Patent Publication Number: US-6656455-B2

Title: Method, apparatus, and composition for automatically coating the human body with plural components

Description:
CROSS-REFERENCE TO RELATED APPLICATION 
     This application is a continuation-in-part of application Ser. No. 09/294,689, filed Apr. 19, 1999, currently pending, which is a continuation-in-part of application Ser. No. 08/946,764, filed Oct. 8, 1997, now U.S. Pat. No. 5,922,333. 
     CLAIM OF PRIORITY 
     Applicant claims priority based on provisional patent application Ser. No. 60/157,541, filed Oct. 4, 1999. 
    
    
     TECHNICAL FIELD 
     The present invention relates generally to systems for automatically coating the human body or selected parts thereof with predetermined fluids. More particularly, the invention relates to an automated self-tanning (a/k/a sunless tanning) system, and to an improved self-tanning composition. 
     BACKGROUND OF THE INVENTION 
     The application of various fluids to all or selected parts of the human body has been known literally for centuries. However, despite the long-standing and widespread practice of coating the human body with various fluids, there has never been a successful way of automatically coating the human body. Therefore, prior to the present invention, it has been necessary to apply fluids to the body manually. 
     Manual application of fluids to the human body results in numerous disadvantages. First, it is almost impossible to uniformly coat the human body with fluids using manual application techniques. This is true even in the case of fluids that are provided in aerosol or spray form because such fluids must be rubbed in after application. Second, the application of fluids to certain parts of the human body, for example, the back, require the availability of an assistant in order that proper manual application can be attempted. 
     The foregoing difficulties are particularly apparent in the case of artificial tanning processes, hereinafter sometimes referred to as self-tanning or sunless tanning compositions and systems. Artificial tanning has been known for more than 40 years, with artificial tanning products appearing on the U.S. market as early as 1959. The two key types of tanning processes are by colorants and bronzers. 
     Tanning by colorants is based on the color reaction which occurs between components of the skin and the colorant. The most commonly used chemical for artificial tanning is dihydroxyacetone (DHA). It is widely used in commercial artificial tanning products, and is recognized as safe and effective by the U.S. Food and Drug Administration (FDA). DHA reacts solely with the stratum corneum. It interacts with amines, peptides and free amino acids to generate a Maillard reaction. The resulting products are cyclic and linear polymers that have a yellow or brown color. 
     Two common bronzers are juglone and lawsone. Both are naphthoquinones. When applied to skin, lawsone produces an orange hue and juglone produces a greenish-brown tan. They are sometimes used in combination with DHA to modify the color or hue of the tan or to intensify the color. 
     Numerous forms of artificial tanning products are now on the market. They include: 
     lotions, 
     creams, 
     gels, 
     oils, 
     sprays. 
     These products are mixtures of a chemically-active skin colorant or a bronzer with combinations of the following: 
     moisturizers, 
     preservatives, 
     anti-microbials, 
     thickeners, 
     solvents, 
     emulsifiers, 
     fragrances, 
     surfactants, 
     stabilizers, 
     sunscreens, 
     pH adjusters, 
     anti-caking agents, 
     ingredients to alter the color reaction. 
     Users of these products often experience significant problems associated with the current methods for applying artificial tanning formations to skin. These problems include the following. 
     If not properly dried, the formulation will streak or form blotches with time. The net result is a very nonuniform tan, with light or dark streaks or blotches. 
     Certain parts of the body will stain more intensely when the formulation is spread manually. This differential staining is due to enhanced absorption of certain skin tissue and the tendency of certain tissue to retain more formulation. The result is that as the formulation is being spread manually, certain tissue absorb or trap more formulation (e.g., the wrinkles in the elbows and knees and the dense tissue in the palms). 
     Most products designed for manual application require components such as thickeners and polymers, which often inhibit the efficacy of DHA. 
     Current formulations typically take about 20 minutes to dry to the touch, and about 1 hour before not transferring from skin to textiles. 
     Application of artificial tanning products is additionally complicated by the tendency of these formulations to stain materials containing amine molecules, including certain fabrics, certain types of carpet, and certain wall coverings and paint. 
     In spite of all of these problems, artificial tanning is becoming increasingly popular. It is apparent that a need exists for a superior application system which solves the foregoing problems. 
     There is also a need for a superior applications system for many other applications, including but not limited to: 
     self-tanning formulations, 
     sunscreens, 
     suntan lotions, 
     tanning accelerators, 
     sunburn treatments, 
     insect repellants, 
     skin toners, 
     skin bleaches, 
     skin lighteners, 
     anti-microbial compositions, 
     moisturizers, 
     exfoliants, 
     nutriments or vitamins, 
     massage aids, 
     muscle relaxants, 
     skin treatment agents, 
     burn treatment agents, 
     decontamination agents, 
     cosmetics, 
     wrinkle treatments or removers. 
     There are specific and significant problems with the manual coating of each of these products. The artificial tanning application provides a good illustration of the types of problems normally encountered when manually coating these products. Artificial tanning is also one of the most demanding applications in that uniformity of the coating is critical to assure uniform tanning. 
     SUMMARY OF THE INVENTION 
     The present invention comprises a system for automatically coating the human body, including a method of and apparatus for uniformly and rapidly coating all or selected parts of the human body. The system includes apparatus which atomizes (also referred to as aerosolization, nebulization, mist generation, fog generation or spray generation) a chemical composition and deposits it uniformly over all or selected parts of the human body. It is not necessary for the individual receiving the treatment nor anyone else to manually apply any of the formulation. Also, a containment system is provided which restrains and collects residue from the application process. The system can optionally recycle the materials used. 
     There are several major advantages resulting from the use of the invention: 
     Uniform application minimizes or eliminates streaking, 
     No assistant is required for applying the composition, 
     The entire skin surface receives the same exposure to the composition, so the uniformity of the coating is greatly enhanced over manual application, 
     The optimal formulation for atomization is very simple, and does not require the addition of components which may inhibit the efficacy of the applied material, 
     The application time can be as quick as a few seconds, and complete drying can occur in just a few minutes, 
     The containment system drastically reduces the unwanted environmental impact, 
     Multiple applications can be used to better control the amount of material applied per unit area, and additional substances can be applied in separate applications. 
     The invention may be practiced utilizing a unitary construction including both a coating chamber and apparatus for coating a person situated within the coating chamber. A door provides ingress to and egress from the coating chamber which is provided with vertically disposed arrays of spray discharging nozzles situated at spaced apart points around the periphery of the chamber. A blower circulates air through the coating chamber to effect drying following the coating procedure and to aid in containment of excess spray. An air compressor supplies liquid for coating and compressed air for spraying the coating liquid to the nozzles situated within the coating chamber. 
     In accordance with another aspect of the invention, there is provided a plural component system for coating the human body. The plural component system may comprise a single discharge nozzle which simultaneously or sequentially receives fluid from separate sources. Alternatively, the plural component system may comprise two or more discharge nozzles each receiving fluid from a separate source. Both techniques keep various components of the composition to be applied to the skin entirely separate until the moment of application. 
     The present invention further comprises an improved self-tanning composition. The improved self-tanning composition is particularly adapted for use in conjunction with the method and apparatus hereof. 
     REFERENCES 
     U.S. Patent Documents 
     
