Patent Publication Number: US-2019172616-A1

Title: R-t-b based permanent magnet

Description:
TECHNICAL FIELD 
     The present invention relates to an R-T-B based permanent magnet. 
     BACKGROUND 
     A rare earth permanent magnet having an R-T-B based composition is a magnet showing superior magnetic properties, and many investigations are performed to further improve the magnetic properties. Indexes which show the magnetic properties are generally a residual magnetic flux density (residual magnetization) Br and a coercive force HcJ. A magnet having high values thereof is determined to have superior magnetic properties. 
     For instance, Patent Document 1 mentions a Nd—Fe—B based rare earth permanent magnet having good magnetic properties and corrosion resistance by adding Dy. 
     In addition, Patent Document 2 mentions a rare earth permanent magnet, in which a magnet body is immersed in a slurry dispersed with a fine powder including a rare earth element in water or organic solvent, then heated to diffuse the rare earth element into the magnet body along grain boundaries. 
     [Patent Document 1] JP Patent No. 3080275 
     [Patent Document 2] a brochure of WO 2006/43348 
     SUMMARY 
     An object of the present invention is to provide an R-T-B based permanent magnet showing high residual magnetic flux density and coercive force, and having enhanced effect of improving the coercive force by diffusing a heavy rare earth element to the grain boundaries. 
     In order to achieve the above object, the R-T-B based permanent magnet of the invention provides, an R-T-B based permanent magnet including M wherein, 
     R is a rare earth element, T is Fe and Co, and B is boron, 
     R at least includes Dy, 
     M is one or more elements selected from Cu, Ga, Al, Mn, Zr, Ti, Cr, Ni, Nb, Ag, Hf, Ta, W, Si, Bi, and Sn, 
     M at least includes Cu, and 
     a total content of R is 28.0 mass % to 30.2 mass %, a content of Dy is 1.0 mass % to 6.5 mass %, a content of Cu is 0.04 mass % to 0.50 mass %, a content of Co is 0.5 mass % to 3.0 mass %, and a content of B is 0.85 mass % to 0.95 mass %. 
     The R-T-B based permanent magnet of the present invention has high residual magnetic flux density and coercive force by having a composition satisfying the above mentioned range. Further, the R-T-B based permanent magnet has enhanced effect of improving the coercive force by diffusing a heavy rare earth element to the grain boundaries. 
     The total content of R may be 29.2 mass % to 30.2 mass %. 
     R may include at least Nd. 
     R may include at least Pr. A content of Pr may be more than zero to 10.0 mass % or less, and may be 5.0 mass % to 10.0 mass %. 
     The content of Dy may be 2.5 mass % to 6.5 mass %. 
     R may at least include Nd and Pr. 
     M may further include Ga, and a content of Ga may be 0.08 mass % to 0.30 mass %. 
     M may further include Al, and a content of Al may be 0.15 mass % to 0.30 mass %. 
     M may further include Zr, and a content of Zr may be 0.10 mass % to 0.30 mass %. 
     An atomic ratio of TRE/B may be 2.19 to 2.60, where TRE is a total content of R. 
     An atomic ratio of Pr/TRE may be less than 0.250 (including 0), where TRE is the total content of R. 
     An atomic ratio of 14B/(Fe+Co) may be more than zero and 1.01 or less. 
    
    
     DETAILED EMBODIMENTS 
     An embodiment of the invention will be described hereinafter. 
     &lt;R-T-B Based Permanent Magnet&gt; 
     The R-T-B based permanent magnet according to the embodiment includes grains made of R 2 T 14 B crystals and grain boundaries thereof. The residual magnetic flux density Br, the coercive force HcJ, a corrosion resistance, and a production stability can be improved by including a plurality of specific elements within a specified range of their content. In addition, an extent of decrease in the residual magnetic flux density Br at a grain boundary diffusion step which will be described in below can be made small, while an extent of increase in the coercive force HcJ can be made large. Namely, the R-T-B based permanent magnet according to the present embodiment shows superior properties even without a grain boundary diffusion step, and also, the R-T-B based permanent magnet is suitable for the grain boundary diffusion step. From the point of improving the coercive force HcJ, the element diffused along the grain boundaries is preferably the heavy rare earth element. 
     R is the rare earth element. The rare earth element includes Sc, Y and lanthanoids, which belongs to the group III in the long-periodic table. In the present specification, lanthanoids include La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu. Also, R preferably includes Nd. 
     The rare earth elements are generally classified as light rare earth elements and heavy rare earth elements. The heavy rare earth elements of the R-T-B based permanent magnet according to the present embodiment are Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu. 
     T is Fe and Co. Also, transition metals which are not included in R or T, and inevitable impurities may be included as well. A content of transition metals which are not included in R or T, and inevitable impurities is preferably 0.1 mass % or less in total, and more preferably it is 0.05 mass % or less. Note that, T does not include C, O, and N. 
     B is boron. 
     M is one or more elements selected from the group consisting of Cu, Ga, Al, Mn, Zr, Ti, Cr, Ni, Nb, Ag, Hf, Ta, W, Si, Bi, and Sn. Also, M at least includes Cu. 
     A total content of R in the R-T-B based permanent magnet of the present embodiment is 28.0 mass % or more and 30.2 mass % or less relative to 100 mass % of a total mass of R, T, B, and M. In case the total content of R is too small, the coercive force HcJ decreases. In case the total content of R is too large, the residual magnetic flux density Br and the corrosion resistance decrease. Further, in case the total content of R is too large, the effect of improving the coercive force HcJ by diffusion of the heavy rare earth metal elements along the grain boundaries decreases. Also, the total content of R may be 29.2 mass % or more and 30.2 mass % or less. When the total content of R is 29.2 mass % or more, a degree of deformation during sintering becomes less, and the production stability improves. As described in below, by making the total content of R within 29.2 mass % or more and 30.2 mass % or less, and also making the content of B within 0.88 mass % or more and 0.95 mass % or less, a squareness ratio Hk/HcJ further improves as well. 
     A total content of Nd and Pr in the R-T-B based permanent magnet of the present embodiment is not particularly limited. Also, the content of Nd may be zero to 30.2 mass %, zero to 29.7 mass %, 19.7 to 29.7 mass %, 19.7 to 24.7 mass %, or 19.7 to 22.6 mass %, relative to 100 mass % of the total mass of R, T, B, and M. Also, the content of Pr may be zero to 10.0 mass %. Namely, Pr may not be included. The content of Pr may be 5.0 mass % or more and 10.0 mass % or less, and further, it may be 5.0 mass % or more and 7.5 mass % or less. In case the content of Pr is 10.0 mass % or less, the coercive force HcJ has superior temperature coefficient. In particular, to improve the coercive force HcJ at high temperatures, the content of Pr is preferably zero to 7.5 mass %. 
     Also, the R-T-B based permanent magnet of the present embodiment includes 1.0 mass % or more and 6.5 mass % or less of Dy as R. In case the content of Dy is too small, the coercive force HcJ and the corrosion resistance decrease. In case the content of Dy is too large, the residual magnetic flux density Br decreases, which causes an increase in cost. Also, the content of Dy is preferably 2.5 mass % or more and 6.5 mass % or less. When the content of Dy is 2.5 mass % or more and 6.5 mass % or less, the coercive force HcJ further improves, and also a demagnetization factor at high temperature decreases. 
     The R-T-B based permanent magnet of the present embodiment may include 0.5 mass % or less of Tb as R. By making the content of Tb to 0.5 mass % or less, good residual magnetic flux density Br is easily maintained. 
     The demagnetization factor at high temperature in the present specification is defined as described in below. First, a sample is magnetized by a pulse magnetic field of 4,000 kA/m. A total magnetic flux amount of the sample at room temperature (23° C.) is defined as B0. Next, the sample is exposed under a high temperature for 2 hours at 200° C., then the temperature is turned back to room temperature. When the temperature of the sample is back to a room temperature, the total magnetic flux amount is measured again, and this is defined as BI. When D is the demagnetization factor at high temperature of the present specification, D is as shown in below. 
         D= 100*( B 1− B 0)/ B 0(%)
 
