Patent Publication Number: US-2018037540-A1

Title: Diazadienyl compound, raw material for forming thin film, method for producing thin film, and diazadiene compound

Description:
TECHNICAL FIELD 
     The present invention relates to a novel diazadienyl compound, a raw material for forming a thin film that includes the compound, a method for manufacturing a thin film by using the raw material for forming a thin film, and a novel diazadiene compound. 
     BACKGROUND ART 
     Thin-film materials including a metal element have been used for a variety of applications because such materials exhibit electric properties, optical properties and the like. For example, copper and copper-containing thin films have been used as wiring materials for LSI because of a high electric conductivity, high resistance to electromigration, and a high melting point. Further, nickel and nickel-containing thin films are mainly used for parts of electronic components such as resistive films and barrier films, parts for recording media such as magnetic films, and parts for thin-film solar cells, such as electrodes. Cobalt and cobalt-containing thin films have been used for electrode films, resistive films, adhesive films, magnetic tapes, ultra-hard tool members and the like. 
     Examples of methods for manufacturing such thin films include a sputtering method, an ion plating method, a Metal Organic Decomposition method (MOD method) using a coating pyrolysis method and a sol-gel method, and a chemical vapor deposition method. Among them, the chemical vapor deposition (referred to hereinbelow simply as CVD) method, inclusive of an ALD (Atomic Layer Deposition) method, is an optimum manufacturing process because it has advantages such as being suitable for mass production, exceling in composition controllability and stepwise coating ability, and enabling hybrid accumulation. 
     A large number of various materials have been reported as metal-supplying sources for use in the chemical vapor deposition method. For example, Patent Document 1 discloses a diazadienyl complex that can be used as a raw material for forming a thin film by an ALD method. Further, Patent Document 2 discloses a diazadiene-based metal compound that can be used in a chemical vapor deposition or atomic layer deposition. Patent Documents 1 and 2 do not specifically describe a diazadiene compound of the present invention.
     Patent Document 1: U.S. Patent Application Publication No. 2013/0164456   Patent Document 2: Japanese Patent Application Laid-open No. 2013-545755   

     SUMMARY OF INVENTION 
     Technical Problem 
     When a metal-containing thin film is formed on a surface of a substrate by vaporizing a raw material for chemical vapor deposition, materials that has a high vapor pressure, no pyrophoricity, a low melting point and capable of thermally decomposing at low temperature to form a thin film are required. In particular, materials that has a high vapor pressure, no pyrophoricity and a low melting point have been strongly required. 
     Solution to the Problem 
     The present inventors have carried out investigations and discovered that the abovementioned problems can be solved by a specific diazadienyl compound, to achieve the present invention. 
     The present invention provides a diazadienyl compound represented by General Formula (I) below, a raw material for forming a thin film that includes the compound, and a method for manufacturing a thin film by using the raw material. 
     
       
         
         
             
             
         
       
     
     In the formula, R 1  and R 2  each independently represent a C 1-6  linear or branched alkyl group, R 3  represents hydrogen, or a C 1-6  linear or branched alkyl group, M represents a metal atom or a silicon atom, and n represents a valence of the metal atom or silicon atom represented by M. 
     The present invention provides a raw material for forming a thin film that includes a diazadienyl compound represented by General Formula (I) above, and a method for manufacturing a thin film, comprising: introducing a vapor including a diazadienyl compound represented by General Formula (I) above into a film formation chamber in which a substrate is disposed; and forming, on a surface of the substrate, a thin film including at least one atom selected from a metal atom and a silicon atom by inducing decomposition and/or chemical reaction of the diazadienyl compound. 
     The present invention also provides a diazadiene compound represented by General Formula (II) below. 
     
       
         
         
             
             
         
       
     
     In the formula, R 4  represents a C 1-6  linear or branched alkyl group. 
     Advantageous Effects of the Invention 
     In accordance with the present invention, it is possible to obtain a diazadienyl compound having a high vapor pressure, no pyrophoricity and a low melting point, which becomes a liquid at normal pressure and 30° C. or becomes a liquid by slight heating. The diazadienyl compound is particularly suitable as a material for forming a thin film for forming a metal thin film by a CVD method. The present invention also can provide a novel diazadiene compound. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1  is a conceptual diagram illustrating an example of a chemical vapor deposition apparatus for use in the method for manufacturing a thin film in the present invention. 
         FIG. 2  is a conceptual diagram illustrating another example of a chemical vapor deposition apparatus for use in the method for manufacturing a thin film in the present invention. 
         FIG. 3  is a conceptual diagram illustrating another example of a chemical vapor deposition apparatus for use in the method for manufacturing a thin film in the present invention. 
         FIG. 4  is a conceptual diagram illustrating another example of a chemical vapor deposition apparatus for use in the method for manufacturing a thin film in the present invention. 
     
    
    
