Patent Publication Number: US-2003224942-A1

Title: Alkylamino-1,3,5-triazines, processes for their preparation and their use as herbicides and plant growth regulators

Description:
[0001] The invention relates to the technical field of the crop protection agents, such as herbicides and plant growth regulators, in particular herbicides for the selective control of harmful plants in crops of useful plants.  
       [0002] It is known that 4-amino-2-[N-(1-arylalkyl)amino]-1,3,5-triazines which are optionally substituted in the 6-position on the triazine ring by unsubstituted or halogenated hydrocarbon groups or else by other groups, and their derivatives, have herbicidal and plant-growth-regulating properties; cf., for example, DE-A-19826670, DE-A-19828519, EP-A-0191496, EP-A-573897, EP-A-573898, JP-A-62,294,669, JP-A-62,298,577, JP-A-1 0025211, JP-A-08198712, US-A-3816419, US-A-5290754 (WO-A-90/9378, EP-A-0411153), WO-A-95/06642, WO-A-97/08156, WO-A-97/31904, WO-A-97/35481, WO-A-98/10654, WO-A-98/15536, WO-A-98/15537, WO-A-98/15538, WO-A-98/15539, WO-A-98/34925, WO-A-98/42684, WO-A-99/188100, WO-A-99/19309, WO-A-99/37627, WO-A-99/44999, WO-A-99/46249, WO-A-99/65882, WO-A-00/00480, WO-A-00/1 6627, WO-A-00/32580, WO-A-00/47579, WO-A-00/56722, WO-A-00/69854 and WO-A-01/10849 and the literature cited in these publications.  
       [0003] Some of the known active compounds have, when used, disadvantages, such as insufficient herbicidal activity against harmful plants, too limited a spectrum of harmful plants which can be controlled with an active compound, or insufficient selectivity in crops of useful plants. Other active compounds cannot be prepared economically on an industrial scale, owing to reagents and precursors which are difficult to obtain, or they have insufficient chemical stability. Accordingly, it is desirable to provide alternative active compounds which may optionally be employed advantageously as herbicides or plant growth regulators. The present invention provides compounds of the formula (I) and salts thereof  
                 
 
       [0004] where  
       [0005] R 1  is (C 1 -C 10 )alkyl, (C 3 -C 6 )cycloalkyl, (C 1 -C 10 )alkoxy or (C 1 -C 10 )alkylthio, where each of the 4 last-mentioned radicals is unsubstituted or substituted by one or more radicals selected from the group consisting of halogen and, in the case of cyclic radicals, also (C 1 -C 6 )alkyl and (C 1 -C 6 )haloalkyl,  
       [0006] preferably R 1 =(C 1 -C 10 )alkyl or (C 3 -C 6 )cycloalkyl, where each of the 2 last-mentioned radicals is unsubstituted or substituted by one or more radicals selected from the group consisting of halogen and, in the case of cyclic radicals, also (C 1 -C 6 )alkyl and (C 1 -C 6 )haloalkyl,  
       [0007] R 2  and R 3  independently of one another are hydrogen, (C 1 -C 4 )alkyl, formyl or [(C 1 -C 10 )alkyl]carbonyl which is unsubstituted or substituted by one or more halogen atoms,  
       [0008] R 4  is hydrogen, (C 1 -Clo)alkyl, (C 2 -Clo)alkenyl, (C 2 -C 10 )alkynyl or (C 3 -C 6 )cycloalkyl, where each of the 4 last-mentioned radicals is unsubstituted or substituted by one or more radicals selected from the group consisting of halogen and, in the case of cyclic radicals, also (C 1 -C 6 )alkyl and (C 1 -C 6 )haloalkyl,  
       [0009] each of the radicals R 5 , R 6 , R 7 , R 8  and R 9  independently of the others is hydrogen, halogen, nitro, cyano, thiocyanato, (C 1 -C 10 )alkyl, (C 2 -C 10 )alkenyl, (C 2 -C 10 )alkynyl, (C 1 -C 10 )alkoxy, (C 2 -C 10 )alkenyloxy, (C 2 -C 10 )alkynyloxy, (C 1 -C 10 )alkylthio, (C 2 -C 10 )alkenylthio, (C 2 -C 10 )alkynylthio, (C 3 -C 6 )cycloalkyl, (C 5 -C 6 )cycloalkenyl, phenyl or heterocyclyl, where each of the 13 last-mentioned radicals is unsubstituted or substituted,  
       [0010] preferably unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, cyano, hydroxyl, amino, (C 1 -C 6 )alkoxy, (C 1 -C 6 )haloalkoxy, and (C 1 -C 6 )alkylthio and, in the case of cyclic radcials, also (C 1 -C 6 )alkyl and (C 1 -C 6 )haloalkyl, in particular unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, cyano, hydroxyl and amino and, in the case of cyclic radicals, also (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, (C 1 -C 6 )alkoxy, (C 1 -C 6 )haloalkoxy and (C 1 -C 6 )alkylthio,  
       [0011] where at least one of the radicals, preferably at least two radicals, in particular 2 or 3 radicals, especially 2 radicals, from the group consisting of R 5 , R 6 , R 7 , R 8  and R 9  is different from hydrogen and where at least one of the radicals R 5 , R 6 , R 7 , R 8  and R 9 , preferably one of the radicals mentioned, is selected from the group consisting of the radicals (C 2 -C 10 )alkenyl, (C 2 -C 10 )alkynyl, (C 3 -C 6 )cycloalkyl and (C 5 -C 6 )cycloalkenyl, where each of the 4 last-mentioned radicals is unsubstituted or substituted, preferably unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, cyano, hydroxy and amino and, in the case of cyclic radicals, also (C 1 -C 6 )alkyl, (C 1 -C 6 )haloalkyl, (C 1 -C 6 )alkoxy, (C 1 -C 6 )haloalkoxy and (C 1 -C 6 )alkylthio.  
       [0012] The invention also provides all stereoisomers embraced by the formula (I), and their mixtures. Such compounds of the formula (I) contain one or more asymmetrically substituted carbon atoms or else double bonds which are not specifically mentioned in the general formulae (I). The possible stereoisomers defined by their specific spatial form, such as enantiomers and diastereomers, including Z and E isomers, are all embraced by the formula (I) and can be obtained by customary methods from mixtures of the stereoisomers or else by stereoselective reactions in combination with the use of stereochemically pure or enriched starting materials. Of particular interest are also the stereoisomers which are formed by the asymmetrically substituted carbon atom to which the group R 4  is attached if R 4  is not hydrogen. The isomers which are R- and S-configured at this center, which are enantiomers, if the molecule of the formula (I) contains no further asymmetrically substituted carbon atom, thus also form part of the subject matter of the invention. In general, the biological activities of these R and S isomers are not identical, but in the individual case, one of the isomers has, depending on the species of harmful plant and the crop, a higher herbicidal action or selectivity.  
       [0013] If compounds of the formula (I) are also capable of forming tautomers which are structurally not formally represented or embraced by the formula (I), these tautomers are nevertheless embraced by the definition of the compounds of the formula (I) according to the invention.  
       [0014] The compounds of the formula (I) can form salts by addition of a suitable inorganic or organic acid, such as, for example, HCI, HBr, H 2 SO 4  or HNO 3 , but also oxalic acid or sulfonic acids, to a basic group, such as, for example, amino or alkylamino. Suitable substituents which are present in deprotonated form, such as, for example, sulfonic acids or carboxylic acids, can form inner salts with groups which for their part can be protonated, such as amino groups. Salts can also be formed by replacing the hydrogen of suitable substituents, such as, for example, sulfonlic acid s or carboxylic acids, by an agriculturally suitable cation. These salts are, for example, metal salts, in particular alkali metal salts or alkaline earth metal salts, in particular sodium salts and potassium salts, or else ammonium salts or salts with organic amines.  
       [0015] In the formula (I) and all the formulae hereinbelow, the radicals alkyl, alkoxy, haloalkyl, haloalkoxy, alkylamino and alkylthio and the corresponding unsaturated and/or substituted radicals can in each case be straight-chain or branched in the carbon skeleton. Unless specifically mentioned otherwise, the lower carbon skeletons, for example with 1 to 6 carbon atoms, or in the case of unsaturated groups with 2 to 6 carbon atoms, are preferred for these radicals. Alkyl radicals, also in the composed meanings, such as alkoxy, haloalkyl, and the like, are, for example, methyl, ethyl, n- or isopropyl, n-, i-, t- or 2-butyl, pentyls, hexyls, such as n-hexyl, isohexyl and 1,3-dimethylbutyl, heptyls, such as n-heptyl, 1-methylhexyl and 1,4-dimethylpentyl; alkenyl and alkynyl radicals have the meaning of the possible unsaturated radicals which correspond to the alkyl radicals; alkenyl is, for example, allyl, 1-methylprop-2-en-1-yl, 2-methylprop-2-en-1-yl, but-2-en-1-yl, but-3-en-1-yl, 1-methyl-but-3-en-1-yl and 1-methyl-but-2-en-1-yl; alkynyl is, for example, propargyl, but-2-yn-1-yl, but-3-yn-1-yl, 1-methylbut-3-yn-1-yl; alkenyl also includes in particular straight-chain or branched hydrocarbons with more than one-double bond, such as 1,3-butadienyl and 1,4-pentadienyl, but also allenyl or aminlenyl radicals with one or more cumulated double bonds, such as, for example, allenyl (1,2-propadienyl), 1,2-butadienyl and 1 ,2,3-pentatrienyl; alkynyl is, for example, propargyl, but-2-yn-1-yl, but-3-yn-1-yl, 1-methylbut-3-yn-1-1 yl. Alkynyl also includes in particular straight-chain or branched hydrocarbon radicals with more than one triple bond or also with one or more triple bonds and one or more double bonds, such as, for example, 1,3-butatrienyl or 3-pentene-1-yn-1-yl.  
       [0016] Alkylidene, for example also in the form (C 1 -C 10 )alkylidene, is the radical of a straight-chain or branched alkane which is attached via a double bond, the position of the binding site not yet being fixed. In the case of a branched alkane, the only possible positions are, of course, those where two hydrogen atoms can be replaced by the double bond; examples of radicals are ═CH 2 , ′CH—CH 3 , ═C(CH 3 )—CH 3 , ═C(CH 3 )—C 2 H 5  or ═C(C 2 H 5 )—C 2 H 5 .  
       [0017] Cycloalkyl is a carbocyclic saturated ring system having preferably 3-8 carbon atoms, for example cyclopropyl, cyclobutyl, cyclopentyl or cyclohexyl. In the case of substituted cycloalkyl, this includes cyclic systems with substituents, where the substitutents are attached to the cycloalkyl radical via a double bond, for example an alkylidene group such as methylidene. Substituted cycloalkyl also includes polycyclic aliphatic systems, such as, for example, bicyclo[1.1.0]butan-1-yl, bicyclo[1.1.0]butan-2-yl, bicyclo[2.1.0]pentan-1-yl, bicyclo[2.1.0]pentan-2-yl, bicyclo[2.1.0]pentan-5-yl, adamantan-1-yl and adamantan-2-yl.  
       [0018] Cycloalkenyl is a carbocyclic, non-aromatic, partially unsaturated ring system having preferably 4-8 carbon atoms, for example 1-cyclobutenyl, 2-cyclobutenyl, 1-cyclopentenyl, 2-cyclopentenyl, 3-cyclopentenyl, or 1-cyclohexenyl, 2-cyclohexenyl, 3-cyclohexenyl, 1,3-cyclohexadienyl or 1,4-cyclohexadienyl. For substituted cycloalkenyl, the illustrations for substituted cycloalkyl apply correspondingly.  
       [0019] Halogen is, for example, fluorine, chlorine, bromine or iodine. Haloalkyl, -alkenyl and -alkynyl is alkyl, alkenyl and alkynyl, respectively, which is partially or fully substituted by halogen, preferably by fluorine, chlorine and/or bromine, in particular by fluorine or chlorine, for example, monohaloalkyl, perhaloalkyl, CF 3 , CHF 2 , CH 2 F, CF 3 CF 2 , CH 2 FCHCl, CCl 3 , CHCl 2 , CH 2 CH 2 Cl; haloalkoxy is, for example, OCF 3 , OCHF 2 , OCH 2 F, CF 3 CF 2 O, OCH 2 CF 3  and OCH 2 CH 2 Cl; this applies correspondingly to haloalkenyl and other halogen-substituted radicals.  
       [0020] Aryl is a mono-, bi- or polycyclic aromatic system, for example phenyl, naphthyl, tetrahydronaphthyl, indenyl, indanyl, pentalenyl, fluorenyl and the like, preferably phenyl.  
       [0021] A heterocyclic radical or ring (heterocyclyl) can be saturated, unsaturated or heteroaromatic; unless defined otherwise, it preferably contains one or more, in particular 1, 2 or 3, heteroatoms in the heterocyclic ring, preferably selected from the group consisting of N, O and S; it is preferably an aliphatic heterocyclyl radical having 3 to 7 ring atoms or a heteroaromatic radical having 5 or 6 ring atoms. The heterocyclic radical can, for example, be a heteroaromatic radical or ring (heteroaryl), such as, for example, a mono-, bi- or polycyclic aromatic system, in which at least 1 ring contains one or more heteroatoms. It is preferably a heteroaromatic ring having one heteroatom selected from the group consisting of N, 0 and S, for example pyridyl, pyrrolyl, thienyl or furyl; furthermore, preferably, it is a corresponding heteroaromatic ring having 2 or 3 heteroatoms, for example pyrimidinyl, pyridazinyl, pyrazinyl, triazinyl, thiazolyl, thiadiazolyl, oxazolyl, isoxazolyl, pyrazolyl, imidazolyl and triazolyl. Furthermore preferably, it is a partially or fully hydrogenated heterocyclic radical having one heteroatom selected from the group consisting of N, O and S, for example oxiranyl, oxetanyl, oxoianyl (=tetrahydrofuryl), oxanyl, pyrrolidyl or piperidyl.  
       [0022] Furthermore preferably, it is a partially or fully hydrogenated heterocyclic radical having 2 heteroatoms selected from the group consisting of N, 0 and S, for example piperazinyl, dioxolanyl, oxazolinyl, isoxazolinyl, oxazolidinyl, isoxazolidinyl and morpholinyl.  
       [0023] Possible substituents for a substituted heterocyclic radical are the substituents mentioned further below, and additionally also oxo. The oxo group can also be present at the hetero ring atoms which can exist in different oxidation states, for example at N and S.  
       [0024] Substituted radicals, such as a substituted alkyl, alkenyl, alkynyl, aryli, phenyl, benzyl, heterocyclyl and heteroaryl radical, are, for example, a substituted radical derived from the unsubstituted skeleton, where the substituents are, for example, one or more, preferably 1, 2 or 3, radicals selected from the group consisting of halogen, alkoxy, haloalkoxy, alkylthio, hydroxyl, amino, nitro, carboxyl, cyano, azido, alkoxycarbonyl, alkylcarbonyl, formyl, carbamoyl, mono- and dialkylaminocarbonyl, substituted amino, such as acylamino, mono- and dialkylamino, and alkylsulfinyl, haloalkylsulfinyl, alkylsulfonyl, haloalkylsulfonyl and, in the case of cyclic radicals, also alkyl, haloalkyl alkylthioalkyl, alkoxyalkyl, substituted or unsubstituted mono- and dialkylaminoalkyl and hydroxyalkyl; the term “substituted radicals”, such as in substituted alkyl and the like, includes as substituents, in addition to the saturated hydrocarbon-containing radicals mentioned, the corresponding unsaturated aliphatic and aromatic radicals, such as unsubstituted or substituted alkenyl, alkynyl, alkenyloxy, alkynyloxy, phenyl, phenoxy etc. Substituted cyclic radicals having aliphatic moieties in the ring also include cyclic systems having substituents which are attached to the ring via a double bond, for example those substittuted by an alkylidene group, such as methylidene or ethylidene.  
       [0025] Among the radicals with carbon atoms, preference is given to those having 1 to 4 carbon atoms, in particular 1 or 2 carbon atoms. In general, preference is given to substituents selected from the group consisting of halogen, for example fluorine and chlorine, (C 1 -C 4 )alkyl, preferably methyl or ethyl, (C 1 -C 4 )haloalkyl, preferably trifluorornethyl, (C 1 -C 4 )alkoxy, preferably methoxy or ethoxy, (C 1 -C 4 )haloalkoxy, nitro and cyano. Particular preference is given here to the substituents methyl, methoxy, fluorine and chlorine.  
       [0026] Substituted amino, such as mono- or disubstituted amino, is a radical from the group of the substituted amino radicals which are N-substituted, for example, by one or two identical or different radicals selected from the group consisting of alkyl, alkoxy, acyl and aryl; preferably mono- and dialkylamino, mono- and diarlamino, acylamino,  
       [0027] N-alkyl-N-arylamino, N-alkyl-N-acylamino and N-heterocycles; preference is given to alkyl radicals having 1 to 4 carbon atoms; aryl is preferably phenyl or substituted phenyl; for acyl, the definition mentioned further below applies, preferably (C 1 -C 4 )alkanoyl. This applies correspondingly to substituted hydroxylamino or hydrazino.  
       [0028] Unsubstituted or substituted phenyl is preferably phenyl which is unsubstituted or mono- or polysubstituted, preferably up to trisubstituted, by identical or different radicals selected from the group consisting of halogen, (C 1 -C 4 )alkyl, (C 1 -C 4 )alkoxy, (C 1 -C 4 )haloalkyl, (C 1 -C 4 )haloalkoxy and nitro, for example o-, m- and p-tolyl, dimethylphenyls, 2-, 3- and 4-chlorophenyl, 2-, 3- and 4-trifluoromethylphenyl and 2-,3-, and 4- trichloromethylphenyl, 2,4-, 3,5-, 2,5- and 2,3-dichlorophenyl, o-, m- and p-methoxyphenyl.  
       [0029] Acyl is a radical of an organic acid which is formally formed by removing a hydroxyl group from the acid function, where the organic radical in the acid can also be attached to the acid function via a heteroatom. Examples of acyl are the radical —CO—R of a carboxylic acid HO—CO—R and radicals of acids derived therefrom, such as thiocarbonic acid, unsubstituted or N-substituted iminocarboxylic acids or the radical of carbonic monoesters, N-substituted carbamic acid, sulfonic acids, sulfinic acids, N-substituted sulfonamide acids, phosphonic acids, phosphinic acids. Acyl is, for example, formyl, alkylcarbonyl, such as [(C 1 -C 4 )alkyl]carbonyl, phenylcarbonyl, alkyloxycarbonyl, phenyloxycarbonyl, benzyloxycarbonyl, alkylsulfonyl, alkylsulfinyl, N-alkyl-1-iminoalkyl and other radicals of organic acids. The radicals can in each case be further substituted in the alkyl or phenyl moiety, for example in the alkyl moiety by one or more radicals selected from the group consisting of halogen, alkoxy, phenyl and phenoxy; examples of substituents in the phenyl moiety are the substituents which have already been mentioned further above generally for substituted phenyl.  
       [0030] Acyl is preferably an acyl radical in the more restricted sense, i.e. a radical of an organic acid where the acid group is directly attached to the carbon atom of an organic radical, for example formyl, alkylcarbonyl, such as acetyl or [(C 1 -C 4 )alkyl]carbonyl, phenylcarbonyl, alkyisulfonyl, alkylsulfinyl and other radicals of organic acids.  
       [0031] In particular for reasons of better herbicidal activity, better selectivity and/or easier preparation, those novel compounds of the formula (I) mentioned or their salts are of particular interest in which individual radicals have one of the preferred meanings already mentioned or mentioned hereinbelow, or, in particular, those, in which one or more of the preferred meanings already mentioned or mentioned hereinbelow are combined.  
       [0032] Of interest are, for example, compounds of the formula (I) according to the invention or salts thereof in which  
       [0033] R 1  is (C 1 -C 6 )alkyl, preferably (C 1 -C 4 )alkyl, or (C 3 -C 6 )cycloalkyl, preferably cyclopropyl, cyclobutyl, cyclopentyl or cyclohexyl, where each of the 7 last-mentioned radicals is unsubstituted or substituted by one or more halogen atoms. R 1  is for example methyl, ethyl, n- or isopropyl, 1-fluoro-1-methylethyl, 1-fluoroethyl, 1-fluoropropyl, CF 3 , CC 13 , cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, 1-methylcyclopropyl, 1-methylcyclobutyl, 1-methylcyclopentyl or 1-methylcyclohexyl. R 1  is in particular (C 1 -C 4 )alkyl or (C 1 -C 4 )haloalkyl.  
       [0034] Also of interest are, for example, compounds of the formula (I) according to the invention or salts thereof in which  
       [0035] R 2  and R 3  independently of one another are hydrogen, formyl, methyl, ethyl or [(C 1 -C 4 )alkyl]carbonyl or [(C 1 -C 4 )haloalkyl]carbonyl.  
       [0036] Preferably, one of the radicals R 2  and R 3  is hydrogen, methyl or ethyl, preferably hydrogen, and the other of the radicals R 2  and R 3  is hydrogen, formyl, methyl, ethyl or [(C 1 -C 4 )alkyl]carbonyl or [(C 1 -C 4 )haloalkyl]carbonyl, preferably hydrogen, formyl, acetyl, propionyl, trifluoroacetyl and trichloroacetyl, in particular hydrogen.  
       [0037] Of interest are, for example, compounds of the formula (I) according to the invention or salts thereof in which  
       [0038] R 4  is hydrogen, (C 1 -C 6 )alkyl, (C 2 -C 6 )alkenyl, (C 2 -C 6 )alkynyl or (C 3 -C 6 )cycloalkyl, where each of the 4 last-mentioned radicals is unsubstituted or substituted by one or more radicals selected from the group consisting of halogen and, in the case of cyclic radicals, also (C 1 -C 6 )alkyl and (C 1 -C 6 )haloalkyl.  
       [0039] R 4  is preferably hydrogen, (CG-C 4 )alkyl, (C 2 -C 4 )alkenyl, (C 2 -C 4 )alkynyl or (C 3 -C 6 )cycloalkyl, in particular H, (C 1 -C 4 )alkyl or (C 3 -C 6 )cycloalkyl, where each of the 8 last-mentioned carbon-containing radicals is unsubstituted or substituted by one or more radicals selected from the group consisting of halogen and, in the case of cyclic radicals, also (C 1 -C 4 )alkyl and (C 1 -C 4 )haloalkyl.  
       [0040] R 4  is in particular hydrogen, methyl, ethyl, isopropyl, n-propyl, 1-fluoro-n-propyl, 1-fluoro-1-methylethyl, 1-fluoroethyl, trifluoromethyl, cyclopropyl, 1-fluorocyclopropyl, 2,2-difluorocyclopropyl, 2,2-dimethylcyclopropyl, cyclobutyl, especially hydrogen, methyl, ethyl, isopropyl, cyclopropyl or cyclobutyl.  
       [0041] Of interest are, for example, compounds of the formula (I) according to the invention or salts thereof in which  
       [0042] each of the radicals R 5 , R 6 , R 7 , R 8  and R 9  independently of the others is hydrogen, halogen, nitro, cyano, thiocyanato, (C 1 -C 4 )alkyl, (C 2 -C 6 )alkenyl, (C 2 -C 6 )alkynyl, (C 3 -C 6 )cycloalkyl, (C 5 -C 6 )cycloalkenyl, phenyl or heterocyclyl, where each of the 7 last-mentioned radicals is unsubstituted or substituted, preferably unsubstituted or substituted by one or more radicals selected from the group consisting-of halogen, cyano and hydroxyl and in the case of cyclic radicals, also (C 1 -C 4 )alkyl and (C 1 -C 4 )haloalkyl, and at least one of the radicals, preferably at least two radicals, in particular 2 or 3 radicals, especially 2 radicals, of the group consisting of R 5 , R 6 , R 7 , R 8  and R 9  are different from hydrogen and where at least one of the radicals R 5 , R 6 , R 7 , R 8  and R 9  is selected from the group consisting of the radicals (C 2 -C 6 )alkenyl, (C 1 -C 6 )alkynyl, (C 3 -C 6 )cycloalkyl and (C 5 -C 6 )cycloalkenyl, where each of the 4 last-mentioned radicals is unsubstituted or substituted, preferably unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, cyano and hydroxyl and, in the case of cyclic radicals, also (C 1 -C 4 )alkyl and (C 1 -C 4 )haloalkyl.  
       [0043] Preferably, each of the radicals from the group consisting of the radicals R 5 , R 6 , R 7 , R 8  and R 9  which is different from hydrogen is, independently of the others, halogen, nitro, cyano, (C 1 -C 4 )alkyl, (C 2 -C 6 )alkenyl, (C 2 -C 6 )alkynyl or (C 3 -C 6 )cycloalkyl, where each of the 4 last-mentioned radicals is unsubstituted or substituted, preferably unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, cyano and hydroxyl and, in the case of cyclic radicals, also (C 1 -C 4 )alkyl and (C 1 -C 4 )haloalkyl, preferably unsubstituted or substituted by halogen, where at least one of the radicals different from hydrogen is (C 2 -C 6 )alkenyl, (C 2 -C 6 )alkynyl or (C 3 -C 6 )cycloalkyl, where each of the 3 last-mentioned radicals is unsubstituted or substituted, preferably unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, cyano and hydroxyl and, in the case of cyclic radicals, also (C 1 -C 4 )alkyl and (C 1 -C 4 )haloalkyl. Particularly preferably, each of the radicals different from hydrogen is a radical selected from the group consisting of halogen, such as fluorine, chlorine or bromine, nitro, cyano, methyl, ethyl, n-propyl, isopropyl, 1-fluoroethyl, 1-fluoropropyl, 1-fluoro-1-methylethyl, trifluoromethyl, trichloromethyl, 1-hydroxyethyl, vinyl, allyl, 1-propen-1-yl, 1,2,2-trifluorethen-1-yl, 1,2,3,3,3-pentafluoroprop-1-en-1-yl, 1,1,2,3,3-pentafluoroprop-2-en-1-yl, 1,2,3,4,5,5,5-heptafluorobut-2-en-1-yl, 1,2-propadienyl, ethynyl, 1-propynyl, 2-propyn-1-yl (propargyl), 1-butynyl, 2-butyn-1-yl, 3-butyn-1-yl, 3-fluorobut-1-yn-1-yl, 3-hydroxybut-1-yn-1-yl, 1-pentynyl, 2-pentyn-1-yl, 3-pentyn-1-yl, 4-pentyn-1-yl, 1-hexynyl, 2-hexyn-1-yl, 3-hexyn-1-yl, 4-hexyn-1-yl, 5-hexyn-1-yl, 5-fluorohex-1-yn-1-yl, 5-hydroxyhex-1-yn-1-yl, cyclopropyl, 2,2-difluorocyclopropyl, 1 ,2,2,3,3-pentafluorocyclopropyl, cyclobutyl, cyclopentyl or cyclohexyl, where at least one radical of these is selected from the group consisting of the radicals (C 2 -C 6 )alkenyl, (C 2 -C 6 )alkynyl and (C 3 -C 6 )cycloalkyl, preferably (C 2 -C 4 )alkenyl, (C 2 -C 4 )alkynyl and (C 3 -C 4 )cycloalkyl.  
       [0044] Of particular interest are also compounds of the formula (I) according to the invention and salts thereof in which individual radicals have one of the meanings mentioned in the examples.  
       [0045] Of particular interest are also compounds of the formula (I) according to the invention and salts thereof in which in the molecule in question a plurality of the above-mentioned preferred meanings of the radicals R 1  to R 9  are combined.  
       [0046] The present invention also provides processes for preparing compounds of the formula (I) or salts thereof, which comprise  
       [0047] (a) reacting a compound of the formula (II),  
       R 1 —Fu  (II)  
       [0048] in which Fu is a functional group selected from the group consisting of carboxylic ester, carboxylic orthoester, carbonyl chloride, carboxamide, carboxylic anhydride and trichloromethyl, with a biguanidide of the formula (IlI) or an acid addition salt thereof  
                 
