Patent Publication Number: US-4320113-A

Title: Process for controlling cockroaches and other crawling insects

Description:
This application is a continuation of U.S. Ser. No. 603,052, filed Aug. 8, 1975, now U.S. Pat. No. 4,102,991. 
    
    
     BACKGROUND OF THE INVENTION 
     1. Field of the Invention 
     The present invention relates to a process for controlling cockroaches and other crawling insects by the deployment, in insect crawl and harborage areas in residential and commercial buildings, of polymeric controlled release dispensers containing selected toxicants found to have unusually effective knockdown (KD) and kill efficacy for crawling insects based upon fairly short periods of contact between the insect and the dispenser. 
     2. Description of the Prior Art 
     Various species of crawling insects, especially the hard-to-kill cockroach, have been a target for eradication by man for centuries. Lately, pesticides have been developed which have high toxicity for cockroaches, but such pesticides frequently present environmental hazards when used in effective concentrations. The repeated application of low concentrations of available chemical toxicants reduces the danger to the environment but is also less effective and relatively more expensive. Accordingly, attempts have been made to develop methods and products for the controlled release of crawling insect toxicants over extended periods of time in a manner which is relatively less dangerous to man&#39;s environment and also is effective to protect the toxicants from premature degradation. 
     According to the prior art, insect repellent fabrics in the form of tapes or strips have previously been provided which comprise laminated materials at least one layer of which contains an insecticide, alone or in combination with insect baits or attractants. Representative of this prior art are U.S. Pat. No. 2,911,756--Geary and U.S. Pat. No. 3,295,246--Landsman et al., although the foregoing references are by no means exhaustive of the prior disclosures concerned with toxicant carriers for pest control. In the Geary patent a flexible sheet or strip is provided with a pressure-sensitive adhesive on one side for mounting the strip on a surface. The other side is provided with an insecticidal and insect attracting composition. An intermediate layer may be provided between the insecticidal composition and the substrate layer, such as cellulose fibers, matted, felted or otherwise joined and bonded to the flexible sheet. When the insecticidal insect attracting compositions are applied to the intermediate layer, the composition is said to be absorbed and kept in close contact therewith. Such devices, of which the Geary structure is typical, have been generally objectionable for a number of reasons, including (1) the external availability on the exposed surface of the dispenser of the main concentration of toxicant, (2) the lack of protection of the toxicant from atmospheric conditions which may result in rapid loss of efficiency, (3) the relatively low control over the rate at which the toxicant becomes available to the environment, and (4) the lack of structural protection of the toxicant layer from abrasion or other mechanical attrition. 
     The structure disclosed in the Landsman et al patent remedies some of the foregoing deficiencies of Geary by providing a protective surface coating on the laminated insect repellent tape. The essential feature of the Landsman et al structure is said to be the provision of an absorbent paper core layer saturated with a residual insecticide. The tape is then coated with a light (thin) resinous solution of vinyl or polyethylene or nylon merely to form a surfacing without forming a substantial layer on the exterior face of the tape. Such structures, with their fragile outer facings, are subject to rupture with the possible result of rapid loss of the insecticide which is merely absorbed in the absorbent core layer of paper or other porous material and the certain result of external availability of the toxicant. Further, such structures would appear to fail to adequately protect the toxicant from degradation due to atmospheric exposure, and to provide minimal control over rate of release of the toxicant. 
     The assignee of the present application has also developed a new technology for imparting active properties to the surfaces of solid, non-porous polymeric substrate materials by a technique which comprises applying to selected solid, non-porous polymeric substrate materials a solid, non-porous layer of a polymeric composition containing selected activating agents capable of migrating from the layer into and throughout the substrate. The migrating agents are incorporated in the layer in an amount sufficient to produce an effective level of activity on the exterior surface of the substrate. The application of the Herculite technology, known in the industry as the HERCON process, to the production of pesticidally active polymeric materials is generally described in U.S. Pat. Nos. 3,705,938, 3,857,934 and 3,864,468. Additionally, the assignee of this application is also the assignee of pending Application Ser. No. 535,658 in the names of Henry Von Kohorn and myself which relates to pesticide dispensers also based upon the HERCON technology. 
     Applicant is also aware of polymeric controlled release dispensers commercially available from the Shell Corporation which have generally been employed to control flying insects. These dispensers comprise a volatile toxicant known as `dichlorvos` or DDVP, which is released into the surrounding atmosphere and which provides a fumigant action in the treated space. Where the space to be treated is unventilated, satisfactory control of crawling insects may be achieved with such fumigant-action dispensers, but in well ventilated rooms this method of control is less effective. Due to the high volatility of DDVP the dispensers tend to lose their efficacy fairly rapidly and the toxicant odors are bothersome to many people. 
     The present most widely employed approaches for the control of crawling insects involve the use of sprays which are environmentally or aesthetically generally unacceptable for residential use due to persistant toxicity of materials dangerous to man or animals or unpleasant non-toxicity effects, such as unpleasant odors, staining of surfaces, etc. Additionally, where non-persistent toxicants are employed in sprays, the effective life is short, and therefore expensive and inconvenient reapplications are required to achieve even a minimally acceptable level of control. 
     Accordingly, an object of the present invention is to provide an effective method for controlling cockroaches and other crawling insects which provides prolonged residual effect, minimizes environmental hazards and prevents premature degradation or loss of the toxicant. 
     DETAILED DESCRIPTION OF THE INVENTION 
     The process of this invention comprises controlling cockroaches and other crawling insects in buildings by deploying in the crawl paths and harborages of the cockroaches and other crawling insects polymeric controlled release dispensers containing a non-volatile toxicant in sufficient amount such that the toxicant is present on the surfaces of the dispensers in a concentration of from about 50 to 500 mg/sq.ft., and preferably from about 100 to 350 mg/sq.ft. of dispenser active surface area. A plurality of dispensers are preferably provided which have an aggregate active surface area of from about 1/3 to 3 sq.ft., per average sized room of 100 to 150 sq.ft. The non-volatile toxicant is one capable of killing roaches and other insects after the insects have had direct contact with a dispenser for only relatively short periods of time. 
     In a preferred embodiment the dispensers are provided in the form of tapes about 1 inch wide and 4 inches long and having a pressure-sensitive adhesive backing. The tapes are deployed by adhesively applying them to known insect crawl paths and harborages and by stuffing the tapes into cracks, crevices, piping holes or other apertures which provide insect ingress or egress. 
     While any suitable polymeric controlled release dispenser may be employed, a preferred dispenser for use in the process is described in copending Application Ser. No. 603,053, filed Aug. 8, 1975 in my name. Typically, the dispensers comprise a layer of barrier material, such as MYLAR or Nylon, having a pressure-sensitive adhesive on one side. On the other surface of the barrier layer there is applied a polymeric layer, e.g., a polyvinyl chloride plastisol layer containing a non-volatile toxicant. Over the plastisol layer there is applied a solid, non-porous polymeric layer e.g., a layer of polyvinyl chloride. The toxicant is present in an amount sufficient to provide a surface concentration, usually of about 50 to 500 mg./sq.ft., which has been found to achieve effective levels of knockdown and kill even upon brief contact with roaches or other crawling insects. In the preferred dispensers, the barrier layer blocks the progress of the toxicant towards the adhesive coated surface of the tape, but molecular migration allows certain toxicants to pass through the outer polyvinyl chloride layer and reach the exposed surface of the tape, thus providing an active surface. During the active life of the dispensers, the amount of toxicant in the body of the tape will be adequate to replace the toxicant depleted from the surface and maintain the surface concentration in the effective desired range of 50 to 500 mg. for extended periods of time. 
     Other less effective but satisfactory controlled release dispensers for use in this invention comprise strips, tapes and films (or other configurations) of solid, polymeric materials, usually thermoplastics, into which effective amounts of non-volatile toxicants may be blended by milling or other processes and from which the toxicant will be gradually released over an extended period of time. 
     In practicing the invention with respect to single or multi-ply polymer sheet applications, there may be used as the sheet of polymer, any polymeric material which is capable of being formed into a self-supporting continuous sheet or film, having adequate mechanical properties to withstand normal handling, abrasion, etc. The polymeric material in sheet form must be substantially non-porous. Suitable materials include various hydrocarbon polymers, such as, rubber, and olefins, for example, polyethylene and polypropylene, imide, amide, ester, urethane, carbonate, cellulosic, halocarbon, ionomer, vinyl, such as polyvinyl chloride, polyvinylidene chloride, polyvinyl acetate, and other polymers, and their blends, interpolymers and copolymers. 
     Non-volatile toxicants suitable for use in the foregoing dispensers include, but are not limited to, chlorpyrifos, diazinon, chlordane, carbaryl, malathion, resmethrin, bioresmethrin, propoxur, fenchlorphos, 2-(1,2-dioxolan-2-yl)phenyl-n-methylcarbamate, 2-2-dimethyl-1,3-benzodioxol-4-ol methylcarbamate and Velsicol&#39;s organo phosphate compound Vel-4283. 
     The amount of active surface area of dispensers necessary to give effective control may, of course, be adjusted, depending on the size of the space, prevailing sanitary conditions, ease of insect access, etc. 
     In addition to the use of a pressure-sensitive adhesive backing, which is preferred, the dispensers may be deployed in accordance with the invention by any practical means, such as by the use of staples or tacks, by means of clips for pipes, ridges or other non-planar surfaces, by the use of separate adhesive tape materials, etc. 
     The amounts of toxicant (and attractants which optionally may be employed) are not critical, nor is the thickness of the polymeric layer or layers, in the case of the preferred multi-layer dispenser. Concentrations and material thicknesses will ordinarily be selected to achieve certain objectives in terms of useful life, flexibility, and other properties such as color, ability to create artificial harborages, etc. 
     In the case of using multi-layer dispensers, as described above, which include a blocking or barrier function, the barrier layers may be composed of polymers containing blocking plasticizers or may be formed from relatively migration resistant polymers, such as, polyamides and polyesters, e.g., Nylon and MYLAR. The latter materials are not resistant to migration of all active materials as has been disclosed in the issued Herculite patent describing the basic HERCON technology, but they are sufficiently resistant to the preferred toxicants identified above largely to control and direct migration of the toxicants through the desired surface layer. 
     The preferred multi-layer, polymeric dispensers are tough, flexible laminates of integrally bonded layers and are highly resistant to mechanical destruction which could result in accidental and rapid loss of the active agent to the environment. The multi-layer polymeric controlled release dispensers, as well as the homogeneous extruded polymeric dispensers, may be used in any configuration or as part of any structural assembly suited to maximize efficacy against crawling insects, such as cockroaches. Forms such as adhesive backed sheets or strips and confetti are useful. The material may also be incorporated into loops, shelters, traps or the like. A particularly preferred embodiment of the invention comprises a strip of the laminated material provided with a pressure-sensitive adhesive coating on all or part of one surface to facilitate locating the dispenser in a manner to allow maximum effect against crawling insects, such as cockroaches. 
     The preferred multi-layer polymeric dispensers for use in the process of this invention have the unique ability to protect active ingredients from degradation, thus prolonging the effective life of the insecticide without increase its persistence in the environment. 
    
