Patent Publication Number: US-9837200-B2

Title: Micromagnetic device and method of forming the same

Description:
This application is a continuation of Ser. No. 14/105,461, entitled “Micromagnetic Device and Method Forming the Same,” filed on Dec. 13, 2013 which will issue on Mar. 29, 2016 as U.S. Pat. No. 9,299,489 which is a continuation of U.S. Pat. No. 8,618,900 (Ser. No. 13/722,797), entitled “Micromagnetic Device and Method Forming the Same,” filed on Dec. 20, 2012, which is a continuation of U.S. Pat. No. 8,339,232 (Ser. No. 13/076,034), entitled “Micromagnetic Device and Method of Forming the Same,” filed on Mar. 30, 2011, which is a continuation of U.S. Pat. No. 7,920,042 (Ser. No. 11/852,688), entitled “Micromagnetic Device and Method of Forming the Same,” filed on Sep. 10, 2007, which are incorporated herein by reference. 
    
    
     TECHNICAL FIELD 
     The invention is directed, in general, to magnetic devices and, more specifically, to a micromagnetic device, method of forming and power converter employing the same, and an electroplating tool and electrolyte employable for constructing a magnetic core layer of the micromagnetic device, and a method of processing a substrate and micromagnetic device. 
     BACKGROUND 
     A switch mode power converter (also referred to as a “power converter”) is a power supply or power processing circuit that converts an input voltage waveform into a specified output voltage waveform, which is typically a well-regulated voltage in electronic device applications. Power converters are frequently employed to power loads having tight voltage regulation characteristics such as a microprocessor with, for instance, a bias voltage of one volt or less provided by the power converter. To provide the voltage conversion and regulation functions, power converters include a reactive circuit element such as an inductor that is periodically switched to the input voltage waveform at a switching frequency that may be on the order of ten megahertz or more by an active switch such as a metal-oxide semiconductor field-effect transistor (“MOSFET”) that is coupled to the input voltage waveform. 
     A power converter configured to power an integrated circuit such as a microprocessor formed with submicron size features is generally referred to as a “point-of-load device,” and the integrated circuit is typically located close to the point-of-load power converter to limit voltage drop and losses in the conductors that couple the devices together. In such applications, a point-of-load power converter may be required to provide substantial current such as ten amperes or more to the integrated circuit. As current levels for integrated circuit loads continue to increase and the bias voltages decrease with on-going reductions in integrated-circuit feature sizes, the size of the power converter and its power conversion efficiency become important design considerations for product acceptance in challenging applications for emerging markets. 
     A recent development direction for reducing the size of point-of-load power converters has been to integrate the magnetic circuit elements therein, such as an isolation transformer or an output filter inductor, onto the same silicon substrate that is used to form the integrated control and switching functions of the power converter. These design directions have led to the development of micromagnetic devices with conductive and magnetic structures such as conductive windings and magnetic cores with micron-scaled dimensions to complement the similarly sized elements in logic and control circuits and in the power switches. The integrated magnetic circuit elements are therein produced with manufacturing processes and materials that are fully compatible with the processes and materials used to produce the corresponding semiconductor-based circuit components. The result of the device integration efforts has been to produce single-chip power converters including planar inductors and transformers capable of operation at the high switching frequencies that are necessary for point-of-load power converters to provide the necessary small physical dimensions. 
     As an example of a process to form a magnetic device that can be integrated onto a semiconductor substrate, Feygenson, et al. (“Feygenson”), in U.S. Pat. No. 6,440,750, entitled “Method of Making Integrated Circuit Having a Micromagnetic Device,” issued Aug. 27, 2002, which is incorporated herein by reference, describe a micromagnetic core formed on a semiconductor substrate by depositing Permalloy (typically 80% nickel and 20% iron) in the presence of a magnetic field. Dimensions of the core are designed using conformal mapping techniques. The magnetic field selectively orients the resulting magnetic domains in the micromagnetic core, thereby producing a magnetically anisotropic device with “easy” and “hard” directions of magnetization, and with corresponding reduction in magnetic core losses at high switching frequencies compared to an isotropic magnetic device. Feygenson further describes depositing a thin chromium and silver film to form a seed layer for further deposition of magnetic material to form a planar magnetic core by an electroplating process that has good adhesion to an insulating oxide layer that is formed on a semiconductor (or other suitable) substrate. The chromium and silver seed layer is etched with a cerric ammonium nitrate reagent without substantial effect on the magnetic alloy. 
     Filas, et al., in U.S. Pat. No. 6,624,498, entitled “Micromagnetic Device Having Alloy of Cobalt, Phosphorus and Iron,” issued Sep. 23, 2003, which is incorporated herein by reference, describe a planar micromagnetic device formed with a photoresist that is etched but retained between magnetic core and conductive copper layers. The micromagnetic device includes a planar magnetic core of an amorphous cobalt-phosphorous-iron alloy, wherein the fractions of cobalt and phosphorus are in the ranges of 5-15% and 13-20%, respectively, and iron being the remaining fraction. Magnetic saturation flux densities in the range of 10-20 Kilogauss (“kG”) are achievable, and low loss in the magnetic core structure is obtained by depositing multiple insulated magnetic layers, each with a thickness less than the skin depth at the switching frequency of the power converter [e.g., about 2.5 micrometers (“μm”) at 8 megahertz (“MHz”) for relative permeability of μ r =1000]. Thin seed layers of titanium and gold are deposited before performing an electroplating process for the magnetic core, and are oxidized and etched without substantial degradation of exposed adjacent conductive copper layers. The planar magnetic core is formed using an electroplating process in an electrolyte with pH about three containing ascorbic acid, sodium biphosphate, ammonium sulfate, cobalt sulfate, and ferrous sulfate. As described by Kossives, et al., in U.S. Pat. No. 6,649,422, entitled “Integrated Circuit Having a Micromagnetic Device and a Method of Manufacture Therefore,” issued Nov. 18, 2003, which is incorporated herein by reference, an integrated device formed on a semiconductor substrate includes a planar magnetic device, a transistor, and a capacitor so that the principal circuit elements of a power converter can be integrated onto a single semiconductor chip. 
     Thus, although substantial progress has been made in development of techniques for production of a highly integrated power converter that is formed on a single chip, these processes are not suitable for manufacturing an integrated micromagnetic device in substantial numbers and with the process yields and repeatability necessary to produce the reliability and cost for an end product. In particular, electrolytes for forming magnetic and conductive layers should have sufficient life for continued operation in an ongoing manufacturing environment. The electroplating processes should repeatably deposit uniformly thick layers of high-performance magnetic materials with consistent and predictable properties. In addition, the high-frequency ac properties of a micromagnetic core so deposited should exhibit low and repeatable core loss. Similarly, the conductive windings should exhibit low and repeatable high-frequency resistance. 
     Accordingly, what is needed in the art is a micromagnetic device and method of producing the same that can be manufactured in high volume and with low cost in a continuing production environment, the necessary electroplating tools and electrolytes therefor, and an electroplateable magnetic alloy with high performance magnetic characteristics at switching frequencies that may exceed one megahertz, that overcome the deficiencies in the prior art. In addition, the resulting micromagnetic device should be dimensionally stable with low internal stresses so that the micromagnetic device remains sufficiently planar to support further processing steps. 
     SUMMARY OF THE INVENTION 
     These and other problems are generally solved or circumvented, and technical advantages are generally achieved, by advantageous embodiments of a micromagnetic device and method of forming the same. In one embodiment, the micromagnetic device includes a first insulating layer formed above a substrate, a first seed layer formed above the first insulating layer, a first conductive winding layer selectively formed above the first seed layer, and a second insulating layer formed above the first conductive winding layer. The micromagnetic device also includes a first magnetic core layer formed above the second insulating layer, a third insulating layer formed above the first magnetic core layer, and a second magnetic core layer formed above the third insulating layer. The micromagnetic device still further includes a fourth insulating layer formed above the second magnetic core layer, a second seed layer formed above the fourth insulating layer, and a second conductive winding layer formed above the second seed layer and in vias to the first conductive winding layer. The first and second conductive winding layers form a winding for the micromagnetic device. 
     In another aspect, the micromagnetic device includes a first seed layer formed above a substrate, a first conductive winding layer selectively formed above the first seed layer, a first insulating layer formed above the first conductive winding layer, and a second seed layer formed above the first insulating layer. The micromagnetic device also includes a first magnetic core layer formed above the second seed layer, a first protective layer formed above the first magnetic core layer, a second insulating layer formed above the first protective layer, a third seed layer formed above the second insulating layer, a second magnetic core layer formed above the third seed layer, and a second protective layer formed above the second magnetic core layer. The micromagnetic device still further includes a third insulating layer formed above the second magnetic core layer, and a second conductive winding layer formed above the third insulating layer and in vias to the first conductive winding layer. The first and second conductive winding layers form a winding for the micromagnetic device. 
     The foregoing has outlined rather broadly the features and technical advantages of the invention in order that the detailed description of the invention that follows may be better understood. Additional features and advantages of the invention will be described hereinafter which form the subject of the claims of the invention. It should be appreciated by those skilled in the art that the conception and specific embodiment disclosed may be readily utilized as a basis for modifying or designing other structures or processes for carrying out the same purposes of the invention. It should also be realized by those skilled in the art that such equivalent constructions do not depart from the spirit and scope of the invention as set forth in the appended claims. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
       For a more complete understanding of the invention, reference is now made to the following descriptions taken in conjunction with the accompanying drawings, in which: 
         FIG. 1  illustrates a block diagram of an embodiment of a power converter constructed according to the principles of the present invention; 
         FIG. 2  illustrates a schematic diagram of an embodiment of a power train of a power converter constructed according to the principles of the present invention; 
         FIG. 3  illustrates a plan view of a micromagnetic device formed according to the principles of the present invention; 
         FIGS. 4 to 28  illustrate cross sectional views of a method of forming a micromagnetic device constructed according to the principles of the present invention; 
         FIG. 29  illustrates a cross sectional view of an embodiment of a micromagnetic device constructed according to the principles of the present invention; 
         FIG. 30  illustrates a scanning electron microscope view of a micromagnetic device constructed according to the principles of the present invention; 
         FIG. 31  illustrates a partial cross-sectional view of magnetic core layers of a magnetic core of a micromagnetic device constructed according to the principles of the present invention; 
         FIG. 32  illustrates an elevational view of an embodiment of an electroplating tool constructed according to the principles of the present invention; and 
         FIG. 33  illustrates a diagram of a portion of an embodiment of an electroplating tool constructed according to the principles of the present invention. 
     
