Patent Publication Number: US-11380854-B2

Title: Heteroleptic iridium complexes as dopants

Description:
CROSS-REFERENCE TO RELATED APPLICATIONS 
     This application is a continuation of U.S. patent application Ser. No. 14/875,147, filed Oct. 5, 2015, which is a continuation of U.S. patent application Ser. No. 14/156,808 filed Jan. 16, 2014, now U.S. Pat. No. 9,184,397, which is a continuation of U.S. patent application Ser. No. 13/193,221 filed Jul. 28, 2011, now U.S. Pat. No. 8,709,615, and this application is a continuation-in-part of U.S. patent application Ser. No. 16/037,164, filed Jul. 7, 2018, which is a continuation of U.S. patent application Ser. No. 14/225,591, filed Mar. 26, 2014, now U.S. Pat. No. 10,056,566, which is a continuation of U.S. patent application Ser. No. 12/727,615, filed Mar. 19, 2010, now U.S. Pat. No. 8,722,205, which claims priority to U.S. Provisional Application No. 61/162,476, filed Mar. 23, 2009, the entire contents of which are incorporated herein by reference. 
    
    
     PARTIES TO A JOINT RESEARCH AGREEMENT 
     The claimed invention was made by, on behalf of, and/or in connection with one or more of the following parties to a joint university corporation research agreement: Regents of the University of Michigan, Princeton University, The University of Southern California, and the Universal Display Corporation. The agreement was in effect on and before the date the claimed invention was made, and the claimed invention was made as a result of activities undertaken within the scope of the agreement. 
     FIELD OF THE INVENTION 
     The present invention relates to heteroleptic iridium complexes suitable for inclusion in OLED devices. 
     BACKGROUND 
     Opto-electronic devices that make use of organic materials are becoming increasingly desirable for a number of reasons. Many of the materials used to make such devices are relatively inexpensive, so organic opto-electronic devices have the potential for cost advantages over inorganic devices. In addition, the inherent properties of organic materials, such as their flexibility, may make them well suited for particular applications such as fabrication on a flexible substrate. Examples of organic opto-electronic devices include organic light emitting devices (OLEDs), organic phototransistors, organic photovoltaic cells, and organic photodetectors. For OLEDs, the organic materials may have performance advantages over conventional materials. For example, the wavelength at which an organic emissive layer emits light may generally be readily tuned with appropriate dopants. 
     OLEDs make use of thin organic films that emit light when voltage is applied across the device. OLEDs are becoming an increasingly interesting technology for use in applications such as flat panel displays, illumination, and backlighting. Several OLED materials and configurations are described in U.S. Pat. Nos. 5,844,363, 6,303,238, and 5,707,745, which are incorporated herein by reference in their entirety. 
     One application for phosphorescent emissive molecules is a full color display. Industry standards for such a display call for pixels adapted to emit particular colors, referred to as “saturated” colors. In particular, these standards call for saturated red, green, and blue pixels. Color may be measured using CIE coordinates, which are well known to the art. 
     One example of a green emissive molecule is tris(2-phenylpyridine) iridium, denoted Ir(ppy) 3 , which has the following structure: 
     
       
         
         
             
             
         
       
     
     In this, and later figures herein, we depict the dative bond from nitrogen to metal (here, Ir) as a straight line. 
     As used herein, the term “organic” includes polymeric materials as well as small molecule organic materials that may be used to fabricate organic opto-electronic devices. “Small molecule” refers to any organic material that is not a polymer, and “small molecules” may actually be quite large. Small molecules may include repeat units in some circumstances. For example, using a long chain alkyl group as a substituent does not remove a molecule from the “small molecule” class. Small molecules may also be incorporated into polymers, for example as a pendent group on a polymer backbone or as a part of the backbone. Small molecules may also serve as the core moiety of a dendrimer, which consists of a series of chemical shells built on the core moiety. The core moiety of a dendrimer may be a fluorescent or phosphorescent small molecule emitter. A dendrimer may be a “small molecule,” and it is believed that all dendrimers currently used in the field of OLEDs are small molecules. 
     As used herein, “top” means furthest away from the substrate, while “bottom” means closest to the substrate. Where a first layer is described as “disposed over” a second layer, the first layer is disposed further away from substrate. There may be other layers between the first and second layer, unless it is specified that the first layer is “in contact with” the second layer. For example, a cathode may be described as “disposed over” an anode, even though there are various organic layers in between. 
     As used herein, “solution processible” means capable of being dissolved, dispersed, or transported in and/or deposited from a liquid medium, either in solution or suspension form. 
     A ligand may be referred to as “photoactive” when it is believed that the ligand directly contributes to the photoactive properties of an emissive material. A ligand may be referred to as “ancillary” when it is believed that the ligand does not contribute to the photoactive properties of an emissive material, although an ancillary ligand may alter the properties of a photoactive ligand. 
     As used herein, and as would be generally understood by one skilled in the art, a first “Highest Occupied Molecular Orbital” (HOMO) or “Lowest Unoccupied Molecular Orbital” (LUMO) energy level is “greater than” or “higher than” a second HOMO or LUMO energy level if the first energy level is closer to the vacuum energy level. Since ionization potentials (IP) are measured as a negative energy relative to a vacuum level, a higher HOMO energy level corresponds to an IP having a smaller absolute value (an IP that is less negative). Similarly, a higher LUMO energy level corresponds to an electron affinity (EA) having a smaller absolute value (an EA that is less negative). On a conventional energy level diagram, with the vacuum level at the top, the LUMO energy level of a material is higher than the HOMO energy level of the same material. A “higher” HOMO or LUMO energy level appears closer to the top of such a diagram than a “lower” HOMO or LUMO energy level. 
     As used herein, and as would be generally understood by one skilled in the art, a first work function is “greater than” or “higher than” a second work function if the first work function has a higher absolute value. Because work functions are generally measured as negative numbers relative to vacuum level, this means that a “higher” work function is more negative. On a conventional energy level diagram, with the vacuum level at the top, a “higher” work function is illustrated as further away from the vacuum level in the downward direction. Thus, the definitions of HOMO and LUMO energy levels follow a different convention than work functions. 
     More details on OLEDs, and the definitions described above, can be found in U.S. Pat. No. 7,279,704, which is incorporated herein by reference in its entirety. 
     SUMMARY OF THE INVENTION 
     In one aspect, a compound having the formula: 
     
       
         
         
             
             
         
       
     
     Formula I is provided. R 1  and R 2  are optionally linked and the sum of the number of carbon atoms in R 1  and R 2  is at least 2. R 3 , R 4 , R 5 , R 6  are optionally linked, and R a  and R b  represent mono-, di-, tri- or tetra-substitution. X is selected from the group consisting of BR, NR, PR, O, S, Se, C═O, S═O, SO 2 , CRR′, SiRR′, and GeRR′, and R a , R b , R, R′, R 1 , R 2 , R 3 , R 4 , R 5 , and R 6  are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and wherein n is 1 or 2. 
     In one aspect, n is 2. In one aspect, X is O. In one aspect, R 1  is hydrogen and R 2  is alkyl. In another aspect, R 1  is alkyl and R 2  is hydrogen. In one aspect, R 1  and R 2  are alkyl. In one aspect, R 1  and R 2  contain one or more deuterium atoms. In another aspect, R 1  or R 2  are independently selected from the group consisting of branched alkyl, cyclic alkyl, bicyclic alkyl, and multicyclic alkyl. In one aspect, R 1  or R 2  is iso-propyl. 
     In one aspect, R 1  or R 2  contain one or more deuterium atoms. In one aspect, R 3 , R 4 , R 5  and R 6  are independently selected from the group consisting of hydrogen, deuterium, alkyl, aryl, and combinations thereof. In another aspect, at least one of R 3 , R 4 , R 5  and R 6  comprises a branched alkyl, cyclic alkyl, bicyclic alkyl, or a multicyclic alkyl. In one aspect, R 3 , R 4 , R 5  or R 6  contain one or more deuterium atoms. 
     In one aspect, the compound is selected from the group consisting of Compound 53, Compounds 157-159, Compound 165, Compound 174, Compound 175, Compounds 184-185, Compound 314, Compound 321, Compounds 625-628, Compound 633, Compound 643, Compounds 652-653, and Compounds 1145-1146. 
     In one aspect, a first device is provided. The first device comprises a first organic light-emitting device, further comprising an anode, a cathode, and an organic layer, disposed between the anode and the cathode, comprising a compound having the formula: 
     
       
         
         
             
             
         
       
     
     Formula I. R 1  and R 2  are optionally linked and the sum of the number of carbon atoms in R 1  and R 2  is at least 2. R 3 , R 4 , R 5 , R 6  are optionally linked, and R a  and R b  represent mono-, di-, tri- or tetra-substitution. X is selected from the group consisting of BR, NR, PR, O, S, Se, C═O, S═O, SO 2 , CRR′, SiRR′, and GeRR′, and R a , R b , R, R′, R 1 , R 2 , R 3 , R 4 , R 5 , and R 6  are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and wherein n is 1 or 2. 
     In one aspect, the first device is a consumer product. In another aspect, the first device is an organic light-emitting device. In another aspect, the first device comprises a lighting panel. In one aspect, the organic layer is an emissive layer and the compound is an emissive dopant. In another aspect, the organic layer is an emissive layer and the compound is a non-emissive dopant. 
     In one aspect, the organic layer further comprises a host. In another aspect, the host comprises a triphenylene containing benzo-fused thiophene or benzo-fused furan, wherein any substituent in the host is an unfused substituent independently selected from the group consisting of C n H 2n+1 , OC n H 2n+1 , OAr 1 , N(C n H 2n+1 ) 2 , N(Ar 1 )(Ar 2 ), CH═CH—C n H 2n+1 , C≡CHC n H 2n+1 , Ar 1 , Ar 1 —Ar 2 , C n H 2n —Ar 1 , or no substitution, wherein Ar 1  and Ar 2  are independently selected from the group consisting of benzene, biphenyl, naphthalene, triphenylene, carbazole, and heteroaromatic analogs thereof, and wherein n is from 1 to 10. 
     In one aspect, the host has the formula 
     
       
         
         
             
             
         
       
     
     In another aspect, the host is selected from the group consisting of: 
                                           
and combinations thereof.
 
     In one aspect, the host is a metal complex. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1  shows an organic light emitting device. 
         FIG. 2  shows an inverted organic light-emitting device that does not have a separate electron transport layer. 
         FIG. 3  shows a compound of Formula I. 
     
    
    
     DETAILED DESCRIPTION 
     Generally, an OLED comprises at least one organic layer disposed between and electrically connected to an anode and a cathode. When a current is applied, the anode injects holes and the cathode injects electrons into the organic layer(s). The injected holes and electrons each migrate toward the oppositely charged electrode. When an electron and hole localize on the same molecule, an “exciton,” which is a localized electron-hole pair having an excited energy state, is formed. Light is emitted when the exciton relaxes via a photoemissive mechanism. In some cases, the exciton may be localized on an excimer or an exciplex. Non-radiative mechanisms, such as thermal relaxation, may also occur, but are generally considered undesirable. 
     The initial OLEDs used emissive molecules that emitted light from their singlet states (“fluorescence”) as disclosed, for example, in U.S. Pat. No. 4,769,292, which is incorporated by reference in its entirety. Fluorescent emission generally occurs in a time frame of less than 10 nanoseconds. 
     More recently, OLEDs having emissive materials that emit light from triplet states (“phosphorescence”) have been demonstrated. Baldo et al., “Highly Efficient Phosphorescent Emission from Organic Electroluminescent Devices,” Nature, vol. 395, 151-154, 1998; (“Baldo-I”) and Baldo et al., “Very high-efficiency green organic light-emitting devices based on electrophosphorescence,” Appl. Phys. Lett., vol. 75, No. 3, 4-6 (1999) (“Baldo-II”), which are incorporated by reference in their entireties. Phosphorescence is described in more detail in U.S. Pat. No. 7,279,704 at cols. 5-6, which are incorporated by reference. 
       FIG. 1  shows an organic light emitting device  100 . The figures are not necessarily drawn to scale. Device  100  may include a substrate  110 , an anode  115 , a hole injection layer  120 , a hole transport layer  125 , an electron blocking layer  130 , an emissive layer  135 , a hole blocking layer  140 , an electron transport layer  145 , an electron injection layer  150 , a protective layer  155 , and a cathode  160 . Cathode  160  is a compound cathode having a first conductive layer  162  and a second conductive layer  164 . Device  100  may be fabricated by depositing the layers described, in order. The properties and functions of these various layers, as well as example materials, are described in more detail in U.S. Pat. No. 7,279,704 at cols. 6-10, which are incorporated by reference. 
     More examples for each of these layers are available. For example, a flexible and transparent substrate-anode combination is disclosed in U.S. Pat. No. 5,844,363, which is incorporated by reference in its entirety. An example of a p-doped hole transport layer is m-MTDATA doped with F.sub.4-TCNQ at a molar ratio of 50:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. Examples of emissive and host materials are disclosed in U.S. Pat. No. 6,303,238 to Thompson et al., which is incorporated by reference in its entirety. An example of an n-doped electron transport layer is BPhen doped with Li at a molar ratio of 1:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. U.S. Pat. Nos. 5,703,436 and 5,707,745, which are incorporated by reference in their entireties, disclose examples of cathodes including compound cathodes having a thin layer of metal such as Mg:Ag with an overlying transparent, electrically-conductive, sputter-deposited ITO layer. The theory and use of blocking layers is described in more detail in U.S. Pat. No. 6,097,147 and U.S. Patent Application Publication No. 2003/0230980, which are incorporated by reference in their entireties. Examples of injection layers are provided in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety. A description of protective layers may be found in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety. 
       FIG. 2  shows an inverted OLED  200 . The device includes a substrate  210 , a cathode  215 , an emissive layer  220 , a hole transport layer  225 , and an anode  230 . Device  200  may be fabricated by depositing the layers described, in order. Because the most common OLED configuration has a cathode disposed over the anode, and device  200  has cathode  215  disposed under anode  230 , device  200  may be referred to as an “inverted” OLED. Materials similar to those described with respect to device  100  may be used in the corresponding layers of device  200 .  FIG. 2  provides one example of how some layers may be omitted from the structure of device  100 . 
     The simple layered structure illustrated in  FIGS. 1 and 2  is provided by way of non-limiting example, and it is understood that embodiments of the invention may be used in connection with a wide variety of other structures. The specific materials and structures described are exemplary in nature, and other materials and structures may be used. Functional OLEDs may be achieved by combining the various layers described in different ways, or layers may be omitted entirely, based on design, performance, and cost factors. Other layers not specifically described may also be included. Materials other than those specifically described may be used. Although many of the examples provided herein describe various layers as comprising a single material, it is understood that combinations of materials, such as a mixture of host and dopant, or more generally a mixture, may be used. Also, the layers may have various sublayers. The names given to the various layers herein are not intended to be strictly limiting. For example, in device  200 , hole transport layer  225  transports holes and injects holes into emissive layer  220 , and may be described as a hole transport layer or a hole injection layer. In one embodiment, an OLED may be described as having an “organic layer” disposed between a cathode and an anode. This organic layer may comprise a single layer, or may further comprise multiple layers of different organic materials as described, for example, with respect to  FIGS. 1 and 2 . 
     Structures and materials not specifically described may also be used, such as OLEDs comprised of polymeric materials (PLEDs) such as disclosed in U.S. Pat. No. 5,247,190 to Friend et al., which is incorporated by reference in its entirety. By way of further example, OLEDs having a single organic layer may be used. OLEDs may be stacked, for example as described in U.S. Pat. No. 5,707,745 to Forrest et al, which is incorporated by reference in its entirety. The OLED structure may deviate from the simple layered structure illustrated in  FIGS. 1 and 2 . For example, the substrate may include an angled reflective surface to improve out-coupling, such as a mesa structure as described in U.S. Pat. No. 6,091,195 to Forrest et al., and/or a pit structure as described in U.S. Pat. No. 5,834,893 to Bulovic et al., which are incorporated by reference in their entireties. 
     Unless otherwise specified, any of the layers of the various embodiments may be deposited by any suitable method. For the organic layers, preferred methods include thermal evaporation, ink-jet, such as described in U.S. Pat. Nos. 6,013,982 and 6,087,196, which are incorporated by reference in their entireties, organic vapor phase deposition (OVPD), such as described in U.S. Pat. No. 6,337,102 to Forrest et al., which is incorporated by reference in its entirety, and deposition by organic vapor jet printing (OVJP), such as described in U.S. patent application Ser. No. 10/233,470, which is incorporated by reference in its entirety. Other suitable deposition methods include spin coating and other solution based processes. Solution based processes are preferably carried out in nitrogen or an inert atmosphere. For the other layers, preferred methods include thermal evaporation. Preferred patterning methods include deposition through a mask, cold welding such as described in U.S. Pat. Nos. 6,294,398 and 6,468,819, which are incorporated by reference in their entireties, and patterning associated with some of the deposition methods such as ink-jet and OVJD. Other methods may also be used. The materials to be deposited may be modified to make them compatible with a particular deposition method. For example, substituents such as alkyl and aryl groups, branched or unbranched, and preferably containing at least 3 carbons, may be used in small molecules to enhance their ability to undergo solution processing. Substituents having 20 carbons or more may be used, and 3-20 carbons is a preferred range. Materials with asymmetric structures may have better solution processability than those having symmetric structures, because asymmetric materials may have a lower tendency to recrystallize. Dendrimer substituents may be used to enhance the ability of small molecules to undergo solution processing. 
     Devices fabricated in accordance with embodiments of the invention may be incorporated into a wide variety of consumer products, including flat panel displays, computer monitors, televisions, billboards, lights for interior or exterior illumination and/or signaling, heads up displays, fully transparent displays, flexible displays, laser printers, telephones, cell phones, personal digital assistants (PDAs), laptop computers, digital cameras, camcorders, viewfinders, micro-displays, vehicles, a large area wall, theater or stadium screen, or a sign. Various control mechanisms may be used to control devices fabricated in accordance with the present invention, including passive matrix and active matrix. Many of the devices are intended for use in a temperature range comfortable to humans, such as 18 degrees C. to 30 degrees C., and more preferably at room temperature (20-25 degrees C.). 
     The materials and structures described herein may have applications in devices other than OLEDs. For example, other optoelectronic devices such as organic solar cells and organic photodetectors may employ the materials and structures. More generally, organic devices, such as organic transistors, may employ the materials and structures. 
     The terms halo, halogen, alkyl, cycloalkyl, alkenyl, alkynyl, arylkyl, heterocyclic group, aryl, aromatic group, and heteroaryl are known to the art, and are defined in U.S. Pat. No. 7,279,704 at cols. 31-32, which are incorporated herein by reference. 
     In one embodiment, a compound having the formula: 
     
       
         
         
             
             
         
       
     
     Formula I is provided. R 1  and R 2  are optionally linked and the sum of the number of carbon atoms in R 1  and R 2  is at least 2. Thus, both R 1  and R 2  both represent a substituent with at least one carbon. If R 1  does not represent substituent containing carbon, then R 2  must represent a substituent containing at least two carbons and vice versa. R 3 , R 4 , R 5 , R 6  are optionally linked, and R a  and R b  represent mono-, di-, tri- or tetra-substitution. X is selected from the group consisting of BR, NR, PR, O, S, Se, C═O, S═O, SO 2 , CRR′, SiRR′, and GeRR′, and R a , R b , R, R′, R 1 , R 2 , R 3 , R 4 , R 5 , and R 6  are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and wherein n is 1 or 2. 
     In one embodiment, n is 2. In one embodiment, X is O. In one embodiment, R 1  is hydrogen and R 2  is alkyl. In another embodiment, R 1  is alkyl and R 2  is hydrogen. In one embodiment, R 1  and R 2  are alkyl. In another embodiment, R 1  or R 2  are independently selected from the group consisting of branched alkyl, cyclic alkyl, bicyclic alkyl, and multicyclic alkyl. In one embodiment, R 1  or R 2  is iso-propyl. Substitution at the 4- and 5-positions of either pyridine ring in the compounds of Formula I can give rise to compounds with desirable properties such as saturated green emission, high efficiencies, and long device lifetimes when incorporated in OLED devices. The photophysical and device properties of devices incorporating these compounds may be tuned by varying the nature of the substituent at the 4- or 5-position on the pyridine. The 4-position on a pyridine ring in the compound of Formula I is the position occupied by the R 5  or R 1  substituent, whereas the 5-position is the position occupied by the R 4  or R 2  substituent. 
     As used herein, fragments containing the following structure: 
                         
are called DBX groups, i.e. dibenzo X, where X is any of the atoms or groups described herein. Atoms A1-A8 can comprise nitrogen or carbon.
 
     In one embodiment, R 1  or R 2  contain one or more deuterium atoms. In one embodiment, R 1  and R 2  contain one or more deuterium atoms. In one embodiment, R 3 , R 4 , R 5  and R 6  are independently selected from the group consisting of hydrogen, deuterium, alkyl, aryl, and combinations thereof. In another embodiment, at least one of R 3 , R 4 , R 5  and R 6  comprises a branched alkyl, cyclic alkyl, bicyclic alkyl, or a multicyclic alkyl. In one embodiment, R 3 , R 4 , R 5  or R 6  contain one or more deuterium atoms. Without being bound by theory, incorporation of deuterium is thought to improve stability of compounds due the greater bond strength of the carbon-deuterium (C-D) bond versus the carbon-hydrogen (C—H) bond. Therefore, compounds wherein labile C—H bonds are replaced by C-D bonds, higher stability can be expected. Without being bound by theory, it is believed that incorporation of deuterium atoms on the alkyl groups of ligands for iridium complexes, the resulting complexes can have longer device lifetimes. 
     In one embodiment, the compound is selected from the group consisting of: 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     In one embodiment, suitable R 1 -R 6  groups in the compounds of Formula I include the configurations of substituents in Table 1. 
     
       
         
           
               
               
               
               
               
               
               
             
               
                 TABLE 1 
               
               
                   
               
               
                 Compound 
                   
                   
                   
                   
                   
                   
               
               
                 # 
                 R 1   
                 R 2   
                 R 3   
                 R 4   
                 R 5   
                 R 6   
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
            
               
                 1. 
                 H 
                 Ethyl 
                 H 
                 H 
                 H 
                 H 
               
               
                 2. 
                 H 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 H 
               
               
                 3. 
                 H 
                 Ethyl 
                 H 
                 Methyl 
                 H 
                 H 
               
               
                 4. 
                 H 
                 Ethyl 
                 H 
                 H 
                 Methyl 
                 H 
               
               
                 5. 
                 H 
                 Ethyl 
                 H 
                 H 
                 H 
                 Methyl 
               
               
                 6. 
                 H 
                 Ethyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
               
               
                 7. 
                 H 
                 Ethyl 
                 Methyl 
                 H 
                 Methyl 
                 H 
               
               
                 8. 
                 H 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 Methyl 
               
               
                 9. 
                 H 
                 Ethyl 
                 H 
                 Methyl 
                 Methyl 
                 H 
               
               
                 10. 
                 H 
                 Ethyl 
                 H 
                 Methyl 
                 H 
                 Methyl 
               
               
                 11. 
                 H 
                 Ethyl 
                 H 
                 H 
                 Methyl 
                 Methyl 
               
               
                 12. 
                 H 
                 Ethyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
               
               
                 13. 
                 H 
                 Ethyl 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
               
               
                 14. 
                 H 
                 Ethyl 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
               
               
                 15. 
                 H 
                 Ethyl 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 16. 
                 H 
                 Ethyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 17. 
                 H 
                 Ethyl 
                 Ethyl 
                 H 
                 H 
                 H 
               
               
                 18. 
                 H 
                 Ethyl 
                 H 
                 Ethyl 
                 H 
                 H 
               
               
                 19. 
                 H 
                 Ethyl 
                 H 
                 H 
                 Ethyl 
                 H 
               
               
                 20. 
                 H 
                 Ethyl 
                 H 
                 H 
                 H 
                 Ethyl 
               
               
                 21. 
                 H 
                 Ethyl 
                 Methyl 
                 Ethyl 
                 H 
                 H 
               
               
                 22. 
                 H 
                 Ethyl 
                 Methyl 
                 H 
                 Ethyl 
                 H 
               
               
                 23. 
                 H 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 Ethyl 
               
               
                 24. 
                 H 
                 Ethyl 
                 H 
                 Ethyl 
                 Methyl 
                 H 
               
               
                 25. 
                 H 
                 Ethyl 
                 H 
                 Ethyl 
                 Ethyl 
                 H 
               
               
                 26. 
                 H 
                 Ethyl 
                 H 
                 Methyl 
                 Ethyl 
                 H 
               
               
                 27. 
                 H 
                 Ethyl 
                 Isopropyl 
                 H 
                 H 
                 H 
               
               
                 28. 
                 H 
                 Ethyl 
                 H 
                 Isopropyl 
                 H 
                 H 
               
               
                 29. 
                 H 
                 Ethyl 
                 H 
                 H 
                 Isopropyl 
                 H 
               
               
                 30. 
                 H 
                 Ethyl 
                 H 
                 H 
                 H 
                 Isopropyl 
               
               
                 31. 
                 H 
                 Ethyl 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
               
               
                 32. 
                 H 
                 Ethyl 
                 Methyl 
                 H 
                 Isopropyl 
                 H 
               
               
                 33. 
                 H 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 Isopropyl 
               
               
                 34. 
                 H 
                 Ethyl 
                 H 
                 Isopropyl 
                 Methyl 
                 H 
               
               
                 35. 
                 H 
                 Ethyl 
                 H 
                 Isopropyl 
                 Isopropyl 
                 H 
               
               
                 36. 
                 H 
                 Ethyl 
                 H 
                 Methyl 
                 Isopropyl 
                 H 
               
               
                 37. 
                 H 
                 Ethyl 
                 H 
                 Isopropyl 
                 Ethyl 
                 H 
               
               
                 38. 
                 H 
                 Ethyl 
                 H 
                 Ethyl 
                 Isopropyl 
                 H 
               
               
                 39. 
                 H 
                 Ethyl 
                 Isobutyl 
                 H 
                 H 
                 H 
               
               
                 40. 
                 H 
                 Ethyl 
                 H 
                 Isobutyl 
                 H 
                 H 
               
               
                 41. 
                 H 
                 Ethyl 
                 H 
                 H 
                 Isobutyl 
                 H 
               
               
                 42. 
                 H 
                 Ethyl 
                 H 
                 H 
                 H 
                 Isobutyl 
               
               
                 43. 
                 H 
                 Ethyl 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
               
               
                 44. 
                 H 
                 Ethyl 
                 Methyl 
                 H 
                 Isobutyl 
                 H 
               
               
                 45. 
                 H 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 Isobutyl 
               
               
                 46. 
                 H 
                 Ethyl 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
               
               
                 47. 
                 H 
                 Ethyl 
                 H 
                 Isobutyl 
                 Isobutyl 
                 H 
               
               
                 48. 
                 H 
                 Ethyl 
                 H 
                 Methyl  
                 Isobutyl 
                 H 
               
               
                 49. 
                 H 
                 Ethyl 
                 H 
                 Isobutyl 
                 Ethyl 
                 H 
               
               
                 50. 
                 H 
                 Ethyl 
                 H 
                 Ethyl  
                 Isobutyl 
                 H 
               
               
                 51. 
                 H 
                 Ethyl 
                 H 
                 Isobutyl 
                 Isopropyl 
                 H 
               
               
                 52. 
                 H 
                 Ethyl 
                 H 
                 Isopropyl 
                 Isobutyl 
                 H 
               
               
                 53. 
                 H 
                 Isopropyl 
                 H 
                 H 
                 H 
                 H 
               