     When an absolute value of the demagnetization factor at high temperature calculated from the above equation is small, this may be simply referred as the demagnetization factor at high temperature is small. 
     The content of Co is 0.5 mass % or more and 3.0 mass % or less relative to 100 mass % of the total mass of R, T, B, and M. By including Co, the corrosion resistance improves. When the content of Co is less than 0.5 mass %, the corrosion resistance of the R-T-B based permanent magnet obtained at the end will deteriorate. The Co content exceeding 3.0 mass % does not provide a further corrosion resistance enhancing effect and also results in increased cost. Also, the content of Co may be 1.0 mass % or more and 3.0 mass % or less. 
     The content of B is 0.85 mass % or more and 0.95 mass % or less relative to 100 mass % of the total mass of R, T, B, and M. When the content of B is less than 0.85 mass %, a high squareness ratio becomes difficult to attain. That is, it becomes difficult to improve the squareness ratio Hk/HcJ. When the content of B exceeds 0.95 mass %, the squareness ratio Hk/HcJ after the grain boundary diffusion decreases. Also, the content of B may be 0.88 mass % or more and 0.94 mass % or less. By making the content of B to 0.88 mass % or more, the residual magnetic flux density Br and the squareness ratio Hk/HcJ tend to further increase. By making the content of B to 0.94 mass % or less, the coercive force HcJ tends to further improve. 
     Although the total M content is not particularly limited, the total M content is preferably 0.04 mass % or more and 1.5 mass % or less based on a total mass of R, T, B, and M of 100 mass %. When the total M content is excessively large, the residual magnetic flux density Br tends to decrease. 
     The content of Cu is 0.04 mass % or more and 0.50 mass % or less relative to 100 mass % of the total mass of R, T, B, and M. The coercive force HcJ tends to decrease when the content of Cu is less than 0.04 mass %. In addition, the extent of enhancement ΔHcJ of the coercive force HcJ by diffusion of the heavy rare earth element (namely, the grain boundary diffusion) becomes insufficient, and the coercive force HcJ after diffusion of heavy rare earth element tends to further decrease. The coercive force HcJ tends to decrease when the content of Cu exceeds 0.50 mass %, and the residual magnetic flux density Br also tends to decrease. In addition, an extent of enhancement ΔHcJ of the coercive force HcJ by diffusion of the heavy rare earth element may be saturated, and also the residual magnetic flux density Br tends to decrease. In addition, the content of Cu may be 0.10 mass % or more and 0.50 mass % or less, and may be 0.10 mass % or more and 0.30 mass % or less. The corrosion resistance tends to improve when the content of Cu is 0.10 mass % or more. 
     The content of Ga is 0.08 mass % or more and 0.30 mass % or less relative to 100 mass % of the total mass of R, T, B, and M. The coercive force HcJ can be sufficiently increased when the content of Ga is 0.08 mass % or more. Sub-phases (such as R-T-Ga phase) tend to be easily formed, and the residual magnetic flux density Br tends to decrease when the content of Ga exceeds 0.30 mass %. In addition, the content of Ga may be 0.10 mass % or more and 0.25 mass % or less. 
     The content of Al is 0.15 mass % or more and 0.30 mass % or less relative to 100 mass % of the total mass of R, T, B, and M. In case the content of Al is 0.15 mass % or more, the coercive force HcJ can be increased. In addition, a difference of the coercive force HcJ due to changes of an aging temperature and/or a heat treatment temperature after diffusion of the heavy rare earth element becomes small, and the properties varies less during mass production. Namely, the production stability improves. The residual magnetic flux density Br before and after diffusion of the heavy rare earth element can be improved when the content of Al is 0.30 mass % or less. The temperature coefficient of the coercive force HcJ can also be improved. The content of Al may be 0.15 mass % or more and 0.25 mass % or less. The difference of the coercive force HcJ due to changes of the aging temperature and/or the heat treatment temperature after diffusion of the heavy rare earth element, becomes even smaller when the content of Al is 0.15 mass % or more and 0.25 mass % or less. 
     The content of Zr is 0.10 mass % or more and 0.30 mass % or less relative to 100 mass % of the total mass of R, T, B, and M. An abnormal grain growth during sintering can be restricted, and the squareness ratio Hk/HcJ and a magnetization ratio under a low magnetic field can be improved by including Zr. By making the content of Zr to 0.10 mass % or more, the abnormal grain growth restricting effect during sintering is enhanced by including Zr, and the squareness ratio Hk/HcJ and the magnetization ratio under a low magnetic field can be improved. Also, the coercive force HcJ tends to easily improve. By making the content of Zr to 0.30 mass % or less, the residual magnetic flux density Br can be improved. Also, the content of Zr may be 0.15 mass % or more and 0.30 mass % or less, and may be 0.15 mass % or more and 0.25 mass % or less. By making the content of Zr to 0.15 mass % or more, an optimal temperature range for sintering becomes wide. Namely, the abnormal grain growth restricting effect during sintering is further enhanced. Further, the properties vary less, and the production stability improves. 
     In addition, the R-T-B based permanent magnet according to the present embodiment may include Mn. In case of including Mn, the content of Mn may be 0.02 mass % to 0.10 mass % relative to 100 mass % of the total mass of R, T, B, and M. By making the content of Mn to 0.02 mass % or more, the residual magnetic flux density Br tends to increase and the extent of enhancement ΔHcJ of the coercive force HcJ after diffusion of the heavy rare earth element tends to increase. By making the content of Mn to 0.10 mass % or less, the coercive force HcJ tends to increase, and the extent of enhancement ΔHcJ of the coercive force HcJ after diffusion of the heavy rare earth element tends to increase. The content of Mn may be 0.02 mass % or more and 0.06 mass % or less. 
     Also, the atomic ratio TRE/B may be 2.19 or more and 2.60 or less, where TRE is the total content of R. When TRE/B is within the above range, the residual magnetic flux density Br and the coercive force HcJ improve. Further, the residual magnetic flux density Br and the coercive force HcJ after the grain boundary diffusion of the heavy rare earth element also improve. 
     Also, the atomic ratio Pr/TRE may be zero or more and less than 0.25, where TRE is the total content of R element. When Pr/TRE is within the above range, the corrosion resistance tends to improve. 
     Also, an atomic ratio of 14B/(Fe+Co) may be more than zero and 1.01 or less. The squareness ratio Hk/HcJ after the grain boundary diffusion tends to increase when 14B/(Fe+Co) is 1.01 or less. 14B/(Fe+Co) may be 1.00 or less. 
     The content of carbon C in the R-T-B based permanent magnet according to the present embodiment may be 1100 ppm or less, 1000 ppm or less, or 900 ppm or less relative to a total mass of the R-T-B based permanent magnet. It may further be 600 to 1100 ppm, 600 to 1000 ppm, or 600 to 900 ppm. The coercive force HcJ before and after diffusion of the heavy rare earth element tends to increase when the content of carbon is 1100 ppm or less. In particular, from the point of improving the coercive force HcJ after diffusion of the heavy rare earth element, the content of carbon can be 900 ppm or less. A production of the R-T-B based permanent magnet having the content of carbon of less than 600 ppm makes process conditions of the R-T-B based permanent magnet to be more difficult, which causes the cost to increase. 
     Note that, from the point of improving the squareness ratio Hk/HcJ after diffusion of the heavy rare earth element, the content of carbon may be 800 to 1100 ppm. 
     The content of nitrogen N in the R-T-B based permanent magnet according to the present embodiment may be 1000 ppm or less, 700 ppm or less, or 600 ppm or less relative to a total mass of the R-T-B based permanent magnet. The content of N may be 250 to 1000 ppm, 250 to 700 ppm, or 250 to 600 ppm. The coercive force HcJ tends to become larger as the content of nitrogen decreases. The production of the R-T-B based permanent magnet having the content of nitrogen of less than 250 ppm makes process conditions of the R-T-B based permanent magnet to be more difficult, which causes the cost to increase. 
     The content of oxygen O in the R-T-B based permanent magnet according to the present embodiment may be 1000 ppm or less, 800 ppm or less, 700 ppm or less, or 500 ppm or less relative to the total mass of the R-T-B based permanent magnet. It may be 350 to 500 ppm. The coercive force HcJ before diffusion of the heavy rare earth element tends to increase as the content of oxygen decreases. The production of the R-T-B based permanent magnet having the content of oxygen of less than 350 ppm makes process conditions of the R-T-B based permanent magnet to become more difficult, which causes the cost to increase. In addition, by making the total content of R to 29.2 mass % or more, and the content of oxygen to 1000 ppm or less, 800 ppm or less, 700 ppm or less, or 500 ppm or less, the deformation during sintering can be restricted and the production stability can be improved. The corrosion resistance can be increased, by making the content of oxygen to 1000 ppm or more, or 3000 ppm or more. 
     A possible reason that deformation during sintering can be suppressed by reducing the oxygen content while having a predetermined or higher total R content is as follows. 
     The sintering mechanism of the R-T-B based permanent magnet is a liquid phase sintering, in which grain boundary phase component called R-rich phase melts to form liquid phase during sintering and promotes densification. On the other hand, oxygen easily reacts with the R-rich phase, and as the content of oxygen increases rare earth oxide phase is formed, and the R-rich phase amount decreases. Although in a very small quantity, oxidizing impurity gases generally exist in a sintering furnace. Therefore, during the sintering process, the R-rich phase oxidizes near the surface of a green compact, and the R-rich phase amount may locally decrease. For the composition having large total content of R and small content of oxygen, the R-rich phase amount is large, and an influence of the oxidation on the shrinking behavior during sintering becomes small. For the composition having small content of R and/or large content of oxygen, the oxidization during sintering affects the shrinking behavior because the R-rich phase amount is small. As a result, a sintered body is deformed by partial change in shrinkage, namely, partial change in size. Thus, the deformation during sintering can be suppressed by making the total content of R to a predetermined amount or larger and by decreasing the content of oxygen. 
     Note that, a measuring method of various components included in the R-T-B based permanent magnet according to the present embodiment can be a conventionally and generally known method. Amounts of various elements can be measured for example by X-ray fluorescence analysis, an inductively coupled plasma atomic emission spectroscopy (ICP analysis), and the like. The content of oxygen is measured for example by an inert gas fusion-nondispersive infrared absorption method. The content of carbon is measured by such as combustion in oxygen stream-infrared absorption method. The content of nitrogen is measured for example by an inert gas fusion-thermal conductivity method. 
     Further, a content of B+C which is a total content of B and C may be less than 1.050 mass %, 0.920 mass % or more and less than 1.050 mass %, 0.940 mass % or more and less than 1.050 mass %, or 0.960 mass % or more and less than 1.050 mass %. By making the content of B+C to less than 1.050 mass %, the squareness ratio Hk/HcJ before and after diffusion of the heavy rare earth element tends to improve. When the content B+C exceeds 1.050 mass %, the grain boundary phase is insufficiently formed, low coercive force component is locally generated, and the squareness ratio Hk/HcJ decreases. 
     The R-T-B based permanent magnet of the present embodiment has any shape, such as a rectangular parallelepiped, an arch, or a C shape. 
     Hereinafter, a manufacturing method of the R-T-B based permanent magnet will be described in detail, however, other known methods can be used. 
     [Preparation Step of Raw Material Powder] 
     A raw material powder can be prepared by a known method. A single alloy method using a single alloy will be described in the present embodiment; however, a so called two alloys method may be used to prepare the raw material powder, in which first and second alloys each having different composition are mixed. 
     First, a raw material alloy of the R-T-B based permanent magnet is prepared (an alloy preparation step). In the alloy preparation step, raw material metals corresponding to the composition of the R-T-B based permanent magnet of the present embodiment are melted by a known method, and then casting is carried out, thereby the raw material alloy having desired composition is prepared. 
     Examples of the raw material metals which can be used include metals such as rare earth metals or rare earth alloys, pure iron, ferroboron, Co, and Cu; and, moreover, alloys and compounds thereof; and the like. Any method can be used as a casting method for forming raw material metals into a raw material alloy by casting. In order to obtain the R-T-B based permanent magnet having increased magnetic properties, a strip casting method may be used. A homogenization treatment may be performed on the obtained raw material alloy by a known method as necessary. 
     After preparing the raw material alloy, it is pulverized (pulverizing step). Note that, an atmosphere of each step from the pulverizing step to the sintering step can be a low oxygen concentration atmosphere to obtain higher magnetic properties. For instance, the oxygen concentration in each step can be 200 ppm or less. By controlling the oxygen concentration in each step, an oxygen amount included in the R-T-B based permanent magnet can be controlled. 
     Below, as a pulverization step, a two-step process is described that includes a coarse pulverization step of pulverizing the alloy to a grain diameter of about several hundred μm to several mm, and a fine pulverization step of finely pulverizing the alloy to a grain diameter of about several jam, while a single-step process consisting solely of a fine pulverization step may be carried out. 
     In the coarse pulverization step, the raw material alloy is coarsely pulverized till the particle diameter becomes approximately several hundred m to several mm. Thereby, the coarsely pulverized powder is obtained. The coarse pulverization can be carried out by any method, and it can be a known method such as a hydrogen storage pulverization method, a method using a coarse pulverizer, and the like. In case of performing the hydrogen storage pulverization, the nitrogen amount included in the R-T-B based permanent magnet can be controlled by controlling nitrogen gas concentration in an atmosphere during the dehydrogenation treatment. 
     Next, the obtained coarsely pulverized powder is finely pulverized till the average particle diameter becomes approximately several μm (fine pulverization step). Thereby, a fine pulverized powder (raw material powder) is obtained. The average particle diameter of the fine pulverized powder may be 1 μm or more and 10 μm or less, 2 μm or more and 6 μm or less, or 3 μm or more and 5 μm or less. The nitrogen amount included in the R-T-B based permanent magnet can be controlled by controlling the nitrogen gas concentration in an atmosphere during the fine pulverization process. 
     The fine pulverization method can be any method. For instance, various kinds of fine pulverizers can be used for the fine pulverization. 
     When finely pulverizing the coarsely pulverized powder in the fine pulverization step, by adding various pulverization aids such as lauramide, oleyamide, and the like, the fine pulverized powder with high orientation when compacting can be obtained. In addition, the carbon amount included in the R-T-B based permanent magnet can be controlled by varying an amount of the pulverization aids added. 
     [Compacting Step] 
     In a compacting step, the above-mentioned fine pulverized powder is compacted to a desired shape. The compacting can be performed by any method. According to the present embodiment, the fine pulverized powder above is filled in a die and pressurized in a magnetic field. The green compact obtained as such has main phase crystals oriented in a specific direction. Therefore, the R-T-B based permanent magnet having higher residual magnetic flux density can be obtained. 
     The pressure during compacting can be 20 MPa to 300 MPa. The magnetic field applied can be 950 kA/m or more, and 950 kA/m to 1600 kA/m. The magnetic field applied is not limited to a static magnetic field, and it can be a pulse magnetic field. Also, the static magnetic field and the pulse magnetic field can be used together. 
     As a compacting method, other than dry compacting wherein the fine pulverized powder is directly molded as described above, wet compacting can be applied wherein a slurry obtained by dispersing the fine pulverized powder in a solvent such as oil is molded. 
     A shape of the green compact obtained by compacting the fine pulverized powder can be any shape. In addition, the density of the green compact at this point can be 4.0 Mg/m 3  to 4.3 Mg/m 3 . 
     [Sintering Step] 
     A sintering step is a process in which the green compact is sintered in a vacuum or inert gas atmosphere to obtain the sintered body. Although a sintering temperature needs to be adjusted depending on conditions such as composition, pulverization method, a difference of particle size and particle size distribution and the like, sintering is carried out by heating the green compact for example in vacuum or under inert gas, at 1,000° C. or higher to 1,200° C. or less for one hour or more to 20 hours or less. Thereby, the sintered body with high density can be obtained. In the present embodiment, the sintered body having the density of 7.45 Mg/m 3  or more is obtained. The density of the sintered body can be 7.50 Mg/m 3  or more. 
     [Aging Treatment Step] 
     An aging treatment step is a step in which the sintered body is heat treated at lower temperature than the sintering temperature. There is no particular limitation whether or not to carry out the aging treatment step, and the number of carrying out the aging treatment step is also not particularly limited. The aging treatment step is performed accordingly depending on the desired magnetic properties. In addition, a grain boundary diffusion step which will be described in below may be used as the aging treatment step. For the R-T-B based permanent magnet according to the present embodiment, two steps of the aging treatment is carried out. Hereinafter, the embodiment carrying out the two steps aging treatment is described. 
     A first-time aging step is referred to as a first aging step, a second-time aging step is referred to as a second aging step, the aging temperature of the first aging step is referred to as T1, and the aging temperature of the second aging step is referred to as T2. 
     The temperature T1 and the aging time during the first aging step are not particularly limited, and may be 700° C. or more and 900° C. or less and one hour to 10 hours. 
     The temperature T2 and the aging time during the second aging step are not particularly limited, and may be 450° C. or more and 700° C. or less and one hour to 10 hours. 
     By such aging treatments, the magnetic properties, especially the coercive force HcJ of the finally obtained R-T-B based permanent magnet can be improved. 
     The production stability of the R-T-B based permanent magnet of the present embodiment can be confirmed by the difference of the magnetic properties due to the change of the aging temperature. For instance, in case the difference of the magnetic properties due to the change of the aging temperature is large, the magnetic properties change even by a small change of the aging temperature. Therefore, an acceptable range of the aging temperature during the aging step becomes narrow and the production stability becomes low. On the contrary, in case the difference of the magnetic properties due to the change of the aging temperature is small, the magnetic properties scarcely change even if the aging temperature changes. Therefore, the acceptable range of the aging temperature during the aging step becomes wide and the production stability becomes high. 
     Thus obtained R-T-B based permanent magnet of the present embodiment has desired properties. Specifically, the residual magnetic flux density Br and the coercive force HcJ are high, and the corrosion resistance and the production stability are superior. Moreover, in case the grain boundary diffusion step, which will be described below, is carried out, the extent of decrease in the residual magnetic flux density Br is small and the extent of enhancement of the coercive force HcJ is large when the heavy rare earth element is diffused along the grain boundaries. Namely, the R-T-B based permanent magnet of the present embodiment is a magnet suitable for the grain boundary diffusion. 
     Note that, the R-T-B based permanent magnet of the present embodiment obtained by the above method becomes an R-T-B based permanent magnet product by magnetizing. 
     The R-T-B based permanent magnet according to the present embodiment is suitably used for a motor, an electric generator, and the like. 
     Note that, the invention is not limited to the above described embodiment and can be variously modified within the scope of the invention. 
     While the R-T-B based permanent magnet can be obtained by the above method, the method for producing the R-T-B based permanent magnet is not limited to the above method, and may be suitably changed. For example, the R-T-B based permanent magnet of the present embodiment may be produced by hot working. A method for producing the R-T-B based permanent magnet by hot working includes the following steps: 
     (a) a melting and quenching step of melting raw material metals and quenching the resulting molten metal to obtain a ribbon; 
     (b) a pulverization step of pulverizing the ribbon to obtain a flake-like raw material powder; 
     (c) a cold forming step of cold-forming the pulverized raw material powder; 
     (d) a preheating step of preheating the cold-formed body; 
     (e) a hot forming step of hot-forming the preheated cold-formed body; 
     (f) a hot plastic deforming step of plastically deforming the hot-formed body into a predetermined shape; and 
     (g) an aging treatment step of aging an R-T-B based permanent magnet. 
     Hereinafter, a method in which the heavy rare earth element is diffused along the grain boundaries in the R-T-B based permanent magnet of the present embodiment is described. 
     [Machining Step (Before the Grain Boundary Diffusion)] 
     A step for machining the R-T-B based permanent magnet according to the present embodiment to a desired shape may be employed if necessary. As examples of the machining method, a shape machining such as cutting and grinding, a chamfering such as barrel polishing, and the like may be mentioned. 
     The heavy rare earth metal and/or the compound or alloy including the heavy rare earth element or so are adhered on the surface of the R-T-B based permanent magnet by coating, deposition, and the like, then the heat treatment is carried out, thereby the grain boundary diffusion can be carried out. The coercive force HcJ of the finally obtained R-T-B based permanent magnet can be further enhanced by the grain boundary diffusion of the heavy rare earth element. 
     The heavy rare earth element may be Dy or Tb, and Tb is preferable. 
     In the embodiments hereinafter, a coating material such as slurry, paste, and the like including the heavy rare earth element is prepared, and the coating material is applied on the surface of the R-T-B based permanent magnet. 
     The coating material can be in any state. Any heavy rare earth metal and any compound or alloy including the heavy rare earth element can be used. Also, any solvent and dispersant can be used. Further, the concentration of the heavy rare earth element in the coating material can be arbitrary concentration. As the compound including the heavy rare earth element, for example fluoride and hydride can be used. 
     A diffusion treatment temperature during the grain boundary diffusion step according to the present embodiment can be 800 to 950° C. The diffusion treatment time can be one hour to 50 hours. Note that, the grain boundary diffusion step can be used as the above-mentioned aging treatment process. 
     An additional heat treatment may be performed after the diffusion treatment. In this case, the heat treatment temperature may be 450 to 600° C. The heat treatment time may be one hour to 10 hours. The magnetic properties, especially the coercive force HcJ, of the finally obtained R-T-B based permanent magnet can be further enhanced by such a heat treatment. 
     The production stability of the R-T-B based permanent magnet of the present embodiment can be confirmed by the difference of the magnetic properties due to the change of the diffusion treatment temperature during the grain boundary diffusion step and/or the heat treatment temperature after the heavy rare earth element diffusion. Hereinafter, the diffusion treatment temperature during the heavy rare earth element diffusion step is described; however, the same applies to the heat treatment temperature after diffusing the heavy rare earth element. For instance, in case the difference of magnetic properties due to the change of diffusion treatment temperature is large, the magnetic properties change even by a small change of the diffusion treatment temperature. Therefore, an acceptable range of the diffusion treatment temperature during the grain boundary diffusion step becomes narrow, and the production stability becomes low. On the contrary, in case the difference of magnetic properties due to the change of diffusion treatment temperature is small, the magnetic properties scarcely change even when the diffusion treatment temperature changes. Therefore, the acceptable range of the diffusion treatment temperature during the grain boundary diffusion step becomes wide and the production stability becomes high. 
     [Machining Step (after the Grain Boundary Diffusion)] 
     Various kinds of the machining may be performed on the R-T-B based permanent magnet after the grain boundary diffusion step. Any kind of machining can be carried out. For example, a shape machining such as cutting and grinding, a chamfering such as barrel polishing, and the like may be carried out. 
     Example 
     Hereinafter, the R-T-B based permanent magnet of the invention will be described in detail referring to examples; however, the invention is not limited thereto. In the examples described in below, an R-T-B based sintered magnet will be described. 
     Experiment 1 
     (Manufacturing R-T-B Based Sintered Magnet) 
     Nd, Pr, alloy of Dy and Fe, an electrolytic iron, and a low carbon ferroboron alloy were prepared as raw material metals. Further, Al, Ga, Cu, Co, Mn, and Zr were prepared as pure metal, or as an alloy with Fe. 
     The raw material alloy was prepared using a strip casting method to the above-mentioned raw material metals in order to make the finally obtained magnet composition having the composition of each sample shown in below-mentioned Tables 1, 3, and 5. Also, the thickness of the raw material alloy was 0.2 mm to 0.4 mm. The contents (mass %) of elements other than C, N, and O shown in Tables 1, 3, and 5 were values based on a total mass of R, T, B, and M of 100 mass %. 
     Subsequently, hydrogen was absorbed into the raw material alloy by flowing hydrogen gas at room temperature for one hour. Then, the atmosphere was changed to Ar gas and the dehydrogenation treatment was performed at 600° C. for one hour to perform the hydrogen storage pulverization to the raw material alloy. Regarding sample numbers 124 to 126, the nitrogen gas concentration in the atmosphere during the dehydrogenation treatment was regulated to make the nitrogen content to a predetermined amount. Subsequently, after cooling, the dehydrogenation treated raw material alloys were sieved to obtain the powder having particle diameter of 425 m or less. Note that, from the hydrogen storage pulverization step to the sintering step which will be described in below, the atmosphere was low oxygen atmosphere in which the oxygen concentration was consistently less than 200 ppm. Regarding sample numbers 117 to 121, the oxygen concentration in the atmosphere was regulated to make the oxygen content to a predetermined amount. 
     Subsequently, a mass ratio of 0.1% oleyamide was added as the pulverization aid to the raw material alloy powder after the hydrogen storage pulverization and sieving, and then these were mixed. Regarding sample numbers 113 to 116, the amount of the pulverization aid added was regulated in order to make the carbon content to a predetermined amount. 
     Subsequently, the obtained powder was finely pulverized in a nitrogen gas stream using an impact plate type jet mill apparatus, and the fine powder (raw material powder) having an average particle diameter of 3.9 to 4.2 m was obtained. Regarding samples 122 and 123, the obtained powder was finely pulverized in a mixed gas stream of Ar and nitrogen, and the nitrogen gas concentration was adjusted to make the nitrogen content to a predetermined amount. Note that, the average particle diameter was an average particle diameter D50 measured by a laser diffraction type particle size analyzer. 
     The obtained fine powder was compacted in the magnetic field and a green compact was manufactured. Here, the magnetic field applied to the obtained fine powder when compacting was a static magnetic field of 1,200 kA/m. The pressure applied during the compacting was 98 MPa. The direction of magnetic field application and the direction of pressurization were perpendicular to each other. The density of the green compact at this point was measured, and all of the green compacts had the density within 4.10 Mg/m 3  to 4.25 Mg/m 3 . 
     Subsequently, the green compact was sintered and a sintered body was obtained. Optimum conditions of sintering vary depending on the composition and the like; however, sintering was carried out within the temperature range of 1,040° C. to 1,100° C. for four hours. Sintering was carried out in a vacuumed atmosphere. The sintered density at this point was within 7.45 Mg/m 3  to 7.55 Mg/m 3 . Then, in Ar atmosphere under atmospheric pressure, the first aging treatment was performed at the first aging temperature Ti=850° C. for one hour and the second aging treatment was further performed at the second aging temperature T2=520° C. for one hour. Accordingly, the R-T-B based sintered magnet of each sample shown in Tables 1, 3, and 5 were obtained. 
     The composition of the obtained R-T-B based sintered magnet was evaluated by X-ray fluorescence analysis. B as boron was evaluated by ICP analysis. The oxygen content was measured by the inert gas fusion-nondispersive infrared absorption method. The carbon content was measured by the combustion in oxygen stream-infrared absorption method. The nitrogen content was measured by the inert gas fusion-thermal conductivity method. The compositions of each sample were confirmed to be as shown in Tables 1, 3, and 5. The Fe content being balance (bal.) means that the contents of elements not listed in above Tables 1, 3, and 5 were included in the Fe content, and the total of R, T, B, and M was 100 mass %. The C, N, and O contents (ppm) shown in Tables 1, 3, and 5 each indicated the contents based on the total mass of the magnet. 
     Also, the obtained R-T-B based sintered magnet was ground to 14 mm×10 mm×11 mm (the direction of easy magnetization axis was 11 mm) by a vertical grinding machine, and the residual magnetic flux density Br was evaluated by a BH tracer. Note that, the magnet was magnetized before the measurement by a pulse magnetic field of 4,000 kA/m. In addition, the obtained R-T-B based sintered magnet was ground to 7 mm×7 mm×7 mm by a vertical grinding machine, and the coercive force HcJ was evaluated by a pulse BH tracer. The sample which was used to evaluate the residual magnetic flux density Br and the sample which was used to evaluate the coercive force HcJ were different samples. Note that, the magnet was magnetized before the measurement by a pulse magnetic field of 4,000 kA/m. 
     Generally, the residual magnetic flux density Br and the coercive force HcJ are in the relationship of a trade-off. Namely, the coercive force HcJ tends to be low as the residual magnetic flux density Br is high, and the residual magnetic flux density Br tends to be low as the coercive force HcJ is high. Thus, for the present example, a performance index PI (Potential Index) was set to comprehensively evaluate the residual magnetic flux density Br and the coercive force HcJ. The following equation was defined where the magnitude of the residual magnetic flux density measured by mT unit was Br (mT), and the magnitude of the coercive force measured by kA/m unit was HcJ (kA/m). 
       PI= Br+ 25× HcJ× 4π/2,000
 