    
    
     Corresponding numerals and symbols in the different figures generally refer to corresponding parts unless otherwise indicated, and may not be redescribed in the interest of brevity after the first instance. The figures are drawn to clearly illustrate the relevant aspects of the preferred embodiments. 
     DETAILED DESCRIPTION OF ILLUSTRATIVE EMBODIMENTS 
     The making and using of embodiments are discussed in detail below. It should be appreciated, however, that the invention provides many applicable inventive concepts that can be embodied in a wide variety of specific contexts. The specific embodiments discussed are merely illustrative of specific ways to make and use the invention, and do not limit the scope of the invention. 
     The invention will be described with respect to exemplary embodiments in a specific context, namely, a micromagnetic device, method of forming the same and a power converter employing the same. Additionally, an electroplating tool and electrolyte employable for constructing a magnetic core layer of the micromagnetic device will also be described herein. Also, a method of processing a substrate and micromagnetic device to relieve stress induced by a conductive film will be described herein. 
     Referring initially to  FIG. 1 , illustrated is a block diagram of an embodiment of a power converter including an integrated micromagnetic device constructed according to the principles of the invention. The power converter includes a power train  110  coupled to a source of electrical power (represented by a battery) for providing an input voltage V in  for the power converter. The power converter also includes a controller  120  and a driver  130 , and provides power to a system (not shown) such as a microprocessor coupled to an output thereof. The power train  110  may employ a buck converter topology as illustrated and described with respect to  FIG. 2  below. Of course, any number of converter topologies may benefit from the use of an integrated micromagnetic device constructed according to the principles of the invention and are well within the broad scope of the invention. 
     The power train  110  receives an input voltage V in  at an input thereof and provides a regulated output characteristic (e.g., an output voltage V out ) to power a microprocessor or other load coupled to an output of the power converter. The controller  120  may be coupled to a voltage reference representing a desired characteristic such as a desired system voltage from an internal or external source associated with the microprocessor, and to the output voltage V out  of the power converter. In accordance with the aforementioned characteristics, the controller  120  provides a signal S PWM  to control a duty cycle and a frequency of at least one power switch of the power train  110  to regulate the output voltage V out  or another characteristic thereof by periodically coupling the integrated magnetic device to the input voltage V in . 
     In accordance with the aforementioned characteristics, a drive signal(s) [e.g., a first gate drive signal PG with duty cycle D functional for a P-channel MOSFET (“PMOS”) power switch and a second gate drive signal NG with complementary duty cycle 1-D functional for a N-channel MOSFET (“NMOS”) power switch] is provided by the driver  130  to control a duty cycle and a frequency of one or more power switches of the power converter, preferably to regulate the output voltage V out  thereof. For a better understanding of power converters and related systems and components therein, see U.S. Pat. No. 7,038,438, entitled “Controller for a Power Converter and a Method of Controlling a Switch Thereof,” to Dwarakanath, et al., issued May 2, 2006, U.S. Pat. No. 7,019,505, entitled “Digital Controller for a Power Converter Employing Selectable Phases of a Clock Signal,” to Dwarakanath, et al., issued Mar. 28, 2006, U.S. Patent Application Publication No. 2005/0168203, entitled “Driver for a Power Converter and a Method of Driving a Switch Thereof,” to Dwarakanath, et al., published Aug. 4, 2005, U.S. Patent Application Publication No. 2005/0167756, entitled “Laterally Diffused Metal Oxide Semiconductor Device and Method of Forming the Same,” to Lotfi, et al., published Aug. 4, 2005 (now U.S. Pat. No. 7,230,203, issued Jun. 12, 2007), and U.S. Pat. No. 7,214,985, entitled “Integrated Circuit Incorporating Higher Voltage Devices and Low Voltage Devices Therein,” to Lotfi, et al., issued May 8, 2007, which are incorporated herein by reference. 
     Turning now to  FIG. 2 , illustrated is a schematic diagram of an embodiment of a power train of a power converter including an integrated micromagnetic device constructed according to the principles of the invention. While in the illustrated embodiment the power train employs a buck converter topology, those skilled in the art should understand that other converter topologies such as a forward converter topology or an active clamp topology are well within the broad scope of the invention. 
     The power train of the power converter receives an input voltage V in  (e.g., an unregulated input voltage) from a source of electrical power (represented by a battery) at an input thereof and provides a regulated output voltage V out  to power, for instance, a microprocessor at an output of the power converter. In keeping with the principles of a buck converter topology, the output voltage V out  is generally less than the input voltage V in  such that a switching operation of the power converter can regulate the output voltage V out . A main power switch Q main , (e.g., a PMOS switch) is enabled to conduct by a gate drive signal PG for a primary interval (generally co-existent with a duty cycle “D” of the main power switch Q main ,) and couples the input voltage V in  to an output filter inductor L out , which may be advantageously formed as a micromagnetic device. During the primary interval, an inductor current I Lout  flowing through the output filter inductor L out  increases as a current flows from the input to the output of the power train. An ac component of the inductor current I Lout  is filtered by an output capacitor C out . 
     During a complementary interval (generally co-existent with a complementary duty cycle “1-D” of the main power switch Q main ), the main power switch Q main  is transitioned to a non-conducting state and an auxiliary power switch Q aux  (e.g., an NMOS switch) is enabled to conduct by a gate drive signal NG. The auxiliary power switch Q aux  provides a path to maintain a continuity of the inductor current L out  flowing through the micromagnetic output filter inductor L out . During the complementary interval, the inductor current I Lout  through the output filter inductor L out  decreases. In general, the duty cycle of the main and auxiliary power switches Q main , Q aux  may be adjusted to maintain a regulation of the output voltage V out  of the power converter. Those skilled in the art should understand, however, that the conduction periods for the main and auxiliary power switches Q main , Q aux  may be separated by a small time interval to avoid cross conduction therebetween and beneficially to reduce the switching losses associated with the power converter. 
     Turning now to  FIG. 3 , illustrated is a plan view of a micromagnetic device formed according to the principles of the invention. The micromagnetic device illustrated herein is an inductor, such as the inductor L out  illustrated and described with reference to  FIG. 2 , that provides an inductance in the range 400-800 nanohenries (“nH”) and can conduct a current of approximately one ampere without substantially saturating the magnetic core thereof. The micromagnetic device is formed with a height of about 150 μm over a substrate such as a silicon substrate. In alternative embodiments, the substrate may be formed of glass, ceramic, or various semiconductor materials. 
     In an advantageous embodiment, the substrate is substantially nonconductive, wherein currents induced in the substrate by high-frequency electromagnetic fields produced by the micromagnetic device do not produce substantial losses in comparison with other parasitic losses inherent within the micromagnetic device. The magnetic and conductive layers of the micromagnetic device are constructed so that it can support a power converter switching frequency of 5-10 MHz without substantial loss in copper conductors or in magnetic core pieces. In an integrated point-of-load power converter to be described hereinbelow, the area of the micromagnetic device is roughly comparable to the area of the semiconductor power switches therein, such as the power switches Q main , Q aux  illustrated and described with reference to  FIG. 2 , and the associated integrated control circuits of a power converter employing the same. In an advantageous embodiment, the micromagnetic device is formed on a separate substrate from an integrated control circuit and the semiconductor power switches. It should be understood, however, that the micromagnetic device may be formed on the same substrate as power semiconductor switches and an integrated control circuit. In a related embodiment, the micromagnetic device may be formed over the semiconductor devices on the same substrate. 
     The micromagnetic device preferably includes iron-cobalt-phosphorus alloy magnetic core pieces  301 ,  302  and includes gaps  305 ,  306 . An exemplary iron-cobalt-phosphorous alloy will be described in more detail below. In the illustrated embodiment, the gaps  305 ,  306  are of length about 10 μm. A copper winding  307  encircles the magnetic core pieces  301 ,  302 . Terminal pads (such as first and second terminal pads  303 ,  304 ) provide an interconnection to the winding  307  for wire bonds or solder bumps. Three terminal pads are illustrated herein. 
     The second terminal pad  304  is coupled to and provides a terminal for the winding  307 . As illustrated in  FIG. 3 , the first terminal pad  303  is not coupled to the winding  307 , but provides a location for three-point mechanical support of the micromagnetic device. In an alternative embodiment, the first terminal pad  303  may be used to provide a tapped connection to the winding  307 , thereby forming a tapped inductor. A fourth terminal pad (not shown) may also be provided in the lower left-hand corner of the micromagnetic device so that the winding  307  may be separated into two dielectrically isolated portions to form an isolating transformer, wherein the top portion of the winding  307  is coupled to the top two terminal pads, and the bottom portion of the winding  307  is coupled to the bottom two terminal pads. A dotted line  308  illustrates the approximate location of an elevation view of the micromagnetic device that will be used in  FIGS. 4 to 28  to illustrate a method of forming the micromagnetic device. It should be understood that the dimensions illustrated with respect to the micromagnetic device of  FIG. 3  are provided for illustrative purposes only. 