 
       [0049] or  
       [0050] (b) reacting a compound of the formula (IV),  
                 
 
       [0051] in which Z 1  is an exchangeable radical or a leaving group, for example chlorine, trichloromethyl, (C 1 -C 4 )alkylsulfonyl and unsubstituted or substituted phenyl-(C 1 -C 4 )alkylsulfonyl or (C 1 -C 4 )alkylphenylsulfonyl, with a suitable amine of the formula (V) or an acid addition salt thereof  
                 
 
       [0052] or  
       [0053] (c) reacting a compound of the formula (I′),  
                 
 
       [0054] in which  
       [0055] X is located in the position on the phenyl ring in which in formula (I) there is a radical selected from the group of the radicals R 5  to R 9  representing an alkenyl, alkynyl, cycloalkyl or cycloalkenyl radical, and is a radical selected from the group consisting of halogen, such as chlorine, bromine or iodine, trifluoromethanesulfonate radical, (F 3 C-SO 2 —O—) boronic acid group, boronic ester group and an organometalllic radical, such as, for example, an organometallic radical containing tin  
       [0056] n is the number of these radicals X and  
       [0057] (R) m  are, based on the radicals (X)n the remaining radicals (m=5 minus n) from the group of the radicals R 5  to R 9  which, with respect to the positions and the radicals, are as defined in formula (I)  
       [0058] with (unsaturated or cyclic) compounds of the formula R—Y, where R has the meaning of the radical in the position X on the phenyl ring defined in formula (I) and  
       [0059] c1) Y=hydrogen, except when R is a cycloalkyl radical, or boronic acid group, boronic ester group or an organometallic radical, such as, for example, an organometallic radical containing tin or zinc as metal atom, in each case in the case where X is a halogen atom or a trifluoromethanesulfonate radical,  
       [0060] c2) Y=hydrogen, except when R is a cycloalkyl radical, or halogen or a trifluoromethanesulfonate radical, in each case in the case where X is an organometallic radical, such as, for example, an organometallic radical containing tin or zinc as metal atom, or  
       [0061] c3) Y=halogen or a trifluoromethanesulfonate radical, in each case in the case where X is a boronic acid group or boronic ester group  
       [0062] under the conditions of the Heck reaction, Suzuki reaction, Stille reaction or Sonogashira reaction or analogous conditions to give compounds of the formula (I) or salts thereof,  
       [0063] where in the formulae (II), (Ill), (IV), (V) and (I′) the radicals R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8  and R 9  are as defined in formula (I).  
       [0064] According to variant (a), the compounds of the formulae (II) and (III) are preferably reacted base-catalyzed in an inert organic solvent, such as, for example, tetrahydrofuran (THF), dioxane, acetonitrile, dimethylformamide (DMF), methanol and ethanol, at temperatures between −10° C. and the boiling point of the solvent, preferably at from 20° C. to 60° C.; if acid addition salts of the formula (Ill) are used, these are generally liberated in situ with the aid of a base. Suitable bases or basic catalysts are alkali metal hydroxides, alkali metal hydrides, alkali metal carbonates, alkali metal alkoxides, alkaline earth metal hydroxides, alkaline earth metal hydrides, alkaline earth metal carbonates or organic bases, such as triethylamine or 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU). The base in question is employed, for example, in the range from 0.1 to 3 molar equivalents, based on the compound of the formula (III). Based on the compound of the formula (III), the compound of the formula (II) can be employed, for example, in equimolar amounts or in an excess of up to 2 molar equivalents. In principle, the corresponding processes are known from the literature (compare: Comprehensive Heterocyclic Chemistry, A. R. Katritzky, C. W. Rees, Pergamon Press, Oxford, New York, 1984, Vol.3; Part 2B; ISBN 0-08-030703-5, p.290).  
       [0065] According to variant (b), the compounds of the formulae (IV) and (V) are preferably reacted base-catalyzed in an inert organic solvent, such as, for example, THF, dioxane, acetonitrile, DMF, methanol and ethanol, at temperatures between −10° C. and the boiling point of the solvent or solvent mixture in question, preferably at from 20° C. to 160° C., in particular from 30° C. to 80° C., where the compound (V), if it is employed as acid addition salt, is, if appropriate, liberated in situ using a base. Suitable bases or basic catalysts are alkali metal hydroxides, alkali metal hydrides, alkali metal carbonates, alkali metal alkoxides, alkaline earth metal hydroxides, alkaline earth metal hydrides, alkaline earth metal carbonates or organic bases such as triethylamine or 1 ,8-diazabicyclo[5.4.0]undec-7-ene (DBU). The base in question is generally employed in the range from 1 to 3 molar equivalents, based on the compound of the formula (IV), and the compound of the formula (IV) can be employed, for example, in equimolar amounts or in an excess of up to 2 molar equivalents, based on the compound of the formula (V). In principle, the corresponding processes are known from the literature (cf. Comprehensive Heterocyclic Chemistry, A. R. Katritzky, C. W. Rees, Pergamon Press, Oxford, New York, 1984, Vol.3; Part 2B; ISBN 0-08-030703-5, p. 482).  
       [0066] The reaction of the compounds of the formula (I′) according to variant (c) is carried out, for example, using unsaturated compounds of the formula R—Y (Y=H) from the group of the alkenes or alkines or using compounds R—Y (Y=boronic acid (ester)) from the group of the alkenylboronic acids and cycloalkylboronic acids or esters thereof in the presence of organopalladium compounds under the conditions known for the C-alkylation of aromatic compounds by the Heck reaction, Suzuki reaction, Stille reaction or Sonogashira reaction or analogous conditions.  
       [0067] Variants result by using other catalysts known to be suitable for the type of reaction.  
       [0068] Alternatively, under appropriate conditions, it is also possible to use compounds R—Y in which Y is an organometallic radical, such as, for example, an organometallic radical containing tin or zinc as metal atom, in the case where X is a halogen atom or a trifuoromethanesulfonate radical.  
       [0069] Alternatively, under appropriate conditions, it is also possible to use compounds R—Y in which Y is halogen or a trifluoromethanesulfonate radical, where X is in each case an organometallic radical such as, for example, an organometallic radical containing tin or zinc as metal ion.  
       [0070] Alternatively, under appropriate conditions, it is also possible to use compounds R—Y in which Y is halogen or a trifluoromethanesulfonate radical, where X is in each case a boronic acid group or a boronic acid ester group.  
       [0071] Cycloalkylaromatic compounds can be generated by a large number of methods. Thus, cyclopropylaromatic compounds can be synthesized, for example, by cyclopropanation of the corresponding styrene derivatives (review on cyclopropanation: T. Aratani, Compr. Asymmetric Catal. l-1113 (1999) 1451-1460) or by coupling cyclopropylboronic acids with aryltrifluoromethanesulfonates (M. -Z. Deng, Synthesis 2000, 8, 1095-1100) or with aryl bromides (M. -Z. Deng, Angew. Chemie, 1998, 110, 20,3061-3063).  
       [0072] Olefins can be coupled with aromatic compounds for example by a Suzuki reaction (G. C. Fu, J. Am. Chem. Soc., 2000,122,4020-4028).  
       [0073] Alkynylaromatic compounds can be generated, for example, by Sonogashira coupling of an alkyn with an aryl halide or an aryltrifluoromethanesulfonate (L. Buchwald and G. C. Fu, Organic Letters, 2000, Vol. 2, No.12, 1729-1731 or N. Krause, J. Org. Chem. 1998, 63, 8551-8553).  
       [0074] (Kreuz) couplings with organometallic groups and/or catalysis by transition metals are described in:  
       [0075] Metal-catalyzed Cross-coupling Reactions, Ed.: F. Diederich; P.J. Stang.—Wiley-VCH, Weinheim 1998;  
       [0076] Transition Metals for Organic Synthesis, Vol.1. Ed.: M. Beller; C. Bolm, Wiley-VCH, Weinheim 1998;  
       [0077] Tsuji, J.: Palladium Reagents and Catalysts, John Wiley &amp; Sons, Chichester 1995; Heck, R. F.: Palladium Reagents in Organic Synthesis.—Academic Press, New York 1985.  
       [0078] Further details about the Stille reaction (i.e. where one of the two coupling partners is an organotin compound) are described in:  
       [0079] Farina, V.; Krishnamurthy, V.; Scott, W. J., Org. React. 50 (1997),1-652;  
       [0080] Farina, V.; Krishnamurthy, V.; Scott, W.J.: The Stille Reaction; John Wiley &amp; Sons, New York 1998; Stille, J. K., Angew. Chem. 98 (1986) 504-519.  
       [0081] The starting materials of the formulae (II), (III), (IV), (V) and (I′) are either commercially available, or they can be prepared by or analogously to processes known from the literature. The compounds can also be prepared, for example, by one of the processes described below.  
       [0082] The compound of the formula (IV), or a direct precursor thereof, can be prepared, for example, as follows:  
       [0083] 1. Reaction of a compound of the formula (II) with an amidinothiourea derivative of the formula (VI),  
                 
 
       [0084] in which Z 2  is (C 1 -C 4 )alkyl or phenyl-(C 1 -C 4 )alkyl and A=NR 2 R 3  as defined in formula (I) gives compounds of the formula (IV) in which Z 1 =—SZ 2 .  
       [0085] 2. Reaction of an amidine of the formula (VII) or an acid addition salt thereof  
       H 2 N—CR 1 =NH  (VII)  
       [0086] in which R 1  is as defined in formula (I)  
       [0087] with an N-cyanodithioiminocarbonate of the formula (VIII)  
       NC—N=C(S—Z 3 ) 2   (VIII)  
       [0088] in which Z 3  is (C 1 -C 4 )alkyl or phenyl-(C 1 -C 4 )alkyl gives compounds of the formula (IV) in which Z 1 =—S—Z 3 .  
       [0089] 3. Reaction of an alkali metal dicyanamide with a carboxylic acid derivative of the formula (II) mentioned gives compounds of the formula (IV) in which Z 1 =NH 2 .  
       [0090] 4. Reaction of trichloroacetonitrile with a nitrile of the formula (IX)  
       R 1 —CN  (IX)  
       [0091] in which R 1  is as defined in formula (I) initially gives compounds of the formula (X)  
                 
 
       [0092] in which Z 1  and Z 4  are each CCl 3  which, by subsequent reaction with compounds of the formula H—NR 2 R 3  (R 2  and R 3  are as defined in formula (I)), gives compounds of the formula (IV) in which Z′=CCl 3 .  
       [0093] The substituted phenylalkylamines of the formula (V) required as starting materials are known and/or can be prepared by processes known per se. For example, the corresponding aromatic ketone can be converted directly into the amine by reductive amination, for example by reaction with sodium cyanoborohydride and ammonium acetate or with ammonium formate or with a mixture of ammonium formate and formic acid or with a mixture of ammonium formate, formamide and formic acid, in each case with subsequent cleavage of the amide, or the ketone is converted into an (cf. JP 11035536; JP 11043470; J. Am. Chem. Soc. 1983, 105,1578; Synthesis 1980, 695).  
       [0094] The reaction of the carboxylic acid derivatives of the formula (II) with the amidinothiourea derivatives of the formula (VI) is preferably carried out base-catalyzed in an organic solvent, such as, for example, acetone, THF, dioxane, acetonitrile, DMF, methanol, ethanol, at temperatures from −10° C. to the boiling point of the solvent, preferably at from 0° C. to 20° C. However, the reaction can also be carried out in water or in aqueous solvent mixtures with one or more of the abovementioned organic solvents. If (VI) is employed as acid addition salt, it can, if appropriate, be liberated in situ using a base. Suitable bases or basic catalysts are alkali metal hydroxides, alkali metal hydrides, alkali metal carbonates, alkali metal alkoxides, alkaline earth metal hydroxides, alkaline earth metal hydrides, alkaline earth metal carbonates or organic bases, such as triethylamine or 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU). The base in question is, for example, employed in the range from 1 to 3 molar equivalents, based on the compound of the formula (VI). Compounds of the formula (II) and (VI) can be employed, for example, in equimolar amounts, or with an excess of up to 2 molar equivalents of the. compound of the formula (II). In principle, the corresponding processes are known from the literature (compare: H. Eilingsfeld, H. Scheuermann, Chem. Ber.; 1967, 100, 1874), the corresponding intermediates of the formula (IV) are novel.  
       [0095] The reaction of the amidines of the formula (VII) with the N-cyanodithioimino-carbonates of the formula (ViII) is preferably carried out base-catalyzed in an inert organic solvent, such as, for example, acetonitrile, DMF, dimethylacetamide (DMA), N-methylpyrrolidone (NMP), methanol and ethanol, at temperatures from −10° C. to the boiling point of the solvent, preferably at from 20° C. to 80° C. If (VII) is employed as acid addition salt, it can, if appropriate, be liberated in situ using a base. Suitable bases or basic catalysts are alkali metal hydroxides, alkali metal hydrides, alkali metal carbonates, alkali metal alkoxides, alkaline earth metal. hydroxides, alkaline earth metal hydrides, alkaline earth metal carbonates or organic bases, such as triethylamine or 1 ,8-diazabicyclo[5.4.0]undec-7-ene (DBU). The base in question is employed, for example, in the range from 1 to 3 molar equivalents, based on the compound of the formula (Vill), and compounds of the formulae (VII) and (VIII) can generally be employed in equimolar amounts or with an excess of two molar equivalents of the compound of the formula (II). In principle, the corresponding processes are known from the literature (compare: T. A. Riley, W. J. Henney, N. K. Dailey, B. E. Wilson, R. K. Robins; J. Heterocyclic Chem.; 1986, 23 (6), 1706-1714), the corresponding intermediates of the formula (IV) are novel.  
       [0096] Intermediates of the formula (X) where Z′=chlorine can be prepared by reacting alkali metal dicyanamide with a carboxylic acid derivative of the formula (II), Fu then preferably being the functional group carbonyl chloride or carboxamide. The reaction of the reaction components is carried out, for example, acid-catalyzed in an inert organic solvent, such as, for example, toluene, chlorobenzene, chlorinated hydrocarbons, at temperatures between −10° C. and the boiling point of the solvent, preferably at from 20° C. to 80° C., where the intermediates formed can be chlorinated in situ using a suitable chlorinating agent, such as, for example, phosphorus oxychloride. Suitable acids are, for example, hydrohalic acids, such as HCl, or else Lewis acids, such as, for example, AICl 3  or BF 3  (compare U.S. Pat. No. 5,095,113, DuPont).  
       [0097] Intermediates of the formula (X) where Z 1 , Z 4 =trihalomethyl can be prepared by reacting the corresponding trihaloacetonitriles with a carbonitrile of the formula (IX). The reaction of the reaction components is carried out, for example, acid-catalyzed in an inert organic solvent, such as, for example, toluene, chlorobenzene, chlorinated hydrocarbons, at temperatures between −40° C. and the boiling point of the solvent, preferably at from −10° C. to 30° C. Suitable acids are, for examnple, hydrohalic acids, such as HCl, or else Lewis acids, such as, for example, AlCl 3  or BF 3  (cf. EP-A-130939, Ciba Geigy).  
       [0098] Intermediates of the formula (IV), in which Z 1 =(C 1 -C 4 )alkylmercapto or unsubstituted phenyl-(C 1 -C 4 )alkylmercapto, can be converted in an inert organic solvent, such as, for example toluene, chlorobenzene, chlorinated hydrocarbons or others, at temperatures between −40° C. and the boiling point of the solvent, preferably at from 20° C. to 80° C., with a suitable chlorinating agent, such as, for example elemental chlorine or phosporus oxychloride, into more reactive chlorotriazines of the formula (IV), in which Z 1 =Cl (cf. J. K. Chakrabarti, D. E. Tupper; Tetrahedron 1975, 31(16), 1879-1882).  
       [0099] Intermediates of the formula (IV), in which Z 1 =(C 1 -C 4 )alkylmercapto or unsubstituted or substituted phenyl-(C 1 -C 4 )alkylmercapto or (C 1 -C 4 )alkylphenylthio can be oxidized in a-suitable solvent, such as, for example, chlorinated hydrocarbons, acetic acid, water, alcohols, acetone or mixtures thereof at temperatures between 0° C. and the boiling point of the solvent, preferably at from 20° C. to 80° C., with a suitable oxidizing agent, such as, for example, m-chloroperbenzoic acid, hydrogen peroxide, potassium peroxomonosulfate (compare: T. A. Riley, W. J. Henney, N. K. Dailey, B. E. Wilson, R. K. Robins; J. Heterocyclic Chem.; 1986, 23 (6),1706-1714).  
       [0100] The compounds of the formula (III) can be prepared from compounds of the formula (V) and/or acid adducts thereof by reaction with cyanoguanide (“dicyandiamide”) of the formula (XI),  
                 
