Patent Publication Number: US-5296016-A

Title: Surface coated cermet blade member

Description:
BACKGROUND OF THE INVENTION 
     1. Field of the Invention 
     The present invention relates to surface-coated cermet blade members, and particularly, those which exhibit excellent wear resistance in high-speed cutting operations and superior fracture resistance in interrupted cutting operations. 
     2. Prior Art 
     Known surface coated cermet blade members comprise: 
     a cermet substrate which consists, apart from unavoidable impurities, of a binder phase of one or more iron family metals such as cobalt (Co) or nickel (Ni), and a hard-dispersed phase of balance carbo-nitride represented by the formula (Ti,M) (C,N), wherein M denotes one or more elements selected from tantalum (Ta), niobium (Nb), vanadium (V), zirconium (Zr), tungsten (W), molybdenum (Mo) and chromium (Cr); and 
     a hard coating of an average thickness of 0.5 to 20 μm formed on the surface of the substrate, the hard coating being composed of a single layer of TiX or of Al 2  O 3 , or of multiple layers of TiX or Al 2  O 3 , wherein X denotes one or more elements selected from carbon (C), nitrogen (N), oxygen (O) and boron (B). 
     For example, Japanese Patent Application First Publication, Serial No. 53-131910 describes a cermet with a hard coating which has an average thickness of 0.5 to 20 μm and is composed of a single layer of a titanium compound such as TiCO or TiCNO, or of Al 2  O 3 , or of multiple layers of titanium compounds and/or Al 2  O 3 . Another Japanese Patent Application First Publication, Serial No. 56-62960 describes a surface-coated cermet in which a hard coating, composed of a single layer of a titanium compound such as TiN or TiCN, or of Al 2  O 3 , or of multiple layers of titanium compounds and/or Al 2  O 3 , is deposited on the surface of the cermet substrate through a TiC intermediate layer containing binder phase constituents distributed therein. Yet another Japanese Patent Application First Publication, Serial No. 63-134654 describes a hard coating composed of a single layer of a titanium compound such as TiC, TiN or TiCN, or of multiple layers of titanium compounds, the titanium compounds being in the form of grains having an average particle size of no greater than 0.5 μm. However, the surface coated cermets disclosed in these three references have the disadvantages that since the bonding strength between the hard coating and the cermet substrate is low, the hard coating is susceptible to separation, resulting in short tool life. 
     Furthermore, in Japanese Patent Application First Publication, Serial No. 2-4972, there is disclosed a surface coated blade member which comprises a cermet substrate having a surface portion composed only of hard-dispersed phase constituents, and has a hard coating deposited thereon, composed of a single layer of a titanium compound such as TiC, TiN or TiCN, or of multiple layers of titanium compounds. However, since no binder phase constituents exist in the surface portion of the cermet substrate, the blade member is susceptible to fracture. 
     Moreover, Japanese Patent Application First Publication, Serial No. 2-22455 discloses a surface coated cermet blade member which comprises a cermet substrate in which the ratio C/C+N is greater at the surface portion than at interior portions, and a hard coating which is composed of a single layer of a titanium compound such as TiC, TiN or TiCN, or of multiple layers of titanium compounds. However, this blade member is also inferior in fracture resistance because the carbon content is great at the surface portion. 
     Thus, although various types of surface-coated cermet blade members have been developed in recent years, their ability to withstand higher cutting speed and the increasingly severe demands of the interrupted cutting operations have not kept pace with the requirements imposed by attempts to reduce labor over head and to improve efficiency. The prior art cermet blade members as described above lack sufficient wear resistance during high-speed cutting operations and are not sufficiently resistant to fracturing during interrupted cutting operations, as a result of which, tool life is reduced. 
     SUMMARY OF THE INVENTION 
     It is therefore the object of the present invention to provide a surface coated cermet blade member which exhibits excellent performance even when used for high-speed cutting and interrupted cutting operations under severe conditions. 
     According to the invention, there is provided a surface coated cermet blade member comprising: 
     a substrate of cermet which consists, apart from unavoidable impurities, of a binder phase of 5 to 30% by weight of at least one element selected from the group consisting of cobalt, nickel, iron and aluminum, and a hard dispersed phase of a balance carbo-nitride of metals, the metals being titanium, tungsten and at least one additional metal selected from the group consisting of tantalum, niobium, vanadium, zirconium, molybdenum and chromium, the substrate including a surface portion of less than 1 mm deep from a surface thereof and an interior portion of no less than 1 mm deep from the surface, the surface portion having greater hardness than said interior portion; and 
     a hard coating of an average thickness of 0.5 to 20 μm deposited on the substrate, the hard coating being composed of at least one coating layer formed of a coating compound selected from the group consisting of TiX and Al 2  O 3 , where X denotes at least one element selected from the group consisting of carbon, nitrogen, oxygen and boron. 
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS 
     FIG. 1 is a graphical representation showing a relationship between the depth from a substrate surface and the Vickers hardness regarding surface coated blade members of the present invention; and 
     FIG. 2 is a graphical representation similar to FIG. 1, but showing comparative blade members. 
    
