Patent Publication Number: US-2018044521-A1

Title: Electrical tracking resistance compositions, articles formed therefrom, and methods of manufacture thereof

Description:
BACKGROUND 
     This disclosure is directed to polyetherimide compositions, and in particular to electrical tracking resistant polyetherimide compositions, articles formed therefrom, and their methods of manufacture. 
     Polyetherimides are known as outstanding high performance materials, having a high glass transition temperature (Tg), high modulus, and strength at elevated temperatures, as well as excellent chemical resistance. They are useful in the manufacture of articles and components for a wide range of applications. Because of their broad use, particularly in the electrical and electronic industries, it is desirable to provide polyetherimides with good electrical tracking resistance. Electrical tracking is the formation of conductive pathways on the surface of a polymer under certain conditions and at a certain voltage. Electrical tracking in a polymer can be a source of fire therefore resistance to electrical tracking is often an important safety requirement for a material used in certain electrical applications. A common method of reporting the electrical tracking resistance of a polymer is by its comparative tracking index rating (CTI). Currently known polyetherimides can have a CTI of 100 to 175 volts. However, some applications can require a material having a higher CTI. 
     There accordingly remains a need in the art for polyetherimide compositions that have excellent electrical tracking resistance. It would be a further advantage if the compositions could be rendered electrical tracking resistant without a significant detrimental effect on one or more of material cost, processability, and mechanical properties. 
     SUMMARY 
     The above-described and other deficiencies of the art are met by a polyetherimide composition comprising: based on the total weight of the composition, 40 to 80 wt % of a polyetherimide; 10 to 50 wt % of talc; and 1 to 15 wt % of a polymer additive comprising a polyphthalamide, a poly(siloxane-etherimide) copolymer, aliphatic polyamide, or a combination comprising at least one of the foregoing; wherein the composition has a number of drops to tracking at 250 volts of greater than or equal to 50 drops determined according to ASTM D-3638-85. 
     In another embodiment, a method of manufacture comprises combining the above-described components to form a polyetherimide composition. 
     In yet another embodiment, an article comprises the above-described polyetherimide composition. 
     In still another embodiment, a method of manufacture of an article comprises molding, extruding, or shaping the above-described polyetherimide composition into an article. 
     The above described and other features are exemplified by the following drawings, detailed description, examples, and claims. 
    
    
     DETAILED DESCRIPTION 
     The inventors have discovered that the addition of 10 wt % to 50 wt % of talc and 1 wt % to 15 wt % of a polymer additive such as a polyphthalamide, a poly(siloxane-etherimide) copolymer, aliphatic polyamide, or a combination comprising at least one of the foregoing to polyetherimides results in a significant improvement in the electrical tracking resistance of the polyetherimides. The polyetherimide compositions have a number of drops to tracking at 250 volts greater than or equal to 50 drops determined according to ASTM D-3638-85 and a tracking voltage greater than or equal to 270 volts determined according to ASTM D-3638-85. The results are surprising because other fillers such as barium titanate, mica, hydrotalcite, silica, aluminum silicate, acidic aluminum oxide, bentonite, halloysite clay, magnesium oxide, calcium hydroxyapatite, or calcium carbonate either do not improve or only slightly improve the electrical tracking resistance of polyetherimides. 
     The polyetherimide compositions can further have balanced mechanical properties. The compositions have a tensile strength greater than or equal to 65 MPa determined according to ASTM D638 and a tensile modulus greater than or equal to 10,000 GPa determined according to ASTM D638. Optionally, the compositions further have a melt flow rate greater than or equal to 5 g/10 min determined according to ASTM D1238 at 337 ° C., using a 6.7 kilogram weight, and a heat deflection temperature of greater than or equal to 200° C. measured on 3.2 millimeter injection molded bar at 1.82 MPa stress according to ASTM D648. 
     Polyetherimides comprise more than 1, for example 2 to 1000, or 5 to 500, or 10 to 100 structural units of formula (1) 
     
       
         
         
             
             
         
       
     
     wherein each R is independently the same or different, and is a substituted or unsubstituted divalent organic group, such as a substituted or unsubstituted C 6-20  aromatic hydrocarbon group, a substituted or unsubstituted straight or branched chain C 2-20  alkylene group, a substituted or unsubstituted C 3-8  cycloalkylene group, in particular a halogenated derivative of any of the foregoing. In some embodiments R is divalent group of one or more of the following formulas (2) 
     
       
         
         
             
             
         
       
     
     wherein Q 1  is —O—, —S—, —C(O)—, —SO 2 —, —SO—, —C y H 2y — wherein y is an integer from 1 to 5 or a halogenated derivative thereof (which includes perfluoroalkylene groups), or —(C 6 H 10 ), — wherein z is an integer from 1 to 4. In some embodiments R is m-phenylene, p-phenylene, or a diarylene sulfone, in particular bis(4,4′-phenylene)sulfone, bis(3,4′-phenylene)sulfone, bis(3,3′-phenylene)sulfone, or a combination comprising at least one of the foregoing. In some embodiments, at least 10 mole percent of the R groups contain sulfone groups, and in other embodiments no R groups contain sulfone groups. 
     Further in formula (1), T is —O— or a group of the formula —O—Z—O— wherein the divalent bonds of the —O— or the —O—Z—O— group are in the 3,3′,3,4′,4,3′, or the 4,4′ positions, and Z is an aromatic C 6-24  monocyclic or polycyclic moiety optionally substituted with 1 to 6 C 1-8  alkyl groups, 1 to 8 halogen atoms, or a combination comprising at least one of the foregoing, provided that the valence of Z is not exceeded. Some groups Z include groups of formula (3) 
     
       
         
         
             
             
         
       
     
     wherein R a  and R b  are each independently the same or different, and are a halogen atom or a monovalent C 1-6  alkyl group, for example; p and q are each independently integers of 0 to 4; c is 0 to 4; and X a  is a bridging group connecting the hydroxy-substituted aromatic groups, where the bridging group and the hydroxy substituent of each C 6  arylene group are disposed ortho, meta, or para (specifically para) to each other on the C 6  arylene group. The bridging group X a  can be a single bond, —O—, —S—, —S(O)—, —S(O) 2 —, —C(O)—, or a C 1-18  organic bridging group. The C 1-18  organic bridging group can be cyclic or acyclic, aromatic or non-aromatic, and can further comprise heteroatoms such as halogens, oxygen, nitrogen, sulfur, silicon, or phosphorous. The C 1-18  organic group can be disposed such that the C 6  arylene groups connected thereto are each connected to a common alkylidene carbon or to different carbons of the C 1-18  organic bridging group. A specific example of a group Z is a divalent group of formula (3a) 
     
       
         
         
             
             
         
       
     
     wherein Q is —O—, —S—, —C(O)—, —SO 2 —, —SO—, or —C y H 2y — wherein y is an integer from 1 to 5 or a halogenated derivative thereof (including a perfluoroalkylene group). In a specific embodiment Z is a derived from bisphenol A, such that Q in formula (3a) is 2,2-isopropylidene. 
     In an embodiment in formula (1), R is m-phenylene, p-phenylene, or a combination comprising at least one of the foregoing, and T is —O—Z—O— wherein Z is a divalent group of formula (3a). Alternatively, R is m-phenylene, p-phenylene, or a combination comprising at least one of the foregoing, and T is —O—Z—O wherein Z is a divalent group of formula (3a) and Q is 2,2-isopropylidene. Alternatively, the polyetherimide can be a copolymer comprising additional structural polyetherimide units of formula (1) wherein at least 50 mole percent (mol %) of the R groups are bis(3,4′-phenylene)sulfone, bis(3,3′-phenylene)sulfone, or a combination comprising at least one of the foregoing and the remaining R groups are p-phenylene, m-phenylene or a combination comprising at least one of the foregoing; and Z is 2,2-(4-phenylene)isopropylidene, i.e., a bisphenol A moiety. 
     In some embodiments, the polyetherimide is a copolymer that optionally comprises additional structural imide units that are not polyetherimide units, for example imide units of formula (4) 
     
       
         
         
             
             
         
       
     
     wherein R is as described in formula (1) and each V is the same or different, and is a substituted or unsubstituted C 6-20  aromatic hydrocarbon group, for example a tetravalent linker of the formulas 
     
       
         
         
             
             
         
       
     
     wherein W is a single bond, —S—, —C(O)—, —SO 2 —, —SO—, or —C y H 2y — wherein y is an integer from 1 to 5 or a halogenated derivative thereof (which includes perfluoroalkylene groups). These additional structural imide units preferably comprise less than 20 mol % of the total number of units, and more preferably can be present in amounts of 0 to 10 mol % of the total number of units, or 0 to 5 mol % of the total number of units, or 0 to 2 mole % of the total number of units. In some embodiments, no additional imide units are present in the polyetherimide. 
     The polyetherimide can be prepared by any of the methods known to those skilled in the art, including the reaction of an aromatic bis(ether anhydride) of formula (5) or a chemical equivalent thereof, with an organic diamine of formula (6) 
     
       
         
         
             
             
         