 
       [0101] if appropriate in the presence of a reaction auxiliary, such as, for example, hydrochloride, and if appropriate in the presence of a diluent, such as, for example, n-decane or 1,2-dichlorobenzene, at temperatures of, for example, from 100° C. to 200° C. (cf. EP-A-492615, Preparation Examples).  
       [0102] The amines of the formula (V) or corresponding precursors for the compounds of the formula (I′) can be synthesized from simple structural building blocks as precursors following known methods. The amino group can be obtained, for example, from corresponding ketones by reductive amination (cf. the literature mentioned above, e.g. on page 1, on aminotriazine herbicides).  
       [0103] Some optically active aminotriazines of the formula (I) and salts thereof (hereinbelow together in short also referred to as “compounds (I) according to the invention” or “compounds (I)”) can be prepared analogously to optically active aminotriazines which are already known from the literature mentioned above; cf. specifically optically active compounds from DE-A-19810349. The international application No. PCT/EPOO/1 1861 (WO-A-01/44208) also proposes optically active compounds (I).  
       [0104] The compounds (I) can be prepared analogously to the methods described therein or analogously to known methods, as described in the patent publications also mentioned further above and in the literature cited therein.  
       [0105] With respect to the preferred compounds, their preparation and general conditions for their use and in particular with respect to the specific compounds given as examples, reference is made to the descriptions of the publications mentioned, and in this respect, these descriptions are incorporated into the present invention.  
       [0106] Optically active compounds (I) can be obtained, for example, from optically active biguanides by reaction of optically active amines and cyanoguanidine of the formula H 2 N—C(═NH)—NH—CN (see, for example, EP-A-492615). In general, the reaction can be carried out efficiently under acid catalysis and in the presence of an organic solvent, such as an optionally halogenated hydrocarbon. Suitable catalysts are, for example, mineral acids, such as hydrogen chloride; suitable solvents are, for example, dichloromethane or n-decane. The reaction is carried out, for example in the range from 0 to 200° C., preferably from 90 to 180° C.  
       [0107] The optically active amines required for the above reaction and for preparation variant b) are known or can be prepared by processes known per se (cf. Tetrahedron Lett. 29 (1988) 223-224, Tetrahedron Left. 36 (1995) 3917-3920; Tetrahedron, Asymmetry 5 (1994) 817-820; EP-A-320898, EP-A-443606, DE-A-3426919, DE-A-400610).  
       [0108] Optically active compounds can also be obtained by customary methods for optical resolutions (cf. textbooks of stereochemistry), for example following processes for separating mixtures into diastereomers, for example physical processes, such as crystallization, chromatographic processes, in particular column chromatography and high pressure liquid chromatography, distillation, if appropriate under reduced pressure, extraction and other processes, it is possible to separate the remaining mixtures of enantiomers, generally by chromatographic separation on chiral solid phases. Suitable for preparative amounts or on an industrial scale are processes such as the crystallization of diastereomeric salts which can be obtained from the compounds (I) using optically active acids and, if appropriate, provided that acidic groups are present, using optically active bases.  
       [0109] Optically active acids which are suitable for optical resolution by crystallization of diastereomeric salts are, for example, camphorsulfonic acid, camphoric acid, bromocamphorsulfonic acid, quinic acid, tartaric acid, dibenzoyltartaric acid and other analogous acids; suitable optically active bases are, for example, quinine, cinchonine, quinidine, brucine, 1-phenylethylamine and other analogous bases.  
       [0110] The crystallizations are then in most cases carried out in aqueous or aqueous-organic solvents, where the diastereomer which is less soluble precipitates first, if appropriate after seeding. One enantiomer of the compound of the formula (I) is then liberated from the precipitated salt, or the other is liberated from the crystals, by acidification or using base.  
       [0111] The following acids are suitable for preparing the acid addition salts of the compounds of the formula (I): hydrohalic acids, such as hydrochloric acid or hydrobromic acid, furthermore phosphoric acid, nitric acid, sulfuric acid, mono- or bifunctional carboxylic acids and hydroxycarboxylic acids, such as acetic acid, maleic acid, succinic acid, fumaric acid, tartaric acid, citric acid, salicylic acid, sorbic acid or lactic acid, and also sulfonic acids, such as p-toluenesulfonic acid and 1,5-naphthalenedisulfonic acid. The acid addition compounds of the formula (I) can be obtained in a simple manner by the customary methods for forming salts, for example by dissolving a compound of the formula (I) in a suitable organic solvent, such as, for example, methanol, acetone, methylene chloride or benzine, and adding the acid at temperatures from 0 to 100° C., and they can be isolated in a known manner, for example by filtration, and, if appropriate, purified by washing with an inert organic solvent.  
       [0112] The base addition salts of the compounds of the formula (I) are preferably prepared in inert polar solvents, such as, for example, water, methanol or acetone, at temperatures from 0 to 100° C. Examples of bases which are,suitable for the preparation of the salts according to the invention are alkali metal carbonates, such as potassium carbonate, alkali metal hydroxides and alkaline earth metal hydroxides, for example NaOH or KOH, alkali metal hydrides and alkaline earth metal hydrides, for example NaH, alkali metal alkoxides and alkaline earth metal alkoxides, for example sodium methoxide or potassium tert-butoxide, or ammonia or ethanolamine.  
       [0113] Solvents referred to as “inert solvents” in the above process variants are to be understood as meaning in each case solvents which are inert under the reaction conditions in question, but which need not be inert under any reaction conditions.  
       [0114] A collection of compounds (I) which can be synthesized by the above mentioned process may also be prepared in a parallel manner where the process may be carried out manually, in a partially automated manner or in a fully automated manner. In this case, it is possible, for example, to automate the procedure of the reaction, the work-up or the purification of the products or of the intermediates. In total, this is to be understood as meaning a procedure as is described, for example, by S. H. DeWitt in “Annual Reports in Combinatorial Chemistry and Molecular Diversity: Automated Synthesis”, Volume 1, Verlag Escom, 1997, pages 69 to 77.  
       [0115] A number of commercially available apparatuses as they are offered by, for example, Stem Corporation, Woodrolfe Road, Tollesbury, Essex, CM9 8SE, England, or H+P Labortechnik GmbH, Bruckmannring 28, 85764 Oberschleiβheim, Germany may be used for the parallel procedure of the reaction and work-up. For the parallel purification of compounds (I), or of intermediates obtained during the preparation, use may be made, inter alia, of chromatography apparatuses, for example those from ISCO, Inc., 4700 Superior Street, Lincoln, Nebr. 68504, USA. The apparatuses mentioned lead to a modular procedure in which the individual process steps are automated, but manual operations have to be performed between the process steps. This can be avoided by employing semi-integrated or fully integrated automation systems where the automation modules in question are operated by, for example, robots. Such automation systems can be obtained, for example, from Zymark Corporation, Zymark Center, Hopkinton, Mass. 01748, USA.  
       [0116] In addition to what has been described here, compounds (I) may be prepared in part or fully by solid-phase-supported methods. For this purpose, individual intermediate steps or all intermediate steps of the synthesis or of a synthesis adapted to suit the procedure in question are bound to a synthetic resin. Solid-phase-supported synthesis methods are described extensively in the specialist literature, for example Barry A. Bunin in “The Combinatorial Index”, Verlag Academic Press, 1998. The use of solid-phase-supported synthesis methods permits a series of protocols which are known from the literature and which, in turn, can be performed manually or in an automated manner. For example, the “tea-bag method” (Houghten, U.S. Pat. No. 4,631,211; Houghten et al., Proc. Natl. Acad. Sci, 1985, 82, 5131-5135), in which products from IRORI, 11149 North Torrey Pines Road, La Joila, Calif. 92037, USA, are employed, may be partially automated. The automation of solid-phase-supported parallel synthesis is performed successfully, for example, by apparatuses from Argonaut Technologies, Inc., 887 Industrial Road, San Carlos, Calif. 94070, USA or MultiSynTech GmbH, Wullener Feld 4, 58454 Witten, Germany.  
       [0117] The preparation methods described here give compounds (I) in the form of collections of substances known as libraries. The present invention also relates to libraries of the compounds (I) which contain at least two compounds (I) and their intermediates.  
       [0118] The compounds of the formula (I) according to the invention and their salts, hereinbelow together referred to as compounds of the formula (I) (according to the invention), have excellent herbicidal activity against a broad spectrum of economically important monocotyledonous and dicotyledonous harmful plants. The active compounds also act efficiently on perennial weeds which produce shoots from rhizomes, root stocks or other perennial organs and which are difficult to control. In this context, it is immaterial whether the substances are applied pre-sowing, pre-emergence or post-emergence.  
       [0119] Specifically, examples may be mentioned of some representatives of the monocotyledonous and dicotyledonous weed flora which can be controlled by the compounds according to the invention, without these being a restriction to certain species.  
       [0120] Examples of weed species on which the active compounds act efficiently are, from amongst the monocotyledons, Avena spp., Alopecurus spp., Brachiaria spp., Digitaria spp., Lolium spp., Echinochloa spp., Panicum spp., Phalaris spp., Poa spp., Setaria spp., and also Cyperus species from the annual sector, and from amongst the perennial species Agropyron, Cynodon, Imperata and Sorghum, and also perennial Cyperus species.  
       [0121] In the case of the dicotyledonous weed species, the spectrum of action extends to species such as, for example, Abutilon spp., Amaranthus spp., Chenopodium spp., Chrysanthemum spp., Galium spp., lpomoea spp., Kochia spp., Lamium spp., Matricaria spp., Pharbitis spp., Polygonum spp., Sida spp., Sinapis spp., Solanum spp., Stellaria spp., Veronica spp,. Viola spp., and Xanthium spp., from amongst the annuals, and Convolvulus, Cirsium, Rumex and Artemisia in the case of the perennial weeds.  
       [0122] The active ingredients according to the invention also effect outstanding control of harmful plants which occur under the specific conditions of rice growing such as, for example, Sagittaria, Alisma, Eleocharis, Scirpus and Cyperus.  
       [0123] If the compounds according to the invention are applied to the soil su rface prior to germination, then the weed seedlings are either prevented completely from emerging, or the weeds grow until they have reached the cotyledon stage but then their growth stops, and, eventually, after three to four weeks have elapsed, they die completely.  
       [0124] If the active compounds are applied post-emergence to the green parts of the plants, growth also stops drastically a very short time after the treatment and the weed plants remain at the developmental stage of the point in time of application, or they die completely after a certain time, so that in this manner competition by the weeds, which is harmful to the crop plants, is eliminated at a very early point in time and in a sustained manner.  
       [0125] Although the compounds according to the invention have an excellent herbicidal activity against monocotyledonous and dicotyledonous weeds, crop plants of economically important crops, for example wheat, barley, rye, rice, corn, sugar beet, cotton and soybean, are not damaged at all, or only to a negligible extent. For these reasons, the present compounds are highly suitable for selectively controlling undesired plant growth in plantings of agriculturally useful plants.  
       [0126] In addition, the substances according to the invention have outstanding growth-regulating properties in crop plants. They engage in the plant metabolism in a regulating manner and can thus be employed for the targeted control of plant constituents and for facilitating harvesting, such as for example by provoking desiccation and stunted growth. Furthermore, they are also suitable for generally regulating and inhibiting undesirable vegetative growth, without destroying the plants in the process. Inhibition of vegetative growth plays an important role in many monocotyledonous and dicotyledonous crops because lodging can be reduced hereby, or prevented completely.  
       [0127] Owing to their herbicidal and plant growth-regulatory properties, the active compounds can also be employed for controlling harmful plants in crops of known or still to be developed genetically engineered plants. The transgenic plants generally have particularly advantageous properties, for example resistance to certain pesticides, in particular certain herbicides, resistance to plant diseases or causative organisms of plant diseases, such as certain insects or microorganisms such as fungi, bacteria or viruses. Other particular properties relate, for example, to the quantity, quality, storage-stability, composition and to specific ingredients of the harvested product. Thus, transgenic plants having an increased starch content or a modified quality of the starch or those having a different fatty acid composition of the harvested product are known.  
       [0128] The use of the compounds of the formula (I) according to the invention or their salts in economically important transgenic crops of useful and ornamental plants, for example of cereal, such as wheat, barley, rye, oats, millet, rice, maniok and corn, or else in crops of sugar beet, cotton, soybean, oilseed rape, potato, tomato, pea and other vegetable species is preferred.  
       [0129] The compounds of the formula (I) can preferably be used as herbicides in crops of useful plants which are resistant or which have been made resistant by genetic engineering toward the phytotoxic effects of the herbicides.  
       [0130] Conventional ways of preparing novel plants which have modified properties compared to known plants comprise, for example, traditional breeding methods and the generation of mutants. Alternatively, novel plants having modified properties can be generated with the aid of genetic engineering methods (see, for example, EP-A 0 221 044, EP-A 0 131 624). For example, there have been described several cases of  
       [0131] genetically engineered changes in crop plants in order to modify the starch synthesized in the plants (for example WO 92/11376, WO 92/14827 and WO 91/19806),  
       [0132] transgenic crop plants which are resistant to certain herbicides of the glufosinate type (cf., for example, EP-A 0 242 236, EP-A 0 242 246) or glyphosate type (WO 92/00377), or of the sulfonylurea type (EP-A 0 257 993, U.S. Pat. No. 5,013,659),  
       [0133] transgenic crop plants, for example cotton, having the ability to produce  Bacillus thuringiensis  toxins (Bt toxins) which impart resistance to certain pests to the plants (EP-A 0 142 924, EP-A 0 193 259),  
       [0134] transgenic crop plants having a modified fattv acid composition (WO 91/13972).  
       [0135] Numerous molecular biological techniques which allow the preparation of novel transgenic plants having modified properties are knowri in principle; see, for example, Sambrook et al., 1989, Molecular Cloning, A Laboratory Manual, 2nd ed. Cold Spring Harbor Laboratory Press, Cold Spring Harbor, N.Y.; or Winnacker “Gene und Klone” [Genes and Clones], VCH Weinheim, 2nd edition 1996, or Christou, “Trends in Plant Science” 1 (1996) 423-431).  
       [0136] In order to carry out such genetic engineering manipulations, it is possible to introduce nucleic acid molecules into plasmids which allow a mutagenesis or a change in the sequence to occur by recombination of DNA sequences. Using the abovementioned standard processes it is possible, for example, to exchange bases, to remove partial sequences or to add natural or synthetic sequences. To link the DNA fragments with each other, it is possible to attach adaptors or linkers to the fragments.  
       [0137] Plant cells having a reduced activity of a gene product can be prepared, for example, by expressing at least one appropriate antisense-RNA, a sense-RNA to achieve a cosuppression effect, or -by expressing at least one appropriately constructed ribozyme which specifically cleaves transcripts of the abovementioned gene product.  
       [0138] To this end, it is possible to employ both DNA molecules which comprise the entire coding sequence of a gene product including any flanking &#39;sequences that may be present, and DNA molecules which comprise only parts of the coding sequence, it being necessary for these parts to be long enough to cause an antisense effect in the cells. It is also possible to use DNA sequences which have a high degree of homology to the coding sequences of a gene product but which are not entirely identical.  
       [0139] When expressing nucleic acid molecules in plants, the synthesized protein can be localized in any desired compartment of the plant cell. However, to achieve localization in a certain compartment, it is, for example, possible to link the coding region with DNA sequences which ensure localization in a certain compartment. Such sequences are known to the person skilled in the art (see, for example, Braun et al., EMBO J. 11 (1992), 3219-3227; Wolter et al., Proc. Natl. Acad. Sci. USA 85 (1988), 846-850; Sonnewald et al., Plant J. 1 (1991), 95-106).  
       [0140] The transgenic plant cells can be regenerated to whole plants using known techniques. The transgenic plants can in principle be plants of any desired plant species, i.e. both monocotyledonous and dicotyledonous plants.  
       [0141] In this manner, it is possible to obtain transgenic plants which have modified properties by overexpression, suppression or inhibition of homologous (=natural) genes or gene sequences or by expression of heterologous (=foreign) genes or gene sequences.  
       [0142] The compounds (I) according to the invention can preferably be used in transgenic crops which are resistant to herbicides selected from the group consisting of the sulfonylureas, imidazolin-ones, glufosinate-ammoniurn or glyphosate-isopropylammonium and analogous active compounds.  
       [0143] When using the active compounds according to the invention in transgenic crops, in addition to the effects against harmful plants which can be observed in other crops, there are frequently effects which are specific for the application in the respective transgenic crop, for example a modified or specifically broadened spectrum of weeds which can be controlled, modified application rates which can be used for the application, preferably good combinability with the herbicides to which the transgenic crop is resistant, and an effect on the growth and the yield of the transgenic crop plants.  
       [0144] The invention therefore also provides for the use of the compounds (I) according to the invention as herbicides for controlling harmful plants in transgenic crop plants.  
       [0145] The compounds according to the invention can be applied in the customary formulations in the form of wettable powders, emulsifiable concentrates, sprayable solutions, dusts or granules. The invention therefore also provides herbicidal and plant growth-regulating compositions comprising compounds of the formula (I).  
       [0146] The compounds of the formula (I) can be formulated in various ways depending on the prevailing biological and/or chemicophysical parameters. Examples of suitable formulation options are: wettable powders (WP), water-soluble powders (SP), water-soluble concentrates, emulsifiable concentrates (EC), emulsions (EW), such as oil-in-water and water-in-oil emulsions, sprayable solutions, suspension concentrates (SC), oil- or water-based dispersions, oil-miscible solutions, capsule suspensions (CS), dusts (DP), seed-dressing compositions, granules for broadcasting and soil application, granules (GR) in the form of microgranules, spray granules, coating granules and adsorption granules, water-dispersible granules (WG), water-soluble granules (SG), ULV formulations, microcapsules and waxes.  
       [0147] These individual formulation types are known in principle and are described, for example, in Winnacker-Kuchler, “Chemische Technologie” [Chemical Technology], Volume 7, C. Hauser Verlag Munich, 4th edition 1986; Wade van Valkenburg, “Pesticide Formulations”, Marcel Dekker, N.Y., 1973; K. Martens, “Spray Drying” Handbook, 3rd ed. 1979, G. Goodwin Ltd. London.  
       [0148] The necessary formulation auxiliaries, such as inert materials, surfactants, solvents and other additives, are likewise known and are described, for example, in: Watkins, “Handbook of Insecticide Dust Diluents and Carriers”, 2nd ed., Darland Books, Caldwell N.J., H.v. Olphen, “Introduction to Clay Colloid Chemistry”; 2nd ed., J. Wiley &amp; Sons, N.Y.; C. Marsden, “Solvents Guide”; 2nd ed., Interscience, N.Y. 1963; McCutcheon&#39;s “Detergents and Emulsifiers Annual”, MC Publ. Corp., Ridgewood N.J., Sislev and Wood, “Encyclopedia of Surface Active Agents”, Chem. Publ. Co. Inc., N.Y. 1964; Schönfeldt, “Grenzflächenaktive Athylenoxidaddukte” [Surface-active ethylene oxide adducts], Wiss. Verlagsgesell., Stuttgart 1976; Winnacker-Küchler, “Chemische Technologie” [Chemical Technology], Volume 7, C. Hauser Verlag Munich, 4th edition 1986.  
       [0149] Based on these formulations it is also possible to produce combinations with other pesticidally active substances, for example insecticides, acaricides, herbicides and fungicides, and also with safeners, fertilizers and/or growth regulators, for example in the form of a ready-mix or tank mix.  
       [0150] Wettable powders are preparations which are uniformly dispersible in water and which, in addition to the active compound and as well as a diluent or inert substance, also contain surfactants of ionic and/or nonionic type (wetting agents, dispersants), for example polyethoxylated alkyl phenols, polyethoxylated fatty alcohols, polyethoxylated fatty amines, fatty alcohol polyglycol ethersulfates, alkanesulfonates, alkylbenzenesulfonates, sodium ligninsulfonate, sodium 2,2′-dinaphthylmethane-6,6′-disulfonate, sodium dibutyinaphthalenesulfonate or else sodium oleoylmethyltaurinate. To prepare the wettable powders, the herbicidally active compounds are finely ground, for example in customary apparatuses- such as hammer mills, fan mills and air-jet mills, and are mixed simultaneously or subsequently with the formulation auxiliaries.  
       [0151] Emulsifiable concentrates are prepared by dissolving the active compound in an organic solvent, for example butanol, cyclohexanone, dimethylformamide, xylene or else relatively high-boiling aromatics or hydrocarbons or mixtures of the organic solvents, with the addition of one or more surfactants of ionic and/or nonionic type (emulsifiers). Examples of emulsifiers which can be used are calcium alkylarylsulfonates, such as Ca dodecylbenzenesulfonate, or nonionic emulsifiers, such as fatty acid polyglycol esters, alkylaryl polyglycol ethers, fatty alcohol polyglycol ethers, propylene oxide-ethylene oxide condensation products, alkyl polyethers, sorbitan esters, for example sorbitan fatty acid esters or polyoxyethylene sorbitan esters, for example polyoxyethylene sorbitan fatty acid esters.  
       [0152] Dusts are obtained by grinding the active compound with finely divided solid substances, for example talc, natural clays, such as kaolin, bentonite and pyrophyllite, or diatomaceous earth.  
       [0153] Suspension concentrates can be water- or oil-based. They can be prepared, for example, by wet milling using commercially customary bead mills, with or without the addition of surfactants as already mentioned above, for example, in the case of the other formulation types.  
       [0154] Emulsions, for example oil-in-water emulsions (EW), can be prepared for example by means of stirrers, colloid mills and/or static mixers using aqueous organic solvents and, if desired, surfactants as already mentioned above, for example, in the case of the other formulation types.  
       [0155] Granules can be prepared either by spraying the active compound onto adsorptive, granulated inert material or by applying active-compound concentrates to the surface of carriers such as sand, kaolinites or granulated inert material, by means of adhesive binders, for example polyvinyl alcohol, sodium polyacrylate or else mineral oils. Suitable active compounds can also be granulated in the manner which is customary for the preparation of fertilizer granules, if desired as a mixture with fertilizers.  
       [0156] Water-dispersible granules are generally prepared by the customary processes, such as spray-drying, fluidized-bed granulation, disk granulation, mixing using high-speed mixers, and extrusion without solid inert material. For the preparation of disk, fluidized-bed, extruder and spray granules, see for example processes in “Spray-Drying Handbook” 3rd ed. 1979, G. Goodwin Ltd., London; J. E. Browning, “Agglomeration”, Chemical and Engineering 1967, pages 147 ff; “Perry&#39;s Chemical Engineer&#39;s Handbook”, 5th ed., McGraw-Hill, New York 1973, pp. 8-57.  
       [0157] For further details on the formulation of crop protection products, see for example G. C. Klingman, “Weed Control as a Science”, John Wiley and Sons., Inc., New York, 1961, pages 81-96 and J. D. Freyer, S. A. Evans, “Weed Control Handbook”, 5th ed., Blackwell Scientific Publications, Oxford, 1968, pages 101-103.  
       [0158] The agrochemical formulations generally contain from 0.1 to 99% by weight, in particular from 0.1 to 95% by weight, of active compound of the formula (I).  
       [0159] In wettable powders the concentration of active compound is, for example, from about 10 to 90% by weight, the remainder to 100% by weight consisting of customary formulation constituents. In emulsifiable concentrates the concentration of active compound can be from about 1 to 90%, preferably from 5 to 80%, by weight. Formulations in the form of dusts contain from 1 to 30% by weight of active compound, preferably most commonly from 5 to 20% by weight of active compound, while sprayable solutions contain from about 0.05 to 80%, preferably from 2 to 50%, by weight of active compound. In the case of water-dispersible granules, the content of active compound depends partly on whether the active compound is in liquid or solid form and on the granulation auxiliaries, fillers, etc. that are used. In water-dispersible granules the content of active compound, for example, is between 1 and 95% by weight, preferably between 10 and 80% by weight.  
       [0160] In addition, said formulations of active compound may comprise the tackifiers, wetting agents, dispersants, emulsifiers, penetrants, preservatives, antifreeze agents, solvents, fillers, carriers, colorants, antifoams, evaporation inhibitors and pH and viscosity regulators which are customary in each case.  
       [0161] The compounds of the formula (I) or their salts can be used as such or combined in the form of their preparations (formulations) with other pesticidally active compounds, such as, for example, insecticides, acaricides, nematicides, herbicides, fungicides, safeners, fertilizers and/or growth regulators, for example as finished formulations or tank mixes.  
       [0162] Suitable active compounds which can be combined with the active compounds according to the invention in mixed formulations or in a tank mix are, for example, known active compounds, whose effect is based on an inhibition of, for example, acetolactate synthase, acetyl-coenzyl-A carboxylase, PS I, PS II, HPPDO, phytoene desaturase, protoporphyrinogen oxidase, glutamine synthetase, cellulose biosynthesis, 5-enolpyruvylshikimate-3-phosphate synthetase. Such compounds, and also other compounds that can be used, with a mechanism of action that is, in some cases, unknown or different, are described, for example, in Weed Research 26, 441-445 (1986), or in “The Pesticide Manual”, 12h edition 2000, published by  
       [0163] The British Crop Protection Council (hereafter also abbreviated to “PM”), and in the literature cited therein. For example, the following active compounds may be mentioned as herbicides which are known from the literature.and which can be combined with the compounds of the formula (I) (note: the compounds are either referred to by the common name in accordance with the International Organization for Standardization (ISO) or by the chemical names, if appropriate together with a customary code number):  
       [0164] acetochlor; acifluorfen(-sodium); aclonifen; AKH 7088, i.e. [[[1-[5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrophenyl]-2-methoxyethylidene]amino]oxy]acetic acid and its methyl ester; alachlor; alloxydim(-sodium); ametryn; amicarbazone; amidochlor, amidosulfuron; amitrol; AMS, i.e. ammonium sulfamate; anilofos; asulam; atrazine; azafenidin; azimsulfuron (DPX-A8947); aziprotryn; barban; BAS 516 H, i.e. 5-fluoro-2-phenyl-4H-3, 1-benzoxazin4-one; beflubutamide; benazolin(-ethyl); benfluralin; benfuresate; bensulfuron(-methyl); bensulide; bentazone; benzobicyclone; benzofenap; benzofluor; benzoylprop(-ethyl); benzthiazuron; bialaphos; bifenox; bispyribac(-sodium); bromacil; bromobutide; bromofenoxim; bromoxynil; bromuron; buminafos; busoxinone; butachlor; butafenacil; butamifos; butenachlor; buthidazole; butralin; butroxydim; butylate; cafenstrole (CH-900); carbetamide; carfentrazone(-ethyl)(ICl A0051); caloxydim; CDM, i.e. 2-chloro-N,N-di-2-propenylacetamide; CDEC, i.e. 2-chloroallyl diethyldithiocarbamate; chlomethoxyfen; chloramben; chlorazifop-butyl; chlormesulon(ICl A0051 ); chlorbromuron; chlorbufam; chlorfenac; chlorflurecol-methyl; chloridazon; chlorimuron(-ethyl); chlornitrofen; chlorotoluron; chloroxuron; chlorpropham; chlorsulfuron; chlorthal-dimethyl; chlorthiamid; chlortoluron, cinidon(-ethyl and -methyl); cinmethylin; cinosulfuron; clefoxydim; clethodim; clodinafop and its ester derivatives (for example clodinafop-propargyl); clomazone; clomeprop; cloproxydim; clopyralid; clopyrasulfuron(-methyl); cloransulam(-methyl); cumyluron (JC 940); cyanazine; cycloate; cyclosulfamuron (AC 104); cycloxydim; cycluron; cyhalofop and its ester derivatives (for example cyhalofop-butyl, DEH-1 12); cyperquat; cyprazine; cyprazole; daimuron; 2,4-D; 2,4-DB; 2,4-DB, dalapon; desmedipham; desmetryn; di-allate; dicamba; dichlobenil; dichlorprop; diclofop- and its esters such as diclofop-methyl; diclosulam, diethatyl(-ethyl); difenoxuron; difenzoquat; diflufenican; diflufenzopyr; dimefuron; dimepiperate; dimethachlor; dimethametryn; dimethenamid (SAN-582H); dimethazone, dimexyflam, dimethipin; dimetrasulfuron, dinitramine; dinoseb; dinoterb; diphenamid; dipropetryn; diquat; dithiopyr; diuron; DNOC; eglinazine-ethyl; EL 77, i.e. 5-cyano-1-(1,1-d imethylethyl)-N-methyl-1 H-pyrazole-4-carboxamide; endothal; epoprodan; EPTC; esprocarb; ethalfluralin; ethametsulfuron(-methyl); ethidimuron; ethiozin; ethofumesate; ethoxyfen and its esters (for example the ethyl ester, HN-252); ethoxysulfuron; etobenzanid (HW 52); F5231, i.e. N-[2-chloro-4-fluoro-5-[4-(3-fluoropropyl)-4,5-dihydro-5-oxo-1 H-tetrazol-1-yl]phenyl]ethanesulfonamide; fenoprop; fenoxan, fenoxaprop and fenoxaprop-P and their esters, for example fenoxaprop-P-ethyl and fenoxaprop-ethyl; fenoxydim; fentrazamide; fenuron; flamprop(-methyl or -isopropyl or -isopropyl-L); flazasulfuron, floazulate, florasulam; fluazifop and fluazifop-P and their esters for example fluazifop-butyl and fluazifop-P-butyl; flucarbazone(-sodium); fluchloralin; flumetsulam; flumeturon; flumiclorac(-pentyl); flumioxazin (S-482); flumipropyn; fluometuron; fluorochloridone, fluorodifen; fluoroglycofen(-ethyl); flupoxam (KNW-739); flupropacil (UBIC-4243), flupyrsulfuron(-methyl, or -sodium); flurenol(-butyl); fluridone; flurochloridone; fluroxypyr(-meptyl); flurprimidol, flurtamone; fluthiacet(-methyl); fluthiamide; fomesafen; foramsulfuron; fosamine; furyloxyfen; glufosinate(-ammonium); glyphosate(-isopropylammonium); halosafen; halosulfuron(-methyl) and its esters (for example the methyl ester, NC-319); haloxyfop and its esters; haloxyfop-P (=R-haloxyfop) and its esters; hexazinone; imazamethabenz(-methyl); imazapyr; imazaquin and salts such as the ammonium salt; imazamethapyr; imrazamox; imazapic; imazethamethapyr; imazethapyr; imazosulfuron; indanofan; ioxvnil; isocarbamid; isoiprop)alin: isoproturon; isouron; isoxaben; isoxachlortole; isoxaflutole; isboxapyrifop; karbutilate; lactofen; lenacil; linuron; MCPA; MCPB; mecoprop; mefenacet; mefliidid; mesosulfuron, mesotrione; metamitron; metazachlor; methabenzthiazuron; metham; methazole; methoxyphenone; methyldymron; metabenzuron, methobenzuron; metobromuron; (alpha-)metolachlor; metosulam (XRD 511); meetoxuron; metribuzin; metsulfuron-methyl; MH; molinate; monalide; monocarbamide dihydrogensulfate; monolinuron; monuron; MT 128, i.e. 6-chloro-N-(3-chloro-2-propenylj-5-methyl-N-phenyl-3-pyridazinamine; MT 5950, i.e. N-[3-chloro4-(1-methylethyl)phenyl]-2-methylpentanamide; naproanilide; napropamide; naptalam; NC 310, i.e. 4-(2,4-dichlorobenzoyl)-1-methyl-5-benzyloxypyrazole; neburon; nicosulfuron; nipyraclophen; nitralin; nitrofen; nitrofluorfen; norflurazodn; orbencarb; oryzalin; oxadiargyl (RP-020630); oxadiazone; oxasulfuron; oxaciclomefone; oxyfluorfen; paraquat; pebulate; pelargonic acid; pendimethalin; pentoxazone; perFluidone; phenisopham; phenmedipham; picloram; picolinafen; piperophos; piributicarb; pirifenop-butyl; pretilachlor; primisulfuron(-methyl); procarbazone(-sodium); procyazine; prodiamine; profluralin; proglinazine(-ethyl); prometon; prometryn; propachlor; propanil; propaquizafop and its esters; propazine; propham; propisochlor; propyzamide; prosulfalin; prosulfocarb; prosulfuron (CGA-152005); prynachlor; pyroflufen(-ethyl); pyrazolinate; pyrazon; pyrazosulfuron(-ethyl); pyrazoxyfen; pyribenzoxim; pyributicarb; pyridafol; pyridate; pyriminobac(-methyl); pyrithiobac(-sodium) (KIH-2031); pyroxofop and its esters (for example propargyl ester); quinclorac; quinmerac; quinoclamine, quinofop and its ester derivatives, quizalofop and quizalofop-P and their ester derivatives, for example quizalofop-ethyl; quizalofop-P-tefuryl and -ethyl; renriduron; rimsulfuron (DPX-E 9636); S 275, i.e. 2-[4-chloro-2-fluoro-5-(2-propynyloxy)phenyl]-4,5,6,7-tetrahydro-2H-indazole; secbumeton; sethoxydim; siduron; simazine; simetryn; SN 106279, i.e. 2-[[7-[2-chloro4-(trifluoromethyl)phenoxy]-2-naphthalenyl]oxy]propanoic acid and its methyl ester; sulcotrione; sulfentrazone (FMC-97285, F-6285); sulfazurone; sulfometuron(-methyl); sulfosate (ICl-A0224); sulfosulfuron; TCA; tebutam (GCP-5544); tebuthiuron; tepraloxydim; terbacil; terbucarb; terbuchior; terbumeton; terbuthylazine; terbutryn; TFH 450, i.e. N,N-diethyl-3-[(2-ethyl-6-methylphenyl)sulfonyl]-1 H-1,2.4-triazole-1-carboxamide; thenylchlor (NSK-850); thiafluamide; thiazafluron; thiazopyr (Mon-13200); thidiazimin (SN-24085); thifensulfuron(-methyl); thiobencarb; tiocarbazil; tralkoxydim; tin-allate; triasulfuron; triaziflam; triazofenamide; tribenuron(-methyl); triclopyr; tridiphane; trietazine; trifluralin; triflusulfuron and esters (e.g. the methyl ester, DPX-66037); trimeturon; tritosulfuron; tsitodef; vernolate; WL 110547, i.e. 5-phenoxy-1-[3-(trifluoromethyl)phenyl]-1 H-tetrazole; BAY MKH 6561, UBH-509; D-489; LS 82-556; KPP-300; NC-324; NC-330; KH-218; DPX-N8189; SC-0774; DOWCO-535; DK-8910; V-53482; PP-600; MBH-001; KIH-9201; ET-751; KIH-6127 and KIH-2023.  
       [0165] Of particular interest is the selective control of harmful plants in crops of useful and ornamental plants. Although the compounds (I) according to the invention have very good to satisfactory selectivity in a large number of crops, it is possible in principle that phytoxicity in the crop plants can occur in some crops and, in particular, when the compounds (I) are mixed with other herbicides which are less selective. In this respect, the combinations of the compounds (I) according to the invention which contain the compounds (I), or their combinations with other herbicides or pesticides, and safeners are of particular interest. The safeners, which are employed in such amounts that they act as antidotes, reduce the phytotoxic side effects of the herbicides/pesticides used, for example in economically important crops such as cereals (wheat, barley, rye, corn, rice, millet), sugar beet, sugar cane, oilseed rape, cotton and soybean, preferably cereal. Suitable safeners for the compounds (I) and their combinations with other pesticides are, for example, the following groups of compounds:  
       [0166] a) Compounds of the dichlorophenylpyrazoline-3-carboxylic acid !type, preferably compounds such as ethyl 1-(2,4-dichlorophenyl)-5-(ethoxycarbonyl)-5-methyl-2-pyrazoline-3-carboxylate (S1-1) (“mefenpyr-diethyl”, PM, pp. 781-782), and related compounds, as described in WO 91/07874,  
       [0167] b) Derivatives of dichlorophenylpyrazole carboxylic acid, preferably compounds such as ethyl 1-(2,4-dichlorophenyl)-5-methylpyrazole-3-carboxylate (S1-2), ethyl 1-(2.4-dichlorophenyl)-5-isopropylrpvr2zole-3-carhoxyvlat (f1-3), ethyl 1-(2,4-dichlorophenyl)-5-(1 ,1-dimethylethyl)pyrazole-3-carboxylate (S 1-4), ethyl 1-(2,4-dichlorophenyl)-5-phenylpyrazole-3-carboxylate (S1-5) and related compounds as described in EP-A-333 131 and EP-A-269 806.  
       [0168] c) Compounds of the triazolecarboxylic acid type, preferably compounds such as fenchlorazole(ethyl ester), i.e. ethyl 1-(2,4-dichlorophenyl)-5-trichloromethyl-(1 H)-1,2,4-triazole-3-carboxylate (S1-6) and related compounds as described in EP-A-174 562 and EP-A-346 620.  
       [0169] d) Compounds of the 5-benzyl- or  5 -phenyl-2-isoxazoline-3-carboxylic acid type, or the 5,5-diphenyl-2-isoxazoline-3-carboxylic acid type, preferably compounds such as ethyl 5-(2,4-dichlorobenzyl)-2-isoxazoline-3-carboxylate (S1-7) or ethyl 5-phenyl-2-isoxazoline-3-carboxylate (SI1-8) and related compounds, as described in WO 91/08202, or ethyl 5,5-diphenyl-2-isoxazolinecarboxylate (S1-9) (“isoxadifen-ethyl”) or its -n-propyl ester (S1-10) or ethyl 5-(4-fluorophenyl)-5-phenyl-2-isoxazoline-3-carboxylate (S1-11), as described in the German patent application (WO-A-95/07897).  
       [0170] e) Compounds of the 8-quinolineoxyacetic acid type (S2), preferably 1-methylhex-1-yl (5-chloro-8-quinolineoxy)acetate (common name “cloquintocet-mexyl”) (S2-1) (see PM, pp. 263-264) 1,3-dimethylbut-1-yl (5-chloro-8-quinolineoxy)acetate (S2-2), 4-allyloxybutyl (5-chloro-8-quinolineoxy)acetate (S2-3), 1-allyloxyprop-2-yl (5-chloro-8-quinolineoxy)acetate (S2-4), ethyl (5-chloro-8-quinolineoxy)acetate (S2-5), methyl (5-chloro-8-quinolineoxy)acetate (S2-6), allyl (5-chloro-8-quinolineoxy)acetate (S2-7), 2-(2-propylideneiminoxy)-1-ethyl (5-chloro-8-quinolineoxy)acetate (S2-8), 2-oxoprop-1-yl (5-chloro-8-quinolineoxy)acetate (S2-9) and related compounds, as described in EP-A-86 750, EP-A-94 349 and EP-A-191 736 or EP-A-0 492 366.  
       [0171] f) Compounds of the (5-chloro-8-quinolineoxy)malonic acid type, preferably compounds such as diethyl (5-chloro-8-quinolineoxy)rnalonate, diallyl (5-chloro-8-quinolineoxy)malonate, methyl ethyl (5-chloro-8-quinolineoxy)malonate and related compounds, as described in EP-A-0 582 198.  
       [0172] g) Active comounds of the phenoxyacetic or -propionic acid derivative type or the aromatic carboxylic acid type, such as, for example, 2,4-dichlorophenoxyacetic acid (esters) (2,4-D), 4-chloro-2-methylphenoxypropionic esters (Mecoprop), MCPA or 3,6-dichloro-2-methoxybenzoic acid (esters) (Dicamba).  
       [0173] h) Active compounds of the pyrimidine type, which are used as soil-acting safeners in rice, such as, for example, “fenclorim” (PM, pp. 512-511) (=4,6-dichloro-2-phenylpyrimidine), which is known as safener for pretilachlor in sown rice,  
       [0174] i) Active compounds of the dichloroacetamide type, which are frequently used as pre-emergent safeners (soil-acting safeners), such as, for example, “dichlormid” (PM, pp. 363-364) (=N,N-diallyl-2,2-dichloroacetamide), “R-29148” (=3-dichloroacetyl-2,2,5-trimethyl-1,3-oxazolidine from Stauffer), “benoxacor” (PM, pp. 102-103) (=4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine), “PPG-1292” (=N-allyl-N-[(1,3-dioxolan-2-yl)methyl]dichloroacetamide from PPG Industries), “DK-24” (=N-allyl-N-[(allylaminocarbonyl)methyl]dichloroacetamide from Sagro-Chem), “AD-67” or “MON 4660” (=3-dichloroacetyl-1-oxa-3-aza-spiro[4,5]decane from Nitrokemia or Monsanto), “diclonon” or “BAS145138” or “LAB145138” (=3-dichloroacetyl-2,5,5-trimethyl-1,3-diazabicyclo[4.3.0]nonane from BASF) and “furilazol” or “MON 13900” (see PM, 637-638) (=(RS)-3-dichloroacetyl-5-(2-furyl)-2,2-dimethyloxazolidine)  
       [0175] j) Active compounds of the type of the dichloroacetone derivatives, such as, for example, “MG 191” (CAS-Reg. No. 96420-72-3) (=2-dichloromethyl-2-methyl-1,3-dioxolane from Nitrokemia), which is known as safener for corn,  
       [0176] k) Active compounds of the oxyimino compound type, which are known as seed dressings, such as, for example, “oxabetrinil” (PM, pp. 902-903) (=(Z)-1,3-dioxolan-2-ylmethoxy-imino(phenyl)acetonitrile), which is known as seed dressing safener for millet against metolachlor damage, “fluxofenim” (PM, pp. 613-614) (=1-(4-chlorophenyl)-2,2,2-trifluoro-1-ethanone O-(1,3-dioxolan-2-ylmethyl) oxime), which is known as seed dressing safener for millet against metolachlor damage, and “cyometrinil” or “-CGA-43089” (PM, p. 1304) (=(Z)-cyanomethoxyimino(phenyl)acetonitrile), which is known as seed dressing safener for millet against metolachlor damage,  
       [0177] l) Active compounds of the thiazolecarboxylic ester type, which are known as seed dressings, such as, for example, “flurazol” (PM, pp. 590-591) (=benzyl 2-chloro4-trifluoromethyl-1,3-thiazole-5-carboxylate), which is known as seed dressing safener for millet against alachlor and metolachlor damage,  
       [0178] m) Active compounds of the naphthalenedicarboxylic acid derivative type, which are known as seed dressings, such as, for example, “naphthalic anhydride” (PM, p. 1342) (=1,8-naphthalenedicarboxylic anhydride), which is known as seed dressing safener for corn against thiocarbamate herbicide damage,  
       [0179] n) Active compounds of the chromanacetic acid derivative type, such as, for example, “CL 304415” (CAS-Reg. No. 31541-57-8) (=2-(4-carboxychroman-4-yl)acetic acid from American Cyanamid), which is known as safener for corn against imidazolinone damage,  
       [0180] o) Active compounds which, in addition to a herbidical action against harmful plants, also have safener action in crop plants such as rice, such as, for example, “dimepiperate” or “MY-93” (PM, pp. 404-405) (=S-1-methyl-1-phenylethyl piperidine-1-thiocarboxylate), which is known as safener for rice against damage caused by the herbicide molinate, “daimuron” or “SK 23” (PM, p. 330) (=1-(1-methyl-1-phenylethyl)-3-p-tolylurea), which is known as safener for rice against damage caused by the herbicide imazosulfuron, “cumyluron”=“JC-940” (=3-(2-chlorophenylmethyl)-1-(1-methyl-1-phenylethyl)urea, see JP-A-60087254), which is known as safener for rice against damage by some herbicides, “methoxyphenon” or “NK 049” (=3,3′-dimethyl4-methoxy-benzophenone), which is known as safener for rice against damage by some herbicides, “CSB” (=1-bromo-4-(chloromethylsulfonyl)benzene) (CAS-Reg. No. 54091-064 from Kumiai), which is known as safener against damage by some herbicides in rice  
       [0181] p) N-Acylsulfonamides of the formula (S3) and salts thereof,  
                 
