Patent Publication Number: US-8968451-B2

Title: Apparatus for concentrating a solution

Description:
BACKGROUND OF THE INVENTION 
     1. Technical Field 
     Presented invention is for a separation apparatus of alcohol water solutions etc., particularly, the concentration apparatus to separate from higher boiling point components to lower boiling point components by atomizing solutions into mist. 
     2. Background Art 
     An apparatus to concentrate and recycle a washing waste solution used in off-set printing has been developed, refer to Patent Document 1. This apparatus can concentrate the washing solution whereby the apparatus atomizes washing waste solution into mist, and the atomized mist is separated by cyclone. The apparatus can concentrate the washing waste solution to remove ink in washing waste solution, soluble components in ink, and machinery oil of rotary press.
     Patent Document 1: JP 2005-131543 A   

     SUMMARY OF INVENTION 
     Problem to be Solved by the Invention 
     The apparatus disclosed in Patent Document 1 concentrates the washing solution to recycle and separate from washing waste solution to machinery oil etc. As washing solution in off-set printing, solvents consisted from volatile compounds are used. The washing solutions after washing printer are contaminated by ink, soluble components in ink, and dirty components from machinery oil of rotary press. Since these contaminated compounds have a property difficult to vaporize, these compounds are separated by evaporation method. As shown in  FIG. 1 , the apparatus disclosed in Patent Document 1 atomizes the washing solution as mist into vaporize  92  with a cyclone shape. The solvent consisted of volatile components in the atomized mist is vaporized and discharged from upward outlet of cyclone vaporizer  92 . Other ink and machinery oil are discharged from downward of vaporizer  92 . The solvent discharged from upward of cyclone vaporizer  92  is cooled at cooling heat exchanger  94  and collected at cyclone condenser  93 . The gas discharged from upward of cyclone condenser  93  is heated at heating heat exchanger  95  and recirculated into ultrasonic atomization chamber  91 . 
     Moreover, the Patent Document 1 also discloses a structure to ultrasonically atomized the washing waste solution into mist and other structure to atomize using spray nozzle  96  as shown in  FIG. 2 . The atomization apparatus of washing waste solution into mist by ultrasonic vibration has a function easy to separate the solvent from contaminated compounds, because the solvents can be easily atomized into mist in comparison with contaminated compounds like machinery oil. However, the apparatus using ultrasonic vibration has an expensive cost due to need ultrasonic oscillators and the power amplifier. Additionally, there is a week point by the higher running cost due to exchange the ultrasonic oscillators at fixed interval. The apparatus using spray nozzles to atomize the washing waste solution into mist will be reduced the equipment cost and running cost. However, since the nozzles just only atomize the whole washing waste solution into the cyclone vaporizer, the only process of atomization from the nozzle can&#39;t separate between solvent and contaminated compounds like machinery oil. Therefore, atomized mist will contains the same concentration of contaminated compounds like machinery oil as the concentration in mist. As mentioned above, there is a week point that nozzle spraying can&#39;t efficiently separate the solvent and contaminated compounds at the vaporizer because nozzle spraying just only atomize the whole washing solution into cyclone vaporizer. 
     The presented invention is developed under purpose to solve the above mentioned week points. 
     The important aim in presented invention is to present the efficient apparatus for concentrating solutions wherein both equipment cost and running cost will be decreased by simple structure that nozzles spray solution into mist. 
     Means to Solve the Problem 
     According to the first aspect of the invention, the apparatus for concentrating solution comprises: 
     a plurality of nozzles  1  to spray a solution into minute particle mist; 
     a gas supplier  2  to supply a carrier gas into the sprayed mist and to transfer mist as gas-mist mixture; and 
     a separator  3  to separate low boiling point component from high boiling point component by supplying gas-mist mixture transferred using the gas supplier  2 , 
     wherein the gas supplier  2  defines a plurality of apertures  9  to supply the carrier gas into the plurality of nozzles  1 , the plurality of nozzles  1  spray mist into the carrier gas supplied from the plurality of apertures  9 . 
     According to the second aspect of the apparatus for concentrating solution, the gas supplier  2  defines a plurality of apertures  9  to supply the carrier gas into each nozzle  1 . 
     According to the third aspect of the apparatus for concentrating solution, the gas supplier  2  comprises a gas pressurizer  6  to compress and flow the carrier gas, and the carrier gas flowed from the gas pressurizer  6  is ejected from the plurality of apertures  9  set around each nozzle  1 . 
     According to the fourth aspect of the apparatus for concentrating solution, the gas supplier  2  defines a plurality of apertures  9  to supply the carrier gas into the plurality of nozzles  1  around the nozzles  1 , and further comprises a gas mist mixer  7 ,  17 ,  27  to generate gas mist mixture that the plurality of nozzles  1  spray mist into the carrier gas supplied from each aperture  9 . 
