Patent Publication Number: US-11037969-B2

Title: Solid-state imaging device having an impurity region on an upper surface of a photoelectric conversion film

Description:
CROSS-REFERENCE TO RELATED APPLICATIONS 
     This application is a continuation of U.S. patent application Ser. No. 15/489,243, filed on Apr. 17, 2017, which is a continuation of U.S. patent application Ser. No. 15/048,741, filed Feb. 19, 2016, which is a continuation of U.S. patent application Ser. No. 13/155,060, filed Jun. 7, 2011, now U.S. Pat. No. 9,570,495, which claims priority to Japanese Patent Application JP 2010-139689, filed in the Japan Patent Office on Jun. 18, 2010, the entire disclosures of which are hereby incorporated herein by reference. 
    
    
     BACKGROUND 
     The present invention relates to a solid-state imaging device and an electronic device. 
     An electronic device such as a digital video camera or a digital still camera includes a solid-state imaging device. For example, a CMOS (complementary metal oxide semiconductor) type image sensor is used as the solid-state imaging device. 
     The solid-state imaging device has a plurality of pixels arranged on a surface of a semiconductor substrate. A photoelectric conversion unit is provided in each pixel. The photoelectric conversion unit is, for example, a photodiode, and generates signal charges by sensing light coming via an externally attached optical system in a light sensing surface and by photoelectric-converting the light. 
     Among the solid-state imaging devices, each pixel of the CMOS type image sensor includes a readout circuit in addition to the photoelectric conversion unit. The readout circuit includes a plurality of transistors, reads out signal charges generated in the photoelectric conversion unit, and outputs the read-out signal charges to a signal line as an electric signal. 
     In the CMOS type image sensor, the photoelectric conversion unit reads out the signal charges for each pixel or for each row where a plurality of pixels is arranged. In this case, exposure time for accumulating the signal charges is difficult to match in all the pixels, and thus in some cases, a captured image is distorted. Particularly, if the motion of a subject is great, this defect is noticeably generated. 
     In order to prevent this defect from being generated, a “global exposure” is performed in which all the pixels start exposure at the same time and finish the exposure at the same time. 
     The “global exposure” is performed, for example, in a “mechanical shutter method” using a mechanical shutter. Specifically, all the pixels start exposure by opening the mechanical shutter, and finish the exposure by closing the mechanical shutter. However, in this “mechanical shutter method,” the size of a device is difficult to decrease since a mechanical light blocking unit is used. Also, since the speed of the driving operation of the mechanism is difficult to increase, the simultaneous exposure in all the pixels is hard to perform with high accuracy. 
     The “global exposure” is performed in a “global shutter method” in addition to the “mechanical shutter method.” Specifically, the “global exposure” is performed by simultaneously driving all the pixels through an electrical control without using the mechanical shutter. In the global shutter method, a size of a device can be easily reduced since the mechanical light blocking unit is not used. Further, the speed of the driving operation is easily increased, and the simultaneous exposure in all the pixels can be performed with high accuracy (for example, refer to Japanese Unexamined Patent Application Publications Nos. 2004-055590, 2009-268083 and 2004-140152). 
     Meanwhile, in the solid-state imaging device, there is a demand for an increase in the number of pixels along with the small size. In this case, since the size of one pixel is small, it is hard for each pixel to sense a sufficient amount of light, and thus it is not easy to improve the image quality of a captured image. For this reason, it is necessary for the solid-state imaging device to have high sensitivity. 
     In order to realize the high sensitivity, there has been proposed one where a chalcopyrite based compound semiconductor film such as a CuInGaSe 2  film with high light absorption coefficient is used in the photoelectric conversion unit (for example, refer to Japanese Unexamined Patent Application Publications No. 2007-123720). 
     In addition, there has been proposed a “lamination type” where photoelectric conversion units for respective colors are laminated and disposed in a depth direction perpendicular to an imaging surface, instead of disposing the photoelectric conversion units which selectively sense light beams of respective colors in a direction along the imaging surface. In the “lamination type,” each pixel senses not only light of one color but also light of plural colors. For this reason, a light sensing surface is extensively formed and thus use efficiency of light can be improved, thereby improving sensitivity (for example, refer to Japanese Unexamined Patent Application Publications No. 2006-245088). 
     Further, there has been proposed a “rear surface illumination type” where a photoelectric conversion unit senses light which is incident from a rear surface opposite to a front surface in which circuits, wires and the like are provided, in a semiconductor substrate. In the “rear surface illumination type,” the circuits, the wires and the like, which block or reflect the incident light are not provided in the incident side, and thus sensitivity can be improved (for example, refer to Japanese Unexamined Patent Application Publications No. 2008-182142). In the “rear surface illumination type,” there has been proposed one where a control gate electrode is formed in the photoelectric conversion unit on a surface opposite to the light sensing surface, a potential is controlled by applying a voltage to the photoelectric conversion unit, and signal charges are efficiently transferred (for example, refer to Japanese Unexamined Patent Application Publications No. 2007-258684). 
     In addition, the inventors of the present invention have recognized that in the solid-state imaging device, light enters an accumulator which accumulates signal charges generated by the photoelectric conversion unit or a readout circuit which reads out the signal charges, which causes noise to be generated, and thus there is a problem in that the image quality of a captured image is deteriorated. 
     In order to prevent the generation of such a defect, a light blocking film may block light from entering the accumulator or the readout circuit. 
     However, if the light blocking film is formed between the photoelectric conversion unit and the accumulator or the readout circuit, the area of the light sensing surface becomes small since the aperture ratio is reduced, and thus sensitivity is lowered in some cases. 
     In addition, light is diffracted or scattered due to the light blocking film, the diffracted light or the scattered light enters the accumulator to generate noise, and thus there are cases where the image quality of a captured image is deteriorated. 
     In the case of the “rear surface illumination type” solid-state imaging device, the accumulator or the readout circuit is formed on the front surface side opposite to the rear surface side which senses light in the substrate, but, in some cases, the above-described defects are generated since the substrate is thin for reading out the signal charges. 
       FIG. 60  is a cross-sectional view illustrating the “rear surface illumination type” solid-state imaging device. 
       FIG. 61  shows a simulation result of a form of light traveling in the “rear surface illumination type” solid-state imaging device. Here, a result of a case where light having a wavelength of 650 nm vertically enters the surface of the silicon substrate  101 J (3 μm thick) is shown. 
     As shown in  FIG. 60 , in the “rear surface illumination type” solid-state imaging device, members such as on-chip lenses ML, color filters CF, and insulating films Z 1 , Z 2  are provided on the rear surface side of the silicon substrate  101 J. A wire layer  111  is provided on the front surface side of the silicon substrate  101 J. The wire layer  111  is provided to cover a readout circuit (not shown) provided on the front surface side of the silicon substrate  101 J. 
     In the “rear surface illumination type” solid-state imaging device, photodiodes (not shown) provided inside the silicon substrate  101 J sense light passing through the respective portions such as the on-chip lenses ML and the color filters CF. Further, the readout circuit (not shown) provided on the front surface side of the silicon substrate  101 J reads out signal charges from the photodiodes (not shown). 
     As shown in  FIG. 61 , in the “rear surface illumination type” solid-state imaging device, the light which enters the rear surface (the upper surface in  FIG. 60 ) of the silicon substrate  101 J through the respective portions such as the on-chip lenses ML and the color filters CF reaches the front surface (lower surface). Specifically, light passing through the red filter layer CFR reaches the front surface of the silicon substrate  101 J more than light passing through the green filter layer CFG, and 28% of the light reaches the front surface. 
     As such, the inventors of the present invention have recognized that even in the “rear surface illumination type,” the light coming from the rear surface side is not blocked and reaches the front surface side on which the accumulator is provided, and thus there are cases where noise is generated and image quality of a captured image is deteriorated. 
     Particularly, in a case where imaging is performed in the “global shutter method,” since exposure in all the pixels is performed at the same time and then signal charges are temporarily accumulated in the accumulator, if light enters the accumulator, noise is notably generated. 
     Therefore, in the solid-state imaging device, there are cases where it is difficult for the small size and the improvement in the image quality of a captured image to be compatible. 
     SUMMARY 
     Disclosed herein are one or more inventions that provide a solid-state imaging device and an electronic device, of which the size can be easily reduced and which can improve the image quality of a captured image by preventing generation of noise. 
     According to an embodiment, a solid-state imaging device includes a substrate and a photoelectric conversion region. The substrate has a charge accumulation region. The photoelectric conversion region is configured to generate signal charges to be accumulated in the charge accumulation region. The photoelectric conversion region is provided on the substrate. The photoelectric conversion region comprises a material that is not transparent. 
     According to an embodiment, an electronic apparatus includes a solid-state imaging device. The solid state imaging device includes (a) a substrate, and (b) a photoelectric conversion region configured to generate signal charges. The photoelectric conversion region is provided on the substrate. The signal processing unit is configured to process an output of the solid-state imaging device. The photoelectric conversion region comprises a material that is not transparent. 
     According to an embodiment, a method for manufacturing a solid-state imaging device includes forming a charge accumulation region in a substrate, and forming a photoelectric conversion region electrically connected to the charge accumulation region. The charge accumulation region is configured to accumulate signal charges generated by the photoelectric conversion region. The photoelectric conversion region comprises a material that is not transparent. 
     Accordingly, it is possible to provide a solid-state imaging device and an electronic device, of which a size can be easily reduced and which can suppress generation of defects such as deterioration in image quality of a captured image, by preventing generation of noise. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1  is a diagram illustrating a configuration of a camera according to a first embodiment. 
         FIG. 2  is a block diagram illustrating an entire configuration of a solid-state imaging device according to the first embodiment. 
         FIG. 3  is a diagram illustrating main portions of the solid-state imaging device according to the first embodiment. 
         FIG. 4  is a diagram illustrating main portions of the solid-state imaging device according to the first embodiment. 
         FIG. 5  is a diagram illustrating a relationship between photon energy and a light absorption coefficient. 
         FIG. 6  is a diagram illustrating a relationship between a lattice constant and a band gap regarding a chalcopyrite material. 