     For the present example, when Br≥1240 mT, HcJ≥1400 kA/m, and PI≥1630 were satisfied before diffusion of Tb which is described in below, the residual magnetic flux density Br and the coercive force HcJ before diffusion of Tb were considered good. Also, when the squareness ratio Hk/HcJ before diffusion of Tb was 95.0% or more, it was considered good. When the squareness ratio Hk/HcJ after diffusion of Tb was 95.0% or more, it was considered good. Note that, the squareness ratio Hk/HcJ in the present example was calculated by Hk/HcJ (%) when Hk (kA/m) is the magnitude of the magnetic field when the magnetization reaches 90% of Br in the second quadrant (J-H demagnetization curve) of a magnetization J—magnetic field H curve. Then, J-H curve was measured using a BH tracer at the measuring temperature of 200° C.; thereby the squareness ratio Hk/HcJ was calculated. 
     When a sample satisfied Br≥1240 mT, HcJ≥1400 kA/m, PI≥1630, and Hk/HcJ≥95.0% before diffusion of Tb which is described in below, such sample was considered good and it was shown by a symbol “∘”. If the sample did not satisfy any one of the above properties, then it was shown by a symbol of “x”. Note that, when HcJ≥1500 kA/m and Hk/HcJ of 98.0% or more were satisfied, then particularly superior demagnetizing force resistance was attained. 
     In addition, the corrosion resistance of each sample was tested. The corrosion resistance was tested by PCT test (Pressure Cooker Test) under saturated vapor pressure. Specifically, a mass change of the R-T-B based sintered magnet before and after the test under pressure of 2 atm for 1,000 hours in 100% RH atmosphere was measured. The corrosion resistance was considered good when the mass decrease per a total surface area of the magnet was 3 mg/cm 2  or less. The corrosion resistance was considered particularly good when the mass decrease was 2 mg/cm 2  or less. The samples showed the corrosion resistance of particularly good, good, and poor, which were shown by the symbols “⊚”, “∘” and “x”, respectively. Note that, none of the samples tested for the corrosion resistance showed “poor” for the corrosion resistance. 
     Further, for each sample, the demagnetization factor at high temperature was measured. First, the sample was ground into a shape having a permeance coefficient of 0.5. Then, the sample was magnetized by the pulse magnetic field of 4,000 kA/m, and the total magnetic flux amount of the sample at room temperature (23° C.) was measured. This was defined as B0. The total magnetic flux amount was for example measured by a flux meter and the like. Next, the sample was exposed under high temperature of 200° C. for 2 hours, and then turned back to room temperature. Once the temperature of the sample turned back to room temperature, the total magnetic flux amount was measured again, and this was defined as BI. When the demagnetization factor at high temperature was D (%), the following equation was satisfied. 
         D= 100×( B 1− B 0)/ B 0(%)
 