     The sequence of steps to produce a micromagnetic device formed according to the principles of the invention will now be described. In the interest of brevity, the details of some processing steps well known in the art may not be included in the descriptive material below. For example, without limitation, cleaning steps such as using deionized water or a reactive ionizing chamber may not be described, generally being ordinary techniques well known in the art. The particular concentration of reagents, the exposure times for photoresists, general processing temperatures, current densities for electroplating processes, chamber operating pressures, chamber gas concentrations, radio frequencies to produce ionized gases, etc., are often ordinary techniques well-known in the art, and will not always be included in the description below. Similarly, alternative reagents and processing techniques to accomplish substantially the same result, for example, the substitution of chemical-vapor deposition for sputtering, etc., will not be identified for each processing step, and such substitutions are included within the broad scope of the invention. The dimensions and material compositions of the exemplary embodiment described below also may be altered in alternative designs to meet particular design objectives, and are included within the broad scope of the invention. 
     Turning now to  FIGS. 4 to 28 , illustrated are cross sectional views of a method of forming a micromagnetic device constructed according to the principles of the invention. Beginning with  FIG. 4 , illustrated is a substrate  401 , approximately 1 mm thick, formed from silicon. A first photoresist layer  404  is spun on to a top surface of the substrate  401  and patterned to form an aperture  407 , exposing thereby a portion of the substrate  401  for further processing. In the illustrated embodiment, photoresist AZ4330, such as available from AZ Electronic Materials USA Corp., Branchburg, N.J., is spun on using standard photolithography techniques to form a three μm thick patterned film. 
     Turning now to  FIG. 5 , a trench  410  is etched into the substrate  401  to form a depressed area about 50 μm deep that will accommodate a conductive winding layer, preferably copper, formed in a later processing step for a conductive winding. The trench  410  is formed using a deep reactive ion etch (“DRIE”) such as the Bosch process. The Bosch process, as is well known in the art, uses a sequence of gases such as sulfur hexafluoride (“SF 6 ”) followed by octofluorocyclobutane (“C 4 F 8 ”) to produce a highly anisotropic etching process that removes exposed portions of the substrate  401  at the bottom of the trench  410 . The width of the trench  410  illustrated in  FIG. 5  is about 465 μm, and the dimension of the trench  410  out of the plane of the FIGURE is about 70 μm. The first photoresist layer  404  is then removed using techniques well-known in the art. 
     Turning now to  FIG. 6 , an insulating layer [e.g., a thermal silicon dioxide (“SiO 2 ”) insulating layer] is deposited onto each side of the substrate  401 , including the trench  410 , as illustrated by first and second insulating layers  412 ,  414 . An alternative process for depositing an insulating layer can use a chemical vapor deposition process. In an advantageous embodiment, the thickness of the first and second insulating layers  412 ,  414  is about five μm on each side of the substrate  401 . The thickness of the first and second insulating layers  412 ,  414  affects residual mechanical stress due to differential thermal expansion of conductive, magnetic, and other layers during device processing steps. The removal of the first insulating layer  412  is a component affecting residual die stress after completion of micromagnetic device processing steps. The thickness of the first and second insulating layers  412 ,  414  can be adjusted using simulation or experimental techniques to produce a die with low residual mechanical stress after completion of micromagnetic device processing. 
     Turning now to  FIG. 7 , a first adhesive layer  415  of titanium (“Ti”) or chromium (“Cr”) is sputtered onto the top surface of the micromagnetic device above the second insulating layer  414 . Deposition of the first adhesive layer  415  is followed by deposition of a first seed layer  418  (e.g., gold or copper) for a later electroplating step. The first seed layer  418  forms a conductive layer onto which a winding will be deposited in a later processing step. The thickness of the first adhesive layer  415  is preferably about 200 angstroms (“A”), and the thickness of the overlying first seed layer  418  is preferably about 2000 Å. 
     Turning now to  FIG. 8 , a second photoresist layer  420  is deposited above the first seed layer  418 . The second photoresist layer  420  is spun on and patterned to form an aperture substantially above the trench  410 , exposing thereby a portion of the first seed layer  418  therebelow. In the illustrated embodiment, the second photoresist layer  420  is NR9 8000 from Futurrex Inc., of Franklin, N.J., and, using standard photolithography techniques, is spun on to produce about a 15 μm thick patterned film. 
     Turning now to  FIGS. 9 and 10 , a first conductive winding layer  423  to form a first winding section for the micromagnetic device is electroplated onto the exposed first seed layer  418 , preferably using an electrolyte and electroplating process as described later hereinbelow. In an advantageous embodiment, the first winding section is formed from copper. As illustrated in  FIG. 9 , the first conductive winding layer  423  is deposited up to and above the top surface of the second photoresist layer  420 . With respect to  FIG. 10 , the second photoresist layer  420  illustrated previously is stripped off a top surface of the micromagnetic device using conventional photoresist stripping techniques. 
     Turning now to  FIG. 11 , the top surface of the micromagnetic device is polished using a conventional chemical-mechanical polishing (“CMP”) process as is known in the art. The result of this process produces a substantially smooth and level surface on the top surface of the micromagnetic device exposing a top surface of the first conductive winding layer  423  and a portion of the second insulating layer  414 . 
     Turning now to  FIG. 12 , a second adhesive layer  425  (e.g., titanium or chromium, approximately 1000 Å thick) is sputtered onto the top surface of the micromagnetic device followed by a sputtered third insulating layer  430  (e.g., silicon dioxide) approximately 5000 Å thick. An alternative process for depositing the third insulating layer  430  uses a chemical vapor deposition process. 
     Turning now to  FIG. 13 , a third adhesive layer  433  of titanium or chromium, preferably 300 Å thick, is deposited by sputtering followed by a second seed layer  435  (e.g., gold or copper) that is 1000 Å thick. A third photoresist layer  440  is then deposited above the second seed layer  435  and patterned with standard photolithography techniques to form a 10 μm thick first photoresist aperture  445  therein exposing portions of the second seed layer  435 . The first photoresist aperture  445  is used to define a shape for a first magnetic core layer including an alloy such as an iron-cobalt alloy that is subsequently electroplated. In the illustrated embodiment, the third photoresist layer  440  is AZ9260 from AZ Electronic Materials USA Corp., Branchburg, N.J. 
     Turning now to  FIG. 14 , a first magnetic core layer  450  formed from an iron-cobalt alloy is electroplated through the first photoresist aperture  445  illustrated in  FIG. 13 . In this embodiment, the thickness of the iron-cobalt alloy is about six μm. Following the electroplating process for the iron-cobalt alloy, the substrate is rinsed with carbon dioxide (“CO 2 ”)-saturated, de-ionized water and immersed in an electrolyte (e.g., a nickel electrolyte) to form a first protective layer  455  (e.g., a thin nickel protective layer at about 250-300 Å) over the first magnetic core layer  450 . 
     Turning now to  FIG. 15 , the third photoresist layer  440  is stripped off the top surface of the micromagnetic device using conventional photoresist stripping techniques. A fourth adhesive layer  457  of titanium or chromium is deposited onto the first protective layer  455 , followed by a sputter-deposited fourth insulating layer  460  of aluminum oxide or silicon dioxide at about 500 Å. 
     Turning now to  FIG. 16 , preparation for a second magnetic core layer of an iron-cobalt alloy electroplating process begins with the sputter deposition of a fifth adhesive layer  462  followed by a third seed layer  464  of gold or copper, preferably similar to those used under the first magnetic core layer  450  (e.g., 300 Å of titanium or chromium followed by 1000 Å of gold or copper). A fourth photoresist layer  465  is deposited above the third seed layer  464  and patterned with standard photolithographic techniques to form a 15 μm thick second photoresist aperture  467  employable to define a shape of the second magnetic core layer that is to be electroplated thereabout. The second photoresist aperture  467  exposes the third seed layer  464 . In the illustrated embodiment, the fourth photoresist layer  465  is AZ9260 from AZ Electronic Materials USA Corp., Branchburg, N.J. 
     Turning now on  FIGS. 17 and 18 , a second magnetic core layer  470  of an iron-cobalt alloy is electroplated through the second photoresist aperture onto the third seed layer  464 . In the illustrated embodiment, the thickness of the iron-cobalt alloy is about six μm. Following the electroplating process for the iron-cobalt alloy, the substrate is rinsed with carbon dioxide (“CO 2 ”)-saturated, de-ionized water and immersed in an electrolyte (e.g., a nickel electrolyte) to form a second protective layer  472  (e.g., a thin nickel protective layer at about 250-300 Å) over the second magnetic core layer  470 . With respect to  FIG. 18 , the fourth photoresist layer  465  is stripped off the top surface of the micromagnetic device using conventional photoresist stripping techniques. While the illustrated embodiment includes two magnetic core layers, it should be understood that the aforementioned process may be repeated any number of times to provide the desired number of magnetic core layers as dictated by a particular application. 