       
         
           
               
               
               
               
               
             
               
                   
                   
               
             
            
               
                   
                 3,932,151 
                 January 1976 
                 Lau 
                  55/229 
               
               
                   
                 4,231,289 
                 November 1980 
                 Domicent 
                  98/115 
               
               
                   
                 5,268,166 
                 December 1993 
                 Barnett 
                 424/047 
               
               
                   
                   
               
            
           
         
       
     
     Foreign Patent Documents 
     
       
         
           
               
               
               
             
               
                   
                   
               
             
            
               
                   
                 WO 94/12146 6/1994 
                 PCT Int&#39;l Appl. 
               
               
                   
                   
               
            
           
         
       
     
     Other Publications 
     Akins, F. J. and Marlowe, E., “Non-Carcinogenicity of Dihydroxyacetone by Skin Painting,” Journal of Environmental Pathology and Toxicology, 5: No. 5, pp. 349-351 (1984). 
     Federal Register, “Color Additive Dihydroxyacetone” 38: No. 148, p. 21615, 2 August 1973. 
     Futterer, E., “Theory and Practice of Artificial Tanning: Literature and Patent Survey,” Cosmetics and Perfumes, 88: No. 8, pp. 31-33 (1973). 
     Johnson, J. A. and Fusaro, R. M., “Persistence of Skin Color and Fluorescence after Treatment with Dihydroxyacetone,” Dermatology 188: pp. 247 (1994). 
     Kurz, T., “Formulating Effective Self-Tanners with DHA,” Cosmetics and Toiletries, 109: No. 11, starting p. 55 (1994). 
     Levy, S. B., “Dihydroxyacetone-Containing Sunless or Self-tanning Lotions,” Journal of the American Academy of Dermatology, 27: No. 6, pp. 989-993 (1992). 
     “Spray Application Processes,” BINKS training brochure TD49-2R-4, August, 1995, BINKS Manufacturing Company, Franklin, Ill. 
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS 
     A more complete understanding of the invention may be had by reference to the following Detailed Description when taken in conjunction with accompanied Drawings, wherein: 
     FIG. 1 is a flow chart illustrating the invention; 
     FIG. 2 is a diagrammatic illustration of the system for automatically coating the human body of the present invention comprising the minimum requirements thereof; 
     FIG. 3 is an illustration similar to FIG. 2 wherein the system of the present invention is further provided with containment apparatus; 
     FIG. 4 is an illustration similar to FIG. 3 wherein the system of the present invention is further provided with an air ventilation apparatus; 
     FIG. 5 is an illustration similar to FIG. 4 wherein the system of the present invention is further provided with collection apparatus for residual spray; 
     FIG. 6 is an illustration similar to FIG. 5 wherein the system of the present invention is further provided with apparatus to effect rotation of the human body being coated; 
     FIG. 7 is an illustration similar to FIG. 6 wherein the system of the present invention is further provided with multiple discharge nozzles; 
     FIG. 8 is an illustration similar to FIG. 5 wherein the system of the present invention is adapted to the coating of a selected part of the human body; 
     FIG. 9 is a front view of an apparatus useful in the practice of the invention; 
     FIG. 10 is a top view of the apparatus of FIG. 9; 
     FIG. 11 is an illustration of one of the spray columns of the apparatus of FIG. 9; 
     FIG. 12 is an enlarged view illustrating the nozzle assemblies utilized in the spray columns of the apparatus of FIG. 9; 
     FIG. 13 is an illustration of a first type of prior art plural component spray discharge system; 
     FIG. 14 is an illustration of a second type of prior art plural component spray discharge system; and 
     FIG. 15 is an illustration of a modification of the apparatus of FIGS. 9-12 to provide a plural component system. 
    
    
     DETAILED DESCRIPTION OF THE INVENTION 
     Referring now to the Drawings, and particularly to FIG. 1, the system for automatically coating the human body of the present invention may comprise an automated coating system for numerous types of formulations, including but not limited to the application of: 
     self-tanning formulations, 
     sunscreens, 
     suntan lotions, 
     tanning accelerators, 
     sunburn treatments, 
     insect repellants, 
     skin toners, 
     skin bleaches, 
     skin lighteners, 
     anti-microbial compositions, 
     moisturizers, 
     exfoliants, 
     nutriments or vitamins, 
     massage aids, 
     muscle relaxants, 
     skin treatment agents, 
     burn treatment agents, 
     decontamination agents, 
     cosmetics, 
     wrinkle treatments or removers. 
     The first component of such a system is the chemical composition. The suitability of a composition for coating is strongly influenced by its viscosity, with the preferred viscosity being close to that of water (1 centipoise). Compositions with viscosities in the 1 to 10 centipoise range generally atomize well, and viscosities in the 10 to 100 range can be atomized, but the resulting spray is not as fine. Higher viscosities can be atomized, and will work, but the spray is not as fine. Most currently marketed compositions of the aforementioned applications can be made suitable for atomization either as is or with appropriate dilution. 
     By way of example, a more detailed description of functional compositions for use in practice of the invention will be based on artificial tanning compositions. Six such compositions are given in Compositions 1, 2, 3, 4, 5, and 6. Individuals skilled in this art can create other compositions. 
     