 
       [0182] as described in WO-A-97/45016,  
       [0183] q) Acylsulfamoylbenzoamides of the formula (S4), if appropriate also in salt form,  
                 
 
       [0184] as described in the International Application No. PCT/EP98/06097, and  
       [0185] r) compounds of the formula (S5),  
                 
 
       [0186] as described in WO-A 98/13 361  
       [0187] including the stereoisomers and the salts used in agriculture.  
       [0188] Among the safeners mentioned, (S1-1) and (S1-9) and (S2-1), in particular (S1-1) and (S1-9) are of particular interest.  
       [0189] Some of the safeners are already known as herbicides and consequently show, in addition to the herbicidal action against harmful plants, also protective action in connection with crop plants.  
       [0190] The ratios by weight of herbicide (mixture) to safener generally depend on the application rate of the herbicide and the efficacy of the safener in question and can vary within wide limits, for example in the range from 200:1 to 1:200, preferably 100:1 to 1:100, in particular 20:1 to 1:20. Analogously to the compounds (I) or their mixtures, the safeners can be formulated with other herbicides/pesticides and be provided and used as ready mix or tank mix with the herbicides.  
       [0191] For use, the formulations which are present in commercially available form are, if appropriate, diluted in the customary manner, for example using water in the case of wettable powders, emulsifiable concentrates, dispersions and water-dispersible granules. Preparations in the form of dusts, granules for soil application or broadcasting and sprayable solutions are usually not further diluted with other inert substances prior to use.  
       [0192] The application rate of the compounds of the formula (I) required varies with the external conditions, such as temperature, humidity, the nature of the herbicide used and the like. It can vary within wide limits, for example between 0.001 and 10.0 kg/ha or more of active substance, but it is preferably between 0.005 and 5 kg/ha. 
     
    
    
     [0193] In the examples below, the amounts (including percentages) are based on weight, unless specifically defined otherwise.  
     [0194] A. Chemical Examples  
     [0195] 2-Amino-4-(1-fluoro-1-methylethyl)-6-{1-[3-(3-hydroxybut-1-yn-1-yl)-4-fluorophenyl]-ethyl}-1,3,5-triazine of the formula  
                 
 
     [0196] (=compound P1 7.840 from table 1)  
     [0197] Step 1: 4-Fluoro-3-(3-hydroxybut-1-yn-1-yl)acetophenone  
     [0198] 10.00 9 (46.1 mmol) of 3-bromo-4-fluoroacetophenone, 4.84 g (69.1 mmol) of 1-butyn-3-ol, 1.62 g (2.3 mmol) of bis(triphenylphosphine)palladium(ll) chloride, 0.30 g (1.2 mmol) of triphenylphosphine and 6.99 g (69.1 mmol) of triethylamine in 200 ml of tetrahydrofuran was stirred for 20 min. 0.11 g (0.6 mmol) of copper(l) iodide was then added. The reaction mixture was stirred at room temperature for 10 days. The solvent was distilled off using a rotary evaporator, the residue was taken up in ethyl acetate and the organic phase was extracted with water. The aqueous phase was then extracted twice with ethyl acetate, and the organic phase was then dried and freed from the solvent using a rotary evaporator. Chromatographic purification gave 8.10 g (85% yield) of the desired product as the brown oil.  
     [0199] Step 2: 1-(4-Fluoro-3-(3-hydroxybut-1-yn-1-yl)phenyl)ethylamine  
     [0200] 4.00 g (19.4 mmol) of 4-fluoro-3-(3-hydroxybut-1-yn-1-yl)acetophenone were dissolved in 80 ml of methanol. 14.95 g (194 mmol) of ammonium acetate and 2.05 g (31.0 mmol) of sodium cyanoborohydride were added, and the reaction mixture was then stirred at room temperature for 11 days. 30 ml of 1N KOH and, to complex the cyanide, a sufficient amount of iron sulfate were added. The content of the flask was stirred at room temperature for another 30 min. The mixture was filtered, the residue was washed with ethyl acetate, water was added to the filtrate and the aqueous phase was extracted three times with ethyl acetate. The organic phase was extracted three times with 1 N hydrochloric acid and the combined extracts were neutralized and extracted three times with ethyl acetate. The organic phase was dried and the filtrate was freed from the solvent using a rotary evaporator, giving 1.6 g (40% yield) of the desired product as a brown oil.  
     [0201] Step 3: 2-Amino-4-[1-(4-fluoro-3-(3-hydroxybut-1-yn-1-yl)phenyl)ethyl]amino-6-(2-fluoroprop-2-yl)-1 ,3,5-triazine  
     [0202] 0.30 g (1.4 mmol) of 1-(4-fluoro-3-(3-hydroxybut-1-yn-1-yl)phenyl)ethylamine, 0.28 g (1.5 mmol) of 2-amino-4-chloro-6-(2-fluoroprop-2-yl)-1,3,5-triazine and 0.24 g (1.7 mmol) of potassium carbonate were initially charged in 20 ml of acetonitrile and heated at 79° C. for three days. The reaction mixture was filtered off with suction, the residue was washed with ethyl acetate and the filtrate was freed from the solvent using a rotary evaporator. The residue was purified-chromatographically, giving 0.19 g (35% yield) of the desired product as a white solid of melting point 119-122° C. The compounds of the formula (I) listed in the table below are prepared by or analogously to the process described above or the processes mentioned in the description.  
     [0203] For Table 1, concerning compounds of the formula (Ia):  
     [0204] (Table 1: see after pretable 1.2)  
     Tr—Ar  (Ia)  
     [0205] Here, Tr and Ar are the following radicals of the formulae Tr and Ar: respectively:  
                 
 
     [0206] Table 1 defines individual compounds of the formula (Ia) which contain certain radicals Tr and Ar referred to by numbers. The radicals Tr-1, Tr-2, Tr-3, Tr4, etc., up to Tr-30 are indicated by the numbers 1, 2, 3, 4, etc., up to 30 appearing in the product number Px.y in place of x. The radicals No. 1, 2, 3, 4, etc., up to 1620 for Ar are indicated by the identical number in the product number Px.y in place of y.  
     [0207] The specific structure of the numbered radicals Tr is shown in Table 1.1 below. The structure of a radical Tr-x (for example Tr-8) is a radical of the formula Tr having the specific meanings of R 1  and R 4 , listed in Table 1.1 for R 1  (see left column) in the row in which Tr-x is located or in the Table 1.1 for R 4  (see top row) in the column in which Tr-x is located.  
               TABLE 1.1                          (pretable for Table 1): Definition of numbered radicals of Tr                                                               R 4                                                   R 1     H   Me   F-Et   c-Pr   c-Bu                       Me   Tr-1   Tr-2   Tr-3   Tr-4   Tr-5           Et   Tr-6   Tr-7   Tr-8   Tr-9   Tr-10           i-Pr   Tr-11   Tr-12   Tr-13   Tr-14   Tr-15           F-i-Pr   Tr-16   Tr-17   Tr-18   Tr-19   Tr-20           F-Et   Tr-21   Tr-22   Tr-23   Tr-24   Tr-25           F-Pr   Tr-26   Tr-27   Tr-28   Tr-29   Tr-30           OMe   Tr-31   Tr-32   Tr-33   Tr-34   Tr-35           OEt   Tr-36   Tr-37   Tr-38   Tr-39   Tr-40           SMe   Tr-41   Tr-42   Tr-43   Tr-44   Tr-45           SEt   Tr-46   Tr-47   Tr-48   Tr-49   Tr-50                      
 
     [0208] Abbreviations for Table 1.1:  
     [0209] Me=methyl; Et=ethyl; i-Pr=isopropyl F-Et=1-fluoroethyl;  
     [0210] F-Pr=1-fluoro-n-propyl; F-i-Pr=(1-fluoro-1-methyl)ethyl;  
     [0211] c-Pr=cyclopropyl; c-Bu=cyclobutyl, OMe=methoxy; OEt=ethoxy;  
     [0212] SMe=methylthio; SEt=ethylthio  
     [0213] In a given column, the meaning of the radical R 4  is identical; in a given row, the meaning of the radical R 1  is identical.  
     [0214] For Table 1.2 (pretable for Table 1): Definition of the radical Ar  
                 