     When the absolute value of the demagnetization factor at high temperature before diffusion of Tb is 50% or less, then it was considered good. 
     (Tb Diffusion) 
     Further, the obtained R-T-B based sintered magnet was ground to 14 mm×10 mm×4.2 mm (the direction of easy magnetization axis was 4.2 mm). Then, the etching treatment was carried out by immersing the R-T-B based sintered magnet for 3 minutes in a mixed solution of nitric acid and ethanol including 3 mass % of nitric acid with respect to 100 mass % of ethanol, and then immersing in ethanol for one minute. The etching treatment of immersing for 3 minutes in the mixed solution and one minute in ethanol was repeated twice. Subsequently, a slurry having TbH 2  particles (average particle diameter D50=10.0 m) dispersed in ethanol was applied on entire surface of the R-T-B sintered magnet after the etching treatment so that a mass ratio of Tb with relative to a mass of the sintered magnet was 0.6 mass %. 
     After applying and drying the slurry, the diffusion treatment was performed in flowing Ar atmosphere (1 atm) at 930° C. for 18 hours, and then the heat treatment was performed at 520° C. for four hours. 
     The R-T-B based sintered magnet after the heat treatment was ground and the magnetic properties were evaluated. Note that, the magnetic properties were evaluated after magnetizing by 4,000 kA/m pulse magnetic field. For the measurement of the residual magnetic flux density Br, each surface of the magnet was ground to form 13.8 mm×9.8 mm×4 mm, then three sintered magnets were layered one on top of the other, then the residual magnetic flux density Br was measured by a BH tracer. For the measurement of the coercive force HcJ, the entire surface of the magnet was evenly ground to form 7 mm×7 mm×4 mm, and using one magnet, the coercive force HcJ was measured by a pulse BH tracer. After diffusion of Tb, when samples satisfied Br≥1230 mT, HcJ≥2150 kA/m, PI≥1740, and Hk/HcJ≥95.0%, such sample was considered good and it was shown by a symbol “∘”. If the sample did not satisfy any one of the above properties, then it was shown by a symbol of “x”. Note that, it was particularly preferable when HcJ≥2250 kA/m. 
     Also, the demagnetization factor at high temperature after diffusion of Tb was measured. The method of measuring the demagnetization factor at high temperature was the same as the method measuring the demagnetization factor at high temperature before diffusion of Tb. When the absolute value of the demagnetization factor at high temperature after diffusion of Tb was less than 1%, then it was considered good. 
     Further, in each Table, the difference of the residual magnetic flux density Br before and after diffusion of Tb was shown by ΔBr, and the difference of the coercive force HcJ before and after diffusion of Tb was shown by ΔHcJ. In the present embodiment, the difference of residual magnetic flux density Br due to Tb diffusion was defined as ΔBr and the difference of coercive force due to Tb diffusion was defined as ΔHcJ. Namely, ΔBr=(Br after Tb diffusion)−(Br before Tb diffusion). Similarly, ΔHcJ=(HcJ after Tb diffusion)−(HcJ before Tb diffusion). When ΔBr≥−15 mT and ΔHcJ≥700 kA/m were satisfied, it was considered that the effect of improving the coercive force HcJ by diffusion of the heavy rare earth element into the grain boundary was large. 
     
       
         
           
               
               
             
               
                 TABLE 1 
               
             
            
               
                   
               
               
                   
                 R-T-B based sintered magnet compostion (before Tb diffusion) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                   
                   
                   
                   
                   
                 14B/  
                   
                   
                   
                   
                   
                   
                   
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                 R 
                   
                 T 
                   
                 TRE/B  
                 Pr/TRE 
                 (Fe + Co) 
                 M 
                   
                   
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Sample  
                 Nd 
                 Pr 
                 Tb 
                 Dy  
                   
                 Co  
                 Fe 
                 B  
                 (atomic 
                 (atomic 
                 (atomic 
                 Al 
                 Ga 
                 Cu 
                 Mn 
                 Zr 
                 C 
                 N 
                 O 
               
               
                 No. 
                 (mass %) 
                 (mass %) 
                 (mass %) 
                 (mass %) 
                 TRE  
                 (mass %) 
                 (mass %) 
                 (mass %) 
                 ratio) 
                 ratio) 
                 ratio) 
                 (mass %) 
                 (mass %) 
                 (mass %) 
                 (mass %) 
                 (mass %) 
                 (ppm) 
                 (ppm) 
                 (ppm) 
               
               
                   
               
               
                  1* 
                 20.5 
                 6.9 
                 0.0 
                 3.3 
                 
                   
                 
                 2.0 
                 bal. 
                 
                   
                 
                 2.38 
                 0.232 
                 1.03 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  2* 
                 20.5 
                 6.9 
                 0.0 
                 3.3 
                 
                   
                 
                 2.0 
                 bal. 
                 0.95 
                 2.41 
                 0.232 
                 1.02 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  3* 
                 20.5 
                 6.9 
                 0.0 
                 3.3 
                 
                   
                 
                 2.0 
                 bal. 
                 0.94 
                 2.43 
                 0.232 
                 1.01 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  4* 
                 20.5 
                 6.9 
                 0.0 
                 3.3 
                 
                   
                 
                 2.0 
                 bal. 
                 0.93 
                 2.46 
                 0.232 
                 1.00 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  5* 
                 20.5 
                 6.9 
                 0.0 
                 3.3 
                 
                   
                 
                 2.0 
                 bal. 
                 0.90 
                 2.54 
                 0.232 
                 0.96 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  6* 
                 20.5 
                 6.9 
                 0.0 
                 3.3 
                 
                   
                 
                 2.0 
                 bal. 
                 0.88 
                 2.60 
                 0.232 
                 0.94 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  7* 
                 20.5 
                 6.9 
                 0.0 
                 3.3 
                 
                   
                 
                 2.0 
                 bal. 
                 0.85 
                 2.69 
                 0.232 
                 0.91 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  8* 
                 20.2 
                 6.7 
                 0.0 
                 3.3 
                 30.2 
                 2.0 
                 bal. 
                 
                   
                 
                 2.34 
                 0.229 
                 1.02 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  9 
                 20.2 
                 6.7 
                 0.0 
                 3.3 
                 30.2 
                 2.0 
                 bal. 
                 0.95 
                 2.37 
                 0.229 
                 1.01 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 10 
                 20.2 
                 6.7 
                 0.0 
                 3.3 
                 30.2 
                 2.0 
                 bal. 
                 0.94 
                 2.39 
                 0.229 
                 1.00 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 11 
                 20.2 
                 6.7 
                 0.0 
                 3.3 
                 30.2 
                 2.0 
                 bal. 
                 0.93 
                 2.42 
                 0.229 
                 0.99 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 12 
                 20.2 
                 6.7 
                 0.0 
                 3.3 
                 30.2 
                 2.0 
                 bal. 
                 0.90 
                 2.50 
                 0.229 
                 0.96 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 13 
                 20.2 
                 6.7 
                 0.0 
                 3.3 
                 30.2 
                 2.0 
                 bal. 
                 0.88 
                 2.55 
                 0.229 
                 0.94 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 14* 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 2.0 
                 bal. 
                 
                   
                 
                 2.30 
                 0.229 
                 1.01 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 15 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 2.0 
                 bal. 
                 0.95 
                 2.33 
                 0.229 
                 1.00 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 16 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 2.0 
                 bal. 
                 0.94 
                 2.35 
                 0.229 
                 0.99 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 17 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 2.0 
                 bal. 
                 0.93 
                 2.38 
                 0.229 
                 0.98 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 18 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 2.0 
                 bal. 
                 0.90 
                 2.46 
                 0.229 
                 0.95 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 19 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 2.0 
                 bal. 
                 0.88 
                 2.51 
                 0.229 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 20 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 2.0 
                 bal. 
                 0.85 
                 2.60 
                 0.229 
                 0.90 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 21* 
                 19.4 
                 6.5 
                 0.0 
                 3.3 
                 29.2 
                 2.0 
                 bal. 
                 
                   
                 
                 2.26 
                 0.230 
                 1.01 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 22 
                 19.4 
                 6.5 
                 0.0 
                 3.3 
                 29.2 
                 2.0 
                 bal. 
                 0.95 
                 2.29 
                 0.230 
                 1.00 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 23 
                 19.4 
                 6.5 
                 0.0 
                 3.3 
                 29.2 
                 2.0 
                 bal. 
                 0.94 
                 2.31 
                 0.230 
                 0.99 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 24 
                 19.4 
                 6.5 
                 0.0 
                 3.3 
                 29.2 
                 2.0 
                 bal. 
                 0.93 
                 2.34 
                 0.230 
                 0.98 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 25 
                 19.4 
                 6.5 
                 0.0 
                 3.3 
                 29.2 
                 2.0 
                 bal. 
                 0.90 
                 2.41 
                 0.230 
                 0.94 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 26 
                 19.4 
                 6.5 
                 0.0 
                 3.3 
                 29.2 
                 2.0 
                 bal. 
                 0.88 
                 2.47 
                 0.230 
                 0.92 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 27 
                 19.4 
                 6.5 
                 0.0 
                 3.3 
                 29.2 
                 2.0 
                 bal. 
                 0.85 
                 2.56 
                 0.230 
                 0.89 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 28* 
                 19.2 
                 6.4 
                 0.0 
                 3.3 
                 28.9 
                 2.0 
                 bal. 
                 
                   
                 
                 2.24 
                 0.228 
                 1.00 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 29 
                 19.2 
                 6.4 
                 0.0 
                 3.3 
                 28.9 
                 2.0 
                 bal. 
                 0.95 
                 2.26 
                 0.228 
                 0.99 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 30 
                 19.2 
                 6.4 
                 0.0 
                 3.3 
                 28.9 
                 2.0 
                 bal. 
                 0.94 
                 2.29 
                 0.228 
                 0.98 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 31 
                 19.2 
                 6.4 
                 0.0 
                 3.3 
                 28.9 
                 2.0 
                 bal. 
                 0.93 
                 2.31 
                 0.228 
                 0.97 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 32 
                 19.2 
                 6.4 
                 0.0 
                 3.3 
                 28.9 
                 2.0 
                 bal. 
                 0.90 
                 2.39 
                 0.228 
                 0.94 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 33 
                 19.2 
                 6.4 
                 0.0 
                 3.3 
                 28.9 
                 2.0 
                 bal. 
                 0.88 
                 2.44 
                 0.228 
                 0.92 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 34 
                 19.2 
                 6.4 
                 0.0 
                 3.3 
                 28.9 
                 2.0 
                 bal. 
                 0.85 
                 2.53 
                 0.228 
                 0.89 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 35* 
                 18.5 
                 6.2 
                 0.0 
                 3.3 
                 28.0 
                 2.0 
                 bal. 
                 