       
         
           
               
            
               
                   
               
               
                 COMPOSITION 1 
               
            
           
           
               
               
               
            
               
                   
                 Ingredient 
                 % 
               
               
                   
                   
               
               
                   
                 Dihydroxyacetone 
                  3.0 
               
               
                   
                 Water 
                 97.0 
               
               
                   
                   
               
            
           
         
       
     
     
       
         
           
               
            
               
                   
               
               
                 COMPOSITION 2 
               
            
           
           
               
               
               
            
               
                   
                 Ingredient 
                 % 
               
               
                   
                   
               
            
           
           
               
               
               
            
               
                   
                 Dihydroxyacetone 
                 3.0 
               
               
                   
                 Denatured Ethanol 
                 20.0 
               
               
                   
                 Water 
                 77.0 
               
               
                   
                   
               
            
           
         
       
     
     
       
         
           
               
            
               
                   
               
               
                 COMPOSITION 3 
               
            
           
           
               
               
               
            
               
                   
                 Ingredient 
                 % 
               
               
                   
                   
               
               
                   
                 Dihydroxyacetone 
                 12.0 
               
               
                   
                 Denatured Ethanol 
                 20.0 
               
               
                   
                 Water 
                 68.0 
               
               
                   
                   
               
            
           
         
       
     
     
       
         
           
               
            
               
                   
               
               
                 COMPOSITION 4 
               
            
           
           
               
               
               
            
               
                   
                 Ingredient 
                 % 
               
               
                   
                   
               
               
                   
                 Dihydroxyacetone 
                 10.0 
               
               
                   
                 Commercial Sunless- 
                 15.0 
               
               
                   
                 Tanning Lotion 
               
               
                   
                 Water 
                 75.0 
               
               
                   
                   
               
            
           
         
       
     
     
       
         
           
               
            
               
                   
               
               
                 COMPOSITION 5 
               
            
           
           
               
               
               
            
               
                   
                 Ingredient 
                 % 
               
               
                   
                   
               
            
           
           
               
               
               
            
               
                   
                 Dihydroxyacetone 
                 9.0 
               
               
                   
                 Commercial moisturizer 
                 20.0 
               
               
                   
                 Citric acid 
                 0.3 
               
               
                   
                 Commercial bath product 
                 0.6 
               
               
                   
                 Bronzer 
                 6.0 
               
               
                   
                 Water 
                 64.1 
               
               
                   
                   
               
            
           
         
       
     
     By way of example, a suitable commercial moisturizer would include Vaseline Brand Intensive Care Aloe and Naturals lotion (Chesebrough-Ponds, Greenwich, Conn.), and a suitable commercial bath product would include Vaseline Brand Intensive Care Foaming Creme Bath (Chesebrough-Ponds, Greenwich, Conn.). The bronzer is a combination of FD&amp;C dyes that yield a golden brown color. 
     
       
         
           
               
            
               
                   
               
               
                 COMPOSITION 6 
               
            
           
           
               
               
               
            
               
                   
                 Ingredient 
                 % 
               
               
                   
                   
               
            
           
           
               
               
               
            
               
                   
                 Bronzer 
                 8.0 
               
               
                   
                 Commercial moisturizer 
                 20.0 
               
               
                   
                 Commercial bath product 
                 0.6 
               
               
                   
                 Ethoxydiglycol 
                 2.0 
               
               
                   
                 Water 
                 69.4 
               
               
                   
                   
               
            
           
         
       
