Patent Publication Number: US-2023159568-A1

Title: Organic molecules for optoelectronic devices

Description:
CROSS-REFERENCE TO RELATED APPLICATIONS 
     This application is a U.S. National Phase Patent Application of International Patent Application Number PCT/EP2021/060074, filed on Apr. 19, 2021, which claims priority to European Patent Application Number 20170817.9, filed on Apr. 22, 2020, the entire contents of all of which are incorporated herein by reference. 
     The disclosure relates to organic light-emitting molecules and their use in organic light-emitting diodes (OLEDs) and in other optoelectronic devices. 
    
    
     DESCRIPTION 
     The object of the present disclosure is to provide molecules which are suitable for use in optoelectronic devices. 
     This object is achieved by the disclosure which provides a new class of organic molecules. 
     According to the disclosure, the organic molecules are purely organic molecules, i.e. they do not contain any metal ions in contrast to metal complexes known for the use in optoelectronic devices. The organic molecules of the disclosure, however, include metalloids, in particular B, Si, Sn, Se, and/or Ge. 
     According to the present disclosure, the organic molecules exhibit emission maxima in the blue, sky-blue or green spectral range. The organic molecules exhibit emission maxima in particular between 420 nm and 520 nm, preferably between 440 nm and 495 nm, more preferably between 450 nm and 470 nm. The photoluminescence quantum yields of the organic molecules according to the disclosure are, in particular, 50% or more. The use of the molecules according to the disclosure in an optoelectronic device, for example, an organic light-emitting diode (OLED), leads to higher efficiencies or higher color purity, expressed by the full width at half maximum (FWHM) of emission, of the device. Corresponding OLEDs have a higher stability than OLEDs with known emitter materials and comparable color. 
     The organic light-emitting molecules according to the disclosure include or consist of a structure represented by Formula I, 
     
       
         
         
             
             
         
       
     
     wherein 
     each of R I , R II , R III , R IV , R V , R VI , R VII , R VII , R IX , R X  and R XI  is independently selected from the group consisting of: 
     hydrogen, deuterium, halogen, 
     C 1 -C 12 -alkyl, 
     wherein optionally one or more hydrogen atoms are each independently substituted by R 5 , 
     C 6 -C 18 -aryl, 
     wherein optionally one or more hydrogen atoms are each independently substituted by R 5 , 
     C 3 -C 15 -heteroaryl, 
     wherein optionally one or more hydrogen atoms are each independently substituted by R 5 . 
     R 5  is at each occurrence independently selected from the group consisting of: 
     hydrogen, deuterium 
     C 1 -C 12 -alkyl, 
     C 6 -C 18 -aryl, 
     wherein optionally one or more hydrogen atoms are each independently substituted by C 1 -C 5 -alkyl substituents. 
     T, V, W, and X are each independently selected from the group consisting of: 
     C 1 -C 12 -alkyl, 
     C 6 -C 18 -aryl, 
     wherein optionally one or more hydrogen atoms are each independently substituted by C 1 -C 5 -alkyl substituents. 
     In certain embodiments of the disclosure, T, V, W, and X are each independently selected from the group consisting of: 
       t Bu and 
     Ph (phenyl), which is optionally substituted with one or more substituents independently selected from the group consisting of Me,  i Pr and  t Bu. 
     In certain embodiments, the organic molecule includes or consists of the following structures: 
     
       
         
         
             
             
         
       
     
     wherein the substituents Ph′ denote the phenyl substituents, which are optionally substituted with one or more substituents independently selected from the group consisting of Me,  i Pr,  t Bu and Ph. 
     In another embodiment, the organic molecule includes or consists of a structure represented by Formula I-1 or Formula I-2: 
     
       
         
         
             
             
         
       
     