         FIG. 7  is a diagram illustrating a relationship between a lattice constant and a band gap regarding a chalcopyrite material. 
         FIG. 8  is a diagram illustrating a band structure of the solid-state imaging device according to the first embodiment. 
         FIGS. 9A and 9B  are diagrams illustrating a manufacturing method of the solid-state imaging device according to the first embodiment. 
         FIG. 10  shows a MOCVD device used in the first embodiment. 
         FIG. 11  is an MBE device used in the first embodiment. 
         FIG. 12  is a diagram illustrating an operation of the solid-state imaging device according to the first embodiment. 
         FIGS. 13A to 13E  are diagrams illustrating an operation of the solid-state imaging device according to the first embodiment. 
         FIG. 14  is a diagram illustrating a simulation result of a form of light traveling in the solid-state imaging device according to the first embodiment. 
         FIG. 15  is a diagram illustrating a relationship between photon energy and an absorption index regarding a silicide material. 
         FIG. 16  is a diagram illustrating a circuit configuration of a pixel constituting a solid-state imaging device according to a modified example 1-2 of the first embodiment. 
         FIG. 17  is a diagram illustrating an operation of the solid-state imaging device according to the modified example 1-2 of the first embodiment. 
         FIGS. 18A to 18F  are diagrams illustrating an operation of the solid-state imaging device according to the modified example 1-2 of the first embodiment. 
         FIG. 19  is a diagram illustrating a circuit configuration of a pixel constituting a solid-state imaging device according to a modified example 1-3 of the first embodiment. 
         FIG. 20  is a diagram illustrating an operation of the solid-state imaging device according to the modified example 1-3 of the first embodiment. 
         FIGS. 21A to 21G  are diagrams illustrating an operation of the solid-state imaging device according to the modified example 1-3 of the first embodiment. 
         FIG. 22  is a diagram illustrating a circuit configuration of a pixel constituting a solid-state imaging device according to a modified example 1-4 of the first embodiment. 
         FIG. 23  is a diagram illustrating an operation of the solid-state imaging device according to the modified example 1-4 of the first embodiment. 
         FIGS. 24A to 24G  are diagrams illustrating an operation of the solid-state imaging device according to the modified example 1-4 of the first embodiment. 
         FIG. 25  is a diagram illustrating main portions of the solid-state imaging device according to a modified example 1-5 of the first embodiment. 
         FIG. 26  is a diagram illustrating a circuit configuration of a pixel constituting the solid-state imaging device according to the modified example 1-5 of the first embodiment. 
         FIGS. 27A to 27F  are diagrams illustrating an operation of the solid-state imaging device according to the modified example 1-5 of the first embodiment. 
         FIG. 28  is a diagram illustrating main portions of the solid-state imaging device according to the modified example 1-5 of the first embodiment. 
         FIG. 29  is a diagram illustrating a circuit configuration of a pixel constituting the solid-state imaging device according to the modified example 1-5 of the first embodiment. 
         FIGS. 30A to 30E  are diagrams illustrating an operation of the solid-state imaging device according to the modified example 1-5 of the first embodiment. 
         FIGS. 31A and 31B  are diagrams illustrating a band structure of a solid-state imaging device according to a modified example 1-6 of the first embodiment. 
         FIG. 32  is a diagram illustrating main portions of a solid-state imaging device according to a second embodiment. 
         FIG. 33  is a diagram illustrating a band structure of a solid-state imaging device according to the second embodiment. 
         FIG. 34  is a diagram illustrating a manufacturing method of the solid-state imaging device according to the second embodiment. 
         FIG. 35  is a diagram illustrating a manufacturing method of the solid-state imaging device according to the second embodiment. 
         FIG. 36  is a diagram illustrating a manufacturing method of the solid-state imaging device according to the second embodiment. 
         FIG. 37  is a diagram illustrating a manufacturing method of the solid-state imaging device according to the second embodiment. 
         FIG. 38  is a diagram illustrating main portions of the solid-state imaging device according to a third embodiment. 
         FIG. 39  is a diagram illustrating a manufacturing method of the solid-state imaging device according to the third embodiment. 
         FIG. 40  is a diagram illustrating a manufacturing method of the solid-state imaging device according to the third embodiment. 
         FIG. 41  is a diagram illustrating a manufacturing method of the solid-state imaging device according to the third embodiment. 
         FIG. 42  is a diagram illustrating main portions of the solid-state imaging device according to a fourth embodiment. 
         FIG. 43  is a diagram illustrating a manufacturing method of the solid-state imaging device according to the fourth embodiment. 
         FIG. 44  is a diagram illustrating a manufacturing method of the solid-state imaging device according to the fourth embodiment. 
         FIG. 45  is a diagram illustrating main portions of a solid-state imaging device according to a fifth embodiment of the present invention. 
         FIG. 46  is a diagram illustrating main portions of a solid-state imaging device according to a sixth embodiment. 
         FIG. 47  is a diagram illustrating an atomic arrangement when a photoelectric conversion film is formed on a silicon substrate which is an off substrate, according to a seventh embodiment. 
         FIG. 48  is a diagram illustrating an atomic arrangement when a photoelectric conversion film is formed on a silicon substrate which is an off substrate, according to the seventh embodiment. 
         FIG. 49  is a diagram illustrating an atomic arrangement when a photoelectric conversion film is formed on a silicon substrate which is an off substrate, according to the seventh embodiment. 
         FIG. 50  is an enlarged perspective view illustrating an area in which an antiphase domain is generated when the photoelectric conversion film is formed on the silicon substrate according to the seventh embodiment. 
         FIG. 51  is a diagram illustrating main portions of a solid-state imaging device according to an eighth embodiment. 
         FIGS. 52A to 52C  are diagrams illustrating examples of materials used for forming a red photoelectric conversion film, a green photoelectric conversion film, and a blue photoelectric conversion film, in the eighth embodiment. 
         FIGS. 53A and 53B  are diagrams illustrating characteristics of the red photoelectric conversion film, the green photoelectric conversion film, and the blue photoelectric conversion film, in the eighth embodiment. 
         FIG. 54  is a diagram illustrating main portions of a solid-state imaging device according to a ninth embodiment. 
         FIG. 55  is a diagram illustrating characteristics of a red photoelectric conversion film, a green photoelectric conversion film, and a blue photoelectric conversion film, in the ninth embodiment. 
         FIG. 56  is a diagram illustrating main portions of a solid-state imaging device according to a tenth embodiment. 
         FIG. 57  is a diagram illustrating main portions of the solid-state imaging device according to an eleventh embodiment. 
         FIG. 58  is a diagram illustrating characteristics of a green photoelectric conversion film and a green filter layer in the eleventh embodiment. 
         FIG. 59  is a diagram illustrating main portions of a solid-state imaging device according to a twelfth embodiment. 
         FIG. 60  is a cross-sectional view illustrating a “rear surface illumination type” solid-state imaging device. 
         FIG. 61  is a diagram illustrating a simulation result of a form of light traveling in the “rear surface illumination type” solid-state imaging device. 
     
    
    
     DETAILED DESCRIPTION OF EMBODIMENTS 
     Hereinafter, devices and constructions embodying principles of the present invention(s) (herein referred to as embodiments) will be described with reference to the accompanying drawings. The description will be carried out in the following order. 
     1. A first embodiment (a rear surface illumination type) 
     2. A second embodiment (with a pixel dividing portion (the First)) 
     3. A third embodiment (with a pixel dividing portion (the Second)) 
     4. A fourth embodiment (with a pixel dividing portion (the Third)) 
     5. A fifth embodiment (with an electrode under a photoelectric conversion film) 
     6. A sixth embodiment (with an electrode under a photoelectric conversion film (a front surface illumination type)) 
     7. A seventh embodiment (in a case of using an off substrate) 
     8. An eighth embodiment (in a case of laminating a photoelectric conversion film (the First)) 
     9. A ninth embodiment (in a case of laminating a photoelectric conversion film (the Second)) 
     10. A tenth embodiment (in a case of laminating a photoelectric conversion film (the Third)) 
     11. An eleventh embodiment (light blocking with a combination a photoelectric conversion film and a color filter (the First)) 
     12. A twelfth embodiment (light blocking with a combination a photoelectric conversion film and a color filter (the Second)) 
     13. Others 
     1. A First Embodiment (a Case where a Photoelectric Conversion Film has a Light Blocking Function) 
     A. A Device Configuration 
     A-1. A Configuration of Main Portions of a Camera 
       FIG. 1  is a diagram illustrating a configuration of a camera  40  according to the first embodiment. 
     As shown in  FIG. 1 , the camera  40  includes a solid-state imaging device  1 , an optical system  42 , a control unit  43  (or controller  43 ), and a signal processing circuit  44 . Each portion will be described sequentially. 
     The solid-state imaging device  1  senses light (subject image) passing through the optical system  42  using an imaging surface PS and performs a photoelectric conversion for the light, thereby generating signal charges. Here, the solid-state imaging device  1  is driven in response to a control signal output from the control unit  43 . Specifically, the solid-state imaging device  1  reads out the signal charges and outputs the read-out signal charges as raw data. 
     The optical system  42  includes optical members such as an imaging lens and a diaphragm, and is disposed so as to collect the incident light H which is incident as a subject image, on the imaging surface PS of the solid-state imaging device  1 . 
     The control unit  43  outputs various kinds of control signals to the solid-state imaging device  1  and the signal processing circuit  44  so as to control and drive the solid-state imaging device  1  and the signal processing circuit  44 . 
     The signal processing circuit  44  performs a signal process for an electric signal output from the solid-state imaging device  1  and thus generates a digital image of a subject image. 
     A-2. A Configuration of Main Portions of the Solid-State Imaging Device 
     An entire configuration of the solid-state imaging device  1  will be described. 
       FIG. 2  is a block diagram illustrating the entire configuration of the solid-state imaging device  1  according to the first embodiment. 
