Patent Publication Number: US-2003227049-A1

Title: Non-volatile semiconductor memory device

Description:
BACKGROUND OF THE INVENTION  
       [0001] 1. Field of the Invention  
       [0002] The present invention relates to a non-volatile semiconductor memory device, and more particularly to a non-volatile semiconductor memory device capable of storing information by accumulating an electric charge in a gate insulating film.  
       [0003] 2. Description of the Background Art  
       [0004] A MONOS Metal-Oxide-Nitride-Oxide Semiconductor) type non-volatile semiconductor memory device wherein a charge accumulation unit for accumulating an electric charge is formed from an insulating film are known as non-volatile semiconductor memory devices in addition to a floating gate-type non-volatile semiconductor memory device wherein a floating gate is formed for holding an electric charge.  
       [0005] Electrons are stored in a carrier trap in a silicon nitride film for holding an electric charge and in a carrier trap of an interface between the silicon nitride film and a silicon oxide film in the MONOS type non-volatile semiconductor memory device. Information can be stored according to the existence of these electrons.  
       [0006] The MONOS type non-volatile semiconductor memory device is, in general, constituted by an ONO (Oxide-Nitride-Oxide) film formed on a silicon substrate, a gate electrode formed on the ONO film, and source and drain regions formed in the semiconductor substrate across the gate electrode.  
       [0007] Such a MONOS type non-volatile semiconductor memory device is, for example, described in Japanese Patent Laying-Open No. 2001-230332.  
       [0008] A plurality of MONOS type non-volatile semiconductor memory elements generally constitutes a memory cell region in a non-volatile semiconductor memory device using MONOS type non-volatile semiconductor memory elements. The plurality of MONOS type non-volatile semiconductor memory elements is arranged in a matrix wherein the respective source regions are connected to each other.  
       [0009] Accordingly, in the case that one MONOS type non-volatile semiconductor memory element is selected, a voltage is applied to the source line of the element, and the voltage is also applied to the source line of other MONOS type non-volatile semiconductor memory elements that share the source line. Therefore, the other MONOS type non-volatile semiconductor memory elements that have not been intentionally selected are also selected. In order to prevent this, a technique for forming selection transistors for the respective MONOS type non-volatile semiconductor memory elements has been under development. However, in the case that field-effect transistors are connected to the respective MONOS type non-volatile semiconductor memory elements as selection transistors, a problem arises wherein the number of manufacturing steps is increased.  
       [0010] In addition, in the case that electrons are injected into an ONO film using GIDL (Gate Induced Drain Leakage), there is a demand for increased injection efficiency of electrons.  
       SUMMARY OF THE INVENTION  
       [0011] The present invention is made in order to solve the above described problems, and one object of the present invention is to provide a non-volatile semiconductor memory device having a field-effect transistor capable of selecting a MONOS type non-volatile semiconductor memory element without increasing the number of manufacturing steps.  
       [0012] Another object of the present invention is to provide a non-volatile semiconductor memory device having MONOS type non-volatile semiconductor memory elements with high injection efficiency of electrons.  
       [0013] A non-volatile semiconductor memory device according to one aspect of the present invention is provided with: a semiconductor substrate having a main surface; an n-type semiconductor region formed in the semiconductor substrate; a non-volatile semiconductor memory element formed in the n-type semiconductor region; and a field-effect transistor formed in the n-type semiconductor region so as to be connected to the non-volatile semiconductor memory element. The non-volatile semiconductor memory element includes: a first gate insulating film formed on the main surface so as to be located on the n-type semiconductor region; a first gate electrode provided on the first gate insulating film; and a pair of source region and drain region formed in the n-type semiconductor region across the first gate electrode and constituted by a p-type impurity region. The first gate insulating film includes: a first silicon oxide film formed on the main surface; a silicon nitride film formed on the first silicon oxide film; and a second silicon oxide film formed on the silicon nitride film. The non-volatile semiconductor memory device stores information by injecting an electron into the first gate insulating film. The field-effect transistor is formed on the main surface so as to be located on the n-type semiconductor region, and includes a second gate insulating film made of the same material as that of the first gate insulating film.  
       [0014] In the non-volatile semiconductor memory device formed in such a manner, the field-effect transistor includes a second gate insulating film made of the same material as that of the first gate insulating film. Therefore, the first gate insulating film and the second gate insulating film can be manufactured in the same step so that the field-effect transistor can be formed as a selection transistor without increasing the number of manufacturing steps.  
       [0015] A non-volatile semiconductor memory device according to another aspect of the present invention is provided with: a semiconductor substrate having a main surface; an n-type semiconductor region formed in the semiconductor substrate; a non-volatile semiconductor memory element formed in the n-type semiconductor region; a p-type semiconductor region formed in the semiconductor substrate; and a field-effect transistor formed in the p-type semiconductor region. The non-volatile semiconductor memory element includes: a first gate insulating film formed on the main surface so as to be located on the n-type semiconductor region; a first gate electrode formed on the first gate insulating film; a first sidewall insulating film formed on a sidewall of the first gate electrode; and a pair of source region and drain region formed in the n-type semiconductor region across the first gate electrode and constituted by a p-type impurity region. The first gate insulating film includes a first silicon oxide film formed on the main surface; a silicon nitride film formed on the first silicon oxide film; and a second silicon oxide film formed on the silicon nitride film. The non-volatile semiconductor memory element stores information by injecting an electron into the first gate insulating film. The field-effect transistor includes: a second gate electrode formed on the p-type semiconductor region so as to interpose a second gate insulating film therebetween; and a second sidewall insulating film formed on a sidewall of the second gate electrode. The width of the first sidewall insulating film in the channel length direction is smaller than the width of the second sidewall insulating film in the channel length direction.  
