Patent Publication Number: US-2022239274-A1

Title: Resonator Device And Method For Manufacturing Resonator Device

Description:
The present application is based on, and claims priority from JP Application Serial Number 2021-010083, filed Jan. 26, 2021, the disclosure of which is hereby incorporated by reference herein in its entirety. 
     BACKGROUND 
     1. Technical Field 
     The present disclosure relates to a resonator device and a method for manufacturing a resonator device. 
     2. Related Art 
     A semiconductor substrate described in JP-T-2014-519201 includes a silicon substrate, an insulating layer formed on the silicon substrate, a conductive pad formed on the insulating layer, and a through electrode penetrating the silicon substrate and the insulating layer and coupled to the conductive pad. A method for forming a through electrode includes forming a through hole in a silicon substrate by dry etching, forming a through hole in an insulating layer by wet etching, and filling the through holes with a metal material. 
     As described above, in the method for forming a through electrode in JP-T-2014-519201, the through hole is formed in the insulating layer by the wet etching. However, the wet etching is isotropic etching. Therefore, there is a problem that side etching occurs in the insulating layer, and the metal material enters a void unintentionally generated by the side etching, which may cause a pattern failure of a wiring (hereinafter, also referred to as “the wiring pattern failure due to the side etching”). 
     SUMMARY 
     A resonator device according to the present disclosure includes: a base; and a resonator component disposed on the base, in which the base includes a semiconductor substrate having a first surface and a second surface that are in a front-to-back relation with each other; an integrated circuit that includes a wiring layer disposed at the second surface side and including a connection pad and includes an insulating layer disposed between the second surface and the wiring layer; a through electrode that penetrates the semiconductor substrate and the insulating layer and is coupled to the connection pad; and an annular metal layer that is disposed so as to penetrate the insulating layer between the second surface and the wiring layer, and surrounds the through electrode in a plan view of the semiconductor substrate. 
     A method for manufacturing a resonator device according to the present disclosure includes: a base preparation step of preparing a base that includes a semiconductor substrate having a first surface and a second surface that are in a front-to-back relation with each other, an integrated circuit that includes a wiring layer disposed at the second surface side and including a connection pad and includes an insulating layer disposed between the second surface and the wiring layer, and an annular metal layer that is disposed so as to penetrate the insulating layer between the second surface and the wiring layer; and a through electrode forming step of forming a through electrode penetrating the semiconductor substrate and the insulating layer and coupled to the connection pad through an inside of the metal layer, in which the through electrode forming step includes a through hole forming step of forming a through hole from the first surface to the connection pad through the inside of the metal layer by penetrating the semiconductor substrate by dry etching and then penetrating the insulating layer by wet etching; and a conductive material arranging step of disposing a conductive material in the through hole to form the through electrode. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1  is a vertical cross-sectional view illustrating a resonator device according to a first embodiment. 
         FIG. 2  is a plan view illustrating an upper surface of a base. 
         FIG. 3  is a vertical cross-sectional view illustrating a metal layer surrounding a through electrode. 
         FIG. 4  is a horizontal cross-sectional view illustrating the metal layer surrounding the through electrode. 
         FIG. 5  is a plan view illustrating a resonator component. 
         FIG. 6  is a flowchart illustrating manufacturing steps of a resonator device. 
         FIG. 7  is a vertical cross-sectional view illustrating a method for manufacturing a resonator device. 
         FIG. 8  is a vertical cross-sectional view illustrating the method for manufacturing the resonator device. 
         FIG. 9  is a vertical cross-sectional view illustrating the method for manufacturing the resonator device. 
         FIG. 10  is a vertical cross-sectional view illustrating the method for manufacturing the resonator device. 
         FIG. 11  is a vertical cross-sectional view illustrating the method for manufacturing the resonator device. 
         FIG. 12  is a vertical cross-sectional view illustrating the method for manufacturing the resonator device. 
         FIG. 13  is a vertical cross-sectional view illustrating the method for manufacturing the resonator device. 
         FIG. 14  is a vertical cross-sectional view illustrating the method for manufacturing the resonator device. 
         FIG. 15  is a vertical cross-sectional view illustrating a resonator device according to a second embodiment. 