       
     
     wherein T and R are defined as described above. Copolymers of the polyetherimides can be manufactured using a combination of an aromatic bis(ether anhydride) of formula (5) and an additional bis(anhydride) that is not a bis(ether anhydride), for example pyromellitic dianhydride or bis(3,4-dicarboxyphenyl) sulfone dianhydride. 
     Illustrative examples of aromatic bis(ether anhydride)s include 2,2-bis[4-(3,4-dicarboxyphenoxy)phenyl]propane dianhydride (also known as bisphenol A dianhydride or BPADA), 3,3-bis[4-(3,4-dicarboxyphenoxy)phenyl]propane dianhydride; 4,4′-bis(3,4-dicarboxyphenoxy)diphenyl ether dianhydride; 4,4′-bis(3,4-dicarboxyphenoxy)diphenyl sulfide dianhydride; 4,4′-bis(3,4-dicarboxyphenoxy)benzophenone dianhydride; 4,4′-bis(3,4-dicarboxyphenoxy)diphenyl sulfone dianhydride; 4,4′-bis(2,3-dicarboxyphenoxy)diphenyl ether dianhydride; 4,4′-bis(2,3-dicarboxyphenoxy)diphenyl sulfide dianhydride; 4,4′-bis(2,3-dicarboxyphenoxy)benzophenone dianhydride; 4,4′-bis(2,3-dicarboxyphenoxy)diphenyl sulfone dianhydride; 4-(2,3-dicarboxyphenoxy)-4′-(3,4-dicarboxyphenoxy)diphenyl-2,2-propane dianhydride; 4-(2,3-dicarboxyphenoxy)-4′-(3,4-dicarboxyphenoxy)diphenyl ether dianhydride; 4-(2,3-dicarboxyphenoxy)-4′-(3,4-dicarboxyphenoxy)diphenyl sulfide dianhydride; 4-(2,3-dicarboxyphenoxy)-4′-(3,4-dicarboxyphenoxy)benzophenone dianhydride; 4,4′-(hexafluoroisopropylidene)diphthalic anhydride; and 4-(2,3-dicarboxyphenoxy)-4′-(3,4-dicarboxyphenoxy)diphenyl sulfone dianhydride. A combination of different aromatic bis(ether anhydride)s can be used. 
     Examples of organic diamines include 1,4-butane diamine, 1,5-pentanediamine, 1,6-hexanediamine, 1,7-heptanediamine, 1,8-octanediamine, 1,9-nonanediamine, 1,10-decanediamine, 1,12-dodecanediamine, 1,18-octadecanediamine, 3-methylheptamethylenediamine, 4,4-dimethylheptamethylenediamine, 4-methylnonamethylenediamine, 5-methylnonamethylenediamine, 2,5-dimethylhexamethylenediamine, 2,5-dimethylheptamethylenediamine, 2,2-dimethylpropylenediamine, N-methyl-bis (3-aminopropyl) amine, 3-methoxyhexamethylenediamine, 1,2-bis(3-aminopropoxy) ethane, bis(3-aminopropyl) sulfide, 1,4-cyclohexanediamine, bis-(4-aminocyclohexyl) methane, m-phenylenediamine, p-phenylenediamine, 2,4-diaminotoluene, 2,6-diaminotoluene, m-xylylenediamine, p-xylylenediamine, 2-methyl-4,6-diethyl-1,3-phenylene-diamine, 5-methyl-4,6-diethyl-1,3-phenylene-diamine, benzidine, 3,3′-dimethylbenzidine, 3,3′-dimethoxybenzidine, 1,5-diaminonaphthalene, bis(4-aminophenyl) methane, bis(2-chloro-4-amino-3,5-diethylphenyl) methane, bis(4-aminophenyl) propane, 2,4-bis(p-amino-t-butyl) toluene, bis(p-amino-t-butylphenyl) ether, bis(p-methyl-o-aminophenyl) benzene, bis(p-methyl-o-aminopentyl) benzene, 1, 3-diamino-4-isopropylbenzene, bis(4-aminophenyl) sulfide, bis-(4-aminophenyl) sulfone (also known as 4,4′-diaminodiphenyl sulfone (DDS)), and bis(4-aminophenyl) ether. Any regioisomer of the foregoing compounds can be used. C 1-4  alkylated or poly(C 1-4 )alkylated derivatives of any of the foregoing can be used, for example a polymethylated 1,6-hexanediamine. Combinations of these compounds can also be used. In some embodiments the organic diamine is m-phenylenediamine, p-phenylenediamine, 4,4′-diaminodiphenyl sulfone, 3,4′-diaminodiphenyl sulfone, 3,3′-diaminodiphenyl sulfone, or a combination comprising at least one of the foregoing. 
     The thermoplastic composition can also comprise a poly(siloxane-etherimide) copolymer comprising polyetherimide units of formula (1) and siloxane blocks of formula (7) 
     
       
         
         
             
             
         
       
     
     wherein E has an average value of 2 to 100, 2 to 31, 5 to 75, 5 to 60, 5 to 15, or 15 to 40, and each R′ is independently a C 1-13  monovalent hydrocarbyl group. For example, each R′ can independently be a C 1-13  alkyl group, C 1-13  alkoxy group, C 2-13  alkenyl group, C 2-13  alkenyloxy group, C 3-6  cycloalkyl group, C 3-6  cycloalkoxy group, C 6-14  aryl group, C 6-10  aryloxy group, C 7-13  arylalkyl group, C 7-13  arylalkoxy group, C 7-13  alkylaryl group, or C 7-13  alkylaryloxy group. The foregoing groups can be fully or partially halogenated with fluorine, chlorine, bromine, or iodine, or a combination comprising at least one of the foregoing. In an embodiment no bromine or chlorine is present, and in another embodiment no halogens are present. Combinations of the foregoing R′ groups can be used in the same copolymer. In an embodiment, the polysiloxane blocks comprises R′ groups that have minimal hydrocarbon content. In a specific embodiment, an R′ group with a minimal hydrocarbon content is a methyl group. 
     The poly (siloxane-etherimide)s can be formed by polymerization of an aromatic bis(ether anhydride) of formula (5) and a diamine component comprising an organic diamine (6) as described above or mixture of diamines, and a polysiloxane diamine of formula (8) 
     
       
         
         
             
             
         
       
     
     wherein R′ and E are as described in formula (7), and R 4  is each independently a C 2 -C 20  hydrocarbon, in particular a C 2 -C 20  arylene, alkylene, or arylenealkylene group. In an embodiment R 4  is a C 2 -C 20  alkylene group, specifically a C 2 -C 10  alkylene group such as propylene, and E has an average value of 5 to 100, 5 to 75, 5 to 60, 5 to 15, or 15 to 40. Procedures for making the polysiloxane diamines of formula (8) are well known in the art. 
     In some poly(siloxane-etherimide)s the diamine component can contain 10 to 90 mole percent (mol %), or 20 to 50 mol %, or 25 to 40 mol % of polysiloxane diamine (8) and 10 to 90 mol %, or 50 to 80 mol %, or 60 to 75 mol % of diamine (6), for example as described in U.S. Pat. No. 4,404,350. The diamine components can be physically mixed prior to reaction with the bisanhydride(s), thus forming a substantially random copolymer. Alternatively, block or alternating copolymers can be formed by selective reaction of (6) and (8) with aromatic bis(ether anhydrides (5), to make polyimide blocks that are subsequently reacted together. Thus, the poly(siloxane-imide) copolymer can be a block, random, or graft copolymer. In an embodiment the copolymer is a block copolymer. 
     Examples of specific poly(siloxane-etherimide)s are described in U.S. Pat. Nos. 4,404,350, 4,808,686 and 4,690,997. In an embodiment, the poly(siloxane-etherimide) has units of formula (9) 
     
       
         
         
             
             
         
       
     
     wherein R′ and E of the siloxane are as in formula (7), the R and Z of the imide are as in formula (1), R 4  is the same as R 4  as in formula (8), and n is an integer from 5 to 100. In a specific embodiment, the R of the etherimide is a phenylene, Z is a residue of bisphenol A, R 4  is n-propylene, E is 2 to 50, 5, to 30, or 10 to 40, n is 5 to 100, and each R′ of the siloxane is methyl. 
     The relative amount of polysiloxane units and etherimide units in the poly(siloxane-etherimide) depends on the desired properties, and are selected using the guidelines provided herein. In particular, as mentioned above, the block or graft poly(siloxane-etherimide) copolymer is selected to have a certain average value of E, and is selected and used in amount effective to provide the desired wt % of polysiloxane units in the composition. In an embodiment the poly(siloxane-etherimide) comprises 10 to 50 wt %, 10 to 40 wt %, or 20 to 35 wt % polysiloxane units, based on the total weight of the poly(siloxane-etherimide). 
     The polyetherimides can have a melt index of 0.1 to 10 grams per minute (g/min), as measured by American Society for Testing Materials (ASTM) D1238 at 340 to 370° C., using a 6.7 kilogram (kg) weight. In some embodiments, the polyetherimidehas a weight average molecular weight (Mw) of 1,000 to 150,000 grams/mole (Dalton), as measured by gel permeation chromatography, using polystyrene standards. In some embodiments the polyetherimide has an Mw of 10,000 to 80,000 Daltons. Such polyetherimides typically have an intrinsic viscosity greater than 0.2 deciliters per gram (dl/g), or, more specifically, 0.35 to 0.7 dl/g as measured in m-cresol at 25° C. 
     The amount of polyetherimide used in the polyetherimide composition can vary widely, and is that amount effective to provide the desired mechanical properties and electrical tracking resistance. In some instances the polyetherimide is present in an amount from 40 wt % to 80 wt %, specifically 40 wt % to 70 wt %, and more specifically 50 wt % to 70 wt %, each based on the total weight of the composition. 
     The polyetherimide compositions further comprise a polymer additive, for example a polyphthalamide. Polyphthalamides comprise repeating units having formula (10) 
     