     Turning now to  FIG. 19 , a sixth adhesive layer  474  (e.g., titanium or chromium at about 300 Å) is deposited by sputtering over the surface of the micromagnetic device. The sixth adhesive layer  474  is followed by sputter-deposition of a fifth insulating layer  476  over the top surface of the sixth adhesive layer  474  at approximately 5000 Å thick. The fifth insulating layer  476  includes aluminum oxide or silicon dioxide at about 500 Å, an insulation polymer, a photoresist, or polyimide. An alternative process for depositing a silicon dioxide or other insulating layer uses a chemical-vapor deposition process. 
     Thus, the first and second magnetic core layers  450 ,  470  are electroplated between the third and fifth insulating layers  430 ,  476 . The iron-cobalt alloy magnetic core layers preferably alternate with layers of nickel, an adhesion layer, an insulation layer, a further adhesion layer, and a seed layer. An exemplary thickness of the iron-cobalt alloy layers is six μm, which is approximately one skin depth for a switching frequency of 10 MHz. The thickness of the iron-cobalt alloy layers is typically constrained to be relatively thin such as six μm to reduce core loss due to induced currents in these magnetically permeable and electrically conductive layers at the switching frequency of a power converter or other end product. In an exemplary design, six magnetic core layers are deposited with five interposed insulating layers, etc. 
     Turning now to  FIG. 20 , vias  478  are opened through the micromagnetic device to the first conductive winding layer  423 . The vias  478  are formed by depositing a photoresist such as AZ4620, by AZ Electronic Materials USA Corp., Branchburg, N.J., by spinning, curing, patterning, and processing to expose apertures to down through the second adhesive layer  425  and the third insulating layer  430 . The exposed portions of the micromagnetic device are then etched down to the first winding section  423  using a buffered oxide etch, which is typically a blend of 49% hydrofluoric acid (“HF”) and 40% ammonium fluoride (“NH 4 F”) in various predetermined ratios, after cleaning the substrate with deionized water, using techniques well known in the art. 
     Turning now to  FIG. 21 , a seventh adhesive layer  480  (e.g., titanium or chromium) followed by a fourth seed layer  482  are deposited across the top surface of the micromagnetic device onto which a conductive layer thereof will be electrodeposited in a later processing step. The fourth seed layer  482  is formed by sequentially sputtering thin sublayers of gold (at about 500 Å) and/or copper (at about 2000 Å). 
     Turning now to  FIG. 22 , a fifth photoresist layer  484  is deposited above the fourth seed layer  482 . The fifth photoresist layer  484  is spun on and patterned to form apertures for a conductive layer to be electrodeposited in a later processing step that forms a portion of a winding of the micromagnetic device. In the illustrated embodiment, the fifth photoresist layer  484  is AZ4620, by AZ Electronic Materials USA Corp., Branchburg, N.J. and is spun on and soft baked using a multi-spin/single exposure technique to produce a 50 μm thick photoresist film. The first spin is followed by a soft bake at 80° C. on a hot plate for approximately five minutes. Then a second layer of photoresist is spun on and a second bake at 120° C. for five minutes is performed to outgas solvents therefrom. Then an ultraviolet exposure and a developing step define the top conductive patterns in the fifth photoresist layer  484 . 
     Turning now to  FIG. 23 , a second conductive winding layer  486  of the micromagnetic device is electrodeposited over the fourth seed layer  482  to form a second winding section. In an advantageous embodiment, the second winding section  486  is formed from copper. The electrodeposition process is preferably performed using an electrolyte as described below. The first and second winding sections form a winding for the micromagnetic device. 
     Turning now to  FIG. 24 , the fifth photoresist layer  484  is stripped off the top surface of the micromagnetic device using conventional photoresist stripping techniques, exposing portions of the fourth seed layer  482  previously covered by the fifth photoresist layer  484 . Thereafter, exposed portions of the fourth seed layer  482  are removed via a sulfuric acid etch and exposed portions of the seventh adhesive layer  480  are removed via a hydrofluoric acid etch. 
     Turning now to  FIG. 25 , an eighth adhesive layer  488  of titanium is sputtered onto the top surface of the micromagnetic device at about 2000 Å. The eighth adhesive layer  488 , after etching, will provide a mechanical base for a solder-ball capture in a later processing step. 
     Turning now to  FIG. 26 , a photoresist layer (not shown) is deposited over the eighth adhesive layer  488 . The photoresist layer is spun on and patterned using conventional processing techniques to expose portions of the eighth adhesive layer  488  that are then removed by etching to form apertures for solder balls or other interconnect to be deposited in a later processing step. In this exemplary embodiment, the photoresist layer is AZ4400 from AZ Electronic Materials USA Corp., Branchburg, N.J. After forming the apertures in the photoresist layer, the exposed portions of the underlying eighth adhesive layer  488  are etched down to the second winding section  486  using a hydrofluoric acid etch. The result is to produce apertures  490  for solder balls in the eighth adhesive layer  488 . 
     Turning now to  FIG. 27 , the first insulating layer  412  is removed by backgrinding, using techniques well understood in the art. The original thickness of the substrate  401  was about one mm, which is now ground down to approximately 200 μm to accommodate thinner packaging and improved heat transfer of the micromagnetic device. In the backgrinding process, the layer of silicon dioxide, which forms the first insulating layer  412 , is removed with an adjoining portion of the substrate  401 . The process of thinning the substrate  401  and removing the first insulating layer  412  is a stress-relieving step that accommodates and relieves a substantial portion of the strain that inherently results from previous processing steps that deposited the conductive and magnetic alloy structures for the micromagnetic device. 
     Turning now to  FIG. 28 , interconnects  495  (e.g., solder balls) for later interconnection of the micromagnetic device to external circuitry are dropped into the apertures  490  that were formed in the eighth adhesive layer  488 . In an advantageous embodiment, the solder balls  495  are lead-free. The solder balls  495  may be placed by positioning a mask on the top surface of the micromagnetic device. The mask is formed with appropriately sized and located apertures that are above the desired solder-ball locations. A quantity of solder balls  495  is poured onto the mask, and the assembly is shaken to cause the solder balls  495  to drop into the mask apertures. The remaining solder balls  495  are poured off. In an alternative process, solder balls  495  may be placed using a placing mechanism employing a vacuum-operated ball-placing tool. As a further alternative for later interconnection of the micromagnetic device, a solder layer can be deposited into the apertures  490  formed in the eighth adhesive layer  488  using an electroplating process.  FIG. 28  also illustrates sawing lines (e.g., sawing line location  497 ) for die singulation as necessary. 
     Turning now to  FIG. 29 , illustrated is a cross sectional view of an embodiment of a micromagnetic device constructed according to the principles of the present invention. In the present embodiment, some layers have been omitted or combined into a single layer for purposes of illustration. The micromagnetic device is formed on a substrate  505  (e.g., silicon) and includes a first insulating layer  510  (e.g., silicon dioxide) formed thereover. Following an electroplating process to form a trench in a center region of the substrate  505 , an adhesive layer (e.g., titanium or chromium) and a first seed layer  515  (e.g., gold or copper) are formed over the first insulating layer  510 . Additionally, a first conductive winding layer  520  of, without limitation, copper, is formed in the trench that forms a first section of a winding for the micromagnetic device. 
     An adhesive layer (e.g., titanium or chromium) and a second insulating layer  525  (e.g., silicon dioxide) is formed above the first conductive winding layer  520 . The micromagnetic device also includes first and second magnetic core layers  530 ,  540  with a third insulating layer  535  therebetween in a center region of the substrate  505  above the first conductive winding layer  520 . The first and second magnetic core layers  530 ,  540  are typically surrounded by an adhesive layer, seed layer and protection layer as set forth below with respect to  FIG. 31 . Also, an adhesive layer may be formed prior to forming the third insulating layer  535 . 
     An adhesive layer (e.g., titanium or chromium) and a fourth insulating layer  545  (e.g., silicon dioxide) are formed above the second magnetic core layer  540  in the center region of the substrate  505  and over the second insulating layer  525  laterally beyond the center region of the substrate  505 . An adhesive layer (e.g., titanium or chromium) and a second seed layer  550  (e.g., gold or copper) are formed above the fourth insulating layer  545  in the center region of the substrate  505  and in vias down to the first conductive winding layer  520  about the center region of the substrate  505 . A second conductive winding layer  555  is formed above the second seed layer  550  and in the vias to the first conductive winding layer  520 . The second conductive winding layer  555  is formed of, without limitation, copper and forms a second section of a winding for the micromagnetic device. Thus, the first conductive winding layer  520  and the second conductive winding layer  555  form the winding for the micromagnetic device. 
     An adhesive layer  560  (e.g., titanium) is formed above the second conductive winding layer  555  in the center region of the substrate  505  and over the fourth insulating layer  545  laterally beyond the center region of the substrate  505 . Solder balls  565  are formed in apertures in the adhesive layer  560 . 
     Turning now to  FIG. 30 , illustrated is a scanning electron microscope view of a micromagnetic device (e.g., an inductor) constructed according to the principles of the invention. The inductor is formed with a layered magnetic core  610  on a silicon substrate  620 . An air gap  630  of length 10 μm between the magnetic core sections is visible in the microphotograph. A copper conductive winding  640  is formed around the layered magnetic core  610 . A 200 μm scale is visible in the lower portion of the microphotograph to provide a reference for feature sizes. Although the formation of a micromagnetic device has been described herein using an iron-cobalt alloy, in an advantageous embodiment, the micromagnetic device employs other materials such as an iron-cobalt-phosphorus alloy as described below. 
