Patent Publication Number: US-11639465-B2

Title: Phosphor and method for producing the phosphor

Description:
RELATED APPLICATIONS 
     The present application is divisional of U.S. patent application Ser. No. 16/302,748, filed on Nov. 19, 2018, which is a National Stage of PCT application No. PCT/EP2017/070329 filed on Aug. 10, 2017, which claims priority from German application No. 10 2016 121 692.5 filed on Nov. 11, 2016 and from German application No. 10 2016 114 993.4 filed on Aug. 12, 2016, all of which are incorporated herein by reference in their entirety. 
    
    
     TECHNICAL FIELD 
     Various embodiments relate to a phoshor and to a method for producing a phosphor. 
     BACKGROUND 
     Phosphors which can be efficiently excited with ultraviolet, blue or green primary radiation and have an efficient emission in the blue, green, yellow, red or deep-red spectral range are of very great interest for the production of white and colored light-emitting diodes (LEDs). Such so-called conversion LEDs are used for many applications, for example for general lighting, display backlighting, signage, in automobiles and in numerous further consumer products. In order to obtain an increase in efficiency, a higher robustness, a better color quality, color space coverage and/or color fidelity of the conversion LEDs, in order firstly to improve the applications and secondly to extend the application spectrum of the conversion LEDs, there is great demand for new phosphors. 
     Known phosphors having an emission in the green to red spectral range with a relatively small full width at half maximum (FWHM) are, for example, EAS:Eu or EAGa 2 S 4 :Eu (EA=alkaline earth metals). However, these phosphors are not very robust and exhibit a temperature-dependent decrease in the intensity of the emitted radiation (thermal quenching). 
     Nitridosilicates and nitridoalumosilicates of the formula M 2 Si 5 N 8 :Eu, MAlSiN 3 :Eu or MM′Si 2 Al 2 N 6 :Eu where M, M′=Mg, Ca, Sr or M, M′=Mg, Ca, Sr, Ba emit in the orange to red spectral range and are very efficient and stable. What is disadvantageous about these phosphors is the relatively large full width at half maximum of the emission band, their expensive starting materials and a complex production method. In some instances, these phosphors are also not resistant to moisture. 
     Garnets of the formula A 3 B 5 O 12 :Ce (A=rare earth metal, B═Al, Ga) and their derivatives emit in the green and yellow spectral range and have a high resistance and a high conversion efficiency. What is disadvantageous about these phosphors is the relatively large full width at half maximum of the emission band and limited adjustability of the emission wavelength. In this regard, an emission in the red spectral range cannot be achieved, for example. 
     Orthosilicates and oxonitridoorthosilicates of the formula M 2 SiO 4 :Eu, M 2−x−a RE x Eu a SiO 4−x N x  or M 2−x−a RE x Eu a Si 1−y O 4−x−2y N x  (M=Sr, Ba, Ca, Mg; RE=rare earth metal) emit radiation in the green to orange spectral range. The main disadvantages of these phosphors are a relatively large full width at half maximum of the emission band and a limited adjustability of the emission wavelength; an emission in the red spectral range cannot be achieved, for example. Moreover, the phosphors exhibit a thermal quenching behavior and are not very robust. 
     Oxonitridosilicates and SiAlONs of the formula MSi 2 O 2 N 2 :Eu, Si 6-z Al z O z N 8-z :RE or Si 6-x Al z O y N 8-y :RE z  (RE=rare earth metal) emit radiation in the blue to yellow spectral range. The main disadvantages of these phosphors are a relatively large full width at half maximum of the emission band and a limited adjustability of the emission wavelength. Moreover, the phosphors in some instances are not very efficient and stable and are expensive to produce inter alia owing to expensive starting materials. 
     Nitridoaluminates of the formula MLiAl 3 N 4 :Eu (M=Ca, Sr) emit in the deep-red spectral range and have a high radiation stability and a high conversion efficiency. A limited adjustability of the emission wavelength is disadvantageous; a narrowband emission in the green and yellow spectral range cannot be achieved, for example. Moreover, these phosphors are expensive to produce and moreover in some instances are not resistant to moisture influences. 
     SUMMARY 
     The object of the present disclosure is to specify phosphors which can be efficiently excited by means ultraviolet, blue or green primary radiation and have an efficient emission in the blue, green, yellow, red and/or deep-red spectral range. A further object is to specify a method for producing phosphors which can be carried out cost-effectively and simply. 
     The objects are achieved by means of a phosphor and a method for producing a phosphor as claimed in the independent claims. Advantageous embodiments and developments of the present disclosure are specified in the respective dependent claims. 
     A phosphor is specified. The phosphor has the general molecular formula:
 
(MA) a (MB) b (MC) c (MD) d (TA) e (TB) f (TC) g (TD) h (TE) i (TF) j (XA) k (XB) l (XC) m (XD) n .
 
     In this case, MA is selected from a group of monovalent metals, MB is selected from a group of divalent metals, MC is selected from a group of trivalent metals, MD is selected from a group of tetravalent metals, TA is selected from a group of monovalent metals, TB is selected from a group of divalent metals, TC is selected from a group of trivalent metals, TD is selected from a group of tetravalent metals, TE is selected from a group of pentavalent elements, TF is selected from a group of hexavalent elements, XA is selected from a group of elements which comprises halogens, XB is selected from a group of elements which comprises O, S and combinations thereof, XC═N and XD=C. The following furthermore hold true:
         a+b+c+d=t;   e+f+g+h+i+j=u   k+l+m+n=v   a+2b+3c+4d+e+2f+3g+4h+5i+6j−k−2l−3m−4n=w   0.8≤t≤1   3.5≤u≤4   3.5≤v≤4   (−0.2)≤w≤0.2.       

     In accordance with at least one embodiment, the phosphor comprises within its molecular formula at least Eu, Ce, Yb and/or Mn. Eu, Ce, Yb and/or Mn serve as activators of the phosphor which is responsible for the emission of radiation. The phosphor can thus have in particular the following formula: (MA) a (MB) b (MC) c (MD) d (TA) e (TB) f (TC) g (TD) h (TE) i (TF) j (XA) k (XB) l (XC) m (XD) n :E, wherein E=Eu, Ce, Yb and/or Mn. 
     Here and hereinafter phosphors are described on the basis of molecular formulae. In the case of the specified molecular formulae it is possible for the phosphor to comprise further elements for instance in the form of impurities, wherein these impurities taken together should advantageously have at most a proportion by weight in the phosphor of at most 1 per mille or 100 ppm (parts per million) or 10 ppm. 
     In accordance with at least one embodiment, the following holds true for the phosphor having the general molecular formula (MA) a (MB) b (MC) c (MD) d (TA) e (TB) f (TC) g (TD) h (TE) i (TF)(XA) k (XB) l (XC) m (XD) n  or (MA) a (MB) b (MC) c (MD) d (TA) e (TB) f (TC) g (TD) h (TE) i (TF) j (XA) k (XB) l (XC) m (XD) n :E: 0≤m&lt;0.875 v and/or v≥l&gt;0.125 v. 
     The assignment of the elements to MA, MB, MC, MD, TA, TB, TC, TD, TE, TF is based in particular on the arrangement thereof within the crystal structures of the phosphors. In particular, in this case, within the crystal structures TA, TB, TC, TD, TE and/or TF are surrounded by XA, XB, XC and/or XD and the resultant structural units are linked via common corners and edges. The corner and edge linkage of the structural units results in particular in the formation of cavities or channels in which MA, MB, MC and/or MD are arranged. On account of this assignment, it is possible for the possible elements in MA, MB, MC, MD, TA, TB, TC, TD, TE and TF to overlap. 
     In accordance with at least one embodiment, the phosphor has the following general molecular formula:
 
(MA) a (MB) b (TA) e (TB) f (TC) g (TD) h (XC) m (XB) l ,
 
     wherein
         MA is selected from a group of monovalent metals which comprises Li, Na, K, Rb, Cs, Cu, Ag and combinations thereof,   MB is selected from a group of divalent metals which comprises Mg, Ca, Sr, Ba, Zn, Mn, Eu, Yb, Ni, Fe, Co and combinations thereof,   TA is selected from a group of monovalent metals which comprises Li, Na, Cu, Ag and combinations thereof,   TB is selected from a group of divalent metals which comprises Mg, Zn, Mn, Eu, Yb, Ni and combinations thereof,   TC is selected from a group of trivalent metals which comprises B, Al, Ga, In, Y, Fe, Cr, Sc, rare earths and combinations thereof,   TD is selected from a group of tetravalent metals which comprises Si, Ge, Sn, Mn, Ti, Zr, Hf, Ce and combinations thereof,   XB is selected from a group of elements which comprises O, S and combinations thereof,   XC═N   a+b=t   e+f+g+h=u   l+m=v   a+2b+e+2f+3g+4h−2l−3m=w   0.8≤t≤1   3.5≤u≤4   3.5≤v≤4   (−0.2)≤w≤0.2 and       

     0≤m&lt;0.875 v and/or v≥l&gt;0.125 v. The phosphor contains in particular within its molecular formula at least Eu, Ce, Yb and/or Mn and has in particular the molecular formula (MA) a (MB) b (TA) e (TB) f (TC) g (TD) h (XC) m (XB) l :E where E=Eu, Ce, Yb and/or Mn. The following advantageously hold true:
         MA is selected from a group of monovalent metals which comprises Li, Na, K, Rb, Cs and combinations thereof,   MB is selected from a group of divalent metals which comprises Mg, Ca, Sr, Ba, Eu and combinations thereof,   TA is selected from a group of monovalent metals which comprises Li, Na, Cu, Ag and combinations thereof,   TB is selected from a group of divalent metals which comprises Eu,   TC is selected from a group of trivalent metals which comprises B, Al, Ga, In and combinations thereof,   TD is selected from a group of tetravalent metals which comprises Si, Ge, Sn, Mn, Ti and combinations thereof,   XB═O.       

     0≤m&lt;0.875 v and/or v≥l&gt;0.125 v means that the mol proportion of XC, that is to say nitrogen, in the phosphor is below 87.5 mol % relative to the total substance amount v of XA, XB, XC and XD and/or the molar proportion of XB, that is to say oxygen and/or sulphur, in the phosphor is above 12.5 mol % relative to the total substance amount v of XA, XB, XC and XD. 
     In accordance with at least one embodiment, MA, MB, MC, MD, TA, TB, TC, TD, TE and TF are the corresponding monovalent, divalent, trivalent, tetravalent, pentavalent or hexavalent cations. In other words, MA and TA have the oxidation number +1, MB and TB have the oxidation number +2, MC and TC have the oxidation number +3, MD and TD have the oxidation number +4, TE has the oxidation number +5 and TF has the oxidation number +6. XA, XB, XC and XD are, in particular, the anions of the corresponding elements. In this case, XA advantageously has the oxidation number −1, XB the oxidation number −2, XC, that is to say N, the oxidation number −3 and XD, that is to say C, the oxidation number −4. 
     WO 2013/175336 A1 describes a new family of red-emitting phosphors which have an emission having small values of the full width at half maximum. The phosphors disclosed therein have a proportion of at least 87.5% nitrogen and at most 12.5% oxygen relative to the total amount of anionic elements of the phosphor. In accordance with WO 2013/175336 A1, a higher oxygen content in the phosphors leads to unstable compounds. Consequently, phosphors having an oxygen content of more than 12.5% could not be isolated. 
     Here and hereinafter the full width at half maximum is understood to mean the spectral width at the level of half the maximum of the emission peak, FWHM for short. The emission peak is understood to mean the peak having the maximum intensity. 
     The inventors of the present disclosure have surprisingly established that a higher oxygen and/or sulfur proportion, that is to say an oxygen and/or sulfur proportion in the phosphor of more than 12.5 mol % relative to the total substance amount of anionic elements, or a lower nitrogen proportion, that is to say a nitrogen proportion in the phosphor of less than 87.5 mol % relative to the total substance amount of anionic elements, leads to very stable and efficient phosphors having a high quantum efficiency. The phosphors have a high absorptivity in the UV range to green range, in particular between 300 nm and 500 nm or between 300 nm and 460 nm, advantageously between 300 nm and 430 nm or 300 nm and 450 nm, and can thus be efficiently excited by a primary radiation in this wavelength range. The primary radiation can be converted completely (full conversion) or partly (partial conversion) into a radiation of longer wavelength, also called secondary radiation, by the phosphors. 
     In accordance with at least one embodiment, it advantageously holds true that: 0≤m&lt;0.75 v or v≥l&gt;0.25 v, 0≤m&lt;0.625 v or v≥l&gt;0.375 v. Particularly advantageously: 0≤m&lt;0.5 v or v≥l&gt;0.5 v, 0≤m&lt;0.375 v or v≥l&gt;0.625 v, 0≤m&lt;0.25 v or v≥l&gt;0.7 v, 0≤m&lt;0.125 v or v≥l&gt;0.875 v or m=0 or l=v. 
     The inventors have discovered that, surprisingly, with increasing oxygen and/or sulfur content or with decreasing nitrogen content, the peak wavelength of the phosphors shifts toward shorter wavelengths and moreover very stable phosphors result. As a result it is advantageously possible to correspondingly set the desired peak wavelength of the phosphor by varying the oxygen or nitrogen content. Moreover, the peak wavelength and/or the full width at half maximum of the phosphor can be varied by combinations or substitutions of the metals or elements MA, MB, MC, MD, TA, TB, TC, TD, TE, TF, XA, XC, XD and/or XB. A possibility has thus been found of providing phosphors which, in terms of their properties, in particular the peak wavelength and the full width at half maximum, can be adapted in a targeted manner for a corresponding application and in this case are surprisingly also still very stable. In particular, the phosphors can have very narrow values of the full width at half maximum, for example below 50 nm, below 30 nm or below 20 nm, which makes the phosphors interesting for many applications, for example for backlighting applications. 
     In the present case, “peak wavelength” denotes the wavelength in the emission spectrum at which the maximum intensity is present in the emission spectrum. 
     In accordance with at least one embodiment, the following hold true for the phosphor having the molecular formula (MA) a (MB) b (MC) c (MD) d (TA) e (TB) f (TC) g (TD) h (TE) i (TF) j (XA) k (XB) l (XC) m (XD) n :E: 
     a+b+c+d=1; 
     e+f+g+h+i+j=4; 
     k+l+m+n=4; 
     a+2b+3c+4d+e+2f+3g+4h+5i+6j−k−2l−3m−4n=0 and m&lt;3.5 or l&gt;0.5. This is therefore an electroneutral phosphor. 
     In accordance with at least one embodiment, it holds true that n=0, k=0, v=4 and m&lt;3.5 and l&gt;0.5. Then the phosphor thus has the following molecular formula: (MA) a (MB) b (MC) c (MD) d (TA) e (TB) f (TC) g (TD) h (TE) i (TF) j  (XB) l (XC) m :E. In this case, MA, MB, MC, MD, TA, TB, TC, TD, TE, TF, XC and XB are defined as above. In accordance with this embodiment, the phosphor comprises only nitrogen and oxygen, nitrogen and sulfur or nitrogen, sulfur and oxygen, advantageously only nitrogen and oxygen, as anions. However, this does not exclude the presence of further, including anionic, elements in the form of impurities. It advantageously holds true that m&lt;3.0 and l&gt;1.0; m&lt;2.5 and l&gt;1.5; m&lt;2.0 and =l&lt;2.0; m&lt;1.5 and l&gt;2.5; m&lt;1.5 and l&gt;2.5; m&lt;1.0 and l&gt;3.0; m&lt;0.5 and l&gt;3.5 or m=0 and l=4. 
     In accordance with at least one embodiment, the phosphor has the general molecular formula (MA) a (MB) b (TA) e (TD) h (XB) l (XC) m :E. In this case, the following advantageously hold true:
         MA is selected from a group of monovalent metals which comprises Li, Na, K, Rb, Cs, Cu, Ag and combinations thereof. Particularly advantageously, MA is selected from a group of monovalent metals which comprises Li, Na, K, Rb, Cs and combinations thereof,   MB is selected from a group of divalent metals which comprises Mg, Ca, Sr, Ba, Zn, Mn, Eu, Yb, Ni, Fe, Co and combinations thereof. Particularly advantageously, MB is selected from a group of divalent metals which comprises Mn, Eu, Yb and combinations thereof. Very particularly advantageously, MB=Eu or a combination of Eu and Mn and/or Yb,   TA is selected from a group of monovalent metals which comprises Li, Na, Cu, Ag and combinations thereof. Particularly advantageously, TA is selected from a group of monovalent metals which comprises Li, Na and combinations thereof. Very particularly advantageously, TA=Li,   TD is selected from a group of tetravalent metals which comprises Si, Ge, Sn, Mn, Ti, Zr, Hf, Ce and combinations thereof. Particularly advantageously, TD is selected from a group of tetravalent metals which comprises Si, Ge, Sn, Mn, Ti, and combinations thereof. Very particularly advantageously, TD=Si,   XB is selected from a group of elements which comprises O, S and combinations thereof. Particularly advantageously, XB═O,   XC═N. The following furthermore hold true:   a+b=t,   e+h=u,   l+m=v,   a+2b+e+4h−2l−3m=w   0.8≤t≤1   3.5≤u≤4   3.5≤v≤4   (−0.2)≤w≤0.2   0≤m&lt;0.875 v and/or v≤l&gt;0.125 v and   E=Eu, Ce, Yb and/or Mn, advantageously E=Eu.       

     In accordance with at least one embodiment, the phosphor has the general molecular formula (MA) a (MB) b (TA) e (TD) h (XB) l (XC) m :E. In this case, the following hold true:
         MA is selected from a group of monovalent metals which comprises Li, Na, K, Rb, Cs, Cu, Ag and combinations thereof. Advantageously, MA is selected from a group of monovalent metals which comprises Li, Na, K, Rb and combinations thereof,   MB is selected from a group of divalent metals which comprises Mg, Ca, Sr, Ba, Zn, Mn, Eu, Yb, Ni, Fe, Co and combinations thereof. It is advantageously selected from a group of divalent metals which comprises Mn, Eu, Yb and combinations thereof. Particularly advantageously, MB=Eu or a combination of Eu with Mn and/or Yb,   TA is selected from a group of monovalent metals which comprises Li, Na, Cu, Ag and combinations thereof. Advantageously, TA is selected from a group of monovalent metals which comprises Li, Na and combinations thereof. Particularly advantageously, TA=Li,   TD is selected from a group of tetravalent metals which comprises Si, Ge, Sn, Mn, Ti, Zr, Hf, Ce and combinations thereof. Advantageously, TD is selected from a group of tetravalent metals which comprises Si, Ge, Sn, Mn, Ti, and combinations thereof. Particularly advantageously, TD=Si,   XB is selected from a group of elements which comprises O, S and combinations thereof. Advantageously, XB═O.   XC═N. The following furthermore hold true:   a+b=1;   e+h=4;   l+m=4;   a+2b+e+4h−2l−3m=0 and m&lt;3.5 or l&gt;0.5 and E=Eu, Ce, Yb and/or Mn, advantageously E=Eu.       

     In accordance with at least one embodiment, the phosphor has the general molecular formula (MA) a (MB) b (TA) e (TC) g (TD) h (XB) l (XC) m :E auf, wherein
         MA is selected from a group of monovalent metals which comprises Li, Na, K, Rb, Cs, Cu, Ag and combinations thereof,   MB is selected from a group of divalent metals which comprises Mg, Ca, Sr, Ba, Zn, Mn, Eu, Yb, Ni, Fe, Co and combinations thereof,   TA is selected from a group of monovalent metals which comprises Li, Na, Cu, Ag and combinations thereof,   TC is selected from a group of trivalent metals which comprises B, Al, Ga, In, Y, Fe, Cr, Sc, rare earths and combinations thereof,   TD is selected from a group of tetravalent metals which comprises Si, Ge, Sn, Mn, Ti, Zr, Hf, Ce and combinations thereof,   XB is selected from a group of elements which comprises O, S and combinations thereof,   XC═N   a+b=t   e+g+h=u   l+m=v   a+2b+e+3g+4h−2l−3m=w   0.8≤t≤1   3.5≤u≤4   3.5≤v≤4   (−0.2)≤w≤0.2 and       

     E=Eu, Ce, Yb and/or Mn. It advantageously holds true that: 0≤m&lt;0.875 v and/or v≥l&gt;0.125 v. In accordance with this embodiment, the phosphor comprises only nitrogen and oxygen, nitrogen and sulfur or nitrogen, sulfur and oxygen, advantageously only nitrogen and oxygen, as anions. 
     In accordance with at least one embodiment, the phosphor has the general molecular formula (MA) a (MB) b (TA) e (TC) g (TD) h (XB) l (XC) m :E auf, wherein
         MA is selected from a group of monovalent metals which comprises Li, Na, K, Rb, Cs, Cu, Ag and combinations thereof,   MB is selected from a group of divalent metals which comprises Mg, Ca, Sr, Ba, Eu and combinations thereof,   TA is selected from a group of monovalent metals which comprises Li, Na, Cu, Ag and combinations thereof,   TC is selected from a group of trivalent metals which comprises B, Al, Ga and combinations thereof,   TD is selected from a group of tetravalent metals which comprises Si, Ge and combinations thereof,   XB═O,   XC═N   a+b=1   e+g+h=4   l+m=4   a+2b+e+3g+4h−2l−3m=0 and       

     E=Eu, Ce, Yb and/or Mn. Advantageously, m&lt;3.5 or l&gt;0.5. This is therefore an electroneutral phosphor comprising only nitrogen and oxygen as anions. 
     In accordance with at least one embodiment, the phosphor has the general molecular formula (MA) a (MB) b (TA) e (TC) g (TD) h (XB) l (XC) m :E, wherein
         MA is selected from a group of monovalent metals which comprises Li, Na, K and combinations thereof,   MB is selected from a group of divalent metals which comprises Mg, Ca, Sr, Ba, Eu and combinations thereof,   TA=Li,   TC=Al,   TD=Si,   XB═O,   XC═N   a+b=1   e+g+h=4   l+m=4   a+2b+e+3g+4h−2l−3m=0 and E=Eu, Ce, Yb and/or Mn, advantageously E=Eu. Advantageously, m&lt;3.5 or l&gt;0.5. This is therefore an electroneutral phosphor comprising only nitrogen and oxygen as anions. The phosphor contains within its molecular formula at least Eu, Ce, Yb and/or Mn.       

     In accordance with at least one embodiment, the phosphor is an oxide, that is to say that only oxygen is present as anionic element in the phosphor. The phosphor then has one of the following general molecular formulae:
 
(MA) 1 (TA) 3 (TD) 1 (XB) 4 :E,
 
(MA) 1 (TA) 3−x (TD) 1−x (TB) x (TC) x (XB) 4 :E,
 
(MA) 1−x′ (MB) x′ (TA) 3 (TD) 1−x (TC) x (XB) 4 :E,
 
(MA) 1−x″ (MB) x″ (TA) 3−x″ (TD) 1−x″ (TB) 2x″ (XB) 4 :E,
 
(MA) 1 (TA) 3−2z (TB) 3z (TD) 1−z (XB) 4 :E or
 
(MA) 1 (TA) 3 (TD) 1−2z′ (TC) z′ (TE) z′ (XB) 4 :E, wherein
 
     XB═O, 
     0≤x≤1, for example x=0, 0.1; 0.2; 0.3; 0.4; 0.5; 0.6; 0.7; 0.8; 0.9 or 1, advantageously 0&lt;x&lt;1, for example x=0.1; 0.2; 0.3; 0.4; 0.5; 0.6; 0.7; 0.8 or 0.9, 
     0≤x′≤1, for example x′=0, 0.1; 0.2; 0.3; 0.4; 0.5; 0.6; 0.7; 0.8; 0.9 or 1, advantageously 0&lt;x′&lt;1, for example x′=0.1; 0.2; 0.3; 0.4; 0.5; 0.6; 0.7; 0.8 or 0.9, 
     0≤x″≤1, for example x″=0, 0.1; 0.2; 0.3; 0.4; 0.5; 0.6; 0.7; 0.8; 0.9 or 1, advantageously 0&lt;x&lt;1, for example x′=0.1; 0.2; 0.3; 0.4; 0.5; 0.6; 0.7; 0.8 or 0.9, 
     0≤z≤1, advantageously z=0, 0.1; 0.2; 0.3; 0.4; 0.5; 0.6; 0.7; 0.8; 0.9 or 1, advantageously 0&lt;z&lt;1, for example z=0.1; 0.2; 0.3; 0.4; 0.5; 0.6; 0.7; 0.8 or 0.9, 
     0≤z′≤0.5, advantageously 0&lt;z′&lt;0.5, for example z′=0, 0.1; 0.2; 0.3 or 0.4, 
     and E is selected from a group comprising Eu, Ce, Yb, Mn and combinations thereof. 
     Here and hereinafter E can also be referred to as activator. The activator and in particular its surroundings in the host lattice are responsible for the luminescence, in particular the peak wavelength of the emission of the phosphor. 
     The metals or elements MA, MB, TA, TB, TC, TD, TE and/or XB form in the phosphors in particular the host lattice; in this case, E can partly replace lattice sites of the cationic elements MA, MB, TA, TB, TC, TD and/or TE, or occupy interstitial sites. In particular, in this case E occupies the lattice sites of MA. For charge balancing, the proportion of the further elements, for example that of TA and/or TD, may change. 
     In accordance with at least one embodiment, the phosphor is an oxide or oxonitride, advantageously an oxonitride, and therefore has in its molecular formula only oxygen or oxygen and nitrogen as anionic elements. In this case, the phosphor can have one of the following general molecular formulae:
 
(MA) 1−y (TB) y (TA) 3−2y (TC) 3y (TD) 1−y (XB) 4−4y (XC) 4y :E,
 
(MA) 1−y* (MB) y* (TA) 3−2y* (TC) y* (TD) 1−y* (XB) 4−4y* (XC) 4y* :E,
 
(MA) 1 (TA) 3−y′ (TC) y′ (TD) 1 (XB) 4−2y′ (XC) 2y′ :E,
 
(MA) 1 (TA) 3−y″ (TB) y″ (TD) 1 (XB) 4−y″ (XC) y″ :E,
 
(MA) 1−w′″ (MB) w′″ (TA) 3 (TD) 1 (XB) 4−w′″ (XC) w′″ :E,
 
(MA) 1 (TA) 3−w′ (TC) 2w′ (TD) 1−w′ (XB) 4−w′ (XC) w′ :E or
 
(MA) 1−w″ (MB) w″ (TA) 3−w″ (TD) 1−w″ (TC) 2w″ (XB) 4−2w″ (XC) 2w″ :E,
 
     wherein 
     XB═O, 
     0≤y≤1, for example y=0; 0.1; 0.2; 0.3; 0.4; 0.5; 0.6; 0.7; 0.8; 0.9 or 1, advantageously 0&lt;y&lt;0.875, for example y=0.1; 0.2; 0.3; 0.4; 0.5; 0.6; 0.7 or 0.8, very particularly advantageously 0≤y≤0.4, 
     0&lt;y*&lt;0.875 or advantageously 0&lt;y*≤0.5, particularly advantageously 0&lt;y*≤0.3, very particularly advantageously 0&lt;y*≤0.1, 
     0≤y′≤2, for example y′=0, 0.1; 0.2; 0.3; 0.4; 0.5; 0.6; 0.7; 0.8; 0.9; 1.0; 1.1; 1.2; 1.3; 1.4; 1.5; 1.6; 1.7; 1.8; 1.9 or 2.0, advantageously 0&lt;y′≤1.75, particularly advantageously 0≤y′≤0.9, 
     0≤y″≤3, for example y″=0, 0.1; 0.2; 0.3; 0.4; 0.5; 0.6; 0.7; 0.8; 0.9; 1.0; 1.1; 1.2; 1.3; 1.4; 1.5; 1.6; 1.7; 1.8; 1.9; 2.0; 2.1; 2.2; 2.3; 2.4; 2.5; 2.6; 2.7; 2.8; 2.9 or 3.0, advantageously 0&lt;y″&lt;3, particularly advantageously 0&lt;y″≤1.9, 
     0≤w′″≤1, for example w′″=0, 0.1; 0.2; 0.3; 0.4; 0.5; 0.6; 0.7; 0.8; 0.9 or 1, advantageously 0&lt;w′″&lt;1, 
     0≤w′≤1, for example w′=0, 0.1; 0.2; 0.3; 0.4; 0.5; 0.6; 0.7; 0.8; 0.9 or 1, advantageously 0&lt;w′&lt;1, 
     0≤w″≤1, for example w″=0, 0.1; 0.2; 0.3; 0.4; 0.5; 0.6; 0.7; 0.8; 0.9 or 1, advantageously 0&lt;w″&lt;1, and E is selected from a group which comprises Eu, Ce, Yb, Mn and combinations thereof. 
     In accordance with at least one embodiment, E is selected from a group which comprises Eu, Ce, Yb, Mn and combinations thereof. In particular, E is Eu 3+,  Eu 2+,  Ce 3+,  Yb 3+,  Yb 2+  and/or Mn 4+ . 
     The metals or elements MA, MB, TA, TB, TC, TD, XC and/or XB form the host lattice in the phosphors; in this case, E can partly replace lattice sites of MA, MB, TA, TB, TC and/or TD, advantageously of MA, or occupy interstitial sites. 
     By using the activators Eu, Ce, Yb and/or Mn, in particular Eu or Eu in combination with Ce, Yb and/or Mn, it is possible for the color locus of the phosphor in the CIE color space, the peak wavelength λpeak thereof or the dominant wavelength λdom thereof, and the full width at half maximum to be set particularly well. 
     The dominant wavelength is a possibility for describing non-spectral (polychromatic) light mixtures by spectral (monochromatic) light that produces a similar hue perception. In the CIE color space, the line connecting a point for a specific color and the point CIE-x=0.333, CIE-y=0.333 can be extrapolated such that it meets the contour of the space at two points. The intersection point that is nearer to said color represents the dominant wavelength of the color as wavelength of the pure spectral color at this intersection point. The dominant wavelength is thus the wavelength that is perceived by the human eye. 
     In accordance with a further embodiment, the activator E can be present in mol % amounts of between 0.1 mol % and 20 mol %, 1 mol % and 10 mol %, 0.5 mol % and 5 mol %, 2 mol % and 5 mol %. Excessively high concentrations of E may lead to a loss of efficiency as a result of concentration quenching. Here and hereinafter, mol % indications for the activator E, in particular Eu, are understood in particular as mol % indications relative to the molar proportions of MA, MB, MC and MD in the respective phosphor. 
     In accordance with at least one embodiment, the phosphor has one of the following general molecular formulae:
 
(MA)Li 3−x Si 1−x Zn x Al x O 4 :E;
 
(MA)Li 3−x Si 1−x Mg x Al x O 4 :E;
 
(MA) 1−x′ Ca x′ Li 3 Si 1−x′ Al x′ O 4 :E;
 
(MA) 1−x″ Ca x″ Li 3−x″ Si 1−x″ Mg 2x″ O 4 :E;
 
(MA)Li 3−2z Mg 3z Si 1−z O 4 :E;
 
(MA)Li 3 Si 1−2z′ Al z′ P z′ O 4 :E.
 
In particular, MA, E, x, x′, x″, z and z′ are accorded the definitions disclosed above.
 
     Proceeding from the phosphor of the molecular formula (MA)Li 3 SiO 4 :E, in accordance with at least one embodiment, LiSi can be at least partly replaced by ZnAl or MgAl and a phosphor of the formula (MA)Li 3−x Si 1−x Zn x Al x O 4 :E or (MA)Li 3−x Si 1−x Mg x Al x O 4 :E is obtained. 
     Proceeding from the phosphor of the molecular formula (MA)Li 3 SiO 4 :E in accordance with at least one embodiment, (MA)Si can be at least partly replaced by CaAl and a phosphor of the formula (MA) 1−x′ Ca x′ Li 3 Si 1−x′ Al x′ O 4 :E is obtained. 
     Proceeding from the phosphor of the molecular formula (MA)Li 3 SiO 4 :E in accordance with at least one embodiment, (MA)LiSi can be at least partly replaced by CaMg 2  and a phosphor of the formula (MA) 1−x″ Ca x″ Li 3−x″ Si 1−x″ Mg 2x ″O 4 :E is obtained. 
     Proceeding from the phosphor of the molecular formula (MA)Li 3 SiO 4 :E in accordance with at least one embodiment, Li 2 Si can be at least partly replaced by Mg 3  and a phosphor of the formula (MA)Li 3−2z Mg 3z Si 1−z O 4 :E is obtained. 
     Proceeding from the phosphor of the molecular formula (MA)Li 3 SiO 4 :E in accordance with at least one embodiment, Si 2  can be at least partly replaced by AlP and a phosphor of the formula (MA)Li 3 Si 1−2z′ Al z′ P z′ O 4 :E is obtained. 
     In accordance with at least one embodiment, the phosphor has one of the following general molecular formulae:
 
(MA) 1−y Zn y Li 3−2y Al 3y Si 1−y O 4−4y N 4y :E
 
(MA) 1−y* Ca y* Li 3−2y* Al 3y* Si 1−y* O 4−4y* N 4y* :E,
 
(MA) 1−y*** Sr y*** Li 3−2y*** Al 3y*** Si 1−y*** O 4−4y*** N 4y*** :E
 
(MA) 1−y** Eu y** Li 3−2y** Al 3y** Si 1−y** O 4−4y** N 4y* :E
 
(MA)Li 3−y′ Al y′ SiO 4−2y′ N 2y′ :E,
 
(MA)Li 3−y″ Mg y″ SiO 4−y″ N y″ :E,
 
(MA) 1−w′″ Ca w′″ Li 3 SiO 4−w′″ N w′″ :E,
 
(MA)Li 3−w′ Al 2w′ Si 1−w′ O 4−w′ N w′ :E,
 
(MA) 1−w″ Ca w″ Li 3−w′ Si 1−w″ Al 2w″ O 4−2w″ N 2w″ :E.
 