       [0016] In the non-volatile semiconductor memory device formed in such a manner, the width of the first sidewall insulating film is smaller than the width of the second sidewall insulating film and, therefore, the source region and the drain region can be formed so that the width of a portion facing to the first gate electrode becomes great in the non-volatile semiconductor memory element in which the first sidewall insulating film is formed. As a result, it becomes easy to generate a hot electron in the portion of the drain region facing to the first gate electrode so that injection of an electron into the first gate insulating film becomes easy. Furthermore, the width of a second sidewall insulating film formed on a sidewall of the second gate electrode of the field-effect transistor, which is an n-channel type transistor, becomes relatively great and, therefore, the width of the source region or of the drain region formed beneath this sidewall insulating film becomes great. An n-channel type field-effect transistor has, in general, a problem that hot carriers easily generate. Therefore, the generation of hot carriers can be prevented by placing the source region and the drain region at a distance from each other in the n-channel type field-effect transistor.  
       [0017] A non-volatile semiconductor memory device according to still another aspect of the present invention is provided with: a semiconductor substrate having a main surface; an n-type semiconductor region formed in the semiconductor substrate; and a non-volatile semiconductor memory element formed in the n-type semiconductor region. The non-volatile semiconductor memory element includes: a first gate insulating film formed on the main surface so as to be located on the n-type semiconductor region; a first gate electrode provided on the first gate insulating film; and a pair of source region and drain region formed in the n-type semiconductor region across the first gate electrode and constituted by a p-type impurity region. The first gate insulating film includes: a first silicon oxide film formed on the main surface; a silicon nitride film formed on the first silicon oxide film; and a second silicon oxide film formed on the silicon nitride film. The non-volatile semiconductor memory element stores information by injecting an electron into the first gate insulating film. The source region and the drain region have portions making contact with the first silicon oxide film and facing to the first gate electrode. The width of the portion of the drain region facing to the first gate electrode is greater than the width of the portion of the source region facing to the first gate electrode.  
       [0018] In the non-volatile semiconductor memory device formed in such a manner, the width of the portion of the drain region facing to the first gate electrode is greater than the width of the portion of the source region facing to the first gate electrode and, therefore, a hot electron is generated in the portion of the drain region facing to the first gate electrode so that it becomes possible to inject the electron into the first gate insulating film. As a result, it becomes easy to inject an electron from the drain region.  
       [0019] The foregoing and other objects, features, aspects and advantages of the present invention will become more apparent from the following detailed description of the present invention when taken in conjunction with the accompanying drawings. 
     
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS  
     [0020]FIG. 1A is a plan view showing a non-volatile semiconductor memory device according to a first embodiment of the present invention;  
     [0021]FIG. 1B is an equivalent circuit diagram showing the non-volatile semiconductor memory device according to the first embodiment of the present invention;  
     [0022]FIG. 2 is a cross sectional view taken along a line II-II in FIG. 1A;  
     [0023] FIGS.  3  to  15  are cross sectional views showing first to thirteen steps of a manufacturing method for the non-volatile semiconductor memory device shown in FIG. 2;  
     [0024]FIG. 16 is a cross sectional view showing a non-volatile semiconductor memory device according to a second embodiment of the present invention;  
     [0025]FIG. 17 is a cross sectional view showing a non-volatile semiconductor memory device according to a third embodiment of the present invention;  
     [0026]FIG. 18 is a cross sectional view showing a non-volatile semiconductor memory device according to a fourth embodiment of the present invention;  
     [0027]FIG. 19 is a cross sectional view showing a non-volatile semiconductor memory device according to a fifth embodiment of the present invention; and  
     [0028]FIG. 20 is a cross sectional view showing a manufacturing step of the non-volatile semiconductor memory device shown in FIG. 19. 
    
    
     DESCRIPTION OF THE PREFERRED EMBODIMENTS  
     [0029] Hereinafter, embodiments of the present invention will be described with reference to the drawings.  
     [0030] First Embodiment  
     [0031] With reference to FIGS. 1A and 1B, an isolation insulating film  3  is formed on a semiconductor substrate made of a silicon substrate in a non-volatile semiconductor memory device  100  according to a first embodiment of the present invention. A portion where isolation insulating film  3  is not formed is an active region, and p-type impurity regions  33 ,  36  and  39  which constitute source and drain regions are formed in this portion. A plurality of first and second gate electrodes  51  and  52  is formed in the direction orthogonal to the direction in which isolation insulating film  3  extends, and p-type impurity regions  33 ,  36  and  39 , respectively, are formed between these first and second gate electrodes  51  and  52 . Contact holes  28   a  and  28   b  are provided so as to reach p-type impurity regions  33 . Contact holes  28   a  and  28   b  allow p-type impurity regions  33  to be connected to bit lines BL 1  and BL 2  provided on first and second gate electrodes  51  and  52 .  
     [0032] Memory cell transistors MG 1  to MG 4  and selection transistors S 1  to S 4  are connected to each other and these share gate insulating films. Memory cell transistors MG 1  and MG 2  share a first gate electrode  51 . Memory cell transistors MG 3  and MG 4  share a first gate electrode  51 . Selection transistors S 1  and S 2  share a second gate electrode  52 . Selection transistors S 3  and S 4  share a second gate electrode  52 .  
     [0033] Memory cell transistors MG 1  and MG 3  are connected to bit line BL 1  while memory cell transistors MG 2  and MG 4  are connected to bit line BL 2 .  
     [0034] With reference to FIG. 2, a non-volatile semiconductor memory device  100  is provided with: a semiconductor substrate  1  having a main surface  1   f;  an n-type well region  2   n  as an n-type semiconductor region formed in semiconductor substrate  1 ; a MONOS element  71  as a non-volatile semiconductor memory element formed in n-type well region  2   n;  and a field-effect transistor  72  formed in n-type well region  2   n  so as to be connected to MONOS element  71 .  