     DESCRIPTION OF EMBODIMENTS 
     The diazadienyl compound in accordance with the present invention is represent by General Formula (I) above. This compound is suitable as a precursor for a thin film manufacturing method having a vaporization step, such as the CVD method, and can be used for forming a thin film using the ALD method. The diazadienyl compound in accordance with the present invention has low melting point, and becomes a liquid at normal pressure and 30° C. or becomes a liquid by slight heating. Since the compound having a low melting point has good transportability, the diazadienyl compound of the present invention is suitable as a precursor for a thin film production method having a vaporization step, such as the CVD method. 
     In General Formula (I) of the present invention, R 1  and R 2  each independently represent a C 1-6  linear or branched alkyl group, R 3  represents hydrogen, or a C 1-6  linear or branched alkyl group, M represents a metal atom or a silicon atom, and n represents a valence of the metal atom or silicon atom represented by M. 
     Examples of the C 1-6  linear or branched alkyl group represented by R 1 , R 2  and R 3  include methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl, tert-butyl, pentyl, isopentyl and hexyl. 
     M in General Formula (I) is a metal atom or a silicon atom. The metal atom is not particularly limited, and examples thereof include lithium, sodium, potassium, magnesium, calcium, strontium, barium, radium, scandium, yttrium, titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, manganese, iron, osmium, cobalt, rhodium, iridium, nickel, palladium, platinum, copper, silver, gold, zinc, cadmium, aluminum, gallium, indium, germanium, tin, lead, antimony, bismuth, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, and ytterbium. Among them, it is particularly preferred that M be copper, iron, nickel, cobalt, or manganese, because of a low melting point. 
     In General Formula (I), it is preferred that R 2  and R 3  are different because this produces a low melting point. In addition, it is preferred that R 3  is hydrogen because this produces a high vapor pressure and a low melting point. In particular, it is preferred that R 2  is a methyl group and R 3  is hydrogen because this produces especially high vapor pressure and low melting point. Further, it is preferred that R 1  is an ethyl group because this produces a high vapor pressure. In methods for producing thin films by MOD methods without a vaporization step, R 1 , R 2  and R 3  may be appropriately selected depending on the solubility in a solvent used, the thin film forming reaction and the like. 
     Preferred specific examples of the diazadienyl compound represented by General Formula (I) include the compounds represented by chemical formulas No. 1 to No. 18 below, in which M is cobalt. In the chemical formulas No. 1 to No. 18, “Me” represents a methyl group, “Et” represents an ethyl group, “Pr” represents a propyl group, “iPr” represents an isopropyl group, “sBu” represents a sec-butyl group and “tBu” represents a tert-butyl group. 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     Preferred specific examples of the diazadienyl compound represented by General Formula (I) include the compounds represented by chemical formulas No. 19 to No. 36 below, in which M is copper. In the chemical formulas No. 19 to No. 36, “Me” represents a methyl group, “Et” represents an ethyl group, “Pr” represents a propyl group, “iPr” represents an isopropyl group, “sBu” represents a sec-butyl group and “tBu” represents a tert-butyl group. 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     Preferred specific examples of the diazadienyl compound represented by General Formula (I) include the compounds represented by chemical formulas No. 37 to No. 54 below, in which M is iron. In the chemical formulas No. 37 to No. 54, “Me” represents a methyl group, “Et” represents an ethyl group, “Pr” represents a propyl group, “iPr” represents an isopropyl group, “sBu” represents a sec-butyl group and “tBu” represents a tert-butyl group. 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     Preferred specific examples of the diazadienyl compound represented by General Formula (I) include the compounds represented by chemical formulas No. 55 to No. 72 below, in which M is nickel. In the chemical formulas No. 55 to No. 72, “Me” represents a methyl group, “Et” represents an ethyl group, “Pr” represents a propyl group, “iPr” represents an isopropyl group, “sBu” represents a sec-butyl group and “tBu” represents a tert-butyl group. 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     Preferred specific examples of the diazadienyl compound represented by General Formula (I) include the compounds represented by chemical formulas No. 73 to No. 90 below, in which M is manganese. In the chemical formulas No. 73 to No. 90, “Me” represents a methyl group, “Et” represents an ethyl group, “Pr” represents a propyl group, “iPr” represents an isopropyl group, “sBu” represents a sec-butyl group and “tBu” represents a tert-butyl group. 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     The diazadienyl compound of the present invention is not particularly restricted by the manufacturing method thereof and can be manufactured by using a well-known reaction. For example, a diazadienyl compound of cobalt can be manufactured, for example, by a method of conducting a reaction of an inorganic cobalt salt such as halide and nitrate, or a hydrate thereof with the corresponding diazadiene compound in the presence of a base such as sodium, lithium, sodium hydride, sodium amide, sodium hydroxide, sodium methylate, ammonia, and amine, or a method of conducting a reaction of an inorganic cobalt salt such as halide and nitrate, or a hydrate thereof with a sodium complex, lithium complex, potassium complex or the like of the corresponding diazadiene compound. 
     In addition, the diazadiene compound used here is not particularly restricted by the manufacturing method thereof and can be manufactured by using a well-known reaction. For example, a diazadiene compound used for manufacturing a diazadienyl compound in which R 3  is hydrogen can be obtained by reacting an alkylamine and an alkylglyoxal in a solvent such as trichloromethane to obtain a product and extracting it with a suitable solvent, followed by dehydration treatment. Further, a diazadiene compound used for manufacturing a diazadienyl compound in which R 3  is a C 1-6  linear or branched alkyl group can be obtained by reacting an alkylamine and a diketone (R 2 —C(═O)C(═O)—R 3)  in a solvent such as trichloromethane to obtain a product and extracting it with a suitable solvent, followed by dehydration treatment. 
     The raw material for forming a thin film of the present invention includes the diazadienyl compound of the present invention, which has been explained hereinabove, as a precursor for the thin film, and the form of the raw material differs depending on the manufacturing process in which the raw material for forming a thin film is to be used. For example, when a thin film including only a metal of one type or silicon is manufactured, the raw material for forming a thin film of the present invention does not include metal compounds or semimetal compounds other than the diazadienyl compound. Meanwhile, where a thin film including metals and/or semimetals of two or more types is manufactured, the raw material for forming a thin film of the present invention includes, in addition to the abovementioned diazadienyl compound, a compound including the desired metal and/or a compound including the desired semimetal (can be also referred to hereinbelow as “other precursor”). As will be described hereinbelow, the raw material for forming a thin film of the present invention may additionally include an organic solvent and/or a nucleophilic reagent. Since physical properties of the diazadienyl compound serving as the precursor are advantageous for the CVD method and ALD method, the raw material for forming a thin film of the present invention is particularly useful as a raw material for chemical vapor deposition (referred to hereinbelow as “CVD”). 
     Where the raw material for forming a thin film of the present invention is a raw material for chemical vapor deposition, the form thereof can be selected, as appropriate, according, e.g., to the delivery and feed method in the CVD method which is to be used. 
     The delivery and feed method can be a gas delivery method in which a CVD source is vaporized by heating and/or depressurizing the interior of a container in which the source is stored (can be referred to hereinbelow simply as “raw material container”), and the obtained vapor is introduced, optionally together with a carrier gas such as argon, nitrogen, and helium, into a film formation chamber in which a substrate is disposed (can be also referred to hereinbelow as “deposition reaction unit”) or a liquid delivery method in which a CVD source is transported in a state of a liquid or solution into a vaporization chamber and vaporized by heating and/or depressurizing in the vaporization chamber, and the vapor is introduced into a film formation chamber. When the gas delivery method is used, the diazadienyl compound itself, which is represented by General Formula (I), can be used as the CVD source. When the liquid delivery method is used, the diazadienyl compound itself, which is represented by General Formula (I), or a solution obtained by dissolving the compound in an organic solvent can be used as the CVD source. Those CVD sources may additionally include the other precursor, a nucleophilic reagent or the like. 
     Further, CVD of a multicomponent system can be implemented by a method of vaporizing and feeding CVD sources for each component independently (can be also referred to hereinbelow as “single source method”) and a method of vaporizing and feeding a mixed raw material obtained by mixing in advance multicomponent raw materials at the desired composition ratio (can be also referred to hereinbelow as “cocktail source method”). When the cocktail source method is used, a mixture of the diazadienyl compound of the present invention and the other precursor, or a mixed solution obtained by dissolving the mixture in an organic solvent can be used as the CVD source. The mixture or mixed solvent may additionally include a nucleophilic reagent. 
     The organic solvent is not particularly limited, and well-known typical organic solvents can be used. Examples of the organic solvents include acetates such as ethyl acetate, butyl acetate, and methoxyethyl acetate; ethers such as tetrahydrofuran, tetrahydropyran, ethylene glycol dimethyl ether, diethylene glycol dimethyl ether, triethylene glycol dimethyl ether, dibutyl ether, and dioxane; ketones such as methyl butyl ketone, methyl isobutyl ketone, ethyl butyl ketone, dipropyl ketone, diisobutyl ketone, methyl amyl ketone, cyclohexanone, and methylcyclohexanone; hydrocarbons such as hexane, cyclohexane, methylcyclohexane, dimethylcyclohexane, ethylcyclohexane, heptane, octane, toluene, and xylene; hydrocarbons including a cyano group such as 1-cyanopropane, 1-cyanobutane, 1-cyanohexane, cyanocyclohexane, cycanobenzene, 1,3-dicyanopropane, 1,4-dicyanobutane, 1,6-dicyanohexane, 1,4-dicyanocyclohexane, and 1,4-dicyanobenzene; pyridine and lutidine. Such organic solvents are used individually or as mixed solvents of two or more thereof according to the relationship between the solute solubility, usage temperature, boiling point, and flash point. When such organic solvents are used, the amount of the entire precursor in the CVD source which is a solvent in which the precursor is dissolved in the organic solvent is preferably 0.01 mol/L to 2.0 mol/L, in particular, 0.05 mol/L to 1.0 mol/L. The amount of the entire precursor, as referred to herein, is the amount of the diazadienyl compound of the present invention when the raw material for forming a thin film of the present invention does not include a metal compound or a semimetal compound other than the diazadienyl compound of the present invention, and is the total amount of the diazadienyl compound of the present invention and the other precursor when the raw material for forming a thin film of the present invention includes a compound including other metal and/or a compound including a semimetal in addition to the diazadienyl compound. 
     When CVD of a multicomponent system is performed, the other precursor which is used together with the diazadienyl compound of the present invention is not particularly limited, and any well-known typical precursor which has been used in CVD sources can be used. 
     Examples of the other precursor include one, or two or more compounds of silicon or a metal selected from a group including compounds having a hydride, a hydroxide, a halide, an azide, an alkyl, an alkenyl, a cycloalkyl, an aryl, an alkynyl, an amino, a dialkylaminoalkyl, a monoalkylamino, a dialkylamino, a diamine, a di(silyl-alkyl)amino, a di(alkyl-silyl)amino, a disilylamino, an alkoxy, an alkoxyalkyl, a hydrazido, a phosphido, a nitrile, a dialkylaminoalkoxy, an alkoxyalkyldialkylamino, a siloxy, a diketonate, a cyclopentadienyl, a silyl, a pyrazolate, a guanidinate, a phosphoguanidinate, an amidinate, a phosphoamidinate, a ketoiminate, a diketoiminate, a carbonyl, and a phosphoamidinate as a ligand. 
     Examples of metals for the precursor include magnesium, calcium, strontium, barium, radium, scandium, yttrium, titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, manganese, iron, osmium, cobalt, rhodium, iridium, nickel, palladium, platinum, copper, silver, gold, zinc, cadmium, aluminum, gallium, indium, germanium, tin, lead, antimony, bismuth, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, and ytterbium. 
     Such other precursors are well known in the pertinent technical field, and the manufacturing methods thereof are also well known. For example, where an alcohol compound is used as the organic ligand, the precursor can be manufactured by conducting a reaction of the abovementioned inorganic metal salt or a hydrate thereof and the alkali metal alkoxide of the alcohol compound. Examples of the inorganic metal salt and hydrate thereof include metal halides and nitrates, and examples of the alkali metal alkoxides include sodium alkoxide, lithium alkoxide, and potassium alkoxide. 
     In the case of a single source method, it is preferred that the other precursor be a compound demonstrating thermal and/or oxidative decomposition behavior similar to that of the diazadienyl compound of the present invention. In the case of a cocktail source method, it is preferred that the other precursor be a compound demonstrating similar thermal and/or oxidative decomposition behavior and further demonstrating no transformations induced by chemical reactions or the like at the time of mixing. 
     Compounds represented by Formulas (II-1) to (II-5) below are examples of precursors including titanium, zirconium, or hafnium among the other precursors. 
     
