Patent Publication Number: US-7906042-B2

Title: Branched surfactant having fluoroalkyl group and hydrocarbon group

Description:
This is a divisional of application Ser. No. 11/596,672 filed Jan. 29, 2007, which is a National Stage Application filed under §371 of PCT Application No. PCT/JP2005/008893 filed May 16, 2005. The entire disclosures of the prior applications are hereby incorporated by reference. 
    
    
     TECHNICAL FIELD 
     The present invention relates to a branched surfactant having a fluoroalkyl group and a hydrocarbon group. 
     The surfactant of the invention, when used in combination with liquid, subcritical, or supercritical carbon dioxide, can improve the function of carbon dioxide as a solvent for chemical reactions, washing, extraction, dyeing, etc. 
     BACKGROUND OF THE INVENTION 
     Due to increasing awareness of environmental problems, attention has been drawn to techniques using CO 2  as a solvent in place of highly toxic organic solvents. If it makes it possible to dissolve a compound in CO 2 , the cost of wastewater treatment may be sharply reduced. Therefore, attention has been drawn particularly to the application of such techniques to industrial fields which require expensive waste water treatments, such as dyeing, plating, organic synthesis, chemical reaction, washing, extraction, etc. 
     Such applications need surfactants to mix carbon dioxide with polar compounds. 
     Examples of hybrid fluorine-based compounds having both a hydrocarbon group and a fluoroalkyl group in the molecule are mentioned as follows: Patent Document 1 discloses H(CF 2 CF 2 ) n (CH 2 CH 2 O) n OOCCH(OSO 3 Na)CH 2 COOR as an additive for improving the application properties of a light-sensitive material; Patent Document 2 discloses H(CF 2 CF 2 ) n CH 2 OCH 2 CH(OSO 3 Na)R as an additive for improving the application properties of a light-sensitive material; and Patent Document 3 discloses H(CF 2 CF 2 ) n CH 2 OCH 2 CH(OSO 3 Na)CH 2 OR as an antistatic material for a light-sensitive material. 
     Surfactants that function well in carbon dioxide are extremely limited. For example, only sulfosuccinic acid esters having fluorine groups, which require two hydrophobic chains or branched hydrophobic group, are reported in Non-patent Documents 1 to 3. Non-patent Document 4 reports that C 7 F 15 CH(OSO 3 Na)C 7 H 15  has a high ability to incorporate water into carbon dioxide. However, due to low stability, this compound has not been put into practical use. Moreover, a test performed by the present inventors confirmed that the water-uptake ability of this compound is insufficient. 
     In view of the above, the synthesis of a hybrid surfactant with stability and an advanced function has been reported in recent years (Non-patent Documents 5 to 8). However, these known hybrid surfactants do not fulfill their functions in carbon dioxide (Non-patent Document 3). 
     Although phosphates as reported in Non-patent Document 9 function well in carbon dioxide, phosphates have problems with stability during long-term use due to the possibility of hydrolysis. A test performed by the present inventors confirmed that phosphates also do not fulfill their functions satisfactorily. 
     Patent Document 1: Japanese Unexamined Patent Publication No. 1976-32322 
     Patent Document 2: Japanese Examined Patent Publication No. 1977-25087 
     Patent Document 3: Japanese Examined Patent Publication No. 1977-26687 
     Non-patent Document 1: Progr, Colloid Polym, Sci., 2000, vol. 115, page 214 
     Non-patent Document 2: Langmuir, 2001, vol. 17, page 274 
     Non-patent Document 3: Langmuir, 2003, vol. 19, page 220 
     Non-patent Document 4: Langmuir, 1994, vol. 10, page 3536 
     Non-patent Document 5: Langmuir, 1995, vol. 11, page 466 
     Non-patent Document 6: Proceeding of Yukagaku Toronkai, 2000 (Abstract, pages 305 and 306) 
     Non-patent Document 7: Proceeding of Yukagaku Toronkai, 2002 (Abstract, page 101) 
     Non-patent Document 8: J. Am. Chem. Soc., 2002, vol. 124, page 6516 
     Non-patent Document 9: J. Am. Chem. Soc., 2002, vol. 124, page 1834 
     DISCLOSURE OF THE INVENTION 
     Problem to be Solved by the Invention 
     An object of the invention is to provide a surfactant usable in a carbon dioxide-water system. 
     Means for Solving the Problem 
     The invention provides the following surfactants. 
     Item 1. A surfactant represented by Formula (I): 
     
       
         
         
             
             
         