               
                 54. 
                 H 
                 Isopropyl  
                 Methyl 
                 H 
                 H 
                 H 
               
               
                 55. 
                 H 
                 Isopropyl 
                 H 
                 Methyl 
                 H 
                 H 
               
               
                 56. 
                 H 
                 Isopropyl 
                 H 
                 H 
                 Methyl 
                 H 
               
               
                 57. 
                 H 
                 Isopropyl 
                 H 
                 H 
                 H 
                 Methyl 
               
               
                 58. 
                 H 
                 Isopropyl  
                 Methyl 
                 Methyl 
                 H 
                 H 
               
               
                 59. 
                 H 
                 Isopropyl  
                 Methyl 
                 H 
                 Methyl 
                 H 
               
               
                 60. 
                 H 
                 Isopropyl  
                 Methyl 
                 H 
                 H 
                 Methyl 
               
               
                 61. 
                 H 
                 Isopropyl 
                 H 
                 Methyl 
                 Methyl 
                 H 
               
               
                 62. 
                 H 
                 Isopropyl 
                 H 
                 Methyl 
                 H 
                 Methyl 
               
               
                 63. 
                 H 
                 Isopropyl 
                 H 
                 H 
                 Methyl 
                 Methyl 
               
               
                 64. 
                 H 
                 Isopropyl  
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
               
               
                 65. 
                 H 
                 Isopropyl  
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
               
               
                 66. 
                 H 
                 Isopropyl  
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
               
               
                 67. 
                 H 
                 Isopropyl 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 68. 
                 H 
                 Isopropyl  
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 69. 
                 H 
                 Isopropyl  
                 Ethyl 
                 H 
                 H 
                 H 
               
               
                 70. 
                 H 
                 Isopropyl 
                 H 
                 Ethyl 
                 H 
                 H 
               
               
                 71. 
                 H 
                 Isopropyl 
                 H 
                 H 
                 Ethyl 
                 H 
               
               
                 72. 
                 H 
                 Isopropyl 
                 H 
                 H 
                 H 
                 Ethyl 
               
               
                 73. 
                 H 
                 Isopropyl  
                 Methyl 
                 Ethyl 
                 H 
                 H 
               
               
                 74. 
                 H 
                 Isopropyl  
                 Methyl 
                 H 
                 Ethyl 
                 H 
               
               
                 75. 
                 H 
                 Isopropyl  
                 Methyl 
                 H 
                 H 
                 Ethyl 
               
               
                 76. 
                 H 
                 Isopropyl 
                 H 
                 Ethyl 
                 Methyl 
                 H 
               
               
                 77. 
                 H 
                 Isopropyl 
                 H 
                 Ethyl 
                 Ethyl 
                 H 
               
               
                 78. 
                 H 
                 Isopropyl 
                 H 
                 Methyl 
                 Ethyl 
                 H 
               
               
                 79. 
                 H 
                 Isopropyl 
                 Isopropyl 
                 H 
                 H 
                 H 
               
               
                 80. 
                 H 
                 Isopropyl 
                 H 
                 Isopropyl 
                 H 
                 H 
               
               
                 81. 
                 H 
                 Isopropyl 
                 H 
                 H 
                 Isopropyl 
                 H 
               
               
                 82. 
                 H 
                 Isopropyl 
                 H 
                 H 
                 H  
                 Isopropyl 
               
               
                 83. 
                 H 
                 Isopropyl 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
               
               
                 84. 
                 H 
                 Isopropyl 
                 Methyl 
                 H 
                 Isopropyl 
                 H 
               
               
                 85. 
                 H 
                 Isopropyl 
                 Methyl 
                 H 
                 H  
                 Isopropyl 
               
               
                 86. 
                 H 
                 Isopropyl 
                 H 
                 Isopropyl 
                 Methyl 
                 H 
               
               
                 87. 
                 H 
                 Isopropyl 
                 H 
                 Isopropyl 
                 Isopropyl 
                 H 
               
               
                 88. 
                 H 
                 Isopropyl 
                 H 
                 Methyl 
                 Isopropyl 
                 H 
               
               
                 89. 
                 H 
                 Isopropyl 
                 H 
                 Isopropyl 
                 Ethyl 
                 H 
               
               
                 90. 
                 H 
                 Isopropyl 
                 H 
                 Ethyl 
                 Isopropyl 
                 H 
               
               
                 91. 
                 H 
                 Isopropyl 
                 Isobutyl 
                 H 
                 H 
                 H 
               
               
                 92. 
                 H 
                 Isopropyl 
                 H 
                 Isobutyl 
                 H 
                 H 
               
               
                 93. 
                 H 
                 Isopropyl 
                 H 
                 H 
                 Isobutyl 
                 H 
               
               
                 94. 
                 H 
                 Isopropyl 
                 H 
                 H 
                 H 
                 Isobutyl 
               
               
                 95. 
                 H 
                 Isopropyl 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
               
               
                 96. 
                 H 
                 Isopropyl 
                 Methyl 
                 H 
                 Isobutyl 
                 H 
               
               
                 97. 
                 H 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 Isobutyl 
               
               
                 98. 
                 H 
                 Isopropyl 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
               
               
                 99. 
                 H 
                 Isopropyl 
                 H 
                 Isobutyl 
                 Isobutyl 
                 H 
               
               
                 100. 
                 H 
                 Isopropyl 
                 H 
                 Methyl 
                 Isobutyl 
                 H 
               
               
                 101. 
                 H 
                 Isopropyl 
                 H 
                 Isobutyl 
                 Ethyl 
                 H 
               
               
                 102. 
                 H 
                 Isopropyl 
                 H 
                 Ethyl 
                 Isobutyl 
                 H 
               
               
                 103. 
                 H 
                 Isopropyl 
                 H 
                 Isobutyl 
                 Isopropyl 
                 H 
               
               
                 104. 
                 H 
                 Isopropyl 
                 H 
                 Isopropyl 
                 Isobutyl 
                 H 
               
               
                 105. 
                 H 
                 Isobutyl 
                 H 
                 H 
                 H 
                 H 
               
               
                 106. 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 H 
               
               
                 107. 
                 H 
                 Isobutyl 
                 H 
                 Methyl 
                 H 
                 H 
               
               
                 108. 
                 H 
                 Isobutyl 
                 H 
                 H 
                 Methyl 
                 H 
               
               
                 109. 
                 H 
                 Isobutyl 
                 H 
                 H 
                 H 
                 Methyl 
               
               
                 110. 
                 H 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
               
               
                 111. 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
                 Methyl 
                 H 
               
               
                 112. 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 Methyl 
               
               
                 113. 
                 H 
                 Isobutyl 
                 H 
                 Methyl 
                 Methyl 
                 H 
               
               
                 114. 
                 H 
                 Isobutyl 
                 H 
                 Methyl 
                 H 
                 Methyl 
               
               
                 115. 
                 H 
                 Isobutyl 
                 H 
                 H 
                 Methyl 
                 Methyl 
               
               
                 116. 
                 H 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
               
               
                 117. 
                 H 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
               
               
                 118. 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
               
               
                 119. 
                 H 
                 Isobutyl 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 120. 
                 H 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 121. 
                 H 
                 Isobutyl 
                 Ethyl 
                 H 
                 H 
                 H 
               
               
                 122. 
                 H 
                 Isobutyl 
                 H 
                 Ethyl 
                 H 
                 H 
               
               
                 123. 
                 H 
                 Isobutyl 
                 H 
                 H 
                 Ethyl 
                 H 
               
               
                 124. 
                 H 
                 Isobutyl 
                 H 
                 H 
                 H 
                 Ethyl 
               
               
                 125. 
                 H 
                 Isobutyl 
                 Methyl 
                 Ethyl 
                 H 
                 H 
               
               
                 126. 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
                 Ethyl 
                 H 
               
               
                 127. 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 Ethyl 
               
               
                 128. 
                 H 
                 Isobutyl 
                 H 
                 Ethyl 
                 Methyl 
                 H 
               
               
                 129. 
                 H 
                 Isobutyl 
                 H 
                 Ethyl 
                 Ethyl 
                 H 
               
               
                 130. 
                 H 
                 Isobutyl 
                 H 
                 Methyl 
                 Ethyl 
                 H 
               
               
                 131. 
                 H 
                 Isobutyl 
                 Isopropyl 
                 H 
                 H 
                 H 
               
               
                 132. 
                 H 
                 Isobutyl 
                 H 
                 Isopropyl 
                 H 
                 H 
               
               
                 133. 
                 H 
                 Isobutyl 
                 H 
                 H 
                 Isopropyl 
                 H 
               
               
                 134. 
                 H 
                 Isobutyl 
                 H 
                 H 
                 H 
                 Isopropyl 
               
               
                 135. 
                 H 
                 Isobutyl 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
               
               
                 136. 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
                 Isopropyl 
                 H 
               
               
                 137. 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 Isopropyl 
               
               
                 138. 
                 H 
                 Isobutyl 
                 H 
                 Isopropyl 
                 Methyl 
                 H 
               
               
                 139. 
                 H 
                 Isobutyl 
                 H 
                 Isopropyl 
                 Isopropyl 
                 H 
               
               
                 140. 
                 H 
                 Isobutyl 
                 H 
                 Methyl 
                 Isopropyl 
                 H 
               
               
                 141. 
                 H 
                 Isobutyl 
                 H 
                 Isopropyl 
                 Ethyl 
                 H 
               
               
                 142. 
                 H 
                 Isobutyl 
                 H 
                 Ethyl 
                 Isopropyl 
                 H 
               
               
                 143. 
                 H 
                 Isobutyl 
                 Isobutyl 
                 H 
                 H 
                 H 
               
               
                 144. 
                 H 
                 Isobutyl 
                 H 
                 Isobutyl 
                 H 
                 H 
               
               
                 145. 
                 H 
                 Isobutyl 
                 H 
                 H 
                 Isobutyl 
                 H 
               
               
                 146. 
                 H 
                 Isobutyl 
                 H 
                 H 
                 H 
                 Isobutyl 
               
               
                 147. 
                 H 
                 Isobutyl 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
               
               
                 148. 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
                 Isobutyl 
                 H 
               
               
                 149. 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 Isobutyl 
               
               
                 150. 
                 H 
                 Isobutyl 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
               
               
                 151. 
                 H 
                 Isobutyl 
                 H 
                 Isobutyl 
                 Isobutyl 
                 H 
               
               
                 152. 
                 H 
                 Isobutyl 
                 H 
                 Methyl 
                 Isobutyl 
                 H 
               
               
                 153. 
                 H 
                 Isobutyl 
                 H 
                 Isobutyl  
                 Ethyl 
                 H 
               
               
                 154. 
                 H 
                 Isobutyl 
                 H 
                 Ethyl 
                 Isobutyl 
                 H 
               
               
                 155. 
                 H 
                 Isobutyl 
                 H 
                 Isobutyl 
                 Isopropyl 
                 H 
               
               
                 156. 
                 H 
                 Isobutyl 
                 H 
                 Isopropyl 
                 Isobutyl 
                 H 
               
               
                 157. 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 H 
                 H 
               
               
                 158. 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 H 
               
               
                 159. 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
                 H 
                 H 
               
               
                 160. 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 Methyl 
                 H 
               
               
                 161. 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 H 
                 Methyl 
               
               
                 162. 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
               
               
                 163. 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
                 H 
               
               
                 164. 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 Methyl 
               
               
                 165. 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
                 H 
               
               
                 166. 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
                 H 
                 Methyl 
               
               
                 167. 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 Methyl 
                 Methyl 
               
               
                 168. 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
               
               
                 169. 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
               
               
                 170. 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
               
               
                 171. 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 172. 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 173. 
                 Methyl 
                 Methyl 
                 Ethyl 
                 H 
                 H 
                 H 
               
               
                 174. 
                 Methyl 
                 Methyl 
                 H 
                 Ethyl 
                 H 
                 H 
               
               
                 175. 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 Ethyl 
                 H 
               
               
                 176. 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 H 
                 Ethyl 
               
               
                 177. 
                 Methyl 
                 Methyl 
                 Methyl 
                 Ethyl 
                 H 
                 H 
               
               
                 178. 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
                 Ethyl 
                 H 
               
               
                 179. 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 Ethyl 
               
               
                 180. 
                 Methyl 
                 Methyl 
                 H 
                 Ethyl 
                 Methyl 
                 H 
               
               
                 181. 
                 Methyl 
                 Methyl 
                 H 
                 Ethyl 
                 Ethyl 
                 H 
               
               
                 182. 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
                 Ethyl 
                 H 
               
               
                 183. 
                 Methyl 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
                 H 
               
               
                 184. 
                 Methyl 
                 Methyl 
                 H 
                 Isopropyl 
                 H 
                 H 
               
               
                 185. 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 Isopropyl 
                 H 
               
               
                 186. 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 H 
                 Isopropyl 
               
               
                 187. 
                 Methyl 
                 Methyl 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
               
               
                 188. 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
                 Isopropyl 
                 H 
               
               
                 189. 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 Isopropyl 
               
               
                 190. 
                 Methyl 
                 Methyl 
                 H 
                 Isopropyl 
                 Methyl 
                 H 
               
               
                 191. 
                 Methyl 
                 Methyl 
                 H 
                 Isopropyl 
                 Isopropyl 
                 H 
               
               
                 192. 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
                 Isopropyl 
                 H 
               
               
                 193. 
                 Methyl 
                 Methyl 
                 H 
                 Isopropyl  
                 Ethyl 
                 H 
               
               
                 194. 
                 Methyl 
                 Methyl 
                 H 
                 Ethyl 
                 Isopropyl 
                 H 
               
               
                 195. 
                 Methyl 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
                 H 
               
               
                 196. 
                 Methyl 
                 Methyl 
                 H 
                 Isobutyl 
                 H 
                 H 
               
               
                 197. 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 Isobutyl 
                 H 
               
               
                 198. 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 H 
                 Isobutyl 
               
               
                 199. 
                 Methyl 
                 Methyl 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
               
               
                 200. 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
                 Isobutyl 
                 H 
               
               
                 201. 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 Isobutyl 
               
               
                 202. 
                 Methyl 
                 Methyl 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
               
               
                 203. 
                 Methyl 
                 Methyl 
                 H 
                 Isobutyl 
                 Isobutyl 
                 H 
               
               
                 204. 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
                 Isobutyl 
                 H 
               
               
                 205. 
                 Methyl 
                 Methyl 
                 H 
                 Isobutyl 
                 Ethyl 
                 H 
               
               
                 206. 
                 Methyl 
                 Methyl 
                 H 
                 Ethyl 
                 Isobutyl 
                 H 
               
               
                 207. 
                 Methyl 
                 Methyl 
                 H 
                 Isobutyl 
                 Isopropyl 
                 H 
               
               
                 208. 
                 Methyl 
                 Methyl 
                 H 
                 Isopropyl  
                 Isobutyl 
                 H 
               
               
                 209. 
                 Methyl 
                 Ethyl 
                 H 
                 H 
                 H 
                 H 
               
               
                 210. 
                 Methyl 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 H 
               
               
                 211. 
                 Methyl 
                 Ethyl 
                 H 
                 Methyl 
                 H 
                 H 
               
               
                 212. 
                 Methyl 
                 Ethyl 
                 H 
                 H 
                 Methyl 
                 H 
               
               
                 213. 
                 Methyl 
                 Ethyl 
                 H 
                 H 
                 H 
                 Methyl 
               
               
                 214. 
                 Methyl 
                 Ethyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
               
               
                 215. 
                 Methyl 
                 Ethyl 
                 Methyl 
                 H 
                 Methyl 
                 H 
               
               
                 216. 
                 Methyl 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 Methyl 
               
               
                 217. 
                 Methyl 
                 Ethyl 
                 H 
                 Methyl 
                 Methyl 
                 H 
               
               
                 218. 
                 Methyl 
                 Ethyl 
                 H 
                 Methyl 
                 H 
                 Methyl 
               
               
                 219. 
                 Methyl 
                 Ethyl 
                 H 
                 H 
                 Methyl 
                 Methyl 
               
               
                 220. 
                 Methyl 
                 Ethyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
               
               
                 221. 
                 Methyl 
                 Ethyl 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
               
               
                 222. 
                 Methyl 
                 Ethyl 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
               
               
                 223. 
                 Methyl 
                 Ethyl 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 224. 
                 Methyl 
                 Ethyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 225. 
                 Methyl 
                 Ethyl 
                 Ethyl 
                 H 
                 H 
                 H 
               
               
                 226. 
                 Methyl 
                 Ethyl 
                 H 
                 Ethyl 
                 H 
                 H 
               
               
                 227. 
                 Methyl 
                 Ethyl 
                 H 
                 H 
                 Ethyl 
                 H 
               
               
                 228. 
                 Methyl 
                 Ethyl 
                 H 
                 H 
                 H 
                 Ethyl 
               
               
                 229. 
                 Methyl 
                 Ethyl 
                 Methyl 
                 Ethyl 
                 H 
                 H 
               
               
                 230. 
                 Methyl 
                 Ethyl 
                 Methyl 
                 H 
                 Ethyl 
                 H 
               
               
                 231. 
                 Methyl 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 Ethyl 
               
               
                 232. 
                 Methyl 
                 Ethyl 
                 H 
                 Ethyl 
                 Methyl 
                 H 
               
               
                 233. 
                 Methyl 
                 Ethyl 
                 H 
                 Ethyl 
                 Ethyl 
                 H 
               
               
                 234. 
                 Methyl 
                 Ethyl 
                 H 
                 Methyl 
                 Ethyl 
                 H 
               
               
                 235. 
                 Methyl 
                 Ethyl  
                 Isopropyl 
                 H 
                 H 
                 H 
               
               
                 236. 
                 Methyl 
                 Ethyl 
                 H 
                 Isopropyl 
                 H 
                 H 
               
               
                 237. 
                 Methyl 
                 Ethyl 
                 H 
                 H 
                 Isopropyl 
                 H 
               
               
                 238. 
                 Methyl 
                 Ethyl 
                 H 
                 H 
                 H 
                 Isopropyl 
               
               
                 239. 
                 Methyl 
                 Ethyl 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
               
               
                 240. 
                 Methyl 
                 Ethyl 
                 Methyl 
                 H 
                 Isopropyl 
                 H 
               
               
                 241. 
                 Methyl 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 Isopropyl 
               
               
                 242. 
                 Methyl 
                 Ethyl 
                 H 
                 Isopropyl 
                 Methyl 
                 H 
               
               
                 243. 
                 Methyl 
                 Ethyl 
                 H 
                 Isopropyl  
                 Isopropyl 
                 H 
               
               
                 244. 
                 Methyl 
                 Ethyl 
                 H 
                 Methyl 
                 Isopropyl 
                 H 
               
               
                 245. 
                 Methyl 
                 Ethyl 
                 H 
                 Isopropyl 
                 Ethyl 
                 H 
               
               
                 246. 
                 Methyl 
                 Ethyl 
                 H 
                 Ethyl 
                 Isopropyl 
                 H 
               
               
                 247. 
                 Methyl 
                 Ethyl 
                 Isobutyl 
                 H 
                 H 
                 H 
               
               
                 248. 
                 Methyl 
                 Ethyl 
                 H 
                 Isobutyl 
                 H 
                 H 
               
               
                 249. 
                 Methyl 
                 Ethyl 
                 H 
                 H 
                 Isobutyl 
                 H 
               
               
                 250. 
                 Methyl 
                 Ethyl 
                 H 
                 H 
                 H 
                 Isobutyl 
               
               
                 251. 
                 Methyl 
                 Ethyl 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
               
               
                 252. 
                 Methyl 
                 Ethyl 
                 Methyl 
                 H 
                 Isobutyl 
                 H 
               
               
                 253. 
                 Methyl 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 Isobutyl 
               
               
                 254. 
                 Methyl 
                 Ethyl 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
               
               
                 255. 
                 Methyl 
                 Ethyl 
                 H 
                 Isobutyl 
                 Isobutyl 
                 H 
               
               
                 256. 
                 Methyl 
                 Ethyl 
                 H 
                 Methyl 
                 Isobutyl 
                 H 
               
               
                 257. 
                 Methyl 
                 Ethyl 
                 H 
                 Isobutyl 
                 Ethyl 
                 H 
               
               
                 258. 
                 Methyl 
                 Ethyl 
                 H 
                 Ethyl 
                 Isobutyl 
                 H 
               
               
                 259. 
                 Methyl 
                 Ethyl 
                 H 
                 Isobutyl 
                 Isopropyl 
                 H 
               
               
                 260. 
                 Methyl 
                 Ethyl 
                 H 
                 Isopropyl  
                 Isobutyl 
                 H 
               
               
                 261. 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
                 H 
                 H 
               
               
                 262. 
                 Methyl 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 H 
               
               
                 263. 
                 Methyl 
                 Isopropyl 
                 H 
                 Methyl 
                 H 
                 H 
               
               
                 264. 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
                 Methyl 
                 H 
               
               
                 265. 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
                 H 
                 Methyl 
               
               
                 266. 
                 Methyl 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
               
               
                 267. 
                 Methyl 
                 Isopropyl 
                 Methyl 
                 H 
                 Methyl 
                 H 
               
               
                 268. 
                 Methyl 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 Methyl 
               
               
                 269. 
                 Methyl 
                 Isopropyl 
                 H 
                 Methyl 
                 Methyl 
                 H 
               
               
                 270. 
                 Methyl 
                 Isopropyl 
                 H 
                 Methyl 
                 H 
                 Methyl 
               
               
                 271. 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
                 Methyl 
                 Methyl 
               
               
                 272. 
                 Methyl 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
               
               
                 273. 
                 Methyl 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
               
               
                 274. 
                 Methyl 
                 Isopropyl 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
               
               
                 275. 
                 Methyl 
                 Isopropyl 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 276. 
                 Methyl 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 277. 
                 Methyl 
                 Isopropyl 
                 Ethyl 
                 H 
                 H 
                 H 
               
               
                 278. 
                 Methyl 
                 Isopropyl 
                 H 
                 Ethyl 
                 H 
                 H 
               
               
                 279. 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
                 Ethyl 
                 H 
               
               
                 280. 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
                 H 
                 Ethyl 
               
               
                 281. 
                 Methyl 
                 Isopropyl 
                 Methyl 
                 Ethyl 
                 H 
                 H 
               
               
                 282. 
                 Methyl 
                 Isopropyl 
                 Methyl 
                 H 
                 Ethyl 
                 H 
               
               
                 283. 
                 Methyl 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 Ethyl 
               
               
                 284. 
                 Methyl 
                 Isopropyl 
                 H 
                 Ethyl 
                 Methyl 
                 H 
               
               
                 285. 
                 Methyl 
                 Isopropyl 
                 H 
                 Ethyl 
                 Ethyl 
                 H 
               
               
                 286. 
                 Methyl 
                 Isopropyl 
                 H 
                 Methyl 
                 Ethyl 
                 H 
               
               
                 287. 
                 Methyl 
                 Isopropyl 
                 Isopropyl 
                 H 
                 H 
                 H 
               
               
                 288. 
                 Methyl 
                 Isopropyl 
                 H 
                 Isopropyl 
                 H 
                 H 
               
               
                 289. 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
                 Isopropyl 
                 H 
               
               
                 290. 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
                 H 
                 Isopropyl 
               
               
                 291. 
                 Methyl 
                 Isopropyl 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
               
               
                 292. 
                 Methyl 
                 Isopropyl 
                 Methyl 
                 H 
                 Isopropyl 
                 H 
               
               
                 293. 
                 Methyl 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 Isopropyl 
               
               
                 294. 
                 Methyl 
                 Isopropyl 
                 H 
                 Isopropyl 
                 Methyl 
                 H 
               
               
                 295. 
                 Methyl 
                 Isopropyl 
                 H 
                 Isopropyl 
                 Isopropyl 
                 H 
               
               
                 296. 
                 Methyl 
                 Isopropyl 
                 H 
                 Methyl 
                 Isopropyl 
                 H 
               
               
                 297. 
                 Methyl 
                 Isopropyl 
                 H 
                 Isopropyl 
                 Ethyl 
                 H 
               
               
                 298. 
                 Methyl 
                 Isopropyl 
                 H 
                 Ethyl 
                 Isopropyl 
                 H 
               
               
                 299. 
                 Methyl 
                 Isopropyl 
                 Isobutyl 
                 H 
                 H 
                 H 
               
               
                 300. 
                 Methyl 
                 Isopropyl 
                 H 
                 Isobutyl 
                 H 
                 H 
               
               
                 301. 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
                 Isobutyl 
                 H 
               
               
                 302. 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
                 H 
                 Isobutyl 
               
               
                 303. 
                 Methyl 
                 Isopropyl 
                 Methyl  
                 Isobutyl 
                 H 
                 H 
               
               
                 304. 
                 Methyl 
                 Isopropyl 
                 Methyl 
                 H 
                 Isobutyl 
                 H 
               
               
                 305. 
                 Methyl 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 Isobutyl 
               
               
                 306. 
                 Methyl 
                 Isopropyl 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
               
               
                 307. 
                 Methyl 
                 Isopropyl 
                 H 
                 Isobutyl 
                 Isobutyl 
                 H 
               
               
                 308. 
                 Methyl 
                 Isopropyl 
                 H 
                 Methyl 
                 Isobutyl 
                 H 
               
               
                 309. 
                 Methyl 
                 Isopropyl 
                 H 
                 Isobutyl 
                 Ethyl 
                 H 
               
               
                 310. 
                 Methyl 
                 Isopropyl 
                 H 
                 Ethyl 
                 Isobutyl 
                 H 
               
               
                 311. 
                 Methyl 
                 Isopropyl 
                 H 
                 Isobutyl 
                 Isopropyl 
                 H 
               
               
                 312. 
                 Methyl 
                 Isopropyl 
                 H 
                 Isopropyl 
                 Isobutyl 
                 H 
               
               
                 313. 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
                 H 
                 H 
               
               
                 314. 
                 Methyl 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 H 
               
               
                 315. 
                 Methyl 
                 Isobutyl 
                 H 
                 Methyl 
                 H 
                 H 
               
               
                 316. 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
                 Methyl 
                 H 
               
               
                 317. 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
                 H 
                 Methyl 
               
               
                 318. 
                 Methyl 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
               
               
                 319. 
                 Methyl 
                 Isobutyl 
                 Methyl 
                 H 
                 Methyl 
                 H 
               
               
                 320. 
                 Methyl 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 Methyl 
               
               
                 321. 
                 Methyl 
                 Isobutyl 
                 H 
                 Methyl 
                 Methyl 
                 H 
               
               
                 322. 
                 Methyl 
                 Isobutyl 
                 H 
                 Methyl 
                 H 
                 Methyl 
               
               
                 323. 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
                 Methyl 
                 Methyl 
               
               
                 324. 
                 Methyl 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
               
               
                 325. 
                 Methyl 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
               
               
                 326. 
                 Methyl 
                 Isobutyl 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
               
               
                 327. 
                 Methyl 
                 Isobutyl 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 328. 
                 Methyl 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 329. 
                 Methyl 
                 Isobutyl 
                 Ethyl 
                 H 
                 H 
                 H 
               
               
                 330. 
                 Methyl 
                 Isobutyl 
                 H 
                 Ethyl 
                 H 
                 H 
               
               
                 331. 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
                 Ethyl 
                 H 
               
               
                 332. 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
                 H 
                 Ethyl 
               
               
                 333. 
                 Methyl 
                 Isobutyl 
                 Methyl 
                 Ethyl 
                 H 
                 H 
               
               
                 334. 
                 Methyl 
                 Isobutyl 
                 Methyl 
                 H 
                 Ethyl 
                 H 
               
