Patent Publication Number: US-2011068467-A1

Title: Semiconductor device and method of manufacturing same

Description:
This application is based on Japanese patent application No. 2009-219645, the content of which is incorporated hereinto by reference. 
     BACKGROUND 
     1. Technical Field 
     The present invention relates to a semiconductor device and a method of manufacturing the same, and more particularly to a semiconductor device that includes an underfill resin provided between a semiconductor chip mounted in a flip-chip style and a substrate, and to a method of manufacturing such semiconductor device. 
     2. Related Art 
     A flip-chip connection is widely employed to mount a semiconductor chip on a substrate a, which includes disposing the semiconductor chip such that the element-carrying surface thereof confronts the substrate, and electrically connecting pads of the semiconductor chip and the substrate, through bumps such as solder balls. In such configuration, an underfill resin is provided between the semiconductor chip and the substrate, in order to assure the effective connection and to protect the connection points. The underfill resin includes a filet formed around the semiconductor chip, to thereby enhance the bonding strength between the semiconductor chip and the substrate. 
     Japanese Laid-Open Utility Publication No. 2001-102414 discloses a technique of heat-pressing a portion of a resin film extending off an outer periphery of the semiconductor chip, at the same time as heat-pressing the semiconductor chip on an interconnect pattern on the circuit substrate with the resin film disposed therebetween, to thereby form the filet of the resin film around lateral faces of the semiconductor chip. 
     It is difficult with the conventional technique, however, to form the filet in a uniform shape around the semiconductor chip, attaining at the same time the advantage of enhanced bonding strength of the underfill resin between the substrate and the semiconductor chip. For example, it is preferable that the substrate and the underfill resin have close thermal expansion coefficients, in order to enhance the bonding strength of the underfill resin between the substrate and the semiconductor chip. This is because the substrate and the underfill resin exhibit similar behavior in the case where these have close thermal expansion coefficients, even though the substrate and the underfill resin expand or contract after the underfill resin has cured, which leads to enhancing the bonding strength between the substrate and the underfill resin. 
     On the other hand, to form the filet in a uniform shape in all directions around the semiconductor chip, to thereby attain uniform stress of the underfill resin, it is preferable, for example, to employ an underfill resin that is relatively soft, in a state before curing. However it has so far been difficult to prepare an underfill resin that satisfies the plurality of characteristics described above. 
     Japanese Laid-Open Utility Publication No. 2008-103700 discloses a semiconductor device including an adhesive film for semiconductor, in which components of the film are separated in two layers, in a cross-sectional view after a dibond sheet has cured. This document also discloses employing a multilayer dibond sheet, which has a multilayer structure. 
     Japanese Laid-Open Utility Publication No. 2003-176461 discloses an ACA film of a three-layer structure, including a main ACA film containing an epoxy resin as the base, non-conductive particles of a size of 0.1 to 1 μm, and conductive particles of a size of 3 to 10 μm, or a main ACA film containing only the conductive particles of a size of 3 to 10 μm; and an adhesive enhancing layer containing an epoxy resin as the base and formed on the respective sides of the main ACA film. 
     Japanese Laid-Open Utility Publication No. 2000-299414 discloses a flip-chip style semiconductor device including an underfill material loaded in a gap between the substrate and the semiconductor chip, and a filet formed so as to encapsulate lateral faces of the semiconductor chip, in which the underfill material is an epoxy resin composition of 20 to 40 ppm/° C. in expansion coefficient under glass transition temperature, and the filet material is an epoxy resin composition of 20 ppm/° C. or lower in expansion coefficient under glass transition temperature. 
     Employing a plurality of types of resin as disclosed in the patented documents, Japanese Laid-Open Utility Publication No. 2008-103700, Japanese Laid-Open Utility Publication No. 2003-176461, and Japanese Laid-Open Utility Publication No. 2000-299414, appears to facilitate the control for satisfying the plurality of characteristics, compared with the case of employing a single resin. However, the techniques according to the patented documents of Japanese Laid-Open Utility Publication No. 2008-103700 and Japanese Laid-Open Utility Publication No. 2003-176461, the underfill resin does not include the filet, and a method of forming the filet in a desirable shape is not provided either. 