     wherein the aforementioned definitions apply. 
     In some embodiments, R I , R II , R III , R IV , R V , R VI , R VII , R VIII , R IX , R X  and R XI  are each independently selected from the group consisting of: 
     hydrogen, deuterium, halogen, 
     C 1 -C 12 -alkyl, 
     C 6 -C 18 -aryl, 
     wherein optionally one or more hydrogen atoms are each independently substituted by C 1 -C 6 -alkyl substituents, or C 6 -C 18 -aryl substituents, 
     C 3 -C 15 -heteroaryl, 
     wherein optionally one or more hydrogen atoms are each independently substituted by C 1 -C 6 -alkyl substituents, or C 6 -C 18 -aryl substituents. 
     In some embodiments, R I , R II , R III , R IV , R V , R VI , R VII , R VIII , R IX , R X  and R XI  are each independently selected from the group consisting of: 
     hydrogen, deuterium, halogen, Me,  i Pr,  t Bu, 
     Ph, which is optionally substituted with one or more substituents independently selected from the group consisting of Me,  i Pr,  t Bu, cyclohexyl and Ph, and 
     carbazole, which is optionally substituted with one or more substituents independently selected from the group consisting of Me,  i Pr,  t Bu, cyclohexyl and Ph. 
     In one embodiment of the disclosure, the organic molecule includes or consists of a structure selected from the group consisting of Formula Ia to Formula In: 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     wherein the aforementioned definitions apply. 
     In another embodiment of the disclosure, the organic molecule includes or consists of a structure selected from the group consisting of Formula IIa to Formula IIn: 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     In some embodiments, R XI  is selected from the group consisting of: 
     hydrogen, deuterium, halogen, Me,  i Pr,  t Bu, 
     Ph, which is optionally substituted with one or more substituents independently selected from the group consisting of Me,  i Pr,  t Bu, cyclohexyl and Ph, and 
     carbazole, which is optionally substituted with one or more substituents independently selected from the group consisting of Me,  i Pr,  t Bu, cyclohexyl and Ph. 
     In some embodiments, R XI  is selected from the group consisting of: 
     hydrogen, deuterium, Me,  i Pr,  t Bu, cyclohexyl, Ph, and carbazole, which is optionally substituted with one or more substituents independently selected from the group consisting of  t Bu and Ph. 
     In certain embodiments, R XI  is hydrogen or Me. 
     In a preferred embodiment, R XI  is hydrogen. 
     In a preferred embodiment, R XI  is Me. 
     In a preferred embodiment, R XI  is phenyl. 
     In certain embodiments, R XI  is carbazole, which is optionally substituted with one or more substituents independently selected from the group consisting of  t Bu and Ph. 
     In a preferred embodiment, R XI  is carbazole, in particular an unsubstituted carbazole. 
     In one embodiment, at least one of R I , R II , R III , R IV , R V  and at least one of R VI , R VII , R VIII , R IX  or R X  is selected from the group consisting of: 
     C 1 -C 12 -alkyl, 
     wherein optionally one or more hydrogen atoms are each independently substituted by R 5 , and 
     C 6 -C 18 -aryl, 
     wherein optionally one or more hydrogen atoms are each independently substituted by R 5 . 
     In certain embodiments of the organic molecule, R I ═R X , R II ═R IX , R III ═R VIII , R IV ═R VII , R V ═R VI , T=X, and V═W. 
     As used throughout the present application, the terms “aryl” and “aromatic” may be understood in the broadest sense as any mono-, bi- or polycyclic aromatic moieties. Accordingly, an aryl group contains 6 to 60 aromatic ring atoms, and a heteroaryl group contains 5 to 60 aromatic ring atoms, of which at least one is a heteroatom. Notwithstanding, throughout the application the number of aromatic ring atoms may be given as subscripted number in the definition of certain substituents. In particular, the heteroaromatic ring includes one to three heteroatoms. Again, the terms “heteroaryl” and “heteroaromatic” may be understood in the broadest sense as any mono-, bi- or polycyclic hetero-aromatic moieties that include at least one heteroatom. The heteroatoms may at each occurrence be the same or different and be individually selected from the group consisting of N, O and S. Accordingly, the term “arylene” refers to a divalent substituent that bears two binding sites to other molecular structures and thereby serving as a linker structure. In case, a group in the exemplary embodiments is defined differently from the definitions given here, for example, the number of aromatic ring atoms or number of heteroatoms differs from the given definition, the definition in the exemplary embodiments is to be applied. According to the disclosure, a condensed (annulated) aromatic or heteroaromatic polycycle is built of two or more single aromatic or heteroaromatic cycles, which formed the polycycle via a condensation reaction. 
     In particular, as used throughout, the term “aryl group” or “heteroaryl group” includes groups which can be bound via any position of the aromatic or heteroaromatic group, derived from benzene, naphthalene, anthracene, phenanthrene, pyrene, dihydropyrene, chrysene, perylene, fluoranthene, benzanthracene, benzophenanthrene, tetracene, pentacene, benzopyrene, furan, benzofuran, isobenzofuran, dibenzofuran, thiophene, benzothiophene, isobenzothiophene, dibenzothiophene; pyrrole, indole, isoindole, carbazole, pyridine, quinoline, isoquinoline, acridine, phenanthridine, benzo-5,6-quinoline, benzo-6,7-quinoline, benzo-7,8-quinoline, phenothiazine, phenoxazine, pyrazole, indazole, imidazole, benzimidazole, naphthoimidazole, phenanthroimidazole, pyridoimidazole, pyrazinoimidazole, quinoxalinoimidazole, oxazole, benzoxazole, naphthooxazole, anthroxazol, phenanthroxazol, isoxazole, 1,2-thiazole, 1,3-thiazole, benzothiazole, pyridazine, benzopyridazine, pyrimidine, benzopyrimidine, 1,3,5-trazine, quinoxaline, pyrazine, phenazine, naphthyridine, carboline, benzocarboline, phenanthroline, 1,2,3-triazole, 1,2,4-triazole, benzotriazole, 1,2,3-oxadiazole, 1,2,4-oxadiazole, 1,2,5-oxadiazole, 1,2,3,4-tetrazine, purine, pteridine, indolizine and benzothiadiazole or combinations of the abovementioned groups. 
     As used throughout, the term “cyclic group” may be understood in the broadest sense as any mono-, bi- or polycyclic moieties. 
     As used throughout, the term “biphenyl” as a substituent may be understood in the broadest sense as ortho-biphenyl, meta-biphenyl, or para-biphenyl, wherein ortho, meta and para is defined in regard to the binding site to another chemical moiety. 
     As used throughout, the term “alkyl group” may be understood in the broadest sense as any linear, branched, or cyclic alkyl substituent. In particular, the term alkyl includes the substituents methyl (Me), ethyl (Et), n-propyl ( n Pr), i-propyl ( i Pr), cyclopropyl, n-butyl ( n Bu), i-butyl ( t Bu), s-butyl ( s Bu), t-butyl ( t Bu), cyclobutyl, 2-methylbutyl, n-pentyl, s-pentyl, t-pentyl, 2-pentyl, neo-pentyl, cyclopentyl, n-hexyl, s-hexyl, t-hexyl, 2-hexyl, 3-hexyl, neo-hexyl, cyclohexyl, 1-methylcyclopentyl, 2-methylpentyl, n-heptyl, 2-heptyl, 3-heptyl, 4-heptyl, cycloheptyl, 1-methylcyclohexyl, n-octyl, 2-ethylhexyl, cyclooctyl, 1-bicyclo[2,2,2]octyl, 2-bicyclo[2,2,2]-octyl, 2-(2,6-dimethyl)octyl, 3-(3,7-dimethyl)octyl, adamantyl, 2,2,2-trifluorethyl, 1,1-dimethyl-n-hex-1-yl, 1,1-dimethyl-n-hept-1-yl, 1,1-dimethyl-n-oct-1-yl, 1,1-dimethyl-n-dec-1-yl, 1,1-dimethyl-n-dodec-1-yl, 1,1-dimethyl-n-tetradec-1-yl, 1,1-dimethyl-n-hexadec-1-yl, 1,1-dimethyl-n-octadec-1-yl, 1,1-diethyl-n-hex-1-yl, 1,1-diethyl-n-hept-1-yl, 1,1-diethyl-n-oct-1-yl, 1,1-diethyl-n-dec-1-yl, 1,1-diethyl-n-dodec-1-yl, 1,1-diethyl-n-tetradec-1-yl, 1,1-diethyl-n-hexadec-1-yl, 1,1-diethyl-n-octadec-1-yl, 1-(n-propyl)-cyclohex-1-yl, 1-(n-butyl)-cyclohex-1-yl, 1-(n-hexyl)-cyclohex-1-yl, 1-(n-octyl)-cyclohex-1-yl and 1-(n-decyl)-cyclohex-1-yl. 
     As used throughout, the term “alkenyl” includes linear, branched, and cyclic alkenyl substituents. The term “alkenyl group”, for example, includes the substituents ethenyl, propenyl, butenyl, pentenyl, cyclopentenyl, hexenyl, cyclohexenyl, heptenyl, cycloheptenyl, octenyl, cyclooctenyl or cyclooctadienyl. 
     As used throughout, the term “alkynyl” includes linear, branched, and cyclic alkynyl substituents. The term “alkynyl group”, for example, includes ethynyl, propynyl, butynyl, pentynyl, hexynyl, heptynyl or octynyl. 
     As used throughout, the term “alkoxy” includes linear, branched, and cyclic alkoxy substituents. The term “alkoxy group”, for example, includes methoxy, ethoxy, n-propoxy, i-propoxy, n-butoxy, i-butoxy, s-butoxy, t-butoxy or 2-methylbutoxy. 
     As used throughout, the term “thioalkoxy” includes linear, branched, and cyclic thioalkoxy substituents, in which the O of the exemplarily alkoxy groups is replaced by S. 
     As used throughout, the terms “halogen” and “halo” may be understood in the broadest sense as being preferably fluorine, chlorine, bromine, or iodine. 
     Whenever hydrogen (H) is mentioned herein, it could also be replaced by deuterium at each occurrence. 
     It is understood that when a molecular fragment is described as being a substituent or otherwise attached to another moiety, its name may be written as if it were a fragment (e.g. naphthyl, dibenzofuryl) or as if it were the whole molecule (e.g. naphthalene, dibenzofuran). As used herein, these different ways of designating a substituent or attached fragment are considered to be equivalent. 
     In one embodiment, the organic molecules according to the disclosure have an excited state lifetime of not more than 150 μs, of not more than 100 μs, in particular of not more than 50 μs, more preferably of not more than 10 μs or not more than 7 μs in a film of poly(methyl methacrylate) (PMMA) with 5% by weight of the organic molecule at room temperature. 
     In a further embodiment of the disclosure, the organic molecules according to the disclosure have an emission peak in the visible or nearest ultraviolet range, i.e., in the range of a wavelength of from 380 nm to 800 nm, with a full width at half maximum of less than 0.23 eV, preferably less than 0.20 eV, more preferably less than 0.19 eV, even more preferably less than 0.18 eV or even less than 0.17 eV in a film of poly(methyl methacrylate) (PMMA) with 5% by weight of the organic molecule at room temperature. 