               
                 335. 
                 Methyl 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 Ethyl 
               
               
                 336. 
                 Methyl 
                 Isobutyl 
                 H 
                 Ethyl 
                 Methyl 
                 H 
               
               
                 337. 
                 Methyl 
                 Isobutyl 
                 H 
                 Ethyl 
                 Ethyl 
                 H 
               
               
                 338. 
                 Methyl 
                 Isobutyl 
                 H 
                 Methyl 
                 Ethyl 
                 H 
               
               
                 339. 
                 Methyl 
                 Isobutyl 
                 Isopropyl 
                 H 
                 H 
                 H 
               
               
                 340. 
                 Methyl 
                 Isobutyl 
                 H 
                 Isopropyl 
                 H 
                 H 
               
               
                 341. 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
                 Isopropyl 
                 H 
               
               
                 342. 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
                 H 
                 Isopropyl 
               
               
                 343. 
                 Methyl 
                 Isobutyl 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
               
               
                 344. 
                 Methyl 
                 Isobutyl 
                 Methyl 
                 H 
                 Isopropyl 
                 H 
               
               
                 345. 
                 Methyl 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 Isopropyl 
               
               
                 346. 
                 Methyl 
                 Isobutyl 
                 H 
                 Isopropyl 
                 Methyl 
                 H 
               
               
                 347. 
                 Methyl 
                 Isobutyl 
                 H 
                 Isopropyl 
                 Isopropyl 
                 H 
               
               
                 348. 
                 Methyl 
                 Isobutyl 
                 H 
                 Methyl 
                 Isopropyl 
                 H 
               
               
                 349. 
                 Methyl 
                 Isobutyl 
                 H 
                 Isopropyl 
                 Ethyl 
                 H 
               
               
                 350. 
                 Methyl 
                 Isobutyl 
                 H 
                 Ethyl 
                 Isopropyl 
                 H 
               
               
                 351. 
                 Methyl 
                 Isobutyl 
                 Isobutyl 
                 H 
                 H 
                 H 
               
               
                 352. 
                 Methyl 
                 Isobutyl 
                 H 
                 Isobutyl 
                 H 
                 H 
               
               
                 353. 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
                 Isobutyl 
                 H 
               
               
                 354. 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
                 H 
                 Isobutyl 
               
               
                 355. 
                 Methyl 
                 Isobutyl 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
               
               
                 356. 
                 Methyl 
                 Isobutyl 
                 Methyl 
                 H 
                 Isobutyl 
                 H 
               
               
                 357. 
                 Methyl 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 Isobutyl 
               
               
                 358. 
                 Methyl 
                 Isobutyl 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
               
               
                 359. 
                 Methyl 
                 Isobutyl 
                 H 
                 Isobutyl 
                 Isobutyl 
                 H 
               
               
                 360. 
                 Methyl 
                 Isobutyl 
                 H 
                 Methyl 
                 Isobutyl 
                 H 
               
               
                 361. 
                 Methyl 
                 Isobutyl 
                 H 
                 Isobutyl 
                 Ethyl 
                 H 
               
               
                 362. 
                 Methyl 
                 Isobutyl 
                 H 
                 Ethyl 
                 Isobutyl 
                 H 
               
               
                 363. 
                 Methyl 
                 Isobutyl 
                 H 
                 Isobutyl 
                 Isopropyl 
                 H 
               
               
                 364. 
                 Methyl 
                 Isobutyl 
                 H 
                 Isopropyl 
                 Isobutyl 
                 H 
               
               
                 365. 
                 Ethyl 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 366. 
                 Ethyl 
                 H 
                 Methyl 
                 H 
                 H 
                 H 
               
               
                 367. 
                 Ethyl 
                 H 
                 H 
                 Methyl 
                 H 
                 H 
               
               
                 368. 
                 Ethyl 
                 H 
                 H 
                 H 
                 Methyl 
                 H 
               
               
                 369. 
                 Ethyl 
                 H 
                 H 
                 H 
                 H 
                 Methyl 
               
               
                 370. 
                 Ethyl 
                 H 
                 Methyl 
                 Methyl 
                 H 
                 H 
               
               
                 371. 
                 Ethyl 
                 H 
                 Methyl 
                 H 
                 Methyl 
                 H 
               
               
                 372. 
                 Ethyl 
                 H 
                 Methyl 
                 H 
                 H 
                 Methyl 
               
               
                 373. 
                 Ethyl 
                 H 
                 H 
                 Methyl 
                 Methyl 
                 H 
               
               
                 374. 
                 Ethyl 
                 H 
                 H 
                 Methyl 
                 H 
                 Methyl 
               
               
                 375. 
                 Ethyl 
                 H 
                 H 
                 H 
                 Methyl 
                 Methyl 
               
               
                 376. 
                 Ethyl 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
               
               
                 377. 
                 Ethyl 
                 H 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
               
               
                 378. 
                 Ethyl 
                 H 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
               
               
                 379. 
                 Ethyl 
                 H 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 380. 
                 Ethyl 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 381. 
                 Ethyl 
                 H 
                 Ethyl 
                 H 
                 H 
                 H 
               
               
                 382. 
                 Ethyl 
                 H 
                 H 
                 Ethyl 
                 H 
                 H 
               
               
                 383. 
                 Ethyl 
                 H 
                 H 
                 H 
                 Ethyl 
                 H 
               
               
                 384. 
                 Ethyl 
                 H 
                 H 
                 H 
                 H 
                 Ethyl 
               
               
                 385. 
                 Ethyl 
                 H 
                 Methyl 
                 Ethyl 
                 H 
                 H 
               
               
                 386. 
                 Ethyl 
                 H 
                 Methyl 
                 H 
                 Ethyl 
                 H 
               
               
                 387. 
                 Ethyl 
                 H 
                 Methyl 
                 H 
                 H 
                 Ethyl 
               
               
                 388. 
                 Ethyl 
                 H 
                 H 
                 Ethyl 
                 Methyl 
                 H 
               
               
                 389. 
                 Ethyl 
                 H 
                 H 
                 Ethyl 
                 Ethyl 
                 H 
               
               
                 390. 
                 Ethyl 
                 H 
                 H 
                 Methyl 
                 Ethyl 
                 H 
               
               
                 391. 
                 Ethyl 
                 H 
                 Isopropyl 
                 H 
                 H 
                 H 
               
               
                 392. 
                 Ethyl 
                 H 
                 H 
                 Isopropyl 
                 H 
                 H 
               
               
                 393. 
                 Ethyl 
                 H 
                 H 
                 H 
                 Isopropyl 
                 H 
               
               
                 394. 
                 Ethyl 
                 H 
                 H 
                 H 
                 H 
                 Isopropyl 
               
               
                 395. 
                 Ethyl 
                 H 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
               
               
                 396. 
                 Ethyl 
                 H 
                 Methyl 
                 H 
                 Isopropyl 
                 H 
               
               
                 397. 
                 Ethyl 
                 H 
                 Methyl 
                 H 
                 H 
                 Isopropyl 
               
               
                 398. 
                 Ethyl 
                 H 
                 H 
                 Isopropyl 
                 Methyl 
                 H 
               
               
                 399. 
                 Ethyl 
                 H 
                 H 
                 Isopropyl 
                 Isopropyl 
                 H 
               
               
                 400. 
                 Ethyl 
                 H 
                 H 
                 Methyl 
                 Isopropyl 
                 H 
               
               
                 401. 
                 Ethyl 
                 H 
                 H 
                 Isopropyl 
                 Ethyl 
                 H 
               
               
                 402. 
                 Ethyl 
                 H 
                 H 
                 Ethyl 
                 Isopropyl 
                 H 
               
               
                 403. 
                 Ethyl 
                 H 
                 Isobutyl 
                 H 
                 H 
                 H 
               
               
                 404. 
                 Ethyl 
                 H 
                 H 
                 Isobutyl 
                 H 
                 H 
               
               
                 405. 
                 Ethyl 
                 H 
                 H 
                 H 
                 Isobutyl 
                 H 
               
               
                 406. 
                 Ethyl 
                 H 
                 H 
                 H 
                 H 
                 Isobutyl 
               
               
                 407. 
                 Ethyl 
                 H 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
               
               
                 408. 
                 Ethyl 
                 H 
                 Methyl 
                 H 
                 Isobutyl 
                 H 
               
               
                 409. 
                 Ethyl 
                 H 
                 Methyl 
                 H 
                 H 
                 Isobutyl 
               
               
                 410. 
                 Ethyl 
                 H 
                 H 
                 Isobutyl  
                 Methyl 
                 H 
               
               
                 411. 
                 Ethyl 
                 H 
                 H 
                 Isobutyl  
                 Isobutyl 
                 H 
               
               
                 412. 
                 Ethyl 
                 H 
                 H 
                 Methyl 
                 Isobutyl 
                 H 
               
               
                 413. 
                 Ethyl 
                 H 
                 H 
                 Isobutyl  
                 Ethyl 
                 H 
               
               
                 414. 
                 Ethyl 
                 H 
                 H 
                 Ethyl 
                 Isobutyl 
                 H 
               
               
                 415. 
                 Ethyl 
                 H 
                 H 
                 Isobutyl  
                 Isopropyl 
                 H 
               
               
                 416. 
                 Ethyl 
                 H 
                 H 
                 Isopropyl 
                 Isobutyl 
                 H 
               
               
                 417. 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 H 
                 H 
               
               
                 418. 
                 Ethyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 H 
               
               
                 419. 
                 Ethyl 
                 Methyl 
                 H 
                 Methyl 
                 H 
                 H 
               
               
                 420. 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 Methyl 
                 H 
               
               
                 421. 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 H 
                 Methyl 
               
               
                 422. 
                 Ethyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
               
               
                 423. 
                 Ethyl 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
                 H 
               
               
                 424. 
                 Ethyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 Methyl 
               
               
                 425. 
                 Ethyl 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
                 H 
               
               
                 426. 
                 Ethyl 
                 Methyl 
                 H 
                 Methyl 
                 H 
                 Methyl 
               
               
                 427. 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 Methyl 
                 Methyl 
               
               
                 428. 
                 Ethyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
               
               
                 429. 
                 Ethyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
               
               
                 430. 
                 Ethyl 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
               
               
                 431. 
                 Ethyl 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 432. 
                 Ethyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 433. 
                 Ethyl 
                 Methyl 
                 Ethyl 
                 H 
                 H 
                 H 
               
               
                 434. 
                 Ethyl 
                 Methyl 
                 H 
                 Ethyl 
                 H 
                 H 
               
               
                 435. 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 Ethyl 
                 H 
               
               
                 436. 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 H 
                 Ethyl 
               
               
                 437. 
                 Ethyl 
                 Methyl 
                 Methyl 
                 Ethyl 
                 H 
                 H 
               
               
                 438. 
                 Ethyl 
                 Methyl 
                 Methyl 
                 H 
                 Ethyl 
                 H 
               
               
                 439. 
                 Ethyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 Ethyl 
               
               
                 440. 
                 Ethyl 
                 Methyl 
                 H 
                 Ethyl 
                 Methyl 
                 H 
               
               
                 441. 
                 Ethyl 
                 Methyl 
                 H 
                 Ethyl 
                 Ethyl 
                 H 
               
               
                 442. 
                 Ethyl 
                 Methyl 
                 H 
                 Methyl 
                 Ethyl 
                 H 
               
               
                 443. 
                 Ethyl 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
                 H 
               
               
                 444. 
                 Ethyl 
                 Methyl 
                 H 
                 Isopropyl 
                 H 
                 H 
               
               
                 445. 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 Isopropyl 
                 H 
               
               
                 446. 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 H 
                 Isopropyl 
               
               
                 447. 
                 Ethyl 
                 Methyl 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
               
               
                 448. 
                 Ethyl 
                 Methyl 
                 Methyl 
                 H 
                 Isopropyl 
                 H 
               
               
                 449. 
                 Ethyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 Isopropyl 
               
               
                 450. 
                 Ethyl 
                 Methyl 
                 H 
                 Isopropyl 
                 Methyl 
                 H 
               
               
                 451. 
                 Ethyl 
                 Methyl 
                 H 
                 Isopropyl 
                 Isopropyl 
                 H 
               
               
                 452. 
                 Ethyl 
                 Methyl 
                 H 
                 Methyl 
                 Isopropyl 
                 H 
               
               
                 453. 
                 Ethyl 
                 Methyl 
                 H 
                 Isopropyl 
                 Ethyl 
                 H 
               
               
                 454. 
                 Ethyl 
                 Methyl 
                 H 
                 Ethyl 
                 Isopropyl 
                 H 
               
               
                 455. 
                 Ethyl 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
                 H 
               
               
                 456. 
                 Ethyl 
                 Methyl 
                 H 
                 Isobutyl 
                 H 
                 H 
               
               
                 457. 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 Isobutyl 
                 H 
               
               
                 458. 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 H 
                 Isobutyl 
               
               
                 459. 
                 Ethyl 
                 Methyl 
                 Methyl  
                 Isobutyl 
                 H 
                 H 
               
               
                 460. 
                 Ethyl 
                 Methyl 
                 Methyl 
                 H 
                 Isobutyl 
                 H 
               
               
                 461. 
                 Ethyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 Isobutyl 
               
               
                 462. 
                 Ethyl 
                 Methyl 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
               
               
                 463. 
                 Ethyl 
                 Methyl 
                 H 
                 Isobutyl 
                 Isobutyl 
                 H 
               
               
                 464. 
                 Ethyl 
                 Methyl 
                 H 
                 Methyl 
                 Isobutyl 
                 H 
               
               
                 465. 
                 Ethyl 
                 Methyl 
                 H 
                 Isobutyl 
                 Ethyl 
                 H 
               
               
                 466. 
                 Ethyl 
                 Methyl 
                 H 
                 Ethyl 
                 Isobutyl 
                 H 
               
               
                 467. 
                 Ethyl 
                 Methyl 
                 H 
                 Isobutyl 
                 Isopropyl 
                 H 
               
               
                 468. 
                 Ethyl 
                 Methyl 
                 H 
                 Isopropyl 
                 Isobutyl 
                 H 
               
               
                 469. 
                 Ethyl 
                 Ethyl 
                 H 
                 H 
                 H 
                 H 
               
               
                 470. 
                 Ethyl 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 H 
               
               
                 471. 
                 Ethyl 
                 Ethyl 
                 H 
                 Methyl 
                 H 
                 H 
               
               
                 472. 
                 Ethyl 
                 Ethyl 
                 H 
                 H 
                 Methyl 
                 H 
               
               
                 473. 
                 Ethyl 
                 Ethyl 
                 H 
                 H 
                 H 
                 Methyl 
               
               
                 474. 
                 Ethyl 
                 Ethyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
               
               
                 475. 
                 Ethyl 
                 Ethyl 
                 Methyl 
                 H 
                 Methyl 
                 H 
               
               
                 476. 
                 Ethyl 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 Methyl 
               
               
                 477. 
                 Ethyl 
                 Ethyl 
                 H 
                 Methyl 
                 Methyl 
                 H 
               
               
                 478. 
                 Ethyl 
                 Ethyl 
                 H 
                 Methyl 
                 H 
                 Methyl 
               
               
                 479. 
                 Ethyl 
                 Ethyl 
                 H 
                 H 
                 Methyl 
                 Methyl 
               
               
                 480. 
                 Ethyl 
                 Ethyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
               
               
                 481. 
                 Ethyl 
                 Ethyl 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
               
               
                 482. 
                 Ethyl 
                 Ethyl 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
               
               
                 483. 
                 Ethyl 
                 Ethyl 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 484. 
                 Ethyl 
                 Ethyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 485. 
                 Ethyl 
                 Ethyl 
                 Ethyl 
                 H 
                 H 
                 H 
               
               
                 486. 
                 Ethyl 
                 Ethyl 
                 H 
                 Ethyl 
                 H 
                 H 
               
               
                 487. 
                 Ethyl 
                 Ethyl 
                 H 
                 H 
                 Ethyl 
                 H 
               
               
                 488. 
                 Ethyl 
                 Ethyl 
                 H 
                 H 
                 H 
                 Ethyl 
               
               
                 489. 
                 Ethyl 
                 Ethyl 
                 Methyl 
                 Ethyl 
                 H 
                 H 
               
               
                 490. 
                 Ethyl 
                 Ethyl 
                 Methyl 
                 H 
                 Ethyl 
                 H 
               
               
                 491. 
                 Ethyl 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 Ethyl 
               
               
                 492. 
                 Ethyl 
                 Ethyl 
                 H 
                 Ethyl 
                 Methyl 
                 H 
               
               
                 493. 
                 Ethyl 
                 Ethyl 
                 H 
                 Ethyl 
                 Ethyl 
                 H 
               
               
                 494. 
                 Ethyl 
                 Ethyl 
                 H 
                 Methyl 
                 Ethyl 
                 H 
               
               
                 495. 
                 Ethyl 
                 Ethyl 
                 Isopropyl 
                 H 
                 H 
                 H 
               
               
                 496. 
                 Ethyl 
                 Ethyl 
                 H 
                 Isopropyl 
                 H 
                 H 
               
               
                 497. 
                 Ethyl 
                 Ethyl 
                 H 
                 H 
                 Isopropyl 
                 H 
               
               
                 498. 
                 Ethyl 
                 Ethyl 
                 H 
                 H 
                 H 
                 Isopropyl 
               
               
                 499. 
                 Ethyl 
                 Ethyl 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
               
               
                 500. 
                 Ethyl 
                 Ethyl 
                 Methyl 
                 H 
                 Isopropyl 
                 H 
               
               
                 501. 
                 Ethyl 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 Isopropyl 
               
               
                 502. 
                 Ethyl 
                 Ethyl 
                 H 
                 Isopropyl 
                 Methyl 
                 H 
               
               
                 503. 
                 Ethyl 
                 Ethyl 
                 H 
                 Isopropyl 
                 Isopropyl 
                 H 
               
               
                 504. 
                 Ethyl 
                 Ethyl 
                 H 
                 Methyl 
                 Isopropyl 
                 H 
               
               
                 505. 
                 Ethyl 
                 Ethyl 
                 H 
                 Isopropyl 
                 Ethyl 
                 H 
               
               
                 506. 
                 Ethyl 
                 Ethyl 
                 H 
                 Ethyl 
                 Isopropyl 
                 H 
               
               
                 507. 
                 Ethyl 
                 Ethyl 
                 Isobutyl 
                 H 
                 H 
                 H 
               
               
                 508. 
                 Ethyl 
                 Ethyl 
                 H 
                 Isobutyl 
                 H 
                 H 
               
               
                 509. 
                 Ethyl 
                 Ethyl 
                 H 
                 H 
                 Isobutyl 
                 H 
               
               
                 510. 
                 Ethyl 
                 Ethyl 
                 H 
                 H 
                 H 
                 Isobutyl 
               
               
                 511. 
                 Ethyl 
                 Ethyl 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
               
               
                 512. 
                 Ethyl 
                 Ethyl 
                 Methyl 
                 H 
                 Isobutyl 
                 H 
               
               
                 513. 
                 Ethyl 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 Isobutyl 
               
               
                 514. 
                 Ethyl 
                 Ethyl 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
               
               
                 515. 
                 Ethyl 
                 Ethyl 
                 H 
                 Isobutyl 
                 Isobutyl 
                 H 
               
               
                 516. 
                 Ethyl 
                 Ethyl 
                 H 
                 Methyl 
                 Isobutyl 
                 H 
               
               
                 517. 
                 Ethyl 
                 Ethyl 
                 H 
                 Isobutyl 
                 Ethyl 
                 H 
               
               
                 518. 
                 Ethyl 
                 Ethyl 
                 H 
                 Ethyl 
                 Isobutyl 
                 H 
               
               
                 519. 
                 Ethyl 
                 Ethyl 
                 H 
                 Isobutyl 
                 Isopropyl 
                 H 
               
               
                 520. 
                 Ethyl 
                 Ethyl 
                 H 
                 Isopropyl  
                 Isobutyl 
                 H 
               
               
                 521. 
                 Ethyl 
                 Isopropyl 
                 H 
                 H 
                 H 
                 H 
               
               
                 522. 
                 Ethyl 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 H 
               
               
                 523. 
                 Ethyl 
                 Isopropyl 
                 H 
                 Methyl 
                 H 
                 H 
               
               
                 524. 
                 Ethyl 
                 Isopropyl 
                 H 
                 H 
                 Methyl 
                 H 
               
               
                 525. 
                 Ethyl 
                 Isopropyl 
                 H 
                 H 
                 H 
                 Methyl 
               
               
                 526. 
                 Ethyl 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
               
               
                 527. 
                 Ethyl 
                 Isopropyl 
                 Methyl 
                 H 
                 Methyl 
                 H 
               
               
                 528. 
                 Ethyl 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 Methyl 
               
               
                 529. 
                 Ethyl 
                 Isopropyl 
                 H 
                 Methyl 
                 Methyl 
                 H 
               
               
                 530. 
                 Ethyl 
                 Isopropyl 
                 H 
                 Methyl 
                 H 
                 Methyl 
               
               
                 531. 
                 Ethyl 
                 Isopropyl 
                 H 
                 H 
                 Methyl 
                 Methyl 
               
               
                 532. 
                 Ethyl 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
               
               
                 533. 
                 Ethyl 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
               
               
                 534. 
                 Ethyl 
                 Isopropyl 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
               
               
                 535. 
                 Ethyl 
                 Isopropyl 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 536. 
                 Ethyl 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 537. 
                 Ethyl 
                 Isopropyl 
                 Ethyl 
                 H 
                 H 
                 H 
               
               
                 538. 
                 Ethyl 
                 Isopropyl 
                 H 
                 Ethyl 
                 H 
                 H 
               
               
                 539. 
                 Ethyl 
                 Isopropyl 
                 H 
                 H 
                 Ethyl 
                 H 
               
               
                 540. 
                 Ethyl 
                 Isopropyl 
                 H 
                 H 
                 H 
                 Ethyl 
               
               
                 541. 
                 Ethyl 
                 Isopropyl 
                 Methyl 
                 Ethyl 
                 H 
                 H 
               
               
                 542. 
                 Ethyl 
                 Isopropyl 
                 Methyl 
                 H 
                 Ethyl 
                 H 
               
               
                 543. 
                 Ethyl 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 Ethyl 
               
               
                 544. 
                 Ethyl 
                 Isopropyl 
                 H 
                 Ethyl 
                 Methyl 
                 H 
               
               
                 545. 
                 Ethyl 
                 Isopropyl 
                 H 
                 Ethyl 
                 Ethyl 
                 H 
               
               
                 546. 
                 Ethyl 
                 Isopropyl 
                 H 
                 Methyl 
                 Ethyl 
                 H 
               
               
                 547. 
                 Ethyl 
                 Isopropyl 
                 Isopropyl 
                 H 
                 H 
                 H 
               
               
                 548. 
                 Ethyl 
                 Isopropyl 
                 H 
                 Isopropyl 
                 H 
                 H 
               
               
                 549. 
                 Ethyl 
                 Isopropyl 
                 H 
                 H 
                 Isopropyl 
                 H 
               
               
                 550. 
                 Ethyl 
                 Isopropyl 
                 H 
                 H 
                 H 
                 Isopropyl 
               
               
                 551. 
                 Ethyl 
                 Isopropyl 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
               
               
                 552. 
                 Ethyl 
                 Isopropyl 
                 Methyl 
                 H 
                 Isopropyl 
                 H 
               
               
                 553. 
                 Ethyl 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 Isopropyl 
               
               
                 554. 
                 Ethyl 
                 Isopropyl 
                 H 
                 Isopropyl 
                 Methyl 
                 H 
               
               
                 555. 
                 Ethyl 
                 Isopropyl 
                 H 
                 Isopropyl  
                 Isopropyl 
                 H 
               
               
                 556. 
                 Ethyl 
                 Isopropyl 
                 H 
                 Methyl 
                 Isopropyl 
                 H 
               
               
                 557. 
                 Ethyl 
                 Isopropyl 
                 H 
                 Isopropyl  
                 Ethyl 
                 H 
               
               
                 558. 
                 Ethyl 
                 Isopropyl 
                 H 
                 Ethyl 
                 Isopropyl 
                 H 
               
               
                 559. 
                 Ethyl 
                 Isopropyl 
                 Isobutyl 
                 H 
                 H 
                 H 
               
               
                 560. 
                 Ethyl 
                 Isopropyl 
                 H 
                 Isobutyl 
                 H 
                 H 
               
               
                 561. 
                 Ethyl 
                 Isopropyl 
                 H 
                 H 
                 Isobutyl 
                 H 
               
               
                 562. 
                 Ethyl 
                 Isopropyl 
                 H 
                 H 
                 H 
                 Isobutyl 
               
               
                 563. 
                 Ethyl 
                 Isopropyl 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
               
               
                 564. 
                 Ethyl 
                 Isopropyl 
                 Methyl 
                 H 
                 Isobutyl 
                 H 
               
               
                 565. 
                 Ethyl 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 Isobutyl 
               
               
                 566. 
                 Ethyl 
                 Isopropyl 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
               
               
                 567. 
                 Ethyl 
                 Isopropyl 
                 H 
                 Isobutyl 
                 Isobutyl 
                 H 
               
               
                 568. 
                 Ethyl 
                 Isopropyl 
                 H 
                 Methyl 
                 Isobutyl 
                 H 
               
               
                 569. 
                 Ethyl 
                 Isopropyl 
                 H 
                 Isobutyl 
                 Ethyl 
                 H 
               
               
                 570. 
                 Ethyl 
                 Isopropyl 
                 H 
                 Ethyl 
                 Isobutyl 
                 H 
               
               
                 571. 
                 Ethyl 
                 Isopropyl 
                 H 
                 Isobutyl 
                 Isopropyl 
                 H 
               
               
                 572. 
                 Ethyl 
                 Isopropyl 
                 H 
                 Isopropyl  
                 Isobutyl 
                 H 
               
               
                 573. 
                 Ethyl 
                 Isobutyl 
                 H 
                 H 
                 H 
                 H 
               
               
                 574. 
                 Ethyl 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 H 
               
               
                 575. 
                 Ethyl 
                 Isobutyl 
                 H 
                 Methyl 
                 H 
                 H 
               
               
                 576. 
                 Ethyl 
                 Isobutyl 
                 H 
                 H 
                 Methyl 
                 H 
               
               
                 577. 
                 Ethyl 
                 Isobutyl 
                 H 
                 H 
                 H 
                 Methyl 
               
               
                 578. 
                 Ethyl 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
               
               
                 579. 
                 Ethyl 
                 Isobutyl 
                 Methyl 
                 H 
                 Methyl 
                 H 
               
               
                 580. 
                 Ethyl 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 Methyl 
               
               
                 581. 
                 Ethyl 
                 Isobutyl 
                 H 
                 Methyl 
                 Methyl 
                 H 
               
               
                 582. 
                 Ethyl 
                 Isobutyl 
                 H 
                 Methyl 
                 H 
                 Methyl 
               
               
                 583. 
                 Ethyl 
                 Isobutyl 
                 H 
                 H 
                 Methyl 
                 Methyl 
               
               
                 584. 
                 Ethyl 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
               
               
                 585. 
                 Ethyl 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
               
               
                 586. 
                 Ethyl 
                 Isobutyl 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
               
               
                 587. 
                 Ethyl 
                 Isobutyl 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 588. 
                 Ethyl 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 589. 
                 Ethyl 
                 Isobutyl 
                 Ethyl 
                 H 
                 H 
                 H 
               
               
                 590. 
                 Ethyl 
                 Isobutyl 
                 H 
                 Ethyl 
                 H 
                 H 
               