     According to the fifth aspect of the apparatus for concentrating solution, the gas mist mixer  7 ,  17 ,  27  comprises a chamber plate  8 ,  18 ,  28  in inside, the chamber plate  8 ,  18 ,  28  separates the gas mist mixer  7 ,  17 ,  27  to an inlet side and an outlet side, the plurality of nozzles  1  are fixed on the chamber plate  8 ,  18 ,  28  as spraying mist toward outlet side. 
     According to the sixth aspect of the apparatus for concentrating solution, the chamber plate  8 ,  18 ,  28  defines the aperture  9  as penetrated holes to supply the carrier gas to nozzle  1  around each nozzle  1 . 
     According to the seventh aspect of the apparatus for concentrating solution, each nozzle  1  defines each aperture  9 . 
     According to the eighth aspect of the apparatus for concentrating solution, the plurality of apertures  9  are defined around the nozzle  1 . 
     According to the ninth aspect of the apparatus for concentrating solution, the gas mist mixer  17  comprises the chamber plate  18  two-dimensionally fixed the plurality of nozzles  1  and opened the plurality of apertures  9  around each nozzle  1 . 
     According to the tenth aspect of the apparatus for concentrating solution, an aperture  9  is set between adjacent nozzles  1 . 
     According to the eleventh aspect of the apparatus for concentrating solution, it comprises: 
     a plurality of nozzles  1  to spray a solution into minute particle mist; 
     a gas supplier  2  to supply a carrier gas into the sprayed mist and to transfer mist as gas-mist mixture; and 
     a separator  3  to separate low boiling point component from high boiling point component by supplying gas-mist mixture transferred using the gas supplier  2 . 
     The gas supplier  2  defines a plurality of apertures  39  with slit shape to supply the carrier gas into the plurality of nozzles  1 , the plurality of nozzles  1  spray mist into the carrier gas supplied from the plurality of apertures  39  with slit shape. 
     According to the twelfth aspect of the apparatus for concentrating solution, an aperture  39  is set between adjacent nozzles  1 . 
     According to the thirteenth aspect of the apparatus for concentrating solution, the gas supplier  2  comprises gas mist mixer  37  for gas mist mixture that the plurality of nozzles  1  spray mist into the carrier gas supplied from the aperture  9 , the gas mist mixer  37  comprises a chamber plate  38  in inside, the chamber plate  38  separates the gas mist mixer  37  to an inlet side and an outlet side, the plurality of nozzles  1  are fixed on the chamber plate  38  as spraying mist toward outlet side, and the gas mist mixer  37  comprises the chamber plate  38  fixed the plurality of nozzles  1  and opened aperture  39  with slit shape. 
     According to the fourteenth aspect of the apparatus for concentrating solution, one or plural line(s) apertures  39  with slit shape is/are set between adjacent nozzles  1 . 
     According to the fifteenth aspect of the invention, the apparatus for concentrating solution, comprises: 
     a plurality of nozzles  1  to spray a solution into minute particle mist; 
     a gas supplier  2  to supply a carrier gas into the sprayed mist and to transfer mist as gas-mist mixture; and 
     a separator  3  to separate low boiling point component from high boiling point component by supplying gas-mist mixture transferred using the gas supplier  2 . 
     The nozzle  1  is two fluid nozzle  41  to spray both the solution and the carrier gas, the gas supplier  2  supplies the carrier gas to the two fluid nozzle  41 , and the nozzle  1  sprays gas mist mixture. 
     According to the sixteenth aspect of the apparatus for concentrating solution, the two fluid nozzle  41  sprays solution supplied from pump  4  into mist by the carrier gas supplied from gas pressurizer  6 . 
     According to the seventeenth aspect of the apparatus for concentrating solution, the two fluid nozzle  41  sprays uncompressed solution into mist by the carrier gas. 
     According to the eighteenth aspect of the apparatus for concentrating solution, the separator  3  is cyclone  30 , and concentrating low boiling point component containing in the carrier gas ejected from upward outlet  33  of the cyclone  30 . 
     According to the nineteenth aspect of the apparatus for concentrating solution, the separator  3  is demister  40 , and concentrating low boiling point component containing in the carrier gas. 
     According to the twentieth aspect of the apparatus for concentrating solution, cooling and spraying the solution sprayed from the nozzles  1 . 
     According to the 21st aspect of the apparatus for concentrating solution, heating the carrier gas by thermal energy to cool the solution sprayed from the nozzles  1 . 
     According to the 22nd aspect of the apparatus for concentrating solution, concentrated solution is one of alcohol water solution, anti-freezing solution, or petroleum. 
     According to the 23rd aspect of the apparatus for concentrating solution, the carrier gas containing one of hydrogen, argon, or methane. 
     According to the 24th aspect of the apparatus for concentrating solution, the solution is anti-freezing solution containing with water and freezing point depressant, concentrating the anti-freezing solution whereby first component ejected from upward outlet of cyclone  30  is put into water bulk with bubble to remove freezing point depressant from carrier gas and ejected, and second component evacuated from downward outlet of cyclone  30  is recirculated into solution spraying from the nozzle  1 . 
     According to the 25th aspect of the apparatus for concentrating solution, the solution is alcohol water solution, first component ejected from upward outlet of cyclone  30  is coagulated, separated and collected the concentrated alcohol. 