 
     [0215] Abbreviations for Table 1.2 below:  
     [0216] Me=methyl; Et=ethyl; Bu=n-butyl; CHF-Me=1-fluoroethyl;  
     [0217] CH(OH)—Me=1-hydroxyethyl; c-Pr=cyclopropyl;  
     [0218] CH(CF 2 -CH 2 )=2,2-difluorocyclopropyl;  
     [0219] CF(CF 2 -CF 2 )=1,2,2,3,3-pentafluorocyclopropyl;  
     [0220] c-Bu=cyclobutyl; c-Pen=cyclopentyl; c-Hex=cyclohexyl;  
     [0221] CC=—CC≡C—=(ethin-1,2-diyl)  
               TABLE 1.2                          The radicals Ar                                 Ar No.   R 5     R 6     R 7     R 8                                           1   H   CF═CF 2     Me   H       2   H   CF═CF 2     Et   H       3   H   CF═CF 2     CHF—Me   H       4   H   CF═CF 2     i-Pr   H       5   H   CF═CF 2     F   H       6   H   CF═CF 2     Cl   H       7   H   CF═CF 2     Br   H       8   H   CF═CF 2     I   H       9   H   CF═CF 2     NO 2     H       10   H   CF═CF 2     CN   H       11   H   CF═CF 2     H   Me       12   H   CF═CF 2     H   Et       13   H   CF═CF 2     H   CHF—Me       14   H   CF═CF 2     H   i-Pr       15   H   CF═CF 2     H   F       16   H   CF═CF 2     H   Cl       17   H   CF═CF 2     H   Br       18   H   CF═CF 2     H   I       19   H   CF═CF 2     H   NO 2         20   H   CF═CF 2     H   CN       21   Me   H   H   CF═CF 2         22   Et   H   H   CF═CF 2         23   CHF—Me   H   H   CF═CF 2         24   i-Pr   H   H   CF═CF 2         25   F   H   H   CF═CF 2         26   Cl   H   H   CF═CF 2         27   Br   H   H   CF═CF 2         28   I   H   H   CF═CF 2         29   NO 2     H   H   CF═CF 2         30   CN   H   H   CF═CF 2         31   H   Me   CF═CF 2     H       32   H   Et   CF═CF 2     H       33   H   CHF—Me   CF═CF 2     H       34   H   i-Pr   CF═CF 2     H       35   H   F   CF═CF 2     H       36   H   Cl   CF═CF 2     H       37   H   Br   CF═CF 2     H       38   H   I   CF═CF 2     H       39   H   NO 2     CF═CF 2     H       40   H   CN   CF═CF 2     H       41   H   Me   CF═CF 2     F       42   H   Me   CF═CF 2     Cl       43   H   Me   CF═CF 2     Br       44   H   Me   CF═CF 2     I       45   H   Me   CF═CF 2     Me       46   H   Et   CF═CF 2     Et       47   H   CHF—Me   CF═CF 2     CHF—Me       48   H   i-Pr   CF═CF 2     i-Pr       49   H   F   CF═CF 2     F       50   H   Cl   CF═CF 2     Cl       51   H   Br   CF═CF 2     Br       52   H   I   CF═CF 2     I       53   H   NO 2     CF═CF 2     NO 2         54   H   CN   CF═CF 2     CN       55   H   CF═CF 2     CF═CF 2     H       56   H   CF═CF 2     CF═CF 2     Me       57   H   CF═CF 2     CF═CF 2     Et       58   H   CF═CF 2     CF═CF 2     CHF—Me       59   H   CF═CF 2     CF═CF 2     i-Pr       60   H   CF═CF 2     CF═CF 2     F       61   H   CF═CF 2     CF═CF 2     Cl       62   H   CF═CF 2     CF═CF 2     Br       63   H   CF═CF 2     CF═CF 2     I       64   H   CF═CF 2     CF═CF 2     NO 2         65   H   CF═CF 2     CF═CF 2     CN       66   H   CF═CF 2     H   CF═CF 2         67   H   CF═CF 2     Me   CF═CF 2         68   H   CF═CF 2     Et   CF═CF 2         69   H   CF═CF 2     CHF—Me   CF═CF 2         70   H   CF═CF 2     i-Pr   CF═CF 2         71   H   CF═CF 2     F   CF═CF 2         72   H   CF═CF 2     Cl   CF═CF 2         73   H   CF═CF 2     Br   CF═CF 2         74   H   CF═CF 2     I   CF═CF 2         75   H   CF═CF 2     NO 2     CF═CF 2         76   H   CF═CF 2     CN   CF═CF 2         77   H   CF═CF—CF 3     Me   H       78   H   CF═CF—CF 3     Et   H       79   H   CF═CF—CF 3     CHF—Me   H       80   H   CF═CF—CF 3     i-Pr   H       81   H   CF═CF—CF 3     F   H       82   H   CF═CF—CF 3     Cl   H       83   H   CF═CF—CF 3     Br   H       84   H   CF═CF—CF 3     I   H       85   H   CF═CF—CF 3     NO 2     H       86   H   CF═CF—CF 3     CN   H       87   H   CF═CF—CF 3     H   Me       88   H   CF═CF—CF 3     H   Et       89   H   CF═CF—CF 3     H   CHF—Me       90   H   CF═CF—CF 3     H   i-Pr       91   H   CF═CF—CF 3     H   F       92   H   CF═CF—CF 3     H   Cl       93   H   CF═CF—CF 3     H   Br       94   H   CF═CF—CF 3     H   I       95   H   CF═CF—CF 3     H   NO 2         96   H   CF═CF—CF 3     H   CN       97   Me   H   H   CF═CF—CF 3         98   Et   H   H   CF═CF—CF 3         99   CHF—Me   H   H   CF═CF—CF 3         100   i-Pr   H   H   CF═CF—CF 3         101   F   H   H   CF═CF—CF 3         102   Cl   H   H   CF═CF—CF 3         103   Br   H   H   CF═CF—CF 3         104   I   H   H   CF═CF—CF 3         105   NO 2     H   H   CF═CF—CF 3         106   CN   H   H   CF═CF—CF 3         107   H   Me   CF═CF—CF 3     H       108   H   Et   CF═CF—CF 3     H       109   H   CHF—Me   CF═CF—CF 3     H       110   H   i-Pr   CF═CF—CF 3     H       111   H   F   CF═CF—CF 3     H       112   H   Cl   CF═CF—CF 3     H       113   H   Br   CF═CF—CF 3     H       114   H   I   CF═CF—CF 3     H       115   H   NO 2     CF═CF—CF 3     H       116   H   CN   CF═CF—CF 3     H       117   H   Me   CF═CF—CF 3     F       118   H   Me   CF═CF—CF 3     Cl       119   H   Me   CF═CF—CF 3     Br       120   H   Me   CF═CF—CF 3     I       121   H   Me   CF═CF—CF 3     Me       122   H   Et   CF═CF—CF 3     Et       123   H   CHF—Me   CF═CF—CF 3     CHF—Me       124   H   i-Pr   CF═CF—CF 3     i-Pr       125   H   F   CF═CF—CF 3     F       126   H   Cl   CF═CF—CF 3     Cl       127   H   Br   CF═CF—CF 3     Br       128   H   I   CF═CF—CF 3     I       129   H   NO 2     CF═CF—CF 3     NO 2         130   H   CN   CF═CF—CF 3     CN       131   H   CF═CF—CF 3     CF═CF—CF 3     H       132   H   CF═CF—CF 3     CF═CF—CF 3     Me       133   H   CF═CF—CF 3     CF═CF—CF 3     Et       134   H   CF═CF—CF 3     CF═CF—CF 3     CHF—Me       135   H   CF═CF—CF 3     CF═CF—CF 3     i-Pr       136   H   CF═CF—CF 3     CF═CF—CF 3     F       137   H   CF═CF—CF 3     CF═CF—CF 3     Cl       138   H   CF═CF—CF 3     CF═CF—CF 3     Br       139   H   CF═CF—CF 3     CF═CF—CF 3     I       140   H   CF═CF—CF 3     CF═CF—CF 3     NO 2         141   H   CF═CF—CF 3     CF═CF—CF 3     CN       142   H   CF═CF—CF 3     H   CF═CF—CF 3         143   H   CF═CF—CF 3     Me   CF═CF—CF 3         144   H   CF═CF—CF 3     Et   CF═CF—CF 3         145   H   CF═CF—CF 3     CHF—Me   CF═CF—CF 3         146   H   CF═CF—CF 3     i-Pr   CF═CF—CF 3         147   H   CF═CF—CF 3     F   CF═CF—CF 3         148   H   CF═CF—CF 3     Cl   CF═CF—CF 3         149   H   CF═CF—CF 3     Br   CF═CF—CF 3         150   H   CF═CF—CF 3     I   CF═CF—CF 3         151   H   CF═CF—CF 3     NO 2     CF═CF—CF 3         152   H   CF═CF—CF 3     CN   CF═CF—CF 3         153   H   CF 2 —CF═CF 2     Me   H       154   H   CF 2 —CF═CF 2     Et   H       155   H   CF 2 —CF═CF 2     CHF—Me   H       156   H   CF 2 —CF═CF 2     i-Pr   H       157   H   CF 2 —CF═CF 2     F   H       158   H   CF 2 —CF═CF 2     Cl   H       159   H   CF 2 —CF═CF 2     Br   H       160   H   CF 2 —CF═CF 2     I   H       161   H   CF 2 —CF═CF 2     NO 2     H       162   H   CF 2 —CF═CF 2     CN   H       163   H   CF 2 —CF═CF 2     H   Me       164   H   CF 2 —CF═CF 2     H   Et       165   H   CF 2 —CF═CF 2     H   CHF—Me       166   H   CF 2 —CF═CF 2     H   i-Pr       167   H   CF 2 —CF═CF 2     H   F       168   H   CF 2 —CF═CF 2     H   Cl       169   H   CF 2 —CF═CF 2     H   Br       170   H   CF 2 —CF═CF 2     H   I       171   H   CF 2 —CF═CF 2     H   NO 2         172   H   CF 2 —CF═CF 2     H   CN       173   Me   H   H   CF 2 —CF═CF 2         174   Et   H   H   CF 2 —CF═CF 2         175   CHF—Me   H   H   CF 2 —CF═CF 2         176   i-Pr   H   H   CF 2 —CF═CF 2         177   F   H   H   CF 2 —CF═CF 2         178   Cl   H   H   CF 2 —CF═CF 2         179   Br   H   H   CF 2 —CF═CF 2         180   I   H   H   CF 2 —CF═CF 2         181   NO 2     H   H   CF 2 —CF═CF 2         182   CN   H   H   CF 2 —CF═CF 2         183   H   Me   CF 2 —CF═CF 2     H       184   H   Et   CF 2 —CF═CF 2     H       185   H   CHF—Me   CF 2 —CF═CF 2     H       186   H   i-Pr   CF 2 —CF═CF 2     H       187   H   F   CF 2 —CF═CF 2     H       188   H   Cl   CF 2 —CF═CF 2     H       189   H   Br   CF 2 —CF═CF 2     H       190   H   I   CF 2 —CF═CF 2     H       191   H   NO 2     CF 2 —CF═CF 2     H       192   H   CN   CF 2 —CF═CF 2     H       193   H   Me   CF 2 —CF═CF 2     F       194   H   Me   CF 2 —CF═CF 2     Cl       195   H   Me   CF 2 —CF═CF 2     Br       196   H   Me   CF 2 —CF═CF 2     I       197   H   Me   CF 2 —CF═CF 2     Me       198   H   Et   CF 2 —CF═CF 2     Et       199   H   CHF—Me   CF 2 —CF═CF 2     CHF—Me       200   H   i-Pr   CF 2 —CF═CF 2     i-Pr       201   H   F   CF 2 —CF═CF 2     F       202   H   Cl   CF 2 —CF═CF 2     Cl       203   H   Br   CF 2 —CF═CF 2     Br       204   H   I   CF 2 —CF═CF 2     I       205   H   NO 2     CF 2 —CF═CF 2     NO 2         206   H   CN   CF 2 —CF═CF 2     CN       207   H   CF 2 —CF═CF 2     CF 2 —CF═CF 2     H       208   H   CF 2 —CF═CF 2     CF 2 —CF═CF 2     Me       209   H   CF 2 —CF═CF 2     CF 2 —CF═CF 2     Et       210   H   CF 2 —CF═CF 2     CF 2 —CF═CF 2     CHF—Me       211   H   CF 2 —CF═CF 2     CF 2 —CF═CF 2     i-Pr       212   H   CF 2 —CF═CF 2     CF 2 —CF═CF 2     F       213   H   CF 2 —CF═CF 2     CF 2 —CF═CF 2     Cl       214   H   CF 2 —CF═CF 2     CF 2 —CF═CF 2     Br       215   H   CF 2 —CF═CF 2     CF 2 —CF═CF 2     I       216   H   CF 2 —CF═CF 2     CF 2 —CF═CF 2     NO 2         217   H   CF 2 —CF═CF 2     CF 2 —CF═CF 2     CN       218   H   CF 2 —CF═CF 2     H   CF 2 —CF═CF 2         219   H   CF 2 —CF═CF 2     Me   CF 2 —CF═CF 2         220   H   CF 2 —CF═CF 2     Et   CF 2 —CF═CF 2         221   H   CF 2 —CF═CF 2     CHF—Me   CF 2 —CF═CF 2         222   H   CF 2 —CF═CF 2     i-Pr   CF 2 —CF═CF 2         223   H   CF 2 —CF═CF 2     F   CF 2 —CF═CF 2         224   H   CF 2 —CF═CF 2     Cl   CF 2 —CF═CF 2         225   H   CF 2 —CF═CF 2     Br   CF 2 —CF═CF 2         226   H   CF 2 —CF═CF 2     I   CF 2 —CF═CF 2         227   H   CF 2 —CF═CF 2     NO 2     CF 2 —CF═CF 2         228   H   CF 2 —CF═CF 2     CN   CF 2 —CF═CF 2         229   H   CF 2 —CF═CF—CF 3     Me   H       230   H   CF 2 —CF═CF—CF 3     Et   H       231   H   CF 2 —CF═CF—CF 3     CHF—Me   H       232   H   CF 2 —CF═CF—CF 3     i-Pr   H       233   H   CF 2 —CF═CF—CF 3     F   H       234   H   CF 2 —CF═CF—CF 3     Cl   H       235   H   CF 2 —CF═CF—CF 3     Br   H       236   H   CF 2 —CF═CF—CF 3     I   H       237   H   CF 2 —CF═CF—CF 3     NO 2     H       238   H   CF 2 —CF═CF—CF 3     CN   H       239   H   CF 2 —CF═CF—CF 3     H   Me       240   H   CF 2 —CF═CF—CF 3     H   Et       241   H   CF 2 —CF═CF—CF 3     H   CHF—Me       242   H   CF 2 —CF═CF—CF 3     H   i-Pr       243   H   CF 2 —CF═CF—CF 3     H   F       244   H   CF 2 —CF═CF—CF 3     H   Cl       245   H   CF 2 —CF═CF—CF 3     H   Br       246   H   CF 2 —CF═CF—CF 3     H   I       247   H   CF 2 —CF═CF—CF 3     H   NO 2         248   H   CF 2 —CF═CF—CF 3     H   CN       249   Me   H   H   CF 2 —CF═CF—CF 3         250   Et   H   H   CF 2 —CF═CF—CF 3         251   CHF—Me   H   H   CF 2 —CF═CF—CF 3         252   i-Pr   H   H   CF 2 —CF═CF—CF 3         253   F   H   H   CF 2 —CF═CF—CF 3         254   Cl   H   H   CF 2 —CF═CF—CF 3         255   Br   H   H   CF 2 —CF═CF—CF 3         256   I   H   H   CF 2 —CF═CF—CF 3         257   NO 2     H   H   CF 2 —CF═CF—CF 3         258   CN   H   H   CF 2 —CF═CF—CF 3         259   H   Me   CF 2 —CF═CF—CF 3     H       260   H   Et   CF 2 —CF═CF—CF 3     H       261   H   CHF—Me   CF 2 —CF═CF—CF 3     H       262   H   i-Pr   CF 2 —CF═CF—CF 3     H       263   H   F   CF 2 —CF═CF—CF 3     H       264   H   Cl   CF 2 —CF═CF—CF 3     H       265   H   Br   CF 2 —CF═CF—CF 3     H       266   H   I   CF 2 —CF═CF—CF 3     H       267   H   NO 2     CF 2 —CF═CF—CF 3     H       268   H   CN   CF 2 —CF═CF—CF 3     H       269   H   Me   CF 2 —CF═CF—CF 3     F       270   H   Me   CF 2 —CF═CF—CF 3     Cl       271   H   Me   CF 2 —CF═CF—CF 3     Br       272   H   Me   CF 2 —CF═CF—CF 3     I       273   H   Me   CF 2 —CF═CF—CF 3     Me       274   H   Et   CF 2 —CF═CF—CF 3     Et       275   H   CHF—Me   CF 2 —CF═CF—CF 3     CHF—Me       276   H   i-Pr   CF 2 —CF═CF—CF 3     i-Pr       277   H   F   CF 2 —CF═CF—CF 3     F       278   H   Cl   CF 2 —CF═CF—CF 3     Cl       279   H   Br   CF 2 —CF═CF—CF 3     Br       280   H   I   CF 2 —CF═CF—CF 3     I       281   H   NO 2     CF 2 —CF═CF—CF 3     NO 2         282   H   CN   CF 2 —CF═CF—CF 3     CN       283   H   CF 2 —CF═CF—CF 3     CF 2 —CF═CF—CF 3     H       284   H   CF 2 —CF═CF—CF 3     CF 2 —CF═CF—CF 3     Me       285   H   CF 2 —CF═CF—CF 3     CF 2 —CF═CF—CF 3     Et       286   H   CF 2 —CF═CF—CF 3     CF 2 —CF═CF—CF 3     CHF—Me       287   H   CF 2 —CF═CF—CF 3     CF 2 —CF═CF—CF 3     i-Pr       288   H   CF 2 —CF═CF—CF 3     CF 2 —CF═CF—CF 3     F       289   H   CF 2 —CF═CF—CF 3     CF 2 —CF═CF—CF 3     Cl       290   H   CF 2 —CF═CF—CF 3     CF 2 —CF═CF—CF 3     Br       291   H   CF 2 —CF═CF—CF 3     CF 2 —CF═CF—CF 3     I       292   H   CF 2 —CF═CF—CF 3     CF 2 —CF═CF—CF 3     NO 2         293   H   CF 2 —CF═CF—CF 3     CF 2 —CF═CF—CF 3     CN       294   H   CF 2 —CF═CF—CF 3     H   CF 2 —CF═CF—CF 3         295   H   CF 2 —CF═CF—CF 3     Me   CF 2 —CF═CF—CF 3         296   H   CF 2 —CF═CF—CF 3     Et   CF 2 —CF═CF—CF 3         297   H   CF 2 —CF═CF—CF 3     CHF—Me   CF 2 —CF═CF—CF 3         298   H   CF 2 —CF═CF—CF 3     i-Pr   CF 2 —CF═CF-CF 3         299   H   CF 2 —CF═CF—CF 3     F   CF 2 —CF═CF—CF 3         300   H   CF 2 —CF═CF—CF 3     Cl   CF 2 —CF═CF—CF 3         301   H   CF 2 —CF═CF—CF 3     Br   CF 2 —CF═CF—CF 3         302   H   CF 2 —CF═CF—CF 3     I   CF 2 —CF═CF—CF 3         303   H   CF 2 —CF═CF—CF 3     NO 2     CF 2 —CF═CF—CF 3         304   H   CF 2 —CF═CF—CF 3     CN   CF 2 —CF═CF—CF 3         305   H   CCH   Me   H       308   H   CCH   Et   H       307   H   CCH   CHF—Me   H       308   H   CCH   i-Pr   H       309   H   CCH   F   H       310   H   CCH   Cl   H       311   H   CCH   Br   H       312   H   CCH   I   H       313   H   CCH   NO 2     H       314   H   CCH   CN   H       315   H   CCH   H   Me       316   H   CCH   H   Et       317   H   CCH   H   CHF—Me       318   H   CCH   H   i-Pr       319   H   CCH   H   F       320   H   CCH   H   Cl       321   H   CCH   H   Br       322   H   CCH   H   I       323   H   CCH   H   NO 2         324   H   CCH   H   CN       325   Me   H   H   CCH       326   Et   H   H   CCH       327   CHF—Me   H   H   CCH       328   i-Pr   H   H   CCH       329   F   H   H   CCH       330   Cl   H   H   CCH       331   Br   H   H   CCH       332   I   H   H   CCH       333   NO 2     H   H   CCH       334   CN   H   H   CCH       335   H   Me   CCH   H       336   H   Et   CCH   H       337   H   CHF—Me   CCH   H       338   H   i-Pr   CCH   H       339   H   Cl   CCH   H       340   H   Br   CCH   H       341   H   I   CCH   H       342   H   NO 2     CCH   H       343   H   CN   CCH   H       344   H   Me   CCH   F       345   H   Me   CCH   Cl       346   H   Me   CCH   Br       347   H   Me   CCH   I       348   H   Me   CCH   Me       349   H   Et   CCH   Et       350   H   CHF—Me   CCH   CHF—Me       351   H   i-Pr   CCH   i-Pr       352   H   F   CCH   F       353   H   Cl   CCH   Cl       354   H   Br   CCH   Br       355   H   I   CCH   I       356   H   NO 2     CCH   NO 2         357   H   CN   CCH   CN       358   H   CCH   CCH   H       359   H   CCH   CCH   Me       360   H   CCH   CCH   Et       361   H   CCH   CCH   CHF—Me       362   H   CCH   CCH   i-Pr       363   H   CCH   CCH   F       364   H   CCH   CCH   Cl       365   H   CCH   CCH   Br       366   H   CCH   CCH   I       367   H   CCH   CCH   NO 2         368   H   CCH   CCH   CN       369   H   CCH   H   CCH       370   H   CCH   Me   CCH       371   H   CCH   Et   CCH       372   H   CCH   CHF—Me   CCH       373   H   CCH   i-Pr   CCH       374   H   CCH   F   CCH       375   H   CCH   Cl   CCH       376   H   CCH   Br   CCH       377   H   CCH   I   CCH       378   H   CCH   NO 2     CCH       379   H   CCH   CN   CCH       380   H   CCMe   Me   H       381   H   CCMe   Et   H       382   H   CCMe   CHF—Me   H       383   H   CCMe   i-Pr   H       384   H   CCMe   F   H       385   H   CCMe   Cl   H       386   H   CCMe   Br   H       387   H   CCMe   I   H       388   H   CCMe   NO 2     H       389   H   CCMe   CN   H       390   H   CCMe   H   Me       391   H   CCMe   H   Et       392   H   CCMe   H   CHF—Me       393   H   CCMe   H   i-Pr       394   H   CCMe   H   F       395   H   CCMe   H   Cl       396   H   CCMe   H   Br       397   H   CCMe   H   I       398   H   CCMe   H   NO 2         399   H   CCMe   H   CN       400   Me   H   H   CCMe       401   Et   H   H   CCMe       402   CHF—Me   H   H   CCMe       403   i-Pr   H   H   CCMe       404   F   H   H   CCMe       405   Cl   H   H   CCMe       406   Br   H   H   CCMe       407   I   H   H   CCMe       408   NO 2     H   H   CCMe       409   CN   H   H   CCMe       410   H   Me   CCMe   H       411   H   Et   CCMe   H       412   H   CHF—Me   CCMe   H       413   H   i-Pr   CCMe   H       414   H   F   CCMe   H       415   H   Cl   CCMe   H       416   H   Br   CCMe   H       417   H   I   CCMe   H       418   H   NO 2     CCMe   H       419   H   CN   CCMe   H       420   H   Me   CCMe   F       421   H   Me   CCMe   Cl       422   H   Me   CCMe   Br       423   H   Me   CCMe   I       424   H   Me   CCMe   Me       425   H   Et   CCMe   Et       426   H   CHF—Me   CCMe   CHF—Me       427   H   i-Pr   CCMe   i-Pr       428   H   F   CCMe   F       429   H   Cl   CCMe   Cl       430   H   Br   CCMe   Br       431   H   I   CCMe   I       432   H   NO 2     CCMe   NO 2         433   H   CN   CCMe   CN       434   H   CCMe   CCMe   H       435   H   CCMe   CCMe   Me       436   H   CCMe   CCMe   Et       437   H   CCMe   CCMe   CHF—Me       438   H   CCMe   CCMe   i-Pr       439   H   CCMe   CCMe   F       440   H   CCMe   CCMe   Cl       441   H   CCMe   CCMe   Br       442   H   CCMe   CCMe   I       443   H   CCMe   CCMe   NO 2         444   H   CCMe   CCMe   CN       445   H   CCMe   H   CCMe       446   H   CCMe   Me   CCMe       447   H   CCMe   Et   CCMe       448   H   CCMe   CHF—Me   CCMe       440   H   CCMe   i-Pr   CCMe       460   H   CCMe   F   CCMe       451   H   CCMe   Cl   CCMe       452   H   CCMe   Br   CCMe       453   H   CCMe   I   CCMe       454   H   CCMe   NO 2     CCMe       455   H   CCMe   CN   CCMe       456   H   CH 2 CCH   Me   H       457   H   CH 2 CCH   Et   H       458   H   CH 2 CCH   CHF—Me   H       459   H   CH 2 CCH   i-Pr   H       460   H   CH 2 CCH   F   H       461   H   CH 2 CCH   Cl   H       462   H   CH 2 CCH   Br   H       463   H   CH 2 CCH   I   H       464   H   CH 2 CCH   NO 2     H       465   H   CH 2 CCH   CN   H       466   H   CH 2 CCH   H   Me       467   H   CH 2 CCH   H   Et       468   H   CH 2 CCH   H   CHF—Me       469   H   CH 2 CCH   H   i-Pr       470   H   CH 2 CCH   H   F       471   H   CH 2 CCH   H   Cl       472   H   CH 2 CCH   H   Br       473   H   CH 2 CCH   H   I       474   H   CH 2 CCH   H   NO 2         475   H   CH 2 CCH   H   CN       476   Me   H   H   CH 2 CCH       477   Et   H   H   CH 2 CCH       478   CHF—Me   H   H   CH 2 CCH       479   i-Pr   H   H   CH 2 CCH       480   F   H   H   CH 2 CCH       481   Cl   H   H   CH 2 CCH       482   Br   H   H   CH 2 CCH       483   I   H   H   CH 2 CCH       484   NO 2     H   H   CH 2 CCH       485   CN   H   H   CH 2 CCH       486   H   Me   CH 2 CCH   H       487   H   Et   CH 2 CCH   H       488   H   CHF—Me   CH 2 CCH   H       489   H   i-Pr   CH 2 CCH   H       490   H   F   CH 2 CCH   H       491   H   Cl   CH 2 CCH   H       492   H   Br   CH 2 CCH   H       493   H   I   CH 2 CCH   H       494   H   NO 2     CH 2 CCH   H       495   H   CN   CH 2 CCH   H       496   H   Me   CH 2 CCH   F       497   H   Me   CH 2 CCH   Cl       498   H   Me   CH 2 CCH   Br       499   H   Me   CH 2 CCH   I       500   H   Me   CH 2 CCH   Me       501   H   Et   CH 2 CCH   Et       502   H   CHF—Me   CH 2 CCH   CHF—Me       503   H   i-Pr   CH 2 CCH   i-Pr       504   H   F   CH 2 CCH   F       505   H   Cl   CH 2 CCH   Cl       506   H   Br   CH 2 CCH   Br       507   H   I   CH 2 CCH   I       508   H   NO 2     CH 2 CCH   NO 2         509   H   CN   CH 2 CCH   CN       510   H   CH 2 CCH   CH 2 CCH   H       511   H   CH 2 CCH   CH 2 CCH   Me       512   H   CH 2 CCH   CH 2 CCH   Et       513   H   CH 2 CCH   CH 2 CCH   CHF—Me       514   H   CH 2 CCH   CH 2 CCH   i-Pr       515   H   CH 2 CCH   CH 2 CCH   F       516   H   CH 2 CCH   CH 2 CCH   Cl       517   H   CH 2 CCH   CH 2 CCH   Br       518   H   CH 2 CCH   CH 2 CCH   I       519   H   CH 2 CCH   CH 2 CCH   NO 2         520   H   CH 2 CCH   CH 2 CCH   CN       521   H   CH 2 CCH   H   CH 2 CCH       522   H   CH 2 CCH   Me   CH 2 CCH       523   H   CH 2 CCH   Et   CH 2 CCH       524   H   CH 2 CCH   CHF—Me   CH 2 CCH       525   H   CH 2 CCH   i-Pr   CH 2 CCH       526   H   CH 2 CCH   F   CH 2 CCH       527   H   CH 2 CCH   Cl   CH 2 CCH       528   H   CH 2 CCH   Br   CH 2 CCH       529   H   CH 2 CCH   I   CH 2 CCH       530   H   CH 2 CCH   NO 2     CH 2 CCH       531   H   CH 2 CCH   CN   CH 2 CCH       532   H   CH 2 CCMe   Me   H       533   H   CH 2 CCMe   Et   H       534   H   CH 2 CCMe   CHF—Me   H       535   H   CH 2 CCMe   i-Pr   H       538   H   CH 2 CCMe   F   H       537   H   CH 2 CCMe   Cl   H       538   H   CH 2 CCMe   Br   H       539   H   CH 2 CCMe   I   H       540   H   CH 2 CCMe   NO 2     H       541   H   CH 2 CCMe   CN   H       542   H   CH 2 CCMe   H   Me       543   H   CH 2 CCMe   H   Et       544   H   CH 2 CCMe   H   CHF—Me       545   H   CH 2 CCMe   H   i-Pr       546   H   CH 2 CCMe   H   F       547   H   CH 2 CCMe   H   Cl       548   H   CH 2 CCMe   H   Br       549   H   CH 2 CCMe   H   I       550   H   CH 2 CCMe   H   NO 2         551   H   CH 2 CCMe   H   CN       552   Me   H   H   CH 2 CCMe       553   Et   H   H   CH 2 CCMe       554   CHF—Me   H   H   CH 2 CCMe       555   i-Pr   H   H   CH 2 CCMe       556   F   H   H   CH 2 CCMe       557   Cl   H   H   CH 2 CCMe       558   Br   H   H   CH 2 CCMe       559   I   H   H   CH 2 CCMe       560   NO 2     H   H   CH 2 CCMe       561   CN   H   H   CH 2 CCMe       562   H   Me   CH 2 CCMe   H       563   H   Et   CH 2 CCMe   H       564   H   CHF—Me   CH 2 CCMe   H       565   H   i-Pr   CH 2 CCMe   H       566   H   F   CH 2 CCMe   H       567   H   Cl   CH 2 CCMe   H       568   H   Br   CH 2 CCMe   H       569   H   I   CH 2 CCMe   H       570   H   NO 2     CH 2 CCMe   H       571   H   CN   CH 2 CCMe   H       572   H   Me   CH 2 CCMe   F       573   H   Me   CH 2 CCMe   Cl       574   H   Me   CH 2 CCMe   Br       575   H   Me   CH 2 CCMe   I       576   H   Me   CH 2 CCMe   Me       577   H   Et   CH 2 CCMe   Et       578   H   CHF—Me   CH 2 CCMe   CHF—Me       579   H   i-Pr   CH 2 CCMe   i-Pr       580   H   F   CH 2 CCMe   F       581   H   Cl   CH 2 CCMe   Cl       582   H   Br   CH 2 CCMe   Br       583   H   I   CH 2 CCMe   I       584   H   NO 2     CH 2 CCMe   NO 2         585   H   CN   CH 2 CCMe   CN       586   H   CH 2 CCMe   CH 2 CCMe   H       587   H   CH 2 CCMe   CH 2 CCMe   Me       588   H   CH 2 CCMe   CH 2 CCMe   Et       589   H   CH 2 CCMe   CH 2 CCMe   CHF—Me       590   H   CH 2 CCMe   CH 2 CCMe   i-Pr       591   H   CH 2 CCMe   CH 2 CCMe   F       592   H   CH 2 CCMe   CH 2 CCMe   Cl       593   H   CH 2 CCMe   CH 2 CCMe   Br       594   H   CH 2 CCMe   CH 2 CCMe   I       595   H   CH 2 CCMe   CH 2 CCMe   NO 2         596   H   CH 2 CCMe   CH 2 CCMe   CN       597   H   CH 2 CCMe   H   CH 2 CCMe       598   H   CH 2 CCMe   Me   CH 2 CCMe       599   H   CH 2 CCMe   Et   CH 2 CCMe       600   H   CH 2 CCMe   CHF—Me   CH 2 CCMe       601   H   CH 2 CCMe   i-Pr   CH 2 CCMe       602   H   CH 2 CCMe   F   CH 2 CCMe       603   H   CH 2 CCMe   Cl   CH 2 CCMe       604   H   CH 2 CCMe   Br   CH 2 CCMe       605   H   CH 2 CCMe   I   CH 2 CCMe       606   H   CH 2 CCMe   NO 2     CH 2 CCMe       607   H   CH 2 CCMe   CN   CH 2 CCMe       608   H   CH═C═CH 2     Me   H       609   H   CH═C═CH 2     Et   H       610   H   CH═C═CH 2     CHF—Me   H       611   H   CH═C═CH 2     i-Pr   H       612   H   CH═C═CH 2     F   H       613   H   CH═C═CH 2     Cl   H       614   H   CH═C═CH 2     Br   H       615   H   CH═C═CH 2     I   H       616   H   CH═C═CH 2     NO 2     H       617   H   CH═C═CH 2     CN   H       618   H   CH═C═CH 2     H   Me       619   H   CH═C═CH 2     H   Et       620   H   CH═C═CH 2     H   CHF—Me       621   H   CH═C═CH 2     H   i-Pr       622   H   CH═C═CH 2     H   F       623   H   CH═C═CH 2     H   Cl       624   H   CH═C═CH 2     H   Br       625   H   CH═C═CH 2     H   I       626   H   CH═C═CH 2     H   NO 2         627   H   CH═C═CH 2     H   CN       628   Me   H   H   CH═C═CH 2         629   Et   H   H   CH═C═CH 2         630   CHF—Me   H   H   CH═C═CH 2         631   i-Pr   H   H   CH═C═CH 2         632   F   H   H   CH═C═CH 2         633   Cl   H   H   CH═C═CH 2         634   Br   H   H   CH═C═CH 2         635   I   H   H   CH═C═CH 2         636   NO 2     H   H   CH═C═CH 2         637   CN   H   H   CH═C═CH 2         638   H   Me   CH═C═CH 2     H       639   H   Et   CH═C═CH 2     H       640   H   CHF—Me   CH═C═CH 2     H       641   H   i-Pr   CH═C═CH 2     H       642   H   F   CH═C═CH 2     H       643   H   Cl   CH═C═CH 2     H       644   H   Br   CH═C═CH 2     H       645   H   I   CH═C═CH 2     H       646   H   NO 2     CH═C═CH 2     H       647   H   CN   CH═C═CH 2     H       648   H   Me   CH═CCH 2     F       649   H   Me   CH═C═CH 2     Cl       650   H   Me   CH═C═CH 2     Br       651   H   Me   CH═C═CH 2     I       652   H   Me   CH═C═CH 2     Me       653   H   Et   CH═C═CH 2     Et       654   H   CHF—Me   CH═C═CH 2     CHF—Me       655   H   i-Pr   CH═C═CH 2     i-Pr       656   H   F   CH═C═CH 2     F       657   H   Cl   CH═C═CH 2     Cl       658   H   Br   CH═C═CH 2     Br       659   H   I   CH═C═CH 2     I       660   H   NO 2     CH═C═CH 2     NO 2         661   H   CN   CH═C═CH 2     CN       662   H   CH═C═CH 2     CH═C═CH 2     H       663   H   CH═C═CH 2     CH═C═CH 2     Me       664   H   CH═C═CH 2     CH═C═CH 2     Et       665   H   CH═C═CH 2     CH═C═CH 2     CHF—Me       666   H   CH═C═CH 2     CH═C═CH 2     i-Pr       667   H   CH═C═CH 2     CH═C═CH 2     F       668   H   CH═C═CH 2     CH═C═CH 2     Cl       669   H   CH═C═CH 2     CH═C═CH 2     Br       670   H   CH═C═CH 2     CH═C═CH 2     I       671   H   CH═C═CH 2     CH═C═CH 2     NO 2         672   H   CH═C═CH 2     CH═C═CH 2     CN       673   H   CH═C═CH 2     H   CH═C═CH 2         674   H   CH═C═CH 2     Me   CH═C═CH 2         675   H   CH═C═CH 2     Et   CH═C═CH 2         676   H   CH═C═CH 2     CHF—Me   CH═C═CH 2         677   H   CH═C═CH 2     i-Pr   CH═C═CH 2         678   H   CH═C═CH 2     F   CH═C═CH 2         679   H   CH═C═CH 2     Cl   CH═C═CH 2         680   H   CH═C═CH 2     Br   CH═C═CH 2         681   H   CH═C═CH 2     I   CH═C═CH 2         682   H   CH═C═CH 2     NO 2     CH═C═CH 2         683   H   CH═C═CH 2     CN   CH═C═CH 2         684   H   CC-Bu   Me   H       685   H   CC-Bu   Et   H       686   H   CC-Bu   CHF—Me   H       687   H   CC-Bu   i-Pr   H       688   H   CC-Bu   F   H       689   H   CC-Bu   Cl   H       690   H   CC-Bu   Br   H       691   H   CC-BU   I   H       692   H   CC-Bu   NO 2     H       693   H   CC-Bu   CN   H       694   H   CC-Bu   H   Me       695   H   CC-Bu   H   Et       696   H   CC-Bu   H   CHF—Me       697   H   CC-Bu   H   i-Pr       698   H   CC-Bu   H   F       699   H   CC-Bu   H   Cl       700   H   CC-Bu   H   Br       701   H   CC-Bu   H   I       702   H   CC-Bu   H   NO 2         703   H   CC-Bu   H   CN       704   Me   H   H   CC-Bu       705   Et   H   H   CC-Bu       706   CHF—Me   H   H   CC-Bu       707   i-Pr   H   H   CC-Bu       708   F   H   H   CC-Bu       709   Cl   H   H   CC-Bu       710   Br   H   H   CC-Bu       711   I   H   H   CC-Bu       712   NO 2     H   H   CC-Bu       713   CN   H   H   CC-Bu       714   H   Me   CC-Bu   H       715   H   Et   CC-Bu   H       716   H   CHF—Me   CC-Bu   H       717   H   i-Pr   CC-Bu   H       718   H   F   CC-Bu   H       719   H   Cl   CC-Bu   H       720   H   Br   CC-Bu   H       721   H   I   CC-Bu   H       722   H   NO 2     CC-Bu   H       723   H   CN   CC-Bu   H       724   H   Me   CC-Bu   F       725   H   Me   CC-Bu   Cl       726   H   Me   CC-Bu   Br       727   H   Me   CC-Bu   I       728   H   Me   CC-Bu   Me       729   H   Et   CC-Bu   Et       730   H   CHF—Me   CC-Bu   CHF—Me       731   H   i-Pr   CC-Bu   i-Pr       732   H   F   CC-Bu   F       733   H   Cl   CC-Bu   Cl       734   H   Br   CC-Bu   Br       735   H   I   CC-Bu   I       736   H   NO 2     CC-Bu   NO 2         737   H   CN   CC-Bu   CN       738   H   CC-Bu   CC-Bu   H       739   H   CC-Bu   CC-Bu   Me       740   H   CC-Bu   CC-Bu   Et       741   H   CC-Bu   CC-Bu   CHF—Me       742   H   CC-Bu   CC-Bu   i-Pr       743   H   CC-Bu   CC-Bu   F       744   H   CC-Bu   CC-Bu   Cl       745   H   CC-Bu   CC-Bu   Br       746   H   CC-Bu   CC-Bu   I       747   H   CC-Bu   CC-Bu   NO 2         748   H   CC-Bu   CC-Bu   CN       749   H   CC-Bu   H   CC-Bu       750   H   CC-Bu   Me   CC-Bu       751   H   CC-Bu   Et   CC-Bu       752   H   CC-Bu   CHF—Me   CC-Bu       753   H   CC-Bu   i-Pr   CC-Bu       754   H   CC-Bu   F   CC-Bu       755   H   CC-Bu   Cl   CC-Bu       756   H   CC-Bu   Br   CC-Bu       757   H   CC-Bu   I   CC-Bu       758   H   CC-Bu   NO 2     CC-Bu       759   H   CC-Bu   CN   CC-Bu       760   H   CC—CHF—Me   Me   H       761   H   CC—CHF—Me   Et   H       762   H   CC—CHF—Me   CHF—Me   H       763   H   CC—CHF—Me   i-Pr   H       764   H   CC—CHF—Me   F   H       765   H   CC—CHF—Me   Cl   H       766   H   CC—CHF—Me   Br   H       767   H   CC—CHF—Me   I   H       768   H   CC—CHF—Me   NO 2     H       769   H   CC—CHF—Me   CN   H       770   H   CC—CHF—Me   H   Me       771   H   CC—CHF—Me   H   Et       772   H   CC—CHF—Me   H   CHF—Me       773   H   CC—CHF—Me   H   i-Pr       774   H   CC—CHF—Me   H   F       775   H   CC—CHF—Me   H   Cl       776   H   CC—CHF—Me   H   Br       777   H   CC—CHF—Me   H   I       778   H   CC—CHF—Me   H   NO 2         779   H   CC—CHF—Me   H   CN       780   Me   H   H   CC—CHF—Me       781   Et   H   H   CC—CHF—Me       782   CHF—Me   H   H   CC—CHF—Me       783   i-Pr   H   H   CC—CHF—Me       784   F   H   H   CC—CHF—Me       785   Cl   H   H   CC—CHF—Me       786   Br   H   H   CC—CHF—Me       787   I   H   H   CC—CHF—Me       788   NO 2     H   H   CC—CHF—Me       789   CN   H   H   CC—CHF—Me       790   H   Me   CC—CHF—Me   H       791   H   Et   CC—CHF—Me   H       792   H   CHF—Me   CC—CHF—Me   H       793   H   i-Pr   CC—CHF—Me   H       794   H   F   CC—CHF—Me   H       795   H   Cl   CC—CHF—Me   H       796   H   Br   CC—CHF—Me   H       797   H   I   CC—CHF—Me   H       798   H   NO 2     CC—CHF—Me   H       799   H   CN   CC—CHF—Me   H       800   H   Me   CC—CHF—Me   F       801   H   Me   CC—CHF—Me   Cl       802   H   Me   CC—CHF—Me   Br       803   H   Me   CC—CHF—Me   I       804   H   Me   CC—CHF—Me   Me       805   H   Et   CC—CHF—Me   Et       806   H   CHF—Me   CC—CHF—Me   CHF—Me       807   H   i-Pr   CC—CHF—Me   i-Pr       808   H   F   CC—CHF—Me   F       809   H   Cl   CC—CHF—Me   Cl       