    
     More specific aspects of this invention will be appreciated in view of the following examples which at the outset demonstrate the efficacy of the preferred dispensers against roaches, and which then proceed to demonstrate the efficacy of the process of the present invention. 
     EXAMPLE 1 
     A sheet of polyvinylchloride film having a thickness of 0.004 inch was coated with plastisol coating prepared by dispersing 100 parts of polyvinylchloride resin in about 25 parts of dioctylphthalate and then dispersing 120 parts of chlorpyrifos into the 125 parts of plastisol. The plastisol thus prepared was mixed until uniform and the coating was applied to the base sheet of polyvinylchloride in a thickness of about 0.02 inches. The coated polyvinylchloride film was then overlaid with a second sheet of polyvinylchloride also having a thickness of 0.004 inches. The assembled layers were then laminated under suitable conditions of heat and pressure until an integral firmly bonded product was obtained. The laminated structure thus produced contained approximately 30.8% chlorpyrifos insecticide based on the total weight of the laminate. 
     Additional dispensers were prepared in accordance with the procedure described in Example 1 but replacing the active agent as follows: 
     
         ______________________________________                                    
Example 2      Malathion       5%                                         
Example 3      Malathion      33.7%                                       
Example 4      Chlorpyrifos    5%                                         
Example 5      Chlordane       5%                                         
Example 6      Chlordane      20.7%                                       
Example 7      Diazinon       21.2%                                       
Example 8      Carbaryl       22.7%                                       
Example 9      Propoxur       10%                                         
______________________________________                                    
 
    
     The testing was performed by the methods developed by J. M. Grayson and H. G. Townsend and described in Pest Control, 30(6), Page 14 (1962) and by J. M. Grayson in Pest Control, February (1970). Two tempered masonite panels, held apart by staples, were placed in the bottom of a one gallon glass jar to provide a hiding place for the insects. The polymeric dispenser was placed on the top of the bottom panel. A sample of 30 female cockroaches was placed in each jar and observations on mortality were then made. In the case of the low concentration (5%) dispensers, the mortality (dead or moribund) was observed after six days; in the case of the high concentration dispensers, mortality was observed at the end of one day, three days and six days. The test with the high concentration dispensers was also repeated after 60 days and 150 days after the date of preparation of the dispensers. The results of this testing are shown in Table 1. 
     
                                           TABLE 1                                 
__________________________________________________________________________
            %           % Mortalities.sup.(1) After                       
            Active                                                        
                  Cockroach                                               
                        Specified Time of Aging                           
Ex. No.                                                                   
     Insecticide                                                          
            Ingredient                                                    
                  Strain                                                  
                        2 days   60 days  150 days                        
__________________________________________________________________________
4    chlorpyrifos                                                         
            5     diazinon-r                                              
                        -- -- 73 -- -- -- -- -- --                        
                  Normal                                                  
                        -- -- 100                                         
                                 -- -- -- -- -- --                        
1           30.8  diazinon-r                                              
                        100                                               
                           100                                            
                              100                                         
                                 100                                      
                                    100                                   
                                       100                                
                                          100                             
                                             100                          
                                                100                       
                  Normal                                                  
                        100                                               
                           100                                            
                              100                                         
                                 100                                      
                                    100                                   
                                       100                                
                                          100                             
                                             100                          
                                                100                       
5    chlordane                                                            
            5     diatinon-r                                              
                        -- -- 100                                         
                                 -- -- -- -- -- --                        
                  Normal                                                  
                        -- -- 100                                         
                                 -- -- -- -- -- --                        
6           20.7  diazinon-r                                              
                        0  67 74 97 97 100                                
                                          71 97 100                       
                  Normal                                                  
                        63 97 97 100                                      
                                    100                                   
                                       100                                
                                          97 100                          
                                                100                       
2    malathion                                                            
            5     diazinon-r                                              
                        -- -- 0  -- -- -- -- -- --                        
                  Normal                                                  
                        -- -- 77 -- -- -- -- -- --                        
3           33.7  diazinon-r                                              
                        0  23 53 41 71 90 83 100                          
                                                100                       
                  Normal                                                  
                        77 97 97 100                                      
                                    100                                   
                                       100                                
                                          100                             
                                             100                          
                                                100                       
7    diazinon                                                             
            21.2  diazinon-r                                              
                        30 93 100                                         
                                 97 100                                   
                                       100                                
                                          100                             
                                             100                          
                                                100                       
                  Normal                                                  
                        97 97 100                                         
                                 100                                      
                                    100                                   
                                       100                                
                                          100                             
                                             100                          
                                                100                       
8    carbaryl                                                             
            22.7  diazinon-r                                              
                        0  0  0  3  3  17 3  10 53                        
                  Normal                                                  
                        3  13 16 77 100                                   
                                       100                                
                                          81 93 100                       
__________________________________________________________________________
 .sup.(1) Under each column the first figure is the percentage mortality a
 the end of a 1day exposure period, the second figure is the same for a 3 
 day exposure period and the third firure is the same for a 6day period.  
 