     Orbital and excited state energies can be determined by means of experimental methods. The energy of the highest occupied molecular orbital E HOMO  is determined by methods known to the person skilled in the art from cyclic voltammetry measurements with an accuracy of 0.1 eV. The energy of the lowest unoccupied molecular orbital E LUMO  is calculated as E HOMO +E gap , wherein E gap  is determined as follows: For host compounds, the onset of the emission spectrum of a film with 10% by weight of the host in poly(methyl methacrylate) (PMMA) is used as E gap , unless stated otherwise. For emitter molecules, E gap  is determined as the energy at which the excitation and emission spectra of a film with 10% by weight of the emitter in PMMA cross. For the organic molecules according to the disclosure, E gap  is determined as the energy at which the excitation and emission spectra of a film with 1% by weight of the emitter in PMMA cross. 
     The energy of the first excited triplet state T1 is determined from the onset of the emission spectrum at low temperature, typically at 77 K. For host compounds, where the first excited singlet state and the lowest triplet state are energetically separated by &gt;0.4 eV, the phosphorescence is usually visible in a steady-state spectrum in 2-Me-THF. The triplet energy can thus be determined as the onset of the phosphorescence spectrum. For TADF emitter molecules, the energy of the first excited triplet state T1 is determined from the onset of the delayed emission spectrum at 77 K, if not otherwise stated, measured in a film of PMMA with 10% by weight of the emitter and in case of the organic molecules according to the disclosure with 1% by weight of the organic molecules according to the disclosure. Both for host and emitter compounds, the energy of the first excited singlet state S1 is determined from the onset of the emission spectrum, if not otherwise stated, measured in a film of PMMA with 10% by weight of the host or emitter compound and in case of the organic molecules according to the disclosure with 1% by weight of the organic molecules according to the disclosure. 
     The onset of an emission spectrum is determined by computing the intersection of the tangent to the emission spectrum with the x-axis. The tangent to the emission spectrum is set at the high-energy side of the emission band and at the point at half maximum of the maximum intensity of the emission spectrum. 
     In one embodiment, the organic molecules according to the disclosure have an onset of the emission spectrum, which is energetically close to the emission maximum, i.e. the energy difference between the onset of the emission spectrum and the energy of the emission maximum is below 0.14 eV, preferably below 0.13 eV, or even below 0.12 eV, while the full width at half maximum (FWHM) of the organic molecules is less than 0.23 eV, preferably less than 0.20 eV, more preferably less than 0.19 eV, even more preferably less than 0.18 eV or even less than 0.17 eV in a film of poly(methyl methacrylate) (PMMA) with 1% by weight of the organic molecule at room temperature, resulting in a CIEy coordinate below 0.20, preferably below 0.18, more preferably below 0.16 or even more preferred below 0.14. 
     A further aspect of the disclosure relates to the use of an organic molecule of the disclosure as a luminescent emitter or as an absorber, and/or as a host material and/or as an electron transport material, and/or as a hole injection material, and/or as a hole blocking material in an optoelectronic device. 
     A preferred embodiment relates to the use of an organic molecule according to the disclosure as a luminescent emitter in an optoelectronic device. 
     The optoelectronic device may be understood in the broadest sense as any device based on organic materials that is suitable for emitting light in the visible or nearest ultraviolet (UV) range, i.e., in the range of a wavelength of from 380 to 800 nm. More preferably, the optoelectronic device may be able to emit light in the visible range, i.e., of from 400 nm to 800 nm. 
     In the context of such use, the optoelectronic device is more particularly selected from the group consisting of: 
     organic light-emitting diodes (OLEDs), 
     light-emitting electrochemical cells, 
     OLED sensors, especially in gas and vapor sensors that are not hermetically shielded to the surroundings, 
     organic diodes, 
     organic solar cells, 
     organic transistors, 
     organic field-effect transistors, 
     organic lasers, and 
     down-conversion elements. 
     In a preferred embodiment in the context of such use, the optoelectronic device is a device selected from the group consisting of an organic light emitting diode (OLED), a light emitting electrochemical cell (LEC), and a light-emitting transistor. 
     In the case of the use, the fraction of the organic molecule according to the disclosure in the emission layer in an optoelectronic device, more particularly in an OLED, is 0.1% to 99% by weight, more particularly 1% to 80% by weight. In an alternative embodiment, the proportion of the organic molecule in the emission layer is 100% by weight. 
     In one embodiment, the light-emitting layer includes not only the organic molecules according to the disclosure, but also a host material whose triplet (T1) and singlet (S1) energy levels are energetically higher than the triplet (T1) and singlet (S1) energy levels of the organic molecule. 
     A further aspect of the disclosure relates to a composition including or consisting of: 
     (a) at least one organic molecule according to the disclosure, in particular in the form of an emitter and/or a host, and 
     (b) one or more emitter and/or host materials, which differ from the organic molecule according to the disclosure and 
     (c) optional one or more dyes and/or one or more solvents. 
     In one embodiment, the light-emitting layer includes or essentially consists of a composition including or consisting of: 
     (a) at least one organic molecule according to the disclosure, in particular in the form of an emitter and/or a host, and 
     (b) one or more emitter and/or host materials, which differ from the organic molecule according to the disclosure and 
     (c) optional one or more dyes and/or one or more solvents. 
     In a particular embodiment, the light-emitting layer EML includes or essentially consists of a composition including or consisting of: 
     (i) 0.1-10% by weight, preferably 0.5-5% by weight, in particular 1-3% by weight, of one or more organic molecules according to the disclosure; 
     (ii) 5-99% by weight, preferably 15-85% by weight, in particular 20-75% by weight, of at least one host compound H; and 
     (iii) 0.9-94.9% by weight, preferably 14.5-80% by weight, in particular 24-77% by weight, of at least one further host compound D with a structure differing from the structure of the molecules according to the disclosure; and 
     (iv)optionally 0-94% by weight, preferably 0-65% by weight, in particular 0-50% by weight, of a solvent; and 
     (v) optionally 0-30% by weight, in particular 0-20% by weight, preferably 0-5% by weight, of at least one further emitter molecule F with a structure differing from the structure of the molecules according to the disclosure. 
     Preferably, energy can be transferred from the host compound H to the one or more organic molecules according to the disclosure, in particular transferred from the first excited triplet state T1(H) of the host compound H to the first excited triplet state T1(E) of the one or more organic molecules E according to the disclosure and/or from the first excited singlet state S1(H) of the host compound H to the first excited singlet state S1(E) of the one or more organic molecules E according to the disclosure. 
     In one embodiment, the host compound H has a highest occupied molecular orbital HOMO(H) having an energy E HOMO (H) in the range of from −5 to −6.5 eV and the at least one further host compound D has a highest occupied molecular orbital HOMO(D) having an energy E HOMO (D), wherein E HOMO (H)&gt;E HOMO (D). 
     In a further embodiment, the host compound H has a lowest unoccupied molecular orbital LUMO(H) having an energy E LUMO (H) and the at least one further host compound D has a lowest unoccupied molecular orbital LUMO(D) having an energy E LUMO (D), wherein E LUMO (H)&gt;E LUMO (D). 
     In one embodiment, the host compound H has a highest occupied molecular orbital HOMO(H) having an energy E HOMO (H) and a lowest unoccupied molecular orbital LUMO(H) having an energy E LUMO (H), and 
     the at least one further host compound D has a highest occupied molecular orbital HOMO(D) having an energy E HOMO (D) and a lowest unoccupied molecular orbital LUMO(D) having an energy E LUMO (D), 
     the organic molecule E according to the disclosure has a highest occupied molecular orbital HOMO(E) having an energy E HOMO (E) and a lowest unoccupied molecular orbital LUMO(E) having an energy E LUMO (E), 
     wherein 
     E HOMO (H)&gt;E HOMO (D) and the difference between the energy level of the highest occupied molecular orbital HOMO(E) of the organic molecule E according to the disclosure (E HOMO (E)) and the energy level of the highest occupied molecular orbital HOMO(H) of the host compound H (E HOMO (H)) is between −0.5 eV and 0.5 eV, more preferably between −0.3 eV and 0.3 eV, even more preferably between −0.2 eV and 0.2 eV or even between −0.1 eV and 0.1 eV; and 
     E LUMO (H)&gt;E LUMO (D) and the difference between the energy level of the lowest unoccupied molecular orbital LUMO(E) of the organic molecule E according to the disclosure (E LUMO (E)) and the energy level of the lowest unoccupied molecular orbital LUMO(D) of the at least one further host compound D (E LUMO (D)) is between −0.5 eV and 0.5 eV, more preferably between −0.3 eV and 0.3 eV, even more preferably between −0.2 eV and 0.2 eV or even between −0.1 eV and 0.1 eV. 