     
     By way of example, a suitable commercial moisturizer would include Vaseline Brand Intensive Care aloe and Naturals lotion (Chesebrough-Ponds, Greenwich, Conn.), and a suitable commercial bath product would include Vaseline Brand Intensive Care Foaming Creme Bath (Chesebrough-Ponds, Greenwich, Conn.). The bronzer is a combination of FD&amp;C dyes that yield a golden brown color. 
     By way of example, suitable commercial sunless tanning preparations include Coppertone® Oil-Free Sunless Tanner (Schering-Plough, Memphis, Tenn.), Neutrogena® Glow Sunless Tanning Lotion for Face and Body (Neutrogena, Los Angeles, Calif.), and Kroger® Sunless Tanning Cream (Kroger, Cincinnati, Ohio). 
     Compositions 1, 2 and 3 are greatly simplified versions of the formulations now on the market or reported in the past. This simplification is possible due to the use of the present invention for applying compositions to skin. These simplified compositions have several advantages over more complex formulations, including: 
     faster drying, 
     less potential inhibition of DHA efficacy, 
     less potential for irritation from chemical components (because there are fewer components), 
     less residue on the skin, 
     less expensive, 
     more environmentally friendly. 
     Compositions 4 and 5 illustrate how a commercial formulation not particularly well suited for atomization can be diluted, effectively atomized and uniformly coated on human skin. Similar dilutions of products representing the other aforementioned applications can be effectively atomized and coated on human skin. 
     There is no pH adjustment required for these compositions, although the pH can be adjusted to alter the hue of the resulting tan and to alter the dihydroxyacetone stability. The optimal tanning occurs with DHA at a pH of below 6.0, preferably with the solution at a pH of 3.0 to 4.0. Unbuffered DHA has a pH of about 5.5. The pH on the surface of human skin is also about 5.5. Nonetheless, these formulations can be used over a wide pH range, and buffers or pH adjusters can be added. 
     A preferred colorant is DHA. DHA is available from Rona (Hawthorne, N.Y.). It is effective, safe, and approved by the FDA for this application. The preferred DHA concentration is 0.5% to 20%, with a more preferred range of 3% to 15%, and a most preferred range of 5% to 12%. 
     Numerous other colorants can also be used. Those agents include, but are not limited to: 
     crotonaldehyde 
     pyruvaldehyde 
     glycolaldehyde 
     glutaraldehyde 
     otho-phthaldehyde 
     sorbose 
     fructose 
     erythrulose 
     methylvinylketone 
     food coloring 
     Various dyes and UV blocking agents can be covalently linked to the colorant or can be mixed into the composition with the colorant. 
     Bronzers can also be used in combination with or as an alternative to DHA. Bronzers which can be used include, but are not limited to, lawsone and juglone. Combinations of DHA and bronzers can also be used, and can be used to modify the resulting color (hue) and intensity of the tan. The preferred range for lawsone, juglone, and FD&amp;C dyes is 0.5% to 10.0% with the more preferred range of 1.0% to 5.0%. 
     Composition 6 is an example of a formulation containing only bronzers (no DHA). The preferred range of FD&amp;C dyes in commercially formulated liquid form (e.g., food coloring by Adams Extract Co., Austin, Tex.) is 1 to 50%, with a more preferred range of 4 to 12%. Ethoxydiglycol is added to enhance the penetration of the dyes into the skin, to reduce transfer to clothing, and to assist in the stabilization of the formulation. The preferred ethoxydiglycol range is 1 to 20%, with a more preferred range of 2 to 10%. 
     Alcohol can be added to the composition to accelerate the rate of drying. Denatured ethanol (USP grade, commodity chemical) works well in this capacity. The preferred range for alcohol concentration is from 1.0% to 50.0%, with a more preferred range from 10.0% to 30.0%, and a most preferred concentration of 20.0%. 
     Other potential additives include: 
     moisturizers, 
     preservatives, 
     anti-microbials, 
     thickeners, 
     solvents, 
     emulsifiers, 
     fragrances, 
     stabilizers, 
     sunscreens, 
     surfactants, 
     pH adjusters, 
     anti-caking agents, 
     ingredients to alter the color reaction. 
     It typically requires about 100 ml of a 5.0% DHA composition to obtain a medium to dark tan over an entire adult body (about 2 square meters of skin). A single application of about 250 ml of a 9% dihydroxyacetone composition over an entire adult human body will result in a very dark tan. The exact amount of dihydroxyacetone required depends on the skin type and intensity of tan desired. The tan can last for about 2 to 7 days, but usually lasts for 3 to 4 days. Multiple applications will darken the tan. 
     The second component of the invention is the atomization of the composition. The required atomization can be obtained by a host of ways, most of which involve passing the composition through an orifice under pressure. Methods now used to atomize solutions include the use of the following systems: 
     air atomization 
     siphon feed 
     gravity feed 
     pressure feed 
     internal atomization 
     external atomization 
     low pressure low volume 
     high volume low pressure 
     airless atomization 
     pressurized through small orifices 
     air-assisted 
     air-assisted heated 
     electrostatic 
     using charged particles 
     heated charged particles 
     high speed rotational atomizers 
     ultrasonic 
     These forms of atomization are the basis for most methods of producing atomized sprays, including misting and nebulization. 
     Using a single airless sprayer with a tip orifice of 0.6 mm, with a circular spray pattern of 12 inches at 12 inches from the tip, and with a flow rate of approximately 400 ml/min. the entire body (excluding the bottom of the feet) of an average-sized person can be coated with solution in 5 to 15 seconds. In practice, the underside of the feet usually gets slightly tanned also from exposure to small quantities of residual artificial tanning composition on the floor of the application area. The use of a single airless sprayer to apply a composition to human skin is illustrated in FIG.  2 . In this figure and subsequent figures,  11  designates the orifice for atomization of the composition,  12  designates the atomized spray, and  13  designates the subject being sprayed. In this configuration, an operator must direct the flow of the spray. The configuration illustrated in FIG. 2 would also work for any of the other atomization methods aforementioned, and for any of the applications aforementioned. The preferred atomization method is the pressure-free air-atomization system, with an internal or external atomization configuration. 
     For a person to be coated as illustrated in FIG. 2 with an artificial tanning composition (or any composition of the applications aforementioned), several precautions should be taken. First, the person should hold their breath during the application and during the time required for the spray to clear. If this process is done in an open area, the coating should take about 5 to 15 seconds and the clearing of residues should take 1 to 10 seconds. Thus, the person would need to hold their breath for 6 to 25 seconds. Alternatively, they could wear a filter over their mouth, have a filter inside of their mouth, or use a breathing tube. They can also wear nose plugs or filters. Second, the eyes should be protected even though most of these formulations are not likely to injure the eye. The simplest and most effective protection is to keep the eyes closed. Goggles or patches also work well, although they leave uncoated areas that must be subsequently coated manually. Next, precautions need to be taken if one wants to avoid the exposure of scalp hair. Scalp hair can be protected with a shower cap or any other similar protective covering impervious to the coating compositions. Also, hair can be coated with a water insoluble material such as petroleum jelly. Similar protection can be used to protect hair on any other parts of the body. Next, if atomization is from a single source, it is recommended that the person being coated turn while being coated, or that the coating apparatus be moved around the person being coated, or there be a combination of these movements. Finally, care must be taken that the nozzle remain at least several inches from the person being coated to prevent any possible injection of composition into the person. Generally, spray injection occurs at pressures greater than 500 psi with the person actually contacting the atomization orifice. The pressures here are less than 80 psi, and more typically 10 to 40 psi, and the person being coated should be a foot or more from the orifice. 
     The issue of what to wear during coating is usually of great concern to the person being coated. In the case of coating with artificial tanning solution, the selection of what to wear is a matter of preference for the person being coated. The subject can be coated nude, with underwear, with a bikini or a bathing suit, or with some form of pasties covering their private parts. 
     The third component of the invention is containment of the spray. Containment is illustrated in FIG.  3 . In this figure and subsequent figures,  14  and  15  designate side panels and  16  and  17  designate the top and bottom panels, respectively. This type of containment is similar to the containment of spray paint using paint booths in automobile refinishing. Alternatively, spray containment can be obtained using electrostatic forces, where the atomized spray is charged and the residual charged spray is removed by activating charged collection plates. Of course, precautions must be taken so that the person being sprayed and the operator are isolated from the charged plates. 
     Containment of the spray is very important for several reasons. These reasons include but are not limited to: 
     reducing waste, 
     avoiding spray getting onto and staining items in the immediate surroundings, 
     facilitating capture and recovery processes, 
     better control of air flow, 
     better control of temperature and humidity. 
     This type of containment facilitates the use of this invention in enclosed areas such as stores or medical facilities. 
     Control of air and spray flow is very important to the quality of the skin coating. It is highly preferable to have an exhaust fan drawing the spray towards the person being coated, and the residual composition out of the booth. In FIG. 4 is shown the addition of an exhaust fan  18 . The fan offers several significant advantages to the invention. These advantages include but are not limited to: 
     better control of air flow 
     shorter exposure to residue spray, requiring less time to hold breath or breathe through filter or air line 