    
     After two days of aging and six days of exposure to the dispenser, diazinon killed all of the female German cockroaches in both strains. Malathion also was effective in killing cockroaches in a normal strain, but not in the diazinon-resistant strain. Chlorpyrifos was the most effective of the treatments, as it gave complete kill of cockroaches in both strains at the end of one day of exposure. Chlordane was reasonably effective against the normal strain, but only moderately effective against the diazinon-resistant strain. Carbaryl exhibited little activity against cockroaches in either strain. 
     The dispensers were then aged and retested. The results, as seen in Table 1, after sixty (60) and one hundred and fifty (150) days of aging are generally better than those obtained after two (2) days of aging. This may be explained by the fact that it takes a period of time, sometimes several days or more, depending on the toxicant, and polymer laminate system for the toxicant to migrate and allow the dispenser to become fully functional. Thus, diazinon, chlorpyrifos and chlordane gave complete kill of normal and diazonon resistant cockroaches after six days of exposure to the dispensers which had been aged for 60 days. Malathion gave complete kill of normal strain and better kill of diazinon-resistant cockroaches than was the case in the first test. Carbaryl gave the poorest results on the diazinon-resistant strain, but produced complete kill of the normal cockroaches after six days of exposure. The results after 150 days of aging do not show any signs of diminishing effectiveness. 
     Grayson, in his continuous study (Pest Control, February, 1972) to find chemicals that will be effective as residual applications against resistant and susceptible strains of German roaches used chlorpyrifos, diazinon, chlordane and malathion oil sprays as controls in his experiments. The test method used was the same as described above and the deposit of insecticide on the masonite panels was approximately 150 mg/ft. 2  The results obtained by Grayson are shown in Table 2. A comparison of the data in Tables 1 and 2 shows that the present dispensers give superior results, especially after two months of aging. 
     
                       TABLE 2                                                     
______________________________________                                    
Percentage Mortalities at the end of one, three and six days.sup.1        
following exposure of female German cockroaches to panels                 
which had been treated with different insecticides and the deposits       
allowed to age for various periods of time. (Testing done at              
Blacksburg, Virgina, 1971)                                                
       Cockroach                                                          
               Age of Insecticide Deposits (Days)                         
Insecticide.sup.2                                                         
         Strain.sup.3                                                     
                   2 Days       60 Days                                   
______________________________________                                    
malathion                                                                 
         diazinon-R                                                       
                   48     92   100  4    18   56                          
3.0%     Normal    97     99   100  44   90   99                          
oil-base                                                                  
chlorpyrifos                                                              
         diazinon-R                                                       
                   56     100  100  0    8    46                          
0.5%     Normal    99     100  100  59   97   99                          
oil-base                                                                  
chlordane                                                                 
         diazinon-R                                                       
                   52     74   92   14   56   82                          
3.0%     Normal    100    100  100  29   100  100                         
oil-base                                                                  
diazinon diazinon-R                                                       
                   82     100  100  4    16   34                          
1.0%     Normal    100    100  100  82   100  100                         
oil-base                                                                  
______________________________________                                    
 .sup.1 Under each column the first figure is the percentage mortality at 
 the end of a 1day exposure period, the second is for a 3day exposure     
 period, and the third figure is for a 6day period.                       
 .sup.2 All materials were applied on a weight/volume basis. The deposit o
 insecticide was approximately 150 mg/sq. ft. from 1.0% formulations.     
 .sup.3 Tests with normal strain were replicated 4 times. Duplicate tests 
 were made with strains resistant to diazinon or malathion, making a total
 of 4 replicates with resistant strains.                                  
 
    
     EXAMPLE 10 
     A synthetic pyrethroid (d-trans resmethrin, also known as bioresmethrin) was incorporated into a dispenser constructed in accordance with Example 1 at a concentration of 12.5% of the total weight and the dispenser was evaluated in sheet as well as 1/8&#34; confetti form in tests against adult, male German cockroaches. Squares of active sheet dispenser were sealed to the upper surfaces of 3&#34;×3&#34; glass plates, with opaque plates mounted 3/16&#34; above these surfaces to give the insects a hiding place. These assemblies were then placed in containers with 20-100 adult, male German cockroaches and knockdown and kill counts were made as shown in Table 3. The insects and the opaque covers were removed after 48 hours so the active dispenser was fully exposed to ambient laboratory lights (65 fc), temperature (80° F.), and humidity (50% RH) until the next test period. The dispenser was compared with the untreated PVC control and with filter paper surfaces treated with bioresmethrin (12.5% of total wt.). The &#34;confetti&#34; form dispenser (2542 mg) was compared with an equal weight of No. 1 Whatman filter paper containing 12.5% pyrethroid by continuous exposure of adult, German cockroaches to the treated materials in larger crystallizing dishes. 
     The sheet dispenser containing synthetic pyrethroid continued to show good knockdown and kill of the insects after 34 days in the laboratory, while the treated filter paper rapidly decreased in activity to a complete loss of effectiveness at the 15 day test. Similarly, the confetti gave high activity through the 15 day period, with loss of effectivenes at the 29 day reading, but the treated filter paper was active only on the first test day (Table 3). 
     The sheet and confetti forms of the dispensers of this invention containing the bioresmethrin dramatically extended the residual activity of this light degradable compound. 
     
                                           TABLE 3                                 
__________________________________________________________________________
Tests Against Adult, Male German Cockroaches (Hazard Strain) With         
Dispensers Containing Bioresmethrin*                                      
           Total                                                          
                Knockdown (%)     Dead and                                
           No.  15 30 45 60 90 120                                        
                                  Moribund (%)                            
Material                                                                  
        Days                                                              
           Roaches                                                        
                Min.                                                      
                   Min.                                                   
                      Min.                                                
                         Min.                                             
                            Min.                                          
                               Min.                                       
                                  24 Hr.                                  
                                      48 Hr.                              
__________________________________________________________________________
        Sheet Form - (Average of 5 Replicates)                            
Dispenser with                                                            
        1  98   13 17 20 24 24 28 52  79                                  
12.5%   8  100  3  15 27 29 32 33 57  74                                  
bioresmethrin                                                             
        15 98   19 35 52 58 59 59 86  91                                  
        29 100  9  23 31 35 37 37 97  100                                 
        34 100  3  13 43 48 62 70 94  98                                  
PVC Control                                                               
        1  100  0  0  0  0  0   0  1   1                                  
Dispenser                                                                 
        8  100  0  0  0  0  0   0  0   1                                  
(Untreated)                                                               
        15 100  0  0  0  0  0   0  0   0                                  
        29 100  0  0  0  0  0   0   0 14                                  
        34 100  0  0  0  0  0   0  0   0                                  
Filter Paper                                                              
        1  99   30 55 69 73 75 74 86  91                                  
with 12.5%                                                                
        8  98   0  1  1  2  13 19 26  37                                  
bioresmethrin                                                             
        15 100  0  0  0  0  0   0  0   0                                  
        Confetti Form - (Continuous Exposure)                             
Dispenser with                                                            
        1  20   25 90 90 95 95 100*                                       
                                  100 100                                 
12.5%   8  20   20 75 95 95 100                                           
                               100*                                       
                                  100 100                                 
bioresmethrin                                                             
        15 19   21 74 84 95 95 95 100*                                    
                                      100                                 
        29 20   0  0  0  0  0   0  4  13                                  
        34 20   0  0  0  0  0   0  0   2                                  
Filter Paper                                                              
        1  20   90 100                                                    
                      100                                                 
                         100                                              
                            100                                           
                               100*                                       
                                  100 100                                 
with 12.5%                                                                
        8  20   0  0  0  0  0   0  0   5                                  
bioresmethrin                                                             
        15 20   0  0  0  0  0   0  0   0                                  
__________________________________________________________________________
 *Cockroaches removed to clear containers for remainder of observations   
 
    
     