     The solid-state imaging device  1  is constituted by, for example, a CMOS type image sensor. The solid-state imaging device  1  includes a silicon substrate  11  as shown in  FIG. 2 . The silicon substrate  11  is a semiconductor substrate made of, for example, a monocrystalline silicon semiconductor, and has an imaging area PA and a peripheral area SA on its surface, as shown in  FIG. 2 . 
     The imaging area PA has a rectangular shape as shown in  FIG. 2 , wherein plural pixels P are respectively arranged in the horizontal direction x and the vertical direction y. In other words, the pixels P are arranged in a matrix. The imaging area PA corresponds to the imaging surface PS shown in  FIG. 1 . Details of the pixels P will be described later. 
     The peripheral area SA is positioned around the imaging area PA as shown in  FIG. 2 . Further, peripheral circuits are provided in the peripheral area SA. 
     Specifically, as shown in  FIG. 2 , as the peripheral circuits, a vertical driving circuit  3 , a column circuit  4 , a horizontal driving circuit  5 , an outward output circuit  7 , and a timing generator  8  are provided. 
     The vertical driving circuit  3 , as shown in  FIG. 2 , is provided in the side part of the imaging area PA in the peripheral area SA, and is electrically connected to the respective rows of the plural pixels P arranged in the horizontal direction H in the imaging area PA. 
     The column circuit  4 , as shown in  FIG. 2 , is provided in the lower part of the imaging area PA in the peripheral area SA, and performs signal processes for signals output from the pixels P with column units. Here, the column circuit  4  includes a CDS (correlated double sampling) circuit (not shown), and performs a signal process for removing fixed pattern noise. 
     The horizontal driving circuit  5  is electrically connected to the column circuit  4  as shown in  FIG. 2 . The horizontal driving circuit  5  includes, for example, shift registers, and sequentially outputs the signals for each column of the pixels P, which are held in the column circuit  4 , to the outward output circuit  7 . 
     The outward output circuit  7 , as shown in  FIG. 2 , is electrically connected to the column circuit  4 , and performs a signal process for the signals output from the column circuit  4 , and then outputs the processed signals to an external device. The outward output circuit  7  includes an AGC (automatic gain control) circuit  7   a  and an ADC (analog-to-digital conversion) circuit  7   b . In the outward output circuit  7 , the AGC circuit  7   a  gives a gain to the signals and then the ADC circuit  7   b  converts the analog signals to digital signals for output to the external device. 
     The timing generator  8 , as shown in  FIG. 2 , is electrically connected to the vertical driving circuit  3 , the column circuit  4 , the horizontal driving circuit  5 , and the outward output circuit  7 . The timing generator  8  generates various kinds of pulse signals, and outputs the pulse signals to the respective portions of the vertical driving circuit  3 , the column circuit  4 , the horizontal driving circuit  5 , and the outward output circuit  7  for driving control. 
     Details thereof will be described later, and the above-described respective portions are operated so as to perform exposure by the “global shutter method.” In other words, incident light is sensed by all the pixels P at the same time, and then the global exposure for finishing the sensing is performed without use of a mechanical light blocking unit. In addition, electric signals output from the respective pixels P are read out to the column circuit  4 , and then the accumulated signals in the column circuit  4  are selected by the horizontal driving circuit  5  and sequentially output to the outward output circuit  7 . 
     A-3. A Detailed Configuration of the Solid-State Imaging Device 
     A detailed configuration of the solid-state imaging device according to this embodiment will be described. 
       FIGS. 3 and 4  are diagrams illustrating main portions of the solid-state imaging device according to the first embodiment. 
     Here,  FIG. 3  shows a cross-section of the pixels P.  FIG. 4  shows a circuit configuration of the pixel P. 
     As shown in  FIG. 3 , the solid-state imaging device  1  includes the silicon substrate  11 , and a photoelectric conversion film  13  is formed on one side surface (upper surface) of the silicon substrate  11 . In addition, on the upper surface, on-chip lenses ML and color filters CF are provided on the silicon substrate  11 . 
     In contrast, a gate MOS  41  is provided on the other side surface (lower surface) of the silicon substrate  11 , as shown in  FIG. 3 . Although not shown in  FIG. 3 , independent gate MOS  42  and a readout circuit  51  are provided as shown in  FIG. 4 . 
     The readout circuit  51 , as shown in  FIG. 4 , includes a PD reset transistor M 11 , an amplification transistor M 21 , and a selection transistor M 31 . 
     Further, a wire layer (not shown) is provided on the other side surface (lower surface) of the silicon substrate  11  so as to cover the respective portions such as the gate MOS  41 . 
     In the solid-state imaging device  1 , the photoelectric conversion film  13  senses the incident light H passing through the on-chip lenses ML and the color filters CF from the rear surface (upper surface) side and generates signal charges. The signal charges generated by the photoelectric conversion film  13  are accumulated in an n type impurity area  12  provided in the silicon substrate  11 . Thereafter, the signal charges accumulated in the n type impurity area  12  is transferred to an n type impurity region  411  by the gate MOS  41  and are accumulated in the n type impurity region  411 . Also, the signal charges are transferred by the gate MOS  42  and read out by the readout circuit  51 , and then output to the vertical signal line  27  as electric signals. 
     That is to say, the solid-state imaging device  1  is constituted by a “rear surface illumination type CMOS image sensor.” 
     The respective portions will be sequentially described in detail. 
     A-3-1. The Photoelectric Conversion Film  13   
     In the solid-state imaging device  1 , the photoelectric conversion film  13 , as shown in  FIG. 3 , is provided on the one side surface (upper surface) of the silicon substrate  11  which is, for example, a p type silicon semiconductor. The photoelectric conversion film  13  is formed as a single body over the plural pixels P, as shown in  FIGS. 2-3 . 
     Here, the photoelectric conversion film  13  is provided to cover the n type impurity areas  12  which are formed to correspond to the plural pixels P in the silicon substrate  11 . As illustrated, the photoelectric conversion film  13  is adjacent to, in contact with, and/or in direct contact with the n-type impurity areas. Each of the n type impurity areas  12  functions as an accumulator which accumulates the signal charges generated by the photoelectric conversion film  13 . In the n type impurity area  12 , the impurity is preferably distributed such that concentration of the impurity increases from the upper surface to the lower surface of the silicon substrate. In this way, the signal charges (here, electrons) moved from the photoelectric conversion film  13  can be naturally moved to the gate MOS  41  side in the n type impurity area  12 . 
     In addition, as shown in  FIG. 3 , a transparent electrode  14  is provided on the photoelectric conversion film  13 . The transparent electrode  14  is connected to the ground, and thus prevents charging due to the accumulation of holes. In other words, the photoelectric conversion film  13  is interposed between the n type impurity area  12  functioning as a lower electrode and the transparent electrode  14  functioning as an upper electrode. 
     The photoelectric conversion film  13  senses the incident light H and performs photoelectric conversion for the light in the respective pixels P, thereby generating signal charges. 
     As shown in  FIG. 4 , the photoelectric conversion film  13  has an anode connected to the ground, and the accumulated signal charges (here, electrons) are read out through the gate MOS  41 , the gate MOS  42  and the readout circuit  51 , and output to the vertical signal line  27  as electric signals. 
     Specifically, the photoelectric conversion film  13  is connected to a gate of the amplification transistor M 21  via the gate MOS  41  and the gate MOS  42 , as shown in  FIG. 4 . Further, in the photoelectric conversion film  13 , the accumulated signal charges are transferred to a floating diffusion FD connected to the gate of the amplification transistor M 21 , by the gate MOS  41  and the gate MOS  42  as output signals. 
     The photoelectric conversion film  13  functions as the accumulator which accumulates the signal charges like the n type impurity area  12  and as a light blocking film which blocks the incident light H from reaching the accumulator, in addition to perform the photoelectric conversion. Along therewith, the photoelectric conversion film  13  functions as a light blocking film which blocks the incident light H which travels towards the readout circuit  51 , from reaching the readout circuit  51 . 
     Specifically, the photoelectric conversion film  13  is made of a compound semiconductor having a chalcopyrite structure. For example, the photoelectric conversion film  13  is made of CuInSe 2  which is the compound semiconductor having the chalcopyrite structure. 
       FIG. 5  is a diagram illustrating a relationship between photon energy and a light absorption coefficient. 
     As shown in  FIG. 5 , CuInSe 2  is higher than other materials in the light absorption coefficient, and particularly, is double digits higher than the Si single crystal (in the figure, x-Si). For this reason, CuInSe 2  suitably functions not only as a photoelectric conversion film but also as a light blocking film which blocks visible light. 
     The photoelectric conversion film  13  may use materials having any crystal structure such as monocrystalline, polycrystalline or amorphous structures as long as the materials have the higher absorption coefficient of visible light than the silicon substrate  11  and realize the photoelectric conversion function. 
     The photoelectric conversion film  13  may be formed using chalcopyrite materials other than CuInSe 2 . 
       FIGS. 6 and 7  are diagrams illustrating a relationship between a lattice constant and a band gap regarding the chalcopyrite materials. 
     As shown in  FIG. 6 , various chalcopyrite materials are shown. Of them, as shown in  FIG. 7 , for example, the photoelectric conversion film  13  may be made of a compound semiconductor with the chalcopyrite structure including copper-aluminum-gallium-indium-sulfur-selenium based mixed crystal. The copper-aluminum-gallium-indium-sulfur-selenium based mixed crystal can be formed through the control of the composition so as to correspond with the lattice constant of silicon (Si), and thus a crystal defect can be reduced. That is to say, since the copper-aluminum-gallium-indium-sulfur-selenium based mixed crystal can be epitaxially grown on the silicon substrate  11  as a monocrystalline thin film, and thus a crystal defect such as a misfit dislocation occurring at a heterointerface, it is possible to suppress generation of dark currents and reduce noise. 
     In addition to the above-described compound semiconductor, the photoelectric conversion film  13  may be formed using a compound semiconductor with the chalcopyrite structure including a copper-aluminum-gallium-indium-zinc-sulfur-selenium based mixed crystal. 
       FIG. 8  is a diagram illustrating a band structure of the solid-state imaging device according to the first embodiment. 