     [0035] MONOS element  71  includes: a first gate insulating film  111  formed on main surface  1   f  so as to be located on n-type well region  2   n;  a first gate electrode  51  provided on first gate insulating film  11 ; and a pair of p-type impurity region  33  as a source region and p-type impurity region  36  as a drain region formed on n-type well region  2   n  across first gate electrode  51 . First gate insulating film  1  includes: a first silicon oxide film  41  formed on main surface  1   f;  a silicon nitride film  42  formed on first silicon oxide film  41 ; and a second silicon oxide film  43  formed on silicon nitride film  42 . MONOS element  71  stores information by injecting an electron  101  into first gate electrode  51 . The electron is injected into any of first silicon oxide film  41 , silicon nitride film  42  and second silicon oxide film  43  or into interfaces between these films and are held therein. That is to say, the electron is injected into first gate insulating film  111  and are held therein. Thereby, information is stored.  
     [0036] Field-effect transistor  72  is formed on main surface  1   f  so as to be located on n-type well region  2   n  and includes a second gate insulating film  112  made of the same material as that of first gate insulating film  111 .  
     [0037] P-type impurity region  33 , as a drain region, has a portion making contact with first silicon oxide film  41  and facing to first gate electrode  51 . A hot electron is generated in the portion of p-type impurity region  33 , as a drain region, facing to first gate electrode  51  and electron  101  is injected into silicon nitride film  42 . First gate insulating film  111  and second gate insulating film  112  make direct contact with each other.  
     [0038] According to this embodiment, MONOS element  71  and field-effect transistor  72  are formed in one cell. Therefore, in the case that MONOS element  71  is not selected, field-effect transistor  72  is turned off. As a result, a so-called channel cutoff potential applied to the unselected MONOS elements becomes unnecessary. Two transistors are formed in one memory cell region and, therefore, the area per bit increases. Therefore, it is necessary to reduce, as much as possible, the size of these two transistor structures. In order to achieve this, second gate insulating film  112  of field-effect transistor  72 , which is a selection transistor, is also given an ONO structure, so that excessive mask adjustments are made unnecessary, as shown in FIG. 2.  
     [0039] Isolation insulating film  3  is formed in the surface of semiconductor substrate  1  formed from a silicon substrate. Isolation insulating film  3  may be formed either by LOCOS (local oxidation) or by trench isolation. N-type well region  2   n  is formed in semiconductor substrate  1 . A counter-doped region  4   n  wherein n-type impurities are included is formed within n-type well region  2   n.  A plurality of p-type impurity regions  33 ,  36  and  39  is formed within counter-doped region  4   n.  In addition, an n-type impurity region  40  is also formed.  
     [0040] P-type impurity regions  33 ,  36  and  39 , respectively, are constituted by p-type impurity regions  31   p,    34   p  and  37   p  of a high concentration, of which the p-type impurity concentration is relatively high, and of p-type impurity regions  32   p,    35   p  and  38   p  of a low concentration, of which the p-type impurity concentration is relatively low.  
     [0041] An ONO (oxide-nitride-oxide) film  27  made by layering a first silicon oxide film  41 , a silicon nitride film  42  and a second silicon oxide film  43  is formed on main surface  1   f.    
     [0042] First gate insulating film  111  and second gate insulating film  112 , respectively, are constituted by ONO film  27 . First gate electrode  51  of MONOS element  71  and second gate electrode  52  of field-effect transistor  72  are formed on ONO film  27 . First gate electrode  51  is formed between p-type impurity regions  33  and  36  while second gate electrode  52  is formed between p-type impurity regions  36  and  39 .  
     [0043] An interlayer insulating film  28  is formed so as to cover ONO film  27  as well as first and second gate electrodes  51  and  52 . A contact hole  28   a  is formed in interlayer insulating film  28  so as to reach p-type impurity region  33  and a plug layer  59  as a drain contact plug is filled into contact hole  28   a.  Noted that MONOS element  71  and field-effect transistor  72  are both formed within a memory cell region  21 .  
     [0044] Noted that one of the reasons why field-effect transistor  72 , as a selection transistor, is formed on the p-type impurity region  36  side, which is the source region of MONOS element  71 , is that the bit line potential at the time of write-in of data to MONOS element  71  is prevented from becoming lower via field-effect transistor  72 .  
     [0045] Furthermore, in this embodiment, electron  101  is injected into silicon nitride film  42  within first gate insulating film  111  by means of GIDL. That is to say, a high electrical field is formed in a region (region overlapping first gate electrode  51 ) facing to first gate electrode  51  of p-type impurity region  31   p  of a high concentration in p-type impurity region  33  as a drain region. As a result of this, tunneling of electrons from a valence band to a conduction band is caused, thereby electron-hole pairs are formed causing a leak current. As a result, electrons are injected into silicon nitride film  42 .  
     [0046] The voltages for the operation in this MONOS element  71  are, for example, as follows. First, at the time of write-in, the potential Vd of p-type impurity region  33 , as a drain region, is −5 V, the potential Vg of first gate electrode  51  is 5 V, the potential of p-type impurity region  36 , which is a source region, is 0 V or is open, and the potential Vnwell of n-type well region  2   n  is 0V.  
     [0047] At the time of erasure, the potential Vd of p-type impurity region  33 , as a drain region, is open, the potential Vg of first gate electrode  51  is −7 V, the potential Vs of p-type impurity region  36 , which is a source region, is open or is 7 V, and the potential Vnwell of n-type well region  2   n  is 7 V.  
     [0048] At the time of read-out, the potential Vd of p-type impurity region  33 , as a drain region, is −2.5 V, the potential Vg of first gate electrode  51  is −2.5 V, the potential Vs of p-type impurity region  36 , which is a source region, is 0 V, and the potential Vnwell of n-type well region  2   n  is 0 V. Noted that these potentials are attained in the case that the threshold voltage Vth of a long channel transistor is assumed as being set at approximately Vth &gt;3 V when no electrons are stored in ONO film  27 .  
     [0049] Here, the use of a GIDL-induced hot electron injection by forming a cell of p-channel transistors has already been reported, including by the present inventor, as a method of injection of electrons into a floating gate electrode. Concretely, it is described in IEDM Tech. Dig., 1995, p. 279, “Novel Electron Injection Method Using Band-to-Band Tunneling Induced Hot Electron for Flash Memory with a P-channel Cell.” The above described injection method is used in a non-volatile semiconductor memory device that has been structurally simplified, leading to a lowering of cost, by replacing, as an electron storage portion, the floating gate according to the concept in the above described reference with an ONO interface trap. In the case that this method of injection of electrons is used, electron injection can be carried out in a low electrical field. Since electrons are not trapped in an oxide film, the property of withstanding against rewriting is enhanced.  