                                           TABLE 4                                 
__________________________________________________________________________
Residual evaluation of Herculite fabric dispensers on plywood against     
normal                                                                    
Blattella germanica. (Dispensers are stapled on plywood for standard      
exposure method;                                                          
2 tests with 10 adult males each; 30-min exposure; mortality assessed     
after 48 hrs.)                                                            
            Percent Mortality on Treated Fabrics After Indicated          
            Week of Testing.sup.a                                         
            Residues on Herculite Fabric Dispensers                       
            Conc:                                                         
Ex. No.                                                                   
     Insecticide:                                                         
            (%) 0.sup.b                                                   
                   1  2  4  8  40 44 48 52                                
__________________________________________________________________________
11   Carbaryl                                                             
            22  0  0  0  0  0  0  0  0  0                                 
12   Chlordane                                                            
            40  100                                                       
                   100                                                    
                      100                                                 
                         100                                              
                            100                                           
                               100                                        
                                  100                                     
                                     100                                  
                                        100                               
13   Chlorpyrifos                                                         
            27  100                                                       
                   100                                                    
                      100                                                 
                         100                                              
                            100                                           
                               100                                        
                                  100                                     
                                     100                                  
                                        100                               
14   Diazinon                                                             
            21  100                                                       
                   100                                                    
                      100                                                 
                         100                                              
                            100                                           
                               100                                        
                                  100                                     
                                     100                                  
                                        100                               
15   Malathion                                                            
            25  0  0  0  0  0  0  0  0  0                                 
16   Propoxur                                                             
            23  100                                                       
                   100                                                    
                      100                                                 
                         100                                              
                            100                                           
                               100                                        
                                  100                                     
                                     100                                  
                                        100                               
__________________________________________________________________________
 .sup.a No mortality in checks                                            
 .sup.b Aged 2 hrs.                                                       
 
    
     
                       TABLE 5                                                     
______________________________________                                    
5% Propoxur*                                                              
            % Knockdown, min.                                             
                          % Dead, Days                                    
Exposure Time                                                             
            After Exposure                                                
                          After Exposure                                  
(seconds)   20     30      50   1    2     3                              
______________________________________                                    
 2          30      85     100   0   60    100                            
10          50     100     --    5   90    100                            
30          65     100     --   10   95    100                            
60          35     100     --   10   90    100                            
120         60     100     --   15   100   --                             
240         85     100     --   20   100                                  
Control      0      0       0    0    0     0                             
______________________________________                                    
 *o-isopropoxyphenyl methylcarbamate or 2(1-methylethoxy)phenol           
 methylcarbamate                                                          
 
    
     It will be seen from the data Table 5 that surprisingly high knockdown and mortality rates were realized after extremely brief contact times. For example, after exposure for only two seconds, 100% of the roaches were dead three days after the exposure. As the exposure times were increased from 2 to 240 seconds, however, much faster knockdown rates were observed and 100% mortality was achieved two days after exposure where the exposure span was 120 seconds. 
     EXAMPLES 18-19 
     Dispensers were prepared generally in accordance with Example 1 but 10% chlorpyrifos and 9% diazinon respectively, were incorporated in the structure. It will be seen from Tables 6 and 7 that somewhat longer exposure times are required to achieve 100% mortality using these agents in the dispensers of this invention, but significant mortality was observed for each type four days after exposure for two minutes or less. 
     
                       TABLE 6                                                     
______________________________________                                    
10% Chlorpyrifos                                                          
            % Knockdown, hrs                                              
                          % Dead, Days                                    
Exposure Time                                                             
            After Exposure                                                
                          After Exposure                                  
(Minutes)   2      4       7    1    2     4                              
______________________________________                                    
2           0       0       5   10   30    45                             
10          0       0       0    5   10    20                             
20          5      65      85   75   100   --                             
30          0      30      70   65   90    95                             
50          5      40      70   85   90    95                             
60          0      50      75   80   90    100                            
______________________________________                                    
 
    
     
                       TABLE 7                                                     
______________________________________                                    
9% Diazinon                                                               
            % Knockdown, hrs                                              
                          % Dead, Days                                    
Exposure Time                                                             
            After Exposure                                                
                          After Exposure                                  
(Minutes)   2      4       7    1    2     4                              
______________________________________                                    
 1          0       0       0   10   15    35                             
 2          0      35      45    5   55    80                             
10          5      35      70   10   100   --                             
20          10     70      95   20   90    100                            
30          50     100     --   20   100   --                             
40          45     85      100  28   100   --                             
Control     0       0      0     0    0     5                             
______________________________________                                    
 
    
     It is expected that chlorpyrifos, diazinon and the other toxicants used in the present invention also would show knock down and kill after very short exposure of the roach to the dispenser, e.g., on the order of two seconds. Since the other agents are somewhat slower acting than propoxur, however, toxicity results take longer to become evident. 
     EXAMPLE 20 
     Dispensers were prepared generally as described in Example 1, but containing 5% by weight of propoxur. The roaches were allowed to come in contact with the dispensers in a cardboard carton situated in a larger container and 75% were knocked down or killed after 10 days. The only roaches not knocked down in these tests were observed resting inside the cardboard carton on the lid, only inches from the dispensers. 
     In replicates of the foregoing tests the roaches were not permitted contact with the tapes, the hole in the cardboard carton having been closed by taping fine screening over the 1/2 inch hole. The larger plastic container in which the cardboard box was situated was also covered over. After 10 days only 8.3% of the roaches were knockdown or killed. 
     The results of the tests are reported in Table 8 show that with this dispenser fumigant action is a minor factor, but a significant knockdown is accomplished by minimal direct physical contact, and 100% kill of adult male German cockroaches is achieved after 2 minutes of direct contact. 
     
                       TABLE 8                                                     
______________________________________                                    
5% Propoxur                                                               
           % Knockdown and Dead After Placement                           
           In Choice Container (Days).sup.a                               
Treatment.sup.b                                                           
             1      2       3    4    7     10                            
______________________________________                                    
Roaches permitted to                                                      
contact tape 61.7   66.7    68.3 70.0 73.3  75.0                          
Roaches not permitted                                                     
to contact tape                                                           
             1.7    5.0     5.0  6.7  6.7   8.3                           
Check        0      0       0    0    0     0                             
______________________________________                                    
 .sup.a Three replicates of 20 adult male German cockroaches              
 .sup.b Two 1&#34; × 4&#34; dispenser strips adhered to inside of covered 1/
 pint cardboard carton with 1/2&#34; hole cut into side. Carton placed in     
 center of larger plastic container and roaches given choice of entering  
 carton or not.                                                           
 
    
     EXAMPLE 21 
     Diazinon-containing dispensers of the invention were compared for residual activity with sprays of diazinon producing comparable surface concentrations. Sheets of dispensers containing 5% and 16.6% of diazinon respectively, and made generally in accordance with Example 1, were stapled to 6&#34;×6&#34; plywood panels in preparation for bio-assay. Diazinon 4EC formulations (Ciba-Geigy) were diluted in water and sprayed on the unpainted plywood panels to yield comparable deposits of 5% and 16.6% of diazinon on the panels. Ten adult German cockroaches were placed on the panels and held under clear, perforated, one-quart plastic containers to confine the cockroaches over the treated panels. Three replicates were performed with the sprayed panels while the tests with the dispensers of the invention were not replicated. The effectiveness of the dispensers versus sprayed applications were evaluated by taking mortality counts at 1/2-, 1-, 2-, 4-, 6- and 24-hours. The panels were bio-assayed on a weekly basis. The results are set forth in Table 9. 
     