       
     
     wherein Rf represents a fluoroalkyl group which may have an ether bond; 
     Rh represents an alkyl group; 
     r represents 1 or 0; 
     when r=0, Z 1  and Z 2  represent (CH 2 ) n1 —(X 1 ) p1 — and —(X 2 ) q1 —, respectively; and 
     when r=1, Z 1  and Z 2  represent (CH 2 Y) p2 —CH 2 — and —(CH 2 Y) q2 —, respectively, 
     wherein X 1  and X 2  may be the same or different and each represents a divalent linking group, 
     p1 represents 0 or 1, 
     q1 represents 0 or 1, 
     n1 represents an integer of 1-10; 
     Y represents O, S or NR, wherein R represents a hydrogen atom, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, or t-butyl; 
     p2 and q2 each represent 0 or 1 but are not 0 at the same time; and 
     M represents a hydrogen atom, alkali metal, ½ alkaline earth metal or ammonium. 
     Item 2. A surfactant represented by Formula (IA) according to item 1: 
     
       
         
         
             
             
         
       
     
     wherein Rf represents a fluoroalkyl group which may have an ether bond; 
     Rh represents an alkyl group; 
     X 1  and X 2  may be the same or different and each represents a divalent linking group, 
     p1 represents 0 or 1, 
     q1 represents 0 or 1, 
     n1 represents an integer of 1-10; and 
     M represents a hydrogen atom, alkali metal, ½ alkaline earth metal or ammonium. 
     Item 3. A surfactant represented by Formula (IB) according to item 1: 
     
       
         
         
             
             
         
       
     
     wherein Rf represents a (per)fluoroalkyl group, (per)fluoroether group, or (per)fluoropolyether group; 
     Rh represents an alkyl group; 
     Y represents O, S, or NR, wherein R represents a hydrogen atom, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, or t-butyl; 
     p2 and q2 each represent 0 or 1 but are not 0 at the same time; and 
     M represents a hydrogen atom, alkali metal, ½ alkaline earth metal or ammonium. 
     Item 4. A surfactant according to claim  1 , wherein Rf has 5 to 12 carbon atoms. 
     Item 5. A surfactant according to item 2 represented by Formula: Rf(CH 2 ) n1 OOCCH(SO 3 M)CH 2 COORh, 
     wherein Rf, Rh, n1, and M are as defined above. 
     Item 6. A surfactant according to item 2 represented by Formula: Rf(CH 2 ) n1 OCCH(SO 3 M)Rh, 
     wherein Rf, Rh, n, and M are as defined above. 
     Item 7. A surfactant according to item 3 represented by Formula: RfCH 2 OCH 2 CH(OSO 3 M)CH 2 ORh, 
     wherein Rf, Rh, and M are as defined above. 
     Item 8. Use of a surfactant according to item 1 for adding to a system comprising carbon dioxide and a polar compound. 
     Item 9. Use of a surfactant according to item 8, wherein the polar compound is water. 
     Item 10. Use of a surfactant according to item 1 for improving solubility of a polar compound in supercritical, subcritical, or liquid carbon dioxide. 
     Effect of the Invention 
     The present invention provides a surfactant with a high ability to incorporate water into carbon dioxide despite water having a low compatibility with carbon dioxide. Thus, the use of the surfactant of the invention in a carbon dioxide-polar compound system achieves a well-mixed state of water and carbon dioxide. 
     Moreover, the invention can provide a surfactant having a sufficiently high water-uptake value and a sufficient ability to form micelles in a mixed system of CO 2 /water and a polar compound (e.g., inorganic salt, polar organic compound, etc.). 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1(A)  is a view schematically showing a device for determining W values. 
         FIG. 1(B)  is a view showing a view cell in detail, in which a sample is placed in portion “a”. 
     
    
    