     Effect of the Invention 
     The presented invention discloses properties that the apparatus for concentrating solution can decrease both the equipment cost and running cost according to spray solution by nozzle without using ultrasonic vibration, and the apparatus can efficiently separate and concentrate solution. The reason why nozzles spraying into mist can efficiently separate and concentrate solution is because necessary carrier gas can be efficiently supply to mist sprayed from the plurality of nozzles. In the apparatus defined in the first aspect, the plurality of nozzles have corresponding plural apertures to supply carrier gas, the plurality of nozzles are spraying mist into carrier gas supplied from plural apertures. In apparatus defined in the eleventh aspect, every nozzle accompany corresponding slit aperture supplying carrier gas, the plurality of nozzles are spraying mist into carrier gas supplied from each slit apertures. Moreover, in apparatus defined in the fifteenth aspect, by using two fluid nozzle spraying both solution and carrier gas, the nozzle can spray mist-gas mixture flow by supplied carrier gas into two fluid nozzle from gas supplier. 
     Apparatus for concentrating solution mentioned above can supply the carrier gas into mist sprayed from each nozzle. Therefore, components with lower boiling point in mist sprayed from the nozzle can be efficiently vaporized into simultaneously supplying carrier gas. Apparatus for concentrating solution to separate low boiling point components and high boiling point component from solution using spry atomization of nozzle is utilizing the deference of relative volatility between low boiling point components and high boiling point component. For example, when alcohol-water solution that alcohol with lower boiling point is solved in water with higher boiling point is atomized into mist, low boiling point&#39;s alcohol containing in mist is faster atomized into carrier gas from mist surface than high boiling point&#39;s water, water, is easier remaining in mist solution side that alcohol, so alcohol is separable from water by separating carrier gas containing alcohol from remaining solution mist. 
     As shown in  FIG. 2 , conventional apparatus is spraying solution into mist from plural nozzle  96  and carrier gas is supplied from on the way of duct after mist is sprayed. This structure can&#39;t efficiently evaporate low boiling point components into the supplied carrier gas. Because the supplied carrier gas is immediately saturated by vaporization from the sprayed mist surface in upper stream of carrier gas, therefore in the lower stream of carrier gas, the low boiling point components can&#39;t be vaporized from mist surface or spray nozzles. Corresponding to this problem structure, in apparatus in the presented invention, the carrier gas is equally supplied towards every nozzle from each plural aperture, equally supplied from every slit aperture, or equally supplied towards atomization fields from two-fluid nozzle. Thereby the carrier gas is evenly supplied into atomized mist, the limitation of vaporization and atomization by biased saturation of low boiling point component into carrier gas is canceled. Therefore, apparatus in this invention can be efficiently separate low boiling point component from high boiling point component whereby the low boiling point component in atomized mist is efficiently vaporized into carrier gas. Therefore, apparatus for concentrating solution in this invention has properties that low boiling point component is efficiently separated from high boiling point component while the carrier gas supplying method toward equally every nozzle is simply realized, and the equipment cost is reduced without using ultrasonic vibration. Moreover, the running cost in presented apparatus is remarkably reduced because of no use of ultrasonic oscillators and no exchange of the oscillators. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1  shows a schematic view of conventional apparatus for concentrating solution; 
         FIG. 2  shows a cross sectional view of a status that conventional apparatus for concentrating solution is spraying solution from plural nozzles; 
         FIG. 3  shows a schematic view of apparatus for concentrating solution in concerning with an example of carrying out of presented invention; 
         FIG. 4  shows a schematic view of apparatus for concentrating solution in concerning with other example of carrying out of presented invention; 
         FIG. 5  shows a schematic view of apparatus for concentrating solution in concerning with other example of carrying out of presented invention; 
         FIG. 6  shows a schematic view of apparatus for concentrating solution in concerning with other example of carrying out of presented invention; 
         FIG. 7  shows a perspective view of a structure that plural nozzles are spraying mist of solution into carrier gas; 
         FIG. 8  shows a view of an example of assignment of plural nozzles and plural apertures; 
         FIG. 9  shows a view of other example of assignment of plural nozzles and apertures; 
         FIG. 10  shows a view of other example of assignment of plural nozzles and plural apertures; 
         FIG. 11  shows a view of an example of assignment of plural nozzles and slit apertures; 
         FIG. 12  shows a cross schematic sectional view of an example of two fluid nozzle; and 
         FIG. 13  shows a graph showing a relationship between flow rate of mist-gas mixture and alcohol concentration in exhaust gas Corresponding to temperatures in alcohol solution. 
     