                       TABLE 9                                                     
______________________________________                                    
Percent Mortality of Adult German Cockroaches After                       
Exposure to Dispenser Containing Diazinon and Spray                       
Applications of Diazinon                                                  
         % Mortality at Indicated Treatment                               
               5%       5%    16.6%  16.6%                                
               Diazinon Dia-  Diazinon                                    
                                     Dia-                                 
Weeks Time of  Dispen-  zinon Dispen-                                     
                                     zinon                                
Aged  Reading  ser      Spray ser    Spray Check                          
______________________________________                                    
0-    30-min.  0        3.0   0      10.0  0                              
week  1-hr.    0        43.3  50.0   10.0  0                              
      2-hr.    30.0     86.0  93.3   10.0  0                              
      4-hr.    100      100   100    --    0                              
      6-hr.    --       --    --     --    0                              
      24-hr.   --       --    --     --    0                              
1-    30-min.  0        0     0      3.0   0                              
week  1-hr.    0        20.0  40.0   63.3  0                              
      2-hr.    50.0     93.3  80.0   100   0                              
      4-hr.    100      100   100    --    0                              
      6-hr.    --       --    --     --    0                              
      24-hr.   --       --    --     --    0                              
2-    30-min.  20.0     0     16.6   16.6  0                              
weeks 1-hr.    50.0     86.6  100    96.6  0                              
      2-hr.    90.0     100   --     100   0                              
      4-hr.    100      --    --     --    16.60                          
      6-hr.    --       --    --     --    --                             
      24-hr.   --       --    --     --    --                             
3-    30-min.  0        0     0      0     0                              
weeks 1-hr.    26.6     13.3  70     90    0                              
      2-hr.    86.6     80.0  100    100   0                              
      4-hr.    100      100   --     --    43.30                          
      6-hr.    --       --    --     --    --                             
      24-hr.   --       --    --     --    --                             
4-    30-min.  0        0     0      0     0                              
weeks 1-hr.    0        0     0      6.0   0                              
      2-hr.    70       0     50     86.7  0                              
      4-hr.    100      60    100    100   30                             
      6-hr.    --       93.3  --     --    33                             
      24-hr.   --       100   --     --    63                             
5-    30-min   0        0     0      0     0                              
weeks 1-hr.    0        0     0      0     0                              
      2-hr.    20.0     3.3   30.0   6.7   0                              
      4-hr.    60.0     23.3  90.0   100   0                              
      6-hr.    100      53.3  100    --    3                              
      24-hr.   --       100   --     --    53                             
6-    30-min   0        10    0      0     0                              
weeks 1-hr.    0        10    0      0     0                              
      2-hr.    10       20    0      16.7  0                              
      4-hr.    100.0    76.7  90     100   26                             
      6-hr.    --       100   100    --    53                             
      24-hr.   --       --    --     --    76                             
7-    30-min   0        0     0      3.3   0                              
weeks 1-hr.    0        0     0      10.0  0                              
      2-hr.    40.0     16.7  30.0   63.3  0                              
      4-hr.    70.0     86.7  100    100   3                              
      6-hr.    100      100   --     --    10                             
      24-hr.   --       --    --     --    10                             
8-    30-min   0        0     0      0     0                              
weeks 1-hr.    10.0     0     0      3.3   0                              
      2-hr.    10.0     0     0      10.0  0                              
      4-hr.    70.0     26.7  70     63.3  0                              
      6-hr.    100      86.7  100    93.3  0                              
      24-hr.   --       100   --     100   10                             
9-    30-min.  0        0     0      0     0                              
weeks 1-hr.    0        0     0      0     0                              
      2-hr.    50.0     23.3  30.0   73.3  0                              
      4-hr.    100      100   100    100   100                            
      6-hr.    --       --    --     --    --                             
      24-hr.   --       --    --     --    --                             
10-   30-min.  0        0     0      0     0                              
weeks 1-hr.    10.0     6.6   0      3.3   0                              
      2-hr.    70.0     6.6   50     53.3  0                              
      4-hr.    100      46.7  100    100   3                              
      6-hr.    --       83.3  --     --    23                             
      24-hr.   --       100   --     --    36                             
11-   30-min.  0        0     0      0     0                              
weeks 1-hr.    0        0     0      0     0                              
      2-hr.    0        0     0      0     0                              
      4-hr.    80       36.9  100    100   0                              
      6-hr.    100      96.7  --     --    0                              
      24-hr.   --       100   --     --    43                             
12-   30-min.  0        0     0      0     0                              
weeks 1-hr.    0        0     0      0     0                              
      2-hr.    10.0     0     10.0   3.3   0                              
      4-hr.    40.0     6.6   90.0   76.6  0                              
      6-hr.    100      50.0  100    100   0                              
      24-hr.   --       100   --     --    30                             
13-   30-min.  0        0     0      0     0                              
weeks 1-hr.    0        0     10.0   0     0                              
      2-hr.    20.0     50.0  80.0   56.7  0                              
      4-hr.    100      96.7  100    100   76                             
      6-hr.    --       100   --     --    100                            
      24-hr.   --       --    --     --    --                             
14-   30-min.  0        0     0      0     0                              
weeks 1-hr.    0        0     0      0     0                              
      2-hr.    10.0     0     30.0   0     0                              
      4-hr.    100      43.3  100    93.3  0                              
      6-hr.    --       63.3  --     100   0                              
      24-hr.   --       100   --     --    56                             
15-   30-min.  0        0     0      0     0                              
weeks 1-hr.    0        0     0      0     0                              
      2-hr.    0        0     50.0   16.6  0                              
      4-hr.    20.0     13.3  90.0   60.0  0                              
      6-hr.    100      30.0  100    90.0  0                              
      24-hr.   --       100   --     100   10                             
16-   30-min.  0        0     0      0     0                              
weeks 1-hr.    0        0     0      0     0                              
      2-hr.    10.0     13.3  30.0   20.0  0                              
      4-hr.    100      46.6  40.0   50.0  0                              
      6-hr.    --       46.6  100    70.0  0                              
      24-hr.   --       100   --     100   23                             
17-   30-min.  0        0     0      0     0                              
weeks 1-hr.    0        0     0      3.3   0                              
      2-hr.    10.0     0     10.0   3.3   0                              
      4-hr.    50.0     0     50.0   20.0  0                              
      6-hr.    90.0     33.3  100    70.0  0                              
      24-hr.   100      100   --     100   43                             
18-   30-min.  0        0     0      0     0                              
weeks 1-hr.    0        0     0      0     0                              
      2-hr.    0        0     10.0   0     0                              
      4-hr.    40.0     30.0  80.0   53.3  0                              
      6-hr.    100      73.3  100    100   10                             
      24-hr.   --       100   --     --    80                             
19-   30-min.  0        0     0      0     0                              
weeks 1-hr.    0        0     10.0   0     0                              
      2-hr.    0        0     20.0   0     0                              
      4-hr.    30.0     6.7   90.0   40.0  0                              
      6-hr.    90.0     33.3  100    96.7  0                              
      24-hr.   100      100   --     100   30                             
21-   30-min.  0        0     0      0     0                              
weeks 1-hr.    0        0     0      0     0                              
      2-hr.    0        0     0      0     0                              
      4-hr.    40.0     0     100    30.0  0                              
      6-hr.    100      6.7   --     86.7  0                              
      24-hr.   --       96.6  --     100   0                              
______________________________________                                    
 
    
     All of the treated surfaces gave 100% control for 21 weeks, as shown in Table 9, when cockroaches were confined for 24 hours. This is very notable when it is considered that diazinon applied at 1% will give 100% control at 24-hours exposure for only 2 to 4 weeks. The 16.6% containing dispenser was the only treatment to sustain 100% control at 6-hours exposure. The 16.6% diazinon spray treatment gave an average of 95% control at 6-hours exposure, but showed definite signs of a break in activity towards the completion of the test, specifically at about 21 weeks of aging. 
     As has been demonstrated, the preferred dispensers depend for efficacy on direct contact with the cockroach or other crawling insects, and, therefore, for maximum efficacy in field conditions it is necessary that the dispensers not be repellent to the target species. Choice boxes are devices used by some researchers to detect the repellent nature of chemicals as well as the relative insecticidal efficacy of candidate materials to be used for cockroach control. A choice box consists of a 12×12×4 inch wooden box with a temperated Masonite floor and a vertical partition dividing the box into two compartments of equal size. A 1/2-inch diameter hole near the top center of the partition provides passage from one compartment to the other. Transparent panels cover both compartments and an opaque cover is placed over one compartment to keep just the one compartment dark. Food and water are placed in the uncovered or light compartment and the cockroaches are introduced into the light side through a hole in the transparent panel covering the light side. Insecticidal material to be tested is placed only in the dark compartment. A cork in the partition hole is removed 2  or 3 hours after the roaches have been placed in a box and observations are made of the number of live and dead cockroaches in each compartment, normally over a period of up to 30 days. 
     The rate at which cockroaches will flee the light compartment and enter the dark (treated) side indicates the relative repellency of the treatment. The total percent mortality of the cockroaches in the box usually indicates the insecticidal activity of the test material applied in the dark side. 
     For tests with the preferred dispensers, the tape was applied only at the floor-wall intersections (19.5 inches of tape per 0.5 ft 2 ). No tape was used in the vertical intersections or on the cover. Twenty adult male German cockroaches were put in each of three choice boxes 18 hours after the tape was applied. Data concerning the mortality of the cockroaches was collected in the test for up to 7 days, at which time there was 97% mortality. The dead cockroaches were then removed from each box, a dark cover was set over each treated compartment and the effectiveness of the tape in the boxes was evaluated in a similar manner after 102, 131, 154, 183 and 258 days of aging under ambient atmospheric conditions. The performance of the aged diazinon tape in terms of total percent mortality produced in the choice boxes is shown in Table 10. 
     