         FIG. 16  is a horizontal cross-sectional view illustrating a metal layer included in a resonator device according to a third embodiment. 
     
    
    
     DESCRIPTION OF EXEMPLARY EMBODIMENTS 
     Hereinafter, preferred embodiments of a resonator device are described with reference to the accompanying drawings. Further, for convenience of illustration, an upper side of a paper surface in  FIGS. 1, 3, and 7 to 15  is also referred to as “upper”, and a lower side of the paper surface is also referred to as “lower”. 
     First Embodiment 
       FIG. 1  is a vertical cross-sectional view illustrating a resonator device according to a first embodiment.  FIG. 2  is a plan view illustrating an upper surface of a base.  FIG. 3  is a vertical cross-sectional view illustrating a metal layer surrounding a through electrode.  FIG. 4  is a horizontal cross-sectional view illustrating the metal layer surrounding the through electrode.  FIG. 5  is a plan view illustrating a resonator component.  FIG. 6  is a flowchart illustrating manufacturing steps of a resonator device.  FIGS. 7 to 14  are vertical cross-sectional views illustrating a method for manufacturing the resonator device.  FIG. 1  is a cross-sectional view taken along a line A-A in  FIG. 2 . 
     As illustrated in  FIG. 1 , a resonator device  1  includes a package  10  including an accommodating portion S, and a resonator component  4  accommodated in the accommodating portion S. The package  10  includes a base  2  on which the resonator component  4  is mounted, and a lid  3  covering the resonator component  4  and bonded to an upper surface of the base  2 . The base  2  includes a semiconductor substrate  5  and an integrated circuit  6  disposed on the semiconductor substrate  5 . 
     The semiconductor substrate  5  is a silicon substrate, in particular, a P-type silicon substrate. However, the semiconductor substrate  5  is not particularly limited, and may be an N-type silicon substrate. The semiconductor substrate  5  may be a semiconductor substrate other than the silicon substrate, for example, a Ge, GaP, GaAs, or InP semiconductor substrate. 
     The semiconductor substrate  5  is plate-shaped and has a first surface  5   a  and a second surface  5   b  that are in a front-to-back relation with each other. The first surface  5   a  is an upper surface, and the second surface  5   b  is a lower surface. An insulating film  50  made of silicon oxide (SiO 2 ) is formed on a surface of the semiconductor substrate  5 . However, the insulating film  50  is not particularly limited, and may be, for example, an organic insulating film. 
     The integrated circuit  6  electrically coupled to the resonator component  4  is formed at a second surface  5   b  side of the semiconductor substrate  5 . By forming the integrated circuit  6  at the semiconductor substrate  5 , the semiconductor substrate  5  can be effectively utilized. In particular, by forming the integrated circuit  6  at the second surface  5   b  side, as compared with a case where the integrated circuit  6  is formed at a first surface  5   a  side, a wide space for forming the integrated circuit  6  can be secured since no bonding region with the lid  3  exists. 
     The integrated circuit  6  includes an oscillation circuit  6 A that is electrically coupled to the resonator component  4  and generates an oscillation signal such as a clock signal by oscillating the resonator component  4 . The integrated circuit  6  may include a circuit in addition to the oscillation circuit  6 A. Examples of the circuit include a processing circuit that processes an output signal from the oscillation circuit  6 A, and examples of such a processing circuit include a PLL circuit. 
     A stacked body  60  in which an etching stop layer  61 , an insulating layer  62 , a wiring layer  63 , an insulating layer  64 , a wiring layer  65 , an insulating layer  66 , a passivation film  67 , and a terminal layer  68  are stacked in this order is formed at the second surface  5   b  side. A plurality of active components (not illustrated) formed at the second surface  5   b  side via the wiring layers  63  and  65  are electrically coupled to form the integrated circuit  6 . The terminal layer  68  includes a plurality of mounting terminals  681 . The integrated circuit  6  is electrically coupled to an external device via the mounting terminals  681 . The number of the wiring layers provided in the stacked body  60  is not particularly limited, and may be one or three or more. 