     Also, the technique according to the patented document of Japanese Laid-Open Utility Publication No. 2000-299414 employs different resins in the region between the substrate and the semiconductor chip and in the filet, and the resin composing the filet is provided alone only around the semiconductor chip. Such structure, however, still has a drawback in that stress of the resin composing the filet, arising from the expansion or contraction of the substrate and the underfill resin after the curing of the underfill resin, is only locally generated, which leads to compromise in the enhancing effect of the bonding strength between the substrate and the underfill resin. Besides, it is difficult to form the filet in a stable shape only around the lateral faces of the semiconductor chip. 
     SUMMARY 
     According to the present invention, there is provided a semiconductor device comprising: 
     a substrate with a pad formed on a surface thereof; 
     a semiconductor chip mounted on the surface of the substrate such that an element-carrying surface thereof on which a bump is provided confronts the surface, and connected in a flip-chip style to the pad, through the bump; and 
     an underfill resin formed on the surface of the substrate in a region between the surface of the substrate and the semiconductor chip, and including a filet formed around the semiconductor chip on the surface of the substrate; 
     wherein the underfill resin includes a first resin layer constituted of a first resin composition and a second resin layer constituted of a second resin composition; the first resin layer and the second resin layer being superposed on each other in at least a part of a region overlapping with the semiconductor chip in a plan view; and at least one of the first resin layer and the second resin layer is formed over an area including the region overlapping with the semiconductor chip in a plan view and the filet. 
     According to the present invention, there is provided a method of manufacturing the foregoing semiconductor device, comprising: 
     disposing on the surface of the substrate one of the first resin composition to constitute the first resin layer and the second resin composition to constitute the second resin layer, the other of the first resin composition and the second resin composition, and the semiconductor chip, such that one of the first resin composition and the second resin composition, the other thereof, and the semiconductor chip are to be stacked in this order; and 
     connecting the pad of the substrate and the bump of the semiconductor chip by heat-pressing, and curing the first resin composition and the second resin composition thereby forming the underfill resin. 
     With such configuration, since the underfill resin is constituted of the plurality of resin layers, the resin materials can be appropriately selected according to desired characteristics. Also, the resin layer constituting at least one of the first resin layer and the second resin layer is provided over the area including the filet and the region overlapping with the semiconductor chip in a plan view. Such structure allows dispersing, in an in-plane direction of the substrate, a stress of the resin layer arising from expansion or contraction of the substrate and the underfill resin resultant from the curing of the underfill resin, for example in the case where an appropriate material for forming the filet in a desirable shape is employed for the resin layer. Meanwhile regarding the other resin layer, for example employing a material having a thermal expansion coefficient close to that of the substrate enables enhancing the bonding strength between the substrate and the underfill resin. Consequently, the foregoing structure allows, in the flip-chip connection of the semiconductor chip to the substrate, stably forming the filet of the underfill resin in a uniform shape, attaining at the same time the enhanced bonding strength. 
     It is to be noted that a different combination of the foregoing constituents, and a conversion of the expression of the present invention between a method and a device are also included in the scope of the present invention. 
     Thus, the present invention allows, in flip-chip connection of a semiconductor chip to a substrate, stably forming a filet of an underfill resin in a uniform shape, attaining at the same time enhanced bonding strength. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
       The above and other objects, advantages and features of the present invention will be more apparent from the following description taken in conjunction with the accompanying drawings, in which: 
         FIG. 1  is a cross-sectional view showing a structure of a semiconductor device according to an embodiment of the present invention; 
         FIG. 2  is a plan view showing a structure of the semiconductor device according to the embodiment of the present invention; 
         FIGS. 3A to 3C  are cross-sectional views for explaining in sequence a manufacturing process of the semiconductor device according to the embodiment of the present invention; 
         FIG. 4  is a flowchart showing a manufacturing process of the semiconductor device according to the embodiment of the present invention; 
         FIG. 5  is a flowchart showing another manufacturing process of the semiconductor device according to the embodiment of the present invention; 
         FIG. 6  is a cross-sectional view showing a structure of a first resin composition and a second resin composition according to the embodiment of the present invention; 
         FIG. 7  is a cross-sectional view showing another structure of the semiconductor device according to the embodiment of the present invention; 
         FIG. 8  is a cross-sectional view showing still another structure of the semiconductor device according to the embodiment of the present invention; 
         FIGS. 9A to 9C  are cross-sectional views for explaining in sequence another manufacturing process of the semiconductor device according to the embodiment of the present invention; 
         FIGS. 10A and 10B  are cross-sectional views showing examples of the structure of the first resin composition and the second resin composition according to the embodiment of the present invention; and 
         FIGS. 11A to 11C  are cross-sectional views for explaining in sequence still another manufacturing process of the semiconductor device according to the embodiment of the present invention. 