                       TABLE 10                                                    
______________________________________                                    
Performance of Dispensers Containing                                      
About 10% Diazinon in Choice Boxes for                                    
Up to 283 Days of Aging at Ambient                                        
Atmospheric Conditions                                                    
           Total % Mortality                                              
Age of Dispenser                                                          
           Days After Start of Test                                       
(Days)     1     2      3     4    5     6    7                           
______________________________________                                    
Fresh       5    68     85    93   95    97    97                         
102        63    93     98    98   98    98   100                         
131        92    95     98    98   100                                    
154        65    ND.sup.1                                                 
                        100                                               
183        95    98     100                                               
250        --.sup.1                                                       
                 --.sup.1                                                 
                        100                                               
283        --    --     100                                               
______________________________________                                    
 .sup.1 No data collected.                                                
 
    
     In another series of tests, conventional commercially available cockroach control spray materials were applied to the dark compartments of choice boxes and were tested after periods of aging up to 85 days. The liquids were prepared in water from diazonin 4E, chlorpyrifos 2E, and propoxur 1E commercial formulations and 3 ml of 1% diazinon, 0.5% chlorpyrifos, or 1% propoxur was applied. Three ml was applied because that is about the amount of material that is applied when sprayed just about to runoff under normal conditions. The deposits were allowed to dry 24 hours at which time the standard choice box evaluations were begun. Tests conducted with the same deposits after 20 and 85 days of aging under ambient atmospheric conditions are also summarized in Table 11. 
     The performance of the liquid deposits in choice boxes was substantially reduced after 85 days of aging. In fact, satisfactory mortality was not achieved within 10 days with diazinon, chlorpyrifos or propoxur. The multi-layer dispensers, on the other hand, had consistently produced very rapid complete mortality for the duration of the tests with aged strips. 
     Repellency in choice boxes is usually calculated on the basis of the percentage of the live cockroaches which can be found alive in the light side. Since there were no live insects after just a brief period of time in the boxes treated with the dispensers of the invention, a repellency of the material could not be detected. With the liquid residues there were usually 90-100% of the surviving cockroaches in the light (untreated) side of each box whenever data was collected. The high percentage of live cockroaches in the light side of the boxes indicated repellency and therefore, also indicated that the initial high degree of effectiveness of the materials was probably due to the high toxicity of the insecticides which would produce mortality after even brief, momentary encounters with the deposits. As the high degree of toxicity is reduced through aging degradation, some cockroaches learn to avoid lethal contacts with the insecticides. 
     
                                           TABLE 11                                
__________________________________________________________________________
Performance In Choice Boxes Of Various                                    
Insecticide Deposits.sup.1 Aged for Up to                                 
85 Days Under Ambient Atmospheric                                         
Conditions                                                                
          Age of                                                          
          Deposit                                                         
               Total % KD - Days After Start of Test                      
Treatment (Days)                                                          
               1  2  5   6   10  18  25                                   
__________________________________________________________________________
Diazinon, 1%                                                              
          Fresh                                                           
               57 98 100                                                  
&#34;         20   75 93 98  98  98  98  100                                  
&#34;         85   --.sup.2                                                   
                  0  4   4   62  95  100                                  
Chlorpyrifos, 0.5%                                                        
          Fresh                                                           
               18 60 98  98  100                                          
&#34;         20   80 97 100                                                  
&#34;         85   --.sup.2                                                   
                  32 38  58  87  97  97                                   
Propoxur, 1%                                                              
          Fresh                                                           
               17 50 83  100                                              
&#34;         20   80 97 98  98  98  100                                      
&#34;         85   --.sup.2                                                   
                  7  13  18  22  28  62                                   
Untreated Fresh                                                           
               0  0  2   2   2   2   --.sup.2                             
&#34;         20   2  3  8   8   17  21  26                                   
&#34;         85   2  3  5   5   7   10  15                                   
__________________________________________________________________________
 .sup.1 Applied 3 ml dilute emulsion to the Masonite floor of the dark    
 compartment with a pipette. Brushed deposit over the substrate with a dam
 camel hair brush.                                                        
 .sup.2 No data collected.                                                
 
    
     In accordance with the invention, polymeric controlled release dispensers containing sufficient amounts of non-volatile, contact-effective toxicants, preferably dispensers as exemplified above, are deployed in structures infested with or apt to be infested with roaches or other crawling insects and specifically in known harborages and crawl paths, e.g., in cracks and crevices around pipes, moldings and the like; on the backs and in the dark corners of appliances, shelves, closets, etc. From about 1/3 to about 3 sq.ft., polymeric, controlled release dispenser material containing a non-volatile, contact-effective toxicant having a surface concentration of toxicant of from about 50 to 500 mg/sq.ft. deployed in an average sized room or space (about 100-150 sq.ft.) has been found to provide effective control of roaches and other crawling insects. In this context &#34;control&#34; is meant to imply a significant reduction in crawling insect population, not necessarily eradication which is sometimes impossible to achieve due to sanitary or other conditions. 
     The following tables summarize field tests using dispensers, containing propoxur and diazinon. Data from field tests wherein residual spray treatments were used alone (or in a few cases, with a fog) are included for comparison. 
     The dispensers were 1&#34;×4&#34; tapes of PVC/PVC plastisol/MYLAR/pressure-sensitive adhesive construction containing about 5% by weight of toxicant initially introduced in the plastisol layer. The dispensers were adherently applied to harborages and crawl path surfaces and cracks and crevices were also treated by inserting a strip or strips. The quantity of strips applied varied according to the size of the apartment kitchen and other rooms, and also according to the number of cracks, crevices and other cockroach harborages. A greater number of roaches were usually found in test sites with many cracks and crevices. Table 12 comparing the results of HERCON &#34;Roach-Type&#34; treatments with spray alone shows the control was definitely better when the strips were used. All sprayed test sites were sprayed by commercial pest control operators or by apartment complex employees who regularly handle spraying duties. After 1 to 11/2 months, percent reduction in sprayed sites was only 55.86%, while test sites with the strips showed more than 70% reduction. The highest average reduction obtained by spray alone was 61.87%, while in the dispenser treated sites it was 92.76%. A reduction of 100% was often observed in dispenser treated sites with moderately low infestations. 
     Very good control was obtained in test sites with the process of this invention. The reduction after 1 to 11/2 months was greatest with dispensers containing propoxur with 88.29% (dispensers of chlorpyrifos had 86.07%, and diazinon containing dispensers had 80.69% reduction). Please note that in the spray alone sites, reduction after 1 to 11/2 months was only 55.86%. Reduction values in test sites treated with dispensers according to this invention were greater two to five months after strip application. 
     
                                           TABLE 12                                
__________________________________________________________________________
Dispenser Tape Treatments Alone Versus Residual Sparay Alone              
Average No. Strips                                                        
               Average No. Roaches                                        
                          % Reduction                                     
Per Site  No. Sites                                                       
               Per Site   1 Red&#39;n                                         
                               2 Red&#39;n                                    
                                    3 Red&#39;n                               
__________________________________________________________________________
40 or less*                                                               
          54   16.26      71.50                                           
                               92.76                                      
                                    91.93                                 
41 or more                                                                
          33   75.18      84.26                                           
                               86.52                                      
                                    79.98                                 
Spray Treatments                                                          
          45   38.71      55.86                                           
                               61.87                                      
                                    57.21                                 
__________________________________________________________________________
         Definitions                                                      
__________________________________________________________________________
% Reduction                                                               
         Percentage of infestation reduction; this is obtained            
         by dividing the number of roaches killed by the total            
         number of roaches observed during the pre-count.                 
Pre-Count                                                                 
or P/C   This is the number of roaches observed prior to                  
         application of insecticidal dispenser strips or appli-           
         cation of residual sprays.                                       
No. Roaches                                                               
Killed   This is estimated by subtracting follow-up count                 
         from pre-count.                                                  
Follow-Up Count                                                           
or F/U   This is the number of roaches after appli-                       
         cation of strips or spray.                                       
         1F/U: This indicates the number of roaches                       
         observed 1 to 11/2 months after strip application                
         (or spray application).                                          
         2F/U: This indicates the number of roaches observed              
         2 to 3 months after treatment.                                   
         3F/U: This indicates the number of roaches observed              
         3 to 5 months after treatment.                                   
1 Red&#39;n  This is % REDUCTION based on the first follow-up                 
         (1F/U) count.                                                    
2 Red&#39;n  This is % REDUCTION based on the second follow-up                
         (2F/U count.                                                     
3 Red&#39;n  This is % REDUCTION based on the third follow-up                 
         (3F/U) count.                                                    
__________________________________________________________________________
 Note:                                                                    
 All estimates of level of infestation, i.e., precounts and followup      
 counts, were obtained by using the FLUSHING METHOD. A sublethal flush    
 using a pressurized pyrethrin/PBO (aerosol) spray was used. Emerging     
 roaches were counted for 3 minutes after flushing.                       
 