       FIG. 8  shows a band structure for parts of the photoelectric conversion film  13  and the silicon substrate  11 . In other words, a band structure in the depth direction z of the photoelectric conversion film  13  and the silicon substrate  11  is shown. 
     As shown in  FIG. 8 , in the depth direction z, the band is formed to be tilted with respect to the photoelectric conversion film  13 . Due to this, accumulated electrons are easily moved to the silicon substrate  11  side. 
     The conductivity type of the photoelectric conversion film  13  is, for example, a p type. The photoelectric conversion film  13  may be of an i type or an n type, in addition to the p type. 
     A-3-2. The Gate MOS  41  and the Gate MOS  42   
     In the solid-state imaging device  1 , the gate MOS  41  and the gate MOS  42  are provided for each of the plural pixels P shown in  FIG. 2 , as shown in  FIG. 4 . 
     The gate MOS  41  and the gate MOS  42  output the generated signal charges to the gate of the amplification transistor M 21  as the electric signals. Specifically, the gate MOS  41  and the gate MOS  42 , as shown in  FIG. 4 , are provided to be interposed between the photoelectric conversion film  13  and the floating diffusion FD. The gate MOS  41  and the gate MOS  42  transfer the signal charges to the floating diffusion FD as output signals when the gates are applied with readout signals from the readout lines H 41  and H 42 . 
     Here, the gate MOS  41  is provided on the opposite surface (front surface) side to the surface (rear surface) on which the photoelectric conversion film  13  is provided in the silicon substrate  11 , as shown in  FIG. 3 . Although not shown in  FIG. 3 , like the gate MOS  41 , the gate MOS  42  is provided on the opposite surface (front surface) side to the surface (rear surface) on which the photoelectric conversion film  13  is provided in the silicon substrate  11 . 
     The gate MOS  41  and the gate MOS  42  have active areas (not shown) formed in the silicon substrate  11 , and the gates thereof are made of conductive materials. 
     A-3-3. The Readout Circuit  51   
     In the solid-state imaging device  1 , the readout circuits  51  are disposed in plurality so as to correspond to the plural pixels P shown in  FIG. 2 . 
     As shown in  FIG. 4 , the readout circuit  51  includes the PD reset transistor M 11 , the amplification transistor M 21 , and the selection transistor M 31 , and reads out the signal charges through the gate MOS  41 . 
     Although not shown in  FIG. 3 , the respective transistors M 11 , M 21  and M 31  constituting the readout circuit  51 , like the gate MOS  41 , is provided on the opposite surface (front surface) side to the surface (rear surface) on which the photoelectric conversion film  13  is provided in the silicon substrate  11 . The respective transistors M 11 , M 21  and M 31  have, for example, active areas (not shown) formed in the silicon substrate  11 , and the gates thereof are made of conductive materials. 
     In the readout circuit  51 , the PD reset transistor M 11  resets a potential at the photoelectric conversion film  13 . 
     Specifically, the PD reset transistor M 11 , as shown in  FIG. 4 , has a gate connected to a PD reset line H 11  which is supplied with a PD reset signal. In addition, the PD reset transistor M 11  is electrically connected to the photodiode which has one terminal connected to the ground and the other terminal which is formed of the photoelectric conversion film  13 . The PD reset transistor M 11  resets a potential at the photodiode in response to the PD reset signal output from the PD reset line H 11 . 
     In the readout circuit  51 , the amplification transistor M 21  amplifies and outputs the electric signals resulting from the signal charges. 
     Specifically, the amplification transistor M 21 , as shown in  FIG. 4 , has a gate connected to the floating diffusion FD. In addition, the amplification transistor M 21  has a drain connected to a power source potential supply line Vdd, and a source connected to the selection transistor M 31 . The amplification transistor M 21  is supplied with a constant current from a constant current source (not shown) when the selection transistor M 31  is turned on, and thus works as a source follower. For this reason, the amplification transistor M 21  amplifies the output signals from the floating diffusion FD when the selection signal is supplied to the selection transistor M 31 . 
     In the readout circuit  51 , the selection transistor M 31  outputs the electric signals output from the amplification transistor M 21  to the vertical signal line  27  when the selection signal is input to the selection transistor M 31 . 
     Specifically, as shown in  FIG. 4 , the selection transistor M 31  has a gate connected to a selection line H 31  which is supplied with the selection signal. The selection transistor M 31  is turned on when the selection signal is supplied, and outputs the output signals amplified by the amplification transistor M 21  to the vertical signal line  27  as described above. 
     A-3-4. Others 
     In addition, as shown in  FIG. 3 , the color filter CF and the on-chip lens ML are provided on the upper surface (rear surface) side of the silicon substrate  11  so as to correspond to the pixel P. 
     Here, the color filter CF includes filters of the three primary colors, for example, a red filter layer (not shown), a green filter layer (not shown), and a blue filter layer (not shown). Further, the filters of the three primary colors are disposed for each pixel P, for example, in the Bayer arrangement. The arrangement of the filter layers of the respective colors is not limited to the Bayer arrangement, but may be other arrangements. 
     As shown in  FIG. 3 , the on-chip lens ML is provided over the upper surface of the silicon substrate  11  via the photoelectric conversion film  13 , the transparent electrode  14 , and the color filter CF. The on-chip lens ML is provided to protrude upwards in the convex shape from the silicon substrate  11 , and collects the incident light H coming from above on the photoelectric conversion film  13 . 
     Although not shown in the figure, the wire layer (not shown) is provided on the lower surface (front surface) of the silicon substrate  11  to cover the respective portions such as the gate MOS  41 . In the wire layer, a wire (not shown) electrically connected to each circuit element is formed inside an insulating layer (not shown). Specifically, the respective wires constituting the wire layer are laminated and formed so as to function as a wire such as the readout line H 41  shown in  FIG. 4 . 
     B. Manufacturing Method 
     The essence of the manufacturing method of the solid-state imaging device  1  will be described. 
       FIGS. 9A and 9B  are diagrams illustrating a manufacturing method of the solid-state imaging device according to the first embodiment. 
     Here,  FIGS. 9A and 9B  show the cross-sections in the same manner as  FIG. 3 , and the solid-state imaging device  1  shown in  FIG. 3  is manufactured through the respective steps shown in  FIGS. 9A and 9B . 
     B-1. Formation of the Photoelectric Conversion Film  13   
     First, the photoelectric conversion film  13  is formed as shown in  FIG. 9A . 
     Here, the respective portions such as the gate MOS  41  are formed on the surface of the silicon substrate  11  before the photoelectric conversion film  13  is formed. Further, the wire layer (not shown) is formed on the surface (front surface) of the silicon substrate  11  so as to cover the respective portions such as the gate MOS  41 . 
     In this embodiment, the respective portions are formed on a silicon layer of a so-called SOI substrate (corresponding to the silicon substrate  11 ), and then the silicon layer is transcribed onto a surface of another glass substrate (not shown). Thereby, the rear surface side of the silicon substrate  11  which is the silicon layer is seen and (100) surface is exposed. The n type impurity area  12  is formed inside or within a portion of the silicon substrate  11 . 
     Next, as shown in  FIG. 9A , the photoelectric conversion film  13  is formed on the opposite surface (rear surface) to the surface on which the respective portions such as the gate MOS  41  are formed in the silicon substrate  11 . 
     The photoelectric conversion film  13  is made of the compound semiconductor with the chalcopyrite structure including, for example, CuInSe 2  mixed crystal. 
     In addition, a compound semiconductor with the chalcopyrite structure including copper-aluminum-gallium-indium-sulfur-selenium based mixed crystal may be formed on the silicon substrate  11  so as to lattice-match with the silicon substrate  11 , thereby forming the photoelectric conversion film  13 . 
     In this case, the compound semiconductor is epitaxially grown on the silicon substrate  11  by, for example, an MBE method, an MOCVD method, or the like, thereby forming the photoelectric conversion film  13 . 
     The lattice constant of silicon (Si) is 5.431 Å. The CuAlGaInSSe based mixed crystal includes a material corresponding to the lattice constant, and can be formed so as to lattice-match with the silicon substrate  11 . Thereby, for example, a CuGa 0.52 In 0.48 S 2  film is formed on the silicon substrate  11  as the photoelectric conversion film  13 . 
     The photoelectric conversion film  13  is formed so as to have, for example, a p type as a conductivity type. In addition to the p type, the photoelectric conversion film  13  may be formed to have an i type or an n type as the conductivity type. 
     In this embodiment, the p type CuGa 0.52 In 0.48 S 2  film is formed and then the photoelectric conversion film  13  is formed such that, for example, concentration of zinc (Zn) which is an n type impurity is reduced according to the crystal growth. Thereby, the photoelectric conversion film  13  can be formed such that the band is tilted in the depth direction z. 
     The photoelectric conversion film  13  is formed such that the concentration of the impurity becomes, for example, 10 14  to 10 16  cm −3 . In addition, the photoelectric conversion film  13  is formed such that the film thickness becomes 300 nm. 
     The photoelectric conversion film  13  is formed to cover parts where pixel dividing portions PB are formed on the silicon substrate by epitaxially growing the compound semiconductor. 
     In the above description, although the case where the n type impurity is contained in the CuGa 0.52 In 0.48 S 2  film is described, this embodiment is not limited thereto. For example, by appropriately controlling each amount of a group III and a group I to be supplied, the photoelectric conversion film  13  can be formed such that the band is tilted in the depth direction z as in the above description. 
       FIG. 10  is a diagram illustrating an MOCVD device used in the first embodiment. 
     In a case where the above-described compound semiconductor is crystal-grown by the MOCVD growth method, for example, the MOCVD device shown in  FIG. 10  is used. 
     If the above-described crystal is grown on the substrate (silicon substrate), the substrate can be placed on a susceptor (made of carbon) as shown in  FIG. 10 . The susceptor is heated by a high frequency heating device (RF coils), and a temperature of the substrate is controlled. For example, the substrate is heated in a temperature range of 400° C. to 1000° C. where thermal decomposition can occur. 