    
     DETAILED DESCRIPTION OF THE INVENTION 
     The inventors have made an extensive study in order to obtain a surface coated cermet blade member which meets the requirements as described above. As a result, they have come to know that when the hardness of the portion of the cermet substrate near the substrate surface is enhanced so as to be greater than the interior portion inside the surface portion, the bonding strength between the hard coating and the hard surface portion can be enhanced and the resulting surface coated blade member has extremely high fracture and wear resistances in high-speed cutting and interrupted cutting operations under very severe conditions. 
     The present invention is based on the above findings, and provides a surface coated cermet blade member which comprises a cermet substrate consisting, apart from unavoidable impurities, of a binder phase of 5 to 30% by weight of at least one element selected from the group consisting of cobalt, nickel, iron and aluminum, and a hard dispersed phase of a balance composite carbo-nitride of metals, the metals being titanium, tungsten and at least one additional metal selected from the group consisting of tantalum, niobium, vanadium, zirconium, molybdenum and chromium, the substrate including a surface portion having greater hardness than the interior portion, and, a hard coating formed on the cermet substrate having an average thickness of 0.5 to 20 μm and is composed of a single coating layer of TiX or Al 2  O 3  or of plural coating layers of TiX and/or Al 2  O 3 , where X denotes at least one element selected from the group consisting of carbon, nitrogen, oxygen and boron. 
     In the foregoing, the term &#34;a surface portion&#34; is defined as a portion near the surface of the cermet substrate which is less than 1 mm, preferably less than 100 μm deep from the surface thereof, while the term &#34;an interior portion&#34; is defined as a portion inside the surface portion which is no less than 1 mm deep from the surface. The hardnesses for the surface portion and the interior portion can be measured using Vickers or Rockwell hardness tester after having determined the measuring points. 
     The surface coated blade member of the aforesaid construction is produced by first preparing a green compact which contains, apart from unavoidable impurities, 5 to 30% by weight of at least one binder phase constituent selected from the group consisting of cobalt, nickel, iron and aluminum, and a balance hard dispersed phase constituent of metal carbo-nitride. The green compact is heated from room temperature to an elevated temperature of 1,100° to 1,400° C. in a vacuum. Subsequently, nitrogen gas is introduced at the above temperature range, and the sintering operation is effected in the nitrogen atmosphere at such a reduced pressure that the substrate surface is denitrified, i.e., at a nitrogen partial pressure of 5 to 100 torr. Then, the last stage of the sintering operation and the subsequent cooling operation are carried out in a non-oxidizing atmosphere such as a vacuum or an inert gas atmosphere. With these procedures, a cermet substrate, of which surface portion has hardness greater than the interior portion, can be successfully obtained. The cermet substrate thus formed is then coated by means of chemical vapor deposition (CVD) or physical vapor deposition (PVD) to form a hard coating of one or more layers of the aforesaid compositions. 
     In the foregoing, when the sintering operation is effected in nitrogen atmosphere at a suitably reduced pressure so that the substrate surface is denitrified, and the subsequent cooling operation is carried out in a non-oxidizing atmosphere such as a vacuum or an inert gas atmosphere, the surface portion of the resulting cermet substrate comes to have less binding metals such as cobalt or nickel but more tungsten compared with the interior portion, this tungsten having higher strength than titanium. Therefore, in the resulting surface coated blade member, the bonding strength between the hard coating and the hard surface portion of the substrate can be enhanced, and the fracture and wear resistances greatly increased. Furthermore, in the case where the sintering operation is effected in a less denitrifying atmosphere, e.g., atmosphere of higher nitrogen pressure or of lower sintering temperature, prior to the cooling operation in a non-oxidizing atmosphere, a thin surface layer composed only of core structures free from surrounding structures may exist at an outermost portion which is no greater than 10 μm deep. In such a case, the binding metal phase is rich in the above outermost portion and becomes the lowest immediately beneath the outermost portion in the surface portion, while the amount of the binding phase at the interior is close to that of the blended mixture before the sintering. Thus, strictly speaking, it is presumably considered that the hardness is low at the outermost surface portion but the greatest immediately beneath the outermost portion in the surface portion, and the interior portion has the hardness which the cermet substrate intrinsically possesses. However, even though the outermost portion has a significant binding metal phase and is low in hardness, the blade member has high fracture and wear resistances because the thickness of the outermost portion is very thin and the surface portion beneath the outermost portion has the greatest hardness. 
