., reaction time half an hour. 
     The pH of the copolymer was adjusted to a value of 8 by means of diluted ammonia. 
     Components for the acrylated urethane prepolymer (in grams): 
     
         ______________________________________                                    
isophorone diisocyanate                                                   
                      489.7                                               
2-hydroxyethyl acrylate                                                   
                      17.0                                                
polypropylene glycol (OH = 55.6)                                          
                      647.4                                               
polypropylene glycol (OH = 198.6)                                         
                      396.9                                               
dimethylol propionic acid                                                 
                      69.5                                                
dibutyltin dilaurate  0.8                                                 
N--butyl methacrylate 284.1                                               
methyl methacrylate   94.6                                                
                      2000.0    g                                         
______________________________________                                    
 
    
     For the isophorone diisocyanate-HEA adduct the following composition was found (GPC--peak area ratio): IPDI/HEA:HEA/IPDI/HEA=93:7. 
     Components for the dispersion and extension of the urethane prepolymer (in grams): 
     
         ______________________________________                                    
prepolymer          646.8                                                 
triethylamine       17.7                                                  
hydrazine monohydrate                                                     
                    4.3                                                   
sodium laurylsulphate (32%)                                               
                    109.7                                                 
demineralized water 48.2                                                  
                    826.7      g                                          
______________________________________                                    
 
    
     Components copolymerization (in grams): 
     
         ______________________________________                                    
acrylated PU-dispersion                                                   
                    826.7                                                 
ammonium persulphate                                                      
                    2.7                                                   
N--butyl methacrylate                                                     
                    220.4                                                 
styrene             232.2                                                 
methacrylic acid    26.6                                                  
Gafac RE-610 ® (20%)                                                  
                    76.4                                                  
sodium laurylsulphate (32%)                                               
                    1.7                                                   
cumene hydroperoxide (80%)                                                
                    1.3                                                   
iso-ascorbic acid   1.1                                                   
demineralized water 610.9                                                 
                    2000.0     g                                          
______________________________________                                    
 
    
     The obtained aqueous urethane acrylate dispersion had the following specifications: 
     
         ______________________________________                                    
solids content        39.6%                                               
pH                    8.0                                                 
Brookfield viscosity (25° C.)                                      
                      43.0 m.Pa.s.                                        
free monomers content 0.08%                                               
coagulum content      0.02%                                               
Soxhlet extraction    91%, residue on                                     
                      total input.                                        
______________________________________                                    
 
    
     Storage stabilities: 
     
         ______________________________________                                    
Freeze-thaw             good                                              
at 4° C.         good                                              
at room temperature     good                                              
at 52° C.        good                                              
______________________________________                                    
 
    
     Film formation: 
     
         ______________________________________                                    
minimum film formation temperature range                                  
                         22-30° C.                                 
appearance               clear, a little                                  
                         yellowish,                                       
                         smooth.                                          
______________________________________                                    
 
    
     Film properties: 
     
         ______________________________________                                    
structure            tough, flexible,                                     
                     not elastic                                          
Konig hardness       80 sec                                               
Resistances:                                                              
water                good                                                 
toluene              moderate                                             
acetone              moderate                                             
ethanol              good                                                 
N--methylpyrrolidone moderate.                                            
______________________________________                                    
 
    
     EXAMPLE VIII 
     The procedure is comparable with example III. 
     Modifications: 
     Diisocyanate: toluene diisocyanate. 
     Coupling agent: tertiary butylamino-ethyl methacrylate (TBAEMA). Reaction temperature adduct preparation: 25°-30° C. 
     The initiation, reaction temperature and reaction time in the copolymerization were the same as in example V. 
     The following post-reactions were carried out: 
     a. with 50% of the indicated amount of ammonium presulphate; half an hour reaction at 90° C. 
     b. with sodium sulphoxylate formaldehyde and tertiary butyl hydroperoxide; half an hour at 60°-65° C. 
     Components for the acrylated urethane prepolymer preparation (in grams): 
     
         ______________________________________                                    
toluene diisocyanate   407.6                                              
tertiary butylamino-ethyl methacrylate                                    
                       29.0                                               
polypropylene glycol   688.5                                              
(OH = 55.6 mg KOH/g)                                                      
polypropylene glycol   422.2                                              
(OH = 108.7 mg KOH/g)                                                     
dimethylol propionic acid                                                 
                       73.9                                               
N--butyl methacrylate  284.2                                              
methyl methacrylate    94.6                                               
                       2000.0    g                                        
______________________________________                                    
 
    
     Composition TDI-TBAEMA adduct: TDI/TBAEMA:TBAEMA/TDI/TBAEMA=88:12 (GPC peak area ratio). 
     The prepolymer was dispersed and extended in accordance with example III. 
     
         ______________________________________                                    
prepolymer          284.8                                                 
triethylamine       7.8                                                   
hydrazine monohydrate                                                     
                    4.9                                                   
sodium laurylsulphate (32%)                                               
                    48.3                                                  
demineralized water 488.3                                                 
                    834.1      g                                          
______________________________________                                    
 
    
     Preparation copolymer (procedure according to example III). 
     
         ______________________________________                                    
acrylated PU-dispersion                                                   
                      834.1                                               
ammonium persulphate  2.2                                                 
iso-ascorbic acid     1.6                                                 
cumene hydroperoxide (80%)                                                
                      3.4                                                 
N--butyl methacrylate 763.7                                               
methyl methacrylate   121.2                                               
sodium sulphoxylate formaldehyde                                          
                      1.1                                                 
tertiary butyl hydroperoxide (79%)                                        
                      1.5                                                 
demineralized water   671.2                                               
                      2000.0    g                                         
______________________________________                                    
 
    
     Specifications urethane acrylate dispersion: 
     
         ______________________________________                                    
solids content        37.8%                                               
pH                    7.0                                                 
Brookfield viscosity (25° C.)                                      
                      12.0 m.Pa.s.                                        
free monomers content 1.3%                                                
coagulum content      0.02%                                               
Soxhlet extraction    86% residue on                                      
                      total input.                                        
______________________________________                                    
 
    
     Storage stabilities: 
     
         ______________________________________                                    
Freeze-thaw            very bad                                           
at 4° C.        bad                                                
at room temperature    moderate                                           
at 52° C.       moderate                                           
______________________________________                                    
 
    
     Film formation: 
     
         ______________________________________                                    
minimum film formation temperature                                        
                        &lt;20° C.                                    
appearance              clear, slightly                                   
                        yellowish,                                        
                        smooth.                                           
______________________________________                                    
 
    
     Film properties: 
     
         ______________________________________                                    
structure           tough, flexible,                                      
                    not elastic                                           
Konig hardness      50 sec                                                
Resistances:                                                              
water               moderate                                              
toluene             good                                                  
acetone             good                                                  
ethanol             moderate                                              
N--methylpyrrolidone                                                      
                    moderate                                              
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