     BEST MODE FOR CARRYING OUT THE INVENTION 
     The surfactants of the invention make it possible to mix CO 2  (supercritical, subcritical, or liquid) with polar compounds, such as water. Moreover, the surfactants of the invention can improve, using CO 2  as a solvent, the efficiency of electrochemical reactions, and also washing, dyeing, extraction, etc. The electrochemical reactions refer to organic/inorganic chemical reactions, plating, etc., in which a polar compound, such as water and the like, is treated. In addition, the surfactants of the invention have stability enough to withstand repeated use in CO 2 -water systems. 
     Preferable as such surfactants are hybrid surfactants having a sulfate group or a sulfonic acid group, and also one fluoroalkyl group and one alkyl group. 
     Examples of polar compounds to be mixed with a CO 2  solvent include water; organic solvents miscible with water such as alcohols (e.g., methanol, ethanol, propanol, butanol, etc.), water-containing alcohols, DMF, DMSO, formamide, glycols (e.g., ethylene glycol, propylene glycol, etc.), acetonitrile, THF, etc.; or mixtures of water and these organic solvents. Among these, water is preferable. Furthermore, metal particles, inorganic salts, organic salts, bio-compounds (e.g., phospholipids, saccharides, proteins, carbohydrates, etc.), etc. can be mentioned. 
     In the surfactants represented by Formula (I), Rf represents a linear or branched fluoroalkyl group which may have an ether bond. Specific examples thereof include (per)fluoroalkyl groups, (per)fluoroether groups, and (per)fluoropolyether groups. Rf has 4 to 50 carbon atoms. The number of carbons of a fluoroalkyl group in which Rf has no ether bond is 4 to 20, preferably 5 to 18, and more preferably 5 to 12. The number of carbons of a fluoroalkyl group in which Rf has an ether bond is 4 to 50, preferably 5 to 40, and more preferably 5 to 35. 
     When r=0, preferable examples of Rf are as follows. Preferable examples of fluoroalkyl groups having no ether bond include: 
     C m F 2m+1 —(n represents an integer of 4 to 20 and m represents an integer of 1 to 10); and 
     HC m F 2m —(n represents an integer of 4 to 20 and m represents an integer of 1 to 10). 
     Preferable examples of fluoroalkyl groups having an ether bond include: 
     C m F 2m+1 O(CF 2 CF 2 O) r CF 2 —(m represents an integer of 1 to 10 and r represents an integer of 1 to 15); 
     C m F 2m+1 O(CF(CF 3 )CF 2 O) r CF(CF 3 )—(m represents an integer of 1-10 and r represents an integer of 1 to 15); 
     HC m F 2m O(CF 2 CF 2 O) r CF 2 —(m represents an integer of 1 to 10 and r represents an integer of 1 to 15); and 
     HC m F 2m O(CF(CF 3 )CF 2 O) r CF(CF 3 )—(M represents an integer of 1 to 10 and r represents an integer of 1 to 15). 
     Preferable examples of Rf among the compounds represented by Formula (I) in which r=1 are as follows. 
     Examples of (per)fluoroalkyl groups include: 
     C n F 2n+1 (CH 2 ) m —(n represents an integer of 5 to 12 and m represents an integer of 1 to 10); and 
     HC n F 2n (CH 2 ) m —(n represents an integer of 5 to 12 and m represents an integer of 1 to 10). 
     Examples of (per)fluoroether groups include Rf1-O—Rf2, such as C 3 F 7 OCF(CF 3 )— and the like, wherein Rf1 is a C 1-6  linear or branched (per)fluoroalkyl group and Rf2 is a C 1-4  linear or branched (per)fluoroalkylene group. 
     Examples of (per)fluoropolyether groups include Rf1-(O—Rf2) r , such as C 3 F 7 OCF(CF 3 )CF 2 OCF(CF 3 )— and the like, wherein (Rf1 and Rf2 are as defined above and r represents an integer of 2 to 4). 
     Rh is a linear or branched alkyl group having 3 to 18 carbon atoms, preferably 4 to 12, and more preferably 4 to 10. Specific preferable examples of Rh include (n-, sec-, iso-, tert-) butyl, pentyl, hexyl, heptyl, octyl, nonyl, and decyl. 
     In order to achieve a balance between a portion that has affinity with CO 2  (Rf) and a hydrophilic group (Rh), the value obtained by dividing the number of carbon atoms of Rf by the number of carbon atoms of Rh is preferably in the range of 1/2 to 2/1, and more preferably in the range of 2/3 to 3/2. 
     M represents a hydrogen atom, alkali metal (Na, K, Li, Cs), ½ alkaline earth metal (Ca, Mg, Ba), ammonium (NH 4 ), or quaternary ammonium (NR 4 ; R represents a C 1-4  linear or branched alkyl group). 
     When r=0, Z 1  and Z 2  represent (CH 2 ) n1 —(X 1 ) p1 — and —(X 2 ) q1 —, respectively. Examples of divalent linking groups represented by X 1  and X 2  include O, S, NH, NR, C═O, C(O)O, OC(O), C(O)S, SC(O), C(O)NH, C(O)NR, NH(O)C, NR(O)C (wherein R is a C 1-4  linear or branched alkyl group). Between X 1  and/or X 2  and CH(SO 3 M) may be positioned a linear or branched alkylene group which may be fluorinated (e.g., (CH 2 ) m , (CF 2 ) n , CF(CF 3 ), (CF 2 ) n (CH 2 ), etc., m and n are integers of 1 to 3). 
     Preferable divalent linking groups represented by X 1  and X 2  are mentioned as follows: 
     —(CH 2 ) n COO—(n is an integer of 0 to 4, preferably 0 or 1) and —(CH 2 ) n O—(n is an integer of 0 to 4, preferably 0 or 1), wherein p1 is 0 or 1; q1 is 0 or 1; n1 is an integer of 1 to 10, preferably 1 to 5; when r=1, Z 1  and Z 2  represent (CH 2 Y) p2 —CH 2 — and —(CH 2 Y) q2 —, respectively; Y is O, S, or NR (R represents a hydrogen atom, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, or t-butyl), preferably O or NR, and more preferably O; and p2 and q2 represent 0 or 1 but are not 0 at the same time. 
     The surfactants of the invention are commercially available or can be easily produced by a person skilled in the art according to known methods (e.g., Patent Documents 1 to 3). 
     In the invention, the amount of surfactant is about 0.001 to about 2000 wt %, preferably about 0.01 to about 1000 wt %, more preferably about 0.01 to about 500 wt %, and particularly preferably about 0.1 to about 100 wt % based on the amount of polar compound to be dissolved in an aqueous solution or carbon dioxide. 