     Furthermore, when the cooling speed in vacuum is decreased, the binding metal phase may effuse on the cermet surface to a thickness of 0.5 to 3 μm. However, even in this case, the cobalt distribution and the hardness gradient are the same as described above, so that the purposes of the invention can be adequately attained. 
     In addition, the cermet substrate obtained by the sintering operation as described above may be ground prior to the chemical or physical vapor deposition of hard coating. Furthermore, in the case where the physical vapor deposition process is applied, metal titanium may be coated on the substrate prior to the coating of TiC, TiN, TiCN and so on. In this case, the thickness of the metal titanium layer should be preferably no greater than 1 μm. 
     Furthermore, in the case where the chemical vapor deposition process is applied, it is preferable that the coating is carried out at low temperature. This is because the binding metal in the substrate diffuses into the hard coating when the coating is carried out at high temperature, so that the wear resistance is unduly lowered. 
     Moreover, in the surface coated cermet blade member in accordance with the present invention, it is necessary to include 5 to 30% by weight of at least one element selected from the group consisting of cobalt, nickel, iron and aluminum as a binder phase constituent. However, in order to balance the wear and fracture resistances, it is preferable that the amount of the above element should be from 10 to 20% by weight. Similarly, although the average thickness of the hard coating is determined so as to be from 0.5 to 20 μm, it is preferable that it ranges from 2 to 10 μm. The bonding strength of the hard coating is influenced by the cermet substrate, especially by the hardness of the surface portion of the substrate, and it is preferable that the hardness of the surface portion be close to the hardness of the hard coating, which is composed of a single layer of titanium compound such as TiC, TiN or TiCN, or of Al 2  O 3 , or of multiple layers of titanium compound such as TiC, TiN or TiCN, and/or Al 2  O 3 . When the hardness of the surface portion of the cermet substrate is low, there occurs discontinuity in hardness. Therefore, when the blade member undergoes an impact during the cutting operation such as interrupted cutting, the surface portion of the cermet substrate is deformed, and the hard coating becomes separated from the substrate. Furthermore, if the hardness of the interior portion of the substrate is unduly great, the toughness becomes insufficient, resulting in lowering of the resistance to propagation of cracks. Therefore, when used under severe cutting conditions such as in interrupted cutting, the blade member is unfavorably subjected to fracture. For these reasons, it is preferable that the maximum Vickers hardness at a load at 100 g in the surface portion of the substrate is no less than 2000 while Vickers hardness in the interior portion thereof is less than 2000. In addition, it is preferable that the hardness of the surface portion is the maximum between the substrate surface and a depth of 100 μm. 
     As described above, the surface coated blade member in accordance with the present invention exhibits excellent wear and fracture resistances even when used in continuous and interrupted cutting operations under severe cutting conditions, and hence can be put into practical use for a prolonged period of time. 
     The present invention will now be described in detail with reference to the following examples. 
     EXAMPLE 1 
     Starting powders of TiCN, TiC, TiN, TaC, NbC, WC, Mo 2  C, VC, Co, Ni and NiAl were prepared, each of which had an average particle size of 1.5 μm. These powders were blended in various blend compositions depicted in Tables 1 and 2 and were subjected to wet mixing in a ball mill for 72 hours. After being dried, the mixtures were pressed into green compacts under a pressure of 1.5 ton/cm 2 , and the green compacts were sintered under the sintering conditions set forth in Tables 3 and 4 to produce cermet substrates A to M and a to m. Subsequently, the cermet substrates were coated with hard coatings as set forth in Tables 5 and 6 by means of coating methods shown in the same Tables to produce surface coated blade members 1 to 14 of the invention and comparative surface coated blade members 1 to 14. 
     Then, as to each of the above blade members, the hardness of the surface portion at a portion 20 μm deep from the substrate surface and at the interior portion 1 mm deep from the substrate surface were measured using Vickers hardness tester under a load of 100 g. The results are shown in Tables 7 and 8. 
     Furthermore, as to the surface coated blade members 3, 11 and 13 of the invention and the comparative surface coated blade members 3, 11 and 13, the Co, Ni and W contents were measured at the surface portion 20 μm deep from the substrate surface and at the interior portion 1 mm deep from the substrate surface. The results are shown in Table 9. 