       
         
         
             
             
         
       
     
     In the formulas, M 1  represents titanium, zirconium, or hafnium; R a  and R b  each independently represent a C 1-20  alkyl group which may be substituted with a halogen atom and may contain an oxygen atom in a chain; R c  represents a C 1-8  alkyl group; R d  represents an optionally branched C 2-18  alkylene group; R e  and R f  each independently represent a hydrogen atom or a C 1-3  alkyl group; R g , R h , R k , and R j  each independently represent a hydrogen atom or a C 1-4  alkyl group; p represents an integer of 0 to 4; q represents 0 or 2; r represents an integer of 0 to 3; s represents an integer of 0 to 4; and t represents an integer of 1 to 4. 
     Examples of the C 1-20  alkyl group which may be substituted with a halogen atom and may contain an oxygen atom in a chain, this group being represented by R a  and R b  in Formulas (II-1) to (II-5), include methyl, ethyl, propyl, isopropyl, butyl, sec-butyl, tert-butyl, isobutyl, pentyl, isopentyl, neopentyl, tert-pentyl, hexyl, cyclohexyl, 1-methylcyclohexyl, heptyl, 3-heptyl, isoheptyl, tert-heptyl, n-octyl, isooctyl, tert-octyl, 2-ethylhexyl, trifluoromethyl, perfluorohexyl, 2-methoxyethyl, 2-ethoxyethyl, 2-butoxyethyl, 2-(2-methoxyethoxy)ethyl, 1-methoxy-1,1-dimethylmethyl, 2-methoxy-1,1-dimethylethyl, 2-ethoxy-1,1-dimethylethyl, 2-isopropoxy-1,1-dimethylethyl, 2-butoxy-1,1-dimethylethyl, and 2-(2-methoxyethoxy)-1,1-dimethylethyl. The C 1-8  alkyl group as represented by R c  includes methyl, ethyl, propyl, isopropyl, butyl, sec-butyl, tert-butyl, isobutyl, pentyl, isopentyl, neopentyl, tert-pentyl, hexyl, 1-ethylpentyl, cyclohexyl, 1-methylcyclohexyl, heptyl, isoheptyl, tert-heptyl, n-octyl, isooctyl, tert-octyl, and 2-ethylhexyl. The optionally branched C 2-18  alkylene group which is represented by R d  is a group derived from a glycol. Examples of the glycol include 1,2-ethanediol, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 2,4-hexanediol, 2,2-dimethyl-1,3-propanediol, 2,2-diethyl-1,3-propanediol, 2,2-diethyl-1,3-butanediol, 2-ethyl-2-butyl-1,3-propanediol, 2,4-pentanediol, 2-methyl-1,3-propanediol, and 1-methyl-2,4-pentanediol. Examples of the C 1-3  alkyl group which is represented by R e  and R f  include methyl, ethyl, propyl, and 2-propyl. Examples of the C 1-4  alkyl group which is represented by R g , R h , R j , and R k  include methyl, ethyl, propyl, isopropyl, butyl, sec-butyl, tert-butyl, and isobutyl. 
     Specific examples of precursors including titanium include tetrakis(alkoxy)titanium such as tetrakis(ethoxy)titanium, tetrakis(2-propoxy)titanium, tetrakis(butoxy)titanium, tetrakis(sec-butoxy)titanium, tetrakis(isobutoxy)titanium, tetrakis(tert-butoxy)titanium, tetrakis(tert-pentyl)titanium, and tetrakis(1-methoxy-2-methyl-2-propoxy)titanium; tetrakis-β-diketonatotitanium such as tetrakis(pentane-2,4-dionato)titanium, (2,6-dimethylheptane-3,5-dionato)titanium, and tetrakis(2,2,6,6-tetramethylheptane-3,5-dionato)titanium; bis(alkoxy)bis(β-diketonato)titanium such as bis(methoxy)bis(pentane-2,4-dionato)titanium, bis(ethoxy)bis(pentane-2,4-dionato)titanium, bis(tert-butoxy)bis(pentane-2,4-dionato)titanium, bis(methoxy)bis(2,6-dimethylheptane-3,5-dionato)titanium, bis(ethoxy)bis(2,6-dimethylheptane-3,5-dionato)titanium, bis(2-propoxy)bis(2,6-dimethylheptane-3,5-dionato)titanium, bis(tert-butoxy)bis(2,6-dimethylheptane-3,5-dionato)titanium, bis(tert-amyloxy)bis(2,6-dimethylheptane-3,5-dionato)titanium, bis(methoxy)bis(2,2,6,6-tetramethylheptane-3,5-dionato)titanium, bis(ethoxy)bis(2,2,6,6-tetramethylheptane-3,5-dionato)titanium, bis(2-propoxy)bis(2,6,6,6-tetramethylheptane-3,5-dionato)titanium, bis(tert-butoxy)bis(2,2,6,6-tetramethylheptane-3,5-dionato)titanium, and bis(tert-amyloxy)bis(2,2,6,6-tetramethylheptane-3,5-dionato)titanium; and glycoxybis(β-diketonato)titanium such as (2-methylpentanedioxy)bis(2,2,6,6-tetramethylheptane-3,5-dionato)titanium and (2-methylpentanedioxy)bis(2,6-dimethylheptane-3,5-dionato)titanium; (cyclopentadienyl)tris(dialkylamino)titanium such as (methylcyclopentadienyl)tris(dimethylamino)titanium, (ethylcyclopentadienyl)tris(dimethylamino)titanium, (cyclopentadienyl)tris(dimethylamino)titanium, (methylcyclopentadienyl)tris(ethylmethylamino)titanium, (ethylcyclopentadienyl)tris(ethylmethylamino)titanium, (cyclopentadienyl)tris(ethylmethylamino)titanium, (methylcyclopentadienyl)tris(diethylamino)titanium, (ethylcyclopentadienyl)tris(diethylamino)titanium, and (cyclopentadienyl)tris(diethylamino)titanium; (cyclopentadienyl)tris(alkoxy)titanium such as (cyclopentadienyl)tris(methoxy)titanium, (methylcyclopenyl)tris(methoxy)titanium, (ethylcyclopentadienyl)tris(methoxy)titanium, (propylcyclopentadienyl)tris(methoxy)titanium, (isopropylcyclopentadienyl)tris(methoxy)titanium, (butylcyclopentadienyl)tris(methoxy)titanium, (isobutylcyclopentadienyl)tris(methoxy)titanium, (tert-butylcyclopentadienyl)tris(methoxy)titanium, and (pentamethylcyclopentadienyl)tris(methoxy)titanium. Examples of precursors including zirconium or hafnium are compounds presented as examples of titanium-containing precursors in which titanium is substituted with zirconium or hafnium. 
     Examples of precursors including rare earth metals are compounds represented by Formulas (III-1) to (III-3). 
     