     In particular, MA, E, y, y*, y′, y″, w′″, w′ and w″ are accorded the definitions disclosed above. It furthermore holds true that 0&lt;y**≤1, advantageously 0&lt;y**&lt;0.875 or 0&lt;y**&lt;0.5, particularly advantageously 0.05≤y**≤0.45, very particularly advantageously 0.1≤y**≤0.4, 0.15≤y**≤0.35 or 0.2≤y**≤0.3 and 0≤y***≤1, advantageously 0&lt;y***&lt;0.875 or 0&lt;y***≤0.5, particularly advantageously 0&lt;y***≤0.3. 
     Proceeding from the phosphor of the molecular formula (MA)Li 3 SiO 4 :E in accordance with at least one embodiment, (MA)Li 3 SiO 4  can be at least partly replaced by CaLiAl 3 N 4  and a phosphor of the formula (MA) 1−y* Ca y* Li 3−2y* Al 3y* Si 1−y* O 4−4y* N 4y* :E is obtained. In this case, MA is selected from a group of monovalent metals which comprises Li, Na, K, Rb, Cs, Cu, Ag and combinations thereof, and E is selected from a group which comprises Eu, Ce, Yb, Mn and combinations thereof. Advantageously, MA is selected from a group of monovalent metals which comprises Li, Na, K, Rb and combinations thereof and E=Eu. Very advantageously, MA=Na. The phosphor is an oxonitridolithoalumosilicate phosphor. It holds true that 0&lt;y*&lt;0.875, advantageously 0&lt;y*≤0.5, particularly advantageously 0&lt;y*≤0.3, very particularly advantageously 0&lt;y*≤0.1. By way of example, it holds true that y*=0.01; 0.02; 0.03; 0.04 or 0.05. 
     Proceeding from the phosphor of the molecular formula (MA)Li 3 SiO 4 :E in accordance with at least one embodiment, (MA)Li 3 SiO 4  can be at least partly replaced by SrLiAl 3 N 4  and a phosphor of the formula (MA) 1−y*** Sr y*** Li 3−2y*** Al 3y*** Si 1−y*** O 4−4y*** N 4y*** :E is obtained. In this case, MA is selected from a group of monovalent metals which comprises Li, Na, K, Rb, Cs, Cu, Ag and combinations thereof and E is selected from a group which comprises Eu, Ce, Yb, Mn and combinations thereof, advantageously, E=Eu. Advantageously, MA is selected from a group of monovalent metals which comprises Li, Na, K, Rb and combinations thereof. Very advantageously, MA=Na. The phosphor is an oxonitridolithoalumosilicate phosphor. It holds true that 0&lt;y***&lt;0.875, advantageously 0&lt;y***≤0.5, particularly advantageously 0&lt;y***≤0.3. For example y***=0.25. 
     Proceeding from the phosphor of the molecular formula (MA)Li 3 SiO 4 :E in accordance with at least one embodiment, (MA)Li 3 SiO 4  can be at least partly replaced by EuLiAl 3 N 4  and a phosphor of the formula (MA) 1−y** Eu y** Li 3−2y** Al 3y** Si 1−y** O 4−4y** N 4y** :E is obtained. In this case, MA is selected from a group of monovalent metals which comprises Li, Na, K, Rb, Cs, Cu, Ag and combinations thereof, and E is selected from a group which comprises Eu, Ce, Yb, Mn and combinations thereof; advantageously, E=Eu. Advantageously, MA is selected from a group of monovalent metals which comprises Li, Na, K, Rb and combinations thereof. Very advantageously, MA=Na. The phosphor is an oxonitridolithoalumosilicate phosphor. It advantageously holds true that 0&lt;y**&lt;0.875 or 0&lt;y**&lt;0.5, particularly advantageously 0.05≤y**≤0.45, very particularly advantageously 0.1≤y**≤0.4, 0.15≤y**≤0.35 or 0.2≤y**≤0.3. Surprisingly, despite the in some instances very high proportions of Eu, the phosphor does not exhibit any concentration-governed quenching behavior and the associated loss of efficiency. Despite the high proportion of Eu, the phosphor is thus surprisingly very efficient. 
     Proceeding from the phosphor of the molecular formula (MA)Li 3 SiO 4 :E in accordance with at least one embodiment, LiO 2  can be at least partly replaced by AlN 2  and a phosphor of the formula (MA)Li 3−y″ Al y′ SiO 4−2y′ N 2y′ :E is obtained. 
     Proceeding from the phosphor of the molecular formula (MA)Li 3 SiO 4 :E in accordance with at least one embodiment, LiO can be at least partly replaced by MgN and a phosphor of the formula (MA)Li 3−y″ Mg y″ SiO 4−y″ N y″ :E is obtained. 
     Proceeding from the phosphor of the molecular formula (MA)Li 3 SiO 4 :E in accordance with at least one embodiment, (MA)O can be at least partly replaced by CaN and a phosphor of the formula (MA) 1−w′″ Ca w′″ Li 3 SiO 4−w′″ N w′″ :E is obtained. 
     Proceeding from the phosphor of the molecular formula (MA)Li 3 SiO 4 :E in accordance with at least one embodiment, LiSiO can be at least partly replaced by Al 2 N and a phosphor of the formula (MA)Li 3−w′ Al 2w′ Si 1−w′ O 4−w′ N w′ :E is obtained. 
     Proceeding from the phosphor of the molecular formula (MA)Li 3 SiO 4 :E in accordance with at least one embodiment, (MA)Li 3 SiO 2  can be at least partly replaced by CaAl 2 N 2  and a phosphor of the formula (MA) 1−w″ Ca w″ Li 3−w″ Si 1−w″ Al 2w″ O 4−2w″ N 2w″ :E is obtained. 
     In accordance with at least one embodiment, MA is selected from a group of monovalent metals which comprises Li, Na, K, Rb, Cs and combinations thereof. By way of example, MA can be chosen as follows: MA=Na, K, (Na,K), (Rb,Li). (Na,K), (Rb,Li) in this case means that a combination of Na and K or a combination of Rb and Li is present. This choice of MA yields particularly efficient phosphors that are applicable in diverse ways. 
     In accordance with at least one embodiment, the phosphor has one of the following general molecular formulae:
 
NaLi 3−x Si 1−x Zn x Al x O 4 :E,
 
NaLi 3−x Si 1−x Mg x Al x O 4 :E,
 
Na 1−x′ Ca x′ Li 3 Si 1−x′ Al x′ O 4 :E,
 
Na 1−x″ Ca x″ Li 3−x″ Si 1−x″ Mg 2x″ O 4 :E,
 
NaLi 3−2z Mg 3z Si 1−z O 4 :E,
 
NaLi 3 Si 1−2z′ Al z′ P z′ O 4 :E.
 
     In particular, x, x′, x″, z and z′ are accorded the meanings mentioned above. 
     In accordance with at least one embodiment, the phosphor has one of the following general molecular formulae:
 
(Na r K 1−r ) 1 Li 3−x Si 1−x Zn x Al x O 4 :E,
 
(Na r K 1−r ) 1 Li 3−x Si 1−x Mg x Al x O 4 :E,
 
(Na r K 1−r ) 1−x′ Ca x′ Li 3 Si 1−x′ Al x′ O 4 :E,
 
(Na r K 1−r ) 1−x″ Ca x″ Li 3−x″ Si 1−x″ Mg 2x″ O 4 :E,
 
(Na r K 1−r ) 1 Li 3−2z Mg 3z Si 1−z O 4 :E,
 
(Na r K 1−r ) 1 Li 3 Si 1−2z′ Al z′ P z′ O 4 :E, wherein
 
     0≤r≤1, for example r=0; 0.05; 0.1; 0.15; 0.2; 0.25; 0.3; 0.35, 0.4; 0.45; 0.5; 0.55; 0.6; 0.65; 0.7; 0.75; 0.8; 0.85; 0.9; 0.95; 1.0. Advantageously, 0≤r≤0.1 or 0.1&lt;r≤0.4 or 0.4&lt;r≤1.0; particularly advantageously r=0, 0.125, 0.25, 0.5 or 1.0. In particular, x, x′, x″, z and z′ are accorded the meanings mentioned above. 
     In accordance with at least one embodiment, the phosphor has one of the following general molecular formulae:
 
(Rb r′ Li 1−r′ ) 1 Li 3−x Si 1−x Zn x Al x O 4 :E,
 
(Rb r′ Li 1−r′ ) 1 Li 3−x Si 1−x Mg x Al x O 4 :E,
 
(Rb r′ Li 1−r′ ) 1−x′ Ca x′ Li 3 Si 1−x′ Al x′ O 4 :E,
 
((Rb r′ Li 1−r′ ) 1−x″ Ca x″ Li 3−x″ Si 1−x″ Mg 2x″ O 4 :E,
 
(Rb r′ Li 1−r′ ) 1 Li 3−2z Mg 3z Si 1−z O 4 :E,
 
(Rb r′ Li 1−r′ ) 1 Li 3 Si 1−2z′ Al z′ P z′ O 4 :E,
 
wherein 0≤r′≤1, for example r′=0; 0.05; 0.1; 0.15; 0.2; 0.25; 0.3; 0.35, 0.4; 0.45; 0.5; 0.55; 0.6; 0.65; 0.7; 0.75; 0.8; 0.85; 0.9; 0.95; 1.0, advantageously 0.25≤r′≤0.75, particularly advantageously 0.4≤r′≤0.6, very particularly advantageously r′=0.5. In particular, x, x′, x″, z and z′ are accorded the meanings mentioned above.
 
     In accordance with at least one embodiment, the phosphor has one of the following general molecular formulae:
 
(Na r K 1−r ) 1−y* Ca y* Li 3−2y* Al 3y* Si 1−y O 4−4y* N 4y* :E,
 
(Na r K 1−r )Li 3−y′ Al y″ SiO 4−2y′ N 2y′ :E,
 
(Na r K 1−r )Li 3−y″ Mg y″ SiO 4−y″ N y″ :E,
 
(Na r K 1−r ) 1−w′″ Ca w′″ Li 3 SiO 4−w′″ N w :E,
 
(Na r K 1−r )Li 3−w′ Al 2w′ Si 1−w′ O 4−w′ N w′ :E,
 
(Na r K 1−r ) 1−w″ Ca w″ Li 3−w″ Si 1−w″ Al 2w″ O 4−2w″ N 2w″ :E, wherein
 
     0≤r≤1, for example r=0; 0.05; 0.1; 0.15; 0.2; 0.25; 0.3; 0.35, 0.4; 0.45; 0.5; 0.55; 0.6; 0.65; 0.7; 0.75; 0.8; 0.85; 0.9; 0.95; 1.0. Advantageously, 0≤r≤0.1 or 0.1&lt;r≤0.4 or 0.4&lt;r≤1.0; particularly advantageously r=0, 0.25, 0.5 or 1.0. In particular, y*, y′, y″, w′″, w′ and w′ are accorded the meanings mentioned above. 
     In accordance with at least one embodiment, the phosphor has one of the following general molecular formulae:
 
(Rb r′ Li 1−r′ ) 1−y* Ca y* Li 3−2y* Al 3y* Si 1−y* O 4−4y* N 4y* :E,
 
(Rb r′ Li 1−r′ )Li 3−y′ Al y′ SiO 4−2y′ N 2y′ :E,
 
(Rb r′ Li 1−r′ )Li 3−y″ Mg y″ SiO 4−y″ N y″ :E,
 
(Rb r′ Li 1−r′ ) 1−w′″ Ca w′″ Li 3 SiO 4−w′″ N w :E,
 
(Rb r′ Li 1−r′ )Li 3−w′ Al 2w′ Si 1−w′ O 4−w′ N w′ :E,
 
(Rb r′ Li 1−r′ ) 1−w″ Ca w″ Li 3−w″ Si 1−w″ Al 2w″ O 4−2w″ N 2w″ :E, wherein
 
     0≤r′≤1, for example r′=0; 0.05; 0.1; 0.15; 0.2; 0.25; 0.3; 0.35, 0.4; 0.45; 0.5; 0.55; 0.6; 0.65; 0.7; 0.75; 0.8; 0.85; 0.9; 0.95; 1.0, advantageously 0.25≤r′≤0.75, particularly advantageously 0.4≤r′≤0.6, very particularly advantageously r′=0.5. In particular, y*, y′, y″, w′″, w′ and w″ are accorded the meanings mentioned above. 
     In accordance with at least one embodiment, the phosphor has one of the following general molecular formulae:
 
Na 1−y* Ca y* Li 3−2y* Al 3y* Si 1−y* O 4−4y* N 4y* :E,
 
NaLi 3−y′ Al y′ SiO 4−2y′ N 2y′ :E,
 
NaLi 3−y″ Mg y″ SiO 4−y″ N y″ :E,
 
Na 1−w′″ Ca w′″ Li 3 SiO 4−w′″ N w :E,
 
NaLi 3−w′ Al 2w′ Si 1−w′ O 4−w′ N w′ :E,
 
Na 1−w″ Ca w″ Li 3−w″ Si 1−w″ Al 2w″ O 4−2w″ N 2w″ :E.
 
In particular, y*, y′, y″, w′″, w′ and w″ are accorded the meanings mentioned above.
 
     In accordance with at least one embodiment, the phosphor has the general molecular formula (MA) 1 (TA) 3 (TD) 1 (XB) 4 :E. In this case, MA is selected from a group of monovalent metals which comprises Li, Na, K, Rb, Cs, Cu, Ag and combinations thereof. Advantageously, MA is selected from a group of monovalent metals which comprises Li, Na, K, Rb, Cs and combinations thereof. TA is selected from a group of monovalent metals which comprises Li, Na, Cu, Ag and combinations thereof. TD is selected from a group of tetravalent metals which comprises Si, Ge, Sm, Mn, Ti, Zr, Hf, Ce and combinations thereof. XB is selected from a group of elements which comprises O, S and combinations thereof. E is selected from a group which comprises Eu, Ce, Yb, Mn and combinations thereof; advantageously, E=Eu. In particular, E occupies the lattice sites of MA or interstitial sites. For charge balancing, in this case the proportion of the further elements, for example that of TA and/or TD, may change. By way of example, E=Eu 2+  and replaces MA +  in the molecular formula; the charge balancing is effected by changing the proportion of TA and/or TD. 
     In accordance with at least one embodiment, the phosphor has the general molecular formula (MA) 1 (TA) 3 (TD) 1 (XB) 4 :E. In this case, MA is selected from a group of monovalent metals which comprises Li, Na, K, Rb, Cs and combinations thereof. TA=Li, TD=Si, XB═O and E is selected from a group which comprises Eu, Ce, Yb, Mn and combinations thereof. It advantageously holds true that: E=Eu or a combination of Eu with Ce, Yb and/or Mn. 
     Surprisingly, it has been found that the properties of the phosphor, in particular with regard to the peak wavelength and the full width at half maximum, can be changed considerably by varying the composition of MA. Moreover, the phosphors have a high absorptivity of primary radiation in the range of 300 nm to 460 nm or 300 nm to 500 nm, in particular between 300 nm and 450 nm or 300 nm and 430 nm. 
     By way of example, the phosphor of the formula NaLi 3 SiO 4 :Eu, upon excitation with a primary radiation having a wavelength of 400 nm, emits in the blue spectral range of the electromagnetic spectrum and exhibits a narrowband emission, that is to say an emission having a small full width at half maximum. By contrast, upon excitation with a primary radiation having a wavelength of 400 nm, the phosphor of the formula KLi 3 SiO 4 :Eu exhibits very broadband emission from the blue to red spectral range, thus giving rise to a white-colored luminous impression. The phosphors of the formula (Na 0.5 K 0.5 )Li 3 SiO 4 :Eu, (Rb 0.25 Na 0.75 )Li 3 SiO 4 :Eu, (Cs 0.25 Na 0.5 K 0.25 )Li 3 SiO 4 :Eu, (Rb 0.25 Na 0.5 K 0.25 )Li 3 SiO 4 :Eu and (Cs 0.25 Na 0.25 Rb 0.25 Li 0.25 )Li 3 SiO 4 :Eu exhibit narrowband emission in the blue-green spectral range of the electromagnetic spectrum and the phosphors of the formula (Rb 0.5 Li 0.5 )Li 3 SiO 4 :Eu, (Rb 0.5 Na 0.5 )Li 3 SiO 4 :Eu, (Na 0.25 K 0.75 )Li 3 SiO 4 :Eu, (Na 0.25 K 0.50 Li 0.25 )Li 3 SiO 4 :Eu and (Cs 0.25 Na 0.25 K 0.25 Li 0.25 )Li 3 SiO 4 :Eu exhibit narrowband emission in the green spectral range of the electromagnetic spectrum. Upon excitation with a primary radiation having a wavelength of 460 nm, the phosphor of the formula Na 0.125 K 0.875 Li 3 SiO 4 :Eu has a band in the yellow-orange range. Besides the latter, Na 0.125 K 0.875 Li 3 SiO 4 :Eu exhibits a further emission peak having high intensity in the blue-green range. 
     The properties of the phosphors are presented in the table below: 
     
       
         
           
               
               
               
               
               
             
               
                   
                   
               
               
                   
                 λ prim   
                 λ peak   
                 λ dom   
                 FWHM 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
            
               
                 NaLi 3 SiO 4 :Eu 
                 400 nm 
                 469 nm 
                 473 nm 
                 32 nm 
               
               
                 KLi 3 SiO 4 :Eu 
                 400 nm 
                 616 nm 
                 585 nm 
                 143 nm  
               
               
                 (Na 0.5 K 0.5 )Li 3 SiO 4 :Eu 
                 400 nm 
                 486 nm 
                 493 nm 
                 19.2 nm   
               
               
                 (Rb 0.5 Li 0.5 )Li 3 SiO 4 :Eu 
                 400 nm 
                 528 nm 
                 538.7 nm   
                 42.8 nm   
               
               
                 (Na 0.25 K 0.75 )Li 3 SiO 4 :Eu 
                 400 nm 
                 529 nm 
                 541.4 nm   
                 45 nm 
               
               
                 (Na 0.25 K 0.5 Li 0.25 )Li 3 SiO 4 :Eu 
                 460 nm 
                 532 nm 
                 540.3 nm   
                 45.6 nm   
               
               
                 (Rb 0.5 Na 0.5 )Li 3 SiO 4 :Eu 
                 460 nm 
                 528 nm 
                 533 nm 
                 43.3 nm   
               
               
                 (Rb 0.25 Na 0.75 )Li 3 SiO 4 :Eu 
                 400 nm 
                 473 nm 
                 476 nm 
                 22.2 nm   
               
               
                 (Cs 0.25 Na 0.25 K 0.25 Li 0.25 )Li 3 SiO 4 :Eu 
                 400 nm 
                 530 nm 
                 532 nm 
                 46 nm 
               
               
                 (Cs 0.25 Na 0.5 K 0.25 )Li 3 SiO 4 :Eu 
                 400 nm 
                 486 nm 
                 497 nm 
                 26 nm 
               
               
                 (Rb 0.25 Na 0.5 K 0.25 )Li 3 SiO 4 :Eu 
                 400 nm 
                 480 nm 
                 490 nm 
                 27 nm 
               
               
                 (Cs 0.25 Na 0.25 Rb 0.25 Li 0.25 )Li 3 SiO 4 :Eu 
                 400 nm 
                 473 nm 
                 489 nm 
                 24 nm 
               
               
                 Na 0.125 K 0.875 Li 3 SiO 4 :Eu 
                 460 nm 
                 516 nm 
                 554 nm 
                 60 nm 
               
               
                   
               
            
           
         
       
     