     In addition, the structure of each blade member was observed. In the observation of the blade member 3 of the invention, it was found that the binding metals such as Co or Ni were exuded immediately beneath the hard coating, i.e., on the surface of the cermet substrate. The hard-dispersed phase was somewhat coarse at the surface portion compared with that at the interior portion. As to the blade member 11 of the invention, the hard dispersed phase of the surface portion was more coarse than that of the interior portion. In the blade member 13 of the invention, an outermost portion composed only of core structures free from surrounding structures was found immediately under the hard coating, i.e., on the substrate surface, in a thickness of 2 to 3 μm, and the hard dispersed phase beneath the outermost portion was more coarse than the interior portion. 
     With respect to each of the comparative blade members 3, 11 and 13, although the substrate surface was somewhat uneven, there was no significant difference in structure between the surface portion and the interior portion. 
     Moreover, as to the surface coated blade members 3, 11 and 13 of the invention and the comparative blade members 3, 11 and 13, the hardness distribution was measured for the portion from the substrate surface to the depth of 2 mm. The results are shown in FIGS. 1 and 2. The hardness of the portion from the substrate surface to the depth of less than 10 μm could not be measured due to the size of Vickers indentation, so that only the hardness distribution from the depth of 10 μm to the depth of 2 mm is shown. As will be seen from the results, the portion having the maximum hardness should exist between the substrate surface and a depth of 10 μm for each of the blade members 3 and 11 of the invention. In the blade member 13 of the invention, the hardest portion existed at a portion of a depth near 20 μm. On the other hand, in the comparative blade members 3, 11 and 13, no distinct maximum hardness was observed. 
     Subsequently, cutting inserts having ISO standards of CNMG 120408 were prepared using the above blade members 1 to 14 of the invention and comparative blade members 1 to 14. In order to evaluate wear resistance characteristics, each insert was then subjected to a high-speed cutting test under the following conditions: 
     Workpiece: round bar of steel (JIS.SCM415; Brinell Hardness: 140) 
     Cutting speed: 300 m/minute 
     Feed rate: 0.2 mm/revolution 
     Depth of cut: 1.0 mm 
     Cutting time: 30 minutes 
     In this test, the flank wear width for the cutting edge was measured, and the results are set forth in Tables 7 and 8. 
     Furthermore, in order to evaluate fracture resistance characteristics, the above cutting inserts were subjected to a high-speed interrupted cutting test under the following conditions: 
     Workpiece: grooved round bar of steel (JIS.SCM440; Brinell Hardness: 220) 
     Cutting speed: 220 m/minute 
     Feed rate: 0.18 mm/revolution 
     Depth of cut: 1.0 mm 
     Cutting time: 3 minutes 
     In this test, the number of inserts subjected to fracture per tested inserts was determined. The results are again shown in Tables 7 and 8. 
     As will be seen from the results shown in Tables 1 to 9, in the surface coated blade members 1 to 14 of the invention, which were obtained by the sintering operation involving introducing nitrogen when the temperature is elevated in the range of 1,100°  to 1,400° C., regulating the amount of nitrogen so as to form an atmosphere which denitrifies the surface portion of the sintered product, and carrying out the last stage of the sintering and the cooling step in vacuum, the hardness is greater at the surface portion of the substrate than at the interior portion of the substrate. The blade members of this construction exhibit less flank wear width in the continuous cutting operations and are less susceptible to fracture in the interrupted cutting operation when compared with comparative blade members 1 to 14, each of which comprises a substrate surface portion having a hardness generally equal to that of the interior portion. 
     EXAMPLE 2 
     The cermet substrate K of the invention and the comparative cermet substrate k of Example 1 were shaped into inserts having ISO standards of TNGA 160408. Then, a hard coating composed of TiN(0.5 μm)-TiCN(3 μm)-TiN(0.5 μm) was formed thereon to provide surface coated blade members 15 to 19 of the invention and a comparative blade member 15. 
     As to each blade member thus formed, the Vickers hardness (load: 100 g) was measured for the surface portion of 20 μm in depth from the surface and the interior portion of 1 mm in depth from the surface. The results are shown in Table 10. 
     Subsequently, in order to evaluate the wear and fracture resistances, the resulting blade members were subjected to the same cutting tests as in Example 1. The results are set forth in Table 10. 
     As will be seen from Table 10, in each of the surface coated blade members 15 to 19 of the invention, the surface portion at a depth of 20 μm has a hardness greater than the interior portion at a depth of 1 mm, while in the comparative blade member 15, the hardness is equal both at the surface portion and the interior portion. Furthermore, even though a part of the surface portion of the substrate is ground, the surface coated blade members 15 to 19 of the invention exhibit less flank wear width in the continuous cutting operation when compared with the comparative blade member 15. 
     