                   
                 
                 2.17 
                 0.228 
                 0.99 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 36 
                 18.5 
                 6.2 
                 0.0 
                 3.3 
                 28.0 
                 2.0 
                 bal. 
                 0.95 
                 2.19 
                 0.228 
                 0.98 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 37 
                 18.5 
                 6.2 
                 0.0 
                 3.3 
                 28.0 
                 2.0 
                 bal. 
                 0.94 
                 2.21 
                 0.228 
                 0.97 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 38 
                 18.5 
                 6.2 
                 0.0 
                 3.3 
                 28.0 
                 2.0 
                 bal. 
                 0.93 
                 2.24 
                 0.228 
                 0.96 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 39 
                 18.5 
                 6.2 
                 0.0 
                 3.3 
                 28.0 
                 2.0 
                 bal. 
                 0.90 
                 2.31 
                 0.228 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 40 
                 18.5 
                 6.2 
                 0.0 
                 3.3 
                 28.0 
                 2.0 
                 bal. 
                 0.88 
                 2.37 
                 0.228 
                 0.91 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                   
               
               
                 *indicates comparative example 
               
            
           
         
       
     
     
       
         
           
               
               
               
               
             
               
                 TABLE 2 
               
             
            
               
                   
               
               
                   
                 Before Tb diffusion 
                 Difference due to 
                 After Tb diffusion 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                   
                   
                   
                 Demagnetization factor 
                   
                   
                 Tb diffusion 
                   
                   
                   
                   
                 Demagnetization factor 
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                 Br 
                 HcJ 
                   
                 Hk/HcJ 
                 at high temperature 
                 PI, Hk/HcJ 
                 Corrosion 
                 Δ Br 
                 Δ HcJ 
                 Br 
                 HcJ 
                   
                 Hk/HcJ 
                 at high temperature 
                 PI, Hk/Hcj 
               
               
                 Sample No. 
                 (mT) 
                 (kA/m) 
                 PI 
                 (%) 
                 (%) 
                 Evaluation 
                 resistance 
                 (mT) 
                 (kA/m) 
                 (mT) 
                 (kA/m) 
                 PI 
                 (%) 
                 (%) 
                 Evaluation 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                  1* 
                 1340 
                 1814 
                 
                   
                 
                 98.9 
                 −27 
                 X 
                 ◯ 
                 −9 
                 
                   
                 
                 1331 
                 2513 
                 
                   
                 
                 
                   
                 
                 0 
                 X 
               
               
                  2* 
                 1339 
                 1825 
                 
                   
                 
                 98.8 
                 −26 
                 X 
                 ◯ 
                 −5 
                 701 
                 1334 
                 2526 
                 
                   
                 
                 97.8 
                 0 
                 X 
               
               
                  3* 
                 1333 
                 1843 
                 
                   
                 
                 98.8 
                 −25 
                 X 
                 ◯ 
                 −7 
                 708 
                 1331 
                 2551 
                 
                   
                 
                 97.8 
                 0 
                 X 
               
               
                  4* 
                 1334 
                 1856 
                 
                   
                 
                 98.9 
                 −24 
                 X 
                 ◯ 
                 −6 
                 705 
                 1328 
                 2561 
                 
                   
                 
                 97.8 
                 0 
                 X 
               
               
                  5* 
                 1335 
                 1869 
                 
                   
                 
                 98.7 
                 −23 
                 X 
                 ◯ 
                 −6 
                 
                   
                 
                 1329 
                 2564 
                 
                   
                 
                 97.3 
                 0 
                 X 
               
               
                  6* 
                 1332 
                 1891 
                 
                   
                 
                 98.5 
                 −21 
                 X 
                 ◯ 
                 −6 
                 
                   
                 
                 1326 
                 2574 
                 
                   
                 
                 97.8 
                 0 
                 X 
               
               
                  7* 
                 1322 
                 1838 
                 
                   
                 
                 98.4 
                 −24 
                 X 
                 ◯ 
                 −8 
                 
                   
                 
                 1314 
                 2516 
                 
                   
                 
                 97.2 
                 0 
                 X 
               
               
                  8* 
                 1352 
                 1797 
                 1634 
                 98.7 
                 −28 
                 ◯ 
                 ⊚ 
                 −8 
                 723 
                 1344 
                 2520 
                 740 
                 
                   
                 
                 0 
                 X 
               
               
                  9 
                 1349 
                 1793 
                 1631 
                 98.7 
                 −28 
                 ◯ 
                 ⊚ 
                 −6 
                 735 
                 1343 
                 2528 
                 1740 
                 98.0 
                 0 
                 ◯ 
               
               
                 10 
                 1350 
                 1807 
                 1634 
                 98.8 
                 −27 
                 ◯ 
                 ⊚ 
                 −6 
                 738 
                 1344 
                 2545 
                 1744 
                 98.5 
                 0 
                 ◯ 
               
               
                 11 
                 1350 
                 1823 
                 1636 
                 98.8 
                 −26 
                 ◯ 
                 ⊚ 
                 −9 
                 726 
                 1341 
                 2549 
                 1741 
                 98.7 
                 0 
                 ◯ 
               
               
                 12 
                 1347 
                 1856 
                 1639 
                 98.5 
                 −24 
                 ◯ 
                 ⊚ 
                 −10 
                 719 
                 1337 
                 2575 
                 1741 
                 98.3 
                 0 
                 ◯ 
               
               
                 13 
                 1345 
                 1854 
                 1636 
                 98.5 
                 −24 
                 ◯ 
                 ⊚ 
                 −7 
                 708 
                 1338 
                 2562 
                 1740 
                 98.3 
                 0 
                 ◯ 
               
               
                 14* 
                 1368 
                 1739 
                 1641 
                 99.5 
                 −32 
                 ◯ 
                 ⊚ 
                 −6 
                 762 
                 1362 
                 2501 
                 1755 
                 
                   
                 
                 0 
                 X 
               
               
                 15 
                 1367 
                 1749 
                 1642 
                 99.5 
                 −31 
                 ◯ 
                 ⊚ 
                 −5 
                 766 
                 1362 
                 2515 
                 1757 
                 98.1 
                 0 
                 ◯ 
               
               
                 16 
                 1368 
                 1785 
                 1648 
                 99.5 
                 −29 
                 ◯ 
                 ⊚ 
                 −6 
                 762 
                 1362 
                 2547 
                 1762 
                 98.1 
                 0 
                 ◯ 
               
               
                 17 
                 1370 
                 1789 
                 1651 
                 99.7 
                 −29 
                 ◯ 
                 ⊚ 
                 −8 
                 761 
                 1362 
                 2550 
                 1763 
                 98.1 
                 0 
                 ◯ 
               
               
                 18 
                 1363 
                 1828 
                 1650 
                 99.4 
                 −26 
                 ◯ 
                 ⊚ 
                 −5 
                 745 
                 1358 
                 2573 
                 1762 
                 98.0 
                 0 
                 ◯ 
               
               
                 19 
                 1361 
                 1842 
                 1650 
                 99.0 
                 −25 
                 ◯ 
                 ⊚ 
                 −5 
                 724 
                 1356 
                 2566 
                 1759 
                 98.1 
                 0 
                 ◯ 
               
               
                 20 
                 1351 
                 1814 
                 1636 
                 98.9 
                 −27 
                 ◯ 
                 ⊚ 
                 −7 
                 714 
                 1344 
                 2528 
                 1741 
                 98.0 
                 0 
                 ◯ 
               
               
                 21* 
                 1380 
                 1697 
                 1647 
                 99.2 
                 −35 
                 ◯ 
                 ⊚ 
                 −4 
                 770 
                 1376 
                 2467 
                 1764 
                 
                   
                 
                 0 
                 X 
               
               
                 22 
                 1377 
                 1714 
                 1646 
                 98.9 
                 −34 
                 ◯ 
                 ⊚ 
                 −4 
                 780 
                 1373 
                 2494 
                 1765 
                 97.8 
                 0 
                 ◯ 
               
               
                 23 
                 1376 
                 1727 
                 1647 
                 99.0 
                 −33 
                 ◯ 
                 ⊚ 
                 −3 
                 781 
                 1373 
                 2508 
                 1767 
                 98.8 
                 0 
                 ◯ 
               
               
                 24 
                 1376 
                 1746 
                 1650 
                 99.1 
                 −32 
                 ◯ 
                 ⊚ 
                 −5 
                 778 
                 1371 
                 2524 
                 1767 
                 99.1 
                 0 
                 ◯ 
               
               
                 25 
                 1370 
                 1788 
                 1651 
                 98.8 
                 −29 
                 ◯ 
                 ⊚ 
                 −6 
                 760 
                 1364 
                 2548 
                 1764 
                 99.0 
                 0 
                 ◯ 
               
               
                 26 
                 1369 
                 1805 
                 1653 
                 93.9 
                 −28 
                 ◯ 
                 ⊚ 
                 −6 
                 743 
                 1363 
                 2548 
                 1763 
                 98.9 
                 0 
                 ◯ 
               
               
                 27 
                 1357 
                 1748 
                 1632 
                 98.5 
                 −31 
                 ◯ 
                 ⊚ 
                 −5 
                 732 
                 1352 
                 2480 
                 1742 
                 97.8 
                 0 
                 ◯ 
               
               
                 28* 
                 1384 
                 1672 
                 1647 
                 99.2 
                 −37 
                 ◯ 
                 ⊚ 
                 −12 
                 780 
                 1372 
                 2452 
                 1757 
                 
                   
                 
                 0 
                 X 
               
               
                 29 
                 1385 
                 1677 
                 1648 
                 98.3 
                 −36 
                 ◯ 
                 ⊚ 
                 −8 
                 789 
                 1377 
                 2466 
                 1764 
                 97.7 
                 0 
                 ◯ 
               
               
                 30 
                 1388 
                 1691 
                 1654 
                 98.4 
                 −36 
                 ◯ 
                 ⊚ 
                 −9 
                 791 
                 1379 
                 2482 
                 1769 
                 97.2 
                 0 
                 ◯ 
               
               
                 31 
                 1382 
                 1722 
                 1652 
                 98.3 
                 −31 
                 ◯ 
                 ⊚ 
                 −6 
                 790 
                 1376 
                 2512 
                 1771 
                 97.3 
                 0 
                 ◯ 
               
               
                 32 
                 1386 
                 1759 
                 1662 
                 98.9 
                 −31 
                 ◯ 
                 ⊚ 
                 −14 
                 767 
                 1372 
                 2526 
                 1769 
                 95.7 
                 0 
                 ◯ 
               
               
                 33 
                 1382 
                 1774 
                 1661 
                 98.0 
                 −30 
                 ◯ 
                 ⊚ 
                 −12 
                 750 
                 1370 
                 2524 
                 1766 
                 96.0 
                 0 
                 ◯ 
               
               
                 34 
                 1371 
                 1735 
                 1644 
                 97.7 
                 −32 
                 ◯ 
                 ⊚ 
                 −11 
                 737 
                 1360 
                 2472 
                 1748 
                 95.5 
                 0 
                 ◯ 
               
               
                 35* 
                 1378 
                 1592 
                 1628 
                 99.0 
                 −42 
                 X 
                 ⊚ 
                 −10 
                 780 
                 1368 
                 2372 
                 1741 
                 
                   
                 
                 0 
                 X 
               
               
                 36 
                 1378 
                 1605 
                 1630 
                 99.1 
                 −41 
                 ◯ 
                 ⊚ 
                 −4 
                 792 
                 1374 
                 2397 
                 1751 
                 99.0 
                 0 
                 ◯ 
               
               
                 37 
                 1378 
                 1619 
                 1632 
                 98.9 
                 −40 
                 ◯ 
                 ⊚ 
                 −9 
                 793 
                 1369 
                 2412 
                 1748 
                 98.4 
                 0 
                 ◯ 
               
               
                 38 
                 1377 
                 1655 
                 1637 
                 98.7 
                 −38 
                 ◯ 
                 ⊚ 
                 −12 
                 790 
                 1365 
                 2445 
                 1749 
                 98.5 
                 0 
                 ◯ 
               
               
                 39 
                 1377 
                 1673 
                 1640 
                 98.8 
                 −37 
                 ◯ 
                 ⊚ 
                 −9 
                 774 
                 1368 
                 2447 
                 1752 
                 98.2 
                 0 
                 ◯ 
               
               
                 40 
                 1374 
                 1673 
                 1637 
                 98.5 
                 −36 
                 ◯ 
                 ⊚ 
                 −8 
                 755 
                 1368 
                 2428 
                 1747 
                 98.0 
                 0 
                 ◯ 
               
               
                   
               
               
                 *indicates comparative example 
               
               
                 Δ Br = (Br after Tb diffusion) − (Br before Tb diffusion) 
               
               
                 Δ HcJ = (HcJ after Tb diffusion) − (HcJ before Tb diffusion) 
               
            
           
         
       
     
     
       
         
           
               
               
             
               
                 TABLE 3 
               
             
            
               
                   
               
               
                   
                 R-T-B based sntered magnet composition (before Tb diffusion) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                 R 
                   
                 T 
                   
                 TRE/B 
                 Pr/TRE 
                 14B/ 
                 M 
                   
                   
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Sample  
                 Nd 
                 Pr 
                 Tb 
                 Dy 
                 TRE 
                 Co 
                 Fe 
                 B 
                 (atomic  
                 (atomic 
                 (Fe + Co) 
                 Al 
                 Ga 
                 Cu 
                 Mn 
                 Zr 
                 C 
                 N 
                 O 
               
               
                 No. 
                 (mass %) 
                 (mass %) 
                 (mass %) 
                 (mass %) 
                 (mass %) 
                 (mass %) 
                 mass %) 
                 (mass %) 
                 rato) 
                 rato) 
                 (mass %) 
                 (mass %) 
                 (mass %) 
                 (mass %) 
                 (mass %) 
                 (mass %) 
                 (ppm) 
                 (ppm) 
                 (ppm) 
               
               
                   
               
               
                 *41 
                 17.0 
                 5.7 
                 0.0 
                 
                   
                 