       
         
         
             
             
         
       
     
     wherein each G 1  is independently a branched or unbranched C 4-8  alkyl. In some embodiments, each G 1  is a 1,6-hexyl group. Polyamides, in general characterized by the presence of an amide group (—C(O)NH—) which is the condensation product of a carboxylic acid and an amine Polyphthalamides are the condensation product of terephthalic acid and an amine, isophthalic acid and an amine, or a combination of terephthalic acid, isophthalic acid, and an amine When employing more than one diamine the ratio of the diamines can affect some of the physical properties of the resulting polymer such as the melt temperature. When employing more than one acid, the ratio of the acids can affect some of the physical properties of the resulting polymer as well. The ratio of diamine to dicarboxylic acid is typically equimolar although excesses of one or the other can be used to determine the end group functionality. In addition the reaction can further include monoamines and monocarboxylic acids which function as chain stoppers and determine, at least in part, the end group functionality. In some embodiments it is preferable to have an amine end group content of greater than or equal to about 30 milliequivalents per gram (meq/g), or, more specifically, greater than or equal to about 40 meq/g. 
     In some embodiments the polyphthalamide is a block copolymer or a random copolymer comprising the units of formula (10) and units of formula (11) 
     
       
         
         
             
             
         
       
     
     wherein each G 2  and G 3  are independently a branched or unbranched C 4-12  alkyl group. 
     In some embodiments, the polymer additive is a nylon, i.e., an aliphatic polyamide. Aliphatic polyamides comprise units of formula (11). Aliphatic polyamides are generally derived from the polymerization of the corresponding C 4-12  organic lactams, or C 4 - 12  amino acids and C 4-12  carboxylic acids as is known in the art. Examples of useful polyamides include nylon 6, nylon 6,6, nylon 4,6, nylon 6, 12, nylon 10, or the like, or combinations including at least one of the foregoing polyamides. 
     Talc has been surprisingly found as a useful additive for improving electrical tracking resistance performance of polyetherimide, especially compared to mineral fillers such as barium titanate, mica, hydrotalcite, silica, aluminum silicate, acidic aluminum oxide, bentonite, halloysite clay, magnesium oxide, calcium hydroxyapatite, or calcium carbonate. 
     The amount of talc in the polyetherimide composition is in the range of 10 to 50 wt %, or 20 to 50 wt %, or in the range of 30 to 50 wt %, or 35 to 45 wt %, based on the total weight of the polyetherimide compositions. 
     The particle size of talc also affects the CTI performance of the polyetherimide compositions. In an embodiment, the titanium dioxide has a D95 of 2 micrometers to 6 micrometers. As used herein, D95 refer to the cut-particle diameter of the particulate where 95 wt % of the particles in the total distribution of the referenced sample have the noted particle diameter or smaller For example, a D95 particle size of 3.5 micrometers means that 95 wt % of the particles in the sample have a diameter of 3.5 micrometers or less. In an embodiment, the particle size is determined by sedigraph analysis using for example a Micromeritics Sedigraph 5120 Particle Size Analysis System. 
     In an embodiment, the polyetherimide compositions comprise 40 wt % to 70 wt % of a polyetherimide, 30 wt % to 50 wt % of talc, and 1 to 15 wt % of a polymer additive selected from a polyphthalamide, a poly(siloxane-etherimide) copolymer, or a combination comprising at least one of the foregoing. 
     The polyetherimide compositions can include various additives ordinarily incorporated into polymer compositions of this type, with the proviso that the additives are selected so as to not significantly adversely affect the desired properties of the composition. Exemplary additives include catalysts, impact modifiers, fillers, antioxidants, thermal stabilizers, light stabilizers, ultraviolet light (UV) absorbing additives, quenchers, plasticizers, lubricants, mold release agents, antistatic agents, visual effect additives such as dyes, pigments, and light effect additives, flame retardants, anti-drip agents, and radiation stabilizers. Combinations of additives can be used, for example a combination of a heat stabilizer, a mold release agent, and optionally an ultraviolet light stabilizer. In an embodiment the polyetherimide compositions further comprise an additive selected from a processing aid, a heat stabilizer, an ultraviolet light absorber, a colorant, a flame retardant, or a combination comprising at least one of the foregoing. In general, the additives are used in the amounts generally known to be effective. The foregoing additives (except any fillers) are generally present in an amount of 0.0001 to 20 wt % or 0.005 to 20 wt %, specifically 0.01 to 10 wt %, based on the total weight of the composition. Alternatively, in some embodiments, the compositions do not contain appreciable amounts of additives, and in some embodiments, there are no detectable amounts of additives, i.e., additives are substantially absent or absent from the compositions. Accordingly, the foregoing additives (except any fillers) can be present in an amount of 0.0001 wt % to 20 wt %, 0.0001 wt % to 15 wt %, 0.01 wt % to 20 wt % or 0.01 wt % to 20 wt %, based on the total weight of the composition. In another embodiment, no appreciable amount of any additive other than a heat stabilizer, a mold release agent, and optionally an ultraviolet light stabilizer is present in the compositions. In still another embodiment, no detectable amount of any additive other than a heat stabilizer, a mold release agent, and optionally an ultraviolet light stabilizer is present in the compositions. 
     Suitable antioxidants can be compounds such as phosphites, phosphonites and hindered phenols or a combination comprising at least one of the foregoing antioxidants. Phosphorus-containing stabilizers including triaryl phosphites and aryl phosphonates are useful additives. Difunctional phosphorus containing compounds can also be unseeded. Preferred stabilizers can have a molecular weight greater than 300. Some exemplary compounds are tris-di-tert-butylphenyl phosphite available from Ciba Chemical Co. as IRGAFOS 168 and bis (2,4-dicumylphenyl) pentaerythritol diphosphite available commercially from Dover Chemical Co. as DOVERPHOS S-9228. 
     Examples of phosphites and phosphonites include: triphenyl phosphite, diphenyl alkyl phosphites, phenyl dialkyl phosphites, tris(nonylphenyl) phosphite, trilauryl phosphite, trioctadecyl phosphite, distearyl pentaerythritol diphosphite, tris(2,4-di-tert-butylphenyl) phosphite, diisodecyl pentaerythritol diphosphite, bis(2,4-di-tert-butylphenyl) pentaerythritol diphosphite, bis(2,6-di-tert-butyl-4-methylphenyl)-pentaerythritol diphosphite, diisodecyloxy pentaerythritol diphosphite, bis(2,4-di-tert-butyl-6-methylphenyl)pentaerythritol diphosphite, bis(2,4,6-tris(tert-butylphenyl)pentaerythritol diphosphite, tristearyl sorbitol tri-phosphite, tetrakis(2,4-di-tert-butyl-phenyl) 4,4′-biphenylene diphosphonite, bis(2,4-di-tert-butyl-6-methylphenyl) methyl phosphite, bis(2,4-di-tert-butyl-6-methylphenyl) ethyl phosphite, 2,2′,2″-nitrilo[triethyl tris(3,3′,5,5′-tetra-tert-butyl-1,1′-biphenyl-2,2′-diyl)phosphite], 2-ethylhexyl(3,3′,5,5′-tetra-tert-butyl-1,1′-biphenyl-2,2′-diyl)phosphite and 5-butyl-5-ethyl-2-(2,4,6-tri-tert-butylphenoxy)-1,3,2-dioxaphosphirane. 
     Combinations comprising more than one organophosphorous compound are contemplated. When used in combination the organo phosphorous compounds can be of the same type or different types. For example, a combination can comprise two phosphite or a combination can comprise a phosphite and a phosphonite. In some embodiments, phosphorus-containing stabilizers with a molecular weight greater than 300 are useful. Phosphorus-containing stabilizers, for example an aryl phosphite are usually present in the composition in an amount from 0.005 to 3 wt %, specifically 0.01 to 1.0 wt %, based on total weight of the composition. 
     Hindered phenols can also be used as antioxidants, for example alkylated monophenols, and alkylated bisphenols or poly phenols. Exemplary alkylated monophenols include 2,6-di-tert-butyl-4-methylphenol; 2-tert-butyl-4,6-dimethylphenol; 2,6-di-tert-butyl-4-ethylphenol; 2,6-di-tert-butyl-4-n-butylphenol; 2,6-di-tert-butyl-4-isobutylphenol; 2,6-dicyclopentyl-4-methylphenol; 2-(alpha-methylcyclohexyl)-4,6-dimethylphenol; 2,6-dioctadecyl-4-methylphenol; 2,4,6-tricyclohexylphenol; 2,6-di-tert-butyl-4-methoxymethylphenol; nonyl phenols which are linear or branched in the side chains, for example, 2,6-di-nonyl-4-methylphenol; 2,4-dimethyl-6-(1′-methylundec-1′-yl)phenol; 2,4-dimethyl-6-(1′-methylheptadec-1′-yl)phenol; 2,4-dimethyl-6-(1′-methyltridec-1′-yl)phenol or a combination comprising at least one of the foregoing phenols. Exemplary alkylidene bisphenols include 2,2′-methylenebis(6-tert-butyl-4-methylphenol), 2,2′-methylenebis(6-tert-butyl-4-ethylphenol), 2,2′-methylenebis[4-methyl-6-(alpha-methylcyclohexyl)-phenol], 2,2′-methylenebis(4-methyl-6-cyclohexylphenol), 2,2′-methylenebis(6-nonyl-4-methylphenol), 2,2′-methylenebis(4,6-di-tert-butylphenol), 2,2′-ethylidenebis(4,6-di-tert-butylphenol), 2,2′-ethylidenebis(6-tert-butyl-4-isobutylphenol), 2,2′-methylenebis[6-(alpha-methylbenzyl)-4-nonylphenol], 2,2′-methylenebis[6-(alpha, alpha-dimethylbenzyl)-4-nonylphenol], 4,4′-methylenebis-(2,6-di-tert-butylphenol), 4,4′-methylenebis(6-tert-butyl-2-methylphenol), 1,1-bis(5-tert-butyl-4-hydroxy-2-methylphenyl)butane, 2,6-bis(3-tert-butyl-5-methyl-2-hydroxybenzyl)-4-methylphenol, 1,1,3-tris(5-tert-butyl-4-hydroxy-2-methylphenyl)butane, 1,1-bis(5-tert-butyl-4-hydroxy-2-methyl-phenyl)-3-n-dodecylmercaptobutane , ethylene glycol bis[3,3-bis(3′-tert-butyl-4′-hydroxyphenyl)butyrate], bis(3-tert-butyl-4-hydroxy-5-methyl-phenyl)dicyclopentadiene, bis[2-(3′-tert-butyl-2′-hydroxy-5′-methylbenzyl)-6-tert-butyl-4-methylphenyl]terephthalate, 1,1-bis-(3,5-dimethyl-2-hydroxyphenyl)butane, 2,2-bis-(3,5-di-tert-butyl-4-hydroxyphenyl)propane, 2,2-bis-(5-tert-butyl-4-hydroxy2-methylphenyl)-4-n-dodecylmercaptobutane, 1,1,5,5-tetra-(5-tert-butyl-4-hydroxy-2-methylphenyepentane, or a combination comprising at least one of the foregoing. 