     
    
    
     DETAILED DESCRIPTION 
     The invention will be now described herein with reference to illustrative embodiments. Those skilled in the art will recognize that many alternative embodiments can be accomplished using the teachings of the present invention and that the invention is not limited to the embodiments illustrated for explanatory purposes. 
     Hereafter, an embodiment of the present invention will be described referring to the drawings. In all the drawings, the same constituents will be given the same numeral, and the description thereof will not be repeated. 
       FIG. 1  is a cross-sectional view showing a structure of a semiconductor device according to an embodiment of the present invention.  FIG. 2  is a plan view showing a structure of the semiconductor device according to this embodiment.  FIG. 1  corresponds to the cross-sectional view taken along a line a-a in  FIG. 2 . 
     The semiconductor device  100  includes a substrate  102 , a semiconductor chip  130  mounted on the substrate  102 , and an underfill resin  120  formed between the substrate  102  and the semiconductor chip  130 . On a surface of the substrate  102  (upper surface according to  FIG. 1 ), pads  140  are provided. In this embodiment, the substrate  102  may be a multilayer interconnect substrate including a plurality of interconnect layers. The semiconductor chip  130  includes an element-carrying surface on which bumps  132  are provided. The bump  132  may be constituted of, for example, a solder ball. The semiconductor chip  130  is mounted on the surface of the substrate  102  such that the element-carrying surface confronts the upper surface of the substrate  102 . The semiconductor chip  130  is electrically connected in a flip-chip style to the pads  140 , through the bumps  132 . 
     The underfill resin  120  is provided on the surface of the substrate  102  and between the substrate  102  and the semiconductor chip  130 , and includes a filet  120   a  provided around the semiconductor chip  130  on the surface of the substrate  102 . In this embodiment, the underfill resin  120  includes a first resin layer  122  constituted of a first resin composition and a second resin layer  124  constituted of a second resin composition, such that the first resin layer and the second resin layer are superposed on each other in at least a part of a region overlapping with the semiconductor chip  130  in a plan view. 
     The second resin layer  124  constitutes an upper layer over the first resin layer  122 . Also, the first resin layer  122  may be formed over an area larger than a half of a region where the underfill resin  120  is in contact with the substrate  102 . 
     In the example shown in  FIG. 1 , both of the first resin layer  122  and the second resin layer  124  are provided over an area including the region overlapping with the semiconductor chip  130  in a plan view and the entirety of the filet  120   a . Here, substantially the entirety of the region where the substrate  102  and the underfill resin  120  are in contact is occupied with the first resin layer  122 . In this example, also, the four corner portions of the semiconductor chip  130 , on the side thereof confronting the substrate  102 , may be covered with the second resin layer  124 . Such structure enhances the bonding strength between the second resin layer  124  and the semiconductor chip  130 . Also, connection points of the pad  140  and the bump  132  may be located inside the first resin layer  122 . 
     Here, the first resin composition constituting the first resin layer  122 , and the second resin composition constituting the second resin layer  124  may respectively contain, as prime materials, a resin serving as the base resin, a hardener, and a filler. The filler may be silica or alumina filler, for example. 
     The first resin composition and the second resin composition may be constituted of, for example, a thermosetting resin. In this case, such resins that are different in fluidity before curing (forming) or during heat-pressing for curing (forming) may be employed for the first resin composition and the second resin composition. 
     For example, the first resin composition and the second resin composition may have different filler contents (wt. %) with respect to the overall resin composition. Reducing the content (wt. %) of the filler leads to higher fluidity of the resin composition. A difference in filler content (wt. %) with respect to the overall resin composition between the first resin composition and the second resin composition may be, for example, 1% or higher. 
     For example, the first resin composition and the second resin composition may be different in average particle diameter of the filler respectively contained therein. Increasing the average particle diameter of the filler leads to higher fluidity of the resin composition. A difference in average particle diameter of the filler between the first resin composition and the second resin composition may be, for example, 5 μm or greater. 