     By virtue of the different emission properties, the phosphors are suitable for a wide variety of applications. 
     The blue or blue-green spectral range is understood to mean the range of the electromagnetic spectrum between 420 nm and 520 nm. 
     The green spectral range is understood to mean the range of the electromagnetic spectrum between 520 nm and 580 nm inclusive. 
     The red spectral range is understood to mean the range of the electromagnetic spectrum between 630 nm and 780 nm. 
     The yellow or yellow-orange spectral range is understood to mean the range of the electromagnetic spectrum between 580 nm and 630 nm. 
     In accordance with at least one embodiment, the phosphor has the general molecular formula (Na r K 1−r ) 1 (TA) 3 (TD) 1 (XB) 4 :E, where 0≤r≤1, for example r=0; 0.05; 0.1; 0.125; 0.15; 0.2; 0.25; 0.3; 0.35, 0.4; 0.45; 0.5; 0.55; 0.6; 0.65; 0.7; 0.75; 0.8; 0.85; 0.9; 0.95; 1.0. Advantageously, 0≤r≤0.1 or 0.1&lt;r≤0.4 or 0.4&lt;r≤1.0; particularly advantageously r=0, 0.125, 0.25, 0.5 or 1.0. Advantageously, TA=Li, TD=Si, XB═O and E=Eu, Ce, Yb and/or Mn, advantageously E=Eu. Surprisingly, the properties of the phosphor, in particular the peak wavelength and the full width at half maximum, change upon variation of the proportions of Na and K in the phosphor. As a result, a wide variety of applications are usable by virtue of these phosphors. 
     In accordance with at least one embodiment, the phosphor (Na r K 1−r ) 1 (TA) 3 (TD) 1 (XB) 4 :E or (Na r K 1−r )Li 3 SiO 4 :E crystallizes in a tetragonal, monoclinic or triclinic crystal system, in particular in a tetragonal or triclinic crystal system. Advantageously, the phosphor in accordance with this embodiment crystallizes in the space group I4 1 /a, I4/m or P-1. Particularly advantageously, the phosphor in accordance with this embodiment crystallizes in a tetragonal crystal system with the space group I4 1 /a or I4/m or in a triclinic crystal system with the space group P-1. 
     In accordance with at least one embodiment, the phosphor has the formula (Na r K 1−r ) 1 (TA) 3 (TD) 1 (XB) 4 :E where 0.4&lt;r≤1, advantageously 0.45&lt;r≤1, very particularly advantageously r=0.5 or 1. Advantageously, TA=Li, TD=Si, XB═O and E=Eu, Ce, Yb and/or Mn, and the phosphor has the formula (Na r K 1−r )Li 3 SiO 4 :E. Advantageously, it holds true that E=Eu. By way of example, the phosphor has the formula NaLi 3 SiO 4 :Eu or (Na 0.5 K 0.5 )Li 3 SiO 4 :Eu. The peak wavelength of the phosphor is in the blue spectral range, in particular in the range between 450 nm and 500 nm. 
     The phosphor (Na r K 1−r ) 1 (TA) 3 (TD) 1 (XB) 4 :E or (Na r K 1−r )Li 3 SiO 4 :E where 0.4&lt;r≤1, for example NaLi 3 SiO 4 :Eu or (Na 0.5 K 0.5 )Li 3 SiO 4 :Eu, is suitable in particular for use in conversion LEDs which emit white radiation. To that end, the phosphor can be combined with a red and green phosphor. 
     Previous white-emitting conversion LEDs use a semiconductor chip, which emits a blue primary radiation, and a red and green phosphor. A superimposition of the blue primary radiation and the red and green secondary radiation gives rise to white light. What is disadvantageous about this solution is that the epitaxially grown semiconductor chips, based for example on GaN or InGaN, can have fluctuations in the peak wavelength of the emitted primary radiation. This leads to fluctuations in the white overall radiation, such as a change in the color locus and the color rendering, since the primary radiation contributes the blue portion to the overall radiation. This is problematic particularly when a plurality of semiconductor chips is used in a device. In order to prevent fluctuations, the semiconductor chips have to be sorted in accordance with their color loci (“binning”). The closer the tolerance is set with regard to the wavelength of the emitted primary radiation, the higher the quality of devices which consist of more than one semiconductor chip. However, even after sorting with close tolerances, the peak wavelength of the semiconductor chips can change significantly in the case of variable operating temperatures and forward currents. In general lighting and other applications, this can lead to a change in the optical properties, such as the color locus and the color temperature. In backlighting applications, this can additionally lead to a shift in the blue color locus and thus to a change in the color space. 
     The phosphor (Na r K 1−r ) 1 (TA) 3 (TD) 1 (XB) 4 :E where 0.4&lt;r≤1, for example NaLi 3 SiO 4 :Eu, (Rb r* Na 1−r* ) 1 (TA) 3 (TD) 1 (XB) 4 :E where 0&lt;r*&lt;0.4, (Cs,Na,Rb,Li) 1 (TA) 3 (TD) 1 (XB) 4 :E, (Cs,Na,K) 1 (TA) 3 (TD) 1 (XB) 4 :E or (Rb,Na,K) 1 (TA) 3 (TD) 1 (XB) 4 :E or (Na 0.5 K 0.5 )Li 3 SiO 4 :Eu, can be efficiently excited with a primary radiation of 300 nm to 460 nm, advantageously 300 nm to 440 nm. The combination of semiconductor chips with a primary radiation of from 300 nm to 440 nm, for example based on GaInN, leads to the emission of a secondary radiation in the blue spectral range which is stable over a significantly wider temperature range and larger ranges for the forward currents. Since the primary radiation of 300 nm to 440 nm is not visible or is scarcely visible, a wide variety of semiconductor chips can be used as primary radiation source and a constant and stable emission spectrum of the conversion LED can nevertheless be obtained. In this regard, complex “binning” of the semiconductor chips can be avoided or simplified and the efficiency can be increased. In combination with a green and a red phosphor, (Na r K 1−r ) 1 (TA) 3 (TD) 1 (XB) 4 :E where 0.4&lt;r≤1 is thus particularly well suited to the application thereof in a white conversion LED. 
     Moreover, the phosphor (Na r K 1−r ) 1 (TA) 3 (TD) 1 (XB) 4 :E or (Na r K 1−r )Li 3 SiO 4 :E where 0.4&lt;r≤1, in particular (Na 0.5 K 0.5 )Li 3 SiO 4 :Eu, is suitable for use in lighting devices such as conversion LEDs which emit a blue radiation. 
     Such conversion LEDs are used for example for signal lights, such as blue lights. Since said signal lights firstly have to be very bright and secondly have to lie in a specific color locus range or at a specific color locus, not all blue light sources are suitable for this use. On the other hand, conversion LEDs comprising the phosphor (Na r K 1−r ) 1 (TA) 3 (TD) 1 (XB) 4 :E where 0.4&lt;r≤1, in particular (Na 0.5 K 0.5 )Li 3 SiO 4 :Eu, are suitable for suppressing melatonin production in human beings. The conversion LEDs can thus be used in a targeted manner to increase vigilance and/or the ability to concentrate. By way of example, they can contribute to overcoming jetlag more rapidly. Moreover, the phosphor or a conversion LED comprising the phosphor is suitable for “color on demand” applications, that is to say for conversion LEDs having blue color loci adapted to consumer desires, for example for realizing certain brand-specific or product-specific colors for example in advertising or else in the design of the interior fittings for automobiles. Alternatively, what is suitable for conversion LEDs which emit a blue radiation is (Rb r* Na 1−r* ) 1 (TA) 3 (TD) 1 (XB) 4 :E, wherein 0&lt;r*&lt;0.4, advantageously 0.1≤r*≤0.35, particularly advantageously 0.2≤r*≤0.3, very particularly advantageously r*=0.25 or (Cs,Na,Rb,Li) 1 (TA) 3 (TD) 1 (XB) 4 :E, (Cs,Na,K) 1 (TA) 3 (TD) 1 (XB) 4 :E and (Rb,Na,K) 1 (TA) 3 (TD) 1 (XB) 4 :E. By way of example, the phosphor has the formula NaLi 3 SiO 4 :Eu or (Na 0.5 K 0.5 )Li 3 SiO 4 :Eu, (Rb 0.25 Na 0.75 )Li 3 SiO 4 :Eu or (Cs 0.25 Na 0.25 Rb 0.25 Li 0.25 )Li 3 SiO 4 :Eu, (Cs 0.25 Na 0.5 K 0.25 )Li 3 SiO 4 :Eu or (Rb 0.25 Na 0.5 K 0.25 )Li 3 SiO 4 :Eu. 
     In accordance with at least one embodiment, the phosphor has the formula (Na r K 1−r ) 1 (TA) 3 (TD) 1 (XB) 4 :E where 0.2&lt;r≤0.4, advantageously 0.2&lt;r≤0.3, very particularly advantageously r=0.25. Advantageously, TA=Li, TD=Si and XB═O and the phosphor has the formula (Na r K 1−r )Li 3 SiO 4 :E. E is selected from a group which comprises Eu, Mn, Ce, Yb and combinations thereof; advantageously, E=Eu. By way of example, the phosphor has the formula (Na 0.25 K 0.75 )Li 3 SiO 4 :Eu. The peak wavelength of the phosphor is in the green spectral range, in particular. 
     The phosphor (Na r K 1−r ) 1 (TA) 3 (TD) 1 (XB) 4 :E or (Na r K 1−r )Li 3 SiO 4 :E where 0.2&lt;r≤0.4, advantageously 0.2&lt;r≤0.4, particularly advantageously 0.2&lt;r≤0.3, very particularly advantageously r=0.25, is suitable in particular for use in conversion LEDs for the backlighting of displays. 
     Moreover, the phosphor (Na r K 1−r ) 1 (TA) 3 (TD) 1 (XB) 4 :E or (Na r K 1−r )Li 3 SiO 4 :E where 0.2&lt;r≤0.4, advantageously 0.2&lt;r≤0.4, in particular (Na 0.25 K 0.75 )Li 3 SiO 4 :Eu, is suitable for use in lighting devices such as conversion LEDs which emit a green radiation. 
     In accordance with at least one embodiment, the phosphor has the formula (Na r K 1−r ) 1 (TA) 3 (TD) 1 (XB) 4 :E where 0.05&lt;r≤0.2, advantageously 0.1&lt;r≤0.2. Advantageously, TA=Li, TD=Si and XB═O and the phosphor has the formula (Na r K 1−r )Li 3 SiO 4 :E. E is selected from a group which comprises Eu, Mn, Ce, Yb and combinations thereof; advantageously, E=Eu. By way of example, the phosphor is Na 0.125 K 0.875 Li 3 SiO 4 :Eu. 
     Surprisingly, the phosphor of the formula (Na r K 1−r ) 1 (TA) 3 (TD) 1 (XB) 4 :E or (Na r K 1−r )Li 3 SiO 4 :E where 0.05&lt;r≤0.2 has a wide emission band. In particular, besides the band having the highest intensity (=peak wavelength), the phosphor has a further emission peak, which has an intensity of similar magnitude to that of the emission peak at the peak wavelength. 
     The phosphor (Na r K 1−r ) 1 (TA) 3 (TD) 1 (XB) 4 :E or (Na r K-r)Li 3 SiO 4 :E where 0.05&lt;r≤0.2, advantageously 0.1&lt;r≤0.2, in particular Na 0.125 K 0.875 Li 3 SiO 4 :Eu, is suitable for example for use in lighting devices such as conversion LEDs which emit white radiation. By virtue of the wide emission, in particular the two emission peaks in the blue or blue-green range and in the yellow-orange range, the phosphor can advantageously be used as sole phosphor in a lighting device such as a conversion LED. In particular, with such a conversion LED it is possible to generate a white overall radiation having color temperatures above 8000 K and a high color rendering index and great color space coverage, which can be used in particular for general lighting and backlighting of displays. 
     In accordance with at least one embodiment, the phosphor has the formula (Na r Kr) 1 (TA) 3 (TD) 1 (XB) 4 :E where 0≤r≤0.05, advantageously r=0. Advantageously, TA=Li, TD=Si and XB═O and the phosphor has the formula (Na r K 1−r ))Li 3 SiO 4 :E. E is selected from a group which comprises Eu, Mn, Ce, Yb and combinations thereof, advantageously, E=Eu. By way of example, the phosphor is KLi 3 SiO 4 :Eu. The phosphor exhibits very broadband emission from the blue to red spectral range, thus giving rise to a white luminous impression. 
     The phosphor (Na r K 1−r ) 1 (TA) 3 (TD) 1 (XB) 4 :E or (Na r K 1−r )Li 3 SiO 4 :E where 0≤r≤0.05, in particular KLi 3 SiO 4 :Eu, is suitable for example for use in lighting devices such as conversion LEDs which emit white radiation. As a result of the wide emission of the phosphor, the latter can advantageously be used as sole phosphor in a lighting device such as a conversion LED. 
     In comparison with the known white-emitting conversion LEDs that use a blue-emitting semiconductor chip and a red and green phosphor for generating white light, here the complex binning of the semiconductor chips can be dispensed with or carried out at least with a greater tolerance. It is possible to use semiconductor chips having a primary radiation that is not perceived or is only scarcely perceived by the human eye (300 nm to 460 nm, advantageously up to 430 nm or 440 nm). Production-temperature- or forward-current-dictated fluctuations of the primary radiations do not adversely affect the overall radiation properties. In comparison with the use of two or more phosphors, color adaptation by varying the concentrations of the phosphors is not necessary, since the emission spectrum is generated by only one phosphor and is thus constant. The conversion LEDs can thus be produced with a high throughput since adaptation or complex chip binning is not necessary. No color shifts or other adverse effects on the emission spectrum as a result of selective degradation of only one phosphor occur. A partial conversion of the primary radiation can also be carried out depending on the application. Since it is possible to excite the phosphor with a primary radiation in the range of 300 nm to 460 nm, a contribution of the primary radiation, advantageously in the short-wave blue range of the electromagnetic spectrum, to the overall radiation has the effect that objects illuminated thereby appear whiter, more radiant and therefore more attractive. It is possible for example for optical brightening agents in textiles to be excited thereby. 
     In accordance with at least one embodiment, the phosphor has the general molecular formula (Rb r′ Li 1−r′ ) 1 (TA) 3 (TD) 1 (XB) 4 :E, wherein 0≤r′≤1, for example r′=0; 0.05; 0.1; 0.15; 0.2; 0.25; 0.3; 0.35, 0.4; 0.45; 0.5; 0.55; 0.6; 0.65; 0.7; 0.75; 0.8; 0.85; 0.9; 0.95; 1.0, advantageously 0.25≤r′≤0.75, particularly advantageously 0.4≤r′≤0.6, very particularly advantageously r′=0.5. Advantageously, TA=Li, TD=Si and XB═O and the phosphor has the formula (Rb r′ Li 1−r′ )Li 3 SiO 4 :E. E is selected from a group which comprises Eu, Mn, Ce, Yb and combinations thereof; advantageously, E=Eu. It has been found that these phosphors have a small full width at half maximum and are applicable in diverse ways. 
     In accordance with at least one embodiment, the phosphor has the general molecular formula (K,Na,Li,Cs) i (TA) 3 (TD) 1 (XB) 4 :E, wherein K, Na, Li and Cs are contained in the phosphor. Advantageously, TA=Li, TD=Si and XB═O and the phosphor has the formula (K,Na,Li,Cs)Li 3 SiO 4 :E. E is selected from a group which comprises Eu, Mn, Ce, Yb and combinations thereof; advantageously, E=Eu. 
     Particularly advantageously, the phosphor has the formula (Cs 0.25 Na 0.25 K 0.25 Li 0.25 ) (TA) 3 (TD) 1 (XB) 4 :E or (Cs 0.25 Na 0.25 K 0.25 Li 0.25 )Li 3 SiO 4 :E. The peak wavelength of the phosphor is in the green spectral range, in particular, and has a full width at half maximum of less than 50 nm. 
     In accordance with at least one embodiment, the phosphor has the general molecular formula (Rb,Na,Li,Cs) 1 (TA) 3 (TD) 1 (XB) 4 :E, wherein Rb, Na, Li and Cs are contained in the phosphor. Advantageously, TA=Li, TD=Si and XB═O and the phosphor has the formula (Rb,Na,Li,Cs)Li 3 SiO 4 :E. E is selected from a group which comprises Eu, Mn, Ce, Yb and combinations thereof; advantageously, E=Eu. Particularly advantageously, the phosphor has the formula (Cs 0.25 Na 0.25 Rb 0.25 Li 0.25 ) (TA) 3 (TD) 1 (XB) 4 :E or (Cs 0.25 Na 0.25 Rb 0.25 Li 0.25 )Li 3 SiO 4 :E. The peak wavelength of the phosphor is in the blue spectral range, in particular, and has a full width at half maximum of less than 30 nm. 
     In accordance with at least one embodiment, the phosphor has the general molecular formula (Cs,Na,K) 1 (TA) 3 (TD) 1 (XB) 4 :E, wherein Na, K and Cs are contained in the phosphor. Advantageously, TA=Li, TD=Si and XB═O and the phosphor has the formula (Cs,Na,K)Li 3 SiO 4 :E. E is selected from a group which comprises Eu, Mn, Ce, Yb and combinations thereof; advantageously, E=Eu. Particularly advantageously, the phosphor has the formula (Cs 0.25 Na 0.50 K 0.25 ) (TA) 3 (TD) 1 (XB) 4 :E or (Cs 0.25 Na 0.50 K 0.25 )Li 3 SiO 4 :E. The peak wavelength of the phosphor is in the blue spectral range, in particular, and has a full width at half maximum of less than 30 nm. 
     In accordance with at least one embodiment, the phosphor has the general molecular formula (Rb,Na,K) 1 (TA) 3 (TD) 1 (XB) 4 :E, wherein Na, K and Rb are contained in the phosphor. Advantageously, TA=Li, TD=Si and XB═O and the phosphor has the formula (Rb,Na,K)Li 3 SiO 4 :E. E is selected from a group which comprises Eu, Mn, Ce, Yb and combinations thereof; advantageously, E=Eu. 
     Particularly advantageously, the phosphor has the formula (Rb 0.25 Na 0.50 K 0.25 ) (TA) 3 (TD) 1 (XB) 4 :E or (Rb 0.25 Na 0.50 K 0.25 )Li 3 SiO 4 :E. The peak wavelength of the phosphor is in the blue spectral range, in particular, and has a full width at half maximum of less than 30 nm. 
     The phosphors (Rb,Na,Li,Cs) i (TA) 3 (TD) 1 (XB) 4 :E, (Cs,Na,K) 1 (TA) 3 (TD) 1 (XB) 4 :E and (Rb,Na,K) 1 (TA) 3 (TD) 1 (XB) 4 :E are suitable in particular for use in conversion LEDs which emit white radiation. To that end, the phosphor can be combined in each case with a red and green phosphor. Moreover, these phosphors are suitable for use in lighting devices such as conversion LEDs which emit a blue radiation. 
     In accordance with at least one embodiment, the phosphor (Rb,Na,Li,Cs) 1 (TA) 3 (TD) 1 (XB) 4 :E, (K,Na,Li,Cs) 1 (TA) 3 (TD) 1 (XB) 4 :E, (Rb,Na,K) 1 (TA) 3 (TD) 1 (XB) 4 :E, (Cs,Na,K) (TA) 3 (TD) 1 (XB) 4 :E, (K,Na,Li,Cs)Li 3 SiO 4 :E, (Rb,Na,Li,Cs)Li 3 SiO 4 :E, (Rb, Na,K)Li 3 SiO 4 :E or (Cs,Na,K)Li 3 SiO 4 :E crystallizes in a tetragonal crystal system. Advantageously, the phosphor in accordance with this embodiment crystallizes in the space group I4/m. Particularly advantageously, the phosphor in accordance with this embodiment crystallizes in a tetragonal crystal system with I4/m. 
     In accordance with at least one embodiment, the phosphor has the general molecular formula (K 1−r″−r′″ Na r″ Li r′″ ) 1 (TA) 3 (TD) 1 (XB) 4 :E, wherein 0&lt;r″&lt;0.5 and 0&lt;r′″&lt;0.5, for example r″=0.05; 0.1; 0.15; 0.2; 0.25; 0.3; 0.35, 0.4; 0.45 and r′″=0.05; 0.1; 0.15; 0.2; 0.25; 0.3; 0.35, 0.4; 0.45. Advantageously, 0.1&lt;r″&lt;0.4 and 0.1&lt;r′″&lt;0.4, particularly advantageously 0.2&lt;r″&lt;0.3 and 0.2&lt;r′″&lt;0.3. Advantageously, TA=Li, TD=Si and XB═O and the phosphor has the formula (K 1−r″−r′″ Na r″ Li r′″ ) 1 Li 3 SiO 4 :E. E is selected from a group which comprises Eu, Mn, Ce, Yb and combinations thereof; advantageously, E=Eu. Surprisingly, the properties of the phosphor, in particular the peak wavelength and the full width at half maximum, change upon variation of the proportions of Na, Li and K in the phosphor. As a result, these phosphors can be used in a wide variety of applications. By way of example, the phosphor has the formula (K 0.5 Na 0.25 Li 0.25 )Li 3 SiO 4 :Eu. The peak wavelength of the phosphor is in the green spectral range, in particular, and has a full width at half maximum of less than 50 nm. 
     In accordance with at least one embodiment, the phosphor (K 1−r″−r′″ Na r″ Li r′″ ) 1 (TA) 3 (TD) 1 (XB) 4 :E or (K 1−r″−r′″ Na r″ Li r′″ )Li 3 SiO 4 :E crystallizes in a tetragonal or monoclinic crystal system. Advantageously, the phosphor in accordance with this embodiment crystallizes in the space group I4/m or C2/m. Particularly advantageously, the phosphor in accordance with this embodiment crystallizes in a tetragonal crystal system with the space group I4/m or in a monoclinic crystal system with the space group C2/m, particularly advantageously in a monoclinic crystal system with the space group C2/m. 
     In accordance with at least one embodiment, the phosphor has the general molecular formula (Rb r* Na 1−r* ) 1 (TA) 3 (TD) 1 (XB) 4 :E, wherein 0&lt;r*&lt;1, for example r*=0.05; 0.1; 0.15; 0.2; 0.25; 0.3; 0.35, 0.4; 0.45; 0.5; 0.55; 0.6; 0.65; 0.7; 0.75; 0.8; 0.85; 0.9; 0.95. Advantageously, TA=Li, TD=Si and XB═O and the phosphor has the formula (Rb r* Na 1−r* )Li 3 SiO 4 :E. E is selected from a group which comprises Eu, Mn, Ce, Yb and combinations thereof; advantageously E=Eu. 
     In accordance with at least one embodiment, the phosphor (Rb r* Na 1−r* ) 1 (TA) 3 (TD) 1 (XB) 4 :E or (Rb r* Na 1−r* )Li 3 SiO 4 :E crystallizes in a tetragonal or monoclinic crystal system. Advantageously, the phosphor in accordance with this embodiment crystallizes in the space group I4/m or C2/m. Particularly advantageously, the phosphor in accordance with this embodiment crystallizes in a tetragonal crystal system with the space group I4/m or in a monoclinic crystal system with the space group C2/m. 
     In accordance with at least one embodiment, the phosphor has the general molecular formula (Rb r* Na 1−r* ) 1 (TA) 3 (TD) 1 (XB) 4 :E, wherein 0.4≤r*&lt;1.0, advantageously 0.4≤r*&lt;0.875 or 0.4≤r*≤0.75, particularly advantageously 0.4≤r*≤0.6 very particularly advantageously r*=0.5. Advantageously, TA=Li, TD=Si and XB═O and the phosphor has the formula (Rb r* Na 1−r* )Li 3 SiO 4 :E. E is selected from a group which comprises Eu, Mn, Ce, Yb and combinations thereof; advantageously E=Eu. By way of example, the phosphor has the formula (Rb 0.5 Na 0.5 )Li 3 SiO 4 :Eu. The peak wavelength of the phosphor is in the green spectral range, in particular, and has a full width at half maximum of between 42 and 44 nm. 
     In accordance with at least one embodiment, the phosphor has the general molecular formula (Rb r* Na 1−r* ) 1 (TA) 3 (TD) 1 (XB) 4 :E, wherein 0&lt;r*&lt;0.4, for example r*=0.05; 0.1; 0.15; 0.2; 0.25; 0.3; 0.35, advantageously 0.1≤r*≤0.35, particularly advantageously 0.2≤r*≤0.3, very particularly advantageously r*=0.25. Advantageously, TA=Li, TD=Si and XB═O and the phosphor has the formula (Rb r* Na 1−r* )Li 3 SiO 4 :E. E is selected from a group which comprises Eu, Mn, Ce, Yb and combinations thereof; advantageously E=Eu. The peak wavelength of the phosphor is advantageously in the blue spectral range and has a full width at half maximum of between 20 and 24 nm. 
     The phosphor (Rb r* Na 1−r* ) 1 (TA) 3 (TD) 1 (XB) 4 :E or (Rb r* Na 1−r* )Li 3 SiO 4 :E where 0&lt;r*&lt;0.4, advantageously 0.1≤r*≤0.35, particularly advantageously 0.2≤r*≤0.3, very particularly advantageously r*=0.25, is suitable in particular for use in conversion LEDs which emit white radiation. To that end, the phosphor can be combined with a red and green phosphor. 
     Moreover, the phosphor (Rb r* Na 1−r* ) 1 (TA) 3 (TD) 1 (XB) 4 :E or (Rb r* Na 1−r* )Li 3 SiO 4 :E where 0&lt;r*&lt;0.4, advantageously 0.1≤r*≤0.35, particularly advantageously 0.2≤r*≤0.3, very particularly advantageously r*=0.25, is suitable for use in lighting devices such as conversion LEDs which emit a blue radiation. 
     In accordance with at least one embodiment, the phosphor has the formula (Na r K 1−r ) 1 (TA) 3 (TD) 1 (XB) 4 :E or (Na r K-r)Li 3 SiO 4 :E where 0.2&lt;r≤0.4, advantageously 0.2&lt;r≤0.3, particularly advantageously r=0.25 or (Rb r′ Li 1−r′ ) 1 (TA) 3 (TD) 1 (XB) 4 :E or (Rb r′ Li 1−r′ )Li 3 SiO 4 :E where 0≤r′≤1, advantageously 0.25≤r′≤0.75, particularly advantageously 0.4≤r′≤0.6. Advantageously, TA=Li, TD=Si and XB═O. The peak wavelength of the phosphor is in the green spectral range, in particular, and has a full width at half maximum of less than 50 nm. 
     In many display applications such as televisions, computer monitors, tablets and smartphones, manufacturers endeavor to render the colors vividly and realistically, since this is very attractive to consumers. 
     Light sources for the backlighting of displays, for example of LCD displays, differ from light sources for general lighting. The requirements made of light sources for general lighting consist, in particular, in a high luminous efficiency combined with a continuous spectrum in order to achieve a high color rendering index. In the case of LCD displays (“liquid crystal displays”) and other displays, the colors are rendered by the primary colors red, green and blue. The bandwidth of colors that can be rendered on a display is therefore limited by the spanned color triangle of the colors red, green and blue. These colors are correspondingly filtered out from the spectrum for backlighting by red, green and blue color filters. However, the wavelength range of the transmitted radiation of the color filters is still very wide. Therefore, light sources having very narrowband emissions, that is to say a small full width at half maximum, in the green, blue and red spectral range are required in order to cover the widest possible color space. As light sources for backlighting applications, predominantly a blue-emitting semiconductor chip with a phosphor having a peak wavelength in the green spectral range and a phosphor having a peak wavelength in the red spectral range are combined, wherein the phosphors have the smallest possible full width at half maximum of the emission. Ideally the emission peaks in this case are congruent with the transmission range of the respective color filter in order to lose as little light as possible, to achieve the maximum efficiency and to reduce crosstalk or an overlap of the different color channels that limits the achievable color space. 
     Conversion LEDs for backlighting applications conventionally use as green phosphor for example an yttrium aluminum garnet, a lutetium aluminum garnet or a β-SiAlON (Si 6-z Al z O z N 8-z :RE or Si 6-x Al z O y N 8-y :RE z  where RE=rare earth metal). However, yttrium aluminum garnet has an emission peak having a large full width at half maximum, such that the achievable color space is limited by the considerable filter losses and the efficiency is reduced as well. β-SiAlON with a full width at half maximum of less than 60 nm has a narrowband emission in the green spectral range that leads to a more saturated green rendering than with the garnet phosphor. However, the β-SiAlONs lack a good internal and external quantum efficiency, which makes the entire backlighting not very efficient. Furthermore, the production of these phosphors requires very high temperatures and costly equipment. Therefore, the phosphor is very expensive to produce, and thus so are conversion LEDs comprising this phosphor. 
     Quantum dots are also used for the conversion of primary radiation for backlighting applications on account of their very narrowband emission. However, quantum dots are very unstable, particularly under the ambient conditions of a conversion LED for backlighting applications. Moreover, most commercially available quantum dots comprise harmful elements such as Hg or Cd, the concentration of which is limited in commercial electrical and electronic devices under the regulations of RoHS (“reduction of hazardous substances”, EU directive 2011/65/EU). 
     Surprisingly, the phosphors according to the present disclosure (Na r K 1−r ) 1 (TA) 3 (TD) 1 (XB) 4 :E where 0.2&lt;r≤0.4, (Rb r′ Li 1−r′ ) 1 (TA) 3 (TD) 1 (XB) 4 :E where 0≤r′≤1, (K 1−r″−r′″ Na r″ Li r′″ ) 1 (TA) 3 (TD) 1 (XB) 4 :E where 0&lt;r″&lt;0.5 and 0&lt;r′″&lt;0.5, (K,Na,Li,Cs) (TA) 3 (TD) 1 (XB) 4 :E, and (Rb r* Na 1−r* ) 1 (TA) 3 (TD) 1 (XB) 4 :E where 0.4≤r*&lt;1.0, for example (Rb 0.5 Li 0.5 )Li 3 SiO 4 :Eu, (Na 0.25 K 0.75 )Li 3 SiO 4 :Eu, (Na 0.25 K 0.50 Li 0.25 )Li 3 SiO 4 :Eu, (Cs 0.25 Na 0.25 K 0.25 Li 0.25 )Li 3 SiO 4 :Eu and (Rb 0.5 Na 0.5 )Li 3 SiO 4 :Eu, have a peak wavelength in the green spectral range and a very small full width at half maximum and are therefore suitable in particular for white-emitting lighting devices such as, for example, white-emitting conversion LEDs in conjunction with a semiconductor chip that emits a blue primary radiation and with a red phosphor for backlighting applications in particular for display elements such as displays. Advantageously, a particularly large bandwidth of colors can be achieved with such a white-emitting conversion LED. As a result of the small full width at half maximum of the phosphors according to the present disclosure (Na r K 1−r ) 1 (TA) 3 (TD) 1 (XB) 4 :E where 0.2&lt;r≤0.4, (Rb r′ Li 1−r′ ) 1 (TA) 3 (TD) 1 (XB) 4 :E where 0≤r′≤1, (K 1−r″−r′″ Na r″ Li r′″ ) 1 (TA) 3 (TD) 1 (XB) 4 :E where 0&lt;r″&lt;0.5 where 0&lt;r′″&lt;0.5, (K,Na,Li,Cs)(TA) 3 (TD) 1 (XB) 4 :E and (Rb r* Na 1−r* ) 1 (TA) 3 (TD) 1 (XB) 4 :E where 0.4≤r*&lt;1.0 for example (Rb 0.5 Li 0.5 )Li 3 SiO 4 :Eu, (Na 0.25 K 0.75 )Li 3 SiO 4 :Eu, (Na 0.25 K 0.50 Li 0.25 )Li 3 SiO 4 :Eu, (Cs 0.25 Na 0.25 K 0.25 Li 0.25 )Li 3 SiO 4 :Eu and (Rb 0.5 Na 0.5 )Li 3 SiO 4 :Eu, the emission peaks exhibit a very large overlap with the transmission range of a standard green filter, such that only little light is lost and the achievable color space is large. 
     Green LEDs which emit a radiation in the green wavelength range can be obtained firstly by means of semiconductor chips which emit green directly or in the form of conversion LEDs, comprising a blue- or UV-emitting semiconductor chip and a green phosphor. Semiconductor chips which emit green directly exhibit a very low quantum efficiency. In the case of the conversion LEDs, the primary radiation can on the one hand be converted completely into green secondary radiation (full conversion) or on the other hand be converted only partly into green secondary radiation (partial conversion) and the remaining portion of primary radiation is filtered out by means of a filter, such that the conversion LED emits exclusively or almost exclusively secondary radiation, in particular green secondary radiation. 
     By contrast, conversion LEDs comprising the green phosphor according to the present disclosure of the formula (Na r K 1−r ) 1 (TA) 3 (TD) 1 (XB) 4 :E where 0.2&lt;r≤0.4, (Rb r′ Li 1−r′ ) 1 (TA) 3 (TD) 1 (XB) 4 :E where 0≤r′≤1, (K 1−r″−r′″ Na r″ Li r′″ ) 1 (TA) 3 (TD) 1 (XB) 4 :E where 0&lt;r″&lt;0.5 and 0&lt;r′″&lt;0.5, (Cs,Na,K,Li) 1 (TA) 3 (TD) 1 (XB) 4 :E, advantageously (Cs 0.25 Na 0.25 K 0.25 Li 0.25 ) (TA) 3 (TD) 1 (XB) 4 :E or (Rb r* Na 1−r* ) 1 (TA) 3 (TD) 1 (XB) 4 :E where 0.4≤r*&lt;0.875, for example (Rb 0.5 Li 0.5 )Li 3 SiO 4 :Eu, (Na 0.25 K 0.75 )Li 3 SiO 4 :Eu, (Na 0.25 K 0.50 Li 0.25 )Li 3 SiO 4 :Eu, (Cs 0.25 Na 0.25 K 0.25 Li 0.25 )Li 3 SiO 4 :Eu or (Rb 0.5 Na 0.5 )Li 3 SiO 4 :Eu, are very efficient and exhibit a high color purity and a high power even without the use of a color filter. 
     Conventionally, (Y,Lu) 3 (Al,Ga) 5 O 12 :Ce, orthosilicates or oxonitridoorthosilicates are used as green phosphors. The conventional conversion LEDs often have a low efficiency and color purity. In order to avoid these disadvantages, filters are used to adapt the emission. However, this adversely affects the total power of the conversion LED. 
     By contrast, conversion LEDs comprising a semiconductor chip and a green phosphor according to the present disclosure of the formula (Na r K 1−r ) 1 (TA) 3 (TD) 1 (XB) 4 :E where 0.2&lt;r≤0.4 and (Rb r′ Li 1−r′ ) 1 (TA) 3 (TD) 1 (XB) 4 :E where 0&lt;r′≤1, for example (Rb 0.5 Li 0.5 )Li 3 SiO 4 :Eu and (Na 0.25 K 0.75 )Li 3 SiO 4 :Eu, are very efficient and exhibit a high color purity and a high power even without the use of a color filter. 
     In accordance with at least one embodiment, the phosphor has the following general molecular formula: Na 1−y* Ca y* Li 3−2y* Al 3y* Si 1−y* O 4−4y* N 4y* :E, wherein 0&lt;y*&lt;0.875; advantageously 0&lt;y*&lt;0.5, particularly advantageously 0&lt;y*≤0.3, very particularly advantageously 0&lt;y*≤0.1. By way of example, y*=0.01; 0.02; 0.03, 0.04 or 0.05. E is selected from a group which comprises Eu, Mn, Ce, Yb and combinations thereof. Advantageously, E=Eu or Eu 2+ . 
     Surprisingly, it has been found that the phosphor of the formula NaLi 3 SiO 4 :Eu has an isotypic crystal structure with respect to the known phosphor CaLiAl 3 N 4 :Eu. The fact that two compounds crystallize in an isotypic crystal structure means, in particular, that the atoms of one compound occupy the same place within the crystal structure as the corresponding atoms of the other compound. As a result, the linkages of structural units within the structures are maintained unchanged. An isotypic crystal structure in the case of oxides and nitrides is atypical since nitrides, in comparison with oxides, usually have a higher degree of condensation of the polyhedra, in particular the tetrahedra, within the crystal structure. This is surprising particularly in the present case since the degree of condensation of the phosphor according to the present disclosure of the formula NaLi 3 SiO 4 :Eu is one, whereas typical oxosilicates have a degree of condensation of less than or equal to 0.5. Surprisingly, the inventors have discovered that, proceeding from the phosphor of the molecular formula NaLi 3 SiO 4 :Eu, the elements Na, Li, Si, O can be partly replaced by the elements Ca, Li, Al and N, thus resulting in a phosphor of the formula Na 1−y* Ca y* Li 3−2y* Al 3y* Si 1−y O 4−4y* N 4y* :Eu. This phosphor is present in a mixed phase, in particular, such that within the crystal structure of NaLi 3 SiO 4 :Eu, the lattice sites are partly occupied by the elements Ca, Li, Al and N. 
     The known phosphor CaLiAl 3 N 4 :Eu is a phosphor which emits in the red range of the electromagnetic spectrum, has a peak wavelength at approximately 670 nm, has a full width at half maximum of approximately 60 nm and crystallizes in an isotypic crystal structure with respect to NaLi 3 SiO 4 . In comparison therewith, NaLi 3 SiO 4 :Eu emits in the blue spectral range of the electromagnetic spectrum with a peak wavelength of approximately 470 nm and exhibits a more narrowband emission, that is to say an emission having a smaller full width at half maximum than 60 nm. The mixed phase according to the present disclosure of these phosphors advantageously makes it possible to provide a phosphor of the formula Na 1−y* Ca y* Li 3−2y* Al 3y* Si 1−y O 4−4y* N 4y* :Eu in which the proportion of CaLiAl 3 N 4  can be varied, which is expressed by the index y* in the formula. As a result of this variation, it is possible to provide a phosphor which, as a result of the variable composition, allows the peak wavelength to be set in a range of between 470 nm and 670 nm. The phosphor can thus be set in a targeted manner with regard to the desired color locus, depending on requirements or application. Consequently, with just one phosphor it is possible, surprisingly, to generate almost all colors of the visible range, from blue to red. 
     The peak wavelength of the phosphor Na 1−y* Ca y* Li 3−2y* Al 3y* Si 1−y* O 4−4y* N 4y* :E where 0&lt;y*&lt;0.875, advantageously 0&lt;y*≤0.5, particularly advantageously 0&lt;y*≤0.3, very particularly advantageously 0&lt;y*≤0.1, is advantageously in the blue or green spectral range. The phosphor is suitable in particular in combination with a green and red phosphor for white conversion LEDs, in particular for general lighting. Moreover, the phosphor is suitable for colored conversion LEDs. 
     In accordance with at least one embodiment, the phosphor Na 1−y* Ca y* Li 3−2y* Al 3y* Si 1−y* O 4−4y* N 4y* :E crystallizes in a tetragonal crystal system. Advantageously, the phosphor in accordance with this embodiment crystallizes in the space group I4 1 /a. Particularly advantageously, the phosphor in accordance with this embodiment crystallizes in a tetragonal crystal system with the space group I4 1 /a. 
     In accordance with at least one embodiment, the phosphor has the following general molecular formula: Na 1−y*** Sr y*** Li 3−2y*** Al 3y*** Si 1−y*** O 4−4y*** N 4y*** :E, wherein 0&lt;y***&lt;0.875; advantageously 0&lt;y***≤0.5, particularly advantageously 0&lt;y***≤0.3. By way of example, it holds true that y***=0.01; 0.02; 0.03, 0.04 or 0.05. E is selected from a group which comprises Eu, Mn, Ce, Yb and combinations thereof. Advantageously, E=Eu or Eu 2+ . 
     In accordance with at least one embodiment, the phosphor has the formula (MB) b (TA) e (TC) g (TD) h (XB) l (XC) m :E, 
     wherein
         MB is selected from a group of divalent metals which comprises Mg, Ca, Sr, Ba, Zn, Mn, Eu, Yb, Ni, Fe, Co and combinations thereof,   TA is selected from a group of monovalent metals which comprises Li, Na, Cu, Ag and combinations thereof,   TC is selected from a group of trivalent metals which comprises B, Al, Ga, In, Y, Fe, Cr, Sc, rare earths and combinations thereof,   TD is selected from a group of tetravalent metals which comprises Si, Ge, Sn, Mn, Ti, Zr, Hf, Ce and combinations thereof,   XB═O and/or S   XC═N   b=1;   e+g+h=4;   l+m=4;   2b+e+3g+4h−2l−3m=0 and m&lt;3.5 or l&gt;0.5.   E=Eu, Ce, Yb and/or Mn, advantageously E=Eu.       

     In accordance with at least one embodiment, the phosphor has the formula (MB) b (TA) e (TC) g  (TD) h (XB) l (XC) m :E, 
     wherein
         MB is selected from a group of divalent metals which comprises Mg, Ca, Sr, Ba and combinations thereof,   TA is selected from a group of monovalent metals which comprises Li, Na and combinations thereof,   TC is selected from a group of trivalent metals which comprises B, Al, Ga and combinations thereof,   TD is selected from a group of tetravalent metals which comprises Si, Ge and combinations thereof,   XC═N   XB═O   b=1;   e+g+h=4;   l+m=4;   2b+e+3g+4h−2l−3m=0 and m&lt;3.5 or l&gt;0.5.   E=Eu, Ce, Yb and/or Mn, advantageously E=Eu.       

     In accordance with at least one embodiment, the phosphor has the following general molecular formula: (MB)(Si 0.25 Al −1/8+r**/2 Li 7/8−r**/2 ) 4 (O 1−r** N r** ) 4 :E, wherein 0.25≤r**≤1, advantageously 0.25&lt;r**&lt;0.875, particularly advantageously 0.4≤r**≤0.8. MB is selected from a group of divalent metals which comprises Mg, Ca, Sr, Ba and combinations thereof, and E=Eu, Ce, Yb and/or Mn, advantageously E=Eu. 
     In accordance with at least one embodiment, the phosphor has the following general molecular formula: Sr(Si 0.25 Al −1/8+r**/2 Li 7/8−r**/2 ) 4 (O 1−r** N r** ) 4 :E, wherein 0.25≤r**≤1, advantageously 0.25&lt;r**&lt;0.875, particularly advantageously 0.4≤r**≤0.8 and E=Eu, Ce, Yb and/or Mn. The phosphor is, in particular, a mixed phase of the compounds SrSiLi 3 O 3 N:Eu (r**=0.25) and Sr 2 Si 2 Al 3 Li 3 N 8 :Eu (r**=1). 
     The mixed phase according to the present disclosure advantageously makes it possible to provide a phosphor in which the proportion of nitrogen can be varied, which is expressed in the formula by the index r**. As a result of this variation, it is possible to provide a phosphor which, as a result of the variable composition, allows the peak wavelength to be set from the yellow to red spectral range. Consequently, the phosphor can be set in a targeted manner with regard to the desired color locus and/or color rendering index, depending on requirements or application. With just one phosphor, surprisingly, it is thus possible to generate many colors of the visible range, in particular from yellow to red. 
     In accordance with at least one embodiment, the phosphor (MB) (Si 0.25 Al −1/8+r**/2 Li 7/8−r**/2 ) 4 (O 1−r** N r** ) 4 :E or Sr(Si 0.25 Al −1/8+r**/2 Li 7/8−r**/2 ) 4 (O 1−r** N r** ) 4 :E crystallizes in a tetragonal crystal system. Advantageously, the phosphor in accordance with this embodiment crystallizes in the space group I4/m. Particularly advantageously, the phosphor in accordance with this embodiment crystallizes in a tetragonal crystal system with the space group I4/m. 
     In accordance with at least one embodiment, the phosphor has the following general molecular formula: Na 1−y** Eu y** Li 3−2y** Al 3y** Si 1−y** O 4−4y** N 4y** :E, wherein 0&lt;y**≤1.0, advantageously 0&lt;y**&lt;0.875 or 0&lt;y**&lt;0.5, particularly advantageously 0.05≤y**≤0.45, very particularly advantageously 0.1≤y**≤0.4, 0.15≤y**≤0.35 or 0.2≤y**≤0.3. E=Eu, Ce, Yb and/or Mn, advantageously E=Eu. 
     Surprisingly, it has been found that the phosphor of the formula Na 1−y** Eu y** Li 3−2y** Al 3y** Si 1−y** O 4−4y** N 4y** :E, advantageously Na 1−y** Eu y** Li 3−2y** Al 3y** Si 1−y** O 4−4y** N 4y** :Eu, can be produced as a mixed phase between NaLi 3 SiO 4 :E or NaLi 3 SiO 4 :Eu (y**=0) and the compound EuLiAl 3 N 4 (y**=1) and moreover constitutes an efficient phosphor having unique properties. This phosphor is present in particular in a mixed phase, such that within the crystal structure of NaLi 3 SiO 4 :Eu the lattice sites are partly occupied by the elements Eu, Li, Al and N. 
     NaLi 3 SiO 4 :Eu emits in the blue spectral range. The mixed phase according to the present disclosure of NaLi 3 SiO 4 :Eu and the compound EuLiAl 3 N 4  advantageously makes it possible to provide a phosphor of the formula Na 1−y** Eu y** Li 3−2y** Al 3y** Si 1−y** O 4−4y** N 4y** :Eu in which the proportion of EuLiAl 3 N 4  can be varied, which is expressed in the formula by the index y**. As a result of this variation, it is possible to provide a phosphor which, as a result of the variable composition, allows the peak wavelength to be set in a range from the yellow to red range. Consequently, the phosphor can be set in a targeted manner with regard to the desired color locus, depending on requirements or application. With just one phosphor, surprisingly, it is thus possible to generate almost all colors of the visible range, from yellow to red. 
     In accordance with at least one embodiment, the phosphor Na 1−y** Eu y** Li 3−2y** Al 3y** Si 1−y** O 4−4y** N 4y** :Eu crystallizes in a tetragonal crystal system. Advantageously, the phosphor in accordance with this embodiment crystallizes in the space group I4/m. Particularly advantageously, the phosphor in accordance with this embodiment crystallizes in a tetragonal crystal system with the space group I4/m. 
     In accordance with at least one embodiment, the phosphor has the formula (MB) b (TA) e (TC) g (XB) l (XC) m :E, 
     wherein
         MB is selected from a group of divalent metals which comprises Mg, Ca, Sr, Ba, Zn, Mn, Eu, Yb, Ni, Fe, Co and combinations thereof,   TA is selected from a group of monovalent metals which comprises Li, Na, Cu, Ag and combinations thereof,   TC is selected from a group of trivalent metals which comprises B, Al, Ga, In, Y, Fe, Cr, Sc, rare earth metals and combinations thereof,   XB═O,   XC═N,   b=1;   e+g=4;   l+m=4;   2b+e+3g−2l−3m=0 and m&lt;3.5 or l&gt;0.5.   E=Eu, Ce, Yb and/or Mn, advantageously E=Eu.       

