Patent Publication Number: US-2006014806-A1

Title: Dihalo-allyloxy-phenol derivatives having pesticidal activity

Description:
The present invention relates (1) to compounds of formula  
                 
 
      wherein  
      A 1  and A 2  are each independently of the other a bond or a C 1 -C 6 alkylene bridge which is unsubstituted or substituted by from one to six identical or different substituents selected from halogen and C 3 -C 8 cycloalkyl;  
      A 3  is a C 1 -C 6 alkylene bridge which is unsubstituted or substituted by from one to six identical or different substituents selected from halogen and C 3 -C 8 cycloalkyl;  
      Y is O, NR 7 , S, SO or SO 2 ;  
      X, and X 2  are each independently of the other fluorine, chlorine or bromine;  
      R 1 , R 2  and R 3  are each independently of the others H, halogen, OH, SH, CN, nitro, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 1 -C 6 alkylcarbonyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, C 2 -C 6 alkynyl, C 1 -C 6 alkoxy, C 1 -C 6 haloalkoxy, C 3 -C 6 alkenyloxy, C 3 -C 6 haloalkenyloxy, C 3 -C 6 alkynyloxy, —(S═O)—C 1 -C 6 alkyl, —(SO) 2 —C 1 -C 6 alkyl or C 1 -C 6 alkoxycarbonyl; the substituents R 3  being independent of one another when m is 2;  
      Q is O, NR 5 , S, SO or SO 2 ;  
      W is O, NR 5 , S, SO, SO 2 , —C(═O)—O—, —O—C(═O)—, —C(═O)—NR 5 — or —NR 5 —C(═O)—;  
      T is a bond, O, NR 5 , S, SO, SO 2 , —C(═O)—O—, —O—C(═O)—, —C(═O)—NR 5 — or —NR 5 —C(═O)—;  
      D is CH or N;  
      R 4  is H, halogen, OH, SH, CN, nitro, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 1 -C 6 alkylcarbonyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, C 2 -C 6 alkynyl, C 1 -C 6 alkoxy, C 1 -C 6 haloalkoxy, C 3 -C 6 -alkenyloxy, C 3 -C 6 haloalkenyloxy, C 3 -C 6 alkynyloxy, —(S═O)—C 1 -C 6 alkyl, —(SO) 2 -C 1 -C 6 alkyl, C 1 -C 6 alkoxycarbonyl or N(R 6 ) 2  wherein the two substituents R 6  are independent of one another; the substituents R 4  being independent of one another when k is greater than 1;  
      R 5 , R 6  and R 7  are each independently of the others H, C 1 -C 6 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 haloalkylcarbonyl, C 1 -C 6 alkoxyalkyl, C 1 -C 6 alkylcarbonyl, C 1 -C 6 alkoxycarbonyl, C 3 -C 8 -cycloalkyl, C 3 -C 8 cycloalkyl-C 1 -C 6 alkyl, C 3 -C 8 cycloalkylcarbonyl;  
      k is 1, 2 or 3 when D is nitrogen; or is 1, 2, 3 or 4 when D is CH;  
      m is 1 or 2;  
      R 10  is any radical which comprises from one to three hetero atoms selected from O, N and S; and which may be connected to R 12  via a C 1 -C 6 alkylene bridge;  
      R 11  is H, C 1 -C 12 alkyl, halogen or any radical which comprises from one to three hetero atoms selected from O, N and S; or R 11  together with R 12  is a bond;  
      or R 10  and R 11 , together with the carbon atom to which they are bonded, are a five- to seven-membered ring which optionally contains from one to three hetero atoms selected from O, N and S and which is unsubstituted or substituted by from one to three identical or different substituents selected from halogen, OH, ═O, SH, ═S, ═N—OH, ═N—O—C 1 -C 6 alkyl, CN, nitro, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 1 -C 6 alkylcarbonyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, C 2 -C 6 alkynyl, C 1 -C 6 alkoxy and C 1 -C 6 haloalkoxy;  
      R 12  is H, C 1 -C 6 alkyl, halo-C 1 -C 6 alkyl, C 1 -C 6 alkoxy-C 1 -C 6 alkyl, C 3 -C 6 cycloalkyl, phenoxy-C 1 -C 6 alkyl, CN, —C(═O)C 1 -C 12 alkyl, unsubstituted heterocyclyl, heterocyclyl which is substituted by one to three substituents selcected form the group consisting of OH, ═O, SH, ═S, halogen, CN, nitro, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 1 -C 6 alkylcarbonyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, C 1 -C 6 alkoxy and C 1 -C 6 haloalkoxy; or R 12  together with R 11  a bond; or is a C 2 -C 6 alkylene bridge which is connected to R 10 ;  
      and, where applicable, their possible E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free form or in salt form, to a process for the preparation of those compounds, E/Z isomers and tautomers and to their use in pest control, to pesticidal compositions in which the active ingredient has been selected from those compounds, E/Z isomers and tautomers, and to a process for the preparation of those compositions and to their use, to intermediates and, where applicable, their possible E/Z isomers, E/Z isomeric mixtures and/or tautomers, in free form or in salt form, for the preparation of those compounds, where applicable to tautomers, in free form or in salt form, of those intermediates and to a process for the preparation of those intermediates and their tautomers and to their use.  
      Certain dihaloallyl derivatives are proposed in the literature as active ingredients in pesticidal compositions. The biological properties of those known compounds are not entirely satisfactory in the field of pest control, however, for which reason there Is a need to provide further compounds having pesticidal properties, especially for controlling insects and members of the order Acarina, that problem being solyed according to the invention by the provision of the present compounds of formula (I).  
      The compounds of formula (I) and, where applicable, their tautomers are able to form salts, e.g. acid addition salts. The latter are formed, for example, with strong inorganic acids, such as mineral acids, e.g. sulfuric acid, a phosphoric acid or a hydrohalic acid, with strong organic carboxylic acids, such as unsubsttuted or substituted, e.g. halo-substituted, C 1 -C 4 alkanecarboxylic acids, for example acetic acid, saturated or unsaturated dicarboxylic acids, e.g. oxalic, malonic, maleic, fumaric or phthalic acid, hydroxycarboxylic acids, e.g. ascorbic, lactic, malic, tartaric or citric acid, or benzoic acid, or with organic sulfonic acids, such as unsubstituted or substituted, e.g. halo-substituted, C 1 -C 4 alkane- or aryl-sulfonic acids, e.g. methane- or p-toluene-sulfonic acid. Furthermore, compounds of formula (I) having at least one acid group are able to form salts with bases. Suitable salts with bases are, for example, metal salts, such as alkali metal or alkaline earth metal salts, e.g. sodium, potassium or magnesium salts, or salts with ammonia or an organic amine, such as morpholine, piperidine, pyrrolidine, a mono-, di- or tri-lower alkylamine, e.g. ethyl-, diethyl-, triethyl- or dimethyl-propyl-amine, or a mono-, di- or tri-hydroxy-lower alkylamine, e.g. mono-, di- or tri-ethanolamine. It may also be possible for corresponding internal salts to be formed. The free form is preferred. Of the salts of compounds of formula (I), preference is given to agrochemically advantageous salts. Hereinabove and hereinbelow any reference to the free compounds of formula (I) or to their salts is to be understood as including, where appropriate, also the corresponding salts or the free compounds of formula (I), respectively. The same applies to tautomers of compounds of formula (I) and their salts.  
      The general terms used hereinabove and hereinbelow have the meanings given below, unless defined otherwise.  
      Halogen, as a group per se and as a structural element of other groups and compounds, such as haloalkyl, halocycloalkyl, haloalkenyl, haloalkynyl and haloalkoxy, is fluorine, chlorine, bromine or iodine, especially fluorine, chlorine or bromine, more especially fluorine or chlorine, especially chlorine.  
      Unless defined otherwise, carbon-containing groups and compounds each contain from 1 up to and including 20, preferably from 1 up to and including 18, especially from 1 up to and including 10, more especially from 1 up to and including 6, especially from 1 up to and including 4, especially from 1 up to and including 3, more especially 1 or 2, carbon atoms; methyl is especially preferred.  
      Alkylene is a straight-chain or branched bridging member and is especially —CH 2 —, —CH 2 CH 2 —, —CH 2 —CH 2 —CH 2 —, —CH 2 —CH 2 —CH 2 CH 2 —, —CH 2 —CH 2 —CH 2 —CH 2 CH 2 —, —CH(CH 3 )—, —CH 2 (CH 3 )CH 2 —CH 2 —, —CH(C 2 H 5 )—, —C(CH 3 ) 2 —, —CH(CH 3 )CH 2 —, —CH(CH 3 )CH(CH 3 )— or —CH 2 C(CH 3 ) 2 —CH 2 —.  
      Alkyl, as a group per se and as a structural element of other groups and compounds, such as haloalkyl, alkoxy, alkoxyalkyl, haloalkoxy, alkoxycarbonyl, alkylthio, haloalkylthio, alkylsulfonyl and alkylsulfonyloxy, is—in each case giving due consideration to the number of carbon atoms contained in the group or compound in question—either straight-chain, e.g. methyl, ethyl, n-propyl, n-butyl, n-hexyl, n-octyl, n-decyl, n-dodecyl, n-hexadecyl or n-octadecyl, or branched, e.g. isopropyl, isobutyl, sec-butyl, tert-butyl, isopentyl, neopentyl or isohexyl.  
      Alkenyl and alkynyl—as groups per se and as structural elements of other groups and compounds, such as haloalkenyl, haloalkynyl, alkenyloxy, haloalkenyloxy, alkynyloxy or haloalkynyloxy—are straight-chain or branched and each contains two or preferably one unsaturated carbon-carbon bond(s). There may be mentioned by way of example vinyl, prop-2-en-1-yl, 2-methylprop-2-en-1-yl, but-2-en-1-yl, but-3-en-1-yl, prop-2-yn-1-yl, but-2-yn-1-yl and but-3-yn-1-yl.  
      Cycloalkyl—as a group per se and as a structural element of other groups and compounds, such as alkyl—is cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl or cyclooctyl. Cyclopentyl and cyclohexyl, and especially cyclopropyl, are preferred.  
      Halo-substituted carbon-containing groups and compounds, such as haloalkyl and haloalkoxy, may be partially halogenated or perhalogenated, the halogen substituents in the case of polyhalogenation being the same or different. Examples of haloalkyl—as a group per se and as a structural element of other groups and compounds, such as haloalkoxy—are methyl substituted from one to three times by fluorine, chlorine and/or bromine, such as CHF 2 , CF 3  or CH 2 Cl; ethyl substituted from one to five times by fluorine, chlorine and/or bromine, such as CH 2 CF 3 , CF 2 CF 3 , CF 2 CCl 3 , CF 2 CHCl 2 , CF 2 CHF 2 , CF 2 CFCl 2 , CH 2 CH 2 Cl, CF 2 CHBr 2 , CF 2 CHCIF, CF 2 CHBrF or CCIFCHCIF; propyl or isopropyl each substituted from one to seven times by fluorine, chlorine and/or bromine, such as CH 2 CHBrCH 2 Br, CF 2 CHFCF 3 , CH 2 CF 2 CF 3 , CF 2 CF 2 CF 3 , CH(CF 3 ) 2  or CH 2 CH 2 CH 2 Cl; and butyl or an isomer thereof substituted from one to nine times by fluorine, chlorine and/or bromine, such as CF(CF 3 )CHFCF 3 , CF 2 (CF 2 ) 2 CF 3  or CH 2 (CF 2 ) 2 CF 3 .  
      Aryl is especially phenyl or naphthyl, preferably phenyl.  
      Heterocyclyl is to be understood as meaning a five- to seven-membered monocyclic ring which is aromatic or nonaromatic and which contains from one to three hetero atoms selected from the group consisting of N, O and S, especially N and S; or a bicyclic ring system which is aromatic or nonaromatic and which may contain, either in one ring only—as in quinolyl, quinoxalinyl, indolinyl, benzothiophenyl or benzofuranyl, for example—or in both rings—as in pteridinyl or purinyl, for example—one or more hetero atoms selected independently of one another from N, O and S. Preference is given to pyridyl, pyrimidyl, s-triazinyl, 1,2,4-triazinyl, tetrazolyl, thienyl, furanyl, tetrahydrofuranyl, pyranyl, tetrahydropyranyl, pyrrolyl, pyrazolyl, imidazolyl, thiazolyl, triazolyl, oxazolyl, isoxazolyl, thiadiazolyl, oxadiazolyl, benzothienyl, quinolyl, quinoxalinyl, benzofuranyl, benzimidazolyl, benzpyrrolyl, benzthiazolyl, indolyl, coumarinyl or indazolyl, which are preferably bonded via a carbon atom; preference is given to thienyl, thiazolyl, benzofuranyl, benzothiazolyl, furanyl tetrahydropyranyl or indolyl; especially pyridyl or thiazolyl.  
      Preferred embodiments within the scope of the invention are  
      (2) compounds of formula (I) according to (1) wherein R 10  is CN, NO 2 , —C(═NOR 14 )—R 13 , —C(═O)—R 15 , —C 1 -C 6 alkyl-O—R 16 , —NH—C(═O)—O—R 17  or —CH(O—R 18 ) 2 ;  
      R 13  is C 1 -C 12 alkyl, C 1 -C 6 haloalkyl, C 3 -C 6 cycloalkyl, C 1 -C 6 alkoxy, C 1 -C 3 haloalkoxy, C 1 -C 6 -alkylamino, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 2 -C 6 haloalkenyl, C 2 -C 6 haloalkynyl; or R 13  together with R 11  is a C 1 -C 6 alkylene bridge; or R 13  together with R 12  a C 3 -C 6 alkylene bridge; preferably wherein R 13  is C 1 -C 12 alkyl, C 1 -C 6 haloalkyl, C 3 -C 6 cycloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 2 -C 6 haloalkenyl or C 2 -C 6 haloalkynyl;  
      R 14  is H, C 1 -C 6 alkyl, C 3 -C 6 cycloalkyl-C 1 -C 6 alkyl, C 3 -C 6 alkenyl or C 3 -C 6 alkynyl;  
      R 15  is H, OH, C 1 -C 12 alkyl, C 1 -C 6 alkoxy, C 1 -C 12 haloalkyl, C 1 -C 6 haloalkoxy, C 3 -C 6 alkenyloxy, C 3 -C 6 haloalkenyloxy, —N(R 18 ) 2 , C 3 -C 6 cycloalkyl, aryl, aryloxy, benzyloxy or heterocyclyl; or R 15 together with R 12  is an C 1 -C 6 alkylene bridge; and  
      R 16  is H, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 3 -C 6 alkenyl, C 3 -C 6 haloalkenyl, C 3 -C 6 alkynyl, C 3 -C 6 cycloalkyl, C 3 -C 6 cycloalkyl-C 1 -C 6 alkyl, C 1 -C 6 alkoxy-C 1 -C 6 alkyl, C 1 -C 6 haloalkoxy-C 1 -C 6 alkyl, C 1 -C 6 alkoxy-C 1 -C 6 alkoxy-C 1 -C 6 alkyl, C 1 -C 6 haloalkoxy-C 1 -C 6 alkoxy-C 1 -C 6 alkyl, C 3 -C 6 alkenyloxy-C 1 -C 6 alkyl, C 3 -C 6 alkynyloxy-C 1 -C 6 alkyl, C 3 -C 6 cycloalkoxy-C 1 -C 6 alkyl, C 3 -C 6 cycloalkyl-C 1 -C 6 alkoxyC 1 -C 6 alkyl or benzyl;  
      R 17  is H, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 3 -C 6 alkenyl, C 3 -C 6 haloalkenyl, C 3 -C 6 alkynyl, C 3 -C 6 cycloalkyl, C 3 -C 6 cycloalkyl-C 1 -C 6 alkyl, C 1 -C 6 alkoxy-C 1 -C 6 alkyl or benzyl;  
      the two substituents R 18  are each independently of the other C 1 -C 12 alkyl or benzyl or together are a C 2 -C 6 alkylene bridge;  
      (3) compounds of formula (I) according to (1) wherein R 10  and R 11 , together with the carbon atom to which they are bonded, are a five- or six-membered ring which optionally contains from one to three hetero atoms selected from O and N and which is unsubstituted or substituted by from one to three identical or different substituents selected from halogen, OH, ═O, SH, ═S, ═N—OH, ═N—O—C 1 -C 6 alkyl, CN, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl and C 1 -C 6 -haloalkoxy;  
      (4) compounds of formula (I) according to (1) wherein R 11  and R 12  together are a bond;  
      (5) compounds of formula (I) according to (1) wherein R 10  is CN;  
      (6) compounds of formula (I) according to (1) wherein R 10  is NO 2 ;  
      (7) compounds of formula (I) according to (1) wherein Ri 0  is —C(═NOR 14 )—R 13  and R 13  is C 1 -C 12 alkyl or C 3 -C 6 cycloalkyl, especially C 1 -C 12 alkyl;  
      (8) compounds of formula (I) according to (1) wherein R 10  is —C(═O)—R 15 ;  
      (9) compounds of formula (I) according to (1) wherein R 10  is R 16   13  O—C 1 -C 6 alkyl;  
      (10) compounds of formula (I) according to (1) wherein R 11  is H, C 1 -C 12 alkyl, halogen, CN or —C(═O)—R 15  and R 15  is as defined under (2);  
      (11) compounds of formula (I) according to (1) to (10) wherein R 12  is H, C 1 -C 6 alkyl, CN, —C(O)—C 1 -C 6 alkyl or halo-C 1 -C 6 alkyl; especially H or C 1 -C 6 alkyl;  
      (12) compounds of formula (I) according to (1) to (10) wherein R 12  is C 1 -C 6 alkoxy-C 1 -C 6 alkyl;  
      (13) compounds of formula (I) according to (1) to (10) wherein R 12  is heteroaryl; preferably pyridyl, isoxazolyl, thienyl, furanyl or benzofuranyl;  
      (14) compounds of formula (I) according to (1) to (13) wherein X 1  and X 2  are chlorine or bromine, especially chlorine;  
      (15) compounds of formula (I) according to (1) to (14) wherein D is CH;  
      (16) compounds of formula (I) according to (1) to (14) wherein D is N;  
      (17) compounds of formula (I) according to (1) to (16) wherein the group A 1 -T-A 2  is a bond;  
      (18) compounds of formula (I) according to (1) to (18) wherein W is oxygen, —C(═O)O— or —C(═O)NH—; especially O;  
      (19) compounds of formula (I) according to (1) to (18) wherein A 3  is a straight-chain alkylene bridge; especially ethylene, propylene or butylenes; more especially propylene;  
      (20) compounds of formula (I) according to (1) to (19) wherein Q is oxygen;  
      (21) compounds of formula (I) according to (1) to (20) wherein Y is oxygen;  
      (22) compounds of formula (I) according to (1) to (21) wherein R 1  and R 2  are bromine or chlorine, especially chlorine;  
      (23) compounds of formula (I) according to (1) to (22) wherein R 3  is hydrogen;  
      (24) compounds of formula (I) according to (1) to (23) wherein R 4  is hydrogen;  
      (25) compounds of formula (I) according to (1) to (24) wherein R 5  is H;  
      (26) compounds of formula (I) according to (1) to (25) wherein R 5  is —C(═O)R 8  or —C(═S)R 8 , and R 8  is C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, C 2 -C 6 alkynyl, C 1 C 6 alkoxy, C 1 -C 6 haloalkoxy, C 3 -C 6 alkenyloxy, C 3 -C 6 haloalkenyloxy, C 3 -C 6 alkynyloxy, C 3 -C 6 cycloalkyl or phenyl;  
      (27) compounds of formula (I) according to (1) to (26) wherein R 6  is H or C 1 -C 6 alkyl;  
      (28) compounds of formula (I) according to (1) to (26) wherein A 1  is a bond, T is oxygen and A 2  is a C 1 -C 6 alkylene bridge;  
      (29) compounds of formula (I) according to (1) to (26) wherein A 1  is a bond, T is —C(═O)O—, wherein the oxygen is bonded to A 2 , or —C(═O)NH—, wherein NH is bonded to A 2 , and A 2  is a C 1 -C 6 alkylene bridge.  
      Special preference is given to the compounds listed in the Tables.  
      The invention relates also to a process for the preparation of a compound of formula (I), or a salt thereof, wherein  
      (a) a compound of formula  
                 