     For example, also, the first resin composition the second resin composition may be different in viscosity before the curing or during the heat-pressing for curing the under fill resin. Increasing the viscosity of the resin composition facilitates forming the filet in a desired uniform shape. 
     Also, the first resin composition and the second resin composition may be different, for example, in glass transition temperature (Tg). A difference in glass transition temperature between the first resin composition and the second resin composition may be, for example, 5° C. or greater. 
     Further, the first resin composition and the second resin composition may be different, for example, in type or ratio of the prime material. The first resin composition and the second resin composition may contain, for example, different resins that serve as the base resin, or different hardeners. 
     Further, the first resin layer  122  and the second resin layer  124  may be different, for example, in insulating performance. For example, the first resin layer  122  and the second resin layer  124  may be formed such that at least one thereof contains conductive particles, and that the content of the conductive particles is different from each other. Also, the other of the first resin layer  122  and the second resin layer  124  may be formed without using the conductive particles. 
     Now, specific examples will be given hereunder about the structure of the first resin layer  122  and the second resin layer  124  according to this embodiment. 
     In this embodiment, the first resin layer  122  may be constituted of a material suitable for assuring the effective connection of the pad  140  of the substrate  102  and the bump  132  of the semiconductor chip  130 . Also, the first resin layer  122  may be constituted of a material having a thermal expansion coefficient close to that of the substrate  102 . For example, the first resin layer  122  may be constituted of a material having a glass transition temperature Tg closer to that of the substrate  102  than the second resin layer  124  is. Further, the first resin layer  122  may have higher conductivity than the second resin layer  124 . 
     On the other hand, the second resin layer  124  may be constituted of a material suitable for assuring the effective connection of the semiconductor chip  130  and the substrate  102 . The second resin layer  124  may be constituted of a material that can be easily controlled for forming the filet  120   a  in a uniform shape. Also, the second resin layer  124  may be constituted of a material having higher insulativeness than the first resin layer  122 . 
     Based on the foregoing viewpoints, the first resin layer  122  may have, for example, a higher elastic modulus than that of the second resin layer  124 . Such arrangement can make the first resin layer  122  harder than the second resin layer  124 , thereby reinforcing the connection between the pad  140  and the bump  132 . Conversely, making the second resin layer  124  softer facilitates controlling the shape of the filet  120   a  of the underfill resin  120 . 
     Also, the first resin layer  122  and the second resin layer  124  may be constituted of a thermosetting resin, such that the second resin composition obtains higher fluidity than the first resin composition before the curing or during the heat-pressing for curing. To attain such structure, for example the first resin composition may have a higher filler content (wt. %) with respect to the entirety of the first resin composition, than that of the second resin composition with respect to the entirety of the second resin composition. Another example for attaining the foregoing structure is employing a filler of a smaller average particle diameter for the first resin composition, than for the second resin composition. 
     Also, the second resin composition may have, for example, higher viscosity before the curing of the underfill resin or during the heat-pressing for curing the underfill resin, than the first resin composition. Forming the second resin composition in higher viscosity facilitates forming the filet in a desired uniform shape. 
     Further, the first resin layer  122  may contain, for example, the same resin as that constituting the substrate  102 , as the resin that serves as the base resin. For example, the substrate  102  may have a multilayer interconnect structure including a polyimide resin and interconnect layers sequentially stacked. In this case, the first resin layer  122  may contain the polyimide resin as the resin that serves as the base resin. Such structure can make the glass transition temperature Tg of the first resin layer  122  closer to that of the substrate  102 , and the thermal expansion coefficient to that of the substrate  102 . Accordingly, the underfill resin  120  and the substrate  102  exhibit similar behavior despite the expansion or contraction thereof after the curing of the underfill resin, which leads to enhancing the bonding strength between the substrate  102  and the first resin layer  122 . Consequently, positional deviation between the pad  140  and the bump  132  located inside the first resin layer  122  can be suppressed despite the expansion of the substrate  102  and the underfill resin  120 , and therefore effective connection between the pad  140  and the bump  132  can be secured. Also, the structure shown in  FIG. 1 , in which the first resin layer  122  is provided over the area including the region overlapping with the semiconductor chip  130  and the entirety of the filet  120   a , mitigates the stress between the substrate  102  and the underfill resin  120 , thereby further assuring the effective connection therebetween. 