     faster drying of the coated composition on skin 
     better quality coating 
     The fan  18  should have a flow of 10 to 5000 cubic feet per minute per square foot of opening, preferably 50 to 1000 cubic feet per minute per square foot, and most preferably 100 to 400 cubic feet per minute per square foot. At flow rates of below 100 cubic feet per minute per square foot, the air movement is sufficient to guide the atomized spray through the containment area. At flow rates of 100 to 400 cubic feet per minute per square foot, the atomized spray is being actively drawn through the containment area and the application and drying process is enhanced. At rates above 400 cubic feet per minute per square foot, the atomized spray is being accelerated and the exhaust flow plays a much more prominent role in the application process. The flow rate of the air through the containment area is therefore a major parameter which can be varied to modify the characteristics of the coating of the artificial tanning composition to the skin. The drying time for the composition deposited on skin is also effected by flow rate, with drying time decreasing as flow rates increase. At rates above 100 cubic feet per minute per square foot, the drying time (to the point of no transfer to other surfaces upon contact) is less than 5 minutes. 
     At any flow rate above 10 cubic feet per minute per square foot, the residual atomized spray is completely removed from the containment area within one second. This rapid removal is important to minimize the time the person being tanned is exposed to spray and has the potential to inhale this spray. In the absence of this air flow, the residual spray lingers in the area for several minutes, and traces can be detected hours later. This vigorous flow also protects any individuals or operators near the atomizing orifices from back spray. 
     The final element of this invention is recovery, or filtering, of residual composition. This feature greatly enhances the utility of the invention because it allows the system to be self-contained in an indoor environment and promotes a more environmentally friendly process. Without a recovery system, there is a potential for the exhausted residue to stain anything it contacts. Also, there could be an accumulation of residue with time. One configuration of the recovery system is shown in FIG.  5 . In this figure and subsequent figures, the recovery system or filter is denoted as  19 . Recovery of both particulates and solvents is possible. Potential filters include a high-efficiency filter such as Binks&#39; (Franklin Park, Ill.) Paint Pockets or Columbus Industries&#39; (Ashville, Ohio) High-Capacity Supra Mini-Mesh, a form of a carbon filter, a water-wash filter, or an exchange-type resin. The efficiency of particulate and solvent removal should be greater than 99%. As an alternative to high-efficiency filtering, the spray residuals could be vented to the outside environment. 
     Additional features adding to the utility of the invention are shown in FIG.  6  and FIG.  7 . In FIG. 6 there is shown the addition of a motorized turntable  20 . This turntable  20  will rotate the person being coated, eliminating rotation by the individual as a possible source of error or problems. It also is a major convenience for the person being coated. The preferred rate of rotation is in the range of 1 to 60 rpm, with a more preferred range of 5 to 20 rpm, with a most preferred rate of rotation of 12 rpm. 
     In FIG. 7 there is shown the use of multiple atomizing orifices. The use of multiple orifices facilitates the automation of this process, and reduces operator effort and potential error. It also reduces the time required to fully coat an individual. The typical round spray pattern is about 12 inches wide at 8 to 12 inches from the orifices, so a preferred spacing of multiple orifices will be 8 to 12 inches apart, but could be positioned from 1 to 48 inches apart. Fan patterns from wide-angle nozzles at 18 inches are typically 24 inches long and 9 inches wide. Using the preferred configuration, an individual can be coated in 5 seconds or less. In FIG. 7, the orifices are aligned in a vertical pattern. The coverage of more area at one time could also be obtained by rapidly moving one or more orifices along a track or by rapidly altering the angle of the orifice. Other patterns are possible, including combinations of vertical and horizontally aligned orifices. Orifices could also be aligned radially, with the subject being sprayed with orifices aligned from 0 to 360°. Another alignment is a horizontal ring containing orifices that surround the body. By vertically raising and lowering the horizontal ring, the entire body or selected parts of the body could be coated. 
     In an open environment, such as a beach or a park, a modified version of configuration illustrated in FIG. 7 could be used to rapidly coat an individual. It would even be possible to have a walk-through coating system. An atomized spray could be produced from multiple nozzles arranged in a single line (as shown in FIG.  7 ), in two single lines facing one another and about 36 to about 48 inches apart, or multiple lines of nozzles. The preferred configuration is multiple lines, with 4 lines being adequate. The atomized spray results in an area of intense atomized solution, which would coat an individual standing in that area. The residual spray would then be dissipated into the surrounding environment. A fan could be used to accelerate the removal of the residuals from the coating area. 
     FIG. 8 illustrates how the system of the present invention can be used to tan a selected part of the body. In this case, just the face is being tanned. In this figure the bottom panel of the apparatus  22  contains an opening through which one can insert his or her head. The top panel  23  is arched. The high-efficiency filter is  19 . The fan and back panel is  18 . Alternately, the setup as shown in FIGS. 2-7 could be used to tan only a select part of the body by protecting the area not desired to be tanned with appropriate barrier apparel or by screens between the atomized spray and the regions of the skin not to be coated. The barrier apparel could be any material impervious to the atomized coating composition. For example, materials appropriate for use with the aforementioned coating compositions include vinyl, polyurethane, and latex rubber. The screens can be sheets composed of any material impervious to the atomized artificial tanning compositions, including most metals or plastics. A preferred screening material is foam with an impervious aluminum foil backing. The foam is aligned with the backing away from the atomizing orifice. The foam is preferred because it absorbs much of the atomized spray, reducing back deflection. 
     FIGS. 9,  10 ,  11 , and  12  illustrate an apparatus which may be utilized in the practice of the invention. The apparatus  30  comprises a unitary construction which includes both a coating chamber  32  adapted to receive a person to be coated with a predetermined substance and various components utilized to effect spraying of the predetermined substance onto the person situated within the coating chamber  32 . 
     The coating chamber  32  includes a door  34  which affords ingress to and egress from the coating chamber. The coating chamber  32  is further provided with a plurality of spray columns  36 . As is best shown in FIG. 10, the spray columns  36  are located at spaced apart points around the periphery of the chamber  32 . Those skilled in the art will appreciate the fact that neither the number nor the precise location of the spray columns  36  is critical to the practice of the invention, and that other spray column arrangements may be utilized in the practice of the invention, if desired. 
     The spray columns  36  are preferably supported for pivotal movement through predetermined arcs under the action of a pneumatic cylinder  38 . In this manner the predetermined material is discharged from the spray columns  36  in such a way as to assure uniform coating of the predetermined material on a person situated within the coating chamber  32 . The pneumatic cylinder  38  is connected to the pivoting mechanism of each of the spray columns  36  through a plurality of links  40 . 
     Referring again to FIG. 9, there is further included a blower  46  which directs a flow of air upwardly along an air guide  48  and then laterally along a top panel  50  into engagement with a plurality of baffles  52 . The baffles  52  direct the air from the blower  46  downwardly through the coating chamber  32 , whereby the flowing air effects drying of the sprayed material and aids in recovery of the sprayed material for reuse. From the coating chamber  32  the air is directed through a plurality of filters  54  and is returned to the blower  46 . 
     The predetermined material which is to be coated onto a person situated within the coating chamber  32  is preferably provided in the form of a liquid which is received in a reservoir  60 . The interior of the reservoir  60  is pressurized by compressed air which is received from an air compressor  62  through an air tank  64 . Compressed air from the air compressor  62  in the tank  64  is also directed to an air tank  66  and to a manifold  68 . The air tank  66  provides compressed air for operating the pneumatic cylinder (FIG.  10 ). The manifold  68  directs compressed air to the spray columns  36 . 
     Ideally, all of the liquid from the reservoir 60 which is discharged from the spray columns  36  would be received on the body of the person within the coating chamber  32 . In actual practice, it is not possible to obtain 100% efficiency in the coating procedure. Excess liquid which is discharged from the spray columns moves downwardly under the action of gravity onto a drain ramp  72 . A drain pump  74  receives the excess liquid through a suction pipe  76  and delivers it to an appropriate drain. 
     Referring to FIGS. 11 and 12, each spray column  36  includes an inner tubular passageway  84  which receives liquid from the reservoir  60  under the action of compressed air supplied by the air compressor  62  through the tank  64  and an outer tubular passageway  86  which receives compressed air from the manifold  68 . Each spray column  36  is provided with a plurality of nozzles  88 . Each nozzle  88  receives compressed air from the outer tubular passageway  86  through a quick disconnect  90  and receives liquid from the inner tubular passageway  84  through a quick disconnect  92 . A check valve  94  prevents reverse flow of liquid back through the quick disconnect  92 . 
     Features Contributing Significantly to the Successful Operation of an Automated Coating System for the Human Body Incorporating the Invention 
     Formula: 
     The following formula is a combination of water, dihydroxyacetone, bronzer, moisturizer, surfactant, and penetration enhancer. The formula is: 
     