     In one embodiment of the disclosure the host compound D and/or the host compound H is a thermally-activated delayed fluorescence (TADF)-material. TADF materials exhibit a ΔE ST  value, which corresponds to the energy difference between the first excited singlet state (S1) and the first excited triplet state (T1), of less than 2500 cm −1 . Preferably the TADF material exhibits a ΔE ST  value of less than 3000 cm −1 , more preferably less than 1500 cm −1 , even more preferably less than 1000 cm −1  or even less than 500 cm −1 . 
     In one embodiment, the host compound D is a TADF material and the host compound H exhibits a ΔE ST  value of more than 2500 cm −1 . In a particular embodiment, the host compound D is a TADF material and the host compound H is selected from the group consisting of CBP, mCP, mCBP, 9-[3-(dibenzofuran-2-yl)phenyl]-9H-carbazole, 9-[3-(dibenzothiophen-2-yl)phenyl]-9H-carbazole, 9-[3,5-bis(2-dibenzofuranyl)phenyl]-9H-carbazole and 9-[3,5-bis(2-dibenzothiophenyl)phenyl]-9H-carbazole. 
     In one embodiment, the host compound H is a TADF material and the host compound D exhibits a ΔE ST  value of more than 2500 cm −1 . In a particular embodiment, the host compound H is a TADF material and the host compound D is selected from the group consisting of T2T (2,4,6-tris(biphenyl-3-yl)-1,3,5-triazine), T3T (2,4,6-tris(triphenyl-3-yl)-1,3,5-triazine) and TST (2,4,6-tris(9,9′-spirobifluorene-2-yl)-1,3,5-triazine). 
     In a further aspect, the disclosure relates to an optoelectronic device including an organic molecule or a composition of the type or kind described here, more particularly in the form of a device selected from the group consisting of organic light-emitting diodes (OLEDs), light-emitting electrochemical cells, OLED sensors, more particularly gas and vapour sensors not hermetically externally shielded, organic diodes, organic solar cells, organic transistors, organic field-effect transistors, organic lasers and down-conversion elements. 
     In a preferred embodiment, the optoelectronic device is a device selected from the group consisting of an organic light emitting diode (OLED), a light emitting electrochemical cell (LEC), and a light-emitting transistor. 
     In one embodiment of the optoelectronic device of the disclosure, the organic molecule E according to the disclosure is used as emission material in a light-emitting layer EML. 
     In one embodiment of the optoelectronic device of the disclosure, the light-emitting layer EML consists of the composition according to the disclosure described here. 
     When the optoelectronic device is an OLED, it may, for example, have the following layer structure: 
     1. substrate 
     2. anode layer A 
     3. hole injection layer, HIL 
     4. hole transport layer, HTL 
     5. electron blocking layer, EBL 
     6. emitting layer, EML 
     7. hole blocking layer, HBL 
     8. electron transport layer, ETL 
     9. electron injection layer, EIL 
     10. cathode layer, 
     wherein the OLED includes each layer selected from the group of HIL, HTL, EBL, HBL, ETL, and EIL only optionally, different layers may be merged and the OLED may include more than one layer of each layer type or kind defined above. 
     Furthermore, the optoelectronic device may, in one embodiment, include one or more protective layers protecting the device from damaging exposure to harmful species in the environment including, for example, moisture, vapor and/or gases. 
     In one embodiment of the disclosure, the optoelectronic device is an OLED, with the following inverted layer structure: 
     1. substrate 
     2. cathode layer 
     3. electron injection layer, EIL 
     4. electron transport layer, ETL 
     5. hole blocking layer, HBL 
     6. emitting layer, B 
     7. electron blocking layer, EBL 
     8. hole transport layer, HTL 
     9. hole injection layer, HIL 
     10. anode layer A 
     wherein the OLED includes each layer selected from the group of HIL, HTL, EBL, HBL, ETL, and EIL only optionally, different layers may be merged and the OLED may include more than one layer of each layer types (kinds) defined above. 
     In one embodiment of the disclosure, the optoelectronic device is an OLED, which may have a stacked architecture. In this architecture, contrary to the typical arrangement in which the OLEDs are placed side by side, the individual units are stacked on top of each other. Blended light may be generated with OLEDs exhibiting a stacked architecture, in particular white light may be generated by stacking blue, green and red OLEDs. Furthermore, the OLED exhibiting a stacked architecture may include a charge generation layer (CGL), which is typically located between two OLED subunits and typically consists of a n-doped and p-doped layer with the n-doped layer of one CGL being typically located closer to the anode layer. 
     In one embodiment of the disclosure, the optoelectronic device is an OLED, which includes two or more emission layers between the anode and the cathode. In particular, this so-called tandem OLED includes three emission layers, wherein one emission layer emits red light, one emission layer emits green light and one emission layer emits blue light, and optionally may include further layers such as charge generation layers, blocking or transporting layers between the individual emission layers. In a further embodiment, the emission layers are adjacently stacked. In a further embodiment, the tandem OLED includes a charge generation layer between each two emission layers. In addition, adjacent emission layers or emission layers separated by a charge generation layer may be merged. 
     The substrate may be formed by any material or composition of materials. Most frequently, glass slides are used as substrates. Alternatively, thin metal layers (e.g., copper, gold, silver or aluminum films) or plastic films or slides may be used. This may allow for a higher degree of flexibility. The anode layer A is mostly composed of materials allowing to obtain an (essentially) transparent film. As at least one of both electrodes should be (essentially) transparent in order to allow light emission from the OLED, either the anode layer A or the cathode layer C is transparent. Preferably, the anode layer A includes a large content or even consists of transparent conductive oxides (TCOs). Such anode layer A may, for example, include indium tin oxide, aluminum zinc oxide, fluorine doped tin oxide, indium zinc oxide, PbO, SnO, zirconium oxide, molybdenum oxide, vanadium oxide, tungsten oxide, graphite, doped Si, doped Ge, doped GaAs, doped polyaniline, doped polypyrrol and/or doped polythiophene. 
     The anode layer A (essentially) may consist of indium tin oxide (ITO) (e.g., (InO 3 ) 0.9 (SnO 2 ) 0.1 ). The roughness of the anode layer A caused by the transparent conductive oxides (TCOs) may be compensated by using a hole injection layer (HIL). Further, the HIL may facilitate the injection of quasi charge carriers (i.e., holes) in that the transport of the quasi charge carriers from the TCO to the hole transport layer (HTL) is facilitated. The hole injection layer (HIL) may include poly-3,4-ethylendioxy thiophene (PEDOT), polystyrene sulfonate (PSS), MoO 2 , V 2 O 5 , CuPC or CuI, in particular a mixture of PEDOT and PSS. The hole injection layer (HIL) may also prevent the diffusion of metals from the anode layer A into the hole transport layer (HTL). The HIL may, for example, include PEDOT:PSS (poly-3,4-ethylendioxy thiophene: polystyrene sulfonate), PEDOT (poly-3,4-ethylendioxy thiophene), mMTDATA (4,4′,4″-tris[phenyl(m-tolyl)amino]triphenylamine), Spiro-TAD (2,2′,7,7′-tetrakis(n,n-diphenylamino)-9,9′-spirobifluorene), DNTPD (N1,N1′-(biphenyl-4,4′-diyl)bis(N1-phenyl-N4,N4-di-m-tolylbenzene-1,4-diamine), NPB (N,N′-nis-(1-naphthalenyl)-N,N′-bis-phenyl-(1,1′-biphenyl)-4,4′-diamine), NPNPB (N,N′-diphenyl-N,N′-di-[4-(N,N-diphenyl-amino)phenyl]benzidine), MeO-TPD (N,N,N′,N′-tetrakis(4-methoxyphenyl)benzidine), HAT-CN (1,4,5,8,9,12-hexaazatriphenylen-hexacarbonitrile) and/or Spiro-NPD (N,N′-diphenyl-N,N′-bis-(1-naphthyl)-9,9′-spirobifluorene-2,7-diamine). 
     Adjacent to the anode layer A or hole injection layer (HIL), a hole transport layer (HTL) is typically located. Herein, any hole transport compound may be used. For example, electron-rich heteroaromatic compounds such as triarylamines and/or carbazoles may be used as hole transport compound. The HTL may decrease the energy barrier between the anode layer A and the light-emitting layer EML. The hole transport layer (HTL) may also be an electron blocking layer (EBL). Preferably, hole transport compounds bear comparably high energy levels of their triplet states T1. For example, the hole transport layer (HTL) may include a star-shaped heterocycle such as tris(4-carbazoyl-9-ylphenyl)amine (TCTA), poly-TPD (poly(4-butylphenyl-diphenyl-amine)), [alpha]-NPD (2,2′-dimethyl-N,N′-di-[(1-naphthyl)-N,N′-diphenyl]-1,1′-biphenyl-4,4′-diamine), TAPC (4,4′-cyclohexyliden-bis[N,N-bis(4-methylphenyl)benzenamine]), 2-TNATA (4,4′,4″-tris[2-naphthyl(phenyl)amino]triphenylamine), Spiro-TAD, DNTPD, NPB, NPNPB, MeO-TPD, HAT-CN and/or TrisPcz (9,9′-diphenyl-6-(9-phenyl-9H-carbazol-3-yl)-9H,9′H-3,3′-bicarbazole). In addition, the HTL may include a p-doped layer, which may be composed of an inorganic or organic dopant in an organic hole-transporting matrix. Transition metal oxides such as vanadium oxide, molybdenum oxide or tungsten oxide may, for example, be used as the inorganic dopant. Tetrafluorotetracyanoquinodimethane (F 4 -TCNQ), copper-pentafluorobenzoate (Cu(I)pFBz) or transition metal complexes may, for example, be used as the organic dopant. 
     The EBL may, for example, include mCP (1,3-bis(carbazol-9-yl)benzene), TCTA, 2-TNATA, mCBP (3,3-di(9H-carbazol-9-yl)biphenyl), tris-Pcz, CzSi (9-(4-tert-Butylphenyl)-3,6-bis(triphenylsilyl)-9H-carbazole), and/or DCB (N,N′-dicarbazolyl-1,4-dimethylbenzene). 