                 30.2 
                 2.0 
                 bal. 
                 0.90 
                 2.46 
                 0.198 
                 0.96 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  42 
                 17.8 
                 5.9 
                 0.0 
                 6.5 
                 30.2 
                 2.0 
                 bal. 
                 0.90 
                 2.47 
                 0.204 
                 0.96 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  43 
                 18.1 
                 6.1 
                 0.0 
                 6.0 
                 30.2 
                 2.0 
                 bal 
                 0.90 
                 2.47 
                 0.210 
                 0.96 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  44 
                 18.5 
                 6.2 
                 0.0 
                 5.5 
                 30.2 
                 2.0 
                 bal. 
                 0.90 
                 2.48 
                 0.213 
                 0.96 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  45 
                 18.9 
                 6.3 
                 0.0 
                 5.0 
                 30.2 
                 2.0 
                 bal. 
                 0.90 
                 2.48 
                 0.216 
                 0.96 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  46 
                 19.3 
                 6.4 
                 0.0 
                 4.5 
                 30.2 
                 2.0 
                 bal. 
                 0.90 
                 2.49 
                 0.219 
                 0.96 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  47 
                 19.6 
                 6.6 
                 0.0 
                 4.0 
                 30.2 
                 2.0 
                 bal. 
                 0.90 
                 2.49 
                 0.226 
                 0.96 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  48 
                 20.0 
                 6.7 
                 0.0 
                 3.5 
                 30.2 
                 2.0 
                 bal. 
                 0.90 
                 2.50 
                 0.229 
                 0.96 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  49 
                 20.4 
                 6.6 
                 0.0 
                 3.0 
                 30.2 
                 2.0 
                 bal. 
                 0.90 
                 2.50 
                 0.232 
                 0.96 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  50 
                 20.8 
                 6.9 
                 0.0 
                 2.5 
                 30.2 
                 2.0 
                 bal. 
                 0.90 
                 2.51 
                 0.235 
                 0.96 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  51 
                 21.9 
                 7.3 
                 0.0 
                 1.0 
                 30.2 
                 2.0 
                 bal. 
                 0.90 
                 2.52 
                 0.247 
                 0.96 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 *52 
                 22.3 
                 7.4 
                 0.0 
                 
                   
                 
                 30.2 
                 2.0 
                 bal. 
                 0.90 
                 2.53 
                 
                   
                 
                 0.96 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 *53 
                 16.6 
                 5.6 
                 0.0 
                 7.5 
                 29.7 
                 2.0 
                 bal. 
                 0.90 
                 2.41 
                 0.198 
                 0.95 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  54 
                 17.4 
                 5.8 
                 0.0 
                 6.5 
                 29.7 
                 2.0 
                 bal. 
                 0.90 
                 2.42 
                 0.204 
                 0.95 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  55 
                 17.8 
                 5.9 
                 0.0 
                 6.0 
                 29.7 
                 2.0 
                 bal. 
                 0.90 
                 2.46 
                 0.207 
                 0.95 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  56 
                 18.1 
                 6.1 
                 0.0 
                 5.5 
                 29.7 
                 2.0 
                 bal. 
                 0.90 
                 2.43 
                 0.214 
                 0.95 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  57 
                 18.5 
                 6.2 
                 0.0 
                 5.0 
                 29.7 
                 2.0 
                 bal. 
                 0.90 
                 2.44 
                 0.217 
                 0.95 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  58 
                 18.9 
                 6.3 
                 0.0 
                 4.5 
                 29.7 
                 2.0 
                 bal. 
                 0.90 
                 2.44 
                 0.220 
                 0.95 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  59 
                 19.3 
                 6.4 
                 0.0 
                 4.0 
                 29.7 
                 2.0 
                 bal. 
                 0.90 
                 2.45 
                 0.223 
                 0.95 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  60 
                 19.6 
                 6.6 
                 0.0 
                 3.5 
                 29.7 
                 2.0 
                 bal 
                 0.90 
                 2.45 
                 0.229 
                 0.95 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  61 
                 20.0 
                 6.7 
                 0.0 
                 3.0 
                 29.7 
                 2.0 
                 bal. 
                 0.90 
                 2.46 
                 0.232 
                 0.95 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  62 
                 20.4 
                 6.8 
                 0.0 
                 2.5 
                 29.7 
                 2.0 
                 bal. 
                 0.90 
                 2.46 
                 0.235 
                 0.95 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  63 
                 21.5 
                 7.2 
                 0.0 
                 1.0 
                 29.7 
                 2.0 
                 bal. 
                 0.90 
                 2.48 
                 0.248  
                 0.95 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 *64 
                 21.9 
                 7.3 
                 0.0 
                 
                   
                 
                 29.7 
                 2.0 
                 bal. 
                 0.90 
                 2.48 
                 
                   
                 
                 0.95 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 *65 
                 16.1 
                 5.4 
                 0.0 
                 
                   
                 
                 28.5 
                 2.0 
                 bal. 
                 0.90 
                 2.32 
                 0.199 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  66 
                 16.5 
                 5.5 
                 0.0 
                 6.5 
                 28.5 
                 2.0 
                 bal. 
                 0.90 
                 2.32 
                 0.202 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  67 
                 16.9 
                 5.6 
                 0.0 
                 6.0 
                 28.5 
                 2.0 
                 bal. 
                 0.90 
                 2.33 
                 0.205 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  68 
                 17.2 
                 5.8 
                 0.0 
                 5.5 
                 26.5 
                 2.0 
                 bal. 
                 0.90 
                 266 
                 0.212 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  69 
                 17.6 
                 5.9 
                 0.0 
                 5.0 
                 28.5 
                 2.0 
                 bal. 
                 0.90 
                 2.34 
                 0.215 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  70 
                 18.0 
                 6.0 
                 0.0 
                 4.5 
                 28.5 
                 2.0 
                 bal. 
                 0.90 
                 2.34 
                 0.218 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  71 
                 18.4 
                 6.1 
                 0.0 
                 4.0 
                 28.5 
                 2.0 
                 bal. 
                 0.90 
                 2.35 
                 0.221 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  72 
                 18.7 
                 6.3 
                 0.0 
                 3.5 
                 28.5 
                 2.0 
                 bal. 
                 0.90 
                 2.35 
                 0.228 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  73 
                 19.1 
                 6.4 
                 0.0 
                 3.0 
                 28.5 
                 2.0 
                 bal. 
                 0.90 
                 2.36 
                 0.231 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  74 
                 19.5 
                 6.5 
                 0.0 
                 2.5 
                 28.5 
                 2.0 
                 bal. 
                 0.90 
                 2.36 
                 0.234 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 *75 
                 21.0 
                 7.0 
                 0.0 
                 
                   
                 
                 28.5 
                 2.0 
                 bal. 
                 0.90 
                 2.38 
                 
                   
                 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 *76 
                 15.4 
                 5.1 
                 0.0 
                 
                   
                 
                 28.0 
                 2.0 
                 bal. 
                 0.90 
                 2.27 
                 0.191 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  77 
                 16.1 
                 5.4 
                 0.0 
                 6.5 
                 28.0 
                 2.0 
                 bal. 
                 0.90 
                 2.28 
                 0.202 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  78 
                 16.5 
                 5.5 
                 0.0 
                 6.0 
                 28.0 
                 2.0 
                 bal. 
                 0.90 
                 2.29 
                 0.205 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  79 
                 16.9 
                 5.6 
                 0.0 
                 5.5 
                 28.0 
                 2.0 
                 bal. 
                 0.90 
                 2.29 
                 0.208 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  80 
                 17.2 
                 5.8 
                 0.0 
                 5.0 
                 28.0 
                 2.0 
                 bal. 
                 0.90 
                 2.30 
                 0.215 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  81 
                 17.6 
                 5.9 
                 0.0 
                 4.5 
                 28.0 
                 2.0 
                 bal. 
                 0.90 
                 2.30 
                 0.219 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  82 
                 18.0 
                 6.0 
                 0.0 
                 4.0 
                 28.0 
                 2.0 
                 bal. 
                 0.90 
                 2.31 
                 0.222 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  83 
                 18.4 
                 6.1 
                 0.0 
                 3.5 
                 28.0 
                 2.0 
                 bal. 
                 0.90 
                 2.31 
                 0.225 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  84 
                 18.7 
                 6.3 
                 0.0 
                 3.0 
                 28.0 
                 2.0 
                 bal. 
                 0.90 
                 2.32 
                 0.232 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                  85 
                 19.1 
                 6.4 
                 0.0 
                 2.5 
                 28.0 
                 2.0 
                 bal 
                 0.90 
                 2.32 
                 0.235 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 *86 
                 20.6 
                 6.9 
                 0.3 
                 
                   
                 
                 28.0 
                 2.0 
                 fca 
                 0.90 
                 2.34 
                 
                   
                 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                   
               
               
                 *indicates comparative example 
               
            
           
         
       
     
     
       
         
           
               
               
               
               
             
               
                 TABLE 4 
               
             
            
               
                   
               
               
                   
                 Before Tb dffusion 
                 Difference due to 
                 After Tb diffusion 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                   
                   
                   
                 Demagnetization factor  
                   
                   
                 Tb diffusion 
                   
                   
                   
                   
                 Demagnetization factor 
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                 Br 
                 HcJ 
                   
                 Hk/HcJ 
                 at high temperature 
                 PI, Hk/HcJ 
                 Corrosion  
                 Δ Br 
                 Δ HcJ  
                 Br 
                 HcJ 
                   
                 Hk/HcJ 
                 at high temperature 
                 PI, Hl/HcJ 
               
               
                 Sample No. 
                 MT 
                 (kA/m) 
                 PI 
                 (%) 
                 (%) 
                 Evaluation 
                 resistance 
                 (mT) 
                 (kA/m) 
                 (mT) 
                 (kA/m) 
                 PI 
                 (%) 
                 (%) 
                 Evaluation 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 *41 
                 
                   
                 
                 2604 
                 
                   
                 
                 98.5 
                 0 
                 X 
                 ⊚ 
                 −7 
                 739 
                 
                   
                 
                 3343 
                 
                   
                 
                 98.3 
                 0 
                 
                   
                 
               
               
                  42 
                 1249 
                 2431 
                 1631 
                 99.5 
                 0 
                 ◯ 
                 ⊚ 
                 −8 
                 755 
                 1241 
                 3186 
                 1741 
                 97.6 
                 0 
                 ◯ 
               
               
                  43 
                 1265 
                 2342 
                 1633 
                 99.6 
                 0 
                 ◯ 
                 ⊚ 
                 −6 
                 725 
                 1259 
                 3067 
                 1741 
                 96.8 
                 0 
                 ◯ 
               
               
                  44 
                 1280 
                 2241 
                 1632 
                 99.7 
                 0 
                 ◯ 
                 ⊚ 
                 −7 
                 756 
                 1273 
                 2997 
                 1744 
                 98.5 
                 0 
                 ◯ 
               
               
                  45 
                 1297 
                 2147 
                 1634 
                 99.4 
                 −3 
                 ◯ 
                 ⊚ 
                 −7 
                 754 
                 1290 
                 2901 
                 1746 
                 97.9 
                 0 
                 ◯ 
               
               
                  46 
                 1309 
                 2061 
                 1633 
                 99.0 
                 −9 
                 ◯ 
                 ⊚ 
                 −7 
                 731 
                 1302 
                 2792 
                 1741 
                 96.8 
                 0 
                 ◯ 
               
               
                  47 
                 1327 
                 1970 
                 1636 
                 98.9 
                 −16 
                 ◯ 
                 ⊚ 
                 −6 
                 743 
                 1321 
                 2713 
                 1747 
                 99.5 
                 0 
                 ◯ 
               
               
                  48 
                 1340 
                 1890 
                 1637 
                 99.2 
                 −22 
                 ◯ 
                 ⊚ 
                 −7 
                 735 
                 1333 
                 2625 
                 1745 
                 98.1 
                 0 
                 ◯ 
               
               
                  49 
                 1358 
                 1794 
                 1640 
                 98.9 
                 −28 
                 ◯ 
                 ⊚ 
                 −7 
                 715 
                 1351 
                 2509 
                 1745 
                 96.8 
                 0 
                 ◯ 
               
               
                  50 
                 1373 
                 1707 
                 1641 
                 99.0 
                 −34 
                 ◯ 
                 ⊚ 
                 −7 
                 735 
                 1366 
                 2442 
                 1750 
                 98.9 
                 0 
                 ◯ 
               
               
                  51 
                 1420 
                 1439 
                 1646 
                 98.9 
                 52 
                 ◯ 
                 ⊚ 
                 −7 
                 722 
                 1413 
                 2161 
                 1752 
                 97.6 
                 −7 
                 ◯ 
               
               
                 *52 
                 1434 
                 
                   
                 
                 1644 
                 98.5 
                 −58 
                 X 
                 ◯ 
                 −7 
                 725 
                 1427 
                 
                   
                 
                 1752 
                 97.6 
                 −13 
                 ◯ 
               
               
                 *53 
                 
                   
                 
                 2570 
                 1636 
                 98.5 
                 0 
                 X 
                 ⊚ 
                 −8 
                 765 
                 
                   
                 