 
      wherein A 1 , A 2 , A 3 , D, W, Q, T, R 1 , R 2 , R 3 , R 4 , R 10 , R 11 , R 12 , m and k are as defined for formula (I) under (1), Z 1  is —C(═O)R 20  and R 20  is H or C 1 -C 6 alkyl, is converted in the presence of an oxidising agent, especially a peracid, into a compound of formula 
 
G-Z 2a    (IIIa), 
 
      wherein Z 2a  is O—C(═O)—C 1 -C 6 alkyl and G denotes the part of the formula in brackets designated G in formula (II); either  
      (b) a compound of formula (IIIa) above or of formula 
 
G-Z 2b    (IIIb), 
 
      wherein G denotes the part of the formula in brackets designated G in formula (II), Z2b is a radical of formula —Y—C(═O)R 21 , Y is as defined for formula (I) under (1) and R 21  is C 1 -C 12 alkyl unsubstituted or substituted by from one to three identical or different halogen substituents, or is phenyl unsubstituted or substituted by from one to three identical or different substituents selected from halogen, CN, nitro, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 1 -C 6 -alkylcarbonyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, C 2 -C 6 alkynyl, C 1 -C 6 alkoxy, C 1 -C 6 haloalkoxy, C 1 -C 6 alkoxycarbonyl and C 3 -C 6 haloalkenyloxy, is converted by hydrolytic cleavage into a compound of formula 
 
G-Z 3    (IV), 
 
      wherein G denotes the part of the formula in brackets designated G in formula (II), Z 3  is YH and Y is as defined for formula (I) under (1); or  
      (c) a compound of formula 
 
G-Z 4    (V), 
 
      wherein Z 4  is Y—CH 2 -phenyl, wherein the phenyl radical is unsubstituted or substituted by from one to three identical or different substituents selected from halogen, CN, nitro, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 1 -C 6 alkylcarbonyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, C 2 -C 6 alkynyl, C 1 -C 6 alkoxy, C 1 -C 6 haloalkoxy, C 1 -C 6 alkoxycarbonyl and C 3 -C 6 haloalkenyloxy, G denotes the part of the formula in brackets designated G in formula (II) and Y is as defined for formula (I), is converted by removal of the benzyl group into a compound of formula (IV), as defined above;  
      (d) the compound of formula (IV) so obtained is reacted in the presence of a base with a compound of formula  
                 
 
      wherein Hal is halogen, preferably bromine or chlorine, and alkyl is C 1 -C 6 alkyl, or the two alkyl radicals together form a C 2 -C 8 alkylene bridge, to form a compound of formula 
 
G-Z 5    (VI), 
 
      wherein G denotes the part of the formula in brackets designated G in formula (II) and Z 5  is  
                 
 
      wherein alkyl and Y are as defined above;  
      (e) the compound of formula (VI) so obtained is converted by deprotection of the acetal function in the presence of an acid into a compound of formula 
 
G-Z 6    (VII), 
 
      wherein Z 6  is a group —Y—CH 2 —C(═O)H, G is as defined above for the compound of formula (II) and Y is as defined for formula (I) under (1), either  
      (f 1 ) for the preparation of a compound of formula (I) wherein X 1  and X 2  are chlorine or bromine, a compound of formula (VII) is reacted in the presence of a phosphine with a compound of formula C(X) 4  wherein X is chlorine or bromine; or  
      (f 2 ) for the preparation of a compound of formula (I) wherein X 1  and X 2  are chlorine, a compound of formula (VII) is reacted first with CCl 3 —COOH or with chloroform in the presence of a strong base, then with acetic anhydride and subsequently with powdered zinc in acetic acid; or  
      (f 3 ) for the preparation of a compound of formula (I) wherein X 1  is fluorine and X 2  is chlorine or bromine, a compound of formula (VII) is reacted in the presence of a phosphine first with a compound of the formula CF 2 X 2 , of the formula CFX 3 , of the formula CF 2 XC(═O)ONa or of the formula CFX 2 C(═O)ONa; or  
      (g 1 ) for the preparation of a compound of formula (I) wherein X 1  and X 2  are chlorine or bromine, a compound of formula (IV) is reacted in the presence of a base with a compound of formula  
                 
 
      wherein L 3  is a leaving group, preferably chlorine or bromine, and Hal is chlorine or bromine; or  
      (g 2 ) for the preparation of a compound of formula (I) wherein X 1  and X 2  are chlorine or bromine, a compound of formula (IVa) or (IVb) is reacted in the presence of a base with a compound of formula  
                 
 
 or of formula  
                 
 
      wherein Hal is halogen and X is chlorine or bromine.  
      The invention relates also to  
      (h) a process for the preparation of a compound of formula (I) as defined under (1) and wherein Q is O, NR 5  or S and R 5  is as defined for formula (I) under (1), wherein a compound of formula  
                 
 
      wherein A 1 , A 2 , A 3 , D, W, T, R 4 , R 10 , R 11 , R 12  and k are as defined for formula (I) under (1) and L 1  is a leaving group, is reacted in the presence of a base with a compound of formula  
                 
 
      wherein R 1 , R 2 , R 3  and m are as defined for formula (I) under (1), Q is O, NR 5  or S and Z is one of the radicals Z 1  to Z 6  as defined for the above formulae (II) to (VII), and R 5  is as defined for formula (I) under (1), and the resulting compound of formula  
                 
 
      wherein A 1 , A 2 , A 3 , D, W, Q, T, R 1 , R 2 , R 3 , R 4 , R 10 , R 11 , R 12 , m and k are as defined for formula (I) under (1) and Z is one of the radicals Z 1  to Z 6  as defined for formulae (II) to (VII) indicated above, is, as necessary, that is to say according to the meaning of the radical Z, reacted further analogously to one or more of process steps (a) to (g).  
      In the compounds of formulae X/a to X/f, Z in compound X/a has the same meanings as Z 1  in the compound of formula (II), and Z in compound X/b has the same meanings as Z 2  as defined for formula (III), and so on.  
      The invention relates also to  
      (i 1 ) a process for the preparation of a compound of formula (I) as defined above wherein W is O, NR 5 , S, —O—C(═O)— or —NR 5 —C(═O)— and R 5  is as defined for formula (I) under (1), wherein a compound of formula  
                 
 
      wherein A 1 , A 2 , A 3 , D, T, R 4 , R 10 , R 11 , R 12  and k are as defined for formula (I) under (1), W 1  is O, NR 5  or S and R 5  is as defined for formula (I) under (1), is reacted with a compound of formula  
                 
 
      wherein A 3 , R 1 , R 2 , R 3 , Q and m are as defined for formula (I) under (1), L 2  is a leaving group or a group Hal-C(═O)— wherein Hal is a halogen atom, preferably chlorine or bromine, and Z is one of the radicals Z 1  to Z 6  as defined in formulae (II) to (VII) indicated above; or  
      (i 2 ) for the preparation of a compound of formula (I) as defined above wherein W is O, NR 5 , S, —C(═O)—O— or —C(═O)—NR 5 — and R 5  is as defined for formula (I) under (1), wherein a compound of formula  
                 
 
      wherein A 1 , A 2 , D, T, R 4 , R 10 , R 11 , R 12  and k are as defined for formula (I) under (1) and L 1  is a leaving group or a group —C(═O)-Hal wherein Hal is a halogen atom, preferably chlorine or bromine, is reacted with a compound of formula  
                 
 
      wherein W 2  is O, NR 5  or S and R 1 , R 2 , R 3  and m are as defined for formula (I) under (1),  
      and a resulting compound of formula (Xa) to (Xf) as defined above is, as necessary, that is to say according to the meaning of the radical Z, reacted further analogously to one or more of process steps (a) to (g).  
      In the compounds of formulae XII/a to XII/f and XIV/a to XIV/f, the radicals Z are as defined above for the compounds X/a to X/f; that is to say, for example, Z in the compound of formula XII/a has the same meanings as Z 1  in the compound of formula (II), and Z in compound XII/b has the same meanings as Z 2  as defined for formula (III), and so on.  
      The invention relates also to  
      (k) a process for the preparation of a compound of formula (I) as defined above under (1), wherein a compound of formula (VIII) as defined above is reacted in the presence of a base with a compound of formula  
                 
 
      wherein R 1 , R 2 , R 3 , O, X 1 , X 2 , Y and m are as defined for formula (I) under (1).  
      The invention relates also to  
      (l) a process for the preparation of a compound of formula (I) as defined above under (1), wherein a compound of formula (XI) as defined above is reacted in a manner analogous to that in process variant (i) with a compound of formula  
                 
 
      wherein A 3 , R 1 , R 2 , R 3 , Q, Y, X 1 , X 2  and m are as defined for formula (l) under (1) and L 2  is as defined for formula (XII).  
      The compounds of formulae (IIIa) and (IIIb) wherein R 1  and R 2  are halogen can be obtained by  
      (m 1 ) reacting a compound of formula  
                 
 
      wherein R 3 , O, Y and m are as defined for formula (I) under (1), with a compound of the formula Hal-C(═O)-phenyl wherein Hal is a halogen atom, preferably chlorine or bromine,  
      (m 2 ) halogenating the resulting compound of formula  
                 
 
      wherein R 3 , Q, Y and m are as defined for formula (I) under (1), and further reacting the resulting compound of formula  
                 
 
      wherein R 3 , Q, Y and m are as defined for formula (I) under (1) and R 1  and R 2  are halogen, analogously to Process (k).  
      The invention relates also to a process  
      (n) for the preparation of a compound of formula (I) wherein R 11  and R 12  together are a bond and the remaining radicals are as defined above for formula (I), wherein a compound of formula  
                 
 
      wherein Hal is a halogen atom, preferably bromine or iodine, and A 1 , A 2 , A 3 , D, W, Q, T, R 1 , R 2 , R 3 , R 4 , m and k are as defined for formula (I) under (1), is reacted in the presence of a heavy metal catalyst and, where appropriate, of a phosphine with a compound of formula 
 
R 10 —C≡CH   (XXI), 
 
      wherein R 10  is as defined for formula (I), and the resulting compound of formula (I) is, if desired, reacted further to form a different compound of formula (I); by, for example,  
      (o) for the preparation of a compound of formula (I) wherein R 10  is a radical R 16 —O—C 1 -C 6 alkyl and R 16  is as defined above, alkylating a compound of formula 
 
K—C≡C—C 1 -C 6 hydroxyalkyl (Ia) 
 
      obtained according to (n), wherein K corresponds to the expression in brackets in the compound of formula (XX), by means of a compound of formula R 16 -Hal wherein R 16  is as defined above and Hal is a halogen atom; or  
      (p) for the preparation of a compound of formula (I) wherein R 10  is —C(═O)—R 13  or —C(═NO—R 14 )—R 13 , converting a compound of formula  
                 
 
      obtainable according to Process (n), wherein K corresponds to the expression in brackets in the compound of formula (XX) and R 13  is as defined above for formula (I), by means of an oxidising agent into a compound of formula  
                 
 
      wherein K corresponds to the expression in brackets in the compound of formula (XX) and R 13  is as defined above for formula (I), and, if desired, reacting the compound of formula (Ic)  
      (q) with a compound of the formula H 2 NOR 14  wherein R 14  is as defined above for formula (I), or with a salt thereof.  
      The invention relates also to a process for the preparation of a compound of formula (I) as defined above, wherein  
      (r) a compound of formula  
                 
 
      which is known or can be prepared by processes known per se and wherein R 12  is as defined for formula (I) and K is as defined for formula (XX), is reacted in the presence of a strong base with a compound of formula 
 
R 10 (R 11 )P(phenyl) 3    (XXIVa) 
 
 or of formula 
 
R 10 (R 11 )P(═O)(O-alkyl) 2    (XXIVb), 
 
      which are known or can be prepared by processes known per se and wherein R 10  and R 11  are as defined for formula (I) under (1); or  
      (s) a compound of the above formula (XX) is reacted with a compound of the above formula 
 
R 10 (R 11 )C═CH 2    (XXV), 
 
      which is known or can be prepared by processes known per se and wherein R 10  and R 11  are as defined for formula (I) under (1); or  
      (t) for the preparation of a compound of formula (I), wherein a compound of formula (XXIII) defined above is reacted with a compound of formula 
 