     Adjacent to the hole transport layer (HTL), the light-emitting layer EML is typically located. The light-emitting layer EML includes at least one light emitting molecule. Particularly, the EML includes at least one light emitting molecule E according to the disclosure. In one embodiment, the light-emitting layer includes only the organic molecules according to the disclosure. Typically, the EML additionally includes one or more host materials H. For example, the host material H is selected from CBP (4,4′-Bis-(N-carbazolyl)-biphenyl), mCP, mCBP Sif87 (dibenzo[b,d]thiophen-2-yltriphenylsilane), CzSi, Sif88 (dibenzo[b,d]thiophen-2-yl)diphenylsilane), DPEPO (bis[2-(diphenylphosphino)phenyl] ether oxide), 9-[3-(dibenzofuran-2-yl)phenyl]-9H-carbazole, 9-[3-(dibenzothiophen-2-yl)phenyl]-9H-carbazole, 9-[3,5-bis(2-dibenzofuranyl)phenyl]-9H-carbazole, 9-[3,5-bis(2-dibenzothiophenyl)phenyl]-9H-carbazole, T2T (2,4,6-tris(biphenyl-3-yl)-1,3,5-triazine), T3T (2,4,6-tris(triphenyl-3-yl)-1,3,5-triazine) and/or TST (2,4,6-tris(9,9′-spirobifluorene-2-yl)-1,3,5-triazine). The host material H typically should be selected to exhibit first triplet (T1) and first singlet (S1) energy levels, which are energetically higher than the first triplet (T1) and first singlet (S1) energy levels of the organic molecule. 
     In one embodiment of the disclosure, the EML includes a so-called mixed-host system with at least one hole-dominant host and one electron-dominant host. In a particular embodiment, the EML includes exactly one light emitting organic molecule according to the disclosure and a mixed-host system including T2T as electron-dominant host and a host selected from CBP, mCP, mCBP, 9-[3-(dibenzofuran-2-yl)phenyl]-9H-carbazole, 9-[3-(dibenzothiophen-2-yl)phenyl]-9H-carbazole, 9-[3,5-bis(2-dibenzofuranyl)phenyl]-9H-carbazole and 9-[3,5-bis(2-dibenzothiophenyl)phenyl]-9H-carbazole as hole-dominant host. In a further embodiment the EML includes 50-80% by weight, preferably 60-75% by weight of a host selected from CBP, mCP, mCBP, 9-[3-(dibenzofuran-2-yl)phenyl]-9H-carbazole, 9-[3-(dibenzothiophen-2-yl)phenyl]-9H-carbazole, 9-[3,5-bis(2-dibenzofuranyl)phenyl]-9H-carbazole and 9-[3,5-bis(2-dibenzothiophenyl)phenyl]-9H-carbazole; 10-45% by weight, preferably 15-30% by weight of T2T and 5-40% by weight, preferably 10-30% by weight of light emitting molecule according to the disclosure. 
     Adjacent to the light-emitting layer EML, an electron transport layer (ETL) may be located. Herein, any electron transporter may be used. Exemplarily, electron-poor compounds such as, e.g., benzimidazoles, pyridines, triazoles, oxadiazoles (e.g., 1,3,4-oxadiazole), phosphinoxides and sulfone, may be used. An electron transporter may also be a star-shaped heterocycle such as 1,3,5-tri(1-phenyl-1H-benzo[d]imidazol-2-yl)phenyl (TPBi). The ETL may include NBphen (2,9-bis(naphthalen-2-yl)-4,7-diphenyl-1,10-phenanthroline), Alq 3  (Aluminum-tris(8-hydroxyquinoline)), TSPO1 (diphenyl-4-triphenylsilylphenyl-phosphinoxide), BPyTP2 (2,7-di(2,2′-bipyridin-5-yl)triphenyle), Sif87 (dibenzo[b,d]thiophen-2-yltriphenylsilane), Sif88 (dibenzo[b,d]thiophen-2-yl)diphenylsilane), BmPyPhB (1,3-bis[3,5-di(pyridin-3-yl)phenyl]benzene) and/or BTB (4,4′-bis-[2-(4,6-diphenyl-1,3,5-triazinyl)]-1,1′-biphenyl). Optionally, the ETL may be doped with materials such as Liq. The electron transport layer (ETL) may also block or reduce holes or a hole blocking layer (HBL) is introduced. 
     The HBL may, for example, include BCP (2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline=Bathocuproine), BAlq (bis(8-hydroxy-2-methylquinoline)-(4-phenylphenoxy)aluminum), NBphen (2,9-bis(naphthalen-2-yl)-4,7-diphenyl-1,10-phenanthroline), Alq 3  (Aluminum-tris(8-hydroxyquinoline)), TSPO1 (diphenyl-4-triphenylsilylphenyl-phosphinoxide), T2T (2,4,6-tris(biphenyl-3-yl)-1,3,5-triazine), T3T (2,4,6-tris(triphenyl-3-yl)-1,3,5-triazine), TST (2,4,6-tris(9,9′-spirobifluorene-2-yl)-1,3,5-triazine), and/or TCB/TCP (1,3,5-tris(N-carbazolyl)benzol/1,3,5-tris(carbazol)-9-yl) benzene). 
     Adjacent to the electron transport layer (ETL), a cathode layer C may be located. The cathode layer C may, for example, include or may consist of a metal (e.g., Al, Au, Ag, Pt, Cu, Zn, Ni, Fe, Pb, LiF, Ca, Ba, Mg, In, W, or Pd) or a metal alloy. For practical reasons, the cathode layer may also consist of (essentially) intransparent metals such as Mg, Ca or Al. Alternatively or additionally, the cathode layer C may also include graphite and/or carbon nanotubes (CNTs). Alternatively, the cathode layer C may also consist of nanoscalic silver wires. 
     An OLED may further, optionally, include a protection layer between the electron transport layer (ETL) and the cathode layer C (which may be designated as electron injection layer (EIL)). This layer may include lithium fluoride, cesium fluoride, silver, Liq (8-hydroxyquinolinolatolithium), Li 2 O, BaF 2 , MgO and/or NaF. 
     Optionally, the electron transport layer (ETL) and/or a hole blocking layer (HBL) may also include one or more host compounds H. 
     In order to modify the emission spectrum and/or the absorption spectrum of the light-emitting layer EML further, the light-emitting layer EML may further include one or more further emitter molecules F. Such an emitter molecule F may be any emitter molecule known in the art. Preferably such an emitter molecule F is a molecule with a structure differing from the structure of the molecules E according to the disclosure. The emitter molecule F may optionally be a TADF emitter. Alternatively, the emitter molecule F may optionally be a fluorescent and/or phosphorescent emitter molecule which is able to shift the emission spectrum and/or the absorption spectrum of the light-emitting layer EML. For example, the triplet and/or singlet excitons may be transferred from the organic emitter molecule according to the disclosure to the emitter molecule F before relaxing to the ground state SO by emitting light typically red-shifted in comparison to the light emitted by an organic molecule. Optionally, the emitter molecule F may also provoke two-photon effects (i.e., the absorption of two photons of half the energy of the absorption maximum). 
     Optionally, an optoelectronic device (e.g., an OLED) may, for example, be an essentially white optoelectronic device. For example, such white optoelectronic device may include at least one (deep) blue emitter molecule and one or more emitter molecules emitting green and/or red light. Then, there may also optionally be energy transmittance between two or more molecules as described above. 
     As used herein, if not defined more specifically in the particular context, the designation of the colors of emitted and/or absorbed light is as follows: 
     violet: wavelength range of &gt;380-420 nm; 
     deep blue: wavelength range of &gt;420-480 nm; 
     sky blue: wavelength range of &gt;480-500 nm; 
     green: wavelength range of &gt;500-560 nm; 
     yellow: wavelength range of &gt;560-580 nm; 
     orange: wavelength range of &gt;580-620 nm; 
     red: wavelength range of &gt;620-800 nm. 
     With respect to emitter molecules, such colors refer to the emission maximum. Therefore, for example, a deep blue emitter has an emission maximum in the range of from &gt;420 to 480 nm, a sky blue emitter has an emission maximum in the range of from &gt;480 to 500 nm, a green emitter has an emission maximum in a range of from &gt;500 to 560 nm, and a red emitter has an emission maximum in a range of from &gt;620 to 800 nm. 
     A deep blue emitter may preferably have an emission maximum of below 480 nm, more preferably below 470 nm, even more preferably below 465 nm or even below 460 nm. It will typically be above 420 nm, preferably above 430 nm, more preferably above 440 nm or even above 450 nm. 
     Accordingly, a further aspect of the present disclosure relates to an OLED, which exhibits an external quantum efficiency at 1000 cd/m 2  of more than 8%, more preferably of more than 10%, more preferably of more than 13%, even more preferably of more than 15% or even more than 20% and/or exhibits an emission maximum between 420 nm and 500 nm, preferably between 430 nm and 490 nm, more preferably between 440 nm and 480 nm, even more preferably between 450 nm and 470 nm and/or exhibits a LT80 value at 500 cd/m 2  of more than 100 h, preferably more than 200 h, more preferably more than 400 h, even more preferably more than 750 h or even more than 1000 h. Accordingly, a further aspect of the present disclosure relates to an OLED, whose emission exhibits a CIEy color coordinate of less than 0.45, preferably less than 0.30, more preferably less than 0.20 or even more preferably less than 0.15 or even less than 0.10. 
     A further aspect of the present disclosure relates to an OLED, which emits light at a distinct color point. According to the present disclosure, the OLED emits light with a narrow emission band (small full width at half maximum (FWHM)). In one aspect, the OLED according to the disclosure emits light with a FWHM of the main emission peak of less than 0.30 eV, preferably less than 0.25 eV, more preferably less than 0.20 eV, even more preferably less than 0.19 eV or even less than 0.17 eV. 
     A further aspect of the present disclosure relates to an OLED, which emits light with CIEx and CIEy color coordinates close to the CIEx (=0.131) and CIEy (=0.046) color coordinates of the primary color blue (CIEx=0.131 and CIEy=0.046) as defined by ITU-R Recommendation BT.2020 (Rec. 2020) and thus is suited for the use in Ultra High Definition (UHD) displays, e.g. UHD-TVs. Accordingly, a further aspect of the present disclosure relates to an OLED, whose emission exhibits a CIEx color coordinate of between 0.02 and 0.30, preferably between 0.03 and 0.25, more preferably between 0.05 and 0.20 or even more preferably between 0.08 and 0.18 or even between 0.10 and 0.15 and/or a CIEy color coordinate of between 0.00 and 0.45, preferably between 0.01 and 0.30, more preferably between 0.02 and 0.20 or even more preferably between 0.03 and 0.15 or even between 0.04 and 0.10. 
     In a further aspect, the disclosure relates to a method for producing an optoelectronic component. In this case an organic molecule of the disclosure is used. 
     The optoelectronic device, in particular the OLED according to the present disclosure can be fabricated by any means of vapor deposition and/or liquid processing. Accordingly, at least one layer is
         prepared by means of a sublimation process,   prepared by means of an organic vapor phase deposition process,   prepared by means of a carrier gas sublimation process, or   solution processed or printed.       