                                           TABLE 1                                 
__________________________________________________________________________
       Blend composition (% by weight)                                    
       TiCN                                                               
           TiC TiN                                                        
                  TaC                                                     
                     NbC                                                  
                        WC Mo.sub.2 C                                     
                               VC Co                                      
                                    Ni Other                              
__________________________________________________________________________
Cermet                                                                    
     A 67  --  -- 9  --  9 9   -- --                                      
                                    6  --                                 
substrate                                                                 
     B 74  --  -- 9  --  9 --  -- --                                      
                                    8  --                                 
     C 58  --  -- 9  1   9 9   -- 9 5  --                                 
     D 59  --  -- 9  -- 14 --  -- 9 9  --                                 
     E --  32  27 5  3  15 10  2  9 5  NbN:2                              
     F --    28.8                                                         
               29 9  -- 10 9   -- 9 5  Al:0.2                             
     G 57  --  -- 5  -- 13 7   -- --                                      
                                    14 TaN:4                              
     H --  29  34 9  1   9 9   -- 9 5  --                                 
     I 48  --  10 6  4  11 7   -- 7 7  --                                 
     J --  27  27 9  1  13 9   -- 9 5  --                                 
     K 63  --  -- 9  1  13 9   -- 9 5  --                                 
     L 58  --  -- 9  1   9 9   -- 9 5  --                                 
     M 53  --   5 9  1   9 9   -- 9 5  --                                 
     N 49  --   9 9  1   9 9   -- 9 5  --                                 
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                                           TABLE 2                                 
__________________________________________________________________________
       Blend composition (% by weight)                                    
       TiCN                                                               
           TiC TiN                                                        
                  TaC                                                     
                     NbC                                                  
                        WC Mo.sub.2 C                                     
                               VC Co                                      
                                    Ni Other                              
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Cermet                                                                    
     a 67  --  -- 9  --  9 9   -- --                                      
                                    6  --                                 
substrate                                                                 
     b 74  --  -- 9  --  9 --  -- --                                      
                                    8  --                                 
     c 58  --  -- 9  1   9 9   -- 9 5  --                                 
     d 59  --  -- 9  -- 14 --  -- 9 9  --                                 
     e --  32  27 5  3  15 10  2  9 5  NbN:2                              
     f --    28.8                                                         
               29 9  -- 10 9   -- 9 5  Al:0.2                             
     g 57  --  -- 5  -- 13 7   -- --                                      
                                    14 TaN:4                              
     h --  29  34 9  1   9 9   -- 9 5  --                                 
     i 48  --  10 6  4  11 7   -- 7 7  --                                 
     j --  27  27 9  1  13 9   -- 9 5  --                                 
     k 63  --  -- 9  1  13 9   -- 9 5  --                                 
     l 58  --  -- 9  1   9 9   -- 9 5  --                                 
     m 53  --   5 9  1   9 9   -- 9 5  --                                 
     n 49  --   9 9  1   9 9   -- 9 5  --                                 
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                                           TABLE 3                                 
__________________________________________________________________________
                                             Degree of vacuum             
       Temperature of                                                     
                 N.sub.2 partial                                          
                       Sintering                                          
                              Holding time                                
                                     Switching time                       
                                             during sintering             
       N.sub.2 to be introduced                                           
                 pressure                                                 
                       temperature                                        
                              for sintering                               
                                     to vacuum*                           
                                             and cooling                  
       (°C.)                                                       
                 (Torr)                                                   
                       (°C.)                                       
                              (min)  (min)   (Torr)                       
__________________________________________________________________________
Cermet                                                                    
     A 1300      20    1570   90     80      0.1                          
substrate                                                                 
     B 1300      15    1570   90     80      0.1                          
     C 1300      30    1530   90     60      0.5                          
     D 1300      15    1490   60     40      0.1                          
     E 1200      30    1530   90     60      0.2                          
     F 1150      50    1530   90     80      0.2                          
     G 1300      15    1530   90     80      0.2                          
     H 1200      100   1530   90     70      0.1                          
     I 1350      30    1550   90     80      0.2                          
     J 1100      50    1530   90     70      0.1                          
     K 1300      40    1550   90     80      0.1                          
     L 1300      30    1530   90     80      0.2                          
     M 1300      40    1500   90     80      0.2                          
     N 1300      50    1550   90     80      0.2                          
__________________________________________________________________________
 *denotes time from the start of the holding operation                    
 