     In addition, an organic solvent (co-solvent) described below can be added to a CO 2 -water system. For example, alcohols such as methanol, ethanol, propanol, butanol, pentanol, etc.; ketones such as acetone and the like; acetonitrile; esters such as ethyl acetate, etc.; ethers such as ethyl ether; halogenated compounds such as frons, methylene chloride, chloroform, etc. Among these, organic solvents with low toxicity and low molecular weight are preferable. 
     Unlike the case where surfactants are used in normal two-phase systems, the weight of the surfactant for use in the invention may be higher than that of a polar compound depending on the kind of the polar compound. For example, in the case of chemical reaction using a metal salt or the like as a catalyst in CO 2 , the amount of surfactant sometimes exceeds 100 wt %. 
     The surfactant of the invention is preferably used in a two-phase system between CO 2  (liquid, subcritical, or supercritical state) and water or a polar compound. 
     EXAMPLES 
     Hereinafter, the present invention will be described with reference to Examples and Reference Examples in detail, but is not limited thereto. 
     (A) Surfactants Having a Sulfonate Group (r=0 in Formula (I)) 
     Examples 1A to 5A 
     Following the description of Japanese Unexamined Patent Publication No. 1976-32322, compounds 1A-5A were synthesized. 
     The physical properties of the obtained compounds are as follows: 
     1A: C 6 F 13 CH 2 CH 2 OOCCH(SO 3 Na)CH 2 COOC 6 H 13    
     Colorless and Amorphous: 
       1 H-NMR (CD 3 OD): δ 0.90 (t, J=6.9 Hz, 3H), 1.19-1.50 (m, 6H), 1.50-1.75 (m, 2H), 2.45-2.79 (m, 2H), 2.93-3.27 (m, 2H), 4.00-4.22 (m, 3H), 4.34-4.50 (m, 2H). 
     IR (KBr, cm −1 ): 2968, 1740, 1241, 1209, 1146, 1033. 
     2A: C 6 F 13 CH 2 CH 2 OOCCH(SO 3 Na)CH 2 COOC 8 H 17    
     Colorless and Amorphous: 
       1 H-NMR (CD 3 OD): δ 0.94 (t, J=7.3 Hz, 3H), 1.27-1.50 (m, 10H), 1.50-1.73 (m, 2H), 2.45-2.80 (m, 2H), 2.94-3.38 (m, 2H), 4.00-4.20 (m, 3H), 4.33-4.50 (m, 2H). 
     IR (KBr, cm −1 ): 2969, 1737, 1241, 1146, 1054. 
     3A: C 8 F 17 CH 2 CH 2 OOCCH(SO 3 Na)CH 2 COOC 10 H 21    
     Colorless and Amorphous: 
       1 H-NMR(CD 3 OD): δ 0.89 (t, J=6.8 Hz, 3H), 1.15-1.45 (m, 14H), 1.50-1.75 (m, 2H), 2.45-2.79 (m, 2H), 2.94-3.27 (m, 2H), 4.02-4.22 (m, 3H), 4.36-4.51 (m, 2H). 
     IR (KBr, cm −1 ): 2930, 1741, 1245, 1220, 1153, 1055. 
     4A: C 8 F 17 CH 2 CH 2 OOCCH(SO 3 Na)CH 2 COOC 6 H 13    
     Colorless and Amorphous: 
       1 H-NMR (CD 3 OD): δ 0.91 (t, J=6.9 Hz, 3H), 1.20-1.50 (m, 6H), 1.50-1.76 (m, 2H), 2.44-2.80 (m, 2H), 2.94-3.47 (m, 2H), 4.02-4.20 (m, 3H), 4.33-4.52 (m, 2H). 
     IR (KBr, cm −1 ): 2967, 1740, 1244, 1210, 1152, 1054. 
     5A: C 4 F 9 CH 2 CH 2 OOCCH(SO 3 Na)CH 2 COOC 4 H 9    
     Colorless and Amorphous: 
       1 H-NMR(CD 3 OD): δ 0.94 (t, J=7.3 Hz, 3H), 1.25-1.50 (m, 2H), 1.50-1.73 (m, 2H), 2.45-2.80 (m, 2H), 2.94-3.37 (m, 2H), 4.02-4.22 (m, 3H), 4.33-4.50 (m, 2H). 
     IR (KBr, cm −1 ): 2967, 1739, 1229, 1135, 1054. 
     Comparative Examples 1A-5A 
     Compounds (6A to 8A) having two fluoroalkyl groups were synthesized according to Bull. Chem. Soc. Jpn., 1991, vol. 64, page 3262. Compound 9A was synthesized in the same manner as described above using an alcohol compound C 4 F 9 CH 2 CH 2 CH 2 CH 2 OH obtained by reducing, with lithium aluminum hydride, a product obtained by radical addition reaction between C 4 F 9 I with CH 2 ═CHCH 2 CH 2 OH. Furthermore, compound 10A was synthesized according to Langmuir 1994, 10, 3536. 
     The structures and compound numbers are shown below. 
     6A: H(CF 2 ) 4 CH 2 OOCCH(SO 3 Na)CH 2 COOCH 2 (CF 2 ) 4 H 
     7A: H(CF 2 ) 6 CH 2 OOCCH(SO 3 Na)CH 2 COOCH 2 (CF 2 ) 6 H 
     8A: F(CF 2 ) 8 CH 2 CH 2 OOCCH(SO 3 Na)CH 2 COOCH 2 CH 2 (CF 2 ) 8 F 
     9A: F(CF 2 ) 4 (CH 2 ) 4 OOCCH(SO 3 Na)CH 2 COO(CH 2 ) 4 (CF 2 ) 4 F 
     10A: C 7 F 15 CH(OSO 3 Na)C 7 H 15    
     Physical Properties of Compound 9A 
     Colorless and Amorphous: 
       1 H-NMR(CD 3 OD): δ 1.56-1.90 (m, 8H), 2.05-2.38 (m, 4H), 2.95-3.28 (m, 2H), 4.02-4.30 (m, 5H). 
     IR (KBr, cm −1 ): 2968, 1738, 1224, 1134, 1051. 
     Test Example 1A 
     A functional test was performed on the compounds obtained in Examples and Comparative Examples. 
     (1) Method for Determining a W Value and Amount of Water Uptake 
     Using an experimental apparatus shown in  FIG. 1 , the W value and amount of water uptake were determined according to the following processes 1 to 4. 
     1) A surfactant was placed in a proportion of 2 wt % based on the proportion of carbon dioxide in portion “a” of a pressure-proof device with an observation window (i.e., view cell). 
     2) After carbon dioxide was introduced and the pressure and temperature were adjusted as specified in Table 1A, water was introduced into portion “a” from a hexagonal valve. 
     3) When the visual observation of the contents through the observation window (sapphire window) showed that the mixture was transparent single phase, it was judged that water dissolved in carbon dioxide. 
     4) The W value and amount of water uptake were calculated from the highest amount of water uptake possible for maintaining a colorless state, and from the weight of the surfactant used for measurement. 
     The adjusted measurement pressures and temperatures of item 2) above are shown in Table 1A, in which surfactant effects were evaluated based on the ability of each surfactant to incorporate water into carbon dioxide: the W value=(the number of water molecules/the number of surfactant molecules) in a micelle; and water uptake=the weight of water dissolved in carbon dioxide, per gram of surfactant. 
     