R 10 CH 2 R 11    (XXVI), 
 
      which is known or can be prepared by processes known per se and wherein R 10  and R 11  are as defined for formula (I) under (1).  
      It will be understood that Processes (n) to (t) according to the invention may also be carried out on any desired precursor, and those precursors can then be processed according to Processes (a) to (m) to form the compounds of formula (I). The invention relates also to corresponding intermediates. Such intermediates, where novel, are the compounds of formulae (II) to (XXVI), in free form or in salt form, and compounds of formulae  
                 
 
      wherein A 1 , A 2 , A 3 , L 1 , T, W 1 , R 4 , d and k are as defined above and E is halogen or a group —CHO, —C(═O)-alkyl or —C(═O)—O-alkyl. It will be understood that such intermediates may have to be protected by protecting groups for further processing, for example by protecting a keto function in ketal form.  
      The same preferred meanings as defined for the compounds of formula (I) under (2) to (29) apply to the intermediates of formulae (II) to (XXIX).  
      The reactions described hereinabove and hereinbelow are carried out in a manner known per se, for example in the absence or, where appropriate, in the presence of a suitable solvent or diluent or of a mixture thereof, the reactions being carried out, as required, with cooling, at room temperature or with heating, for example in a temperature range of approximately from −80° C. to the boiling temperature of the reaction mixture, preferably from approximately −20° C. to approximately +150° C., and, if necessary, in a closed vessel, under pressure, under an inert gas atmosphere and/or under anhydrous conditions. Especially advantageous reaction conditions can be found in the Examples.  
      A leaving group, for example the leaving groups L 1  and L 2  defined above, or a counterion is to be understood hereinabove and hereinbelow as being any removable group that customarily comes into consideration for chemical reactions, such as are known to the person skilled in the art; especially OH, halogens, such as fluorine, chlorine, bromine, iodine, —O—Si(C 1 -C 8 alkyl) 3 , —O-aryl, —S—(C 1 -C 8 alkyl), —S-aryl, —O—S(═O) 2 U, —S(═O)U or —S(═O) 2 U, wherein U is unsubstituted or substituted C 1 -C 8 alkyl, C 2 -C 8 alkenyl, C 2 -C 8 alkynyl, unsubstituted or substituted aryl or unsubstituted or substituted benzyl. Especially preferred as leaving group are chlorine, bromine, mesylate, triflate, tosylate, especially chlorine; and chloride or bromide, especially chloride.  
      Process (a): The reaction is carried out in acetic acid or a halogenated hydrocarbon, such as dichloromethane, at temperatures of from −20° C. to 100° C., preferably at from 20° C. to 50° C. As oxidising agents there are used, for example, hydrogen peroxide, a peracid, such as peracetic acid, trifluoroperacetic acid or 3-chloroperbenzoic acid, or a mixture thereof, such as sodium perborate in acetic acid.  
      Process (b): The reaction is preferably carried out in an alcohol, such as methanol, ethanol or an alcohol/water mixture, in the presence of an inorganic base, such as NaOH or KOH, and at temperatures of from 0° C. to 150° C., preferably from 20° C. to 80° C. Alternatively aminolysis with a primary amine, such as n-butylamine, can be carried out in a hydrocarbon, such as toluene or benzene, at temperatures of from 0° C. to 150° C., preferably at from 20° C. to 80° C.  
      Process (c): Depending upon the nature of the benzyl substituent to be removed, the reaction can be carried out, for example, under a hydrogen atmosphere, at a pressure of from 1 to 150 bar, especially at from 1 to 20 bar, and with the addition of a catalyst, such as palladium/carbon, in an alcohol or ether. The preferred reaction temperature is from 0° C. to 120° C., especially from 20° C. to 80° C.  
      Processes (d) and (g): The reactions are preferably carried out in the presence of a base, such as potassium or sodium carbonate, in acetone or dimethylformamide, at temperatures of from 0° C. to 150° C., preferably from 20° C. to 80° C. If necessary, catalytic amounts of potassium iodide or sodium iodide, or phase transfer catalysts, such as crown ethers or quaternary ammonium salts, are added.  
      Process (e): The reaction is preferably carried out in acetone, dichloromethane, acetic acid, or especially in water, optionally with the addition of a mineral acid, at temperatures of from 0° C. to 120° C., preferably at from 20° C. to 50° C. For complete cleavage of the acetal it is preferable to add a strong mineral acid, for example hydrochloric acid, sulfuric acid or 4-toluenesulfonic acid.  
      Process (f): For the preparation of the difluoro-, dichloro-, dibromo-, chlorofluoro- and bromofluoro-vinyl compounds, reaction with CCl 4 , CBr 4 , CF 2 X 2 , CFX 3 , CF 2 XC(═O)ONa or CFX 2 C(═O)ONa wherein X is bromine or chlorine is carried out in the presence of a trialkyl- or triaryl-phosphine, optionally with the addition of powdered zinc. The reaction is carried out in an inert solvent, for example benzene or toluene, or an ether, such as diethyl ether, diisopropyl ether, dioxane or tetrahydrofuran, at temperatures of from 0° C. to 150° C., preferably at from 20° C. to 80° C.  
      For the preparation of the dichlorovinyl compounds it is also possible for the process to be carried out in dimethylformamide, benzene, toluene, or in an ether, at temperatures of from 0° C. to 120° C., preferably at from 20° C. to 80° C., and in the presence of trichloroacetic acid/sodium trichloroacetate, then by addition of acetic anhydride, optionally with the addition of base, for example triethylamine, and finally by addition of zinc and acetic acid.  
      Processes (h) and (k): The reactions are preferably carried out in an ether, dimethylformamide, dimethylacetamide or N-methylpyrrolidone, at temperatures of from 0° C. to 150° C., preferably at from 20° C. to 80° C., with the addition of a base, such as potassium or sodium carbonate. Alternatively a coupling reagent, for example azodicarboxylic acid diethyl or diisopropyl ester and triphenylphosphine, can be used.  
      Processes (i) and (I):  
      Where L 2  is a group Hal-C(═O)—, the process can be carried out in an inert solvent, such as in an ether or in toluene, at from 0° C. to 80° C., and in the presence of a suitable base, for example a trialkylamine.  
      In the other cases the reaction is carried out in an ether, in an amide, such as dimethylformamide or N-methylpyrrolidone, and at from 0° C. to 150° C. Sodium hydride, for example, can be used as base.  
      Process (m 1 ):  
      The reaction is preferably carried out in a solvent, such as dioxane, dichloromethane, acetonitrile or toluene, at from 0 to 100° C., and in the presence of a base.  
      Process (m 2 ):  
      The reaction is preferably carried out in water or a chlorinated hydrocarbon and using a halogenating agent, such as chlorine, bromine, NaOCl or tert-butyl hypochlorite.  
      Process (n):  
      The reaction is preferably carried out in dimethylformamide, dimethylacetamide, N-methylpyrrolidone, dioxane, tetrahydrofuran, dimethoxyethane or acetonitrile at from 0 to 200° C., preferably at from 50 to 120° C.  
      Suitable catalysts are, for example, Pd(OAc) 2 , PdCl 2 , PdCl 2 (PPh 3 ) and Pd(PPh 3 ) 4 ; a phosphine, for example a triaryl- or trialkyl-phosphine, may be added where appropriate.  
      Especially preferred reaction conditions can be found in Example P2.1.  
      Process (o):  
      The reaction is preferably carried out in an amide, such as dimethylformamide, dimethylacetamide or N-methylpyrrolidone, in dioxane, dimethoxyethane, acetonitrile, tetrahydrofuran, using an alkyl halide at from 0° C. to 120° C., preferably at from 20° to 80° C.  
      Suitable bases are, for example, potassium carbonate, sodium carbonate and sodium hydride. A phase transfer catalyst, for example a tetraalkylammonium salt, is added where appropriate.  
      The process conditions can be found inter alia in Example P.3.  
      Process (p):  
      There is used as oxidising agent, for example, sodium bichromate or chromium trioxide in aqueous sulfuric acid, with a solvent such as acetone; at a working temperature of from 0° C. to about 60° C.; or with pyridinium dichromate in dichloromethane at −40° C. In an alternative procedure it is possible to use a mixture of dimethyl sulfoxide and oxalyl chloride, in dichloromethane as solvent and in the presence of a base, for example triethylamine, preferably at a working temperature of from −70° C. to +40° C.  
      Especially preferred reaction conditions can be found in Example P.4.  
      Process (g):  
      The process is preferably carried out in an alcohol, for example methanol, ethanol or isopropanol, in an amide, such as dimethylformamide, dimethylacetamide, N-methylpyrrolidone, in an ether, such as dioxane or dimethoxyethane, in pyridine or in acetonitrile; at from 0° to 120° C., preferably at from 20 to 80° C.  
      A base, for example potassium carbonate, sodium carbonate, sodium acetate, potassium acetate, triethylamine, ethyidiisopropylamine or sodium hydride, is preferably used.  
      Compounds of formula (I) wherein R 14  is hydrogen can be reacted further by alkylation with a compound R 14 -Hal, wherein R 14  is as defined above for formula (I), except for the meaning H, and Hal is a halogen atom. That reaction is preferably carried out in dimethylformamide, dimethylacetamide, N-methylpyrrolidone, dioxane, dimethoxyethane, acetonitrile, tetrahydrofuran with an alkyl halide at from 0 to 120° C., preferably at from 20 to 80° C.  
      A phase transfer catalyst, for example a tetraalkylammonium salt, is used where appropriate.  
      Especially preferred process conditions can be found in Example P.5.  
      Process (r):  
      The reaction is preferably carried out in toluene, tetrahydrofuran, dioxane, dimethoxyethane, dimethylformamide or dichloromethane at from −60 to 150° C., preferably at from 20° C. to 80° C., and in the presence of a base.  
      There is used as the base, for example, potassium tert-butoxide, sodium tert-butoxide, butyllithium, sodium hydride, lithium diisopropylamine, sodium methoxide or an organic base, such as triethylamine, ethyldiisopropylamine, 1,8-diazabicyclo[5.4.0]undec-7-ene, in the presence of lithium chloride or lithium bromide.  
      Especially preferred reaction conditions can be found in Example P.1.  
      Process (s):  
      The reaction is preferably carried out using compounds of formula (XX) wherein Hal is chlorine, bromine or iodine. Suitable solvents are amides, such as dimethylformamide, dimethylacetamide and N-methylpyrrolidone, ethers, for example dioxane or dimethoxyethane, or acetonitrile. The reaction is carried out at from 0° C. to 200° C., preferably at from 50° C. to 120° C.  
      The reaction is carried out with the use of a palladium catalyst, such as Pd(OAc) 2 , PdCl 2  or PdCl 2 (PPh 3 ), where appropriate in the presence of a triaryl- or trialkyl-phosphine, and of a base, such as triethylamine, lithium diisopropylamide, sodium carbonate, potassium carbonate, caesium carbonate or sodium hydride.  
      Process (t):  
      The reaction can be carried out on the one hand in an alcohol, for example methanol or ethanol, in dimethylformamide, N-methylpyrrolidone or tetrahydrofuran as solvent, in the presence of a base, for example diethylamine, diisopropylamine, piperidine, KOH, NaOH or sodium methoxide, at a temperature of from −70° C. to the boiling temperature of the solvent; on the other hand it can also be carried out, for example, in acetic acid at from 20° C. to 120° C. in the presence of ammonium acetate.  
      Process conditions can be found inter alia in Example P.6.  
      The invention relates especially to the preparation processes described in Examples P1 to P11.  
      Compounds of formula (I) obtainable in accordance with the process or by other means can be converted into other compounds of formula (I) in a manner known per se by replacement of one or more substituents in the starting compound of formula (I) in customary manner by another (other) substituent(s) according to the invention.  
      In the case of such replacement, depending upon the choice of reaction conditions and starting materials suitable therefor, it is possible for only one substituent to be replaced by another substituent according to the invention in a reaction step or for a plurality of substituents to be replaced by other substituents according to the invention in the same reaction step.  
      Salts of compounds of formula (I) can be prepared in a manner known per se. For example, salts of compounds of formula (I) with bases are obtained by treatment of the free compounds with a suitable base or with a suitable ion exchange reagent.  
      Salts of compounds of formula (I) can be converted into the free compounds of formula (I) in customary manner, for example by treatment with a suitable acid or with a suitable ion exchange reagent.  
      Salts of compounds of formula (I) can be converted in a manner known per se into other salts of a compound of formula (I).  
      The compounds of formula (I), in free form or in salt form, may be in the form of one of the possible isomers or in the form of a mixture thereof, for example, depending upon the number of asymmetric carbon atoms occurring in the molecule and their absolute and relative configuration, and/or depending upon the configuration of non-aromatic double bonds occurring in the molecule, in the form of pure isomers, such as antipodes and/or diastereoisomers, or in the form of mixtures of isomers, such as mixtures of enantiomers, for example racemates, mixtures of diastereoisomers or mixtures of racemates. The invention relates both to the pure isomers and to all possible mixtures of isomers and is to be interpreted as such hereinbefore and hereinafter, even if stereochemical details are not mentioned specifically in every case.  
      Mixtures of diastereoisomers, mixtures of racemates and mixtures of double bond isomers of compounds of formula (I), in free form or in salt form, which may be obtained in accordance with the process—depending upon the starting materials and procedures chosen—or by some other method, can be separated into the pure diastereoisomers or racemates in known manner on the basis of the physico-chemical differences between the constituents, for example by means of fractional crystallisation, distillation and/or chromatography.  
      Mixtures of enantiomers, such as racemates, that are obtainable in a corresponding manner can be resolyed into the enantiomers by known methods, for example by recrystallisation from an optically active solvent, by chromatography on chiral adsorbents, for example high pressure liquid chromatography (HPLC) on acetylcellulose, with the aid of suitable microorganisms, by cleavage with specific, immobilised enzymes, via the formation of inclusion compounds, for example using chiral crown ethers, only one enantiomer being complexed, or by conversion into diastereoisomeric salts and separation of the mixture of diastereoisomers so obtained, for example on the basis of their different solubilities by fractional crystallisation, into the diastereoisomers, from which the desired enantiomer can be freed by the action of suitable agents.  
      Apart from by separation of corresponding mixtures of isomers, pure diastereoisomers or enantiomers can be obtained according to the invention also by generally known methods of diastereoselective or enantioselective synthesis, for example by carrying out the process according to the invention using starting materials having correspondingly suitable stereochemistry.  