     In accordance with at least one embodiment, the phosphor has the formula (MB) b (TA) e (TC) g (XB) l (XC) m :E, 
     wherein
         MB is selected from a group of divalent metals which comprises Mg, Ca, Sr, Ba, Zn and combinations thereof,   TA is selected from a group of monovalent metals which comprises Li, Na, Cu, Ag and combinations thereof,   TC is selected from a group of trivalent metals which comprises B, Al, Ga and combinations thereof,   XB=0,   XC═N,   b=1;   e+g=4;   l+m=4;   2b+e+3g−2l−3m=0 and m&lt;3.5 or l&gt;0.5.   E=Eu, Ce, Yb and/or Mn, advantageously E=Eu.       

     In accordance with at least one embodiment, the phosphor has the following general molecular formula: (MB)Li 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu where 0&lt;x**&lt;1.0, advantageously 0&lt;x**&lt;0.875, particularly advantageously 0.125&lt;x**&lt;0.875 or 0.125≤x**≤0.5, very particularly advantageously 0.125≤x**≤0.45. MB is selected from a group of divalent metals which comprises Mg, Ca, Sr, Ba, Zn and combinations thereof. 
     In accordance with at least one embodiment, the phosphor has the following general molecular formula: SrLi 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu where 0&lt;x**≤1.0, advantageously 0&lt;x**&lt;0.875, particularly advantageously 0.125≤x**&lt;0.875 or 0.125≤x**≤0.5, very particularly advantageously 0.125≤x**≤0.45. 
     Surprisingly, it has been found that the phosphor of the formula SrLi 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu can be produced as a mixed phase between SrLi 3 AlO 4 :Eu (x**=0) and the compound SrLiAl 3 N 4  (x**=1) and moreover constitutes an efficient phosphor having unique properties. In particular, the phosphors have a small full width at half maximum. 
     SrLiAl 3 N 4 :Eu is a known phosphor exhibiting narrowband emission in the red spectral range. The mixed phase according to the present disclosure of SrLi 3 AlO 4 :Eu and the compound SrLiAl 3 N 4  advantageously makes it possible to provide a phosphor of the formula SrLi 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu in which the proportion of SrLiAl 3 N 4  can be varied, which is expressed in the formula by the index x**. As a result of this variation, it is possible to provide a phosphor which, as a result of the variable composition, allows the peak wavelength to be set in a range from the green to yellow or yellow-orange range. As a result, it is possible to achieve color loci which cannot be achieved with known phosphors. Consequently, the phosphor can be set in a targeted manner with regard to the desired color locus in the green to yellow range, depending on requirements or application. 
     Surprisingly, it has been found that the phosphor of the formula SrLi 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu, as x** increases, starting from x**≥0.1250, crystallizes in the same crystal structure but in the process the cell volume of the unit cell increases and at the same time, as x** increases, the peak wavelength is shifted into the longer-wavelength range, in particular from the green right into the red spectral range. Thus, the phosphor SrLi 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu where 0.125≤x**≤1, advantageously 0.125≤x**&lt;0.875, particularly advantageously 0.125≤x**≤0.5, very particularly advantageously 0.125≤x**≤0.45, is usable in diverse ways and is suitable in particular for colored conversion LEDs comprising SrLi 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu as sole phosphor. In addition, the phosphors advantageously have small values of full width at half maximum of less than 80 nm. 
     The phosphor SrLi 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu, in particular where x**≥0.1250, is suitable for example for use in lighting devices such as conversion LEDs which emit white radiation, wherein a superimposition of the blue primary radiation and the secondary radiation yields a white overall radiation. The phosphor is very robust and efficient and it is advantageously possible to provide a conversion LED which emits an overall radiation having a color temperature of less than 3600 K, in particular 3400 K±100 K, and a color locus near the Planckian locus. 
     In accordance with at least one embodiment, the phosphor has the following general molecular formula: SrLi 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu where 0&lt;x**&lt;0.125, advantageously 0&lt;x**&lt;0.120. 
     The phosphor SrLi 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu where 0&lt;x**&lt;0.125 surprisingly does not crystallize in an isotypic crystal structure with respect to the crystal structure of SrLi 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu where x**≥0.125. In particular, the phosphor where 0&lt;x**&lt;0.125 can form a crystal structure which can be described as a crystallographic superstructure of the crystal structure of variants of the phosphor where x** 2≥0.125. 
     Advantageously, the peak wavelength of this phosphor is in the green range of the electromagnetic spectrum. The full width at half maximum is advantageously smaller in comparison with SrLi 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu where x**≥0.125. 
     In accordance with at least one embodiment, the phosphor (MB)Li 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu or SrLi 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu crystallizes in a tetragonal crystal system. Advantageously, the phosphor in accordance with this embodiment crystallizes in the space group I4/m. Particularly advantageously, the phosphor in accordance with this embodiment crystallizes in a tetragonal crystal system in the space group I4/m. 
     In accordance with at least one embodiment, the phosphor crystallizes in a crystal structure having the same atomic sequence as in UCr 4 C 4 , CsKNa 2 Li 12 Si 4 O 16  or RbLi 5 {Li[SiO 4 ]} 2 . The fact that the phosphor crystallizes in a crystal structure having the same atomic sequence as in UCr 4 C 4 , CsKNa 2 Li 12 Si 4 O 16  or RbLi 5 {Li[SiO 4 ]} 2  means, here and hereinafter, that the succession of the atoms of the phosphor follows the same pattern as the succession of the atoms in UCr 4 C 4 , CsKNa 2 Li 12 Si 4 O 16  or RbLi 5 {Li[SiO 4 ]} 2 . In other words, the crystal structure exhibits the same structural motifs as UCr 4 C 4 , CsKNa 2 Li 12 Si 4 O 16  or RbLi 5 {Li[SiO 4 ]} 2 . By way of example, the phosphor of the formula (Na 0.5 K 0.5 )Li 3 SiO 3 :Eu crystallizes in a crystal structure having the same atomic sequence as in CsKNa 2 Li 12 Si 4 O 16 ; in this case, K occupies the sites of Cs and of K, Na occupies the sites of Na, Li occupies the sites of Li, Si occupies the sites of Si, and O occupies the sites of O. As a result of the variation of the ionic radii in the course of substitution with other atomic species, the absolute position (atomic coordinates) of the atoms may change. 
     The phosphor can also crystallize in a crystal structure having the same atomic sequence as in the structures NaLi 3 SiO 4  or KLi 3 GeO 4  derived from UCr 4 C 4 . 
     In accordance with at least one embodiment, the phosphor crystallizes in the same structure type as
         NaLi 3 SiO 4      KLi 3 SiO 4      RbLi 5 {Li[SiO 4 ]} 2      UCr 4 C 4      CsKNa 2 Li 12 Si 4 O 16  or   CsKNaLi 9 {Li[SiO 4 ]} 4 .       

     The crystal structures of the embodiments are distinguished in particular by a three-dimensionally linked spatial network. In this case, TA, TB, TC, TD, TE and/or TF are surrounded by XA, XB, XC and/or XD and the resultant structural units, advantageously tetrahedra, are linked via common corners and edges. This arrangement results in a three-dimensionally extending anionic structural unit. MA, MB, MC and/or MD are arranged in the resultant cavities and/or channels. 
     In accordance with at least one embodiment, the phosphor has a crystal structure in which TA, TB, TC, TD, TE and/or TF are surrounded by XA, XB, XC and/or XD and the resultant structural units are linked via common corners and edges to form a three-dimensional spatial network having cavities and/or channels and MA, MB, MC and/or MD are arranged in the cavities and/or channels. In particular, the structural units are tetrahedra, wherein advantageously XA, XB, XC and/or XD occupy the corners of the tetrahedra and TA, TB, TC, TD, TE and/or TF are arranged in the center of the tetrahedra. 
     By way of example, in the crystal structure of the embodiment KLi 3 SiO 4 :E, which is isotypic with respect to KLi 3 GeO 4 , Li and Si are surrounded by O and form the anionic structural unit in the form of a spatial network of distorted (Li/Si)O 4  tetrahedra. In the resultant cavities, the K atoms are surrounded by 8 O atoms in a distorted cubic fashion. 
     In the crystal structure of the exemplary embodiment RbLi 55 {Li[SiO 4 ]} 2 :E, one portion of the Li atoms and Si are surrounded by O and form the anionic structural unit in the form of a spatial network. In this case, the Si atoms are surrounded by 4 O atoms in a distorted tetrahedral fashion. The Li atoms which participate in the structural unit are surrounded by 3 O atoms in a distorted trigonal planar fashion in their first coordination sphere. With addition of further O atoms in the vicinity, the coordination can also be described as distorted tetrahedral or distorted trigonal bipyramidal. In the resultant cavities, the Rb atoms are surrounded by 8 O atoms in a distorted cubic fashion, while the other portion of the Li atoms is surrounded by 4 O atoms in a distorted square planar fashion. 
     Depending on the chemical composition of the phosphors disclosed here, a severe distortion of the coordination sphere around MA, MB, MC and/or MD may occur. In the case of the exemplary embodiment NaLi 3 SiO 4 :E, for example, that has the effect that the vicinity of the Na atoms is present as a distorted trigonal prism or, with addition of a further O atom, as a distorted capped cube. 
     The specified embodiments of the phosphor can be produced in accordance with methods specified below. All features described for the phosphor thus also apply to the method for producing said phosphor, and vice-versa. 
     A method for producing a phosphor is specified. 
     In accordance with at least one embodiment, the phosphor has the general molecular formula:
 
(MA) a (MB) b (MC) c (MD) d (TA) e (TB) f (TC) g (TD) h (TE) i (TF)(XA) k (XB) l (XC) m (XD) n :E
 
     In this case, MA is selected from a group of monovalent metals, MB is selected from a group of divalent metals, MC is selected from a group of trivalent metals, MD is selected from a group of tetravalent metals, TA is selected from a group of monovalent metals, TB is selected from a group of divalent metals, TC is selected from a group of trivalent metals, TD is selected from a group of tetravalent metals, TE is selected from a group of pentavalent elements, TF is selected from a group of hexavalent elements, XA is selected from a group of elements which comprises halogens, XB is selected from a group of elements which comprises O, S and combinations thereof, XC═N and XD=C. The following furthermore hold true:
         a+b+c+d=t;   e+f+g+h+i+j=u   k+l+m+n=v   a+2b+3c+4d+e+2f+3g+4h+5i+6j−k−2l−3m−4n=w   0.8≤t≤1   3.5≤u≤4   3.5≤v≤4   (−0.2)≤w≤0.2 and E=Eu, Ce, Yb and/or Mn. It advantageously holds true that: 0≤m&lt;0.875 v and/or v≥l&gt;0.125 v.       

     The method comprises the following method steps: 
     A) mixing starting materials with the phosphor, 
     B) heating the mixture obtained under A) to a temperature T 1  of between 500 and 1400° C., advantageously between 700 and 1400° C., 
     C) annealing the mixture at a temperature T 1  of 500 to 1400° C., advantageously between 700 and 1400° C., for 0.5 minute to 10 hours. 
     In one embodiment, the starting materials are present as powder. 
     In one embodiment, method step C) is followed by a further method step: 
     D) cooling the mixture to room temperature. Room temperature is understood to mean 20° C., in particular. 
     In one embodiment, method step D) is followed by method steps B) and C) again, wherein the phosphor obtained in method step D) is then heated and annealed, respectively. The optical properties of the phosphor can be improved by this further annealing process. 
     In accordance with at least one embodiment, the starting materials melt during the process of heating the mixture obtained under A) in method step B). 
     The heating and cooling rates can be for example 250° C. per hour. 
     In one embodiment, method steps B), C) and/or D) take place under forming gas atmosphere. Advantageously, in the forming gas the ratio of nitrogen:hydrogen is 92.5:7.5. 
     In one embodiment, method steps B), C) and/or D) take place in a tube furnace. 
     In accordance with at least one embodiment, the method comprises the following method step A): 
     A) mixing the starting materials comprising K 2 CO 3 , Cs 2 CO 3 , Na 2 CO 3  and/or Rb 2 CO 3 . 
     In accordance with at least one embodiment, the method comprises the following method step A): 
     A) mixing the starting materials comprising or consisting of SiO 2 , Eu 2 O 3 , Li 2 CO 3  and at least one carbonate from K 2 CO 3 , Cs 2 CO 3 , Na 2 CO 3  and Rb 2 CO 3 . In particular, with the use of these starting materials it is possible to produce the phosphors (Na r K 1−r )Li 3 SiO 4 :Eu, (Rb r′ Li 1−r′ )Li 3 SiO 4 :Eu and (K 1−r″−r′″ Na r″ Li r′″ )Li 3 SiO 4 :Eu, advantageously NaLi 3 SiO 4 :Eu, KLi 3 SiO 4 :Eu, (Na 0.5 K 0.5 )Li 3 SiO 4 :Eu, (Rb 0.5 Li 0.5 )Li 3 SiO 4 :Eu, (Na 0.25 K 0.75 )Li 3 SiO 4 :Eu and (Na 0.25 K 0.5 Li 0.25 )Li 3 SiO 4 :Eu. 
     In accordance with at least one embodiment, the method comprises the following method step A): 
     A) mixing the starting materials comprising or consisting of CaO, NaF, LiN 3 , Li 2 O, LiAlH 4 , AlF 3 , SiO 2  and EuF 3 . In particular, with the use of these starting materials it is possible to produce a phosphor of the formula Na 1−y* Ca y* Li 3−2y* Al 3y* Si 1−y O 4−4y* N 4y* :Eu, for example Na 0.97 Ca 0.03 Li 2.94 Al 0.09 Si 0.97 O 3.88 N 0.12 :Eu. 
     The production method can be carried out very simply in comparison with many other methods for producing phosphors. In particular, no protective gas atmosphere is required since the products are insensitive to moisture or oxygen. Moreover, the synthesis is carried out at moderate temperatures and is therefore very energy-efficient. The requirements made, for example, of the furnace used are thus low. The starting materials are commercially available in a cost-effective manner and are non-toxic. 
     EXEMPLARY EMBODIMENTS 
     The first exemplary embodiment (Al) of the phosphor according to the present disclosure has the molecular formula NaLi 3 SiO 4 :Eu 2+  (2 mol % Eu 2+  relative to the substance amount of Na) and is produced as follows: Na 2 CO 3 , Li 2 CO 3 , SiO 2  and Eu 2 O 3  are melted in a stoichiometric ratio corresponding to the molecular formula in an open nickel crucible. The weighed-in quantities of the starting materials are found in table 1 below. The nickel crucible with the mixed starting materials is heated for one hour to approximately 1000° C. under a forming gas atmosphere (N 2 :H 2 =92.5:7.5) and then cooled. Further heating under the same forming gas atmosphere and to temperatures below the melting point of the phosphor can be carried out in order to further improve the optical properties of the phosphor. 
     
       
         
           
               
               
               
               
             
               
                   
                 TABLE 1 
               
               
                   
                   
               
               
                   
                 Starting 
                 Substance 
                   
               
               
                   
                 material 
                 amount/mmol 
                 Mass/g 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
            
               
                   
                 Na 2 CO 3   
                 21.82 
                 2.313 
               
               
                   
                 Li 2 CO 3   
                 66.21 
                 4.892 
               
               
                   
                 SiO 2   
                 43.94 
                 2.640 
               
               
                   
                 Eu 2 O 3   
                 0.44 
                 0.155 
               
               
                   
                   
               
            
           
         
       
     
     The starting materials of the phosphor are commercially available, stable and moreover very inexpensive. The synthesis at comparatively low temperatures makes the phosphor very inexpensive to produce and, as a result, also economically attractive. 
     The phosphor of the first exemplary embodiment (AB1) exhibits an emission in the blue spectral range of the electromagnetic spectrum. 
     The second exemplary embodiment (AB2) of the phosphor according to the present disclosure has the molecular formula KLi 3 SiO 4 :Eu 2+  (2 mol % Eu 2+  relative to the substance amount of K) and is produced as follows: K 2 CO 3 , Li 2 CO 3 , SiO 2  and Eu 2 O 3  are melted in a stoichiometric ratio corresponding to the molecular formula in an open nickel crucible. The weighed-in quantities of the starting materials are found in table 2 below. The nickel crucible with the mixed starting materials is heated for one hour to approximately 1000° C. under a forming gas atmosphere (N 2 :H 2 =92.5:7.5) and then cooled. Further heating under the same forming gas atmosphere and to temperatures below the melting point of the phosphor can be carried out in order to further improve the optical properties of the phosphor. 
     
       
         
           
               
               
               
               
             
               
                   
                 TABLE 2 
               
               
                   
                   
               
               
                   
                 Starting 
                 Substance 
                   
               
               
                   
                 material 
                 amount/mmol 
                 Mass/g 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
            
               
                   
                 K 2 CO 3   
                 40.78 
                 5.636 
               
               
                   
                 Li 2 CO 3   
                 123.71 
                 9.141 
               
               
                   
                 SiO 2   
                 82.10 
                 4.933 
               
               
                   
                 Eu 2 O 3   
                 0.82 
                 0.290 
               
               
                   
                   
               
            
           
         
       
     
     The phosphor of the second exemplary embodiment (AB2) exhibits a wide emission from the blue to red spectral range of the electromagnetic spectrum and thus emits white, in particular warm-white, radiation having a color temperature of less than 3500 K. 
     The third exemplary embodiment (AB3) of the phosphor according to the present disclosure has the molecular formula (Na 0.5 K 0.5 )Li 3 SiO 4 :Eu 2+  (2 mol % Eu 2+  relative to the substance amount of Na and K) or NaKLi 6 Si 2 O 8 :Eu 2+  and is produced as follows: K 2 CO 3 , Na 2 CO 3 , Li 2 CO 3 , SiO 2  and Eu 2 O 3  are melted in a stoichiometric ratio corresponding to the molecular formula in an open nickel crucible. The weighed-in quantities of the starting materials are found in table 3 below. The nickel crucible with the mixed starting materials is heated for one hour to eight hours to 800° C. to 1100° C. under a forming gas atmosphere (N 2 :H 2 =92.5:7.5) and then cooled. Further heating under the same forming gas atmosphere and to temperatures below the melting point of the phosphor can be carried out in order to further improve the optical properties of the phosphor. 
     
       
         
           
               
               
               
               
             
               
                   
                 TABLE 3 
               
               
                   
                   
               
               
                   
                 Starting 
                 Substance 
                   
               
               
                   
                 material 
                 amount/mmol 
                 Mass/g 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
            
               
                   
                 Na 2 CO 3   
                 10.65 
                 1.129 
               
               
                   
                 K 2 CO 3   
                 10.44 
                 1.443 
               
               
                   
                 Li 2 CO 3   
                 63.97 
                 4.727 
               
               
                   
                 SiO 2   
                 42.46 
                 2.551 
               
               
                   
                 Eu 2 O 3   
                 0.43 
                 0.150 
               
               
                   
                   
               
            
           
         
       
     
     The phosphor of the third exemplary embodiment (AB3) exhibits an emission in the blue spectral range of the electromagnetic spectrum. 
     The fourth exemplary embodiment (AB4) of the phosphor according to the present disclosure has the molecular formula (Na 0.25 K 0.75 )Li 3 SiO 4 :Eu 2+  (2 mol % Eu 2+  relative to the substance amount of Na and K) or NaK 3 Li 2 Si 4 O 16 :Eu 2+  and is produced as follows: K 2 CO 3 , Na 2 CO 3 , Li 2 CO 3 , SiO 2  and Eu 2 O 3  are melted in a stoichiometric ratio corresponding to the molecular formula in an open nickel crucible. The weighed-in quantities of the starting materials are found in table 4 below. The nickel crucible with the mixed starting materials is heated for four hours to 900° C. to 1100° C. under a forming gas atmosphere (N 2 :H 2 =92.5:7.5) and then cooled. Further heating under the same forming gas atmosphere and to temperatures below the melting point of the phosphor can be carried out in order to further improve the optical properties of the phosphor. 
     
       
         
           
               
               
               
               
             
               
                   
                 TABLE 4 
               
               
                   
                   
               
               
                   
                 Starting 
                 Substance 
                   
               
               
                   
                 material 
                 amount/mmol 
                 Mass/g 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
            
               
                   
                 Na 2 CO 3   
                 5.24 
                 0.555 
               
               
                   
                 K 2 CO 3   
                 15.50 
                 2.142 
               
               
                   
                 Li 2 CO 3   
                 62.90 
                 4.648 
               
               
                   
                 SiO 2   
                 41.75 
                 2.508 
               
               
                   
                 Eu 2 O 3   
                 0.42 
                 0.147 
               
               
                   
                   
               
            
           
         
       
     
     The phosphor of the fourth exemplary embodiment (AB4) exhibits an emission in the green spectral range of the electromagnetic spectrum. 
     The fifth exemplary embodiment (AB5) of the phosphor according to the present disclosure has the molecular formula (Rb 0.5 Li 0.5 )Li 3 SiO 4 :Eu 2+  (2 mol % Eu 2+  relative to the substance amount of (Rb 0.5 Li 0.5 )) or RbLiLi 6 Si 2 O 8 :Eu 2+  and is produced as follows: Rb 2 CO 3 , Li 2 CO 3 , SiO 2  and Eu 2 O 3  are melted in a stoichiometric ratio corresponding to the molecular formula in an open nickel crucible. The weighed-in quantities of the starting materials are found in table 5 below. The nickel crucible with the mixed starting materials is heated for four hours to approximately 1000° C. under a forming gas atmosphere (N 2 :H 2 =92.5:7.5) and then cooled. Afterward, the product obtained is ground and a green powder is obtained. 
     Further heating under the same forming gas atmosphere and to temperatures below the melting point of the phosphor can be carried out in order to further improve the optical properties of the phosphor. 
     
       
         
           
               
               
               
               
             
               
                   
                 TABLE 5 
               
               
                   
                   
               
               
                   
                 Starting 
                 Substance 
                   
               
               
                   
                 material 
                 amount/mmol 
                 Mass/g 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
            
               
                   
                 Rb 2 CO 3   
                 17.05 
                 3.937 
               
               
                   
                 Li 2 CO 3   
                 52.30 
                 3.864 
               
               
                   
                 SiO 2   
                 34.56 
                 2.076 
               
               
                   
                 Eu 2 O 3   
                 0.35 
                 0.122 
               
               
                   
                   
               
            
           
         
       
     
     The phosphor of the fifth exemplary embodiment (AB5) exhibits an emission in the green spectral range of the electromagnetic spectrum. 
     The sixth exemplary embodiment (AB6) of the phosphor according to the present disclosure has the molecular formula Na 1−y* Ca y* Li 3−2y* Al 3y* Si 1−y* O 4−4y* N 4y* :Eu (where y*=0.03; Eu 2+  approximately 2 mol % relative to the substance amount of Na and Ca) and is produced as follows: CaO, NaF, NiN 3 , Li 2 O, LiAlH 4 , AlF 3 , SiO 2  and EuF 3  are heated in a stoichiometric ratio corresponding to the molecular formula to a maximum of 950° C. in a welded shut tantalum ampoule. During the heating or firing process, the ampoule is situated in an evacuated glass tube in order to avoid oxidation of the ampoule (reduced stability) and hence bursting, which results from the vapor pressure of evaporated starting materials during heating. After cooling to room temperature, individual crystals of the phosphor can be isolated from byproducts and be structurally and optically examined. The weighed-in quantities of the starting materials are found in table 6 below. 
     
       
         
           
               
               
               
             
               
                   
                 TABLE 6 
               
               
                   
                   
               
               
                   
                 Starting 
                   
               
               
                   
                 material 
                 Mass/mg 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
            
               
                   
                 CaO 
                 7.01 
               
               
                   
                 NaF 
                 15.75 
               
               
                   
                 LiN 3   
                 8.15 
               
               
                   
                 Li 2 O 
                 21.51 
               
               
                   
                 LiAlH 4   
                 9.49 
               
               
                   
                 AlF 3   
                 10.50 
               
               
                   
                 SiO 2   
                 22.53 
               
               
                   
                 EuF 3   
                 2.09 
               
               
                   
                   
               
            
           
         
       
     
     The synthesis at comparatively low temperatures makes the phosphor very inexpensive to produce and, as a result, also economically attractive. By means of energy dispersive X-ray spectroscopy on single crystals of the phosphor, an average Ca proportion of 3 mol % based on the total substance amount of Na and Ca and a nitrogen proportion of 3 mol % relative to the total substance amount of nitrogen and oxygen were determined, which accords with the formula Na 0.97 Ca 0.03 Li 2.94 Al 0.09 Si 0.97 O 3.88 N 0.12 :Eu. 
     The phosphor of the sixth exemplary embodiment (AB6) exhibits an emission in the blue-green spectral range of the electromagnetic spectrum. 
     The seventh exemplary embodiment (AB7) of the phosphor according to the present disclosure has the molecular formula (Na 0.25 K 0.50 Li 0.25 )Li 3 SiO 4 :Eu 2+  or NaK 2 Li(Li 3 SiO 4 ) 4 :Eu 2+  and is produced as follows: K 2 CO 3 , Na 2 CO 3 , Li 2 CO 3 , SiO 2  and Eu 2 O 3  are mixed in a stoichiometric ratio corresponding to the molecular formula in an open nickel crucible. The weighed-in quantities of the starting materials are found in table 7 below. The nickel crucible with the mixed starting materials is heated for four hours to approximately 750° C. under a forming gas atmosphere (N 2 :H 2 =92.5:7.5) and then cooled. Further heating under the same forming gas atmosphere and to temperatures below the melting point of the phosphor can be carried out in order to further improve the optical properties of the phosphor. After cooling, an agglomerate of light green crystals is obtained, which are separated into individual crystals by grinding for example in an agate mortar. 
     
       
         
           
               
               
               
               
             
               
                   
                 TABLE 7 
               
               
                   
                   
               
               
                   
                 Starting 
                 Substance amount/ 
                   
               
               
                   
                 material 
                 mmol 
                 Mass/g 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
            
               
                   
                 Na 2 CO 3   
                 1.377 
                 0.146 
               
               
                   
                 K 2 CO 3   
                 9.420 
                 1.302 
               
               
                   
                 Li 2 CO 3   
                 77.192 
                 5.704 
               
               
                   
                 SiO 2   
                 46.117 
                 2.771 
               
               
                   
                 Eu 2 O 3   
                 0.220 
                 0.078 
               
               
                   
                   
               
            
           
         
       
     
     The phosphor of the seventh exemplary embodiment (AB7) exhibits an emission in the green spectral range of the electromagnetic spectrum. By means of single crystal diffractometry, the molecular formula (Na 0.25 K 0.50 Li 0.25 )Li 3 SiO 4 :Eu 2+  can be allocated to the phosphor. 
     The eighth exemplary embodiment (AB8) of the phosphor according to the present disclosure has the molecular formula (Rb 0.5 Na 0.5 )Li 3 SiO 4 :Eu 2+  or RbNaLi 6 Si 2 O 8 :Eu 2+  and is produced as follows: Rb 2 CO 3 , Na 2 CO 3 , Li 2 CO 3 , SiO 2  and Eu 2 O 3  are mixed in a stoichiometric ratio corresponding to the molecular formula in an open nickel crucible. The weighed-in quantities of the starting materials are found in table 8 below. The nickel crucible with the mixed starting materials is heated for one to eight hours to between 700° C. and 1000° C. under a forming gas atmosphere (N 2 :H 2 =92.5:7.5) and then cooled. The product obtained is then ground and a green powder is obtained. 
     Further heating under the same forming gas atmosphere and to temperatures below the melting point of the phosphor can be carried out in order to further improve the optical properties of the phosphor. 
     
       
         
           
               
               
               
               
             
               
                   
                 TABLE 8 
               
               
                   
                   
               
               
                   
                 Starting 
                 Substance amount/ 
                   
               
               
                   
                 material 
                 mmol 
                 Mass/g 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
            
               
                   
                 Rb 2 CO 3   
                 9.64 
                 2.226 
               
               
                   
                 Na 2 CO 3   
                 8.77 
                 0.929 
               
               
                   
                 Li 2 CO 3   
                 59.2 
                 4.371 
               
               
                   
                 SiO 2   
                 39.1 
                 2.348 
               
               
                   
                 Eu 2 O 3   
                 0.358 
                 0.126 
               
               
                   
                   
               
            
           
         
       
     
     The phosphor of the eighth exemplary embodiment (AB8) exhibits an emission in the green spectral range of the electromagnetic spectrum. 
     The ninth exemplary embodiment (AB9) of the phosphor according to the present disclosure has the molecular formula (Rb 0.25 Na 0.75 )Li 3 SiO 4 :Eu 2+  or RbNa 3 Li 12 Si 4 O 16 :Eu 2+  and is produced as follows: Rb 2 CO 3 , Na 2 CO 3 , Li 2 CO 3 , SiO 2  and Eu 2 O 3  are mixed in a stoichiometric ratio corresponding to the molecular formula in an open nickel crucible. The weighed-in quantities of the starting materials are found in table 9 below. The nickel crucible with the mixed starting materials is heated for one to eight hours to between 700° C. and 1000° C. under a forming gas atmosphere (N 2 :H 2 =92.5:7.5) and then cooled. The product obtained is then ground and a green powder is obtained. 
     Further heating under the same forming gas atmosphere and to temperatures below the melting point of the phosphor can be carried out in order to further improve the optical properties of the phosphor. 
     
       
         
           
               
               
               
               
             
               
                   
                 TABLE 9 
               
               
                   
                   
               
               
                   
                 Starting 
                 Substance amount/ 
                   
               
               
                   
                 material 
                 mmol 
                 Mass/g 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
            
               
                   
                 Rb 2 CO 3   
                 5.521 
                 1.275 
               
               
                   
                 Na 2 CO 3   
                 14.96 
                 1.586 
               
               
                   
                 Li 2 CO 3   
                 60.28 
                 4.454 
               
               
                   
                 SiO 2   
                 44.10 
                 2.650 
               
               
                   
                 Eu 2 O 3   
                 0.1 
                 0.035 
               
               
                   
                   
               
            
           
         
       
     
     The phosphor of the ninth exemplary embodiment (AB9) exhibits an emission in the blue spectral range of the electromagnetic spectrum. 
     The tenth exemplary embodiment (AB10) of the phosphor according to the present disclosure has the molecular formula Sr(Si 0.25 Al −1/8+r**/2 Li 7/8−r**/2 ) 4 (O 1−r** N r** ) 4  where r**=0.67 and thus SrSiAl 0.84 Li 2.16 O 1.32 N 2.68 :Eu 2+  and is produced as follows: NaLi 3 SiO 4 , SrO, LiAlH 4  and Eu 2 O 3  are mixed in an open nickel crucible. The weighed-in quantities of the starting materials are found in table 10 below. The nickel crucible with the mixed starting materials is heated for one to eight hours, advantageously 2 to six hours, very particularly advantageously for four hours, to a temperature between 800° C. and 1000° C., advantageously 900° C., under a forming gas atmosphere (N 2 :H 2 =92.5:7.5) in a tube furnace and then cooled. 
     Further heating under the same forming gas atmosphere and to temperatures below the melting point of the phosphor can be carried out in order to further improve the optical properties of the phosphor. 
     
       
         
           
               
               
               
               
             
               
                   
                 TABLE 10 
               
               
                   
                   
               
               
                   
                 Starting 
                 Substance amount/ 
                   
               
               
                   
                 material 
                 mmol 
                 Mass/g 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
            
               
                   
                 NaLi 3 SiO 4   
                 31.42 
                 4.270 
               
               
                   
                 SrO 
                 23.70 
                 2.456 
               
               
                   
                 LiAlH 4   
                 77.12 
                 2.922 
               
               
                   
                 Eu 2 O 3   
                 1.00 
                 0.352 
               
               
                   
                   
               
            
           
         
       
     
     The phosphor of the tenth exemplary embodiment (AB10) exhibits an emission in the yellow or yellow-orange spectral range of the electromagnetic spectrum. The composition of the tenth exemplary embodiment was determined by means of energy dispersive X-ray spectroscopy on single crystals and single crystal diffractometry. 
     The eleventh exemplary embodiment (AB11) of the phosphor according to the present disclosure has the molecular formula Na 1−y** Eu y* Li 3−2y** Al 3y** Si 1−y** O 4−4y** N 4y** :Eu where y**=0.2224 and is produced as follows: CaO, LiF, LiN 3 , Li 2 O, LiAlH 4 , SiO 2  and EuF 3  are heated to a maximum of 900° C. in a welded shut tantalum ampoule. During the heating or firing process, the ampoule is situated in an evacuated glass tube in order to avoid oxidation of the ampoule (reduced stability) and hence bursting, which results from the vapor pressure of evaporated starting materials during heating. After cooling to room temperature, individual orange crystals of the phosphor can be isolated from byproducts and be structurally and optically examined. The weighed-in quantities of the starting materials are found in table 11 below. 
     