       
         
         
             
             
         
       
     
     In the formulas, M 2  represents a rare earth atom; R a  and R b  each independently represent a C 1-20  alkyl group which may be substituted with a halogen atom and may contain an oxygen atom in a chain; R c  represents a C 1-8  alkyl group; R e  and R f  each independently represent a hydrogen atom or a C 1-3  alkyl group; R g  and R j  each independently represent a C 1-4  alkyl group; p′ represents an integer of 0 to 3; and r′ represents an integer of 0 to 2. 
     Examples of rare earth atoms represented by M 2  in the precursor including a rare earth element include scandium, yttrium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium. Examples of groups represented by R a , R b , R c , R e , R f , R g , and R j  include groups presented by way of examples with respect to the titanium-containing precursors. 
     If necessary, the raw material for forming a thin film of the present invention may include a nucleophilic reagent to stabilize the diazadienyl compound of the present invention and the other precursor. Examples of the nucleophilic reagent include ethylene glycol ethers such as glyme, diglyme, triglyme, and tetraglyme; crown ethers such as 18-crown-6, dicyclohexyl-18-crown-6, 24-crown-8, dicyclohexyl-24-crown-8, and dibenzo-24-crown-8; polyamines such as ethylenediamine, N,N′-tetramethylethylenediamine, diethylenetriamine, triethylenetetramine, tetraethylenepentamine, pentaethylenehexamine, 1,1,4,7,7-pentamethyldiethylenetriamine, 1,1,4,7,10,10-hexamethyltriethylenetetramine, and triethoxytriethyleneamine; cyclic polyamines such as cyclam and cyclen; heterocyclic compounds such as pyridine, pyrrolidine, piperidine, morpholine, N-methylpyrrolidine, N-methylpiperidine, N-methylmorpholine, tetrahydrofuran, tetrahydropyran, 1,4-dioxane, oxazole, thiazole, and oxathiolane; 3-keto esters such as methyl acetoacetate, ethyl acetoacetate, and 2-methoxyethyl acetoacetate; and 3-diketones such as acetylacetone, 2,4-hexanedione, 2,4-heptanedione, 3,5-heptanedione, and dipivaroylmethane. These nucleophilic reagents are used in an amount preferably within a range of 0.1 mol to 10 mol, more preferably 1 mol to 4 mol per mole of the amount of the entire precursor. 
     In the raw material for forming a thin film of the present invention, the amount of metal element impurities, halogen impurities such as chlorine-containing impurities, and organic impurities, which are different from the components constituting the raw materials, needs to be minimized. The content of the metal element impurities is preferably 100 ppb or less, and more preferably 10 ppb or less for each element, and the total amount of the impurities is preferably 1 ppm or less, and more preferably 100 ppb or less. In particular, when the raw material is used to form a gate insulating layer, a gate film, or a barrier layer of an LSI, it is necessary to reduce the amount of alkali metal elements and alkaline earth metal elements which affect the electric properties of a thin film to be obtained. The amount of the halogen impurities is preferably 100 ppm or less, more preferably 10 ppm or less, and most preferably 1 ppm or less. The total amount of organic impurities is preferably 500 ppm or less, more preferably 50 ppm or less, and most preferably 10 ppm or less. Since moisture causes particle generation in the raw material for chemical vapor deposition or particle generation during thin film formation, it is better to remove moisture as much as possible prior to use from the metal compound, the organic solvent, and the nucleophilic reagent in order to reduce the amount of moisture therein. The amount of moisture in each of the metal compound, the organic solvent, and the nucleophilic reagent is 10 ppm or less, and more preferably 1 ppm or less. 
     Further, in order to reduce or prevent the particle contamination of the thin film to be formed, it is preferred that the raw material for forming a thin film of the present invention include as few particles as possible. More specifically, in particle measurements with a particle detector of a light scattering type in a liquid phase, the number of particles larger than 0.3 μm is preferably 100 or less in 1 ml of the liquid phase, more preferably the number of particles larger than 0.2 μm is 1000 or less in 1 ml of the liquid phase, and most preferably the number of particles larger than 0.2 μm is 100 or less in 1 ml of the liquid phase. 
     A method for manufacturing a thin film of the present invention by which a thin film is manufactured by using the raw material for forming a thin film of the present invention is based on the CVD method in which a vapor produced by vaporizing the raw material for forming a thin film of the present invention, and an optionally used reactive gas are introduced into a film formation chamber in which a substrate is disposed, and the precursor is then decomposed and/or chemically reacted on the substrate to grow and deposit a thin film including a metal on the substrate surface. The method for delivering and feeding the raw materials, the deposition method, manufacturing conditions, and manufacturing apparatus are not particularly restricted, and well-known typical conditions and methods can be used. 
     Examples of the optionally used reactive gas include oxidative gases such as oxygen, ozone, nitrogen dioxide, nitrogen monoxide, water vapor, hydrogen peroxide, formic acid, acetic acid, and acetic anhydride; reductive gases such as hydrogen; and gases producing nitrides, for example, organic amine compounds such as monoalkylamines, dialkylamines, trialkylamines, and alkylenediamines, hydrazine, and ammonia. These gases can be used individually or in combinations of two or more thereof. 
     Examples of the delivery and feeding methods include the above-described gas delivery method, liquid delivery method, single source method, and cocktail source method. 
     Examples of the deposition method include thermal CVD in which a source gas or a source gas and a reactive gas are reacted only by heat in order to deposit a thin film; plasma CVD in which heat and plasma are used; photo-excited CVD in which heat and light are used; photo- and plasma-excited CVD in which heat, light and plasma are used; and ALD in which the CVD deposition reaction is separated into elementary steps and deposition is performed step by step at a molecular level. 
     Examples of the substrate material include silicon, ceramics such as silicon nitride, titanium nitride, tantalum nitride, titanium oxide, titanium nitride ruthenium oxide, zirconium oxide, hafnium oxide, and lanthanum oxide; glass; and metals such as metallic ruthenium. The substrate may be in the form of a sheet, sphere, fibers, and flakes. The substrate surface may be flat or may have a three-dimensional structure such as a trench structure. 
     The manufacturing conditions include the reaction temperature (substrate temperature), reaction pressure, deposition rate, and the like. The reaction temperature is preferably 100° C. or higher, at which the diazadienyl compound of the present invention is sufficiently reactive, and more preferably 150° C. to 400° C. Since the diazadienyl compound of the present invention can be thermally decomposed at a temperature lower than 250° C., a temperature of 150° C. to 250° C. is especially desirable. The reaction pressure is preferably from atmospheric pressure to 10 Pa for thermal CVD and photo-excited CVD, and preferably from 2000 Pa to 10 Pa when plasma is used. 
     The deposition rate can be controlled by the raw material feed conditions (vaporization temperature and vaporization pressure), reaction temperature, and reaction pressure. Since a high deposition rate can degrade the properties of the resulting thin film and a low deposition rate can cause problems with productivity, the deposition rate is preferably 0.01 nm/min to 100 nm/min and more preferably 1 nm/min to 50 nm/min. In the ALD method, the control is performed by the number of cycles so as to obtain the desired film thickness. 