     [0050] Here, it is necessary to withdraw electrons from the silicon nitride film at the time of data erasure. According to this method, the channel FN tunnel phenomenon is used. Thereby, deterioration of first silicon oxide film  41  can be restricted. In addition, it is preferable for the withdrawal of electrons to be carried out as a unit in the array block, in the same manner as in flash memory. In this case, well division per bit is not necessary so that an increase in the area of the memory block and of the decoder can be restricted.  
     [0051] In order to increase the GIDL efficiency, it is necessary for a portion where first gate electrode  51  and p-type impurity region  33 , having p-type impurity region  31   p  of a high concentration wherein the concentration of p-type impurities is 10 19  cm −3  or greater, face each other, to exist. Therefore, in order to increase the GIDL efficiency in MONOS element  71 , a conversion to a thin film for a sidewall on only the side wherein the GIDL-induced electron injection is made to generate or a conversion of a high concentration of the p -type diffusion layer may become necessary.  
     [0052] On the other hand, in order to reduce the cell size in a configuration wherein two transistors are formed in one memory cell, it is necessary to form a portion without a gate between the cell transistor and the selection transistor, that is to say, a portion between the cell transistor and the selection transistor, of the minimum possible dimensions.  
     [0053] A p-type diffusion layer of a high concentration is, in general, formed through ion implantation after the formation of sidewalls. Thereby, the same steps as above can be used for manufacture of peripheral transistors, leading to a lowering of cost. Even in the case that the step of implanting p-type impurities of a high concentration is additionally carried out, after the formation of a sidewall on a space having the minimum dimensions as a result of patterning, it becomes difficult to effectively enhance the concentration of the p-type impurities. This is because, in some cases, the sidewall fills in the space between the gate electrode of the cell transistor and the gate electrode of the selection transistor. Therefore, the selection transistor is not provided on the drain side.  
     [0054] In the case that ONO film  27  of field-effect transistor  72 , as a selection transistor, is removed in the same steps for processing peripheral transistors, it must be determined whether or not ONO is to be removed at the gate division portion between the cell transistor and the selection transistor. It is difficult to adjust the position of the mask for removing the ONO film in a region for removal having the minimum gate dimensions. Accordingly, the gate structure of field-effect transistor  72 , that is a selection transistor, is formed of ONO film  27 , thereby it becomes unnecessary to take into consideration the adjustment of the position of the mask. Furthermore, in the case that the selection transistor is provided on the source side, it is not necessary to be concerned about the potential drop, as described above, even when the oxide film thickness of the gate oxide film, having an ONO structure, effectively increases and the channel conductance is lowered.  
     [0055] Next, a manufacturing method for the non-volatile semiconductor memory device shown in FIG. 2 will be described.  
     [0056] With reference to FIG. 3, a semiconductor substrate  1  made of a silicon substrate is prepared. A memory cell region  21 , n-channel type transistor regions  22  and  23  as well as p-channel type transistor regions  24  and  25  are formed in semiconductor substrate  1 . LOCOS or STI (shallow trench isolation) is formed in a main surface  1   f  of semiconductor substrate  1  as an element isolation structure.  
     [0057] With reference to FIG. 4, a resist pattern  10  is formed on main surface  1   f  N-type impurity ions are injected into semiconductor substrate  1  in the direction shown by arrow  85  using resist pattern  10  as a mask, thereby n-type well regions  2   n  are formed. Noted that a logic circuit is formed in p-channel type transistor region  24  while a transistor driven at a high voltage is formed in p-channel type transistor region  25 .  
     [0058] With reference to FIG. 5, a resist pattern  11  is formed on main surface  1   f  of semiconductor substrate  1 . P-type impurity ions are injected into semiconductor substrate  1  in the direction shown by arrow  86  using resist pattern  11  as a mask. Thereby, p-type well regions  6   p  are formed. Here, a logic circuit is formed in n-channel type transistor region  22  while a high voltage driven transistor is formed in n-channel type transistor region  23 .  
     [0059] With reference to FIG. 6, a resist pattern  12  is formed on main surface  1   f  of semiconductor substrate  1 . N-type impurity ions are injected into semiconductor substrate  1  in the direction shown by arrow  87  using resist pattern  12  as a mask. Thereby, counter-doped regions  4   n  are formed. Counter-doped regions  4   n  are formed in memory cell region  21  and in p-channel type transistor region  24 . At this time, counter-doped regions  4   n  in memory cell region  21  and counter-doped region  4   n  in p-channel type transistor region  24  can be formed in the same injection step and, therefore, a reduction in the number of mask adjustments can be achieved, leading to a further lowering of cost.  
     [0060] With reference to FIG. 7, a resist pattern  13  is formed so as to expose n-channel type transistor region  22  in the peripheral region. P-type impurity ions are implanted into semiconductor substrate  1  in the direction shown by arrow  88  using resist pattern  13  as a mask. Thereby, a counter-doped region  8   p  is formed within p-type well region  6   p.  Counter-doped region  8   p  is formed in n-channel type transistor region  22 .  
     [0061] In reference FIG. 8, main surface  1   f  of semiconductor substrate  1  is oxidized, thereby a first silicon oxide film  41  is formed as a bottom oxide film. After that, a silicon nitride film  42  is formed by means of a CVD method (chemical vapor deposition method). A second silicon oxide film  43  is formed on silicon nitride film  42  as a top oxide film using TEOS (Tetra Ethyl Ortho Silicate) as a material. After that, a resist pattern  14  is formed for solely covering memory cell region  21 . After that, an etchant is sprayed onto first silicon oxide film  41 , silicon nitride film  42  and second silicon oxide film  43  in the direction shown by arrow  89 , thereby the ONO film in the peripheral region is removed.  