       
         
           
               
               
               
             
               
                   
                 TABLE 11 
               
               
                   
                   
               
               
                   
                 Starting 
                   
               
               
                   
                 material 
                 Mass/mg 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
            
               
                   
                 Na 2 O 
                 11.02 
               
               
                   
                 LiF (Flux) 
                 10 
               
               
                   
                 LiN 3   
                 11.61 
               
               
                   
                 Li 2 O 
                 17.72 
               
               
                   
                 LiAlH 4   
                 13.50 
               
               
                   
                 SiO 2   
                 21.37 
               
               
                   
                 EuF 2   
                 24.78 
               
               
                   
                   
               
            
           
         
       
     
     The phosphor of the eleventh exemplary embodiment (AB11) exhibits an emission in the yellow-orange spectral range of the electromagnetic spectrum. 
     The twelfth exemplary embodiment (AB12) of the phosphor according to the present disclosure has the molecular formula SrLi 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu where x**=0.2014 and is produced as follows: SrAl 2 O 4 :Eu and LiN 3  are heated to a maximum of 900° C. in a welded shut tantalum ampoule. During the heating or firing process, the ampoule is situated in an evacuated glass tube in order to avoid oxidation of the ampoule (reduced stability) and hence bursting, which results from the vapor pressure of evaporated starting materials during heating. After cooling to room temperature, individual yellow/green crystals of the phosphor can be isolated from byproducts and be structurally and optically examined. The weighed-in quantities of the starting materials are found in table 12 below. 
     
       
         
           
               
               
               
             
               
                   
                 TABLE 12 
               
               
                   
                   
               
               
                   
                 Starting 
                   
               
               
                   
                 material 
                 Mass/mg 
               
               
                   
                   
               
             
            
               
                   
                 SrAl 2 O 4 :Eu 
                 30.64 
               
               
                   
                 LiN 3   
                 22.06 
               
               
                   
                   
               
            
           
         
       
     
     The phosphor can be produced at comparatively low temperatures, below 1000° C., which makes possible a cost-saving synthesis. 
     The phosphor of the twelfth exemplary embodiment (AB12) exhibits an emission in the green to yellow spectral range of the electromagnetic spectrum. 
     Further exemplary embodiments of the phosphor having the molecular formula SrLi 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu are produced by mixing the starting materials in accordance with table 13 below in an open nickel crucible. The nickel crucible with the mixed starting materials is heated for one to 12 hours, advantageously 4 to 8 hours, to a temperature of between 800° C. and 1200° C., advantageously 900° C., under a forming gas atmosphere (N 2 :H 2 =92.5:7.5) under atmospheric pressure or slightly reduced pressure in a tube furnace and is then cooled. After cooling to room temperature, individual yellow/green crystals can be isolated. 
     
       
         
           
               
               
               
               
               
             
               
                 TABLE 13 
               
               
                   
               
               
                 Exemplary 
                   
                 Starting 
                 Substance 
                   
               
               
                 embodiment 
                 x** 
                 material 
                 amount/mmol 
                 Mass/g 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
            
               
                 AB12-1 
                 0.125 
                 SrO 
                 70.00 
                 7.253 
               
               
                   
                   
                 Al 2 O 3   
                 17.67 
                 1.802 
               
               
                   
                   
                 Li 3 N 
                 23.57 
                 0.821 
               
               
                   
                   
                 Eu 2 O 3   
                 0.3524 
                 0.124 
               
               
                 AB12-2 
                 0.1375 
                 SrO 
                 75.17 
                 7.789 
               
               
                   
                   
                 Al 2 O 3   
                 15.18 
                 1.548 
               
               
                   
                   
                 Li 3 N 
                 15.19 
                 0.529 
               
               
                   
                   
                 Eu 2 O 3   
                 0.3808 
                 0.134 
               
               
                 AB12-3 
                 0.17 
                 SrO 
                 63.22 
                 6.551 
               
               
                   
                   
                 Al 2 O 3   
                 43.00 
                 4.385 
               
               
                   
                   
                 Li 2 CO 3   
                 21.50 
                 1.589 
               
               
                   
                   
                 Li 3 N 
                 64.51 
                 2.247 
               
               
                   
                   
                 Eu 2 O 3   
                 0.6450 
                 0.227 
               
               
                 AB12-4 
                 0.20 
                 SrO 
                 69.44 
                 7.195 
               
               
                   
                   
                 Al 2 O 3   
                 49.60 
                 5.057 
               
               
                   
                   
                 Li 2 CO 3   
                 7.092 
                 0.524 
               
               
                   
                   
                 Li 3 N 
                 56.68 
                 1.974 
               
               
                   
                   
                 Eu 2 O 3   
                 0.7075 
                 0.249 
               
               
                 AB12-5 
                 0.24 
                 SrO 
                 70.48 
                 7.303 
               
               
                   
                   
                 Al 2 O 3   
                 48.90 
                 4.986 
               
               
                   
                   
                 AlN 
                 8.636 
                 0.354 
               
               
                   
                   
                 Li 3 N 
                 60.40 
                 2.104 
               
               
                   
                   
                 Eu 2 O 3   
                 0.7189 
                 0.253 
               
               
                 AB12-6 
                 0.28 
                 SrO 
                 70.04 
                 7.258 
               
               
                   
                   
                 Al 2 O 3   
                 44.79 
                 4.567 
               
               
                   
                   
                 AlN 
                 21.91 
                 0.898 
               
               
                   
                   
                 Li 3 N 
                 58.14 
                 2.025 
               
               
                   
                   
                 Eu 2 O 3   
                 0.7161 
                 0.252 
               
               
                 AB12-7 
                 0.34 
                 SrO 
                 69.41 
                 7.192 
               
               
                   
                   
                 Al 2 O 3   
                 38.72 
                 3.948 
               
               
                   
                   
                 AlN 
                 41.55 
                 1.703 
               
               
                   
                   
                 Li 3 N 
                 54.78 
                 1.908 
               
               
                   
                   
                 Eu 2 O 3   
                 0.7075 
                 0.249 
               
               
                 AB12-8 
                 0.44 
                 SrO 
                 68.37 
                 7.085 
               
               
                   
                   
                 Al 2 O 3   
                 28.83 
                 2.940 
               
               
                   
                   
                 AlN 
                 73.48 
                 3.012 
               
               
                   
                   
                 Li 3 N 
                 49.30 
                 1.717 
               
               
                   
                   
                 Eu 2 O 3   
                 0.6990 
                 0.246 
               
               
                   
               
            
           
         
       
     
     The thirteenth exemplary embodiment (AB13) of the phosphor according to the present disclosure has the molecular formula (Cs 0.25 Na 0.25 K 0.25 Li 0.25 )Li 3 SiO 4 :Eu 2+  and is produced analogously to the eighth exemplary embodiment. The starting materials are indicated in table 14 below. 
     
       
         
           
               
               
               
               
             
               
                   
                 TABLE 14 
               
               
                   
                   
               
               
                   
                 Starting 
                 Substance amount/ 
                   
               
               
                   
                 material 
                 mmol 
                 Mass/g 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
            
               
                   
                 Cs 2 CO 3   
                 4.75 
                 1.547 
               
               
                   
                 Na 2 CO 3   
                 5.16 
                 0.547 
               
               
                   
                 Li 2 CO 3   
                 62.1 
                 4.585 
               
               
                   
                 K 2 CO 3   
                 5.16 
                 0.713 
               
               
                   
                 SiO 2   
                 41.0 
                 2.463 
               
               
                   
                 Eu 2 O 3   
                 0.412 
                 0.145 
               
               
                   
                   
               
            
           
         
       
     
     The phosphor of the thirteenth exemplary embodiment (AB13) exhibits an emission in the green spectral range of the electromagnetic spectrum. 
     The fourteenth exemplary embodiment (AB14) of the phosphor according to the present disclosure has the molecular formula (Cs 0.25 Na 0.50 K 0.25 )Li 3 SiO 4 :Eu 2+  and is produced analogously to the eighth exemplary embodiment. The starting materials are indicated in table 15 below. 
     
       
         
           
               
               
               
               
             
               
                   
                 TABLE 15 
               
               
                   
                   
               
               
                   
                 Starting 
                 Substance amount/ 
                   
               
               
                   
                 material 
                 mmol 
                 Mass/g 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
            
               
                   
                 Cs 2 CO 3   
                 4.50 
                 1.466 
               
               
                   
                 Na 2 CO 3   
                 9.78 
                 1.037 
               
               
                   
                 Li 2 CO 3   
                 58.8 
                 4.347 
               
               
                   
                 K 2 CO 3   
                 4.89 
                 0.676 
               
               
                   
                 SiO 2   
                 38.9 
                 2.336 
               
               
                   
                 Eu 2 O 3   
                 0.392 
                 0.138 
               
               
                   
                   
               
            
           
         
       
     
     The phosphor of the fourteenth exemplary embodiment (AB14) exhibits an emission in the blue spectral range of the electromagnetic spectrum. 
     The fifteenth exemplary embodiment (AB15) of the phosphor according to the present disclosure has the molecular formula (Rb 0.25 Na 0.50 K 0.25 )Li 3 SiO 4 :Eu 2+  and is produced analogously to the eighth exemplary embodiment. The starting materials are indicated in table 16 below. 
     
       
         
           
               
               
               
               
             
               
                   
                 TABLE 16 
               
               
                   
                   
               
               
                   
                 Starting 
                 Substance amount/ 
                   
               
               
                   
                 material 
                 mmol 
                 Mass/g 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
            
               
                   
                 Rb 2 CO 3   
                 4.70 
                 1.086 
               
               
                   
                 Na 2 CO 3   
                 10.2 
                 1.083 
               
               
                   
                 Li 2 CO 3   
                 61.5 
                 4.541 
               
               
                   
                 K 2 CO 3   
                 5.11 
                 0.706 
               
               
                   
                 SiO 2   
                 40.6 
                 2.440 
               
               
                   
                 Eu 2 O 3   
                 0.409 
                 0.144 
               
               
                   
                   
               
            
           
         
       
     
     The phosphor of the fifteenth exemplary embodiment (AB15) exhibits an emission in the blue spectral range of the electromagnetic spectrum. 
     The sixteenth exemplary embodiment (AB16) of the phosphor according to the present disclosure has the molecular formula (Rb 0.25 Na 0.25 Cs 0.25 Li 0.25 )Li 3 SiO 4 :Eu 2+  and is produced analogously to the eighth exemplary embodiment. The starting materials are indicated in table 17 below. 
     
       
         
           
               
               
               
               
             
               
                   
                 TABLE 17 
               
               
                   
                   
               
               
                   
                 Starting 
                 Substance amount/ 
                   
               
               
                   
                 material 
                 mmol 
                 Mass/g 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
            
               
                   
                 Rb 2 CO 3   
                 4.49 
                 1.036 
               
               
                   
                 Cs 2 CO 3   
                 4.48 
                 1.461 
               
               
                   
                 Na 2 CO 3   
                 9.34 
                 0.990 
               
               
                   
                 Li 2 CO 3   
                 56.2 
                 4.151 
               
               
                   
                 SiO 2   
                 37.1 
                 2.230 
               
               
                   
                 Eu 2 O 3   
                 0.375 
                 0.132 
               
               
                   
                   
               
            
           
         
       
     
     The phosphor of the sixteenth exemplary embodiment (AB16) exhibits an emission in the blue spectral range of the electromagnetic spectrum. 
     The seventeenth exemplary embodiment (AB17) of the phosphor according to the present disclosure has the molecular formula (Na 0.125 K 0.875 )Li 3 SiO 4 :Eu 2+  or NaK 7  (Li 3 SiO 4 ) 8 :Eu 2+  and is produced as follows: K 2 CO 3 , Na 2 CO 3 , Li 2 CO 3 , SiO 2  and Eu 2 O 3  are mixed in a stoichiometric ratio corresponding to the molecular formula in an open nickel crucible. The weighed-in quantities of the starting materials are found in table 18 below. The nickel crucible with the mixed starting materials is heated for four hours to 1000° C. under a forming gas atmosphere (N 2 :H 2 =92.5:7.5) and is then cooled at a constant cooling rate to 300° C. The furnace is switched off and, after cooling to room temperature, yellow-green single crystals are isolated. 
     
       
         
           
               
               
               
             
               
                   
                 TABLE 18 
               
               
                   
                   
               
               
                   
                 Starting 
                   
               
               
                   
                 material 
                 Mass/mg 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
            
               
                   
                 Na 2 CO 3   
                 25.97 
               
               
                   
                 K 2 CO 3   
                 101.58 
               
               
                   
                 Li 2 CO 3   
                 221.67 
               
               
                   
                 SiO 2   
                 120.17 
               
               
                   
                 Eu 2 O 3   
                 7.04 
               
               
                   
                   
               
            
           
         
       
     
     The phosphor of the seventeenth exemplary embodiment (AB17) exhibits an emission in the blue-green and in the yellow-orange spectral range of the electromagnetic spectrum. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
       In the drawings, like reference characters generally refer to the same parts throughout the different views. The drawings are not necessarily to scale, emphasis instead generally being placed upon illustrating the principles of the disclosed embodiments. In the following description, various embodiments described with reference to the following drawings, in which: 
         FIGS.  1 A,  1 B,  1 BA,  1 BB,  1 C,  1 D,  1 E,  1 F  show a selection of possible electroneutral molecular formulae of substitution experiments. 
         FIGS.  2 ,  13 ,  23 ,  38 ,  63 ,  68 ,  74 ,  82 ,  83 ,  92 ,  93 ,  102 ,  103 ,  105 ,  112 ,  118 B,  129 ,  131 ,  133 ,  135 ,  152 B ,  154 ,  161 ,  163  show emission spectra of exemplary embodiments of the phosphor according to the present disclosure. 
         FIGS.  3 ,  14 ,  24 ,  39 ,  64 ,  84 ,  94 ,  104 ,  130 ,  132 ,  134 ,  136    show the Kubelka-Munk functions for exemplary embodiments of the phosphor according to the present disclosure. 
         FIGS.  4 ,  43 ,  66 ,  70 ,  76 ,  86 ,  96 ,  121 ,  123    show a comparison of optical properties of an exemplary embodiment of the phosphor according to the present disclosure with comparative examples. 
         FIGS.  5 ,  6 ,  44 ,  67 ,  69 ,  75 ,  85 ,  95 ,  122    show a comparison of emission spectra of an exemplary embodiment with comparative examples. 
         FIG.  7    shows a comparison of the Kubelka-Munk function of an exemplary embodiment with comparative examples. 
         FIGS.  8 ,  18 ,  25 ,  71 ,  77 ,  78 ,  88 ,  97 ,  107 ,  114 ,  137 ,  138 ,  139 ,  140 ,  160 ,  171 ,  172 ,  173    show excerpts from the crystal structure for exemplary embodiments of the phosphor according to the present disclosure. 
         FIGS.  9 ,  19 ,  40 ,  65 ,  111 ,  118 A,  177    show X-ray diffraction powder diffractograms using copper K α1  radiation or molybdenum K α1  radiation. 
         FIGS.  10 ,  20 ,  26 ,  89 ,  98 ,  141 ,  142 ,  143 ,  144    show Rietveld refinements of X-ray powder diffractograms of exemplary embodiments of the phosphor according to the present disclosure. 
         FIGS.  11 ,  12 ,  21 ,  22 ,  27 ,  28 ,  72 ,  73 ,  79 ,  80 ,  81 ,  90 ,  91 ,  99 ,  100 ,  108 ,  109 ,  110 ,  115 ,  116 ,  117   ,  126 ,  127 ,  128 ,  145 - 151 ,  152 A,  158 ,  159 ,  174 ,  175 ,  176  show characteristic properties of exemplary embodiments of the phosphor according to the present disclosure. 
         FIGS.  15 ,  16 ,  124    show comparisons of emission spectra of a conversion LED with an exemplary embodiment of the phosphor according to the present disclosure with comparative examples. 
         FIGS.  17 ,  125 ,  164 ,  167    show a comparison of optical properties of a conversion LED with an exemplary embodiment of the phosphor according to the present disclosure with comparative examples. 
         FIG.  29    shows a comparison of emission spectra of an exemplary embodiment with comparative examples and the sensitivity curve for melatonin production. 
         FIG.  30    shows the overlap of emission spectra of various phosphors and various blue-emitting LEDs with the sensitivity curve for melatonin production. 
         FIGS.  31 ,  120 ,  165    show color loci of various phosphors in the CIE standard diagram ( 1931 ). 
         FIGS.  32 ,  33 ,  34    show comparisons of the color purity at different dominant wavelengths of the primary radiation of an exemplary embodiment with comparative examples. 
         FIGS.  35 ,  36 ,  37 ,  166 ,  168    show simulated LED spectra at various excitation wavelengths. 
         FIG.  41    shows the reflection positions and the relative intensity of the reflections of the X-ray diffraction powder diffractogram of an exemplary embodiment of the phosphor according to the present disclosure. 
         FIGS.  42 ,  87 ,  101    show the thermal quenching behavior of an exemplary embodiment of the phosphor according to the present disclosure in comparison with the conventional phosphor. 
         FIG.  45    shows the coverage of the color space rec2020 by different combinations of green and red phosphor. 
         FIGS.  46  to  53    show graphical representations of the coverage of the color space rec2020 by different combinations of green and red phosphor. 
         FIGS.  54 A,  54 AA,  54 AB,  54 AC,  54 AD,  54 B,  54 BA,  54 BB,  54 BC,  54 BD   54 C,  54 CA,  54 CB,  54 CC, and  54 CD show the coverage of various standard color spaces and color loci of filtered spectra of different combinations of green and red phosphor. 
         FIGS.  55  to  58    show the spanned color spaces of filtered spectra with different combinations of green and red phosphor upon excitation with a primary radiation λdom=448 nm. 
         FIGS.  59  to  62    show the simulated emission spectra of conversion LEDs with different combinations of green and red phosphor. 
         FIGS.  106 ,  113 ,  119 ,  153 ,  155 ,  162    show optical properties of exemplary embodiments. 
         FIGS.  156  and  157    show the dependence of the peak wavelength on the cell volume of a unit cell. 
         FIGS.  169  and  170    show spanned color spaces of the filtered overall radiation of various conversion LEDs. 
     
    
    
     DETAILED DESCRIPTION 
     In the following description, numerous specific details are given to provide a thorough understanding of embodiments. The embodiments may be practiced without one or several specific details, or with other methods, components, materials, etc. In other instances, well-known structures, materials, or operations are not shown or described in detail to avoid obscuring aspects of the embodiments. 
     Reference throughout this specification to “one embodiment” or “an embodiment” means that a particular feature, structure, or characteristic described in connection with the embodiment is included in at least one embodiment. Thus, the appearances of the phrases “in one embodiment” or “in an embodiment” in various places throughout this specification are not necessarily all referring to the same embodiment. Furthermore, the particular features, structures, or characteristics may be combined in any suitable manner in one or more embodiments. 
       FIGS.  1 A,  1 B,  1 C,  1 D,  1 E and  1 F  show tables with possible electroneutral phosphors which are achievable by substitution experiments, analogously to the general molecular formula (MA) a (MB) b (MC) c (MD) d (TA) e (TB) f (TC) g (TD) h (TE) i (TF)(XA) k (XB) l (XC) m (XD) n . The substitutions shown are merely by way of example, other substitutions are likewise possible. The activator E is illustrated in each case only in the general formula and not in the concrete embodiments, but is nevertheless also present in the concrete embodiments. 
       FIG.  2    illustrates the emission spectrum of the first exemplary embodiment AB1 of the phosphor according to the present disclosure having the molecular formula NaLi 3 SiO 4 . The wavelength in nanometers is plotted on the x-axis and the emission intensity in percent is plotted on the y-axis. For measuring the emission spectrum, the phosphor according to the present disclosure was excited with primary radiation having a wavelength of 400 nm. The phosphor has a full width at half maximum of 32 nm or 1477 cm −1  and a dominant wavelength of 473 nm; the peak wavelength is approximately 469 nm. 
       FIG.  3    shows a normalized Kubelka-Munk function (K/S), plotted against the wavelength λ in nm, for the first exemplary embodiment (AB1) of the phosphor according to the present disclosure. In this case, K/S was calculated as follows:
 
K/S=(1−R inf ) 2 /2R inf ,
 
wherein R inf  corresponds to the diffuse reflection of the phosphor.
 