    
    
     DETAILED DESCRIPTION OF THE INVENTION 
     We will explain modes for carrying out in this invention based on drawings. It should be noted that the modes for carrying out as follows are persistently in just only for examples to explain the realization of this invention thought for apparatus for concentrating solution, the presented invention is not restricted under the following examples. 
     Moreover, this disclosure is numbering to elements shown in this embodiment for understandings of the invention claims, the reference numerals are indicated with the elements in figures and embodiment. It should be noted that the elements defined on the claims are not restricted by the elements in the embodiment. 
     Apparatus in presented invention concentrates solution by separating a part of components from solution containing plural components that have various boiling point or physic chemical properties. Examples of the solutions are as follows. The following solutions are aqueous solution, solutes in solvents except for water, or mixtures of plural liquids. 
     (1) Bio mass alcohol, refined sake, beer, wine, vinegar, mirin (sweet sake for cooking), spirits, shochu (Japanese spirits), brandy, whisky and liqueur. 
     (2) Solutions containing a perfume such as pinene, linalool, limonene, or polyphenols, an aromatic component, or a fragrant component. 
     (3) Petroleum 
     (4) Solutions containing an organic compound that is classified as any one of alkane and cycloalkane, which are a saturated hydrocarbon, alkene, cycloalkene, and alkyne, which are an unsaturated hydrocarbon, ether, thioether, and aromatic hydrocarbon, or a compound obtained by bonding these.
 
(5) Solution containing a substance obtained by substituting a halogen(s) for at least one hydrogen atom or functional group of an organic compound that is classified as any one of alkane and cycloalkane, which are a saturated hydrocarbon, alkene, cycloalkene and alkyne, which are an unsaturated hydrocarbon, ether, thioether, and aromatic hydrocarbon, or a bonded compound of these.
 
(6) Solution containing a substance obtained by substituting a hydroxy group(s) for at least one hydrogen atom or functional group of an organic compound that is classified as any one of alkane and cycloalkane, which are a saturated hydrocarbon, alkene, cycloalkene and alkyne, which are an unsaturated hydrocarbon, ether, thioether, and aromatic hydrocarbon, or a bonded compound of these.
 
(7) Solution containing a substance obtained by substituting an amino group(s) for at least one hydrogen atom or functional group of an organic compound that is classified as any one of alkane and cycloalkane, which are a saturated hydrocarbon, alkene, cycloalkene and alkyne, which are an unsaturated hydrocarbon, ether, thioether, and aromatic hydrocarbon, or a bonded compound of these.
 
(8) Solution containing a substance obtained by substituting a carbonyl group(s) for at least one hydrogen atom or functional group of an organic compound that is classified as any one of alkane and cycloalkane, which are a saturated hydrocarbon, alkene, cycloalkene and alkyne, which are an unsaturated hydrocarbon, ether, thioether, and aromatic hydrocarbon, or a bonded compound of these.
 
(9) Solution containing a substance obtained by substituting a carboxyl group(s) for at least one hydrogen atom or functional group of an organic compound that is classified as any one of alkane and cycloalkane, which are a saturated hydrocarbon, alkene, cycloalkene and alkyne, which are an unsaturated hydrocarbon, ether, thioether, and aromatic hydrocarbon, or a bonded compound of these.
 
(10) Solution containing a substance obtained by substituting a nitro group(s) for at least one hydrogen atom or functional group of an organic compound that is classified as any one of alkane and cycloalkane, which are a saturated hydrocarbon, alkene, cycloalkene and alkyne, which are an unsaturated hydrocarbon, ether, thioether, and aromatic hydrocarbon, or a bonded compound of these.
 
(11) Solution containing a substance obtained by substituting a cyano group(s) for at least one hydrogen atom or functional group of an organic compound that is classified as any one of alkane and cycloalkane, which are a saturated hydrocarbon, alkene, cycloalkene and alkyne, which are an unsaturated hydrocarbon, ether, thioether, and aromatic hydrocarbon, or a bonded compound of these.
 
(12) Solution containing a substance obtained by substituting a mercapto group(s) for at least one hydrogen atom or functional group of an organic compound that is classified as any one of alkane and cycloalkane, which are a saturated hydrocarbon, alkene, cycloalkene and alkyne, which are an unsaturated hydrocarbon, ether, thioether, and aromatic hydrocarbon, or a bonded compound of these.
 
(13) Solutions containing a substance obtained by substituting a metal ion(s) for at least one atom of the target substances mentioned in (4) to (12).
 
(14) Solutions containing a substance obtained by substituting an arbitrary molecule(s) of the molecules mentioned in (4) to (12) for an arbitrary hydrogen atom(s), carbon atom(s), or functional group(s) contained in the target substances mentioned in (4) to (12).
 
(15) Coolant containing glycol.
 
(16) Aqueous solution of ammonia.
 
(17) Aqueous solution of inorganic acids.
 
(18) Aqueous solution of organic acids.
 
(19) Aqueous solution of alkali.
 