     The base  2  is formed with a pair of through holes  21  and  22  that penetrate from the upper surface side of the base to the wiring layer  63  through the semiconductor substrate  5 , the etching stop layer  61 , and the insulating layer  62  in a thickness direction. As will be described in a method for manufacturing the resonator device  1  described later, the through holes  21  and  22  are formed by penetrating the semiconductor substrate  5  and the etching stop layer  61  by dry etching, and then penetrating the insulating layer  62  by wet etching. According to such a forming method, since the through holes  21  and  22  reach the wiring layer  63  during the wet etching, a plasma damage to the wiring layer  63  can be prevented. Since the semiconductor substrate  5  is penetrated by the dry etching, the through holes  21  and  22  having a high aspect ratio can be formed. Therefore, a reliability of the resonator device  1  can be improved and a size of the resonator device  1  can be reduced. 
     A conductive material E is filled in the through holes  21  and  22 , and through electrodes  210  and  220  are formed. The through electrodes  210  and  220  are electrically coupled to connection pads  631  and  632  of the wiring layer  63 , respectively. That is, the through electrodes  210  and  220  are coupled to the connection pads  631  and  632  included in the wiring layer  63 , located closest to the semiconductor substrate  5 , among the plurality of wiring layers  63  and  65  included in the integrated circuit  6 . Accordingly, the through electrodes  210  and  220  can be shortened as compared with a case of coupling to connection pads included in the wiring layer  65 . Therefore, the through electrodes  210  and  220  can be easily formed. However, the present disclosure is not limited thereto, and for example, the through electrodes  210  and  220  may be coupled to the connection pads included in the wiring layer  65 . 
     As illustrated in  FIG. 2 , a pair of wirings  28  and  29  electrically coupled to the resonator component  4  via metal bumps  81  and  82  are disposed at the first surface  5   a  side of the semiconductor substrate  5 . The wiring  28  is electrically coupled to the integrated circuit  6  via the through electrode  210 , and the wiring  29  is electrically coupled to the integrated circuit  6  via the through electrode  220 . 
     As illustrated in  FIGS. 1 and 3 , the base  2  is formed with metal layers  691  and  692  disposed between the etching stop layer  61  and the wiring layer  63  so as to penetrate the insulating layer  62 . As illustrated in  FIG. 4 , each of the metal layers  691  and  692 , in a plan view of the semiconductor substrate  5 , has an annular shape surrounding the through electrodes  210  and  220 . The wiring layer  63  is provided with the connection pads  631  and  632  coupled to the through electrodes  210  and  220 , and in the plan view of the semiconductor substrate  5 , the metal layer  691  is included in the connection pad  631 , and the metal layer  692  is included in the connection pad  632 . Therefore, upper ends of the metal layers  691  and  692  penetrate the insulating layer  62  and come into contact with a lower surface of the etching stop layer  61 , and lower ends of the metal layers  691  and  692  penetrate the insulating layer  62  and come into contact with upper surfaces of the connection pads  631  and  632 . 
     As will be described in the method for manufacturing the resonator device  1  described later, such metal layers  691  and  692  function as guard rings which are etching stop layers when forming the through holes  21  and  22 . By providing the metal layers  691  and  692 , when the through holes  21  and  22  are formed in the insulating layer  62  by the wet etching, side etching to an outside of the metal layers  691  and  692  is restricted, and further unintended side etching can be prevented. Therefore, the wiring pattern failure due to the side etching can be prevented, and the resonator device  1  has a high reliability. 
     The lid  3 , similar to the semiconductor substrate  5 , is a silicon substrate. Accordingly, linear expansion coefficients of the semiconductor substrate  5  and the lid  3  are equal. Therefore, generation of a thermal stress due to thermal expansion is prevented, and the resonator device  1  has excellent resonating characteristics. In addition, since the resonator device  1  can be formed by a semiconductor process, the resonator device  1  can be manufactured with a high accuracy, and the size of the resonator device  1  can be reduced. However, the lid  3  is not particularly limited, and may use a semiconductor substrate other than silicon substrate, for example, a Ge, GaP, GaAs, or InP semiconductor substrate. For example, a substrate other than a metal substrate such as a kovar substrate, or a semiconductor substrate such as a glass substrate may be used. 