       
         
           
               
               
               
             
               
                 TABLE 1A 
               
               
                   
               
               
                   
                 W value (measurement pressure and 
                   
               
               
                 Compound Number 
                 temperature) 
                 Water uptake 
               
               
                   
               
             
            
               
                 1A 
                 30 (33 MPa, 50° C.) 
                 0.9 g 
               
               
                 2A 
                 30 (33 MPa, 50° C.) 
                 0.9 g 
               
               
                 4A 
                 30 (24 MPa, 50° C.) 
                 0.7 g 
               
               
                 6A 
                  7 (31 MPa, 50° C.) 
                 0.2 g 
               
               
                 7A 
                 15 (26 MPa, 56° C.) 
                 0.3 g 
               
               
                 8A 
                 30 (34 MPa, 50° C.) 
                 0.5 g 
               
               
                 9A 
                  9 (17 MPa, 50° C.) 
                 0.2 g 
               
               
                 10A  
                  0 (33 MPa, 50° C.) 
                   0 g 
               
               
                   
               
            
           
         
       
     
     Compound 10A has been reported to be unstable but have advanced function (Langmuir 1994, 10, 3536). However, a test performed by the present inventors showed that compound 10A did not fulfill its function at all. This is probably because the test was performed at 50° C. under the same conditions as in other compounds. After the test, the samples were collected so as to determine the cause by instrumental analysis (NMR). The analysis showed that, small but complicated peaks were observed (decomposition possibly progressed even at 50° C.) in addition to the fact that the sulfate was hydrolyzed, which possibly forms a serious obstacle to the practical use of compound 10A. 
     Although compounds 7A to 8A have been reported to be stable and function best (Langmuir, 2001, vol. 17, page 274; Langmuir, 1997, vol. 13, page 6980), compounds 1A to 4A of the invention function better than compounds 7A to 8A. 
     The evaluation results show that compound 9A does not have high ability of water uptake, even if two carbon chains each have a fluoroalkyl chain and a hydrocarbon chain, and thus the number of carbon atoms in each of fluoroalkyl and hydrocarbon chains is eight in total, respectively. 
     Next, a mixture of compound 6A and AOT:C 8 H 17 OOCCH(SO 3 Na)CH 2 COOC 8 H 17 , which is sulfosuccinic acid ester having only a hydrocarbon group in the molecule, in a molar ratio of 1:1 was examined. 
     As shown below, the results of the examination of the mixture are the same as those obtained with only compound 6A, whose number of molecules is half that of the mixture. This shows that the desired function cannot be achieved by mixing a compound having two hydrocarbon groups with a compound having two fluoroalkyl groups, and that unless the compound has both a fluoroalkyl group and a hydrocarbon group in the molecule, such compound cannot exhibit the advanced function of the invention. 
     
       
         
           
               
               
               
             
               
                 TABLE 2A 
               
               
                   
               
               
                 Compound Number 
                 W value 
                 Water uptake 
               
               
                   
               
             
            
               
                 Compound 6A and AOT 
                 7 (31 MPa, 50° C.) 
                 0.2 g 
               
               
                 (molar ratio of 1:1) 
                   
                 (based on the amount of 
               
               
                   
                   
                 Compound 6A) 
               
               
                 Compound 6A 
                 7 (31 MPa, 50° C.) 
                 0.2 g 
               
               
                   
               
            
           
         
       
     