     The hindered phenol compound can have a molecular weight of greater than 300 g/mole. The high molecular weight can help retain the hindered phenol moiety in the polymer melt at high processing temperatures, for example greater than 300° C. Hindered phenol stabilizers, are usually present in the composition in an amount from 0.005 to 2 wt %, specifically 0.01 to 1.0 wt %, based on total weight of the composition. 
     Examples of mold release agents include both aliphatic and aromatic carboxylic acids and their alkyl esters, for example, stearic acid, behenic acid, pentaerythritol tetrastearate, glycerin tristearate, and ethylene glycol distearate. Polyolefins such as high-density polyethylene, linear low-density polyethylene, low-density polyethylene and similar polyolefin homopolymers and copolymers can also be used a mold release agents. Mold release agents are typically present in the composition at 0.05 to 10 wt %, based on total weight of the composition, specifically 0.1 to 5 wt %. Preferred mold release agents will have high molecular weight, typically greater than 300, to prevent loss of the release agent from the molten polymer mixture during melt processing. 
     In particular, an optional polyolefin can be added to modify the chemical resistance characteristics and mold release characteristics of the composition. Homopolymers such as polyethylene, polypropylene, polybutene can be used either separately or in combination. Polyethylene can be added as high-density polyethylene (HDPE), low-density polyethylene (LDPE), or branched polyethylene. Polyolefins can also be used in copolymeric form with compounds containing carbonic acid groups such as maleic acid or citric acid or their anhydrides, acid compounds containing acrylic acid groups such as acrylic acid ester, and the like, as well as combinations comprising at least one of the foregoing. When present, the polyolefin, in particular HDPET, is used in an amount from more than 0 to 10 wt %, specifically 0.1 to 8 wt %, more specifically from 0.5 to 5 wt %, all based on the total weight of the composition. 
     In some embodiments, the polyetherimide compositions can further include at least one additional polymer. Examples of such additional polymers include and are not limited to PPSU (polyphenylene sulfone), polyetherimides, PSU (polysulfone), PPET (polyphenylene ether), PFA (perfluoroalkoxy alkane), MFA (co-polymer of TFE tetrafluoroethylene and PFVE perfluorinated vinyl ether), FEP (fluorinated ethylene propylene polymers), PPS (poly(phenylene sulfide), PTFE (polytetrafluoroethylene), PA (polyamide), PBI (polybenzimidizole) and PAI (poly(amide-imide)), poly(ether sulfone), poly(aryl sulfone), polyphenylenes, polybenzoxazoles, polybenzthiazoles, as well as blends and co-polymers thereof. When present, the polymer is used in an amount from more than 0 to 20 wt %, specifically 0.1 to 15 wt %, more specifically from 0.5 to 10 wt %, all based on the total weight of the composition. In an embodiment, no polymer other than the polyetherimide as described herein is present in the composition. 
     Colorants such as pigment and/or dye additives can also optionally be present. Useful pigments can include, for example, inorganic pigments such as metal oxides and mixed metal oxides such as zinc oxide, titanium dioxide, iron oxides, or the like; sulfides such as zinc sulfides, or the like; aluminates; sodium sulfo-silicates sulfates, chromates, or the like; carbon blacks; zinc ferrites; ultramarine blue; organic pigments such as azos, di-azos, quinacridones, perylenes, naphthalene tetracarboxylic acids, flavanthrones, isoindolinones, tetrachloroisoindolinones, anthraquinones, enthrones, dioxazines, phthalocyanines, and azo lakes; Pigment Red 101, Pigment Red 122, Pigment Red 149, Pigment Red 177, Pigment Red 179, Pigment Red 202, Pigment Violet 29, Pigment Blue 15, Pigment Blue 60, Pigment Green 7, Pigment Yellow 119, Pigment Yellow 147, Pigment Yellow 150, and Pigment Brown 24; or combinations comprising at least one of the foregoing pigments. Pigments are generally used in amount from 0 to 10 wt %, specifically 0 to 5 wt %, based on the total weight of the composition. In some instances, where improved impact is desired pigments such as titanium dioxide will have a mean particle size of less than 5 micrometers. 
     In some instances it is desired to have polyetherimide compositions that are essentially free of bromine and chlorine. “Essentially free” of bromine and chlorine means that the composition has less than 3 wt % of bromine and chlorine, and in other embodiments less than 1 wt % bromine and chlorine by weight of the composition. In other embodiments, the composition is halogen free. “Halogen free” is defined as having a halogen content (total amount of fluorine, bromine, chlorine, and iodine) of less than 1000 parts by weight of halogen per million parts by weight of the total composition (ppm). The amount of halogen can be determined by ordinary chemical analysis such as atomic absorption. 
     The polyetherimide compositions can be prepared by blending the ingredients under conditions for the formation of an intimate blend. Such conditions often include melt mixing in single or twin screw type extruders, mixing bowl, or similar mixing devices that can apply a shear to the components. Twin-screw extruders are often preferred due to their more intensive mixing capability and self-wiping capability, over single screw extruders. It is often advantageous to apply a vacuum to the blend through at least one vent port in the extruder to remove volatile impurities in the composition. Often it is advantageous to dry the PET and polyimide polymers prior to melting. The melt processing is often done at 290 to 340° C. to avoid excessive polymer degradation while still allowing sufficient melting to get an intimate polymer mixture free of any unbelted components. The polymer blend can also be melt filtered using a 40 to 100 micrometer candle or screen filter to remove undesirable black specks or other heterogeneous contaminants 
     In an exemplary process, the various components are placed into an extrusion compounder to produce a continuous strand that is cooled and then chopped into pellets. In another procedure, the components are mixed by dry blending, and then fluxed on a mill and comminuted, or extruded and chopped. The composition and any optional components can also be mixed and directly molded, e.g., by injection or transfer molding techniques. Preferably, all of the components are freed from as much water as possible. In addition, compounding is carried out to ensure that the residence time in the machine is short; the temperature is carefully controlled; the friction heat is utilized; and an intimate blend between the components is obtained. The polyetherimide compositions can then be molded in any equipment conventionally used for polyetherimide compositions, such as a Newbury or van Dorn type injection-molding machine with conventional cylinder temperatures, at 250° C. to 320° C., and conventional mold temperatures at 55° C. to 120° C. 
     As discussed above, the polyetherimide compositions are formulated to have excellent electrical tracking resistance. In an embodiment, the compositions have number of drops to tracking at 250 volts greater than or equal to 50 drops, greater than or equal to 60 drops, greater than or equal to 70 drops, greater than or equal to 80 drops, greater than or equal to 90 drops, or greater than or equal to 100 drops, determined according to ASTM D-3638-85. 
     The polyetherimide compositions can have a tracking voltage greater than or equal to 270 volts, greater than or equal to 280 volts, greater than or equal to 290 volts, or greater than or equal to 300 volts determined according to ASTM D-3638-85. 
     The polyetherimide compositions can further have a tensile strength of greater than or equal to 65 MPa (Mega Pascal), greater than or equal to 70 MPa, greater than or equal to 75 MPa, or greater than or equal to 80 MPa determined according to ASTM D638. 
     The polyetherimide compositions can have a combination of glow wire ignition temperature of greater than or equal to 960° C. and glow wire flammability index of greater than or equal to 850° C. determined according to IEC 60695-2-13. 
     The polyetherimide compositions can further have a tensile modulus of greater than or equal to 11,000 GPa (Giga Pascal), greater than or equal to 12,000 GPa determined according to ASTM D638. 
     The polyetherimide compositions can further have a heat deflection temperature (HDT) of 190 to 250 ° C., more specifically 190 to 230 ° C., 200° C. to 220° C. or 200° C. to 210° C. measured on 3.2 millimeter injection molded bar at 1.82 MPa stress according to ASTM D648. 
     The compositions further have a melt flow rate greater than or equal to 5 g/10 min or between 5 g/10 min and 15 g/10 min determined according to ASTM D1238 at 337 ° C., using a 6.7 kilogram weight. 
     Shaped, formed, or molded articles comprising the polyetherimide compositions are also provided. The polyetherimide compositions can be molded into useful shaped articles by a variety of means such as injection molding, extrusion, rotational molding, blow molding, and thermoforming. Thus the polyetherimide compositions can be used to form a foamed article, a molded article, a thermoformed article, an extruded film, an extruded sheet, one or more layers of a multi-layer article (e.g. a cap-layer), a substrate for a coated article, or a substrate for a metallized article. 
     In another embodiment, at least one of the following articles are contained in or are derived from the compositions encompassed by this disclosure: a solar apparatus, an electrical junction box, an electrical connector, an electrical vehicle charger, an outdoor electrical enclosure, a smart meter enclosure, a smart grid power node, PV (photovoltaic) frame, and miniature circuit breaker (MCB) applications. 
     The polyetherimide compositions having improved CTI performance and balanced mechanical properties are further illustrated by the following non-limiting examples. All parts and percentages are by weight unless explicitly stated otherwise. All temperatures are degrees Celsius unless explicitly stated otherwise. 
     EXAMPLES 
     The materials used in the Examples are described in Table 1. 
     