     As illustrated in  FIG. 1 , the lid  3  includes a bottomed recess  31  that opens in a lower surface of the lid  3  and accommodates the resonator component  4  therein. The lower surface of the lid  3  is bonded to the upper surface of the base  2  via a bonding member  7 . Accordingly, the accommodating portion S, which is a space accommodating the resonator component  4 , is formed between the lid  3  and the base  2 . In the present embodiment, the lid  3  and the base  2  are bonded by using diffusion bonding utilizing diffusion between metals. However, a bonding method between the lid  3  and the base  2  is not particularly limited. 
     The accommodating portion S is airtight and in a reduced pressure state, preferably in a state close to a vacuum. Accordingly, viscous resistance is reduced, and oscillation characteristics of the resonator component  4  are improved. However, an atmosphere of the accommodating portion S is not particularly limited, and may be, for example, an atmosphere in which an inert gas such as nitrogen or Ar is sealed, or may be in an atmospheric pressure state or a pressurized state instead of the reduced pressure state. 
     As illustrated in  FIG. 5 , the resonator component  4  includes a resonator substrate  41  and an electrode  42  disposed on a surface of the resonator substrate  41 . The resonator substrate  41  includes a thickness-shear resonation mode, and is formed by an AT-cut quartz crystal substrate in the present embodiment. Since the AT-cut quartz crystal substrate has cubic frequency-temperature characteristics, the AT-cut quartz crystal substrate is the resonator component  4  having excellent temperature characteristics. The electrode  42  includes an excitation electrode  421  disposed on an upper surface of the resonator substrate  41  and an excitation electrode  422  disposed on a lower surface so as to face the excitation electrode  421 . The electrode  42  includes a pair of terminals  423  and  424  disposed on the lower surface of the resonator substrate  41 , a wiring  425  that electrically couples the terminal  423  to the excitation electrode  421 , and a wiring  426  that electrically couples the terminal  424  to the excitation electrode  422 . 
     A configuration of the resonator component  4  is not limited to the above configuration. For example, the resonator component  4  may be a mesa shape in which a resonation region sandwiched between the excitation electrodes  421  and  422  protrudes from a periphery of the resonation region, or conversely, may be an inverted mesa shape in which the resonation region is recessed from the periphery of the resonation region. Bevel processing for grinding a periphery of the resonator substrate  41  and convex processing in which the upper surface and the lower surface are made as convex curve surfaces may be performed. 
     The resonator component  4  is not limited to one that resonates in the thickness-shear resonation mode, and for example, may be one in which a plurality of resonating arms are bent and resonate in an in-plane direction like a tuning fork type resonator component. That is, the resonator substrate  41  is not limited to one formed by the AT-cut quartz crystal substrate, and may be formed by a quartz crystal substrate other than the AT-cut quartz crystal substrate, for example, an X-cut quartz crystal substrate, a Y-cut quartz crystal substrate, a Z-cut quartz crystal substrate, a BT-cut quartz crystal substrate, an SC-cut quartz crystal substrate, and an ST-cut quartz crystal substrate. 
     A constituent material of the resonator substrate  41  is not limited to a quartz crystal, and may be formed by, for example, a lithium niobate, lithium tantalate, lithium tetraborate, langasite, potassium niobate, or gallium phosphate monocrystalline piezoelectric body, or may be formed by other monocrystalline piezoelectric bodies. Further, the resonator component  4  is not limited to a piezoelectric driven type resonator element, and may be an electrostatically driven type resonator element using an electrostatic force. 
     Such a resonator component  4  is located at the first surface  5   a  side of the semiconductor substrate  5 . The resonator component  4  is bonded to the base  2  by the pair of metal bumps  81  and  82 , and is electrically coupled to the wirings  28  and  29 . The metal bumps  81  and  82  are stud bumps, plated bumps, or the like. The method for coupling the resonator component  4  to the base  2  is not particularly limited, and for example, the resonator component  4  may be bonded to the base  2  by a conductive adhesive and may be electrically coupled to the wirings  28  and  29 . 