               
                 591. 
                 Ethyl 
                 Isobutyl 
                 H 
                 H 
                 Ethyl 
                 H 
               
               
                 592. 
                 Ethyl 
                 Isobutyl 
                 H 
                 H 
                 H 
                 Ethyl 
               
               
                 593. 
                 Ethyl 
                 Isobutyl 
                 Methyl 
                 Ethyl 
                 H 
                 H 
               
               
                 594. 
                 Ethyl 
                 Isobutyl 
                 Methyl 
                 H 
                 Ethyl 
                 H 
               
               
                 595. 
                 Ethyl 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 Ethyl 
               
               
                 596. 
                 Ethyl 
                 Isobutyl 
                 H 
                 Ethyl 
                 Methyl 
                 H 
               
               
                 597. 
                 Ethyl 
                 Isobutyl 
                 H 
                 Ethyl 
                 Ethyl 
                 H 
               
               
                 598. 
                 Ethyl 
                 Isobutyl 
                 H 
                 Methyl 
                 Ethyl 
                 H 
               
               
                 599. 
                 Ethyl 
                 Isobutyl 
                 Isopropyl 
                 H 
                 H 
                 H 
               
               
                 600. 
                 Ethyl 
                 Isobutyl 
                 H 
                 Isopropyl 
                 H 
                 H 
               
               
                 601. 
                 Ethyl 
                 Isobutyl 
                 H 
                 H 
                 Isopropyl 
                 H 
               
               
                 602. 
                 Ethyl 
                 Isobutyl 
                 H 
                 H 
                 H 
                 Isopropyl 
               
               
                 603. 
                 Ethyl 
                 Isobutyl 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
               
               
                 604. 
                 Ethyl 
                 Isobutyl 
                 Methyl 
                 H 
                 Isopropyl 
                 H 
               
               
                 605. 
                 Ethyl 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 Isopropyl 
               
               
                 606. 
                 Ethyl 
                 Isobutyl 
                 H 
                 Isopropyl 
                 Methyl 
                 H 
               
               
                 607. 
                 Ethyl 
                 Isobutyl 
                 H 
                 Isopropyl 
                 Isopropyl 
                 H 
               
               
                 608. 
                 Ethyl 
                 Isobutyl 
                 H 
                 Methyl 
                 Isopropyl 
                 H 
               
               
                 609. 
                 Ethyl 
                 Isobutyl 
                 H 
                 Isopropyl 
                 Ethyl 
                 H 
               
               
                 610. 
                 Ethyl 
                 Isobutyl 
                 H 
                 Ethyl 
                 Isopropyl 
                 H 
               
               
                 611. 
                 Ethyl 
                 Isobutyl 
                 Isobutyl 
                 H 
                 H 
                 H 
               
               
                 612. 
                 Ethyl 
                 Isobutyl 
                 H 
                 Isobutyl 
                 H 
                 H 
               
               
                 613. 
                 Ethyl 
                 Isobutyl 
                 H 
                 H 
                 Isobutyl 
                 H 
               
               
                 614. 
                 Ethyl 
                 Isobutyl 
                 H 
                 H 
                 H 
                 Isobutyl 
               
               
                 615. 
                 Ethyl 
                 Isobutyl 
                 Methyl  
                 Isobutyl 
                 H 
                 H 
               
               
                 616. 
                 Ethyl 
                 Isobutyl 
                 Methyl 
                 H 
                 Isobutyl 
                 H 
               
               
                 617. 
                 Ethyl 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 Isobutyl 
               
               
                 618. 
                 Ethyl 
                 Isobutyl 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
               
               
                 619. 
                 Ethyl 
                 Isobutyl 
                 H 
                 Isobutyl 
                 Isobutyl 
                 H 
               
               
                 620. 
                 Ethyl 
                 Isobutyl 
                 H 
                 Methyl 
                 Isobutyl 
                 H 
               
               
                 621. 
                 Ethyl 
                 Isobutyl 
                 H 
                 Isobutyl 
                 Ethyl 
                 H 
               
               
                 622. 
                 Ethyl 
                 Isobutyl 
                 H 
                 Ethyl 
                 Isobutyl 
                 H 
               
               
                 623. 
                 Ethyl 
                 Isobutyl 
                 H 
                 Isobutyl 
                 Isopropyl 
                 H 
               
               
                 624. 
                 Ethyl 
                 Isobutyl 
                 H 
                 Isopropyl 
                 Isobutyl 
                 H 
               
               
                 625. 
                 Isopropyl 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 626. 
                 Isopropyl 
                 H 
                 Methyl 
                 H 
                 H 
                 H 
               
               
                 627. 
                 Isopropyl 
                 H 
                 H 
                 Methyl 
                 H 
                 H 
               
               
                 628. 
                 Isopropyl 
                 H 
                 H 
                 H 
                 Methyl 
                 H 
               
               
                 629. 
                 Isopropyl 
                 H 
                 H 
                 H 
                 H 
                 Methyl 
               
               
                 630. 
                 Isopropyl 
                 H 
                 Methyl 
                 Methyl 
                 H 
                 H 
               
               
                 631. 
                 Isopropyl 
                 H 
                 Methyl 
                 H 
                 Methyl 
                 H 
               
               
                 632. 
                 Isopropyl 
                 H 
                 Methyl 
                 H 
                 H 
                 Methyl 
               
               
                 633. 
                 Isopropyl 
                 H 
                 H 
                 Methyl 
                 Methyl 
                 H 
               
               
                 634. 
                 Isopropyl 
                 H 
                 H 
                 Methyl 
                 H 
                 Methyl 
               
               
                 635. 
                 Isopropyl 
                 H 
                 H 
                 H 
                 Methyl 
                 Methyl 
               
               
                 636. 
                 Isopropyl 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
               
               
                 637. 
                 Isopropyl 
                 H 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
               
               
                 638. 
                 Isopropyl 
                 H 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
               
               
                 639. 
                 Isopropyl 
                 H 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 640. 
                 Isopropyl 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 641. 
                 Isopropyl 
                 H 
                 Ethyl 
                 H 
                 H 
                 H 
               
               
                 642. 
                 Isopropyl 
                 H 
                 H 
                 Ethyl 
                 H 
                 H 
               
               
                 643. 
                 Isopropyl 
                 H 
                 H 
                 H 
                 Ethyl 
                 H 
               
               
                 644. 
                 Isopropyl 
                 H 
                 H 
                 H 
                 H 
                 Ethyl 
               
               
                 645. 
                 Isopropyl 
                 H 
                 Methyl 
                 Ethyl 
                 H 
                 H 
               
               
                 646. 
                 Isopropyl 
                 H 
                 Methyl 
                 H 
                 Ethyl 
                 H 
               
               
                 647. 
                 Isopropyl 
                 H 
                 Methyl 
                 H 
                 H 
                 Ethyl 
               
               
                 648. 
                 Isopropyl 
                 H 
                 H 
                 Ethyl 
                 Methyl 
                 H 
               
               
                 649. 
                 Isopropyl 
                 H 
                 H 
                 Ethyl 
                 Ethyl 
                 H 
               
               
                 650. 
                 Isopropyl 
                 H 
                 H 
                 Methyl 
                 Ethyl 
                 H 
               
               
                 651. 
                 Isopropyl 
                 H 
                 Isopropyl 
                 H 
                 H 
                 H 
               
               
                 652. 
                 Isopropyl 
                 H 
                 H 
                 Isopropyl 
                 H 
                 H 
               
               
                 653. 
                 Isopropyl 
                 H 
                 H 
                 H 
                 Isopropyl 
                 H 
               
               
                 654. 
                 Isopropyl 
                 H 
                 H 
                 H 
                 H 
                 Isopropyl 
               
               
                 655. 
                 Isopropyl 
                 H 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
               
               
                 656. 
                 Isopropyl 
                 H 
                 Methyl 
                 H 
                 Isopropyl 
                 H 
               
               
                 657. 
                 Isopropyl 
                 H 
                 Methyl 
                 H 
                 H 
                 Isopropyl 
               
               
                 658. 
                 Isopropyl 
                 H 
                 H 
                 Isopropyl 
                 Methyl 
                 H 
               
               
                 659. 
                 Isopropyl 
                 H 
                 H 
                 Isopropyl 
                 Isopropyl 
                 H 
               
               
                 660. 
                 Isopropyl 
                 H 
                 H 
                 Methyl 
                 Isopropyl 
                 H 
               
               
                 661. 
                 Isopropyl 
                 H 
                 H 
                 Isopropyl 
                 Ethyl 
                 H 
               
               
                 662. 
                 Isopropyl 
                 H 
                 H 
                 Ethyl 
                 Isopropyl 
                 H 
               
               
                 663. 
                 Isopropyl 
                 H 
                 Isobutyl 
                 H 
                 H 
                 H 
               
               
                 664. 
                 Isopropyl 
                 H 
                 H 
                 Isobutyl 
                 H 
                 H 
               
               
                 665. 
                 Isopropyl 
                 H 
                 H 
                 H 
                 Isobutyl 
                 H 
               
               
                 666. 
                 Isopropyl 
                 H 
                 H 
                 H 
                 H 
                 Isobutyl 
               
               
                 667. 
                 Isopropyl 
                 H 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
               
               
                 668. 
                 Isopropyl 
                 H 
                 Methyl 
                 H 
                 Isobutyl 
                 H 
               
               
                 669. 
                 Isopropyl 
                 H 
                 Methyl 
                 H 
                 H 
                 Isobutyl 
               
               
                 670. 
                 Isopropyl 
                 H 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
               
               
                 671. 
                 Isopropyl 
                 H 
                 H 
                 Isobutyl  
                 Isobutyl 
                 H 
               
               
                 672. 
                 Isopropyl 
                 H 
                 H 
                 Methyl 
                 Isobutyl 
                 H 
               
               
                 673. 
                 Isopropyl 
                 H 
                 H 
                 Isobutyl  
                 Ethyl 
                 H 
               
               
                 674. 
                 Isopropyl 
                 H 
                 H 
                 Ethyl 
                 Isobutyl 
                 H 
               
               
                 675. 
                 Isopropyl 
                 H 
                 H 
                 Isobutyl 
                 Isopropyl 
                 H 
               
               
                 676. 
                 Isopropyl 
                 H 
                 H 
                 Isopropyl 
                 Isobutyl 
                 H 
               
               
                 677. 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 H 
                 H 
               
               
                 678. 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 H 
               
               
                 679. 
                 Isopropyl 
                 Methyl 
                 H 
                 Methyl 
                 H 
                 H 
               
               
                 680. 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 Methyl 
                 H 
               
               
                 681. 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 H 
                 Methyl 
               
               
                 682. 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
               
               
                 683. 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
                 H 
               
               
                 684. 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 Methyl 
               
               
                 685. 
                 Isopropyl 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
                 H 
               
               
                 686. 
                 Isopropyl 
                 Methyl 
                 H 
                 Methyl 
                 H 
                 Methyl 
               
               
                 687. 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 Methyl 
                 Methyl 
               
               
                 688. 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
               
               
                 689. 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
               
               
                 690. 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
               
               
                 691. 
                 Isopropyl 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 692. 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 693. 
                 Isopropyl 
                 Methyl 
                 Ethyl 
                 H 
                 H 
                 H 
               
               
                 694. 
                 Isopropyl 
                 Methyl 
                 H 
                 Ethyl 
                 H 
                 H 
               
               
                 695. 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 Ethyl 
                 H 
               
               
                 696. 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 H 
                 Ethyl 
               
               
                 697. 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 Ethyl 
                 H 
                 H 
               
               
                 698. 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 H 
                 Ethyl 
                 H 
               
               
                 699. 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 Ethyl 
               
               
                 700. 
                 Isopropyl 
                 Methyl 
                 H 
                 Ethyl 
                 Methyl 
                 H 
               
               
                 701. 
                 Isopropyl 
                 Methyl 
                 H 
                 Ethyl 
                 Ethyl 
                 H 
               
               
                 702. 
                 Isopropyl 
                 Methyl 
                 H 
                 Methyl 
                 Ethyl 
                 H 
               
               
                 703. 
                 Isopropyl 
                 Methyl  
                 Isopropyl 
                 H 
                 H 
                 H 
               
               
                 704. 
                 Isopropyl 
                 Methyl 
                 H 
                 Isopropyl 
                 H 
                 H 
               
               
                 705. 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 Isopropyl 
                 H 
               
               
                 706. 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 H 
                 Isopropyl 
               
               
                 707. 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
               
               
                 708. 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 H 
                 Isopropyl 
                 H 
               
               
                 709. 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 Isopropyl 
               
               
                 710. 
                 Isopropyl 
                 Methyl 
                 H 
                 Isopropyl  
                 Methyl 
                 H 
               
               
                 711. 
                 Isopropyl 
                 Methyl 
                 H 
                 Isopropyl  
                 Isopropyl 
                 H 
               
               
                 712. 
                 Isopropyl 
                 Methyl 
                 H 
                 Methyl 
                 Isopropyl 
                 H 
               
               
                 713. 
                 Isopropyl 
                 Methyl 
                 H 
                 Isopropyl 
                 Ethyl 
                 H 
               
               
                 714. 
                 Isopropyl 
                 Methyl 
                 H 
                 Ethyl 
                 Isopropyl 
                 H 
               
               
                 715. 
                 Isopropyl 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
                 H 
               
               
                 716. 
                 Isopropyl 
                 Methyl 
                 H 
                 Isobutyl 
                 H 
                 H 
               
               
                 717. 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 Isobutyl 
                 H 
               
               
                 718. 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 H 
                 Isobutyl 
               
               
                 719. 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
               
               
                 720. 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 H 
                 Isobutyl 
                 H 
               
               
                 721. 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 Isobutyl 
               
               
                 722. 
                 Isopropyl 
                 Methyl 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
               
               
                 723. 
                 Isopropyl 
                 Methyl 
                 H 
                 Isobutyl 
                 Isobutyl 
                 H 
               
               
                 724. 
                 Isopropyl 
                 Methyl 
                 H 
                 Methyl 
                 Isobutyl 
                 H 
               
               
                 725. 
                 Isopropyl 
                 Methyl 
                 H 
                 Isobutyl 
                 Ethyl 
                 H 
               
               
                 726. 
                 Isopropyl 
                 Methyl 
                 H 
                 Ethyl 
                 Isobutyl 
                 H 
               
               
                 727. 
                 Isopropyl 
                 Methyl 
                 H 
                 Isobutyl 
                 Isopropyl 
                 H 
               
               
                 728. 
                 Isopropyl 
                 Methyl 
                 H 
                 Isopropyl  
                 Isobutyl 
                 H 
               
               
                 729. 
                 Isopropyl 
                 Ethyl 
                 H 
                 H 
                 H 
                 H 
               
               
                 730. 
                 Isopropyl 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 H 
               
               
                 731. 
                 Isopropyl 
                 Ethyl 
                 H 
                 Methyl 
                 H 
                 H 
               
               
                 732. 
                 Isopropyl 
                 Ethyl 
                 H 
                 H 
                 Methyl 
                 H 
               
               
                 733. 
                 Isopropyl 
                 Ethyl 
                 H 
                 H 
                 H 
                 Methyl 
               
               
                 734. 
                 Isopropyl 
                 Ethyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
               
               
                 735. 
                 Isopropyl 
                 Ethyl 
                 Methyl 
                 H 
                 Methyl 
                 H 
               
               
                 736. 
                 Isopropyl 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 Methyl 
               
               
                 737. 
                 Isopropyl 
                 Ethyl 
                 H 
                 Methyl 
                 Methyl 
                 H 
               
               
                 738. 
                 Isopropyl 
                 Ethyl 
                 H 
                 Methyl 
                 H 
                 Methyl 
               
               
                 739. 
                 Isopropyl 
                 Ethyl 
                 H 
                 H 
                 Methyl 
                 Methyl 
               
               
                 740. 
                 Isopropyl 
                 Ethyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
               
               
                 741. 
                 Isopropyl 
                 Ethyl 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
               
               
                 742. 
                 Isopropyl 
                 Ethyl 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
               
               
                 743. 
                 Isopropyl 
                 Ethyl 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 744. 
                 Isopropyl 
                 Ethyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 745. 
                 Isopropyl 
                 Ethyl 
                 Ethyl 
                 H 
                 H 
                 H 
               
               
                 746. 
                 Isopropyl 
                 Ethyl 
                 H 
                 Ethyl 
                 H 
                 H 
               
               
                 747. 
                 Isopropyl 
                 Ethyl 
                 H 
                 H 
                 Ethyl 
                 H 
               
               
                 748. 
                 Isopropyl 
                 Ethyl 
                 H 
                 H 
                 H 
                 Ethyl 
               
               
                 749. 
                 Isopropyl 
                 Ethyl 
                 Methyl 
                 Ethyl 
                 H 
                 H 
               
               
                 750. 
                 Isopropyl 
                 Ethyl 
                 Methyl 
                 H 
                 Ethyl 
                 H 
               
               
                 751. 
                 Isopropyl 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 Ethyl 
               
               
                 752. 
                 Isopropyl 
                 Ethyl 
                 H 
                 Ethyl 
                 Methyl 
                 H 
               
               
                 753. 
                 Isopropyl 
                 Ethyl 
                 H 
                 Ethyl 
                 Ethyl 
                 H 
               
               
                 754. 
                 Isopropyl 
                 Ethyl 
                 H 
                 Methyl 
                 Ethyl 
                 H 
               
               
                 755. 
                 Isopropyl 
                 Ethyl  
                 Isopropyl 
                 H 
                 H 
                 H 
               
               
                 756. 
                 Isopropyl 
                 Ethyl 
                 H 
                 Isopropyl 
                 H 
                 H 
               
               
                 757. 
                 Isopropyl 
                 Ethyl 
                 H 
                 H 
                 Isopropyl 
                 H 
               
               
                 758. 
                 Isopropyl 
                 Ethyl 
                 H 
                 H 
                 H 
                 Isopropyl 
               
               
                 759. 
                 Isopropyl 
                 Ethyl 
                 Methyl  
                 Isopropyl 
                 H 
                 H 
               
               
                 760. 
                 Isopropyl 
                 Ethyl 
                 Methyl 
                 H 
                 Isopropyl 
                 H 
               
               
                 761. 
                 Isopropyl 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 Isopropyl 
               
               
                 762. 
                 Isopropyl 
                 Ethyl 
                 H 
                 Isopropyl 
                 Methyl 
                 H 
               
               
                 763. 
                 Isopropyl 
                 Ethyl 
                 H 
                 Isopropyl 
                 Isopropyl 
                 H 
               
               
                 764. 
                 Isopropyl 
                 Ethyl 
                 H 
                 Methyl 
                 Isopropyl 
                 H 
               
               
                 765. 
                 Isopropyl 
                 Ethyl 
                 H 
                 Isopropyl 
                 Ethyl 
                 H 
               
               
                 766. 
                 Isopropyl 
                 Ethyl 
                 H 
                 Ethyl 
                 Isopropyl 
                 H 
               
               
                 767. 
                 Isopropyl 
                 Ethyl  
                 Isobutyl 
                 H 
                 H 
                 H 
               
               
                 768. 
                 Isopropyl 
                 Ethyl 
                 H 
                 Isobutyl 
                 H 
                 H 
               
               
                 769. 
                 Isopropyl 
                 Ethyl 
                 H 
                 H 
                 Isobutyl 
                 H 
               
               
                 770. 
                 Isopropyl 
                 Ethyl 
                 H 
                 H 
                 H 
                 Isobutyl 
               
               
                 771. 
                 Isopropyl 
                 Ethyl 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
               
               
                 772. 
                 Isopropyl 
                 Ethyl 
                 Methyl 
                 H 
                 Isobutyl 
                 H 
               
               
                 773. 
                 Isopropyl 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 Isobutyl 
               
               
                 774. 
                 Isopropyl 
                 Ethyl 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
               
               
                 775. 
                 Isopropyl 
                 Ethyl 
                 H 
                 Isobutyl 
                 Isobutyl 
                 H 
               
               
                 776. 
                 Isopropyl 
                 Ethyl 
                 H 
                 Methyl 
                 Isobutyl 
                 H 
               
               
                 777. 
                 Isopropyl 
                 Ethyl 
                 H 
                 Isobutyl 
                 Ethyl 
                 H 
               
               
                 778. 
                 Isopropyl 
                 Ethyl 
                 H 
                 Ethyl 
                 Isobutyl 
                 H 
               
               
                 779. 
                 Isopropyl 
                 Ethyl 
                 H 
                 Isobutyl 
                 Isopropyl 
                 H 
               
               
                 780. 
                 Isopropyl 
                 Ethyl 
                 H 
                 Isopropyl 
                 Isobutyl 
                 H 
               
               
                 781. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 H 
                 H 
                 H 
               
               
                 782. 
                 Isopropyl 
                 Isopropyl  
                 Methyl 
                 H 
                 H 
                 H 
               
               
                 783. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 Methyl 
                 H 
                 H 
               
               
                 784. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 H 
                 Methyl 
                 H 
               
               
                 785. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 H 
                 H 
                 Methyl 
               
               
                 786. 
                 Isopropyl 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
               
               
                 787. 
                 Isopropyl 
                 Isopropyl 
                 Methyl 
                 H 
                 Methyl 
                 H 
               
               
                 788. 
                 Isopropyl 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 Methyl 
               
               
                 789. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 Methyl 
                 Methyl 
                 H 
               
               
                 790. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 Methyl 
                 H 
                 Methyl 
               
               
                 791. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 H 
                 Methyl 
                 Methyl 
               
               
                 792. 
                 Isopropyl 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
               
               
                 793. 
                 Isopropyl 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
               
               
                 794. 
                 Isopropyl 
                 Isopropyl 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
               
               
                 795. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 796. 
                 Isopropyl 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 797. 
                 Isopropyl 
                 Isopropyl 
                 Ethyl 
                 H 
                 H 
                 H 
               
               
                 798. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 Ethyl 
                 H 
                 H 
               
               
                 799. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 H 
                 Ethyl 
                 H 
               
               
                 800. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 H 
                 H 
                 Ethyl 
               
               
                 801. 
                 Isopropyl 
                 Isopropyl 
                 Methyl 
                 Ethyl 
                 H 
                 H 
               
               
                 802. 
                 Isopropyl 
                 Isopropyl 
                 Methyl 
                 H 
                 Ethyl 
                 H 
               
               
                 803. 
                 Isopropyl 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 Ethyl 
               
               
                 804. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 Ethyl 
                 Methyl 
                 H 
               
               
                 805. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 Ethyl 
                 Ethyl 
                 H 
               
               
                 806. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 Methyl 
                 Ethyl 
                 H 
               
               
                 807. 
                 Isopropyl 
                 Isopropyl 
                 Isopropyl 
                 H 
                 H 
                 H 
               
               
                 808. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 Isopropyl 
                 H 
                 H 
               
               
                 809. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 H 
                 Isopropyl 
                 H 
               
               
                 810. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 H 
                 H 
                 Isopropyl 
               
               
                 811. 
                 Isopropyl 
                 Isopropyl 
                 Methyl  
                 Isopropyl 
                 H 
                 H 
               
               
                 812. 
                 Isopropyl 
                 Isopropyl 
                 Methyl 
                 H 
                 Isopropyl 
                 H 
               
               
                 813. 
                 Isopropyl 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 Isopropyl 
               
               
                 814. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 Isopropyl 
                 Methyl 
                 H 
               
               
                 815. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 Isopropyl 
                 Isopropyl 
                 H 
               
               
                 816. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 Methyl 
                 Isopropyl 
                 H 
               
               
                 817. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 Isopropyl 
                 Ethyl 
                 H 
               
               
                 818. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 Ethyl 
                 Isopropyl 
                 H 
               
               
                 819. 
                 Isopropyl 
                 Isopropyl 
                 Isobutyl 
                 H 
                 H 
                 H 
               
               
                 820. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 Isobutyl 
                 H 
                 H 
               
               
                 821. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 H 
                 Isobutyl 
                 H 
               
               
                 822. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 H 
                 H 
                 Isobutyl 
               
               
                 823. 
                 Isopropyl 
                 Isopropyl 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
               
               
                 824. 
                 Isopropyl 
                 Isopropyl 
                 Methyl 
                 H 
                 Isobutyl 
                 H 
               
               
                 825. 
                 Isopropyl 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 Isobutyl 
               
               
                 826. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
               
               
                 827. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 Isobutyl 
                 Isobutyl 
                 H 
               
               
                 828. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 Methyl 
                 Isobutyl 
                 H 
               
               
                 829. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 Isobutyl 
                 Ethyl 
                 H 
               
               
                 830. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 Ethyl 
                 Isobutyl 
                 H 
               
               
                 831. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 Isobutyl 
                 Isopropyl 
                 H 
               
               
                 832. 
                 Isopropyl 
                 Isopropyl 
                 H 
                 Isopropyl  
                 Isobutyl 
                 H 
               
               
                 833. 
                 Isopropyl  
                 Isobutyl 
                 H 
                 H 
                 H 
                 H 
               
               
                 834. 
                 Isopropyl  
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 H 
               
               
                 835. 
                 Isopropyl  
                 Isobutyl 
                 H 
                 Methyl 
                 H 
                 H 
               
               
                 836. 
                 Isopropyl  
                 Isobutyl 
                 H 
                 H 
                 Methyl 
                 H 
               
               
                 837. 
                 Isopropyl  
                 Isobutyl 
                 H 
                 H 
                 H 
                 Methyl 
               
               
                 838. 
                 Isopropyl  
                 Isobutyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
               
               
                 839. 
                 Isopropyl  
                 Isobutyl 
                 Methyl 
                 H 
                 Methyl 
                 H 
               
               
                 840. 
                 Isopropyl  
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 Methyl 
               
               
                 841. 
                 Isopropyl  
                 Isobutyl 
                 H 
                 Methyl 
                 Methyl 
                 H 
               
               
                 842. 
                 Isopropyl  
                 Isobutyl 
                 H 
                 Methyl 
                 H 
                 Methyl 
               
               
                 843. 
                 Isopropyl  
                 Isobutyl 
                 H 
                 H 
                 Methyl 
                 Methyl 
               
               
                 844. 
                 Isopropyl  
                 Isobutyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
               
               
                 845. 
                 Isopropyl  
                 Isobutyl 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
               
               
                 846. 
                 Isopropyl  
                 Isobutyl 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
               
               
                 847. 
                 Isopropyl  
                 Isobutyl 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 848. 
                 Isopropyl  
                 Isobutyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 849. 
                 Isopropyl  
                 Isobutyl 
                 Ethyl 
                 H 
                 H 
                 H 
               
               
                 850. 
                 Isopropyl  
                 Isobutyl 
                 H 
                 Ethyl 
                 H 
                 H 
               
               
                 851. 
                 Isopropyl  
                 Isobutyl 
                 H 
                 H 
                 Ethyl 
                 H 
               
               
                 852. 
                 Isopropyl  
                 Isobutyl 
                 H 
                 H 
                 H 
                 Ethyl 
               
               
                 853. 
                 Isopropyl  
                 Isobutyl 
                 Methyl 
                 Ethyl 
                 H 
                 H 
               
               
                 854. 
                 Isopropyl 
                 Isobutyl 
                 Methyl 
                 H 
                 Ethyl 
                 H 
               
               
                 855. 
                 Isopropyl  
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 Ethyl 
               
               
                 856. 
                 Isopropyl  
                 Isobutyl 
                 H 
                 Ethyl 
                 Methyl 
                 H 
               
               
                 857. 
                 Isopropyl  
                 Isobutyl 
                 H 
                 Ethyl 
                 Ethyl 
                 H 
               