     [0062] With reference to FIG. 9, thick gate insulating films  45  are formed in n-channel type transistor region  23 , which has a peripheral high voltage system, and in p-channel type transistor region  24 . In general, a high voltage system handles a high voltage in comparison with a logic system and, therefore, an oxide film of a great film thickness is used in a high voltage system. Such an oxide film is formed by carrying out two oxidation processes.  
     [0063] First, the first oxidation is carried out by taking the increase in the amount of oxidation of the gate in the logic system region in the post-process into consideration. After that, resist pattern  15  is formed through a photomechanical process. An etchant is sprayed onto gate insulating films  45  in n-channel type transistor region  22  and in p-channel type transistor region  24  in the direction shown by arrow  90 , thereby gate insulating films  45  in these portions are removed.  
     [0064] With reference to FIG. 10, gate oxidation is carried out on n-channel type transistor regions  22  and  23  as well as on p-channel type transistor region  24  and  25 . As a result, gate insulating films  45  having the desired thicknesses are formed over the entirety of the peripheral region. A conductive material that becomes the gate electrodes is deposited. A resist pattern  16  is formed on this conductive material. The conductive material is etched using the resist pattern as a mask, thereby first and second gate electrodes  51  and  52 , as well as gate electrodes  53  to  56  in the peripheral region, are formed.  
     [0065] With reference to FIG. 11, a resist pattern  17  is formed on semiconductor substrate  1 . Resist pattern  17  exposes n-channel type transistor region  22 . N-type impurity ions are injected into n-channel type transistor region  22  in the direction shown by arrow  91 , thereby n-type impurity regions  61   n  of a low concentration are formed on each side of gate electrode  53 .  
     [0066] With reference to FIG. 12, a resist pattern  18  is formed on semiconductor substrate  1 . Resist pattern  18  exposes memory cell region  21  and p-channel type transistor region  24 . P-type impurity ions are injected into memory cell region  21  and p-channel type transistor region  24  in the direction shown by arrow  92  using resist pattern  18  as a mask. Thereby, p-type impurity regions  32   p,    35   p,    38   p  and  62   p  of a low concentration are formed.  
     [0067] With reference to FIG. 13, a silicon oxide film is formed so as to cover first and second gate electrodes  51  and  52  as well as gate electrodes  53  to  56  and first sidewall insulating film  64   a,  second sidewall insulating film  64   b  and sidewall insulating films  64   c  to  64   f  are formed by etching back the entire surface of this silicon oxide film. A resist pattern  19  is formed on semiconductor substrate  1 . Resist pattern  19  exposes n-channel type transistor regions  22  and  23 . N-type impurity ions are injected into semiconductor substrate  1  in the direction shown by arrow  93  using resist pattern  19  as a mask. Thereby, n-type impurity regions  65   n  of a high concentration are formed.  
     [0068] With reference to FIG. 14 a resist pattern  20  is formed on semiconductor substrate  1 . Resist pattern  20  exposes memory cell region  21  as well as p-channel type transistor regions  24  and  25 . P-type impurity ions are injected into memory cell region  21  as well as p-channel type transistor regions  24  and  25  in the direction shown by arrow  94  using resist pattern  20  as a mask. Thereby, p-type impurity regions  31   p,    34   p,    37   p  and  67   p  of a high concentration are formed.  
     [0069] With reference to FIG. 15, an interlayer insulating film  28  is formed on semiconductor substrate  1 . A resist pattern  29  having a predetermined pattern is formed on interlayer insulating film  28 . Interlayer insulating film  28  is etched using resist pattern  29  as a mask, thereby contact holes  28   a  are formed. After that, plug layers are formed so as to fill in into contact holes  28   a,  and then a non-volatile semiconductor memory device shown in FIG. 2 is completed. Here, non-volatile semiconductor memory device  100  in FIG. 2 is shown as an enlarged view of a portion of memory cell region  21  in FIGS.  2  to  15 .  
     [0070] In such a non-volatile semiconductor memory device, first gate insulating film  111  of MONOS element  71  and second gate insulating film  112  of field-effect transistor  72 , which is a selection transistor, are formed of the same ONO film  27 . Therefore, these ONO films  27  can be manufactured in one step so that field-effect transistor  72 , which is a selection transistor, can be formed without increasing the number of manufacturing steps.  
     [0071] Second Embodiment  
     [0072] With reference to FIG. 16, a non-volatile semiconductor memory device  100  according to a second embodiment of the present invention differs from non-volatile semiconductor memory device  100  according to the first embodiment in the point that first gate insulating film  111  of MONOS element  71  and second gate insulating film  112  of field-effect transistor  72 , which is a selection transistor, are separated from each other though they are formed of the same ONO film  27  in non-volatile semiconductor memory device  100  according to the second embodiment. Furthermore, the drain region of MONOS element  71  is formed solely of p-type impurity region  31   p  of a high concentration while the source region of MONOS element  71  is formed solely of p-type impurity region  34   p  of a high concentration. In addition, the source region of field-effect transistor  72  is formed solely of p-type impurity region  37   p  of a high concentration. Furthermore, a counter-doped region is not formed within n-type well region  2   n.    
     [0073] Non-volatile semiconductor memory device  100  according to the second embodiment of the present invention, formed in the above described manner, has the same effects as of non-volatile semiconductor memory device  100  according to the first embodiment.  
     [0074] Third Embodiment  
     [0075] With reference to FIG. 17, a non-volatile semiconductor memory device according to a third embodiment of the present invention includes a memory cell region  21  and an n-channel type transistor region  22  of the first embodiment. N-type well region  2   n  is formed in semiconductor substrate  1  in memory cell region  21 . P-type impurity region  34   p  of a high concentration as a source region and a p-type impurity region  31   p  of a high concentration as a drain region are formed in n-type well region  2   n.  A first gate insulating film  111  is formed between p-type impurity regions  31   p  and  34   p  of a high concentration. First gate insulating film  111  is constituted by an ONO film  27 . ONO film  27  is constituted by a first silicon oxide film  41 , a silicon nitride film  42  formed on first silicon oxide film  41  and a second silicon oxide film  43  formed on silicon nitride film  42 . A first gate electrode  51  is formed on first gate insulating film  111 . Sidewall insulating films  64   a  are formed on sidewalls  51   s  of first gate electrode  51 .  