     A configuration of the resonator device  1  is described above. Next, a method for manufacturing the resonator device  1  will be described. The method for manufacturing the resonator device  1 , as illustrated in  FIG. 6 , includes a base preparation step S 1 , a through electrode forming step S 2 , a resonator component arranging step S 3 , and a lid arranging step S 4 . The through electrode forming step S 2  includes a through hole forming step S 21  and a conductive material arranging step S 22 . 
     Base Preparation Step S 1   
     First, as illustrated in  FIG. 7 , the base  2  is prepared. At this stage, the through electrodes  210  and  220  and the wirings  28  and  29  are not formed at the base  2 . That is, the base  2  includes the semiconductor substrate  5 , the integrated circuit  6  provided at the second surface  5   b  side of the semiconductor substrate  5 , and the annular metal layers  691  and  692  formed in the integrated circuit  6 . The etching stop layer  61  is made of silicon nitride (SiN), and the insulating layers  62  and  64  are made of silicon oxide (SiO 2 ). The wiring layers  63  and  65 , the terminal layer  68 , and the metal layers  691  and  692  are each made of aluminum (Al), and the passivation film  67  is made of polyimide. However, the constituent materials of the respective layers are not particularly limited as long as the layers can exhibit their functions. 
     Through Electrode Forming Step S 2   
     Through Hole Forming Step S 21   
     Next, as illustrated in  FIG. 8 , the through holes  211  and  221  that penetrate the semiconductor substrate  5  in the thickness direction are formed. The through holes  211  and  221  are formed by the dry etching, especially by a Bosch method. Accordingly, the through holes  211  and  221  having a high aspect ratio can be formed. The etching stop layer  61  functions as a stop layer for the dry etching. In particular, by forming the etching stop layer  61  with SiN (silicon nitride), the etching stop layer  61  has a high selectivity for the dry etching, and over-etching can be effectively prevented. Therefore, for example, the through holes  211  and  221  can be effectively prevented from reaching the wiring layer  63  and causing the plasma damage to the wiring layer  63 . As a result, the wiring pattern failure due to the dry etching can be prevented, and the resonator device  1  having a high reliability can be manufactured. 
     Next, as illustrated in  FIG. 9 , digging is performed from lower ends of the through holes  211  and  221  to form through holes  212  and  222  that penetrate the etching stop layer  61  in the thickness direction. The through holes  212  and  222  are formed by the dry etching. However, the present disclosure is not limited thereto, and the through holes  212  and  222  may be formed by the wet etching. 
     Next, as illustrated in  FIG. 10 , digging is performed from lower ends of the through hole  212  and  222  to form through holes  213  and  223  that pass through an inside of the metal layers  691  and  692  and penetrate the insulating layer  62  in the thickness direction. The through holes  213  and  223  are formed by the wet etching. By forming the through holes  213  and  223  by the wet etching, the plasma damage to the wiring layer  63  as in a case of forming the through holes  213  and  223  by the dry etching does not occur. Therefore, the wiring pattern failure due to the dry etching can be prevented. Instead, in the wet etching, the side etching may occur, resulting in the wiring pattern failure due to the wet etching. However, in the present embodiment, since the through holes  213  and  223  pass through the inside of the metal layers  691  and  692 , the metal layers  691  and  692  further restrict the side etching to the outside. Therefore, the unintended side etching is prevented. As a result, the wiring pattern failure due to the side etching is prevented, and the resonator device  1  having a high reliability can be manufactured. 
     In particular, in the present embodiment, in the plan view of the semiconductor substrate  5 , the metal layers  691  and  692  are included in the connection pads  631  and  632 , and the lower ends of the metal layers  691  and  692  come into contact with the upper surfaces of the connection pads  631  and  632 . Therefore, entering of an etching solution to the outside of the metal layers  691  and  692  can be effectively prevented, and the unintended side etching can be effectively prevented. As a result, the wiring pattern failure due to the wet etching can be more effectively prevented. 
     By the above steps, the through holes  21  and  22  are formed from the first surface  5   a  through the inside of the metal layers  691  and  692  to the connection pads  631  and  632  of the wiring layer  63 . According to the method for forming the through holes  21  and  22  as described above, the plasma damage to the wiring layer  63  and the wiring pattern failure due to the side etching can be prevented, and the through holes  21  and  22  having a high aspect ratio can be formed. Therefore, the highly reliable and compact resonator device  1  can be manufactured. 
