Patent Publication Number: US-2020288713-A1

Title: Pesticidally active pyrazole derivatives

Description:
The present invention relates to pyrazole derivatives, to processes for preparing them, to intermediates for preparing them, to pesticidal, in particular insecticidal, acaricidal, molluscicidal and nematicidal compositions comprising those derivatives and to methods of using them to combat and control pests such as insect, acarine, mollusc and nematode pests. 
     It has now surprisingly been found that certain pyrazole derivatives have highly potent insecticidal properties. Other compounds in this area are known from WO2014/122083, WO2012/107434, WO2015/067646, WO2015/067647, WO2015/067648, WO2015/150442, WO2015/193218 and WO2010/051926. 
     Thus, as embodiment 1, the present invention provides a compound of formula (I), 
     
       
         
         
             
             
         
       
     
     wherein 
     R 1  is selected from H, C 1 -C 6 -alkyl, C 2 -C 6  alkenyl, C 2 -C 6  alkynyl, C 3 -C 7  cycloalkyl, C 3 -C 7  cycloalkyl-C 1 -C 3 -alkyl, C 1 -C 6 -alkylcarbonyl, C 3 -C 7  cycloalkylcarbonyl, C 1 -C 6 -alkoxycarbonyl, C 1 -C 6 -alkoxy-C 1 -C 6 -alkyl, aryl(C 0 -C 3 )-alkyl and heteroaryl(C 0 -C 3 )-alkyl, wherein each of C 1 -C 6 -alkyl, C 2 -C 6  alkenyl, C 2 -C 6  alkynyl, C 3 -C 7  cycloalkyl, C 3 -C 7  cycloalkyl-C 1 -C 3 -alkyl, C 1 -C 6 -alkylcarbonyl, C 3 -C 7  cycloalkylcarbonyl, C 1 -C 6 -alkoxycarbonyl, C 1 -C 6 -alkoxy-C 1 -C 6 -alkyl, aryl(C 0 -C 3 )-alkyl and heteroaryl(C 0 -C 3 )-alkyl is unsubstituted or substituted with 1 to 5 substituents independently selected from halogen, cyano, C 1 -C 6 -alkoxy and C 1 -C 6 -alkoxycarbonyl; 
     Q is H or cyano; 
     or an agrochemically acceptable salt or N-oxide thereof. 
     Preferred values of R 1  and Q in relation to each compound of the present invention, including the intermediate compounds, are set out below in embodiments 1 to 7. 
     As embodiment 2, there is provided a compound or salt according to embodiment 1 wherein R 1  is selected from H, C 1 -C 6 -alkyl, C 2 -C 6  alkynyl, C 3 -C 7  cycloalkyl-C 1 -C 3 -alkyl, C 1 -C 6 -alkylcarbonyl, C 3 -C 7  cycloalkylcarbonyl, C 1 -C 6 -alkoxycarbonyl and C 1 -C 6 -alkoxy-C 1 -C 6 -alkyl, wherein each of C 1 -C 6 -alkyl, C 2 -C 6  alkynyl, C 3 -C 7  cycloalkyl-C 1 -C 3 -alkyl, C 1 -C 6 -alkylcarbonyl, C 3 -C 7  cycloalkylcarbonyl, C 1 -C 6 -alkoxycarbonyl and C 1 -C 6 -alkoxy-C 1 -C 6 -alkyl is unsubstituted or substituted with 1 to 5 substituents independently selected from halogen, cyano, C 1 -C 6 -alkoxy and C 1 -C 6 -alkoxycarbonyl. 
     As embodiment 3, there is provided a compound or salt according to embodiment 1 or 2 wherein R 1  is selected from H, methyl, ethyl, isobutyl, 2,2,2-trifluoroethyl, —C(═O)CH 3 , —C(═O)CH 2 CH 3 , —C(═O)cyclopropyl, —C(═O)OCH 3 , —C(═O)OCH 2 CH 3 , —C(═O)CH(CH 3 )(CH 3 ), —CH 2 —C—CH, —CH 2 CN, —CH 2 —O—CH 3 , —CH 2 —O—CH 2 —CH 3  and —CH 2 -cyclopropyl. 
     As embodiment 4, there is provided a compound or salt according to any one of embodiments 1 to 3 wherein R 1  is selected from H, methyl, ethyl, —C(═O)CH 3 , —C(═O)CH 2 CH 3 , —C(═O)cyclopropyl, —C(═O)OCH 3 , —C(═O)OCH 2 CH 3 , —CH 2 —C—CH, —CH 2 CN, —CH 2 —O—CH 3 , —CH 2 —O—CH 2 —CH 3  and —CH 2 -cyclopropyl. 
     As embodiment 5, there is provided a compound or salt according to any one of embodiments 1 to 4 wherein R 1  is selected from H, methyl and ethyl. 
     As embodiment 6, there is provided a compound or salt according to any one of embodiments 1 to 5 wherein Q is cyano. 
     As embodiment 7, there is provided a compound or salt according to any one of embodiments 1 to 6 wherein the compound is selected from 
     
       
         
           
               
               
               
             
               
                   
               
               
                 Ex. 
                   
                   
               
               
                 No. 
                 Structure 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
            
               
                 1 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 N-(1-cyanocyclopropyl)-5- [1-[4-(difluoromethoxy)-2- methyl-5-(1,1,2,2,2- pentafluoroethyl)pyrazol-3- yl]pyrazol-4-yl]-2- (trifluoromethyl)benzamide 
               
               
                   
               
               
                 2 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 N-(1-cyanocyclopropyl)-5- [1-[4-(difluoromethoxy)-2- methyl-5-(1,1,2,2,2- pentafluoroethyl)pyrazol-3- yl]pyrazol-4-yl]-N-methyl-2- (trifluoromethyl)benzamide; 
               
               
                   
               
               
                 3 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 N-(1-cyanocyclopropyl)-5- [1-[4-(difluoromethoxy)-2- methyl-5-(1,1,2,2,2- pentafluoroethyl)pyrazol-3- yl]pyrazol-4-yl]-N-ethyl-2- (trifluoromethyl)benzamide; 
               
               
                   
               
               
                 4 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 N-cyclopropyl-5-[1-[4- (difluoromethoxy)-2-methyl- 5-(1,1,2,2,2- pentafluoroethyl)pyrazol-3- yl]pyrazol-4-yl]-2- (trifluoromethyl)benzamide. 
               
               
                   
               
               
                 5 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 N-(1-cyanocyclopropyl)-N- (cyclopropylmethyl)-5-[1-[4- (difluoromethoxy)-2-methyl- 5-(1,1,2,2,2- pentafluoroethyl)pyrazol-3- yl]pyrazol-4-yl]-2- (trifluoromethyl)benzamide 
               
               
                   
               
               
                 6 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 N-acetyl-N-(1- cyanocyclopropyl)-5-[1-[4- (difluoromethoxy)-2-methyl- 5-(1,1,2,2,2- pentafluoroethyl)pyrazol-3- yl]pyrazol-4-yl]-2- (trifluoromethyl)benzamide 
               
               
                   
               
               
                 7 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 N-(1-cyanocyclopropyl)-5- [1-[4-(difluoromethoxy)-2- methyl-5-(1,1,2,2,2- pentafluoroethyl)pyrazol-3- yl]pyrazol-4-yl]-N- (methoxymethyl)-2- (trifluoromethyl)benzamide 
               
               
                   
               
               
                 8 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 N-(1-cyanocyclopropyl)-N- (cyanomethyl)-5-[1-[4- (difluoromethoxy)-2-methyl- 5-(1,1,2,2,2- pentafluoroethyl)pyrazol-3- yl]pyrazol-4-yl]-2- (trifluoromethyl)benzamide 
               
               
                   
               
               
                 9 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 ethyl N-(1- cyanocyclopropyl)-N-[5-[1- [4-(difluoromethoxy)-2- methyl-5-(1,1,2,2,2- pentafluoroethyl)pyrazol-3- yl]pyrazol-4-yl]-2- (trifluoromethyl)benzoyl] carbamate 
               
               
                   
               
               
                 10 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 N-(1-cyanocyclopropyl)-5- [1-[4-(difluoromethoxy)-2- methyl-5-(1,1,2,2,2- pentafluoroethyl)pyrazol-3- yl]pyrazol-4-yl]-prop-2- ynyl-2- (trifluoromethyl)benzamide 
               
               
                   
               
            
           
         
       
     
     Definitions 
     The term “alkyl” as used herein—in isolation or as part of a chemical group—represents straight-chain or branched hydrocarbons, preferably with 1 bis 6 carbon atoms, for example methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, s-butyl, t-butyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,2-dimethylpropyl, 1,1-dimethylpropyl, 2,2-dimethylpropyl, 1-ethylpropyl, hexyl, 1-methylpentyl, 2-methylpentyl, 3-methylpentyl, 4-methylpentyl, 1,2-dimethylpropyl, 1,3-dimethylbutyl, 1,4-dimethylbutyl, 2,3-dimethylbutyl, 1,1-dimethylbutyl, 2,2-dimethylbutyl, 3,3-dimethylbutyl, 1,1,2-trimethylpropyl, 1,2,2-trimethylpropyl, 1-ethylbutyl and 2-ethylbutyl. Alkyl groups with 1 to 4 carbon atoms are preferred, for example methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, s-butyl or t-butyl. 
     The term “alkenyl”—in isolation or as part of a chemical group—represents straight-chain or branched hydrocarbons, preferably with 2 bis 6 carbon atoms and at least one double bond, for example vinyl, 2-propenyl, 2-butenyl, 3-butenyl, 1-methyl-2-propenyl, 2-methyl-2-propenyl, 2-pentenyl, 3-pentenyl, 4-pentenyl, 1-methyl-2-butenyl, 2-methyl-2-butenyl, 3-methyl-2-butenyl, 1-methyl-3-butenyl, 2-methyl-3-butenyl, 3-methyl-3-butenyl, 1,1-dimethyl-2-propenyl, 1,2-dimethyl-2-propenyl, 1-ethyl-2-propenyl, 2-hexenyl, 3-hexenyl, 4-hexenyl, 5-hexenyl, 1-methyl-2-pentenyl, 2-methyl-2-pentenyl, 3-methyl-2-pentenyl, 4-methyl-2-pentenyl, 3-methyl-3-pentenyl, 4-methyl-3-pentenyl, 1-methyl-4-pentenyl, 2-methyl-4-pentenyl, 3-methyl-4-pentenyl, 4-methyl-4-pentenyl, 1, 1-dimethyl-2-butenyl, 1,1-dimethyl-3-butenyl, 1,2-dimethyl-2-butenyl, 1,2-dimethyl-3-butenyl, 1,3-dimethyl-2-butenyl, 2,2-dimethyl-3-butenyl, 2,3-dimethyl-2-butenyl, 2,3-dimethyl-3-butenyl, 1-ethyl-2-butenyl, 1-ethyl-3-butenyl, 2-ethyl-2-butenyl, 2-ethyl-3-butenyl, 1, 1,2-trimethyl-2-propenyl, 1-ethyl-1-methyl-2-propenyl und 1-ethyl-2-methyl-2-propenyl. Alkenyl groups with 2 to 4 carbon atoms are preferred, for example 2-propenyl, 2-butenyl or 1-methyl-2-propenyl. 
     The term “alkynyl”—in isolation or as part of a chemical group—represents straight-chain or branched hydrocarbons, preferably with 2 bis 6 carbon atoms and at least one triple bond, for example 2-propynyl, 2-butynyl, 3-butynyl, 1-methyl-2-propynyl, 2-pentynyl, 3-pentynyl, 4-pentynyl, 1-methyl-3-butynyl, 2-methyl-3-butynyl, 1-methyl-2-butynyl, 1,1-dimethyl-2-propynyl, 1-ethyl-2-propynyl, 2-hexynyl, 3-hexynyl, 4-hexynyl, 5-hexynyl, 1-methyl-2-pentynyl, 1-methyl-3-pentynyl, 1-methyl-4-pentynyl, 2-methyl-3-pentynyl, 2-methyl-4-pentynyl, 3-methyl-4-pentynyl, 4-methyl-2-pentynyl, 1,1-dimethyl-3-butynyl, 1,2-dimethyl-3-butynyl, 2,2-dimethyl-3-butynyl, 1-ethyl-3-butynyl, 2-ethyl-3-butynyl, 1-ethyl-1-methyl-2-propynyl and 2,5-hexadiynyl. Alkynyls with 2 to 4 carbon atoms are preferred, for example ethynyl, 2-propynyl or 2-butynyl-2-propenyl. 
     The term “cycloalkyl”—in isolation or as part of a chemical group—represents saturated or partially unsaturated mono-, bi- or tricyclic hydrocarbons, preferably 3 to 10 carbon atoms, for example cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, bicyclo[2.2.1]heptyl, bicyclo[2.2.2]octyl or adamantyl. 
     Cycloalkyls with 3, 4, 5, 6 or 7 carbon atoms are preferred, for example cyclopropyl or cyclobutyl. 
     The term “cycloalkylalkyl” represents mono, bi- or tricyclic cycloalkylalkyls, preferably 4 to 10 or 4 to 7 carbon atoms, for example cyclopropylmethyl, cyclobutylmethyl, cyclopentylmethyl, cyclohexylmethyl and cyclopentylethyl. Cycloalkylalkyls with 4, 5 or 7 carbon atoms are preferred, for example cyclopropylmethyl or cyclobutylmethyl. 
     The term “halogen” or “halo” represents fluoro, chloro, bromo or iodo, particularly fluoro, chloro or bromo. The chemical groups which are substituted with halogen, for example haloalkyl, halocycloalkyl, haloalkyloxy, haloalkylsulfanyl, haloalkylsulfinyl or haloalkylsulfonyl are substituted one or up to the maximum number of substituents with halogen. If “alkyl”, “alkenyl” or “alkynyl” are substituted with halogen, the halogen atoms can be the same or different and can be bound at the same carbon atom or different carbon atoms. 
     The term “haloalkyl”, “haloalkenyl” or “haloalkynyl” represents alkyls, alkenyls or alkynyls substituted with halogen, preferably with 1 to 9 halogen atoms that are the same or different, for example monohaloalkyls (=monohaloalkyl) like CH 2 CH 2 Cl, CH 2 CH 2 F, CHClCH 3 , CHFCH 3 , CH 2 Cl, CH 2 F; perhaloalkyls like CCl 3  or CF 3  or CF 2 CF 3 ; polyhaloalkyls like CHF 2 , CH 2 F, CH 2 CHFCl, CF 2 CF 2 H, CH 2 CF 3 . The same applies for haloalkenyl and other groups substituted by halogen. 
     Examples of haloalkoxy are for example OCF 3 , OCHF 2 , OCH 2 F, OCF 2 CF 3 , OCH 2 CF 3 , OCF 3 , OCHF 2 , OCH 2 F, OCF 2 CF 3 , OCH 2 CF 3 . 
     Further examples of haloalkyls are trichloromethyl, chlorodifluoromethyl, dichlorofluoromethyl, 1-fluoroethyl, 2-fluoroethyl, 2,2-difluoroethyl, 2,2,2-trifluorethyl, 2,2,2-trichloroethyl, 2-chloro-2,2-difluoroethyl, pentafluorethyl and pentafluoro-t-butyl. 
     Haloalkyls having 1 to 4 carbon atoms and 1 to 9, preferably 1 to 5 of the same or different halogen atoms selected from fluoro, chloro or bromo, are preferred. 
     Haloalkyls having 1 or 2 carbon atoms and 1 to 5 gleichen of the same or different halogen atoms selected from fluoro or chloro, for example difluoromethyl, trifluoromethyl or 2,2-difluoroethyl, are particularly preferred. 
     The term “alkoxy” represents straight or branched chain O-alkyl, preferably having 1 to 6 carbon atoms, for example methoxy, ethoxy, n-propoxy, isopropoxy, n-butoxy, isobutoxy, s-butoxy und t-butoxy. Alkoxy having 1 to 4 carbon atoms are preferred. 
     The term “haloalkoxy” represents straight or branched chain O-alkyl substituted with halogen, preferably with 1 to 6 carbon atoms, for example difluoromethoxy, trifluoromethoxy, 2,2-difluoroethoxy, 1,1,2,2-tetrafluoroethoxy, 2,2,2-Trifluoroethoxy and 2-Chloro-1,1,2-trifluoroethoxy. 
     Haloalkoxy having 1 to 4 carbon atoms are preferred. 
     The term “alkylcarbonyl” represents straight or branched chain alkyl-C(═O), preferably having 2 to 7 carbon atoms, for example methylcarbonyl, ethylcarbonyl, n-propylcarbonyl, isopropylcarbonyl, s-butylcarbonyl and t-butylcarbonyl. 
     Alkylcarbonyls having 1 to 4 carbon atoms are preferred. 
     The term “cycloalkylcarbonyl” represents cycloalkyl-carbonyl, preferably 3 to 10 carbon atoms in the cycloalkyl part, for example cyclopropylcarbonyl, cyclobutylcarbonyl, cyclopentylcarbonyl, cyclohexyl-carbonyl, cycloheptyl-carbonyl, cyclooctylcarbonyl, bicyclo[2.2.1]heptyl, bycyclo[2.2.2]octylcarbonyl and adamantylcarbonyl. Cycloalkylcarbonyls having 3, 5 or 7 carbon atoms in the cycloalkyl part are preferred. 
     The term “alkoxycarbonyl”—in isolation or as part of a chemical group—represents straight or branched chain alkoxycarbonyl, preferably having 1 to 6 carbon atoms or 1 to 4 carbon atoms in the alkoxy part, for example methoxycarbonyl, ethoxycarbonyl, n-propoxycarbonyl, isopropoxycarbonyl, s-butoxycarbonyl and t-butoxycarbonyl. 
     The term “aryl” represents a mono-, bi- or polycyclical aromatic system with preferably 6 to 14, more preferably 6 to 10 ring-carbon atoms, for example phenyl, naphthyl, anthryl, phenanthrenyl, preferably phenyl. “Aryl” also represents polycyclic systems, for example tetrahydronaphtyl, indenyl, indanyl, fluorenyl, biphenyl. Arylalkyls are examples of substituted aryls, which may be further substituted with the same or different substituents both at the aryl or alkyl part. Benzyl and 1-phenylethyl are examples of such arylalkyls. 
     The term “heterocyclyl”, “heterocyclic ring” or “heterocyclic ring system” represents a carbocyclic ring system with at least one ring, in which ring at least one carbon atom is replaced by a heteroatom, preferably selected from N, O, S, P, B, Si, Se, and which ring is saturated, unsaturated or partially saturated, and which ring is unsubstituted or substituted with a substituent Z, wherein the connecting bond is located at a ring atom. Unless otherwise defined, the heterocyclic ring has preferably 3 to 9 ring atoms, preferably 3 to 6 ring atoms, and one or more, preferably 1 to 4, more preferably 1, 2 or 3 heteroatoms in the heterocyclic ring, preferably selected from N, O, and S, wherein no O atoms can be located next to each other. The heterocyclic rings normally contain no more than 4 nitrogens, and/or no more than 2 oxygen atoms and/or no more than 2 sulfur atoms. In case that the heterocyclic substituent or the heterocyclic ring are further substituted, it can be further annulated with other heterocyclic rings. 
     The term “heterocyclic” also includes polycyclic systems, for example 8-aza-bicyclo[3.2.1]octanyl or 1-aza-bicyclo[2.2.1]heptyl. 
     The term “heterocyclic” also includes spirocyclic systems, for example 1-oxa-5-aza-spiro[2.3]hexyl. Examples of heterocyclyls are for example piperidinyl, piperazinyl, morpholinyl, thiomorpholinyl, dihydropyranyl, tetrahydropyranyl, dioxanyl, pyrrolinyl, pyrrolidinyl, imidazolinyl, imidazolidinyl, thiazolidinyl, oxazolidinyl, dioxolanyl, dioxolyl, pyrazolidinyl, tetrahydrofuranyl, dihydrofuranyl, oxetanyl, oxiranyl, azetidinyl, aziridinyl, oxazetidinyl, oxaziridinyl, oxazepanyl, oxazinanyl, azepanyl, oxopyrrolidinyl, dioxopyrrolidinyl, oxomorpholinyl, oxopiperazinyl und oxepanyl. 
     Particularly important are heteroaryls, i.e. heteroaromatic systems. 
     The term “heteroaryl” represents heteroaromatic groups, i.e. completely unsaturated aromatic heterocyclic groups, which fall under the above definition of heterocycles. “Heteroaryls” with 5 to 7-membered rings with 1 to 3, preferably 1 or 2 of the same or different heteroatoms selected from N, O, and S. Examples of “heteroaryls” are furyl, thienyl, pyrazolyl, imidazolyl, 1,2,3- and 1,2,4-triazolyl, isoxazolyl, thiazolyl, isothiazolyl, 1,2,3-, 1,3,4-, 1,2,4- and 1,2,5-oxadiazolyl, azepinyl, pyrrolyl, pyridyl, pyridazinyl, pyrimidinyl, pyrazinyl, 1,3,5-, 1,2,4- and 1,2,3-triazinyl, 1,2,4-, 1,3,2-, 1,3,6- and 1,2,6-oxazinyl, oxepinyl, thiepinyl, 1,2,4-triazolonyl and 1,2,4-diazepinyl. 
     A compound according to any one of embodiments 1 to 7 which has at least one basic centre can form, for example, acid addition salts, for example with strong inorganic acids such as mineral acids, for example perchloric acid, sulfuric acid, nitric acid, nitrose acid, a phosphorus acid or a hydrohalic acid, with strong organic carboxylic acids, such as C 1 -C 4 alkanecarboxylic acids which are unsubstituted or substituted, for example by halogen, for example acetic acid, such as saturated or unsaturated dicarboxylic acids, for example oxalic acid, malonic acid, succinic acid, maleic acid, fumaric acid or phthalic acid, such as hydroxycarboxylic acids, for example ascorbic acid, lactic acid, malic acid, tartaric acid or citric acid, or such as benzoic acid, or with organic sulfonic acids, such as C 1 -C 4 alkane- or arylsulfonic acids which are unsubstituted or substituted, for example by halogen, for example methane- or p-toluenesulfonic acid. A compounds according to any one of embodiments 1 to 7 which have at least one acidic group can form, for example, salts with bases, for example mineral salts such as alkali metal or alkaline earth metal salts, for example sodium, potassium or magnesium salts, or salts with ammonia or an organic amine, such as morpholine, piperidine, pyrrolidine, a mono-, di- or tri-lower-alkylamine, for example ethyl-, diethyl-, triethyl- or dimethylpropylamine, or a mono-, di- or trihydroxy-lower-alkylamine, for example mono-, di- or triethanolamine. 
     Compounds according to any one of embodiments 1 to 7 also include hydrates which may be formed during the salt formation. 
     The compounds according to any one of embodiments 1 to 7 may be made by a variety of methods well known to a person skilled in the art or as shown in Schemes 1 to 4. Further instructions regarding the preparation can be found in WO2015/067646, WO2015/150442, WO2015/193218, WO2014/122083 and WO2012/107434. 
     For example, compounds of formula (Ia) or (Ib) can be prepared according to Scheme 1. 
     