     Turing now to  FIG. 31 , illustrated is a partial cross-sectional view of magnetic core layers of a magnetic core of a micromagnetic device constructed according to the principles of the present invention. As mentioned above, while the present embodiment illustrates two magnetic core layers, the principles of the present invention are not so limited. The first and second magnetic core layers (designated “Layer 1” and “Layer 2”) include an adhesion layer (designated “Adhesive Layer”) of, without limitation, titanium or chromium and a seed layer (designed “Seed Layer”) of, without limitation, gold or copper. The first and second magnetic core layers also include a magnetic core layer (designated “Magnetic Core Layer”) of, without limitation, an iron-cobalt-phosphorus alloy and a protective layer (designated “Protective Layer”) of, without limitation, nickel. First and second insulating layers (designated “Insulating Layer 1” and “Insulating Layer 2”) include an adhesion layer (designated “Adhesive Layer”) of, without limitation, titanium or chromium and an insulting layer (designated “Insulating Layer”) of, without limitation, silicon dioxide or aluminum oxide. The sequence of magnetic core layers and insulation layers can be repeated as needed to form the desired number of magnetic core layers. 
     Thus, a sequence of steps has been introduced for forming a micromagnetic device with improved magnetic characteristics using processes that readily accommodate high-volume production. Although the exemplary device that was described with reference to  FIG. 4 , et seq., is an inductor, straightforward alterations to the process can be readily made by one with ordinary skill in the art to form a transformer with dielectrically isolated windings. 
     In an exemplary embodiment, the micromagnetic device is formed on a substrate and includes a first insulating layer (e.g., silicon dioxide) formed above the substrate (e.g., silicon), and a first seed layer (e.g., gold or copper) formed above the first insulating layer. The micromagnetic device also includes a first conductive winding layer (e.g., gold) selectively formed above the first seed layer, a second insulating layer (e.g., silicon dioxide) formed above the first conductive winding layer, and a first magnetic core layer (e.g., iron-cobalt alloy or an iron-cobalt-phosphorus alloy) formed above the second insulating layer. Thereabove, the micromagnetic device includes a second magnetic core layer (e.g., iron-cobalt alloy or an iron-cobalt-phosphorus alloy) formed between third and fourth insulating layers (e.g., aluminum oxide, silicon dioxide, insulation polymer, photoresist or polyimide). The micromagnetic device further includes a second seed layer (e.g., sublayers of gold and copper) formed above the fourth insulating layer, and a second conductive winding layer (e.g., gold) formed above the second seed layer and in vias to the first conductive winding layer. The first conductive winding layer and the second conductive winding layer form a winding for the micromagnetic device. In an advantageous embodiment, a protective layer (e.g., nickel) may be formed above the first and second magnetic core layers. Additionally, an interconnect (e.g., solder balls) may be formed in an aperture of an adhesive layer formed above the second conductive winding layer. Having introduced an exemplary micromagnetic device, method of forming the same and a power converter employing the same, we will now turn our attention to an electroplating tool and electrolyte employable for constructing the micromagnetic device. 
     Regarding the magnetic core layers, to provide an alloy with magnetic properties improved over alloys currently available, a ternary alloy including iron, cobalt, and phosphorous is introduced. The iron-cobalt-phosphorous (“FeCoP”) alloy includes cobalt in the range of 1.8-4.5 atomic percent (e.g., preferably 2.5 percent), phosphorus in the range of 20.1-30 atomic percent (e.g., preferably 22 percent), and iron including substantially the remaining proportion. The alloy preferably includes trace amounts of sulfur, vanadium, tungsten, copper, and/or combinations thereof, with a concentration of each in the range of 1 to 100 parts per million (“ppm”), to reduce stress and/or increase resistivity compared to the basic ternary alloy without these trace elements. In the past, iron-cobalt-phosphorous alloys used higher proportions of cobalt (e.g., 5-15 atomic percent), and lower proportions of phosphorous (e.g., 13-20 atomic percent), which do not provide the advantageous high-frequency magnetic characteristics and other properties as described herein. 
     An iron-cobalt-phosphorous alloy employable with the magnetic core layers of  FIG. 4 , et seq., advantageously sustains a magnetic saturation flux density of about 1.5-1.7 tesla (15,000-17,000 gauss), and accommodates a power converter switching frequency of, without limitation, 10 MHz with low loss when electroplated in layers four μm thick, each layer separated by a thin insulation layer (e.g., aluminum oxide and/or silicon dioxide). In comparison, soft ferrites of the past commonly used in the design of switch-mode power converters typically sustain a magnetic saturation flux density of only about 0.3 tesla. The iron-cobalt-phosphorous alloy described herein is readily adaptable to a repeatable and continuing manufacturing process, and can provide long operational life in a typical application environment without substantial degradation of operating characteristics. The iron-cobalt-phosphorous alloy can be electroplated with a sufficiently high current density to accommodate a low-cost manufacturing operation. The iron-cobalt-phosphorous alloy can be readily electroplated in alternating layers with intervening insulating layers onto a surface patterned, such as with a photoresist, to produce a micromagnetic device operable at a high switching frequency with a low level of power dissipation. 
     Thus, a micromagnetic device formed with a ternary alloy with magnetic properties improved over those currently available, and related method, have been introduced herein formed over a substrate (e.g., silicon, glass, ceramic). In an advantageous embodiment, the new ternary alloy includes iron, cobalt and phosphorous and the magnetic alloy is an amorphous or nanocrystalline magnetic alloy. 
     In one embodiment, the micromagnetic device includes a substrate and a magnetic core layer formed over the substrate from a magnetic alloy. The micromagnetic device also includes an insulating layer formed over the magnetic core layer and another magnetic core layer formed over the insulating layer from a magnetic alloy. At least one of the magnetic alloys include iron, cobalt and phosphorous and a content of said cobalt is in the range of 1.8 to 4.5 atomic percent, a content of said phosphorus is in the range of 20.1 to 30 atomic percent, and a content of said iron is substantially a remaining proportion of said at least one of said magnetic alloys. 
     Turning now to  FIG. 32 , illustrated is an elevational view of an embodiment of an electroplating tool constructed according to the principles of the invention. An electrolyte employable in the electroplating tool is adaptable for the deposition of a magnetic alloy including ones of iron, cobalt and phosphorus with advantageous magnetic properties as described below. The electroplating tool includes an electroplating cell  705  supplied with an electrolyte  710  from a reservoir  715 . The reservoir  715  contains the electrolyte  710  with chemical composition including phosphorous as described below. In the embodiment represented in  FIG. 32 , the combined volume of the electrolyte  710  in the electroplating cell  705  and the reservoir  715  is approximately 90 liters. The electrolyte  710  is pumped by a first circulating pump  720  from the reservoir  715  through a first tube  725  to the electroplating cell  705 , the flow of which is adjusted or regulated by first and second valves  727 ,  729 . The electrolyte  710  supplied by the first circulating pump  720  flows through nozzles  730  into the electroplating cell  705  at a high flow rate to provide electrolyte agitation for electroplating uniformity. In an advantageous embodiment wherein a wafer (e.g., a six inch silicon wafer) is electroplated with a magnetic alloy, the flow rate of electrolyte  710  through apertures in the nozzles  730  is adjusted to approximately 120 liters per minute. The height of the electrolyte  710  in the electroplating cell  705  is controlled by a partition  735  over which excess electrolyte  710  flows behind a wall  740 , and is returned to the reservoir  715  through a second tube  745 . 
     The electrolyte  710  supplied to the electroplating cell  705  from the reservoir  715  through the first and second valves  727 ,  729  is dispersed through the electrolyte  710  already contained within the electroplating cell  705  through the nozzles  730 . In an advantageous embodiment, the nozzles  730  include apertures (e.g., apertures similar to apertures in an ordinary bathroom shower head) angularly disposed in six lines of apertures oriented 60° apart. 
     Although the reservoir  715  and the electroplating cell  705  are fitted with covers that can be opened to provide interior access, the reservoir  715  and the electroplating cell  705  are typically closed and substantially sealed to the outside atmosphere during an electroplating process. Lying in a lower position in the electroplating cell  705  and in reservoir  715  are first and second porous tubes  750 ,  752 , respectively, through which an inert gas (e.g., nitrogen) flows from an inert gas source (e.g., a nitrogen source) during an electroplating operation. Small bubbles  755  (e.g., bubbles of nitrogen) are formed on the outer surface areas of the first and second porous tubes  750 ,  752  and are dispersed throughout the electrolyte  710  in each container. Oxygen in upper portions  755 ,  760 , respectively, of the electroplating cell  705  and the reservoir  715  is thereby exhausted to the outside atmosphere. By this means, the electrolyte  710  in the electroplating cell  705  and the reservoir  715  becomes substantially oxygen free, sustaining a dissolved oxygen level less than ten ppb during an electroplating operation. 