       
         
           
               
               
               
             
               
                   
                   
               
               
                   
                 Range 
                 Preferred 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
            
               
                 water 
                 base 
                 16%-65% 
                 41.7% 
               
               
                 dihydroxyacetone 
                 self-tanning 
                  3%-15% 
                 10.0% 
               
               
                 bronzer* 
                 cosmetic colorant 
                  0%-10% 
                 8.0% 
               
               
                 ethoxy diglycol 
                 penetration enhancer 
                  0%-10% 
                 5.0% 
               
               
                 commercial 
               
               
                 moisturizer lotion** 
                 film former, 
                 10%-25% 
                 15.0% 
               
               
                 commercial bath 
                 viscosity 
               
               
                 product*** 
                 surfactant 
                 0%-2% 
                 0.6% 
               
               
                 citric acid 
                 pH adjustment 
                 0.1%-1.0% 
                 0.2% 
               
               
                 10x aloe vera concentrate 
                 moisturizer, tan 
                 1%-5% 
                 2.5% 
               
               
                   
                 enhancer 
               
               
                 isopropyl alcohol with 
                 solvent, 
                  5%-25% 
                 15.0% 
               
               
                 methyl salicylate 
                 penetration enhancer 
               
               
                 Trivosol ® 
                 emulsifier 
                     .5%-10% 
                 2.0% 
               
               
                   
               
               
                 *By way of example, a suitable bronzer would be a combination of the following food dyes provided by Adams Extract Company, Austin, Texas: 4 parts red, 2 parts yellow, 1 part green, and 3 parts purple.  
               
               
                 **By way of example, a suitable commercial moisturizer lotion includes Vaseline Intensive Care Lotion (Aloe Vera Triple Action Formula, Chesebrough-Ponds, Greenwich, CT).  
               
               
                 ***By way of example, a suitable commercial bath product includes Vaseline Intensive Care Foaming Crème Bath (Chesebrough-Ponds, Greenwich, CT).  
               
            
           
         
       