       
         
         
             
             
         
       
     
     wherein R 1′  is as defined in any one of embodiments 1 to 7 but is not H, and Q are as defined in any one of embodiments 1 to 7, LG represents a leaving group such as Cl, Br, I, OMs, OTs or OTf. Compounds of formula (1), (2), (5), (10), (12) and (13) are commercially available or are known from the chemistry literature. Compound of formula (3) can be prepared according to processes described e.g. in U.S. Pat. No. 5,536,701. Compound of formula (4) can be prepared according to  Synth. Commun.  2004, 34, 1541 (Vilsmeier reaction). Compound of formula (7) can be prepared according to processes described e.g. in WO2007/060525 (Bayer-Villiger oxidation). Compound of formula (8) can be obtained by difluoromethylation of compound of formula (7) according to processes described e.g. in WO2016/044446. Compounds of formula (9) can be obtained by borylation of compound of formula (8) with a palladium (0) catalyst and a borylation reagent according to processes described e.g. in WO2013/053983. Compound of formula (11) can be obtained by classical Suzuki coupling between compound of formula (10) and a boronic acid, ester (e.g. pinacol ester) or trifluoroborate of formula (9) as described in N. Miyaura, A. Suzuki,  Chem. Rev.  1995, 95, 2457-2483 or in G. A. Molander, L. Jean-Gérard,  Org. React.  2013, 79, 1-316. Compounds of formula (Ia) can be prepared in analogy to literature methods from compounds (11) and (12) via known peptide coupling methods (for example as shown in WO2010/051926 and WO2010/133312). Compounds of formula (Ib) can be prepared according to known methods from compounds of formula (Ia) in the presence of a compound (13) and a base. 
     A compound according to any one of embodiments 1 to 7 can be converted in a manner known per se into another compound according to any one of embodiments 1 to 7 by replacing one or more substituents of the starting compound according to any one of embodiments 1 to 7 in the customary manner by (an)other substituent(s) according to the invention. 
     Depending on the choice of the reaction conditions and starting materials which are suitable in each case, it is possible, for example, in one reaction step only to replace one substituent by another substituent according to the invention, or a plurality of substituents can be replaced by other substituents according to the invention in the same reaction step. 
     Salts of compounds of formula (I) can be prepared in a manner known per se. Thus, for example, acid addition salts of compounds according to any one of embodiments 1 to 7 are obtained by treatment with a suitable acid or a suitable ion exchanger reagent and salts with bases are obtained by treatment with a suitable base or with a suitable ion exchanger reagent. 
     Salts of compounds according to any one of embodiments 1 to 7 can be converted in the customary manner into the free compounds, acid addition salts, for example, by treatment with a suitable basic compound or with a suitable ion exchanger reagent and salts with bases, for example, by treatment with a suitable acid or with a suitable ion exchanger reagent. 
     Salts of compounds according to any one of embodiments 1 to 7 can be converted in a manner known per se into other salts of compounds according to any one of embodiments 1 to 7, acid addition salts, for example, into other acid addition salts, for example by treatment of a salt of inorganic acid such as hydrochloride with a suitable metal salt such as a sodium, barium or silver salt, of an acid, for example with silver acetate, in a suitable solvent in which an inorganic salt which forms, for example silver chloride, is insoluble and thus precipitates from the reaction mixture. 
     Depending on the procedure or the reaction conditions, the compounds according to any one of embodiments 1 to 7, which have salt-forming properties can be obtained in free form or in the form of salts. 
     The compounds according to any one of embodiments 1 to 7 and, where appropriate, the tautomers thereof, in each case in free form or in salt form, can be present in the form of one of the stereoisomers which are possible or as a mixture of these, for example in the form of pure stereoisomers, such as antipodes and/or diastereomers, or as stereoisomer mixtures, such as enantiomer mixtures, for example racemates, diastereomer mixtures or racemate mixtures, depending on the number, absolute and relative configuration of asymmetric carbon atoms which occur in the molecule and/or depending on the configuration of non-aromatic double bonds which occur in the molecule; the invention relates to the pure stereoisomers and also to all stereoisomer mixtures which are possible and is to be understood in each case in this sense hereinabove and hereinbelow, even when stereochemical details are not mentioned specifically in each case. 
     Diastereomer mixtures or racemate mixtures of compounds according to any one of embodiments 1 to 7, in free form or in salt form, which can be obtained depending on which starting materials and procedures have been chosen can be separated in a known manner into the pure diasteromers or racemates on the basis of the physicochemical differences of the components, for example by fractional crystallization, distillation and/or chromatography. 
     Enantiomer mixtures, such as racemates, which can be obtained in a similar manner can be resolved into the optical antipodes by known methods, for example by recrystallization from an optically active solvent, by chromatography on chiral adsorbents, for example high-performance liquid chromatography (HPLC) on acetyl celulose, with the aid of suitable microorganisms, by cleavage with specific, immobilized enzymes, via the formation of inclusion compounds, for example using chiral crown ethers, where only one enantiomer is complexed, or by conversion into diastereomeric salts, for example by reacting a basic end-product racemate with an optically active acid, such as a carboxylic acid, for example camphor, tartaric or malic acid, or sulfonic acid, for example camphorsulfonic acid, and separating the diastereomer mixture which can be obtained in this manner, for example by fractional crystallization based on their differing solubilities, to give the diastereomers, from which the desired enantiomer can be set free by the action of suitable agents, for example basic agents. 
     Pure diastereomers or enantiomers can be obtained according to the invention not only by separating suitable stereoisomer mixtures, but also by generally known methods of diastereoselective or enantioselective synthesis, for example by carrying out the process according to the invention with starting materials of a suitable stereochemistry. 
     N-oxides can be prepared by reacting a compound according to any one of embodiments 1 to 7 with a suitable oxidizing agent, for example the H 2 O 2 /urea adduct in the presence of an acid anhydride, e.g. trifluoroacetic anhydride. Such oxidations are known from the literature, for example from J. Med. Chem., 32 (12), 2561-73, 1989 or WO 00/15615. 
     It is advantageous to isolate or synthesize in each case the biologically more effective stereoisomer, for example enantiomer or diastereomer, or stereoisomer mixture, for example enantiomer mixture or diastereomer mixture, if the individual components have a different biological activity. 
     The compounds according to any one of embodiments 1 to 7 and, where appropriate, the tautomers thereof, in each case in free form or in salt form, can, if appropriate, also be obtained in the form of hydrates and/or include other solvents, for example those which may have been used for the crystallization of compounds which are present in solid form. 
     The following Examples illustrate, but do not limit, the invention. 
     The compounds of the invention can be distinguished from known compounds by virtue of greater efficacy at low application rates, which can be verified by the person skilled in the art using the experimental procedures outlined in the Examples, using lower application rates if necessary, for example 50 ppm, 12.5 ppm, 6 ppm, 3 ppm, 1.5 ppm or 0.8 ppm. 
     The present invention also provides intermediates useful for the preparation of compounds according to any one of embodiments 1 to 7. Certain intermediates are novel and as such form a further aspect of the invention. 
     One group of novel intermediates are compounds of formula (II) 
     
       
         
         
             
             
         
       
     
     wherein P is hydroxy, C 1 -C 15 -alkoxy or halogen, such as bromo, chloro or fluoro. 
     Specifically, one novel intermediate is the compound of formula (IIa) 
     
       
         
         
             
             
         
       
     
     Another novel intermediate is the compound of formula (IIb) 
     
       
         
         
             
             
         
       
     
     One group of novel intermediates are compounds of formula (III) 
     
       
         
         
             
             
         
       
     
     wherein U is hydrogen, halogen, such as bromo, chloro or fluoro or a boronic acid (—B(OH) 2 ) or boronic ester derivative, (e.g. —B(OR′) 2 , wherein R′ is C 1 -C 8 -alkyl such as methyl or ethyl). 
     One group of novel intermediates are compounds of formula (IV) 
     
       
         
         
             
             
         
       
     
     wherein R 1  and Q are as defined in any one of embodiments 1 to 7. The preferences for R 1  and Q are the same as the preferences set out for the corresponding substituents of a compound according to any one of embodiments 1 to 7. 
     One group of novel intermediates are compounds of formula (V) 
     
       
         
         
             
             
         
       
     
     wherein R 1  and Q are as defined in any one of embodiments 1 to 7 and X B  is a halogen, amino, cyano, C 1 -C 8 alkylsulfonyloxy, C 1 -C 8 haloalkylsulfonyloxy, C 1 -C 8 arylsulfonyloxy, optionally substituted C 1 -C 8 arylsulfonyloxy (aryl is preferably phenyl), diazonium salts (e.g. X is —N 2   + Cl − , —N 2   + BF 4   − , —N 2   + Br − , —N 2   + PF 6   − ), phosphonate esters (e.g. —OP(O)(OR′) 2 , wherein R′ is methyl or ethyl) or a boronic acid (—B(OH) 2 ) or boronic ester derivative, (e.g. —B(OR′) 2 , wherein R′ is C 1 -C 8 -alkyl such as methyl or ethyl), preferably X B  is bromo, iodo, chloro, cyano, trifluoromethylsulfoxy, p-toluenesulfoxy and diazonium chloride. The preferences for R 1  and Q are the same as the preferences set out for the corresponding substituents of a compound according to any one of embodiments 1 to 7. 
     The compounds according to any one of embodiments 1 to 7 are preventively and/or curatively valuable active ingredients in the field of pest control, even at low rates of application, which have a very favorable biocidal spectrum and are well tolerated by warm-blooded species, fish and plants. The active ingredients according to the invention act against all or individual developmental stages of normally sensitive, but also resistant, animal pests, such as insects or representatives of the order Acarina. The insecticidal or acaricidal activity of the active ingredients according to the invention can manifest itself directly, i. e. in destruction of the pests, which takes place either immediately or only after some time has elapsed, for example during ecdysis, or indirectly, for example in a reduced oviposition and/or hatching rate. 
     Examples of the above mentioned animal pests are: 
     from the order Acarina, for example, 
       Acalitus  spp,  Aculus  spp,  Acaricalus  spp,  Aceria  spp,  Acarus siro, Amblyomma  spp.,  Argas  spp.,  Boophilus  spp.,  Brevipalpus  spp.,  Bryobia  spp,  Calipitrimerus  spp.,  Chorioptes  spp.,  Dermanyssus gallinae, Dermatophagoides  spp,  Eotetranychus  spp,  Eriophyes  spp.,  Hemitarsonemus  spp,  Hyalomma  spp.,  Ixodes  spp.,  Olygonychus  spp,  Ornithodoros  spp.,  Polyphagotarsone latus, Panonychus  spp.,  Phyllocoptruta oleivora, Phytonemus  spp,  Polyphagotarsonemus  spp,  Psoroptes  spp.,  Rhipicephalus  spp.,  Rhizoglyphus  spp.,  Sarcoptes  spp.,  Steneotarsonemus  spp,  Tarsonemus  spp. and  Tetranychus  spp.; 
     from the order Anoplura, for example, 
       Haematopinus  spp.,  Linognathus  spp.,  Pediculus  spp.,  Pemphigus  spp. and  Phylloxera  spp.; 
     from the order Coleoptera, for example, 
       Agriotes  spp.,  Amphimallon majale, Anomala orientalis, Anthonomus  spp.,  Aphodius  spp,  Astylus atromaculatus, Ataenius  spp,  Atomaria linearis, Chaetocnema tibialis, Cerotoma  spp,  Conoderus  spp,  Cosmopolites  spp.,  Cotinis nitida, Curculio  spp.,  Cyclocephala  spp,  Dermestes  spp.,  Diabrotica  spp.,  Diloboderus abderus, Epilachna  spp.,  Eremnus  spp.,  Heteronychus arator, Hypothenemus hampei, Lagria vilosa, Leptinotarsa decemLineata, Lissorhoptrus  spp.,  Liogenys  spp,  Maecolaspis  spp,  Maladera castanea, Megascelis  spp,  Melighetes aeneus, Melolontha  spp.,  Myochrous armatus, Orycaephilus  spp.,  Otiorhynchus  spp.,  Phyllophaga  spp,  Phlyctinus  spp.,  Popillia  spp.,  Psylliodes  spp.,  Rhyssomatus aubtilis, Rhizopertha  spp.,  Scarabeidae, Sitophilus  spp.,  Sitotroga  spp.,  Somaticus  spp,  Sphenophorus  spp,  Sternechus subsignatus, Tenebrio  spp.,  Tribolium  spp. and  Trogoderma  spp.; 
     from the order Diptera, for example, 
       Aedes  spp.,  Anopheles  spp,  Antherigona soccata, Bactrocea oleae, Bibio hortulanus, Bradysia  spp,  Calliphora erythrocephala, Ceratitis  spp.,  Chrysomyia  spp.,  Culex  spp.,  Cuterebra  spp.,  Dacus  spp.,  Delia  spp,  Drosophila melanogaster, Fannia  spp.,  Gastrophilus  spp.,  Geomyza tripunctata, Glossina  spp.,  Hypoderma  spp.,  Hyppobosca  spp.,  Liriomyza  spp.,  Lucilia  spp.,  Melanagromyza  spp.,  Musca  spp.,  Oestrus  spp.,  Orseolia  spp.,  Oscinella frit, Pegomyia hyoscyami, Phorbia  spp.,  Rhagoletis  spp,  Rivelia quadrifasciata, Scatella  spp,  Sciara  spp.,  Stomoxys  spp.,  Tabanus  spp.,  Tannia  spp. and  Tipula  spp.; 
     from the order Hemiptera, for example, 
       Acanthocoris scabrator, Acrosternum  spp,  Adelphocoris lineolatus, Amblypelta nitida, Bathycoelia thalassina, Blissus  spp,  Cimex  spp.,  Clavigralla tomentosicollis, Creontiades  spp,  Distantiella theobroma, Dichelops furcatus, Dysdercus  spp.,  Edessa  spp,  Euchistus  spp.,  Eurydema pulchrum, Eurygaster  spp.,  Halyomorpha halys, Horcias nobilellus, Leptocorisa  spp.,  Lygus  spp,  Margarodes  spp,  Murgantia histrionic, Neomegalotomus  spp,  Nesidiocoris tenuis, Nezara  spp.,  Nysius simulans, Oebalus insularis, Piesma  spp.,  Piezodorus  spp,  Rhodnius  spp.,  Sahlbergella singularis, Scaptocoris castanea, Scotinophara  spp.,  Thyanta  spp,  Triatoma  spp.,  Vatiga illudens;    
       Acyrthosium pisum, Adalges  spp,  Agalliana ensigera, Agonoscena targionii, Aleurodicus  spp,  Aleurocanthus  spp,  Aleurolobus barodensis, Aleurothrixus floccosus, Aleyrodes brassicae, Amarasca biguttula, Amritodus atkinsoni, Aonidiella  spp.,  Aphididae, Aphis  spp.,  Aspidiotus  spp.,  Aulacorthum solani, Bactericera cockerelli, Bemisia  spp,  Brachycaudus  spp,  Brevicoryne brassicae, Cacopsylla  spp,  Cavariella aegopodii Scop., Ceroplaster  spp.,  Chrysomphalus aonidium, Chrysomphalus dictyospermi, Cicadella  spp,  Cofana spectra, Cryptomyzus  spp,  Cicadulina  spp,  Coccus hesperidum, Dalbulus maidis, Dialeurodes  spp,  Diaphorina citri, Diuraphis noxia, Dysaphis  spp,  Empoasca  spp.,  Eriosoma larigerum, Erythroneura  spp.,  Gascardia  spp.,  Glycaspis brimblecombei, Hyadaphis pseudobrassicae, Hyalopterus  spp,  Hyperomyzus pallidus, Idioscopus clypealis, Jacobiasca lybica, Laodelphax  spp.,  Lecanium corni, Lepidosaphes  spp.,  Lopaphis erysimi, Lyogenys maidis, Macrosiphum  spp.,  Mahanarva  spp,  Metcalfa pruinosa, Metopolophium dirhodum, Myndus crudus, Myzus  spp.,  Neotoxoptera  sp,  Nephotettix  spp.,  Nilaparvata  spp.,  Nippolachnus piri Mats, Odonaspis ruthae, Oregma lanigera Zehnter, Parabemisia myricae, Paratrioza cockerelli, Parlatoria  spp.,  Pemphigus  spp.,  Peregrinus maidis, Perkinsiella  spp,  Phorodon humuli, Phylloxera  spp,  Planococcus  spp.,  Pseudaulacaspis  spp.,  Pseudococcus  spp.,  Pseudatomoscelis seriatus, Psylla  spp.,  Pulvinaria aethiopica, Quadraspidiotus  spp.,  Quesada gigas, Recilia dorsalis, Rhopalosiphum  spp.,  Saissetia  spp.,  Scaphoideus  spp.,  Schizaphis  spp.,  Sitobion  spp.,  Sogatella furcifera, Spissistilus festinus, Tarophagus Proserpina, Toxoptera  spp,  Trialeurodes  spp,  Tridiscus sporoboli, Trionymus  spp,  Trioza erytreae, Unaspis citri, Zygina flammigera, Zyginidia scutellaris;    
     from the order Hymenoptera, for example, 
       Acromyrmex, Arge  spp,  Atta  spp.,  Cephus  spp.,  Diprion  spp.,  Diprionidae, Gilpinia polytoma, Hoplocampa  spp.,  Lasius  spp.,  Monomorium pharaonis, Neodiprion  spp.,  Pogonomyrmex  spp,  Slenopsis invicta, Solenopsis  spp. and  Vespa  spp.; 
     from the order Isoptera, for example, 
       Coptotermes  spp,  Corniternes cumulans, Incisitermes  spp,  Macrotermes  spp,  Mastotermes  spp,  Microtermes  spp,  Reticulitermes  spp.;  Solenopsis geminate    
     from the order Lepidoptera, for example, 
       Acleris  spp.,  Adoxophyes  spp.,  Aegeria  spp.,  Agrotis  spp.,  Alabama argillaceae, Amylois  spp.,  Anticarsia gemmatalis, Archips  spp.,  Argyresthia  spp,  Argyrotaenia  spp.,  Autographa  spp.,  Bucculatrix thurberiella, Busseola fusca, Cadra cautella, Carposina nipponensis, Chilo  spp.,  Choristoneura  spp.,  Chrysoteuchia topiaria, Clysia ambiguella, Cnaphalocrocis  spp.,  Cnephasia  spp.,  Cochylis  spp.,  Coleophora  spp.,  Colias lesbia, Cosmophila flava, Crambus  spp,  Crocidolomia binotalis, Cryptophlebia leucotreta, Cydalima perspectalis, Cydia  spp.,  Diaphania perspectalis, Diatraea  spp.,  Diparopsis castanea, Earias  spp.,  Eldana saccharina, Ephestia  spp.,  Epinotia  spp,  Estigmene acrea, Etiella zinckinella, Eucosma  spp.,  Eupoecilia ambiguella, Euproctis  spp.,  Euxoa  spp.,  Feltia jaculiferia, Gra - pholita  spp.,  Hedya nubiferana, Heliothis  spp.,  Hellula undalis, Herpetogramma  spp,  Hyphantria cunea, Keiferia lycopersicella, Lasmopalpus lignosellus, Leucoptera scitella, Lithocollethis  spp.,  Lobesia botrana, Loxostege bifidalis, Lymantria  spp.,  Lyonetia  spp.,  Malacosoma  spp.,  Mamestra brassicae, Manduca sexta, Mythimna  spp,  Noctua  spp,  Operophtera  spp.,  Orniodes indica, Ostrinia nubilalis, Pammene  spp.,  Pandemis  spp.,  Panolis flammea, Papaipema nebris, Pectinophora gossypiela, Perileucoptera coffeella, Pseudaletia unipuncta, Phthorimaea operculella, Pieris rapae, Pieris  spp.,  Plutella xylostella, Prays  spp.,  Pseudoplusia  spp,  Rachiplusia nu, Richia albicosta, Scirpophaga  spp.,  Sesamia  spp.,  Sparganothis  spp.,  Spodoptera  spp.,  Sylepta derogate, Synanthedon  spp.,  Thaumetopoea  spp.,  Tortrix  spp.,  Trichoplusia ni, Tuta absoluta , and  Yponomeuta  spp.; 
     from the order Mallophaga, for example, 
       Damalinea  spp. and  Trichodectes  spp.; 
     from the order Orthoptera, for example, 
       Blatta  spp.,  Blattella  spp.,  Gryllotalpa  spp.,  Leucophaea maderae, Locusta  spp.,  Neocurtilla hexadactyla, Periplaneta  spp.,  Scapteriscus  spp, and  Schistocerca  spp.; 
     from the order Psocoptera, for example, 
       Liposcelis  spp.; 
     from the order Siphonaptera, for example, 
       Ceratophyllus  spp.,  Ctenocephalides  spp. and  Xenopsylla cheopis;    
     from the order Thysanoptera, for example, 
       Calliothrips phaseoli, Frankliniella  spp.,  Heliothrips  spp,  Hercinothrips  spp.,  Parthenothrips  spp,  Scirtothrips aurantii, Sericothrips variabilis, Taeniothrips  spp.,  Thrips  spp; 
     from the order Thysanura, for example,  Lepisma saccharina.    
     The active ingredients according to the invention can be used for controlling, i. e. containing or destroying, pests of the abovementioned type which occur in particular on plants, especially on useful plants and ornamentals in agriculture, in horticulture and in forests, or on organs, such as fruits, flowers, foliage, stalks, tubers or roots, of such plants, and in some cases even plant organs which are formed at a later point in time remain protected against these pests. 
     Suitable target crops are, in particular, cereals, such as wheat, barley, rye, oats, rice, maize or sorghum; beet, such as sugar or fodder beet; fruit, for example pomaceous fruit, stone fruit or soft fruit, such as apples, pears, plums, peaches, almonds, cherries or berries, for example strawberries, raspberries or blackberries; leguminous crops, such as beans, lentils, peas or soya; oil crops, such as oilseed rape, mustard, poppies, olives, sunflowers, coconut, castor, cocoa or ground nuts; cucurbits, such as pumpkins, cucumbers or melons; fibre plants, such as cotton, flax, hemp or jute; citrus fruit, such as oranges, lemons, grapefruit or tangerines; vegetables, such as spinach, lettuce, asparagus, cabbages, carrots, onions, tomatoes, potatoes or bell peppers; Lauraceae, such as avocado, Cinnamonium or camphor; and also tobacco, nuts, coffee, eggplants, sugarcane, tea, pepper, grapevines, hops, the plantain family, latex plants and ornamentals. 
     The active ingredients according to the invention are especially suitable for controlling  Aphis craccivora, Diabrotica balteata, Heliothis virescens, Myzus persicae, Plutella xylostella  and  Spodoptera littoralis  in cotton, vegetable, maize, rice and soya crops. The active ingredients according to the invention are further especially suitable for controlling  Mamestra  (preferably in vegetables),  Cydia pomonella  (preferably in apples),  Empoasca  (preferably in vegetables, vineyards),  Leptinotarsa  (preferably in potatoes) and  Chilo supressalis  (preferably in rice). 
     In a further aspect, the invention may also relate to a method of controlling damage to plant and parts thereof by plant parasitic nematodes (Endoparasitic-, Semiendoparasitic- and Ectoparasitic nematodes), especially plant parasitic nematodes such as root knot nematodes,  Meloidogyne hapla, Meloidogyne incognita, Meloidogyne javanica, Meloidogyne arenaria  and other  Meloidogyne  species; cyst-forming nematodes,  Globodera rostochiensis  and other  Globodera  species;  Heterodera avenae, Heterodera glycines, Heterodera schachtii, Heterodera trifolii , and other  Heterodera  species; Seed gall nematodes,  Anguina  species; Stem and foliar nematodes,  Aphelenchoides  species; Sting nematodes,  Belonolaimus longicaudatus  and other  Belonolaimus  species; Pine nematodes,  Bursaphelenchus xylophilus  and other  Bursaphelenchus  species; Ring nematodes,  Criconema  species,  Criconemella  species,  Criconemoides  species,  Mesocriconema  species; Stem and bulb nematodes,  Ditylenchus destructor, Ditylenchus dipsaci  and other  Ditylenchus  species; Awl nematodes,  Dolichodorus  species; Spiral nematodes,  Heliocotylenchus multicinctus  and other  Helicotylenchus  species; Sheath and sheathoid nematodes,  Hemicycliophora  species and  Hemicriconemoides  species;  Hirshmanniella  species; Lance nematodes,  Hoploaimus  species; false rootknot nematodes,  Nacobbus  species; Needle nematodes,  Longidorus elongatus  and other  Longidorus  species; Pin nematodes,  Pratylenchus  species; Lesion nematodes,  Pratylenchus neglectus, Pratylenchus penetrans, Pratylenchus curvitatus, Pratylenchus goodeyi  and other  Pratylenchus  species; Burrowing nematodes,  Radopholus similis  and other  Radopholus  species; Reniform nematodes,  Rotylenchus robustus, Rotylenchus reniformis  and other  Rotylenchus  species;  Scutellonema  species; Stubby root nematodes,  Trichodorus primitivus  and other  Trichodorus  species,  Paratrichodorus  species; Stunt nematodes,  Tylenchorhynchus claytoni, Tylenchorhynchus dubius  and other  Tylenchorhynchus  species; Citrus nematodes,  Tylenchulus  species; Dagger nematodes,  Xiphinema  species; and other plant parasitic nematode species, such as  Subanguina  spp.,  Hypsoperine  spp.,  Macroposthonia  spp.,  Melinius  spp.,  Punctodera  spp., and  Quinisulcius  spp. 
     The compounds according to any one of embodiments 1 to 7 may also have activity against the molluscs. Examples of which include, for example, Ampullariidae;  Arion  ( A. ater, A. circumscriptus, A. hortensis, A. rufus ); Bradybaenidae ( Bradybaena fruticum );  Cepaea  ( C. hortensis, C. nemoralis ); ochlodina;  Deroceras  ( D. agrestis, D. empiricorum, D. laeve, D. reticulatum );  Discus  ( D. rotundatus );  Euomphalia; Galba  ( G. trunculata );  Helicelia  ( H. itala, H. obvia );  Helicidae Helicigona arbustorum );  Helicodiscus; Helix  ( H. aperta );  Limax  ( L. cinereoniger, L. flavus, L. marginatus, L. maximus, L. tenellus );  Lymnaea; Milax  ( M. gagates, M. marginatus, M. sowerbyi );  Opeas; Pomacea  ( P. canaticulata );  Vallonia  and  Zanitoides.    
     The term “crops” is to be understood as including also crop plants which have been so transformed by the use of recombinant DNA techniques that they are capable of synthesising one or more selectively acting toxins, such as are known, for example, from toxin-producing bacteria, especially those of the genus  Bacillus.    
     Toxins that can be expressed by such transgenic plants include, for example, insecticidal proteins, for example insecticidal proteins from  Bacillus cereus  or  Bacillus popilliae ; or insecticidal proteins from  Bacillus thuringiensis , such as 8-endotoxins, e.g. Cry1Ab, Cry1Ac, Cry1F, Cry1Fa2, Cry2Ab, Cry3A, Cry3Bb1 or Cry9C, or vegetative insecticidal proteins (Vip), e.g. Vip1, Vip2, Vip3 or Vip3A; or 
     insecticidal proteins of bacteria colonising nematodes, for example  Photorhabdus  spp. or  Xenorhabdus  spp., such as  Photorhabdus luminescens, Xenorhabdus nematophilus ; toxins produced by animals, such as scorpion toxins, arachnid toxins, wasp toxins and other insect-specific neurotoxins; toxins produced by fungi, such as Streptomycetes toxins, plant lectins, such as pea lectins, barley lectins or snowdrop lectins; agglutinins; proteinase inhibitors, such as trypsin inhibitors, serine protease inhibitors, patatin, cystatin, papain inhibitors; ribosome-inactivating proteins (RIP), such as ricin, maize-RIP, abrin, luffin, saporin or bryodin; steroid metabolism enzymes, such as 3-hydroxysteroidoxidase, ecdysteroid-UDP-glycosyl-transferase, cholesterol oxidases, ecdysone inhibitors, HMG-COA-reductase, ion channel blockers, such as blockers of sodium or calcium channels, juvenile hormone esterase, diuretic hormone receptors, stilbene synthase, bibenzyl synthase, chitinases and glucanases. 
     In the context of the present invention there are to be understood by 8-endotoxins, for example Cry1Ab, Cry1Ac, Cry1F, Cry1Fa2, Cry2Ab, Cry3A, Cry3Bb1 or Cry9C, or vegetative insecticidal proteins (Vip), for example Vip1, Vip2, Vip3 or Vip3A, expressly also hybrid toxins, truncated toxins and modified toxins. Hybrid toxins are produced recombinantly by a new combination of different domains of those proteins (see, for example, WO 02/15701). Truncated toxins, for example a truncated Cry1Ab, are known. In the case of modified toxins, one or more amino acids of the naturally occurring toxin are replaced. In such amino acid replacements, preferably non-naturally present protease recognition sequences are inserted into the toxin, such as, for example, in the case of Cry3A055, a cathepsin-G-recognition sequence is inserted into a Cry3A toxin (see WO 03/018810). 
     Examples of such toxins or transgenic plants capable of synthesising such toxins are disclosed, for example, in EP-A-0 374 753, WO93/07278, WO95/34656, EP-A-0 427 529, EP-A-451 878 and WO 03/052073. 
     The processes for the preparation of such transgenic plants are generally known to the person skilled in the art and are described, for example, in the publications mentioned above. Cry1-type deoxyribonucleic acids and their preparation are known, for example, from WO 95/34656, EP-A-0 367 474, EP-A-0 401 979 and WO 90/13651. 
     The toxin contained in the transgenic plants imparts to the plants tolerance to harmful insects. Such insects can occur in any taxonomic group of insects, but are especially commonly found in the beetles (Coleoptera), two-winged insects (Diptera) and moths (Lepidoptera). 
     Transgenic plants containing one or more genes that code for an insecticidal resistance and express one or more toxins are known and some of them are commercially available. Examples of such plants are: YieldGard® (maize variety that expresses a Cry1Ab toxin); YieldGard Rootworm® (maize variety that expresses a Cry3Bb1 toxin); YieldGard Plus® (maize variety that expresses a Cry1Ab and a Cry3Bb1 toxin); Starlink® (maize variety that expresses a Cry9C toxin); Herculex I® (maize variety that expresses a Cry1 Fa2 toxin and the enzyme phosphinothricine N-acetyltransferase (PAT) to achieve tolerance to the herbicide glufosinate ammonium); NuCOTN 33B® (cotton variety that expresses a Cry1Ac toxin); Bollgard I® (cotton variety that expresses a Cry1Ac toxin); Bollgard II® (cotton variety that expresses a Cry1Ac and a Cry2Ab toxin); VipCot® (cotton variety that expresses a Vip3A and a Cry1Ab toxin); NewLeaf® (potato variety that expresses a Cry3A toxin); NatureGard®, Agrisure® GT Advantage (GA21 glyphosate-tolerant trait), Agrisure® CB Advantage (Btl 1 corn borer (CB) trait) and Protecta®. 
     Further examples of such transgenic crops are: 
     1. Btll Maize from Syngenta Seeds SAS, Chemin de l&#39;Hobit 27, F-31 790 St. Sauveur, France, registration number C/FR/96/05/10. Genetically modified  Zea mays  which has been rendered resistant to attack by the European corn borer ( Ostrinia nubilalis  and  Sesamia nonagrioides ) by transgenic expression of a truncated Cry1Ab toxin. Btl 1 maize also transgenically expresses the enzyme PAT to achieve tolerance to the herbicide glufosinate ammonium. 
     2. Bt176 Maize from Syngenta Seeds SAS, Chemin de l&#39;Hobit 27, F-31 790 St. Sauveur, France, registration number C/FR/96/05/10. Genetically modified  Zea mays  which has been rendered resistant to attack by the European corn borer ( Ostrinia nubilalis  and  Sesamia nonagrioides ) by transgenic expression of a Cry1Ab toxin. Bt176 maize also transgenically expresses the enzyme PAT to achieve tolerance to the herbicide glufosinate ammonium. 
     3. MIR604 Maize from Syngenta Seeds SAS, Chemin de l&#39;Hobit 27, F-31 790 St. Sauveur, France, registration number C/FR/96/05/10. Maize which has been rendered insect-resistant by transgenic expression of a modified Cry3A toxin. This toxin is Cry3A055 modified by insertion of a cathepsin-G-protease recognition sequence. The preparation of such transgenic maize plants is described in WO 03/018810. 
     4. MON 863 Maize from Monsanto Europe S.A. 270-272 Avenue de Tervuren, B-1150 Brussels, Belgium, registration number C/DE/02/9. MON 863 expresses a Cry3Bb1 toxin and has resistance to certain Coleoptera insects. 
     5. IPC 531 Cotton from Monsanto Europe S.A. 270-272 Avenue de Tervuren, B-1150 Brussels, Belgium, registration number C/ES/96/02. 
     6. 1507 Maize from Pioneer Overseas Corporation, Avenue Tedesco, 7 B-1160 Brussels, Belgium, registration number C/NL/00/10. Genetically modified maize for the expression of the protein Cry1F for achieving resistance to certain Lepidoptera insects and of the PAT protein for achieving tolerance to the herbicide glufosinate ammonium. 
     7. NK603 x MON 810 Maize from Monsanto Europe S.A. 270-272 Avenue de Tervuren, B-1150 Brussels, Belgium, registration number C/GB/02/M3/03. Consists of conventionally bred hybrid maize varieties by crossing the genetically modified varieties NK603 and MON 810. NK603 x MON 810 Maize transgenically expresses the protein CP4 EPSPS, obtained from  Agrobacterium  sp. strain CP4, which imparts tolerance to the herbicide Roundup® (contains glyphosate), and also a Cry1Ab toxin obtained from  Bacillus thuringiensis  subsp.  kurstaki  which brings about tolerance to certain Lepidoptera, include the European corn borer. 
     Transgenic crops of insect-resistant plants are also described in BATS (Zentrum für Biosicherheit und Nachhaltigkeit, Zentrum BATS, Clarastrasse 13, 4058 Basel, Switzerland) Report 2003, (http://bats.ch). The term “crops” is to be understood as including also crop plants which have been so transformed by the use of recombinant DNA techniques that they are capable of synthesising antipathogenic substances having a selective action, such as, for example, the so-called “pathogenesis-related proteins” (PRPs, see e.g. EP-A-0 392 225). Examples of such antipathogenic substances and transgenic plants capable of synthesising such antipathogenic substances are known, for example, from EP-A-0 392 225, WO95/33818 and EP-A-0 353 191. The methods of producing such transgenic plants are generally known to the person skilled in the art and are described, for example, in the publications mentioned above. 
     Crops may also be modified for enhanced resistance to fungal (for example  Fusarium , Anthracnose, or  Phytophthora ), bacterial (for example  Pseudomonas ) or viral (for example potato leafroll virus, tomato spotted wilt virus, cucumber mosaic virus) pathogens. 
     Crops also include those that have enhanced resistance to nematodes, such as the soybean cyst nematode. 
     Crops that are tolerant to abiotic stress include those that have enhanced tolerance to drought, high salt, high temperature, chill, frost, or light radiation, for example through expression of NF-YB or other proteins known in the art. 
     Antipathogenic substances which can be expressed by such transgenic plants include, for example, ion channel blockers, such as blockers for sodium and calcium channels, for example the viral KP1, KP4 or KP6 toxins; stilbene synthases; bibenzyl synthases; chitinases; glucanases; the so-called “pathogenesis-related proteins” (PRPs; see e.g. EP-A-0 392 225); antipathogenic substances produced by microorganisms, for example peptide antibiotics or heterocyclic antibiotics (see e.g. WO95/33818) or protein or polypeptide factors involved in plant pathogen defence (so-called “plant disease resistance genes”, as described in WO 03/000906). 
     Further areas of use of the compositions according to the invention are the protection of stored goods and store rooms and the protection of raw materials, such as wood, textiles, floor coverings or buildings, and also in the hygiene sector, especially the protection of humans, domestic animals and productive livestock against pests of the mentioned type. 
     The present invention also provides a method for controlling pests (such as mosquitoes and other disease vectors; see also http://www.who.int/malaria/vector_control/irs/en/). In one embodiment, the method for controlling pests comprises applying the compositions of the invention to the target pests, to their locus or to a surface or substrate by brushing, rolling, spraying, spreading or dipping. By way of example, an IRS (indoor residual spraying) application of a surface such as a wall, ceiling or floor surface is contemplated by the method of the invention. In another embodiment, it is contemplated to apply such compositions to a substrate such as non-woven or a fabric material in the form of (or which can be used in the manufacture of) netting, clothing, bedding, curtains and tents. 
     In another embodiment, the method for controlling such pests comprises applying a pesticidally effective amount of the compositions of the invention to the target pests, to their locus, or to a surface or substrate so as to provide effective residual pesticidal activity on the surface or substrate. Such application may be made by brushing, rolling, spraying, spreading or dipping the pesticidal composition of the invention. By way of example, an IRS application of a surface such as a wall, ceiling or floor surface is contemplated by the method of the invention so as to provide effective residual pesticidal activity on the surface. In another embodiment, it is contemplated to apply such compositions for residual control of pests on a substrate such as a fabric material in the form of (or which can be used in the manufacture of) netting, clothing, bedding, curtains and tents. 
     Substrates including non-woven, fabrics or netting to be treated may be made of natural fibres such as cotton, raffia, jute, flax, sisal, hessian, or wool, or synthetic fibres such as polyamide, polyester, polypropylene, polyacrylonitrile or the like. The polyesters are particularly suitable. The methods of textile treatment are known, e.g. WO 2008/151984, WO 2003/034823, U.S. Pat. No. 5,631,072, WO 2005/64072, WO2006/128870, EP 1724392, WO2005113886 or WO 2007/090739. 
     Further areas of use of the compositions according to the invention are the field of tree injection/trunk treatment for all ornamental trees as well all sort of fruit and nut trees. 
     In the field of tree injection/trunk treatment, the compounds according to the present invention are especially suitable against wood-boring insects from the order Lepidoptera as mentioned above and from the order Coleoptera, especially against woodborers listed in the following tables A and B: 
     