     Meanwhile, the second resin layer  124  may contain an epoxy resin as the base resin. Employing the epoxy resin for the second resin layer  124  can make the Young&#39;s modulus of the second resin layer  124 , the upper layer over the first resin layer  122 , lower than that of the first resin layer  122 , thereby facilitating forming the filet  120   a  in a desired uniform shape. Forming thus the filet  120   a  constituted of the second resin layer  124  in the desired uniform shape allows ensuring the adhesion of the semiconductor chip  130  and the underfill resin  120 . In this example, also, the corner portions of the semiconductor chip  130  on the side confronting the substrate  102  are covered with the second resin layer  124 , which further assures the adhesion between the semiconductor chip  130  and the underfill resin  120 . 
     Further, the first resin composition may contain, for example, conductive particles. Examples of the material constituting the conductive particles include metals such as gold, silver, copper, palladium, aluminum, and nickel, and carbon-based materials. Employing such materials allows improving the electrical connection between the pad  140  and the bump  132 . On the other hand, the second resin composition may be formed without using the conductive particle. In this case, the insulativeness of the second resin layer  124  can be further assured. 
     In this embodiment, the foregoing materials that constitute the first resin layer  122  and the second resin layer  124  may be employed in desired combinations. For example, in the case where the first resin layer  122  contains the polyimide resin containing the conductive particles as the base resin, the second resin layer  124  may contain the epoxy resin that does not contain the conductive particles, as the base resin. 
     Hereunder, description will be given on a manufacturing process of the semiconductor device  100  according to this embodiment. 
       FIGS. 3A to 3C  are cross-sectional views for explaining in sequence a manufacturing process of the semiconductor device  100  shown in  FIGS. 1 and 2 .  FIG. 4  is a flowchart showing the manufacturing process of the semiconductor device  100 . 
     The first resin composition  122   a  before the heat-pressing of the first resin layer  122 , and the second resin composition  124   a  before the heat-pressing of the second resin layer  124  may be respectively prepared in various forms including a film such as a die attach film, and paste. The following description represents the case where the first resin composition  122   a  and the second resin composition  124   a  are prepared in a form of a film. 
     First, the first resin composition  122   a  is placed on the substrate  102  on which the pads  140  are provided ( FIG. 3A , and step S 100  in  FIG. 4 ). Then the second resin composition  124   a  is placed on the first resin composition  122   a  on the substrate  102  ( FIG. 3B , and step S 102  in  FIG. 4 ). The semiconductor chip  130  is then placed on the second resin composition  124   a  on the substrate  102  ( FIG. 3C , and step S 104  in  FIG. 4 ). This is followed by a positioning process between the substrate  102  and the semiconductor chip  130 , and a heat-pressing process from over the semiconductor chip  130  (step S 106  in  FIG. 4 ). The condition for the heat-pressing differs depending on the type of the resin composition employed, but generally may be set at approx. 20 gf/bump to 100 gf/bump in pressure, and approx. 200° C. to 300° C. in temperature. 
     Such process connects the bumps  132  and the pads  140 , and bonds the first resin composition  122   a  and the second resin composition  124   a  to the substrate  102  and the semiconductor chip  130 , respectively. Here, the heat-pressing process also bonds the first resin composition  122   a  and the second resin composition  124   a  together. Through the foregoing process, the first resin composition  122   a  and the second resin composition  124   a  are cured or formed, and the semiconductor device  100  having the structure as shown in  FIG. 1  can be obtained. 
     Alternatively, the second resin composition  124   a  constituting the upper layer may be a resin solution. In this case, although the semiconductor chip  130  may be placed on the second resin composition  124   a  after stacking it on the first resin composition  122   a  as shown in  FIG. 4 , a different process may be adopted, for example as the flowchart shown in  FIG. 5 . 
     In this process also, firstly the first resin composition  122   a  is placed on the substrate  102  on which the pads  140  are provided (step S 120 ). Then the semiconductor chip  130  is placed on the first resin composition  122   a  on the substrate  102  (step S 122 ). At this stage, a gap may be formed between the first resin composition  122   a  and the semiconductor chip  130 . Here, the positioning between the substrate  102  and the semiconductor chip  130  is executed. Then the second resin composition  124   a , which is a resin solution, is injected into between the first resin composition  122   a  and the semiconductor chip  130  (step S 124 ). This is followed by the heat-pressing from over the semiconductor chip  130 , as shown in  FIG. 4  (step S 126 ). Such process connects the bumps  132  and the pads  140 , and bonds the first resin composition  122   a  and the second resin composition  124   a  to the substrate  102  and the semiconductor chip  130 , respectively. Here, the heat-pressing process also bonds the first resin composition  122   a  and the second resin composition  124   a  together. Thus, the first resin composition  122   a  and the second resin composition  124   a  are cured or formed, and the semiconductor device  100  having the structure as shown in  FIG. 1  can be obtained. 