     An anode  765  immersed for the electroplating process in the electrolyte  710  is advantageously formed with an alloy of about four atomic percent cobalt and 96 atomic percent iron. A wafer or substrate  770  onto which the magnetic alloy is electroplated, is mounted on a magnet  775  which is rotated at a rotational rate, such as 100 revolutions per minute (“rpm”), by a motor  780 . Rotation of the wafer  770  during the electroplating process advantageously provides uniformity of coverage of the electroplated alloy thereon. The magnet  775  provides a magnetic field of approximately 1000-2000 gauss to orient the easy axis of magnetization of the electroplated material, forming thereby a magnetically anisotropic layer. The magnet  775  in the representation illustrated in  FIG. 32  includes a rare earth permanent magnet. In an alternative advantageous arrangement, the magnet  775  includes a current-carrying coil. 
     To maintain cleanliness during the electroplating process of the electrolyte  710  contained in the electroplating cell  705  and in the reservoir  715 , the electrolyte  710  in the reservoir  715  is recirculated by a second circulating pump  785  through a microporous filter  787 . In an advantageous arrangement, the microporous filter  787  is a 0.2 μm filter or better. To further maintain electrolyte  710  cleanliness during the electroplating process, metallic and other microscopic particles that slough off the anode  765  are captured by encasing the anode  765  within an envelope of a semipermeable membrane (see below). The filtered electrolyte  710  from the microporous filter  787  flows into the electroplating cell  705  and reservoir  715  through a third tube  790 . Additionally, the proper pH is maintained by including pH-sensing electrode(s)  792  in the electroplating cell  705  and/or the reservoir  715  and adding acid, for example, 12% perchloric acid (“HClO 4 ”), or base, as needed, with a metering pump control assembly  794  (e.g., including a controller and a meter pump such as an Replenisher Model REPL50-5-B by Ivek Corporation of North Springfield, Vt.) to the electroplating cell  705  (via a fourth tube  796 ) and/or the reservoir  715  (via a fifth tube  798 ) when the sensed pH rises above a threshold level. 
     Turning now to  FIG. 33 , illustrated is a diagram of a portion of an embodiment of an electroplating tool constructed according to the principles of the present invention. The present embodiment illustrates an anode  810  immersed in an electrolyte  820  and contained within semipermeable membrane  830  in accordance with an electroplating tool constructed according to the principles of the invention. The filtered electrolyte  820  from a microporous filter (see  FIG. 32 ) flows into the volume contained by the semipermeable membrane  830  through a first tube  840  and is returned filtered to a reservoir (see  FIG. 32 ) through a second tube  850  and filter  860 . In an advantageous embodiment, the filter  860  includes a 0.2 μm filter or better. The cleanliness of electrolyte  820  in close proximity to a wafer (see  FIG. 32 ) during a continued electroplating operation is thereby preserved. 
     Several characteristics of the electroplating process are advantageously employed to form a uniformly electroplated layer of a magnetic alloy such as iron-cobalt-phosphorous alloy onto a surface of a wafer. First, a sufficiently high flow rate of the electrolyte is provided through apertures in the nozzles to provide agitation of the electrolyte in the electroplating cell (e.g., 120 liters per minute for a six inch wafer) such as by using a circulating pump (e.g., Baldor Model CL 3506 pump by Baldor Electric Company of Fort Smith, Ark.). Second, the wafer is rotated (e.g., at 100 rpm) with a Leeson Model 985-616 D motor drive and a Leeson Speedmaster Controller Model 1740102.00 by Leeson Electric Corporation of Grafton, Wis., onto which the electrolyte is electroplated to provide uniformity of electroplating coverage. Third, a sufficiently low level of dissolved oxygen in the electrolyte is maintained to prevent oxidation of metallic species and other oxidizable electrolyte components. A mechanism to maintain a low level of dissolved oxygen is the bubbling of nitrogen (or other gas inert to chemical species in the electroplating process) through the electrolyte to drive out residual dissolved oxygen. The dissolved oxygen level can be monitored with a dissolved oxygen sensor, a monitoring process well known in the art, and the electroplating process can be interrupted when the dissolved oxygen level exceeds, for example, 10 parts per billion (“ppb”). Fourth, the pH level of the electrolyte may be maintained below a level of, for instance, about three and preferably between about two and three. The proper pH is maintained by including pH-sensing electrodes in the electroplating cell and/or the reservoir (see  FIG. 32 ), and adding acid, for example, 12% perchloric acid (“HClO 4 ”), or base, as needed, with metering pumps to the electroplating cell and/or the reservoir when the sensed pH rises above a threshold level. During an ordinary electroplating process, the pH of the electrolyte increases, requiring continued addition of acid to maintain a particular pH level. 
     A fifth characteristic includes filtering the electrolyte in the reservoir at a sufficiently high rate with a microporous filter, such as a 0.2 μm filter or better, to remove microscopic particles produced by the electroplating process such that a complete turn of the electrolyte volume in the electroplating cell and the reservoir may be one minute or less. Sixth, an anode should be provided of an iron-cobalt alloy, preferably about four atomic percent cobalt and 96 atomic percent iron alloy circular anode (e.g., an anode with about 130 millimeter diameter and 10 millimeter thick from Sophisticated Alloys, Inc. of Butler, Pa. Seventh, the anode should be enclosed within a semipermeable membrane in the electroplating cell and the electrolyte should be filtered inside the volume contained by the semipermeable membrane with a 0.2 μm filter or better, to prevent contamination of the electrolyte in the vicinity of the wafer being electroplated. 
     Thus, an electroplating tool and related method have been introduced that accommodate electroplating onto a wafer a magnetically anisotropic layer that can sustain a high magnetic field density without saturation and with low power dissipation at a high excitation frequency, the magnetically anisotropic layer advantageously including an iron-cobalt-phosphorous alloy. The process can produce an electroplated layer of an alloy such as an iron-cobalt-phosphorous alloy with minimal variability over the wafer surface, and can sustain continued and repeatable operation in a manufacturing environment. 
     In an advantageous embodiment, the electroplating tool includes a reservoir having a cover configured to substantially seal the reservoir to an outside atmosphere during an electroplating process, and a porous tube couplable to an inert gas source configured to bubble an inert gas through an electrolyte containable therein. The electroplating tool also includes an electroplating cell, coupled to the reservoir, having another cover configured to substantially seal the electroplating cell to an outside atmosphere during an electroplating process, and another porous tube couplable to an inert gas source configured to bubble an inert gas through an electrolyte containable therein. The electroplating cell also includes an anode, encased in an envelope of a semipermeable membrane, formed with an alloy of electroplating material, and a magnet configured to orient an axis of magnetization of the electroplating material for application to a wafer couplable thereto during an electroplating process. The electroplating tool further includes a circulating pump coupled through a tube with a valve to the electroplating cell and the reservoir. The circulating pump is configured to pump the electrolyte at a flow rate from the reservoir through the tube to the electroplating cell through nozzles therein. The electroplating tool still further includes another circulating pump and microporous filter coupled through a tube to the electroplating cell and the reservoir. The another circulating pump is configured to pump the electrolyte through the microporous filter from the reservoir through the tube to the electroplating cell and the reservoir. 
     The electrolyte chemistry and procedures to support electroplating a magnetic alloy such as an iron-cobalt-phosphorous alloy will now be described. Additions to the material formulations described below to provide further enhanced properties are contemplated and can be readily made within the broad scope of the invention. 
     In electrolytes of the prior art employed to electroplate a magnetic alloy such as Permalloy, the iron, cobalt, and other electrolyte components include aqueous sulfates with pH of approximately three, are not buffered, and utilize an iron anode. The electrolyte as described herein includes aqueous perchlorates of iron, cobalt, and other electrolyte components, with a pH of approximately two, is preferably buffered, and uses an iron-cobalt alloy anode. In an advantageous embodiment, the pH is buffered in the range of about two to three, and preferably less than about three. Other improvements of the electrolyte include neutralizing excess acid therein with ammonium bicarbonate, and using a higher current density during an electroplating operation. 
     While the electrolytes of the prior art are unstable with continued use, the electrolyte as described herein is more robust. Higher electroplating rates are possible using the electrolyte as described herein, and are reproducible from substrate to substrate, which is not the case using electrolytes of the prior art. By using an iron-cobalt alloy anode as described herein, the cobalt in the electrolyte is continuously replenished. Phosphorus is replenished by adding electrolyte containing a phosphorous salt as described below. 
     Preparation of an exemplary 30-liter perchlorate electrolyte for an iron-cobalt-phosphorous ternary alloy will now be described. The electrolyte can be modified to add, without limitation, any or all of a trace amount (e.g., less than about 10 millimolar) of elements such as sulfur, vanadium, tungsten, and copper. 
     The electrolyte (e.g., 24 liters (“L”) of water) is first deoxygenated by bubbling nitrogen for 15-30 minutes. Chemicals are then added preferably in the order given below. An iron perchlorate is preferably ground into a powder before adding to a mixing tank since it is usually lumpy as received from a vendor in bulk form. Since the iron in solution is air sensitive, the solution should be prepared and stored under a nitrogen or other atmosphere inert to the chemical constituents. A polyethylene mixing tank with a recirculating pump and 0.2-μm or better filter may be used in an advantageous embodiment of the invention. 
     In an exemplary embodiment, the materials as listed below in Table I include components to produce 30 L of electrolyte. 
     