       
         
           
               
             
               
                 TABLE A 
               
             
            
               
                   
               
               
                 Examples of exotic woodborers of economic importance. 
               
            
           
           
               
               
               
            
               
                 Family 
                 Species 
                 Host or Crop Infested 
               
               
                   
               
               
                 Buprestidae 
                 
                   Agrilus planipennis 
                 
                 Ash 
               
               
                 Cerambycidae 
                 
                   Anoplura glabripennis 
                 
                 Hardwoods 
               
               
                   
                 
                   Xylosandrus crassiusculus 
                 
                 Hardwoods 
               
               
                 Scolytidae 
                 
                   X. mutilatus 
                 
                 Hardwoods 
               
               
                   
                 
                   Tomicus piniperda 
                 
                 Conifers 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE B 
               
             
            
               
                   
               
               
                 Examples of native woodborers of economic importance. 
               
            
           
           
               
               
               
            
               
                 Family 
                 Species 
                 Host or Crop Infested 
               
               
                   
               
               
                   
                 
                   Agrilus anxius 
                 
                 Birch 
               
               
                   
                 
                   Agrilus politus 
                 
                 Willow, Maple 
               
               
                   
                 
                   Agrilus sayi 
                 
                 Bayberry, Sweetfern 
               
               
                   
                 
                   Agrilus vittaticoillis 
                 
                 Apple, Pear, Cranberry, 
               
               
                   
                   
                 Serviceberry, Hawthorn 
               
               
                   
                 
                   Chrysobothris  
                 
                 Apple, Apricot, Beech, Boxelder, 
               
               
                 Buprestidae 
                 
                   femorata 
                 
                 Cherry, Chestnut, Currant, Elm, 
               
               
                   
                   
                 Hawthorn, Hackberry, Hickory, 
               
               
                   
                   
                 Horsechestnut, Linden, Maple, 
               
               
                   
                   
                 Mountain-ash, Oak, Pecan, Pear, 
               
               
                   
                   
                 Peach, Persimmon, Plum, Poplar, 
               
               
                   
                   
                 Quince, Redbud, Serviceberry, 
               
               
                   
                   
                 Sycamore, Walnut, Willow 
               
               
                   
                 
                   Texania campestris 
                 
                 Basswood, Beech, Maple, Oak, 
               
               
                   
                   
                 Sycamore, Willow, Yellow-poplar 
               
               
                   
                 
                   Goes pulverulentus 
                 
                 Beech, Elm, Nuttall, Willow,  
               
               
                   
                   
                 Black oak, Cherrybark oak,  
               
               
                   
                   
                 Water oak, Sycamore 
               
               
                   
                 
                   Goes tigrinus 
                 
                 Oak 
               
               
                   
                 
                   Neoclytus acuminatus 
                 
                 Ash, Hickory, Oak, Walnut,  
               
               
                   
                   
                 Birch, Beech, Maple, Eastern 
               
               
                   
                   
                 hophornbeam, Dogwood, 
               
               
                   
                   
                 Persimmon, Redbud, Holly, 
               
               
                   
                   
                 Hackberry, Black locust, 
               
               
                   
                   
                 Honeylocust, Yellow-poplar, 
               
               
                   
                   
                 Chestnut, Osage-orange,  
               
               
                   
                   
                 Sassafras, Lilac, Mountain- 
               
               
                   
                   
                 mahogany, Pear, Cherry,  
               
               
                   
                   
                 Plum, Peach, Apple, Elm, 
               
               
                   
                   
                 Basswood, Sweetgum 
               
               
                 Cerambycidae 
                 
                   Neoptychodes  
                 
                 Fig, Alder, Mulberry, Willow,  
               
               
                   
                 
                   trilineatus 
                 
                 Netleaf hackberry 
               
               
                   
                 
                   Oberea ocellata 
                 
                 Sumac, Apple, Peach, Plum, Pear, 
               
               
                   
                   
                 Currant, Blackberry 
               
               
                   
                 
                   Oberea tripunctata 
                 
                 Dogwood, Viburnum, Elm, 
               
               
                   
                   
                 Sourwood, Blueberry, 
               
               
                   
                   
                 Rhododendron, Azalea, Laurel, 
               
               
                   
                   
                 Poplar, Willow, Mulberry 
               
               
                   
                 
                   Oncideres cingulata 
                 
                 Hickory, Pecan, Persimmon, Elm, 
               
               
                   
                   
                 Sourwood, Basswood,  
               
               
                   
                   
                 Honeylocust, Dogwood,  
               
               
                   
                   
                 Eucalyptus, Oak, Hackberry,  
               
               
                   
                   
                 Maple, Fruit trees 
               
               
                   
                 
                   Saperda calcarata 
                 
                 Poplar 
               
               
                   
                 
                   Strophiona nitens 
                 
                 Chestnut, Oak, Hickory, Walnut, 
               
               
                   
                   
                 Beech, Maple 
               
               
                   
                 
                   Corthylus  
                 
                 Maple, Oak, Yellow-poplar,  
               
               
                   
                 
                   columbianus 
                 
                 Beech, Boxelder, Sycamore,  
               
               
                   
                   
                 Birch, Basswood, Chestnut, Elm 
               
               
                 Scolytidae 
                 
                   Dendroctonus  
                 
                 Pine 
               
               
                   
                 
                   frontalis 
                 
                   
               
               
                   
                 
                   Dryocoetes betulae 
                 
                 Birch, Sweetgum, Wild cherry, 
               
               
                   
                   
                 Beech, Pear 
               
               
                   
                 
                   Monarthrum  
                 
                 Oak, Maple, Birch, Chestnut, 
               
               
                   
                 
                   fasciatum 
                 
                 Sweetgum, Blackgum, Poplar, 
               
               
                   
                   
                 Hickory, Mimosa, Apple, Peach,  
               
               
                   
                   
                 Pine 
               
               
                   
                 
                   Phloeotribus  
                 
                 Peach, Cherry, Plum, Black  
               
               
                   
                 
                   liminaris 
                 
                 cherry, Elm, Mulberry,  
               
               
                   
                   
                 Mountain-ash 
               
               
                   
                 
                   Pseudopityophthorus  
                 
                 Oak, American beech, Black  
               
               
                   
                 
                   pruinosus 
                 
                 cherry, Chickasaw plum,  
               
               
                   
                   
                 Chestnut, Maple, Hickory,  
               
               
                   
                   
                 Hornbeam, Hophornbeam 
               
               
                   
                 
                   Paranthrene simulans 
                 
                 Oak, American chestnut 
               
               
                   
                 
                   Sannina uroceriformis 
                 
                 Persimmon 
               
               
                   
                 
                   Synanthedon exitiosa 
                 
                 Peach, Plum, Nectarine, Cherry, 
               
               
                   
                   
                 Apricot, Almond, Black cherry 
               
               
                   
                 
                   Synanthedon pictipes 
                 
                 Peach, Plum, Cherry, Beach,  
               
               
                   
                   
                 Black Cherry 
               
               
                 Sesiidae 
                 
                   Synanthedon  
                 
                 Tupelo 
               
               
                   
                 
                   rubrofascia 
                 
                   
               
               
                   
                 
                   Synanthedon scitula 
                 
                 Dogwood, Pecan, Hickory, Oak, 
               
               
                   
                   
                 Chestnut, Beech, Birch, Black  
               
               
                   
                   
                 cherry, Elm, Mountain-ash,  
               
               
                   
                   
                 Viburnum, Willow, Apple,  
               
               
                   
                   
                 Loquat, Ninebark, Bayberry 
               
               
                   
                 
                   Vitacea polistiformis 
                 
                 Grape 
               
               
                   
               
            
           
         
       
     