     [0076] P-type well region  6   p  is formed in semiconductor substrate  1  in n-channel type transistor region  22 . A pair of n-type impurity regions  66  is formed in p-type well region  6   p.  N-type impurity regions  66  are constituted by n-type impurity regions  61   n  of a low concentration, wherein the n-type impurity concentration is low, and of n-type impurity regions  65   n  of a high concentration, wherein the n-type impurity concentration is high.  
     [0077] A gate insulating film  45  constituted by a silicon oxide film is formed between the pair of n-type impurity regions  66 . A gate electrode  53  is formed on gate insulating film  45 . Gate electrode  53  has sidewalls  53   s,  and sidewall insulating films  64   c  are formed so as to make contact with these sidewalls  53   s.    
     [0078] Non-volatile semiconductor memory device  100  is provided with: semiconductor substrate  1  having main surface  1   f;  n-type well region  2   n,  as an n-type semiconductor region, formed in semiconductor substrate  1 ; MONOS element  71 , as a non-volatile semiconductor memory element, formed in n-type well region  2   n;  p-type well region  6   p,  as a p-type semiconductor region, formed in semiconductor substrate  1 ; and field-effect transistor  73  formed in p-type well region  6   p.    
     [0079] MONOS element  71  includes: first gate insulating film  111  formed on main surface  1   f  so as to be located on n-type well region  2   n;  first gate electrode  51  formed on first gate insulating film  111 ; first sidewall insulating films  64   a  formed on sidewalls  5  is of first gate electrode  51 ; pair of p-type impurity regions  34   p  and  31   p  of a high concentration, as a source region and a drain region, formed of p-type impurity regions on each side of first gate electrode  51  in n-type well region  2   n.    
     [0080] First gate insulating film  111  includes: first silicon oxide film  41  formed on main surface  1   f  silicon nitride film  42  formed on first silicon oxide film  41 ; and second silicon oxide film  43  formed on silicon nitride film  42 . MONOS element  71  stores information by injecting electrons  101  into silicon nitride film  42 .  
     [0081] P-type impurity region  31   p  of a high concentration, as a drain region, has a portion making contact with first silicon oxide film  41  and facing to first gate electrode  51 . Hot electrons are generated by means of GIDL in the portion of p-type impurity region  33 , as a drain region, facing to first gate electrode  51  so that electrons  101  are injected into silicon nitride film  42 .  
     [0082] Field-effect transistor  73  includes: second gate electrode  53  formed on p-type well region  6   p  so as to interpose gate insulating film  45  therebetween; and second sidewall insulating films  64   c  formed on sidewalls  53   s  of second gate electrode  53 . The width W1 of first sidewall insulating films  64   a  is smaller than the width W3 of second sidewall insulating films  64   c.    
     [0083] Field-effect transistor  73  includes a pair of n-type impurity regions  65   n  of a high concentration, as a source region and a drain region, constituted by n-type impurity regions on each side of gate electrode  53 , as the second gate electrode, in p-type well region  6   p.  P-type impurity regions  31   p  and  34   p  of a high concentration as well as n-type impurity region  63   n  of a high concentration of MONOS element  71  and of field-effect transistor  73  are formed by injecting impurities into semiconductor substrate  1  using first and second sidewall insulating films  64   a  and  64   c  as a mask. Therefore, p-type impurity region  31   p  of a high concentration is formed up to the vicinity of first gate electrode  51 .  
     [0084] In order to make GIDL efficiency generate as described above, p-type impurity regions  31   p  of a high concentration must be formed in the above described manner with respect to the gate electrode so that the impurity concentration thereof becomes of 10 19  cm −3  or greater and p-type impurity region  31   p  of a high concentration overlaps gate electrode  51 .  
     [0085] An additional new mask is not necessary for the formation of p-type impurity regions  31   p  and  34   p  of a high concentration, which is carried out in the same steps as for the formation of the source and drain regions of the transistors in the peripheral region. P-type impurity regions  31   p  and  34   p  of a high concentration are formed by implantation using sidewall insulating films  64   a  as a mask. Afterward, P-type impurity regions  31   p  and  34   p  of a high concentration spread through a thermal treatment so as to form gate overlap regions.  
     [0086] The main factors that decide the width of the sidewall insulating films are hot carrier effects within n-channel type transistor region  22  of a logic circuit. Accordingly, in the case that the width of each of first sidewall insulating films  64   a  is narrowed before the injection for p-type impurity regions  31   p  and  34   p  of a high concentration, it becomes easy to secure the overlap regions between first gate electrode  51  and p-type impurity region  31   p  of a high concentration, which are formed through a subsequent heat treatment.  
     [0087] The width of first sidewall insulating film  64   a  may be narrowed immediately before the step shown in FIG. 14 in the above described manufacturing method. In this case, n-type impurity regions  65   n  of a high concentration are formed according to the steps shown in FIG. 13 under the condition wherein second sidewall insulating films  64   c  in n-channel type transistor region  22  are thick. That is to say, p-type impurity region  34   p  of a high concentration, as the source region of MONOS element  71 , and p-type impurity region  31   p  of a high concentration, as the drain region, are formed by injecting impurities into semiconductor substrate  1  using first sidewall insulating film  64   a  of a small width as a mask while n-type impurity regions  66 , as the source region and the drain region of field-effect transistor  73 , are formed by injecting impurities into semiconductor substrate  1  using second sidewall insulating film  64   c  of a great width as a mask.  
     [0088] In non-volatile semiconductor memory device  100  according to the third embodiment of the present invention formed in the above described manner, the width W2 of the region where first gate electrode  51  and p-type impurity region  31   p  of a high concentration, which forms the drain region, overlap can be secured and, therefore, the GIDL efficiency becomes great so that injection of electrons becomes easy. Furthermore, the generation of hot carriers in n-channel type transistor region  22 , which is the periphery, can be prevented.  