               
                 858. 
                 Isopropyl  
                 Isobutyl 
                 H 
                 Methyl 
                 Ethyl 
                 H 
               
               
                 859. 
                 Isopropyl  
                 Isobutyl  
                 Isopropyl 
                 H 
                 H 
                 H 
               
               
                 860. 
                 Isopropyl  
                 Isobutyl 
                 H 
                 Isopropyl 
                 H 
                 H 
               
               
                 861. 
                 Isopropyl  
                 Isobutyl 
                 H 
                 H 
                 Isopropyl 
                 H 
               
               
                 862. 
                 Isopropyl  
                 Isobutyl 
                 H 
                 H 
                 H 
                 Isopropyl 
               
               
                 863. 
                 Isopropyl  
                 Isobutyl 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
               
               
                 864. 
                 Isopropyl 
                 Isobutyl 
                 Methyl 
                 H 
                 Isopropyl 
                 H 
               
               
                 865. 
                 Isopropyl 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 Isopropyl 
               
               
                 866. 
                 Isopropyl 
                 Isobutyl 
                 H 
                 Isopropyl 
                 Methyl 
                 H 
               
               
                 867. 
                 Isopropyl 
                 Isobutyl 
                 H 
                 Isopropyl 
                 Isopropyl 
                 H 
               
               
                 868. 
                 Isopropyl 
                 Isobutyl 
                 H 
                 Methyl 
                 Isopropyl 
                 H 
               
               
                 869. 
                 Isopropyl 
                 Isobutyl 
                 H 
                 Isopropyl 
                 Ethyl 
                 H 
               
               
                 870. 
                 Isopropyl 
                 Isobutyl 
                 H 
                 Ethyl 
                 Isopropyl 
                 H 
               
               
                 871. 
                 Isopropyl 
                 Isobutyl 
                 Isobutyl 
                 H 
                 H 
                 H 
               
               
                 872. 
                 Isopropyl 
                 Isobutyl 
                 H 
                 Isobutyl 
                 H 
                 H 
               
               
                 873. 
                 Isopropyl 
                 Isobutyl 
                 H 
                 H 
                 Isobutyl 
                 H 
               
               
                 874. 
                 Isopropyl 
                 Isobutyl 
                 H 
                 H 
                 H 
                 Isobutyl 
               
               
                 875. 
                 Isopropyl 
                 Isobutyl 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
               
               
                 876. 
                 Isopropyl 
                 Isobutyl 
                 Methyl 
                 H 
                 Isobutyl 
                 H 
               
               
                 877. 
                 Isopropyl 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 Isobutyl 
               
               
                 878. 
                 Isopropyl 
                 Isobutyl 
                 H 
                 Isobutyl  
                 Methyl 
                 H 
               
               
                 879. 
                 Isopropyl 
                 Isobutyl 
                 H 
                 Isobutyl 
                 Isobutyl 
                 H 
               
               
                 880. 
                 Isopropyl 
                 Isobutyl 
                 H 
                 Methyl 
                 Isobutyl 
                 H 
               
               
                 881. 
                 Isopropyl 
                 Isobutyl 
                 H 
                 Isobutyl  
                 Ethyl 
                 H 
               
               
                 882. 
                 Isopropyl 
                 Isobutyl 
                 H 
                 Ethyl 
                 Isobutyl 
                 H 
               
               
                 883. 
                 Isopropyl 
                 Isobutyl 
                 H 
                 Isobutyl  
                 Isopropyl 
                 H 
               
               
                 884. 
                 Isopropyl 
                 Isobutyl 
                 H 
                 Isopropyl 
                 Isobutyl 
                 H 
               
               
                 885. 
                 Isobutyl 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 886. 
                 Isobutyl 
                 H 
                 Methyl 
                 H 
                 H 
                 H 
               
               
                 887. 
                 Isobutyl 
                 H 
                 H 
                 Methyl 
                 H 
                 H 
               
               
                 888. 
                 Isobutyl 
                 H 
                 H 
                 H 
                 Methyl 
                 H 
               
               
                 889. 
                 Isobutyl 
                 H 
                 H 
                 H 
                 H 
                 Methyl 
               
               
                 890. 
                 Isobutyl 
                 H 
                 Methyl 
                 Methyl 
                 H 
                 H 
               
               
                 891. 
                 Isobutyl 
                 H 
                 Methyl 
                 H 
                 Methyl 
                 H 
               
               
                 892. 
                 Isobutyl 
                 H 
                 Methyl 
                 H 
                 H 
                 Methyl 
               
               
                 893. 
                 Isobutyl 
                 H 
                 H 
                 Methyl 
                 Methyl 
                 H 
               
               
                 894. 
                 Isobutyl 
                 H 
                 H 
                 Methyl 
                 H 
                 Methyl 
               
               
                 895. 
                 Isobutyl 
                 H 
                 H 
                 H 
                 Methyl 
                 Methyl 
               
               
                 896. 
                 Isobutyl 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
               
               
                 897. 
                 Isobutyl 
                 H 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
               
               
                 898. 
                 Isobutyl 
                 H 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
               
               
                 899. 
                 Isobutyl 
                 H 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 900. 
                 Isobutyl 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 901. 
                 Isobutyl 
                 H 
                 Ethyl 
                 H 
                 H 
                 H 
               
               
                 902. 
                 Isobutyl 
                 H 
                 H 
                 Ethyl 
                 H 
                 H 
               
               
                 903. 
                 Isobutyl 
                 H 
                 H 
                 H 
                 Ethyl 
                 H 
               
               
                 904. 
                 Isobutyl 
                 H 
                 H 
                 H 
                 H 
                 Ethyl 
               
               
                 905. 
                 Isobutyl 
                 H 
                 Methyl 
                 Ethyl 
                 H 
                 H 
               
               
                 906. 
                 Isobutyl 
                 H 
                 Methyl 
                 H 
                 Ethyl 
                 H 
               
               
                 907. 
                 Isobutyl 
                 H 
                 Methyl 
                 H 
                 H 
                 Ethyl 
               
               
                 908. 
                 Isobutyl 
                 H 
                 H 
                 Ethyl 
                 Methyl 
                 H 
               
               
                 909. 
                 Isobutyl 
                 H 
                 H 
                 Ethyl 
                 Ethyl 
                 H 
               
               
                 910. 
                 Isobutyl 
                 H 
                 H 
                 Methyl 
                 Ethyl 
                 H 
               
               
                 911. 
                 Isobutyl 
                 H 
                 Isopropyl 
                 H 
                 H 
                 H 
               
               
                 912. 
                 Isobutyl 
                 H 
                 H 
                 Isopropyl 
                 H 
                 H 
               
               
                 913. 
                 Isobutyl 
                 H 
                 H 
                 H 
                 Isopropyl 
                 H 
               
               
                 914. 
                 Isobutyl 
                 H 
                 H 
                 H 
                 H 
                 Isopropyl 
               
               
                 915. 
                 Isobutyl 
                 H 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
               
               
                 916. 
                 Isobutyl 
                 H 
                 Methyl 
                 H 
                 Isopropyl 
                 H 
               
               
                 917. 
                 Isobutyl 
                 H 
                 Methyl 
                 H 
                 H 
                 Isopropyl 
               
               
                 918. 
                 Isobutyl 
                 H 
                 H 
                 Isopropyl 
                 Methyl 
                 H 
               
               
                 919. 
                 Isobutyl 
                 H 
                 H 
                 Isopropyl 
                 Isopropyl 
                 H 
               
               
                 920. 
                 Isobutyl 
                 H 
                 H 
                 Methyl 
                 Isopropyl 
                 H 
               
               
                 921. 
                 Isobutyl 
                 H 
                 H 
                 Isopropyl  
                 Ethyl 
                 H 
               
               
                 922. 
                 Isobutyl 
                 H 
                 H 
                 Ethyl 
                 Isopropyl 
                 H 
               
               
                 923. 
                 Isobutyl 
                 H 
                 Isobutyl 
                 H 
                 H 
                 H 
               
               
                 924. 
                 Isobutyl 
                 H 
                 H 
                 Isobutyl 
                 H 
                 H 
               
               
                 925. 
                 Isobutyl 
                 H 
                 H 
                 H 
                 Isobutyl 
                 H 
               
               
                 926. 
                 Isobutyl 
                 H 
                 H 
                 H 
                 H 
                 Isobutyl 
               
               
                 927. 
                 Isobutyl 
                 H 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
               
               
                 928. 
                 Isobutyl 
                 H 
                 Methyl 
                 H 
                 Isobutyl 
                 H 
               
               
                 929. 
                 Isobutyl 
                 H 
                 Methyl 
                 H 
                 H 
                 Isobutyl 
               
               
                 930. 
                 Isobutyl 
                 H 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
               
               
                 931. 
                 Isobutyl 
                 H 
                 H 
                 Isobutyl  
                 Isobutyl 
                 H 
               
               
                 932. 
                 Isobutyl 
                 H 
                 H 
                 Methyl 
                 Isobutyl 
                 H 
               
               
                 933. 
                 Isobutyl 
                 H 
                 H 
                 Isobutyl 
                 Ethyl 
                 H 
               
               
                 934. 
                 Isobutyl 
                 H 
                 H 
                 Ethyl 
                 Isobutyl 
                 H 
               
               
                 935. 
                 Isobutyl 
                 H 
                 H 
                 Isobutyl  
                 Isopropyl 
                 H 
               
               
                 936. 
                 Isobutyl 
                 H 
                 H 
                 Isopropyl 
                 Isobutyl 
                 H 
               
               
                 937. 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 H 
                 H 
               
               
                 938. 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 H 
               
               
                 939. 
                 Isobutyl 
                 Methyl 
                 H 
                 Methyl 
                 H 
                 H 
               
               
                 940. 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 Methyl 
                 H 
               
               
                 941. 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 H 
                 Methyl 
               
               
                 942. 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
               
               
                 943. 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
                 H 
               
               
                 944. 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 Methyl 
               
               
                 945. 
                 Isobutyl 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
                 H 
               
               
                 946. 
                 Isobutyl 
                 Methyl 
                 H 
                 Methyl 
                 H 
                 Methyl 
               
               
                 947. 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 Methyl 
                 Methyl 
               
               
                 948. 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
               
               
                 949. 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
               
               
                 950. 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
               
               
                 951. 
                 Isobutyl 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 952. 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 953. 
                 Isobutyl 
                 Methyl 
                 Ethyl 
                 H 
                 H 
                 H 
               
               
                 954. 
                 Isobutyl 
                 Methyl 
                 H 
                 Ethyl 
                 H 
                 H 
               
               
                 955. 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 Ethyl 
                 H 
               
               
                 956. 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 H 
                 Ethyl 
               
               
                 957. 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 Ethyl 
                 H 
                 H 
               
               
                 958. 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 H 
                 Ethyl 
                 H 
               
               
                 959. 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 Ethyl 
               
               
                 960. 
                 Isobutyl 
                 Methyl 
                 H 
                 Ethyl 
                 Methyl 
                 H 
               
               
                 961. 
                 Isobutyl 
                 Methyl 
                 H 
                 Ethyl 
                 Ethyl 
                 H 
               
               
                 962. 
                 Isobutyl 
                 Methyl 
                 H 
                 Methyl 
                 Ethyl 
                 H 
               
               
                 963. 
                 Isobutyl 
                 Methyl  
                 Isopropyl 
                 H 
                 H 
                 H 
               
               
                 964. 
                 Isobutyl 
                 Methyl 
                 H 
                 Isopropyl 
                 H 
                 H 
               
               
                 965. 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 Isopropyl 
                 H 
               
               
                 966. 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 H 
                 Isopropyl 
               
               
                 967. 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
               
               
                 968. 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 H 
                 Isopropyl 
                 H 
               
               
                 969. 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 Isopropyl 
               
               
                 970. 
                 Isobutyl 
                 Methyl 
                 H 
                 Isopropyl 
                 Methyl 
                 H 
               
               
                 971. 
                 Isobutyl 
                 Methyl 
                 H 
                 Isopropyl 
                 Isopropyl 
                 H 
               
               
                 972. 
                 Isobutyl 
                 Methyl 
                 H 
                 Methyl 
                 Isopropyl 
                 H 
               
               
                 973. 
                 Isobutyl 
                 Methyl 
                 H 
                 Isopropyl 
                 Ethyl 
                 H 
               
               
                 974. 
                 Isobutyl 
                 Methyl 
                 H 
                 Ethyl 
                 Isopropyl 
                 H 
               
               
                 975. 
                 Isobutyl 
                 Methyl  
                 Isobutyl 
                 H 
                 H 
                 H 
               
               
                 976. 
                 Isobutyl 
                 Methyl 
                 H 
                 Isobutyl 
                 H 
                 H 
               
               
                 977. 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 Isobutyl 
                 H 
               
               
                 978. 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 H 
                 Isobutyl 
               
               
                 979. 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
               
               
                 980. 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 H 
                 Isobutyl 
                 H 
               
               
                 981. 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
                 Isobutyl 
               
               
                 982. 
                 Isobutyl 
                 Methyl 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
               
               
                 983. 
                 Isobutyl 
                 Methyl 
                 H 
                 Isobutyl 
                 Isobutyl 
                 H 
               
               
                 984. 
                 Isobutyl 
                 Methyl 
                 H 
                 Methyl 
                 Isobutyl 
                 H 
               
               
                 985. 
                 Isobutyl 
                 Methyl 
                 H 
                 Isobutyl 
                 Ethyl 
                 H 
               
               
                 986. 
                 Isobutyl 
                 Methyl 
                 H 
                 Ethyl 
                 Isobutyl 
                 H 
               
               
                 987. 
                 Isobutyl 
                 Methyl 
                 H 
                 Isobutyl 
                 Isopropyl 
                 H 
               
               
                 988. 
                 Isobutyl 
                 Methyl 
                 H 
                 Isopropyl  
                 Isobutyl 
                 H 
               
               
                 989. 
                 Isobutyl 
                 Ethyl 
                 H 
                 H 
                 H 
                 H 
               
               
                 990. 
                 Isobutyl 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 H 
               
               
                 991. 
                 Isobutyl 
                 Ethyl 
                 H 
                 Methyl 
                 H 
                 H 
               
               
                 992. 
                 Isobutyl 
                 Ethyl 
                 H 
                 H 
                 Methyl 
                 H 
               
               
                 993. 
                 Isobutyl 
                 Ethyl 
                 H 
                 H 
                 H 
                 Methyl 
               
               
                 994. 
                 Isobutyl 
                 Ethyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
               
               
                 995. 
                 Isobutyl 
                 Ethyl 
                 Methyl 
                 H 
                 Methyl 
                 H 
               
               
                 996. 
                 Isobutyl 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 Methyl 
               
               
                 997. 
                 Isobutyl 
                 Ethyl 
                 H 
                 Methyl 
                 Methyl 
                 H 
               
               
                 998. 
                 Isobutyl 
                 Ethyl 
                 H 
                 Methyl 
                 H 
                 Methyl 
               
               
                 999. 
                 Isobutyl 
                 Ethyl 
                 H 
                 H 
                 Methyl 
                 Methyl 
               
               
                 1000. 
                 Isobutyl 
                 Ethyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
               
               
                 1001. 
                 Isobutyl 
                 Ethyl 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
               
               
                 1002. 
                 Isobutyl 
                 Ethyl 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
               
               
                 1003. 
                 Isobutyl 
                 Ethyl 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 1004. 
                 Isobutyl 
                 Ethyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 1005. 
                 Isobutyl 
                 Ethyl 
                 Ethyl 
                 H 
                 H 
                 H 
               
               
                 1006. 
                 Isobutyl 
                 Ethyl 
                 H 
                 Ethyl 
                 H 
                 H 
               
               
                 1007. 
                 Isobutyl 
                 Ethyl 
                 H 
                 H 
                 Ethyl 
                 H 
               
               
                 1008. 
                 Isobutyl 
                 Ethyl 
                 H 
                 H 
                 H 
                 Ethyl 
               
               
                 1009. 
                 Isobutyl 
                 Ethyl 
                 Methyl 
                 Ethyl 
                 H 
                 H 
               
               
                 1010. 
                 Isobutyl 
                 Ethyl 
                 Methyl 
                 H 
                 Ethyl 
                 H 
               
               
                 1011. 
                 Isobutyl 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 Ethyl 
               
               
                 1012. 
                 Isobutyl 
                 Ethyl 
                 H 
                 Ethyl 
                 Methyl 
                 H 
               
               
                 1013. 
                 Isobutyl 
                 Ethyl 
                 H 
                 Ethyl 
                 Ethyl 
                 H 
               
               
                 1014. 
                 Isobutyl 
                 Ethyl 
                 H 
                 Methyl 
                 Ethyl 
                 H 
               
               
                 1015. 
                 Isobutyl 
                 Ethyl 
                 Isopropyl 
                 H 
                 H 
                 H 
               
               
                 1016. 
                 Isobutyl 
                 Ethyl 
                 H 
                 Isopropyl 
                 H 
                 H 
               
               
                 1017. 
                 Isobutyl 
                 Ethyl 
                 H 
                 H 
                 Isopropyl 
                 H 
               
               
                 1018. 
                 Isobutyl 
                 Ethyl 
                 H 
                 H 
                 H 
                 Isopropyl 
               
               
                 1019. 
                 Isobutyl 
                 Ethyl 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
               
               
                 1020. 
                 Isobutyl 
                 Ethyl 
                 Methyl 
                 H 
                 Isopropyl 
                 H 
               
               
                 1021. 
                 Isobutyl 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 Isopropyl 
               
               
                 1022. 
                 Isobutyl 
                 Ethyl 
                 H 
                 Isopropyl 
                 Methyl 
                 H 
               
               
                 1023. 
                 Isobutyl 
                 Ethyl 
                 H 
                 Isopropyl  
                 Isopropyl 
                 H 
               
               
                 1024. 
                 Isobutyl 
                 Ethyl 
                 H 
                 Methyl 
                 Isopropyl 
                 H 
               
               
                 1025. 
                 Isobutyl 
                 Ethyl 
                 H 
                 Isopropyl 
                 Ethyl 
                 H 
               
               
                 1026. 
                 Isobutyl 
                 Ethyl 
                 H 
                 Ethyl 
                 Isopropyl 
                 H 
               
               
                 1027. 
                 Isobutyl 
                 Ethyl 
                 Isobutyl 
                 H 
                 H 
                 H 
               
               
                 1028. 
                 Isobutyl 
                 Ethyl 
                 H 
                 Isobutyl 
                 H 
                 H 
               
               
                 1029. 
                 Isobutyl 
                 Ethyl 
                 H 
                 H 
                 Isobutyl 
                 H 
               
               
                 1030. 
                 Isobutyl 
                 Ethyl 
                 H 
                 H 
                 H 
                 Isobutyl 
               
               
                 1031. 
                 Isobutyl 
                 Ethyl 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
               
               
                 1032. 
                 Isobutyl 
                 Ethyl 
                 Methyl 
                 H 
                 Isobutyl 
                 H 
               
               
                 1033. 
                 Isobutyl 
                 Ethyl 
                 Methyl 
                 H 
                 H 
                 Isobutyl 
               
               
                 1034. 
                 Isobutyl 
                 Ethyl 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
               
               
                 1035. 
                 Isobutyl 
                 Ethyl 
                 H 
                 Isobutyl 
                 Isobutyl 
                 H 
               
               
                 1036. 
                 Isobutyl 
                 Ethyl 
                 H 
                 Methyl 
                 Isobutyl 
                 H 
               
               
                 1037. 
                 Isobutyl 
                 Ethyl 
                 H 
                 Isobutyl 
                 Ethyl 
                 H 
               
               
                 1038. 
                 Isobutyl 
                 Ethyl 
                 H 
                 Ethyl 
                 Isobutyl 
                 H 
               
               
                 1039. 
                 Isobutyl 
                 Ethyl 
                 H 
                 Isobutyl 
                 Isopropyl 
                 H 
               
               
                 1040. 
                 Isobutyl 
                 Ethyl 
                 H 
                 Isopropyl 
                 Isobutyl 
                 H 
               
               
                 1041. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 H 
                 H 
                 H 
               
               
                 1042. 
                 Isobutyl 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 H 
               
               
                 1043. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 Methyl 
                 H 
                 H 
               
               
                 1044. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 H 
                 Methyl 
                 H 
               
               
                 1045. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 H 
                 H 
                 Methyl 
               
               
                 1046. 
                 Isobutyl 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
               
               
                 1047. 
                 Isobutyl 
                 Isopropyl 
                 Methyl 
                 H 
                 Methyl 
                 H 
               
               
                 1048. 
                 Isobutyl 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 Methyl 
               
               
                 1049. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 Methyl 
                 Methyl 
                 H 
               
               
                 1050. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 Methyl 
                 H 
                 Methyl 
               
               
                 1051. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 H 
                 Methyl 
                 Methyl 
               
               
                 1052. 
                 Isobutyl 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
               
               
                 1053. 
                 Isobutyl 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
               
               
                 1054. 
                 Isobutyl 
                 Isopropyl 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
               
               
                 1055. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 1056. 
                 Isobutyl 
                 Isopropyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 1057. 
                 Isobutyl 
                 Isopropyl 
                 Ethyl 
                 H 
                 H 
                 H 
               
               
                 1058. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 Ethyl 
                 H 
                 H 
               
               
                 1059. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 H 
                 Ethyl 
                 H 
               
               
                 1060. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 H 
                 H 
                 Ethyl 
               
               
                 1061. 
                 Isobutyl 
                 Isopropyl 
                 Methyl 
                 Ethyl 
                 H 
                 H 
               
               
                 1062. 
                 Isobutyl 
                 Isopropyl 
                 Methyl 
                 H 
                 Ethyl 
                 H 
               
               
                 1063. 
                 Isobutyl 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 Ethyl 
               
               
                 1064. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 Ethyl 
                 Methyl 
                 H 
               
               
                 1065. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 Ethyl 
                 Ethyl 
                 H 
               
               
                 1066. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 Methyl 
                 Ethyl 
                 H 
               
               
                 1067. 
                 Isobutyl 
                 Isopropyl 
                 Isopropyl 
                 H 
                 H 
                 H 
               
               
                 1068. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 Isopropyl 
                 H 
                 H 
               
               
                 1069. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 H 
                 Isopropyl 
                 H 
               
               
                 1070. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 H 
                 H 
                 Isopropyl 
               
               
                 1071. 
                 Isobutyl 
                 Isopropyl 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
               
               
                 1072. 
                 Isobutyl 
                 Isopropyl 
                 Methyl 
                 H 
                 Isopropyl 
                 H 
               
               
                 1073. 
                 Isobutyl 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 Isopropyl 
               
               
                 1074. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 Isopropyl 
                 Methyl 
                 H 
               
               
                 1075. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 Isopropyl 
                 Isopropyl 
                 H 
               
               
                 1076. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 Methyl 
                 Isopropyl 
                 H 
               
               
                 1077. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 Isopropyl 
                 Ethyl 
                 H 
               
               
                 1078. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 Ethyl 
                 Isopropyl 
                 H 
               
               
                 1079. 
                 Isobutyl 
                 Isopropyl 
                 Isobutyl 
                 H 
                 H 
                 H 
               
               
                 1080. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 Isobutyl 
                 H 
                 H 
               
               
                 1081. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 H 
                 Isobutyl 
                 H 
               
               
                 1082. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 H 
                 H 
                 Isobutyl 
               
               
                 1083. 
                 Isobutyl 
                 Isopropyl 
                 Methyl  
                 Isobutyl 
                 H 
                 H 
               
               
                 1084. 
                 Isobutyl 
                 Isopropyl 
                 Methyl 
                 H 
                 Isobutyl 
                 H 
               
               
                 1085. 
                 Isobutyl 
                 Isopropyl 
                 Methyl 
                 H 
                 H 
                 Isobutyl 
               
               
                 1086. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
               
               
                 1087. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 Isobutyl 
                 Isobutyl 
                 H 
               
               
                 1088. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 Methyl 
                 Isobutyl 
                 H 
               
               
                 1089. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 Isobutyl 
                 Ethyl 
                 H 
               
               
                 1090. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 Ethyl 
                 Isobutyl 
                 H 
               
               
                 1091. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 Isobutyl 
                 Isopropyl 
                 H 
               
               
                 1092. 
                 Isobutyl 
                 Isopropyl 
                 H 
                 Isopropyl 
                 Isobutyl 
                 H 
               
               
                 1093. 
                 Isobutyl  
                 Isobutyl 
                 H 
                 H 
                 H 
                 H 
               
               
                 1094. 
                 Isobutyl 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 H 
               
               
                 1095. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 Methyl 
                 H 
                 H 
               
               
                 1096. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 H 
                 Methyl 
                 H 
               
               
                 1097. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 H 
                 H 
                 Methyl 
               
               
                 1098. 
                 Isobutyl 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 H 
                 H 
               
               
                 1099. 
                 Isobutyl 
                 Isobutyl 
                 Methyl 
                 H 
                 Methyl 
                 H 
               
               
                 1100. 
                 Isobutyl 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 Methyl 
               
               
                 1101. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 Methyl 
                 Methyl 
                 H 
               
               
                 1102. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 Methyl 
                 H 
                 Methyl 
               
               
                 1103. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 H 
                 Methyl 
                 Methyl 
               
               
                 1104. 
                 Isobutyl 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 H 
               
               
                 1105. 
                 Isobutyl 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 H 
                 Methyl 
               
               
                 1106. 
                 Isobutyl 
                 Isobutyl 
                 Methyl 
                 H 
                 Methyl 
                 Methyl 
               
               
                 1107. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 1108. 
                 Isobutyl 
                 Isobutyl 
                 Methyl 
                 Methyl 
                 Methyl 
                 Methyl 
               
               
                 1109. 
                 Isobutyl 
                 Isobutyl 
                 Ethyl 
                 H 
                 H 
                 H 
               
               
                 1110. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 Ethyl 
                 H 
                 H 
               
               
                 1111. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 H 
                 Ethyl 
                 H 
               
               
                 1112. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 H 
                 H 
                 Ethyl 
               
               
                 1113. 
                 Isobutyl 
                 Isobutyl 
                 Methyl 
                 Ethyl 
                 H 
                 H 
               
               
                 1114. 
                 Isobutyl 
                 Isobutyl 
                 Methyl 
                 H 
                 Ethyl 
                 H 
               
               
                 1115. 
                 Isobutyl 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 Ethyl 
               
               
                 1116. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 Ethyl 
                 Methyl 
                 H 
               
               
                 1117. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 Ethyl 
                 Ethyl 
                 H 
               
               
                 1118. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 Methyl 
                 Ethyl 
                 H 
               
               
                 1119. 
                 Isobutyl 
                 Isobutyl 
                 Isopropyl 
                 H 
                 H 
                 H 
               
               
                 1120. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 Isopropyl 
                 H 
                 H 
               
               
                 1121. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 H 
                 Isopropyl 
                 H 
               
               
                 1122. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 H 
                 H 
                 Isopropyl 
               
               
                 1123. 
                 Isobutyl 
                 Isobutyl 
                 Methyl 
                 Isopropyl 
                 H 
                 H 
               
               
                 1124. 
                 Isobutyl 
                 Isobutyl 
                 Methyl 
                 H 
                 Isopropyl 
                 H 
               
               
                 1125. 
                 Isobutyl 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 Isopropyl 
               
               
                 1126. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 Isopropyl 
                 Methyl 
                 H 
               
               
                 1127. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 Isopropyl 
                 Isopropyl 
                 H 
               
               
                 1128. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 Methyl 
                 Isopropyl 
                 H 
               
               
                 1129. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 Isopropyl 
                 Ethyl 
                 H 
               
               
                 1130. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 Ethyl 
                 Isopropyl 
                 H 
               
               
                 1131. 
                 Isobutyl 
                 Isobutyl 
                 Isobutyl 
                 H 
                 H 
                 H 
               
               
                 1132. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 Isobutyl 
                 H 
                 H 
               
               
                 1133. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 H 
                 Isobutyl 
                 H 
               
               
                 1134. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 H 
                 H 
                 Isobutyl 
               
               
                 1135. 
                 Isobutyl 
                 Isobutyl 
                 Methyl 
                 Isobutyl 
                 H 
                 H 
               
               
                 1136. 
                 Isobutyl 
                 Isobutyl 
                 Methyl 
                 H 
                 Isobutyl 
                 H 
               
               
                 1137. 
                 Isobutyl 
                 Isobutyl 
                 Methyl 
                 H 
                 H 
                 Isobutyl 
               
               
                 1138. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 Isobutyl 
                 Methyl 
                 H 
               
               
                 1139. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 Isobutyl 
                 Isobutyl 
                 H 
               
               
                 1140. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 Methyl 
                 Isobutyl 
                 H 
               
               
                 1141. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 Isobutyl 
                 Ethyl 
                 H 
               
               
                 1142. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 Ethyl 
                 Isobutyl 
                 H 
               
               
                 1143. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 Isobutyl 
                 Isopropyl 
                 H 
               
               
                 1144. 
                 Isobutyl 
                 Isobutyl 
                 H 
                 Isopropyl 
                 Isobutyl 
                 H 
               
               
                 1145. 
                 CD 3 CH 2   
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 1146. 
                 (CD 3 ) 2 CH 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
            
           
         
       
     
     In one embodiment, a first device is provided. The first device comprises a first organic light emitting device, further comprising an anode, a cathode, and an organic layer, disposed between the anode and the cathode, comprising a compound having the formula: 
     
       
         
         
             
             
         
       
     
     R 1  and R 2  are optionally linked and the sum of the number of carbon atoms in R1 and R2 is at least 2. R 3 , R 4 , R 5 , R 6  are optionally linked, and R a  and R b  represent mono-, di-, tri- or tetra-substitution. X is selected from the group consisting of BR, NR, PR, O, S, Se, C═O, S═O, SO 2 , CRR′, SiRR′, and GeRR′, and R a , R b , R, R′, R 1 , R 2 , R 3 , R 4 , R 5 , and R 6  are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and wherein n is 1 or 2. 
     In one embodiment, the first device is a consumer product. In another embodiment, the first device is an organic light-emitting device. In another embodiment, the first device comprises a lighting panel. In one embodiment, the organic layer is an emissive layer and the compound is an emissive dopant. In another embodiment, the organic layer is an emissive layer and the compound is a non-emissive dopant. 
     In one embodiment, the organic layer further comprises a host. In another embodiment, the host comprises a triphenylene containing benzo-fused thiophene or benzo-fused furan, wherein any substituent in the host is an unfused substituent independently selected from the group consisting of C n H 2n+1 , OC n H 2n+1 , OAr 1 , N(C n H 2n−1 ) 2 , N(Ar 1 )(Ar 2 ), CH═CH—C n H 2n+1 , C≡CHC n H 2n−1 , Ar 1 , Ar 1 —Ar 2 , C n H 2n —Ar 1 , or no substitution, wherein Ar 1  and Ar 2  are independently selected from the group consisting of benzene, biphenyl, naphthalene, triphenylene, carbazole, and heteroaromatic analogs thereof, and wherein n is from 1 to 10. 
     In one embodiment, the host has the formula 
     
       
         
         
             
             
         
       
     
     In another embodiment, the host is selected from the group consisting of: 
                                           
and combinations thereof.
 