     As shown in  FIG. 6 , an adhesive  126  may be provided between the first resin composition  122   a  and the second resin composition  124   a  before the heat-pressing process, to thereby form a two-layer film. In this case, the semiconductor chip  130  may be mounted on those resin compositions after mounting them on the substrate  102 , and then the heat-pressing may be executed. Such process also provides the semiconductor device  100  having the structure as shown in  FIG. 1 . 
     For example, a film containing an epoxy resin as the base resin, such as T693/R6000 series manufactured by Nagase ChemteX Corporation, a paste such as T693/UFR series manufactured by Nagase ChemteX Corporation, and a resin solution such as T693/R3000 series manufactured by Nagase ChemteX Corporation may be employed for the second resin composition  124   a . For the first resin composition  122   a , for example a polyimide-based film such as DF series manufactured by Hitachi Chemical Co., Ltd. may be employed. 
     Also, though the first resin layer  122  is also provided over the area including the region overlapping with the semiconductor chip  130  and the entirety of the filet  120   a  in the example shown in  FIG. 1 , the first resin layer  122  may be formed in a region corresponding to only a part of the filet  120   a , as shown in  FIG. 7 . In this case also, the first resin layer  122  is provided over the entirety of the region overlapping with the semiconductor chip  130  in a plan view. In such structure, also, the majority of the region where the underfill resin  120  is in contact with the substrate  102  is occupied with the first resin layer  122 , and the connection points between the pad  140  and the bump  132  are located inside the first resin layer  122 . Accordingly, the advantages offered by the structure shown in  FIG. 1  can be equally obtained. 
       FIGS. 8 and 9A  to  9 C illustrate another example of the structure of the semiconductor device  100  according to this embodiment.  FIG. 8  is a cross-sectional view of the semiconductor device  100 , and  FIGS. 9A to 9C  are cross-sectional views for explaining in sequence the manufacturing process of the semiconductor device  100  shown in  FIG. 8 . 
     This example is different from the structure shown in  FIG. 1  in that the first resin layer  122  of the underfill resin  120  is only provided in the region overlapping with the semiconductor chip  130 , and barely provided in the region corresponding to the filet  120   a.    
     The semiconductor device  100  thus configured can be obtained for example by forming the first resin layer  122  in a smaller size than the second resin layer  124 , as shown in  FIGS. 9A to 9C . Also, as shown in  FIG. 10A , the second resin composition  124   a , for example of a paste form, may be squeezed by a roll  128  into a recess formed on the first resin composition  122   a , for example of a film form, and a unified type resin composition may be formed by heat-pressing as shown in  FIG. 10B . Then the semiconductor device  100  of the structure shown in  FIG. 8  can also be obtained by placing the resin composition thus formed on the substrate  102  in the same way as  FIG. 9B , and placing the semiconductor chip  130  on the resin composition and executing the heat-pressing. 
     The semiconductor device  100  and the manufacturing method thereof according to this embodiment offer the following advantageous effects. 
     In the foregoing semiconductor device  100 , the second resin layer  124  is formed over the area including the filet  120   a  and the region overlapping with the semiconductor chip  130  in a plan view. Such structure allows dispersing, in an in-plane direction of the substrate, the stress of the second resin layer  124  arising from expansion or contraction of the substrate  102  and the semiconductor chip  130  after the curing of the underfill resin  120 , in the case where an appropriate material for forming the filet in a desirable shape is employed for the second resin layer  124 . Meanwhile regarding the first resin layer  122 , for example employing a material having a thermal expansion coefficient close to that of the substrate  102  enables enhancing the bonding strength between the substrate  102  and the semiconductor chip  130 . Consequently, the foregoing structure allows, in the flip-chip connection of the semiconductor chip  130  to the substrate  102 , achieving an optimal balance between obtaining sufficient bonding strength and stably forming the filet of the semiconductor chip  130  in a uniform shape. 