                 3335 
                 1751 
                 96.8 
                 0 
                 ◯ 
               
               
                  54 
                 1266 
                 2392 
                 1642 
                 99.5 
                 0 
                 ◯ 
                 ⊚ 
                 −8 
                 741 
                 1258 
                 3133 
                 1750 
                 98.8 
                 0 
                 ◯ 
               
               
                  55 
                 1280 
                 2299 
                 1641 
                 99.6 
                 0 
                 ◯ 
                 ⊚ 
                 −8 
                 779 
                 1272 
                 3078 
                 1755 
                 97.7 
                 0 
                 ◯ 
               
               
                  56 
                 1297 
                 2205 
                 1643 
                 99.7 
                 0 
                 ◯ 
                 ⊚ 
                 −3 
                 759 
                 1289 
                 2964 
                 1755 
                 98.6 
                 0 
                 ◯ 
               
               
                  57 
                 1313 
                 2125 
                 1647 
                 99.4 
                 −5 
                 ◯ 
                 ⊚ 
                 −7 
                 758 
                 1306 
                 2883 
                 1759 
                 96.6 
                 0 
                 ◯ 
               
               
                  58 
                 1328 
                 2028 
                 1647 
                 99.0 
                 −12 
                 ◯ 
                 ⊚ 
                 −8 
                 741 
                 1320 
                 2769 
                 1755 
                 99.2 
                 0 
                 ◯ 
               
               
                  59 
                 1339 
                 1937 
                 1643 
                 98.9 
                 −18 
                 ◯ 
                 ⊚ 
                 −7 
                 757 
                 1332 
                 2694 
                 1755 
                 97.3 
                 0 
                 ◯ 
               
               
                  60 
                 1360 
                 1857 
                 1652 
                 99.2 
                 −24 
                 ◯ 
                 ⊚ 
                 −8 
                 761 
                 1352 
                 2618 
                 1763 
                 98.1 
                 0 
                 ◯ 
               
               
                  61 
                 1375 
                 1759 
                 1651 
                 98.9 
                 −31 
                 ◯ 
                 ⊚ 
                 −8 
                 781 
                 1367 
                 2540 
                 1766 
                 96.7 
                 0 
                 ◯ 
               
               
                  62 
                 1389 
                 1673 
                 1652 
                 99.0 
                 −37 
                 ◯ 
                 ⊚ 
                 −8 
                 766 
                 1381 
                 2439 
                 1764 
                 98.4 
                 0 
                 ◯ 
               
               
                  63 
                 1435 
                 1407 
                 1656 
                 98.9 
                 −54 
                 ◯ 
                 ⊚ 
                 −8 
                 770 
                 1427 
                 2177 
                 1769 
                 98.5 
                 −6 
                 ◯ 
               
               
                 *64 
                 1451 
                 
                   
                 
                 1658 
                 98.5 
                 −59 
                 X 
                 ◯ 
                 −8 
                 784 
                 1443 
                 
                   
                 
                 1773 
                 97.8 
                 −11 
                 ◯ 
               
               
                 *65 
                 1256 
                 2375 
                 
                   
                 
                 99.5 
                 0 
                 X 
                 ⊚ 
                 −10 
                 760 
                 1246 
                 3135 
                 
                   
                 
                 97.1 
                 0 
                 
                   
                 
               
               
                  66 
                 1273 
                 2301 
                 1634 
                 99.5 
                 0 
                 ◯ 
                 ⊚ 
                 −9 
                 740 
                 1264 
                 3041 
                 1742 
                 96.7 
                 0 
                 ◯ 
               
               
                  67 
                 1289 
                 2202 
                 1635 
                 99.6 
                 0 
                 ◯ 
                 ⊚ 
                 −8 
                 749 
                 1281 
                 2951 
                 1745 
                 97.0 
                 0 
                 ◯ 
               
               
                  68 
                 1305 
                 2108 
                 1636 
                 99.7 
                 −6 
                 ◯ 
                 ⊚ 
                 −10 
                 767 
                 1295 
                 2875 
                 1747 
                 98.4 
                 0 
                 ◯ 
               
               
                  69 
                 1321 
                 2018 
                 1638 
                 99.4 
                 −12 
                 ◯ 
                 ⊚ 
                 −8 
                 741 
                 1313 
                 2759 
                 1746 
                 96.9 
                 0 
                 ◯ 
               
               
                  70 
                 1335 
                 1922 
                 1637 
                 99.0 
                 −19 
                 ◯ 
                 ⊚ 
                 −10 
                 748 
                 1325 
                 2670 
                 1744 
                 97.5 
                 0 
                 ◯ 
               
               
                  71 
                 1351 
                 1840 
                 1640 
                 98.9 
                 −25 
                 ◯ 
                 ⊚ 
                 −8 
                 775 
                 1343 
                 2615 
                 1754 
                 98.8 
                 0 
                 ◯ 
               
               
                  72 
                 1367 
                 1755 
                 1643 
                 99.2 
                 −31 
                 ◯ 
                 ⊚ 
                 −9 
                 738 
                 1358 
                 2493 
                 1750 
                 98.1 
                 0 
                 ◯ 
               
               
                  73 
                 1380 
                 1659 
                 1641 
                 98.9 
                 −33 
                 ◯ 
                 ⊚ 
                 −9 
                 750 
                 1371 
                 2409 
                 1749 
                 97.5 
                 0 
                 ◯ 
               
               
                  74 
                 1396 
                 1569 
                 1643 
                 99.0 
                 −43 
                 ◯ 
                 ⊚ 
                 −9 
                 749 
                 1387 
                 2318 
                 1751 
                 98.8 
                 0 
                 ◯ 
               
               
                 *75 
                 1460 
                 
                   
                 
                 1650 
                 98.5 
                 −66 
                 X 
                 ◯ 
                 −9 
                 759 
                 1451 
                 
                   
                 
                 1760 
                 97.3 
                 −20 
                 ◯ 
               
               
                 *76 
                 1246 
                 2417 
                 
                   
                 
                 98.5 
                 0 
                 X 
                 ⊚ 
                 −9 
                 743 
                 1237 
                 3160 
                 
                   
                 
                 99.0 
                 0 
                 
                   
                 
               
               
                  77 
                 1276 
                 2263 
                 1631 
                 99.5 
                 0 
                 ◯ 
                 ⊚ 
                 −9 
                 761 
                 1267 
                 3024 
                 1742 
                 97.7 
                 0 
                 ◯ 
               
               
                  78 
                 1292 
                 2162 
                 1632 
                 99.6 
                 −1 
                 ◯ 
                 ⊚ 
                 −9 
                 754 
                 1283 
                 2916 
                 1741 
                 99.8 
                 0 
                 ◯ 
               
               
                  79 
                 1306 
                 2068 
                 1631 
                 99.7 
                 −8 
                 ◯ 
                 ⊚ 
                 −10 
                 764 
                 1296 
                 2832 
                 1741 
                 98.5 
                 0 
                 ◯ 
               
               
                  80 
                 1324 
                 1974 
                 1634 
                 99.4 
                 −15 
                 ◯ 
                 ⊚ 
                 −8 
                 735 
                 1316 
                 2709 
                 1742 
                 98.5 
                 0 
                 ◯ 
               
               
                  81 
                 1338 
                 1875 
                 1633 
                 99.0 
                 −22 
                 ◯ 
                 ⊚ 
                 −10 
                 762 
                 1328 
                 2640 
                 1743 
                 97.9 
                 0 
                 ◯ 
               
               
                  82 
                 1356 
                 1799 
                 1639 
                 98.9 
                 −28 
                 ◯ 
                 ⊚ 
                 −9 
                 754 
                 1347 
                 2553 
                 1748 
                 99.5 
                 0 
                 ◯ 
               
               
                  83 
                 1370 
                 1713 
                 1639 
                 99.2 
                 −34 
                 ◯ 
                 ⊚ 
                 −9 
                 742 
                 1361 
                 2455 
                 1747 
                 98.1 
                 0 
                 ◯ 
               
               
                  84 
                 1382 
                 1617 
                 1636 
                 98.9 
                 −40 
                 ◯ 
                 ⊚ 
                 −9 
                 741 
                 1373 
                 2358 
                 1743 
                 96.7 
                 0 
                 ◯ 
               
               
                  85 
                 1399 
                 1526 
                 1639 
                 99.0 
                 −46 
                 ◯ 
                 ⊚ 
                 −8 
                 747 
                 1391 
                 2273 
                 1748 
                 99.2 
                 0 
                 ◯ 
               
               
                 *86 
                 1464 
                 
                   
                 
                 1647 
                 98.5 
                 −69 
                 X 
                 ◯ 
                 −10 
                 741 
                 1454 
                 
                   
                 
                 1754 
                 99.0 
                 −24 
                 ◯ 
               
               
                   
               
               
                 *indicates comparative example 
               
               
                 Δ Br = (Br after Tb diffusion) − (Br before Tb diffusion) 
               
               
                 Δ HcJ = (HcJ after Tb diffusion) − (HcJ before Tb diffusion) 
               
            
           
         
       
     
     
       
         
           
               
               
             
               
                 TABLE 5 
               
             
            
               
                   
               
               
                   
                 R-T-B based sintered magnet composition (before Tb diffusion) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
            
               
                   
                 R 
                   
                   
                 T 
                   
                 M 
                   
                   
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                 Nd 
                 Pr 
                 Tb 
                 Dy 
                 TRE 
                 Pr/TRE 
                 Co 
                 Fe 
                 B 
                 Al 
                 Ga 
                 Cu 
                 Mn 
                 Zr 
                 C 
                 N 
                 O 
               
               
                 Sample No. 
                 (mass %) 
                 (mass %) 
                 (mass %) 
                 (mass %) 
                 (mass %) 
                 (atomic ratio) 
                 (mass %) 
                 (mass %) 
                 (mass %) 
                 (mass %) 
                 (mass %) 
                 (mass %) 
                 (mass %) 
                 (mass %) 
                 (ppm) 
                 (ppm) 
                 (ppm) 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 91 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 0.5 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 92 
                 19.8 
                 6.8 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 1.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 17 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 94 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 3.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 95 
                 19.3 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.15 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 17 
                 13.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 97 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.25 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 98 
                 19.3 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.30 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 99 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.04 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 100 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.10 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 17 
                 19.3 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 102 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.30 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 103 
                 19.3 
                 6.5 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.50 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 104 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.08 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 105 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.10 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 17 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 106 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.25 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 107 
                 19.3 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.30 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 109 
                 19.3 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.10 
                 900 
                 500 
                 500 
               
               
                 17 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 111 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.25 
                 900 
                 500 
                 500 
               
               
                 112 
                 19.3 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.30 
                 900 
                 500 
                 500 
               
               
                 113 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 600 
                 500 
                 500 
               
               
                 114 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 750 
                 500 
                 500 
               
               
                 17 
                 19.3 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 115 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 1000 
                 500 
                 500 
               
               
                 116 
                 19.3 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 1100 
                 500 
                 500 
               
               
                 117 
                 19.3 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 350 
               
               
                 118 
                 19.3 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 400 
               
               
                 17 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 120 
                 19.3 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 800 
               
               
                 121 
                 19.3 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 1000 
               
               
                 122 
                 19.3 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 250 
                 500 
               
               
                 123 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 300 
                 500 
               
               
                 17 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 124 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 600 
                 500 
               
               
                 125 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 700 
                 500 
               
               
                 126 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 1000 
                 500 
               
               
                 127 
                 26.4 
                 0.0 
                 0.0 
                 3.3 
                 29.7 
                 0 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 128 
                 21.4 
                 5.0 
                 0.0 
                 3.3 
                 29.7 
                 0.174 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 17 
                 19.8 
                 6.6 
                 0.0 
                 3.3 
                 29.7 
                 0.229 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                 130 
                 16.4 
                 10.0 
                 0.0 
                 3.3 
                 29.7 
                 0.346 
                 2.0 
                 bal. 
                 0.93 
                 0.20 
                 0.20 
                 0.20 
                 0.03 
                 0.15 
                 900 
                 500 
                 500 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
             
               
                 TABLE 6 
               
             
            
               
                   
               
               
                   
                 Before Tb diffusion 
                 Difference due to  
                 After Tb diffusion 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                   
                   
                   
                 Demagnetization factor 
                   
                   
                 Tb diffusion 
                   
                   
                   
                   
                 Demagnetization factor  
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                 Br 
                 HcJ 
                   
                 Hk/HcJ 
                 at high temperature 
                 PI, Hk/HcJ 
                 Corrosion  
                 Δ Br 
                 Δ HcJ 
                 Br 
                 HcJ 
                   