     In one embodiment, the host is a metal complex. 
     Device Examples 
     All example devices were fabricated by high vacuum (&lt;10 −7  Torr) thermal evaporation (VTE). The anode electrode is 1200 Å of indium tin oxide (ITO). The cathode consisted of 10 Å of LiF followed by 1,000 Å of Al. All devices are encapsulated with a glass lid sealed with an epoxy resin in a nitrogen glove box (&lt;1 ppm of H 2 O and O 2 ) immediately after fabrication, and a moisture getter was incorporated inside the package. 
     The organic stack of the device examples consisted of sequentially, from the ITO surface, 100 Å of Compound C as the hole injection layer (HIL), 300 Å of 4,4′-bis[N-(1-naphthyl)-N-phenylamino]biphenyl (alpha-NPD) as the hole transporting layer (HTL), 300 Å of the invention compound doped in Compound D as host with 5-15 weight percent of a compound of Formula I as the emissive layer (EML), 50 Å of Compound D as blocking layer (BL), and 400 Å of Alq (tris-8-hydroxyquinoline aluminum) as the ETL. Comparative Examples with Compound A and Compound B were fabricated similarly to the Device Examples except that Compound A and Compound B were used as the emitter in the EML. 
     The device results and data are summarized in Tables 1 from those devices. As used herein, NPD, Alq, Compound A, Compound B, Compound C, and Compound D have the following structures: 
     
       
         
         
             
             
         
       
     
     
       
         
           
               
             
               
                 TABLE 2 
               
             
            
               
                   
               
               
                 VTE Phosphorescent OLEDs 
               
            
           
           
               
               
               
               
               
               
            
               
                 Example 
                 HIL 
                 HTL 
                 EML (300 Å, doping %) 
                 BL 
                 ETL 1 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
            
               
                 Comparative  
                 Compound C 
                 NPD 300 Å 
                 Compound 
                 Compound A 
                 Compound D 
                 Alq 400 Å 
               
               
                 Example 1 
                 100 Å 
                   
                 D 
                 10% 
                 50 Å 
                   
               
               
                 Comparative 
                 Compound C 
                 NPD 300 Å 
                 Compound 
                 Compound B 
                 Compound D 
                 Alq 400 Å 
               
               
                 Example 2 
                 100 Å 
                   
                 D 
                 10% 
                 50 Å 
                   
               
               
                 Example 1 
                 Compound C 
                 NPD 300 Å 
                 Compound 
                 Compound 53 
                 Compound D 
                 Alq 400 Å 
               
               
                   
                 100 Å 
                   
                 D 
                 12% 
                 50 Å 
                   
               
               
                 Example 2 
                 Compound C 
                 NPD 300 Å 
                 Compound 
                 Compound 157 
                 Compound D 
                 Alq 400 Å 
               
               
                   
                 100 Å 
                   
                 D 
                 10% 
                 50 Å 
                   
               
               
                 Example 3 
                 Compound C 
                 NPD 300 Å 
                 Compound 
                 Compound 158 
                 Compound D 
                 Alq 400 Å 
               
               
                   
                 100 Å 
                   
                 D 
                 12% 
                 50 Å 
                   
               
               
                 Example 4 
                 Compound C  
                 NPD 300 Å 
                 Compound 
                 Compound 159 
                 Compound D 
                 Alq 400 Å 
               
               
                   
                 100 Å 
                   
                 D 
                 10% 
                 50 Å 
                   
               
               
                 Example 5 
                 Compound C 
                 NPD 300 Å 
                 Compound 
                 Compound 165 
                 Compound D 
                 Alq 400 Å 
               
               
                   
                 100 Å 
                   
                 D 
                 12% 
                 50 Å 
                   
               
               
                 Example 6 
                 Compound C 
                 NPD 300 Å 
                 Compound 
                 Compound 174 
                 Compound D 
                 Alq 400 Å 
               
               
                   
                 100 Å 
                   
                 D 
                  8% 
                 50 Å 
                   
               
               
                 Example 7 
                 Compound C 
                 NPD 300 Å 
                 Compound 
                 Compound 175 
                 Compound D 
                 Alq 400 Å 
               
               
                   
                 100 Å 
                   
                 D 
                  8% 
                 50 Å 
                   
               
               
                 Example 8 
                 Compound C 
                 NPD 300 Å 
                 Compound 
                 Compound 184 
                 Compound D 
                 Alq 400 Å 
               
               
                   
                 100 Å 
                   
                 D 
                  7% 
                 50 Å 
                   
               
               
                 Example 9 
                 Compound C 
                 NPD 300 Å 
                 Compound 
                 Compound 185 
                 Compound D 
                 Alq 400 Å 
               
               
                   
                 100 Å 
                   
                 D 
                 10% 
                 50 Å 
                   
               
               
                 Example 10 
                 Compound C 
                 NPD 300 Å 
                 Compound 
                 Compound 314 
                 Compound D 
                 Alq 400 Å 
               
               
                   
                 100 Å 
                   
                 D 
                 12% 
                 50 Å 
                   
               
               
                 Example 11 
                 Compound C  
                 NPD 300 Å 
                 Compound 
                 Compound 321 
                 Compound D 
                 Alq 400 Å 
               
               
                   
                 100 Å 
                   
                 D 
                 12% 
                 50 Å 
                   
               
               
                 Example 12 
                 Compound C 
                 NPD 300 Å 
                 Compound 
                 Compound 625 
                 Compound D 
                 Alq 400 Å 
               
               
                   
                 100 Å 
                   
                 D 
                 12% 
                 50 Å 
                   
               
               
                 Example 13 
                 Compound C 
                 NPD 300 Å 
                 Compound 
                 Compound 626 
                 Compound D 
                 Alq 400 Å 
               
               
                   
                 100 Å 
                   
                 D 
                 10% 
                 50 Å 
                   
               
               
                 Example 14 
                 Compound C 
                 NPD 300 Å 
                 Compound 
                 Compound 627 
                 Compound D 
                 Alq 400 Å 
               
               
                   
                 100 Å 
                   
                 D 
                  8% 
                 50 Å 
                   
               
               
                 Example 15 
                 Compound C 
                 NPD 300 Å 
                 Compound 
                 Compound 628 
                 Compound D 
                 Alq 400 Å 
               
               
                   
                 100 Å 
                   
                 D 
                  8% 
                 50 Å 
                   
               
               
                 Example 16 
                 Compound C 
                 NPD 300 Å 
                 Compound 
                 Compound 633 
                 Compound D 
                 Alq 400 Å 
               
               
                   
                 100 Å 
                   
                 D 
                 10% 
                 50 Å 
                   
               
               
                 Example 17 
                 Compound C 
                 NPD 300 Å 
                 Compound 
                 Compound 643 
                 Compound D 
                 Alq 400 Å 
               
               
                   
                 100 Å 
                   
                 D 
                  8% 
                 50 Å 
                   
               
               
                 Example 18 
                 Compound C  
                 NPD 300 Å 
                 Compound 
                 Compound 652 
                 Compound D 
                 Alq 400 Å 
               
               
                   
                 100 Å 
                   
                 D 
                  8% 
                 50 Å 
                   
               
               
                 Example 19 
                 Compound C 
                 NPD 300 Å 
                 Compound 
                 Compound 653 
                 Compound D 
                 Alq 400 Å 
               
               
                   
                 100 Å 
                   
                 D 
                  8% 
                 50 Å 
                   
               
               
                 Example 20 
                 Compound C  
                 NPD 300 Å 
                 Compound 
                 Compound 1145 
                 Compound D 
                 Alq 400 Å 
               
               
                   
                 100 Å 
                   
                 D 
                 10% 
                 50 Å 
                   
               
               
                 Example 21 
                 Compound C 
                 NPD 300 Å 
                 Compound 
                 Compound 1146 
                 Compound D 
                 Alq 400 Å 
               
               
                   
                 100 Å 
                   
                 D 
                 10% 
                 50 Å 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 3 
               
             
            
               
                   
               
               
                 VTE Device Data 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                   
                 λ max   
                 FWHM 
                 Voltage 
                 LE 
                 EQE 
                 PE 
                 LT80% 
               
               
                   
                 x 
                 y 
                 (nm) 
                 (nm) 
                 (V) 
                 (Cd/A) 
                 (%) 
                 (lm/W) 
                 (h) 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
            
               
                 Comparative 
                 0.367 
                 0.607 
                 532 
                 66 
                 6.5 
                 43.2 
                 11.5 
                 21 
                 250 
               
               
                 Example 1 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Compound A 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Comparative 
                 0.336 
                 0.623 
                 524 
                 66 
                 5.2 
                 58.2 
                 15.7 
                 35 
                 170 
               
               
                 Example 2 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Compound B 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Example 1 
                 0.345 
                 0.619 
                 526 
                 64 
                 5.1 
                 69.2 
                 18.7 
                 42.7 
                 20 
               
               
                 Compound 53 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Example 2 
                 0.336 
                 0.618 
                 518 
                 70 
                 5.8 
                 62.2 
                 17.3 
                 33.6 
                 166 
               
               
                 Compound 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 157 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Example 3 
                 0.318 
                 0.632 
                 518 
                 60 
                 4.7 
                 73.4 
                 20.2 
                 49.1 
                 55 
               
               
                 Compound 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 158 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Example 4 
                 0.339 
                 0.616 
                 520 
                 66 
                 5.4 
                 58.3 
                 16.2 
                 33.9 
                 82 
               
               
                 Compound 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 159 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Example 5 
                 0.333 
                 0.626 
                 522 
                 62 
                 4.6 
                 56.1 
                 15.2 
                 38.3 
                 54 
               
               
                 Compound 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 165 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Example 6 
                 0.327 
                 0.627 
                 520 
                 64 
                 4.9 
                 61.5 
                 16.9 
                 39.3 
                 62 
               
               
                 Compound 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 174 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Example 7 
                 0.314 
                 0.635 
                 518 
                 60 
                 5.3 
                 71.2 
                 19.5 
                 42.2 
                 77 
               
               
                 Compound 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 175 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Example 8 
                 0.331 
                 0.623 
                 518 
                 64 
                 5.7 
                 52.8 
                 14.6 
                 28.8 
                 66 
               
               
                 Compound 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 184 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Example 9 
                 0.331 
                 0.623 
                 518 
                 64 
                 5.4 
                 56.7 
                 15.7 
                 32.9 
                 53 
               
               
                 Compound 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 185 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Example 10 
                 0.308 
                 0.636 
                 516 
                 60 
                 5.0 
                 61.4 
                 16.9 
                 38.9 
                 44 
               
               
                 Compound 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 314 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Example 11 
                 0.326 
                 0.630 
                 520 
                 60 
                 5.1 
                 61.4 
                 16.6 
                 37.7 
                 73 
               
               
                 Compound 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 321 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Example 12 
                 0.338 
                 0.622 
                 524 
                 66 
                 5.1 
                 60.1 
                 16.3 
                 37.2 
                 124 
               
               
                 Compound 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 625 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Example 13 
                 0.336 
                 0.624 
                 522 
                 64 
                 5.5 
                 67.4 
                 18.2 
                 38.2 
                 71 
               
               
                 Compound 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 626 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Example 14 
                 0.345 
                 0.619 
                 526 
                 64 
                 5.2 
                 65.2 
                 17.7 
                 39.2 
                 121 
               
               
                 Compound 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 627 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Example 15 
                 0.351 
                 0.615 
                 526 
                 64 
                 5.6 
                 68.6 
                 18.6 
                 38.7 
                 124 
               
               
                 Compound 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 628 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Example 16 
                 0.366 
                 0.608 
                 528 
                 66 
                 5.0 
                 66.3 
                 17.8 
                 41.8 
                 56 
               
               
                 Compound 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 633 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Example 17 
                 0.339 
                 0.625 
                 526 
                 60 
                 5.2 
                 71.5 
                 19.1 
                 43.3 
                 108 
               
               
                 Compound 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 643 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Example 18 
                 0.349 
                 0.616 
                 526 
                 66 
                 5.7 
                 53.4 
                 14.5 
                 29.3 
                 104 
               
               
                 Compound 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 652 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Example 19 
                 0.337 
                 0.626 
                 524 
                 62 
                 5.1 
                 65.6 
                 17.6 
                 40.8 
                 84 
               
               
                 Compound 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 653 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Example 20 
                 0.343 
                 0.618 
                 524 
                 68 
                 5.6 
                 61.3 
                 16.7 
                 34.4 
                 59 
               
               
                 Compound 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 1145 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Example 21 
                 0.343 
                 0.618 
                 524 
                 68 
                 5.6 
                 63 
                 17.2 
                 35.5 
                 157 
               
               
                 Compound 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 1146 
               
               
                   
               
            
           
         
       
     
     Table 3 is a summary of the device data. The luminous efficiency (LE), external quantum efficiency (EQE) and power efficiency (PE) were measured at 1000 nits, while the lifetime (LT 80% ) was defined as the time required for the device to decay to 80% of its initial luminance under a constant current density of 40 mA/cm 2 . 
     The advantage of alkyl substitution on the 4- and 5-positions of the DBX-pyridine ring is clear from Table 3. Compared to Comparative Example 1, with no substitution at the 4- or 5-positions of the DBX-pyridine ring, the compounds of Formula I are more saturated (lower CIE x coordinate and shorter λ max ) and the broadness as measured by the FWHM is comparable. In all the inventive compounds, the voltage is lower and the LE, PE and EQE values are all higher. In the case of Compounds 53, 158, 175, 633 and 643, the PE is at least twice as high as Comparative Example 1. 
     Compared to Comparative Example 2 (Compound B), with only one-carbon substitution (methyl) at the 4-position of the DBX-pyridine ring, Compounds 53, 158, 174, 175, 184, 185, and 314 have more saturated color based CIE x coordinate and Compounds 157, 158, 159, 165, 174, 175, 184, 185, 314, 321 and 626 all have shorter λmax values. Most of the compounds of Formula I have narrower emission profiles (as measured by FWHM) than Comparative Example 2. Compounds 53, 158, 165, 314, 321, 625, 633 and 653 all have lower driving voltages than Comparative Example 2. Most of the compounds of Formula I have greater LE, PE and EQE values than Comparative Example 2. 
     Combination with other Materials 
     The materials described herein as useful for a particular layer in an organic light emitting device may be used in combination with a wide variety of other materials present in the device. For example, emissive dopants disclosed herein may be used in conjunction with a wide variety of hosts, transport layers, blocking layers, injection layers, electrodes and other layers that may be present. The materials described or referred to below are non-limiting examples of materials that may be useful in combination with the compounds disclosed herein, and one of skill in the art can readily consult the literature to identify other materials that may be useful in combination. 
     HIL/HTL: 
     A hole injecting/transporting material to be used in the present invention is not particularly limited, and any compound may be used as long as the compound is typically used as a hole injecting/transporting material. Examples of the material include, but not limit to: a phthalocyanine or porphryin derivative; an aromatic amine derivative; an indolocarbazole derivative; a polymer containing fluorohydrocarbon; a polymer with conductivity dopants; a conducting polymer, such as PEDOT/PSS; a self-assembly monomer derived from compounds such as phosphonic acid and sliane derivatives; a metal oxide derivative, such as MoO x ; a p-type semiconducting organic compound, such as 1,4,5,8,9,12-Hexaazatriphenylenehexacarbonitrile; a metal complex, and a cross-linkable compounds. 
     Examples of aromatic amine derivatives used in HIL or HTL include, but not limit to the following general structures: 
     
       
         
         
             
             
         
       
     
     Each of Ar 1  to Ar 9  is selected from the group consisting aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, azulene; group consisting aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and group consisting 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Wherein each Ar is further substituted by a substituent selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof. 
     In one aspect, Ar 1  to Ar 9  is independently selected from the group consisting of: 
     
       
         
         
             
             
         
       
     
     k is an integer from 1 to 20; X 1  to X 8  is C (including CH) or N; Ar 1  has the same group defined above. 
     Examples of metal complexes used in HIL or HTL include, but not limit to the following general formula: 
     
       
         
         
             
             
         
       
     
     M is a metal, having an atomic weight greater than 40; (Y 1 -Y 2 ) is a bidentate ligand, Y 1  and Y 2  are independently selected from C, N, O, P, and S; L is an ancillary ligand; m is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and m+n is the maximum number of ligands that may be attached to the metal. 
     In one aspect, (Y 1 -Y 2 ) is a 2-phenylpyridine derivative. 
     In another aspect, (Y 1 -Y 2 ) is a carbene ligand. 
     In another aspect, M is selected from Ir, Pt, Os, and Zn. 
     In a further aspect, the metal complex has a smallest oxidation potential in solution vs. Fc + /Fc couple less than about 0.6 V. 
     Host: 
     The light emitting layer of the organic EL device of the present invention preferably contains at least a metal complex as light emitting material, and may contain a host material using the metal complex as a dopant material. Examples of the host material are not particularly limited, and any metal complexes or organic compounds may be used as long as the triplet energy of the host is larger than that of the dopant. 
     Examples of metal complexes used as host are preferred to have the following general formula: 
     
       
         
         
             
             
         
       
     
     M is a metal; (Y 3 -Y 4 ) is a bidentate ligand, Y 3  and Y 4  are independently selected from C, N, O, P, and S; L is an ancillary ligand; m is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and m+n is the maximum number of ligands that may be attached to the metal. 
     In one aspect, the metal complexes are: 
     
       
         
         
             
             
         
       
     
     (O—N) is a bidentate ligand, having metal coordinated to atoms O and N. 
     In another aspect, M is selected from Ir and Pt. 
     In a further aspect, (Y 3 -Y 4 ) is a carbene ligand. 
     Examples of organic compounds used as host are selected from the group consisting aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, azulene; group consisting aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and group consisting 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Wherein each group is further substituted by a substituent selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof. 
     In one aspect, host compound contains at least one of the following groups in the molecule: 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     R 1  to R 7  is independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, when it is aryl or heteroaryl, it has the similar definition as Ar&#39;s mentioned above. 
     k is an integer from 0 to 20. 
     X 1  to X 8  is selected from C (including CH) or N. 
     HBL: 
     A hole blocking layer (HBL) may be used to reduce the number of holes and/or excitons that leave the emissive layer. The presence of such a blocking layer in a device may result in substantially higher efficiencies as compared to a similar device lacking a blocking layer. Also, a blocking layer may be used to confine emission to a desired region of an OLED. 
     In one aspect, compound used in HBL contains the same molecule used as host described above. 
     In another aspect, compound used in HBL contains at least one of the following groups in the molecule: 
     
       
         
         
             
             
         
       
     
     k is an integer from 0 to 20; L is an ancillary ligand, m is an integer from 1 to 3. 
     ETL: 
     Electron transport layer (ETL) may include a material capable of transporting electrons. Electron transport layer may be intrinsic (undoped), or doped. Doping may be used to enhance conductivity. Examples of the ETL material are not particularly limited, and any metal complexes or organic compounds may be used as long as they are typically used to transport electrons. 
     In one aspect, compound used in ETL contains at least one of the following groups in the molecule: 
     
       
         
         
             
             
         
       
     
     R 1  is selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, it has the similar definition as Ar&#39;s mentioned above. 
     Ar 1  to Ar 3  has the similar definition as Ar&#39;s mentioned above. 
     k is an integer from 0 to 20. 
     X 1  to X 8  is selected from C (including CH) or N. 
     In another aspect, the metal complexes used in ETL contains, but not limit to the following general formula: 
     
       
         
         
             
             
         
       
     
     (O—N) or (N—N) is a bidentate ligand, having metal coordinated to atoms O, N or N, N; L is an ancillary ligand; m is an integer value from 1 to the maximum number of ligands that may be attached to the metal. 
     In any above-mentioned compounds used in each layer of the OLED device, the hydrogen atoms can be partially or fully deuterated. 
     In addition to and/or in combination with the materials disclosed herein, many hole injection materials, hole transporting materials, host materials, dopant materials, exiton/hole blocking layer materials, electron transporting and electron injecting materials may be used in an OLED. Non-limiting examples of the materials that may be used in an OLED in combination with materials disclosed herein are listed in Table 3 below. Table 3 lists non-limiting classes of materials, non-limiting examples of compounds for each class, and references that disclose the materials. 
     