     In addition, organic metal raw-materials are bubbled by hydrogen to enter a saturated vapor pressure state, and each raw-material molecule is transferred to a reaction tube. Here, a flow rate of hydrogen which flows towards each raw-material due to a mass flow controller (MFC) is controlled, and a molar amount of the raw-material which is transferred per unit of time is adjusted. The organic metal raw-materials are thermally decomposed on the substrate and grow the crystal. There is a correlation between a ratio of transferred molar amount and a composition ratio of the crystal. Thereby, the composition ratio of the crystal can be arbitrarily adjusted. 
     As raw gases, the following organic metals may be used. 
     Specifically, as an organic metal of copper, for example, acetylacetone copper (Cu(C 5 H 7 O 2 ) 2 ) is used. In addition, cyclopentadienyl copper triethylene (h5-(C 2 H 5 ) Cu:P (C 2 H 5 ) 3 ) may be used. 
     As an organic metal of gallium (Ga), for example, trimethyl gallium (Ga(CH 3 ) 3 ) is used. In addition, triethyl gallium (Ga(C 2 H 5 ) 3 ) may be used. 
     As an organic metal of aluminum (Al), for example, trimethyl aluminum (Al(CH 3 ) 3 ) is used. In addition, triethyl aluminum (Al(C 2 H 5 ) 3 ) may be used. 
     As an organic metal of indium (In), for example, trimethyl indium (In(CH 3 ) 3 ) is used. In addition, triethyl indium (In(C 2 H 5 ) 3 ) may be used. 
     As an organic metal of selenium (Se), for example, dimethyl selenium (Se(CH 3 ) 2 ) is used. In addition, diethyl selenium (Se(C 2 H 5 ) 2 ) may be used. 
     As an organic metal of sulfur (S), for example, dimethyl sulfide (S(CH 3 ) 3 ) is used. In addition, diethyl sulfide (S(C 2 H 5 ) 2 ) may be used. 
     As an organic metal of zinc (Zn), for example, dimethyl zinc (Zn(CH 3 ) 2 ) is used. In addition, diethyl zinc (Zn(C 2 H 5 ) 2 ) may be used. 
     In addition to the organic metals, for example, as a Se raw-material, hydrogen selenide (H 2 Se) may be used. Further, as an S raw-material, hydrogen sulfide (H 2 S) may be used. 
     In addition, the raw-material such as cyclopentadienyl copper triethylene (h5-(C 2 H 5 )Cu:P(C 2 H 5 ) 3 ), acetylacetone copper (Cu(C 5 H 7 O 2 ) 2 ) or trimethyl indium (In(CH 3 ) 3 ) is in a solid phase state at room temperature. In this case, the raw-material enters a liquid phase state through heating. In addition, even in the solid phase state, the raw-material may be used in a high vapor pressure simply at a high temperature. 
       FIG. 11  is a diagram illustrating an MBE device used in the first embodiment. 
     In a case where the above-described compound semiconductor is crystal-grown by the MBE growth method, for example, the MBE device shown in  FIG. 11  is used. 
     In this case, the simple substance raw-material of copper, and each of the simple substance raw-materials of gallium (Ga), aluminum (Al), indium (In), selenium (Se), and sulfur (S) are contained in each Knudsen cell. Further, these raw-materials are heated at an appropriate temperature, and the substrate is irradiated with each of molecular beams so as to perform crystal growth. 
     In this case, in a raw-material having a particularly high vapor pressure such as sulfur (S), stability of an amount of the molecular beams is lacking. Therefore, in this case, the amount of the molecular beams may be stabilized using a valved cracking cell. In addition, as in the gas source MBE, a portion of raw-materials may use gas sources. For example, as a Se material, hydrogen selenide (H 2 SE) may be used, and, as a sulfur (S) raw-material, hydrogen sulfide (H 2 S) may be used. 
     B-2. Formation of the Transparent Electrode  14   
     Next, the transparent electrode  14  is formed as shown in  FIG. 9B . 
     Here, the transparent electrode  14  is formed to cover the upper surface of the photoelectric conversion film  13 . For example, the transparent electrode  14  is made of indium tin oxide (ITO). In addition, the transparent electrode  14  may be made of a transparent conductive material such as zinc oxide or indium zinc oxide. 
     The transparent electrode  14  is formed as a single body over the plural pixels P shown in  FIG. 2 . 
     Further, as shown in  FIG. 3 , the respective portions such as the color filters CF and the on-chip lenses ML are formed on the upper surface (rear surface) of the silicon substrate  11 . In this way, the rear surface illumination type CMOS image sensor is completed. 
     C. An Operation 
     An operation of the solid-state imaging device  1  will be described. 
       FIGS. 12 to 13E  are diagrams illustrating an operation of the solid-state imaging device  1  according to the first embodiment. 
       FIG. 12  is a cross-sectional view and shows movements of electrons or holes when the incident light H enters the photoelectric conversion film  13 . 
     Also,  FIGS. 13A to 13E  show timing charts. In  FIGS. 13A to 13E ,  FIG. 13A  indicates a voltage at the photodiode constituted by the photoelectric conversion film  13  (refer to  FIG. 4 ).  FIG. 13B  indicates a PD reset signal transmitted to the gate of the PD reset transistor M 11  via the PD reset line H 11 .  FIG. 13C  indicates a first readout signal transmitted to the gate of the gate MOS  41  via the readout line H 41 .  FIG. 13D  indicates a second readout signal transmitted to the gate of the gate MOS  42  via the readout line H 42 .  FIG. 13E  indicates a selection signal transmitted to the gate of the selection transistor M 31  via the selection line H 31 .  FIGS. 13A to 13E  shows that the signals have a high level at the longitudinal lines extending vertically from the transverse lines, and thus the respective transistors are turned on. 
     As described above, in this embodiment, the global exposure is performed in which the incident light is sensed by all the pixels P at the same time, and then the sensing is finished without using a mechanical light blocking unit. That is to say, the exposure is performed by the “global shutter method.” 
     Specifically, as shown in  FIG. 12 , the incident light H enters the photoelectric conversion film  13  passing through the respective portions from the upper side of the silicon substrate  11 . In the photoelectric conversion film  13  which the incident light H has entered, the generated electrons (signal charges) are moved to the n type impurity area  12  (accumulator 1) of the silicon substrate  11 , and the holes are moved to the transparent electrode  14 . 
     In addition, as shown in  FIGS. 12 to 13E , the signal charges accumulated in the n type impurity area  12  (accumulator 1) are transferred to the n type impurity region  411  (accumulator 2) by the gate MOS  41 , and immediately thereafter, PD reset is made. In other words, the n type impurity area  12  (accumulator 1) is connected to the ground by the PD reset transistor M 11 , and the potential is reset to the voltage 0V (or, the power source voltage Vdd) (refer to  FIG. 4 ). Furthermore, immediately after the rest, as shown in  FIGS. 13A to 13E , the signal charges begin to accumulate. 
     The signal charges are transferred to the n type impurity region  421  (FD) by the gate MOS  42  and then accumulated. 
     This operation is performed in all the pixels P. The readout circuit  51  reads out the signal charges for each pixel P and outputs the read-out signal charges to the vertical signal line  27  as electric signals. 
     In the above description, the fixed pattern noise in the amplification transistor M 21  can be removed through the subtraction between the signals before and after the reset by the CDS circuit. However, the PD reset is made immediately after the signal charges accumulated in the n type impurity area  12  (accumulator 1) are transferred to the n type impurity region  411  (accumulator 2). For this reason, a variation in the reset signal voltage which is used as a reference when the CDS process is performed occurs, and thus kTC noise is included. 
     In this embodiment, the photoelectric conversion film  13  functions as a light blocking film along with the photoelectric conversion function. Thereby, as shown in  FIG. 12 , the incident light H is blocked from entering the respective n type impurity areas  12  and  411 , which function as the accumulators, by the photoelectric conversion film  13 . In addition, the incident light H is blocked from entering the readout circuit  51  or the n type impurity region  421  (floating diffusion layer) which functions as a floating diffusion by the photoelectric conversion film  13 . 
       FIG. 14  is a diagram illustrating a simulation result of a form of light traveling in the solid-state imaging device according to the first embodiment. Here, a result is shown when light having the wavelength of 650 nm enters a CuInGaS 2  film with the thickness of 0.3 μm which is formed as the photoelectric conversion film  13  on the silicon substrate  11  (0.5 μm thick) as in  FIG. 60 . 
     As shown in  FIG. 14 , in the solid-state imaging device in this embodiment, it can be seen that the incident light is absorbed and blocked by the photoelectric conversion film  13  and thus does not enter the silicon substrate  11 . In this case, it can be seen that if a rate of light reaching the bottom of the silicon substrate  11  is specifically estimated, only the light of 1.8×10 −3 % reaches, and the light is nearly blocked. 
     As such, in this embodiment, since the incident light H coming from the upper surface (rear surface) can be blocked, and the light does not reach the respective portions such as the accumulators, it is possible to prevent the generation of noise and improve the image quality of a captured image. 
     D. Conclusion 
     As described above, in this embodiment, in the pixels P, the photoelectric conversion film  13  generates the signal charges by sensing and photoelectric-converting the incident light H. The signal charges generated by the photoelectric conversion film  13  are read out by the readout circuit  51 . Also, the signal charges generated by the photoelectric conversion film  13  are accumulated in the n type impurity areas  12  and  411  which are the accumulators. Here, the photoelectric conversion film  13  is provided at the side where the incident light H enters when seen from the readout circuit  51  and the n type impurity areas  12  and  411  in the silicon substrate  11 , and thus blocks the incident light H from entering the readout circuit  51  and the n type impurity areas  12  and  411 . 
     For this reason, in this embodiment, it is possible to realize a small size, prevent the generation of noise, and improve the image quality of a captured image. 