                 Hk/HcJ 
                 at high temperature 
                 PI, Hk/HcJ 
               
               
                 Sample No. 
                 (mT) 
                 (kA/m) 
                 PI 
                 (%) 
                 (%) 
                 Evaluation 
                 resistance 
                 (mT) 
                 (kA/m) 
                 (mT) 
                 (ka/m) 
                 PI 
                 (%) 
                 (%) 
                 Evaluation 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 91 
                 1372 
                 1753 
                 1647 
                 99.8 
                 −31 
                 ◯ 
                 ◯ 
                 −9 
                 766 
                 1363 
                 2519 
                 1759 
                 98.1 
                 0 
                 ◯ 
               
               
                 92 
                 1372 
                 1762 
                 1649 
                 99.5 
                 −31 
                 ◯ 
                 ⊚ 
                 −8 
                 765 
                 1364 
                 2527 
                 1761 
                 98.1 
                 0 
                 ◯ 
               
               
                 17 
                 1370 
                 1789 
                 1651 
                 99.7 
                 −29 
                 ◯ 
                 ⊚ 
                 −8 
                 761 
                 1362 
                 2550 
                 1763 
                 98.1 
                 0 
                 ◯ 
               
               
                 94 
                 1372 
                 1741 
                 1645 
                 99.5 
                 −32 
                 ◯ 
                 ⊚ 
                 −8 
                 762 
                 1364 
                 2503 
                 1757 
                 98.0 
                 0 
                 ◯ 
               
               
                 95 
                 1373 
                 1754 
                 1654 
                 99.6 
                 −31 
                 ◯ 
                 ⊚ 
                 −7 
                 746 
                 1371 
                 2500 
                 1764 
                 97.9 
                 0 
                 ◯ 
               
               
                 17 
                 1369 
                 1793 
                 1651 
                 99.7 
                 −29 
                 ◯ 
                 ⊚ 
                 −8 
                 761 
                 1361 
                 2554 
                 1762 
                 98.1 
                 0 
                 ◯ 
               
               
                 97 
                 1360 
                 1820 
                 1646 
                 99.5 
                 −27 
                 ◯ 
                 ⊚ 
                 −9 
                 770 
                 1351 
                 2590 
                 1758 
                 98.1 
                 0 
                 ◯ 
               
               
                 93 
                 1354 
                 1842 
                 1643 
                 99.5 
                 −25 
                 ◯ 
                 ⊚ 
                 −11 
                 780 
                 1343 
                 2622 
                 1755 
                 97.8 
                 0 
                 ◯ 
               
               
                 99 
                 1375 
                 1778 
                 1654 
                 99.7 
                 −30 
                 ◯ 
                 ⊚ 
                 −9 
                 741 
                 1366 
                 2519 
                 1762 
                 98.0 
                 0 
                 ◯ 
               
               
                 100 
                 1372 
                 1785 
                 1652 
                 99.5 
                 −29 
                 ◯ 
                 ⊚ 
                 −5 
                 752 
                 1367 
                 2537 
                 1766 
                 97.7 
                 0 
                 ◯ 
               
               
                 17 
                 1370 
                 1789 
                 1651 
                 99.7 
                 −29 
                 ◯ 
                 ⊚ 
                 −8 
                 761 
                 1362 
                 2550 
                 1763 
                 98.1 
                 0 
                 ◯ 
               
               
                 102 
                 1368 
                 1771 
                 1646 
                 99.5 
                 −30 
                 ◯ 
                 ⊚ 
                 −7 
                 790 
                 1361 
                 2561 
                 1763 
                 98.2 
                 0 
                 ◯ 
               
               
                 103 
                 1364 
                 1704 
                 1632 
                 98.5 
                 −34 
                 ◯ 
                 ⊚ 
                 −8 
                 811 
                 1356 
                 2515 
                 1751 
                 97.6 
                 0 
                 ◯ 
               
               
                 104 
                 1373 
                 1769 
                 1651 
                 99.2 
                 −30 
                 ◯ 
                 ⊚ 
                 −9 
                 759 
                 1364 
                 2528 
                 1761 
                 98.3 
                 0 
                 ◯ 
               
               
                 105 
                 1371 
                 1765 
                 1648 
                 99.0 
                 −31 
                 ◯ 
                 ⊚ 
                 −9 
                 759 
                 1362 
                 2524 
                 1758 
                 98.5 
                 0 
                 ◯ 
               
               
                 17 
                 1370 
                 1789 
                 1651 
                 99.7 
                 −29 
                 ◯ 
                 ⊚ 
                 −8 
                 761 
                 1362 
                 2550 
                 1763 
                 98.1 
                 0 
                 ◯ 
               
               
                 106 
                 1371 
                 1793 
                 1653 
                 99.7 
                 −29 
                 ◯ 
                 ⊚ 
                 −9 
                 764 
                 1362 
                 2557 
                 1764 
                 98.3 
                 0 
                 ◯ 
               
               
                 107 
                 1369 
                 1808 
                 1653 
                 99.7 
                 −28 
                 ◯ 
                 ⊚ 
                 −8 
                 768 
                 1361 
                 2576 
                 1766 
                 98.1 
                 0 
                 ◯ 
               
               
                 109 
                 1370 
                 1786 
                 1651 
                 99.5 
                 −29 
                 ◯ 
                 ⊚ 
                 −8 
                 766 
                 1362 
                 2552 
                 1763 
                 98.0 
                 0 
                 ◯ 
               
               
                 17 
                 1370 
                 1789 
                 1651 
                 99.7 
                 −29 
                 ◯ 
                 ⊚ 
                 −8 
                 761 
                 1362 
                 2550 
                 1763 
                 98.1 
                 0 
                 ◯ 
               
               
                 111 
                 1367 
                 1794 
                 1649 
                 99.4 
                 −29 
                 ◯ 
                 ⊚ 
                 −11 
                 759 
                 1356 
                 2553 
                 1757 
                 97.2 
                 0 
                 ◯ 
               
               
                 112 
                 1363 
                 1819 
                 1649 
                 99.2 
                 −27 
                 ◯ 
                 ⊚ 
                 −14 
                 741 
                 1349 
                 2560 
                 1751 
                 97.2 
                 0 
                 ◯ 
               
               
                 113 
                 1363 
                 1835 
                 1651 
                 96.0 
                 −26 
                 ◯ 
                 ⊚ 
                 −3 
                 762 
                 1360 
                 2597 
                 1768 
                 95.8 
                 0 
                 ◯ 
               
               
                 114 
                 1367 
                 1821 
                 1653 
                 95.4 
                 −27 
                 ◯ 
                 ⊚ 
                 −8 
                 770 
                 1359 
                 2591 
                 1766 
                 95.4 
                 0 
                 ◯ 
               
               
                 17 
                 1370 
                 1789 
                 1651 
                 99.7 
                 −29 
                 ◯ 
                 ⊚ 
                 −8 
                 761 
                 1362 
                 2550 
                 1763 
                 98.1 
                 0 
                 ◯ 
               
               
                 115 
                 1373 
                 1785 
                 1653 
                 99.5 
                 −29 
                 ◯ 
                 ⊚ 
                 −9 
                 741 
                 1364 
                 2526 
                 1761 
                 98.0 
                 0 
                 ◯ 
               
               
                 116 
                 1376 
                 1778 
                 1655 
                 99.6 
                 −30 
                 ◯ 
                 ⊚ 
                 −11 
                 720 
                 1365 
                 2498 
                 1757 
                 98.0 
                 0 
                 ◯ 
               
               
                 117 
                 1308 
                 1809 
                 1652 
                 99.5 
                 −28 
                 ◯ 
                 ⊚ 
                 −8 
                 747 
                 1360 
                 2556 
                 1761 
                 98.2 
                 0 
                 ◯ 
               
               
                 118 
                 1371 
                 1804 
                 1654 
                 99.3 
                 −28 
                 ◯ 
                 ⊚ 
                 −7 
                 754 
                 1364 
                 2558 
                 1766 
                 97.9 
                 0 
                 ◯ 
               
               
                 17 
                 1370 
                 1789 
                 1651 
                 99.7 
                 −29 
                 ◯ 
                 ⊚ 
                 −8 
                 761 
                 1362 
                 2550 
                 1763 
                 98.1 
                 0 
                 ◯ 
               
               
                 120 
                 1371 
                 1775 
                 1650 
                 99.5 
                 −30 
                 ◯ 
                 ⊚ 
                 −7 
                 784 
                 1364 
                 2559 
                 1766 
                 98.0 
                 0 
                 ◯ 
               
               
                 121 
                 1370 
                 1753 
                 1645 
                 99.2 
                 −31 
                 ◯ 
                 ⊚ 
                 −8 
                 791 
                 1362 
                 2544 
                 1762 
                 98.0 
                 0 
                 ◯ 
               
               
                 122 
                 1368 
                 1808 
                 1652 
                 99.8 
                 −28 
                 ◯ 
                 ⊚ 
                 −7 
                 780 
                 1361 
                 2588 
                 1768 
                 98.1 
                 0 
                 ◯ 
               
               
                 123 
                 1370 
                 1808 
                 1654 
                 99.7 
                 −28 
                 ◯ 
                 ⊚ 
                 −8 
                 778 
                 1362 
                 2586 
                 1768 
                 98.2 
                 0 
                 ◯ 
               
               
                 17 
                 1370 
                 1789 
                 1651 
                 99.7 
                 −29 
                 ◯ 
                 ⊚ 
                 −8 
                 761 
                 1362 
                 2550 
                 1763 
                 98.1 
                 0 
                 ◯ 
               
               
                 124 
                 1372 
                 1785 
                 1652 
                 99.6 
                 −29 
                 ◯ 
                 ⊚ 
                 −9 
                 749 
                 1363 
                 2534 
                 1761 
                 98.0 
                 0 
                 ◯ 
               
               
                 125 
                 1371 
                 1776 
                 1650 
                 99.3 
                 −30 
                 ◯ 
                 ⊚ 
                 −9 
                 735 
                 1362 
                 2511 
                 1756 
                 98.0 
                 0 
                 ◯ 
               
               
                 126 
                 1368 
                 1758 
                 1644 
                 99.1 
                 −31 
                 ◯ 
                 ⊚ 
                 −7 
                 725 
                 1361 
                 2483 
                 1751 
                 98.0 
                 0 
                 ◯ 
               
               
                 127 
                 1371 
                 1775 
                 1650 
                 99.6 
                 −30 
                 ◯ 
                 ⊚ 
                 −7 
                 760 
                 1364 
                 2535 
                 1762 
                 98.2 
                 0 
                 ◯ 
               
               
                 128 
                 1369 
                 1781 
                 1649 
                 99.6 
                 −29 
                 ◯ 
                 ⊚ 
                 −7 
                 758 
                 1362 
                 2539 
                 1761 
                 98.1 
                 0 
                 ◯ 
               
               
                 17 
                 1370 
                 1789 
                 1651 
                 99.7 
                 −29 
                 ◯ 
                 ⊚ 
                 −8 
                 761 
                 1362 
                 2550 
                 1763 
                 98.1 
                 0 
                 ◯ 
               
               
                 130 
                 1369 
                 1804 
                 1652 
                 99.7 
                 −28 
                 ◯ 
                 ⊚ 
                 −8 
                 763 
                 1361 
                 2567 
                 1764 
                 98.1 
                 0 
                 ◯ 
               
               
                   
               
               
                 Δ Br = (Bt ater Tb diffusion) − (Br before Tb diffusion) 
               
               
                 Δ HcJ = (HcJ aterTb dffjsion) − (HcJ before Tb diffusion) 
               
            
           
         
       
     
     In Table 1, TRE and B were varied. Also, Nd and Pr were included so that the mass ratio of Nd and Pr were approximately 3:1. Results are shown in Table 2. In Table 3, TRE and Dy were varied. Results are shown in Table 4. For the sample numbers 91 to 126 shown in Table 5, the contents of components other than R and B were varied. Also, for the sample numbers 127 to 130 shown in Table 5, the content of TRE and Dy were fixed, and the content of Nd and Pr were varied. Results are shown in Table 6. 
     According to Tables 1 to 6, in all Examples, Br, HcJ, PI, the squareness ratio, and the corrosion resistance before Tb diffusion were good. Moreover, in all Examples, Br, HcJ, PI, and the squareness ratio after Tb diffusion were also good. On the other hand, in all Comparative Examples, at least one of Br, HcJ, PI, and the squareness ratio before Tb diffusion as well as Br, HcJ, PI, and the squareness ratio after Tb diffusion was not good. 
     The example having the content of Dy of 2.5 mass % or more and 6.5 mass % or less tended to have good demagnetization factor at high temperature. 
     The example having the content of Co of 1.0 mass % or more, the content of Cu of 0.10 mass % or more, and Pr/TRE of less than 0.250 tended to have good corrosion resistance. 
     Further, the example having the content of C of 900 ppm to 1100 ppm tended to have good squareness ratio. 
     Also, for the R-T-B based permanent magnet after diffusion of Tb shown in Tables 1 to 6, Tb concentration distribution was measured using an electron probe micro analyzer (EPMA). As a result, it was confirmed that Tb concentration decreases from outside to inside of the R-T-B based permanent magnets after Tb diffusion.