      In each case it is advantageous to isolate or synthesise the biologically more active isomer, e.g. enantiomer or diastereoisomer, or isomeric mixture, e.g. enantiomeric mixture or diastereolsomeric mixture, where the individual components have different biological activity.  
      The compounds of formula (I), in free form or in salt form, can also be obtained in the form of their hydrates and/or may include other solvents, for example solvents which may have been used for the crystallisation of compounds in solid form.  
      The invention relates to all those embodiments of the process according to which a compound obtainable as starting material or intermediate at any stage of the process is used as starting material and some or all of the remaining steps are carried out or a starting material is used in the form of a derivative or salt and/or its racemates or antipodes or, especially, is formed under the reaction conditions.  
      In the process of the present invention it is preferable to use those starting materials and intermediates, in each case in free form or in salt form, which result in the compounds of formula (I) and their salts described at the beginning as being especially valuable.  
      In the area of pest control, the compounds of formula (I) according to the invention are active ingredients exhibiting valuable preventive and/or curative activity with a very advantageous biocidal spectrum and a very broad spectrum, even at low rates of concentration, while being well tolerated by warm-blooded animals, fish and plants. They are, surprisingly, equally suitable for controlling both plant pests and ecto- and endo-parasites in humans and more especially in productive livestock, domestic animals and pets. They are effective against all or individual development stages of normally sensitive animal pests, but also of resistant animal pests, such as insects and representatives of the order Acarina, nematodes, cestodes and trematodes, while at the same time protecting useful organisms. The insecticidal or acaricidal activity of the active ingredients according to the invention may manifest itself directly, i.e. in the mortality of the pests, which occurs immediately or only after some time, for example during moulting, or indirectly, for example in reduced oviposition and/or hatching rate. Good activity corresponds to a mortality of at least 50 to 60%.  
      Successful control within the scope of the subject of the invention is possible, in particular, of pests from the orders Lepidoptera, Coleoptera, Orthoptera, Isoptera, Psocoptera, Anoplura, Mallophaga, Thysanoptera, Heteroptera, Homoptera, Hymenoptera, Diptera, Siphonaptera, Thysanura and Acarina, mainly Acarina, Diptera, Thysanoptera, Lepidoptera and Coleoptera. Very especially good control is possible of the following pests:  
       Abagrotis  spp.,  Abraxas  spp.,  Acantholeucania  spp.,  Acanthoplusia  spp.,  Acarus  spp.,  Acarus siro, Aceria  spp.,  Aceria sheldoni, Acleris  spp.,  Acoloithus  spp.,  Acompsia  spp.,  Acossus  spp.,  Acria  spp.,  Acrobasis  spp.,  Acrocercops  spp.,  Acrolepia  spp.,  Acrolepiopsis  spp.,  Acronicta  spp.,  Acropolitis  spp.,  Actebia  spp.,  Aculus  spp.,  Aculus schlechtendali, Adoxophyes  spp.,  Adoxophyes reticulana, Aedes  spp.,  Aegeria  spp.,  Aethes  spp.,  Agapeta  spp.,  Agonopterix  spp.,  Agriopis  spp.,  Agriotes  spp.,  Agriphila  spp.,  Agrochola  spp.,  Agroperina  spp.,  Alabama  spp.,  Alabama argillaceae, Agrotis  spp.,  Albuna  spp.,  Alcathoe  spp.,  Alcis  spp.,  Aleimma  spp.,  Aletia  spp.,  Aleurothrixus  spp.,  Aleurothrixus floccosus, Aleyrodes  spp.,  Aleyrodes brassicae, Allophyes  spp.,  Alsophila  spp.,  Amata  spp.,  Amathes  spp.,  Amblyomma  spp.,  Amblyptilia  spp.,  Ammoconia  spp.,  Amorbia  spp.,  Amphion  spp.,  Amphipoea  spp.,  Amphipyra  spp.,  Amyelois  spp.,  Anacamptodes  spp.,  Anagrapha  spp.,  Anarsia  spp.,  Anatrychyntis  spp.,  Anavitrinella  spp.,  Ancylis  spp.,  Andropolia  spp.,  Anhimella  spp.,  Antheraea  spp.,  Antherigona  spp.,  Antherigona soccata, Anthonomus  spp.,  Anthonomus grandis, Anticarsia  spp.,  Anticarsia gemmatalis, Aonidiella  spp.,  Apamea  spp.,  Aphania  spp.,  Aphelia  spp.,  Aphididae, Aphis  spp.,  Apotomis  spp.,  Aproaerema  spp.,  Archippus  spp.,  Archips  spp.,  Acromyrmex, Arctia  spp.,  Argas  spp.,  Argolamprotes  spp.,  Argyresthia  spp.,  Argyrogramma  spp.,  Argyroploce  spp.,  Argyrotaenia  spp.,  Arotrophora  spp.,  Ascotis  spp.,  Aspidiotus  spp.,  Aspilapteryx  spp.,  Asthenoptycha  spp.,  Aterpia  spp.,  Athetis  spp.,  Atomaria  spp.,  Atomaria linearis, Atta  spp.,  Atypha  spp.,  Autographa  spp.,  Axylia  spp.,  Bactra  spp.,  Barbara  spp.,  Batrachedra  spp.,  Battaristis  spp.,  Bembecia  spp.,  Bemisia  spp.,  Bemisia tabaci, Bibio  spp.,  Bibio hortulanis, Bisigna  spp.,  Blastesthia  spp.,  Blatta  spp.,  Blatella  spp.,  Blepharosis  spp.,  Bleptina  spp.,  Boarmia  spp.,  Bombyx  spp.,  Bomolocha  spp.,  Boophilus  spp.,  Brachmia  spp.,  Bradina  spp.,  Brevipalpus  spp.,  Brithys  spp.,  Bryobia  spp.,  Bryobia praetiosa, Bryotropha  spp.,  Bupalus  spp.,  Busseola  spp.,  Busseola fusca, Cabera  spp.,  Cacoecimorpha  spp.,  Cadra  spp.,  Cadra cautella, Caenurgina  spp.,  Calipitrimerus  spp.,  Callierges  spp.,  Callophpora  spp.,  Callophpora erythrocephala, Calophasia  spp.,  Caloptilia  spp.,  Calybites  spp.,  Capnoptycha  spp.,  Capua  spp.,  Caradrina  spp.,  Caripeta  spp.,  Carmenta  spp.,  Carposina  spp.,  Carposina nipponensis, Catamacta  spp.,  Catelaphris  spp.,  Catoptria  spp.,  Caustoloma  spp.,  Celaena  spp.,  Celypha  spp.,  Cenopis  spp.,  Cephus  spp.,  Ceramica  spp.,  Cerapteryx  spp.,  Ceratitis spp, Ceratophyllus  spp.,  Ceroplaster  spp.,  Chaetocnema  spp.,  Chaetocnema tibialis, Chamaesphecia  spp.,  Charanvca  spp.,  Cheimophila  spp.,  Chersotis  spp.,  Chiasmia  spp.,  Chilo  spp.,  Chionodes  spp.,  Chorioptes  spp.,  Choristoneura  spp.,  Chrysaspidia  spp.,  Chrysodeixis  spp.,  Chrysomya  spp.,  Chrysomphalus  spp.,  Chrysomphalus dictyospermi, Chrysomphalus aonidium, Chrysoteuchia  spp.,  Cilix  spp.,  Cimex  spp.,  Clysia  spp.,  Clysia ambiguella, Clepsis  spp.,  Cnaemidophorus  spp.,  Cnaphalocrocis  spp.,  Cnephasia  spp.,  Coccus  spp.,  Coccus hesperidum, Cochylis  spp.,  Coleophora  spp.,  Colotois  spp.,  Commophila  spp.,  Conistra  spp.,  Conopomorpha  spp.,  Corcyra  spp.,  Cornutiplusia  spp.,  Cosmia  spp.,  Cosmopolites  spp.,  Cosmopterix  spp.,  Cossus  spp.,  Costaeonvexa  spp.,  Crambus  spp.,  Creatonotos  spp.,  Crocidolomia  spp.,  Crocidolomia binotalis, Croesia  spp.,  Crymodes  spp.,  Cryptaspasma  spp.,  Cryptoblabes  spp.,  Cryptocala  spp.,  Cryptophlebia  spp.,  Cryptophlebia leucotreta, Cryptoptila  spp.,  Ctenopseustis  spp.,  Ctenocephalides  spp.,  Cucullia  spp.,  Curculio  spp.,  Culex  spp.,  Cuterebra  spp.,  Cydia  spp.,  Cydia pomonella, Cymbalophora  spp.,  Dactylethra  spp.,  Dacus  spp.,  Dadica  spp.,  Damalinea  spp.,  Dasychira  spp.,  Decadarchis  spp.,  Decodes  spp.,  Deilephila  spp.,  Deltodes  spp.,  Dendrolimus  spp.,  Depressaria  spp.,  Dermestes  spp.,  Dermanyssus  spp.,  Dermanyssus gallinae, Diabrotica  spp.,  Diachrysia  spp.,  Diaphania  spp.,  Diarsia  spp.,  Diasemia  spp.,  Diatraea  spp.,  Diceratura  spp.,  Dichomeris  spp.,  Dichrocrocis  spp.,  Dichrorampha  spp.,  Dicycla  spp.,  Dioryctria  spp.,  Diparopsis  spp.,  Diparopsis castanea, Dipleurina  spp.,  Diprion  spp.,  Diprionidae, Discestra  spp.,  Distantiella  spp.,  Distantiella theobroma, Ditula  spp.,  Diurnea  spp.,  Doratopteryx  spp.,  Drepana  spp.,  Drosphila  spp.,  Drosphila melanogaster, Dysauxes  spp.,  Dysdercus  spp.,  Dysstroma  spp.,  Eana  spp.,  Earias  spp.,  Ecclitica  spp.,  Ecdytolopha  spp.,  Ecpyrrhorrhoe  spp.,  Ectomyelois  spp.,  Eetropis  spp.,  Egira  spp.,  Elasmopalpus  spp.,  Emmelia  spp.,  mpoasca  spp.,  Empyreuma  spp.,  Enargia  spp.,  Enarmonia  spp.,  Endopiza  spp.,  Endothenia  spp.,  Endotricha  spp.,  Eoreuma  spp.,  Eotetranychus  spp.,  Eotetranychus carpini, Epagoge  spp.,  Epelis  spp.,  Ephestia  spp.,  Ephestiodes  spp.,  Epiblema  spp.,  Epiehoristodes  spp.,  Epinotia  spp.,  Epiphyas  spp.,  Epiplema  spp.,  Epipsestis  spp.,  Epirrhoe  spp.,  Episimus  spp.,  Epitymbia  spp.,  Epilachna  spp.,  Erannis  spp.,  Erastria  spp.,  Eremnus  spp.,  Ereunetis  spp.,  Eriophyes  spp.,  Eriosoma  spp.,  Eriosoma lanigerum, Erythroneura  spp.,  Estigmene  spp.,  Ethmia  spp.,  Etiella  spp.,  Euagrotis  spp.,  Eucosma  spp.,  Euehlaena  spp.,  Euelidia  spp.,  Eueosma  spp.,  Euchistus  spp.,  Eucosmomorpha  spp.,  Eudonia  spp.,  Eufidonia  spp.,  Euhyponomeutoides  spp.,  Eulepitodes  spp.,  Eulia  spp.,  Eulithis  spp.,  Eupithecia  spp.,  Euplexia  spp.,  Eupoecilia  spp.,  Eupoecilia ambiguella, Euproctis  spp.,  Eupsilia  spp.,  Eurhodope  spp.,  Eurois  spp.,  Eurygaster  spp.,  Eurythmia  spp.,  Eustrotia  spp.,  Euxoa  spp.,  Euzophera  spp.,  Evergestis  spp.,  Evippe  spp.,  Exartema  spp.,  Fannia  spp.,  Faronta  spp.,  Feltia  spp.,  Filatima  spp.,  Fishia  spp.,  Frankliniella  spp.,  Fumibotys  spp.,  Gaesa  spp.,  Gasgardia  spp.,  Gastrophilus  spp.,  Gelechia  spp.,  Gilpinia  spp.,  Gilpinia polytoma, Glossina  spp.,  Glyphipterix  spp.,  Glyphodes  spp.,  Gnorimoschemini  spp.,  Gonodonta  spp.,  Gortyna  spp.,  Gracillaria  spp.,  Graphania  spp.,  Grapholita  spp.,  Grapholitha  spp.,  Gravitarmata  spp.,  Gretchena  spp.,  Griselda  spp.,  Gryllotalpa  spp.,  Gynaephora  spp.,  Gypsonoma  spp.,  Hada  spp.,  Haematopinus  spp.,  Halisidota  spp.,  Harpipteryx  spp.,  Harrisina  spp.,  Hedya  spp.,  Helicoverpa  spp.,  Heliophobus  spp.,  Heliothis  spp.,  Hellula  spp.,  Helotropa  spp.,  Hemaris  spp.,  Hercinothrips  spp.,  Herculia  spp.,  Hermonassa  spp.,  Heterogenea  spp.,  Holomelina  spp.,  Homadaula  spp.,  Homoeosoma  spp.,  Homoglaea  spp.,  Homohadena  spp.,  Homona  spp.,  Homonopsis  spp.,  Hoplocampa  spp.,  Hoplodrina  spp.,  Hoshinoa  spp.,  Hxalomma  spp.,  Hydraecia  spp.,  Hydriomena  spp.,  Hyles  spp.,  Hyloicus  spp.,  Hypagyrtis  spp.,  Hypatima  spp.,  Hyphantria  spp.,  Hyphantria cunea, Hypocala  spp.,  Hypocoena  spp.,  Hypodema  spp.,  Hyppobosca  spp.,  Hypsipyla  spp.,  Hyssia  spp.,  Hysterosia  spp.,  Idaea  spp.,  Idia  spp.,  Ipimorpha  spp.,  Isia  spp.,  Isochorista  spp.,  Isophrictis  spp.,  Isopolia  spp.,  Isotrias  spp.,  Ixodes  spp.,  Itame  spp.,  Jodia  spp.,  Jodis  spp.,  Kawabea  spp.,  Keiferia  spp.,  Keiferia lycopersicella, Labdia  spp.,  Lacinipolia  spp.,  Lambdina  spp.,  Lamprothritpa  spp.,  Laodelphax  spp.,  Lasius  spp.,  Laspeyresia  spp.,  Leptinotarsa  spp.,  Leptinotarsa decemlineata, Leptocorisa  spp.,  Leptostales  spp.,  Lecanium  spp.,  Lecanium comi, Lepidosaphes  spp.,  Lepisma  spp.,  Lepisma saccharina, Lesmone  spp.,  Leucania  spp.,  Leucinodes  spp.,  Leucophaea  spp.,  Leucophaea maderae, Leucoptera  spp.,  Leucoptera scitella, Linognathus  spp.,  Liposcelis  spp.,  Lissorhoptrus  spp.,  Lithacodia  spp.,  Lithocolletis  spp.,  Lithomoia  spp.,  Lithophane  spp.,  Lixodessa  spp.,  Lobesia  spp.,  Lobesia botrana, Lobophora  spp.,  Locusta  spp.,  Lomanaltes  spp.,  Lomographa  spp.,  Loxagrotis  spp.,  Loxostege  spp.,  Lucilia  spp.,  Lymantria  spp.,  Lymnaecia  spp.,  Lyonetia  spp.,  Lyriomyza  spp.,  Macdonnoughia  spp.,  Macrauzata  spp.,  Macronoctua  spp.,  Macrosiphus  spp.,  Malacosoma  spp.,  Maliarpha  spp.,  Mamestra  spp.,  Mamestra brassicae, Manduca  spp.,  Manduca sexta, Marasmia  spp.,  Margaritia  spp.,  Matratinea  spp.,  Matsumuraeses  spp.,  Melanagromyza  spp.,  Melipotes  spp.,  Melissopus  spp.,  Melittia  spp.,  Melolontha  spp.,  Meristis  spp.,  Meritastis  spp.,  Merophyas  spp.,  Mesapamea  spp.,  Mesogona  spp.,  Mesoleuca  spp.,  Metanema  spp.,  Metendothenia  spp.,  Metzneria  spp.,  Micardia  spp.,  Microcorses  spp.,  Microleon  spp.,  Mnesictena  spp.,  Mocis  spp.,  Monima  spp.,  Monochroa  spp.,  Monomorium  spp.,  Monomorium pharaonis, Monopsis  spp.,  Morrisonia  spp.,  Musca  spp.,  Mutuuraia  spp.,  Myelois  spp.,  Mythimna  spp.,  Myzus  spp.,  Naranga  spp.,  Nedra  spp.,  Nemapogon  spp.,  Neodiprion  spp.,  Neosphaleroptera  spp.,  Nephelodes  spp.,  Nephotettix  spp.,  Nezara  spp.,  Nilaparvata  spp.,  Niphonympha  spp.,  Nippoptilia  spp.,  Noctua  spp.,  Nola  spp.,  Notocelia  spp.,  Notodonta  spp.,  Nudaurelia  spp.,  Ochropleura  spp.,  Ocnerostoma  spp.,  Oestrus  spp.,  Olethreutes  spp.,  Oligia  spp.,  Olindia  spp.,  Olygonychus  spp.,  Olygonychus gallinae, Oncocnemis  spp.,  Operophtera  spp.,  Ophisma  spp.,  Opogona  spp.,  Oraesia  spp.,  Omiodoros  spp.,  Orgyia  spp.,  Oria  spp.,  Orseolia  spp.,  Orthodes  spp.,  Orthogonia  spp.,  Orthosia  spp.,  Oryzaephilus  spp.,  Oscinella  spp.,  Oscinella frit, Osminia  spp.,  Ostrinia  spp.,  Ostrinia nubilalis, Otiorhynchus  spp.,  Ourapteryx  spp.,  Pachetra  spp.,  Pachysphinx  spp.,  Pagyda  spp.,  Paleacrita  spp.,  Paliga  spp.,  Palthis  spp.,  Pammene  spp.,  Pandemis  spp.,  Panemeria  spp.,  Panolis  spp.,  Panolis flammea, Panonychus  spp.,  Parargyresthia  spp.,  Paradiarsia  spp.,  Paralobesia  spp.,  Paranthrene  spp.,  Parapandemis  spp.,  Parapediasia  spp.,  Parastichtis  spp.,  Parasyndemis  spp.,  Paratoria  spp.,  Pareromeme  spp.,  Pectinophora  spp.,  Pectinophora gossypiella, Pediculus  spp.,  Pegomyia  spp.,  Pegomyia hyoscyami, Pelochrista  spp.,  Pennisetia  spp.,  Penstemonia  spp.,  Pemphigus  spp.,  Peribatodes  spp.,  Peridroma  spp.,  Perileucoptera  spp.,  Periplaneta  spp.,  Perizoma  spp.,  Petrova  spp.,  Pexicopia  spp.,  Phalonia  spp.,  Phalonidia  spp.,  Phaneta  spp.,  Phlyctaenia  spp.,  Phlyotinus  spp.,  Phorbia  spp.,  Phragmatobia  spp.,  Phricanthes  spp.,  Phthorimaea  spp.,  Phthorimaea operculella, Phyllocnistis  spp.,  Phyllocoptruta  spp.,  Phyllocoptruta oleivora, Phyllonorycter  spp.,  Phyllophila  spp.,  Phylloxera  spp.,  Pieris  spp.,  Pieris rapae, Piesma  spp.,  Planococus  spp.,  Planotortrix  spp.,  Platyedra  spp.,  Platynota  spp.,  Platyptilia  spp.,  Platysenta  spp.,  Plodia  spp.,  Plusia  spp.,  Plutella  spp.,  Plutella xylostella, Podosesia  spp.,  Polia  spp.,  Popillia  spp.,  Polymixis  spp.,  Polyphagotarsonemus  spp.,  Polyphagotarsonemus latus, Prays  spp.,  Prionoxystus  spp.,  Probole  spp.,  Proceras  spp.,  Prochoerodes  spp.,  Proeulia  spp.,  Proschistis  spp.,  Proselena  spp.,  Proserpinus  spp.,  Protagrotis  spp.,  Proteoteras  spp.,  Protobathra  spp.,  Protoschinia  spp.,  Pselnophorus  spp.,  Pseudaletia  spp.,  Pseudanthonomus  spp.,  Pseudaternelia  spp.,  Pseudaulacaspis  spp.,  Pseudexentera  spp.,  Pseudococus  spp.,  Pseudohermenias  spp.,  Pseudoplusia  spp.,  Psoroptes  spp.,  Psylla  spp.,  Psylliodes  spp.,  Pterophoru.s  spp.,  Ptycholoma  spp.,  Pulyinaria  spp.,  Pulyinaria aethiopica, Pyralis  spp.,  Pyrausta  spp.,  Pyrgotis  spp.,  Pyrreferra  spp.,  Pyrrharctia  spp.,  Quadraspidiotus  spp.,  Rancora  spp.,  Raphia  spp.,  Reticultermes  spp.,  Retinia  spp.,  Rhagoletis  spp.,  Rhagoletis pomonella, Rhipicephalus  spp.,  Rhizoglyphus  spp.,  Rhizopertha  spp.,  Rhodnius  spp.,  Rhophalosiphum  spp.,  Rhopobota  spp.,  Rhyacia  spp.,  Rhyacionia  spp.,  Rhynchopacha  spp.,  Rhyzosthenes  spp.,  Rivula  spp.,  Rondotia  spp.,  Rusidrina  spp.,  Rynchaglaea  spp.,  Sabulodes  spp.,  Sahlbergella  spp.,  Sahlbergella singularis, Saissetia  spp.,  Samia  spp.,  Sannina  spp.,  Sanninoidea  spp.,  Saphoideus  spp.,  Sarcoptes  spp.,  Sathrobrota  spp.,  Scarabeidae, Sceliodes  spp.,  Schinia  spp.,  Schistocerca  spp.,  Schizaphis  spp.,  Schizura  spp.,  Schreckensteinia  spp.,  Sciara  spp.,  Scirpophaga  spp.,  Scirthrips auranti, Scoparia  spp.,  Scopula  spp.,  Scotia  spp.,  Scotinophara  spp.,  Scotogramma  spp.,  Scrobipalpa  spp.,  Scrobipalpopsis  spp.,  Semiothisa  spp.,  Sereda  spp.,  Sesamia  spp.,  Sesia  spp.,  Sicya  spp.,  Sideridis  spp.,  Simyra  spp.,  Sineugraphe  spp.,  Sitochroa  spp.,  Sitobion  spp.,  Sitophilus  spp.,  Sitotroga  spp.,  Solenopsis  spp.,  Smerinthus  spp.,  Sophronia  spp.,  Spaelotis  spp.,  Spargaloma  spp.,  Sparganothis  spp.,  Spatalistis  spp.,  Sperchia  spp.,  Sphecia  spp.,  Sphinx  spp.,  Spilonota  spp.,  Spodoptera  spp.,  Spodoptera littoralis, Stagmatophora  spp.,  Staphylinochrous  spp.,  Stathmopoda  spp.,  Stenodes  spp.,  Sterrha  spp.,  Stomoxys  spp.,  Strophedra  spp.,  Sunira  spp.,  Sutyna  spp.,  Swammerdamia  spp.,  Syllomatia  spp.,  Sympistis  spp.,  Synanthedon  spp.,  Synaxis  spp.,  Syncopacma  spp.,  Syndemis  spp.,  Syngrapha  spp.,  Synthomeida  spp.,  Tabanus  spp.,  Taeniarchis  spp.,  Taeniothrips  spp.,  Tannia  spp.,  Tarsonemus  spp.,  Tegulifera  spp.,  Tehama  spp.,  Teleiodes  spp.,  Telorta  spp.,  Tenebrio  spp.,  Tephrina  spp.,  Teratoglaea  spp.,  Terricula  spp.,  Tethea  spp.,  Tetranychus  spp.,  Thalpophila  spp.,  Thaumetopoea  spp.,  Thiodia  spp.,  Thrips  spp.,  Thrips palmi, Thrips tabaci, Thyridopteryx  spp.,  Thyris  spp.,  Tineola  spp.,  Tipula  spp.,  Tortricidia  spp.,  Tortrix  spp.,  Trachea  spp.,  Trialeurodes  spp.,  Trialeurodes vaporariorum, Triatoma  spp.,  Triaxomeraspp, Tribolium  spp.,  Tricodectes  spp.,  Trichoplusia  spp.,  Trichoplusia ni, Trichoptilus  spp.,  Trioza  spp.,  Trioza erytreae, Triphaenia  spp.,  Triphosa  spp.,  Trogoderma  spp.,  Tyria  spp.,  Udea  spp.,  Unaspis  spp.,  Unaspis citri, Utetheisa  spp.,  Valeriodes  spp.,  Vespa  spp.,  Vespamima  spp.,  Vitacea  spp.,  Vitula  spp.,  Witlesia  spp.,  Xanthia  spp.,  Xanthorhoe  spp.,  Xanthotype  spp.,  Xenomicta  spp.,  Xenopsylla  spp.,  Xenopsylla cheopsis, Xestia  spp.,  Xylena  spp.,  Xylomyges  spp.,  Xyrosaris  spp.,  Yponomeuta  spp.,  Ypsolopha  spp.,  Zale  spp.,  Zanclognathus  spp.,  Zeiraphera  spp.,  Zenodoxus  spp.,  Zeuzera  spp.,  Zygaena  spp.,  