     The above results reveal that a branched hybrid sulfonate, which has, in the molecule, both a fluoroalkyl group whose carbon number of one carbon chain is at least four and a hydrocarbon chain whose carbon chain length is nearly equal to that of the fluoroalkyl group, function well when a polar compound, such as water, is dissolved in carbon dioxide. 
     (B) Surfactant Group Having a Sulfonate Group (r=1 in Formula (I)) 
     Example 1B 
     1B: C 8 F 17 CH 2 CH(OSO 3 Na)CH 2 OC 8 H 17    
     A mixture of heptadecafluoropropylene oxide (1.09 g, 2.3 mmol), octanol (1.02 g, 7.8 mmol), and one drop of sulfuric acid was heated at 100° C. for 48 hours under stirring. The result was extracted with ethyl acetate, and the organic layer was washed with saturated aqueous sodium bicarbonate and brine. The washed matter was dried with magnesium sulfate, and the solvent was then distilled off under reduced pressure. The reactant obtained was isolated by silica gel column chromatography (n-hexane:EtOAc=30:1), yielding an alcohol compound (830 mg, 60%). To the alcohol compound obtained was added a SO 3 -Py complex (416 mg, 2.6 mmol). The mixture was stirred in 5 ml of pyridine at 40° C. for 24 hours. The reactant was placed in saturated aqueous sodium bicarbonate, and heated to dryness. Inorganic salt was removed from the remaining reactant by extraction with acetone using a Soxhlet extractor, yielding compound 1B (730 mg, two steps, 45%). 
     Colorless and Amorphous: 
       1 H-NMR (CDCl 3 ): δ 0.88 (t, J=6.5 Hz, 3H), 1.15-1.47 (m, 10H) 1.47-1.65 (m, 2H), 2.47-2.87 (m, 2H), 3.35-3.62 (m, 2H), 3.62-3.78 (m, 2H), 4.74-4.90 (m, 1H). 
     IR: (KBr, cm −1 ): 2934, 1243, 1213, 1152, 951. 
     Example 2B 
     2B: C 6 F 13 CH 2 CH(OSO 3 Na)CH 2 OC 6 H 13    
     Tridecafluoro propylene oxide (5.0 g, 13.3 mmol) and hexanol (8.35 ml, 66.5 mmol) were reacted in the presence of sulfuric acid, giving an alcohol compound (3.5 g, 55%). A SO 3 -Py complex (2.3 g, 14.6 mmol) was reacted with this alcohol compound in pyridine (12 ml). Inorganic salt was removed from the rough product by extraction with acetone using a Soxhlet extractor, yielding compound 2B (3.1 g, two steps, 40%). 
     Colorless and Amorphous: 
       1 H-NMR(CDCl 3 ): δ 0.89 (t, J=6.8 Hz, 3H), 1.15-1.44 (m, 7H), 1.44-1.68 (m, 2H), 2.40-2.86 (m, 2H), 3.32-3.76 (m, 4H), 4.70-5.0 (m, 1H). 
     IR (KBr, cm −1 ): 2936, 1244, 1214, 1150. 
     Example 3B 
     3B: H(CF 2 ) 6 CH 2 OCH 2 CH(OSO 3 Na)CH 2 OC 6 H 13    
     In the same manner as in Example 1B, compound 3B (3.1 g, two steps, 52%) was synthesized from dodecafluoroheptyl glycidyl ether (3.88 g, 10 mmol) and hexanol (2.94 g, 30 mmol). 
     Colorless and Amorphous: 
       1 H-NMR(CDCl 3 ): δ 0.89 (t, J=7.0 Hz, 3H), 1.22-1.40 (m, 6H), 1.49-1.60 (m, 2H), 3.43-3.52 (m, 2H), 3.60-3.69 (m, 2H), 3.85 (d-d, J=10.9, 4.4 Hz, 1H), 3.92 (d-d, J=10.9, 4.4 Hz, 1H), 4.13 (t, J=14.1 Hz, 2H), 4.45-4.52 (m, 1H), 6.61 (t-t, J=50.8, 4.9 Hz, 1H). 
     IR (KBr, cm −1 ): 2938, 1240, 1202, 1142, 1045, 797. 
     Example 4B 
     4B: H(CF 2 ) 8 CH 2 OCH 2 CH(OSO 3 Na)CH 2 OC 8 H 17    
     In the same manner as in Example 1B, an alcohol compound was synthesized from hexadecafluoroheptyl glycidyl ether (8.06 g, 16.5 mmol) and octanol (13 ml, 82.3 mmol), and sulfonate compound 4B (5.0 g, two steps, 42%) was then synthesized from the alcohol compound. 
     Colorless and Amorphous: 
       1 H-NMR (CD 3 OH): δ 0.89 (t, J=6.9 Hz, 3H), 1.15-1.46 (m, 10H) 1.46-1.65 (m, 2H), 3.48 (t, J=6.4 Hz, 2H), 3.60-3.75 (m, 2H), 3.80-4.00 (m, 2H), 4.16 (t, J=14.1 Hz, 2H), 4.43-4.55 (m, 1H), 6.69 (t-t, J=51.1 Hz, 5.1 Hz, 1H). 
     IR (KBr, cm −1 ): 2936, 1214, 1149, 1043, 806. 
     Example 5B 
     5B: H(CF 2 ) 6 CH 2 OCH 2 CH(OSO 3 Na)CH 2 OC 8 H 17    