     The methods used to fabricate the optoelectronic device, in particular the OLED according to the present disclosure are known in the art. The different layers are individually and successively deposited on a suitable substrate by means of subsequent deposition processes. The individual layers may be deposited using the same or differing deposition methods. 
     Vapor deposition processes, for example, include thermal (co)evaporation, chemical vapor deposition and physical vapor deposition. For active matrix OLED display, an AMOLED backplane is used as substrate. The individual layer may be processed from solutions or dispersions employing adequate solvents. Solution deposition process, for example, include spin coating, dip coating and jet printing. Liquid processing may optionally be carried out in an inert atmosphere (e.g., in a nitrogen atmosphere) and the solvent may be completely or partially removed by means known in the state of the art. 
    
    
     EXAMPLES 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     
       
         
         
             
             
         
       
     
     E1 (1.00 equivalent), aniline (E2 2.20 equivalents), tris(dibenzylideneacetone)dipalladium Pd 2 (dba) 3  (0.01 equivalents, CAS: 51364-51-3), tri-tert-butyl-phosphine P( t Bu) 3  (0.04 equivalents, CAS: 13716-12-6) and sodium tert-butoxide NaO t Bu (4.20 equivalents, CAS: 865-48-5) are stirred under nitrogen atmosphere in toluene at 90° C. After cooling down to room temperature (rt) the reaction mixture is extracted with toluene and brine and the phases are separated. The combined organic layers are dried over MgSO 4  and then the solvent is removed under reduced pressure. The crude product obtained is purified by recrystallization or column chromatography and 11 is obtained as a solid. 
     