     It is evident from  FIG.  3    that the maximum of K/S for the first exemplary embodiment (AB1) of the phosphor according to the present disclosure is approximately 360 nm. High K/S values mean a high absorption in this range. The phosphor can be efficiently excited with a primary radiation starting from approximately 300 nm to 430 nm or 440 nm. 
       FIG.  4    shows a comparison of the full width at half maximum (FWHM), the peak wavelength (λ peak ), the dominant wavelength (λ dom ) and the luminous efficiency (LER) between a first comparative example (VB1: BaMgAl 10 O 17 :Eu), a second comparative example (VB2: Sr 5 (PO 4 ) 3 Cl:Eu), a third comparative example (VB3: BaMgAl 10 O 17 :Eu) and the first exemplary embodiment of the phosphor according to the present disclosure NaLi 3 SiO 4 :Eu (AB1). VB1 and VB3 differ in the concentration of Eu. All phosphors emit radiation in the blue range of the electromagnetic spectrum. The peak wavelength of the phosphor according to the present disclosure NaLi 3 SiO 4 :Eu is of somewhat longer wavelength in comparison with the comparative examples. As evident, the phosphor according to the present disclosure NaLi 3 SiO 4 :Eu has a significantly smaller full width at half maximum and/or a higher luminous efficiency (LER) than the comparison examples. The shift in the peak wavelength to a longer wavelength and the smaller full width at half maximum result in an increase in the overlap with the eye sensitivity curve. Consequently, the phosphor according to the present disclosure has a very high luminous efficiency that is higher in comparison with the comparative examples. 
       FIGS.  5  and  6    show the emission spectra of VB1, VB2, VB3 and AB1, as described in  FIG.  4   . In  FIG.  5   , the wavelength in nanometers is plotted on the x-axis and the emission intensity in percent is plotted on the y-axis. In  FIG.  6   , the wave number in cm −1  is plotted on the x-axis and the emission intensity in percent is plotted on the y-axis. The significantly smaller full width at half maximum of the phosphor according to the present disclosure NaLi 3 SiO 4 :Eu in comparison with VB1 and VB3 (BaMgAl 10 O 17 :Eu) becomes evident here. In contrast to AB1, moreover, BaMgAl 10 O 17 :Eu phosphors exhibit a low absorption starting from a wavelength of 350 nm (cf.  FIG.  7   ). Together with the relatively large full width at half maximum, that results in a relatively poor color purity of the phosphors VB1 and VB3. Although the known phosphor VB2 exhibits a small full width at half maximum, it has the disadvantage that it contains chlorine. Many applications are subject to strict conditions as far as the chlorine content is concerned, and so the application of this phosphor is limited if only for this reason. The risk of the release of corrosive HCl during its production is also disadvantageous, which increases the costs for the synthesis equipment and the maintenance measures thereof. 
       FIG.  7    shows a normalized Kubelka-Munk function (K/S), plotted against the wavelength λ in nm, for various phosphors VB1, VB2, VB3 and AB1, as defined in  FIG.  4   . The curve with the reference signs VB1, VB2 and VB3 represents K/S for known phosphors; the curve with the reference sign AB1 represents K/S for the first exemplary embodiment of the phosphor according to the present disclosure. It is evident that the phosphor according to the present disclosure AB1 has a higher absorption at longer wavelengths, in particular in the range starting from 360 nm, in comparison with the comparative examples VB1, VB2 and VB3. This is particularly advantageous since an efficient excitation of the phosphor according to the present disclosure with a primary radiation having a peak wavelength in the UV range to blue range of the electromagnetic spectrum, in particular in the range of between 300 nm and 460 nm, advantageously between 300 nm and 430 nm or 440 nm, is possible. Therefore, the phosphor according to the present disclosure is able to be employed particularly well in combination with semiconductor chips which have a primary radiation in the range of between 300 nm and 430 nm or 440 nm. 
       FIG.  8    shows the tetragonal crystal structure of the phosphor NaLi 3 SiO 4 :Eu in a schematic illustration. The hatched circles represent the Na atoms. The crystal structure corresponds to the crystal structure of NaLi 3 SiO 4 , as described in B. Nowitzki, R. Hoppe, Neues iber Oxide vom Typ A[(TO) n ]: NaLi 3 SiO 4 , NaLi 3 GeO 4 , NaLi 3 TiO 4 , [New findings concerning oxides of the type A[(TO) n ]: NaLi 3 SiO 4 , NaLi 3 GeO 4 , NaLi 3 TiO 4 ]  Revue de Chimie minérale,  1986, 23, 217-230. The crystal structure is isotypic with respect to that of CaLiAl 3 N 4 :Eu, described in P. Pust, A. S. Wochnik, E. Baumann, P. J. Schmidt, D. Wiechert, C. Scheu, W. Schnick, Ca[LiAl 3 N 4 ]:Eu 2+ —A Narrow-Band Red-Emitting Nitridolithoaluminate,  Chemistry of Materials  2014 26, 3544-3549. 
     Two X-ray diffraction powder diffractograms using copper K α1  radiation are indicated in  FIG.  9   . The diffraction angles in °2θ values are indicated on the x-axis, and the intensity is indicated on the y-axis. The X-ray diffraction powder diffractogram provided with the reference sign I shows that of the first exemplary embodiment AB1 of the phosphor according to the present disclosure NaLi 3 SiO 4 :Eu. The X-ray diffraction powder diffractogram provided with the reference sign II shows the X-ray diffraction powder diffractogram for NaLi 3 SiO 4  simulated from the crystal structure of NaLi 3 SiO 4  (B. Nowitzki, R. Hoppe, Neues iber Oxide vom Typ A[(TO) n ]: NaLi 3 SiO 4 , NaLi 3 GeO 4 , NaLi 3 TiO 4   , Revue de Chimie minérale,  1986, 23, 217-230). From the correspondence of the reflections it is evident that the phosphor according to the present disclosure NaLi 3 SiO 4 :Eu crystallizes in the same crystal structure as NaLi 3 SiO 4 . 
     A crystallographic evaluation is found in  FIG.  10   .  FIG.  10    shows a Rietveld refinement of the X-ray powder diffractogram of the first exemplary embodiment AB1, that is to say for NaLi 3 SiO 4 :Eu. For the Rietveld refinement, the atomic parameters for NaLi 3 SiO 4  (table 7 in B. Nowitzki, R. Hoppe,  Revue de Chimie minérale,  1986, 23, 217-230) were used to show that the crystal structure of NaLi 3 SiO 4 :Eu corresponds to that of NaLi 3 SiO 4 . The upper diagram here illustrates the superimposition of the measured reflections with the calculated reflections for NaLi 3 SiO 4 . The lower diagram illustrates the differences between the measured and calculated reflections. 
       FIG.  11    shows crystallographic data of NaLi 3 SiO 4 . 
       FIG.  12    shows atomic positions in the structure of NaLi 3 SiO 4 . 
       FIG.  13    illustrates the emission spectrum of the second exemplary embodiment AB2 of the phosphor according to the present disclosure having the molecular formula KLi 3 SiO 4 :Eu 2+ . The wavelength in nanometers is plotted on the x-axis and the emission intensity in percent is plotted on the y-axis. For measuring the emission spectrum, the phosphor according to the present disclosure was excited with primary radiation having a wavelength of 400 nm. The phosphor exhibits a broadband emission from approximately 430 nm to approximately 780 nm and thus emits white radiation or the emitted radiation produces a white luminous impression. The color locus of the phosphor is advantageously near that of the Planckian radiator at 2700 K. The color locus is at the following coordinates CIE-x=0.449 and CIE-y=0.397 in the CIE standard chromaticity diagram from 1931. The color temperature (CCT) is 2742 K, the luminous efficiency is 290 lm/W, the CRI (color rendering index) is 81, and the color rendering index R9 is 21. A conversion LED comprising the phosphor according to the present disclosure KLi 3 SiO 4 :Eu 2+  is thus suitable in particular for general lighting. 
       FIG.  14    shows a normalized Kubelka-Munk function (K/S), plotted against the wavelength λ in nm, for the second exemplary embodiment (AB2) of the phosphor according to the present disclosure. 
     It is evident from  FIG.  14    that the maximum of K/S for the second exemplary embodiment (AB2) of the phosphor according to the present disclosure is approximately 340 nm. The phosphor can be efficiently excited with a primary radiation starting from approximately 300 nm to 430 nm or 440 nm. 
       FIGS.  15  and  16    show simulated emission spectra of various conversion LEDs which emit white radiation. The primary radiation source used is an InGaN-based semiconductor layer sequence which emits a primary radiation having a peak wavelength of 410 nm ( FIG.  15   ) or having a peak wavelength of 390 nm ( FIG.  16   ). The construction of the conversion LEDs is shown in  FIG.  17   . As evident, the conversion LEDs according to the present disclosure (LED  1  and LED  2 ) using only one phosphor, the KLi 3 SiO 4 :Eu 2+  according to the present disclosure, exhibit similar emission spectra to the comparative examples VLED2 and VLED1 each comprising a green and a red phosphor. The phosphor according to the present disclosure thus advantageously makes it possible to provide a conversion LED which emits warm-white light having a color temperature of less than 3500 K, advantageously less than 3000 K, and for this purpose requires only one phosphor, unlike known white-emitting conversion LEDs that require at least one green and one red phosphor in combination with a blue primary radiation. 
       FIG.  17    compares various properties of conversion LEDs comprising the phosphor according to the present disclosure KLi 3 SiO 4 :Eu 2+  (LED1, LED2) and the comparative examples (VLED1 and VLED2). In this case, λ prim  stands for the wavelength of the primary radiation. The first and second phosphors are indicated in the third and fourth columns. CIE-x and CIE-y indicate the color coordinates x and y of the radiation in the CIE standard chromaticity diagram from 1931. CCT/K indicates the correlated color temperature of the overall radiation in kelvins. R9 stands for a color rendering index known to the person skilled in the art (saturated red). LER stands for the luminous efficiency (“luminous efficacy”) in lumens per watt. As evident, the conversion LEDs comprising the phosphor according to the present disclosure KLi 3 SiO 4 :Eu 2+  as sole phosphor have similar optical properties to conventional conversion LEDs based on two phosphors. In this case, however, the disadvantages arising from the use of two or more phosphors are eliminated. Firstly, the resulting spectrum is greatly dependent on the used ratio of the phosphors. As a result of batch fluctuations in phosphor production, frequent adaptations of the concentration of the phosphors are necessary as a result, which makes the production of the conversion LEDs very complicated. The phosphors additionally exhibit different emission properties depending on temperature, the radiance of the primary radiation and the excitation wavelength and additionally exhibit a different degradation behavior, that is to say a different stability with regard to temperature, radiation, moisture or gas influences. The production of phosphor mixtures may also be difficult if the phosphors differ greatly in their physical properties such as, for example, density, grain size and in the sedimentation behavior. With the use of two phosphors, all these effects lead to fluctuating color locus distributions and color shifts under changing operating conditions, for example current and/or temperature, in the products. In order conventionally to obtain a high color rendering index, advantageously with low color temperature, in particular less than 3500 K or less than 3000 K, red-emitting phosphors are required. However, all known red-emitting phosphors can only be synthesized by means of complex production methods and are therefore very much more expensive than known green and yellow phosphors. By contrast, the phosphor according to the present disclosure KLi 3 SiO 4 :Eu 2+  can be produced cost-effectively since the starting materials are commercially available, stable and moreover very inexpensive. Moreover, the synthesis does not require an inert gas atmosphere and therefore proves to be comparatively simple. 
     The use of the phosphor according to the present disclosure in a white-emitting conversion LED has numerous advantages. It is possible to use a primary radiation which is not perceived or is only scarcely perceived by the human eye (300 nm to 430 nm or 440 nm). Fluctuations of the primary radiations thus do not adversely affect the overall radiation properties. No color adaptation is required since the emission spectrum is constant. The conversion LEDs can be produced with a high throughput since color adaptation or complex chip binning is not required. No color shifts or other negative effects on the emission spectrum as a result of selective degradation of only one phosphor or changes in the primary radiation caused by temperature or forward current fluctuations occur. Furthermore, the conversion LED does not have an inherent color, but rather exhibits a white appearance in the switched-off state. Therefore, the phosphor is also suitable for “remote phosphor” arrangements in which a yellow or orange appearance in the switched-off state is not desired. A partial conversion of the primary radiation can also be carried out depending on the application. Since it is possible to excite the phosphor with a primary radiation in the range of 300 nm to 430 nm or 440 nm, a contribution of the primary radiation, advantageously in the short-wave blue range of the electromagnetic spectrum, to the overall radiation has the effect that objects illuminated thereby appear whiter, more radiant and therefore more attractive. By way of example, optical brightening agents in textiles can be excited thereby. 
       FIG.  18    shows a triclinic crystal structure of the phosphor KLi 3 SiO 4 :Eu in a schematic illustration. The hatched circles represent the K atoms. The crystal structure corresponds to the crystal structure of KLi 3 SiO 4 , as described in K. Werthmann, R. Hoppe, Über Oxide des neuen Formeltyps A[(T 4 O 4 )]: Zur Kenntnis von KLi 3 GeO 4 , KLi 3 SiO 4  und KLi 3 TiO 4  [Regarding oxides of the new formula type A[(T 4 O 4 )]: Zur Kenntnis von KLi 3 GeO 4 , KLi 3 SiO 4  and KLi 3 TiO 4 ],  Z. Anorg. Allg. Chem.,  1984, 509, 7-22. The crystal structure is isotypic with respect to that of SrLiAl 3 N 4 :Eu, described in P. Pust, V. Weiler, C. Hecht, A. Tücks, A. S. Wochnik, A.-K. Henß, D. Wiechert, C. Scheu, P. J. Schmidt, W. Schnick, Narrow-Band Red-Emitting Sr[LiAl 3 N 4 ]:Eu 2+  as a Next-Generation LED-Phosphor  Material Nat. Mater.  2014 13, 891-896. 
     Two X-ray diffraction powder diffractograms using copper K α1  radiation are indicated in  FIG.  19   . The diffraction angles in °2θ values are indicated on the x-axis and the intensity is indicated on the y-axis. The X-ray diffraction powder diffractogram provided with the reference sign III shows that of the second exemplary embodiment of the phosphor according to the present disclosure KLi 3 SiO 4 :Eu. The X-ray diffraction powder diffractogram provided with the reference sign IV shows the X-ray diffraction powder diffractogram for KLi 3 SiO 4  simulated from the crystal structure of KLi 3 SiO 4 . From the correspondence of the reflections it is evident that the phosphor according to the present disclosure KLi 3 SiO 4 :Eu crystallizes in the same crystal structure as KLi 3 SiO 4 . 
     A crystallographic evaluation is found in  FIG.  20   .  FIG.  20    shows a Rietveld refinement of the X-ray powder diffractogram of the second exemplary embodiment AB2, that is to say KLi 3 SiO 4 :Eu. For the Rietveld refinement, the atomic parameters for KLi 3 SiO 4  (K. Werthmann, R. Hoppe, Über Oxide des neuen Formeltyps A[(T4O4)]: Zur Kenntnis von KLi3GeO4, KLi3SiO4 und KLi3TiO4, Z. Anorg. Allg. Chem., 1984, 509, 7-22) are used to show that the crystal structure of KLi 3 SiO 4 :Eu corresponds to that of KLi 3 SiO 4 . In this case, the upper diagram illustrates the superimposition of the measured reflections with the calculated reflections for KLi 3 SiO 4 . The lower diagram illustrates the differences between the measured and calculated reflections. A peak of an unknown secondary phase has been marked with an asterisk. 
       FIG.  21    shows crystallographic data of KLi 3 SiO 4 . 
       FIG.  22    shows atomic positions in the structure of KLi 3 SiO 4 . 
       FIG.  23    illustrates the emission spectrum of the third exemplary embodiment AB3 of the phosphor according to the present disclosure having the molecular formula (Na 0.5 K 0.5 )Li 3 SiO 4 :Eu 2+ . The wavelength in nanometers is plotted on the x-axis and the emission intensity in percent is plotted on the y-axis. For measuring the emission spectrum, the phosphor according to the present disclosure was excited with primary radiation having a wavelength of 400 nm. The phosphor has a full width at half maximum of less than 20 nm and a peak wavelength of 486 nm. With this small full width at half maximum, this phosphor belongs to the most narrowband Eu 2+ -doped phosphors known. The peak wavelength is in the blue-green spectral range of the electromagnetic spectrum, which spectral range can also be referred to as cyan-colored. Only a small number of phosphors having a peak wavelength in this range have been known hitherto and none of these phosphors has such a small full width at half maximum. With a peak wavelength of 486 nm and the small full width at half maximum, the phosphor has a good overlap with the eye sensitivity curve. The conversion of the UV or blue primary radiation into a secondary radiation having a somewhat longer wavelength in the blue range of the electromagnetic spectrum (peak wavelength of 486 nm), increases the efficiency of the conversion LED. The peak wavelength of the secondary radiation is closer to the eye sensitivity maximum at 555 nm in comparison with the primary radiation, whereby the emitted radiation has a higher overlap with the eye sensitivity curve and is thus perceived as brighter. Similar optical properties are also obtained with AB9, AB14, AB15 and AB16. 
       FIG.  24    shows a normalized Kubelka-Munk function (K/S), plotted against the wavelength λ in nm, for the third exemplary embodiment (AB3) of the phosphor according to the present disclosure. 
     It is evident from  FIG.  24    that the maximum of K/S for the third exemplary embodiment (AB3) of the phosphor according to the present disclosure is between 350 nm and 420 nm. Up to 500 nm, K/S is significantly above the value zero. The phosphor (Na 0.5 K 0.5 )Li 3 SiO 4 :Eu 2+  can be efficiently excited with a primary radiation starting from approximately 340 nm. 
       FIG.  25    shows the tetragonal crystal structure of the phosphor (Na 0.5 K 0.5 )Li 3 SiO 4 :Eu 2+  in a schematic illustration. The hatched circles represent the Na atoms; the circles enclosing white areas represent the K atoms. The crystal structure was determined from X-ray powder diffractogram data. The crystal structure of CsKNa 2 Li 12 Si 4 O 16  with Cs being substituted by K was used as the starting point. 
     A crystallographic evaluation is found in  FIG.  26   .  FIG.  26    shows a Rietveld refinement of the X-ray powder diffractogram of the third exemplary embodiment AB3, that is to say (Na 0.5 K 0.5 )Li 3 SiO 4 :Eu 2+ . The parameters and atomic coordinates of all non-Li atoms were freely refined. In this case, the upper diagram illustrates the superimposition of the measured reflections with the calculated reflections for CsKNa 2 Li 12 Si 4 O 16 . The lower diagram illustrates the differences between the measured and calculated reflections. The phosphor (Na 0.5 K 0.5 )Li 3 SiO 4 :Eu 2+  is structurally isotypic with respect to the compounds CsKNa 2 Li 8 {Li[SiO 4 ]} 4 , RbNa 3 Li 8 {Li[SiO 4 ]} 4 , CsNa 3 Li 8 {Li[GeO 4 ]} 4  and RbNa 3 Li 8 {Li[TiO 4 ]} 4 . The structure is also similar to that of the first exemplary embodiment NaLi 3 SiO 4 :Eu and the second exemplary embodiment KLi 3 SiO 4 :Eu of the phosphor according to the present disclosure, but has a complicated arrangement of the alkali metals. 
       FIG.  27    shows crystallographic data of (Na 0.5 K 0.5 )Li 3 SiO 4 . 
       FIG.  28    shows atomic positions in the structure of (Na 0.5 K 0.5 )Li 3 SiO 4 . 
       FIG.  29    shows the emission spectra of the third exemplary embodiment of the phosphor according to the present disclosure AB3 and three comparative examples C1S, OS and G, wherein C1S stands for Ca 8 Mg(SiO 4 ) 4 Cl 2 :Eu, OS stands for (Sr,Ba) 2 SiO 4 :Eu and G stands for Lu 3 (Al,Ga) 5 O 12 :Ce. All the phosphors emit in the blue to blue-green range of the electromagnetic spectrum. AB3, as evident, has the smallest full width at half maximum and the peak wavelength is shifted to shorter wavelengths in comparison with the comparative examples. Therefore, the phosphor according to the present disclosure is suitable for example for an application in signal lights such as blue lights of, for example, police vehicles, ambulances, emergency doctor vehicles or fire department vehicles, the dominant wavelength of which is advantageously in a range of between 465 nm and 480 nm. The use of the comparative examples is less well suited thereto since the peak wavelengths thereof are above 510 nm, whereas the phosphor according to the present disclosure has a peak wavelength of 486 nm. On account of similar optical properties, AB9, AB14, AB15 and AB16 are also suitable for an application in signal lights. 
     The curve designated by smel shows the sensitivity curve for melatonin production, that is to say with what wavelengths melatonin production in the body can best be suppressed (“human response function for melanopic effects”; Lucas et al., Trends in Neurosciences January 2014 Vol. 37 No. 1). As evident, the emission spectrum of AB3 exhibits a high overlap with smel, and so this radiation can be effectively used for suppressing the formation of melatonin. Such irradiation can lead to an increased vigilance or ability to concentrate. 
       FIG.  30    shows the overlap of emission spectra of various phosphors (AB3, CIS, OS and G, as described under  FIG.  29   ) and various blue-emitting LEDs (unconverted) with the sensitivity curve for melatonin production. The LEDs are light-emitting diodes having InGaN-based semiconductor chips. The LEDs Ipeak430 nm (peak wavelength of 430 nm) and Ipeak435 nm (peak wavelength of 435 nm) are not usually commercially available in large numbers, but are very efficient. The LEDs Ipeak440 nm (peak wavelength of 440 nm), Ipeak445 nm (peak wavelength of 445 nm), Ipeak450 nm (peak wavelength of 450 nm) and Ipeak455 nm (peak wavelength of 455 nm) are commercially available, inexpensive and efficient. The LEDs Ipeak460 nm (peak wavelength of 460 nm), Ipeak465 nm (peak wavelength of 465 nm) and Ipeak470 nm (peak wavelength of 470 nm) have only low efficiency and are not usually commercially available. InGaN-based semiconductor chips can in principle emit a radiation having a peak wavelength of up to 500 nm, although the efficiency decreases as the wavelength increases, for which reason they are produced in large numbers usually only up to a peak wavelength of up to approximately 460 nm. As a result, the areas of application for InGaN-based semiconductor chips in light-emitting diodes (without phosphor) are limited. As evident, the emission of the phosphor according to the present disclosure AB3 exhibits a greater overlap with the sensitivity curve for melatonin production than the phosphors C1S, OS and G and also than the InGaN-based LEDs. Melatonin production can thus be efficiently suppressed with the phosphor according to the present disclosure. On account of similar optical properties, AB9, AB14, AB15 and AB16 are also suitable for suppressing melatonin production. 
       FIG.  31    shows the CIE standard diagram ( 1931 ), wherein the CIE-x portion of the primary color red is plotted on the x-axis and the CIE-y portion of the primary color green is plotted on the y-axis. The color loci of various phosphors (AB3, C1S, OS and G, as described under  FIG.  29   ) are depicted in the CIE standard diagram. The black quadrilaterals represent color loci of various blue and blue-green InGaN semiconductor chips having peak wavelengths of between 430 nm and 492 nm and dominant wavelengths of between 436 nm and 493 nm. The black dot marks the white point Ew having the coordinates CIE-x=1/3 and CIE-y=1/3. The black lines linking the color loci of a blue indium gallium nitride semiconductor chip (λpeak=445 nm; λdom=449 nm) with the color loci of the phosphors represent the conversion lines of conversion LEDs that are constructed from the indium gallium nitride semiconductor chip and corresponding phosphors. The area identified by EVL shows the typical blue color space for products for application in the field of signal lights for police vehicles, for example. The open circles mark color loci having 100% color purity for selected dominant wavelengths at 468 nm, 476 nm and 487 nm. The dashed line represents color loci having dominant wavelengths at 487 nm with varying color purity. Color loci on this dashed line which lie nearer to the open circle 487 exhibit higher color purities than color loci that lie nearer to the white point E. The advantageous effects of the new phosphor AB3 become clear from this figure: the conversion line (KL) of a typical blue LED to the color locus of the phosphor according to the present disclosure AB3 intersects the EVL color space in the center, whereas the conversion lines of the same blue LED comprising the phosphors OS, C1S and G exhibit only a small overlap with the EVL color space. It is thus advantageously possible to obtain a plurality of color spaces within the EVL color space by using the phosphor AB3 by comparison with the conventional phosphors. Moreover, the conversion line K intersects the dashed line for the dominant wavelength 487 nm at the point I1, which has a higher color purity in comparison with the intersection points of the conversion lines of the known phosphors. The same improvement in the color purity using the phosphor according to the present disclosure AB3 is also manifested for other target dominant wavelengths, in particular within the EVL color space. The corresponding lines are not shown, for the sake of clarity. A high color purity results in a more saturated color impression. The phosphor according to the present disclosure thus makes it possible to obtain additional color loci which have not been able to be achieved hitherto. The phosphor according to the present disclosure (Na 0.5 K 0.5 )Li 3 SiO 4 :Eu 2+  is therefore particularly suitable for conversion LEDs which emit a blue radiation with high color saturation. These conversion LEDs are suitable for use in blue lights or else for “color on demand” applications. On account of similar optical properties, AB9, AB14, AB15 and AB16 are also suitable for conversion LEDs which emit a blue radiation with high color saturation. 
       FIGS.  32 ,  33  and  34    show a comparison of the achievable color purities of different conversion LEDs at various target dominant wavelengths and wavelengths of the primary radiation. In order to carry out the simulation experiments, a blue semiconductor chip was combined with the different phosphors AB3, C1S, OS and G. Semiconductor chips based on InGaN and having a high efficiency were used in this case. The content of phosphor was varied for each experiment in order to attain the target dominant wavelength; the color purity was subsequently determined from the resulting spectra. The results show that for all chosen target dominant wavelengths and all chosen wavelengths of the primary radiation, the conversion LEDs comprising the phosphor AB3 and also comprising AB9, AB14, AB15 and AB16 (not shown) exhibit a significantly higher color purity than the comparative examples. 
       FIGS.  35 ,  36  and  37    shows the simulated emission spectra of the conversion LEDs corresponding to  FIGS.  32 ,  33  and  34   . In this case,  FIG.  35    shows the emission spectra of a conversion LED having a primary radiation of 430 nm and of a conversion LED having a primary radiation of 455 nm in each case comprising the phosphor AB3 at a target dominant wavelength of 468 nm.  FIG.  36    shows the emission spectra of a conversion LED having a primary radiation of 430 nm and of a conversion LED having a primary radiation of 455 nm in each case comprising the phosphor AB3 at a target dominant wavelength of 487 nm.  FIG.  37    shows the emission spectra of a conversion LED having a primary radiation of 430 nm and of a conversion LED having a primary radiation of 455 nm in each case comprising the phosphor AB3 at a target dominant wavelength of 476 nm. 
       FIG.  38    illustrates the emission spectrum of the fourth exemplary embodiment AB4 of the phosphor according to the present disclosure having the molecular formula (Na 0.25 K 0.75 )Li 3 SiO 4 :Eu 2+.  The wavelength in nm is plotted on the x-axis and the emission intensity in % is plotted on the y-axis. For measuring the emission spectrum, the phosphor according to the present disclosure was excited with a primary radiation having a wavelength of 400 nm. The phosphor has a full width at half maximum of less than 50 nm, a peak wavelength of 529 nm, a dominant wavelength of 541 nm and a color locus in the CIE color space having the coordinates CIE-x: 0.255 and CIE-y: 0.680. The narrow full width at half maximum of the phosphor leads to a saturated green emission of the phosphor. 
       FIG.  39    shows a normalized Kubelka-Munk function (K/S), plotted against the wavelength λ in nm, for the fourth exemplary embodiment (AB4) of the phosphor according to the present disclosure. The phosphor according to the present disclosure can be efficiently excited with a primary radiation in the range of between 330 nm and 500 nm, advantageously 340 nm to 460 nm, particularly advantageously 350 nm to 450 nm. As a result, the phosphor is suitable in particular for backlighting applications, using a semiconductor chip with a primary radiation in the near UV range or blue range of the electromagnetic spectrum. 
       FIG.  40    shows the X-ray powder diffractogram of the fourth exemplary embodiment AB4. The intensity is indicated on the y-axis and the °2θ values are indicated on the x-axis. The reflection positions and the relative intensity in % of the reflection positions of the X-ray powder diffractogram are indicated in  FIG.  41   . 
     In  FIG.  42   , the emission intensity in % is plotted against the temperature in ° C. As evident, the exemplary embodiment AB4 of the phosphor according to the present disclosure exhibits a high thermal stability.  FIG.  42    shows the thermal quenching behavior of the phosphor according to the present disclosure AB4 in comparison with a conventional phosphor OS2, a green orthosilicate of the formula (Sr,Ba) 2 SiO 4 :Eu. The phosphors were excited with a blue primary radiation having a wavelength of 460 nm at various temperatures from 25 to 225° C. and their emission intensity was recorded in the process. It is clearly evident that the phosphor AB4 according to the present disclosure has a significantly smaller loss of emission intensity at typical temperatures that prevail in a conversion LED, in particular temperatures above 140° C. The phosphor can thus advantageously be used even at higher operating temperatures in conversion LEDs. 
       FIG.  43    shows various optical properties of the fourth exemplary embodiment of the phosphor according to the present disclosure AB4 in comparison with conventional phosphors G2 and OS2. In this case, OS2 stands for a phosphor of the formula (Sr,Ba) 2 SiO 4 :Eu and G2 stands for a phosphor of the formula Lu 3 (Al,Ga) 5 O 12 :Ce. All three phosphors exhibit a similar dominant wavelength. In this case, however, the phosphor AB4 according to the present disclosure exhibits a significantly higher luminous efficiency (LER) and a significantly higher color purity. This leads to an improved color saturation, as a result of which it is possible to achieve a higher color space coverage, and to an improved overall efficiency. The reason for the improved properties is the small full width at half maximum of the fourth exemplary embodiment AB4 having the formula (Na 0.25 K 0.75 )Li 3 SiO 4 :Eu 2+  of the phosphor according to the present disclosure in comparison with the conventional phosphors. On account of a similar position of the peak wavelengths and values of the full width at half maximum, the exemplary embodiments AB5, AB7, AB13 and AB8 likewise exhibit improved properties. The high luminous efficiency increases the efficiency of green conversion LEDs having partial or full conversion in comparison with green conversion LEDs comprising known green phosphors having a comparable dominant and/or peak wavelength. 
       FIG.  44    shows a comparison of the emission spectra of the fourth exemplary embodiment AB4 of the phosphor according to the present disclosure in comparison with the conventional phosphors G2 and OS2 described under  FIG.  43   . 
       FIG.  45    shows the coverage of the color space rec2020 (xy) in the CIE color space system and rec2020 (u′v′) in the CIE LUV color space system ( 1976 ) by different combinations of a green phosphor and a red phosphor in conjunction with a blue primary radiation of varying dominant wavelength. In this case AB4 stands for the fourth exemplary embodiment (Na 0.25 K 0.75 )Li 3 SiO 4 :Eu 2+  of the phosphor according to the present disclosure and AB5 stands for the fifth exemplary embodiment (Rb 0.5 Li 0.5 )Li 3 SiO 4  of the phosphor according to the present disclosure, and BS stands for a conventional green-emitting beta-SiAlON:Eu phosphor. The proportions of blue, green and red radiation were adapted such that the white color locus for typical backlighting applications (CIE-x=0.278 and CIE-y=0.255) was obtained. Typical color filter curves were applied to the resulting spectrum and the resulting color loci for blue, green and red were calculated. The overlap of the resulting color space with the standard color spaces was then calculated and compared. In all cases it is evident that the spectra obtained with the exemplary embodiments AB4 and AB5 of the phosphor according to the present disclosure result in a greater coverage of the respective color space. Like AB4 and AB5, AB7, AB13 and AB8 also have a high coverage of the respective color space on account of the similar peak wavelength and full width at half maximum ( FIGS.  76 ,  129 ,  86   ) in combination with the red phosphors indicated in  FIG.  45   . A greater bandwidth of colors can thus be rendered with the phosphors according to the present disclosure. Thus, by way of example, a display device, such as a display, having a conversion LED comprising the phosphor according to the present disclosure can render a significantly increased number of colors by comparison with what has been possible hitherto with conventional phosphors. 
       FIGS.  46  to  53    show a graphical representation of the results of the color space coverage as described in  FIG.  45    for a dominant wavelength of the primary radiation at 448 nm. The second red phosphor used, together with its molecular formula, is indicated in each of the diagrams. 
       FIGS.  54 A,  54 B and  54 C  show a more comprehensive list of the data from  FIG.  45   , which additionally show the color loci of the filtered spectra and coverages with other standard color spaces. 
       FIGS.  55  to  58    show the spanned color spaces of various examples of the combinations illustrated in  FIG.  45    with a wavelength of the primary radiation λdom=448 nm. Each figure shows a comparison of three different green phosphors (AB4, AB5 or BS) in each case combined with a red phosphor, which is indicated with its molecular formula in the figures. The color spaces spanned by the filtered spectra with the exemplary embodiments according to the present disclosure AB4 and AB5 are almost congruent. It is evident that a greater bandwidth of colors can be rendered with the exemplary embodiments AB4 and AB5 of the phosphor according to the present disclosure, primarily in the green and red corners of the spanned color triangle (marked by arrows). A similar behavior is also obtained with the exemplary embodiments AB7, AB13 and AB8 (not illustrated). This is assigned to the very narrowband emission of the phosphors according to the present disclosure AB4 and AB5, AB7, AB13 and AB8. The bandwidth of green colors is thus increased by the use of the phosphors according to the present disclosure AB4, AB5, AB7, AB13 and AB8 in comparison with conventional phosphors. The narrow full width at half maximum of the phosphors according to the present disclosure additionally reduces the radiation loss that arises as a result of the filtering. In comparison with the known phosphor β-SiAlON (BS), the phosphors according to the present disclosure can be produced on the basis of inexpensive starting materials and moreover the synthesis is carried out at moderate temperatures. This keeps the production costs low, which makes the phosphors also economically highly attractive for the production of mass-produced products such as LCD televisions, computer monitors or displays for smartphones or tablets. 
       FIGS.  59  to  62    show the corresponding conversion LED spectra of the examples of  FIGS.  55  to  58   . The red phosphor is indicated together with its molecular formula in the figures. 
       FIG.  63    illustrates the emission spectrum of the fifth exemplary embodiment AB5 of the phosphor according to the present disclosure having the molecular formula (Rb 0.5 Li 0.5 )Li 3 SiO 4 . The wavelength in nm is plotted on the x-axis and the emission intensity in % is plotted on the y-axis. For measuring the emission spectrum, the phosphor according to the present disclosure was excited with light having a wavelength of 400 nm. 
     The phosphor has a full width at half maximum of 43 nm and a peak wavelength of 528 mm and a dominant wavelength of 539 nm. The coordinates CIE-x and CIE-y are at 0.238 and 0.694. The phosphor thus proves to be very suitable for backlighting applications that have to have a saturated green hue. 
       FIG.  64    shows a standardized Kubelka-Munk function (K/S), plotted against the wavelength λ in nm, for the fifth exemplary embodiment of the phosphor according to the present disclosure. The maximum of K/S for the fifth exemplary embodiment of the phosphor according to the present disclosure is approximately 400 nm, although the range of high absorption extends into the blue-green spectral range up to approximately 500 nm. Therefore, the phosphor can be efficiently excited with a primary radiation having a wavelength of between 330 and 500 nm, advantageously 340 and 460 nm, particularly advantageously 350 to 450 nm. 
       FIG.  65    shows the X-ray powder diffractogram of the fifth exemplary embodiment AB5 of the phosphor according to the present disclosure with the reference sign V. The X-ray powder diffractogram provided with the reference sign VI shows a simulated diffractogram of the compound RbLi(Li 3 SiO 4 ) 2  (K. Bernet, R. Hoppe, Ein “Lithosilicat” mit Kolumnareinheiten: RbLi 5 {Li[SiO 4 ]} 2  [A “lithosilicate” having columnar units: RbLi 5 {Li[SiO 4 ]} 2 ],  Z. Anorg. Allg. Chem.,  1991, 592, 93-105). Peaks in the X-ray powder diffractogram V which can be assigned to the secondary phase Li 4 SiO 4  are identified by asterisks. 
       FIG.  66    shows various optical properties of the fifth exemplary embodiment of the phosphor according to the present disclosure AB5 in comparison with conventional phosphors G1 and OS1. In this case, OS1 stands for a phosphor of the formula (Sr,Ba) 2 SiO 4 :Eu and G1 stands for a phosphor of the formula Lu 3 (Al,Ga) 5 O 12 :Ce. In comparison with the phosphors G2 and OS2, the phosphors G1 and OS1 have a different Eu and Ce content, respectively, in order in each case to obtain the same dominant wavelength as the exemplary embodiment AB5. All three phosphors exhibit a similar dominant wavelength. In this case, however, the phosphor according to the present disclosure AB5 exhibits a significantly higher luminous efficiency (LER) and a significantly higher color purity. This leads to an improved color saturation, whereby a higher color space coverage can be achieved, and to an improved overall efficiency. The reason for the improved properties is the full width at half maximum of the fourth exemplary embodiment AB5 having the formula (Rb 0.5 Li 0.5 )Li 3 SiO 4  of the phosphor according to the present disclosure in comparison with the conventional phosphors. The high luminous efficiency increases the efficiency of green conversion LEDs having partial or full conversion in comparison with green conversion LEDs comprising known green phosphors having a comparable peak wavelength. 
       FIG.  67    shows a comparison of the emission spectra of the fifth exemplary embodiment AB5 of the phosphor according to the present disclosure in comparison with the conventional phosphors G1 and OS1 described under  FIG.  66   . 
       FIG.  68    illustrates the emission spectrum of the first exemplary embodiment AB1 having the molecular formula NaLi 3 SiO 4 :Eu and of the sixth exemplary embodiment AB6 having the molecular formula Na 0.97 Ca 0.03 Li 2.94 Al 0.09 Si 0.97 O 3.88 N 0.12 :Eu. The wavelength in nanometers is plotted on the x-axis and the emission intensity in percent is plotted on the y-axis. For measuring the emission spectrum, the phosphors according to the present disclosure were excited with primary radiation having a wavelength of 400 nm (AB1) and 460 nm (AB6). The phosphor AB1 has a full width at half maximum of 32 nm or 1477 cm −1  and a dominant wavelength of 473 nm; the peak wavelength is approximately 469 nm. The phosphor AB6 has a full width at half maximum of 72.8 nm, a dominant wavelength of 548 nm; the peak wavelength is approximately 516.9 nm. The color locus of AB6 is at the following coordinates CIE-x=0.301 and CIE-y=0.282 in the CIE standard chromaticity diagram from 1931. The luminous efficiency of AB6 is 432.8 lm/W. The different properties of AB1 and AB6, in particular the peak wavelength of Na 0.97 Ca 0.03 Li 2.94 Al 0.09 Si 0.97 O 3.88 N 0.12 :Eu shifted into the longer-wavelength range in comparison with NaLi 3 SiO 4 :Eu, are due to a greater nephelauxetic effect of the nitrogen atoms surrounding the activator ions, here the Eu 2+  ions, in the mixed phase Na 0.97 Ca 0.03 Li 2.94 Al 0.09 Si 0.97 O 3.88 N 0.12 :Eu. The higher the proportion of nitrogen in the vicinity of the activator ions, the longer the peak wavelength. As a result, with an increasing nitrogen content and thus with a rising value for y* in the phosphor Na 1−y* Ca y* Li 3−2y* A 3y* Si 1−y O 4−4y* N 4y* :Eu, the peak wavelength can be shifted within the visible range of the electromagnetic spectrum, in particular in a range of between 470 nm and 670 nm. The phosphor is thus suitable in particular for lighting devices or conversion LEDs in which phosphors having very specific properties are required (so-called “color on demand” applications). 
       FIG.  69    shows the emission spectra of AB6 (excitation wavelength 460 nm) and four garnet phosphors as comparative examples (excitation wavelength in each case 460 nm; 440 nm in the case of Y 3 Al 3 Ga 2 O 12 :Ce). In comparison with the known garnet phosphors Y 3 Al 5 O 12 :Ce, Y 3 Al 3 Ga 2 O 12 :Ce and Lu 3 Al 5 O 12 :Ce, the exemplary embodiment according to the present disclosure AB6 has a peak wavelength shifted to shorter wavelengths and a smaller full width at half maximum. A similar peak wavelength to AB6 is exhibited by Lu 3 Al 3 Ga 2 O 12 :Ce. In comparison with the garnet phosphors Y 3 Al 5 O 12 :Ce, Y 3 Al 3 Ga 2 O 12 :Ce and Lu 3 Al 5 O 12 :Ce, the peak wavelength of AB6 and Lu 3 Al 3 Ga 2 O 12 :Ce lies nearer to the blue spectral range, in which in conventional conversion LEDs a spectral gap may disadvantageously be found, in which no or only very little light is emitted. Said spectral gap results in poor color rendering. Therefore, Lu 3 Al 3 Ga 2 O 12 :Ce is often used to reduce the spectral gap. In comparison with Lu 3 Al 3 Ga 2 O 12 :Ce, however, the sixth exemplary embodiment Na 0.97 Ca 0.03 Li 2.94 Al 0.09 Si 0.97 O 3.88 N 0.12 :Eu has a significantly smaller full width at half maximum and, owing to the smaller full width at half maximum, a greater color purity. An additional factor is that the exemplary embodiment according to the present disclosure AB6 has a higher overlap with the eye sensitivity curve, thus resulting in a higher luminous efficiency. A comparison of the optical data is shown in  FIG.  70   . The percentages indicated between parentheses reflect the changes in the values in comparison with Lu 3 Al 3 Ga 2 O 12 :Ce. The conversion of the UV or blue primary radiation into a secondary radiation having a wavelength in the green range of the electromagnetic spectrum (peak wavelength of 516.9 nm) increases the efficiency of a conversion LED. In comparison with the primary radiation, the peak wavelength of the secondary radiation is nearer to the eye sensitivity maximum at 555 nm, as a result of which the emitted radiation has a higher overlap with the eye sensitivity curve and is thus perceived as brighter. Conversion LEDs comprising the phosphor in particular in combination with a green and red phosphor are suitable in particular for white conversion LEDs, for example for general lighting. In particular, a white overall radiation having a high color temperature can be generated. 
       FIG.  71    shows the tetragonal crystal structure of the phosphor Na 0.97 Ca 0.03 Li 2.94 Al 0.09 Si 0.97 O 3.88 N 0.12 :Eu in a schematic illustration along the crystallographic c-axis. The structure was determined by X-ray analysis of a single crystal of the phosphor. The hatched circles represent the mixed occupied positions for the Na and Ca atoms. The hatched regions represent the mixed occupied Li/Si/Al-O/N tetrahedra. The crystal structure corresponds to the crystal structure of NaLi 3 SiO 4 :Eu (see  FIG.  8   ). The crystal structure is isotypic with respect to that of CaLiAl 3 N 4 :Eu, described in P. Pust, A. S. Wochnik, E. Baumann, P. J. Schmidt, D. Wiechert, C. Scheu, W. Schnick, Ca[LiAl 3 N 4 ]:Eu 2+ —A Narrow-Band Red-Emitting Nitridolithoaluminate,  Chemistry of Materials  2014 26, 3544-3549. 
       FIG.  72    shows crystallographic data of Na 0.97 Ca 0.03 Li 2.94 Al 0.09 Si 0.97 O 3.88 N 0.12 :Eu. 
       FIG.  73    shows atomic positions in the structure of Na 0.97 Ca 0.03 Li 2.94 Al 0.09 Si 0.97 O 3.88 N 0.12 :Eu. 
       FIG.  74    illustrates the emission spectrum of the seventh exemplary embodiment AB7 of the phosphor according to the present disclosure having the molecular formula (Na 0.25 K 0.5 Li 0.25 )Li 3 SiO 4 :Eu 2+ . For measuring the emission spectrum, a single crystal of the phosphor according to the present disclosure was excited with a primary radiation having a wavelength of 460 nm. The phosphor has a full width at half maximum of less than 50 nm, a peak wavelength of 532 nm, a dominant wavelength of 540.3 nm and a color locus in the CIE color space having the coordinates CIE-x: 0.235 and CIE-y: 0.640. The narrow full width at half maximum of the phosphor leads to a saturated green emission of the phosphor. The phosphor (K 1−r″−r′″ Na r″ Li r′″ ) 1 (TA) 3 (TD) 1 (XB) 4 :E or (K 1−r″−r′″ Na r″ Li r′″ ) where 0&lt;r″&lt;0.5 and 0&lt;r″&lt;0.5, in particular (Na 0.25 K 0.5 Li 0.25 )Li 3 SiO 4 :Eu 2+,  is therefore particularly attractive for its use in a conversion LED in which a narrowband emission in the green spectral range is required, such as for the backlighting of LCD displays. 
       FIG.  75    shows the emission spectra of AB7 and a β-SiAlON:Eu (BS) as comparative example. The phosphors have comparable peak and dominant wavelengths and color purities, although AB7 exhibits a smaller full width at half maximum and, associated therewith, a greater luminous efficiency and higher color purity. This leads to an improved color saturation, as a result of which it is possible to achieve a higher color space coverage, and to an improved overall efficiency. The reason for the improved properties is the small full width at half maximum of the seventh exemplary embodiment AB7 having the formula (Na 0.25 K 0.50 Li 0.25 )Li 3 SiO 4 :Eu 2+  of the phosphor according to the present disclosure in comparison with the known phosphor BS. The high luminous efficiency increases the efficiency of green conversion LEDs having partial or full conversion in comparison with green conversion LEDs comprising known green phosphors having a comparable dominant and/or peak wavelength. The optical data of the phosphors AB7 and BS are shown in  FIG.  76   . The phosphor K 1−r″−r′″ Na r″ Li r′″ ) 1 (TA) 3 (TD) 1 (XB) 4 :E or (K 1−r″−r′″ Na r″ Li r′″ ) 1 Li 3 SiO 4 :E where 0&lt;r″&lt;0.5 and 0&lt;r′″&lt;0.5, in particular (Na 0.25 K 0.5 Li 0.25 )Li 3 SiO 4 :Eu 2+ , thus proves to be very suitable for applications in which a saturated green hue is desired, as in backlighting applications. 
       FIG.  77    shows the monoclinic crystal structure of the phosphor (Na 0.25 K 0.50 Li 0.25 )Li 3 SiO 4 :Eu 2+  in a schematic illustration along the crystallographic b-axis. The black circles represent Na atoms, the hatched circles represent K atoms and the circles enclosing white areas represent the Li atoms. The phosphor AB7 crystallizes in the same space group, C2/m, as the fifth exemplary embodiment (Rb 0.5 Li 0.5 )Li 3 SiO 4 :Eu 2+  with comparable lattice parameters. The crystal structures of the phosphors (Na 0.25 K 0.50 Li 0.25 )Li 3 SiO 4 :Eu and (Rb 0.5 Li 0.5 )Li 3 SiO 4 :Eu 2+  have identical (Li 3 SiO 4 ) structural units. The occupation of the channels within these structural units is different in this case, however. (Rb 0.5 Li 0.5 )Li 3 SiO 4 :Eu 2+  contains two types of channels, wherein one channel is occupied only by Rb and the other is occupied only by Li, while (Na 0.25 K 0.50 Li 0.25 )Li 3 SiO 4 :Eu also contains two types of channels, wherein one channel is occupied only by K and the other channel is occupied only by Li and Na. The arrangement of Na and K in (Na 0.25 K 0.50 Li 0.25 )Li 3 SiO 4 :Eu is similar to the arrangement in CsKNaLi(Li 3 SiO 4 ) 4 , as described in K. Bernet, R. Hoppe, Z. Anorg. Chem., 1991, 592, 93-105. The exact arrangement of Na and Li within a channel cannot be ascertained by means of X-ray diffraction. A statistical arrangement is taken as a basis in the present case. The crystal structure of AB7 is a crystal structure derived from the UCr 4 C 4  structure type with a higher degree of ordering. 
       FIG.  78    shows the arrangement of Li, Na and K within the channels of the (Li 3 SiO 4 ) structural units for (Na 0.25 K 0.50 Li 0.25 )Li 3 SiO 4 :Eu. The black circles represent Na atoms, the hatched circles represent K atoms and the circles enclosing white areas represent the Li atoms. The arrangement is shown along the crystallographic c-axis. 
       FIG.  79    shows crystallographic data of (Na 0.25 K 0.50 Li 0.25 )Li 3 SiO 4 :Eu. 
       FIG.  80    shows atomic positions in the structure of (Na 0.25 K 0.50 Li 0.25 )Li 3 SiO 4 :Eu. 
       FIG.  81    shows anisotropic displacement parameters of (Na 0.25 K 0.50 Li 0.25 )Li 3 SiO 4 :Eu. 
       FIG.  82    illustrates the emission spectrum of the eighth exemplary embodiment AB8 of the phosphor according to the present disclosure having the molecular formula (Na 0.5 Rb 0.5 )Li 3 SiO 4 :Eu 2+ . The wavelength in nm is plotted on the x-axis and the emission intensity in percent is plotted on the y-axis. For measuring the emission spectrum, a powder of the phosphor according to the present disclosure was excited with a primary radiation having a wavelength of 400 nm. The phosphor has a peak wavelength of approximately 525 nm and a dominant wavelength of 531 nm. The full width at half maximum is less than 45 nm and the color locus in the CIE color space lies at the coordinates CIE-x: 0.211 and CIE-y: 0.671. 
       FIG.  83    illustrates the emission spectrum of the eighth exemplary embodiment AB8 of the phosphor according to the present disclosure having the molecular formula (Na 0.5 Rb 0.5 )Li 3 SiO 4 :Eu 2+ . For measuring the emission spectrum, a powder of the phosphor according to the present disclosure was excited with a primary radiation having a wavelength of 460 nm. The phosphor has a full width at half maximum of less than 45 nm, a peak wavelength of 528 nm, a dominant wavelength of 533 nm and a color locus in the CIE color space having the coordinates CIE-x: 0.212 and CIE-y: 0.686. The narrow full width at half maximum of the phosphor results in a saturated green emission of the phosphor. On account of the small full width at half maximum, the phosphor (Rb r* Na 1−r* ) 1 (TA) 3 (TD) 1 (XB) 4 :E or Rb r* Na 1−r* ) 1 Li 3 SiO 4 :E where 0.4≤r*&lt;1.0, in particular (Na 0.5 Rb 0.5 )Li 3 SiO 4 :Eu 2+,  is particularly attractive for the use thereof in a conversion LED in which a narrowband emission in the green spectral range is required, as for the backlighting of LCD displays. 
       FIG.  84    shows a normalized Kubelka-Munk function (K/S), plotted against the wavelength λ in nm, for the eighth exemplary embodiment (AB8) of the phosphor according to the present disclosure. The phosphor according to the present disclosure can be efficiency excited with a primary radiation in the range of between 330 nm and 500 nm, advantageously 340 nm to 460 nm, particularly advantageously 350 nm to 450 nm. As a result, the phosphor is suitable in particular for backlighting applications, using a semiconductor chip with a primary radiation in the near UV range or blue range of the electromagnetic spectrum. 
       FIG.  85    shows a comparison of the emission spectra of the eighth exemplary embodiment AB8 of the phosphor according to the present disclosure in comparison with the conventional phosphors C1S and OS1 described under  FIG.  86   . 
       FIG.  86    shows various optical properties of the eighth exemplary embodiment of the phosphor according to the present disclosure AB8 in comparison with conventional phosphors C1S and OS1. In this case, OS1 stands for a phosphor of the formula (Sr, Ba) 2 SiO 4 :Eu, and C1S stands for Ca 7.8 Eu 0.2 Mg(SiO 4 ) 4 Cl 2 . All three phosphors exhibit a similar dominant wavelength. In this case, however, the phosphor AB8 according to the present disclosure exhibits a significantly higher luminous efficiency (LER). This leads to an improved color saturation, as a result of which it is possible to achieve a higher color space coverage, and to an improved overall efficiency. The reason for the improved properties is the small full width at half maximum of the eighth exemplary embodiment AB8 having the formula (Na 0.5 Rb 0.5 )Li 3 SiO 4 :Eu 2+  of the phosphor according to the present disclosure in comparison with the conventional phosphors. The high luminous efficiency increases the efficiency of green conversion LEDs having partial or full conversion in comparison with green conversion LEDs comprising known green phosphors having a comparable dominant and/or peak wavelength. 
     In  FIG.  87   , the relative brightness in % is plotted against the temperature in ° C. As is evident, the exemplary embodiment AB8 of the phosphor according to the present disclosure exhibits a high thermal stability.  FIG.  87    shows the thermal quenching behavior of the phosphor according to the present disclosure AB8 (represented as open squares) in comparison with a conventional phosphor OS1 of the formula (Sr,Ba) 2 SiO 4 :Eu (represented as filled rhombi). The phosphors were excited with a blue primary radiation having a wavelength of 400 nm for the phosphor according to the present disclosure AB8 and 460 nm for OS1 at various temperatures from 25 to 225° C. and their emission intensity was recorded in the process. It is clearly evident that the phosphor according to the present disclosure AB8 has a significantly smaller loss of emission intensity at typical temperatures that prevail in a conversion LED, in particular temperatures above 140° C. The phosphor can thus advantageously be used even at higher operating temperatures in conversion LEDs. Starting from 125° C., AB8 exhibits a significantly smaller loss of emission intensity in comparison with OS1. Moreover, AB8 at a temperature of 225° C. still exhibits an emission intensity of 90% in comparison with the emission intensity of 100% at 25° C. The emission intensity at 225° C. is more than twice as high as the emission intensity of OS1 at 225° C. 
       FIG.  88    shows the monoclinic crystal structure of the phosphor (Na 0.5 Rb 0.5 )Li 3 SiO 4 :Eu 2+  in a schematic illustration. The black circles represent Rb atoms and the circles enclosing white areas represent Na atoms. The phosphor AB8 crystallizes in the same space group, C2/m, as the fifth exemplary embodiment (Rb 0.5 Li 0.5 )Li 3 SiO 4 :Eu 2+  and the sixth exemplary embodiment (Na 0.25 K 0.50 Li 0.25 )Li 3 SiO 4 :Eu with comparable lattice parameters. The crystal structures of the phosphors (Na 0.5 Rb 0.5 )Li 3 SiO 4 :Eu 2+ , (Na 0.25 K 0.50 Li 0.25 )Li 3 SiO 4 :Eu and (Rb 0.5 Li 0.5 )Li 3 SiO 4 :Eu 2+  have the same (Li 3 SiO 4 ) structural units. The (Li 3 SiO 4 ) structural units are SiO 4  and LiO 4  tetrahedra, wherein oxygen occupies the corners and Li and Si, respectively, occupy the center of the tetrahedron. The occupation of the channels within these structural units is different in this case, however. (Rb 0.5 Li 0.5 )Li 3 SiO 4 :Eu 2+  contains two types of channels, wherein one channel is occupied only by Rb and the other is occupied only by Li, (Na 0.25 K 0.50 Li 0.25 )Li 3 SiO 4 :Eu also contains two types of channels, wherein one channel is occupied only by K and the other channel is occupied only by Li and Na, and (Rb 0.5 Na 0.5 )Li 3 SiO 4 :Eu 2+  contains two types of channels, wherein one channel is occupied only by Rb and the other channel is occupied only by Na. 
     A crystallographic evaluation is found in  FIG.  89   .  FIG.  89    shows a Rietveld refinement of the X-ray powder diffractogram of the eighth exemplary embodiment AB8. The diagram illustrates the superimposition of the measured reflections with the calculated reflections for (Na 0.5 Rb 0.5 )Li 3 SiO 4 :Eu, and also the differences between the measured and calculated reflections. The phosphor is contaminated with a small proportion of Na 3 RbLi 12 Si 4 O 16 . 
       FIG.  90    shows crystallographic data of (Na 0.5 Rb 0.5 )Li 3 SiO 4 :Eu. 
       FIG.  91    shows atomic positions in the structure of (Na 0.5 Rb 0.5 )Li 3 SiO 4 :Eu. 
       FIG.  92    illustrates the emission spectrum of the ninth exemplary embodiment AB9 of the phosphor according to the present disclosure having the molecular formula (Rb 0.25 Na 0.75 )Li 3 SiO 4 :Eu. The wavelength in nm is plotted on the x-axis and the emission intensity in % is plotted on the y-axis. For measuring the emission spectrum, a powder of the phosphor according to the present disclosure was excited with a primary radiation having a wavelength of 400 nm. The phosphor has a peak wavelength of approximately 473 nm and a dominant wavelength of 476 nm. The full width at half maximum is at 22 nm and the color locus in the CIE color space is at the coordinates CIE-x: 0.127 and CIE-y: 0.120. 
       FIG.  93    illustrates the emission spectrum of the ninth exemplary embodiment AB9 of the phosphor according to the present disclosure having the molecular formula (Na 0.75 Rb 0.25 )Li 3 SiO 4 :Eu 2+ . For measuring the emission spectrum, a powder of the phosphor according to the present disclosure was excited with a primary radiation having a wavelength of 420 nm and 440 nm. In comparison with the excitation with a primary radiation of 400 nm as shown in  FIG.  92   , the phosphor has an even smaller full width at half maximum of between 19 nm and 21 nm. (Na 0.75 Rb 0.25 )Li 3 SiO 4 :Eu 2+  and (Na 0.5 K 0.5 )Li 3 SiO 4 :Eu 2+  belong to the most narrowband Eu 2+ -doped phosphors known. 
       FIG.  94    shows a normalized Kubelka-Munk function (K/S), plotted against the wavelength λ in nm, for the ninth exemplary embodiment (AB9) of the phosphor according to the present disclosure, and of BaMgAl 10 O 17 :Eu (50 mol %) (VB1) as comparative example. The phosphor according to the present disclosure can be efficiently excited with a primary radiation in the range of between 340 nm and 470 nm, advantageously 340 nm to 450 nm, particularly advantageously 340 nm to 420 nm. As a result, the phosphor (Rb r* Na 1−r* ) 1 (TA) 3 (TD) 1 (XB) 4 :E or Rb r* Na 1−r* )Li 3 SiO 4 :E where 0&lt;r*&lt;0.4, in particular (Na 0.75 Rb 0.25 )Li 3 SiO 4 :Eu 2+ , is suitable in particular for backlighting applications, using a semiconductor chip with a primary radiation in the near UV range or blue range of the electromagnetic spectrum. As is evident, in comparison with VB1, AB9 is able to be efficiently excited even in the blue range of the electromagnetic spectrum. 
       FIG.  95    shows a comparison of the emission spectra of the ninth exemplary embodiment AB9 of the phosphor according to the present disclosure in comparison with the conventional phosphors VB1 and VB4 described under  FIG.  96   , at an excitation wavelength of 400 nm. 
       FIG.  96    shows various optical properties of the ninth exemplary embodiment of the phosphor according to the present disclosure AB9 in comparison with conventional phosphors VB1 and VB4. In this case, VB1 stands for a phosphor of the formula BaMgAl 10 O 17 :Eu and VB4 stands for (Ba 0.75 Sr 0.25 )Si 2 O 2 N 2 :Eu. All three phosphors exhibit a similar dominant wavelength and peak wavelength. In this case, however, the phosphor AB9 according to the present disclosure exhibits a significantly smaller full width at half maximum than the comparative examples. 
       FIG.  97    shows the tetragonal crystal structure of the phosphor (Na 0.75 Rb 0.25 )Li 3 SiO 4 :Eu 2+  in a schematic illustration. The black circles represent Rb atoms and the circles enclosing white areas represent Na atoms. The phosphor AB9 crystallizes in the same space group, I4/m, as the third exemplary embodiment (Na 0.5 K 0.5 )Li 3 SiO 4 :Eu 2+.  The crystal structures of the phosphors (Na 0.5 K 0.5 )Li 3 SiO 4 :Eu 2+  and (Na 0.75 Rb 0.25 )Li 3 SiO 4 :Eu 2+  have the same (Li 3 SiO 4 ) structural units. The (Li 3 SiO 4 ) structural units have SiO 4  and LiO 4  tetrahedra, wherein oxygen occupies the corners and Li and Si, respectively, occupy the center of the tetrahedron. The occupation of the channels within these structural units is different in the phosphors. (K 0.5 Na 0.5 )Li 3 SiO 4 :Eu 2+  contains two types of channels, wherein one channel is occupied only by K and the other is occupied only by Na. (Na 0.75 Rb 0.25 )Li 3 SiO 4 :Eu 2+  likewise contains two types of channels, wherein one channel is occupied only by Na and the other is occupied alternately by Na and Rb in mixed fashion. 
     A crystallographic evaluation is found in  FIG.  98   .  FIG.  98    shows a Rietveld refinement of the X-ray powder diffractogram of the ninth exemplary embodiment AB9. The diagram illustrates the superimposition of the measured reflections with the calculated reflections for (Na 0.75 Rb 0.25 )Li 3 SiO 4 :Eu, and also illustrates the differences between the measured and calculated reflections. The phosphor is contaminated with a small proportion of NaLi 3 SiO 4 . 
       FIG.  99    shows crystallographic data of (Na 0.75 Rb 0.25 )Li 3 SiO 4 :Eu. 
       FIG.  100    shows atomic positions in the structure of (Na 0.75 Rb 0.25 )Li 3 SiO 4 :Eu. 
     In  FIG.  101   , the relative brightness in % is plotted against the temperature in ° C. As is evident, the exemplary embodiment AB9 of the phosphor according to the present disclosure exhibits a high thermal stability.  FIG.  101    shows the thermal quenching behavior of the phosphor according to the present disclosure AB9 in comparison with a known phosphor BaMgAl 10 O 17 :Eu (VB1). The phosphors were excited with a blue primary radiation having a wavelength of 400 nm at various temperatures from 25 to 225° C. and their emission intensity between 410 nm and 780 nm was recorded in the process. It is clearly evident that the phosphor AB9 according to the present disclosure has a significantly smaller loss of emission intensity at temperatures above 100° C. At a temperature of 225° C., AB9 still exhibits an emission intensity of more than 95% in comparison with the emission intensity of 100% at 25° C. 
       FIG.  102    illustrates the emission spectrum of the tenth exemplary embodiment AB10 of the phosphor according to the present disclosure having the molecular formula SrSiAl 0.84 Li 2.16 O 1.32 N 2.68 :Eu. For measuring the emission spectrum, a single crystal of the phosphor according to the present disclosure was excited with a primary radiation having a wavelength of 460 nm. The phosphor has a peak wavelength of approximately 628.7 nm and a dominant wavelength of 598 nm. The full width at half maximum is at 99 nm and the color locus in the CIE color space is at the coordinates CIE-x: 0.617 and CIE-y: 0.381. 
       FIG.  103    illustrates the emission spectrum of the tenth exemplary embodiment AB10 of the phosphor according to the present disclosure having the molecular formula SrSiAl 0.84 Li 2.16 O 1.32 N 2.68 :Eu. For measuring the emission spectrum, a powder of the phosphor according to the present disclosure was excited with a primary radiation having a wavelength of 460 nm. The phosphor has a peak wavelength of approximately 632 nm and a dominant wavelength of 600 nm. The full width at half maximum is at 97.7 nm and the color locus in the CIE color space is at the coordinates CIE-x: 0.626 and CIE-y: 0.372. On account of self-absorption, the emission spectrum of the powder has a smaller full width at half maximum than the emission spectrum of the single crystal from  FIG.  102   . 
       FIG.  104    shows a normalized Kubelka-Munk function (K/S), plotted against the wavelength λ in nm, for the tenth exemplary embodiment (AB10) of the phosphor according to the present disclosure. The phosphor according to the present disclosure can be efficiency excited with a primary radiation in the range of between 340 nm and 500 nm, advantageously 340 nm to 460 nm. 
       FIG.  105    illustrates the emission spectrum of the tenth exemplary embodiment AB10 of the phosphor according to the present disclosure having the molecular formula SrSiAl 0.84 Li 2.16 O 1.32 N 2.68 :Eu and of two further exemplary embodiments (AB-10a and AB-10b) of the phosphor having the general formula Sr (Si 0.25 Al −1/8+r**/2 Li 7/8−r**/2 ) 4 (O 1−r** N r** ) 4 . The exemplary embodiments were produced like AB10; the weighed-in quantities are indicated in tables below. 
     