      It is also possible to control pests of the class Nematoda using the compounds according to the invention. Such pests include, for example,  
      root knot nematodes, cyst-forming nematodes and also stem and leaf nematodes;  
      especially of  Heterodera  spp., e.g.  Heterodera schachtii, Heterodora avenae  and  Heterodora trifolii; Globodera  spp., e.g.  Globodera rostochiensis; Meloidogyne  spp., e.g.  Meloidogyne incognita  and  Meloidogyne javanica; Radopholus  spp., e.g.  Radopholus similis; Pratylenchus,  e.g.  Pratylenchus neglectans  and  Pratylenchus penetrans; Tylenchulus,  e.g.  Tylenchulus semipenetrans; Longidorus, Trichodorus, Xiphinema, Ditylenchus, Apheenchoides  and  Anguina;  especially  Meloidogyne,  e.g.  Meloidogyne incognita,  and  Heterodera,  e.g.  Heterodera glycines.    
      An especially important aspect of the present invention is the use of the compounds of formula (I) according to the invention in the protection of plants against parasitic feeding pests.  
      The action of the compounds according to the invention and the compositions comprising them against animal pests can be significantly broadened and adapted to the given circumstances by the addition of other insecticides, acaricides or nematicides. Suitable additives include, for example, representatives of the following classes of active ingredient: organophosphorus compounds, nitrophenols and derivatives, formamidines, ureas, carbamates, pyrethroids, chlorinated hydrocarbons, neonicotinoids and  Bacillus thuringiensis  preparations.  
      Examples of especially suitable mixing partners include: azamethiphos; chlorfenvinphos; cypermethrin, cypermethrin high-cis; cyromazine; diafenthiuron; diazinon; dichlorvos; dicrotophos; dicyclanil; fenoxycarb; fluazuron; furathiocarb; isazofos; iodfenphos; kinoprene; lufenuron; methacriphos; methidathion; monocrotophos; phosphamidon; profenofos; diofenolan; a compound obtainable from the  Bacillus thuringiensis  strain GC91 or from strain NCTC 11821;  pymetrozine; bromopropylate; methoprene; disulfoton; quinalphos; taufluvalinate; thiocyclam; thiometon; aldicarb; azinphos-methyl; benfuracarb; bifenthrin; buprofezin; carbofuran; dibutylaminothio; cartap; chlorfluazuron; chlorpyrifos; clothianidin; cyfluthrin; lambda-cyhalothrin; alpha-cypermethrin; zeta-cypermethrin; deltamethrin; diflubenzuron; endosulfan; ethiofencarb; fenitrothion; fenobucarb; fenvalerate; formothion; methiocarb; heptenophos; imidacloprid; isoprocarb; methamidophos; methomyl; mevinphos; parathion; parathion-methyl; phosalone; pirimicarb; propoxur; teflubenzuron; terbufos; triazamate; fenobucarb; tebufenozide; fipronil; beta-cyfluthrin; silafluofen; fenpyroximate; pyridaben; pyridalyl; fenazaquin; pyriproxyfen; pyrimidifen; nitenpyram; acetamiprid; emamectin; emamectin-benzoate; spinosad; a plant extract that is active against insects; a preparation that comprises nematodes and is active against insects; a preparation obtainable from Bacillus subtilis; a preparation that comprises fungi and is active against insects; a preparation that comprises viruses and is active against insects; chlorfenapyr; acephate; acrinathrin; alanycarb; alphamethrin; amitraz; AZ 60541; azinphos A; azinphos M; azocyclotin; bendiocarb; bensultap; beta-cyfluthrin; brofenprox; bromophos A; bufencarb; butocarboxin; butylpyridaben; cadusafos; carbaryl; carbophenothion; chloethocarb; chlorethoxyfos; chlormephos; cis-resmethrin; clocythrin; clofentezine; cyanophos; cycloprothrin; cyhexatin; demeton M; demeton S; demeton-S-methyl; dichlofenthion; dicliphos; diethion; dimethoate; dimethylyinphos; dioxathion; edifenphos; esfenvalerate; ethion; ethofenprox; ethoprophos; etrimphos; fenamiphos; fenbutatin oxide; fenothiocarb; fenpropathrin; fenpyrad; fenthion; fluazinam; flucycloxuron; flucythrinate; flufenoxuron; flufenprox; fonophos; fosthiazate; fubfenprox; HCH; hexaflumuron; hexythiazox; flonicamid; iprobenfos; isofenphos; isoxathion; ivermectin; malathion; mecarbam; mesulfenphos; metaldehyde; metolcarb; milbemectin; moxidectin; naled; NC 184; nithiazine; omethoate; oxamyl; oxydemethon M; oxydeprofos; permethrin; phenthoate; phorate; phosmet; phoxim; pirimiphos M; pirimiphos E; promecarb; propaphos; prothiofos; prothoate; pyrachlophos; pyradaphenthion; pyresmethrin; pyrethrum; tebufenozide; salithion; sebufos; sulfotep; sulprofos; tebufenpyrad; tebupirimphos; tefluthrin; temephos; terbam; tetrachlorvinphos; thiacloprid; thiafenox; thiamethoxam; thiodicarb; thiofanox; thionazin; thuringiensin; tralomethrin; triarathene; triazophos; triazuron; trichlorfon; triflumuron; trimethacarb; vamidothion; xylylcarb; etoxazole; zetamethrin; indoxacarb; methoxyfenozide; bifenazate; XMC (3,5-xylyl methylcarbamate); or the fungus pathogen Metarhizium anisopliae.  
      The compounds according to the invention can be used to control, i.e. to inhibit or destroy, pests of the mentioned type occurring on plants, especially on useful plants and ornamentals in agriculture, in horticulture and in forestry, or on parts of such plants, such as the fruits, blossoms, leaves, stems, tubers or roots, while in some cases plant parts that grow later are still protected against those pests.  
      Target crops include especially cereals, such as wheat, barley, rye, oats, rice, maize and sorghum; beet, such as sugar beet and fodder beet; fruit, e.g. pomes, stone fruit and soft fruit, such as apples, pears, plums, peaches, almonds, cherries and berries, e.g. strawberries, raspberries and blackberries; leguminous plants, such as beans, lentils, peas and soybeans; oil plants, such as rape, mustard, poppy, olives, sunflowers, coconut, castor oil, cocoa and groundnuts; cucurbitaceae, such as marrows, cucumbers and melons; fibre plants, such as cotton, flax, hemp and jute; citrus fruits, such as oranges, lemons, grapefruit and mandarins; vegetables, such as spinach, lettuce, asparagus, cabbages, carrots, onions, tomatoes, potatoes and paprika; lauraceae, such as avocado, cinnamon and camphor; and tobacco, nuts, coffee, aubergines, sugar cane, tea, pepper, vines, hops, bananas, natural rubber plants and ornamentals.  
      Further areas of use of the compounds according to the invention are the protection of stored goods and storerooms and the protection of raw materials, and also in the hygiene sector, especially the protection of domestic animals and productive livestock against pests of the mentioned type, more especially the protection of domestic animals, especially cats and dogs, from infestation by fleas, ticks and nematodes.  
      The invention therefore relates also to pesticidal compositions, such as emulsifiable concentrates, suspension concentrates, directly sprayable or dilutable solutions, spreadable pastes, dilute emulsions, wettable powders, soluble powders, dispersible powders, wettable powders, dusts, granules and encapsulations of polymer substances, that comprise at least one of the compounds according to the invention, the choice of formulation being made in accordance with the intended objectives and the prevailing circumstances.  
      The active ingredient is used in those compositions in pure form, a solid active ingredient, for example, in a specific particle size, or preferably together with at least one of the adjuvants customary in formulation technology, such as extenders, e.g. solvents or solid carriers, or surface-active compounds (surfactants). In the area of parasite control in humans, domestic animals, productive livestock and pets it will be self-evident that only physiologically tolerable additives are used.  
      Solvents are, for example: non-hydrogenated or partly hydrogenated aromatic hydrocarbons, preferably fractions C 8  to C 12  of alkylbenzenes, such as xylene mixtures, alkylated naphthalenes or tetrahydronaphthalene, aliphatic or cycloaliphatic hydrocarbons, such as paraffins or cyclohexane, alcohols, such as ethanol, propanol or butanol, glycols and ethers and esters thereof, such as propylene glycol, dipropylene glycol ether, ethylene glycol or ethylene glycol monomethyl or -ethyl ether, ketones, such as cyclohexanone, isophorone or diacetone alcohol, strongly polar solvents, such as N-methylpyrrolid-2-one, dimethyl sulfoxide or N,N-dimethylformamide, water, non-epoxidized or epoxidized plant oils, such as non-epoxidized or epoxidized rapeseed, castor, coconut or soya oil, and silicone oils.  
      The solid carriers used, for example for dusts and dispersible powders, are as a rule natural rock powders, such as calcite, talc, kaolin, montmorillonite or attapulgite. Highly disperse silicic acids or highly disperse absorbent polymers can also be added to improve the physical properties. Granular adsorptive granule carriers are porous types, such as pumice, crushed brick, sepiolite or bentonite, and non-sorbent carrier materials are calcite or sand. A large number of granular materials of inorganic or organic nature can furthermore be used, in particular dolomite or comminuted plant residues.  
      Surface-active compounds are, depending on the nature of the active compound to be formulated, nonionic, cationic and/or anionic surfactants or surfactant mixtures with good emulsifying, dispersing and wetting properties. The surfactants listed below are to be regarded only as examples; many other surfactants which are customary in formulation technology and are suitable according to the invention are described in the relevant literature.  
      Nonionic surfactants are, in particular, polyglycol ether derivatives of aliphatic or cycloaliphatic alcohols, saturated or unsaturated fatty acids and alkylphenols, which can contain 3 to 30 glycol ether groups and 8 to 20 carbon atoms in the (aliphatic) hydrocarbon radical and 6 to 18 carbon atoms in the alkyl radical of the alkylphenols. Substances which are furthermore suitable are water-soluble polyethylene oxide adducts, containing 20 to 250 ethylene glycol ether and 10 to 100 propylene glycol ether groups, on propylene glycol, ethylene diaminopolypropylene glycol and alkyl polypropylene glycol having 1 to 10 carbon atoms in the alkyl chain. The compounds mentioned usually contain 1 to 5 ethylene glycol units per propylene glycol unit. Examples are nonylphenol-polyethoxyethanols, castor oil polyglycol ethers, polypropylene-polyethylene oxide adducts, tributylphenoxypolyethoxyethanol, polyethylene glycol and octylphenoxypolyethoxyethanol. Other substances are fatty acid esters of polyoxyethylene sorbitan, such as polyoxyethylene sorbitan trioleate.  
      The cationic surfactants are, in particular, quaternary ammonium salts which contain, as substituents, at least one alkyl radical having 8 to 22 C atoms and, as further substituents, lower, non-halogenated or halogenated alkyl, benzyl or lower hydroxyalkyl radicals. The salts are preferably in the form of halides, methyl-sulfates or ethyl-sulfates. Examples are stearyl-trimethyl-ammonium chloride and benzyl-di-(2-chloroethyl)-ethyl-ammonium bromide.  
      Suitable anionic surfactants can be both water-soluble soaps and water-soluble synthetic surface-active compounds. Suitable soaps are the alkali metal, alkaline earth metal and substituted or unsubstituted ammonium salts of higher fatty acids (C 10 -C 22 ), such as the sodium or potassium salts of oleic or stearic acid, or of naturally occurring fatty acid mixtures, which can be obtained, for example, from coconut oil or tall oil; and furthermore also the fatty acid methyl-taurine salts. However, synthetic surfactants are more frequently used, in particular fatty sulfonates, fatty sulfates, sulfonated benzimidazole derivatives or alkylarylsulfonates. The fatty sulfonates and sulfates are as a rule in the form of alkali metal, alkaline earth metal or substituted or unsubstituted ammonium salts and in general have an alkyl radical of 8 to 22 C atoms, alkyl also including the alkyl moiety of acyl radicals; examples are the sodium or calcium salt of ligninsulfonic acid, of dodecylsulfuric acid ester or of a fatty alcohol sulfate mixture prepared from naturally occurring fatty acids. These also include the salts of sulfuric acid esters and sulfonic acids of fatty alcohol-ethylene oxide adducts. The sulfonated benzimidazole derivatives preferably contain 2 sulfonic acid groups and a fatty acid radical having about 8 to 22 C atoms. Alkylarylsulfonates are, for example, the sodium, calcium or triethanolammonium salts of dodecylbenzenesulfonic acid, of dibutylnaphthalenesulfonic acid or of a naphthalenesulfonic acid-formaldehyde condensation product. Corresponding phosphates, such as salts of the phosphoric acid ester of a p-nonylphenol-(4-14)-ethylene oxide adduct or phospholipids, can further also be used.  
      The compositions as a rule comprise 0.1 to 99%, in particular 0.1 to 95%, of active compound and 1 to 99.9%, in particular 5 to 99.9%, of—at least—one solid or liquid auxiliary, it being possible as a rule for 0 to 25%, in particular 0.1 to 20%, of the composition to be surfactants (% is in each case per cent by weight). While concentrated compositions are more preferred as commercial goods, the end user as a rule uses dilute compositions which comprise considerably lower concentrations of active compound. Preferred compositions are composed, in particular, as follows (%=per cent by weight):  
                               Emulsifiable concentrates:                                                active ingredient:   1 to 90%, preferably 5 to 20%           surfactant:   1 to 30%, preferably 10 to 20%           solvent:   5 to 98%, preferably 70 to 85%                      
 