     Conductive Material Arranging Step S 22   
     Next, as illustrated in  FIG. 11 , the insulating film is formed on the first surface  5   a  of the semiconductor substrate  5  and inner surfaces of the through holes  21  and  22 . The method for forming the insulating film  50  is not particularly limited, and for example, chemical vapor deposition (CVD) can be used. Next, as illustrated in  FIG. 12 , the insulating film  50  formed on bottom surfaces of the through holes  21  and  22  is removed by etching to expose the connection pads  631  and  632  in the through holes  21  and  22 . 
     Next, the conductive material E is disposed in a film shape on the first surface  5   a  and filled in the through holes  21  and  22 . Then, the conductive material E on the first surface  5   a  is patterned by etching. Accordingly, as illustrated in  FIG. 13 , the wirings  28  and  29  and the through electrodes  210  and  220  are collectively formed. The conductive material E is not particularly limited, and for example, the same material as the wiring layer  63  can be used. Accordingly, an affinity between the through electrodes  210  and  220  and the wiring layer  63  is enhanced, and contact failure or the like between the through electrodes  210  and  220  and the wiring layer  63  can be effectively prevented. Since the materials can be shared, manufacturing cost of the resonator device  1  can be reduced. However, the conductive material E is not particularly limited, and for example, a stacked structure of titanium-tungsten alloy (TiW)/copper (Cu)/gold (Au) may be used. 
     Resonator Component Arranging Step S 3   
     Next, the resonator component  4  is mounted on the wirings  28  and  29  via the metal bumps  81  and  82 . 
     Lid Arranging Step S 4   
     Next, the lid  3  is bonded to the upper surface of the base  2 . Accordingly, as illustrated in  FIG. 14 , the resonator device  1  is manufactured. 
     The resonator device  1  and the method for manufacturing the resonator device  1  are described in detail above. As described above, such a resonator device  1  includes the base  2  and the resonator component  4  disposed on the base  2 . The base  2  includes the semiconductor substrate  5  having the first surface  5   a  and the second surface  5   b  that are in the front-to-back relation with each other; the integrated circuit  6  that includes the wiring layer  63  disposed at the second surface  5   b  side and having the connection pads  631  and  632  and includes the insulating layer  62  disposed between the second surface  5   b  and the wiring layer  63 ; the through electrodes  210  and  220  that penetrate the semiconductor substrate  5  and the insulating layer  62  and are coupled to the connection pads  631  and  632 ; and the annular metal layers  691  and  692  that are disposed so as to penetrate the insulating layer  62  between the second surface  5   b  and the wiring layer  63  and surround the through electrodes  210  and  220  in the plan view of the semiconductor substrate  5 . According to the resonator device  1  having such a configuration, even if the through holes  213  and  223  penetrating the insulating layer  62  are formed by the wet etching, the metal layers  691  and  692  function as the guard rings, and further side etching is restricted. Therefore, for example, the plasma damage as in the case of the dry etching is not given to the wiring layer  63 , and the wiring pattern failure due to the side etching is prevented. Therefore, the resonator device  1  has a high reliability. 
     As described above, in the plan view of the semiconductor substrate  5 , the metal layers  691  and  692  are included in the connection pads  631  and  632 . As a result, the entering of the etching solution to the outside of the metal layers  691  and  692  can be more effectively prevented, and the wiring pattern failure due to the side etching can be more effectively prevented. 
     As described above, the integrated circuit  6  includes the plurality of wiring layers  63  and  65  stacked in the thickness direction of the semiconductor substrate  5 , and the through electrodes  210  and  220  are coupled to the connection pads  631  and  632  included in the wiring layer  63 , located closest to the semiconductor substrate  5  side, among the plurality of wiring layers  63  and  65 . Accordingly, the through electrodes  210  and  220  can be shortened as much as possible, and the through electrodes  210  and  220  can be easily formed. 