     In the hygiene sector, the compositions according to the invention are active against ectoparasites such as hard ticks, soft ticks, mange mites, harvest mites, flies (biting and licking), parasitic fly larvae, lice, hair lice, bird lice and fleas. 
     Examples of such parasites are: 
     Of the order Anoplurida:  Haematopinus  spp.,  Linognathus  spp.,  Pediculus  spp. and  Phtirus  spp.,  Solenopotes  spp. 
     Of the order Mallophagida:  Trimenopon  spp.,  Menopon  spp.,  Trinoton  spp.,  Bovicola  spp.,  Werneckiella  spp.,  Lepikentron  spp.,  Damalina  spp.,  Trichodectes  spp. and  Felicola  spp. 
     Of the order Diptera and the suborders Nematocerina and Brachycerina, for example  Aedes  spp.,  Anopheles  spp.,  Culex  spp.,  Simulium  spp.,  Eusimulium  spp.,  Phlebotomus  spp.,  Lutzomyia  spp.,  Culicoides  spp.,  Chrysops  spp.,  Hybomitra  spp.,  Atylotus  spp.,  Tabanus  spp.,  Haematopota  spp.,  Philipomyia  spp.,  Braula  spp.,  Musca  spp.,  Hydrotaea  spp.,  Stomoxys  spp.,  Haematobia  spp.,  Morellia  spp.,  Fannia  spp.,  Glossina  spp.,  Calliphora  spp.,  Lucilia  spp.,  Chrysomyia  spp.,  Wohlfahrtia  spp.,  Sarcophaga  spp.,  Oestrus  spp.,  Hypoderma  spp.,  Gasterophilus  spp.,  Hippobosca  spp.,  Lipoptena  spp. and  Melophagus  spp. 
     Of the order Siphonapterida, for example  Pulex  spp.,  Ctenocephalides  spp.,  Xenopsylla  spp.,  Ceratophyllus  spp. 
     Of the order Heteropterida, for example  Cimex  spp.,  Triatoma  spp.,  Rhodnius  spp.,  Panstrongylus  spp. 
     Of the order Blattarida, for example  Blatta orientalis, Periplaneta americana, Blattelagermanica  and  Supella  spp. 
     Of the subclass Acaria (Acarida) and the orders Meta- and Meso- stigmata , for example  Argas  spp.,  Ornithodorus  spp.,  Otobius  spp.,  Ixodes  spp.,  Amblyomma  spp.,  Boophilus  spp.,  Dermacentor  spp.,  Haemophysalis  spp.,  Hyalomma  spp.,  Rhipicephalus  spp.,  Dermanyssus  spp.,  Raillietia  spp.,  Pneumonyssus  spp.,  Sternostoma  spp. and  Varroa  spp. 
     Of the orders Actinedida (Prostigmata) and Acaridida (Astigmata), for example  Acarapis  spp.,  Cheyletiella  spp.,  Ornithocheyletia  spp.,  Myobia  spp.,  Psorergates  spp.,  Demodex  spp.,  Trombicula  spp.,  Listrophorus  spp.,  Acarus  spp.,  Tyrophagus  spp.,  Caloglyphus  spp.,  Hypodectes  spp.,  Pterolichus  spp.,  Psoroptes  spp.,  Chorioptes  spp.,  Otodectes  spp.,  Sarcoptes  spp.,  Notoedres  spp.,  Knemidocoptes  spp.,  Cytodites  spp. and  Laminosioptes  spp. 
     The compositions according to the invention are also suitable for protecting against insect infestation in the case of materials such as wood, textiles, plastics, adhesives, glues, paints, paper and card, leather, floor coverings and buildings. 
     The compositions according to the invention can be used, for example, against the following pests: beetles such as  Hylotrupes bajulus, Chlorophorus pilosis, Anobium punctatum, Xestobium rufovillosum, Ptilinuspecticornis, Dendrobium pertinex, Ernobius mollis, Priobium carpini, Lyctus brunneus, Lyctus africanus, Lyctus planicollis, Lyctus linearis, Lyctus pubescens, Trogoxylon aequale, Minthesrugicollis, Xyleborus  spec.,  Tryptodendron  spec.,  Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon  spec. and  Dinoderus minutus , and also hymenopterans such as  Sirex juvencus, Urocerus gigas, Urocerus gigas taignus  and  Urocerus augur , and termites such as  Kalotermes flavicollis, Cryptotermes brevis, Heterotermes indicola, Reticulitermes flavipes, Reticulitermes santonensis, Reticulitermes lucifugus, Mastotermes darwiniensis, Zootermopsis nevadensis  and  Coptotermes formosanus , and bristletails such as  Lepisma saccharina.    
     In one aspect, the invention therefore also relates to pesticidal compositions such as emulsifiable concentrates, suspension concentrates, microemulsions, oil dispersibles, directly sprayable or dilutable solutions, spreadable pastes, dilute emulsions, soluble powders, dispersible powders, wettable powders, dusts, granules or encapsulations in polymeric substances, which comprise—at least—one of the active ingredients according to any one of embodiments 1 to 7 and which are to be selected to suit the intended aims and the prevailing circumstances. In these compositions, the active ingredient is employed in pure form, a solid active ingredient for example in a specific particle size, or, preferably, together with—at least—one of the auxiliaries conventionally used in the art of formulation, such as extenders, for example solvents or solid carriers, or such as surface-active compounds (surfactants). 
     Examples of suitable solvents are: unhydrogenated or partially hydrogenated aromatic hydrocarbons, preferably the fractions C 8  to C 12  of alkylbenzenes, such as xylene mixtures, alkylated naphthalenes or tetrahydronaphthalene, aliphatic or cycloaliphatic hydrocarbons, such as paraffins or cyclohexane, alcohols such as ethanol, propanol or butanol, glycols and their ethers and esters such as propylene glycol, dipropylene glycol ether, ethylene glycol or ethylene glycol monomethyl ether or ethylene glycol monoethyl ether, ketones, such as cyclohexanone, isophorone or diacetone alcohol, strongly polar solvents, such as N-methylpyrrolid-2-one, dimethyl sulfoxide or N,N-dimethylformamide, water, unepoxidized or epoxidized vegetable oils, such as unexpodized or epoxidized rapeseed, castor, coconut or soya oil, and silicone oils. 
     Solid carriers which are used for example for dusts and dispersible powders are, as a rule, ground natural minerals such as calcite, talc, kaolin, montmorillonite or attapulgite. To improve the physical properties, it is also possible to add highly disperse silicas or highly disperse absorbtive polymers. Suitable adsorptive carriers for granules are porous types, such as pumice, brick grit, sepiolite or bentonite, and suitable non-sorptive carrier materials are calcite or sand. In addition, a large number of granulated materials of inorganic or organic nature can be used, in particular dolomite or comminuted plant residues. 
     Suitable surface-active compounds are, depending on the type of the active ingredient to be formulated, non-ionic, cationic and/or anionic surfactants or surfactant mixtures which have good emulsifying, dispersing and wetting properties. The surfactants mentioned below are only to be considered as examples; a large number of further surfactants which are conventionally used in the art of formulation and suitable according to the invention are described in the relevant literature. 
     Suitable non-ionic surfactants are, especially, polyglycol ether derivatives of aliphatic or cycloaliphatic alcohols, of saturated or unsaturated fatty acids or of alkyl phenols which may contain approximately 3 to approximately 30 glycol ether groups and approximately 8 to approximately 20 carbon atoms in the (cyclo)aliphatic hydrocarbon radical or approximately 6 to approximately 18 carbon atoms in the alkyl moiety of the alkyl phenols. Also suitable are water-soluble polyethylene oxide adducts with polypropylene glycol, ethylenediaminopolypropylene glycol or alkyl polypropylene glycol having 1 to approximately 10 carbon atoms in the alkyl chain and approximately 20 to approximately 250 ethylene glycol ether groups and approximately 10 to approximately 100 propylene glycol ether groups. Normally, the abovementioned compounds contain 1 to approximately 5 ethylene glycol units per propylene glycol unit. Examples which may be mentioned are nonylphenoxypolyethoxyethanol, castor oil polyglycol ether, polypropylene glycol/polyethylene oxide adducts, tributylphenoxypolyethoxyethanol, polyethylene glycol or octylphenoxypolyethoxyethanol. Also suitable are fatty acid esters of polyoxyethylene sorbitan, such as polyoxyethylene sorbitan trioleate. 
     The cationic surfactants are, especially, quaternary ammonium salts which generally have at least one alkyl radical of approximately 8 to approximately 22 C atoms as substituents and as further substituents (unhalogenated or halogenated) lower alkyl or hydroxyalkyl or benzyl radicals. The salts are preferably in the form of halides, methylsulfates or ethylsulfates. Examples are stearyltrimethylammonium chloride and benzylbis(2-chloroethyl)ethylammonium bromide. 
     Examples of suitable anionic surfactants are water-soluble soaps or water-soluble synthetic surface-active compounds. Examples of suitable soaps are the alkali, alkaline earth or (unsubstituted or substituted) ammonium salts of fatty acids having approximately 10 to approximately 22 C atoms, such as the sodium or potassium salts of oleic or stearic acid, or of natural fatty acid mixtures which are obtainable for example from coconut or tall oil; mention must also be made of the fatty acid methyl taurates. However, synthetic surfactants are used more frequently, in particular fatty sulfonates, fatty sulfates, sulfonated benzimidazole derivatives or alkylaryl sulfonates. As a rule, the fatty sulfonates and fatty sulfates are present as alkali, alkaline earth or (substituted or unsubstituted) ammonium salts and they generally have an alkyl radical of approximately 8 to approximately 22 C atoms, alkyl also to be understood as including the alkyl moiety of acyl radicals; examples which may be mentioned are the sodium or calcium salts of lignosulfonic acid, of the dodecylsulfuric ester or of a fatty alcohol sulfate mixture prepared from natural fatty acids. This group also includes the salts of the sulfuric esters and sulfonic acids of fatty alcohol/ethylene oxide adducts. The sulfonated benzimidazole derivatives preferably contain 2 sulfonyl groups and a fatty acid radical of approximately 8 to approximately 22 C atoms. Examples of alkylarylsulfonates are the sodium, calcium or triethanolammonium salts of decylbenzenesulfonic acid, of dibutylnaphthalenesulfonic acid or of a naphthalenesulfonic acid/formaldehyde condensate. Also possible are, furthermore, suitable phosphates, such as salts of the phosphoric ester of a p-nonylphenol/(4-14)ethylene oxide adduct, or phospholipids. 
     As a rule, the compositions comprise 0.1 to 99%, especially 0.1 to 95%, of active ingredient and 1 to 99.9%, especially 5 to 99.9%, of at least one solid or liquid adjuvant, it being possible as a rule for 0 to 25%, especially 0.1 to 20%, of the composition to be surfactants (% in each case meaning percent by weight). Whereas concentrated compositions tend to be preferred for commercial goods, the end consumer as a rule uses dilute compositions which have substantially lower concentrations of active ingredient. 
     Typically, a pre-mix formulation for foliar application comprises 0.1 to 99.9%, especially 1 to 95%, of the desired ingredients, and 99.9 to 0.1%, especially 99 to 5%, of a solid or liquid adjuvant (including, for example, a solvent such as water), where the auxiliaries can be a surfactant in an amount of 0 to 50%, especially 0.5 to 40%, based on the pre-mix formulation. 
     Normally, a tank-mix formulation for seed treatment application comprises 0.25 to 80%, especially 1 to 75%, of the desired ingredients, and 99.75 to 20%, especially 99 to 25%, of a solid or liquid auxiliaries (including, for example, a solvent such as water), where the auxiliaries can be a surfactant in an amount of 0 to 40%, especially 0.5 to 30%, based on the tank-mix formulation. 
     Typically, a pre-mix formulation for seed treatment application comprises 0.5 to 99.9%, especially 1 to 95%, of the desired ingredients, and 99.5 to 0.1%, especially 99 to 5%, of a solid or liquid adjuvant (including, for example, a solvent such as water), where the auxiliaries can be a surfactant in an amount of 0 to 50%, especially 0.5 to 40%, based on the pre-mix formulation. 
     Whereas commercial products will preferably be formulated as concentrates (e.g., pre-mix composition (formulation)), the end user will normally employ dilute formulations (e.g., tank mix composition). 
     Preferred seed treatment pre-mix formulations are aqueous suspension concentrates. The formulation can be applied to the seeds using conventional treating techniques and machines, such as fluidized bed techniques, the roller mill method, rotostatic seed treaters, and drum coaters. Other methods, such as spouted beds may also be useful. The seeds may be presized before coating. After coating, the seeds are typically dried and then transferred to a sizing machine for sizing. Such procedures are known in the art. 
     In general, the pre-mix compositions of the invention contain 0.5 to 99.9 especially 1 to 95, advantageously 1 to 50%, by mass of the desired ingredients, and 99.5 to 0.1, especially 99 to 5%, by mass of a solid or liquid adjuvant (including, for example, a solvent such as water), where the auxiliaries (or adjuvant) can be a surfactant in an amount of 0 to 50, especially 0.5 to 40%, by mass based on the mass of the pre-mix formulation. 
     Examples of foliar formulation types for pre-mix compositions are: 
     GR: Granules 
     WP: wettable powders 
     WG: water dispersable granules (powders) 
     SG: water soluble granules 
     SL: soluble concentrates 
     EC: emulsifiable concentrate 
     EW: emulsions, oil in water 
     ME: micro-emulsion 
     SC: aqueous suspension concentrate 
     CS: aqueous capsule suspension 
     OD: oil-based suspension concentrate, and 
     SE: aqueous suspo-emulsion. 
     Whereas, examples of seed treatment formulation types for pre-mix compositions are: 
     WS: wettable powders for seed treatment slurry 
     LS: solution for seed treatment 
     ES: emulsions for seed treatment 
     FS: suspension concentrate for seed treatment 
     WG: water dispersible granules, and 
     CS: aqueous capsule suspension. 
     Examples of formulation types suitable for tank-mix compositions are solutions, dilute emulsions, suspensions, or a mixture thereof, and dusts. 
     Preferred compositions are composed in particular as follows (%=percent by weight): 
     Emulsifiable Concentrates: 
     active ingredient: 1 to 95%, preferably 5 to 20% 
     surfactant: 1 to 30%, preferably 10 to 20% 
     solvent: 5 to 98%, preferably 70 to 85% 
     Dusts: 
     active ingredient: 0.1 to 10%, preferably 0.1 to 1% 
     solid carrier: 99.9 to 90%, preferably 99.9 to 99% 
     Suspension Concentrates: 
     active ingredient: 5 to 75%, preferably 10 to 50% 
     water: 94 to 24%, preferably 88 to 30% 
     surfactant: 1 to 40%, preferably 2 to 30% 
     Wettable Powders: 
     active ingredient: 0.5 to 90%, preferably 1 to 80% 
     surfactant: 0.5 to 20%, preferably 1 to 15% 
     solid carrier: 5 to 99%, preferably 15 to 98% 
     Granulates: 
     active ingredient: 0.5 to 30%, preferably 3 to 15% 
     solid carrier: 99.5 to 70%, preferably 97 to 85% 
    
    
     EXAMPLES 
     The following compounds according to embodiment 1 may be prepared according to the methods described herein or according to known methods. 
     Experimental 
     The following examples are intended to illustrate the invention and are not to be construed as being limitations thereon. 
     “Mp” means melting point in ° C.  1 H NMR measurements were recorded on a Brucker 400 MHz spectrometer, chemical shifts are given in ppm relevant to a TMS standard. Spectra measured in deuterated solvents as indicated. 
     LC MS Method A: Standard: 
     Spectra were recorded on a Mass Spectrometer from Waters (SQD or ZQ Single quadrupole mass spectrometer) equipped with an electrospray source (Polarity: positive or negative ions, Capillary: 3.00 kV, Cone range: 30-60 V, Extractor: 2.00 V, Source Temperature: 150° C., Desolvation Temperature: 350° C., Cone Gas Flow: 0 L/Hr, Desolvation Gas Flow: 650 L/Hr, Mass range: 100 to 900 Da) and an Acquity UPLC from Waters: Binary pump, heated column compartment and diode-array detector. 
     Solvent degasser, binary pump, heated column compartment and diode-array detector. Column: Waters UPLC HSS T3, 1.8 μm, 30×2.1 mm, Temp: 60° C., DAD Wavelength range (nm): 210 to 500, Solvent Gradient: A=water+5% MeOH+0.05% HCOOH, B=Acetonitrile+0.05% HCOOH: gradient: gradient: 0 min 0% B, 100% A; 1.2-1.5 min 100% B; Flow (ml/min) 0.85. 
     LC MS Method B: Standard Long: 
     Spectra were recorded on a Mass Spectrometer from Waters (SQD or ZQ Single quadrupole mass spectrometer) equipped with an electrospray source (Polarity: positive or negative ions, Capillary: 3.00 kV, Cone range: 30-60 V, Extractor: 2.00 V, Source Temperature: 150° C., Desolvation Temperature: 350° C., Cone Gas Flow: 0 L/Hr, Desolvation Gas Flow: 650 L/Hr, Mass range: 100 to 900 Da) and an Acquity UPLC from Waters: Binary pump, heated column compartment and diode-array detector. Solvent degasser, binary pump, heated column compartment and diode-array detector. Column: Waters UPLC HSS T3, 1.8 μm, 30×2.1 mm, Temp: 60° C., DAD Wavelength range (nm): 210 to 500, Solvent Gradient: A=water+5% MeOH+0.05% HCOOH, B=Acetonitrile+0.05% HCOOH: gradient: gradient: 0 min 0% B, 100% A; 2.7-3.0 min 100% B; Flow (ml/min) 0.85. 
     LC MS Method C: Standard Long Gradient: 
     Spectra were recorded on a ACQUITY SQD Mass Spectrometer from Waters (Single quadrupole mass spectrometer) equipped with an electrospray source (Polarity: positive ions, Capillary: 3.00 kV, Cone range: 20 V, Extractor: 3.00 V, Source Temperature: 150° C., Desolvation Temperature: 400° C., Cone Gas Flow: 60 L/Hr, Desolvation Gas Flow: 700 L/Hr, Mass range: 210 to 800 Da) and an Acquity UPLC from Waters: Column: Waters ACQUITY UPLC HSS T3; Column length: 30 mm; Internal diameter of column: 2.1 mm; Particle Size: 1.8 micron; Temperature: 60° C. DAD Wavelength range (nm): 210 to 400, Solvent Gradient: A=water+5% MeOH+0.05% HCOOH, B=Acetonitrile+0.05% HCOOH: gradient: gradient: 0 min 0% B, 100% A; 2.5-2.8 min 100% B; 3.0 min 100% A Flow (ml/min) 0.75. 
     Example 1: Preparation of N-(1-cyanocyclopropyl)-5-[1-[4-(difluoromethoxy)-2-methyl-5-(1,1,2,2,2-pentafluoroethyl)pyrazol-3-yl]pyrazol-4-yl]-2-(trifluoromethyl)benzamide 
     a) Preparation of 2-Methyl-5-(1,1,2,2,2-pentafluoroethyl)pyrazol-3-ol 
     
       
         
         
             
             
         
       
     
     A solution of ethyl 4,4,5,5,5-pentafluoro-3-oxo-pentanoate (30 g) and methyl hydrazine (6.2 g) in 120 ml of ethanol was stirred at RT overnight under Argon, the reaction mixture was then heated to 60° C. for 24 h to have a complete conversion. The solvent was evaporated under vacuum and the residue purified by flash chromatography to give 2-methyl-5-(1,1,2,2,2-pentafluoroethyl)pyrazol-3-ol as a beige solid. 
       1 H NMR (400 MHz, DMSO-d 6 ) δ ppm 3.60 (s, 3H) 5.71 (s, 1H) 11.70 (s, 1H). 
     LC-MS (Method B): t R =1.03 min, m/z=215 [M−1], 217 [M+1]. 
     b) Preparation of 5-Chloro-1-methyl-3-(1,1,2,2,2-pentafluoroethyl)pyrazole-4-carbaldehyde 
     
       
         
         
             
             
         
       
     
     Under Argon and at 0° C., POCl 3  (16.3 ml) was carefully added dropwise to 2.5 ml of N,N-dimethylformamide. To this reaction mixture was added 2-methyl-5-(1,1,2,2,2-pentafluoroethyl)pyrazol-3-ol (5 g), the mixture was then heated at 100° C. for 18 h. The reaction mixture was then cooled to RT and poured slowly on an aqueous solution of sodium hydrogen carbonate, the solution was extracted three time with ethyl acetate, dried over magnesium sulfate and evaporated under vacuum. The residue was purified by flash chromatography to give 5-chloro-1-methyl-3-(1,1,2,2,2-pentafluoroethyl)pyrazole-4-carbaldehyde as a yellow oil. 
       1 H NMR (400 MHz, CDCl 3 ) δ ppm 4.00 (s, 3H) 10.00 (s, 1H) 
     LC-MS (Method B): t R =1.37 min, m/z=263 [M+1]. 
     c) Preparation of 5-(4-Bromoprazol-1-yl)-1-methyl-3-(1,1,2,2,2-pentafluoroethyl)pyrazole-4-carbaldehyde 
     
       
         
         
             
             
         
       
     
     Under Argon, 5-chloro-1-methyl-3-(1,1,2,2,2-pentafluoroethyl)pyrazole-4-carbaldehyde (12.85 g, 48.9 mmol) was dissolved in acetonitrile (500 ml), then cesium carbonate (31.8 g) was added. To this mixture, 4-bromo-1H-pyrazole (7.9 g) was added and the mixture was stirred at RT for 18 h. The mixture was diluted with ethyl acetate, washed with water and brine, the organic layers were dried over magnesium sulfate and evaporated under vacuum. The residue was purified by flash chromatography to give 5-(4-bromopyrazol-1-yl)-1-methyl-3-(1,1,2,2,2-pentafluoroethyl)pyrazole-4-carbaldehyde as a white solid. 
       1 H NMR (400 MHz, CDCl 3 ) δ ppm 3.98 (s, 3H) 7.83 (s, 1H) 8.09 (s, 1H) 9.97 (s, 1H). 
     LC-MS (Method B): t R =1.63 min, m/z=371 [M−1], 373 [M+1]. 
     d) Preparation of 5-(4-Bromoprazol-1-yl)-1-methyl-3-(1,1,2,2,2-pentafluoroethyl)pyrazol-4-ol 
     
       
         
         
             
             
         
       
     
     To a solution of 5-(4-bromopyrazol-1-yl)-1-methyl-3-(1,1,2,2,2-pentafluoroethyl)pyrazole-4-carbaldehyde (500 mg) in dichloromethane (5 ml) was added meta-chloroperbenzoic acid (642 mg). The mixture was stirred at RT for 5 days. The mixture was diluted with ethyl acetate, and washed with water, and aqueous solutions of sodium hydrogen carbonate and sodium thiosulfate. The organic layers were dried over magnesium sulfate and reduced under vacuum. The residue was purified by flash chromatography to give 5-(4-bromopyrazol-1-yl)-1-methyl-3-(1,1,2,2,2-pentafluoroethyl)pyrazol-4-ol as a white solid. 
       1 H NMR (400 MHz, CDCl 3 ) δ ppm 3.79 (s, 3H) 6.35 (s, 1H) 7.66 (s, 1H) 7.75 (s, 1H) 
     LC-MS (Method B): t R =1.39 min, m/z=361 [M−1], 363 [M+1]. 
     e) Preparation of 5-(4-Bromoprazol-1-yl)-4-(difluoromethoxy)-1-methyl-3-(1,1,2,2,2-pentafluoroethyl)pyrazole 
     
       
         
         
             
             
         
       
     