     In this embodiment, also, the four corner portions of the semiconductor chip  130  on the side confronting the substrate  102  are covered with the second resin layer  124 . Accordingly, the corner portions are free from an interface between the plurality of resin layers, which contributes to enhancing the bonding strength between the second resin layer  124  and the semiconductor chip  130 . 
     Also, the connection points between the pad  140  and the bump  132  are located inside the first resin layer  122 . Therefore the first resin layer  122  serves to assure the effective connection of the pad  140  and the bump  132 . The electrical connection between the pad  140  and the bump  132  can also be assured by, for example, providing a material containing conductive particles in the first resin layer  122 . 
     Further, in order to enhance the bonding strength between the substrate  102  and the semiconductor chip  130  through the foregoing process, the heat-pressing has to be executed under a high pressure. However, increasing the pressure urges the filet  120   a  to creep upward to the upper surface of the semiconductor chip  130 , thereby making it difficult to form the filet  120   a  in a uniform shape. In this embodiment, however, since a material that facilitates controlling the shape of the filet is employed for the second resin layer  124 , the filet  120   a  can be formed in a uniform shape. 
     Stabilizing the shape of the filet allows improving the reliability (temperature cycle resistance). Also, suppressing the filet from excessively spreading leads to improvement in mounting efficiency. 
     Forming a narrow gap between the semiconductor chip and the substrate may make it difficult to fill the gap with the underfill resin, however locating the first resin composition  122   a  and the second resin composition  124   a  on the substrate  102  as shown in  FIG. 4  before mounting the semiconductor chip  130  allows eliminating such disadvantage and assuring optimal formation of the underfill resin. 
     Although the embodiment of the present invention has been described in details as above referring to the drawings, the embodiment is only exemplary and various other structures may be adopted in the scope of the present invention. 
     One of the first resin composition  122   a  and the second resin composition  124   a  may be constituted of a thermosetting resin, and the other may be constituted of a thermoplastic resin. For example, the thermosetting resin may be employed for the first resin layer  122 , and the thermoplastic resin for the second resin layer  124 . In this case, the second resin composition  124   a  obtains higher fluidity than that of the first resin composition  122   a.    
     Although the underfill resin  120  contains two types of resin layers in the foregoing embodiment, the underfill resin  120  may contain three or more types of resin layers. In this case also, the underfill resin  120  can equally be cured by executing the heat-pressing process with the resin compositions constituting the respective resin layers stacked on each other. 
     Also, although the foregoing embodiment exemplifies the case where the second resin layer  124  is provided on top of the first resin layer  122 , the first resin layer  122  may constitute the upper layer over the second resin layer  124 .  FIGS. 11A to 11C  are cross-sectional views for explaining in sequence a manufacturing process of the semiconductor device  100  thus configured. Such structure can also be obtained through the same manufacturing process as that described referring to  FIGS. 3A to 3B  and  FIG. 4 . 
     In the foregoing structure also, the second resin layer  124  may be formed over the area including the filet  120   a  and the region overlapping with the semiconductor chip  130  in a plan view. Such structure allows dispersing, in an in-plane direction of the substrate, the stress of the second resin layer  124  arising from expansion or contraction of the substrate  102  and the semiconductor chip  130  after the curing of the underfill resin  120 , in the case where an appropriate material for forming the filet in a desirable shape is employed for the second resin layer  124 . Meanwhile regarding the first resin layer  122 , for example employing a material having a thermal expansion coefficient close to that of the substrate  102  enables enhancing the bonding strength between the substrate  102  and the semiconductor chip  130 . Consequently, the foregoing structure allows, in the flip-chip connection of the semiconductor chip  130  to the substrate  102 , achieving an optimal balance between obtaining sufficient bonding strength and stably forming the filet of the semiconductor chip  130  in a uniform shape. 
     Such structure offers further advantage that the first resin layer  122  serves as a block that prevents the second resin composition  124   a  from creeping upward to the surface of the semiconductor chip  130  opposite to the surface thereof confronting the substrate  102  (upper surface according to the drawings), during the formation of the filet  120   a  of the second resin composition  124   a . This leads to stabilization of the shape of the filet, and to improvement in reliability (temperature cycle resistance). Also, suppressing the filet from excessively spreading leads to improvement in mounting efficiency. 
     It is apparent that the present invention is not limited to the above embodiment, and may be modified and changed without departing from the scope and spirit of the invention.