     The temperature or pressure during vaporization of the raw material for forming a thin film can be also considered as the manufacturing condition. The step of obtaining the vapor by vaporizing the raw material for forming a thin film may be performed inside the raw material container or inside the vaporization chamber. In either case, it is preferred that the raw material for forming a thin film of the present invention be evaporated at 0° C. to 150° C. Further, where the raw material for forming a thin film is vaporized to obtain the vapor inside the raw material container or vaporization chamber, it is preferred that the pressure inside the raw material container and the pressure inside the vaporization chamber be 1 Pa to 10,000 Pa. 
     The method for manufacturing a thin film of the present invention, when it is realized by the ALD method, may include a raw material introduction step in which the raw material for forming a thin film is vaporized to obtain a vapor and the vapor is introduced into the film formation chamber by the abovementioned delivery and feeding method, and also a precursor thin film formation step of forming a precursor thin film on the surface of the substrate with the diazadienyl compound in the vapor, an evacuation step of evacuating the unreacted diazadienyl compound gas, and a metal-containing thin film formation step of chemically reacting the precursor thin film with a reactive gas and forming a thin film including the metal on the surface of the substrate. 
     Each of the abovementioned steps will be described hereinbelow in greater detail with reference to the case of forming a metal oxide thin film. When a metal oxide thin film is formed by the ALD method, initially, the raw material introduction step, which has been explained hereinabove, is performed. The temperature and pressure preferred when vaporizing the raw material for forming a thin film are the same as explained hereinabove. Then, a precursor thin film is formed on the substrate surface with the diazadienyl compound introduced in the deposition reaction unit (precursor thin film formation step). At this time, heat may be applied by heating the substrate or heating the deposition reaction unit. The precursor thin film which is formed in this step is a metal oxide thin film or a thin film generated by decomposition and/or reaction of part of the diazadienyl compound and has a composition different from the target metal oxide thin film. The substrate temperature employed in this step is preferably from room temperature to 500° C., more preferably from 150° C. to 350° C. The pressure in the system (in the film formation chamber) when this step is performed is preferably 1 Pa to 10,000 Pa, more preferably 10 Pa to 1000 Pa. 
     The unreacted diazadienyl compound gas and byproduct gas are then evacuated from the deposition reaction unit (evacuation step). The unreacted diazadienyl compound gas and byproduct gas are ideally completely evacuated from the deposition reaction unit, but such complete evacuation is not always necessary. Examples of the evacuation method include a method of purging the interior of the system with an inactive gas such as nitrogen, helium, and argon, a method of evacuating by depressurizing the interior of the system, and a method in which the aforementioned methods are combined. The degree of depressurization when the depressurization method is used is preferably 0.01 Pa to 300 Pa, more preferably 0.01 Pa to 100 Pa. 
     The reactive gas is then introduced into the deposition reaction unit and a metal oxide thin film is formed from the precursor thin film, which has been formed in the preceding precursor thin film formation step, under the action of the oxidizing gas or the action of the oxidizing gas and heat (metal oxide-containing thin film formation step). The temperature when heat is used in this step is preferably from room temperature to 500° C., more preferably from 150° C. to 350° C. The pressure in the system (in the film formation chamber) in which this step is performed is preferably 1 Pa to 10,000 Pa, more preferably 10 Pa to 1000 Pa. The diazadienyl compound of the present invention has good reactivity with oxidizing gases and can yield a metal oxide thin film. 
     When the ALD method is used in the above-described manner in the method for manufacturing a thin film of the present invention, thin film deposition performed by a series of operations including the raw material introduction step, precursor thin film formation step, evacuation step, and metal oxide-containing thin film formation step may be taken as one cycle, and such cycles may be repeated a plurality of times till a thin film of a necessary thickness is obtained. In this case, after one cycle is completed, it is preferred that the unreacted diazadienyl compound gas, reactive gas (oxidizing gas when a metal oxide thin film is formed), and byproduct gas be evacuated from the deposition reaction unit in the same manner as in the evacuation step, and the next cycle be thereafter performed. 
     When a metal oxide thin film is formed by the ALD method, energy such as plasma, light, and voltage may be applied, and a catalyst may be used. The time period for applying the energy and the time period for using the catalyst are not particularly limited. For example, the energy may be applied and the catalyst may be used when the diazadienyl compound gas is introduced in the raw material introduction step, during heating in the precursor thin film formation step or metal oxide-containing thin film formation step, during evacuation of the interior of the system in the evacuation step, when the oxidizing gas is introduced in the metal oxide-containing thin film formation step, and also between the aforementioned steps. 
     Further, in the method for manufacturing a thin film of the present invention, annealing may be performed under an inactive gas atmosphere, an oxidizing atmosphere, or a reducing atmosphere after the thin film deposition to obtain better electric properties, and a reflow step may be employed when bump embedding is needed. In this case, the temperature is 200° C. to 1000° C., preferably 250° C. to 500° C. 
     A well-known chemical vapor deposition apparatus can be used for manufacturing a thin film by using the raw material for forming a thin film of the present invention. Specific examples of suitable apparatuses include an apparatus, such as depicted in  FIG. 1 , in which a precursor can be fed by bubbling, and an apparatus, such as depicted in  FIG. 2 , which has a vaporization chamber. An apparatus can be also used in which, as depicted in  FIG. 3  and  FIG. 4 , plasma treatment can be performed with respect to a reactive gas. The single-substrate apparatuses, such as depicted in  FIG. 1  to  FIG. 4 , are not limiting, and an apparatus which uses a batch furnace and is capable of simultaneous processing of a large number of substrates can be also used. 
     Where a thin film is manufactured using the raw material for forming a thin film of the present invention, the desired type of thin film such as metal, oxide ceramic, nitride ceramic, and glass can be formed by appropriately selecting the other precursor, reactive gas, and manufacturing conditions. Such thin films are known to exhibit various electric properties, optical properties and the like, and are used for a variety of applications. For example, copper and copper-containing thin films have been used as wiring materials for LSI because of a high electric conductivity, high resistance to electromigration, and a high melting point. Further, nickel and nickel-containing thin films are mainly used for parts of electronic components such as resistive films and barrier films, parts for recording media such as magnetic films, and parts for thin-film solar cells, such as electrodes. Cobalt and cobalt-containing thin films have been used for electrode films, resistive films, adhesive films, magnetic tapes, ultra-hard tool members and the like. 
     The diazadiene compound of the present invention is represented by General Formula (II) below. This compound is particularly advantageous as a ligand to be used in a compound advantageous as a precursor in a method for forming a thin film that has a vaporization step, such as the CVD method. 
     