       
         
         
             
             
         
       
     
     I1 (1.00 equivalents), E3 (2.10 equivalents), tris(dibenzylideneacetone)dipalladium Pd 2 (dba) 3  (0.01 equivalents; CAS: 51364-51-3), tri-tert-butyl-phosphine P( t Bu) 3  (0.04 equivalents, CAS: 13716-12-6) and sodium tert-butoxide NaO t Bu (4.00 equivalents, CAS: 865-48-5) are stirred under nitrogen atmosphere in toluene at 110° C. After cooling down to room temperature (rt), the reaction mixture is extracted with toluene and brine and the phases are separated. The combined organic layers are dried over MgSO 4  and then the solvent is removed under reduced pressure. The crude product obtained is purified by recrystallization or column chromatography and I2 is obtained as a solid. 
     
       
         
         
             
             
         
       
     
     I2 (1.00 equivalent) is stirred under nitrogen atmosphere in  t Bu-benzene at 40° C. Tert-butyllithium ( t BuLi, 2.20 equivalents, CAS 594-19-4) is added dropwise and the reaction is heated to 50° C. The lithiation is quenched by slowly adding trimethyl borate (6 equivalents, CAS 121-43-7) at room temperature. After heating the reaction mixture to 60° C. for 2 h, the reaction mixture is cooled down to room temperature. Water is added and the mixture is stirred for another 2 h. After extraction with ethyl acetate, the organic phase is dried over MgSO 4  and the solvent is removed under reduced pressure. The crude product obtained is purified by recrystallization or column chromatography and 13 is obtained as a solid. 
     
       
         
         
             
             
         
       
     
     I3 (1.00 equivalent) is stirred und nitrogen atmosphere in chlorobenzene. N,N-diisopropylethylamine (10.0 equivalents, CAS 7087-68-5) and aluminum chloride (AlCl 3 , 10.0 equivalents, CAS 7446-70-0) are added and the reaction mixture is heated to 120° C. After 60 min, N,N-Diisopropylethylamine (5.00 equivalents, CAS 7087-68-5) and aluminum chloride (AlCl 3 , 5.00 equivalents, CAS 7446-70-0) are added and the reaction mixture is stirred for 1.5 h. After cooling down to room temperature, the reaction mixture is extracted between DCM and water. The organic phase is dried over MgSO 4  and the solvent is removed under reduced pressure. The crude product P1 can be further purified by recrystallization or column chromatography. 
     
       
         
         
             
             
         
       
     
     Under nitrogen atmosphere E4 (1.00 equivalent), E5 (1.50 equivalents), tris(dibenzylideneacetone)-dipalladium(0) (0.005 equivalents, CAS 51364-51-3), 2-dicyclohexylphosphino-2′,4′,6′-tri-isopropyl-1,1′-biphenyl (0.02 equivalents, X-Phos, CAS 564483-18-7) and tribasic potassium phosphate (2.00 equivalents, CAS 7778-53-2) were suspended in toluene/water (4:1 by volume). The mixture was heated to 110° C. until completion of the reaction. After cooling down to room temperature, the phases were separated and the aqueous phase extracted with ethyl acetate. The combined organic layers were stirred at rt for 15 min with a 1:1:1 mixture of Charcoal/Celite® (kieselgur)/MgSO 4 , filtered and concentrated. The crude product was purified by recrystallization to yield E2. 
     Cyclic Voltammetry 
     Cyclic voltammograms are measured from solutions having concentration of 10 −3  mol/L of the organic molecules in dichloromethane or a suitable solvent and a suitable supporting electrolyte (e.g. 0.1 mol/L of tetrabutylammonium hexafluorophosphate). The measurements are conducted at room temperature under nitrogen atmosphere with a three-electrode assembly (Working and counter electrodes: Pt wire, reference electrode: Pt wire) and calibrated using FeCp 2 /FeCp 2   +  as internal standard. The HOMO data was corrected using ferrocene as internal standard against a saturated calomel electrode (SCE). 
     Density Functional Theory Calculation 
     Molecular structures are optimized employing the BP86 functional and the resolution of identity approach (RI). Excitation energies are calculated using the (BP86) optimized structures employing Time-Dependent DFT (TD-DFT) methods. Orbital and excited state energies are calculated with the B3LYP functional. Def2-SVP basis sets and a m4-grid for numerical integration are used. The Turbomole program package is used for all calculations. 
     Photophysical Measurements 
     Sample pretreatment: Spin-coating 
     Apparatus: Spin150, SPS euro. 
     The sample concentration is 10 mg/ml, dissolved in a suitable solvent. 
     Program: 1) 3 s at 400 U/min; 2) 20 s at 1000 U/min at 1000 Upm/s; 3) 10 s at 4000 U/min at 1000 Upm/s. After coating, the films are dried at 70° C. for 1 min. 
     Photoluminescence Spectroscopy and Time-Correlated Single-Photon Counting (TCSPC) 
     Steady-state emission spectroscopy is measured by a Horiba Scientific, Modell FluoroMax-4 equipped with a 150 W Xenon-Arc lamp, excitation- and emissions monochromators and a Hamamatsu R928 photomultiplier and a time-correlated single-photon counting option. Emissions and excitation spectra are corrected using standard correction fits. 
     Excited state lifetimes are determined employing the same system using the TCSPC method with FM-2013 equipment and a Horiba Yvon TCSPC hub. 
     Excitation sources: 
     NanoLED 370 (wavelength: 371 nm, puls duration: 1.1 ns) 
     NanoLED 290 (wavelength: 294 nm, puls duration: &lt;1 ns) 
     SpectraLED 310 (wavelength: 314 nm) 
     SpectraLED 355 (wavelength: 355 nm). 
     Data analysis (exponential fit) is done using the software suite DataStation and DAS6 analysis software. The fit is specified using the chi-squared-test. 
     Photoluminescence Quantum Yield Measurements 
     For photoluminescence quantum yield (PLQY) measurements an Absolute PL Quantum Yield Measurement C9920-03G system (Hamamatsu Photonics) is used. Quantum yields and CIE coordinates are determined using the software U6039-05 version 3.6.0. 
     Emission maxima are given in nm, quantum yields ϕ in % and CIE coordinates as x,y values. 
     PLOY is determined using the following protocol: 
     Quality assurance: Anthracene in ethanol (known concentration) is used as reference 
     Excitation wavelength: the absorption maximum of the organic molecule is determined and the molecule is excited using this wavelength 
     Measurement 
     Quantum yields are measured, for sample, of solutions or films under nitrogen atmosphere. The yield is calculated using the equation: 
     
       
         
           
             
               Φ 
               
                 P 
                 ⁢ 
                 L 
               
             
             = 
             
               
                 