     As described above, the base  2  is disposed between the second surface  5   b  and the insulating layer  62  and includes the etching stop layer  61  made of SiN. Accordingly, when the semiconductor substrate  5  is dry-etched to form the through holes  211  and  221 , over-etching can be prevented, and the plasma damage to the wiring layer  63  can be effectively prevented. 
     As described above, the wiring layer  63  and the through electrodes  210  and  220  are made of the same material. Accordingly, the affinity between the through electrodes  210  and  220  and the wiring layer  63  is enhanced, and contact failure or the like between the through electrodes  210  and  220  and the wiring layer  63  can be effectively prevented. Since the material can be shared, the manufacturing cost of the resonator device  1  can be reduced. 
     As described above, the resonator component  4  is disposed at the first surface  5   a  side of the semiconductor substrate  5 . The resonator device  1  includes the lid  3  for accommodating the resonator component  4  between the lid  3  and the base  2 . Accordingly, the resonator component  4  can be protected. By forming the integrated circuit  6  at the second surface  5   b  side, as compared with the case where the integrated circuit  6  is formed at the first surface  5   a , the wide space for forming the integrated circuit  6  can be secured since no bonding region with the lid  3  exists. 
     As described above, the method for manufacturing the resonator device  1  includes the base preparation step S 1  of preparing the base  2  that includes the semiconductor substrate  5  having the first surface  5   a  and the second surface  5   b  that are in the front-to-back relation with each other, the integrated circuit  6  that includes the wiring layer  63  disposed at the second surface  5   b  side and including the connection pads  631  and  632  and includes the insulating layer  62  disposed between the second surface  5   b  and the wiring layer  63 , and the annular metal layers  691  and  692  that are disposed so as to penetrate the insulating layer  62  between the second surface  5   b  and the wiring layer  63 ; and the through electrode forming step S 2  of forming the through electrodes  210  and  220  penetrating the semiconductor substrate  5  and the insulating layer  62  and coupled to the connection pads  631  and  632  through the inside of the metal layers  691  and  692 . The through electrode forming step S 2  includes the through hole forming step S 21  of forming the through holes  21  and  22  from the first surface  5   a  to the connection pads  631  and  632  through the inside of the metal layers  691  and  692  by penetrating the semiconductor substrate  5  by the dry etching and then penetrating the insulating layer  62  by the wet etching, and the conductive material arranging step S 22  of disposing the conductive material E in the through holes  21  and  22  to form the through electrodes  210  and  220 . According to such a method, even if the through holes  213  and  223  penetrating the insulating layer  62  are formed by the wet etching, the metal layers  691  and  692  function as the guard rings, and further side etching is restricted. Therefore, for example, the plasma damage as in the case of the dry etching is not given to the wiring layer  63 , and the wiring pattern failure due to the side etching is prevented. Therefore, the resonator device  1  has a high reliability. 
     As described above, the base  2  is disposed between the second surface  5   b  and the insulating layer  62  and includes the etching stop layer  61  made of SiN. Accordingly, when the semiconductor substrate  5  is dry-etched to form the through holes  211  and  221 , over-etching can be prevented, and the plasma damage to the wiring layer  63  can be effectively prevented. 
     Second Embodiment 
       FIG. 15  is a vertical cross-sectional view illustrating a resonator device according to a second embodiment. 
     The resonator device  1  according to the present embodiment, except that the configuration of the base  2  is different, is the same as the resonator device  1  according to the first embodiment described above. In the following description, the present embodiment will be described with a focus on the difference from the above embodiment, and a description of similar matters will be omitted. In  FIG. 15 , the same reference numerals are given to configurations similar to those according to the above embodiment. 
     As illustrated in  FIG. 15 , the base  2  according to the present embodiment is upside down with respect to the first embodiment described above, and the integrated circuit  6  is formed at the upper surface side, that is, the second surface  5   b  side of the semiconductor substrate  5 . The resonator component  4  is disposed at the upper surface side of the semiconductor substrate  5 , and the resonator element  4  and the integrated circuit  6  are bonded via the pair of metal bumps  81  and  82 . The integrated circuit  6 , in order to secure a bonding space with the lid  3  on the second surface  5   b  of the semiconductor substrate  5 , is formed to be slightly smaller than the base  2  so as to exclude an outer peripheral portion of the second surface  5   b . According to such a configuration, the integrated circuit  6  can be accommodated and protected in the accommodating portion S together with the resonator component  4 . 