     In the same manner as in Example 1B, an alcohol compound was synthesized from dodecafluoroheptyl glycidyl ether (5.92 g, 15.2 mmol) and octanol (12 ml, 76 mmol), and compound 5B (4.2 g, two steps, 45%) was then synthesized from a SO 3 -Py complex via the alcohol compound. 
     Colorless and Amorphous: 
       1 H-NMR(CD 3 OH): δ 0.89 (t, J=6.9 Hz, 3H), 1.17-1.47 (m, 10H), 1.47-1.66 (m, 2H), 3.45 (t, J=6.4 Hz, 2H), 3.60-3.74 (m, 2H), 3.80-4.00 (m, 2H), 4.15 (t, J=14.1 Hz, 2H), 4.43-4.55 (m, 1H), 6.65 (t-t, J=51.1, 5.1 Hz, 1H). 
     IR (KBr, cm −1 ): 2936, 1202, 1142, 1043, 796. 
     Example 6B 
     6B: C 3 F 7 OCF(CF 3 )CH 2 OCH 2 CH(OSO 3 Na)CH 2 OCH 2 CH(C 2 H 5 )C 4 H 9    
     In the same manner as in Example 1B, an aqueous sodium hydroxide solution (1.3 g of NaOH and 6.3 ml of water) was added dropwise at 90° C. under stirring to a mixture of 2-ethylhexyl glycidyl ether (6.55 ml, 31.6 mmol) and 2-hepta fluoro-propoxy-2,3,3,3-tetrafluoro propanol (10.0 g, 32 mmol), and the mixture was reacted for 6 hours. The reaction liquid was extracted with ethyl acetate, the organic phase was dried, and the solvent was distilled off, giving an alcohol compound. Compound 6B (6.76 g, two processes, 35%) was synthesized from this alcohol compound using a SO 3 -Py complex. 
     Colorless Liquid: 
       1 H-NMR(CD 3 OH): δ 0.80-1.00 (m, 6H), 1.15-1.65 (m, 9H), 3.34 (d, J=5.6 Hz, 2H), 3.42 (d-d, J=5.1, 1.5 Hz, 2H), 3.50-3.76 (m, 2H), 3.76-3.91 (m, 1H), 4.19 (d, J=11.9 Hz, 2H). 
     IR (KBr, cm −1 ): 2933, 1239, 1150, 998. 
     Example 7B 
     7B: C 3 F 7 OCF(CF 3 )CH 2 OCH 2 CH(OSO 3 Na)C 6 H 13    
     In the same manner as in compound 5B, an alcohol compound was synthesized from 1,2-epoxyoctane (4.83 ml, 31.6 mmol) and 2-heptafluoro-propoxy-2,3,3,3-tetrafluoropropanol (10.0 g, 32 mmol), and compound 7B (9.8 g, two steps, 56%) was then synthesized via the alcohol compound using a SO 3 -Py complex. 
     Colorless and Amorphous: 
       1 H-NMR(CD 3 OH): δ 0.87 (t, J=7.0 Hz, 3H), 1.15-1.55 (m, 8H) 1.55-1.77 (m, 2H), 3.75-3.89 (m, 2H), 4.08-4.30 (m, 2H), 4.30-4.46 (m, 1H). 
     IR (KBr, cm −1 ): 2936, 1336, 1236, 1151, 997, 936. 
     Comparative Example 1B 
     8B: (C 6 F 13 CH 2 CH 2 O) 2 P(O)ONa 
     Compound 8B was synthesized according to J. Am. Chem. Soc., 2002, vol. 124, page 1834. 
     Comparative Example 2B 
     9B: C 7 F 15 CH(OSO 3 Na)C 7 H 15    
     Compound 9B was synthesized according to J. Phys. Chem., 1992, vol. 96, page 6738. 
     Test Example 1B 
     A functional test was performed on the compounds obtained in Examples and Comparative Examples. 
     (1) Method for Determining a W Value and Amount of Water Uptake 
     Using a measuring device shown in  FIG. 1 , the W value and water uptake were determined according to the following processes 1 to 4. 
     1) A surfactant was placed in a proportion of 2 wt % based on the proportion of carbon dioxide in portion “a” of a pressure-proof device with an observation window (i.e., view cell). 
     2) After carbon dioxide was introduced and the pressure and temperature were adjusted as specified in Table 1B, water was introduced into portion “a” from a hexagonal valve. 
     3) When the visual observation of the contents through the observation window (sapphire window) showed that the mixture was colorless and homogeneous, it was judged that water dissolved in carbon dioxide. 
     4) The W value and amount of water uptake were calculated from the highest amount of water uptake possible for maintaining a colorless state, and from the weight of the surfactant used for measurement. 
     The adjusted measurement pressures and temperatures of item 2) above are shown in Table 1B, in which surfactant effects were evaluated based on the ability of each surfactant to incorporate water into carbon dioxide: the W value=(the number of water molecules/the number of surfactant molecules) in a micelle; and water uptake=weight of water dissolved in carbon dioxide, per gram of surfactant. 
     