     
       
         
           
               
             
               
                   
               
               
                   
               
               
                 Dusts: 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
            
               
                   
                 active ingredient: 
                  0.1 to 10%, preferably 0.1 to 1% 
               
               
                   
                 solid carrier: 
                 99.9 to 90%, preferably 99.9 to 99% 
               
               
                   
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                   
               
               
                   
               
               
                 Suspension concentrates: 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
            
               
                   
                 active ingredient: 
                  5 to 75%, preferably 10 to 50% 
               
               
                   
                 water: 
                 94 to 24%, preferably 88 to 30% 
               
               
                   
                 surfactant: 
                  1 to 40%, preferably 2 to 30% 
               
               
                   
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                   
               
               
                   
               
               
                 Wettable powders: 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
            
               
                   
                 active ingredient: 
                 0.5 to 90%, preferably 1 to 80% 
               
               
                   
                 surfactant: 
                 0.5 to 20%, preferably 1 to 15% 
               
               
                   
                 solid carrier: 
                   5 to 99%, preferably 15 to 98% 
               
               
                   
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                   
               
               
                   
               
               
                 Granules: 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
            
               
                   
                 active ingredient: 
                  0.5 to 30%, preferably 3 to 15% 
               
               
                   
                 solid carrier: 
                 99.5 to 70%, preferably 97 to 85% 
               
               
                   
                   
               
            
           
         
       
     
      The compositions according to the invention may also comprise further solid or liquid adjuvants, such as stabilisers, e.g. vegetable oils or epoxidised vegetable oils (e.g. epoxidised coconut oil, rapeseed oil or soybean oil), antifoams, e.g. silicone oil, preservatives, viscosity regulators, binders and/or tackifiers as well as fertilisers or other active ingredients for obtaining special effects, e.g. acaricides, bactericides, fungicides, nematicides, molluscicides or selective herbicides.  
      The crop protection products according to the invention are prepared in known manner, in the absence of adjuvants, e.g. by grinding, sieving and/or compressing a solid active ingredient or mixture of active ingredients, for example to a certain particle size, and in the presence of at least one adjuvant, for example by intimately mixing and/or grinding the active ingredient or mixture of active ingredients with the adjuvant(s). The invention relates likewise to those processes for the preparation of the compositions according to the invention and to the use of the compounds of formula (I) in the preparation of those compositions.  
      The invention relates also to the methods of application of the crop protection products, i.e. the methods of controlling pests of the mentioned type, such as spraying, atomising, dusting, coating, dressing, scattering or pouring, which are selected in accordance with the intended objectives and the prevailing circumstances, and to the use of the compositions for controlling pests of the mentioned type. Typical rates of concentration are from 0.1 to 1000 ppm, preferably from 0.1 to 500 ppm, of active ingredient. The rates of application per hectare are generally from 1 to 2000 g of active ingredient per hectare, especially from 10 to 1000 g/ha, preferably from 20 to 600 g/ha.  
      A preferred method of application in the area of crop protection is application to the foliage of the plants (foliar application), the frequency and the rate of application being dependent upon the risk of infestation by the pest in question. However, the active ingredient can also penetrate the plants through the roots (systemic action) when the locus of the plants is impregnated with a liquid formulation or when the active ingredient is incorporated in solid form into the locus of the plants, for example into the soil, e.g. in granular form (soil application). In the case of paddy rice crops, such granules may be applied in metered amounts to the flooded rice field.  
      The crop protection products according to the invention are also suitable for protecting plant propagation material, e.g. seed, such as fruits, tubers or grains, or plant cuttings, against animal pests. The propagation material can be treated with the composition before planting: seed, for example, can be dressed before being sown. The active ingredients according to the invention can also be applied to grains (coating), either by impregnating the seeds in a liquid formulation or by coating them with a solid formulation. The composition can also be applied to the planting site when the propagation material is being planted, for example to the seed furrow during sowing. The invention relates also to such methods of treating plant propagation material and to the plant propagation material so treated.  
      The following Examples serve to illustrate the invention. They do not limit the invention. Temperatures are given in degrees Celsius; mixing ratios of solvents are given in parts by volume. 
    
    
     PREPARATION EXAMPLES  
     EXAMPLE P1)  
     Preparation of 3-(4-{3- 8  2,6-dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-propoxy}-phenyl)-acrylonitrile  
      58 mg of cyanomethanephosphoric acid diethyl ester, 59 mg of 5.4 molar solution of sodium methoxide in methanol and 150 mg of 4-{3-[2,6-dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-propoxy}-benzaldehyde are stirred for 24 hours at room temperature in 2 ml of ethanol. The reaction mixture is poured into water and extracted with ethyl acetate. Concentration of the organic phase and purification over silica gel yield the title compound (compound 1.1).  
     EXAMPLE P2)  
     Preparation of 4-(4-{3-[2,6-dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-propoxy}-phenyl)-but-3-yn-2-ol  
      P2.1. 740 mg of tetrakis(triphenylphosphine)palladium and 427 mg of copper(I) iodide are stirred for 5 minutes in 25 ml of diisopropylamine. 7 g of 4-iodophenol and a solution of 2.2 g of 3-butyn-2-ol in 25 ml of diisopropylamine are then added. After 4 hours&#39; stirring at room temperature, the reaction mixture is poured into ammonium chloride solution and extracted with ethyl acetate. Concentration of the organic phase and purification over silica gel yield 4-(3-hydroxy-but-1-ynyl)-phenol.  1 H-NMR (CDCl 3 ) 300 MHz: 1.54 (d, 3H), 2.04 (s, 1H), 4.76 (m, 1H), 5.49 (s, 1H), 6.77 (d, 2H), 7.30 (d, 2H).  
      P2.2: 840 mg of 4-(3-hydroxy-but-1-ynyl)-phenol, 2.2 g of methanesulfonic acid 3-[2,6-dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-propyl ester and 2.2 g of potassium carbonate are stirred for 24 hours at 50° C. in 20 ml of dimethylformamide. The reaction mixture is poured onto water and extracted with ethyl acetate. Concentration of the organic phase and purification over silica gel yield the title compound (compound 1.7).  
     EXAMPLE P3)  
     Preparation of 1,3-dichloro-5-(3,3-dichloro-allyloxy)-2-{3-[4-(3-methoxy-methoxy-but-1-ynyl)-phenoxy]-propoxy}-benzene  
      20 mg of chloromethyl methyl ether and 32 mg of N-ethyl-diisopropylamine are added to a solution of 100 mg of 4-(4-{3-[2,6-dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-propoxy}-phenyl)-but-3-yn-2-ol in 4 ml of dichloromethane, and stirring is carried out for 36 hours at room temperature. The reaction mixture is diluted with ethyl acetate and washed in succession with dilute hydrochloric acid and water. Concentration of the organic phase and purification over silica gel yield the title compound (compound 1.11).  
     EXAMPLE P4)  
     Preparation of 4-(4-}3-[2,6-dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-propoxy}-phenyl)-but-3-yn-2-one  
      306 mg of dimethyl sulfoxide are added dropwise in the course of 5 minutes at −60° C. to a solution of 228 mg of oxalyl chloride in 20 ml of dichloromethane. After 30 minutes, a solution of 800 mg of 4-(4-{3-[2,6-dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-propoxy}-phenyl)-but-3-yn-2-ol in 10 ml of dichloromethane is added dropwise in the course of 20 minutes at −60° C. After a further 30 minutes, 1.1 ml of triethylamine are added dropwise, and stirring is carried out for a further 15 minutes at −60° C. The reaction mixture is heated slowly to room temperature, then poured into water and extracted with dichloromethane. Concentration of the organic phase and purification over silica gel yield the title compound (compound 1.15).  
     EXAMPLE P5)  
     Preparation of 4-(4-{3-[2,6-dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-propoxy}-phenyl)-but-3-yn-2-one O-methyl-oxime  
      20.9 mg of O-methylhydroxylamine hydrochloride, 20.5 mg of sodium acetate and 122 mg of 4-(4-{3-[2,6-dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-propoxy}-phenyl)-but-3-yn-2-one are stirred for 24 hours at room temperature in 4 ml of methanol. The reaction mixture is diluted with ethyl acetate and washed with water. Concentration of the organic phase and purification over silica gel yield the title compound (compound 1.16).  
     EXAMPLE P6)  
     Preparation of 1,3-dichloro-5-(3,3-dichloro-allyloxy)-2-{3-[4-(2-nitro-vinyl)-phenoxy]-propoxy}-benzene  
      100 mg of 4-{3-[2,6-dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-propoxy}-benzaldehyde, 68 mg of ammonium acetate and 83 mg of nitromethane are stirred for 30 minutes at 120° C. in 0.1 ml of acetic acid. The reaction mixture is poured into water and extracted with ethyl acetate. Concentration of the organic phase and purification over silica gel yield the title compound (compound 1.4).  
     EXAMPLE P7)  
     Preparation of 4-(4-{3-[2,6-dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-propoxy}-phenyl)-but-3-en-2-one  
      52 mg of 4-(4-hydroxy-phenyl)-but-3-en-2-one, 129 mg of methanesulfonic acid 3-[2,6-dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-propyl ester and 84 mg of potassium carbonate are stirred for 2 hours at 50° C. in 2 ml of dimethylformamide. The reaction mixture is poured into water and extracted with ethyl acetate. Concentration of the organic phase and purification over silica gel yield the title compound (compound 1.19).  
     EXAMPLE P8)  
     Preparation of 4-(4-{3-[2.6-dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]- propoxy}-phenyl)-but-3-en-2-one O-ethyl-oxime  
      100 mg of 4-(4-{3-[2,6-dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-propoxy}-phenyl)-but-3-en-2-one, 17 mg of O-methylhydroxylamine hydrochloride and 17 mg of sodium acetate are stirred for 16 hours at room temperature in 10 ml of methanol. The reaction mixture is poured into water and extracted with ethyl acetate. Concentration of the organic phase and purification over silica gel yield the title compound (compound 1.14).  
     EXAMPLE P9)  
     Preparation of 3-(4-{3-[2,6-dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-propoxy}-phenyl)-acrylic acid ethyl ester  
      315 mg of 4-{3-[2,6-dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-propoxy}-benzaldehyde, 132 mg of phosphonoacetic acid triethyl ester, 164 mg of N-ethyldiisopropylamine and 65 mg of lithium chloride are stirred for 18 hours at room temperature in 5 ml of dimethyl-formamide. The reaction mixture is poured into water and extracted with ethyl acetate. Concentration of the organic phase and purification over silica gel yield the title compound (compound 1.22).  
     EXAMPLE P10)  
     Preparation of 3-(4-{3-[2,6-dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-propoxy}-phenyl)-4-methoxy-but-2-ene-nitrile  
      P10.1 1.8 g of 2-bromo-1-(4-hydroxy-phenyl)-ethanone in 10 ml of methanol are added dropwise to 16 ml of 5.4M sodium methoxide in methanol and 50 ml of methanol, and stirring is carried out for 30 minutes at 60° C. The reaction mixture is concentrated and the residue is taken up in water and adjusted to pH 1 with concentrated hydrochloric acid. Extraction with ethyl acetate is then carried out, the organic phase is concentrated and the crude product is purified over silica gel. 1-(4-Hydroxy-phenyl)-2-methoxy-ethanone is obtained.  1 H-NMR (CDCl 3 ) 300 MHz: 3.50 (s, 3H), 4.68 (s, 2H), 6.23 (s, 1H), 6.91 (d, 2H), 7.90 (d, 2H).  
      P10.2 2.76 g of methanesulfonic acid 3-[2,6-dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-propyl ester, 1.19 g of 1-(4-hydroxy-phenyl)-2-methoxy-ethanone and 2.7 g of potassium carbonate are stirred for 20 hours at 50° C. in 90 ml of dimethylformamide. The reaction mixture is poured into water and extracted with ethyl acetate. Concentration of the organic phase and purification over silica gel yield 1-(4-{3-[2,6-dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-propoxy}-phenyl)-2-methoxy-ethanone.  1 H-NMR (CDCl 3 ) 300 MHz: 2.31 (m, 2H), 3.50 (s, 3H), 4.17 (t, 2H), 4.37 (t, 2H), 4.58 (d, 2H), 4.66 (s, 2H), 6.10 (t, 1H), 6.82 (s, 2H), 6.98 (d, 2H), 7.93 (d, 2H).  
      P10.3 300 mg of 1-(4-{3-[2,6-dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-propoxy}-phenyl)-2-methoxy-ethanone and 108 mg of cyanomethyl-phosphonic acid diethyl ester are dissolyed in 3 ml of ethanol. After the addition of 0.11 ml of 5.4M sodium methoxide in methanol, stirring is carried out for 17 hours at room temperature. The reaction mixture is diluted with 16 ml of ethyl acetate and washed twice with water. Concentration of the organic phase and purification over silica gel yield the title compound (compound 1.27).  
     EXAMPLE P11)  
      The Examples of the following Tables can also be prepared in a manner analogous to that described above. Some of the compounds listed in the Tables are obtained in the form of E/Z isomeric mixtures, although only one isomer is indicated in the E column. Mp. is the melting point in ° C., n D   20  the refraction index at 20° C. and the wavelength of the sodium D-line. The symbol . . . in the formulae signifies the bond of the fragment E to the remainder of the structure.  
               TABLE 1                          Compounds of formula                                                                   No.   E     1 H-NMR (CDCl 3 ) 300 MHz, melting point or n D   20                                 1.1                         2.31 (m, 2H), 4.15 (t, 2H), 4.31 (t, 2H), 4.60 (d, 2H), 5.70 + 5.77 (s + s, 1H), 6.11 (t, 1H), 6.95 (d, 2H), 7.38-7.47 (m, 2H)               1.2                         2.30 (m, 2H), 2.43 (s, 3H), 4.16 (t, 2H), 4.30 (t, 2H), 4.48 (d, 2H), 5.55 (s, 1H), 6.10 (t, 1H), 6.84 (s, 1H), 6.94 (d, 2H), 7.43 (d, 2H)               1.3                         1.09 + 1.15 (t + t, 3H), 2.30 (m, 2H), 2.59 + 2.90 (q + q, 2H), 4.18 (t, 2H), 4.30 (t, 2H), 4.59 (d, 2H), 5.30 + 5.44 (s + s, 1H), 6.11 (t, 1H), 6.84 (s, 2H), 6.92-7.11 (m, 2H), 7.40 + 7.48 (d + d, 2H)               1.4                         2.30 (m, 2H), 4.17 (t, 2H); 4.34 (t, 2H), 4.59 (d, 2H), 6.11 (t, 1H), 6.81 (s, 2H), 6.98 (d, 2H), 7.46-7.58 (m, 3H), 8.00 (d, 1H)               1.5                         2.32 (m, 2H), 2.48 (s, 3H), 4.17 (t, 2H); 4.32 (t, 2H), 4.59 (d, 2H), 6.10 (t, 1H), 6.84 (s, 2H), 7.00 (d, 2H), 7.43 (d, 2H), 8.09 (s, 1H)               1.6                         1.30 (t, 3H), 2.32 (m, 2H), 2.91 (q, 2H), 4.17 (t, 2H); 4.34 (t, 2H), 4.59 (d, 2H), 6.10 (t, 1H), 6.85 (s, 2H), 7.00 (d, 2H), 7.42 (d, 2H), 8.02 (s, 1H)               1.7                         1.53 (d, 3H), 2.28 (m, 2H), 4.12 (t, 2H), 4.25 (t, 2H), 4.58 (d, 2H), 4.74 (m, 1H), 6.10 (t, 1H), 6.82 (s, 2H), 6.86 (d, 2H), 7.36 (d, 2H)               1.8                         1.56 (d, 3H), 2.29 (m, 2H), 3.40 (s, 3H), 4.13 (t, 2H), 4.26 (t, 2H), 4.58 (d, 2H), 4.61-4.70 (m, 2H), 5.01 (d, 1H), 6.10 (t, 1H), 6.82 (s, 2H), 6.86 (d, 2H), 7.38 (d, 2H)               1.9                         1.70 (s, 1H), 2.28 (m, 2H), 4.12 (t, 2H), 4.35 (t, 2H), 4.48 (s, 2H), 4.58 (d, 2H), 6.11 (t, 1H), 6.84 (s, 2H), 6.88 (d, 2H), 7.38 (d, 2H)               1.10                         2.29 (m, 2H), 3.43 (s, 3H), 4.13 (t, 2H), 4.27 (t, 2H), 4.30 (s, 2H), 4.58 (d, 2H), 6.11 (t, 1H), 6.83 (s, 2H), 6.88 (d, 2H), 7.40 (d, 2H               1.11                         2.39 (m, 2H), 3.40 (s, 3H), 4.13 (t, 2H), 4.35 (t, 2H), 4.43 (s, 2H), 4.58 (d, 2H), 4.78 (s, 2H), 6.10 (t, 1H), 6.82 (s, 2H), 6.86 (d, 2H), 7.38 (d, 2H)               1.12                         1.60 (s, 6H), 2.29 (m, 2H), 4.12 (t, 2H), 4.25 (t, 2H), 4.58 (d, 2H), 6.10 (t, 1H), 6.81 (s, 2H), 6.85 (d, 2H), 7.36 (d, 2H)               1.13                         1.58 (s, 6H), 2.28 (m, 2H), 3.42 (s, 3H), 4.13 (t, 2H), 4.27 (t, 2H), 4.58 (d, 2H), 4.99 (s, 2H), 6.10 (t, 1H), 6.82 (s, 2H), 6.85 (d, 2H), 7.36 (d, 2H)               1.14 
                 