                   
                     n 
                     photon 
                   
                   , 
                   emited 
                 
                 
                   
                     n 
                     photon 
                   
                   , 
                   absorbed 
                 
               
               = 
               
                 
                   ∫ 
                   
                     
                       
                         λ 
                         hc 
                       
                       [ 
                       
                         
                           
                             Int 
                             emitted 
                             sample 
                           
                           ( 
                           λ 
                           ) 
                         
                         - 
                         
                           
                             Int 
                             absorbed 
                             sample 
                           
                           ( 
                           λ 
                           ) 
                         
                       
                       ] 
                     
                     ⁢ 
                     d 
                     ⁢ 
                     λ 
                   
                 
                 
                   ∫ 
                   
                     
                       
                         λ 
                         hc 
                       
                       [ 
                       
                         
                           
                             Int 
                             emitted 
                             reference 
                           
                           ( 
                           λ 
                           ) 
                         
                         - 
                         
                           
                             Int 
                             absorbed 
                             reference 
                           
                           ( 
                           λ 
                           ) 
                         
                       
                       ] 
                     
                     ⁢ 
                     d 
                     ⁢ 
                     λ 
                   
                 
               
             
           
         
       
     
     wherein n photon  denotes the photon count and Int. denotes the intensity. 
     Production and Characterization of Optoelectronic Devices 
     Optoelectronic devices, in particular OLED devices, including organic molecules according to the disclosure can be produced via vacuum-deposition methods. If a layer contains more than one compound, the weight-percentage of one or more compounds is given in %. The total weight-percentage values amount to 100%, thus if a value is not given, the fraction of this compound equals to the difference between the given values and 100%. 
     The not fully optimized OLEDs are characterized using standard methods and measuring electroluminescence spectra, the external quantum efficiency (in %) in dependency on the intensity, calculated using the light detected by the photodiode, and the current. The OLED device lifetime is extracted from the change of the luminance during operation at constant current density. The LT50 value corresponds to the time, where the measured luminance decreased to 50% of the initial luminance, analogously LT80 corresponds to the time point, at which the measured luminance decreased to 80% of the initial luminance, LT 95 to the time point, at which the measured luminance decreased to 95% of the initial luminance etc. 
     Accelerated lifetime measurements are performed (e.g. applying increased current densities). For example, LT80 values at 500 cd/m 2  are determined using the following equation: 
     
       
         
           
             
               LT 
               ⁢ 
               80 
               ⁢ 
               
                 ( 
                 
                   500 
                   ⁢ 
                   
                     cd 
                     
                       m 
                       2 
                     
                   
                 
                 ) 
               
             
             = 
             
               LT 
               ⁢ 
               80 
               ⁢ 
               
                 ( 
                 
                   L 
                   0 
                 
                 ) 
               
               ⁢ 
               
                 
                   ( 
                   
                     
                       L 
                       0 
                     
                     
                       500 
                       ⁢ 
                       
                         cd 
                         
                           m 
                           2 
                         
                       
                     
                   
                   ) 
                 
                 1.6 
               
             
           
         
       
     
     wherein L 0  denotes the initial luminance at the applied current density. 
     The values correspond to the average of several pixels (typically two to eight), and the standard deviation between these pixels is given. 
     HPLC-MS 
     HPLC-MS analysis is performed on an HPLC by Agilent (1100 series) with MS-detector (Thermo LTQ XL). 
     For example, a typical HPLC method is as follows: a reverse phase column 4.6 mm×150 mm, particle size 3.5 μm from Agilent (ZORBAX Eclipse Plus 95 Å C18, 4.6×150 mm, 3.5 μm HPLC column) is used in the HPLC. The HPLC-MS measurements are performed at room temperature (rt) following gradients 
     
       
         
           
               
               
               
               
               
             
               
                   
               
               
                 Flow rate [ml/min] 
                 Time [min] 
                 A[%] 
                 B[%] 
                 C[%] 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
            
               
                 2.5 
                 0 
                 40 
                 50 
                 10 
               
               
                 2.5 
                 5 
                 40 
                 50 
                 10 
               
               
                 2.5 
                 25 
                 10 
                 20 
                 70 
               
               
                 2.5 
                 35 
                 10 
                 20 
                 70 
               
               
                 2.5 
                 35.01 
                 40 
                 50 
                 10 
               
               
                 2.5 
                 40.01 
                 40 
                 50 
                 10 
               
               
                 2.5 
                 41.01 
                 40 
                 50 
                 10 
               
               
                   
               
            
           
         
       
     
     using the following solvent mixtures: 
     
       
         
           
               
               
               
               
             
               
                   
                   
               
             
            
               
                   
                 Solvent A: 
                 H2O (90%) 
                 MeCN (10%) 
               
               
                   
                 Solvent B: 
                 H2O (10%) 
                 MeCN (90%) 
               
               
                   
                 Solvent C: 
                 THF (50%) 
                 MeCN (50%) 
               
               
                   
                   
               
            
           
         
       
     
     An injection volume of 5 μL from a solution with a concentration of 0.5 mg/mL of the analyte is taken for the measurements. 
     Ionization of the probe is performed using an atmospheric pressure chemical ionization (APCI) source either in positive (APCI+) or negative (APCI−) ionization mode. 
     Example 1 
     
       
         
         
             
             
         
       
     
     Example 1 was synthesized according to 
     AAV5 (44% yield) using 4-tert-butyl-3-chloroaniline (CAS 52756-36-2) as E4 and phenylboronic acid (CAS 98-80-6) as E5; 
     AAV1 (52% yield) using 4-chloro-3,5-dibromotoluene (CAS 202925-05-1) as E1; 
     AAV2 (69% yield) using 1-bromo-3,5-di-tert-butylbenzene (CAS 22385-77-9) as E3; 
     AAV3 (26% yield) and 
     AAV4 (15% yield). 
     MS (HPLC-MS), m/z (retention time): 924.4 (8.75 min) 
     The emission maximum of example 1 (2% by weight in PMMA) is at 461 nm, the full width at half maximum (FWHM) is 0.16 eV, and the CIEy coordinate is 0.11. The photoluminescence quantum yield (PLQY) is 77%. 
     Example D1 
     Example 1 was tested in the OLED D1, which was fabricated with the following layer structure: 
     
       
         
           
               
               
               
             
               
                   
               
               
                 Layer # 
                 Thickness 
                 D1 
               
               
                   
               
             
            
               
                 9 
                 100 nm 
                 Al 
               
               
                 8 
                  2 nm 
                 Liq 
               
               
                 7 
                  11 nm 
                 NBPhen 
               
               
                 6 
                  20 nm 
                 MAT1 
               
               
                 5 
                  20 nm 
                 MAT2 (98%):Example 1 (2%) 
               
               
                 4 
                  10 nm 
                 MAT3 
               
               
                 3 
                  50 nm 
                 MAT4 
               
               
                 2 
                  7 nm 
                 HAT-CN 
               
               
                 1 
                  50 nm 
                 ITO 
               
               
                 Substrate 
                   
                 Glass 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                   
                     
                     
                         
                         
                     
                   
                   
                     
                     
                         
                         
                     
                   
                   
                     
                     
                         
                         
                     
                   
                 
               
            
           
         
       
     
     OLED D1 yielded an external quantum efficiency (EQE) at 1000 cd/m 2  of 11.1%. The emission maximum is at 465 nm with a FWHM of 28 nm at 3.7 V. The corresponding CIEx value is 0.13 and the CIEy value is 0.10. A LT95-value at 1200 cd/m 2  of 12 h was determined. 
     Additional Examples of Organic Molecules of the Disclosure