       
         
           
               
             
               
                 TABLE 1B 
               
             
            
               
                   
               
               
                 Water uptake = the weight of water dissolved in 
               
               
                 carbon dioxide per gram of surfactant 
               
            
           
           
               
               
               
            
               
                 Compound Number 
                 W value (measurement conditions) 
                 Water uptake 
               
               
                   
               
               
                 2B (Example 2B) 
                 41 (33 MPa, 33° C.) 
                 1.3 g 
               
               
                 3B (Example 3B) 
                 40 (33 MPa, 33° C.) 
                 1.3 g 
               
               
                 5B (Example 5B) 
                 40 (25 MPa, 50° C.) 
                 1.2 g 
               
               
                 6B (Example 6B) 
                 37 (24 MPa, 50° C.) 
                 1.1 g 
               
               
                 8B (Comparative 
                 14 (19 MPa, 50° C.) 
                 0.3 g 
               
               
                 Example 1B) 
               
               
                 9B (Comparative 
                  0 (33 MPa, 50° C.) 
                   0 g 
               
               
                 Example 2B) 
               
               
                   
               
            
           
         
       
     
     Compounds 8B and 9B have been reported to function best (J. Am. Chem. Soc., 2002, vol. 124, page 1834; Langmuir, 1994, vol. 10, page 3536), and these publications describe that the amount of water uptake of these compounds reaches one gram per gram of surfactant, which is the highest water uptake value reported until now. However, the amount of water uptake of each of compounds 2B, 3B, 5B, and 6B of the present invention is larger than that of compound 8B or 9B. 
     The present inventors synthesized and evaluated compounds 8B and 9B under the same conditions as the compounds of the invention. The evaluation results show that although compound 8B fulfilled its function at relatively low pressure, the water uptake of compound 8B was notably lower than that of the reported data. 
     On the other hand, compound 9B did not fulfill its function at all, probably because the test was performed at 50° C. After the test, samples were collected so as to determine the cause by instrumental analysis (NMR). The analysis confirmed that small but complicated peaks were observed (decomposition possibly progressed even at 50° C.) in addition to the fact that the sulfate was hydrolyzed, which possibly forms a serious obstacle to practical use of compound 9B. 
     In contrast, it was confirmed that the compounds of the invention fulfill their functions stably under the conditions of the evaluation test (after the evaluation test, samples were collected and confirmed by an instrumental analysis). 
     As is clear from the above, the compounds of the invention are surfactants that demonstrate excellent properties in dissolving polar compounds, such as water, in a medium comprising carbon dioxide as a solvent.