       
         
           
               
               
               
             
               
                 TABLE 1 
               
               
                   
               
               
                   
                   
                 Source, 
               
               
                 Component 
                 Chemical Description 
                 Vendor 
               
               
                   
               
             
            
               
                 PEI 
                 Polyetherimide (ULTEM*) 
                 SABIC 
               
               
                 PEI-Si 
                 Siloxane polyetherimide copolymer 
                 SABIC 
               
               
                   
                 (STM* 1700) 
               
               
                 PPA 
                 Polyphthalamides (ZYTEL* HTN 501) 
                 DuPont 
               
               
                 Nylon 6,6 
                 Poly[imino(1,6-dioxohexamethylene) 
                 DuPont 
               
               
                   
                 imnohexamethylene] (ZYTEL* PA66) 
               
               
                 Jetfine Talc 1A 
                 Talc having a D95 of 2.9 micrometers 
                 IMERYS 
               
               
                 Jetfine Talc 3CA 
                 Talc having a D95 of 3.5 micrometers 
                 IMERYS 
               
               
                 Jetfine Talc 8CF 
                 Talc having a D95 of 5.7 micrometers 
                 IMERYS 
               
               
                 Talc powder 
                 Talc having a D95 of less than 
                 Aldrich 
               
               
                   
                 10 micrometers 
               
               
                 Talc - HM4 
                 Talc having a D95 of 30 micrometers 
                 Imifabi 
               
               
                 Talc - ultrafine 
                 Talc having a D95 of 4.5 micrometers 
                 Imifabi 
               
               
                 Talc - HTP1 
                 Talc having a D95 of 8 micrometers 
                 Imifabi 
               
               
                 Barium Titanate 
                 3-12 mm &amp; less than 3 micrometers 
                 Aldrich 
               
               
                 (IV) 
               
               
                 Calcium 
                 Ca 10 (PO 4 ) 6 (OH) 2   
                 Aldrich 
               
               
                 hydroxyapatite 
               
               
                 Calcium 
                 10-30 micrometer 
                 Aldrich 
               
               
                 carbonate 
               
               
                 Mica 
                 Less than 5 micrometers 
                 Sanbaomica 
               
               
                 Halloysite clay 
                 Less than 5 micrometers 
                 Applied 
               
               
                   
                   
                 Minerals Inc. 
               
               
                 Hydrotalcite 
                 Mg 6 Al 2 (CO 3 )(OH) 16 •4H 2 O 
                 Aldrich 
               
               
                 Magnesium oxide 
                 325 mesh size 
                 Aldrich 
               
               
                 Zirconium silicate 
                 325 mesh size 
                 Aldrich 
               
               
                 Silica 
                 200 nm size 
                 Aldrich 
               
               
                 Aluminum 
                 Hydrated 
                 Nano 
               
               
                 silicate 
                   
                 Products 
               
               
                   
                   
                 Corp. 
               
               
                 Bentonite 
                 Aluminum Phyllosilicate 
                 E-Merck 
               
               
                   
               
            
           
         
       
     
     Blending, Extrusion, and Molding Conditions 
     Compositions were formed by melt mixing the polyetherimide, talc, and PPA or nylon 6,6, or PEI-Si. Extrusion was carried out in a 2.5-inch twin screw, vacuum vented extruder. The extruder was set at about 300-350° C. The blends were run at approximately 250 rotations per minute (rpm) under vacuum. Compositions were made in a one pass method. The extrudate was cooled, pelletized, and dried at 150° C. Test samples were injection molded at a set temperature of 340-350° C. and mold temperature of 150-160° C. using a 30 second cycle time. 
     Testing Procedures 
     All molded samples were conditioned for at least 48 hours at 50% relative humidity prior to testing. Properties were measured using ASTM test methods. Unless specified to the contrary herein, all test standards are the most recent standard in effect at the time of filing this application. 
     Unnotched Izod impact values were measured at room temperature on 3.2 millimeter thick bars as per ASTM D256. Samples were tested at room temperature. Results are in Joules per meter (J/m). 
     Tensile properties were measured on 3 2 millimeter type I bars as per ASTM method D638 at 23 ° C. with a crosshead speed of 5 millimeters/minute. Percent elongation (% Elongation) is reported at break (B). Tensile modulus, tensile strength at yield, and tensile strength at break results are reported in MPa (Mega Pascal) or GPa (Giga Pascal). 
     Melt flow rates (MFR) were measured in accordance with ASTM D1238 at 337° C., using a 6.7 kilogram (kg) weight. MFR is reported in grams per 10 minutes (g/10 min). 
     Heat Deflection Temperature (HDT) was measured on 3 2 millimeter injection molded bar at 1.82 MPa stress according to ASTM D648. HDT is reported in degree Celsius (C). 
     Electrical tracking resistance tests were performed on a 3mm square plaque (6×6 cm) in accordance with the ASTM D-3638. The test can be started at any given voltage. At each voltage 5 specimens are tested and the average number of drops is recorded. The test is performed at (at least) 4 different voltages, where there should be at least two data points with an average number of drops higher than 50 and two data points with an average number of drops lower than 50. A voltage extrapolation to 50 drops is made, and based on this voltage (V ASTM ) a PLC class is assigned. This assignment is provided according to the table below. The CTI rating of a polymer indicates how resistant the polymeric material is to electrical tracking at certain voltages. CTI ratings range from CTI-0 to CTI-5 with a CTI-1 rating indicating that a polymer is more resistant to electrical tracking than a polymer with a lower CTI rating (for example CTI-3). 
     
       
         
           
               
               
               
             
               
                   
                   
               
               
                   
                 VASTM 
                 PLC 
               
               
                   
                   
               
             
            
               
                   
                 &lt;100 
                 5 
               
               
                   
                 100-174 
                 4 
               
               
                   
                 175-249 
                 3 
               
               
                   
                 250-399 
                 2 
               
               
                   
                 400-599 
                 1 
               
               
                   
                 ≧600 
                 0 
               
               
                   
                   
               
            
           
         
       
     
     A screening method was employed to predict the CTI-2 performance of polyetherimide compositions. The method employed the ASTM D-3638 method but testing was conducted at only one voltage, 250 V. The number of drops until failure was recorded and no more than 100 drops were applied. A prediction of a CTI-2 rating for a sample was based on reaching at least 50 drops of the electrolyte solution before failure at 250 V. A prediction of not receiving a CTI rating was based on failure before reaching 50 drops of the electrolyte solution at 250 V. The screening method for predicting CTI-2 rating is identified throughout the disclosure as the CTI test. 
     Glow wire ignition temperature (GWIT) refers to the temperature which is 25° C. higher than the maximum temperature which does not cause ignition of a test specimen at a given thickness during three subsequent tests. Glow wire flammability index (GWFT) refers to the maximum temperature in which all flaming and glowing cease within 30 seconds after removal of the glow-wire during three subsequent tests. GWIT and GWFT were tested in accordance with IEC 60695-2-13. 
     Examples 1-6 
     Examples 1-6 demonstrate the effect of the addition of polymer additives and talc to polyetherimide on mechanical and CTI properties. Formulations and results are shown in Table 2. 
     