       
         
           
               
            
               
                   
               
               
                 Weighed-in quantities of the starting materials for AB-10a 
               
            
           
           
               
               
               
               
            
               
                   
                 Starting 
                 Substance amount/ 
                   
               
               
                   
                 material 
                 mmol 
                 Mass/g 
               
               
                   
                   
               
            
           
           
               
               
               
               
            
               
                   
                 NaLi 3 SiO 4   
                 28.08 
                 3.817 
               
               
                   
                 SrO 
                 26.96 
                 2.794 
               
               
                   
                 LiAlH 4   
                 84.25 
                 3.192 
               
               
                   
                 Eu 2 O 3   
                 0.56 
                 0.198 
               
               
                   
                   
               
            
           
         
       
     
     
       
         
           
               
            
               
                   
               
               
                 Weighed-in quantities of the starting materials for AB-10b 
               
            
           
           
               
               
               
               
            
               
                   
                 Starting 
                 Substance amount/ 
                   
               
               
                   
                 material 
                 mmol 
                 Mass/g 
               
               
                   
                   
               
            
           
           
               
               
               
               
            
               
                   
                 NaLi 3 SiO 4   
                 29.82 
                 4.052 
               
               
                   
                 SrO 
                 22.50 
                 2.331 
               
               
                   
                 Li 3 N 
                 8.13 
                 0.283 
               
               
                   
                 AlN 
                 73.18 
                 3.000 
               
               
                   
                 Eu 2 O 3   
                 0.95 
                 0.334 
               
               
                   
                   
               
            
           
         
       