     Further, in this embodiment, the pixels P include the photoelectric conversion film  13 , and the photoelectric conversion film  13  is made of the compound semiconductor having the chalcopyrite structure. The photoelectric conversion film  13  is formed on the silicon substrate  11  so as to lattice-match with the silicon substrate  11 . In this case, since the misfit dislocation occurring in the heterointerface can be reduced, the crystallinity of the photoelectric conversion film  13  is improved. Thus, the crystal defect is reduced, and thereby it is possible to suppress the generation of a dark current and prevent deterioration of the image quality due to white dots. Further, since high sensitivity can be realized, a high quality imaging can be performed even in a dark imaging environment (for example, night time). 
     In the above description, the definition of the “lattice matching” includes a state close to the lattice matching under a condition of the thickness of the photoelectric conversion film being within a critical film thickness. 
     In other words, if the thickness is within the critical film thickness, the lattice matching is not completely made, but the crystallinity can become good since the misfit dislocation is not included. 
     Further, the “critical film thickness” is defined by the equation (1) by “Matthews and Blakeslee” (for example, refer to J. W. Mathews and A. E. Blakeslee, J. Cryst. Growth 27(1974) 118-125) and the equation (2) by “People and Bean” (for example, refer to R. People and J. C. Bean, Appl. Phys. Lett. 47(1985) 322-324). In the following equations, a denotes a lattice constant, b denotes a Burgers vector for dislocation, v denotes a Poisson ratio, and f denotes a lattice mismatching |Δa/a|. 
     
       
         
           
             
               
                 
                   
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     E. Modified Examples 
     E-1. A Modified Example 1-1 
     In the above description, although the case where the photoelectric conversion film  13  is made of the chalcopyrite materials has been described, the present invention is not limited thereto. 
     The photoelectric conversion film  13  may be made of silicide based materials. 
       FIG. 15  is a diagram illustrating a relationship between the photon energy (eV) and the absorption index k in the silicide materials. 
     The light absorption coefficient α indicates the following relation with respect to the absorption index k and the wavelength λ.
 
α=4π k/λ 
 
     For this reason, as can be seen from  FIG. 15 , the silicide based materials such as CoSi, CrSi, HfSi, IrSi, MoSi, NiSi, PdSi, ReSi, TaSi, TiSi, WSi, and ZrSi have a higher light absorption coefficient α than Si. 
     In addition, a β-iron silicide material (β-FeSi 2 ) is double digits higher than Si in the light absorption coefficient (refer to H. Katsumata, et al., J. Appl. Phys. 80 (10), 5955 (1996)). 
     In addition, the β-iron silicide material (β-FeSi 2 ) can be epitaxially grown on a silicon substrate (refer to John E. Mahan, et al., Appl. Phys. Lett. 56 (21), 2126 (1990)). Thereby, the photoelectric conversion film  13  can be formed so as to realize both the photoelectric conversion function and the light blocking function by using the β-iron silicide material (β-FeSi 2 ). 
     Further, a Barium silicide based material (BaSi 2 ) or Ba 1−x Sr x Si 2  is about double digits higher than silicon (Si) in the light absorption coefficient (refer to the following reference). In the same manner, silicide materials such as SiGe, Mg 2 SiGe, SrSi 2 , MnSi 1.7 , CrSi 2 , Ni—Si, Cu/Si, Co/Si, or Pt/Si are higher than Si in the light absorption coefficient. 
     Therefore, the photoelectric conversion film  13  can be formed so as to also function as a light blocking film by using silicide materials. 
     In addition to the above-described inorganic materials, the photoelectric conversion film  13  may be formed using organic materials. 
     For example, quinacridone or coumarin based organic materials, or the like have the light absorption coefficient almost twice higher than Si, and the photoelectric conversion film  13  can be formed so as to have the light blocking function along with the photoelectric conversion function by using them. 
     E-2. A Modified Example 1-2 
     In the first embodiment, as described above, the kTC noise is included in the signal, but the kTC noise may be removed as described below. 
       FIG. 16  is a diagram illustrating a circuit configuration of a pixel constituting a solid-state imaging device according to a modified example 1-2 of the first embodiment. 
       FIGS. 17 to 18F  are diagrams illustrating an operation of the solid-state imaging device according to the modified example 1-2 of the first embodiment. 
       FIG. 17  is a cross-sectional view in the same manner as  FIG. 12 , and shows movements of electrons or holes when the incident light H enters the photoelectric conversion film  13 . 
     Also,  FIGS. 18A to 18F  show timing charts in the same manner as  FIGS. 13A to 13E . In  FIGS. 18A to 18F ,  FIG. 18A  indicates a voltage at the photodiode constituted by the photoelectric conversion film  13  (refer to  FIG. 16 ).  FIG. 18B  indicates a voltage at the n type impurity region  411  which functions as a floating diffusion.  FIG. 18C  indicates a PD reset signal transmitted to the gate of the PD reset transistor M 11  via the PD reset line H 11 .  FIG. 18D  indicates an FD reset signal transmitted to a gate of an FD reset transistor M 12  via an FD reset line H 12 .  FIG. 18E  indicates a readout signal transmitted to the gate of the gate MOS  41  via the readout line H 41 .  FIG. 18F  indicates a selection signal transmitted to the gate of the selection transistor M 31  via the selection line H 31 .  FIGS. 18A to 18F  shows that the signals have a high level at the longitudinal lines extending vertically from the transverse lines, and thus the respective transistors are turned on. 
     As shown in  FIGS. 16 to 18F , the FD reset transistor M 12  which resets a potential at the floating diffusion FD may be provided instead of the gate MOS  42  (refer to  FIG. 4 ) in the first embodiment. 
     Specifically, the FD reset transistor M 12 , as shown in  FIG. 16 , has the gate connected to the FD reset line H 12  which is supplied with the FD reset signal. Further, the FD reset transistor M 12  has one terminal connected to the floating diffusion FD (n type impurity region  411 ) and the other terminal electrically connected to the power source potential supply line Vdd. Also, the FD reset transistor M 12  resets a potential at the floating diffusion FD (n type impurity region  411 ) in response to the FD reset signal output from the FD reset line H 12 . 
     In this modified example, as shown in  FIG. 17 , the incident light H enters the photoelectric conversion film  13  passing through the respective portions from the upper side of the silicon substrate  11 . In the photoelectric conversion film  13  which the incident light H has entered, the generated electrons (signal charges) are moved to the n type impurity area  12  (accumulator 1) of the silicon substrate  11 , and the holes are moved to the transparent electrode  14 . The photoinduced charges generated by the photoelectric conversion film  13  are moved to the surface opposite to the light incident surface since an internal electric field generated by a doping control exists in the n type impurity area  12  (accumulator 1) of the silicon substrate  11 . 
     Also, the “FD reset” is made and then the potential at the floating diffusion FD is reset. 
     After a predetermined time for accumulation has elapsed, a potential at the n type impurity area  12  (accumulator 1) is reset to 0V or the power source voltage Vdd (V) through the “PD reset” (here, the case where reset to Vdd (V) is shown). Immediately after the reset, the signal charges begin to accumulate. In other words, after the potential at the n type impurity area  12  (accumulator 1) is reset by the PD reset transistor M 11  as shown in  FIGS. 18A to 18F , the electrons (signal charges) begin to accumulate. 
     As shown in  FIGS. 17 to 18F , the signal charges accumulated in the n type impurity area  12  (accumulator 1) are transferred to the n type impurity region  411  (accumulator 2) by the gate MOS  41  and then accumulated. The readout circuit  51  reads out the signal charges and outputs the read-out signal charges to the vertical signal line  27  as electric signals. 
     This operation is performed in all the pixels P. 
     Thereafter, the selection transistor M 31  is turned on using the selection line H 31  for each pixel P or each row of the pixels P, a voltage variation in the n type impurity region  411  (accumulator 2 also used as FD) is amplified by the amplification transistor M 21 , and then the signals are sequentially read out. 
     At this time, by the CDS circuit, a difference between the amplified voltage and an initial voltage is read out as a signal. 
     In the above description, as shown in  FIGS. 18A to 18F , the PD voltage drops due to the accumulation of the signal charges. In this modified example, a variation in the voltage occurs when the “PD reset” or the “FD reset” is made, and thus the kTC noise is generated. However, the variation is removed through the correlated double sampling (CDS) process and thus the kTC can be removed. In other words, as shown in  FIGS. 18A to 18F , the noise can be removed with a difference between the pixel signal voltage and the reset signal voltage (CDS operation). However, in this case, since the n type impurity region  411  (according to 2 also used as FD) comes into direct contact with the surface of the silicon substrate  11 , a dark current is generated at a surface level. 
     In addition, in this embodiment as well, the photoelectric conversion film  13  functions as a light blocking film along with the photoelectric conversion function. Thereby, as shown in  FIG. 17 , the incident light H is blocked from entering the respective n type impurity areas  12  and  411 , which function as the accumulators, by the photoelectric conversion film  13 . 
     Therefore, in this modified example as well, since the incident light H coming from the upper surface (rear surface) can be blocked by the photoelectric conversion film  13 , and the light does not reach the accumulators, it is possible to prevent the generation of noise and improve the image quality of a captured image. 
     E-3. A Modified Example 1-3 
       FIG. 19  is a diagram illustrating a circuit configuration of a pixel constituting a solid-state imaging device according to a modified example 1-3 of the first embodiment. 
       FIGS. 20 to 21G  are diagrams illustrating an operation of the solid-state imaging device according to the modified example 1-3 of the first embodiment. 
       FIG. 20  is a cross-sectional view in the same manner as  FIG. 17 , and shows movements of electrons or holes when the incident light H enters the photoelectric conversion film  13 . 
     Also,  FIGS. 21A to 21G  are diagrams illustrating an operation of the solid-state imaging device according to the modified example 1-3 of the first embodiment.  FIGS. 21A to 21G  show timing charts. In  FIGS. 21A to 21G ,  FIG. 21A  indicates a voltage at the photodiode constituted by the photoelectric conversion film  13  (refer to  FIG. 20 ).  FIG. 21B  indicates a voltage at the n type impurity region  411  which functions as a floating diffusion.  FIG. 21C  indicates a PD reset signal transmitted to the gate of the PD reset transistor M 11  via the PD reset line H 11 .  FIG. 21D  indicates an FD reset signal transmitted to a gate of an FD reset transistor M 12  via an FD reset line H 12 .  FIG. 21E  indicates a signal (transparent electrode) transmitted to the transparent electrode  14 .  FIG. 21F  indicates a readout signal transmitted to the gate of the gate MOS  41  via the readout line H 41 .  FIG. 21G  indicates a selection signal transmitted to the gate of the selection transistor M 31  via the selection line H 31 .  FIGS. 21A to 21G  show that the signals have a high level at the longitudinal lines extending vertically from the transverse lines, and thus the respective transistors are turned on. 