       
         
           
               
               
               
               
             
               
                   
                 TABLE I 
               
               
                   
                   
               
               
                   
                 CHEMICAL 
                 GRAMS TO MAKE 30 L 
                 pH 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
            
               
                   
                 Water, N 2   
                 24 kg (liters) 
                 ~7.0 
               
               
                   
                 Ascorbic Acid 
                 0.01M → 52.84 g  
                 3.13 
               
               
                   
                 Sodium Hypophosphite 
                 0.08M → 254.38 g 
                 3.07 
               
               
                   
                 NaH 2 PO 2 •H 2 O 
               
               
                   
                 Ammonium Perchlorate 
                 0.50M → 1762.5 g 
                 2.87 
               
               
                   
                 (NH 4 )ClO 4   
               
               
                   
                 Ferrous Perchlorate 
                 0.65M → 7075.4 g 
                 0.60 
               
               
                   
                 Fe(ClO 4 ) 2 •6H 2 O 
               
               
                   
                 Cobalt Perchlorate 
                 0.006M → 66.01 g  
                 0.60 
               
               
                   
                 CoClO 4 •6H 2 O 
               
               
                   
                   
               
            
           
         
       
     
     Due to excess perchloric acid in the (hydrated) ferrous perchlorate, the acid should be neutralized to raise the pH. Raising the pH should be done slowly to avoid precipitation of iron hydroxides and oxidation to ferric iron. In general, the pH should be kept less than about three. Ammonium bicarbonate solution (e.g., 150 grams/L) is added drop-wise with vigorous stirring under nitrogen or other inert atmosphere. A white precipitate may form when the neutralizing solution comes in contact with the electrolyte, but if agitation is sufficient, it immediately redissolves without detrimental effect. A metering pump is preferably used to add the neutralizing solution. The pump rate is initially set at about 10 milliliters (“ml”) per minute. 
     A pH meter is used to monitor the pH in the mixing tank. The glass electrode of the pH meter often requires changing the supporting electrolyte therein from saturated potassium chloride (“KCl”) to one molar ammonium perchlorate. Failure to follow this procedure will generally result in inaccurate pH readings. The meter is preferably calibrated with pH equaling one and two buffers with measurement to an accuracy of 0.01 unit. The pH rises slowly at first, then more rapidly when the pH is above one. When the pH reaches a target value of 1.95, water is added to bring the volume to 30 L. 
     Some brown precipitate remains in the solution in the mixing tank from impurities in the iron perchlorate, but it can be removed by filtering in an hour or less, depending on the pump rate in the mixing tank. The solution can be monitored spectrophotometrically to check for suspended particles and their concentrations. For example, at 400 nanometers (“nm”), an unfiltered solution (one centimeter path length) has a baseline absorbance of A=0.0400, and after filtering, A=0.0046. Iron is kept in the ferrous state by ascorbic acid, which needs periodic monitoring. A Hach ascorbic acid test kit can be used to determine the ascorbic acid concentration. The ascorbic acid absorbs strongly below 300 nm, and a convenient measure of the “health” of the electrolyte is the “wavelength cutoff,” λc, defined as the wavelength at which the absorption of a one centimeter cm path is one. A newly prepared solution has λc=291 nm and, as the solution ages, the wavelength cutoff moves to longer wavelengths. As long as λc&lt;300 nm and the ascorbic acid concentration is 0.01 M, the electrolyte should be useable. Without a nitrogen atmosphere, ascorbic acid and iron oxidize, and the wavelength cutoff shifts into the visible range rapidly. 
     For unpatterned substrates (i.e., for substrates that have not been patterned and processed with a photoresist), conditions for good electroplating results with vigorous electrolyte agitation are listed in Table II below: 
     
       
         
           
               
               
               
               
               
             
               
                 TABLE II 
               
               
                   
               
               
                 pH 
                 Co (M) 
                 mA/cm 2   
                 CE (%) 
                 μm/seconds 
               
               
                   
               
             
            
               
                 2.0 
                 0.006 
                 22 
                 50-56 
                 210-230 
               
               
                   
               
            
           
         
       
     
     A higher pH gives a larger current efficiency (“CE”), but lowering the pH allows a larger current density (“mA/cm 2 ”) and electroplating rate (“μm/seconds”). For patterned substrates, increasing the current density (“CD”) by about 10% over the current density for un-patterned substrates may be necessary to optimize current density, current efficiency, etc., in a manufacturing environment. During an electroplating operation, the pH of the electrolyte will rise. To lower the electrolyte pH, 12% perchloric acid is added, preferably using a metering pump. 
     An iron-cobalt-phosphorous alloy is stained in water. Rinsing the alloy without damage can be performed by saturating the rinse water with carbon dioxide (e.g., bubbling carbon dioxide through the rinse water for five minutes). Drying the alloy quickly with nitrogen blow-off will then prevent the formation of brown stains on the alloy surface. 
     Sometimes, however, hand drying of the substrate can still allow some oxidation to occur. An alternative procedure for eliminating any staining of the alloy during drying is to electroplate a thin (e.g., 300 Å) layer of nickel on the iron-cobalt-phosphorous alloy. For example, after rinsing the substrate in water saturated with carbon dioxide, the cathode assembly is placed, still wet, into a sulfamate solution containing 1 M of Ni(SO 3 NH 2 ) 2 , 0.03 M of NiCl 3 , 0.6 M of H 3 BO 3  at pH=4 and a nickel anode. Electroplating at a current density of 2 mA/cm 2  for about one minute produces a nickel layer thick enough (approximately 250 Å) to protect the ferrous alloy from oxidizing in water. 
     Preferably, the addition of a buffer (e.g., up to about 0.1 molar) to the electrolyte can help to maintain the surface pH low if agitation from the electroplating tool is insufficient to produce a bright and shiny deposit, which is a necessary but not sufficient condition for a good deposit. A non-complexing organic acid can be used if it has sufficient solubility and the proper acidity constant, K a . At first order, an effective buffer should have its logarithm acidity constant pK a  close to the target pH. The situation is complicated by the fact that the electrolyte is highly concentrated with salts (i.e., it has high ionic strength). The logarithm acidity constant pK a  of an acid is a function of ionic strength according to the Debye-Hückel equation:
 
Δ pK   a   =pK   a   ′−pK   a =(2 za− 1)[( A ( I ) 1/2 )/(1+( I ) 1/2 )−0.1 I],  
 
wherein za is the charge on the conjugate acid species, A is a constant (A=0.51 for 20-30° C.), I is the ionic strength, and pK a ′ is the actual logarithm acidity constant pK a  in the ionic medium. Two cases of interest are summarized in Table III below, where “AP” is ammonium phosphate, and “SHP” is sodium hypophosphite.
 