    
     Dispenser tapes were applied as needed. Fifty-four of 87 test sites which received the dispenser treatment had 40 strips or less. This represents 62.07% of the total tape-treated sites, suggesting that an average apartment can be sufficiently treated with approximately 40 strips. (The presence of more cracks and crevices, and very severe cockroach infestations will also influence the number of strips to be used. The above table also showed that there were approximately 16 cockroaches in sites receiving 40 or less strips, while sites with approximately 75 cockroaches had 41 or more strips. Percentage infestation reduction obtained by using dispenser strips alone was greater than that obtained by using residual sprays. 
     
                                           TABLE 13                                
__________________________________________________________________________
Dispenser Tapes Containing Propoxur alone                                 
summary:                                                                  
No. sites with Propoxur strips alone                                      
                                 25                                       
Average no. cockroaches per site 66.92                                    
Average percentage infestation reduction:                                 
During 1st Follow-Up (after 1-11/2 mos.)                                  
                                 88.29%                                   
During 2nd Follow-Up (after2-3 mos.)                                      
                                 96.17%                                   
During 3rd Follow-Up (after 3-5 mos.)                                     
                                 89.34%*                                  
__________________________________________________________________________
 *Obtained from 7 sites                                                   
 
    
     
         No. Strips/site                                                           
             P/C 1F/U                                                     
                     2F/U                                                 
                         3F/U                                             
                             1 Red&#39;n                                      
                                  2 Red&#39;n                                 
                                       3 Red&#39;n                            
__________________________________________________________________________
CALIFORNIA, Alameda                                                       
67           30  3            90.00                                       
11           35  0           100.00                                       
70           130 6            95.38                                       
FLORIDA, Orlando                                                          
16           8   0           100.00                                       
15           1   0           100.00                                       
25           1   0           100.00                                       
25           5   0           100.00                                       
34           3   0   0       100.00                                       
                                  100.00                                  
FLORIDA, Tampa                                                            
20           5   0           100.00                                       
12           6   0           100.00                                       
New York, New York                                                        
Hotel Site                                                                
54           20  1            95.00                                       
26           33  4            87.88                                       
34           20  5            75.00                                       
Restaurant Site                                                           
82           22  1   0        95.00                                       
                                  100.00                                  
NEW YORK, New York                                                        
Hotel Site                                                                
24           9   1   0   1    88.88                                       
                                  100.00                                  
                                        88.88                             
46           100 --  --  0   --   --   100.00                             
40           30  20  0   10   33.33                                       
                                  100.00                                  
                                        66.67                             
52           500 200 10  --   60.00                                       
                                   98.00                                  
                                       --                                 
NEW YORK, Candy                                                           
Factory Site                                                              
50           50  1   2        98.00                                       
                                   96.00                                  
__________________________________________________________________________
 
    
     
                                           TABLE 14                                
__________________________________________________________________________
Dispensing Tapes Containing Chlorpyrifos Alone                            
summary:                                                                  
No. Sites treated with Chlorpyrifos tapes alone                           
                                 24                                       
Average no. cockroaches per site 13.17                                    
Average percentage infestation reduction:                                 
During 1st Follow-Up (after 1-11/2 mos.)                                  
                                 86.07%                                   
During 2nd Follow-Up (after 2-3 mos.)                                     
                                 100.00%                                  
During 3rd Follow-Up (after 3-5 mos.)                                     
                                 100.00%*                                 
__________________________________________________________________________
 Obtained from 3 sites                                                    
 
    
     
         COCKROACH                                                                 
             COUNTS          % REDUCTION                                  
No. Strips/site                                                           
             P/C 1F/U                                                     
                     2F/U                                                 
                         3F/U                                             
                             1 Red&#39;n                                      
                                  2 Red&#39;n                                 
                                       3 Red&#39;n                            
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OKLAHOMA, Stillwater                                                      
45           35  8   3   3    77.14                                       
                                   91.43                                  
                                        91.43                             
45           51  3   8   3    94.12                                       
                                   84.31                                  
                                        94.12                             
45           51  8   8   8    84.31                                       
                                   84.31                                  
                                        84.31                             
OREGON, Cornelius                                                         
53           500 75  0        85.00                                       
                                  100.00                                  
40           25  10  0        60.00                                       
                                  100.00                                  
TENNESSEE, Memphis                                                        
28           3   0   0   0   100.00                                       
                                  100.00                                  
                                       100.00                             
CALIFORNIA, Alameda                                                       
14           25  15           40.00                                       
NEW YORK, New York                                                        
Hotel Site                                                                
47           45  0           100.00                                       
42           50  0           100.00                                       
45           10  0           100.00                                       
Hotel Site                                                                
17           3   0   0   0   100.00                                       
                                  100.00                                  
                                       100.00                             
11           4   0   --  0   100.00                                       
                                  --   100.00                             
11           5   3   --  0    40.00                                       
                                  --   100.00                             
OREGON, Cornelius                                                         
30           5   5   0       0    100.00                                  
TENNESSEE, Memphis                                                        
52           25  0           100.00                                       
39           23  0           100.00                                       
58           30  0           100.00                                       
FLORIDA, Orlando                                                          
36           2   0   --      100.00                                       
36           3   0   0       100.00                                       
                                  100.00                                  
36           5   0   0       100.00                                       
                                  100.00                                  
36           1   0   0       100.00                                       
                                  100.00                                  
36           2   0   0       100.00                                       
                                  100.00                                  
36           7   0   0       100.00                                       
                                  100.00                                  
36           1   0   0       100.00                                       
                                  100.00                                  
36           1   0   0       100.00                                       
                                  100.00                                  
36           3   0           100.00                                       
36           7   1            85.71                                       
36           30  0           100.00                                       
36           19  0           100.00                                       
36           15  19  --      0    --                                      
__________________________________________________________________________
 
    
     