     In  FIGS. 21A to 21G ,  FIG. 21E  shows the signal (transparent electrode) transmitted to the transparent electrode  14  in addition to the signals shown in  FIGS. 18A to 18F . 
     As shown in  FIGS. 19 to 21G , the modified example 1-2 of the first embodiment may be configured to apply a signal to the transparent electrode  14  so as to control the potential. Due to this, even in a case where there is a single accumulator, the exposure by the global shutter method can be performed. 
     Specifically, first, a signal of a zero bias or a negative bias is applied to the transparent electrode  14 . Thereby, the generated photoinduced charges are moved to the n type impurity area  12  (accumulator 1) and then begin to be accumulated. 
     Next, the “PD reset” is made. Thereby, the n type impurity area  12  (accumulator 1) is reset to the voltage 0V or Vdd (V), and immediately thereafter, the accumulation begins again. In addition,  FIGS. 21A to 21G  show a case where the n type impurity area  12  (accumulator 1) is reset to Vdd (V). After a predetermined time for accumulation has elapsed, a positive bias is applied to the transparent electrode  14 . Therefore, newly generated photoinduced charges are moved to the transparent electrode  14  side, and the accumulation in the n type impurity area  12  (accumulator 1) is finished. 
     Then, immediately after the “FD reset” is made, the photoinduced charges are transferred to the n type impurity region  411  (FD) using the readout line H 41 . Further, immediately thereafter, using the selection line H 31  for each pixel P or each row of the pixels P, a voltage variation in the n type impurity region  411  (FD) is amplified by the amplification transistor M 21 , and then a signal thereof is read out. This is sequentially repeated. 
     In this way, it is possible to suppress a dark current from being generated by shortening the time for the accumulation in the n type impurity region  411  (FD). In addition, at this time, the kTC noise can be removed by reading out a difference between the pixel signal voltage and the reset signal voltage as a signal using the CDS circuit. This structure is effective for a fine pixel since the number of transistors necessary for each pixel is reduced. 
     E-4. A Modified Example 1-4 
     In the modified example 1-2 described above, since the n type impurity region  411  (accumulator 2 also used as FD) comes into direct contact with the surface of the silicon substrate  11 , a dark current is generated at a surface level. 
     In order to lower the dark current at a surface level, the following configuration may be employed. 
       FIG. 22  is a diagram illustrating a circuit configuration of a pixel constituting a solid-state imaging device according to a modified example 1-4 of the first embodiment. 
       FIGS. 23 to 24G  are diagrams illustrating an operation of the solid-state imaging device according to the modified example 1-4 of the first embodiment. 
       FIG. 23  is a cross-sectional view in the same manner as  FIG. 12 , and shows movements of electrons or holes when the incident light H enters the photoelectric conversion film  13 . 
     Also,  FIGS. 24A to 24G  show timing charts in the same manner as  FIGS. 13A to 13E . In  FIGS. 24A to 24G ,  FIG. 24A  indicates a voltage at the photodiode constituted by the photoelectric conversion film  13  (refer to  FIG. 22 ). FIG.  24 B indicates a voltage at the n type impurity region  421  which functions as a floating diffusion.  FIG. 24C  indicates a PD reset signal transmitted to the gate of the PD reset transistor M 11  via the PD reset line H 11 .  FIG. 24D  indicates an FD reset signal transmitted to a gate of an FD reset transistor M 12  via an FD reset line H 12 .  FIG. 24E  indicates a first readout signal transmitted to the gate of the gate MOS  41  via the readout line H 41 .  FIG. 24F  indicates a second readout signal transmitted to the gate of the gate MOS  42  via the readout line H 42 .  FIG. 24G  indicates a selection signal transmitted to the gate of the selection transistor M 31  via the selection line H 31 .  FIGS. 24A to 24G  shows that the signals have a high level at the longitudinal lines extending vertically from the transverse lines, and thus the respective transistors are turned on. 
     As shown in  FIGS. 22 to 24G , the FD reset transistor M 12  described in the modified example 1-2 may be added to the configuration according to the first embodiment. 
     Specifically, the FD reset transistor M 12 , as shown in  FIG. 22 , has the gate connected to the FD reset line H 12  which is supplied with the FD reset signal. Further, the FD reset transistor M 12  has one terminal connected to the floating diffusion FD (n type impurity region  421 ) and the other terminal electrically connected to the power source potential supply line Vdd. Also, the FD reset transistor M 12  resets a potential at the floating diffusion FD (n type impurity region  421 ) in response to the FD reset signal output from the FD reset line H 12 . 
     In this modified example as well, as shown in  FIG. 23 , the incident light H enters the photoelectric conversion film  13  passing through the respective portions from the upper side of the silicon substrate  11 . In the photoelectric conversion film  13  which the incident light H has entered, the generated electrons (signal charges) are moved to the n type impurity area  12  (accumulator 1) of the silicon substrate  11 , and the holes are moved to the transparent electrode  14 . 
     In addition, as shown in  FIGS. 24A to 24G , a potential at the n type impurity area  12  (accumulator 1) is reset to 0V or the power source voltage Vdd (V) through the “PD reset” (here, the case where reset to Vdd (V) is shown). Immediately after the reset, the signal charges begin to be accumulated. In other words, after the potential at the n type impurity area  12  (accumulator 1) is reset by the PD reset transistor M 11  as shown in  FIGS. 24A to 24G , the electrons (signal charges) begin to be accumulated. 
     Also, after a predetermined time for the accumulation has elapsed, the gate MOS  41  is turned on so as to transfer the signal charges from the n type impurity area  12  (accumulator 1) to the n type impurity region  411  (accumulator 2) (the “readout 1” is performed). 
     Through the “FD reset,” a potential at the n type impurity region  421  (FD) functioning as a floating diffusion is reset. 
     Further, immediately after the “FD reset,” as shown in  FIGS. 17 to 18F , the signal charges accumulated in the n type impurity area  12  (accumulator 1) are transferred to the n type impurity region  421  (FD) by the gate MOS  41  and then accumulated (the “readout 2” is performed). 
     Immediately thereafter, a voltage variation in the n type impurity region  421  (FD) is amplified by the amplification transistor M 21  for each pixel P or each row of the pixels P, the readout circuit  51  reads out the signals thereof and outputs the read-out signal to the vertical signal line  27  as electric signals. 
     In the modified example 1-2, the n type impurity region  411  functioning as the accumulator and FD is formed on the surface of the silicon substrate  11 , and thus it is difficult to suppress a dark current generated at a surface level. 
     However, in this modified example, the n type impurity region  421  (FD) functioning as FD is formed separately, and the n type impurity region  411  (accumulator 2) does not function as FD. 
     Although not shown, a p+ layer in which a p type impurity is diffused with high concentration is formed in the surface of the n type impurity region  421 . In other words, the p+ layer in which a impurity diffusion layer having the conductivity type different from the n type impurity region  421  (accumulator) is provided in the surface layer of the silicon substrate  11 . 
     Moreover, it is possible to suppress a dark current from being generated by shortening the time for the accumulation in the n type impurity region  421  (FD). In addition, at this time, the kTC noise can be removed by reading out a difference between the pixel signal voltage and the reset signal voltage as a signal using the CDS circuit. 
     Thereby, in this modified example, in the same manner as the modified example 1-2, it is possible to prevent the generation of the kTC noise and prevent the generation of a dark current. 
     E-5. A Modified Example 1-5 
       FIG. 25  is a diagram illustrating main portions of a solid-state imaging device according to a modified example 1-5 of the first embodiment.  FIG. 25  shows a cross-section of the pixel P in the same manner as  FIG. 12 . 
       FIG. 26  is a diagram illustrating a circuit configuration of a pixel constituting the solid-state imaging device according to the modified example 1-5 of the first embodiment. 
       FIGS. 27A to 27F  are diagram illustrating an operation of the solid-state imaging device according to the modified example 1-5 of the first embodiment.  FIGS. 27A to 27F  show timing charts.  FIGS. 27A to 27F  show a third readout signal (readout 3) transmitted to a control gate  15  via a readout line H 43  in addition to the signals shown in  FIGS. 13A to 13E . 
     As shown in  FIGS. 25 and 26 , the control gate  15  may be further added to the configuration(refer to  FIG. 12 ). 
     Specifically, the control gate  15  may be formed so as to cover the part where the n type impurity area  12  (accumulator 1) is formed in the surface of the silicon substrate  11 . 
     In the control gate  15 , for example, an electric field is applied such that the signal charges (here, electrons) generated by the photoelectric conversion film  13  are moved to the n type impurity area  12  through drift. 
     In addition, an electric field may be applied to the control gate  15  such that the signal charges generated by the photoelectric conversion film  13  are temporarily accumulated and then moved to the n type impurity area  12  (accumulator 1). 
     As shown in  FIG. 26 , the control gate  15  is electrically connected to the readout line H 43 . Further, as shown in  FIGS. 27A to 27F , a potential at the control gate  15  may be controlled via the readout line H 43 . 
     Specifically, as shown in  FIGS. 25 to 27F , an electric field is applied to the control gate  15  for a long time such that the signal charges are moved from the photoelectric conversion film  13  to the n type impurity area  12  (accumulator 1). After the state, for a short time the electric field is not applied to the control gate  15 . During the time when the electric field is not applied, the signal charges are moved from the n type impurity area  12  (accumulator 1) to the n type impurity region  411  (accumulator 2) by the gate MOS  41 . Thereafter, the “PD reset” is made. Next, the electric field is secondly applied to the control gate  15  for a long time such that the signal charges are moved from the photoelectric conversion film  13  to the n type impurity area  12  (accumulator 1). During this interval, the amplified signal is read out in the same manner as in the first embodiment. 