       
         
         
             
             
         
       
     
     In the formula, R 4  represents a C 1-6  linear or branched alkyl group. 
     In General Formula (II) of the present invention, R 4  represents a C 1-6  linear or branched alkyl group. Examples of the C 1-6  linear or branched alkyl group represented by R 4  include methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl, tert-butyl, pentyl, isopentyl and hexyl. 
     Preferred specific examples of the diazadiene compound represented by General Formula (II) include compounds represented by Chemical Formulas No. 91 to 96 below. In the chemical formulas No. 91 to No. 96, “Me” represents a methyl group, “Et” represents an ethyl group, “Pr” represents a propyl group, “iPr” represents an isopropyl group, “sBu” represents a sec-butyl group and “tBu” represents a tert-butyl group. 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     The diazadiene compound of the present invention is not restricted by the manufacturing method thereof and can be manufactured by using well-known reactions. For example, the diazadiene compound can be obtained by reacting ethylamine and an alkylglyoxal in a solvent such as trichloromethane to obtain a product and extracting it with a suitable solvent, followed by dehydration treatment. 
     The diazadiene compound of the present invention can be used as a ligand of a metal compound to be used in a raw material for forming a thin film, and the like. The alcohol compound of the present invention can be also used as, for example, a raw material for synthesis of solvents, perfumes, agricultural chemicals, medicines, various polymers and the like. 
     EXAMPLES 
     The present invention will be explained hereinbelow in greater detail with reference to Examples and Evaluation Examples. However, the present invention is not limited by the Examples, etc., below. 
     Example 1: Manufacture of Compound No. 91 
     530.9 g (3.89 mol) of a 33% ethylamine aqueous solution and 398 g (3.33 mol) of trichloromethane were loaded into a 2 L 4-necked flask and cooled to about 6° C. 200 g (1.11 mol) of a 40% 1-methylglyoxal (pyruvaldehyde) aqueous solution was added dropwise to this solution at a liquid temperature of 6 to 8° C. for 1.5 hours. After the end of the dropping, the mixture was stirred at a liquid temperature of 6 to 8° C. for 3.5 hours. Thereafter, the reaction solution was allowed to stand and the organic layer was separated. Further, the aqueous layer was extracted twice with trichloromethane (100 g), and the organic layer was recovered. All the organic layers were combined, dehydrated with sodium sulfate (an appropriate amount) and filtered, and the solvent was removed at an oil bath temperature of 60 to 70° C. under a slightly reduced pressure. Thereafter, distillation was performed at an oil bath temperature of 70° C. under a reduced pressure. The obtained fraction was a pale yellow transparent liquid. The yield was 67.0 g and the percentage yield was 47.8%. 
     (Analytical Data) 
     (1) Mass spectrometry m/z: 126 (M+) 
     (2) Elemental analysis C: 53.7 mass %, H: 9.41 mass %, N: 18.1 mass % (theoretical values; C: 54.0 mass %, H: 9.07 mass %, N: 18.00 mass %) 
     Example 2: Manufacture of Compound No. 2 
     194 g (154 mmol) of Compound No. 91 obtained above and dehydrated tetrahydrofuran (111 g) were loaded into a 200 mL 3-necked flask and cooled to −10° C. with an isopropanol bath cooled with dry ice. 1.07 g (154 mmol) of metallic lithium pieces was gradually added thereto and reacted at −20 to −10° C. This solution was added dropwise to a suspension of 10.0 g (77.0 mmol) of cobalt chloride and 83.3 g of dehydrated tetrahydrofuran at about 0° C., and then reacted for 12 hours under ice cooling. Thereafter, a solvent was removed at a bath temperature of 70° C. under a slightly reduced pressure. After allowing it to cool, 100 g of dehydrated hexane was added to dissolve the product, followed by filtration through a 0.2 μm membrane filter. The solvent was removed from the resulting filtrate at a bath temperature of 70° C. under a slightly reduced pressure and the residue was dried. The obtained residue was subjected to simple distillation at a bath temperature of 120° C. and a pressure of 100 Pa to obtain a dark black viscous liquid. Thereafter, the liquid was purified at a distillation temperature of 90 to 105° C. and a pressure of 60 Pa by using a Kugelrohr refiner to obtain a dark green liquid target product. The yield was 3.60 g, and the percentage yield was 15.0%. Spontaneous combustion was checked with respect to the obtained target product by allowing the product to stay in the air. There was no spontaneous combustion. 
     (Analytical Data) 
     (1) Mass spectrometry m/z: 311 (M+) 
     (2) Elemental analysis (metal analysis: ICP-AES, chlorine analysis: TOX) 
     Co: 18.7 mass %, C: 53.6 mass %, H: 9.12 mass %, N: 18.1 mass % (theoretical values: Co: 18.9 mass %, C: 54.0 mass %, H: 9.07 mass %, N: 18.0 mass %) 
     Chlorine (TOX): less than 10 ppm 
     [Manufacture example 1: Manufacture of N, N′-dipropyl-propane-1,2-diimine] 
     65.6 g (1.11 mol) of n-propylamine and 132 g (1.11 mol) of dehydrated trichloromethane were loaded into a 1 L 4-necked flask and cooled to about 8° C. 50.0 g (0.278 mol) of a 40% pyruvaldehyde aqueous solution was added dropwise to this solution for 1 hour so that a liquid temperature was 8 to 10° C. After the end of the dropping, the mixture was stirred at a liquid temperature of 10° C. for 2 hours. Thereafter, the reaction solution was allowed to stand and the organic layer was separated. Further, the aqueous layer was extracted twice with trichloromethane (100 g), and the organic layer was recovered. All the organic layers were combined, dehydrated with sodium sulfate (an appropriate amount) and filtered, and the solvent was removed at an oil bath temperature of 60 to 70° C. under a slightly reduced pressure. Thereafter, distillation was performed at an oil bath temperature of 100° C. under a reduced pressure. The obtained fraction was a pale yellow transparent liquid. The yield was 26.7 g and the percentage yield was 62.4%. 
     (Analytical Data) 
     (1) Mass spectrometry m/z: 154 (M+) 
     (2) Elemental analysis C: 72.2 mass %, H: 12.0 mass %, N: 17.9 mass % (theoretical values; C: 70.0 mass %, H: 11.8 mass %, N: 18.2 mass %) 
     Example 3: Manufacture of Compound No. 3 
     23.8 g (154 mmol) of N, N′-dipropyl-propane-1,2-diimine obtained above and dehydrated tetrahydrofuran (111 g) were loaded into a 300 mL 3-necked flask and cooled to −35° C. with a dry ice/IPA bath. 1.07 g (154 mmol) of metallic lithium pieces was gradually added thereto and reacted at −35° C. This solution was added dropwise to a suspension of 10.0 g (77.0 mmol) of cobalt chloride and 83.3 g of dehydrated tetrahydrofuran at about −3° C., and then reacted for 12 hours under ice cooling. Thereafter, a solvent was removed at a bath temperature of 70° C. under a slightly reduced pressure. After allowing it to cool, 100 g of dehydrated hexane was added to dissolve the product, followed by filtration through a 0.5 μm membrane filter. The solvent was removed from the resulting filtrate at a bath temperature of 69° C. under a slightly reduced pressure and the residue was dried. The obtained residue was subjected to distillation at a bath temperature of 135° C. and a pressure of 110 Pa to obtain a dark black viscous liquid target product. The yield was 13.6 g, and the percentage yield was 48.1%. Spontaneous combustion was checked with respect to the obtained target product by allowing the product to stay in the air. There was no spontaneous combustion. 