       
         
           
               
               
               
               
               
               
               
             
               
                   
                 TABLE 2 
               
               
                   
                   
               
               
                   
                 1* 
                 2 
                 3 
                 4 
                 5 
                 6 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
            
               
                 Component 
                   
                   
                   
                   
                   
                   
               
               
                 PEI 
                 100 
                 55 
                 50 
                 55 
                 50 
                 55 
               
               
                 Jet fine Talc 3CA 
                   
                 40 
                 40 
                 40 
                 40 
                 40 
               
               
                 PPA 
                   
                 5 
                 10 
               
               
                 PEI-Si 
                   
                   
                   
                 5 
                 10 
               
               
                 Nylon 6,6 
                   
                   
                   
                   
                   
                 5 
               
               
                 Property 
               
               
                 Tensile strength (MPa) 
                 100 
                 78 
                 91 
                 80 
                 67 
                 54 
               
               
                 Tensile modulus (GPa) 
                 3580 
                 11106 
                 11028 
                 11582 
                 11006 
                 10036 
               
               
                 % Elongation 
                 7 
                 1 
                 1 
                 1 
                 1 
                 1 
               
               
                 Flexural strength (GPa) 
                 165 
                 127 
                 148 
                 129 
                 134 
                 101 
               
               
                 Flexural Modulus (MPa) 
                 3510 
                 11431 
                 11280 
                 10832 
                 10339 
                 10903 
               
               
                 Unnotched Impact (J/m) 
                 1335 
                 139 
                 241 
                 185 
                 143 
                 112 
               
               
                 MFR 337° C., 6.7 Kg, 5 min (g/10 min) 
                 17.8 
                 5 
                 10 
                 5 
                 6 
                 14 
               
               
                 HDT (1.82 MPa) 
                 198 
                 205 
                 202 
                 209 
                 207 
                 207 
               
               
                 No. of drops for tracking@ 250 Volts 
                 10 
                 74 
                 100 
                 100 
                 100 
                 100 
               
               
                 Tracking Voltage (Volts) 
                 162 
                 357 
                 360 
                 275 
                 300 
                 270 
               
               
                 PLC Rating 
                 4 
                 2 
                 2 
                 2 
                 2 
                 2 
               
               
                   
               
               
                 *Comparative Example 
               
            
           
         
       
     
     Comparative example 1 shows that a composition containing 100% PEI has a number of drops to tracking at 250 volts of 10 drops, and a tracking voltage of 162 volts. By blending 5 to 10 wt % of PPA or PEI-Si with polyetherimide and talc, compositions having a tensile strength greater than or equal to 65 MPa, tensile modulus greater than or equal to 11,000 GPa, melt flow rate greater than or equal to 5 g/10 min, HDT greater than or equal to 200° C., number of drops to tracking at 250 volts greater than or equal to 50 drops, and tracking voltage greater than or equal to 270 volts are obtained. Blending 5 wt % of nylon 6,6 with polyetherimide and talc improves the number of drops to tracking at 250 volts to 100 and the tracking voltage to 270. 
     Examples 7-12 
     Examples 7-12 demonstrate the effect of the addition of various amounts of talc and polymer additive to polyetherimide on CTI properties. Formulations and results are shown in Table 3. 
     
       
         
           
               
               
               
               
               
               
               
             
               
                   
                 TABLE 3 
               
               
                   
                   
               
               
                   
                 7* 
                 8 
                 9 
                 10 
                 11 
                 12 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
            
               
                 Component 
                   
                   
                   
                   
                   
                   
               
               
                 PEI 
                 100 
                 65 
                 60 
                 55 
                 55 
                 55 
               
               
                 Jet fine talc 3CA 
                   
                 35 
                 40 
                 40 
                 40 
                 40 
               
               
                 PPA 
                   
                   
                   
                 5 
               
               
                 PEI-Si 
                   
                   
                   
                   
                 5 
               
               
                 Nylon 6,6 
                   
                   
                   
                   
                   
                 5 
               
               
                 Property 
               
               
                 T GW   
                 960 
                 960 
                 960 
                 960 
                 960 
                 960 
               
               
                 T i   
                 0 
                 19 
                 20 
                 0 
                 26 
                 0 
               
               
                 T E   
                 30 
                 11 
                 14 
                 19 
                 4 
                 12 
               
               
                 T R   
                 # 
                 # 
                 # 
                 # 
                 # 
                 # 
               
               
                 X 1   
                 1, 4 
                 1, 4 
                 1, 4 
                 1, 4 
                 1, 4 
                 1, 4 
               
               
                 GWFI @ 3 mm (° C.) 
                 960 
                 960 
                 960 
                 960 
                 960 
                 960 
               
               
                 T GW   
                 800 
                 850 
                 850 
                 850 
                 875 
                 775 
               
               
                 T i   
                 * 
                 * 
                 * 
                 27 
                 28 
                 * 
               
               
                 T E   
                 * 
                 * 
                 * 
                 3 
                 2 
                 * 
               
               
                 T R   
                 # 
                 # 
                 # 
                 # 
                 # 
                 # 
               
               
                 X 1   
                 1, 4 
                 1, 4 
                 1, 4 
                 1, 4 
                 1, 4 
                 1, 4 
               
               
                 T GW   
                 825 
                 875 
                 875 
                 875 
                 900 
                 800 
               
               
                 T i   
                 18 
                 17 
                 23 
                 5 
                 6 
                 3 
               
               
                 T E   
                 12 
                 13 
                 7 
                 25 
                 6 
                 7 
               
               
                 T R   
                 # 
                 # 
                 # 
                 # 
                 # 
                 # 
               
               
                 X 1   
                 1, 4 
                 1, 4 
                 1, 4 
                 1, 4 
                 1, 4 
                 1, 4 
               
               
                 GWIT @ 3 mm (° C.) 
                 825 
                 875 
                 875 
                 875 
                 900 
                 800 
               
               
                   
               
               
                 *Comparative Example 
               
               
                 T GW  = Glow Wire Tip Temperature 
               
               
                 T I  = Time to Ignite 
               
               
                 T E  = Total Flaming and Glowing time (for GWIT) 
               
               
                 T R  = Total Flaming and Glowing Time After Glow Wire Tip Removal (for GWFI) Observations (X 1 ) 
               
               
                 (#) No ignition after 30 second application; 
               
               
                 (*) No flame at time of application and after 30 second application; 
               
               
                 (1) Specimen did not drip; 
               
               
                 (2) Specimen dripped particles which did not ignite tissue paper; 
               
               
                 (3) Specimen dripped particles which ignited tissue paper; 
               
               
                 (4) Tip penetrated sample; 
               
               
                 Ignition: flame that persists for longer than 5 s. 
               
            
           
         
       
     
     These examples demonstrate that by adding talc together with polymer additives such as PPA, PEI-Si, and nylon 6,6 to polyetherimide, the obtained compositions are capable of achieving a combination of GWFI greater than or equal to 960° C. and GWIT greater than or equal to 850° C., which is higher than that of the neat polyetherimide. Examples 13-17 
     Examples 13-17 demonstrate the effect of the addition of polymer additives and talc having a D95 of 2.9 micrometers to polyetherimide on mechanical and CTI properties. Formulations and results are shown in Table 4. 
     
       
         
           
               
               
               
               
               
               
             
               
                   
                 TABLE 4 
               
               
                   
                   
               
               
                   
                 13* 
                 14 
                 15 
                 16 
                 17 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
            
               
                 Component 
                   
                   
                   
                   
                   
               
               
                 PEI 
                 100 
                 55 
                 50 
                 55 
                 50 
               
               
                 Jet fine talc 1A 
                   
                 40 
                 40 
                 40 
                 40 
               
               
                 PPA 
                   
                 5 
                 10 
               
               
                 PEI-Si 
                   
                   
                   
                 5 
               
               
                 Nylone 6,6 
                   
                   
                   
                   
                 5 
               
               
                 Property 
               
               
                 Tensile strength (MPa) 
                 100 
                 72 
                 66 
                 70 
                 45 
               
               
                 Tensile modulus (GPa) 
                 3580 
                 10292 
                 10626 
                 10613 
                 10130 
               
               
                 % Elongation 
                 7 
                 1 
                 1 
                 1 
                 1 
               
               
                 Flexural strength (GPa) 
                 165 
                 119 
                 124 
                 103 
                 69 
               
               
                 Flexural Modulus (MPa) 
                 3510 
                 9890 
                 10228 
                 9687 
                 9076 
               
               
                 Unnotched Impact (J/m) 
                 1335 
                 177 
                 184 
                 200 
                 65 
               
               
                 MFR 337° C., 6.7 Kg, 
                 17.8 
                 8 
                 12 
                 5 
                 103 
               
               
                 5 min (g/10 min) 
               
               
                 HDT (1.82 MPa) 
                 198 
                 205 
                 201 
                 209 
                 200 
               
               
                 No. of drops for 
                 10 
                 100 
                 100 
                 100 
                 100 
               
               
                 tracking@ 250 Volts 
               
               
                 Tracking Voltage (Volts) 
                 162 
                 293 
                 324 
                 307 
                 301 
               
               
                 PLC Rating 
                 4 
                 2 
                 2 
                 2 
                 2 
               
               
                   
               
               
                 *Comparative Example 
               
            
           
         
       
     
     Comparative example 1 shows that a composition containing 100% PEI has a number of drops to tracking at 250 volts of 10 drops, and a tracking voltage of 162 volts. By blending 5 to 10 wt % of PPA or PEI-Si with polyetherimide and talc having a D95 of 2.9 micrometers, compositions having a tensile strength greater than or equal to 65 MPa, tensile modulus greater than or equal to 10,000 GPa, HDT greater than or equal to 200° C., number of drops to tracking at 250 volts greater than or equal to 50 drops, and tracking voltage greater than or equal to 270 volts can be provided. Example 17 shows that blending 5 wt % of nylon 6,6 with polyetherimide and talc improves the number of drops to tracking at 250 volts to 100 drops and the tracking voltage to 301 volts. 
     Examples 18-22 
     Examples 18-22 demonstrate the effect of the addition of talc having a D95 of 5.7 micrometers to polyetherimide on mechanical and CTI properties. Formulations and results are shown in Table 5. 
     