     
       
         
           
               
               
               
               
               
               
               
             
               
                 TABLE III 
               
               
                   
               
               
                 CASE 
                 FE 
                 AP 
                 SHP 
                 CO 
                 I 
                 ΔpK a   
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
            
               
                 1 
                 0.65 
                 0.50 
                 0.015 
                 0.015 
                 0.39 
                 −0.137 
               
               
                 2 
                 1.00 
                 0.50 
                 0.015 
                 0.015 
                 2.03 
                 −0.097 
               
               
                   
               
            
           
         
       
     
     Two acids that have good solubility and are not strong complexing agents for iron and cobalt are malonic acid (CH 2 (COOH) 2 , pK a =2.83) and sarcosine (CH 3 NHCH 2 COOH, pK a =2.21). Since the cathode consumes hydrogen H+, the highest buffering action occurs when the pH is below the pK a ′, so malonic acid should be a good buffer with an electrolyte at pH=2.5, and sarcosine should be a good buffer with an electrolyte at pH=2.0. 
     A phosphorous donor such as sodium hypophosphate in a 90 L electrolyte is preferably replenished on a maintenance basis using a metering pump after 1.3 grams thereof have been consumed (e.g., after electroplating about 3-4 eight-inch substrates, each electroplated 3.5 μm thick). Sodium hypophosphite is preferably added using an estimated consumption based on the percentage of phosphorus in the electroplated deposit such as demonstrated in a substrate electroplating log. It should be understood that other donors such as boron may be included in the electrolyte. 
     Thus, an electrolyte has been introduced including water, ascorbic acid, a donor such as a phosphorous donor (e.g., sodium hypophosphite), ammonium perchlorate, ferrous perchlorate, cobalt perchlorate, and a buffering agent of malonic acid, sarcosine, methanesulfonylacetic acid, phenylsulfonylacetic acid, and/or phenylmalonic acid. In an advantageous embodiment employable with an electroplating tool, a pH meter is immersed in the electrolyte to monitor its pH and the electrolyte is filtered with a microporous filter (e.g., 0.2 μm filter or better). In an advantageous embodiment employable with an electroplating tool, the electrolyte is substantially sealed to the atmosphere with a cover, and a substantially inert atmosphere is maintained above the electrolyte. An inert gas (e.g., nitrogen) is bubbled through the electrolyte to remove oxygen. 
     Ammonium bicarbonate solution advantageously is added to the electrolyte during an electroplating operation and during solution preparation to raise a pH thereof to approximately two. In a further advantageous embodiment, ammonium bicarbonate solution is added to the electrolyte during an electrolyte preparation or an electroplating operation to raise a pH thereof in the range of about two to three. In an advantageous embodiment, the ammonium bicarbonate solution has a concentration of 150 grams per liter, and is added drop wise with agitation to the electrolyte. In one embodiment, phosphorus in the electrolyte is replenished during an electroplating operation by adding electrolyte containing a phosphorous salt. In an advantageous embodiment, the phosphorous salt is sodium hypophosphite. 
     In a further embodiment employable with an electroplating tool, an iron-cobalt anode is held in the electrolyte, wherein the iron-cobalt anode is substantially four atomic percent cobalt and 96 atomic percent iron. In a further advantageous embodiment, the iron-cobalt anode includes sulfur, vanadium, tungsten, copper, and/or combinations thereof, with a concentration in the range of 1 to 100 ppm. In a further embodiment employable with an electroplating tool, a substrate is held in the electrolyte, and the substrate is advantageously mounted in a magnetic field. In a further advantageous embodiment, the magnetic field is a rotating magnetic field. In a further advantageous embodiment, the magnetic field is produced with a current-carrying coil. 
     Conductive films such as copper films, particularly copper films formed on a silicon substrate by an electrodeposition process (e.g., the first conductive winding layer  423  illustrated and described with reference to  FIG. 9  above), generally develop mechanical stress after exposure to high downstream process temperatures. High downstream temperatures are encountered in processing steps such as sputtering and curing of a photoresist. Development of film stress in copper is a consequence of copper having a higher coefficient of thermal expansion than silicon. Elevated temperatures thus lead to preferential expansion of the copper film and the development of a compressive stress therein at an elevated temperature by the less expansive silicon. Copper films approach the copper yield stress in compression at 250° C., and again in tension when returned to room temperature. Copper films show significant stress development even after exposure to temperatures as low as 110° C. The effect of such stress is to induce a bow in the substrate on which it is deposited when the substrate is cooled to room temperature. For example, the substrate  401  illustrated in  FIG. 9  can develop a bow due to mismatch of the coefficients of thermal expansion of the substrate  401  and the first conductive winding layer  423 . 
     The substrate or wafer bow is the amount of deflection at the edges thereof from a plane tangent to the center of the substrate. The radius of curvature and substrate bow depend on thickness of the copper film relative to the thickness of the silicon substrate. To prepare such a substrate with an electrodeposited copper film for further processing steps, it is important to reduce the substrate bow, particularly the bow of a patterned substrate. Unrelieved copper stress can lead to later increased room-temperature film stress by inducing grain growth or by causing sufficient mismatched thermal expansion stress to plastically deform the film. 
     A substantial portion of the residual copper film stress can be relieved in an advantageous embodiment by reducing the substrate temperature to a stress-compensating temperature (e.g., well below room temperature). Even modest below-room temperature excursions lead to plastic film deformation, making the film more compressive and closer to a stress-free level when the substrate temperature returns to room temperature or to an expected operating temperature. In effect, the reverse phenomenon is utilized to relax the residual mechanical stress present at room temperature in a copper film. 
     In an advantageous embodiment, a substrate after electrodeposition of a copper film is gradually cooled to well below room temperature (e.g., −75 degrees Celsius) by placing the substrate in a suitable refrigeration device at room temperature and turning on the device cooling mechanism such as the device compressor. In an advantageous embodiment, the substrate is maintained at a temperature of −75 degrees Celsius for a period of 24 hours to obtain substantial stress relief. In a further advantageous embodiment, the substrate is maintained at a temperature of −75 degrees Celsius for a period of six hours to obtain substantial stress relief. In a further advantageous embodiment, other low annealing temperatures to provide stress relief are contemplated. For example, a substrate can be placed inside a closed flat-pack in an operating refrigeration device to slow the substrate cooling rate. In a further advantageous embodiment, a substrate cassette containing a plurality of substrates can be placed inside an operating refrigeration device to slow the wafer cooling rate. After annealing at −75 degrees Celsius, the temperature of the substrate is gradually returned to room temperature. For example, the substrate can be gradually returned to room temperature over a period of one hour. 
     When taken from a freezer at −75 degrees Celsius and warmed to room temperature, a substrate may become wet with condensation. If condensation forms on the substrate surface, the substrate is preferably placed in front of a fan to fully bring its temperature to room temperature, and is then dried with a nitrogen gun. 
     Detailed procedures for ramping substrate temperatures to room temperature in a production environment would depend on the available equipment. For instance, a freezer with programmable heating and cooling profiles may be used, thereby avoiding or reducing condensation on the surface of a substrate. Alternatively, the refrigeration and heating process can take place in a vacuum device to reduce or even prevent condensation. By performing an annealing process, a substantial portion of the residual stress in a copper film deposited on a silicon substrate can be relieved, often reducing wafer bow by 90% or more. 
     Thus, a method of processing a substrate with a conductive film is introduced to reduce mechanical stress therein after exposure to high downstream process temperatures. In an advantageous embodiment, the substrate is a silicon, glass, or ceramic substrate. In an advantageous embodiment, the conductive film is formed on the silicon substrate by an electroplating process. 
     The method includes reducing the temperature of the substrate to a stress-compensating temperature well below room temperature and maintaining the temperature of the substrate at the stress-compensating temperature for a period of time. In an advantageous embodiment, the period of time is one to 24 hours. The method further includes increasing the temperature of the substrate to room temperature. In an advantageous embodiment, reducing the temperature of the substrate includes gradually reducing the temperature of the substrate at rate of approximately one degrees Celsius per minute. In an advantageous embodiment, the stress-compensating temperature is a temperature of less than zero degrees Celsius. In a further advantageous embodiment, increasing the temperature of the substrate to room temperature is performed over a period of one to two hours. 
     In a further advantageous embodiment, the substrate is dried with inert gas within an inert gas environment after the increasing the temperature of the substrate to room temperature. In an advantageous embodiment, the inert gas is nitrogen, and the inert gas environment advantageously is a nitrogen environment. 
     In a related embodiment, a method of forming a micromagnetic device is introduced herein that includes forming an insulating layer over a substrate, forming a conductive winding layer over the insulating layer, forming another insulating layer over the conductive winding layer, and forming a magnetic core layer over the another insulating layer. The method also includes reducing a temperature of the micromagnetic device to a stress-compensating temperature, maintaining the temperature of the micromagnetic device at the stress-compensating temperature for a period of time, and increasing the temperature of the micromagnetic device above the stress-compensating temperature. 
     Those skilled in the art should understand that the previously described embodiments of the micromagnetic devices, related methods, power converter employing the same, electroplating tool and electrolyte, and method of processing a substrate and micromagnetic device are submitted for illustrative purposes only and that other embodiments capable of producing the same are well within the broad scope of the invention. Additionally, exemplary embodiments of the invention have been illustrated with reference to specific electronic components, reagents, and processes. Those skilled in the art are aware, however, that other components reagents, and processes may be substituted (not necessarily with elements of the same type) to create desired conditions or accomplish desired results. For instance, multiple components may be substituted for a single component and vice-versa. 
     The principles of the invention may be applied to a wide variety of power converter topologies. While the micromagnetic devices, related methods, electroplating tool and electrolyte, and method of processing a substrate and micromagnetic device have been described in the environment of a power converter, those skilled in the art should understand that the aforementioned and related principles of the invention may be applied in other environments or applications such as a power amplifier or signal processor. 
     For a better understanding of power converters see “Modern DC-to-DC Switchmode Power Converter Circuits,” by Rudolph P. Severns and Gordon Bloom, Van Nostrand Reinhold Company, New York, N.Y. (1985) and “Principles of Power Electronics,” by J. G. Kassakian, M. F. Schlecht and G. C. Verghese, Addison-Wesley (1991). The aforementioned references are incorporated herein by reference in their entirety. 
     Although the invention has been described in detail, those skilled in the art should understand that they can make various changes, substitutions and alterations herein without departing from the spirit and scope of the invention in its broadest form.