     
     Foot Shields: 
     The feet are one of the most difficult parts of the body to coat uniformly. This difficulty is due in large part to the irregular structure of feet. Also, the downward motion of the atomized mist, both by gravity and from air currents, tends to cause the mist to settle on the tops of the feet. Therefore, the feet are provided with shields to assure a more uniform coating of the feet. The shields may take the form of a large, bottomless shoe. The shields produce a silhouette effect from the top of the feet to the toes. Holes and openings are provided in the shields which are located 0.25 to 2 inches from the feet, allowing the mist to result in a silhouette effect rather than defined lines. 
     Air Shield to Deflect Air Away From the Feet: 
     To reduce the amount of mist settling on the feet, a plastic shield shaped like a figure eight is placed between the fleximat flooring the user stands on and the metal grating supporting the fleximat. Dimensions of the figure eight are two 18 inch diameter overlapping circles with a total width of 26 inches. The total width can vary from 18 inches to 36 inches, and the circle diameters can vary from 12 inches to 20 inches. 
     Toweling Buffing After Coating: 
     After coating it is advantageous to use a towel rub to buff over the entire body to yield a more uniform coating and to remove any areas of excess. The toweling yields a more cosmetically pleasing result and reduces transfer to clothing. It is preferred to towel using long, light strokes. A cotton bath towel 16 inches by 32 inches may be used. The towel could vary from a hand cloth (8″×8″) to a large beach towel (18″×48″). Care must be taken not to rub so hard or too much as to rub off the coating (or tan). Basically, the weight of the preferred towel is adequate, without additional pressure. 
     Stance During Coating: 
     The stance used during the coating is important. After trial and evaluation of numerous methods, it has been discovered that the “ballerina stance” seems to work best. Key elements of the stance are: 
     hands over the head 
     preferred 2 inches 
     lower limit—hands touching head 
     upper limit—arms extended fully up 
     hands parallel to the floor 
     hands could be, but not recommended to be, perpendicular to floor in a praying stance, or facing downwardly 
     feet separated about 12 inches 
     to allow mist to coat inside of legs 
     feet are flat on flooring 
     use of feet shields as described above 
     Hair Net: 
     Although the above-described self-tanning solution does not turn hair orange, it may accumulate on hair. To avoid this accumulation, the user can wear a hair net or bouffant. Preferred compositions for the hair net include a cloth or plastic mesh or a continuess plastic sheet. 
     Barrier Cream: 
     It has been discovered that the commercial barrier cream produced by GoJo blocks the tanning solution from the skin. During the coating process, this lotion can be used to prevent tanning of specific areas, such as the palms of the hands. 
     High Efficiency Filter: 
     The use of high efficiency filters to remove excess mist is important. Preferably, a Binks high-efficiency paint-pockets filter is used. 
     Recharging of Filter: 
     It has been discovered that the tanning solution trapped in the filter can be removed with a water rinse. The solution, which is water soluble, is flushed out using water that is back-washed (water applied to the top surface opposite of the surface facing the solution) or water, preferably under moderate (greater than 60 psi) pressure, that is hosed on the filtered surface. 
     Uniform Air Flow: 
     Uniformity of air flow is very important to assure that the mist continues to be applied uniformly over the body even after the pressurized spray stops. Air flow parameters are, in the downward motion: 
     
       
         
           
               
               
               
             
               
                   
                   
               
             
            
               
                   
                 most preferred 
                 100 cfm 
               
               
                   
                 next preferred 
                  50 cfm to 200 cfm 
               
               
                   
                 next preferred 
                  25 cfm to 300 cfm 
               
               
                   
                   
               
            
           
         
       