       
         
           
               
               
               
               
               
               
             
               
                   
                 TABLE 5 
               
               
                   
                   
               
               
                   
                 18* 
                 19 
                 20 
                 21 
                 22 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
            
               
                 Component 
                   
                   
                   
                   
                   
               
               
                 PEI 
                 100 
                 55 
                 50 
                 55 
                 50 
               
               
                 Jet fine Talc 8CF 
                 — 
                 40 
                 40 
                 40 
                 40 
               
               
                 PPA 
                   
                 5 
                 10 
               
               
                 PEI-Si 
                   
                   
                   
                 5 
               
               
                 Nylon 6,6 
                   
                   
                   
                   
                 5 
               
               
                 Property 
               
               
                 Tensile strength (MPa) 
                 100 
                 85 
                 84 
                 74 
                 75 
               
               
                 Tensile modulus (GPa) 
                 3580 
                 11474 
                 11403 
                 11290 
                 11210 
               
               
                 % Elongation 
                 7 
                 1 
                 1 
                 1 
                 1 
               
               
                 Flexural strength (GPa) 
                 165 
                 137 
                 124 
                 115 
                 102 
               
               
                 Flexural Modulus (MPa) 
                 3510 
                 10909 
                 11019 
                 10197 
                 10727 
               
               
                 Unnotched Impact (J/m) 
                 1335 
                 193 
                 172 
                 170 
                 144 
               
               
                 MFR 337° C., 6.7 Kg, 
                 17.8 
                 8 
                 12 
                 7 
                 49 
               
               
                 5 min (g/10 min) 
               
               
                 HDT (1.82 MPa) 
                 198 
                 205 
                 200 
                 207 
                 198 
               
               
                 No. of drops for 
                 10 
                 100 
                 100 
                 100 
                 100 
               
               
                 tracking@ 250 Volts 
               
               
                 Tracking Voltage (Volts) 
                 162 
                 276 
                 323 
                 308 
                 309 
               
               
                 PLC Rating 
                 4 
                 2 
                 2 
                 2 
                 2 
               
               
                   
               
               
                 *Comparative Example 
               
            
           
         
       
     
     Comparative example 1 shows that a composition containing 100% PEI has a number of drops to tracking at 250 volts of 10 drops, and tracking voltage of 162 volts. By blending 5 to 10 wt % of PPA or PEI-Si with polyetherimide and talc having a D95 of 5.7 micrometers, compositions having a combination of a tensile strength greater than or equal to 70 MPa, tensile modulus greater than or equal to 11,000 GPa, HDT greater than or equal to 200° C., number of drops to tracking at 250 volts greater than or equal to 50 drops, and tracking voltage is greater than or equal to 275 volts can be provided. Comparative example 22 shows that blending 5 wt % of nylon 6,6 with polyetherimide and talc slightly decreases the HDT of the polyetherimide composition 
     Examples 23-27 
     Examples 23-27 demonstrate the effect of the addition of various fillers to polyetherimide on tensile strength, tensile modulus, and CTI properties. Formulations and results are shown in Table 6. 
     
       
         
           
               
               
               
               
               
               
             
               
                 TABLE 6 
               
               
                   
               
               
                 Component 
                 23* 
                 24* 
                 25* 
                 26* 
                 27* 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
            
               
                 PEI 
                 60 
                 60 
                 60 
                 60 
                 60 
               
               
                 Mica 
                 40 
               
               
                 Hydrotalcite 
                   
                 40 
               
               
                 Zirconium silicates 
                   
                   
                 40 
               
               
                 Silica 
                   
                   
                   
                 40 
               
               
                 Aluminum silicate 
                   
                   
                   
                   
                 40 
               
               
                 Property 
               
               
                 Tensile strength (MPa) 
                 98 
                 43 
                 93 
                 43 
                 25 
               
               
                 Tensile modulus (GPa) 
                 10302 
                 4564 
                 5357 
                 5681 
                 5902 
               
               
                 % Elongation 
                 1 
                 1 
                 4 
                 1 
                 1 
               
               
                 Flexural strength (GPa) 
                 220 
                 85 
                 153 
                 75 
                 77 
               
               
                 Flexural Modulus (MPa) 
                 10810 
                 4944 
                 5432 
                 5790 
                 6321 
               
               
                 MFR 337° C., 6.7 Kg, 5 min 
                 11 
                 21 
                 9 
                 33 
                 46 
               
               
                 (g/10 min) 
               
               
                 Unnotched Impact (J/m) 
                 153 
                 163 
                 460 
                 184 
                 65 
               
               
                 HDT (1.82 MPa) 
                 199 
                 179 
                 200 
                 177 
                 170 
               
               
                 No. of drops for 
                 10 
                 6 
                 5 
                 10 
                 5 
               
               
                 tracking@ 250 Volts 
               
               
                   
               
               
                 *Comparative Example 
               
            
           
         
       
     
     Comparative examples 23-27 show that formulations containing 60 wt % of polyetherimide and 40 wt % of mica, or 40 wt % of hydrotalcite, or 40 wt % of zirconium silicates, or 40 wt % of silica, or 40 wt % of aluminum silicate have poor CTI performance with number of drops to tracking at 250 volts being 10, 6, 5, 10, and 5 respectively. The number of drops to tracking at 250 volts for polyetherimide is 5 drops. Accordingly, the addition of 40 wt % of aluminum silicate or 40 wt % of zirconium silicates does not improve the CTI performance of polyetherimide at all. The addition of 40 wt % of mica, 40 wt % of hydrotalcite, or 40 wt % of silica only slightly improves the CTI performance of polyetherimide with the number of drops to tracking at 250 volts still failing the 50 drops test. 
     Examples 28-35 
     Examples 28-35 demonstrate the effect of the addition of various fillers to polyetherimide. Formulations and results are shown in Table 7. 
     
       
         
           
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 7 
               
               
                   
               
               
                   
                 28* 
                 29* 
                 30* 
                 31* 
                 32* 
                 33* 
                 34* 
                 35* 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
            
               
                 Component 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 PEI 
                 60 
                 60 
                 60 
                 60 
                 60 
                 60 
                 60 
                 60 
               
               
                 Barium Titanate (3-12 micrometers) 
                 40 
               
               
                 Barium Titanate (&lt;3 micrometers) 
                   
                 40 
               
               
                 Aluminum oxide (Acidic) 
                   
                   
                 40 
               
               
                 Bentonite 
                   
                   
                   
                 40 
               
               
                 Halloysite clay 
                   
                   
                   
                   
                 40 
               
               
                 Magnesium Oxide 
                   
                   
                   
                   
                   
                 40 
               
               
                 Calcium Hydroxyapatite 
                   
                   
                   
                   
                   
                   
                 40 
               
               
                 Calcium carbonate 
                   
                   
                   
                   
                   
                   
                   
                 40 
               
               
                 Property 
               
               
                 Tensile strength (MPa) 
                 13 
                 86 
                 68 
                 35 
                 54 
                 40 
                 100 
                 84 
               
               
                 Tensile modulus (GPa) 
                 2209 
                 4549 
                 4879 
                 4399 
                 5756 
                 4735 
                 4140 
                 5057 
               
               
                 % Elongation 
                 1 
                 3 
                 1 
                 1 
                 1 
                 1 
                 4 
                 2 
               
               
                 Flexural strength (GPa) 
                 44 
                 181 
                 105 
                 59 
                 61 
                 87 
                 120 
                 121 
               
               
                 Flexural Modulus (MPa) 
                 2660 
                 4879 
                 5369 
                 4814 
                 6122 
                 4826 
                 4222 
                 5502 
               
               
                 MFR 337° C., 6.7 Kg, 5 min (g/10 min) 
                 17 
                 12 
                 14 
                 35 
                 39 
                 14 
                 8 
                 5 
               
               
                 Unnotched Impact (J/m) 
                 104 
                 460 
                 178 
                 57 
                 168 
                 129 
                 231 
                 377 
               
               
                 HDT (1.82 MPa) 
                 181 
                 194 
                 190 
                 187 
                 181 
                 190 
                 184 
                 192 
               
               
                 No. of drops for tracking at 250 volts 
                 19 
                 9 
                 18 
                 3 
                 9 
                 5 
                 9 
                 19 
               
               
                   
               
               
                 *Comparative Example 
               
            
           
         
       