         __________________________________________________________________________
Dispenser Tapes Containing                                                
Diazinon Alone                                                            
__________________________________________________________________________
Summary:                                                                  
No. sites treated with diazinon strips alone                              
                                 38                                       
Average number of cockroaches per site                                    
                                 35.92                                    
Average percentage infestation reduction:                                 
During 1st follow-up (after 1-11/2 mos.)                                  
                                 80.69%                                   
During 2nd follow-up (after 2-3 months)                                   
                                 84.46%                                   
During 3rd follow-up (after 3-5 months)                                   
                                 84.74%                                   
__________________________________________________________________________
No. Strips/Site P/C 1F/U                                                  
                        2F/U                                              
                            3F/U                                          
                                1Red&#39;n                                    
                                    2Red&#39;n                                
                                        3Red&#39;n                            
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CALIFORNIA, Alameda                                                       
48              35  12          65.71                                     
CONNECTICUT, New Haven                                                    
96              92  36  2   0   60.87                                     
                                    97.83                                 
                                        100.00                            
South Orange                                                              
24              30  1   0       96.67                                     
                                    100.0                                 
37              40  41  20      0   50.00                                 
36              60  30  50      50.00                                     
                                    16.67                                 
30              30  10  tc --   66.67                                     
                                    --                                    
FLORIDA, Orlando                                                          
46              5   0   0       100.00                                    
                                    100.00                                
FLORIDA, Tampa                                                            
95              12  12          0                                         
15              13  0           100.00                                    
30              4   0           100.00                                    
80              2   0           100.00                                    
GEORGIA, Atlanta                                                          
32              63  0           100.00                                    
NEW YORK, New York                                                        
Hotel Site                                                                
68              52  6           88.46                                     
32              50  5           90.00                                     
36              8   0           100.00                                    
Hotel Site                                                                
47              150 1   4   5   99.33                                     
                                    97.33                                 
                                        96.67                             
15              5   0   0   0   100.00                                    
                                    100.00                                
                                        100.00                            
26              15  3   3   0   80.00                                     
                                    80.00                                 
                                        100.00                            
33              20  1   0   2   95.00                                     
                                    100.00                                
                                        90.00                             
New Hyde Park                                                             
14              10  0   0   5   100.00                                    
                                    100.00                                
                                        50.00                             
30              12  0   0   2   100.00                                    
                                    100.00                                
                                        83.00                             
Hotel Site                                                                
28              5   0   0   0   100.00                                    
                                    100.00                                
                                        100.00                            
22              5   0   0   0   100.00                                    
                                    100.00                                
                                        100.00                            
21              3   0   0   0   100.00                                    
                                    100.00                                
                                        100.00                            
OKLAHOMA, Stillwater                                                      
45              35  8   8   3   77.14                                     
                                    77.14                                 
                                        91.43                             
45              51  8   8   8   84.31                                     
                                    84.31                                 
                                        84.31                             
45              51  8   8   3   84.31                                     
                                    84.31                                 
                                        94.12                             
OREGON, Cornelius                                                         
30              10  5   0       50.00                                     
                                    100.00                                
TENNESSEE, Memphis                                                        
96              25  7   2   0   72.00                                     
                                    92.00                                 
                                        100.00                            
89              7   0   --  0   100.00                                    
                                    --  100.00                            
36              30  10  --  --  66.67                                     
                                    --  --                                
17              20  5   1   0   75.00                                     
                                    95.00                                 
                                        100.00                            
23              100 20  1   --  80.00                                     
                                    99.00                                 
                                        --                                
73              70  25  45  45  64.29                                     
                                    35.71                                 
                                        35.71                             
80              60  45  40  65  25.00                                     
                                    33.33                                 
                                        0                                 
Public Housing Authority                                                  
118             112 6           94.64                                     
60              53  0           100.00                                    
43              20  0           100.00                                    
__________________________________________________________________________
 
    
     
                                           TABLE 16                                
__________________________________________________________________________
Conventional Residual                                                     
Spray Treatment Alone                                                     
__________________________________________________________________________
Summary:                                                                  
Number of sites receiving spray treatments                                
                                 45                                       
Average number of cockroaches per site                                    
                                 38.71                                    
Average percentage infestation reduction:                                 
During 1st follow-up (after 1-11/2 mos.)                                  
                                 55.86%                                   
During 2nd follow-up (after 2-3 mos.)                                     
                                 61.87%                                   
During 3rd follow-up (after 3-5 mos.)                                     
                                 57.21%                                   
__________________________________________________________________________
                P/C 2F/U                                                  
                        2F/U                                              
                            3F/U                                          
                                1Red&#39;n                                    
                                    2Red&#39;n                                
                                        Red&#39;n                             
__________________________________________________________________________
CALIFORNIA, Alameda                                                       
Treatment: Dizainon 4E                                                    
spray alone     150 11          92.67                                     
CONNECTICUT, New Haven                                                    
Treatment: Baygon spray                                                   
plus fog        3   0   0   12  100.00                                    
                                    100.00                                
                                        0                                 
                90  77  42  62  14.44                                     
                                    54.33                                 
                                        31.11                             
                3   0   0   1   100.00                                    
                                    100.00                                
                                        66.67                             
                15  1   2   7   93.33                                     
                                    86.67                                 
                                        53.33                             
                55  42  21  60  23.64                                     
                                    61.82                                 
                                        0                                 
                2   0   0   1   100.00                                    
                                    100.00                                
                                        50.00                             
                80  63  50  12  21.25                                     
                                    37.50                                 
                                        85.00                             
Treatment: Diazinon 4E                                                    
spray plus fog  5   10  50      0   0                                     
                20  25  1       0   95.00                                 
                3   35  19      0   0                                     
                19  0   0   0   100.00                                    
                                    100.00                                
                                        100.00                            
Treatment: Diazinon 4E                                                    
                77  36  0   0   53.25                                     
                                    100.00                                
                                        100.00                            
spray plus fog  8   2   0   0   75.00                                     
                                    100.00                                
                                        100.00                            
                32  7   2   28  78.13                                     
                                    93.75                                 
                                        12.50                             
                26  10  5   --  61.54                                     
                                    80.77                                 
                                        --                                
                14  4   3   15  71.43                                     
                                    78.57                                 
                                        0                                 
NEW YORK, New York                                                        
Hotel Site                                                                
Treatment: Diazinon 4E                                                    
                30  30              0                                     
spray alone     6   4   0       33.33                                     
                                    100.00                                
                10  6   4       40.00                                     
                                    20.00                                 
                30  25  2       16.67                                     
                                    93.33                                 
Hotel Site      50  --  --  50  --  --  0                                 
                10  50  1   --  0   90.00                                 
                                        --                                
Treatment: Dursban                                                        
                8   3   3   --  62.50                                     
                                    62.50                                 
                                        --                                
spray biweekly  5   0   0   --  100.00                                    
                                    100.00                                
                                        --                                
                50  --  50  75  --  0   0                                 
Hotel Site      6   5   2   2   16.67                                     
                                    66.67                                 
                                        66.67                             
                10  5   0   0   50.00                                     
                                    100.00                                
                                        100.00                            
Treatment: Baygon                                                         
                4   19  4   3   0   0   25.00                             
spray alone                                                               
OKLAHOMA, Stillwater                                                      
Treatment: Diazinon                                                       
                51  3   3   8   94.12                                     
                                    94.12                                 
                                        84.31                             
                51  3   3   8   94.12                                     
                                    94.12                                 
                                        84.31                             
                35  3   3   3   94.12                                     
                                    94.12                                 
                                        94.12                             
Treatment: Baygon                                                         
                51  3   3   3   94.12                                     
                                    94.12                                 
                                        94.12                             
spray alone     51  3   8   8   94.12                                     
                                    84.31                                 
                                        84.31                             
                51  3   3   8   94.12                                     
                                    94.12                                 
                                        84.31                             
NEW YORK, New York                                                        
Hotel Site      30  30          0                                         
Treatment: Diazinon 4E                                                    
                6   4   0       33.33                                     
                                    100.00                                
spray alone     10  6   4       40.00                                     
                                    20.00                                 
                30  25  2       16.67                                     
                                    93.33                                 
Hotel Site      50  --  --  50  --  --  0                                 
Treatment: Durasban                                                       
                10  50  1   --  0   90.00                                 
                                        --                                
spray biweekly  8   3   3   --  62.50                                     
                                    62.50                                 
                                        --                                
                5   0   0   --  100.00                                    
                                    100.00                                
                                        --                                
                50  --  50  75  --  0   0                                 
Hotel Site      6   5   2   2   16.67                                     
                                    66.67                                 
                                        66.67                             
Treatment: Baygon spray                                                   
                10  5   0   0   50.00                                     
                                    100.00                                
                                        100.00                            
alone           4   19  4   3   0   0   25.00                             
OKLAHOMA, Stillwater                                                      
Treatment: Diazinon                                                       
                51  3   3   8   94.12                                     
                                    94.12                                 
                                        84.31                             
spray alone     51  3   3   8   94.12                                     
                                    94.12                                 
                                        84.31                             
                35  3   3   3   94.12                                     
                                    94.12                                 
                                        94.12                             
Treatment: Baygon                                                         
                51  3   3   3   94.12                                     
                                    94.12                                 
                                        94.12                             
spray alone     51  3   8   8   94.12                                     
                                    84.31                                 
                                        84.31                             
                51  3   3   8   94.12                                     
                                    94.12                                 
                                        84.31                             
Oregon, Cornelius                                                         
Treatment: Baygon spray                                                   
                350 50  0       85.71                                     
                                    100.00                                
TENNESSEE, Memphis                                                        
Public Housing                                                            
Treatment: Diazinon 4E                                                    
                20  50          0                                         
spray alone     15  30          0                                         
                100 50          50.00                                     
                35  20          42.86                                     
                10  10          0                                         
                60  15          75.00                                     
                7   0           100.00                                    
__________________________________________________________________________