     In the terminal layer  68  of the integrated circuit  6 , in place of the mounting terminals  681  in the first embodiment described above, wirings  682  and  683  that electrically couple the resonator component  4  to the wiring layer  65  are disposed. At the first surface  5   a  side of the semiconductor substrate  5 , a plurality of mounting terminals  26  are disposed in place of the wirings  28  and  29  described above. The respective mounting terminals  26  pass through an annular metal layer  693  formed through the insulating layer  62  and are electrically coupled to the integrated circuit  6  via the through electrode  230  passing through the semiconductor substrate  5 , the etching stop layer  61 , and the insulating layer  62 . The through electrode  230  has the same configuration as the through electrodes  210  and  220  in the first embodiment described above, and the metal layer  693  has the same configuration as the metal layers  691  and  692  in the first embodiment described above. Moreover, the through electrode  230  and the metal layer  693  are formed by the same method as in the first embodiment described above. 
     As described above, in the resonator device  1  according to the present embodiment, the resonator component is disposed at the second surface  5   b  side of the semiconductor substrate  5 . The resonator device  1  includes the lid  3  for accommodating the resonator component  4  and the integrated circuit  6  between the lid  3  and the base  2 . Accordingly, the resonator component  4  and the integrated circuit  6  can be protected. 
     According to such a second embodiment, the same effect as that of the first embodiment described above can also be exerted. 
     Third Embodiment 
       FIG. 16  is a horizontal cross-sectional view illustrating a metal layer included in a resonator device according to a third embodiment. 
     The resonator device  1  according to the present embodiment, except that the configurations of the metal layers  691  and  692  are different, is the same as the resonator device  1  according to the first embodiment described above. In the following description, the present embodiment will be described with a focus on differences from the above embodiments, and a description of similar matters will be omitted. In  FIG. 16 , the same reference numerals are given to configurations similar to those according to the above embodiments. 
     As illustrated in  FIG. 16 , the resonator device  1  according to the present embodiment includes a plurality of concentrically arranged metal layers  691 . Specifically, the plurality of metal layers  691  include a first metal layer  691   a  located at an innermost position and surrounding the through electrode  210 , a second metal layer  691   b  located outside the first metal layer  691   a  and surrounding the first metal layer  691   a , and a third metal layer  691   c  located outside the second metal layer  691   b  and surrounding the second metal layer  691   b . According to such a configuration, the triple metal layers  691  can prevent an etching solution from leaking, and thus the wiring pattern failure due to the side etching can be more reliably prevented. However, the number of the metal layers  691  is not particularly limited, and may be two or four or more. 
     Similarly, the resonator device  1  according to the present embodiment includes a plurality of concentrically arranged metal layers  692 . Specifically, the plurality of metal layers  692  include a first metal layer  692   a  located at an innermost position and surrounding the through electrode  220 , a second metal layer  692   b  located outside the first metal layer  692   a  and surrounding the first metal layer  692   a , and a third metal layer  692   c  located outside the second metal layer  692   b  and surrounding the second metal layer  692   b . According to such a configuration, the triple metal layers  692  can prevent the etching solution from leaking, and thus the wiring pattern failure due to the side etching can be more reliably prevented. However, the number of the metal layers  692  is not particularly limited, and may be two or four or more. 
     As described above, in the resonator device  1  according to the present embodiment, the metal layers  691  and  692  include the first metal layers  691   a  and  692   a  surrounding the through electrodes  210  and  220  and the second metal layers  691   b  and  692   b  surrounding the first metal layers  691   a  and  692   a . Accordingly, the wiring pattern failure due to the side etching can be more reliably prevented. 
     According to such a third embodiment, the same effect as in the first embodiment described above can also be exerted. 
     Although the resonator device of the present disclosure and the method for manufacturing the resonator device are described above based on the illustrated embodiments, the present disclosure is not limited thereto, and the configuration of each unit can be replaced with an optional configuration having the same function. Further, any other constituents may be added to the present disclosure. Each of the embodiments may be combined as appropriate.