     [0089] Fourth Embodiment  
     [0090] With reference to FIG. 18, a non-volatile semiconductor memory device  100  according to a fourth embodiment of the present invention has a memory cell region  21  formed in semiconductor substrate  1 . An n-type well region  2   n  is formed in semiconductor substrate  1  in memory cell region  21 . A MONOS element  71  is formed in n-type well region  2   n.    
     [0091] MONOS element  71  has a pair of p-type impurity regions,  34   p  and  31   p,  of a high concentration as the source and drain regions formed at a distance from each other and a first gate electrode  51  formed above main surface  1   f  between these regions. P-type impurity regions  34   p  and  31   p  of a high concentration are formed within an n-type well region  2   n.  P-type impurity region  34   p  of a high concentration is the source region while p-type impurity region  31   p  of a high concentration is the drain region.  
     [0092] First gate insulating film  111  is formed on main surface  1   f  so as to be interposed between a pair of source and drain regions. First gate insulating film  111  is constituted by an ONO film  27 , and ONO film  27  has a first silicon oxide film  41  formed on main surface  1   f,  a silicon nitride film  42  formed on first silicon oxide film  41  and a second silicon oxide film  43  formed on silicon nitride film  42 .  
     [0093] First gate electrode  51  is formed on first gate insulating film  111  and first sidewall insulating films  64   a  are formed so as to make contact with sidewalls  51   s  of the first gate electrode.  
     [0094] Non-volatile semiconductor memory device  100  is provided with: semiconductor substrate  1  having main surface  1   f;  n-type well region  2   n  as an n-type semiconductor region formed on semiconductor substrate  1 ; and MONOS element  71  as a non-volatile semiconductor memory element formed in n-type well region  2   n.  MONOS element  71  includes: first gate insulating film  111 , as a first insulating film formed on main surface  1   f  so as to be located on n-type well region  2   n;  a first gate electrode  51  provided on first gate insulating film  111 ; and a pair of p-type impurity regions of high concentration  34   p  and  31   p,  as source region and drain region, formed in n-type well region  2   n  and on both sides of first gate electrode  51 , and constituted by the p-type impurity region.  
     [0095] First gate insulating film  11  includes: first silicon oxide film  41  formed on main surface  1   f;  silicon nitride film  42  formed on first silicon oxide film  41 ; and second silicon oxide film  43  formed on silicon nitride film  42 . MONOS element  71 , as a non-volatile semiconductor memory element, stores information by injecting electrons into first gate insulating film  111 .  
     [0096] P-type impurity regions  34   p  and  31   p  of a high concentration have portions making contact with first silicon oxide film  41  and facing to first gate electrode  51 . The width W4 of the portion of p-type impurity region  31   p  of a high concentration, which is the drain region, facing to first gate electrode  51  is greater than the width W5 of the portion of p-type impurity region  34   p  of a high concentration, which is the source region, facing to first gate electrode  51 .  
     [0097] Non-volatile semiconductor memory device  100  is further provided with first sidewall insulating films  64   a,  as a pair of sidewall insulating films, formed on sidewalls  51   s  on each side of first gate electrode  51 . The sidewall insulating film provided on the source region side has a relatively great width W7 while sidewall insulating film  64   a  provided on the drain region side has a relatively small width W6.  
     [0098] As for a manufacturing method for such a non-volatile semiconductor memory device  100 , a resist mask that exposes p-type impurity region  31   p  of a high concentration, which is the drain region, is formed before the formation of p-type impurity regions  34   p  and  31   p  of a high concentration. Sidewall insulating films  64   a  are etched using this resist pattern as a mask, thereby the width of sidewall insulating film  64   a  on the drain region side is reduced. P-type impurity regions are implanted using sidewall insulating films  64   a  as a mask, thereby p-type impurity region  34   p  of a high concentration, as the source region, and p-type impurity region  31   p  of a high concentration, as the drain region, are formed. Thereby, the overlap region of p-type impurity region  31   p  of a high concentration and first gate electrode  51  can be expanded solely on the drain side wherein the generation of GIDL is desired. In contrast to this, the width W7 of sidewall insulating film  64   a  can be conventionally secured on the source side and, therefore, the channel length of the cell transistor is shortened only by the length of one side so that the short channel effect can be suppressed.  
     [0099] Fifth Embodiment  
     [0100] With reference to FIG. 19, an n-type well region  2   n  is formed in a semiconductor substrate  1  in a non-volatile semiconductor memory device according to a fifth embodiment of the present invention. MONOS elements  71  and  72  are formed in n-type well region  2   n.  MONOS elements  71  and  72  have p-type impurity regions  34   p  of a high concentration as the source regions and p-type impurity regions  31   p  and  37   p  of a high concentration as the drain regions.  
     [0101] In addition, MONOS elements  71  and  72  have first and second gate insulating films  111  and  112  formed between the source regions and the drain regions and gate electrodes  51   a,    51   b,    52   a  and  52   b  formed on these gate insulating films. First and second gate insulating films  111  and  112  are constituted by ONO films  27 , and these ONO films  27  are formed by layering first silicon oxide films  41 , silicon nitride films  42  and second silicon oxide films  43 . Gate electrodes  51   a  and  52   a  are formed on first and second gate insulating films  111  and  112 .  
     [0102] P-type impurity region  34   p  of a high concentration, as the source region, and p-type impurity region  31   p  of a high concentration, as the drain region have portions contacting first silicon oxide film  41  and facing gate electrode  51   a,  as the first gate electrode. The width of the portion of p-type impurity region  31   p  of a high concentration, as the drain region facing gate electrode  51   a  is greater than the width of the portion of p-type impurity region  34   p  of a high concentration, as the source region, facing gate electrode  51   a,  as the first gate electrode.  