     The solutions as indicated above can be concentrated by concentration apparatus as shown in  FIG. 3  and  FIG. 6 . The apparatus for concentrating solution in these figures comprises plural nozzles  1  to spray solution into minute mist, gas supplier  2  to transfer gas-mist mixture flow including mist sprayed from the nozzle  1  by supplying of carrier gas, and separator  3  to separate low boiling point components from high boiling point components by supplying of the gas-mist mixture flow transferred by gas supplier  2 . Moreover, apparatus in figures comprises a pump  4  to supply the pressurized solution sprayed from the nozzles  1 . And, the apparatuses in  FIGS. 3 ,  5  and  6  also comprise cooling unit  5  to cool and supply the solution sprayed from the nozzles  1 . The apparatus with spraying from the nozzles  1  while solution is cooled by cooling unit  5  has a property that concentration of component with low boiling point can be elevated higher. It should be noted that apparatus in this invention as shown in  FIG. 4  can be also supply solution into nozzles  1  without cooling unit. Moreover, apparatuses as shown in  FIGS. 3 ,  4 , and  6  employ cyclone  30  as separator  3 , on the other hand, can be also use demister  40  as separator  3  instead of cyclone as shown in  FIG. 5 . 
     Pump  4  is supplying pressurized solution into nozzles  1 . In the case that the pressure of solution supply is higher by pump  4 , the average mist diameter will be smaller sprayed from the nozzles  1 . It should be noted that the average diameter is not varied from only solution pressure by pump but also nozzle structure. From above fact, the pressure into nozzles by pump should be optimized by considering with nozzle structure and mist diameter, the pressure is preferably set more than 0.1 MPa, preferably, more than 0.2 MPa, more preferably, more than 0.3 MPa. If the solution pressure set point into nozzles is higher, pump equipment cost is not only expensive but also the running cost will be elevated by increasing of consumption electric energy. Therefore, the solution pressure set point into nozzles is for example less than 1 MPa, preferably less than 0.8 MPA, more preferably, less than 0.7 MPa. When alcohol water solution or coolant is concentrated, the solution pressure into nozzles is set from 0.3 MPa to 0.6 MPa, preferably. 
     Nozzles  1  are spraying to minute mist atomization from pressurized solution. Nozzles  1  also make solution form the gas-mist mixture flow by atomizing into carrier gas. This gas-mist mixture flow is supplied into cyclone  30  or demister  40  as separator  3 , and separated. 
       FIG. 7  shows a structure that nozzles  1  spray solution into carrier gas. The carrier gas is supplied into nozzles  1  by gas supplier  2 . The gas supplier  2  in  FIG. 7  comprises a gas pressurizer  6  to compress and transfer the carrier gas. The gas pressurizer  6  can be a pressured fan, blower, or air pump. The carrier gas transferred from the gas pressurizer  6  is ejected from plural aperture  9  set around nozzles  1 .  FIG. 7  and  FIG. 8  indicates gas-mist mixture  7  to mix between mist sprayed from plural nozzles  1  and carrier gas supplied from each aperture  9  whereby plural apertures  9  to supply carrier gas to plural nozzles are set around each nozzles  1 . A chamber plate  8  set within this gas mist mixture  7  separates inlet side and outlet side. The plurality of nozzles  1  are fixed two-dimensionally onto the chamber plate  8 . The nozzles  1  are fixed onto the chamber plate  8  as to spray mist toward outlet side. Moreover, the chamber plate  8  is set apertures  9  as penetrated holes around each nozzle  1  to supply the carrier gas to nozzle spraying ranges. As shown in this figure, the structure one aperture  9  is set around one nozzle  1  can be efficiently vaporized low boiling point compounds because mist from each nozzle can be sprayed into fresh carrier gas. 
     Moreover, as shown in  FIG. 9 , the structure that plural apertures  9  are set around one nozzle  1  can more efficiently vaporize low boiling point components sprayed from the nozzle  1 . Gas mist mixer  17  in  FIG. 9  is set  4  apertures as penetrated holes at even intervals around each nozzle  1  while plural nozzles  1  are fixed two dimensionally onto a chamber plate  18 . Fresh air or carrier gas ejected from apertures  9  makes low boiling point components in mist sprayed from a nozzle  1  efficiently vaporize, and it is very important that the fresh air or carrier gas is prevented from saturation by mist sprayed from other nozzles  1 . Therefore, the reason why plural nozzles  1  are supplied the carrier gas from plural apertures  9  is because to spray mist from the nozzles  1  into fresh air or carrier gas makes low boiling point components efficiently vaporize. From the above reason, it is not necessarily that plural apertures  9  are set around all nozzles  1 , for example as shown in  FIG. 10 , the apertures  9  are set between adjacent nozzles, the fresh air or carrier gas can be also supplied to each nozzle  1 . Gas mist mixer  27  in  FIG. 10  is set two-dimensionally plural nozzles  1  onto a chamber plate  28 , while apertures  9  as penetrated holes are opened between nozzles  1 . 