               1.15                         2.29 (m, 2H), 2.43 (s, 3H), 4.13 (t, 2H), 4.30 (t, 2H), 4.58 (d, 2H), 4.74 (m, 1H), 6.10 (t, 1H), 6.82 (s, 2H), 6.92 (d, 2H), 7.53 (d, 2H)               1.16                         2.08 + 2.10 (s + s, 3H), 2.38 (m, 2H), 3.97 (s, 3H), 4.13 (t, 2H), 4.28 (m, 2H), 4.56 (d, 2H), 6.10 (t, 1H), 6.82 (s, 2H), 6.88 (m, 2H), 7.47 (m, 2H)               1.17                         1.27-1.39 (m, 3H), 2.08 + 2.10 (s + s, 3H), 2.38 (m, 2H), 4.09-4.31 (m, 6H), 4.57 (d, 2H), 6.10 (t, 1H), 6.82 (s, 2H), 6.88 (m, 2H), 7.46 (m, 2H)               1.18                         2.10 (s, 3H), 2.38 (m, 2H), 4.14 (m, 2H), 4.26 (m, 2H), 4.58 (d, 2H), 4.65 (m, 2H), 5.19-5.40 (m, 2H), 5.94-6.13 (m, 2H), 6.81 (s, 2H), 6.88 (m, 2H), 7.43 (m, 2H)               1.19                         2.30 (m, 2H), 2.36 (s, 3H), 4.16 (t, 2H), 4.31 (t, 2H), 4.59 (d, 2H), 6.11 (t, 1H), 6.61 (d, 1H), 6.82 (s, 2H), 6.95 (d, 2H), 7.44-7.52 (m, 3H)               1.20                         2.08 (s, 3H), 2.30 (m, 2H), 3.93 (s, 3H), 4.16 (t, 2H), 4.28 (t, 2H), 4.59 (d, 2H), 6.11 (t, 1H), 6.70 (d, 1H), 6.75-6.93 (m, 5H), 7.40 (d, 2H)               1.21                         1.32 (t, 3H), 2.08 (s, 3H), 2.30 (m, 2H), 4.11-4.22 (m, 4H), 4.28 (t, 2H), 4.59 (d, 2H), 6.10 (t, 1H), 6.68-6.92 (m, 6H), 7.40 (d, 2H)               1.22                         1.32 (t, 3H), 2.30 (m, 2H), 4.15 (t, 2H), 4.21-4.33 (m, 4H), 4.58 (d, 2H), 6.11 (t, 1H), 6.30 (d, 1H), 6.82 (s, 2H), 6.92 (d, 2H), 7.48 (d, 2H), 7.63 (d, 1H)               1.23                         1.35 (t, 3H), 2.13 (s, 3H), 2.30 (m, 2H), 4.16 (t, 2H), 4.22-4.33 (m, 4H), 4.58 (d, 2H), 6.10 (t, 1H), 6.82 (s, 2H), 6.94 (d, 2H), 7.39 (d, 2H), 7.63 (s, 1H)               1.24                         1.51 (s, 9H), 2.30 (m, 2H), 4.15 (t, 2H), 4.30 (t, 2H), 4.58 (d, 2H), 6.10 (t, 1H), 6.25 (d, 1H), 6.84 (s, 2H), 6.92 (d, 2H), 7.46 (d, 2H), 7.53 (d, 1H)               1.25                         2.30 (m, 2H), 4.14 (t, 2H), 4.30 (t, 2H), 4.58 (d, 2H), 4.70 (d, 2H), 5.28 (d, 1H), 5.38 (d, 1H), 5.92-6.07 (m, 1H), 6.10 (t, 1H), 6.34 (d, 1H), 6.83 (s, 2H), 6.92 (d, 2H), 7.49 (d, 2H), 7.68 (d, 1H)               1.26                         1.40 (t, 3H), 2.30 (m, 2H), 4.16 (t, 2H), 4.22-4.32 (m, 4H), 4.59 (d, 2H), 6.11 (t, 1H), 6.80-6.93 (m, 5H), 7.52 (d, 2H)               1.27                         2.30 (m, 2H), 3.48 (s, 2H), 3.78 (s, 3H), 4.14 (t, 2H), 4.26 (t, 2H), 4.58 (d, 2H), 6.11 (t, 1H), 6.42 (s, 1H), 6.82 (s, 2H), 6.90 (d, 2H), 7.21 (d, 2H)               1.28                         n D   20  : 1.5660               1.29                         n D   20  : 1.5867               1.30                         n D   20  : 1.5835               1.31                         n D   20  : 1.5900               1.32                                     1.33                         n D   20  : 1.5721               1.34                         n D   20  : 1.5748               1.35                         mp: 78-81° C.               1.36                                     1.37                         n D   20  : 1.6069               1.38                                     1.39                         mp.: 88-93° C.               1.40                         n D   20  : 1.5960               1.41                                     1.42                         n D   20  : 1.6080               1.43                         n D   20  : 1.5950               1.44                         n D   20  : 1.6090               1.45                         n D   20  : 1.6060               1.46                                     1.47                         n D   20  : 1.6239               1.48                         n D   20  : 1.6210               1.49                         n D   20  : 1.6130               1.50                         n D   20  : 1.5750               1.51                         Mp.: 100-103° C.               1.52                                     1.53                                     1.54                                        
 
     
       
         
           
               
             
               
                 TABLE A 
               
               
                   
               
               
                   
               
               
                 Compounds of formulae 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
            
               
                   
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Id) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Ie) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (If) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Ig) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Ih) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Ii) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Ik) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Im) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (In) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Io) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Ip) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Iq) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Ir) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Is) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (It) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Iu) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Iv) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Iw) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Ix) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Iy) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Iz) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Iaa) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Ibb) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Icc) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Idd) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Iee) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Iff) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Igg) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Ihh) 
               
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 (Iii) 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
             
               
                   
                 TABLE B 
               
               
                   
                   
               
               
                   
                   
               
               
                   
                 No. 
                 R 10   
               
               
                   
                   
               
             
            
               
                   
                 B.1 
                 CN 
               
               
                   
                 B.2 
                 NO 2   
               
               
                   
                 B.3 
                 COOCH 3   
               
               
                   
                 B.4 
                 COOC 2 H 5   
               
               
                   
                 B.5 
                 COOn—C 3 H 7   
               
               
                   
                 B.6 
                 COOn—C 4 H 9   
               
               
                   
                 B.7 
                 COOn—C 5 H 11   
               
               
                   
                 B.8 
                 COOn—C 6 H 13   
               
               
                   
                 B.9 
                 COO-iso-C 3 H 7   
               
               
                   
                 B.10 
                 COO-iso-C 4 H 9   
               
               
                   
                 B.11 
                 COO-iso-C 5 H 11   
               
               
                   
                 B.12 
                 COO-tert-C 4 H 9   
               
               
                   
                 B.13 
                 CH 2 OCH 3   
               
               
                   
                 B.14 
                 CH 2 OC 2 H 5   
               
               
                   
                 B.15 
                 CH 2 O-n-C 3 H 7   
               
               
                   
                 B.16 
                 CH 2 O-n-C 4 H 9   
               
               
                   
                 B.17 
                 CH 2 O-n-C 5 H 11   
               
               
                   
                 B.18 
                 CH 2 O-n-C 6 H 13   
               
               
                   
                 B.19 
                 CH 2 O-iso-C 3 H 7   
               
               
                   
                 B.20 
                 CH 2 O-iso-C 4 H 9   
               
               
                   
                 B.21 
                 CH 2 O-iso-C 5 H 11   
               
               
                   
                 B.22 
                 CH 2 O-tert-C 4 H 9   
               
               
                   
                 B.23 
                 CH 2 OCH 2 C(CH 3 ) 3   
               
               
                   
                 B.24 
                 CH 2 OCH 2 (cyclo-propyl) 
               
               
                   
                 B.25 
                 CH 2 OCF 3   
               
               
                   
                 B.26 
                 CH 2 OCH 2 CF 3   
               
               
                   
                 B.27 
                 CH 2 OCH 2 CHF 2   
               
               
                   
                 B.28 
                 CH 2 OC H 2 CH 2 F 
               
               
                   
                 B.29 
                 CH 2 OCH 2 CH═CH 2   
               
               
                   
                 B.30 
                 CH 2 OCH 2 C≡CH 
               
               
                   
                 B.31 
                 CH 2 OCH 2 C≡CCH 3   
               
               
                   
                 B.32 
                 CH 2 OCH 2 OCH 3   
               
               
                   
                 B.33 
                 CH 2 OCH 2 OC 2 H 5   
               
               
                   
                 B.34 
                 CH 2 OCH 2 On—C 3 H 7   
               
               
                   
                 B.35 
                 CH 2 OCH 2 On—C 4 H 9   
               
               
                   
                 B.36 
                 CH 2 OCH 2 On—C 5 H 11   
               
               
                   
                 B.37 
                 CH 2 OCH 2 On—C 6 H 13   
               
               
                   
                 B.38 
                 CH 2 OCH 2 Oiso-C 3 H 7   
               
               
                   
                 B.39 
                 CH 2 OCH 2 Oiso-C 4 H 9   
               
               
                   
                 B.40 
                 CH 2 OCH 2 Oiso-C 5 H 11   
               
               
                   
                 B.41 
                 CH 2 OCH 2 Otert-C 4 H 9   
               
               
                   
                 B.42 
                 CH 2 OCH 2 OCH 2 C(CH 3 ) 3   
               
               
                   
                 B.43 
                 CH 2 OCH 2 OCH 2 (cyclo-propyl) 
               
               
                   
                 B.44 
                 CH 2 OCH 2 OCF 3   
               
               
                   
                 B.45 
                 CH 2 OCH 2 OCH 2 CF 3   
               
               
                   
                 B.46 
                 CH 2 OCH 2 OCH 2 CHF 2   
               
               
                   
                 B.47 
                 CH 2 OCH 2 OCH 2 CH 2 F 
               
               
                   
                 B.48 
                 CH 2 OCH 2 OCH 2 CH═CH 2   
               
               
                   
                 B.49 
                 CH 2 OCH 2 OCH 2 C≡CH 
               
               
                   
                 B.50 
                 CH 2 OCH 2 OCH 2 C≡CCH 3   
               
               
                   
                 B.51 
                 CH(CH 3 )—OCH 3   
               
               
                   
                 B.52 
                 CH(CH 3 )—OC 2 H 5   
               
               
                   
                 B.53 
                 CH(CH 3 )-On-C 3 H 7   
               
               
                   
                 B.54 
                 CH(CH 3 )-On-C 4 H 9   
               
               
                   
                 B.55 
                 CH(CH 3 )-On-C 5 H 11   
               
               
                   
                 B.56 
                 CH(CH 3 )-On-C 6 H 13   
               
               
                   
                 B.57 
                 CH(CH 3 )-Oiso-C 3 H 7   
               
               
                   
                 B.58 
                 CH(CH 3 )-Oiso-C 4 H 9   
               
               
                   
                 B.59 
                 CH(CH 3 )-Oiso-C 5 H 11   
               
               
                   
                 B.60 
                 CH(CH 3 )-Otert-C 4 H 9   
               
               
                   
                 B.61 
                 CH(CH 3 )—OCH 2 C(CH 3 ) 3   
               
               
                   
                 B.62 
                 CH(CH 3 )—OCH 2 (cyclo-propyl) 
               
               
                   
                 B.63 
                 CH(CH 3 )—OCF 3   
               
               
                   
                 B.64 
                 CH(CH 3 )—OCH 2 CF 3   
               
               
                   
                 B.65 
                 CH(CH 3 )—OCH 2 CHF 2   
               
               
                   
                 B.66 
                 CH(CH 3 )—OCH 2 CH 2 F 
               
               
                   
                 B.67 
                 CH(CH 3 )—OCH 2 CH═CH 2   
               
               
                   
                 B.68 
                 CH(CH 3 )—OCH 2 C≡CH 
               
               
                   
                 B.69 
                 CH(CH 3 )—OCH 2 C≡CCH 3   
               
               
                   
                 6.70 
                 CH(CH 3 )—OCH 2 OCH 3   
               
               
                   
                 B.71 
                 CH(CH 3 )—OCH 2 OC 2 H 5   
               
               
                   
                 B.72 
                 CH(CH 3 )—OCH 2 On-C 3 H 7   
               
               
                   
                 B.73 
                 CH(CH 3 )—OCH 2 On-C 4 H 9   
               
               
                   
                 B.74 
                 CH(CH 3 )—OCH 2 On-C 5 H 11   
               
               
                   
                 B.75 
                 CH(CH 3 )—OCH 2 On-C 6 H 13   
               
               
                   
                 B.76 
                 CH(CH 3 )—OCH 2 Oiso-C 3 H 7   
               
               
                   
                 B.77 
                 CH(CH 3 )—OCH 2 Oiso-C 4 H 9   
               
               
                   
                 B.78 
                 CH(CH 3 )—OCH 2 Oiso-C 5 H 11   
               
               
                   
                 B.79 
                 CH(CH 3 )—OCH 2 Otert-C 4 H 9   
               
               
                   
                 B.80 
                 CH(CH 3 )—OCH 2 OCH 2 C(CH 3 ) 3   
               
               
                   
                 B.81 
                 CH(CH 3 )—OCH 2 OCH 2 (cyclo-propyl) 
               
               
                   
                 B.82 
                 CH(CH 3 )—OCH 2 OCF 3   
               
               
                   
                 B.83 
                 CH(CH 3 )—OCH 2 OCH 2 CF 3   
               
               
                   
                 B.84 
                 CH(CH 3 )—OCH 2 OCH 2 CHF 2   
               
               
                   
                 B.85 
                 CH(CH 3 )—OCH 2 OCH 2 CH 2 F 
               
               
                   
                 B.86 
                 CH(CH 3 )—OCH 2 OCH 2 CH═CH 2   
               
               
                   
                 B.87 
                 CH(CH 3 )—OCH 2 OCH 2 C≡CH 
               
               
                   
                 B.88 
                 CH(CH 3 )—OCH 2 OCH 2 C≡CCH 3   
               
               
                   
                 B.89 
                 C(CH 3 ) 2 —OCH 3   
               
               
                   
                 B.90 
                 C(CH 3 ) 2 —OC 2 H 5   
               
               
                   
                 B.91 
                 C(CH 3 ) 2 -On-C 3 H 7   
               
               
                   
                 B.92 
                 C(CH 3 ) 2 -On-C 4 H 9   
               
               
                   
                 B.93 
                 C(CH 3 ) 2 -On-C 5 H 11   
               
               
                   
                 B.94 
                 C(CH 3 ) 2 -On-C 6 H 13   
               
               
                   
                 B.95 
                 C(CH 3 ) 2 -Oiso-C 3 H 7   
               
               
                   
                 B.96 
                 C(CH 3 ) 2 -Oiso-C 4 H 9   
               
               
                   
                 B.97 
                 C(CH 3 ) 2 -Oiso-C 5 H 11   
               
               
                   
                 B.98 
                 C(CH 3 ) 2 -Otert-C 4 H 9   
               
               
                   
                 B.99 
                 C(CH 3 ) 2 —OCH 2 C(CH 3 ) 3   
               
               
                   
                 B.100 
                 C(CH 3 ) 2 —OCH 2 (cyclo-propyl) 
               
               
                   
                 B.101 
                 C(CH 3 ) 2 —OCF 3   
               
               
                   
                 B.102 
                 C(CH 3 ) 2 —OCH 2 CF 3   
               
               
                   
                 B.103 
                 C(CH 3 ) 2 —OCH 2 CHF 2   
               
               
                   
                 B.104 
                 C(CH 3 ) 2 —OCH 2 CH 2 F 
               
               
                   