810   H   Br   CC—CHF—Me   Br       811   H   I   CC—CHF—Me   I       812   H   NO 2     CC—CHF—Me   NO 2         813   H   CN   CC—CHF—Me   CN       814   H   CC—CHF—Me   CC—CHF—Me   H       815   H   CC—CHF—Me   CC—CHF—Me   Me       816   H   CC—CHF—Me   CC—CHF—Me   Et       817   H   CC—CHF—Me   CC—CHF—Me   CHF—Me       818   H   CC—CHF—Me   CC—CHF—Me   i-Pr       819   H   CC—CHF—Me   CC—CHF—Me   F       820   H   CC—CHF—Me   CC—CHF—Me   Cl       821   H   CC—CHF—Me   CC—CHF—Me   Br       822   H   CC—CHF—Me   CC—CHF—Me   I       823   H   CC—CHF—Me   CC—CHF—Me   NO 2         824   H   CC—CHF—Me   CC—CHF—Me   CN       825   H   CC—CHF—Me   H   CC—CHF—Me       826   H   CC—CHF—Me   Me   CC—CHF—Me       827   H   CC—CHF—Me   Et   CC—CHF—Me       828   H   CC—CHF—Me   CHF—Me   CC—CHF—Me       829   H   CC—CHF—Me   i-Pr   CC—CHF—Me       830   H   CC—CHF—Me   F   CC—CHF—Me       831   H   CC—CHF—Me   Cl   CC—CHF—Me       832   H   CC—CHF—Me   Br   CC—CHF—Me       833   H   CC—CHF—Me   I   CC—CHF—Me       834   H   CC—CHF—Me   NO 2     CC—CHF—Me       835   H   CC—CHF—Me   CN   CC—CHF—Me       836   H   CC—CH(OH)—Me   Me   H       837   H   CC—CH(OH)—Me   Et   H       838   H   CC—CH(OH)—Me   CHF—Me   H       839   H   CC—CH(OH)—Me   i-Pr   H       840   H   CC—CH(OH)—Me   F   H       841   H   CC—CH(OH)—Me   Cl   H       842   H   CC—CH(OH)—Me   Br   H       843   H   CC—CH(OH)—Me   I   H       844   H   CC—CH(OH)—Me   NO 2     H       845   H   CC—CH(OH)—Me   CN   H       846   H   CC—CH(OH)—Me   H   Me       847   H   CC—CH(OH)—Me   H   Et       848   H   CC—CH(OH)—Me   H   CHF—Me       849   H   CC—CH(OH)—Me   H   i-Pr       850   H   CC—CH(OH)—Me   H   F       851   H   CC—CH(OH)—Me   H   Cl       852   H   CC—CH(OH)—Me   H   Br       853   H   CC—CH(OH)—Me   H   I       854   H   CC—CH(OH)—Me   H   NO 2         855   H   CC—CH(OH)—Me   H   CN       856   Me   H   H   CC—CH(OH)—Me       857   Et   H   H   CC—CH(OH)—Me       858   CHF—Me   H   H   CC—CH(OH)—Me       859   i-Pr   H   H   CC—CH(OH)—Me       860   F   H   H   CC—CH(OH)—Me       861   Cl   H   H   CC—CH(OH)—Me       862   Br   H   H   CC—CH(OH)—Me       863   I   H   H   CC—CH(OH)—Me       864   NO 2     H   H   CC—CH(OH)—Me       865   CN   H   H   CC—CH(OH)—Me       866   H   Me   CC—CH(OH)—Me   H       867   H   Et   CC—CH(OH)—Me   H       868   H   CHF—Me   CC—CH(OH)—Me   H       869   H   i-Pr   CC—CH(OH)—Me   H       870   H   F   CC—CH(OH)—Me   H       871   H   Cl   CC—CH(OH)—Me   H       872   H   Br   CC—CH(OH)—Me   H       873   H   I   CC—CH(OH)—Me   H       874   H   NO 2     CC—CH(OH)—Me   H       875   H   CN   CC—CH(OH)—Me   H       876   H   Me   CC—CH(OH)—Me   F       877   H   Me   CC—CH(OH)—Me   Cl       878   H   Me   CC—CH(OH)—Me   Br       879   H   Me   CC—CH(OH)—Me   I       880   H   Me   CC—CH(OH)—Me   Me       881   H   Et   CC—CH(OH)—Me   Et       882   H   CHF—Me   CC—CH(OH)—Me   CHF—Me       883   H   i-Pr   CC—CH(OH)—Me   i-Pr       884   H   F   CC—CH(OH)—Me   F       885   H   Cl   CC—CH(OH)—Me   Cl       886   H   Br   CC—CH(OH)—Me   Br       887   H   I   CC—CH(OH)—Me   I       888   H   NO 2     CC—CH(OH)—Me   NO 2         889   H   CN   CC—CH(OH)—Me   CN       890   H   CC—CH(OH)—Me   CC—CH(OH)—Me   H       891   H   CC—CH(OH)—Me   CC—CH(OH)—Me   Me       892   H   CC—CH(OH)—Me   CC—CH(OH)—Me   Et       893   H   CC—CH(OH)—Me   CC—CH(OH)—Me   CHF—Me       894   H   CC—CH(OH)—Me   CC—CH(OH)—Me   i-Pr       895   H   CC—CH(OH)—Me   CC—CH(OH)—Me   F       896   H   CC—CH(OH)—Me   CC—CH(OH)—Me   Cl       897   H   CC—CH(OH)—Me   CC—CH(OH)—Me   Br       898   H   CC—CH(OH)—Me   CC—CH(OH)—Me   I       899   H   CC—CH(OH)—Me   CC—CH(OH)—Me   NO 2         900   H   CC—CH(OH)—Me   CC—CH(OH)—Me   CN       901   H   CC—CH(OH)—Me   H   CC—CH(OH)—Me       902   H   CC—CH(OH)—Me   Me   CC—CH(OH)—Me       903   H   CC—CH(OH)—Me   Et   CC—CH(OH)—Me       904   H   CC—CH(OH)—Me   CHF—Me   CC—CH(OH)—Me       905   H   CC—CH(OH)—Me   i-Pr   CC—CH(OH)—Me       906   H   CC—CH(OH)—Me   F   CC—CH(OH)—Me       907   H   CC—CH(OH)—Me   Cl   CC—CH(OH)—Me       908   H   CC—CH(OH)—Me   Br   CC—CH(OH)—Me       909   H   CC—CH(OH)—Me   I   CC—CH(OH)—Me       910   H   CC—CH(OH)—Me   NO 2     CC—CH(OH)—Me       911   H   CC—CH(OH)—Me   CN   CC—CH(OH)—Me       912   H   c-Pr   Me   H       913   H   c-Pr   Et   H       914   H   c-Pr   CHF—Me   H       915   H   c-Pr   i-Pr   H       916   H   c-Pr   F   H       917   H   c-Pr   Cl   H       918   H   c-Pr   Br   H       919   H   c-Pr   I   H       920   H   c-Pr   NO 2     H       921   H   c-Pr   CN   H       922   H   c-Pr   H   Me       923   H   c-Pr   H   Et       924   H   c-Pr   H   CHF—Me       925   H   c-Pr   H   i-Pr       926   H   c-Pr   H   F       927   H   c-Pr   H   Cl       928   H   c-Pr   H   Br       929   H   c-Pr   H   I       930   H   c-Pr   H   NO 2         931   H   c-Pr   H   CN       932   Me   H   H   c-Pr       933   Et   H   H   c-Pr       934   CHF—Me   H   H   c-Pr       935   i-Pr   H   H   c-Pr       936   F   H   H   c-Pr       937   Cl   H   H   c-Pr       938   Br   H   H   c-Pr       939   I   H   H   c-Pr       940   NO 2     H   H   c-Pr       941   CN   H   H   c-Pr       942   H   Me   c-Pr   H       943   H   Et   c-Pr   H       944   H   CHF—Me   c-Pr   H       945   H   i-Pr   c-Pr   H       946   H   F   c-Pr   H       947   H   Cl   c-Pr   H       948   H   Br   c-Pr   H       949   H   I   c-Pr   H       950   H   NO 2     c-Pr   H       951   H   CN   c-Pr   H       952   H   Me   c-Pr   F       953   H   Me   c-Pr   Cl       954   H   Me   c-Pr   Br       955   H   Me   c-Pr   I       956   H   Me   c-Pr   Me       957   H   Et   c-Pr   Et       958   H   CHF—Me   c-Pr   CHF—Me       959   H   i-Pr   c-Pr   i-Pr       960   H   F   c-Pr   F       961   H   Cl   c-Pr   Cl       962   H   Br   c-Pr   Br       963   H   I   c-Pr   I       964   H   NO 2     c-Pr   NO 2         965   H   CN   c-Pr   CN       966   H   c-Pr   c-Pr   H       967   H   c-Pr   c-Pr   Me       968   H   c-Pr   c-Pr   Et       969   H   c-Pr   c-Pr   CHF—Me       970   H   c-Pr   c-Pr   i-Pr       971   H   c-Pr   c-Pr   F       972   H   c-Pr   c-Pr   Cl       973   H   c-Pr   c-Pr   Br       974   H   c-Pr   c-Pr   I       975   H   c-Pr   c-Pr   NO 2         976   H   c-Pr   c-Pr   CN       977   H   c-Pr   H   c-Pr       978   H   c-Pr   Me   c-Pr       979   H   c-Pr   Et   c-Pr       980   H   c-Pr   CHF—Me   c-Pr       981   H   c-Pr   i-Pr   c-Pr       982   H   c-Pr   F   c-Pr       983   H   c-Pr   Cl   c-Pr       984   H   c-Pr   Br   c-Pr       985   H   c-Pr   I   c-Pr       986   H   c-Pr   NO 2     c-Pr       987   H   c-Pr   CN   c-Pr       988   H   CH(CF 2 —CH 2 )   Me   H       989   H   CH(CF 2 —CH 2 )   Et   H       990   H   CH(CF 2 —CH 2 )   CHF—Me   H       991   H   CH(CF 2 —CH 2 )   i-Pr   H       992   H   CH(CF 2 —CH 2 )   F   H       993   H   CH(CF 2 —CH 2 )   Cl   H       994   H   CH(CF 2 —CH 2 )   Br   H       995   H   CH(CF 2 —CH 2 )   I   H       996   H   CH(CF 2 —CH 2 )   NO 2     H       997   H   CH(CF 2 —CH 2 )   CN   H       998   H   CH(CF 2 —CH 2 )   H   Me       999   H   CH(CF 2 —CH 2 )   H   Et       1000   H   CH(CF 2 —CH 2 )   H   CHF—Me       1001   H   CH(CF 2 —CH 2 )   H   i-Pr       1002   H   CH(CF 2 —CH 2 )   H   F       1003   H   CH(CF 2 —CH 2 )   H   Cl       1004   H   CH(CF 2 —CH 2 )   H   Br       1005   H   CH(CF 2 —CH 2 )   H   I       1006   H   CH(CF 2 —CH 2 )   H   NO 2         1007   H   CH(CF 2 —CH 2 )   H   CN       1008   Me   H   H   CH(CF 2 —CH 2 )       1009   Et   H   H   CH(CF 2 —CH 2 )       1010   CHF—Me   H   H   CH(CF 2 —CH 2 )       1011   i-Pr   H   H   CH(CF 2 —CH 2 )       1012   F   H   H   CH(CF 2 —CH 2 )       1013   Cl   H   H   CH(CF 2 —CH 2 )       1014   Br   H   H   CH(CF 2 —CH 2 )       1015   I   H   H   CH(CF 2 —CH 2 )       1016   NO 2     H   H   CH(CF 2 —CH 2 )       1017   CN   H   H   CH(CF 2 —CH 2 )       1018   H   Me   CH(CF 2 —CH 2 )   H       1019   H   Et   CH(CF 2 —CH 2 )   H       1020   H   CHF—Me   CH(CF 2 —CH 2 )   H       1021   H   i-Pr   CH(CF 2 —CH 2 )   H       1022   H   F   CH(CF 2 —CH 2 )   H       1023   H   Cl   CH(CF 2 —CH 2 )   H       1024   H   Br   CH(CF 2 —CH 2 )   H       1025   H   I   CH(CF 2 —CH 2 )   H       1026   H   NO 2     CH(CF 2 —CH 2 )   H       1027   H   CN   CH(CF 2 —CH 2 )   H       1028   H   Me   CH(CF 2 —CH 2 )   F       1029   H   Me   CH(CF 2 —CH 2 )   Cl       1030   H   Me   CH(CF 2 —CH 2 )   Br       1031   H   Me   CH(CF 2 —CH 2 )   I       1032   H   Me   CH(CF 2 —CH 2 )   Me       1033   H   Et   CH(CF 2 —CH 2 )   Et       1034   H   CHF—Me   CH(CF 2 —CH 2 )   CHF—Me       1035   H   i-Pr   CH(CF 2 —CH 2 )   i-Pr       1036   H   F   CH(CF 2 —CH 2 )   F       1037   H   Cl   CH(CF 2 —CH 2 )   Cl       1038   H   Br   CH(CF 2 —CH 2 )   Br       1039   H   I   CH(CF 2 —CH 2 )   I       1040   H   NO 2     CH(CF 2 —CH 2 )   NO 2         1041   H   CN   CH(CF 2 —CH 2 )   CN       1042   H   CH(CF 2 —CH 2 )   CH(CF 2 —CH 2 )   H       1043   H   CH(CF 2 —CH 2 )   CH(CF 2 —CH 2 )   Me       1044   H   CH(CF 2 —CH 2 )   CH(CF 2 —CH 2 )   Et       1045   H   CH(CF 2 —CH 2 )   CH(CF 2 —CH 2 )   CHF—Me       1046   H   CH(CF 2 —CH 2 )   CH(CF 2 —CH 2 )   i-Pr       1047   H   CH(CF 2 —CH 2 )   CH(CF 2 —CH 2 )   F       1048   H   CH(CF 2 —CH 2 )   CH(CF 2 —CH 2 )   Cl       1049   H   CH(CF 2 —CH 2 )   CH(CF 2 —CH 2 )   Br       1050   H   CH(CF 2 —CH 2 )   CH(CF 2 —CH 2 )   I       1051   H   CH(CF 2 —CH 2 )   CH(CF 2 —CH 2 )   NO 2         1052   H   CH(CF 2 —CH 2 )   CH(CF 2 —CH 2 )   CN       1053   H   CH(CF 2 —CH 2 )   H   CH(CF 2 —CH 2 )       1054   H   CH(CF 2 —CH 2 )   Me   CH(CF 2 —CH 2 )       1055   H   CH(CF 2 —CH 2 )   Et   CH(CF 2 —CH 2 )       1056   H   CH(CF 2 —CH 2 )   CHF—Me   CH(CF 2 —CH 2 )       1057   H   CH(CF 2 —CH 2 )   i-Pr   CH(CF 2 —CH 2 )       1058   H   CH(CF 2 —CH 2 )   F   CH(CF 2 —CH 2 )       1059   H   CH(CF 2 —CH 2 )   Cl   CH(CF 2 —CH 2 )       1060   H   CH(CF 2 —CH 2 )   Br   CH(CF 2 —CH 2 )       1061   H   CH(CF 2 —CH 2 )   I   CH(CF 2 —CH 2 )       1062   H   CH(CF 2 —CH 2 )   NO 2     CH(CF 2 —CH 2 )       1063   H   CH(CF 2 —CH 2 )   CN   CH(CF 2 —CH 2 )       1064   H   CF(CF 2 —CF 2 )   Me   H       1065   H   CF(CF 2 —CF 2 )   Et   H       1066   H   CF(CF 2 —CF 2 )   CHF—Me   H       1067   H   CF(CF 2 —CF 2 )   i-Pr   H       1068   H   CF(CF 2 —CF 2 )   F   H       1069   H   CF(CF 2 —CF 2 )   Cl   H       1070   H   CF(CF 2 —CF 2 )   Br   H       1071   H   CF(CF 2 —CF 2 )   I   H       1072   H   CF(CF 2 —CF 2 )   NO 2     H       1073   H   CF(CF 2 —CF 2 )   CN   H       1074   H   CF(CF 2 —CF 2 )   H   Me       1075   H   CF(CF 2 —CF 2 )   H   Et       1076   H   CF(CF 2 —CF 2 )   H   CHF—Me       1077   H   CF(CF 2 —CF 2 )   H   i-Pr       1078   H   CF(CF 2 —CF 2 )   H   F       1079   H   CF(CF 2 —CF 2 )   H   Cl       1080   H   CF(CF 2 —CF 2 )   H   Br       1081   H   CF(CF 2 —CF 2 )   H   I       1082   H   CF(CF 2 —CF 2 )   H   NO 2         1083   H   CF(CF 2 —CF 2 )   H   CN       1084   Me   H   H   CF(CF 2 —CF 2 )       1085   Et   H   H   CF(CF 2 —CF 2 )       1086   CHF—Me   H   H   CF(CF 2 —CF 2 )       1087   i-Pr   H   H   CF(CF 2 —CF 2 )       1088   F   H   H   CF(CF 2 —CF 2 )       1089   Cl   H   H   CF(CF 2 —CF 2 )       1090   Br   H   H   CF(CF 2 —CF 2 )       1091   I   H   H   CF(CF 2 —CF 2 )       1092   NO 2     H   H   CF(CF 2 —CF 2 )       1093   CN   H   H   CF(CF 2 —CF 2 )       1094   H   Me   CF(CF 2 —CF 2 )   H       1095   H   Et   CF(CF 2 —CF 2 )   H       1096   H   CHF—Me   CF(CF 2 —CF 2 )   H       1097   H   i-Pr   CF(CF 2 —CF 2 )   H       1098   H   F   CF(CF 2 —CF 2 )   H       1099   H   Cl   CF(CF 2 —CF 2 )   H       1100   H   Br   CF(CF 2 —CF 2 )   H       1101   H   I   CF(CF 2 —CF 2 )   H       1102   H   NO 2     CF(CF 2 —CF 2 )   H       1103   H   CN   CF(CF 2 —CF 2 )   H       1104   H   Me   CF(CF 2 —CF 2 )   F       1105   H   Me   CF(CF 2 —CF 2 )   Cl       1106   H   Me   CF(CF 2 —CF 2 )   Br       1107   H   Me   CF(CF 2 —CF 2 )   I       1108   H   Me   CF(CF 2 —CF 2 )   Me       1109   H   Et   CF(CF 2 —CF 2 )   Et       1110   H   CHF—Me   CF(CF 2 —CF 2 )   CHF—Me       1111   H   i-Pr   CF(CF 2 —CF 2 )   i-Pr       1112   H   F   CF(CF 2 —CF 2 )   F       1113   H   Cl   CF(CF 2 —CF 2 )   Cl       1114   H   Br   CF(CF 2 —CF 2 )   Br       1115   H   I   CF(CF 2 —CF 2 )   I       1116   H   NO 2     CF(CF 2 —CF 2 )   NO 2         1117   H   CN   CF(CF 2 —CF 2 )   CN       1118   H   CF(CF 2 —CF 2 )   CF(CF 2 —CF 2 )   H       1119   H   CF(CF 2 —CF 2 )   CF(CF 2 —CF 2 )   Me       1120   H   CF(CF 2 —CF 2 )   CF(CF 2 —CF 2 )   Et       1121   H   CF(CF 2 —CF 2 )   CF(CF 2 —CF 2 )   CHF—Me       1122   H   CF(CF 2 —CF 2 )   CF(CF 2 —CF 2 )   i-Pr       1123   H   CF(CF 2 —CF 2 )   CF(CF 2 —CF 2 )   F       1124   H   CF(CF 2 —CF 2 )   CF(CF 2 —CF 2 )   Cl       1125   H   CF(CF 2 —CF 2 )   CF(CF 2 —CF 2 )   Br       1126   H   CF(CF 2 —CF 2 )   CF(CF 2 —CF 2 )   I       1127   H   CF(CF 2 —CF 2 )   CF(CF 2 —CF 2 )   NO 2         1128   H   CF(CF 2 —CF 2 )   CF(CF 2 —CF 2 )   CN       1129   H   CF(CF 2 —CF 2 )   H   CF(CF 2 —CF 2 )       1130   H   CF(CF 2 —CF 2 )   Me   CF(CF 2 —CF 2 )       1131   H   CF(CF 2 —CF 2 )   Et   CF(CF 2 —CF 2 )       1132   H   CF(CF 2 —CF 2 )   CHF—Me   CF(CF 2 —CF 2 )       1133   H   CF(CF 2 —CF 2 )   i-Pr   CF(CF 2 —CF 2 )       1134   H   CF(CF 2 —CF 2 )   F   CF(CF 2 —CF 2 )       1135   H   CF(CF 2 —CF 2 )   Cl   CF(CF 2 —CF 2 )       1136   H   CF(CF 2 —CF 2 )   Br   CF(CF 2 —CF 2 )       1137   H   CF(CF 2 —CF 2 )   I   CF(CF 2 —CF 2 )       1138   H   CF(CF 2 —CF 2 )   NO 2     CF(CF 2 —CF 2 )       1139   H   CF(CF 2 —CF 2 )   CN   CF(CF 2 —CF 2 )       1140   H   c-Bu   Me   H       1141   H   c-Bu   Et   H       1142   H   c-Bu   CHF—Me   H       1143   H   c-Bu   i-Pr   H       1144   H   c-Bu   F   H       1145   H   c-Bu   Cl   H       1146   H   c-Bu   Br   H       1147   H   c-Bu   I   H       1148   H   c-Bu   NO 2     H       1149   H   c-Bu   CN   H       1150   H   c-Bu   H   Me       1151   H   c-Bu   H   Et       1152   H   c-Bu   H   CHF—Me       1153   H   c-Bu   H   i-Pr       1154   H   c-Bu   H   F       1155   H   c-Bu   H   Cl       1156   H   c-Bu   H   Br       1157   H   c-Bu   H   I       1158   H   c-Bu   H   NO 2         1159   H   c-Bu   H   CN       1160   Me   H   H   c-Bu       1161   Et   H   H   C-Bu       1162   CHF—Me   H   H   c-Bu       1163   i-Pr   H   H   c-Bu       1164   F   H   H   c-Bu       1165   Cl   H   H   c-Bu       1166   Br   H   H   c-Bu       1167   I   H   H   c-Bu       1168   NO 2     H   H   c-Bu       1169   CN   H   H   c-Bu       1170   H   Me   c-Bu   H       1171   H   Et   c-Bu   H       1172   H   CHF—Me   c-Bu   H       1173   H   i-Pr   c-Bu   H       1174   H   F   c-Bu   H       1175   H   Cl   c-Bu   H       1176   H   Br   c-Bu   H       1177   H   I   c-Bu   H       1178   H   NO 2     c-Bu   H       1179   H   CN   c-Bu   H       1180   H   Me   c-Bu   F       1181   H   Me   c-Bu   Cl       1182   H   Me   c-Bu   Br       1183   H   Me   c-Bu   I       1184   H   Me   c-Bu   Me       1185   H   Et   c-Bu   Et       1186   H   CHF—Me   c-Bu   CHF—Me       1187   H   i-Pr   c-Bu   i-Pr       1188   H   F   c-Bu   F       1189   H   Cl   c-Bu   Cl       1190   H   Br   c-Bu   Br       1191   H   I   c-Bu   I       1192   H   NO 2     c-Bu   NO 2         1193   H   CN   c-Bu   CN       1194   H   c-Bu   c-Bu   H       1195   H   c-Bu   c-Bu   Me       1196   H   c-Bu   c-Bu   Et       1197   H   c-Bu   c-Bu   CHF—Me       1198   H   c-Bu   c-Bu   i-Pr       1199   H   c-Bu   c-Bu   F       1200   H   c-Bu   c-Bu   Cl       1201   H   c-Bu   c-Bu   Br       1202   H   c-Bu   c-Bu   I       1203   H   c-Bu   c-Bu   NO 2         1204   H   c-Bu   c-Bu   CN       1205   H   c-Bu   H   c-Bu       1206   H   c-Bu   Me   c-Bu       1207   H   c-Bu   Et   c-Bu       1208   H   c-Bu   CHF—Me   c-Bu       1209   H   c-Bu   i-Pr   c-Bu       1210   H   c-Bu   F   c-Bu       1211   H   c-Bu   Cl   c-Bu       1212   H   c-Bu   Br   c-Bu       1213   H   c-Bu   I   c-Bu       1214   H   c-Bu   NO 2     c-Bu       1215   H   c-Bu   CN   c-Bu       1216   H   c-Pen   Me   H       1217   H   c-Pen   Et   H       1218   H   c-Pen   CHF—Me   H       1219   H   c-Pen   i-Pr   H       1220   H   c-Pen   F   H       1221   H   c-Pen   Cl   H       1222   H   c-Pen   Br   H       1223   H   c-Pen   I   H       1224   H   c-Pen   NO 2     H       1225   H   c-Pen   CN   H       1226   H   c-Pen   H   Me       1227   H   c-Pen   H   Et       1228   H   c-Pen   H   CHF—Me       1229   H   c-Pen   H   i-Pr       1230   H   c-Pen   H   F       1231   H   c-Pen   H   Cl       1232   H   c-Pen   H   Br       1233   H   c-Pen   H   I       1234   H   c-Pen   H   NO 2         1235   H   c-Pen   H   CN       1236   Me   H   H   c-Pen       1237   Et   H   H   c-Pen       1238   CHF—Me   H   H   c-Pen       1239   i-Pr   H   H   c-Pen       1240   F   H   H   c-Pen       1241   Cl   H   H   c-Pen       1242   Br   H   H   c-Pen       1243   I   H   H   c-Pen       1244   NO 2     H   H   c-Pen       1245   CN   H   H   c-Pen       1246   H   Me   c-Pen   H       1247   H   Et   c-Pen   H       1248   H   CHF—Me   c-Pen   H       1249   H   i-Pr   c-Pen   H       1250   H   F   c-Pen   H       1251   H   Cl   c-Pen   H       1252   H   Br   c-Pen   H       1253   H   I   c-Pen   H       1254   H   NO 2     c-Pen   H       1255   H   CN   c-Pen   H       1256   H   Me   c-Pen   F       1257   H   Me   c-Pen   Cl       1258   H   Me   c-Pen   Br       1259   H   Me   c-Pen   I       1260   H   Me   c-Pen   Me       1261   H   Et   c-Pen   Et       1262   H   CHF—Me   c-Pen   CHF—Me       1263   H   i-Pr   c-Pen   i-Pr       1264   H   F   c-Pen   F       1265   H   Cl   c-Pen   Cl       1266   H   Br   c-Pen   Br       1267   H   I   c-Pen   I       1268   H   NO 2     c-Pen   NO 2         1269   H   CN   c-Pen   CN       1270   H   c-Pen   c-Pen   H       1271   H   c-Pen   c-Pen   Me       1272   H   c-Pen   c-Pen   Et       1273   H   c-Pen   c-Pen   CHF—Me       1274   H   c-Pen   c-Pen   i-Pr       1275   H   c-Pen   c-Pen   F       1276   H   c-Pen   c-Pen   Cl       1277   H   c-Pen   c-Pen   Br       1278   H   c-Pen   c-Pen   I       1279   H   c-Pen   c-Pen   NO 2         1280   H   c-Pen   c-Pen   CN       1281   H   c-Pen   H   c-Pen       1282   H   c-Pen   Me   c-Pen       1283   H   c-Pen   Et   c-Pen       1284   H   c-Pen   CHF—Me   c-Pen       1285   H   c-Pen   i-Pr   c-Pen       1286   H   c-Pen   F   c-Pen       1287   H   c-Pen   Cl   c-Pen       1288   H   c-Pen   Br   c-Pen       1289   H   c-Pen   I   c-Pen       1290   H   c-Pen   NO 2     c-Pen       1291   H   c-Pen   CN   c-Pen       1292   H   c-Hex   Me   H       1293   H   c-Hex   Et   H       1294   H   c-Hex   CHF—Me   H       1295   H   c-Hex   i-Pr   H       1296   H   c-Hex   F   H       1297   H   c-Hex   Cl   H       1298   H   c-Hex   Br   H       1299   H   c-Hex   I   H       1300   H   c-Hex   NO 2     H       1301   H   c-Hex   CN   H       1302   H   c-Hex   H   Me       1303   H   c-Hex   H   Et       1304   H   c-Hex   H   CHF—Me       1305   H   c-Hex   H   i-Pr       1306   H   c-Hex   H   F       1307   H   c-Hex   H   Cl       1308   H   c-Hex   H   Br       1309   H   c-Hex   H   I       1310   H   c-Hex   H   NO 2         1311   H   c-Hex   H   CN       1312   Me   H   H   c-Hex       1313   Et   H   H   c-Hex       1314   CHF—Me   H   H   c-Hex       1315   i-Pr   H   H   c-Hex       1316   F   H   H   c-Hex       1317   Cl   H   H   c-Hex       1318   Br   H   H   c-Hex       1319   I   H   H   c-Hex       1320   NO 2     H   H   c-Hex       1321   CN   H   H   c-Hex       1322   H   Me   c-Hex   H       1323   H   Et   c-Hex   H       1324   H   CHF—Me   c-Hex   H       1325   H   i-Pr   c-Hex   H       1326   H   F   c-Hex   H       1327   H   Cl   c-Hex   H       1328   H   Br   c-Hex   H       1329   H   I   c-Hex   H       1330   H   NO 2     c-Hex   H       1331   H   CN   c-Hex   H       1332   H   Me   c-Hex   F       1333   H   Me   c-Hex   Cl       1334   H   Me   c-Hex   Br       1335   H   Me   c-Hex   I       1336   H   Me   c-Hex   Me       1337   H   Et   c-Hex   Et       1338   H   CHF—Me   c-Hex   CHF—Me       1339   H   i-Pr   c-Hex   i-Pr       1340   H   F   c-Hex   F       1341   H   Cl   c-Hex   Cl       1342   H   Br   c-Hex   Br       1343   H   I   c-Hex   I       1344   H   NO 2     c-Hex   NO 2         1345   H   CN   c-Hex   CN       1346   H   c-Hex   c-Hex   H       1347   H   c-Hex   c-Hex   Me       1348   H   c-Hex   c-Hex   Et       1349   H   c-Hex   c-Hex   CHF—Me       1350   H   c-Hex   c-Hex   i-Pr       1351   H   c-Hex   c-Hex   F       1352   H   c-Hex   c-Hex   Cl       1353   H   c-Hex   c-Hex   Br       1354   H   c-Hex   c-Hex   I       1355   H   c-Hex   c-Hex   NO 2         1356   H   c-Hex   c-Hex   CN       1357   H   c-Hex   H   c-Hex       1358   H   c-Hex   Me   c-Hex       1359   H   c-Hex   Et   c-Hex       1360   H   c-Hex   CHF—Me   c-Hex       1361   H   c-Hex   i-Pr   c-Hex       1362   H   c-Hex   F   c-Hex       1363   H   c-Hex   Cl   c-Hex       1364   H   c-Hex   Br   c-Hex       1365   H   c-Hex   I   c-Hex       1366   H   c-Hex   NO 2     c-Hex       1367   H   c-Hex   CN   c-Hex       1368   H   CF═CF 2     c-Pr   H       1369   H   CF═CF 2     c-Pr   Me       1370   H   CF═CF 2     c-Pr   Et       1371   H   CF═CF 2     c-Pr   CHF—Me       1372   H   CF═CF 2     c-Pr   i-Pr       1373   H   CF═CF 2     c-Pr   F       1374   H   CF═CF 2     c-Pr   Cl       1375   H   CF═CF 2     c-Pr   Br       1376   H   CF═CF 2     c-Pr   I       1377   H   CF═CF 2     c-Pr   NO 2         1378   H   CF═CF 2     c-Pr   CN       1379   H   c-Pr   CF═CF 2     H       1380   H   c-Pr   CF═CF 2     Me       1381   H   c-Pr   CF═CF 2     Et       1382   H   c-Pr   CF═CF 2     CHF—Me       1383   H   c-Pr   CF═CF 2     i-Pr       1384   H   c-Pr   CF═CF 2     F       1385   H   c-Pr   CF═CF 2     Cl       1386   H   c-Pr   CF═CF 2     Br       1387   H   c-Pr   CF═CF 2     I       1388   H   c-Pr   CF═CF 2     NO 2         1389   H   c-Pr   CF═CF 2     CN       1390   H   c-Pr   H   CF═CF 2         1391   H   c-Pr   Me   CF═CF 2         1392   H   c-Pr   Et   CF═CF 2         1393   H   c-Pr   CHF—Me   CF═CF 2         1394   H   c-Pr   i-Pr   CF═CF 2         1395   H   c-Pr   F   CF═CF 2         1396   H   c-Pr   Cl   CF═CF 2         1397   H   c-Pr   Br   CF═CF 2         1398   H   c-Pr   I   CF═CF 2         1399   H   c-Pr   NO 2     CF═CF 2         1400   H   c-Pr   CN   CF═CF 2         1401   H   CCMe   c-Pr   H       1402   H   CCMe   c-Pr   Me       1403   H   CCMe   c-Pr   Et       1404   H   CCMe   c-Pr   CHF—Me       1405   H   CCMe   c-Pr   i-Pr       1406   H   CCMe   c-Pr   F       1407   H   CCMe   c-Pr   Cl       1408   H   CCMe   c-Pr   Br       1409   H   CCMe   c-Pr   I       1410   H   CCMe   c-Pr   NO 2         1411   H   CCMe   c-Pr   CN       1412   H   c-Pr   CCMe   H       1413   H   c-Pr   CCMe   Me       1414   H   c-Pr   CCMe   Et       1415   H   c-Pr   CCMe   CHF—Me       1416   H   c-Pr   CCMe   i-Pr       1417   H   c-Pr   CCMe   F       1418   H   c-Pr   CCMe   Cl       1419   H   c-Pr   CCMe   Br       1420   H   c-Pr   CCMe   I       1421   H   c-Pr   CCMe   NO 2         1422   H   c-Pr   CCMe   CN       1423   H   c-Pr   H   CCMe       1424   H   c-Pr   Me   CCMe       1425   H   c-Pr   Et   CCMe       1426   H   c-Pr   CHF—Me   CCMe       1427   H   c-Pr   i-Pr   CCMe       1428   H   c-Pr   F   CCMe       1429   H   c-Pr   Cl   CCMe       1430   H   c-Pr   Br   CCMe       1431   H   c-Pr   I   CCMe       1432   H   c-Pr   NO 2     CCMe       1433   H   c-Pr   CN   CCMe       1434   H   CF═CF 2     CF(CF 2 —CF 2 )   H       1435   H   CF═CF 2     CF(CF 2 —CF 2 )   Me       1436   H   CF═CF 2     CF(CF 2 —CF 2 )   Et       1437   H   CF═CF 2     CF(CF 2 —CF 2 )   CHF—Me       1438   H   CF═CF 2     CF(CF 2 —CF 2 )   i-Pr       1439   H   CF═CF 2     CF(CF 2 —CF 2 )   F       1440   H   CF═CF 2     CF(CF 2 —CF 2 )   Cl       1441   H   CF═CF 2     CF(CF 2 —CF 2 )   Br       1442   H   CF═CF 2     CF(CF 2 —CF 2 )   I       1443   H   CF═CF 2     CF(CF 2 —CF 2 )   NO 2         1444   H   CF═CF 2     CF(CF 2 —CF 2 )   CN       1445   H   CF(CF 2 —CF 2 )   CF═CF 2     H       1446   H   CF(CF 2 —CF 2 )   CF═CF 2     Me       1447   H   CF(CF 2 —CF 2 )   CF═CF 2     Et       1448   H   CF(CF 2 —CF 2 )   CF═CF 2     CHF—Me       1449   H   CF(CF 2 —CF 2 )   CF═CF 2     i-Pr       1450   H   CF(CF 2 —CF 2 )   CF═CF 2     F       1451   H   CF(CF 2 —CF 2 )   CF═CF 2     Cl       1452   H   CF(CF 2 —CF 2 )   CF═CF 2     Br       1453   H   CF(CF 2 —CF 2 )   CF═CF 2     I       1454   H   CF(CF 2 —CF 2 )   CF═CF 2     NO 2         1455   H   CF(CF 2 —CF 2 )   CF═CF 2     CN       1456   H   CF(CF 2 —CF 2 )   H   CF═CF 2         1457   H   CF(CF 2 —CF 2 )   Me   CF═CF 2         1458   H   CF(CF 2 —CF 2 )   Et   CF═CF 2         1459   H   CF(CF 2 —CF 2 )   CHF—Me   CF═CF 2         1460   H   CF(CF 2 —CF 2 )   i-Pr   CF═CF 2         1461   H   CF(CF 2 —CF 2 )   F   CF═CF 2         1462   H   CF(CF 2 —CF 2 )   Cl   CF═CF 2         1463   H   CF(CF 2 —CF 2 )   Br   CF═CF 2         1464   H   CF(CF 2 —CF 2 )   I   CF═CF 2         1465   H   CF(CF 2 —CF 2 )   NO 2     CF═CF 2         1466   H   CF(CF 2 —CF 2 )   CN   CF═CF 2         1467   H   CCMe   CF(CF 2 —CF 2 )   H       1468   H   CCMe   CF(CF 2 —CF 2 )   Me       1469   H   CCMe   CF(CF 2 —CF 2 )   Et       1470   H   CCMe   CF(CF 2 —CF 2 )   CHF—Me       1471   H   CCMe   CF(CF 2 —CF 2 )   i-Pr       1472   H   CCMe   CF(CF 2 —CF 2 )   F       1473   H   CCMe   CF(CF 2 —CF 2 )   Cl       1474   H   CCMe   CF(CF 2 —CF 2 )   Br       1475   H   CCMe   CF(CF 2 —CF 2 )   I       1476   H   CCMe   CF(CF 2 —CF 2 )   NO 2         1477   H   CCMe   CF(CF 2 —CF 2 )   CN       1478   H   CF(CF 2 —CF 2 )   CCMe   H       1479   H   CF(CF 2 —CF 2 )   CCMe   Me       1480   H   CF(CF 2 —CF 2 )   CCMe   Et       1481   H   CF(CF 2 —CF 2 )   CCMe   CHF—Me       1482   H   CF(CF 2 —CF 2 )   CCMe   i-Pr       1483   H   CF(CF 2 —CF 2 )   CCMe   F       1484   H   CF(CF 2 —CF 2 )   CCMe   Cl       1485   H   CF(CF 2 —CF 2 )   CCMe   Br       1486   H   CF(CF 2 —CF 2 )   CCMe   I       1487   H   CF(CF 2 —CF 2 )   CCMe   NO 2         1488   H   CF(CF 2 —CF 2 )   CCMe   CN       1489   H   CF(CF 2 —CF 2 )   H   CCMe       1490   H   CF(CF 2 —CF 2 )   Me   CCMe       1491   H   CF(CF 2 —CF 2 )   Et   CCMe       1492   H   CF(CF 2 —CF 2 )   CHF—Me   CCMe       1493   H   CF(CF 2 —CF 2 )   i-Pr   CCMe       1494   H   CF(CF 2 —CF 2 )   F   CCMe       1495   H   CF(CF 2 —CF 2 )   Cl   CCMe       1496   H   CF(CF 2 —CF 2 )   Br   CCMe       1497   H   CF(CF 2 —CF 2 )   I   CCMe       1498   H   CF(CF 2 —CF 2 )   NO 2     CCMe       1499   H   CF(CF 2 —CF 2 )   CN   CCMe       1500   H   CCH   CF(CF 2 —CF 2 )   H       1501   H   CCH   CF(CF 2 —CF 2 )   Me       1502   H   CCH   CF(CF 2 —CF 2 )   Et       1503   H   CCH   CF(CF 2 —CF 2 )   CHF—Me       1504   H   CCH   CF(CF 2 —CF 2 )   i-Pr       1505   H   CCH   CF(CF 2 —CF 2 )   F       1506   H   CCH   CF(CF 2 —CF 2 )   Cl       1507   H   CCH   CF(CF 2 —CF 2 )   Br       1508   H   CCH   CF(CF 2 —CF 2 )   I       1509   H   CCH   CF(CF 2 —CF 2 )   NO 2         1510   H   CCH   CF(CF 2 —CF 2 )   CN       1511   H   CF(CF 2 —CF 2 )   CCH   H       1512   H   CF(CF 2 —CF 2 )   CCH   Me       1513   H   CF(CF 2 —CF 2 )   CCH   Et       1514   H   CF(CF 2 —CF 2 )   CCH   CHF—Me       1515   H   CF(CF 2 —CF 2 )   CCH   i-Pr       1516   H   CF(CF 2 —CF 2 )   CCH   F       1517   H   CF(CF 2 —CF 2 )   CCH   Cl       1518   H   CF(CF 2 —CF 2 )   CCH   Br       1519   H   CF(CF 2 —CF 2 )   CCH   I       1520   H   CF(CF 2 —CF 2 )   CCH   NO 2         1521   H   CF(CF 2 —CF 2 )   CCH   CN       1522   H   CF(CF 2 —CF 2 )   H   CCH       1523   H   CF(CF 2 —CF 2 )   Me   CCH       1524   H   CF(CF 2 —CF 2 )   Et   CCH       1525   H   CF(CF 2 —CF 2 )   CHF—Me   CCH       1526   H   CF(CF 2 —CF 2 )   i-Pr   CCH       1527   H   CF(CF 2 —CF 2 )   F   CCH       1528   H   CF(CF 2 —CF 2 )   Cl   CCH       1529   H   CF(CF 2 —CF 2 )   Br   CCH       1530   H   CF(CF 2 —CF 2 )   I   CCH       1531   H   CF(CF 2 —CF 2 )   NO 2     CCH       1532   H   CF(CF 2 —CF 2 )   CN   CCH       1533   H   CCH   c-Pr   H       1534   H   CCH   c-Pr   Me       1535   H   CCH   c-Pr   Et       1536   H   CCH   c-Pr   CHF—Me       1537   H   CCH   c-Pr   i-Pr       1538   H   CCH   c-Pr   F       1539   H   CCH   c-Pr   Cl       1540   H   CCH   c-Pr   Br       1541   H   CCH   c-Pr   I       1542   H   CCH   c-Pr   NO 2         1543   H   CCH   c-Pr   CN       1544   H   c-Pr   CCH   H       1545   H   c-Pr   CCH   Me       1546   H   c-Pr   CCH   Et       1547   H   c-Pr   CCH   CHF—Me       1548   H   c-Pr   CCH   i-Pr       1549   H   c-Pr   CCH   F       1550   H   c-Pr   CCH   Cl       1551   H   c-Pr   CCH   Br       1552   H   c-Pr   CCH   I       1553   H   c-Pr   CCH   NO 2         1554   H   c-Pr   CCH   CN       1555   H   c-Pr   H   CCH       1556   H   c-Pr   Me   CCH       1557   H   c-Pr   Et   CCH       1558   H   c-Pr   CHF—Me   CCH       1559   H   c-Pr   i-Pr   CCH       1560   H   c-Pr   F   CCH       1561   H   c-Pr   Cl   CCH       1562   H   c-Pr   Br   CCH       1563   H   c-Pr   I   CCH       1564   H   c-Pr   NO 2     CCH       1565   H   c-Pr   CN   CCH       1566   CF═CF 2     H   H   H       1567   H   CF═CF 2     H   H       1568   H   H   CF═CF 2     H       1569   CF═CF—CF 3     H   H   H       1570   H   CF═CF—CF 3     H   H       1571   H   H   CF═CF—CF 3     H       1572   CF 2 —CF═CF 2     H   H   H       1573   H   CF 2 —CF═CF 2     H   H       1574   H   H   CF 2 —CF═CF 2     H       1575   CF 2 —CF═CF—   H   H   H           CF 3         1576   H   CF 2 —CF═CF—CF 3     H   H       1577   H   H   CF 2 —CF═CF—CF 3     H       1578   CCH   H   H   H       1579   H   CCH   H   H       1580   H   H   CCH   H       1581   CCMe   H   H   H       1582   H   CCMe   H   H       1583   H   H   CCMe   H       1584   CH 2 CCH   H   H   H       1585   H   CH 2 CCH   H   H       1586   H   H   CH 2 CCH   H       1587   CH 2 CCMe   H   H   H       1588   H   CH 2 CCMe   H   H       1589   H   H   CH 2 CCMe   H       1590   CH═C═CH 2     H   H   H       1591   H   CH═C═CH 2     H   H       1592   H   H   CH═C═CH 2     H       1593   CC-Bu   H   H   H       1594   H   CC-Bu   H   H       1595   H   H   CC-Bu   H       1596   CC—CHF—Me   H   H   H       1597   H   CC—CHF—Me   H   H       1598   H   H   CC—CHF—Me   H       1599   CC—CH(OH)—   H   H   H           Me       1600   H   CC—CH(OH)—Me   H   H       1601   H   H   CC—CH(OH)—Me   H       1602   c-Pr   H   H   H       1603   H   c-Pr   H   H       1604   H   H   c-Pr   H       1605   CH(CF 2 —   H   H   H           CH 2 )       1606   H   CH(CF 2 —CH 2 )   H   H       1607   H   H   CH(CF 2 —CH 2 )   H       1608   CF(CF 2 —CF 2 )   H   H   H       1609   H   CF(CF 2 —CF 2 )   H   H       1610   H   H   CF(CF 2 —CF 2 )   H       1611   c-Bu   H   H   H       1612   H   c-Bu   H   H       1613   H   H   c-Bu   H       1614   c-Pen   H   H   H       1615   H   c-Pen   H   H       1616   H   H   c-Pen   H       1617   c-Hex   H   H   H       1618   H   c-Hex   H   H       1619   H   H   c-Hex   H       1620   H   F   CCH   H                  
 