     Moreover, it is not necessarily that plural apertures are set around one nozzle  1 .  FIG. 11  shows that plural nozzles  1  are spraying mist into carrier gas supplied from apertures  39  with a slit shape whereby apertures  9  with a slit shape to supply carrier gas are set around each nozzle  1 .  FIG. 11  shows that the apertures  39  with the slit shape are opened on chamber plate  38  between adjacent nozzles  1 . This gas mist mixer  37  has apertures  39  with the slit shape opened on the chamber plate  38  that is fixed on plural nozzles  1 . One aperture  39  can supply fresh air or carrier gas to plural nozzles  1  because the aperture has an elongated shape. Therefore, one aperture  39  can supply fresh air or carrier gas to plural nozzles  1 . On the other hand, the structure with two-dimensionally arraying plural nozzles can supply fresh air or carrier gas to each nozzle  1  whereby one or plural lines of apertures  39  with the slit shape are set between adjacent nozzles  1 . 
     Additionally, carrying out example as shown in  FIG. 6  uses two-fluid nozzle  41  as nozzle  1  that ejects both solution and carrier gas. Two-fluid nozzle  41  is spraying solution supplied from pump  4  into mist by carrier gas supplied from the gas pressurizer  6 . It is not necessarily that two-fluid nozzle  41  should be supplied solution under positive pressure condition, only the carrier gas can atomize solution into mist. Two-fluid nozzle  41  shown in cross sectional  FIG. 12  sprays the supplied solution into mist by carrier gas. Since two-fluid nozzle  41  sprays solution into mist by carrier gas, low boiling point components can be efficiently vaporized into carrier gas. It is not always necessary that concentrating apparatus using two-fluid nozzle  41  as nozzle  1  has plural nozzle. It should be noted that it can improve the performance by spraying mist from plural two-fluid nozzles. 
     The apparatus for concentrating solution shown in above figures cyclically uses carrier gas. Apparatus for concentrating solution with this cyclical structure uses hydrogen, helium, and nitrogen as carrier gas. Preferably, concentrating apparatus uses hydrogen or helium. While, as carrier gas, hydrogen and helium mixture gas, hydrogen and air mixture gas, helium and air mixture gas, or/and hydrogen, helium and air mixture gas are also used for concentrating apparatus. Moreover, inert gases can be also used for carrier gas. 
     The apparatus for concentrating solution with cyclical structure of carrier gas can prevent from leaking out of solution, because carrier gases are not ejected to outside. Additionally, running cost can be decreased by using hydrogen and/or helium for carrier gas. It should be noted that the apparatus for concentrating solution indicated in this invention is not restricted about these gases as carrier gas in above embodiments, air is also preferable for carrier gas. Air can be used in cyclical structure and non-cyclical structure. In an apparatus for concentrating solution with non-cyclical structure, fresh air is vacuumed by gas supplier and supplied around nozzles. 
     Cooling units as shown in  FIGS. 3 ,  5  and  6  cool solution supplied to nozzles  1 . Moreover, cooling units  5  in figures are heating the carrier gas by thermal energy for cooling. Cooling units as shown in  FIGS. 3 ,  5  and  6  are cooling or heating heat exchangers by latent heat and condensation heat of coolant. This cooling unit  5  comprises compressor  21  to compress vaporized coolant, heating heat exchanger  22  to liquefy the vaporized coolant by radiation of heat of coolant, expansion valve  23  to adiabatic expand the coolant liquefied at heating heat exchanger  22 , and cooling heat exchanger  24  to evaporate the coolant supplied from expansion valve  23  within itself and simultaneously to cool solution in outside by vaporization heat. 
     The apparatuses for concentrating solution in  FIGS. 3 and 6  are cooling solution via solution duct  26  by cooling heat exchanger  24  wherein cooling heat exchanger  24  is thermally connected to solution duct  26  of solution. This structure can quickly cool solution by cooling heat exchanger  24 . Additionally, concentrating apparatus as shown in  FIG. 5  set cooling heat exchanger  24  to solution tank  14  to reserve solution vacuumed by pump  4 . This cooling unit  5  is cooling the solution in solution tank  14  setting cooling heat exchanger  24 . The above cooling heat exchanger  24  is cooling solution, for example from 0 degree Celsius to 20 degree Celsius that the temperature is solution isn&#39;t solidified. By cooling the solution, the concentration of component ejected from upward of cyclone  30  can be elevated. Therefore, for example, in concentrating apparatus for alcohol water solution, the decrease of temperature in solution can elevate the concentration of alcohol ejected from upward of cyclone  30 . Additionally, in the case of anti-freezing solution containing freezing point depressant, the concentration of freezing point depressant in solution from upward of cyclone  30  is decreased, in the other words, the concentration of water in the solution is increased. 
     Moreover, concentrating apparatuses as shown in  FIGS. 3 ,  5 , and  6  are heating carrier gas via duct  25  by heating heat exchanger  22  wherein heating heat exchanger  22  is thermally connected to duct  24  with carrier gas. Carrier gas can elevates the vaporization efficiency of mist sprayed from the nozzles with increasing carrier gas temperature. Because the carrier gas temperature increasing causes increasing of component amount containing in unit carrier gas. Heating heat exchanger  22  is heating carrier gas to 25 to 30 degrees Celsius. It should be noted that heating heat exchanger  22  can also heat carrier gas 15 to 40 degrees Celsius. 