       
         
           
               
               
               
             
               
                 TABLE 3 
               
               
                   
               
               
                 MATERIAL 
                 EXAMPLES OF MATERIAL 
                 PUBLICATIONS 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
            
               
                 Hole injection materials 
               
            
           
           
               
               
               
            
               
                 Phthalocyanine and porphryin compounds 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 69, 2160 (1996) 
               
               
                   
               
               
                 Starburst triarylamines 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 J. Lumin. 72-74, 985 (1997)  
               
               
                   
               
               
                 CF x  Fluorohydrocarbon polymer 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 78, 673 (2001) 
               
               
                   
               
               
                 Conducting polymers (e.g., PEDOT:PSS, polyaniline, polypthiophene) 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 Synth. Met. 87, 171 (1997) WO2007002683 
               
               
                   
               
               
                 Phosphonic acid and  sliane SAMs 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 US20030162053 
               
               
                   
               
               
                 Triarylamine or polythiophene polymers with conductivity dopants 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 EP1725079A1 
               
               
                   
               
               
                 Arylamines complexed with metal oxides such as molybdenum and tungsten oxides 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 SID Symposium Digest, 37, 923 (2006) WO2009018009 
               
               
                   
               
               
                 p-type semiconducting organic complexes 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 US20020158242 
               
               
                   
               
               
                 Metal organometallic complexes 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 US20060240279 
               
               
                   
               
               
                 Cross-linkable  compounds 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 US20080220265 
               
               
                   
               
            
           
           
               
            
               
                 Hole transporting materials 
               
            
           
           
               
               
               
            
               
                 Triarylamines (e.q., TPD, α-NPD 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 51, 913 (1987) 
               
               
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 US5061569 
               
               
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 EP650955 
               
               
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 J. Mater. Chem. 3,  319 (1993) 
               
               
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 90, 183503 (2007) 
               
               
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 90, 183503 (2007) 
               
               
                   
               
               
                 Triaylamine on spirofluorene core 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 Synth. Met. 91, 209 (1997) 
               
               
                   
               
               
                 Arylamine carbazole compounds 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 Adv. Mater. 6, 677 (1994), US20080124572 
               
               
                   
               
               
                 Triarylamine with (di)benzothiophene/ (di)benzofuran 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 US20070278938, US20080106190 
               
               
                   
               
               
                 Indolocarbazoles 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 Synth. Met. 111, 421 (2000) 
               
               
                   
               
               
                 Isoindole compounds 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 Chem. Mater. 15,  3148 (2003)  
               
               
                   
               
               
                 Metal carbene complexes 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 US20080018221 
               
               
                   
               
            
           
           
               
            
               
                 Phosphorescent OLED host materials 
               
               
                   
               
               
                 Red hosts 
               
            
           
           
               
               
               
            
               
                 Arylcarbazoles 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 78, 1622 (2001) 
               
               
                   
               
               
                 Metal  8-hydroxyquinolates (e.q., Alq 3 , BAlq) 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 Nature 395, 151  (1998) 
               
               
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 US20060202194 
               
               
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 WO2005014551 
               
               
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 WO2006072002 
               
               
                   
               
               
                 Metal phenoxybenzothiazole compounds 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 90, 123509 (2007) 
               
               
                   
               
               
                 Conjugated oligomers and polymers (e.g., polyfluorene) 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 Org. Electron. 1, 15 (2000) 
               
               
                   
               
               
                 Aromatic fused rings 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 WO2009066779, WO2009066778, WO2009063833, US20090045731, US20090045730, WO2009008311, US20090008605, US20090009065 
               
               
                   
               
               
                 Zinc complexes 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 WO2009062578 
               
               
                   
               
            
           
           
               
            
               
                 Green hosts 
               
            
           
           
               
               
               
            
               
                 Arylcarbazoles 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 78, 1622 (2001) 
               
               
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 US20030175553 
               
               
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 WO2001039234 
               
               
                   
               
               
                 Aryltriphenylene compounds 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 US20060280965 
               
               
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 US20060280965 
               
               
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 WO2009021126 
               
               
                   
               
               
                 Donor acceptor type molecules 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 WO2008056746 
               
               
                   
               
               
                 Aza-carbazole/DBT/DBF 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 JP2008074939 
               
               
                   
               
               
                 Polymers (e.g., PVK) 
                 
                   
                     
                     
                         
                         
                     
                   
                 
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                 Spirofluorene compounds 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 WO2004093207 
               
               
                   
               
               
                 Metal phenoxybenzooxazole compounds 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 WO2005089025 
               
               
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 WO2006132173 
               
               
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 JP200511610 
               
               
                   
               
               
                 Spirofluorene-carbazole compounds 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 JP2007254297 
               
               
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 JP2007254297 
               
               
                   
               
               
                 Indolocabazoles 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 WO2007063796 
               
               
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 WO2007063754 
               
               
                   
               
               
                 5-member ring electron deficient heterocycles (e.g., triazole, oxadiazole) 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 J. Appl. Phys. 90,  5048 (2001) 
               
               
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 WO2004107822 
               
               
                   
               
               
                 Tetraphenylene  complexes 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 US20050112407 
               
               
                   
               
               
                 Metal phenoxypyridine compounds 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 WO2005030900 
               
               
                   
               
               
                 Metal coordination complexes (e.g., Zn, Al with N{circumflex over ( )}N ligands) 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 US20040137268, US20040137267 
               
            
           
           
               
            
               
                 Blue hosts 
               
            
           
           
               
               
               
            
               
                 Arylcarbazoles 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett, 82, 2422 (2003) 
               
               
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 US20070190359 
               
               
                   
               
               
                 Dibenzothiophene/ Dibenzofuran-carbazole compounds 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 WO2006114966, US20090167162 
               
               
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 US20090167162 
               
               
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 WO2009086028 
               
               
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 US20090030202, US20090017330 
               
               
                   
               
               
                 Silicon aryl compounds 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 US20050238919 
               
               
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 WO2009003898 
               
               
                   
               
               
                 Silicon/Germanium aryl compounds 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 EP2034538A 
               
               
                   
               
               
                 Aryl benzoyl ester 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 WO2006100298 
               
               
                   
               
               
                 High triplet metal organometallic complex 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 US7154114 
               
               
                   
               
            
           
           
               
            
               
                 Phosphorescent dopants 
               
               
                   
               
               
                 Red dopants 
               
            
           
           
               
               
               
            
               
                 Heavy metal porphyrins (e.g., PtOEP) 
                 
                   
                     
                     
                         
                         
                     
                   
                 
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                 Iridium(III)  organometallic complexes 
                 
                   
                     
                     
                         
                         
                     
                   
                 
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                 US20070087321 
               
               
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
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                 WO2009100991 
               
               
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 WO2008101842  
               
               
                   
               
               
                 Platinum(II) organometallic complexes 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 WO2003040257 
               
               
                   
               
               
                 Osminum(III) complexes 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 Chem. Mater. 17,  3532 (2005) 
               
               
                   
               
               
                 Ruthenium(II) complexes 
                 
                   
                     
                     
                         
                         
                     
                   
                 
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                 Rhenium (I), (II), and (III) complexes 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 US20050244673 
               
               
                   
               
            
           
           
               
            
               
                 Green dopants 
               
            
           
           
               
               
               
            
               
                 Iridium(III)  organometallic complexes 
                 
                   
                     
                     
                         
                         
                     
                   
                 
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                 Iridium(III)  organometallic complexes 
                 
                   
                     
                     
                         
                         
                     
                   
                 
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                 US20060251923 
               
               
                   
               
               
                   
                 
                   
                     
                     
                         
                         
                     
                   
                 
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                 WO2006082742 
               
               
                   
               
               
                 Osmium(II) complexes 
                 
                   
                     
                     
                         
                         
                     
                   
                 
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                 Platinum(II) complexes 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 WO2006098120, WO2006103874 
               
               
                   
               
            
           
           
               
            
               
                 Exciton/hole blocking layer materials 
               
            
           
           
               
               
               
            
               
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                 Aza triphenylene derivatives 
                 
                   
                     
                     
                         
                         
                     
                   
                 
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     EXPERIMENTAL 
     Chemical abbreviations used throughout this document are as follows: Cy is cyclohexyl, dba is dibenzylideneacetone, EtOAc is ethyl acetate, DME is dimethoxyethane, dppe is 1,2-bis(diphenylphosphino)ethane, THF is tetrahydrofuran, DCM is dichloromethane, S-Phos is dicyclohexyl(2′,6′-dimethoxy-[1,1′-biphenyl]-2-yl)phosphine. 
     
       
         
         
             
             
         
       
     
     Synthesis of 5-chloro-2-(dibenzo[b,d]furan-4-yl)pyridine: Dibenzo[b,d]furan-4-ylboronic acid (9.5 g, 44.8 mmol), 2,5-dichloropyridine (7.0 g, 47.0 mmol), Pd(PPh 3 ) 4  (2.6 g, 2.2 mmol) and potassium carbonate (18.6 g, 134 mmol) were added to dimethoxyethane (75 mL) and water (75 mL). The reaction mixture was degassed with nitrogen before being heated to reflux overnight. EtOAc and water were added, the organic layer separated and the aqueous layer was extracted with 3×50 mL dichloromethane and dried over sodium sulfate. After removing the solvent under reduced pressure, the crude product was chromatographed on silica gel with dichloromethane to yield 11.7 g of crude product. The product was crystallized from hexane to give 9.5 g (76%) of 5-chloro-2-(dibenzo[b,d]furan-4-yl)pyridine as white needles. The product was confirmed by GC/MS. 
     
       
         
         
             
             
         
       
     
     Synthesis of 2-(dibenzo[b,d]furan-4-yl)-5-(prop-1-en-2-yl)pyridine: 5-Chloro-2-(dibenzo[b,d]furan-4-yl)pyridine (9.5 g, 34.0 mmol), dicyclohexyl(2′,6′-dimethoxy-[1,1′-biphenyl]-2-yl)phosphine (1.1 g, 2.7 mmol), and potassium phosphate tribasic monohydrate (23.5 g, 102 mmol) were added to toluene (200 mL) and water (20 mL) and the reaction mixture was degassed with nitrogen. Pd 2 (dba) 3  (0.622 g, 0.679 mmol) and 4,4,5,5-tetramethyl-2-(prop-1-en-2-yl)-1,3,2-dioxaborolane (7.7 mL, 40.8 mmol) were added and the reaction mixture was heated to reflux overnight. EtOAc and water were added, the organic layer separated and the aqueous layer was extracted with 3×50 mL dichloromethane and dried over sodium sulfate. After removing the solvent under reduced pressure, 12.7 g of amber oil was obtained. The crude material was chromatographed on silica with 9/1 (v/v) hexane/EtOAc to give 7.5 g (77%) of 2-(dibenzo[b,d]furan-4-yl)-5-(prop-1-en-2-yl)pyridine as a white solid. The product was confirmed by GC/MS and used without further purification. 
     
       
         
         
             
             
         
       
     
     Synthesis of 2-(dibenzo[b,d]furan-4-yl)-5-isopropylpyridine: 2-(Dibenzo[b,d]furan-4-yl)-5-(prop-1-en-2-yl)pyridine (7.5 g, 26.3 mmol) was added to a hydrogenator bottle containing EtOH (150 mL). The reaction mixture was degassed by bubbling nitrogen for 10 min. Pd/C (0.28 g, 2.63 mmol) and Pt/C (0.26 g, 1.3 mmol) were added to the reaction mixture. The reaction mixture was placed on the Parr hydrogenator for 1 h. The reaction mixture was filtered on a tightly packed Celite® bed and washed with dichloromethane to yield 7.5 g (99%) of the desired product. The product was confirmed by GC/MS and NMR. 
     
       
         
         
             
             
         
       
     
     Synthesis of 5-chloro-2-(dibenzo[b,d]furan-4-yl)pyridine: Dibenzo[b,d]furan-4-ylboronic acid (25 g, 118 mmol), 2,4-dichloropyridine (19.2 g, 130 mmol), Pd(PPh 3 ) 4  (4.1 g, 3.5 mmol) and potassium carbonate (48.9 g, 354 mmol) were added to dimethoxyethane (200 mL) and water (200 mL). The reaction mixture was degassed with nitrogen before being heated to reflux overnight. EtOAc and water were added, the organic layer separated and the aqueous layer was extracted with 3×50 mL dichloromethane and dried over sodium sulfate. After removing the solvent under reduced pressure, the crude product was chromatographed on silica gel with dichloromethane to yield 33.4 g of crude product. The product was crystallized from hexane to give 27.0 g (82%) of 4-chloro-2-(dibenzo[b,d]furan-4-yl)pyridine as white needles. The product was confirmed by GC/MS and NMR. 
     
       
         
         
             
             
         
       
     
     Synthesis of 2-(dibenzo[b,d]furan-4-yl)-4-(prop-1-en-2-yl)pyridine: 4-Chloro-2-(dibenzo[b,d]furan-4-yl)pyridine (24.0 g, 86.0 mmol), dicyclohexyl(2′,6′-dimethoxy-[1,1′-biphenyl]-2-yl)phosphine (2.8 g, 6.9 mmol), and potassium phosphate tribasic monohydrate (59.3 g, 257 mmol) were added to toluene (400 mL) and water (40 mL) and the reaction mixture was degassed. Pd 2 (dba) 3  (1.6 g, 1.7 mmol) and 4,4,5,5-tetramethyl-2-(prop-1-en-2-yl)-1,3,2-dioxaborolane (19.4 mL, 103 mmol) were added and the reaction mixture was heated to reflux overnight. EtOAc and water were added, the organic layer separated and the aqueous layer was extracted with 3×50 mL dichloromethane and dried over sodium sulfate. After removing the solvent under reduced pressure, 33.0 g of amber oil was obtained. The crude material was chromatographed on silica with 9/1 (v/v) DCM/EtOAc to give 23.5 g (96%) of 2-(dibenzo[b,d]furan-4-yl)-4-(prop-1-en-2-yl)pyridine as a white solid. The product was confirmed by GC/MS and used without further purification. 
     
       
         
         
             
             
         
       
     
     Synthesis of 2-(dibenzo[b,d]furan-4-yl)-4-isopropylpyridine: 2-(Dibenzo[b,d]furan-4-yl)-5-(prop-1-en-2-yl)pyridine (8.0 g, 28 mmol) was added to a hydrogenator bottle containing EtOH (150 mL). The reaction mixture was degassed by bubbling N 2  for 10 min. Pd/C (0.60 g, 5.6 mmol) and Pt/C (0.55 g, 2.8 mmol) were added to the reaction mixture. The reaction mixture was placed on the Parr hydrogenator for 1 h. The reaction mixture was filtered on a tightly packed Celite® bed and washed with dichloromethane. The crude product was chromatographed on silica gel with 9/1 (v/v) hexane/EtOAc to yield 7.2 g (96%) of 2-(dibenzo[b,d]furan-4-yl)-4-isopropylpyridine. The product was confirmed by GC/MS and NMR. 
     
       
         
         
             
             
         
       
     
     Synthesis of 5-bromo-2-(dibenzo[b,d]furan-4-yl)-4-methylpyridine: 2,5-Dibromo-4-methylpyridine (30 g, 118 mmol), dibenzo[b,d]furan-4-ylboronic acid (25 g, 118 mmol), Pd(PPh 3 ) 4  (1.4 g, 1.18 mmol), and K 2 CO 3  (49 g, 354 mmol) were added to a flask with dimethoxyethane (450 mL) and water (100 mL) and degassed with nitrogen. The reaction mixture was heated to reflux for 15 h before cooling to room temperature. EtOAc and water were added, the organic layer separated and the aqueous layer was extracted with 3×50 mL dichloromethane and dried over sodium sulfate. After removing the solvent under reduced pressure, the crude product was chromatographed on silica gel with dichloromethane and 29.7 g of crude product was obtained. The product was crystallized from hexane to give 28.8 g (72%) of pure product. The product was confirmed by NMR and HPLC (99.3% pure) 
     
       
         
         
             
             
         
       
     
     Synthesis of 2-(dibenzo[b,d]furan-4-yl)-4,5-dimethylpyridine: 5-Bromo-2-(dibenzo[b,d]furan-4-yl)-4-methylpyridine (28.7 g, 85 mmol), dicyclohexyl(2′,6′-dimethoxy-[1,1′-biphenyl]-2-yl)phosphine (1.394 g, 3.39 mmol) and potassium phosphate monohydrate (58.6 g, 255 mmol) were added to toluene (500 mL) and water (50 mL) and degassed for 20 min. Trimethylboroxine (14.83 mL, 106 mmol) and Pd 2 (dba) 3  (0.777 g, 0.849 mmol) were added and the reaction mixture heated to reflux overnight. After cooling, the organic layer was separated and the aqueous layer extracted 3×50 mL with EtOAc, dried over sodium sulfate and evaporated. The crude product was chromatographed on silica gel with 8/2 (v/v) dichloromethane/EtOAc in hexane to give 19.2 g of an off-white solid, which was recrystallized from heaxane to give 16.8 g (83%) of the product as white needles. The product was confirmed by NMR and HPLC (99.97% pure). 
     
       
         
         
             
             
         
       
     
     Synthesis of 2-(dibenzo[b,d]furan-4-yl)-5-isobutyl-4-methylpyridine: 5-Bromo-2-(dibenzo[b,d]furan-4-yl)-4-methylpyridine (13.0 g, 38.3 mmol), isobutylboronic acid (11.7 g, 115 mmol), dicyclohexyl(2′,6′-dimethoxy-[1,1′-biphenyl]-2-yl)phosphine (0.63 g, 1.53 mmol) and potassium phosphate monohydrate (22.1 g, 96 mmol) were mixed in water (10 mL) and toluene (210 mL). The system was degassed for 20 min. with nitrogen and Pd 2 (dba) 3  (0.35 g, 0.38 mmol) was then added and the system was refluxed overnight. After cooling to room temperature, the reaction mixture was filtered through a small plug of silica gel and eluted with dicloromethane. The filtrated was concentrated and then crystallized from hexane to give 2-(dibenzo[b,d]furan-4-yl)-5-isobutyl-4-methylpyridine (9.0 g, 74%). 
     
       
         
         
             
             
         
       
     
     Synthesis of 5-chloro-2-phenylpyridine: 2,5-Dichloropyridine (30 g, 203 mmol), phenylboronic acid (24.72 g, 203 mmol) and potassium carbonate (84 g, 608 mmol) were added to dimethoxyethane (500 mL) and water (100 mL). The reaction mixture was degassed with nitrogen for 20 min, and Pd(PPh 3 ) 4  (2.3 g, 2.0 mmol) was added and reaction mixture was allowed to reflux for 18 h. The reaction was cooled to room temperature, the aqueous layer removed and dimethoxyethane was concentrated to dryness by rotary evaporation under vacuum. The residue was dissolved in DCM and passed through a silica gel plug, eluting with DCM. The solvent was removed and the crude product was chromatographed on silica with 40/60 (v/v) DCM/hexane to 50/50 (v/v)DCM/hexane to yield 28 g (73%) of the product as a white solid (HPLC purity: 99.7%). 
     
       
         
         
             
             
         
       
     
     Synthesis of 5-ethyl-2-phenylpyridine: 5-Chloro-2-phenylpyridine (16 g, 84 mmol) and Ni(dppe)Cl 2  (0.891 g, 1.687 mmol) were added to 300 mL of THF and the reaction mixture was degassed with nitrogen for 20 min. before being cooled to 0° C. Ethylmagnesium bromide (169 mL, 169 mmol) was added dropwise over a period of 60 min. and the reaction mixture stirred for and additional 3 h at before warming to room temperature overnight. The reaction mixture was recooled to 0° C. and quenched with 250 mL of water, extracted with EtOAc and the organic layer dried over sodium sulfate and filtered. The crude material was chromatographed on silica with 95/5 hexane/EtOAc to give 2.9 g (19%) of 5-ethyl-2-phenylpyridine as a white solid. 
     
       
         
         
             
             
         
       
     
     Synthesis of 2-phenyl-5-(prop-1-en-2-yl)pyridine: To a 1 L round bottom flask was added 5-chloro-2-phenylpyridine (10.15 g, 53.5 mmol), dicyclohexyl(2′,6′-dimethoxy-[1,1′-biphenyl]-2-yl)phosphine (1.8 g, 4.3 mmol), potassium phosphate tribasic monohydrate (37.0 g, 161 mmol) with toluene (200 mL) and water (20 mL). The reaction mixture was degassed with nitrogen for 20 mins. 4,4,5,5-tetramethyl-2-(prop-1-en-2-yl)-1,3,2-dioxaborolane (12.07 mL, 64.2 mmol) and Pd 2 (dba) 3  (0.980 g, 1.070 mmol) were added and the reaction mixture was refluxed for 18 h. The aqueous layer was removed and the organic layer was concentrated to dryness. The crude product was chromatographed on silica gel with 0-20% EtOAc in hexane to yield 11 g of the desired product (HPLC purity: 95%). The product was confirmed by GC/MS. 
     
       
         
         
             
             
         
       
     
     Synthesis of 2-phenyl-5-isopropylpyridine: 2-Phenyl-5-(prop-1-en-2-yl)pyridine (11 g, 56.3 mmol) was added to a hydrogenator bottle containing EtOH (150 mL). The reaction mixture was degassed by bubbling N 2  for 10 min. Pd/C (0.60 g, 5.63 mmol) and Pt/C (0.55 g, 2.82 mmol) were added to the reaction mixture. The reaction mixture was placed on the Parr hydrogenator for 1.5 h. The reaction mixture was filtered on a tightly packed Celite® bed and washed with dichloromethane. The solvent was removed on rotoevaporator and GC/MS confirmed complete conversion. The crude product was adsorbed on Celite® for column chromatography. The crude product was chromatographed on silica gel with 10% EtOAc in hexane to yield 6 g (54%) of 2-phenyl-5-isopropylpyridine (HPLC purity: 100%). The product was confirmed by GC/MS. 
     
       
         
         
             
             
         
       
     
     Synthesis of 4-chloro-2-phenylpyridine: A 1 L round bottom flask was charged with 2,4-dichloropyridine (30 g, 203 mmol), phenylboronic acid (24.7 g, 203 mmol), potassium carbonate (84 g, 608 mmol), Pd(PPh 3 ) 4  (2.3 g, 2.0 mmol), dimethoxyethane (500 mL) and water (150 mL). The mixture was degassed and heated to reflux for 20 h. After cooling, the aqueous layer was extracted with EtOAc; the organic portion was combined and subjected to column chromatography (SiO 2 , 5% EtOAc in hexane to 10% EtOAc in hexane) to give 34 g (88%) of 4-chloro-2-phenylpyridine. The product was confirmed by GC/MS and NMR. 
     
       
         
         
             
             
         
       
     
     Synthesis of 2-phenyl-4-(prop-1-en-2yl)pyridine: 4-Chloro-2-phenylpyridine (14 g, 73.8 mmol) and potassium phosphate (51.0 g, 221 mmol) were dissolved in 300 mL of toluene and 30 mL of water. The reaction was purged with nitrogen for 20 minutes and then 4,4,5,5-tetramethyl-2-(prop-1-en-2-yl)-1,3,2-dioxaborolane (16.65 mL, 89 mmol), Pd 2 (dba) 3  (1.35 g, 1.48 mmol) and S-Phos (2.42 g, 5.91 mmol) were added. The reaction was brought to reflux for 18 h. After cooling, 100 mL of water was added, separated and the aqueous layer extracted twice with 100 mL of ethyl acetate. The organic layers were passed through a plug of silica gel, eluting with DCM. After evaporation of the solvent, the crude product was subjected to column chromatography (SiO 2 , 5% EtOAc in hexane to 10% EtOAc in hexane) to get 13.5 g (90%) of 2-phenyl-4-(prop-1-en-2yl)pyridine. 
     
       
         
         
             
             
         
       
     
     Synthesis of 2-phenyl-4-isopropylpyridine: 2-Phenyl-4-(prop-1-en-2-yl) pyridine (13.5 g, 69.1 mmol) was added to a hydrogenator bottle containing EtOH (150 mL). The reaction mixture was degassed by bubbling with nitrogen for 10 min. Pd/C (0.736 g, 6.9 mmol) and Pt/C (0.674 g, 3.5 mmol) was added to the reaction mixture. The reaction mixture was placed on the Parr hydrogenator for 2 h. The reaction mixture was filtered on a tightly packed Celite® bed and washed with dichloromethane. The solvent was removed on a rotary evaporator and GC/MS confirmed complete conversion. The crude product was adsorbed on Celite® for column chromatography. The crude product was chromatographed on silica gel with 10% EtOAc in hexane to yield 10 g (75%) of 2-phenyl-4-isopropylpyridine (HPLC purity: 99.8%). The product was confirmed by GC/MS. 
     
       
         
         
             
             
         
       
     
     Synthesis of 5-methyl-2-phenylpyridine: 2-Bromo-5-methylpyridine (30 g, 174 mmol), phenylboronic acid (25.5 g, 209 mmol), dicyclohexyl(2′,6′-dimethoxy-[1,1′-biphenyl]-2-yl)phosphine (2.86 g, 6.98 mmol) and potassium phosphate tribasic monohydrate (120 g, 523 mmol) were added to toluene (600 mL) and water (60 mL). The reaction mixture was degassed with nitrogen for 20 min. Pd 2 (dba) 3  (3.19 g, 3.49 mmol) was added and the reaction mixture was refluxed for 18 h. After cooling, the organic layer was separated and the aqueous layer extracted with 3×50 mL dichloromethane, dried over sodium sulfate and evaporated. The crude product was chromatographed on silica gel with 75/25 (v/v) hexane/EtOAc and then distilled on a Kugelrohr apparatus (150° C., 100 mbar) to give 26 g (88%) of 5-methyl-2-phenylpyridine as a white solid. The product was confirmed by NMR and GC/MS. HPLC purity: 99.2%. 
     
       
         
         
             
             
         
       
     
     Synthesis of 4-methyl-2-phenylpyridine: A 1 L round bottom flask was charged with 2-chloro-4-methylpyridine (25 g, 196 mmol), phenylboronic acid (23.9 g, 196 mmol), potassium carbonate (81 g, 588 mmol), Pd(PPh 3 ) 4  (2.3 g, 1.9 mmol), dimethoxyethane (500 mL) and water (150 mL). The reaction mixture was degassed with nitrogen and heated to reflux for 22 h. After cooling, the aqueous layer was extracted with EtOAc; the organic portion was combined and subjected to column chromatography (SiO 2 , 5% EtOAc in hexane to 10% EtOAc in hexane) to give 28 g (78%) of 4-methyl-2-phenylpyridine. The product was confirmed by NMR and GC/MS. 
     
       
         
         
             
             
         
       
     
     Synthesis of 4-ethyl-2-phenylpyridine: To 4-methyl-2-phenylpyridine (8 g, 47.3 mmol) in dry THF (150 mL) at −78° C. was added dropwise lithium diisopropylamide (LDA) (30.7 mL, 61.5 mmol). The dark solution was stirred for 3 h at −78° C. and then CH 3 I was added (4.1 mL, 66.2 mmol) dropwise. The reaction mixture was allowed to slowly warm to room temperature overnight. Ammonium chloride solution and EtOAc were added and the reaction transferred to a separatory funnel. The layers were separated, washing the aqueous twice with EtOAc and combined organics once with water. After removal of the solvent, the crude product was chromatographed on silica gel with 9/1 (v/v) hexane/EtOAc to give 5.5 g (63.5%) of 4-ethyl-2-phenylpyridine. HPLC purity: 99.0%. 
     
       
         
         
             
             
         
       
     
     Synthesis of 4-methyl-2-phenylpyridine chloro-bridged dimer: To a 500 mL round-bottom flask was added 4-methyl-2-phenylpyridine (7 g, 41 mmol) and iridium(III) chloride hydrate (4.86 g, 13.79 mmol) with 2-ethoxyethanol (90 mL) and water (30 mL) under a nitrogen atmosphere. The resulting reaction mixture was refluxed at 130° C. for 18 h. The resulting precipitate was filtered and washed with methanol (3-4 times) and hexane (3-4 times). The product obtained was dried to give 7.5 g (90%) of the desired product. The product was used without further purification. 
     
       
         
         
             
             
         
       
     
     Synthesis of 5-methyl-2-phenylpyridine chloro-bridged dimer: To a 500 mL round bottom flask was added 5-methyl-2-phenylpyridine (12 g, 70.9 mmol) and iridium(III) chloride hydrate (7.1 g, 20.3 mmol) with 2-ethoxyethanol (100 mL) and water (33.3 mL) under a nitrogen atmosphere. The resulting reaction mixture was refluxed at 130° C. for 18 h. The resulting precipitate was filtered and washed with methanol (3-4 times) and hexane (3-4 times). The product obtained was dried to give 11.0 g (96%) of the desired product. The product was used without further purification. 
     
       
         
         
             
             
         
       
     
     Synthesis of 2-phenyl-5-isopropylpyridine chloro-bridged dimer: To a 500 mL round-bottom flask was added 5-isopropyl-2-phenylpyridine (6.0 g, 30.4 mmol) and iridium(III) chloride hydrate (3.6 g, 10.1 mmol) with 2-ethoxyethanol (100 mL) and water (33.3 mL) under a nitrogen atmosphere. The resulting reaction mixture was refluxed at 130° C. for 18 h. The resulting precipitate was filtered and washed with methanol (3-4 times) and hexane (3-4 times). The product obtained was dried to give 7 g (100%) of the desired product. The product was used without further purification. 
     
       
         
         
             
             
         
       
     
     Synthesis of 2-phenyl-4-isopropylpyridine chloro-bridged dimmer: To a 500 mL round-bottom flask was added 4-isopropyl-2-phenylpyridine (8.0 g, 40.6 mmol) and iridium(III) chloride hydrate (7.4 g, 20.3 mmol) with 2-ethoxyethanol (90 mL) and water (30 mL) under a nitrogen atmosphere. The resulting reaction mixture was refluxed at 130° C. for 18 h. The resulting precipitate was filtered and washed with methanol (3-4 times) and hexane (3-4 times). The product obtained was dried to give 6.1 g (95%) of the desired product. The product was used without further purification. 
     
       
         
         
             
             
         
       
     
     Synthesis of 4-ethyl-2-phenylpyridine chloro-bridged dimmer: To a 500 mL round-bottom flask was added 4-isopropyl-2-phenylpyridine (5.5 g, 30.0 mmol) and iridium(III) chloride hydrate (5.8 g, 16.5 mmol) with 2-ethoxyethanol (90 mL) and water (30 mL) under a nitrogen atmosphere. The resulting reaction mixture was refluxed at 130° C. for 18 h. The resulting precipitate was filtered and washed with methanol (3-4 times) and hexane (3-4 times). The product obtained was dried to give 6.5 g (72%) of the desired product. The product was used without further purification. 
     
       
         
         
             
             
         
       
     
     Synthesis of 5-ethyl-2-phenylpyridine chloro-bridged dimer: To a 500 mL round bottom flask was added 5-ethyl-2-phenylpyridine (2.9 g, 15.7 mmol) and iridium(III) chloride hydrate (1.8 g, 5.2 mmol) with 2-ethoxyethanol (60 mL) and water (20 mL) under a nitrogen atmosphere. The reaction mixture was refluxed at 130° C. for 18 h. The resulting precipitate was filtered and washed with methanol (3-4 times) and hexane (3-4 times). The product obtained was dried to give 2.45 g (89.3%) of the desired product. The product was used without further purification. 
     