     To a solution of 5-(4-bromopyrazol-1-yl)-1-methyl-3-(1,1,2,2,2-pentafluoroethyl)pyrazol-4-ol (466 mg) and potassium hydroxide (1.44 g) in a mixture of 4 ml of acetonitrile/water (1:1) was added at −78° C. 1-[[bromo(difluoro)methyl]-ethoxy-phosphoryl]oxyethane (689 mg). The mixture was allowed to warm to RT and stirred in a closed vessel for 3 h. In order to complete the reaction, 1-[[bromo(difluoro)methyl]-ethoxy-phosphoryl]oxyethane (172 mg) was added at −78° C. and the reaction was stirred at RT for another 1 h. The reaction mixture was diluted with ether, washed with brine and water. The organic layers were dried over magnesium sulfate and reduced under vacuum. The residue was purified by flash chromatography to give 5-(4-bromopyrazol-1-yl)-4-(difluoromethoxy)-1-methyl-3-(1,1,2,2,2-pentafluoroethyl)pyrazole as a colourless oil. 
       1 H NMR (400 MHz, CDCl 3 ) δ ppm 3.87 (s, 3H) 6.08-6.52 (m, 1H) 7.78 (s, 1H) 7.81 (s, 1H). 
     LC-MS (Method B): t R =1.79 min, m/z=409 [M−1], 411 [M+1]. 
     f) Preparation of 4-(difluoromethoxy)-1-methyl-3-(1,1,2,2,2-pentafluoroethyl)-5-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrazol-1-yl pyrazole 
     
       
         
         
             
             
         
       
     
     In a microwave tube, 5-(4-bromopyrazol-1-yl)-4-(difluoromethoxy)-1-methyl-3-(1,1,2,2,2-pentafluoroethyl)pyrazole (1.5 g), 4,4,5,5-tetramethyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,3,2-dioxaborolane (1.11 g) and potassium acetate (1.09 g) were dissolved in 7 ml dioxane. The mixture was purged with argon for 5 min. Pd(PPh 3 ) 4  (211 mg) was added and the mixture was irradiated in the microwave oven at 140° C. for 40 min. The mixture was evaporated, diluted with ethyl acetate, quenched with 25 ml water, extracted three times with ethyl acetate; the combined organic phases were washed with brine, dried over sodium sulfate, filtrated and evaporated. The black-brown resin was purified over silica gel to give 4-(difluoromethoxy)-1-methyl-3-(1,1,2,2,2-pentafluoroethyl)-5-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrazol-1-yl]pyrazole as a colorless oil. 
       1 H NMR (400 MHz, CDCl 3 ) δ ppm 1.38 (s, 12H), 3.88 (s, 3H) 6.10-6.50 (m, 1H), 8.0 (s, 1H) 8.10 (s, 1H). 
     LC-MS (Method B): t R =1.99 min, m/z=459 [M+1]. 
     g) Preparation of 5-[1-[4-(difluoromethoxy)-2-methyl-5-(1,1,2,2,2-pentafluoroethyl)pyrazol-3-l]pyrazol-4-yl]-2-(trifluoromethyl)benzoic Acid 
     
       
         
         
             
             
         
       
     
     In a flask, 4-(difluoromethoxy)-1-methyl-3-(1,1,2,2,2-pentafluoroethyl)-5-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrazol-1-yl]pyrazole (1.91 g), 5-bromo-2-(trifluoromethyl)benzoic acid (790 mg) were dissolved in 18 mL of DMF. The mixture was purged with argon for 5 min. Pd(PPh 3 ) 4  (325 mg) and a solution of potassium carbonate (1.17 g) in 3.3 mL of water were added and the mixture was heated at 85° C. for 50 min. The mixture was diluted with DCM and poured onto a solution of NaOH 0.5 M, the basic water phase was washed with DCM twice, then the pH was adjusted to acidic with an aqueous solution of HCl (6N) and extracted with DCM three times. The combined organic phases were dried over sodium sulfate, filtrated and evaporated to give 5-[1-[4-(difluoromethoxy)-2-methyl-5-(1,1,2,2,2-pentafluoroethyl)pyrazol-3-yl]pyrazol-4-yl]-2-(trifluoromethyl)benzoic acid as a white solid. 
     LC-MS (Method A): t R =1.07 min, m/z=519 [M−1]. 
     h) Preparation of N-(1-cyanocyclopropyl)-5-[1-[4-(difluoromethoxy)-2-methyl-5-(1,1,2,2,2-pentafluoroethyl)pyrazol-3-yl]pyrazol-4-yl]-2-(trifluoromethyl)benzamide 
     
       
         
         
             
             
         
       
     
     A mixture of 5-[1-[4-(difluoromethoxy)-2-methyl-5-(1,1,2,2,2-pentafluoroethyl)pyrazol-3-yl]pyrazol-4-yl]-2-(trifluoromethyl)benzoic acid (150 mg), 1-amino-1-cyano-cyclopropane hydrochloride (42 mg), HATU (139 mg) and N,N-diisopropylethylamine (144 mg) in 1.1 ml DMF was stirred at RT for 48 hours. The mixture was diluted with ethyl acetate, quenched with a solution of ammonium acetate; the organic phase was washed with brine, dried over sodium sulfate, filtered and evaporated. The crude product was purified by flash chromatography to give N-(1-cyanocyclopropyl)-5-[1-[4-(difluoromethoxy)-2-methyl-5-(1,1,2,2,2-pentafluoroethyl)pyrazol-3-yl]pyrazol-4-yl]-2-(trifluoromethyl)benzamide as a white solid. 
       1 H NMR (400 MHz, CDCl 3 ) δ ppm 1.39-1.47 (m, 2H) 1.66-1.75 (m, 2H) 3.97 (s, 3H) 6.15-6.55 (m, 2H) 7.71-7.80 (m, 3H) 8.12-8.16 (m, 1H) 8.18-8.22 (m, 1H). 
       19 F NMR (377 MHz, CDCl 3 ) δ ppm −113.43 (s, 2F) −84.04 (s, 3F) −82.58 (s, 2F) −58.21 (s, 3F) 
     LC-MS (Method A): t R =1.07 min, m/z=585 [M+1]. 
     The following compounds which have been characterized were prepared in analogy to Example 1. 
     
       
         
           
               
             
               
                 TABLE 1 
               
             
            
               
                   
               
               
                 Examples of compounds of formula (I): 
               
            
           
           
               
               
               
               
            
               
                   
                   
                   1 H-NMR (400 MHz)/ 
                   
               
               
                   
                 Structure 
                 LC MS (method) 
                   19 F NMR (377 MHz) 
               
               
                   
               
            
           
           
               
               
               
               
            
               
                 2 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (CDCl 3 ) δ ppm: 1.30- 1.88 (m, 4 H) 2.86- 3.33 (m, 3 H) 3.94- 3.98 (m, 3 H) 6.17-6.54  (m, 1 H) 7.57-7.92 (m, 3 H) 8.13-8.28 (m, 2 H) 
                 (CDCl 3 ) δ ppm 113.32- 113.43 (m, 2 F) 83.98- 84.03 (m, 3 F) 82.58- 82.80 (m, 2 F) 58.72- 59.98 (m, 3 F) 
               
               
                   
               
               
                 3 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (CDCl 3 ) δ ppm 1.07- 1.88 (m, 7 H) 3.13- 3.50 (m, 2 H) 3.95- 4.10 (m, 3 H) 6.15-6.52 (m, 1 H) 7.57-7.92 (m, 3 H) 8.12-8.27 (m, 2 H) 
                 (CDCl 3 ) δ ppm 113.32- 113.43 (m, 2 F) 83.98- 84.03 (m, 3 F) 82.56- 82.80 (m, 2 F) 58.60- 59.80 (m, 3 F) 
               
               
                   
               
               
                 4 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 LC-MS (C): tR = 1.81 min, m/z = 560 [M + 1]+  
                 — 
               
               
                   
               
               
                 5 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (CDCl 3 ) δ ppm 1.00- 2.01 (m, 9 H) 2.79-3.22  (m, 2 H) 3.97 (d, J = 10.27 Hz, 3 H) 6.11- 6.57 (m, 1 H) 7.60-7.99 (m, 3 H) 8.09-8.37 (m, 2H) LC-MS (A): tR = 1.18 min, m/z = 639 [M + 1]+  
                 CDCl3) δ ppm −113.36 (m, 2 F) −84.00 (m, 3 F) −82.67 (m, 2 F) −61.77- −55.75 (m, 3 F) 
               
               
                   
               
               
                 6 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (CDCl 3 ) δ ppm 1.44 (m, 2 H) 1.72-1.84 (m, 2 H) 2.56 (s, 3 H) 3.95 (s, 3 H) 6.15-6.54 (m, 1 H) 7.76-7.85 (m, 3 H) 8.16- 8.28 (m, 2 H) LC-MS (A): tR = 1.15 min, m/z = 627 [M + 1]+  
                 (CDCl 3 ) δ ppm −113.61- −113.20 (m, 2 F) −84.02 (s, 3 F) −82.73 (br s, 2 F) −58.39 (s, 3 F) 
               
               
                   
               
               
                 7 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (CDCl 3 ) δ ppm 1.03- 1.88 (m, 4 H) 3.19-3.59  (m, 3 H) 3.90-4.03 (m, 3 H) 4.35-5.34 (m, 2 H)  6.15-6.54 (m, 1 H) 7.65- 8.01 (m, 3 H) 8.06- 8.33 (m, 2 H) LC-MS (A): tR = 1.14 min, m/z = 629 [M + 1]+  
                 (CDCl 3 ) δ ppm −113.42 (br s, 2 F) −84.17- −83.84 (m, 3 F) −82.95- −82.39 (m, 2 F) −59.83- −58.17 (m, 3 F) 
               
               
                   
               
               
                 8 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (CDCl 3 ) δ ppm 1.57 (s, 4 H) 3.93-4.01 (m, 3 H) 4.08-4.64 (m, 2 H) 6.13- 6.57 (m, 1 H) 7.78- 7.98 (m, 3 H) 8.14-8.32 (m, 2 H) LC-MS (A): tR = 1.10 min, m/z = 624 [M + 1]+  
                 (CDCl3) δ ppm −113.28 (s, 2 F) −83.99 (br s, 3 F) −83.14-−82.27 (m, 2 F) −60.00-−58.08 (m, 3 F) 
               
               
                   
               
               
                 9 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (CDCl 3 ) δ ppm 1.16 (t, J = 7.15 Hz, 3 H) 1.49- 1.56 (m, 2 H) 1.87-1.96 (m, 2 H) 3.96 (s, 3 H) 4.19 (q, J = 6.97 Hz, 2 H) 6.12-6.59 (m, 1 H) 7.59 (s, 1 H) 7.73 (d, J = 1.10 Hz, 2 H) 8.11 (s, 1 H) 8.20 (s, 1 H) LC-MS (A): tR = 1.18 min, m/z = 657 [M + 1]+  
                 (CDCl 3 ) δ ppm −113.44 (br s, 2 F) −84.04 (s, 3 F) −82.59 (br s, 2 F) −59.16 (s, 3 F) 
               
               
                   
               
               
                 10 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (CDCl 3 ) δ ppm 1.28 (br s, 2 H) 1.60-1.86 (m, 2  H) 2.42-2.50 (m, 1 H) 3.84-4.84 (m, 5 H) 6.11- 6.57 (m, 1 H) 7.66- 8.00 (m, 3 H) 8.11-8.32 (m, 2 H) LC-MS (A): tR = 1.13 min, m/z = 623 [M + 1]+  
                 (CDCl 3 ) δ ppm −113.40 (br s, 2 F) −84.01 (br d, J = 13.23 Hz, 3 F) −82.67 (br d, J = 108.00 Hz, 2 F) −60.59-−57.83 (m, 3 F) 
               
               
                   
               
            
           
         
       
     
     Formulation Examples (%=Percent by Weight) 
     Example F1: Emulsion Concentrates 
       
     
       
         
           
               
               
               
               
               
             
               
                   
                   
               
               
                   
                   
                 a) 
                 b) 
                 c) 
               
               
                   
                   
               
             
            
               
                   
                 Active ingredient 
                 25% 
                 40% 
                 50% 
               
               
                   
                 Calcium dodecylbenzenesulfonate 
                  5% 
                  8% 
                  6% 
               
               
                   
                 Castor oil polyethylene 
                  5% 
                 — 
                 — 
               
               
                   
                 glycol ether (36 mol of EO) 
                   
                   
                   
               
               
                   
                 Tributylphenoxypolyethylene glycol 
                 — 
                 12% 
                  4% 
               
               
                   
                 ether (30 mol of EO) 
                   
                   
                   
               
               
                   
                 Cyclohexanone 
                 — 
                 15% 
                 20% 
               
               
                   
                 Xylene mixture 
                 65% 
                 25% 
                 20% 
               
               
                   
                   
               
            
           
         
       
     
     Emulsions of any desired concentration can be prepared from such concentrates by dilution with water. 
     Example F2: Solutions 
       
     
       
         
           
               
               
               
               
               
               
             
               
                   
                   
               
               
                   
                   
                 a) 
                 b) 
                 c) 
                 d) 
               
               
                   
                   
               
             
            
               
                   
                 Active ingredient 
                 80% 
                 10% 
                  5% 
                 95% 
               
               
                   
                 Ethylene glycol monomethyl 
                 20% 
                 — 
                 — 
                 — 
               
               
                   
                 ether 
                   
                   
                   
                   
               
               
                   
                 Polyethylene glycol 
                   
                   
                   
                   
               
               
                   
                 MW 400 
                 — 
                 70% 
                 — 
                 — 
               
               
                   
                 N-Methylpyrrolid-2-one 
                 — 
                 20% 
                 — 
                 — 
               
               
                   
                 Epoxidized coconut oil 
                 — 
                 — 
                  1% 
                  5% 
               
               
                   
                 Petroleum ether 
                   
                   
                   
                   
               
               
                   
                 (boiling range: 160-190°) 
                 — 
                 — 
                 94% 
                 — 
               
               
                   
                   
               
            
           
         
       
     
     The solutions are suitable for use in the form of microdrops. 
     Example F3: Granules 
       
     
       
         
           
               
               
               
               
               
             
               
                   
               
               
                   
                 a) 
                 b) 
                 c) 
                 d) 
               
               
                   
               
             
            
               
                 Active ingredient 
                  5% 
                 10% 
                  8% 
                 21% 
               
               
                 Kaolin 
                 94% 
                 — 
                 79% 
                 54% 
               
               
                 Highly disperse silica 
                  1% 
                 — 
                 13% 
                  7% 
               
               
                 Attapulgite 
                 — 
                 90% 
                 — 
                 18% 
               
               
                   
               
            
           
         
       
     
     The active ingredient is dissolved in dichloromethane, the solution is sprayed onto the carrier(s), and the solvent is subsequently evaporated in vacuo. 
     Example F4: Dusts 
       
     
       
         
           
               
               
               
               
             
               
                   
                   
               
               
                   
                   
                 a) 
                 b) 
               
               
                   
                   
               
             
            
               
                   
                 Active ingredient 
                  2% 
                  5% 
               
               
                   
                 Highly disperse silica  
                  1% 
                  5% 
               
               
                   
                 Talc 
                 97% 
                 — 
               
               
                   
                 Kaolin 
                 — 
                 90% 
               
               
                   
                   
               
            
           
         
       
     
     Ready-to-use dusts are obtained by intimately mixing the carriers and the active ingredient. 
     Example F5: Wettable Powders 
       
     
       
         
           
               
               
               
               
             
               
                   
               
               
                   
                 a) 
                 b) 
                 c) 
               
               
                   
               
             
            
               
                 Active ingredient 
                 25% 
                 50% 
                 75% 
               
               
                 Sodium lignosulfonate 
                  5% 
                  5% 
                 — 
               
               
                 Sodium lauryl sulfate 
                  3% 
                 — 
                  5% 
               
               
                 Sodium diisobutyl- 
                 — 
                  6% 
                 10% 
               
               
                 naphthalenesulfonate 
                   
                   
                   
               
               
                 Octylphenoxypolyethylene glycol 
                 — 
                  2% 
                 — 
               
               
                 ether (7-8 mol of EO) 
                   
                   
                   
               
               
                 Highly disperse silica 
                  5% 
                 10% 
                 10% 
               
               
                 Kaolin 
                 62% 
                 27% 
                 — 
               
               
                   
               
            
           
         
       
     
     The active ingredient is mixed with the additives and the mixture is ground thoroughly in a suitable mill. This gives wettable powders, which can be diluted with water to give suspensions of any desired concentration. 
     Example F6: Extruder Granules 
       
     
       
         
           
               
               
               
             
               
                   
                   
               
             
            
               
                   
                 Active ingredient 
                 10% 
               
               
                   
                 Sodium lignosulfonate 
                  2% 
               
               
                   
                 Carboxymethylcellulose 
                  1% 
               
               
                   
                 Kaolin 
                 87% 
               
               
                   
                   
               
            
           
         
       
     
     The active ingredient is mixed with the additives, and the mixture is ground, moistened with water, extruded, granulated and dried in a stream of air. 
     Example F7: Coated Granules 
       
     
       
         
           
               
               
               
             
               
                   
                   
               
             
            
               
                   
                 Active ingredient 
                  3% 
               
               
                   
                 Polyethylene glycol (MW 200) 
                  3% 
               
               
                   
                 Kaolin 
                 94% 
               
               
                   
                   
               
            
           
         
       
     
     In a mixer, the finely ground active ingredient is applied uniformly to the kaolin, which has been moistened with the polyethylene glycol. This gives dust-free coated granules. 
     Example F8: Suspension Concentrate 
       
     
       
         
           
               
               
             
               
                   
               
             
            
               
                 Active ingredient 
                  40% 
               
               
                 Ethylene glycol 
                  10% 
               
               
                 Nonylphenoxypolyethylene glycol ether (15 mol of EO) 
                   6% 
               
               
                 Sodium lignosulfonate 
                  10% 
               
               
                 Carboxymethylcellulose 
                   1% 
               
               
                 37% aqueous formaldehyde solution 
                 0.2% 
               
               
                 Silicone oil (75% aqueous emulsion) 
                 0.8% 
               
               
                 Water 
                  32% 
               
               
                   
               
            
           
         
       
     
     The finely ground active ingredient is mixed intimately with the additives. Suspensions of any desired concentration can be prepared from the thus resulting suspension concentrate by dilution with water. 
     Example F9: Powders for Dry Seed Treatment 
       
     
       
         
           
               
               
               
               
               
             
               
                   
                   
               
               
                   
                   
                 a) 
                 b) 
                 c) 
               
               
                   
                   
               
             
            
               
                   
                 active ingredient 
                 25% 
                 50% 
                 75% 
               
               
                   
                 light mineral oil 
                  5% 
                  5% 
                  5% 
               
               
                   
                 highly disperse silica acid 
                  5% 
                  5% 
                 — 
               
               
                   
                 Kaolin 
                 65% 
                 40% 
                 — 
               
               
                   
                 Talcum 
                 — 
                 — 
                 20% 
               
               
                   
                   
               
            
           
         
       
     
     The combination is thoroughly mixed with the adjuvants and the mixture is thoroughly ground in a suitable mill, affording powders that can be used directly for seed treatment. 
     Example F10: Emulsifiable Concentrate 
       
     
       
         
           
               
               
               
             
               
                   
                   
               
             
            
               
                   
                 active ingredient 
                 10% 
               
               
                   
                 octylphenol polyethylene glycol ether 
                  3% 
               
               
                   
                 (4-5 mol of ethylene oxide) 
                   
               
               
                   
                 calcium dodecylbenzenesulfonate 
                  3% 
               
               
                   
                 castor oil polyglycol ether (35 mol of ethylene oxide) 
                  4% 
               
               
                   
                 Cyclohexanone 
                 30% 
               
               
                   
                 xylene mixture 
                 50% 
               
               
                   
                   
               
            
           
         
       
     
     Emulsions of any required dilution, which can be used in plant protection, can be obtained from this concentrate by dilution with water. 
     Example F11: Flowable Concentrate for Seed Treatment 
       
     
       
         
           
               
               
             
               
                   
               
             
            
               
                 active ingredients 
                 40% 
               
               
                 propylene glycol 
                  5% 
               
               
                 copolymer butanol PO/EO 
                  2% 
               
               
                 Tristyrenephenole with 10-20 moles EO 
                  2% 
               
               
                 1,2-benzisothiazolin-3-one (in the form of a 20% solution in  
                 0.5%  
               
               
                 water) 
                   
               
               
                 monoazo-pigment calcium salt 
                  5% 
               
               
                 Silicone oil (in the form of a 75% emulsion in water) 
                 0.2%  
               
               
                 Water 
                 45.3%   
               
               
                   
               
            
           
         
       
     