     (Analytical Data) 
     (1) Mass spectrometry m/z: 367 (M+) 
     (2) Elemental analysis (metal analysis: ICP-AES, chlorine analysis: TOX) 
     Co: 15.5 mass %, C: 58.2 mass %, H: 9.78 mass %, N: 15.4 mass % (theoretical values: Co: 16.0 mass %, C: 58.8 mass %, H: 9.88 mass %, N: 15.3 mass %) 
     Chlorine (TOX): less than 10 ppm 
     Manufacture Example 2: Manufacture of N, N′-diisopropyl-propane-1,2-diimine 
     197 g (3.33 mol) of isopropylamine and 496 g (4.16 mol) of dehydrated trichloromethane were loaded into a 1 L 4-necked flask and cooled to about 10° C. 150.0 g (0.833 mol) of a 40% pyruvaldehyde aqueous solution was added dropwise to this solution for 1 hour so that a liquid temperature was 10 to 14° C. After the end of the dropping, the mixture was stirred at a liquid temperature of 10° C. for 2 hours. Thereafter, the reaction solution was allowed to stand and the organic layer was separated. Further, the aqueous layer was extracted twice with trichloromethane (100 g), and the organic layer was recovered. All the organic layers were combined, dehydrated with sodium sulfate and filtered, and the solvent was removed at an oil bath temperature of 60 to 70° C. under a slightly reduced pressure. Thereafter, distillation was performed at an oil bath temperature of 64° C. under a reduced pressure. The obtained fraction was a pale yellow transparent liquid. The yield was 95.5 g and the percentage yield was 74.0%. 
     (Analytical Data) 
     (1) Mass spectrometry m/z: 154 (M+) 
     (2) Elemental analysis C: 72.2 mass %, H: 12.0 mass %, N: 17.9 mass % (theoretical values; C: 70.0 mass %, H: 11.8 mass %, N: 18.2 mass %) 
     Example 4: Manufacture of Compound No. 4 
     15.4 g (49.9 mmol) of N, N′-diisopropyl-propane-1,2-diimine obtained above and dehydrated tetrahydrofuran (111 g) were loaded into a 200 mL 3-necked flask and cooled to −20° C. with a dry ice/IPA bath. 0.69 g (99.8 mmol) of metallic lithium pieces was gradually added thereto and reacted at −20 to −15° C. This solution was added dropwise to a suspension of 6.5 g (49.9 mmol) of cobalt chloride and 110 g of dehydrated tetrahydrofuran at about −3° C., and then reacted for 12 hours under ice cooling. Thereafter, a solvent was removed at a bath temperature of 65° C. under a slightly reduced pressure. After allowing it to cool, 100 g of dehydrated hexane was added to dissolve the product, followed by filtration through a 0.2 μm membrane filter. The solvent was removed from the resulting filtrate at a bath temperature of 69° C. under a slightly reduced pressure and the residue was dried. The obtained residue was subjected to distillation at a bath temperature of 125° C. and a pressure of 50 Pa to obtain a dark black viscous liquid target product. The yield was 10.7 g, and the percentage yield was 58%. Spontaneous combustion was checked with respect to the obtained target product by allowing the product to stay in the air. There was no spontaneous combustion. 
     (Analytical Data) 
     (1) Mass spectrometry m/z: 367 (M+) 
     (2) Elemental analysis (metal analysis: ICP-AES, chlorine analysis: TOX) 
     Co: 15.9 mass %, C: 58.6 mass %, H: 10.0 mass %, N: 15.4 mass % (theoretical values: Co: 16.0 mass %, C: 58.8 mass %, H: 9.88 mass %, N: 15.3 mass %) 
     Chlorine (TOX): less than 10 ppm 
     Manufacture Example 3: Manufacture of N, N′-diethyl-pentane-2,3-diimine 
     530.9 g (3.89 mol) of a 33% ethylamine aqueous solution and 398 g (3.33 mol) of trichloromethane were loaded into a 2 L 4-necked flask and cooled to about 6° C. 111 g (1.11 mol) of ethyl methyl diketone (2,3-pentanedione) was added dropwise to this solution at a liquid temperature of 6 to 8° C. for 1.5 hours. After the end of the dropping, the mixture was stirred at a liquid temperature of 6 to 8° C. for 3.5 hours. Thereafter, the reaction solution was allowed to stand and the organic layer was separated. Further, the aqueous layer was extracted twice with trichloromethane (100 g), and the organic layer was recovered. All the organic layers were combined, dehydrated with sodium sulfate (an appropriate amount) and filtered, and the solvent was removed at an oil bath temperature of 60 to 70° C. under a slightly reduced pressure. Thereafter, distillation was performed at an oil bath temperature of 70° C. under a reduced pressure. The obtained fraction was a pale yellow transparent liquid. The yield was 68.7 g and the percentage yield was 40.1%. 
     (Analytical Data) 
     (1) Mass spectrometry m/z: 154 (M+) 
     (2) Elemental analysis C: 69.7 mass %, H: 11.4 mass %, N: 18.0 mass % (theoretical values; C: 70.0 mass %, H: 11.8 mass %, N: 18.2 mass %) 
     Example 5: Manufacture of Compound No. 14 
     18.9 g (123 mmol) of N, N′-diethyl-pentane-2,3-diimine obtained above and dehydrated tetrahydrofuran (180 g) were loaded into a 300 mL 3-necked flask and cooled to −30° C. with a dry ice/IPA bath. 0.851 g (122.6 mmol) of metallic lithium pieces was gradually added thereto and reacted at −10° C. This solution was added dropwise to a suspension of 10.0 g (6.13 mmol) of cobalt chloride and 180 g of dehydrated tetrahydrofuran at about −3° C., and then reacted for 12 hours under ice cooling. Thereafter, a solvent was removed at a bath temperature of 76° C. under a slightly reduced pressure. After allowing it to cool, the product was redissolved with dehydrated hexane and filtered by a membrane filter. The solvent was removed from the resulting filtrate at a bath temperature of 70° C. under a slightly reduced pressure and the residue was dried. The obtained residue was subjected to distillation at a bath temperature of 120° C. and a pressure of 65 Pa to obtain a dark black viscous liquid target product. The yield was 5.0 g, and the percentage yield was 22.0%. Spontaneous combustion was checked with respect to the obtained target product by allowing the product to stay in the air. There was no spontaneous combustion. 
     (Analytical Data) 
     (1) Mass spectrometry m/z: 367 (M+) 
     (2) Elemental analysis (metal analysis: ICP-AES, chlorine analysis: TOX) 
     Co: 15.6 mass %, C: 58.2 mass %, H: 9.78 mass %, N: 15.4 mass % (theoretical values: Co: 16.0 mass %, C: 58.8 mass %, H: 9.88 mass %, N: 15.3 mass %) 
     Chlorine (TOX): less than 10 ppm 
     [Evaluation Example 1] Evaluation of Physical Properties of Cobalt Compounds 
     The states of Compounds Nos. 2, 3, 4 and 14 and Comparative Compound 1 shown below at normal pressure, 30° C. were each visually observed, and the melting point of Comparative Compound 2 in the solid state was measured with a micro-melting point measurement apparatus. The temperatures at which the weights of Compounds Nos. 2, 3, 4 and 14 and Comparative Compounds 1 and 2 shown below were reduced by 50% were measured by TG-DTA. The results are shown in Table 1. 
     (Normal Pressure TG-DTA Measurement Conditions) 
     Normal pressure, Ar flow: 100 ml/min, Heating rate: 10° C./min, sample amount: about 10 mg 
     (Reduced Pressure TG-DTA Measurement Conditions) 
     10 Torr, Ar flow: 50 ml/min, Heating rate: 10° C./min, sample amount: about 10 mg 
     