    
     
                                           TABLE 4                                 
__________________________________________________________________________
                                             Degree of vacuum             
       Temperature of                                                     
                 N.sub.2 partial                                          
                       Sintering                                          
                              Holding time                                
                                     Switching time                       
                                             during sintering             
       N.sub.2 to be introduced                                           
                 pressure                                                 
                       temperature                                        
                              for sintering                               
                                     to vacuum                            
                                             and cooling                  
       (°C.)                                                       
                 (Torr)                                                   
                       (°C.)                                       
                              (min)  (min)   (Torr)                       
__________________________________________________________________________
Cermet                                                                    
     a --           0.01                                                  
                       1550   90     --      0.01                         
substrate        (vacuum)                                                 
     b --           0.01                                                  
                       1550   90     --      0.01                         
                 (vacuum)                                                 
     c 1300      120   1530   90     --      N.sub.2 30                   
     d 1300      140   1490   60     --      N.sub.2 40                   
     e 1200      160   1530   90     --      N.sub.2 50                   
     f 1150      200   1530   90     --      N.sub.2 60                   
     g 1300      140   1530   90     --      N.sub.2 40                   
     h 1200      200   1530   90     --      N.sub.2 60                   
     i 1350      160   1530   90     --      N.sub.2 50                   
     j 1100      200   1530   90     --      N.sub.2 60                   
     k 1300      160   1550   90     --      N.sub.2 50                   
     l 1300      160   1530   90     --      N.sub.2 50                   
     m 1300      160   1500   90     --      N.sub.2 50                   
     n 1300      200   1550   90     --      N.sub.2 60                   
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                       TABLE 5                                                     
______________________________________                                    
                                 Coat-                                    
Sub-        Hard coating**       ing                                      
strate      ←Lower layer Upper layer→                         
                                 method                                   
______________________________________                                    
Blade  1    A       TiN(2)             PVD                                
mem-   2    B       TiCN(2)-TiN(1)     PVD                                
bers   3    C       TiN(0.5)-TiC(1)-TiCN(1)-TiN(0.5)                      
                                       CVD                                
of the                                                                    
       4    D       TiC(2)-TiCNO(1)-Al.sub.2 O.sub.3 (1)                  
                                       CVD                                
inven-                                                                    
       5    E       TiC(1)-TiCN(1)-TiN(1)                                 
                                       CVD                                
tion   6    F       Ti(0.2)-(Ti, Al)N(3)-TiN(0.5)                         
                                       PVD                                
       7    G       TiN(0.5)-(Ti, Al)N(2)-TiN(0.5)                        
                                       PVD                                
       8    H       Ti(0.2)-TiN(4)     PVD                                
       9    I       TiN(0.5)-TiCN(2)-TiN(0.5)                             
                                       PVD                                
      10    J       TiN(0.5)-TiCN(2)-TiN(0.5)                             
                                       PVD                                
      11    K       TiN(0.5)-TiCN(2)-TiN(0.5)                             
                                       PVD                                
      12    L       TiN(0.5)-TiCN(3)-TiN(0.5)                             
                                       CVD                                
      13    M       TiN(0.5)-TiCN(3)-TiN(0.5)                             
                                       CVD                                
      14    N       Ti(0.2)-TiN(1)-TiCN(2)-TiN(0.5)                       
                                       PVD                                
______________________________________                                    
 **Value in parentheses indicates thickness (μm) of each layer         
 