     The finely ground combination is intimately mixed with the adjuvants, giving a suspension concentrate from which suspensions of any desired dilution can be obtained by dilution with water. Using such dilutions, living plants as well as plant propagation material can be treated and protected against infestation by microorganisms, by spraying, pouring or immersion. 
     The activity of the compositions according to the invention can be broadened considerably, and adapted to prevailing circumstances, by adding other insecticidally, acaricidally and/or fungicidally active ingredients. The mixtures of the compounds according to any one of embodiments 1 to 7 with other insecticidally, acaricidally and/or fungicidally active ingredients may also have further surprising advantages which can also be described, in a wider sense, as synergistic activity. For example, better tolerance by plants, reduced phytotoxicity, insects can be controlled in their different development stages or better behaviour during their production, for example during grinding or mixing, during their storage or during their use. 
     Suitable additions to active ingredients here are, for example, representatives of the following classes of active ingredients: organophosphorus compounds, nitrophenol derivatives, thioureas, juvenile hormones, formamidines, benzophenone derivatives, ureas, pyrrole derivatives, carbamates, pyrethroids, chlorinated hydrocarbons, acylureas, pyridylmethyleneamino derivatives, macrolides, neonicotinoids and  Bacillus thuringiensis  preparations. 
     The following mixtures of the compounds according to any one of embodiments 1 to 7 with active ingredients are preferred (the abbreviation “TX” means “one compound selected from the compounds according to any one of embodiments 1 to 7, preferably one compound from Table 1): an adjuvant selected from the group of substances consisting of petroleum oils (alternative name) (628)+TX, 
     an acaricide selected from the group of substances consisting of 1,1-bis(4-chlorophenyl)-2-ethoxyethanol (IUPAC name) (910)+TX, 2,4-dichlorophenyl benzenesulfonate (IUPAC/Chemical Abstracts name) (1059)+TX, 2-fluoro-N-methyl-N-1-naphthylacetamide (IUPAC name) (1295)+TX, 4-chlorophenyl phenyl sulfone (IUPAC name) (981)+TX, abamectin (1)+TX, acequinocyl (3)+TX, acetoprole [CCN]+TX, acrinathrin (9)+TX, aldicarb (16)+TX, aldoxycarb (863)+TX, alpha-cypermethrin (202)+TX, amidithion (870)+TX, amidoflumet [CCN]+TX, amidothioate (872)+TX, amiton (875)+TX, amiton hydrogen oxalate (875)+TX, amitraz (24)+TX, aramite (881)+TX, arsenous oxide (882)+TX, AVI 382 (compound code)+TX, AZ 60541 (compound code)+TX, azinphos-ethyl (44)+TX, azinphos-methyl (45)+TX, azobenzene (IUPAC name) (888)+TX, azocyclotin (46)+TX, azothoate (889)+TX, benomyl (62)+TX, benoxafos (alternative name) [CCN]+TX, benzoximate (71)+TX, benzyl benzoate (IUPAC name) [CCN]+TX, bifenazate (74)+TX, bifenthrin (76)+TX, binapacryl (907)+TX, brofenvalerate (alternative name)+TX, bromocyclen (918)+TX, bromophos (920)+TX, bromophos-ethyl (921)+TX, bromopropylate (94)+TX, buprofezin (99)+TX, butocarboxim (103)+TX, butoxycarboxim (104)+TX, butylpyridaben (alternative name)+TX, calcium polysulfide (IUPAC name) (111)+TX, camphechlor (941)+TX, carbanolate (943)+TX, carbaryl (115)+TX, carbofuran (118)+TX, carbophenothion (947)+TX, CGA 50′439 (development code) (125)+TX, chinomethionat (126)+TX, chlorbenside (959)+TX, chlordimeform (964)+TX, chlordimeform hydrochloride (964)+TX, chlorfenapyr (130)+TX, chlorfenethol (968)+TX, chlorfenson (970)+TX, chlorfensulfide (971)+TX, chlorfenvinphos (131)+TX, chlorobenzilate (975)+TX, chloromebuform (977)+TX, chloromethiuron (978)+TX, chloropropylate (983)+TX, chlorpyrifos (145)+TX, chlorpyrifos-methyl (146)+TX, chlorthiophos (994)+TX, cinerin I (696)+TX, cinerin II (696)+TX, cinerins (696)+TX, clofentezine (158)+TX, closantel (alternative name) [CCN]+TX, coumaphos (174)+TX, crotamiton (alternative name) [CCN]+TX, crotoxyphos (1010)+TX, cufraneb (1013)+TX, cyanthoate (1020)+TX, cyflumetofen (CAS Reg. No.: 400882-07-7)+TX, cyhalothrin (196)+TX, cyhexatin (199)+TX, cypermethrin (201)+TX, DCPM (1032)+TX, DDT (219)+TX, demephion (1037)+TX, demephion-O (1037)+TX, demephion-S (1037)+TX, demeton (1038)+TX, demeton-methyl (224)+TX, demeton-O (1038)+TX, demeton-O-methyl (224)+TX, demeton-S (1038)+TX, demeton-S-methyl (224)+TX, demeton-S-methylsulfon (1039)+TX, diafenthiuron (226)+TX, dialifos (1042)+TX, diazinon (227)+TX, dichlofluanid (230)+TX, dichlorvos (236)+TX, dicliphos (alternative name)+TX, dicofol (242)+TX, dicrotophos (243)+TX, dienochlor (1071)+TX, dimefox (1081)+TX, dimethoate (262)+TX, dinactin (alternative name) (653)+TX, dinex (1089)+TX, dinex-diclexine (1089)+TX, dinobuton (269)+TX, dinocap (270)+TX, dinocap-4 [CCN]+TX, dinocap-6 [CCN]+TX, dinocton (1090)+TX, dinopenton (1092)+TX, dinosulfon (1097)+TX, dinoterbon (1098)+TX, dioxathion (1102)+TX, diphenyl sulfone (IUPAC name) (1103)+TX, disulfiram (alternative name) [CCN]+TX, disulfoton (278)+TX, DNOC (282)+TX, dofenapyn (1113)+TX, doramectin (alternative name) [CCN]+TX, endosulfan (294)+TX, endothion (1121)+TX, EPN (297)+TX, eprinomectin (alternative name) [CCN]+TX, ethion (309)+TX, ethoate-methyl (1134)+TX, etoxazole (320)+TX, etrimfos (1142)+TX, fenazaflor (1147)+TX, fenazaquin (328)+TX, fenbutatin oxide (330)+TX, fenothiocarb (337)+TX, fenpropathrin (342)+TX, fenpyrad (alternative name)+TX, fenpyroximate (345)+TX, fenson (1157)+TX, fentrifanil (1161)+TX, fenvalerate (349)+TX, fipronil (354)+TX, fluacrypyrim (360)+TX, fluazuron (1166)+TX, flubenzimine (1167)+TX, flucycloxuron (366)+TX, flucythrinate (367)+TX, fluenetil (1169)+TX, flufenoxuron (370)+TX, flumethrin (372)+TX, fluorbenside (1174)+TX, fluvalinate (1184)+TX, FMC 1137 (development code) (1185)+TX, formetanate (405)+TX, formetanate hydrochloride (405)+TX, formothion (1192)+TX, formparanate (1193)+TX, gamma-HCH (430)+TX, glyodin (1205)+TX, halfenprox (424)+TX, heptenophos (432)+TX, hexadecyl cyclopropanecarboxylate (IUPAC/Chemical Abstracts name) (1216)+TX, hexythiazox (441)+TX, iodomethane (IUPAC name) (542)+TX, isocarbophos (alternative name) (473)+TX, isopropyl O-(methoxyaminothiophosphoryl)salicylate (IUPAC name) (473)+TX, ivermectin (alternative name) [CCN]+TX, jasmolin I (696)+TX, jasmolin II (696)+TX, jodfenphos (1248)+TX, lindane (430)+TX, lufenuron (490)+TX, malathion (492)+TX, malonoben (1254)+TX, mecarbam (502)+TX, mephosfolan (1261)+TX, mesulfen (alternative name) [CCN]+TX, methacrifos (1266)+TX, methamidophos (527)+TX, methidathion (529)+TX, methiocarb (530)+TX, methomyl (531)+TX, methyl bromide (537)+TX, metolcarb (550)+TX, mevinphos (556)+TX, mexacarbate (1290)+TX, milbemectin (557)+TX, milbemycin oxime (alternative name) [CCN]+TX, mipafox (1293)+TX, monocrotophos (561)+TX, morphothion (1300)+TX, moxidectin (alternative name) [CCN]+TX, naled (567)+TX, NC-184 (compound code)+TX, NC-512 (compound code)+TX, nifluridide (1309)+TX, nikkomycins (alternative name) [CCN]+TX, nitrilacarb (1313)+TX, nitrilacarb 1:1 zinc chloride complex (1313)+TX, NNI-0101 (compound code)+TX, NNI-0250 (compound code)+TX, omethoate (594)+TX, oxamyl (602)+TX, oxydeprofos (1324)+TX, oxydisulfoton (1325)+TX, pp′-DDT (219)+TX, parathion (615)+TX, permethrin (626)+TX, petroleum oils (alternative name) (628)+TX, phenkapton (1330)+TX, phenthoate (631)+TX, phorate (636)+TX, phosalone (637)+TX, phosfolan (1338)+TX, phosmet (638)+TX, phosphamidon (639)+TX, phoxim (642)+TX, pirimiphos-methyl (652)+TX, polychloroterpenes (traditional name) (1347)+TX, polynactins (alternative name) (653)+TX, proclonol (1350)+TX, profenofos (662)+TX, promacyl (1354)+TX, propargite (671)+TX, propetamphos (673)+TX, propoxur (678)+TX, prothidathion (1360)+TX, prothoate (1362)+TX, pyrethrin 1 (696)+TX, pyrethrin II (696)+TX, pyrethrins (696)+TX, pyridaben (699)+TX, pyridaphenthion (701)+TX, pyrimidifen (706)+TX, pyrimitate (1370)+TX, quinalphos (711)+TX, quintiofos (1381)+TX, R-1492 (development code) (1382)+TX, RA-17 (development code) (1383)+TX, rotenone (722)+TX, schradan (1389)+TX, sebufos (alternative name)+TX, selamectin (alternative name) [CCN]+TX, SI-0009 (compound code)+TX, sophamide (1402)+TX, spirodiclofen (738)+TX, spiromesifen (739)+TX, SSI-121 (development code) (1404)+TX, sulfiram (alternative name) [CCN]+TX, sulfluramid (750)+TX, sulfotep (753)+TX, sulfur (754)+TX, SZI-121 (development code) (757)+TX, tau-fluvalinate (398)+TX, tebufenpyrad (763)+TX, TEPP (1417)+TX, terbam (alternative name)+TX, tetrachlorvinphos (777)+TX, tetradifon (786)+TX, tetranactin (alternative name) (653)+TX, tetrasul (1425)+TX, thiafenox (alternative name)+TX, thiocarboxime (1431)+TX, thiofanox (800)+TX, thiometon (801)+TX, thioquinox (1436)+TX, thuringiensin (alternative name) [CCN]+TX, triamiphos (1441)+TX, triarathene (1443)+TX, triazophos (820)+TX, triazuron (alternative name)+TX, trichlorfon (824)+TX, trifenofos (1455)+TX, trinactin (alternative name) (653)+TX, vamidothion (847)+TX, vaniliprole [CCN] and YI-5302 (compound code)+TX, 
     an algicide selected from the group of substances consisting of bethoxazin [CCN]+TX, copper dioctanoate (IUPAC name) (170)+TX, copper sulfate (172)+TX, cybutryne [CCN]+TX, dichlone (1052)+TX, dichlorophen (232)+TX, endothal (295)+TX, fentin (347)+TX, hydrated lime [CCN]+TX, nabam (566)+TX, quinoclamine (714)+TX, quinonamid (1379)+TX, simazine (730)+TX, triphenyltin acetate (IUPAC name) (347) and triphenyltin hydroxide (IUPAC name) (347)+TX, 
     an anthelmintic selected from the group of substances consisting of abamectin (1)+TX, crufomate (1011)+TX, doramectin (alternative name) [CCN]+TX, emamectin (291)+TX, emamectin benzoate (291)+TX, eprinomectin (alternative name) [CCN]+TX, ivermectin (alternative name) [CCN]+TX, milbemycin oxime (alternative name) [CCN]+TX, moxidectin (alternative name) [CCN]+TX, piperazine [CCN]+TX, selamectin (alternative name) [CCN]+TX, spinosad (737) and thiophanate (1435)+TX, 
     an avicide selected from the group of substances consisting of chloralose (127)+TX, endrin (1122)+TX, fenthion (346)+TX, pyridin-4-amine (IUPAC name) (23) and strychnine (745)+TX, a bactericide selected from the group of substances consisting of 1-hydroxy-1H-pyridine-2-thione (IUPAC name) (1222)+TX, 4-(quinoxalin-2-ylamino)benzenesulfonamide (IUPAC name) (748)+TX, 8-hydroxyquinoline sulfate (446)+TX, bronopol (97)+TX, copper dioctanoate (IUPAC name) (170)+TX, copper hydroxide (IUPAC name) (169)+TX, cresol [CCN]+TX, dichlorophen (232)+TX, dipyrithione (1105)+TX, dodicin (1112)+TX, fenaminosulf (1144)+TX, formaldehyde (404)+TX, hydrargaphen (alternative name) [CCN]+TX, kasugamycin (483)+TX, kasugamycin hydrochloride hydrate (483)+TX, nickel bis(dimethyldithiocarbamate) (IUPAC name) (1308)+TX, nitrapyrin (580)+TX, octhilinone (590)+TX, oxolinic acid (606)+TX, oxytetracycline (611)+TX, potassium hydroxyquinoline sulfate (446)+TX, probenazole (658)+TX, streptomycin (744)+TX, streptomycin sesquisulfate (744)+TX, tecloftalam (766)+TX, and thiomersal (alternative name) [CCN]+TX, a biological agent selected from the group of substances consisting of  Adoxophyes orana  GV (alternative name) (12)+TX,  Agrobacterium radiobacter  (alternative name) (13)+TX,  Amblyseius  spp. (alternative name) (19)+TX,  Anagrapha falcifera  NPV (alternative name) (28)+TX,  Anagrus atomus  (alternative name) (29)+TX,  Aphelinus abdominalis  (alternative name) (33)+TX,  Aphidius colemani  (alternative name) (34)+TX,  Aphidoletes aphidimyza  (alternative name) (35)+TX,  Autographa californica  NPV (alternative name) (38)+TX,  Bacillus firmus  (alternative name) (48)+TX,  Bacillus sphaericus  Neide (scientific name) (49)+TX,  Bacillus thuringiensis  Berliner (scientific name) (51)+TX,  Bacillus thuringiensis  subsp.  aizawai  (scientific name) (51)+TX,  Bacillus thuringiensis  subsp.  israelensis  (scientific name) (51)+TX,  Bacillus thuringiensis  subsp.  japonensis  (scientific name) (51)+TX,  Bacillus thuringiensis  subsp.  kurstaki  (scientific name) (51)+TX,  Bacillus thuringiensis  subsp.  tenebrionis  (scientific name) (51)+TX,  Beauveria bassiana  (alternative name) (53)+TX,  Beauveria brongniartii  (alternative name) (54)+TX, Chrysoperla  carnea  (alternative name) (151)+TX,  Cryptolaemus montrouzieri  (alternative name) (178)+TX,  Cydia pomonella  GV (alternative name) (191)+TX,  Dacnusa sibirica  (alternative name) (212)+TX,  Diglyphus isaea  (alternative name) (254)+TX,  Encarsia formosa  (scientific name) (293)+TX,  Eretmocerus eremicus  (alternative name) (300)+TX,  Helicoverpa zea  NPV (alternative name) (431)+TX,  Heterorhabditis bacteriophora  and  H. megidis  (alternative name) (433)+TX,  Hippodamia convergens  (alternative name) (442)+TX,  Leptomastix dactylopii  (alternative name) (488)+TX,  Macrolophus caliginosus  (alternative name) (491)+TX,  Mamestra brassicae  NPV (alternative name) (494)+TX,  Metaphycus helvolus  (alternative name) (522)+TX,  Metarhizium anisopliae  var.  acridum  (scientific name) (523)+TX,  Metarhizium anisopliae  var.  anisopliae  (scientific name) (523)+TX,  Neodiprion sertifer  NPV and  N. lecontei  NPV (alternative name) (575)+TX,  Orius  spp. (alternative name) (596)+TX,  Paecilomyces fumosoroseus  (alternative name) (613)+TX,  Phytoseiulus persimilis  (alternative name) (644)+TX,  Spodoptera exigua  multicapsid nuclear polyhedrosis virus (scientific name) (741)+TX,  Steinernema bibionis  (alternative name) (742)+TX,  Steinernema carpocapsae  (alternative name) (742)+TX,  Steinernema feltiae  (alternative name) (742)+TX,  Steinernema glaseri  (alternative name) (742)+TX,  Steinernema riobrave  (alternative name) (742)+TX,  Steinernema riobravis  (alternative name) (742)+TX,  Steinernema scapterisci  (alternative name) (742)+TX,  Steinernema  spp. (alternative name) (742)+TX,  Trichogramma  spp. (alternative name) (826)+TX,  Typhlodromus occidentalis  (alternative name) (844) and  Verticillium lecanii  (alternative name) (848)+TX, a soil sterilant selected from the group of substances consisting of iodomethane (IUPAC name) (542) and methyl bromide (537)+TX, 
     a chemosterilant selected from the group of substances consisting of apholate [CCN]+TX, bisazir (alternative name) [CCN]+TX, busulfan (alternative name) [CCN]+TX, diflubenzuron (250)+TX, dimatif (alternative name) [CCN]+TX, hemel [CCN]+TX, hempa [CCN]+TX, metepa [CCN]+TX, methiotepa [CCN]+TX, methyl apholate [CCN]+TX, morzid [CCN]+TX, penfluron (alternative name) [CCN]+TX, tepa [CCN]+TX, thiohempa (alternative name) [CCN]+TX, thiotepa (alternative name) [CCN]+TX, tretamine (alternative name) [CCN] and uredepa (alternative name) [CCN]+TX, 
     an insect pheromone selected from the group of substances consisting of (E)-dec-5-en-1-yl acetate with (E)-dec-5-en-1-ol (IUPAC name) (222)+TX, (E)-tridec-4-en-1-yl acetate (IUPAC name) (829)+TX, (E)-6-methylhept-2-en-4-ol (IUPAC name) (541)+TX, (E,Z)-tetradeca-4,10-dien-1-yl acetate (IUPAC name) (779)+TX, (Z)-dodec-7-en-1-yl acetate (IUPAC name) (285)+TX, (Z)-hexadec-11-enal (IUPAC name) (436)+TX, (Z)-hexadec-11-en-1-yl acetate (IUPAC name) (437)+TX, (Z)-hexadec-13-en-11-yn-1-yl acetate (IUPAC name) (438)+TX, (Z)-icos-13-en-10-one (IUPAC name) (448)+TX, (Z)-tetradec-7-en-1-al (IUPAC name) (782)+TX, (Z)-tetradec-9-en-1-ol (IUPAC name) (783)+TX, (Z)-tetradec-9-en-1-yl acetate (IUPAC name) (784)+TX, (7E,9Z)-dodeca-7,9-dien-1-yl acetate (IUPAC name) (283)+TX, (9Z,11E)-tetradeca-9,11-dien-1-yl acetate (IUPAC name) (780)+TX, (9Z,12E)-tetradeca-9,12-dien-1-yl acetate (IUPAC name) (781)+TX, 14-methyloctadec-1-ene (IUPAC name) (545)+TX, 4-methylnonan-5-ol with 4-methylnonan-5-one (IUPAC name) (544)+TX, alpha-multistriatin (alternative name) [CCN]+TX, brevicomin (alternative name) [CCN]+TX, codlelure (alternative name) [CCN]+TX, codlemone (alternative name) (167)+TX, cuelure (alternative name) (179)+TX, disparlure (277)+TX, dodec-8-en-1-yl acetate (IUPAC name) (286)+TX, dodec-9-en-1-yl acetate (IUPAC name) (287)+TX, dodeca-8+TX, 10-dien-1-yl acetate (IUPAC name) (284)+TX, dominicalure (alternative name) [CCN]+TX, ethyl 4-methyloctanoate (IUPAC name) (317)+TX, eugenol (alternative name) [CCN]+TX, frontalin (alternative name) [CCN]+TX, gossyplure (alternative name) (420)+TX, grandlure (421)+TX, grandlure I (alternative name) (421)+TX, grandlure II (alternative name) (421)+TX, grandlure III (alternative name) (421)+TX, grandlure IV (alternative name) (421)+TX, hexalure [CCN]+TX, ipsdienol (alternative name) [CCN]+TX, ipsenol (alternative name) [CCN]+TX, japonilure (alternative name) (481)+TX, lineatin (alternative name) [CCN]+TX, litlure (alternative name) [CCN]+TX, looplure (alternative name) [CCN]+TX, medlure [CCN]+TX, megatomoic acid (alternative name) [CCN]+TX, methyl eugenol (alternative name) (540)+TX, muscalure (563)+TX, octadeca-2,13-dien-1-yl acetate (IUPAC name) (588)+TX, octadeca-3,13-dien-1-yl acetate (IUPAC name) (589)+TX, orfralure (alternative name) [CCN]+TX, oryctalure (alternative name) (317)+TX, ostramone (alternative name) [CCN]+TX, siglure [CCN]+TX, sordidin (alternative name) (736)+TX, sulcatol (alternative name) [CCN]+TX, tetradec-11-en-1-yl acetate (IUPAC name) (785)+TX, trimedlure (839)+TX, trimedlure A (alternative name) (839)+TX, trimedlure B 1  (alternative name) (839)+TX, trimedlure B 2  (alternative name) (839)+TX, trimedlure C (alternative name) (839) and trunc-call (alternative name) [CCN]+TX, 
     an insect repellent selected from the group of substances consisting of 2-(octylthio)ethanol (IUPAC name) (591)+TX, butopyronoxyl (933)+TX, butoxy(polypropylene glycol) (936)+TX, dibutyl adipate (IUPAC name) (1046)+TX, dibutyl phthalate (1047)+TX, dibutyl succinate (IUPAC name) (1048)+TX, diethyltoluamide [CCN]+TX, dimethyl carbate [CCN]+TX, dimethyl phthalate [CCN]+TX, ethyl hexanediol (1137)+TX, hexamide [CCN]+TX, methoquin-butyl (1276)+TX, methylneodecanamide [CCN]+TX, oxamate [CCN] and picaridin [CCN]+TX, 