     Cyclone  30  in separator  3  centrifuges the sprayed mist. Therefore, the carrier gas containing mist is flowed into tangential direction of cyclone  30 . The cyclones as shown in  FIGS. 3 ,  4 , and  6  comprise inlet  31  of gas and mist, downward outlet  32  to eject the second component centrifugally down around inner wall of the cyclone, and upward outlet  33  to evacuate up the first component gathering to center of cyclone. Cyclone  30  separate the mist flowed from inlet  31  by centrifugation of inner rotating. The centrifugal force against rotating mist in cyclone  30  is different from the mist diameters. The centrifugal force is proportional to the weight of mist. Therefore, the larger mist is transferred around inner wall of cyclone by larger centrifugal force, fallen down around inner wall and ejected from downward outlet  32 . On the other hand, the smaller mist and the gases vaporized from mist surface have smaller weight, therefore these are gathered to center of cyclone, and evacuated from upward outlet  33 . 
     Additionally, the demister  40  of separator  3  as shown in  FIG. 5  also separate larger mist and smaller mist. The demister makes the carrier gas including mist pass, simultaneously the larger mist impact to the demister and coagulate to larger droplets. The demister makes the smaller diameter mist and the gases from mist surface pass, and evacuates separately from upward of the demister. 
     As the separator  3 , except for cyclone and demister, every means, for example some adsorbents, can be also useful for separation of mist using the deference of diameter or weight of gas-mist mixture. 
     Therefore, when anti-freezing solution containing freezing point depressant like ethylene glycol is sprayed into mist by nozzle  1  and supplied to cyclone  30  by carrier gas, water in mist is vaporized into carrier gas and ejected from upward outlet  33  of cyclone, and freezing point depressant like ethylene glycol which has higher boiling point than that of water is evacuated from downward outlet  32  with mist state, because water is easier vaporized than freezing point depressant like ethylene glycol. Therefore, in the first component ejected from upward outlet  33 , the concentration of freezing point depressant is low, while in the second component evacuated from downward outlet  32 , the concentration of freezing point depressant is high. The carrier gas can be separated from water and freezing point depressant by putting with bubble the first ejected component into water bulk. The carrier gas separated from water and freezing point depressant can be recirculated to cyclone  30  again. Since the concentration of freezing point depressant is high in the second evacuated component from downward outlet  32 , the concentration of freezing point depressant can be elevated by recirculation this second component into solution tank  16 . The apparatus for concentrating solution as shown in  FIG. 4  has water tank  15  to put the first ejected component with bobble. The freezing point depressant and water are removed from carrier gas by putting the first ejected component into this water tank  15 . The carrier gas removed freezing point depressant and water in water tank  15  is recirculated into cyclone  30  from the nozzle  1  by compressor or blower etc. as the gas pressurizer  6 . The apparatus for concentrating solution as shown in  FIG. 4  is more suitable for concentration of freezing, point depressant than water, because freezing point depressant is more difficult to be vaporized that water. 
     The apparatus for concentrating solute that is easier to be vaporized than solvent, for example alcohol water solution, can concentrate alcohol whereby the alcohol in the carrier gas ejected from upward outlet  33  of cyclone  30  is coagulated and separated. When the alcohol water solution is sprayed into mist and supplied into cyclone  30 , the alcohol containing in mist is vaporized into the carrier gas and ejected from upward outlet  33 . Water that is not vaporized is evacuated from downward outlet  32  as mist state. Therefore, concentrated alcohol can be obtained from the first ejected component from upward outlet  33 . 
     The apparatuses for concentrating solution that is easier to be vaporized that water solvent like alcohol etc. are shown in  FIGS. 3 ,  5  and  6 . These apparatuses for concentrating solution have collection portion  50  to collect the first ejected component from upward outlet  33  of cyclone  30  or upward of demister  40 . The collection portion  50  collects the first ejected component by coagulation and separates from carrier gas. Therefore, this collection portion is possible all structures that can collect and make low boiling point component as the first ejected component coagulate. The structure is both that has already developed and will be developed. For example, an embodiment of correction portion is collector to coagulate the component like alcohol etc. contained in carrier gas by cooling, or other embodiment is collector to adsorb the component like alcohol etc. contained in carrier gas onto adsorbent. 
     Collection portion to collect alcohol by cooling carrier gas with alcohol has cooling heat exchanger to coagulate alcohol by cooling carrier gas with alcohol as not shown. This cooling heat exchanger can cool the carrier gas by recirculating coolant or cooling water into heat exchanging pipes. The cooling heat exchanger is more efficient if the heat exchanging pipes are attached fins. This collection portion can collect alcohol component contained in carrier gas as solution. 