    
     
                       TABLE 6                                                     
______________________________________                                    
                                 Coat-                                    
Sub-        Hard coating**       ing                                      
strate      ←Lower layer Upper layer→                         
                                 method                                   
______________________________________                                    
Com-   1    a       TiN(2)             PVD                                
para-  2    b       TiCN(2)-TiN(1)     PVD                                
tive   3    c       TiN(0.5)-TiC(1)-TiCN(1)-TiN(0.5)                      
                                       CVD                                
blade  4    d       TiC(2)-TiCNO(1)-Al.sub.2 O.sub.3 (1)                  
                                       CVD                                
mem-   5    e       TiC(1)-TiCN(1)-TiN(1)                                 
                                       CVD                                
bers   6    f       Ti(0.2)-(Ti, Al)N(3)-TiN(0.5)                         
                                       PVD                                
       7    g       TiN(0.5)-(Ti, Al)N(2)-TiN(0.5)                        
                                       PVD                                
       8    h       Ti(0.2)-TiN(4)     PVD                                
       9    i       TiN(0.5)-TiCN(2)-TiN(0.5)                             
                                       PVD                                
      10    j       TiN(0.5)-TiCN(2)-TiN(0.5)                             
                                       PVD                                
      11    k       TiN(0.5)-TiCN(2)-TiN(0.5)                             
                                       PVD                                
      12    l       TiN(0.5)-TiCN(3)-TiN(0.5)                             
                                       CVD                                
      13    m       TiN(0.5)-TiCN(3)-TiN(0.5)                             
                                       CVD                                
      14    n       Ti(0.2)-TiN(1)-TiCN(2)-TiN(0.5)                       
                                       PVD                                
______________________________________                                    
 **Value in parentheses indicates thickness (μm) of each layer         
 
    
     
                                           TABLE 7                                 
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            Vickers hardness                                              
            Surface portion                                               
                     Interior portion                                     
                              Continuous cutting                          
            at depth of 20 μm                                          
                     at depth of 1 mm                                     
                              Flank wear                                  
                                        Interrupted cutting               
       Cermet                                                             
            from the substrate                                            
                     from the substrate                                   
                              width     Fractured inserts/                
       substrate                                                          
            surface  surface  (mm)      tested inserts                    
__________________________________________________________________________
Blade                                                                     
      1                                                                   
       A    2450     1930     0.12      4/10                              
members                                                                   
      2                                                                   
       B    2330     1860     0.16      3/10                              
of the                                                                    
      3                                                                   
       C    2310     1630     0.17      1/10                              
invention                                                                 
      4                                                                   
       D    2310     1520     0.18      4/10                              
      5                                                                   
       E    2230     1700     0.22      3/10                              
      6                                                                   
       F    2270     1600     0.20      0/10                              
      7                                                                   
       G    2280     1580     0.19      2/10                              
      8                                                                   
       H    2200     1720     0.24      0/10                              
      9                                                                   
       I    2210     1640     0.23      3/10                              
     10                                                                   
       J    2240     1580     0.21      0/10                              
     11                                                                   
       K    2350     1570     0.15      0/10                              
     12                                                                   
       L    2320     1630     0.17      1/10                              
     13                                                                   
       M    2260     1630     0.17      1/10                              
     14                                                                   
       N    2300     1600     0.18      0/10                              
__________________________________________________________________________
 