     an insecticide selected from the group of substances consisting of 1-dichloro-1-nitroethane (IUPAC/Chemical Abstracts name) (1058)+TX, 1,1-dichloro-2,2-bis(4-ethylphenyl)ethane (IUPAC name) (1056), +TX, 1,2-dichloropropane (IUPAC/Chemical Abstracts name) (1062)+TX, 1,2-dichloropropane with 1,3-dichloropropene (IUPAC name) (1063)+TX, 1-bromo-2-chloroethane (IUPAC/Chemical Abstracts name) (916)+TX, 2,2,2-trichloro-1-(3,4-dichlorophenyl)ethyl acetate (IUPAC name) (1451)+TX, 2,2-dichlorovinyl 2-ethylsulfinylethyl methyl phosphate (IUPAC name) (1066)+TX, 2-(1,3-dithiolan-2-yl)phenyl dimethylcarbamate (IUPAC/Chemical Abstracts name) (1109)+TX, 2-(2-butoxyethoxy)ethyl thiocyanate (IUPAC/Chemical Abstracts name) (935)+TX, 2-(4,5-dimethyl-1,3-dioxolan-2-yl)phenyl methylcarbamate (IUPAC/Chemical Abstracts name) (1084)+TX, 2-(4-chloro-3,5-xylyloxy)ethanol (IUPAC name) (986)+TX, 2-chlorovinyl diethyl phosphate (IUPAC name) (984)+TX, 2-imidazolidone (IUPAC name) (1225)+TX, 2-isovalerylindan-1,3-dione (IUPAC name) (1246)+TX, 2-methyl(prop-2-ynyl)aminophenyl methylcarbamate (IUPAC name) (1284)+TX, 2-thiocyanatoethyl laurate (IUPAC name) (1433)+TX, 3-bromo-1-chloroprop-1-ene (IUPAC name) (917)+TX, 3-methyl-1-phenylpyrazol-5-yl dimethylcarbamate (IUPAC name) (1283)+TX, 4-methyl(prop-2-ynyl)amino-3,5-xylyl methylcarbamate (IUPAC name) (1285)+TX, 5,5-dimethyl-3-oxocyclohex-1-enyl dimethylcarbamate (IUPAC name) (1085)+TX, abamectin (1)+TX, acephate (2)+TX, acetamiprid (4)+TX, acethion (alternative name) [CCN]+TX, acetoprole [CCN]+TX, acrinathrin (9)+TX, acrylonitrile (IUPAC name) (861)+TX, alanycarb (15)+TX, aldicarb (16)+TX, aldoxycarb (863)+TX, aldrin (864)+TX, allethrin (17)+TX, allosamidin (alternative name) [CCN]+TX, allyxycarb (866)+TX, alpha-cypermethrin (202)+TX, alpha-ecdysone (alternative name) [CCN]+TX, aluminium phosphide (640)+TX, amidithion (870)+TX, amidothioate (872)+TX, aminocarb (873)+TX, amiton (875)+TX, amiton hydrogen oxalate (875)+TX, amitraz (24)+TX, anabasine (877)+TX, athidathion (883)+TX, AVI 382 (compound code)+TX, AZ 60541 (compound code)+TX, azadirachtin (alternative name) (41)+TX, azamethiphos (42)+TX, azinphos-ethyl (44)+TX, azinphos-methyl (45)+TX, azothoate (889)+TX,  Bacillus thuringiensis  delta endotoxins (alternative name) (52)+TX, barium hexafluorosilicate (alternative name) [CCN]+TX, barium polysulfide (IUPAC/Chemical Abstracts name) (892)+TX, barthrin [CCN]+TX, Bayer 22/190 (development code) (893)+TX, Bayer 22408 (development code) (894)+TX, bendiocarb (58)+TX, benfuracarb (60)+TX, bensultap (66)+TX, beta-cyfluthrin (194)+TX, beta-cypermethrin (203)+TX, bifenthrin (76)+TX, bioallethrin (78)+TX, bioallethrin S-cyclopentenyl isomer (alternative name) (79)+TX, bioethanomethrin [CCN]+TX, biopermethrin (908)+TX, bioresmethrin (80)+TX, bis(2-chloroethyl) ether (IUPAC name) (909)+TX, bistrifluron (83)+TX, borax (86)+TX, brofenvalerate (alternative name)+TX, bromfenvinfos (914)+TX, bromocyclen (918)+TX, bromo-DDT (alternative name) [CCN]+TX, bromophos (920)+TX, bromophos-ethyl (921)+TX, bufencarb (924)+TX, buprofezin (99)+TX, butacarb (926)+TX, butathiofos (927)+TX, butocarboxim (103)+TX, butonate (932)+TX, butoxycarboxim (104)+TX, butylpyridaben (alternative name)+TX, cadusafos (109)+TX, calcium arsenate [CCN]+TX, calcium cyanide (444)+TX, calcium polysulfide (IUPAC name) (111)+TX, camphechlor (941)+TX, carbanolate (943)+TX, carbaryl (115)+TX, carbofuran (118)+TX, carbon disulfide (IUPAC/Chemical Abstracts name) (945)+TX, carbon tetrachloride (IUPAC name) (946)+TX, carbophenothion (947)+TX, carbosulfan (119)+TX, cartap (123)+TX, cartap hydrochloride (123)+TX, cevadine (alternative name) (725)+TX, chlorbicyclen (960)+TX, chlordane (128)+TX, chlordecone (963)+TX, chlordimeform (964)+TX, chlordimeform hydrochloride (964)+TX, chlorethoxyfos (129)+TX, chlorfenapyr (130)+TX, chlorfenvinphos (131)+TX, chlorfluazuron (132)+TX, chlormephos (136)+TX, chloroform [CCN]+TX, chloropicrin (141)+TX, chlorphoxim (989)+TX, chlorprazophos (990)+TX, chlorpyrifos (145)+TX, chlorpyrifos-methyl (146)+TX, chlorthiophos (994)+TX, chromafenozide (150)+TX, cinerin I (696)+TX, cinerin II (696)+TX, cinerins (696)+TX, cis-resmethrin (alternative name)+TX, cismethrin (80)+TX, clocythrin (alternative name)+TX, cloethocarb (999)+TX, closantel (alternative name) [CCN]+TX, clothianidin (165)+TX, copper acetoarsenite [CCN]+TX, copper arsenate [CCN]+TX, copper oleate [CCN]+TX, coumaphos (174)+TX, coumithoate (1006)+TX, crotamiton (alternative name) [CCN]+TX, crotoxyphos (1010)+TX, crufomate (1011)+TX, cryolite (alternative name) (177)+TX, CS 708 (development code) (1012)+TX, cyanofenphos (1019)+TX, cyanophos (184)+TX, cyanthoate (1020)+TX, cyclethrin [CCN]+TX, cycloprothrin (188)+TX, cyfluthrin (193)+TX, cyhalothrin (196)+TX, cypermethrin (201)+TX, cyphenothrin (206)+TX, cyromazine (209)+TX, cythioate (alternative name) [CCN]+TX, d-limonene (alternative name) [CCN]+TX, d-tetramethrin (alternative name) (788)+TX, DAEP (1031)+TX, dazomet (216)+TX, DDT (219)+TX, decarbofuran (1034)+TX, deltamethrin (223)+TX, demephion (1037)+TX, demephion-O (1037)+TX, demephion-S (1037)+TX, demeton (1038)+TX, demeton-methyl (224)+TX, demeton-O (1038)+TX, demeton-O—methyl (224)+TX, demeton-S (1038)+TX, demeton-S-methyl (224)+TX, demeton-S-methylsulphon (1039)+TX, diafenthiuron (226)+TX, dialifos (1042)+TX, diamidafos (1044)+TX, diazinon (227)+TX, dicapthon (1050)+TX, dichlofenthion (1051)+TX, dichlorvos (236)+TX, dicliphos (alternative name)+TX, dicresyl (alternative name) [CCN]+TX, dicrotophos (243)+TX, dicyclanil (244)+TX, dieldrin (1070)+TX, diethyl 5-methylpyrazol-3-yl phosphate (IUPAC name) (1076)+TX, diflubenzuron (250)+TX, dilor (alternative name) [CCN]+TX, dimefluthrin [CCN]+TX, dimefox (1081)+TX, dimetan (1085)+TX, dimethoate (262)+TX, dimethrin (1083)+TX, dimethylvinphos (265)+TX, dimetilan (1086)+TX, dinex (1089)+TX, dinex-diclexine (1089)+TX, dinoprop (1093)+TX, dinosam (1094)+TX, dinoseb (1095)+TX, dinotefuran (271)+TX, diofenolan (1099)+TX, dioxabenzofos (1100)+TX, dioxacarb (1101)+TX, dioxathion (1102)+TX, disulfoton (278)+TX, dithicrofos (1108)+TX, DNOC (282)+TX, doramectin (alternative name) [CCN]+TX, DSP (1115)+TX, ecdysterone (alternative name) [CCN]+TX, EI 1642 (development code) (1118)+TX, emamectin (291)+TX, emamectin benzoate (291)+TX, EMPC (1120)+TX, empenthrin (292)+TX, endosulfan (294)+TX, endothion (1121)+TX, endrin (1122)+TX, EPBP (1123)+TX, EPN (297)+TX, epofenonane (1124)+TX, eprinomectin (alternative name) [CCN]+TX, esfenvalerate (302)+TX, etaphos (alternative name) [CCN]+TX, ethiofencarb (308)+TX, ethion (309)+TX, ethiprole (310)+TX, ethoate-methyl (1134)+TX, ethoprophos (312)+TX, ethyl formate (IUPAC name) [CCN]+TX, ethyl-DDD (alternative name) (1056)+TX, ethylene dibromide (316)+TX, ethylene dichloride (chemical name) (1136)+TX, ethylene oxide [CCN]+TX, etofenprox (319)+TX, etrimfos (1142)+TX, EXD (1143)+TX, famphur (323)+TX, fenamiphos (326)+TX, fenazaflor (1147)+TX, fenchlorphos (1148)+TX, fenethacarb (1149)+TX, fenfluthrin (1150)+TX, fenitrothion (335)+TX, fenobucarb (336)+TX, fenoxacrim (1153)+TX, fenoxycarb (340)+TX, fenpirithrin (1155)+TX, fenpropathrin (342)+TX, fenpyrad (alternative name)+TX, fensulfothion (1158)+TX, fenthion (346)+TX, fenthion-ethyl [CCN]+TX, fenvalerate (349)+TX, fipronil (354)+TX, flonicamid (358)+TX, flubendiamide (CAS. Reg. No.: 272451-65-7)+TX, flucofuron (1168)+TX, flucycloxuron (366)+TX, flucythrinate (367)+TX, fluenetil (1169)+TX, flufenerim [CCN]+TX, flufenoxuron (370)+TX, flufenprox (1171)+TX, flumethrin (372)+TX, fluvalinate (1184)+TX, FMC 1137 (development code) (1185)+TX, fonofos (1191)+TX, formetanate (405)+TX, formetanate hydrochloride (405)+TX, formothion (1192)+TX, formparanate (1193)+TX, fosmethilan (1194)+TX, fospirate (1195)+TX, fosthiazate (408)+TX, fosthietan (1196)+TX, furathiocarb (412)+TX, furethrin (1200)+TX, gamma-cyhalothrin (197)+TX, gamma-HCH (430)+TX, guazatine (422)+TX, guazatine acetates (422)+TX, GY-81 (development code) (423)+TX, halfenprox (424)+TX, halofenozide (425)+TX, HCH (430)+TX, HEOD (1070)+TX, heptachlor (1211)+TX, heptenophos (432)+TX, heterophos [CCN]+TX, hexaflumuron (439)+TX, HHDN (864)+TX, hydramethylnon (443)+TX, hydrogen cyanide (444)+TX, hydroprene (445)+TX, hyquincarb (1223)+TX, imidacloprid (458)+TX, imiprothrin (460)+TX, indoxacarb (465)+TX, iodomethane (IUPAC name) (542)+TX, IPSP (1229)+TX, isazofos (1231)+TX, isobenzan (1232)+TX, isocarbophos (alternative name) (473)+TX, isodrin (1235)+TX, isofenphos (1236)+TX, isolane (1237)+TX, isoprocarb (472)+TX, isopropyl O-(methoxy-aminothiophosphoryl)salicylate (IUPAC name) (473)+TX, isoprothiolane (474)+TX, isothioate (1244)+TX, isoxathion (480)+TX, ivermectin (alternative name) [CCN]+TX, jasmolin 1 (696)+TX, jasmolin 11 (696)+TX, jodfenphos (1248)+TX, juvenile hormone I (alternative name) [CCN]+TX, juvenile hormone II (alternative name) [CCN]+TX, juvenile hormone Ill (alternative name) [CCN]+TX, kelevan (1249)+TX, kinoprene (484)+TX, lambda-cyhalothrin (198)+TX, lead arsenate [CCN]+TX, lepimectin (CCN)+TX, leptophos (1250)+TX, lindane (430)+TX, lirimfos (1251)+TX, lufenuron (490)+TX, lythidathion (1253)+TX, m-cumenyl methylcarbamate (IUPAC name) (1014)+TX, magnesium phosphide (IUPAC name) (640)+TX, malathion (492)+TX, malonoben (1254)+TX, mazidox (1255)+TX, mecarbam (502)+TX, mecarphon (1258)+TX, menazon (1260)+TX, mephosfolan (1261)+TX, mercurous chloride (513)+TX, mesulfenfos (1263)+TX, metaflumizone (CCN)+TX, metam (519)+TX, metam-potassium (alternative name) (519)+TX, metam-sodium (519)+TX, methacrifos (1266)+TX, methamidophos (527)+TX, methanesulfonyl fluoride (IUPAC/Chemical Abstracts name) (1268)+TX, methidathion (529)+TX, methiocarb (530)+TX, methocrotophos (1273)+TX, methomyl (531)+TX, methoprene (532)+TX, methoquin-butyl (1276)+TX, methothrin (alternative name) (533)+TX, methoxychlor (534)+TX, methoxyfenozide (535)+TX, methyl bromide (537)+TX, methyl isothiocyanate (543)+TX, methylchloroform (alternative name) [CCN]+TX, methylene chloride [CCN]+TX, metofluthrin [CCN]+TX, metolcarb (550)+TX, metoxadiazone (1288)+TX, mevinphos (556)+TX, mexacarbate (1290)+TX, milbemectin (557)+TX, milbemycin oxime (alternative name) [CCN]+TX, mipafox (1293)+TX, mirex (1294)+TX, monocrotophos (561)+TX, morphothion (1300)+TX, moxidectin (alternative name) [CCN]+TX, naftalofos (alternative name) [CCN]+TX, naled (567)+TX, naphthalene (IUPAC/Chemical Abstracts name) (1303)+TX, NC-170 (development code) (1306)+TX, NC-184 (compound code)+TX, nicotine (578)+TX, nicotine sulfate (578)+TX, nifluridide (1309)+TX, nitenpyram (579)+TX, nithiazine (1311)+TX, nitrilacarb (1313)+TX, nitrilacarb 1:1 zinc chloride complex (1313)+TX, NNI-0101 (compound code)+TX, NNI-0250 (compound code)+TX, nornicotine (traditional name) (1319)+TX, novaluron (585)+TX, noviflumuron (586)+TX, 0-5-dichloro-4-iodophenyl O-ethyl ethylphosphonothioate (IUPAC name) (1057)+TX, O,O-diethyl 0-4-methyl-2-oxo-2H-chromen-7-yl phosphorothioate (IUPAC name) (1074)+TX, O,O-diethyl O-6-methyl-2-propylpyrimidin-4-yl phosphorothioate (IUPAC name) (1075)+TX, O,O,O′,O′-tetrapropyl dithiopyrophosphate (IUPAC name) (1424)+TX, oleic acid (IUPAC name) (593)+TX, omethoate (594)+TX, oxamyl (602)+TX, oxydemeton-methyl (609)+TX, oxydeprofos (1324)+TX, oxydisulfoton (1325)+TX, pp′-DDT (219)+TX, para-dichlorobenzene [CCN]+TX, parathion (615)+TX, parathion-methyl (616)+TX, penfluron (alternative name) [CCN]+TX, pentachlorophenol (623)+TX, pentachlorophenyl laurate (IUPAC name) (623)+TX, permethrin (626)+TX, petroleum oils (alternative name) (628)+TX, PH 60-38 (development code) (1328)+TX, phenkapton (1330)+TX, phenothrin (630)+TX, phenthoate (631)+TX, phorate (636)+TX, phosalone (637)+TX, phosfolan (1338)+TX, phosmet (638)+TX, phosnichlor (1339)+TX, phosphamidon (639)+TX, phosphine (IUPAC name) (640)+TX, phoxim (642)+TX, phoxim-methyl (1340)+TX, pirimetaphos (1344)+TX, pirimicarb (651)+TX, pirimiphos-ethyl (1345)+TX, pirimiphos-methyl (652)+TX, polychlorodicyclopentadiene isomers (IUPAC name) (1346)+TX, polychloroterpenes (traditional name) (1347)+TX, potassium arsenite [CCN]+TX, potassium thiocyanate [CCN]+TX, prallethrin (655)+TX, precocene I (alternative name) [CCN]+TX, precocene II (alternative name) [CCN]+TX, precocene III (alternative name) [CCN]+TX, primidophos (1349)+TX, profenofos (662)+TX, profluthrin [CCN]+TX, promacyl (1354)+TX, promecarb (1355)+TX, propaphos (1356)+TX, propetamphos (673)+TX, propoxur (678)+TX, prothidathion (1360)+TX, prothiofos (686)+TX, prothoate (1362)+TX, protrifenbute [CCN]+TX, pymetrozine (688)+TX, pyraclofos (689)+TX, pyrazophos (693)+TX, pyresmethrin (1367)+TX, pyrethrin 1 (696)+TX, pyrethrin II (696)+TX, pyrethrins (696)+TX, pyridaben (699)+TX, pyridalyl (700)+TX, pyridaphenthion (701)+TX, pyrimidifen (706)+TX, pyrimitate (1370)+TX, pyriproxyfen (708)+TX, quassia (alternative name) [CCN]+TX, quinalphos (711)+TX, quinalphos-methyl (1376)+TX, quinothion (1380)+TX, quintiofos (1381)+TX, R-1492 (development code) (1382)+TX, rafoxanide (alternative name) [CCN]+TX, resmethrin (719)+TX, rotenone (722)+TX, RU 15525 (development code) (723)+TX, RU 25475 (development code) (1386)+TX, ryania (alternative name) (1387)+TX, ryanodine (traditional name) (1387)+TX, sabadilla (alternative name) (725)+TX, schradan (1389)+TX, sebufos (alternative name)+TX, selamectin (alternative name) [CCN]+TX, SI-0009 (compound code)+TX, SI-0205 (compound code)+TX, SI-0404 (compound code)+TX, SI-0405 (compound code)+TX, silafluofen (728)+TX, SN 72129 (development code) (1397)+TX, sodium arsenite [CCN]+TX, sodium cyanide (444)+TX, sodium fluoride (IUPAC/Chemical Abstracts name) (1399)+TX, sodium hexafluorosilicate (1400)+TX, sodium pentachlorophenoxide (623)+TX, sodium selenate (IUPAC name) (1401)+TX, sodium thiocyanate [CCN]+TX, sophamide (1402)+TX, spinosad (737)+TX, spiromesifen (739)+TX, spirotetrmat (CCN)+TX, sulcofuron (746)+TX, sulcofuron-sodium (746)+TX, sulfluramid (750)+TX, sulfotep (753)+TX, sulfuryl fluoride (756)+TX, sulprofos (1408)+TX, tar oils (alternative name) (758)+TX, tau-fluvalinate (398)+TX, tazimcarb (1412)+TX, TDE (1414)+TX, tebufenozide (762)+TX, tebufenpyrad (763)+TX, tebupirimfos (764)+TX, teflubenzuron (768)+TX, tefluthrin (769)+TX, temephos (770)+TX, TEPP (1417)+TX, terallethrin (1418)+TX, terbam (alternative name)+TX, terbufos (773)+TX, tetrachloroethane [CCN]+TX, tetrachlorvinphos (777)+TX, tetramethrin (787)+TX, theta-cypermethrin (204)+TX, thiacloprid (791)+TX, thiafenox (alternative name)+TX, thiamethoxam (792)+TX, thicrofos (1428)+TX, thiocarboxime (1431)+TX, thiocyclam (798)+TX, thiocyclam hydrogen oxalate (798)+TX, thiodicarb (799)+TX, thiofanox (800)+TX, thiometon (801)+TX, thionazin (1434)+TX, thiosultap (803)+TX, thiosultap-sodium (803)+TX, thuringiensin (alternative name) [CCN]+TX, tolfenpyrad (809)+TX, tralomethrin (812)+TX, transfluthrin (813)+TX, transpermethrin (1440)+TX, triamiphos (1441)+TX, triazamate (818)+TX, triazophos (820)+TX, triazuron (alternative name)+TX, trichlorfon (824)+TX, trichlormetaphos-3 (alternative name) [CCN]+TX, trichloronat (1452)+TX, trifenofos (1455)+TX, triflumuron (835)+TX, trimethacarb (840)+TX, triprene (1459)+TX, vamidothion (847)+TX, vaniliprole [CCN]+TX, veratridine (alternative name) (725)+TX, veratrine (alternative name) (725)+TX, XMC (853)+TX, xylylcarb (854)+TX, YI-5302 (compound code)+TX, zeta-cypermethrin (205)+TX, zetamethrin (alternative name)+TX, zinc phosphide (640)+TX, zolaprofos (1469) and ZXI 8901 (development code) (858)+TX, cyantraniliprole [736994-63-19+TX, chlorantraniliprole [500008-45-7]+TX, cyenopyrafen [560121-52-0]+TX, cyflumetofen [400882-07-7]+TX, pyrifluquinazon [337458-27-2]+TX, spinetoram [187166-40-1+187166-15-0]+TX, spirotetramat [203313-25-1]+TX, sulfoxaflor [946578-00-3]+TX, flufiprole [704886-18-0]+TX, meperfluthrin [915288-13-0]+TX, tetramethylfluthrin [84937-88-2]+TX, triflumezopyrim (disclosed in WO 2012/092115)+TX, 
     a molluscicide selected from the group of substances consisting of bis(tributyltin) oxide (IUPAC name) (913)+TX, bromoacetamide [CCN]+TX, calcium arsenate [CCN]+TX, cloethocarb (999)+TX, copper acetoarsenite [CCN]+TX, copper sulfate (172)+TX, fentin (347)+TX, ferric phosphate (IUPAC name) (352)+TX, metaldehyde (518)+TX, methiocarb (530)+TX, niclosamide (576)+TX, niclosamide-olamine (576)+TX, pentachlorophenol (623)+TX, sodium pentachlorophenoxide (623)+TX, tazimcarb (1412)+TX, thiodicarb (799)+TX, tributyltin oxide (913)+TX, trifenmorph (1454)+TX, trimethacarb (840)+TX, triphenyltin acetate (IUPAC name) (347) and triphenyltin hydroxide (IUPAC name) (347)+TX, pyriprole [394730-71-3]+TX, a nematicide selected from the group of substances consisting of AKD-3088 (compound code)+TX, 1,2-dibromo-3-chloropropane (IUPAC/Chemical Abstracts name) (1045)+TX, 1,2-dichloropropane (IUPAC/Chemical Abstracts name) (1062)+TX, 1,2-dichloropropane with 1,3-dichloropropene (IUPAC name) (1063)+TX, 1,3-dichloropropene (233)+TX, 3,4-dichlorotetrahydrothiophene 1,1-dioxide (IUPAC/Chemical Abstracts name) (1065)+TX, 3-(4-chlorophenyl)-5-methylrhodanine (IUPAC name) (980)+TX, 5-methyl-6-thioxo-1,3,5-thiadiazinan-3-ylacetic acid (IUPAC name) (1286)+TX, 6-isopentenylaminopurine (alternative name) (210)+TX, abamectin (1)+TX, acetoprole [CCN]+TX, alanycarb (15)+TX, aldicarb (16)+TX, aldoxycarb (863)+TX, AZ 60541 (compound code)+TX, benclothiaz [CCN]+TX, benomyl (62)+TX, butylpyridaben (alternative name)+TX, cadusafos (109)+TX, carbofuran (118)+TX, carbon disulfide (945)+TX, carbosulfan (119)+TX, chloropicrin (141)+TX, chlorpyrifos (145)+TX, cloethocarb (999)+TX, cytokinins (alternative name) (210)+TX, dazomet (216)+TX, DBCP (1045)+TX, DCIP (218)+TX, diamidafos (1044)+TX, dichlofenthion (1051)+TX, dicliphos (alternative name)+TX, dimethoate (262)+TX, doramectin (alternative name) [CCN]+TX, emamectin (291)+TX, emamectin benzoate (291)+TX, eprinomectin (alternative name) [CCN]+TX, ethoprophos (312)+TX, ethylene dibromide (316)+TX, fenamiphos (326)+TX, fenpyrad (alternative name)+TX, fensulfothion (1158)+TX, fosthiazate (408)+TX, fosthietan (1196)+TX, furfural (alternative name) [CCN]+TX, GY-81 (development code) (423)+TX, heterophos [CCN]+TX, iodomethane (IUPAC name) (542)+TX, isamidofos (1230)+TX, isazofos (1231)+TX, ivermectin (alternative name) [CCN]+TX, kinetin (alternative name) (210)+TX, mecarphon (1258)+TX, metam (519)+TX, metam-potassium (alternative name) (519)+TX, metam-sodium (519)+TX, methyl bromide (537)+TX, methyl isothiocyanate (543)+TX, milbemycin oxime (alternative name) [CCN]+TX, moxidectin (alternative name) [CCN]+TX,  Myrothecium verrucaria  composition (alternative name) (565)+TX, NC-184 (compound code)+TX, oxamyl (602)+TX, phorate (636)+TX, phosphamidon (639)+TX, phosphocarb [CCN]+TX, sebufos (alternative name)+TX, selamectin (alternative name) [CCN]+TX, spinosad (737)+TX, terbam (alternative name)+TX, terbufos (773)+TX, tetrachlorothiophene (IUPAC/Chemical Abstracts name) (1422)+TX, thiafenox (alternative name)+TX, thionazin (1434)+TX, triazophos (820)+TX, triazuron (alternative name)+TX, xylenols [CCN]+TX, YI-5302 (compound code) and zeatin (alternative name) (210)+TX, fluensulfone [318290-98-1]+TX, a nitrification inhibitor selected from the group of substances consisting of potassium ethylxanthate [CCN] and nitrapyrin (580)+TX, 
     a plant activator selected from the group of substances consisting of acibenzolar (6)+TX, acibenzolar-S-methyl (6)+TX, probenazole (658) and  Reynoutria sachalinensis  extract (alternative name) (720)+TX, a rodenticide selected from the group of substances consisting of 2-isovalerylindan-1,3-dione (IUPAC name) (1246)+TX, 4-(quinoxalin-2-ylamino)benzenesulfonamide (IUPAC name) (748)+TX, alpha-chlorohydrin [CCN]+TX, aluminium phosphide (640)+TX, antu (880)+TX, arsenous oxide (882)+TX, barium carbonate (891)+TX, bisthiosemi (912)+TX, brodifacoum (89)+TX, bromadiolone (91)+TX, bromethalin (92)+TX, calcium cyanide (444)+TX, chloralose (127)+TX, chlorophacinone (140)+TX, cholecalciferol (alternative name) (850)+TX, coumachlor (1004)+TX, coumafuryl (1005)+TX, coumatetralyl (175)+TX, crimidine (1009)+TX, difenacoum (246)+TX, difethialone (249)+TX, diphacinone (273)+TX, ergocalciferol (301)+TX, flocoumafen (357)+TX, fluoroacetamide (379)+TX, flupropadine (1183)+TX, flupropadine hydrochloride (1183)+TX, gamma-HCH (430)+TX, HCH (430)+TX, hydrogen cyanide (444)+TX, iodomethane (IUPAC name) (542)+TX, lindane (430)+TX, magnesium phosphide (IUPAC name) (640)+TX, methyl bromide (537)+TX, norbormide (1318)+TX, phosacetim (1336)+TX, phosphine (IUPAC name) (640)+TX, phosphorus [CCN]+TX, pindone (1341)+TX, potassium arsenite [CCN]+TX, pyrinuron (1371)+TX, scilliroside (1390)+TX, sodium arsenite [CCN]+TX, sodium cyanide (444)+TX, sodium fluoroacetate (735)+TX, strychnine (745)+TX, thallium sulfate [CCN]+TX, warfarin (851) and zinc phosphide (640)+TX, 
     a synergist selected from the group of substances consisting of 2-(2-butoxyethoxy)ethyl piperonylate (IUPAC name) (934)+TX, 5-(1,3-benzodioxol-5-yl)-3-hexylcyclohex-2-enone (IUPAC name) (903)+TX, farnesol with nerolidol (alternative name) (324)+TX, MB-599 (development code) (498)+TX, MGK 264 (development code) (296)+TX, piperonyl butoxide (649)+TX, piprotal (1343)+TX, propyl isomer (1358)+TX, S421 (development code) (724)+TX, sesamex (1393)+TX, sesasmolin (1394) and sulfoxide (1406)+TX, 