                 B.105 
                 C(CH 3 ) 2 —OCH 2 CH═CH 2   
               
               
                   
                 B.106 
                 C(CH 3 ) 2 —OCH 2 C≡CH 
               
               
                   
                 B.107 
                 C(CH 3 ) 2 —OCH 2 C≡CCH 3   
               
               
                   
                 B.108 
                 C(CH 3 ) 2 —OCH 2 OCH 3   
               
               
                   
                 B.109 
                 C(CH 3 ) 2 —OCH 2 OC 2 H 5   
               
               
                   
                 B.110 
                 C(CH 3 ) 2 —OCH 2 On-C 3 H 7   
               
               
                   
                 B.111 
                 C(CH 3 ) 2 —OCH 2 On-C 4 H 9   
               
               
                   
                 B.112 
                 C(CH 3 ) 2 —OCH 2 On-C 5 H 11   
               
               
                   
                 B.113 
                 C(CH 3 ) 2 —OCH 2 On-C 6 H 13   
               
               
                   
                 B.114 
                 C(CH 3 ) 2 —OCH 2 Oiso-C 3 H 7   
               
               
                   
                 B.115 
                 C(CH 3 ) 2 —OCH 2 Oiso-C 4 H 9   
               
               
                   
                 B.116 
                 C(CH 3 ) 2 —OCH 2 Oiso-C 5 H 11   
               
               
                   
                 B.117 
                 C(CH 3 ) 2 —OCH 2 Otert-C 4 H 9   
               
               
                   
                 B.118 
                 C(CH 3 ) 2 —OCH 2 OCH 2 C(CH 3 ) 3   
               
               
                   
                 B.119 
                 C(CH 3 ) 2 —OCH 2 OCH 2 (cyclo-propyl) 
               
               
                   
                 B.120 
                 C(CH 3 ) 2 —OCH 2 OCF 3   
               
               
                   
                 B.121 
                 C(CH 3 ) 2 —OCH 2 OCH 2 CF 3   
               
               
                   
                 B.122 
                 C(CH 3 ) 2 —OCH 2 OCH 2 CHF 2   
               
               
                   
                 B.123 
                 C(CH 3 ) 2 —OCH 2 OCH 2 CH 2 F 
               
               
                   
                 B.124 
                 C(CH 3 ) 2 —OCH 2 OCH 2 CH═CH 2   
               
               
                   
                 B.125 
                 C(CH 3 ) 2 —OCH 2 OCH 2 C≡CH 
               
               
                   
                 B.126 
                 C(CH 3 ) 2 —OCH 2 OCH 2 C≡CCH 3   
               
               
                   
                 B.127 
                 C(═O)CH 3   
               
               
                   
                 B.128 
                 C(═O)C 2 H 5   
               
               
                   
                 B.129 
                 C(═O)-n-C 3 H 7   
               
               
                   
                 B.130 
                 C(═O)-n-C 4 H 9   
               
               
                   
                 B.131 
                 C(═O)-n-C 5 H 11   
               
               
                   
                 B.132 
                 C(═O)-n-C 6 H 13   
               
               
                   
                 B.133 
                 C(═O)-iso-C 3 H 7   
               
               
                   
                 B.134 
                 C(═O)-iso-C 4 H 9   
               
               
                   
                 B.135 
                 C(═O)-iso-C 5 H 11   
               
               
                   
                 B.136 
                 C(═O)-tert-C 4 H 9   
               
               
                   
                 B.137 
                 C(═O)-cyclo-propyl 
               
               
                   
                 B.138 
                 C(═N—OCH 3 )CH 3   
               
               
                   
                 B.139 
                 C(═N—OCH 3 )C 2 H 5   
               
               
                   
                 B.140 
                 C(═N—OCH 3 )-n-C 3 H 7   
               
               
                   
                 B.141 
                 C(═N—OCH 3 )-n-C 4 H 9   
               
               
                   
                 B.142 
                 C(═N—OCH 3 )-n-C 5 H 11   
               
               
                   
                 B.143 
                 C(═N—OCH 3 )-n-C 6 H 13   
               
               
                   
                 B.144 
                 C(═N—OCH 3 )-iso-C 3 H 7   
               
               
                   
                 B.145 
                 C(═N—OCH 3 )-iso-C 4 H 9   
               
               
                   
                 B.146 
                 C(═N—OCH 3 )-iso-C 5 H 11   
               
               
                   
                 B.147 
                 C(═N—OCH 3 )-tert-C 4 H 9   
               
               
                   
                 B.148 
                 C(═N—OCH 3 )-cyclo-propyl 
               
               
                   
                 B.149 
                 C(═N—OCH 2 CH 3 )CH 3   
               
               
                   
                 B.150 
                 C(═N—OCH 2 CH 3 )C 2 H 5   
               
               
                   
                 B.151 
                 C(═N—OCH 2 CH 3 )-n-C 3 H 7   
               
               
                   
                 B.152 
                 C(═N—OCH 2 CH 3 )-n-C 4 H 9   
               
               
                   
                 B.153 
                 C(═N—OCH 2 CH 3 )-n-C 5 H 11   
               
               
                   
                 B.154 
                 C(═N—OCH 2 CH 3 )-n-C 6 H 13   
               
               
                   
                 B.155 
                 C(═N—OCH 2 CH 3 )-iso-C 3 H 7   
               
               
                   
                 B.156 
                 C(═N—OCH 2 CH 3 )-iso-C 4 H 9   
               
               
                   
                 B.157 
                 C(═N—OCH 2 CH 3 )-iso-C 5 H 11   
               
               
                   
                 B.158 
                 C(═N—OCH 2 CH 3 )-tert-C 4 H 9   
               
               
                   
                 B.159 
                 C(═N—OCH 2 CH 3 )-cyclo-propyl 
               
               
                   
                 B.160 
                 C(═N—OCH 2 CH═CH 2 )CH 3   
               
               
                   
                 B.161 
                 C(═N—OCH 2 CH═CH 2 )C 2 H 5   
               
               
                   
                 B.162 
                 C(═N—OCH 2 CH═CH 2 )-n-C 3 H 7   
               
               
                   
                 B.163 
                 C(═N—OCH 2 CH═CH 2 )-n-C 4 H 9   
               
               
                   
                 B.164 
                 C(═N—OCH 2 CH═CH 2 )-n-C 5 H 11   
               
               
                   
                 B.165 
                 C(═N—OCH 2 CH═CH 2 )-n-C 6 H 13   
               
               
                   
                 B.166 
                 C(═N—OCH 2 CH═CH 2 )-iso-C 3 H 7   
               
               
                   
                 B.167 
                 C(═N—OCH 2 CH═CH 2 )-iso-C 4 H 9   
               
               
                   
                 B.168 
                 C(═N—OCH 2 CH═CH 2 )-iso-C 5 H 11   
               
               
                   
                 B.169 
                 C(═N—OCH 2 CH═CH 2 )-tert-C 4 H 9   
               
               
                   
                 B.170 
                 C(═N—OCH 2 CH═CH 2 )-cyclo-propyl 
               
               
                   
                 B.171 
                 C(═N—OCH 2 C≡CH)CH 3   
               
               
                   
                 B.172 
                 C(═N—OCH 2 C≡CH)C 2 H 5   
               
               
                   
                 B.173 
                 C(═N—OCH 2 C≡CH)n-C 3 H 7   
               
               
                   
                 B.174 
                 C(═N—OCH 2 C≡CH)n-C 4 H 9   
               
               
                   
                 B.175 
                 C(═N—OCH 2 C≡CH)n-C 5 H 11   
               
               
                   
                 B.176 
                 C(═N—OCH 2 C≡CH)n-C 6 H 13   
               
               
                   
                 B.177 
                 C(═N—OCH 2 C≡CH)iso-C 3 H 7   
               
               
                   
                 B.178 
                 C(═N—OCH 2 C≡CH)iso-C 4 H 9   
               
               
                   
                 B.179 
                 C(═N—OCH 2 C≡CH)iso-C 5 H 11   
               
               
                   
                 B.180 
                 C(═N—OCH 2 C≡CH)tert-C 4 H 9   
               
               
                   
                 B.181 
                 C(═N—OCH 2 C≡CH)cyclo-propyl 
               
               
                   
                 B.182 
                 CONH—CH 3   
               
               
                   
                 B.183 
                 CONH—C 2 H 5   
               
               
                   
                 B.184 
                 CONH-n-C 3 H 7   
               
               
                   
                 B.185 
                 CONH-n-C 4 H 9   
               
               
                   
                 B.186 
                 CONH-n-C 5 H 11   
               
               
                   
                 B.187 
                 CONH-n-C 6 H 13   
               
               
                   
                 B.188 
                 CONH-iso-C 3 H 7   
               
               
                   
                 B.189 
                 CONH-iso-C 4 H 9   
               
               
                   
                 B.190 
                 CONH-iso-C 5 H 11   
               
               
                   
                 B.191 
                 CONH-tert-C 4 H 9   
               
               
                   
                   
               
            
           
         
       
     
      Table 2: A compound of the general formula (Id) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 3: A compound of the general formula (Ie) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 4: A compound of the general formula (If) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 5: A compound of the general formula (Ig) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 6: A compound of the general formula (Ih) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 7: A compound of the general formula (Ii) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 8: A compound of the general formula (Ik) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 9: A compound of the general formula (Im) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 10: A compound of the general formula (In) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 11: A compound of the general formula (Io) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 12: A compound of the general formula (Ip) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 13: A compound of the general formula (Iq) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 14: A compound of the general formula (Ir) wherein X 1  and X 2  are chlorine and n is 2, and the substituent RIo for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 15: A compound of the general formula (Is) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 16: A compound of the general formula (It) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 17: A compound of the general formula (Iu) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 18: A compound of the general formula (Iy) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 19: A compound of the general formula (Iw) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 20: A compound of the general formula (Ix) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 21: A compound of the general formula (Iy) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 22: A compound of the general formula (Iz) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 23: A compound of the general formula (Iaa) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 24: A compound of the general formula (Ibb) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 25: A compound of the general formula (Icc) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 26: A compound of the general formula (Idd) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 27: A compound of the general formula (Iee) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 28: A compound of the general formula (Iff) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 29: A compound of the general formula (Igg) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 30: A compound of the general formula (Ihh) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 31: A compound of the general formula (Iii) wherein X 1  and X 2  are chlorine and n is 2, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 32: A compound of the general formula (Id) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 33: A compound of the general formula (Ie) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 34: A compound of the general formula (If) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 35: A compound of the general formula (Ig) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 36: A compound of the general formula (Ih) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 37: A compound of the general formula (Ii) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 38: A compound of the general formula (Ik) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 39: A compound of the general formula (Im) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 40: A compound of the general formula (In) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 41: A compound of the general formula (Io) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 42: A compound of the general formula (Ip) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 43: A compound of the general formula (Iq) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 44: A compound of the general formula (Ir) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 45: A compound of the general formula (Is) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 46: A compound of the general formula (It) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 47: A compound of the general formula (Iu) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 48: A compound of the general formula (Iy) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 49: A compound of the general formula (Iw) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 50: A compound of the general formula (Ix) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 51: A compound of the general formula (Iy) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 52: A compound of the general formula (Iz) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 53: A compound of the general formula (Iaa) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 54: A compound of the general formula (Ibb) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 55: A compound of the general formula (Icc) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 56: A compound of the general formula (Idd) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 57: A compound of the general formula (Iee) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 58: A compound of the general formula (Iff) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 59: A compound of the general formula (Igg) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 60: A compound of the general formula (Ihh) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 61: A compound of the general formula (Iii) wherein X 1  and X 2  are chlorine and n is 3, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 62: A compound of the general formula (Id) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 63: A compound of the general formula (Ie) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 64: A compound of the general formula (If) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 65: A compound of the general formula (Ig) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 66: A compound of the general formula (Ih) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 67: A compound of the general formula (Ii) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 68: A compound of the general formula (Ik) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 69: A compound of the general formula (Im) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 70: A compound of the general formula (In) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 71: A compound of the general formula (Io) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 72: A compound of the general formula (Ip) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 73: A compound of the general formula (Iq) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 74: A compound of the general formula (Ir) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 75: A compound of the general formula (Is) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 76: A compound of the general formula (It) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 77: A compound of the general formula (Iu) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 78: A compound of the general formula (Iy) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 79: A compound of the general formula (Iw) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 80: A compound of the general formula (Ix) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 81: A compound of the general formula (Iy) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 82: A compound of the general formula (Iz) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 83: A compound of the general formula (Iaa) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 84: A compound of the general formula (Ibb) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 85: A compound of the general formula (Icc) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 86: A compound of the general formula (Idd) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 87: A compound of the general formula (Iee) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 88: A compound of the general formula (Iff) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 89: A compound of the general formula (Igg) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 90: A compound of the general formula (Ihh) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
      Table 91: A compound of the general formula (Iii) wherein X 1  and X 2  are chlorine and n is 4, and the substituent R 10  for each compound corresponds to a line B.1 to B.191 of Table B.  
     FORMULATION EXAMPLES (%=PERCENT BY WEIGHT)  
     
       
         
           
               
               
               
               
             
               
                   
               
               
                   
               
               
                 Example F1: Emulsifiable concentrates 
                 a) 
                 b) 
                 c) 
               
               
                   
               
             
            
               
                 active ingredient 
                 25% 
                 40% 
                 50% 
               
               
                 calcium dodecylbenzenesulfonate 
                  5% 
                  8% 
                  6% 
               
               
                 castor oil polyethylene glycol ether (36 mol EO) 
                  5% 
                 — 
                 — 
               
               
                 tributylphenol polyethylene glycol 
                 — 
                 12% 
                  4% 
               
               
                 ether (30 mol EO) 
               
               
                 cyclohexanone 
                 — 
                 15% 
                 20% 
               
               
                 xylene mixture 
                 65% 
                 25% 
                 20% 
               
               
                   
               
            
           
         
       
     
      Mixing finely ground active ingredient and additives gives an emulsifiable concentrate which yields emulsions of the desired concentration on dilution with water.  
                                               Example F2: Solutions   a)   b)   c)   d)                  active ingredient   80%   10%    5%   95%       ethylene glycol monomethyl ether   20%   —   —   —       polyethylene glycol (MW 400)   —   70%   —   —       N-methylpyrrolid-2-one   —   20%   —   —       epoxidised coconut oil   —   —    1%    5%       benzine (boiling range: 160-190°)   —   —   94%   —                  
 
      Mixing finely ground active ingredient and additives gives a solution suitable for use in the form of microdrops.  
                                                               Example F3: Granules   a)   b)   c)   d)                          active ingredient    5%   10%    8%   21%           kaolin   94%   —   79%   54%           highly dispersed silicic acid    1%   —   13%    7%           attapulgite   —   90%   —   18%                      
 
      The active ingredient is dissolyed in dichloromethane, the solution is sprayed onto the carrier mixture and the solvent is evaporated off in vacuo.  
     BIOLOGICAL EXAMPLES  
     EXAMPLE B1  
     Action against  Heliothis virescens  Caterpillars  
      Young soybean plants are sprayed with an aqueous emulsion spray mixture comprising 400 ppm of active ingredient. After the spray-coating has dried, the soybean plants are populated with 10 caterpillars of Heliothis virescens in the first stage and placed in a plastics container. Evaluation is made 6 days later. The percentage reduction in population and the percentage reduction in feeding damage (% activity) are determined by comparing the number of dead caterpillars and the feeding damage on the treated plants with that on untreated plants.  
      The compounds of the Tables exhibit good activity against  Heliothis virescens  in this test. In particular, the compounds 1.1 to 1.13 and 1.15 to 1.27 are more than 80% effective.  
     EXAMPLE B2  
     Action against  Plutella xylostella  caterpillars  
      Young cabbage plants are sprayed with an aqueous emulsion spray mixture comprising 400 ppm of active ingredient. After the spray-coating has dried, the cabbage plants are populated with 10 caterpillars of  Plutella xylostella  in the third stage and placed in a plastics container. Evaluation is made 3 days later. The percentage reduction in population and the percentage reduction in feeding damage (% activity) are determined by comparing the number of dead caterpillars and the feeding damage on the treated plants with that on untreated plants.  
      The compounds of the Tables exhibit good activity against  Plutella xylostella  in this test. In particular, the compounds 1.1 to 1.13 and 1.15 to 1.27 are more than 80% effective.  
     EXAMPLE B3  
     Action against  Spodoptera littoralis    
      Young soybean plants are sprayed with an aqueous emulsion spray mixture comprising 400 ppm of active ingredient and, after the spray-coating has dried, the plants are populated with 10 caterpillars of  Spodoptera littoralis  in the first stage and then placed in a plastics container. 3 days later, the percentage reduction in population and the percentage reduction in feeding damage (% activity) are determined by comparing the number of dead caterpillars and the feeding damage on the treated plants with that on untreated plants.  
      The compounds of the Tables exhibit good activity against  Spodoptera littoralis  in this test. In particular, the compounds 1.1 to 1.13 and 1.15 to 1.27 are more than 80% effective.