     
     As is evident, by varying r** in the formula Sr(Si 0.25 Al −1/8+r**/2 Li 7/8−r**/2 ) 4 (O 1−r** N r** ) 4 , it is possible for the peak wavelength to be shifted from the yellow into the red spectral range. A comparison of optical properties of AB10, AB-10a and AB-10b is shown in  FIG.  106   . Known phosphors that exhibit emissions in this spectral range are α-SiAlON:Eu or (Ca,Sr,Ba) 2 SisN 8 :Eu. However, α-SiAlONs exhibit less adjustability of the peak wavelength than Sr(Si 0.25 Al −1/8+r**/2 Li 7/8−r**/2 ) 4 (O 1−r** N r** ) 4  and are thus limited in their application. Although a better adjustability of the peak wavelength is exhibited by (Ca, Sr,Ba) 2 Si 5 N 8 :Eu, the use thereof is associated with high costs as a result of expensive starting materials, such as alkaline earth metal nitrides, and high synthesis temperatures over 1400° C. The phosphor (MB) (Si 0.25 Al −1/8+r**/2 Li 7/8−r**/2 ) 4 (O 1−r** N r** ) 4 :E or Sr (Si 0.25 Al −1/8+r**/2 Li 7/8−r**/2 ) 4 (O 1−r** N r** ) 4 :E where 0.25≤r**≤1 can thus be adjusted in a targeted manner with regard to the desired color locus and/or color rendering index depending on requirements or application. Surprisingly many colors of the visible range, in particular from yellow to red, can thus be generated with just one phosphor. The phosphor is suitable in particular for conversion light-emitting diodes configured to emit a yellow to red radiation or a white radiation. 
       FIG.  107    shows the tetragonal crystal structure of the phosphor SrSiAl 0.84 Li 2.16 O 1.32 N 2.68 :Eu in a schematic illustration along the crystallographic c-axis. The hatched circles represent Sr atoms and hatched regions represent (Li,Si,Al) (O,N) 4  tetrahedra. The phosphor AB10 crystallizes in the UCr 4 C 4  structure type. The Sr atoms are situated in tetragonal channels formed by the corner- and edge-linked (Li,Si,Al) (O,N) 4  tetrahedra. The phosphor crystallizes in the space group I4/m. 
       FIG.  108    shows crystallographic data of SrSiAl 0.84 Li 2.16 O 1.32 N 2.68 :Eu. 
       FIG.  109    shows atomic positions in the structure of SrSiAl 0.84 Li 2.16 O 1.32 N 2.68 :Eu. 
       FIG.  110    shows anisotropic displacement parameters of SrSiAl 0.84 Li 2.16 O 1.32 N 2.68 :Eu. 
       FIG.  111    shows a crystallographic evaluation of the X-ray powder diffractogram of the tenth exemplary embodiment AB10. The diagram illustrates the superimposition of the measured reflections with the calculated reflections for SrSiAl 0.84 Li 2.16 O 1.32 N 2.68 :Eu. The upper part of the diagram shows the experimentally observed reflections (Cu K α1  radiation); the lower part of the diagram shows the calculated reflection positions. The calculation was made on the basis of the structure model for SrSiAl 0.84 Li 2.16 O 1.32 N 2.68 :Eu, as described in  FIGS.  107 - 110   . Reflections of secondary phases are identified by *. The secondary phases are present in a very small proportion. 
       FIG.  112    illustrates the emission spectrum of the eleventh exemplary embodiment AB11 of the phosphor according to the present disclosure having the molecular formula Na 1−y** Eu y** Li 3−2y** Al 3y** Si 1−y** O 4−4y** N 4y** :Eu where y**=0.2224 in comparison with the first exemplary embodiment AB1 NaLi 3 SiO 4 . The phosphor AB11 has a peak wavelength of approximately 613.4 nm and a dominant wavelength of 593.6 nm. The full width at half maximum is at 105 nm and the color locus in the CIE color space is at the coordinates CIE-x: 0.595 and CIE-y: 0.404. The different properties of AB1 and AB11, in particular the peak wavelength shifted into the longer-wavelength range for Na 1−y* Eu y** Li 3−2y** Al 3y** Si 1−y** O 4−4y** N 4y** :Eu where y**=0.2224 in comparison with NaLi 3 SiO 4 :Eu is due to a stronger nephelauxetic effect of the nitrogen atoms surrounding the activator ions, here the Eu 2+  ions, in the mixed phase Na 1−y** Eu y** Li 3−2y** Al 3y** Si 1−y** O 4−4y** N 4y** :Eu where y**=0.2224. The higher the proportion of nitrogen in the vicinity of the activator ions, the longer the peak wavelength. As a result, with increasing nitrogen content and thus with a rising value for y** in the phosphor Na 1−y* Eu y** Li 3−2y** Al 3y** Si 1−y** O 4−4y** N 4y** :Eu, the peak wavelength can be shifted within the visible range of the electromagnetic spectrum, in particular in a range of between 470 nm and 670 nm. The phosphor (MA) 1−y*** Sr y*** Li 3−2y*** Al 3y*** Si 1−y*** O 4−4y*** N 4y*** :E or Na 1−y** Eu y** Li 3−2y** Al 3y** Si 1−y** O 4−4y** N 4y** :E where 0&lt;y***&lt;0.875 is thus suitable in particular for lighting devices or conversion LEDs in which phosphors having very specific properties are required (so-called “color on demand” applications), for example for flashing lights in a motor vehicle. 
     Optical data for AB11 are shown in  FIG.  113   . 
       FIG.  114    shows the tetragonal crystal structure of the phosphor Na 1−y** Eu y** Li 3−2y** Al 3y** Si 1−y** O 4−4y** N 4y** :Eu where y**=0.2224 (AB11) and in a schematic illustration along the crystallographic c-axis. The hatched circles represent Na/Eu atoms and the hatched regions represent (Li,Si,Al) (O,N) 4  tetrahedra. The phosphor AB11 crystallizes in the UCr 4 C 4  structure type. The Na and Eu atoms are situated in tetragonal channels formed by the corner- and edge-linked (Li,Si,Al)(O,N) 4  tetrahedra. The phosphor crystallizes in the space group I4/m. The crystal structure is known e.g. for phosphors of the formula Sr[Mg 2 Al 2 N 4 ]:Eu 2+  (WO 2013/175336 A1 or P. Pust et al., Chem. Mater., 2014, 26, 6113). Surprisingly, in the present case it has been possible to show that even phosphors having a proportion of less than 87.5% nitrogen can be synthesized and are stable. 
       FIG.  115    shows crystallographic data of Na 1−y** Eu y** Li 3−2y** Al 3y** Si 1−y** O 4−4y** N 4y** :Eu where y**=0.2224. 
       FIG.  116    shows atomic positions in the structure of Na 1−y* Eu y** Li 3−2y** Al 3y** Si 1−y** O 4−4y** N 4y** :Eu where y**=0.2224. 
       FIG.  117    shows anisotropic displacement parameters of Na 1−y** Eu y** Li 3−2y** Al 3y** Si 1−y** O 4−4y** N 4y** :Eu where y**=0.2224. 
       FIG.  118 A  shows a crystallographic evaluation of the X-ray powder diffractogram of the eleventh exemplary embodiment AB11. The diagram illustrates a comparison of the measured reflections with the calculated reflections for Na 1−y* Eu y** Li 3−2y** Al 3y** Si 1−y** O 4−4y** N 4y** :Eu where y**=0.2224. The upper part of the diagram shows the experimentally observed reflections (Mo K α1  radiation); the lower part of the diagram shows the calculated reflection position. The calculation was made on the basis of the structure model for Na l−y** Eu y** Li 3−2y** Al 3y** Si 1−y** O 4−4y** N 4y** :Eu where y**=0.2224, as described in  FIGS.  114 - 117   . The correspondence of the reflections of the calculated powder diffractogram to the reflections of the measured powder diffractogram reveals a correspondence of the crystal structure of single crystals and powders of the phosphor. 
       FIG.  118 B  shows the emission spectra of Na 1−y** Eu y** Li 3−2y** Al 3y** Si 1−y** O 4−4y** N 4y** :Eu where y**=0.1 (AB11-1), Na 1−y* Ca y* Li 3−2y* Al 3y* Si 1−y* O 4−4y* N 4y* :Eu where y*=0.25 (AB6-1; AB6-2) and Na 1−y*** Sr y*** Li 3−2y*** Al 3y*** Si 1−y*** O 4−4y*** N 4y*** :Eu where y***=0.25 (AB18). A comparison of the optical properties is shown in  FIG.  119   . 
       FIG.  120    shows an excerpt from the CIE color space. In this excerpt, the region designated by ECE corresponds to color loci for flashing lights in the exterior region of a motor vehicle in the yellow or yellow-orange color range which correspond to the ECE regulations (ECE: Economic Commission for Europe). The ECE regulations are a catalog of internationally agreed, standardized technical specifications for motor vehicles and for parts and items of equipment of motor vehicles. Furthermore, the color loci of the eleventh exemplary embodiment AB11 and of a comparative example (Sr,Ca,Ba) 2 SisN 8 :Eu (Comp 258) are shown. The color loci of both phosphors lie within the ECE region and are therefore suitable for the use of said phosphors in conversion LEDs for flashing lights in motor vehicles. In contrast to (Sr,Ca,Ba) 2 Si 5 N 8 :Eu, the phosphor according to the present disclosure AB11 can be produced at lower temperatures. A yellow or yellow-orange conversion LED comprising AB11 (full conversion) is much more efficient and more temperature-stable in comparison with a yellow or yellow-orange LED, based on InGaAlP. 
       FIG.  121    shows the color loci of AB11 and Comp 258. 
       FIG.  122    illustrates the emission spectrum of a single crystal of the twelfth exemplary embodiment AB12 of the phosphor according to the present disclosure having the molecular formula SrLi 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu where x**=0.2014 in comparison with a comparative example (Ca,Sr,Ba) 2 SiO 4 :Eu. The phosphor AB12 has a peak wavelength of approximately 580.3 nm and a dominant wavelength of 576.5 nm. The full width at half maximum is at 80 nm and the color locus in the CIE color space is at the coordinates CIE-x: 0.486 and CIE-y: 0.506. A comparison of the optical data of AB12 and (Ca,Sr,Ba) 2 SiO 4 :Eu is illustrated in  FIG.  123   . (MB)Li 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu or SrLi 3−2x **Al 1+2x** O 4−4x** N 4x** :Eu where 0&lt;x**&lt;0.875, in particular where x**=0.2014, is suitable for use in colored conversion LEDs in which the primary radiation is completely or almost completely converted into secondary radiation and is thus usable in particular for “color on demand” applications. As illustrated in  FIG.  123   , a conversion LED comprising AB12 has a higher luminous efficiency than a conversion LED comprising (Ca,Sr,Ba) 2 SiO 4 :Eu. 
       FIG.  124    shows simulated emission spectra of conversion LEDs. Emission spectra of conversion LEDs with a primary radiation of 442 nm with the twelfth exemplary embodiment AB12 and phosphors as comparative examples are shown. White emission spectra in which the overall radiation is composed of the primary radiation and the respective secondary radiation are shown. The optical data are illustrated in  FIG.  125   . On account of the small full width at half maximum of AB12 in comparison with the comparative examples, the conversion LED comprising the phosphor according to the present disclosure AB12 has a higher luminous efficiency (LER) since the overlap with the eye sensitivity curve is greater than in the comparative examples. (MB)Li 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu or SrLi 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu where 0&lt;x**&lt;0.875, in particular the twelfth exemplary embodiment, is thus suitable in particular for use as sole phosphor in a conversion LED for generating warm-white overall radiation, in particular having a color temperature of 3400 K±100 K in combination with a primary radiation in the UV to blue range, for example with a layer sequence based on InGaN. Color temperatures of 3400 K±100 K with color loci near the Planckian locus are not achieved with the use of Y 3 Al 5 O 12 :Ce. Although the use of modifications of Y 3 Al 5 O 12 :Ce, such as (Y,Lu,Gd,Tb) 3 (Al,Ga) 5 O 12 :Ce ( FIG.  125   ), leads to the desired color loci and color temperatures, the luminous efficiency is lower than with the use of Y 3 AlO 12 :Ce and the thermal quenching behavior is higher. Orthosilicates such as (Ca,Sr,Ba) 2 SiO 4 :Eu are thermally and chemically less stable in comparison with Y 3 Al 5 O 12 :Ce and additionally have a poorer luminous efficiency in comparison with a conversion LED comprising AB12. 
       FIG.  114    and  FIG.  160    show the tetragonal crystal structure of the phosphor SrLi 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu where x**=0.2014 (AB12) in a schematic illustration along the crystallographic c-axis. The hatched circles represent Sr atoms and hatched regions represent (Li,Al) (O,N) 4  tetrahedra. The phosphor AB12 crystalizes in the UCr 4 C 4  structure type. The phosphor crystallizes in the space group I4/m. The crystal structure is known e.g. for phosphors of the formula Sr[Mg 2 Al 2 N 4 ]:Eu 2+  (WO 2013/175336 A1 or P. Pust et al., Chem. Mater., 2014, 26, 6113). The (Li,Al)(O,N) 4  tetrahedra form tetragonal channels in which the Sr atoms are arranged. Surprisingly, in the present case it has been possible to show that even phosphors having a proportion of less than 87.5% nitrogen can be synthesized and are stable. The phosphors of the formula SrLi 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu where x**≥0.1250 crystallize in this crystal type, which has been able to be shown on the basis of the exemplary embodiments AB12-1 to AB12-8. With increasing x**, the volume of the unit cell increases and the peak wavelength is shifted to longer wavelengths. 
       FIG.  126    shows crystallographic data of SrLi 3−2x** Al 1+2x **O 4−4x **N 4x** :Eu where x**=0.2014 (AB12). 
       FIG.  127    shows atomic positions in the structure of SrLi 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu where x**=0.2014 (AB12). 
       FIG.  128    shows anisotropic displacement parameters of SrLi 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu where x**=0.2014 (AB12). 
       FIG.  129    illustrates the emission spectrum of AB13 of the phosphor according to the present disclosure having the molecular formula (Cs 0.25 Na 0.25 K 0.25 Li 0.25 )Li 3 SiO 4 :Eu 2+ . For measuring the emission spectrum, a powder of the phosphor according to the present disclosure was excited with a primary radiation having a wavelength of 400 nm. The phosphor has a full width at half maximum of 46 nm, a peak wavelength of 530 nm and a dominant wavelength of 532 nm. The color locus is at CIE-x: 0.222 and CIE-y: 0.647. The optical properties are similar to those of the eighth exemplary embodiment. The peak at approximately 490 nm is probably attributable to a contamination by CsNa 2 K(Li 3 SiO 4 ) 4 :Eu 2+ . 
       FIG.  130    shows a normalized Kubelka-Munk function (K/S), plotted against the wavelength λ in nm, for AB13. The phosphor can be efficiently excited with a primary radiation in the blue range. 
       FIG.  131    illustrates the emission spectrum of AB14 of the phosphor according to the present disclosure having the molecular formula (Cs 0.25 Na 0.5 K 0.25 )Li 3 SiO 4 :Eu 2+ . For measuring the emission spectrum, a powder of the phosphor according to the present disclosure was excited with a primary radiation having a wavelength of 400 nm. The phosphor has a full width at half maximum of 26 nm, a peak wavelength of 486 nm and a dominant wavelength of 497 nm. The color locus is at CIE-x: 0.138 and CIE-y: 0.419. 
       FIG.  132    shows a normalized Kubelka-Munk function (K/S), plotted against the wavelength λ in nm, for AB14. The phosphor can be efficiently excited with a primary radiation in the blue range. 
       FIG.  133    illustrates the emission spectrum of AB15 of the phosphor according to the present disclosure having the molecular formula (Rb 0.25 Na 0.5 K 0.25 )Li 3 SiO 4 :Eu 2+ . For measuring the emission spectrum, a powder of the phosphor according to the present disclosure was excited with a primary radiation having a wavelength of 400 nm. The phosphor has a full width at half maximum of 27 nm, a peak wavelength of 480 nm and a dominant wavelength of 490 nm. The color locus is at CIE-x: 0.139 and CIE-y: 0.313. The peak at approximately 530 nm is probably attributable to a contamination by RbNa(Li 3 SiO 4 ) 2  or K 2 NaLi(Li 3 SiO 4 ) 4 . 
       FIG.  134    shows a normalized Kubelka-Munk function (K/S), plotted against the wavelength λ in nm, for AB15. The phosphor can be efficiently excited with a primary radiation in the blue range. 
       FIG.  135    illustrates the emission spectrum of AB16 of the phosphor according to the present disclosure having the molecular formula (Cs 0.25 Na 0.25 Rb 0.25 Li 0.25 )Li 3 SiO 4 :Eu 2+ . For measuring the emission spectrum, a powder of the phosphor according to the present disclosure was excited with a primary radiation having a wavelength of 400 nm. The phosphor has a full width at half maximum of 24 nm, a peak wavelength of 473 nm, and a dominant wavelength of 489 nm. The peak at approximately 530 nm is probably attributable to a contamination by RbNa(Li 3 SiO 4 ) 2 . 
     The optical properties of AB14, AB15 and AB16 are similar to those of AB9 and AB3. 
       FIG.  136    shows a normalized Kubelka-Munk function (K/S), plotted against the wavelength λ in nm, for AB16. The phosphor can be efficiently excited with a primary radiation in the blue range. 
       FIG.  137    shows the tetragonal crystal structure of AB13 of the phosphor according to the present disclosure having the molecular formula (Cs 0.25 Na 0.25 K 0.25 Li 0.25 )Li 3 SiO 4 :Eu 2+.  The black circles represent Cs atoms, the circles enclosing white areas represent Li atoms, the circles with ruled lines represent K atoms and the checked circles represent Na atoms. The crystal structure is similar to the crystal structure of the ninth exemplary embodiment AB9; AB13 crystallizes in the same space group, I4/m. The (Li 3 SiO 4 ) structural units have SiO 4  and LiO 4  tetrahedra, wherein oxygen occupies the corners and Li and Si, respectively, occupy the center of the tetrahedron. (Cs 0.25 Na 0.25 K 0.25 Li 0.25 )Li 3 SiO 4 :Eu 2+  contains two types of channels within the (Li 3 SiO 4 ) structural units, wherein one channel is occupied by Na and Li and the other is occupied alternately by Cs and K. The arrangement of Na and Li within one channel corresponds to that of AB7. The exact arrangement of Na and Li within one channel cannot be ascertained by means of X-ray diffraction. 
       FIG.  138    shows the tetragonal crystal structure of AB14 of the phosphor according to the present disclosure having the molecular formula (Cs 0.25 Na 0.5 K 0.25 )Li 3 SiO 4 :Eu 2+ . The black circles represent Cs atoms, the circles with ruled lines represent K atoms and the checked circles represent Na atoms. The crystal structure is similar to the crystal structure of the ninth exemplary embodiment AB9; AB13 crystallizes in the same space group I4/m. The (Li 3 SiO 4 ) structural units have SiO 4  and LiO 4  tetrahedra, wherein oxygen occupies the corners and Li and Si, respectively, occupy the center of the tetrahedron. (Cs 0.25 Na 0.5 K 0.25 )Li 3 SiO 4 :Eu 2+  contains two types of channels within the (Li 3 SiO 4 ) structural units, wherein one channel is occupied by Na and the other is occupied alternately by Cs and K. 
       FIG.  139    shows the tetragonal crystal structure of AB15 of the phosphor according to the present disclosure having the molecular formula (Rb 0.25 Na 0.5 K 0.25 )Li 3 SiO 4 :Eu 2+ . The black circles represent Rb atoms, the circles with ruled lines represent K atoms and checked circles represent Na atoms. The crystal structure is isostructural with respect to that of AB14, wherein the positions of the Cs atoms are occupied by Rb atoms. 
       FIG.  140    shows the tetragonal crystal structure of AB16 of the phosphor according to the present disclosure having the molecular formula (Cs 0.25 Na 0.25 Rb 0.25 Li 0.25 )Li 3 SiO 4 :Eu 2+ . The black circles represent Cs atoms, the circles with ruled lines represent Rb atoms, the checked circles represent Na atoms and the white circles represent Li atoms. The crystal structure is isostructural with respect to that of AB13, wherein the positions of the K atoms are occupied by Rb atoms. 
       FIGS.  141 - 144    each show a Rietveld refinement of the X-ray powder diffractogram of AB13 ( FIG.  141   ), of AB14 ( FIG.  142   ), of AB15 ( FIG.  143   ) and of AB16 ( FIG.  144   ). The diagram illustrates the superimposition of the measured reflections with the calculated reflections, and also the differences between the measured and calculated reflections. 
       FIG.  145    shows crystallographic data and  FIG.  146    shows atomic positions of AB13. 
       FIG.  147    shows crystallographic data and  FIG.  148    shows atomic positions of AB14. 
       FIG.  149    shows crystallographic data and  FIG.  150    shows atomic positions of AB15. 
       FIG.  151    shows crystallographic data and  FIG.  152 A  shows atomic positions of AB16. 
       FIG.  152 B  shows the emission spectrum of single crystals of the phosphors AB12-1 and AB12-2 of the phosphor according to the present disclosure having the molecular formulae SrLi 3−2x** Al 1+2x** O 4−4x** N 4** :Eu 2+  where x**=0.125 (AB12-1) and x**=0.1375 (AB12-2). The optical properties are shown in  FIG.  153   . 
       FIG.  154    shows the emission spectrum of a single crystal of the phosphor SrLi 3−2x** Al 1+2x**  O 4−4x** N 4x** :Eu 2+  where x**&lt;0.125. The phosphors SrLi 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu 2+  where x**&lt;0.125 have a smaller full width at half maximum than phosphors where x**≥0.125. The optical properties are shown in  FIG.  155   . The crystal structure of phosphors of the formula SrLi 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu 2+  where x**&lt;0.125 is related to the UCr 4 C 4  structure type, although reflections in single crystal diffraction data indicate a higher degree of ordering. This results in a crystal structure having a higher degree of ordering that is derived from the UCr 4 C 4  structure type. Surprisingly, phosphors having a higher oxygen content exhibit a higher degree of ordering within the crystal structure. The smaller full width at half maximum is attributable to the higher degree of ordering of the crystal structure. 
       FIG.  156    illustrates the peak wavelength λpeak in nm plotted against the cell volume of the unit cell of the crystal structure of phosphors of the formula SrLi 3−2** Al 1+2x** O 4−4x** N 4x** :Eu where x**≥0.1250 for powders and single crystals of SrLi 3−2x** Al 1+2x** O 4−4X** N 4x** :Eu having different proportions of x**. The differences in the peak wavelengths in the measurement of powders and single crystals are caused by reabsorption effects in the powder measurement, which can lead to a long-wave shift in the observed peak wavelength. The peak wavelengths can be adjusted by adapting the cell volume of the unit cell. As x** rises, the cell volume of the unit cell increases and at the same time the peak wavelength is shifted into the longer-wavelength range. Advantageously, by varying x**≥0.125, it is possible for the peak wavelength to be shifted from the green into the red spectral range. The peak wavelengths and cell volumes (V) for various proportions x** are shown in  FIG.  157   . As a result, the phosphor of the general molecular formula SrLi 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu is interesting for very many applications. In particular, it is possible to provide phosphors which have peak wavelengths between those of the yellow-emitting Y 3 Al 5 O 12 :Ce, of the orange-red-emitting (Ca,Sr,Ba) 2 SisN 8 :Eu and of the red-emitting (Sr,Ca)SiAlN 3 :Eu. 
       FIG.  158    shows crystallographic data of single crystals of the phosphors AB12-1 and AB12-2 of the phosphor according to the present disclosure having the molecular formulae SrLi 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu 2+  where x**=0.125 (AB12-1) and x**=0.1375 (AB12-2). 
       FIG.  159    shows atomic positions in the structure of SrLi 3−2x** Al 1+2x** O 4−4x** N 4x** :Eu 2+  for AB12-2. 
       FIG.  161    illustrates the emission spectrum of AB17 of the phosphor according to the present disclosure having the molecular formula Na 0.125 K 0.87 Li 3 SiO 4 :Eu. For measuring the emission spectrum, a single crystal of the phosphor according to the present disclosure was excited with a primary radiation having a wavelength of 460 nm. The curves designated by Peak1 and Peak2 represent two Gaussian curves for describing the total emission with two emission peaks. The measured curve is congruent with the sum of the two Gaussian curves as calculated curve. The wavelength of the emission peak having the highest intensity is referred to as peak wavelength. The wavelength of the emission peak having lower intensity is referred to as relative emission maximum. The data resulting from the spectrum are summarized in  FIG.  162   . 
       FIG.  163    shows the emission spectrum of three embodiments of the phosphor according to the present disclosure (Na r K 1−r ) 1 Li 3 SiO 4 :Eu where 0.05&lt;r&lt;0.2 with different proportions r. These also exhibit a wide emission. 
       FIG.  164    shows an overview of simulated optical data of conversion LEDs. A blue-emitting semiconductor chip based on InGaN is used as primary radiation source; the peak wavelength of the primary radiation is 438 nm or 443 nm. The phosphors used for converting the primary radiation are AB17 and (Lu,Y) 3 Al 5 O 12 :Ce. The comparative examples are identified by Comp1, Comp2 and Comp3 and the embodiments according to the present disclosure by AB17-LED1 and AB17-LED2. For all the conversion LEDs, the overall radiation of the conversion LEDs results from a superimposition of the primary and secondary radiations. The color loci of the overall radiation all lie in the cold-white range with color temperatures of more than 8000 K close to the locus of the Planckian radiator. Surprisingly, the embodiments according to the present disclosure have a high color rendering index where CRI&gt;80 and R9&gt;50, while the comparative examples only have a CRI&lt;70 and R9&lt;0. This is attributable to the wide emission of the phosphor AB17 from the green to the red spectral range. The phosphor (Na r K 1−r ) 1 (TA) 3 (TD) 1 (XB) 4 :Eu where 0.05&lt;r&lt;0.2, in particular (Na r K 1−r ) 1 Li 3 SiO 4 :Eu, is thus suitable in particular for conversion LEDs for general lighting. The phosphor can advantageously be used as sole phosphor in a conversion LED for general lighting. 
       FIG.  165    illustrates the color loci of the overall radiation of the conversion LEDs from  FIG.  164   . As is evident, the color loci are all situated close to the color loci of the Planckian radiator. 
       FIG.  166    illustrates emission spectra of the conversion LEDs AB17-LED2 and Comp2 from  FIG.  164   . 
       FIG.  167    shows an overview of simulated optical data of conversion LEDs. A blue-emitting semiconductor chip based on InGaN is used as primary radiation source; the peak wavelength is 443 nm, 446 nm or 433 nm. The phosphors used for converting the primary radiation are AB17 and Lu 3 Al 5 O 12 :Ce. The comparative examples are identified by Comp4 and Comp5 and the embodiments according to the present disclosure are identified by AB17-LED3, AB17-LED4 and AB17-LED5. In the embodiments according to the i present disclosure nvention, only AB17 is used as phosphor, while in the comparative examples, a second, red-emitting phosphor CaAlSiN 3 :Eu is used alongside Lu 3 Al 5 O 12 :Ce. Surprisingly, the overall radiation of the embodiments according to the present disclosure has a very large overlap with the transmission range of standard filters and filters for larger color spaces (HCG, High Color Gamut), such that only little light is lost and the achievable color space is as large as possible. As is evident, with the embodiments according to the present disclosure having only one phosphor, it is possible to obtain a high, in some instances greater coverage of the colors of the sRBG color space than with the comparative examples in which two phosphors are used. The phosphor (Na r K 1−r ) 1 (TA) 3 (TD) 1 (XB) 4 :Eu where 0.05&lt;r&lt;0.2, in particular (Na r K 1−r ) 1 Li 3 SiO 4 :Eu, is thus suitable in particular for conversion LEDs for backlighting applications. The phosphor can advantageously be used as sole phosphor in a conversion LED for backlighting applications. 
       FIG.  168    illustrates emission spectra of the conversion LEDs AB17-LED5 and Comp5 from  FIG.  167   . 
       FIGS.  169  and  170    show the spanned color spaces of the filtered overall radiation of various conversion LEDs from  FIG.  167    and the overlap thereof with the sRGB color space. It is evident that a large bandwidth of colors can be rendered with the exemplary embodiments AB17-LED3 and AB17-LED5; primarily in the green corner of the spanned color triangle it is possible to attain more colors than with the exemplary embodiments. 
       FIG.  171    shows a unit cell of the tetragonal crystal structure of the phosphor Na 0.125 K 0.87 Li 3 SiO 4 :Eu (AB17) in a schematic illustration along the crystallographic c-axis. The closely hatched circles represent Na atoms and the white circles represent K atoms. The hatched regions represent LiO 4  tetrahedra, and the closely hatched regions represent SiO 4  tetrahedra. The LiO 4  and SiO 4  tetrahedra are corner- and edge-linked and form channels in which the Na and K atoms are arranged. The crystal structure is related to the crystal structure of AB3, AB7, AB8, AB9, AB13, AB14, AB15 and AB16. 
     In particular, two types of channels are contained in the crystal structure. Exclusively K atoms are arranged in the first channels, while Na and K atoms are arranged in the other channels. SiO 4  tetrahedra (closely hatched) are arranged in the form of a helix ( FIG.  172   ) around the channels in which exclusively K atoms are arranged. The Na atoms (closely hatched circles), within the channels in which Na and K atoms are arranged, are surrounded by SiO 4  tetrahedra in distorted tetrahedral fashion (black regions;  FIG.  173   ).  FIG.  172    shows the channel containing only K atoms.  FIG.  173    shows the channel containing K atoms and Na atoms. The sequence of the arrangement of the K atoms and Na atoms within the channel is NaKKKNaKKK. The illustrations of the excerpts from the crystal structure in  FIGS.  172  and  173    are perpendicular to the crystallographic c-axis. 
       FIG.  174    shows crystallographic data of Na 0.125 K 0.875 Li 3 SiO 4 :Eu (AB17). 
       FIG.  175    shows atomic positions in the structure of Na 0.125 K 0.75 Li 3 SiO 4 :Eu (AB17). 
       FIG.  176    shows anisotropic displacement parameters of Na 0.125 K 0.875 Li 3 SiO 4 :Eu (AB17). 
       FIG.  177    shows a crystallographic evaluation of the X-ray powder diffractogram of the seventeenth exemplary embodiment AB17. The diagram illustrates a comparison of the measured reflections with the calculated reflections for Na 0.125 K 0.875 Li 3 SiO 4 :Eu. The upper part of the diagram shows the experimentally observed reflections (Mo K α1  radiation); the lower part of the diagram shows the calculated reflection positions. The calculation was made on the basis of the structure model for Na 0.125 K 0.875 Li 3 SiO 4 :Eu, as described in  FIGS.  171 - 176   . Reflections of secondary phases are identified by *. The correspondence of the reflections of the calculated powder diffractogram to the reflections of the measured powder diffractogram reveals a correspondence of the crystal structure of single crystals and powders of the phosphor. 
     The present disclosure is not restricted to the exemplary embodiments by the description on the basis of said exemplary embodiments. Rather, the present disclosure encompasses any novel feature and also any combination of features, which in particular includes any combination of features in the patent claims, even if this feature or this combination itself is not explicitly specified in the patent claims or exemplary embodiments. 
     While the disclosed embodiments have been particularly shown and described with reference to specific embodiments, it should be understood by those skilled in the art that various changes in form and detail may be made therein without departing from the spirit and scope of the disclosed embodiments as defined by the appended claims. The scope of the disclosed embodiments is thus indicated by the appended claims and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced. 
     The following exemplary embodiments pertain to further aspects of this disclosure: 
     Embodiment 1 is a phosphor having the general molecular formula
 
(MA) a (MB) b (MC) c (MD) d (TA) e (TB) f (TC) g (TD) h (TE) i (TF) j (XA) k (XB) l (XC) m (XD) n :E,
 
     wherein
         MA is selected from a group of monovalent metals which comprises Li, Na, K, Rb, Cs, Cu, Ag and combinations thereof,   MB is selected from a group of divalent metals which comprises Mg, Ca, Sr, Ba, Zn, Mn, Eu, Yb, Ni, Fe, Co and combinations thereof,   MC is selected from a group of trivalent metals which comprises Y, Fe, Cr, Sc, In, rare earth metals and combinations thereof,   MD is selected from a group of tetravalent metals which comprises Zr, Hf, Mn, Ce and combinations thereof,   TA is selected from a group of monovalent metals which comprises Li, Na, Cu, Ag and combinations thereof,   TB is selected from a group of divalent metals which comprises Mg, Zn, Mn, Eu, Yb, Ni and combinations thereof,   TC is selected from a group of trivalent metals which comprises B, Al, Ga, In, Y, Fe, Cr, Sc, rare earth metals and combinations thereof,   TD is selected from a group of tetravalent metals which comprises Si, Ge, Sn, Mn, Ti, Zr, Hf, Ce and combinations thereof,   TE is selected from a group of pentavalent elements which comprises P, Ta, Nb, V and combinations thereof,   TF is selected from a group of hexavalent elements which comprises W, Mo and combinations thereof,   XA is selected from a group of elements which comprises F, Cl, Br and combinations thereof,   XB is selected from a group of elements which comprises O, S and combinations thereof,   XC═N   XD=C   E=Eu, Ce, Yb and/or Mn,   a+b+c+d=t   e+f+g+h+i+j=u   k+l+m+n=v   a+2b+3c+4d+e+2f+3g+4h+5i+6j−k−2l−3m−4n=w   0.8≤t≤1   3.5≤u≤4   3.5≤v≤4   (−0.2)≤w≤0.2 and   0≤m&lt;0.875 v and/or v≥l&gt;0.125 v.       

     Embodiment 2 is the phosphor according to embodiment 1, which has a crystal structure in which TA, TB, TC, TD, TE and/or TF are surrounded by XA, XB, XC and/or XD and the resultant structural units are linked via common corners and edges to form a three-dimensional spatial network having cavities or channels and MA, MB, MC and/or MD are/is arranged in the cavities or channels. 
     Embodiment 3 is the phosphor according to embodiments 1 or 2 claims, wherein
         a+b+c+d=1   e+f+g+h+i+j=4   k+l+m+n=4   a+2b+3c+4d+e+2f+3g+4h+5i+6j−k−2l−3m−4n=0 and   m&lt;3.5.       

     Embodiment 4 is the phosphor according to any of embodiments 1 to 3, which has the following general molecular formula:
 
(MA) a (MB) b (TA) e (TB) f (TC) g (TD) h (XB) l (XC) m :E,
 
     wherein
         MA is selected from a group of monovalent metals which comprises Li, Na, K, Rb, Cs, Cu, Ag and combinations thereof,   MB is selected from a group of divalent metals which comprises Mg, Ca, Sr, Ba, Zn, Mn, Eu, Yb, Ni, Fe, Co and combinations thereof,   TA is selected from a group of monovalent metals which comprises Li, Na, Cu, Ag and combinations thereof,   TB is selected from a group of divalent metals which comprises Mg, Zn, Mn, Eu, Yb, Ni and combinations thereof,   TC is selected from a group of trivalent metals which comprises B, Al, Ga, In, Y, Fe, Cr, Sc, rare earths and combinations thereof,   TD is selected from a group of tetravalent metals which comprises Si, Ge, Sn, Mn, Ti, Zr, Hf, Ce and combinations thereof,   XB is selected from a group of elements which comprises O, S and combinations thereof,   XC═N   E=Eu, Ce, Yb and/or Mn,   a+b=1   e+f+g+h=4   l+m=4   a+2b+e+2f+3g+4h−2l−3m=0
           and   
               

     0≤m&lt;3.5. 
     Embodiment 5 is the phosphor according to embodiment 4, wherein
         MA is selected from a group of monovalent metals which comprises Li, Na, K, Rb, Cs and combinations thereof,   MB is selected from a group of divalent metals which comprises Mg, Ca, Sr, Ba, Eu and combinations thereof,   TA is selected from a group of monovalent metals which comprises Li, Na, Cu, Ag and combinations thereof,   TB is selected from a group of divalent metals which comprises Eu,   TC is selected from a group of trivalent metals which comprises B, Al, Ga, In and combinations thereof,   TD is selected from a group of tetravalent metals which comprises Si, Ge, Sn, Mn, Ti and combinations thereof,   XB═O.       

     Embodiment 6 is the phosphor according to any of embodiments 4 to 5, wherein f=g=0. 
     Embodiment 7 is the phosphor according to any of embodiments 1 to 5, which has one of the following general molecular formulae:
 
(MA) 1 (TA) 3 (TD) 1 (XB) 4 :E,
 
(MA) 1 (TA) 3−x (TD) 1−x (TB) x (TC) x (XB) 4 :E,
 
(MA) 1−x′ (MB) x′ (TA) 3 (TD) 1−x (TC) x (XB) 4 :E,
 
(MA) 1−x″ (MB) x″ (TA) 3−x″ (TD) 1−x″ (TB) 2x″ (XB) 4 :E,
 
(MA) 1 (TA) 3−2z (TB) 3z (TD) 1−z (XB) 4 :E or
 
(MA) 1 (TA) 3 (TD) 1−2z′ (TC) z′ (TE) z′ (XB) 4 :E, wherein
 
     0≤x≤1, 
     0≤x′≤1, 
     0≤x″≤1, 
     0≤z≤1, 
     0≤z′≤0.5 
     and E is selected from a group which comprises Eu, Ce, Yb, Mn and combinations thereof. 
     Embodiment 8 is the phosphor according to any of embodiments 1 5, which has one of the following general molecular formulae:
 
(MA) 1−y (TB) y (TA) 3−2y (TC) 3y (TD) 1−y (XB) 4−4y (XC) 4y :E,
 
(MA) 1−y* (MB) y* (TA) 3−2y* (TC) 3y* (TD) 1−y* (XB) 4−4y* (XC) 4y* :E,
 
(MA) 1 (TA) 3−y′ (TC) y′ (TD) 1 (XB) 4−2y′ (XC) 2y′ :E,
 
(MA) 1 (TA) 3−y″ (TB) y″ (TD) 1 (XB) 4−y″ (XC) y″ :E,
 
(MA) 1−w′″ (MB) w′″ (TA) 3 (TD) 1 (XB) 4−w′″ (XC) w′″ :E,
 
(MA) 1 (TA) 3−w′ (TC) 2w′ (TD) 1−w′ (XB) 4−w′ (XC) w′ :E or
 
(MA) 1−w″ (MB) w″ (TA) 3−w″ (TD) 1−w″ (TC) 2w″ (XB) 4−2w″ (XC) 2w″ :E,
 
     wherein 
     0≤y&lt;0.875, 
     0&lt;y*&lt;0.875, 
     0≤y′&lt;1.75, 
     0≤y″≤3, 
     0≤w′″≤1, 
     0≤w′≤1, 
     0≤w″≤1 
     and E is selected from a group which comprises Eu, Ce, Yb, Mn and combinations thereof. 
     Embodiment 9 is the phosphor according to embodiment 7, which has one of the following general molecular formulae:
 
(MA)Li 3−x Si 1−x Zn x Al x O 4 :E;
 
(MA)Li 3−x Si 1−x Mg x Al x O 4 :E;
 
(MA) 1−x′ Ca x′ Li 3 Si 1−x′ Al x′ O 4 :E;
 
(MA) 1−x″ Ca x″ Li 3−x″ Si 1−x″ Mg 2x″ O 4 :E;
 
(MA)Li 3−2z Mg 3z Si 1−z O 4 :E; or
 
(MA)Li 3 Si 1−2z′ Al z′ P z′ O 4 :E, wherein
 
     0≤x≤1, 
     0≤x′≤1, 
     0≤x″≤1, 
     0≤z≤1, 
     0≤z′≤0.5 and E is selected from a group which comprises Eu, Ce, Yb, Mn and combinations thereof. 
     Embodiment 10 is the phosphor according to embodiment 8, which has one of the following general molecular formulae:
 
(MA) 1−y Zn y Li 3−2y Al 3y Si 1−y O 4−4y N 4y :E
 
(MA) 1−y* Ca y* Li 3−2y* Al 3y* Si 1−y* O 4−4y* N 4y* :E,
 
(MA) 1−y*** Sr y*** Li 3−2y*** Al 3y*** Si 1−y*** O 4−4y*** N 4y*** :E
 
(MA) 1−y** Eu y** Li 3−2y** Al 3y** Si 1−y** O 4−4y** N 4y* :E
 
(MA)Li 3−y′ Al y′ SiO 4−2y′ N 2y′ :E,
 
(MA)Li 3−y″ Mg y″ SiO 4−y″ N y″ :E,
 
(MA) 1−w′″ Ca w′″ Li 3 SiO 4−w′″ N w′″ :E,
 
(MA)Li 3−w′ Al 2w′ Si 1−w′ O 4−w′ N w′ :E,
 
(MA) 1−w″ Ca w″ Li 3−w′ Si 1−w″ Al 2w″ O 4−2w″ N 2w″ :E.
 
     wherein 
     0&lt;y*&lt;0.875, 
     0&lt;y**&lt;0.875, 
     0&lt;y***&lt;0.875, 
     0≤y&lt;0.875, 
     0≤y′≤1.75, 
     0≤y″≤3, 
     0≤w′″≤1, 
     0≤w′≤1, 
     0≤w″≤1 and E is selected from a group which comprises Eu, Ce, Yb, Mn and combinations thereof. 
     Embodiment 11 is the phosphor according to embodiment 7, which has one of the following general molecular formulae: (Na r K 1−r ) 1 (TA) 3 (TD) 1 (XB) 4 :E, (Rb r′ Li 1−r′ ) 1 (TA) 3 (TD) 1 (XB) 4 :E, (K 1−r″−r′″ Na r″ Li r′″ ) 1 (TA) 3 (TD) 1 (XB) 4 :E, (Cs,Na,K,Li) 1 (TA) 3 (TD) 1 (XB) 4 :E or (Rb r* Na 1−r* ) 1 (TA) 3 (TD) 1 (XB) 4 :E, (Cs,Na,Rb,Li) 1 (TA) 3 (TD) 1 (XB) 4 :E, (Cs,Na,K) 1 (TA) 3 (TD) 1 (XB) 4 :E or (Rb,Na,K) 1 (TA) 3 (TD) 1 (XB) 4 :E, 
     wherein 
     0≤r≤1, 
     0≤r′≤1, 
     0&lt;r″&lt;0.5, 
     0&lt;r′″&lt;0.5, 
     0&lt;r*&lt;1 
     and E is selected from a group which comprises Eu, Ce, Yb, Mn and combinations thereof. 
     Embodiment 12 is the phosphor according to embodiment 11, which has one of the following general molecular formulae: (Na r K 1−r )Li 3 SiO 4 :E, (Rb r′ Li 1−r′ )Li 3 SiO 4 :E, (K 1−r″−r′″ Na r″ Li r′″ )Li 3 SiO 4 :E, (Cs,Na,K,Li)Li 3 SiO 4 :E, (Rb r* Na 1−r* ) 1 Li 3 SiO 4 :E, (Cs,Na,Rb,Li) 1 Li 3 SiO 4 :E, (Cs,Na,K)Li 3 SiO 4 :E or (Rb,Na,K)Li 3 SiO 4 :E 
     wherein 
     0≤r≤1, 
     0≤r′≤1, 
     0&lt;r′&lt;0.5, 
     0&lt;r′″&lt;0.5, 
     0&lt;r*&lt;1 
     and E is selected from a group which comprises Eu, Ce, Yb, Mn and combinations thereof. 
     Embodiment 13 is the phosphor according to embodiment 10, which has the formula Na 1−y* Ca y* Li 3−2y* Al 3y* Si 1y* O 4−4y* N 4y* :E, wherein 0&lt;y*&lt;0.875, preferably 0&lt;y*&lt;0.5, and E is selected from a group which comprises Eu, Mn, Ce, Yb and combinations thereof. 
     Embodiment 14 is the phosphor according to embodiment 10, which has the formula Na 1−y** Eu y** Li 3−2y** Al 3y** Si 1−y** O 4−4y** N 4y** :E, wherein 0&lt;y**&lt;0.875, preferably 0&lt;y**&lt;0.5, and E is selected from a group which comprises Eu, Mn, Ce, Yb and combinations thereof. 
     Embodiment 15 is the phosphor according to any of embodiments 1 to 5, which has the formula (MB)Li 3−2x** Al 1+2x** O 4−4x** N 4x** :E, wherein 
     0&lt;x**&lt;0.875, MB is selected from a group of divalent metals which comprises Mg, Ca, Sr, Ba, Zn and combinations thereof, and E is selected from a group which comprises Eu, Mn, Ce, Yb and combinations thereof. 
     Embodiment 16 is the phosphor according to any of embodiments 1 to 5, which has the formula (MB) (Si 0.25 Al −/8+r**/2 Li 7/8−r**/2 ) 4 (O 1−r** N r** ) 4 :E, wherein 0.25≤r**≤1, MB is selected from a group of divalent metals which comprises Mg, Ca, Sr, Ba and combinations thereof, and E=Eu, Ce, Yb and/or Mn. 
     Embodiment 17 is a method for producing the phosphor according to any of embodiments 1 to 16 including the following method steps: 
     A) mixing starting materials of the phosphor, 
     B) heating the mixture obtained under A) to a temperature T 1  of between 500 and 1400° C., 
     C) annealing the mixture at a temperature T 1  of 500 to 1400° C. for 0.5 minute to ten hours. 
     LIST OF REFERENCE SIGNS 
     
         
         ppm Parts per million 
         λpeak Peak wavelength 
         λdom Dominant wavelength 
         AB Exemplary embodiment 
         g Gram 
         E Emission 
         mmol Millimol 
         Mol % Mol percent 
         R inf  Diffuse reflection 
         lm Lumen 
         W Watt 
         LER Luminous efficiency 
         LED Light-emitting diode 
         CRI Color rendering index 
         CCT Correlated color temperature 
         R9 Color rendering index 
         K/S Kubelka-Munk function 
         K Kelvin 
         cm Centimeter 
         nm Nanometer 
         °2θ Degree 2 Theta 
         I, II, III, IV, V, VI X-ray powder diffractogram 
         Ew White point 
         KL Conversion line 
         T Temperature 
         ° C. Degree Celsius