     [0222] Table 1: Compounds of the formula (Ia)  
     Tr—Ar  (Ia)  
     [0223] In the table below, the individual compounds are defined as combinations of the partial radicals Tr and Ar and also given the product numbers Px.y, x and y being numbers. A product number allows an unambiguous assignment to the structure of the compound of the formula (Tr—No.)-(Ar—No.) by the scheme:  
     P(No. of the radical Tr)·(No. of the radical Ar)  
     [0224] where the partial structures of the radicals Tr and Ar can be found in the Pretables 1.1 and 1.2 (see above). Accordingly, the product number P1.1 denotes the compound of the formula (Tr-1)-(Ar-1) or of the chemical formula (P1. 1):  
                 
 
     [0225] In each row, the Table 1 contains compounds of the formula (Ia) in which the radical Tr has the same partial formula (=compounds of the formula (Tr—No.)-Ar having the same radical Tr, see left-hand column). In accordance with Pretable 1.2, the radicals Ar are defined by ascending numbers. For the sake of brevity, only the first, second, penultimate and ultimate radical for Ar and the corresponding columns with product numbers are given. Accordingly, the compound of row 3 and the 5th column under Ar has the structure of the formula (Tr-3)-(Ar-5) and the product number P3.5 according to table 1.  
                       TABLE 1                                      Ar (see definition of Ar from Table 1.2 and abbreviations)                                     Tr-Ar   (Ar-1)   (Ar-2)   (Ar-y)   (Ar-1619)   (Ar-1620)               (Tr-1)-Ar   P1.1   P1.2   P1.y   P1.1619   P1.1620       (Tr-2)-Ar   P2.1   P2.2   P2.y   P2.1619   P2.1620       (Tr-3)-Ar   P3.1   P3.2   P3.y   P3.1619   P3.1620       (Tr-4)-Ar   P4.1   P4.2   P4.y   P4.1619   P4.1620       (Tr-5)-Ar   P5.1   P5.2   P5.y   P5.1619   P5.1620       (Tr-6)-Ar   P6.1   P6.2   P6.y   P6.1619   P6.1620       (Tr-7)-Ar   P7.1   P7.2   P7.y   P7.1619   P7.1620       (Tr-8)-Ar   P8.1   P8.2   P8.y   P8.1619   P8.1620       (Tr-9)-Ar   P9.1   P9.2   P9.y   P9.1619   P9.1620       (Tr-10)-Ar   P10.1   P10.2   P10.y   P10.1619   P10.1620       (Tr-11)-Ar   P11.1   P11.2   P11.y   P11.1619   P11.1620       (Tr-12)-Ar   P12.1   P12.2   P12.y   P12.1619   P12.1620       (Tr-13)-Ar   P13.1   P13.2   P13.y   P13.1619   P13.1620       (Tr-14)-Ar   P14.1   P14.2   P14.y   P14.1619   P14.1620       (Tr-16)-Ar   P16.1   P16.2   P16.y   P16.1619   P16.1620       (Tr-17)-Ar   P17.1   P17.2   P17.y   P17.1619   P17.1620       (Tr-18)-Ar   P18.1   P18.2   P18.y   P18.1619   P18.1620       (Tr-19)-Ar   P19.1   P19.2   P19.y   P19.1619   P19.1620       (Tr-20)-Ar   P20.1   P20.2   P20.y   P20.1619   P20.1620       (Tr-21)-Ar   P21.1   P21.2   P21.y   P21.1619   P21.1620       (Tr-22)-Ar   P22.1   P22.2   P22.y   P22.1619   P22.1620       (Tr-23)-Ar   P23.1   P23.2   P23.y   P23.1619   P23.1620       (Tr-24)-Ar   P24.1   P24.2   P24.y   P24.1619   P24.1620       (Tr-25)-Ar   P25.1   P25.2   P25.y   P25.1619   P25.1620       (Tr-26)-Ar   P26.1   P26.2   P26.y   P26.1619   P26.1620       (Tr-27)-Ar   P27.1   P27.2   P27.y   P27.1619   P27.1620       (Tr-28)-Ar   P28.1   P28.2   P28.y   P28.1619   P28.1620       (Tr-29)-Ar   P29.1   P29.2   P29.y   P29.1619   P29.1620       (Tr-30)-Ar   P30.1   P30.2   P30.y   P30.1619   P30.1620       (Tr-31)-Ar   P31.1   P31.2   P31.y   P31.1619   P31.1620       (Tr-32)-Ar   P32.1   P32.2   P32.y   P32.1619   P32.1620       (Tr-33)-Ar   P33.1   P33.2   P33.y   P33.1619   P33.1620       (Tr-34)-Ar   P34.1   P34.2   P34.y   P34.1619   P34.1620       (Tr-35)-Ar   P35.1   P35.2   P35.y   P35.1619   P35.1620       (Tr-36)-Ar   P36.1   P36.2   P36.y   P36.1619   P36.1620       (Tr-37)-Ar   P37.1   P37.2   P37.y   P37.1619   P37.1620       (Tr-38)-Ar   P38.1   P38.2   P38.y   P38.1619   P38.1620       (Tr-39)-Ar   P39.1   P39.2   P39.y   P39.1619   P39.1620       (Tr-40)-Ar   P40.1   P40.2   P40.y   P40.1619   P40.1620       (Tr-41)-Ar   P41.1   P41.2   P41.y   P41.1619   P41.1620       (Tr-42)-Ar   P42.1   P42.2   P42.y   P42.1619   P42.1620       (Tr-43)-Ar   P43.1   P43.2   P43.y   P43.1619   P43.1620       (Tr-44)-Ar   P44.1   P44.2   P44.y   P44.1619   P44.1620       (Tr-45)-Ar   P45.1   P45.2   P45.y   P45.1619   P45.1620       (Tr-46)-Ar   P46.1   P46.2   P46.y   P46.1619   P46.1620       (Tr-47)-Ar   P47.1   P47.2   P47.y   P47.1619   P47.1620       (Tr-48)-Ar   P48.1   P48.2   P48.y   P48.1619   P48.1620       (Tr-49)-Ar   P49.1   P49.2   P49.y   P49.1619   P49.1620       (Tr-50)-Ar   P50.1   P50.2   P50.y   P50.1619   P50.1620                  
 