     
     It was expected that fillers having higher dielectric constant will enhance the CTI performance due to better insulating behavior in comparison with fillers having lower dielectric constant. The results are unexpected as the comparative examples shows that filler having higher dielectric constant such as barium titanate doesn&#39;t show the expected improvement in the CTI performance 
     Examples 30-35 show that none of the compositions containing aluminum oxide (acidic), bentonite, halloysite clay, magnesium oxide, calcium hydroxyapatite, or calcium carbonate have a combination of a tensile strength greater than or equal to 70 MPa, tensile modulus of greater than or equal to 10,000 GPa, impact strength greater than or equal to 200 J/m, and a number of drops to tracking at 250 volts greater than or equal to 50 drops. 
     Set forth below are specific embodiments of polyetherimide compositions, methods of manufacture and articles comprising the same. 
     In an embodiment, a composition comprises, based on the total weight of the composition, 40 to 80 wt % of a polyetherimide; 10 to 50 wt % of talc; and 1 to 15 wt % of a polymer additive comprising a polyphthalamide, a poly(siloxane-etherimide) copolymer, aliphatic polyamide, or a combination comprising at least one of the foregoing; wherein the composition has a number of drops to tracking at 250 volts of greater than or equal to 50 drops determined according to ASTM D-3638-85. 
     In another embodiment, a composition comprises, based on the total weight of the composition, 40 to 70 wt % of a polyetherimide; and 30 to 50 wt % of talc; and 1 to 15 wt % of a polymer additive comprising a polyphthalamide, a poly(siloxane-etherimide) copolymer, aliphatic polyamide, or a combination comprising at least one of the foregoing; wherein the composition has: a number of drops to tracking at 250 volts of greater than or equal to 50 drops determined according to ASTM D-3638-85; a tensile strength greater than or equal to 50 MPa determined according to ASTM D638; and a tensile modulus of greater than or equal to 10,000 GPa determined according to ASTM method D638. 
     For the foregoing embodiments, one or more of the following conditions can apply: (a) the composition has a tensile strength greater than or equal to 65 MPa determined according to ASTM D638 and a tensile modulus greater than equal to 10,000 GPa determined according to ASTM D638; (b) the polyetherimide comprises units of the formula (1) wherein R is the same or different, and is a substituted or unsubstituted divalent organic group, T is —O— or a group of the formula —O—Z—O— wherein the divalent bonds of the —O— or the —O—Z—O— group are in the 3,3′,3,4′,4,3′, or the 4,4′ positions; and wherein Z is an aromatic C 6-24  monocyclic or polycyclic moiety optionally substituted with 1 to 6 C 1-8  alkyl groups, 1 to 8 halogen atoms, or a combination thereof, provided that the valence of Z is not exceeded, preferably R is a divalent group of the formula (2) wherein Q 1  is —O—, —S—, —C(O)—, —SO 2 —, —SO—, —C y H 2y — wherein y is an integer from 1 to 5 or a halogenated derivative thereof, or —(C 6 H 10 ) z — wherein z is an integer from 1 to 4, and Z is a divalent group of the formula (3a) wherein Q is —O—, —S—, —C(O)—, —SO 2 —, —SO—, or —C y H 2y — wherein y is an integer from 1 to 5 or a halogenated derivative thereof, more preferably R is m-phenylene and Q is isopropylidene; (c) the poly(siloxane-etherimide) copolymer comprises etherimide units of the formula (1), wherein R is the same or different, and is a substituted or unsubstituted divalent organic group, T is —o— or a group of the formula —O—Z—O— wherein the divalent bonds of the —O— or the —O—Z—O— group are in the 3,3′,3,4′,4,3′, or the 4,4′ positions; and wherein Z is an aromatic C 6-24  monocyclic or polycyclic moiety optionally substituted with 1 to 6 C 1-8  alkyl groups, 1 to 8 halogen atoms, or a combination thereof, provided that the valence of Z is not exceeded; preferably R is m-phenylene and Q is isopropylidene; and siloxane units derived from a polysiloxane diamine of the formula (8) wherein R′ is each independently a C 1 -C 13  hydrocarbon group, R 4  is each independently a C 2 -C 20  hydrocarbon group, and E has an average value of 5 to 100, preferably R′ is methyl, R 4  is 1,3-propylene, and E is 5 to 100; and in the etherimide units, R is phenylene and Z is a residue of bisphenol A; (e) polyphthalamide comprises units of the formula (10), wherein each G 1  is independently a branched or unbranched C 4-8  alkyl group, preferably each G 1  is a 1,6-hexyl group; (f) the aliphatic polyamide comprises units of the formula (11), wherein each G 2  and G 3  are independently a branched or unbranched C 4-12  alkyl group; (f) talc has a D95 of 2 to 6 micrometers; (g) the composition further comprises an additive selected from a processing aid, a heat stabilizer, an ultraviolet light absorber, a colorant, a flame retardant, or a combination comprising at least one of the foregoing; or (h) the composition comprises, based on the total weight of the composition, from 0.0001 to 20 wt % of each additive present in the composition. 
     In an embodiment, an insulating material comprises the composition of any one or more of the above embodiments. 
     In another embodiment, disclosed is an article selected from a molded article, a thermoformed article, an extruded film, an extruded sheet, one or more layers of a multi-layer article, a substrate for a coated article, and a substrate for a metallized article made from the composition of any one or more of the foregoing embodiments. 
     A method of manufacture of an article, comprises molding, extruding, or casting the composition of any one or more of the above embodiments. 
     A method of controlling the tracking of an electrical current of an article of manufacture comprises providing a composition of any one or more of the above embodiments and processing the composition to form an article of manufacture. 
     In the foregoing articles or methods, the article can be a solar apparatus, an electrical junction box, an electrical connector, an electrical vehicle charger, an outdoor electrical enclosure, a smart meter enclosure, a smart grid power node, a photovoltaic frame and a miniature circuit breaker. 
     The singular forms “a”, “an”, and “the” include plural referents unless the context clearly dictates otherwise. “Or” means “and/or”. The endpoints of all ranges directed to the same component or property are inclusive and independently combinable. Unless defined otherwise, technical and scientific terms used herein have the same meaning as is commonly understood by one of skill in the art to which this invention belongs. 
     As used herein, a “combination” is inclusive of blends, mixtures, alloys, reaction products, and the like. Compounds are described using standard nomenclature. For example, any position not substituted by any indicated group is understood to have its valency filled by a bond as indicated, or a hydrogen atom. A dash (“-”) that is not between two letters or symbols is used to indicate a point of attachment for a substituent. For example, -CHO is attached through carbon of the carbonyl group. 
     The term “alkyl” includes branched or straight chain, unsaturated aliphatic C 1-30  hydrocarbon groups e.g., methyl, ethyl, n-propyl, i-propyl, n-butyl, s-butyl, t-butyl, n-pentyl, s-pentyl, n- and s-hexyl, n-and s-heptyl, and, n- and s-octyl. “Alkenyl” means a straight or branched chain, monovalent hydrocarbon group having at least one carbon-carbon double bond (e.g., ethenyl (—HC═CH 2 )). “Alkoxy” means an alkyl group that is linked via an oxygen (i.e., alkyl-O—), for example methoxy, ethoxy, and sec-butyloxy groups. “Alkylene” means a straight or branched chain, saturated, divalent aliphatic hydrocarbon group (e.g., methylene (—CH 2 —) or, propylene (—(CH 2 ) 3 —)). “Cycloalkylene” means a divalent cyclic alkylene group, —C n H 2n-x , wherein x represents the number of hydrogens replaced by cyclization(s). The term “aryl” means an aromatic hydrocarbon group containing the specified number of carbon atoms, such as to phenyl, tropone, indanyl, or naphthyl. The prefix “hetero” means that the compound or group includes at least one ring member that is a heteroatom (e.g., 1, 2, or 3 heteroatom(s)), wherein the heteroatom(s) is each independently N, O, S, or P. 
     “Substituted” means that the compound or group is substituted with at least one (e.g., 1, 2, 3, or 4) substituents instead of hydrogen, where each substituent is independently nitro (—NO 2 ), cyano (—CN), hydroxy (—OH), halogen, thiol (—SH), thiocyano (—SCN), C 1-6  alkyl, C 2-6  alkenyl, C 2-6  alkynyl, C 1-6  haloalkyl, C 1-9  alkoxy, C 1-6  haloalkoxy, C 3-12  cycloalkyl, C 5-18  cycloalkenyl, C 6-12  aryl, C 7-13  arylalkylene (e.g, benzyl), C 7-12  alkylarylene (e.g, toluyl), C 4-12  heterocycloalkyl, C 3-12  heteroaryl, C 1-6  alkyl sulfonyl (—S(═O) 2 -alkyl), C 6-12  arylsulfonyl (—S(═O) 2 -aryl), or tosyl (CH 3 C 6 H 4 SO 2 —), provided that the substituted atom&#39;s normal valence is not exceeded, and that the substitution does not significantly adversely affect the manufacture, stability, or desired property of the compound. When a compound is substituted, the indicated number of carbon atoms is the total number of carbon atoms in the group, including those of the substituent(s). 
     All references cited herein are incorporated by reference in their entirety. While typical embodiments have been set forth for the purpose of illustration, the foregoing descriptions should not be deemed to be a limitation on the scope herein. Accordingly, various modifications, adaptations, and alternatives can occur to one skilled in the art without departing from the spirit and scope herein.