     [0103] Non-volatile semiconductor memory device  100  is further provided with: a second gate electrode  52   a  formed on the p-type impurity region  34   p  side of a high concentration, as the source region, so as to be isolated from gate electrode  51   a;  and gate electrode  51   b,  as the third gate electrode, formed on the p-type impurity region  31   p  side of a high concentration, as the drain region, so as to be isolated from gate electrode  51   a.  The distance W10 between gate electrode  51   a  and gate electrode  51   b  is greater than the distance W   9   between first gate electrode  51   a  and gate electrode  52   a.  The width W8 of each of the gate electrodes  51   a  and  52   a  and the width W9 between the gate electrodes in p-type impurity region  34   p  of a high concentration, as the source region, are approximately equal. In contrast to this, the distance W10 between the gate electrodes in p-type impurity region  31   p  of a high concentration, as the drain region, is approximately twice as W8.  
     [0104] Next, a manufacturing method for the non-volatile semiconductor memory device shown in FIG. 19 will be described. A diagonal injection of impurity ions is utilized in order to form the source regions and the drain regions shown in FIG. 19.  
     [0105] That is to say, as shown in FIG. 20, impurity ions are injected into semiconductor substrate  1  in the direction formed an acute angle relative to main surface  1   f  using the second and third gate electrodes as a mask, thereby p-type impurity regions  34   p  of a high concentration, as the source regions, and p-type impurity regions  31   p  of a high concentration, as the drain regions, are formed. At this time, the distances between the gate electrodes in p-type impurity regions  31   p  of a high concentration, as the drain regions, are great so that a sufficient amount of impurities is injected into the drain regions. Therefore, the width W11 of each of p-type impurity regions  31   p  of a high concentration facing gate electrodes  51   a  and  52   a  becomes relatively great.  
     [0106] In contrast to this, the widths between the gate electrodes in p-type impurity regions  34   p  of a high concentration, as the source regions, are narrow so that a sufficient amount of impurity ions is not injected. As a result, the width W12 of each of the portions of p-type impurity regions  34   p  of a high concentration, facing to gate electrodes  52   a  and  51   a  becomes relatively small.  
     [0107] The non-volatile semiconductor memory device according to the fifth embodiment of the present invention formed in such a manner, has the same effects as of non-volatile semiconductor memory device  100  according to the third embodiment.  
     [0108] According to the present invention, a GIDL-induced hot electron injection is used as an injection method of electrons in a p-channel type MONOS element, thereby the following effects are obtained. That is to say, the device can be manufactured at a low cost using a simplified process, in comparison with a flash memory. Miniaturization of the cell size becomes possible, in comparison with a conventional MONOS device. The device has excellent withstanding properties against rewriting, in comparison with an NROM (nitride read only memory).  
     [0109] The field-effect transistor includes a pair of source region and drain region formed in the p-type semiconductor regions and on both sides of the second gate electrode, and constituted by an n-type impurity region. The source region and the drain region of the non-volatile semiconductor memory element are formed by implanting impurities into the semiconductor substrate using the first sidewall insulating films as a mask while the source regions and the drain regions of the field-effect transistor are formed by implanting impurities into the semiconductor substrate using the second sidewall insulating films as a mask.  
     [0110] In this case, the source regions and the drain regions of the non-volatile semiconductor memory element and of the field-effect transistor are formed by injecting impurities into the semiconductor substrate using the first and second sidewall insulating films as a mask and, therefore, the distance between the first gate electrode and the source region in the non-volatile semiconductor memory element as well as the distance between the first gate electrode and the drain region in the non-volatile semiconductor memory element become relatively small while the distance between the second gate electrode and the source region in the field-effect transistor as well as the distance between the second gate electrode and the drain region in the field-effect transistor become relatively great. Therefore, the area of the portion where the first gate electrode and the drain region overlap becomes great in the non-volatile semiconductor memory device so that hot electrons can be generated in the portion of the drain facing the first gate electrode and these electrons can be injected into the first gate insulating film.  
     [0111] Impurity ions are injected into the semiconductor substrate using the second sidewall insulating films, having relatively great thicknesses, as a mask so that the source region and the drain region are formed in the n channel-type field-effect transistor and, therefore, the distance between the second gate electrode and the source region as well as the distance between the second gate electrode and the drain region become great. As a result, the distance between the source and drain regions can be secured so that the generation of hot carriers can be prevented.  
     [0112] The non-volatile semiconductor memory device is further provided with a pair of sidewall insulating films formed on the sidewalls on each side of the first gate electrode. The sidewall insulating film provided on the source region side has a relatively great width while the sidewall insulating film provided on the drain region side has a relatively small width. In this case, when the source region and the drain region are formed by implanting impurities into the silicon substrate using the sidewall insulating films as a mask, the drain region is formed in a portion close to the first gate electrode while the source region is formed in a portion far away from the first gate electrode. As a result, the width of the portion where the drain region and the first gate electrode face each other becomes great so that hot carriers are generated in the portion of the drain region facing the first gate electrode and these electrons can be injected into the first gate insulating film.  
     [0113] The non-volatile semiconductor memory device is further provided with a second gate electrode formed on the source region side so as to be isolated from the first gate electrode and with a third gate electrode formed on the drain region side so as to be isolated from the first gate electrode. The distance between the first gate electrode and the third gate electrode is greater than the distance between the first gate electrode and the second gate electrode.  
     [0114] The source region and the drain region are formed by implanting impurities into the semiconductor substrate in the direction forming an acute angle relative to the main surface using the second and third gate electrodes as a mask. The source region and the drain region have portions contacting the first silicon oxide film and facing the first gate electrode. The width of the portion of the drain region facing the first gate electrode is greater than the width of the portion of the source region facing the first gate electrode. As for the formation of such a source region and drain region, such a source region and drain region are formed by implanting impurity ions into the semiconductor substrate using the second and third gate electrodes as a mask. As a result, the source region and the drain region can be formed without specifically increasing the number of steps.  
     [0115] Although the present invention has been described and illustrated in detail, it is clearly understood that the same is by way of illustration and example only and is not to be taken by way of limitation, the spirit and scope of the present invention being limited only by the terms of the appended claims.