       
         
         
             
             
         
       
     
     Synthesis of 5-methyl-2-phenylpyridine iridium trifluoromethanesulfonate salt: The iridium dimer (11 g, 9.8 mmol) was suspended in 600 mL of dichloromethane. In a separate flask, silver(I) trifluoromethanesulfonate (5.3 g, 20.5 mmol) was dissolved in MeOH (300 mL) and added slowly to the dichloromethane solution with continuous stirring at room temperature. The reaction mixture was stirred overnight in the dark. The reaction mixture was filtered through a tightly packed Celite® bed and the solvent was removed under vacuum to give 15 g (100%) of product as a brownish green solid. The product was used without further purification. 
     
       
         
         
             
             
         
       
     
     Synthesis of 4-methyl-2-phenylpyridine iridium trifluoromethanesulfonate salt: The iridium dimer (7.5 g, 6.6 mmol) was dissolved in 600 mL of dichloromethane. In a separate flask, silver(I) trifluoromethanesulfonate (3.5 g, 13.8 mmol) was dissolved in MeOH (300 mL) and added slowly to the dichloromethane solution with continuous stirring at room temperature. The reaction mixture was stirred overnight in the dark. The reaction mixture was filtered through a tightly packed Celite® bed and the solvent was removed under vacuum to give 10 g (100%) of product as a brownish green solid. The product was used without further purification. 
     
       
         
         
             
             
         
       
     
     Synthesis of 2-phenyl-5-isopropylpyridine iridium trifluoromethanesulfonate salt: The iridium dimer (5.3 g, 4.3 mmol) was dissolved in 500 mL of dichloromethane. In a separate flask, silver(I) trifluoromethanesulfonate (2.3 g, 8.9 mmol) was dissolved in MeOH (250 mL) and added slowly to the dichloromethane solution with continuous stirring at room temperature. The reaction mixture was stirred overnight in the dark. The reaction mixture was filtered through a tightly packed Celite® bed and the solvent was removed under vacuum to give 6.9 g (100%) of product as a brownish solid. The product was used without further purification. 
     
       
         
         
             
             
         
       
     
     Synthesis of 2-phenyl-4-isopropylpyridine iridium trifluoromethanesulfonate salt: The iridium dimer (6.2 g, 4.94 mmol) was dissolved in 500 mL of dichloromethane. In a separate flask, silver(I) trifluoromethanesulfonate (2.7 g, 10.4 mmol) was dissolved in MeOH (250 mL) and added slowly to the dichloromethane solution with continuous stirring at room temperature. The reaction mixture was stirred overnight in the dark. The reaction mixture was filtered through a tightly packed Celite® bed and the solvent was removed under vacuum to give 7.8 g (100%) of product as a brownish green solid. The product was used without further purification. 
     
       
         
         
             
             
         
       
     
     Synthesis of 4-ethyl-2-phenylpyridine iridium trifluoromethanesulfonate salt: The iridium dimer (6.8 g, 5.7 mmol) was dissolved in 500 mL of dichloromethane. In a separate flask, silver(I) trifluoromethanesulfonate (3.2 g, 12.5 mmol) was dissolved in MeOH (250 mL) and added slowly to the dichloromethane solution with continuous stirring at room temperature. The reaction mixture was stirred overnight in the dark. The reaction mixture was filtered through a tightly packed Celite® bed and the solvent was removed under vacuum to give 5.5 g (63%) of product as a brownish green solid. The product was used without further purification. 
     
       
         
         
             
             
         
       
     
     Synthesis of 5-ethyl-2-phenylpyridine iridium trifluoromethanesulfonate salt: The iridium dimer (2.8 g, 2.4 mmol) was suspended in 500 mL of dichloromethane. In a separate flask, silver(I) trifluoromethanesulfonate (1.3 g, 4.91 mmol) was dissolved in MeOH (250 mL) and added slowly to the dichloromethane solution with continuous stirring at room temperature. The reaction mixture was stirred overnight in the dark. The reaction mixture was filtered through a tightly packed Celite® bed and the solvent was removed under vacuum to give 3.6 g (100%) of product as a brownish green solid. The product was used without further purification. 
     
       
         
         
             
             
         
       
     
     Synthesis of Compound 53: A mixture of the appropriate iridium trifluoromethanesulfonate complex (3.5 g, 4.9 mmol) and 2-(dibenzo[b,d]furan-4-yl)-5-isopropylpyridine (3.5 g, 12.18 mmol) in EtOH (25 mL) and MeOH (25 mL) was refluxed for 20 h under inert atmosphere. The reaction mixture was cooled to room temperature, diluted with ethanol, Celite® was added and the mixture stirred for 10 min. The mixture was filtered on a small silica gel plug on a frit and washed with ethanol (3-4 times) and with hexane (3-4 times). The filtrate was discarded. The Celite®/silica plug was then washed with dichloromethane to elute the product. The crude product was chromatographed on silica gel with 1/1 (v/v) dichloromethane/hexane to yield 1.3 g (33%) of Compound 53 as a yellow solid. The product was confirmed by HPLC (99.5% pure) and LC/MS. 
     
       
         
         
             
             
         
       
     
     Synthesis of Compound 157—A mixture of the appropriate iridium trifluoromethanesulfonate complex (2.5 g, 3.50 mmol) and 2-(dibenzo[b,d]furan-4-yl)-4,5-dimethylpyridine (2.5 g, 9.15 mmol)) in EtOH (25 mL) and MeOH (25 mL) was refluxed for 20 h under inert atmosphere. The reaction mixture was refluxed for 24 h. The reaction mixture was cooled to room temperature, diluted with ethanol, Celite® was added and the mixture stirred for 10 min. The mixture was filtered on a small silica gel plug on a frit and washed with ethanol (3-4 times) and with hexane (3-4 times). The filtrate was discarded. The Celite®/silica plug was then washed with dichloromethane to elute the product. The solvent was removed to half the volume and the product precipitated by addition of isopropanol and removing dichloromethane under reduced pressure. The filtered material was washed with isopropanol and hexane to yield a mixture of fac- and mer-isomers by LC/MS. The mixture was isomerized to the fac-isomer in a Rayonet at 350 nm in DMSO. The crude product was chromatographed on silica gel with 1/1 dichloromethane/hexane to yield 1.4 g (52%) of Compound 157 as a yellow solid. The product was confirmed by HPLC (98.7% pure) and LC/MS. 
     
       
         
         
             
             
         
       
     
     Synthesis of Compound 158: A mixture of the appropriate iridium trifluoromethanesulfonate complex (2.5 g, 3.37 mmol) and 2-(dibenzo[b,d]furan-4-yl)-4,5-dimethylpyridine (2.5 g, 9.15 mmol) in EtOH (25 mL) and MeOH (25 mL) was refluxed for 20 h under inert atmosphere. The reaction mixture was cooled to room temperature, diluted with ethanol, Celite® was added and the mixture stirred for 10 min. The mixture was filtered on a small silica gel plug on a frit and washed with ethanol (3-4 times) and with hexane (3-4 times). The filtrate was discarded. The Celite®/silica plug was then washed with dichloromethane to elute the product. The solvent was removed to half the volume and the product precipitated by addition of isopropanol and removing dichloromethane under reduced pressure. The filtered material was washed with isopropanol and hexane and dried to yield 2.7 g (100%) of Compound 158 as a yellow solid. The product was confirmed by HPLC (99.4% pure) and LC/MS. 
     
       
         
         
             
             
         
       
     
     Synthesis of Compound 159: A mixture of the appropriate iridium trifluoromethanesulfonate complex (3.0 g, 4.04 mmol) and 2-(dibenzo[b,d]furan-4-yl)-4,5-dimethylpyridine (3.0 g, 10.98 mmol) in EtOH (30 mL) and MeOH (30 mL) was refluxed for 20 h under inert atmosphere. The reaction mixture was cooled to room temperature, diluted with ethanol, Celite® was added and the mixture stirred for 10 min. The mixture was filtered on a small silica gel plug on a frit and washed with ethanol (3-4 times) and with hexane (3-4 times). The filtrate was discarded. The Celite®/silica plug was then washed with dichloromethane to elute the product. The solubility of the desired product was very poor. Large amount of solvent was used to elute the product. The crude product was chromatographed on silica gel with 1/1 (v/v) dichloromethane/hexane and later 4/1 dichloromethane/hexane to yield 0.3 g of the product as a yellow solid. The product was confirmed by HPLC (99.9% pure) and LC/MS. 
     
       
         
         
             
             
         
       
     
     Synthesis of Compound 165: A mixture of the appropriate iridium trifluoromethanesulfonate complex (2.5 g, 3.25 mmol) and 2-(dibenzo[b,d]furan-4-yl)-4,5-dimethylpyridine (2.5 g, 9.15 mmol) in EtOH (25 mL) and MeOH (25 mL) was refluxed for 20 h under inert atmosphere. The reaction mixture was cooled to room temperature, diluted with ethanol, Celite® was added and the mixture stirred for 10 min. The mixture was filtered on a small silica gel plug on a frit and washed with ethanol (3-4 times) and with hexane (3-4 times). The filtrate was discarded. The Celite®/silica plug was then washed with dichloromethane to elute the product. The solvent was removed to half the volume and the product precipitated by addition of isopropanol and removing dichloromethane under reduced pressure. The filtered material was washed with isopropanol and hexane and dried. The crude product was chromatographed on silica gel with 1/1 (v/v) dichloromethane/hexane to yield 1.2 g (43%) of Compound 165 as a yellow solid. The product was confirmed by HPLC (99.4% pure) and LC/MS. 
     
       
         
         
             
             
         
       
     
     Synthesis of Compound 174: A mixture of the appropriate iridium trifluoromethanesulfonate complex (3.6 g, 4.68 mmol) and 2-(dibenzo[b,d]furan-4-yl)-4,5-dimethylpyridine (3.6 g, 13.17 mmol) in EtOH (50 mL) and MeOH (50 mL) was refluxed for 20 h under inert atmosphere. The reaction mixture was cooled to room temperature, diluted with ethanol, Celite® was added and the mixture stirred for 10 min. The mixture was filtered on a small silica gel plug on a frit and washed with ethanol (3-4 times) and with hexane (3-4 times). The filtrate was discarded. The Celite®/silica plug was then washed with dichloromethane to elute the product. The crude product was chromatographed on silica gel with 1/1 (v/v) dichloromethane/hexane to yield 0.8 g of product as a yellow solid was confirmed by HPLC (98.6% pure) and LC/MS. 
     
       
         
         
             
             
         
       
     
     Synthesis of Compound 175: A mixture of the appropriate iridium trifluoromethanesulfonate complex (2.5 g, 3.25 mmol) and 2-(dibenzo[b,d]furan-4-yl)-4,5-dimethylpyridine (2.66 g, 9.74 mmol) in EtOH (30 mL) and MeOH (30 mL) was refluxed for 20 h under nitrogen atmosphere. The reaction mixture was cooled to room temperature, diluted with ethanol, Celite® was added and the mixture stirred for 10 min. The mixture was filtered on a small silica gel plug and washed with ethanol (3-4 times) and with hexane (3-4 times). The filtrate was discarded. The Celite®/silica plug was then washed with dichloromethane to elute the product. The crude product was chromatographed on silica gel with 2/3 (v/v) THF/hexane to yield 0.8 g of product by HPLC. The product was recrystallized by slow evaporation of DCM from a 1/3 DCM/hexane solution to yield 0.6 g (22%) as a yellow crystalline solid. The product was confirmed by HPLC (99.4% pure) and LC/MS. 
     
       
         
         
             
             
         
       
     
     Synthesis of Compound 184: A mixture of the appropriate iridium trifluoromethanesulfonate complex (3.0 g, 3.76 mmol) and 2-(dibenzo[b,d]furan-4-yl)-4,5-dimethylpyridine (3.0 g, 10.98 mmol) in EtOH (30 mL) and MeOH (30 mL) was refluxed for 20 h under inert atmosphere. The reaction mixture was cooled to room temperature, diluted with ethanol, Celite® was added and the mixture stirred for 10 min. The mixture was filtered on a small silica gel plug on a frit and washed with ethanol (3-4 times) and with hexane (3-4 times). The filtrate was discarded. The Celite®/silica plug was then washed with dichloromethane to elute the product. The crude product was chromatographed on silica gel with 1/1 (v/v) dichloromethane/hexane to yield 2.1 g (65%) of product as a yellow solid. The product was confirmed by HPLC (99.8% pure) and LC/MS. 
     
       
         
         
             
             
         
       
     
     Synthesis of Compound 185: A mixture of the appropriate iridium trifluoromethanesulfonate complex (2.8 g, 3.51 mmol) and 2-(dibenzo[b,d]furan-4-yl)-4,5-dimethylpyridine (2.88.0 g, 10.53 mmol) in EtOH (30 mL) and MeOH (30 mL) was refluxed for 20 h under N 2  atmosphere. The reaction mixture was cooled to room temperature, diluted with ethanol, Celite® was added and the mixture stirred for 10 min. The mixture was filtered on a small silica gel plug and washed with ethanol (3-4 times) and with hexane (3-4 times). The filtrate was discarded. The Celite®/silica plug was then washed with dichloromethane to elute the product. The crude product was chromatographed on silica gel with 2/3 (v/v) dichloromethane/hexane to yield 2.1 g (69%) of product as a yellow solid. The product was confirmed by HPLC (99.9% pure) and LC/MS. 
     
       
         
         
             
             
         
       
     
     Synthesis of Compound 314: A mixture of the appropriate iridium trifluoromethanesulfonate complex (2.5 g, 3.37 mmol) and 2-(dibenzo[b,d]furan-4-yl)-5-isobutyl-4-methylpyridine (2.5 g, 7.93 mmol) in EtOH (25 mL) and MeOH (25 mL) was refluxed for 20 h under inert atmosphere. The reaction mixture was cooled to room temperature, diluted with ethanol, Celite® was added and the mixture stirred for 10 min. The mixture was filtered on a small silica gel plug on a frit and washed with ethanol (3-4 times) and with hexane (3-4 times). The filtrate was discarded. The Celite®/silica plug was then washed with dichloromethane to elute the product. The solvent was removed to half the volume and the product precipitated by addition of isopropanol and removing dichloromethane under reduced pressure. The filtered material was washed with isopropanol and hexane and dried to yield 3.0 g (100%) of Compound 314 as a yellow solid. The product was confirmed by HPLC (99.6% pure) and LC/MS. 
     
       
         
         
             
             
         
       
     
     Synthesis of Compound 321: A mixture of the appropriate iridium trifluoromethanesulfonate complex (2.2 g, 2.86 mmol) and 2-(dibenzo[b,d]furan-4-yl)-5-isobutyl-4-methylpyridine (2.2 g, 6.98 mmol) in EtOH (25 mL) and MeOH (25 mL) was refluxed for 20 h under inert atmosphere. The reaction mixture was cooled to room temperature, diluted with ethanol, Celite® was added and the mixture stirred for 10 min. The mixture was filtered on a small silica gel plug on a frit and washed with ethanol (3-4 times) and with hexane (3-4 times). The filtrate was discarded. The Celite®/silica plug was then washed with dichloromethane to elute the product. The solvent was removed to half the volume and the product precipitated by addition of isopropanol and removing dichloromethane under reduced pressure. The filtered material was washed with isopropanol and hexane. The crude product was chromatographed on silica gel with 1/1 (v/v) dichloromethane/hexane to yield 1.6 g (50%) of Compound 321 as a yellow solid. The product was confirmed by HPLC (99.0% pure) and LC/MS. 
     
       
         
         
             
             
         
       
     
     Synthesis of Compound 625: A mixture of the appropriate iridium trifluoromethanesulfonate complex (2.2 g, 3.08 mmol) and 2-(dibenzo[b,d]furan-4-yl)-4-isopropylpyridine (2.2 g, 7.66 mmol) in EtOH (25 mL) and MeOH (25 mL) was refluxed for 20 h under inert atmosphere. The reaction mixture was cooled to room temperature, diluted with ethanol, Celite® was added and the mixture stirred for 10 min. The mixture was filtered on a small silica gel plug on a frit and washed with ethanol (3-4 times) and with hexane (3-4 times). The filtrate was discarded. The Celite®/silica plug was then washed with dichloromethane to elute the product. The solvent was removed to half the volume and the product precipitated by addition of isopropanol and removing dichloromethane under reduced pressure. The filtered material was washed with isopropanol and hexane and dried to yield 1.7 g (67%) of Compound 625 as a yellow solid. The product was confirmed by HPLC (99.8% pure) and LC/MS. 
     
       
         
         
             
             
         
       
     
     Synthesis of Compound 626: A mixture of the appropriate iridium trifluoromethanesulfonate complex (2.5 g, 3.37 mmol) and 2-(dibenzo[b,d]furan-4-yl)-4-isopropylpyridine (2.5 g, 8.70 mmol) in EtOH (25 mL) and MeOH (25 mL) was refluxed for 20 h under inert atmosphere. The reaction mixture was cooled to room temperature, diluted with ethanol, Celite® was added and the mixture stirred for 10 min. The mixture was filtered on a small silica gel plug on a frit and washed with ethanol (3-4 times) and with hexane (3-4 times). The filtrate was discarded. The Celite®/silica plug was then washed with dichloromethane to elute the product. The solvent was removed to half the volume and the product precipitated by addition of isopropanol and removing dichloromethane under reduced pressure. The filtered material was washed with isopropanol and hexane and dried. The crude product was chromatographed on silica gel with 1/1 (v/v) dichloromethane/hexane to yield 2.5 g (89%) of Compound 626 as a yellow solid. The product was confirmed by HPLC (99.4% pure) and LC/MS. 
     
       
         
         
             
             
         
       
     
     Synthesis of Compound 627: A mixture of the appropriate iridium trifluoromethanesulfonate complex (3.0 g, 4.0 mmol) and 2-(dibenzo[b,d]furan-4-yl)-4-isopropylpyridine (3.0 g, 10.4 mmol in EtOH (30 mL) and MeOH (30 mL) was refluxed for 20 h under inert atmosphere. The reaction mixture was cooled to room temperature, diluted with ethanol, Celite® was added and the mixture stirred for 10 min. The mixture was filtered on a small silica gel plug on a frit and washed with ethanol (3-4 times) and with hexane (3-4 times). The filtrate was discarded. The Celite®/silica plug was then washed with dichloromethane to elute the product. The crude product was chromatographed on silica gel with 1/1 (v/v) dichloromethane/hexane to yield 2.0 g (60%) of Compound 627 as a yellow solid. The product was confirmed by HPLC (99.9% pure) and LC/MS. 
     
       
         
         
             
             
         
       
     
     Synthesis of Compound 628: A mixture of the appropriate iridium trifluormethanesulfonate complex (3.0 g, 4.0 mmol) and 2-(dibenzo[b,d]furan-4-yl)4-isopropylpyridine (3.0 g, 10.5 mmol) in EtOH (25 mL) and MeOH (25 mL) was refluxed for 24 h under nitrogen atmosphere. The reaction mixture was cooled to room temperature, diluted with ethanol, Celite® was added and the mixture stirred for 10 min. The mixture was filtered on a small silica gel plug and washed with ethanol (3-4 times) and with hexane (3-4 times). The filtrate was discarded. The Celite®/silica plug was then washed with dichloromethane to elute the product. The crude product was chromatographed on silica gel with 2/3 (v/v) dichloromethane/hexane to yield 2.1 g (64%) of product as a yellow solid. The product was confirmed by HPLC (99.95% pure) and LC/MS. 
     
       
         
         
             
             
         
       
     
     Synthesis of Compound 633: A mixture of the appropriate iridium trifluoromethanesulfonate complex (2.5 g, 3.25 mmol) and 2-(dibenzo[b,d]furan-4-yl)-4-isopropylpyridine (2.5 g, 8.70 mmol) in EtOH (25 mL) and MeOH (25 mL) was refluxed for 20 h under inert atmosphere. The reaction mixture was cooled to room temperature, diluted with ethanol, Celite® was added and the mixture stirred for 10 min. The mixture was filtered on a small silica gel plug on a frit and washed with ethanol (3-4 times) and with hexane (3-4 times). The filtrate was discarded. The Celite®/silica plug was then washed with dichloromethane to elute the product. The solvent was removed to half the volume and the product precipitated by addition of isopropanol and removing dichloromethane under reduced pressure. The filtered material was washed with isopropanol and hexane and dried. The crude product was chromatographed on silica gel with 1/1 (v/v) dichloromethane/hexane to yield 1.6 g (59%) of Compound 633 as a yellow solid. The product was confirmed by HPLC (99.7% pure) and LC/MS. 
     
       
         
         
             
             
         
       
     
     Synthesis of Compound 643: A mixture of the appropriate iridium trifluoromethanesulfonate complex (2.4 g, 3.12 mmol) and 2-(dibenzo[b,d]furan-4-yl)4-ethylpyridine (2.69 g, 9.35 mmol) in EtOH (30 mL) and MeOH (30 mL) was refluxed for 20 h under nitrogen atmosphere. The reaction mixture was cooled to room temperature, diluted with ethanol, Celite® was added and the mixture stirred for 10 min. The mixture was filtered on a small silica gel plug and washed with ethanol (3-4 times) and with hexane (3-4 times). The filtrate was discarded. The Celite®/silica plug was then washed with dichloromethane to elute the product. The crude product was chromatographed on silica gel with 2/3 (v/v) dichloromethane/hexane to yield 1.3 g (50%) of product as a yellow solid. The product was confirmed by HPLC (100% pure) and LC/MS. 
     
       
         
         
             
             
         
       
     
     Synthesis of Compound 652: A mixture of the appropriate iridium trifluoromethanesulfonate complex (3.1 g, 3.9 mmol) and 2-(dibenzo[b,d]furan-4-yl)-4-isopropylpyridine (3.1 g, 10.9 mmol) in EtOH (30 mL) and MeOH (30 mL) was refluxed for 20 h under inert atmosphere. The reaction mixture was cooled to room temperature, diluted with ethanol, Celite® was added and the mixture stirred for 10 min. The mixture was filtered on a small silica gel plug on a frit and washed with ethanol (3-4 times) and with hexane (3-4 times). The filtrate was discarded. The Celite®/silica plug was then washed with dichloromethane to elute the product. The crude product was chromatographed on silica gel with 1/1 (v/v) dichloromethane/hexane to yield 2.1 g (62%) of Compound 652 as a yellow solid. The product was confirmed by HPLC (99.9% pure) and LC/MS 
     
       
         
         
             
             
         
       
     
     Synthesis of Compound 653: A mixture of iridium trifluoromethanesulfonate complex (2.4 g, 3.01 mmol) and 2-(dibenzo[b,d]furan-4-yl)4isopropylpyridine (3.0 g, 9.02 mmol) in EtOH (30 mL) and MeOH (30 mL) was refluxed for 20 h under nitrogen atmosphere. The reaction mixture was cooled to room temperature, diluted with ethanol, Celite® was added and the mixture stirred for 10 min. The mixture was filtered on a small silica gel plug and washed with ethanol (3-4 times) and with hexane (3-4 times). The filtrate was discarded. The Celite®/silica plug was then washed with dichloromethane to elute the product. The crude product was chromatographed on silica gel with 2/3 (v/v) dichloromethane/hexane to yield 0.96 g (45%) of product as a yellow solid. The product was confirmed by HPLC (99.8% pure) and LC/MS. 
     
       
         
         
             
             
         
       
     
     Synthesis of 2-(dibenzo[b,d]furan-4-yl)-4-ethyl-d 3 -pyridine: To 2-(dibenzo[b,d]furan-4-yl)-4-methylpyridine (15.3 g, 59.0 mmol) in dry THF (250 mL) at −78° C. was added dropwise lithium diisopropylamide (35.4 mL, 70.8 mmol). The dark solution was stirred for 2 h at −78° C. and then CD 3 I was added (4.41 mL, 70.8 mmol) dropwise. The reaction mixture was allowed to slowly warm to RT overnight. Ammonium chloride solution and EtOAc were added and the reaction transferred separatory funnel. The layers were separated, washing the aqueous twice with EtOAc and combined organics once with water. After removal of the solvent, the crude product was chromatographed on silica gel with 8/2 (v/v) hexane/EtOAc and then 7/3 hexane/EtOAc to give 14.5 g of product as a pale yellow solid. Recrystallization from hexane gave 12.9 g (79%) of 2-(dibenzo[b,d]furan-4-yl)-4-ethyl-d 3 -pyridine. HPLC purity: 99.4%. 
     
       
         
         
             
             
         
       
     
     Synthesis of 2-(dibenzo[b,d]furan-4-yl)-4-isopropyl-d 6 -pyridine: 2-(Dibenzo[b,d]furan-4-yl)-4-ethyl-d 3 -pyridine was dissolved in dry THF (100 mL) and cooled to −78° C. Lithium diisopropylamide (19.0 mL, 38.0 mmol) was added dropwise and the reaction mixture stirred for 2 h at −78° C. CD 3 I was added dropwise and the reaction mixture was allowed to slowly warm to room temperature overnight. The reaction was quenched with MeOH, NH 4 Cl (aq.) and EtOAc were added and the bipasic mixture transferred to a separatory funnel, The layers were separated, washing the aqueous layer twice with EtOAc and the combined organics with water. After removal of the solvent, the crude product was chromatographed on silica gel with 8/2 (v/v) hexane/EtOAc to give 6.4 g (86%) of 2-(dibenzo[b,d]furan-4-yl)-4-isopropyl-d 6 -pyridine. HPLC purity: 99.2%. 
     
       
         
         
             
             
         
       
     
     Synthesis of Compound 1145: A mixture of the appropriate iridium trifluoromethanesulfonate complex (3.5 g, 4.9 mmol) and 2-(dibenzo[b,d]furan-4-yl)-4-d 3 -ethylylpyridine (3.5 g, 12.7 mmol) in EtOH (30 mL) and MeOH (30 mL) was refluxed for 20 h under inert atmosphere. The reaction mixture was cooled to room temperature, diluted with ethanol, celite was added and the mixture stirred for 10 min. The mixture was filtered on a small silica gel plug on a frit and washed with ethanol (3-4 times) and with hexane (3-4 times). The filtrate was discarded. The Celite®/silica plug was then washed with dichloromethane to elute the product. The crude product was chromatographed on silica gel with dichloromethane to yield 1.8 g (47%) of Compound 1145 as a yellow solid. The product was confirmed by HPLC (98.7% pure) and LC/MS. 
     
       
         
         
             
             
         
       
     
     Synthesis of Compound 1146: 2-(Dibenzo[b,d]furan-4-yl)-4-isopropyl-d 6 -pyridine and the appropriate iridium trifluoromethanesulsonate complex were combined in ethanol (25 mL) and methanol (25 mL) and heated to reflux for 16 h. The reaction mixture was cooled to room temperature, diluted with ethanol, Celite® was added and the mixture stirred for 10 min. The mixture was filtered on a small silica gel plug on a frit and washed with ethanol (3-4 times) and with hexane (3-4 times). The filtrate was discarded. The celite/silica plug was then washed with dichloromethane to dissolve the product. The crude product was chromatographed on silica gel with 50-70% dichloromethane in hexane to and then sublimed to yield 1.7 g (43%) of Compound 1146 as a yellow solid. The product was confirmed by HPLC (99.5% pure) and LC/MS. 
     It is understood that the various embodiments described herein are by way of example only, and are not intended to limit the scope of the invention. For example, many of the materials and structures described herein may be substituted with other materials and structures without deviating from the spirit of the invention. The present invention as claimed may therefore include variations from the particular examples and preferred embodiments described herein, as will be apparent to one of skill in the art. It is understood that various theories as to why the invention works are not intended to be limiting.