    
     
                                           TABLE 8                                 
__________________________________________________________________________
              Vickers hardness                                            
              Surface portion                                             
                       Interior portion                                   
                                Continuous cutting                        
              at depth of 20 μm                                        
                       at depth of 1 mm                                   
                                Flank wear                                
                                          Interrupted cutting             
         Cermet                                                           
              from the substrate                                          
                       from the substrate                                 
                                width     Fractured inserts/              
         substrate                                                        
              surface  surface  (mm)      tested inserts                  
__________________________________________________________________________
Comparative                                                               
        1                                                                 
         a    1830     1850     0.30      10/10                           
Blade   2                                                                 
         b    1780     1790     0.38      10/10                           
members                                                                   
        3                                                                 
         c    1610     1620     0.45      7/10                            
        4                                                                 
         d    1530     1520     0.62      7/10                            
        5                                                                 
         e    1680     1680     0.48      9/10                            
        6                                                                 
         f    1600     1600     0.44      7/10                            
        7                                                                 
         g    1570     1560     0.58      8/10                            
        8                                                                 
         h    1700     1700     0.45      8/10                            
        9                                                                 
         i    1620     1620     0.52      10/10                           
       10                                                                 
         j    1560     1570     0.60      7/10                            
       11                                                                 
         k    1550     1550     0.62      7/10                            
       12                                                                 
         l    1590     1600     0.45      8/10                            
       13                                                                 
         m    1580     1590     0.47      8/10                            
       14                                                                 
         n    1600     1600     0.55      7/10                            
__________________________________________________________________________
 
    
     
                       TABLE 9                                                     
______________________________________                                    
Contents of constituents (% by weight)                                    
Co           Ni            W                                              
Sur-             Sur-            Sur-                                     
face    Interior face     Interior                                        
                                 face   Interior                          
portion portion  portion  portion                                         
                                 portion                                  
                                        portion                           
______________________________________                                    
Blade members of the invention                                            
 3  4.9     8.5      2.7    4.7    13.2   8.3                             
11  4.8     8.4      2.6    4.6    19.5   12.3                            
13  4.8     8.4      2.7    4.7    13.3   8.3                             
Comparative blade members                                                 
 3  9.1     8.9      5.1    5.0     8.8   8.9                             
11  9.1     9.0      5.0    4.9    12.9   13.1                            
13  9.0     8.9      4.9    4.9     9.0   9.0                             
______________________________________                                    
 
    
     
                                           TABLE 10                                
__________________________________________________________________________
                    Vickers hardness  Continuous                          
         Ground surface                                                   
                    Surface portion                                       
                             Interior portion                             
                                      cutting                             
                                            Interrupted                   
         and amount at depth of 20 μm                                  
                             at depth of 1 mm                             
                                      Flank wear                          
                                            cutting                       
         Flank                                                            
             Rake surface                                                 
                    from the substrate                                    
                             from the substrate                           
                                      width Fractured inserts/            
         (μm)                                                          
             (μm)                                                      
                    surface  surface  (mm)  tested inserts                
__________________________________________________________________________
Blade  15                                                                 
          75 none   1880     1570     0.21  0/10                          
members                                                                   
       16                                                                 
         120 none   1680     1570     0.25  0/10                          
of the 17                                                                 
         none                                                             
              50    1990     1570     0.19  0/10                          
invention                                                                 
       18                                                                 
         none                                                             
             100    1720     1570     0.20  0/10                          
       19                                                                 
          50  50    1990     1570     0.22  0/10                          
Comparative                                                               
       15                                                                 
         500 500    1550     1550     0.37  0/10                          
blade                                                                     
members                                                                   
__________________________________________________________________________