     an animal repellent selected from the group of substances consisting of anthraquinone (32)+TX, chloralose (127)+TX, copper naphthenate [CCN]+TX, copper oxychloride (171)+TX, diazinon (227)+TX, dicyclopentadiene (chemical name) (1069)+TX, guazatine (422)+TX, guazatine acetates (422)+TX, methiocarb (530)+TX, pyridin-4-amine (IUPAC name) (23)+TX, thiram (804)+TX, trimethacarb (840)+TX, zinc naphthenate [CCN] and ziram (856)+TX, a virucide selected from the group of substances consisting of imanin (alternative name) [CCN] and ribavirin (alternative name) [CCN]+TX, 
     a wound protectant selected from the group of substances consisting of mercuric oxide (512)+TX, octhilinone (590) and thiophanate-methyl (802)+TX, 
     and biologically active compounds selected from the group consisting of azaconazole (60207-31-0]+TX, bitertanol [70585-36-3]+TX, bromuconazole [116255-48-2]+TX, cyproconazole [94361-06-5]+TX, difenoconazole [119446-68-3]+TX, diniconazole [83657-24-3]+TX, epoxiconazole [106325-08-0]+TX, fenbuconazole [114369-43-6]+TX, fluquinconazole [136426-54-5]+TX, flusilazole [85509-19-9]+TX, flutriafol [76674-21-0]+TX, hexaconazole [79983-71-4]+TX, imazalil [35554-44-0]+TX, imibenconazole [86598-92-7]+TX, ipconazole [125225-28-7]+TX, metconazole [125116-23-6]+TX, myclobutanil [88671-89-0]+TX, pefurazoate [101903-30-4]+TX, penconazole [66246-88-6]+TX, prothioconazole [178928-70-6]+TX, pyrifenox [88283-41-4]+TX, prochloraz [67747-09-5]+TX, propiconazole [60207-90-1]+TX, simeconazole [149508-90-7]+TX, tebuconazole [107534-96-3]+TX, tetraconazole [112281-77-3]+TX, triadimefon [43121-43-3]+TX, triadimenol [55219-65-3]+TX, triflumizole [99387-89-0]+TX, triticonazole [131983-72-7]+TX, ancymidol [12771-68-5]+TX, fenarimol [60168-88-9]+TX, nuarimol [63284-71-9]+TX, bupirimate [41483-43-6]+TX, dimethirimol [5221-53-4]+TX, ethirimol [23947-60-6]+TX, dodemorph [1593-77-7]+TX, fenpropidine [67306-00-7]+TX, fenpropimorph [67564-91-4]+TX, spiroxamine [118134-30-8]+TX, tridemorph [81412-43-3]+TX, cyprodinil [121552-61-2]+TX, mepanipyrim [110235-47-7]+TX, pyrimethanil [53112-28-0]+TX, fenpiclonil [74738-17-3]+TX, fludioxonil [131341-86-1]+TX, benalaxyl [71626-11-4]+TX, furalaxyl [57646-30-7]+TX, metalaxyl [57837-19-1]+TX, R-metalaxyl [70630-17-0]+TX, ofurace [58810-48-3]+TX, oxadixyl [77732-09-3]+TX, benomyl [17804-35-2]+TX, carbendazim [10605-21-7]+TX, debacarb [62732-91-6]+TX, fuberidazole [3878-19-1]+TX, thiabendazole [148-79-8]+TX, chlozolinate [84332-86-5]+TX, dichlozoline [24201-58-9]+TX, iprodione [36734-19-7]+TX, myclozoline [54864-61-8]+TX, procymidone [32809-16-8]+TX, vinclozoline [50471-44-8]+TX, boscalid [188425-85-6]+TX, carboxin [5234-68-4]+TX, fenfuram [24691-80-3]+TX, flutolanil [66332-96-5]+TX, mepronil [55814-41-0]+TX, oxycarboxin [5259-88-1]+TX, penthiopyrad [183675-82-3]+TX, thifluzamide [130000-40-7]+TX, guazatine [108173-90-6]+TX, dodine [2439-10-3] [112-65-2] (free base)+TX, iminoctadine [13516-27-3]+TX, azoxystrobin [131860-33-8]+TX, dimoxystrobin [149961-52-4]+TX, enestroburin {Proc. BCPC, Int. Congr., Glasgow, 2003, 1, 93}+TX, fluoxastrobin [361377-29-9]+TX, kresoxim-methyl [143390-89-0]+TX, metominostrobin [133408-50-1]+TX, trifloxystrobin [141517-21-7]+TX, orysastrobin [248593-16-0]+TX, picoxystrobin [117428-22-5]+TX, pyraclostrobin [175013-18-0]+TX, ferbam [14484-64-1]+TX, mancozeb [8018-01-7]+TX, maneb [12427-38-2]+TX, metiram [9006-42-2]+TX, propineb [12071-83-9]+TX, thiram [137-26-8]+TX, zineb [12122-67-7]+TX, ziram [137-30-4]+TX, captafol [2425-06-1]+TX, captan [133-06-2]+TX, dichlofluanid [1085-98-9]+TX, fluoroimide [41205-21-4]+TX, folpet [133-07-3]+TX, tolylfluanid [731-27-1]+TX, bordeaux mixture [8011-63-0]+TX, copperhydroxid [20427-59-2]+TX, copperoxychlorid [1332-40-7]+TX, coppersulfat [7758-98-7]+TX, copperoxid [1317-39-1]+TX, mancopper [53988-93-5]+TX, oxine-copper [10380-28-6]+TX, dinocap [131-72-6]+TX, nitrothal-isopropyl [10552-74-6]+TX, edifenphos [17109-49-8]+TX, iprobenphos [26087-47-8]+TX, isoprothiolane [50512-35-1]+TX, phosdiphen [36519-00-3]+TX, pyrazophos [13457-18-6]+TX, tolclofos-methyl [57018-04-9]+TX, acibenzolar-S-methyl [135158-54-2]+TX, anilazine [101-05-3]+TX, benthiavalicarb [413615-35-7]+TX, blasticidin-S [2079-00-7]+TX, chinomethionat [2439-01-2]+TX, chloroneb [2675-77-6]+TX, chlorothalonil [1897-45-6]+TX, cyflufenamid [180409-60-3]+TX, cymoxanil [57966-95-7]+TX, dichlone [117-80-6]+TX, diclocymet [139920-32-4]+TX, diclomezine [62865-36-5]+TX, dicloran [99-30-9]+TX, diethofencarb [87130-20-9]+TX, dimethomorph [110488-70-5]+TX, SYP-LI90 (Flumorph) [211867-47-9]+TX, dithianon [3347-22-6]+TX, ethaboxam [162650-77-3]+TX, etridiazole [2593-15-9]+TX, famoxadone [131807-57-3]+TX, fenamidone [161326-34-7]+TX, fenoxanil [115852-48-7]+TX, fentin [668-34-8]+TX, ferimzone [89269-64-7]+TX, fluazinam [79622-59-6]+TX, fluopicolide [239110-15-7]+TX, flusulfamide [106917-52-6]+TX, fenhexamid [126833-17-8]+TX, fosetyl-aluminium [39148-24-8]+TX, hymexazol [10004-44-1]+TX, iprovalicarb [140923-17-7]+TX, IKF-916 (Cyazofamid) [120116-88-3]+TX, kasugamycin [6980-18-3]+TX, methasulfocarb [66952-49-6]+TX, metrafenone [220899-03-6]+TX, pencycuron [66063-05-6]+TX, phthalide [27355-22-2]+TX, polyoxins [11113-80-7]+TX, probenazole [27605-76-1]+TX, propamocarb [25606-41-1]+TX, proquinazid [189278-12-4]+TX, pyroquilon [57369-32-1]+TX, quinoxyfen [124495-18-7]+TX, quintozene [82-68-8]+TX, sulfur [7704-34-9]+TX, tiadinil [223580-51-6]+TX, triazoxide [72459-58-6]+TX, tricyclazole [41814-78-2]+TX, triforine [26644-46-2]+TX, validamycin [37248-47-8]+TX, zoxamide (RH7281) [156052-68-5]+TX, mandipropamid [374726-62-2]+TX, isopyrazam [881685-58-1]+TX, sedaxane [874967-67-6]+TX, 3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid (9-dichloromethylene-1,2,3,4-tetrahydro-1,4-methano-naphthalen-5-yl)-amide (disclosed in WO 2007/048556)+TX, 3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxylic acid (3′,4′,5′-trifluoro-biphenyl-2-yl)-amide (disclosed in WO 2006/087343)+TX, [(3S,4R,4aR,6S,6aS,12R,12aS,12bS)-3-[(cyclopropylcarbonyl)oxy]-1,3,4,4a,5,6,6a,12,12a,12b-decahydro-6,12-dihydroxy-4,6a,12b-trimethyl-11-oxo-9-(3-pyridinyl)-2H,11Hnaphtho[2,1-b]pyrano[3,4-e]pyran-4-yl]methyl-cyclopropanecarboxylate [915972-17-7]+TX and 1,3,5-trimethyl-N-(2-methyl-1-oxopropyl)-N-[3-(2-methylpropyl)-4-[2,2,2-trifluoro-1-methoxy-1-(trifluoromethyl)ethyl]phenyl]-1H-pyrazole-4-carboxamide [926914-55-8]+TX. 
     The references in brackets behind the active ingredients, e.g. [3878-19-1] refer to the Chemical Abstracts Registry number. The above described mixing partners are known. Where the active ingredients are included in “The Pesticide Manual” [The Pesticide Manual—A World Compendium; Thirteenth Edition; Editor: C. D. S. TomLin; The British Crop Protection Council], they are described therein under the entry number given in round brackets hereinabove for the particular compound; for example, the compound “abamectin” is described under entry number (1). Where “[CCN]” is added hereinabove to the particular compound, the compound in question is included in the “Compendium of Pesticide Common Names”, which is accessible on the internet [A. Wood;  Compendium of Pesticide Common Names , Copyright @ 1995-2004]; for example, the compound “acetoprole” is described under the internet address http://www.alanwood.net/pesticides/acetoprole.html. 
     Most of the active ingredients described above are referred to hereinabove by a so-called “common name”, the relevant “ISO common name” or another “common name” being used in individual cases. If the designation is not a “common name”, the nature of the designation used instead is given in round brackets for the particular compound; in that case, the IUPAC name, the IUPAC/Chemical Abstracts name, a “chemical name”, a “traditional name”, a “compound name” or a “development code” is used or, if neither one of those designations nor a “common name” is used, an “alternative name” is employed. “CAS Reg. No” means the Chemical Abstracts Registry Number. 
     The active ingredient mixture of the compounds according to any one of embodiments 1 to 7 with active ingredients described above comprises a compound according to any one of embodiments 1 to 7 and an active ingredient as described above preferably in a mixing ratio of from 100:1 to 1:6000, especially from 50:1 to 1:50, more especially in a ratio of from 20:1 to 1:20, even more especially from 10:1 to 1:10, very especially from 5:1 and 1:5, special preference being given to a ratio of from 2:1 to 1:2, and a ratio of from 4:1 to 2:1 being likewise preferred, above all in a ratio of 1:1, or 5:1, or 5:2, or 5:3, or 5:4, or 4:1, or 4:2, or 4:3, or 3:1, or 3:2, or 2:1, or 1:5, or 2:5, or 3:5, or 4:5, or 1:4, or 2:4, or 3:4, or 1:3, or 2:3, or 1:2, or 1:600, or 1:300, or 1:150, or 1:35, or 2:35, or 4:35, or 1:75, or 2:75, or 4:75, or 1:6000, or 1:3000, or 1:1500, or 1:350, or 2:350, or 4:350, or 1:750, or 2:750, or 4:750. Those mixing ratios are by weight. 
     The mixtures as described above can be used in a method for controlling pests, which comprises applying a composition comprising a mixture as described above to the pests or their environment, with the exception of a method for treatment of the human or animal body by surgery or therapy and diagnostic methods practised on the human or animal body. 
     The mixtures comprising a compound of according to any one of embodiments 1 to 7 and one or more active ingredients as described above can be applied, for example, in a single “ready-mix” form, in a combined spray mixture composed from separate formulations of the single active ingredient components, such as a “tank-mix”, and in a combined use of the single active ingredients when applied in a sequential manner, i.e. one after the other with a reasonably short period, such as a few hours or days. The order of applying the compounds according to any one of embodiments 1 to 7 and the active ingredients as described above is not essential for working the present invention. 
     The compositions according to the invention can also comprise further solid or liquid auxiliaries, such as stabilizers, for example unepoxidized or epoxidized vegetable oils (for example epoxidized coconut oil, rapeseed oil or soya oil), antifoams, for example silicone oil, preservatives, viscosity regulators, binders and/or tackifiers, fertilizers or other active ingredients for achieving specific effects, for example bactericides, fungicides, nematocides, plant activators, molluscicides or herbicides. 
     The compositions according to the invention are prepared in a manner known per se, in the absence of auxiliaries for example by grinding, screening and/or compressing a solid active ingredient and in the presence of at least one auxiliary for example by intimately mixing and/or grinding the active ingredient with the auxiliary (auxiliaries). These processes for the preparation of the compositions and the use of the compounds I for the preparation of these compositions are also a subject of the invention. 
     The application methods for the compositions, that is the methods of controlling pests of the abovementioned type, such as spraying, atomizing, dusting, brushing on, dressing, scattering or pouring—which are to be selected to suit the intended aims of the prevailing circumstances—and the use of the compositions for controlling pests of the abovementioned type are other subjects of the invention. Typical rates of concentration are between 0.1 and 1000 ppm, preferably between 0.1 and 500 ppm, of active ingredient. The rate of application per hectare is generally 1 to 2000 g of active ingredient per hectare, in particular 10 to 1000 g/ha, preferably 10 to 600 g/ha. 
     A preferred method of application in the field of crop protection is application to the foliage of the plants (foliar application), it being possible to select frequency and rate of application to match the danger of infestation with the pest in question. Alternatively, the active ingredient can reach the plants via the root system (systemic action), by drenching the locus of the plants with a liquid composition or by incorporating the active ingredient in solid form into the locus of the plants, for example into the soil, for example in the form of granules (soil application). In the case of paddy rice crops, such granules can be metered into the flooded paddy-field. 
     The compounds of the invention and compositions thereof are also be suitable for the protection of plant propagation material, for example seeds, such as fruit, tubers or kernels, or nursery plants, against pests of the abovementioned type. The propagation material can be treated with the compound prior to planting, for example seed can be treated prior to sowing. Alternatively, the compound can be applied to seed kernels (coating), either by soaking the kernels in a liquid composition or by applying a layer of a solid composition. It is also possible to apply the compositions when the propagation material is planted to the site of application, for example into the seed furrow during drilling. These treatment methods for plant propagation material and the plant propagation material thus treated are further subjects of the invention. Typical treatment rates would depend on the plant and pest/fungi to be controlled and are generally between 1 to 200 grams per 100 kg of seeds, preferably between 5 to 150 grams per 100 kg of seeds, such as between 10 to 100 grams per 100 kg of seeds. 
     The term seed embraces seeds and plant propagules of all kinds including but not limited to true seeds, seed pieces, suckers, corns, bulbs, fruit, tubers, grains, rhizomes, cuttings, cut shoots and the like and means in a preferred embodiment true seeds. 
     The present invention also comprises seeds coated or treated with or containing a compound according to any one of embodiments 1 to 7. The term “coated or treated with and/or containing” generally signifies that the active ingredient is for the most part on the surface of the seed at the time of application, although a greater or lesser part of the ingredient may penetrate into the seed material, depending on the method of application. When the said seed product is (re)planted, it may absorb the active ingredient. In an embodiment, the present invention makes available a plant propagation material adhered thereto with according to any one of embodiments 1 to 7. Further, it is hereby made available, a composition comprising a plant propagation material treated with a compound according to any one of embodiments 1 to 7. 
     Seed treatment comprises all suitable seed treatment techniques known in the art, such as seed dressing, seed coating, seed dusting, seed soaking and seed pelleting. The seed treatment application of the compound according to any one of embodiments 1 to 7 can be carried out by any known methods, such as spraying or by dusting the seeds before sowing or during the sowing/planting of the seeds. 
     The pesticidal/insecticidal properties of the compounds according to any one of embodiments 1 to 7 can be illustrated via the following tests: 
       Diabrotica balteata  (Corn Root Worm): 
     Maize sprouts placed onto an agar layer in 24-well microtiter plates were treated with aqueous test solutions prepared from 10′000 ppm DMSO stock solutions by spraying. After drying, the plates were infested with L2 larvae (6 to 10 per well). The samples were assessed for mortality 4 days after infestation. The following compounds resulted in at least 80% mortality at an application rate of 200 ppm: 1, 2, 3 and 4. 
       Euschistus heros  (Neotropical Brown Stink Bug): Feeding/Contact Activity 
     Soybean leaves on agar in 24-well microtiter plates were sprayed with aqueous test solutions prepared from 10′000 ppm DMSO stock solutions. After drying the leaves were infested with N2 nymphs. The samples were assessed for mortality 5 days after infestation. The following compounds resulted in at least 80% mortality at an application rate of 200 ppm: 1, 2, 3, 4, 5, 6, 7, 8, 9 and 10. 
       Myzus persicae  (Green Peach Aphid): Feeding/Contact Activity 
     Sunflower leaf discs were placed onto agar in a 24-well microtiter plate and sprayed with aqueous test solutions prepared from 10′000 ppm DMSO stock solutions. After drying, the leaf discs were infested with an aphid population of mixed ages. The samples were assessed for mortality 6 days after infestation. The following compounds resulted in at least 80% mortality at an application rate of 200 ppm: 1, 2, 3, 4, 5, 6, 7, 8, 9 and 10. 
       Plutella xylostella  (Diamond Back Moth): Feeding/Contact Activity 
     24-well microtiter plates with artificial diet were treated with aqueous test solutions prepared from 10′000 ppm DMSO stock solutions by pipetting. After drying, the plates were infested with L2 larvae (10 to 15 per well). The samples were assessed for mortality 5 days after infestation. The following compounds resulted in at least 80% mortality at an application rate of 200 ppm: 1, 2, 3, 4, 5, 6, 7, 8, 9 and 10. 
       Spodoptera littoralis  (Egyptian cotton leaf worm): Feeding/contact activity Cotton leaf discs were placed onto agar in 24-well microtiter plates and sprayed with aqueous test solutions prepared from 10′000 ppm DMSO stock solutions. After drying the leaf discs were infested with five L1 larvae. The samples were assessed for mortality 3 days after infestation. The following compounds resulted in at least 80% mortality at an application rate of 200 ppm: 1, 2, 3, 4, 5, 6, 7, 8, 9 and 10. 
       Tetranychus urticae  (Two-Spotted Spider Mite): Feeding/Contact Activity 
     Bean leaf discs on agar in 24-well microtiter plates were sprayed with aqueous test solutions prepared from 10′000 ppm DMSO stock solutions. After drying the leaf discs were infested with a mite population of mixed ages. The samples were assessed for mortality on mixed population (mobile stages) 8 days after infestation. The following compounds resulted in at least 80% mortality at an application rate of 200 ppm: 1, 2, 3, 4, 6, 7, 8, 9 and 10. 
       Thrips tabaci  (Onion Thrips): Feeding/Contact Activity 
     Sunflower leaf discs were placed on agar in 24-well microtiter plates and sprayed with aqueous test solutions prepared from 10′000 ppm DMSO stock solutions. After drying the leaf discs were infested with a thrips population of mixed ages. The samples were assessed for mortality 6 days after infestation. The following compounds resulted in at least 80% mortality at an application rate of 200 ppm: 1, 2, 3, 4, 5, 6, 7, 8, 9 and 10. 
     The compounds of the invention can be distinguished from known compounds by virtue of greater efficacy at low application rates, which can be verified by the person skilled in the art using the experimental procedures outlined in the Examples, using lower application rates if necessary, for example 50 ppm, 12.5 ppm, 6 ppm, 3 ppm, 1.5 ppm, 0.8 ppm or 0.2 ppm. 
     Furthermore, besides of the insecticidal properties, the compounds according to any one of embodiments 1 to 7 have surprisingly shown to have improved degradation properties compared with prior art compounds. Additionally, the compounds according to any one of embodiments 1 to 7 have surprisingly shown to be less toxic to bees compared with prior art compounds.