     Collection portion to collect alcohol by adsorbing onto adsorbent can collects whereby alcohol adsorbed onto adsorbent is desorbed by heated collection gas and alcohol is coagulated and separated from collection gas containing desorbed alcohol by cooling as not shown. An embodiment of this collection portion comprises rotor set with adsorbent in its void and rotating mechanism for the rotor. The rotor is honeycomb rotor with void that makes carrier gas pass through direction of rotating shaft. As adsorbent, for example, one of or mixture of zeolite, activated carbon, lithia, and silica gel is available. By this collection portion makes rotor rotate at appropriate speed by rotating mechanism, the rotor can be shifted from adsorbing area to adsorb alcohol to desorbing area to collect desorbed alcohol. When rotor is shifted to adsorbing area, alcohol containing in carrier gas is adsorbed onto adsorbent by passing carrier gas with alcohol through the void with adsorbent. When rotor is shifted to desorbing area by rotation, the adsorbed alcohol is desorbed. The desorbed alcohol is collected by cooling collection gas containing alcohol vapor. The carrier gas through adsorbing area of rotor is recirculated to gas supplier. 
     Moreover, the apparatus for concentrating solution as shown in  FIG. 6  elevates the alcohol concentration whereby the first ejected component from upward outlet  33  of cyclone  30  as separator  3  is supplied into second plural cyclones. 
     Particularly, the apparatus in  FIG. 6  has a structure to collect higher concentration alcohol by repeating above process. The apparatus for concentrating solution in  FIG. 6  is supplying the first ejected component from upward outlet  33  of cyclone  30  supplied from the nozzle  1  into plural second cyclones  30 A. Number of this second cyclone  30 A is increased from number of cyclone  30  supplied mist from the nozzle  1 , and the flow volume to a second cyclone is decreased from flow volume to a cyclone  30 . Therefore, this second cyclone  30 A is adopted smaller volume one than cyclone  30  supplied mist from the nozzle  1 . The first ejected component from the first cyclone  30  is supplied into the second cyclone  30 A, centrifuged at each second cyclone  30 A, and ejected as the second ejected component from upward outlet  33 A of second cyclone  30 A. Moreover, the apparatus for concentrating solution in Figure is supplying the second ejected component from upward outlet  33 A of second cyclone  30 A into plural third cyclones  30 B. Number of the third cyclone  30 B is increased from number of second cyclone  30 A, and the flow volume to a third cyclone is decreased from flow volume to a second cyclone. Therefore, this third cyclone  30 B is adopted smaller volume one than second cyclone  30 A. The second ejected component from the second cyclone  30 A is supplied into the third cyclone  30 B, centrifuged at each third cyclone  30 B, and ejected as the third ejected component from upward outlet  33 B of third cyclone  30 B. As described above, the alcohol concentration in ejected component is elevated by repeating separation of ejected component from upward outlet of cyclone. Particularly, the apparatus for concentrating solution has a separation feature that the concentration of alcohol is higher because the volumes of carrier gas supplied to each cyclone are less as repeating plural process of the first cyclone  30  separation process, the second cyclone  30 A separation process, and the third cyclone  30 B separation process. 
       FIG. 13  shows the relationship between flow rate of gas-mist mixture and alcohol concentration in ejected gas against each temperature of 10% alcohol water solution supplied to apparatus. As shown in  FIG. 13 , in the case of lower temperature in alcohol solution, the concentration of alcohol in ejected, gas is higher. From this result, to cool solution supplied into nozzle  1  is effective to separate alcohol as shown in  FIGS. 3 ,  4 , and  6 . Additionally, as shown in figures, it indicates that the alcohol concentration in ejected gas is higher as the flow rate of gas-mist mixture is smaller. Therefore, as the apparatus for concentrating solution shown in  FIG. 6 , alcohol concentration in ejected gas can be elevated by repeating separation processes by plural cyclones and less flow rate of gas-mist mixture. 
     INDUSTRIAL APPLICABILITY 
     In the presented invention, the apparatus for concentrating solution can efficiently concentrate and separate solution by utilization of separation phenomenon low boiling point component from high boiling point component solution is sprayed into mist according to spray solution from the nozzles, while both the equipment cost and the running cost are simultaneously reduced by simple spraying and gas supplying method/structure. 
     DENOTATION OF REFERENCE NUMERALS 
     
         
           1 : nozzle 
           2 : gas supplier 
           3 : separator 
           4 : pump 
           5 : cooling unit 
           6 : gas pressurizer 
           7 : gas mist mixer 
           8 : chamber plate 
           9 : aperture 
           14 : solution tank 
           15 : water tank 
           17 : gas mist mixer 
           18 : chamber plate 
           21 : compressor 
           22 : heating heat exchanger 
           23 : expansion valve 
           24 : cooling heat exchanger 
           25 : duct 
           26 : solution duct 
           27 : gas mist mixer 
           28 : chamber plate 
           30 : cyclone;  30 A: second cyclone;  30 B: third cyclone 
           31 : inlet 
           32 : downward outlet 
           33 : upward outlet;  33 A: upward outlet;  33 B: upward outlet 
           37 : gas mist mixer 
           38 : chamber plate 
           39 : aperture 
           40 : demister 
           41 : two fluid nozzle 
           50 : collection portion 
           91 : ultrasonic atomization chamber 
           92 : vaporizer 
           93 : condenser 
           94 : cooling heat exchanger 
           95 : heating heat exchanger 
           96 : nozzle