     
     Warming of Air: 
     Atomization of liquids as done here by the nozzles results in a significant reduction in liquid temperature (as much as 20° F.). To keep the temperature to a warm, pleasant experience, four halogen lamps (250 watts each) can be added to the system to provide both illumination and heat. A coating chamber temperature of 80° F. to 110° F. is preferred, with 90° F. to 100° F. being more preferred. Other heating devices include infrared lamps and electrical heating elements. 
     EXAMPLES 
     Example 1 
     A twenty year old female of type III skin tanned by this process. She first applied a heart shaped sticker on her right arm. She covered her hair with a nylon mesh hair net and applied barrier cream over the palms of her hands. She tanned in the coating chamber. The subject above was coated for 7 seconds. About 300 grams of solution was applied during such time. There was a subsequent 7 second period in which the mist was circulated in the booth. The residual mist was removed from the booth and the subject dried for about 45 seconds. The subject then removed any excess lotion with a towel. The final result was that the subject was 1 to 2 shades darker after tanning. This difference was especially apparent when comparing the area under the sticker with the area with no sticker. The initial color was mainly from the bronzer, and is a deep brown color. Color was much more intense the next day, when the color was at least two shades darker than before tanning. After the subject showered, the intensity was dropped to about 1 shade darker than prior to tanning. This color, which was mainly from the dihydroxyacetone, was golden-brown. The color persisted about 1 shade darker for 3-4 days, and noticeable color was present for 7 days. 
     Example 2 
     A forty-seven year old male with type II skin tanned by this process. He first applied a heart shaped sticker on his right arm. He covered his hair with a nylon mesh hair net and applied barrier cream over the palms of his hands and the bottoms of his feet. He tanned in the coating chamber. The subject above was coated for 7 seconds. About 300 grams of solution was applied during time. There was a subsequent 7 second period in which the mist was circulated in the booth. The residual mist was removed from the booth and the subject dried for about 45 seconds. The subject then removed any excess lotion with a towel. The final result was that the subject was about 1 shade darker after tanning. This difference was especially apparent when comparing the area under the sticker with the area with no sticker. The initial color was mainly from the bronzer, and is a deep brown color. Color was much more intense the next day, when the color was one to two shades darker than before tanning. After the subject showered, the intensity was dropped to about 1 shade darker than prior to tanning. This color, which was mainly from the dihydroxyacetone, was golden-brown. The subject repeated the tanning process again later the second day. This time, the initial tan from the combination of previous tan and new bronzer was about 2 shades darker than before. Even after showering the next day, the tan was about two shades darker than prior to initially tanning. The color persisted about 2 shades darker for 3-4 days, and noticeable color was present for 10 days. 
     Example 3 
     A 24 year old female with type II skin tanned as described in examples 1 and 2 for five consecutive days. The results were a highly uniform, very dark tan. Her skin color was about 3 shades darker by the end of the week. The color was golden-brown. The color remained 2 to 3 shades darker for about 4 days, and some color (about 1 shade) was observed after 7 days. 
     Discoveries 
     Very Fast Drying: 
     Traditional sunless tanning products require 20 minutes or more to dry. The sunless tanning composition of the present invention drys within a minute after use. 
     Less Transfer to Clothing Than Expected: 
     Traditional sunless tanning products do not contain bronzers because bronzers transfer to clothing and other fabrics. The present invention exhibits almost no such transfer. 
     Tan Hue Less Orange Than Expected: 
     The combination of bronzers, tan enhancers, and a super application process produces a long lasting, golden-brown color. 
     Hair is Not Turned Orange: 
     Self-tanning lotions have been reported to turn body hair orange. The formulation and application of the present invention do not cause the hair to turn orange. First, the formulation does not penetrate the hair, but rather beads up on it. Next, it is applied in a very thin coat. The net result is that the hair does not turn orange. 
     Produces a Very Uniform Tan: 
     The present invention facilitates the application of a thin, uniform film over the entire body. Consequently, the resulting coating and tan is far superior to manual application methods. 
     Bronzer Tends to Last Longer Than Expected: 
     The bronzer provides immediate color and a method for observing the uniformity of the tan. The uniformity of the bronzer application is greatly enhanced because it is applied in a uniform thin film and its substantivity is enhanced because of deeper penetration into skin with the presence of a penetration enhancer. 
     Use of Ethoxy Diglycol as a Penetration Enhancer Makes the Tan Last Longer and More Uniform: 
     With the use of ethoxy diglycol, the duration of uniform intense tan has increased from an average of about 2 days to an average of about 4 days, and some color persists for up to 14 days. 
     The foregoing improved self-tanning composition is advantageously utilized in conjunction with the method and apparatus of the present invention. 
     Plural Component Systems 
     As is well known by those skilled in the art, the vast majority of cosmetics are single component systems. Examples include traditional creams, lotions, or sprays. 
     Plural component systems are a rare exception. Although many cosmetic products would perform better as plural component systems, the consumer market generally does not like or cannot deal with multiple component systems. Even professionals, such as beauticians, generally prefer single component systems. 
     Even medical or industrial products are generally single component. Again, the end users do not like dealing with multiple component systems. 
     In some cases, these objections are circumvented by unique delivery systems which automatically mix the components. One example of such a system is the dual syringe delivery apparatus used with two part epoxy systems. Another example comprises spray devices for applying paints and coatings using plural nozzle heads. 
     Referring to FIG. 13, there is shown a plural component spraying system  100  of the type conventionally utilized in applying paints and coatings. The spray system  100  includes a spray gun  102  having a single nozzle  104 . The spray gun  102  receives compressed air through a line  106 . A first component of a composition to be applied is received through a line  108  and a second component of the composition is received through a line  110 . The two components are mixed in the nozzle  104  and discharged therefrom as a unitary composition. 
     Referring to FIG. 14, there is shown a plural component spraying system  120  of the type conventionally utilized in the application of paints and coatings. The plural component spraying system  120  includes a spray gun  122  having dual discharge nozzles  124  and  126 . A first component of a composition to be applied is received by the nozzle  124  through a line  128 . A second component of the composition to be applied is received by the nozzle  126  through a line  130 . Compressed air is directed to the spray gun  122  through a line  132 . 
     In the operation of the plural component spraying system  120 , the component parts of the composition to be applied are not mixed in the nozzles  124  and  126 . Rather, the nozzles  124  and  126  each discharge a separate and distinct component of the ultimate composition to be applied. Mixing of the two components to form the ultimate composition occurs as the components which are discharged from the nozzles  124  and  126  simultaneously engage the surface to be coated. 
     FIG. 15 illustrates an adaptation of the apparatus illustrated in FIGS. 9,  10 ,  11 , and  12  and described hereinabove in connection therewith whereby the apparatus is adapted for plural component spraying. 
     A nozzle  140  receives fluid from two passageways  142  and  144 . Remotely operated valves  146  and  148  are utilized to control the flow of fluid from the passageways  142  and  144 , respectively, to the nozzle  140 . 
     The fluids received by the nozzle  140  from the passageways  142  and  144  through the remotely operated valves  146  and  148 , respectively, may comprise the components of a plural component system to be applied, for example, to the human body. Alternatively, the passageways  142  and  144  may be utilized to supply entirely separate fluids which are applied sequentially. For example, a skin preconditioner could be supplied through the passageway  142  and discharged from the nozzle  140  for application to the skin of the person to be tanned, allowed to remain in contact with the skin of the person to be tanned for a predetermined period of time, and thereafter removed from the skin by towel rubbing prior to the application of a self-tanning composition which is received by the nozzle  140  through the passageway  144  and discharged by the nozzle onto the skin of the person to be tanned. 
     Those skilled in the art will appreciate the fact that the apparatus illustrated in FIG. 15 is not limited to receiving the discharging two fluids. Rather, multiple lines can be connected to the nozzle through multiple remotely operated or valve components thereby facilitating the application of a plurality of fluids either simultaneously or sequentially. The remotely operated valves are conventional in construction and operation and may operate responsive to electrical, electromagnetic, pneumatic, and/or hydraulic signals. 
     The plural component spraying systems shown in FIGS. 13,  14 , and  15  can be used with a wide variety of nozzles, all of which are listed in U.S. Pat. No. 5,922,333 which is assigned to the assignee hereof. Included are traditional atomization nozzles and electrostatic nozzles. 
     The plural component spraying systems of FIGS. 13,  14 , and  15  are advantageously used to apply self-tanning (a.k.a. sunless tanning) compositions. For example, a DHA/bronzer/moisturizer mixture may comprise a first component and a tan enhancing component, which normally would destabilize the DHA component, and may comprise the second component of a plural component self-tanning composition. Examples of the tan enhancing component include penetration enhancers and materials which effect the chemical binding of the DHA to skin components. By simultaneously or sequentially misting the two components, an enhanced tan is achieved without requiring the consumer to deal with a multi-component system. 
     In a second example, a plural component wrinkle treatment which includes solutions at different pHs, or which rapidly react with each other, is applied to the skin sequentially. 
     Yet another example comprises on-skin polymerization. This is used to spray apply a body barrier layer which is impervious to water, radiation, etc. In this example, the solutions which contain reactive ingredients come into contact only after being applied to the skin. 
     Still another example is the use of an activator and base. The two component hydrogen peroxide system which is disclosed in U.S. Pat. No. 6,117,118 is advantageously applied by a plural mist-on process illustrated in FIGS. 13,  14 , and  15  and described hereinabove in conjunction therewith. The end effect is whole-body bleaching of a sunless tan. 
     Although preferred embodiments of the invention are illustrated in the Drawings and described in the Detailed Description, it will be understood that the invention is not limited to the embodiments disclosed, but is capable of numerous modifications and rearrangements of parts and elements without departing from the spirit of the invention.