       
         
         
             
             
         
       
     
     
       
         
           
               
               
               
               
               
               
             
               
                   
                 TABLE 1 
               
               
                   
                   
               
               
                   
                   
                   
                   
                 Normal 
                 Reduced 
               
               
                   
                   
                   
                   
                 pressure 
                 pressure 
               
               
                   
                   
                   
                   
                 TG-DTA 
                 TG-DTA 
               
               
                   
                   
                   
                 Melt- 
                 50% mass 
                 50% mass 
               
               
                   
                   
                   
                 ing 
                 reduction 
                 reduction 
               
               
                   
                   
                   
                 point 
                 temperature 
                 temperature 
               
               
                   
                 Compound 
                 State 
                 [° C.] 
                 [° C.] 
                 [° C.] 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
            
               
                 Comparative 
                 Comparative 
                 Solid 
                 171 
                 228 
                 157 
               
               
                 Example 1 
                 Compound 1 
               
               
                 Comparative 
                 Comparative 
                 Liquid 
                 — 
                 210 
                 130 
               
               
                 Example 2 
                 Compound 2 
               
               
                 Evaluation 
                 Compound 
                 Liquid 
                 — 
                 208 
                 128 
               
               
                 Example 1-1 
                 No. 2 
               
               
                 Evaluation 
                 Compound 
                 Liquid 
                 — 
                 226 
                 147 
               
               
                 Example 1-2 
                 No. 3 
               
               
                 Evaluation 
                 Compound 
                 Liquid 
                 — 
                 225 
                 143 
               
               
                 Example 1-3 
                 No. 4 
               
               
                 Evaluation 
                 Compound 
                 Liquid 
                 — 
                 210 
                 126 
               
               
                 Example 1-4 
                 No. 14 
               
               
                   
               
            
           
         
       
     
     It can be seen from Table 1 above that while Comparative Example 1 is a compound with a melting point of 171° C., the Evaluation Examples 1-1 to 1-4 are all compounds that are liquid under conditions of normal pressure, 30° C. Since a raw material for forming a thin film having a low melting point is easy to transport, such a raw material for forming a thin film can improve productivity. Further, the TG-DTA results show that Evaluation Examples 1-1 to 1-4 have lower 50% mass reduction temperatures than Comparative Example 1. This shows that Evaluation Examples 1-1 to 1-4 exhibit better vapor pressure than Comparative Example 1. Particularly, it is found that Evaluation Examples 1-1 and 1-4 show particularly excellent vapor pressures. 
     [Example 6] Manufacture of Metal Cobalt Thin Films by ALD 
     Metal cobalt thin films were manufactured on Cu substrates by ALD under the following conditions using Compounds Nos. 2, 3 and 4 as raw materials for chemical vapor deposition, using the ALD apparatus shown in  FIG. 1 . When the film thicknesses of the resulting thin films were measured by the X-ray reflectivity method and the thin film structures and compositions were confirmed by X-ray analysis and X-ray photoelectron spectroscopy, the film thicknesses were 3 to 6 nm, the films were composed of metal cobalt (confirmed from Co2p peak in XPS analysis), and the carbon contents were below the detection limit of 0.1 atom %. The film thickness obtained per cycle was 0.02 to 0.04 nm. 
     (Conditions) 
     Reaction temperature (substrate temperature): 230° C., reactive gas: hydrogen gas 
     (Steps) 
     150 cycles were performed, with each cycle consisting of the series of steps shown in (1) to (4) below: 
     (1) Vapor from chemical vapor deposition material that has been vaporized at a material container heating temperature of 100° C. and a material container internal pressure of 100 Pa is introduced, and deposited for 30 seconds at a system pressure of 100 Pa; 
     (2) Unreacted material is removed by 5 seconds of argon purging; 
     (3) Reactive gas is introduced, and reacted for 30 seconds at a system pressure of 100 Pa; 
     (4) Unreacted material is removed by 5 seconds of argon purging. 
     [Example 7] Manufacture of Metal Cobalt Thin Film by ALD 
     A metal cobalt thin film was manufactured on a Cu substrate by ALD under the following conditions using Compound No. 14 as a raw material for chemical vapor deposition, using the ALD apparatus shown in  FIG. 1 . When the film thickness of the resulting thin film was measured by the X-ray reflectivity method and the thin film structure and composition were confirmed by X-ray analysis and X-ray photoelectron spectroscopy, the film thickness was 6 to 9 nm, the film was composed of metal cobalt (confirmed from Co2p peak in XPS analysis), and the carbon content was 0.5 atom %. The film thickness obtained per cycle was 0.04 to 0.06 nm. 
     (Conditions) 
     Reaction temperature (substrate temperature): 210° C., reactive gas: hydrogen gas 
     (Steps) 
     150 cycles were performed, with each cycle consisting of the series of steps shown in (1) to (4) below: 
     (1) Vapor from chemical vapor deposition material that has been vaporized at a material container heating temperature of 100° C. and a material container internal pressure of 100 Pa is introduced, and deposited for 30 seconds at a system pressure of 100 Pa; 
     (2) Unreacted material is removed by 5 seconds of argon purging; 
     (3) Reactive gas is introduced, and reacted for 30 seconds at a system pressure of 100 Pa; 
     (4) Unreacted material is removed by 5 seconds of argon purging. 
     [Comparative Example 3] Manufacture of Metal Cobalt Thin Film by ALD 
     An attempt was made to manufacture a metal cobalt thin film on a Cu substrate by ALD under the following conditions using Comparative Compound 2 as a raw material for chemical vapor deposition, but a smooth thin film could not be obtained. The carbon content of the Co-containing material formed on the Cu substrate was 10 atom % or more. 
     (Conditions) 
     Reaction temperature (substrate temperature): 230° C., reactive gas: hydrogen gas 
     (Steps) 
     150 cycles were performed, with each cycle consisting of the series of steps shown in (1) to (4) below: 
     (1) Vapor from chemical vapor deposition material that has been vaporized at a material container heating temperature of 100° C. and a material container internal pressure of 100 Pa is introduced, and deposited for 30 seconds at a system pressure of 100 Pa; 
     (2) Unreacted material is removed by 5 seconds of argon purging; 
     (3) Reactive gas is introduced, and reacted for 30 seconds at a system pressure of 100 Pa; 
     (4) Unreacted material is removed by 5 seconds of argon purging. 
     The results of Examples 6 and 7 show that good quality metal cobalt thin films could be obtained in all cases. Particularly, in the case of using Compound Nos. 2, 3 and 4, it was possible to obtain metal cobalt thin films having a very low carbon content. 
     On the other hand, in Comparative Example 3, a smooth thin film could not be formed on the Cu substrate, and small lumps appeared scattered on the substrate. Moreover, the carbon content of the Co-containing material formed on the Cu substrate was 10 atom % or more, indicating that a good quality metal cobalt thin film could not be obtained. 
     The present international application claims priority from Japanese Patent Application No. 2015-044993 filed on Mar. 6, 2015, the full contents whereof are incorporated herein by reference.