     [0226] Abbreviations:  
     [0227] Ar—Nr, x, y and Px.y=see definitions for tables 1, 1.1 and 1.2; y is an integer and generally runs from 1 to1620, specifically; on the 3 rd  column under Ar it has the value 3, in the 4 th  column it has the value 4, etc.  
               TABLE 2                          Physical data for compounds of the formula (Ia) from Table 1                             Product (number)   Physical data                       P1.5   resin           P1.49   resin           P1.309   resin           P1.352   resin           P1.384   resin           P1.428   resin           P1.916   resin           P1.960   resin           P1.1567   resin           P1.1568   resin           P1.1579   resin           P1.1580   resin           P1.1582   resin           P1.1583   resin           P1.1603   resin           P1.1604   resin           P2.5   resin           P2.49   resin           P2.309   resin           P2.352   resin           P2.384   resin           P2.428   resin           P2.916   resin           P2.960   resin           P2.1567   resin           P2.1568   resin           P2.1579   resin           P2.1580   resin           P2.1582   resin           P2.1583   resin           P2.1603   resin           P2.1604   resin           P2.1620   resin           P4.5   resin           P4.49   resin           P4.309   resin           P4.384   resin           P4.428   resin           P4.1567   resin           P4.1568   resin           P4.1579   resin           P4.1580   resin           P4.1582   resin           P4.1583   resin           P4.1603   resin           P4.1604   resin           P6.5   resin           P6.49   resin           P6.309   resin           P6.352   resin           P6.384   resin           P6.428   resin           P6.916   resin           P6.960   resin           P6.1567   resin           P6.1568   resin           P6.1579   resin           P6.1580   resin           P6.1582   resin           P6.1583   resin           P6.1603   resin           P6.1604   resin           P7.5   resin           P7.49   resin           P7.309   oil           P7.335   oil           P7.348   resin           P7.369   oil           P7.384   oil           P7.428   resin           P7.656   resin           P7.840   133-138° C.           P7.916   resin           P7.960   resin           P7.1567   resin           P7.1568   resin           P7.1579   resin           P7.1580   oil           P7.1582   resin           P7.1583   resin           P7.1603   resin           P7.1604   oil           P7.1620   resin           P9.309   resin           P9.352   resin           P9.384   resin           P9.428   resin           P9.1567   resin           P9.1568   resin           P9.1579   resin           P9.1580   resin           P9.1582   resin           P9.1583   resin           P9.1603   resin           P9.1604   resin           P11.1567   resin           P11.1568   resin           P11.1579   resin           P11.1580   resin           P11.1582   resin           P11.1583   resin           P11.1603   resin           P11.1604   resin           P12.5   resin           P12.49   resin           P12.335   oil           P12.840   oil           P12.916   resin           P12.960   resin           P12.1567   resin           P12.1568   resin           P12.1579   oil           P12.1603   resin           P12.1604   oil           P12.1620   resin           P14.309   resin           P14.352   resin           P14.384   resin           P14.428   resin           P14.1567   resin           P14.1568   resin           P14.1579   resin           P14.1580   resin           P14.1582   resin           P14.1583   resin           P14.1603   resin           P14.1604   resin           P16.5   resin           P16.49   resin           P16.309   resin           P16.352   resin           P16.384   resin           P16.428   resin           P16.916   resin           P16.960   resin           P16.1567   resin           P16.1568   resin           P16.1579   resin           P16.1580   resin           P16.1582   resin           P16.1583   resin           P16.1603   resin           P16.1604   resin           P17.5   resin           P17.49   resin           P17.309   oil           P17.335   oil           P17.348   resin           P17.352   113-119° C.           P17.358   63-66° C.           P17.369   oil           P17.384   121-124° C.           P17.424   oil           P17.428   resin           P17.450   resin           P17.656   resin           P17.688   oil           P17.728   oil           P17.764   oil           P17.840   oil           P17.916   resin           P17.960   resin           P17.1567   resin           P17.1568   resin           P17.1579   resin           P17.1580   oil           P17.1582   resin           P17.1583   resin           P17.1594   resin           P17.1595   resin           P17.1597   resin           P17.1598   resin           P17.1600   resin           P17.1601   resin           P17.1603   resin           P17.1604   oil           P17.1620   resin           P19.309   resin           P19.352   resin           P19.384   resin           P19.428   resin           P19.1567   resin           P19.1568   resin           P19.1579   resin           P19.1580   resin           P19.1582   resin           P19.1583   resin           P19.1603   resin           P19.1604   resin           P21.5   resin           P21.49   resin           P21.309   resin           P21.352   resin           P21.384   resin           P21.428   resin           P21.916   resin           P21.1567   resin           P21.1568   resin           P21.1579   resin           P21.1580   resin           P21.1582   resin           P21.1583   resin           P21.1603   resin           P21.1604   resin           P22.5   resin           P22.309   oil           P22.335   oil           P22.348   resin           P22.352   oil           P22.369   oil           P22.384   oil           P22.428   resin           P22.656   resin           P22.688   oil           P22.764   resin           P22.840   119-122° C.           P22.916   resin           P22.1567   resin           P22.1568   resin           P22.1579   oil           P22.1580   134-140° C.           P22.1582   resin           P22.1583   resin           P22.1595   resin           P22.1597   resin           P22.1598   resin           P22.1600   resin           P22.1601   resin           P22.1603   resin           P22.1604   oil           P22.1620   resin           P24.1567   resin           P24.1568   resin           P24.1579   resin           P24.1580   resin           P24.1582   resin           P24.1583   resin           P24.1603   resin           P24.1604   resin           P26.5   resin           P26.49   resin           P26.309   resin           P26.352   resin           P26.384   resin           P26.428   resin           P26.916   resin           P26.960   resin           P26.1567   resin           P26.1568   resin           P26.1579   resin           P26.1580   resin           P26.1582   resin           P26.1583   resin           P26.1603   resin           P26.1604   resin           P27.5   resin           P27.49   resin           P27.309   resin           P27.335   resin           P27.352   resin           P27.384   resin           P27.428   resin           P27.840   oil           P27.916   resin           P27.960   resin           P27.1567   resin           P27.1568   resin           P27.1579   resin           P27.1580   49-56° C.           P27.1582   resin           P27.1583   resin           P27.1600   resin           P27.1601   resin           P27.1603   resin           P27.1604   oil           P29.309   resin           P29.352   resin           P29.384   resin           P29.428   resin           P29.1567   resin           P29.1568   resin           P29.1579   resin           P29.1580   resin           P29.1582   resin           P29.1583   resin           P29.1603   resin           P29.1604   resin                      
 
     [0228] B. Formulation examples  
     [0229] a) A dust is obtained by mixing 10 parts by weight of a compound of the formula (I) and 90 parts by weight of talc as inert substance and comminuting the mixture in a hammer mill.  
     [0230] b) A wettable powder which is readily dispersible in water is obtained by mixing 25 parts by weight of a compound of the formula (I), 64 parts by weight of kaolin-containing quartz as inert substance, 10 parts by weight of potassium lignosulfonate and 1 part by weight of sodium oleoylmethyltaurinate as wetter and dispersant and grinding the mixture in a pinned-disk mill.  
     [0231] c) A dispersion concentrate which is readily dispersible in water is obtained by mixing 20 parts by weight of a compound of the formula (I) with 6 parts by weight of alkylphenol polyglycol ether (®Triton X 207), 3 parts by weight of isotridecanol polyglycol ether (8 EO) and 71 parts by weight of paraffinic mineral oil (boiling range for example approx. 255 to above 277° C.) and grinding the mixture in a ball mill to a fineness of below 5 microns.  
     [0232] d) An emulsifiable concentrate is obtained from 15 parts by weight of a compound of the formula (I), 75 parts by weight of cyclohexanone as the solvent and 10 parts by weight of ethoxylated nonylphenol as the emulsifier.  
     [0233] e) Water-dispersible granules are obtained by mixing 75 parts by weight of a compound of the formula (I), 10 parts by weight of calcium lignosulfonate, 5 parts by weight of sodium lauryl sulfate, 3 parts by weight of polyvinyl alcohol and 7 parts by weight of kaolin grinding the mixture in a pinned-disk mill and granulating the powder in a fluidized bed by spraying on water as the granulation liquid.  
     [0234] f) Water-dispersible granules are also obtained by homogenizing and precomminuting, in a colloid mill, 25 parts by weight of a compound of the formula (I), 5 parts by weight of sodium 2,2′-dinaphthyAmpthane-6,6′-disulfonate 2 parts by weight of sodium oleoylmethyltaurinate, 1 part by weight of polyvinyl alcohol, 17 parts by weight of calcium carbonate and 50 parts by weight of water, subsequently grinding the mixture in a bead mill and atomizing and drying the resulting suspension in a spray tower by means of a single-substance nozzle.  
     [0235] C. Biological Examples  
     [0236] 1. Pre-emergence Effect on Weeds  
     [0237] Seeds or rhizome pieces of monocotyledonous and dicotyledonous weed plants are placed in sandy loam soil in plastic pots and covered with soil. The compounds according to the invention which are formulated in the form of wettable powders or emulsion concentrates are then applied to the surface of the soil cover in the form of aqueous suspensions or emulsions at an application rate of 600 to 800 1 of water/ha (converted), in various dosages.  
     [0238] After the treatment, the pots are placed in a greenhouse and kept under good growth conditions for the weeds. After the test plants have emerged, the damage to the plants or the negative effect on the emergence is scored visually after a test period of 3 to 4 weeks by comparison with untreated controls. As shown by the test results, compounds according to the invention have good herbicidal pre-emergence activity against a broad spectrum of weed grasses and broad-leaved weeds. For example, in the test the compounds of Example Nos. P1.5, P1.49, P1.309, P1.352, P1.384, Pl.428, PI.916, PI.960, P1.1567, P1.1568, Pl.1579, Pl.1580, P1.1582, P1.1583, P1.1603, P1.1604, P2.5, P2.49, P2.309, P2.352, P2.384, P2.428, P2.916, P2.960, P2.1567, P2.1568, P2.1579, P2.1580, P2.1582, P2.1583, P2.1603, P2.1604, P2.1620, P4.5, P4.49, P4.309, P4.384, P4.428, P4.1567, P4.1568, P4.1579, P4.1580, P4.1582, P4.1583, P4.1603, P4.1604, P6.5, P6.49, P6.309, P6.352, P6.384, P6.428, P6.916, P6.960, P6.1567, P6.1568, P6.1579, P6.1580, P6.1582, P6.1583. P6.1603, P6.1604, P7.5, P7.49, P7.309, P7.335, P7.348, P7.369, P7.384, P7.428, P7.656, P7.840, P7.916, P7.960, P7.1567, P7.1568, P7.1579, P7.1580, P7.1582, P7.1583, P7.1603, P7.1604, P7.1620, P9.309, P9.352, P9.384, P9.428, P9.1567, P9.1568, P9.1579, P9.1580, P9.1582, P9.1583, P9.1603, P9.1604, P11.1567, P11.1568, P11.1579, P11.1580, P11.1582, PlI.1583, P11.1603, P11.1604, P12.5, P12.49, P12.335, P12.840, P12.916, P12.960, P12.1567, P12.1568, P12.1579, P12.1603, P12.1604, P12.1620, P14.309, P14.352, P14.384, P14.428, P14.1567, P14.1568, P14.1579, P14.1580, P14.1582, P14.1583, P14.1603, P14.1604, P16.5, P16.49, P16.309, P16.352, P16.384, P16.428, P16.916, P16.960, P16.1567, P16.1568, P16.1579, P16.1580, P16.1582, P16.1583, P16.1603, P16.1604, P17.5, P17.49, P17.309, P17.335, P17.348, P17.352, P17.358, P17.369, P17.384, P17.424, P17.428, P17.450, P17.656, P17.688, P17.728, P17.764, P17.840, P17.916, P17.960, P17.1567, P17.1568, P17.1579, P17.1580, P17.1582, P17.1583, P17.1594, P17.1595, P17.1597, P17.1598, P17.1600, P17.1601, P17.1603, P17.1604, P17.1620, P19.309, P19.352, P19.384, P19.428, P19.1567, P19.1568, P19.1579, P19.1580, P19.1582, P19.1583, P19.1603, P19.1604, P21.5, P21.49, P21.309, P21.352, P21.384, P21.428, P21.916, P21.1567, P21.1568, P21.1579, P21.1580, P21.1582, P21.1583, P21.1603, P21.1604, P22.5, P22.309, P22.335, P22.348, P22.352, P22.369, P22.384, P22.428, P22.656, P22.688, P22.764, P22.840, P22.916, P22.1567, P22.1568, P22.1579, P22.1580, P22.1582, P22.1583, P22.1595, P22.1597, P22.1598, P22.1600, P22.1601, P22.1603, P22.1604, P22.1620, P24.1567, P24.1568, P24.1579, P24.1580, P24.1582, P24.1583, P24.1603, P24.1604, P26.5, P26.49, P26.309, P26.352, P26.384, P26.428, P26.916, P26.960, P26.1567, P26.1568, P26.1579, P26.1580, P26.1582, P26.1583, P26.1603, P26.1604, P27.5, P27.49, P27.309, P27.335, P27.352, P27.384, P27.428, P27.840, P27.916, P27.960, P27.1567, P27.1568, P27.1579, P27.1580, P27.1582, P27.1583, P27.1600, P27.1601, P27.1603, P27.1604, P29.309, P29.352, P29.384, P29.428, P29.1567, P29.1568, P29.1579, P29.1580, P29.1582 (see Table 1) have very good herbicidal activity pre-emergence against harmful plants from the group consisting of Alopecurus spp., Apera spp., Poa spp., Echinochloa spp., Setaria spp., Digitaria spp., Chenopodium spp., Matricaria spp., Veronica spp., Viola spp., Stellarlia spp., s nn liCAtion rate of O5 ka and less of active substance per hectare.  
     [0239] 2. Post-emergence Effect on Weeds  
     [0240] Seeds or rhizome pieces of monocotyledonous and dicotyledonous weeds are placed in sandy loam soil in plastic pots, covered with soil and grown in a greenhouse under good growth conditions. Three weeks after sowing, the test plants are treated at the three-leaf stage. The compounds according to the invention which are formulated as wettable powders or emulsion concentrates are sprayed, at various dosages, onto the green parts of the plants at an application rate of 600 to 800 1 of water/ha (converted). After the test plants have remained in the greenhouse for about 3 to 4 weeks under optimum growth conditions, the effect of the preparations is scored visually by comparison with untreated controls. The agents according to the invention also have good herbicidal activity post-emergence against a broad spectrum of economically important weed grasses and broad-leaved weeds. For example, in the test, the compounds of Example Nos. P1.5, P1.49, P1.309, P1.352, P1.384, P1.428, P1.916, P1.960, P1.1567, P1.1568, P1.1579, P1.1580, P1.1582, P1.1583, P1.1603, P1.1604, P2.5, P2.49, P2.309, P2.352, P2.384, P2.428, P2.916, P2.960, P2.1567, P2.1568, P2.1579, P2.1580, P2.1582, P2.1583, P2.1603, P2.1604, P2.1620, P4.5, P4.49, P4.309, P4.384, P4.428, P4.1567, P4.1568, P4.1579, P4.1580, P4.1582, P4.1583, P4.1603, P4.1604, P6.5, P6.49, P6.309, P6.352, P6.384, P6.428, P6.916, P6.960, P6.1567, P6.1568, P6.1579, P6.1580, P6.1582, P6.1583, P6.1603, P6.1604, P7.5, P7.49, P7.309, P7.335, P7.348, P7.369, P7.384, P7.428, P7.656, P7.840, P7.916, P7.960, P7.1567, P7.1568, P7.1579, P7.1580, P7.1582, P7.1583, P7.1603, P7.1604, P7.1620, P9.309, P9.352, P9.384, P9.428, P9.1567, P9.1568, P9.1579, P9.1580, P9.1582, P9.1583, P9.1603, P9.1604,P11.1567,P11.1568,P11.1579,P11.1580,P11.1582,P11.1583, P11.1603, P11.1604, P12.5, P12.49, P12.335, P12.840, P12.916, P12.960, P12.1567, P12.1568, P12.1579, P12.1603, P12.1604, P12.1620, P14.309, P14.352, P14.384, P14.428, P14.1567, P14.1568, P14.1579, P14.1580, P14.1582, P14.1583, P14.1603 P14.1604, P16.5, P16.49, P16.309, P16.352, P16.384, P16.428, P16.916, P16.960, P16.1567, P16.1568, P16.1579, P16.1580, P16.1582, P16.1583, P16.1603,P16.1604, P17.5, P17.49, P17.309, P17.335, P17.348, P17.352, P17.358, P17.369, P17.384, P17.424, P17.428, P17.450, P17.656, P17.688, P17.728, P17.764, P17.840, P17.916, P17.960, P17.1567, P17.1568, P17.1579, P17.1580, P17.1582, P17.1583, P17.1594, P17.1595, P17.1597, P17.1598, P17.1600, P17.1601, P17.1603, P17.1604, P17.1620, P19.309, P19.352, P19.384, P19.428, P19.1567, P19.1568, P19.1579, P19.1580, P19.1582, P19.1583, P19.1603, P19.1604, P21.5, P21.49, P21.309, P21.352, P21.384, P21.428, P21.916, P21.1567, P21.1568, P21.1579, P21.1580, P21.1582, P21.1583, P21.1603, P21.1604, P22.5, P22.309, P22.335, P22.348, P22.352, P22.369, P22.384, P22.428, P22.656, P22.688, P22.764, P22.840, P22.916, P22.1567, P22.1568, P22.1579, P22.1580, P22.1582, P22.1583, P22.1595, P22.1597, P22.1598, P22.1600, P22.1601, P22.1603, P22.1604, P22.1620, P24.1567, P24.1568, P24.1579, P24.1580, P24.1582, P24.1583, P24.1603, P24.1604, P26.5, P26.49, P26.309, P26.352, P26.384, P26.428, P26.916, P26.960, P26.1567, P26.1568, P26.1579, P26.1580, P26.1582, P26.1583, P26.1603, P26.1604, P27.5, P27.49, P27.309, P27.335, P27.352, P27.384, P27.428, P27.840, P27.916, P27.960, P27.1567, P27.1568, P27.1579, P27.1580, P27.1582, P27.1583, P27.1600, P27.1601, P27.1603, P27.1604, P29.309, P29.352, P29.384, P29.428, P29.1567, P29.1568, P29.1579, P29.1580, P29.1582 (see Table 1) have very good herbicidal activity post-emergence against harmful plants from the group consisting of Chenopodium spp., Papaver spp., Polygonum spp., Veronica spp. or Viola spp. at an application rate of 0.5 kg and less of active substance per hectare.  
     [0241] 3. Action on Harmful Plants in Rice  
     [0242] Transplanted and sown rice and also typical rice weeds (gramineous and broad-leaved) are cultivated in closed plastic pots in a greenhouse to the three-leaf stage (Echinochloa crus-galli 1.5-leaf) under paddy rice conditions (dammed height of water: 2-3 cm). This is followed by treatment with the compounds according to the invention. For this purpose, the formulated active compounds are suspended, dissvlved or emulsified in water and applied by pourinn them into the dammed water around the test plants in different dosages. After this treatment, the test plants are set up in a greenhouse under optimum growth conditions and are maintained in this way throughout the test period.  
     [0243] About three weeks after application, evaluation is made by visual scoring of the damage to the plants by comparison with untreated controls. The compounds according to the invention show very good herbicidal activity against harmful plants. For example, the compounds of Example Nos. P1.5, P1.49, P1.309, P1.352, P1.384, P1.428, P1.916, P1.960, P1.1567, P1.1568, P1.1579, Pl.1580, P1.1582, P1.1583, P1.1603, P1.1604, P2.5, P2.49, P2.309, P2.352, P2.384, P2.428, P2.916, P2.960, P2.1567, P2.1568, P2.1579, P2.1580, P2.1582, P2.1583, P2.1603, P2.1604, P2.1620, P4.5, P4.49, P4.309, P4.384, P4.428, P4.1567, P4.1568, P4.1579, P4.1580, P4.1582, P4.1583, P4.1603, P4.1604, P6.5, P6.49, P6.309, P6.352, P6.384, P6.428, P6.916, P6.960, P6.1567, P6.1568, P6.1579, P6.1580, P6.1582, P6.1583, P6.1603, P6.1604, P7.5, P7.49, P7.309, P7.335, P7.348, P7.369, P7.384, P7.428, P7.656, P7.840, P7.916, P7.960, P7.1567, P7.1568, P7.1579, P7.1580, P7.1582, P7.1583, P7.1603, P7.1604, P7.1620, P9.309, P9.352, P9.384, P9.428, P9.1567, P9.1568, P9.1579, P9.1580, P9.1582, P9.1583, P9.1603, P9.1604, P11.1567,P11.1568,P11.1579,P11.1580,P11.1582,P11.1583,P11.1603, P11.1604, P12.5, P12.49, P12.335, P12.840, P12.916, P12.960, P12.1567, P12.1568, P12.1579, P12.1603, P12.1604, P12.1620, P14.309, P14.352, P14.384, P14.428, P14.1567, P14.1568, P14.1579, P14.1580, P14.1582, P14.1583, P14.1603, P14.1604, P16.5, P16.49, P16.309, P16.352, P16.384, P16.428, P16.916, P16.960, P16.1567, P16.1568, P16.1579, P16.1580, P16.1582, P16.1583, P16.1603, P16.1604, P17.5, P17.49, P17.309, P17.335, P17.348, P17.352, P17.358, P17.369, P17.384, P17.424, P17.428, P17.450, P17.656, P17.688, P17.728, P17.764, P17.840, P17.916, P17.960, P17.1567, P17.1568, P17.1579, P17.1580, P17.1582, P17.1583, P17.1594, P17.1595, P17.1597, P17.1598, P17.1600, P17.1601, P17.1603, P17.1604, P17.1620, P19.309, P19.352, P19.384, P19.428, P19.1567, P19.1568, P19.1579, P19.1580, P19.1582, P19.1583, P19.1603, P19.1604, P21.5, P21.49, P21.309, P21.352, P21.384, P21.428, P21.916, P21.1567, P21.1568, P21.1579, P21.1580, P21.1582, P21.1583, P21.1603, P21.1604, P22.5, P22.309, P22.335, P22.348, P22.352, P22.369, P22.384, P22.428, P22.656, P22.688, P22.764, P22.840, P22.916, P22.1567, P22.1568, P22.1579, P22.1580,P22.1582, P22.1583, P22.1595, P22.1597, P22.1598, P22.1600, P22.1601, P22.1603, P22.1604, P22.1620, P24.1567, P24.1568, P24.1579, P24.1580, P24.1582, P24.1583, P24.1603, P24.1604, P26.5, P26.49, P26.309, P26.352, P26.384, P26.428, P26.916, P26.960, P26.1567, P26.1568, P26.1579, P26.1580, P26.1582, P26.1583, P26.1603, P26.1604, P27.5, P27.49, P27.309, P27.335, P27.352, P27.384, P27.428, P27.840, P27.916, P27.960, P27.1567, P27.1568, P27.1579, P27.1580, P27.1582, P27.1583, P27.1600, P27.1601, P27.1603, P27.1604, P29.309, P29.352, P29.384, P29.428, P29.1567, P29.1568, P29.1579, P29.1580, P29.1582 (see Table 1) show very good herbicidal activity in the test against harmful plants which are typical for rice crops, for example Cyperus spp., Echinochloa spp., Digitaria spp., Sagitaria spp. and Scirpus spp.  
     [0244] 4. Tolerance by Crop Plants  
     [0245] In further greenhouse experiments, seeds of a substantial number of crop plants and weeds are placed in sandy loam soil and covered with soil. Some of the pots were treated immediately as described under Section 1, and the remaining pots are placed in the greenhouse until the plants have developed two to three true leaves and then sprayed with various dosages of the substances of the formula (I) according to the invention, as described under Section 2. Visual scoring four to five weeks after the application and after the plants had been in the greenhouse reveals that compounds according to the invention left dicotyledonous crops such as soybean, cofton, oilseed rape, sugar beet or potatoes unharmed even when high dosages of active ingredient were used by the pre- and post-emergence method. Moreover, some substances also spare Gramineae crops such as barley, wheat, rye, sorghum species, corn or rice. Some of the compounds of the formula (I) have high selectivity, and they are therefore suitable for controlling undesirable vegetation in agricultural crops.