     If the control gate  15  is formed, this modified example is not limited to the above-described configuration. 
       FIG. 28  is a diagram illustrating main portions of the solid-state imaging device according to the modified example 1-5 of the first embodiment.  FIG. 28  shows a cross-section of the pixel P in the same manner as  FIG. 25 . 
       FIG. 29  is a diagram illustrating a circuit configuration of a pixel constituting the solid-state imaging device according to the modified example 1-5 of the first embodiment. 
       FIGS. 30A to 30E  are diagrams illustrating an operation of the solid-state imaging device according to the modified example 1-5 of the first embodiment.  FIGS. 30A to 30E  show timing charts. 
     As shown in  FIGS. 28 to 30E , the respective portions may be driven without forming the gate MOS  42  and the n type impurity region  411  (accumulator 2). In other words, as shown in  FIGS. 30A to 30E , the signal charges are instantly moved from the photoelectric conversion film  13  of all the pixels P to the n type impurity area  12  (accumulator 1) (refer to the “readout 3”). Thereafter, in the same manner as the above-described case, the “readout 1” and the “selection” are performed, and an amplified signal is sequentially read out. 
     E-6. A Modified Example 1-6 
       FIGS. 31A and 31B  are diagrams illustrating a band structure of a solid-state imaging device according to a modified example 1-6 of the first embodiment. 
       FIGS. 31A and 31B , in the same manner as  FIG. 8 , show a band structure in the depth direction z of the photoelectric conversion film  13  and the silicon substrate  11 .  FIG. 31A  shows a case where the photoelectric conversion film  13  with a band structure different from that in  FIG. 8  is formed, and  FIG. 31B  shows a preferable case in that case. 
     A lattice matching chalcopyrite material may not be constant in the band structure. In other words, as shown in  FIG. 31A , the photoelectric conversion film  13  having the different band structure may be formed in some cases as can be seen from the comparison with  FIG. 8 . 
     For example, as disclosed in D. S. Substrate and W. Neumann, Appl. Phys. Lett. 73, 785, (1998), since a CuAu type regular phase is formed according to a growth condition, this alters the band structure, and the electron affinity (an energy difference between a bottom and a vacuum level in the conduction band) may vary. 
     For this reason, there are cases of not forming the relation of (the electron affinity of the silicon substrate  11 )&gt;(the electron affinity of the photoelectric conversion film  13 ) unlike the case in  FIG. 8 . 
     As shown in  FIG. 31A , in the case of (the electron affinity of the silicon substrate  11 )&lt;(the electron affinity of the photoelectric conversion film  13 ), a potential barrier exists between the silicon substrate  11  and the photoelectric conversion film  13 . Thereby, electrons accumulated in the photoelectric conversion film  13  are hard to move to the silicon substrate  11  side in some cases. 
     In order to prevent the generation of such a defect, as shown in  FIG. 31B , an intermediate layer IT may be interposed between the silicon substrate  11  and the photoelectric conversion film  13 . 
     The electron affinity of the intermediate layer IT is formed to lie between the electron affinity of the silicon substrate  11  and the electron affinity of the photoelectric conversion film  13  in order to lower the potential barrier between the silicon substrate  11  and the photoelectric conversion film  13 . In other words, the electron affinity of the intermediate layer IT has the following relation.
 
(the electron affinity of the silicon substrate 11)&lt;(the electron affinity of the intermediate layer IT)&lt;(the electron affinity of the photoelectric conversion film 13)
 
     Most preferably, the electron affinity of the intermediate layer IT is exactly half the electron affinity of the silicon substrate  11  and the electron affinity of the photoelectric conversion film  13 . 
     For example, the intermediate layer IT is preferably formed under the conditions of the following materials and film thickness. 
     Materials (composition): CuGa 0.64 In 0.36 S 2    
     Film thickness: 5 nm 
     In addition, as long as the intermediate layer IT has the film thickness within a critical film thickness, the intermediate layer IT may not be lattice-matched with the silicon substrate  11 . For example, in the case of the intermediate layer IT (CuGa 0.64 In 0.36 S 2 ), the lattice mismatching with the Si substrate becomes Δa/a=5.12×10 −3 . At this time, if the film thickness is 5 nm, the film thickness is smaller than the critical film thickness defined by the equation (1) by “Matthews and Blakeslee” (J. W. Mathews and A. E. Blakeslee, J. Cryst. Growth 27(1974) 118-125) and the equation (2) by “People and Bean” (R. People and J. C. Bean, Appl. Phys. Lett. 47(1985) 322-324). 
     2. A Second Embodiment (a Case of Forming a Pixel Dividing Portion Doped Through an Ion Implantation) 
     A. A Device Configuration and the Like 
       FIG. 32  is a diagram illustrating main portions of a solid-state imaging device according to a second embodiment. 
       FIG. 32  shows a cross-section of the pixel P in the same manner as  FIG. 3 . 
     As shown in  FIG. 32 , in this embodiment, a pixel dividing portion PB is provided. Further, instead of the transparent electrode  14 , a p+ layer  14   p  is provided. Except for this, this embodiment is the same as the first embodiment. Therefore, the description of the overlapping parts will be omitted. 
     The pixel dividing portion PB, as shown in  FIG. 32 , is interposed between the pixels P shown in  FIG. 2 , and is provided to divide the pixels from each other. In other words, the pixel dividing portion PB is provided to extend in the horizontal direction x and the vertical direction y so as to be interposed between the pixels on the imaging surface (xy plane). 
     Here, the pixel dividing portion PB, as shown in  FIG. 32 , is provided on the lateral surface of the photoelectric conversion film  13  which is provided for each P on the one surface of the silicon substrate  11 . 
     In this embodiment, the pixel dividing portion PB is made of semiconductors including p type impurities. For example, the pixel dividing portion PB is made of a chalcopyrite based compound semiconductor including p type impurities with high concentration. 
     That is to say, the pixel dividing portion PB is formed to block the incident light H from entering the n type impurity areas  12 ,  411  and  421  which function as an accumulator in the same manner as the photoelectric conversion film  13 . 
     The p+ layer  14   p , as shown in  FIG. 32 , is made of a semiconductor including a p type impurity on the upper surface of the photoelectric conversion film  13 . 
     Here, the p+ layer  14   p  is formed with a high concentration of the impurity such that holes generated in the photoelectric conversion film  13  enter the p+ layer  14   p  and are moved in the transverse direction. 
     For example, the p+ layer  14   p  is made of a compound semiconductor with the chalcopyrite structure in the same manner as the photoelectric conversion film  13  and the pixel dividing portion PB. 
       FIG. 33  is a diagram illustrating a band structure of the solid-state imaging device according to the second embodiment. 
       FIG. 33  shows a band structure for the part XXXIII-XXXIII marked with the chain line in  FIG. 32 . In other words,  FIG. 33  shows a band structure for the parts where the photoelectric conversion film  13  and the pixel dividing portion PB are formed in the direction x along the surface of the silicon substrate  11 . 
     As shown in  FIG. 33 , in the direction x along the surface of the silicon substrate  11 , a potential barrier is formed between the photoelectric conversion film  13  and the pixel dividing portion PB. For this reason, the accumulated electrons are blocked from being moved between the pixels P. 
     B. Manufacturing Method 
     The essence of the manufacturing method of the solid-state imaging device will be described. 
       FIGS. 34 to 37  are diagrams illustrating the manufacturing method of the solid-state imaging device according to the second embodiment. 
     Here,  FIGS. 34 to 37  show the cross-sections in the same manner as  FIG. 3 , and the solid-state imaging device  1  shown in  FIG. 32  and the like is manufactured through the respective steps shown in  FIGS. 34 to 37 . 
     B-1. Formation of the Photoelectric Conversion Film  13  and the p+ Layer  14   p    
     First, the photoelectric conversion film  13  and the p+ layer  14   p  are formed as shown in  FIG. 34 . 
     Here, the respective portions such as the gate MOS  41  are formed on the surface (front surface) of the silicon substrate  11  before the photoelectric conversion film  13  and the p+ layer  14   p  are formed in the same manner as the first embodiment. Further, the wire layer (not shown) is formed on the surface (front surface) of the silicon substrate  11  so as to cover the respective portions such as the gate MOS  41 . 
     Next, as shown in  FIG. 34 , the photoelectric conversion film  13  and the p+ layer  14   p  are sequentially formed on the opposite surface (rear surface) to the surface on which the respective portions such as the gate MOS  41  are formed in the silicon substrate  11 . 
     The photoelectric conversion film  13  is made of the compound semiconductor with the chalcopyrite structure in the same manner as the first embodiment. In this embodiment, the photoelectric conversion film  13  is formed to cover a part in which the pixel dividing portion PB is formed on the upper surface of the silicon substrate  11 . 
     Further, the p+ layer  14   p  is formed to cover the upper surface of the photoelectric conversion film  13 . The p+ layer  14   p  is also made of the compound semiconductor with the chalcopyrite structure. 
     The p+ layer  14   p  is formed through the crystal growth of the compound semiconductor with the chalcopyrite structure under the condition of including a lot of an impurity such as Ga, In, As, or P, by the MOCVD method, the MBE method, or the like. Here, the p+ layer  14   p  is formed with high concentration such that holes enter the p+ layer  14   p  and are moved in the transverse direction. 
     For example, the p+ layer  14   p  is formed to have the impurity concentration of 10 17  to 10 19  cm −3 . In addition, the p+ layer  14   p  is formed to have the film thickness of 10 to 100 nm. 
     B-2. Formation of a Resist Pattern PR 
     Next, as shown in  FIG. 35 , a resist pattern PR is formed. 
     Here, as shown in  FIG. 35 , the resist pattern PR is formed on the p+ layer  14   p.    
     In this embodiment, the resist pattern PR has apertures in order to expose a part of the upper surface of the p+ layer  14   p  under which the pixel dividing portion PB will be formed and to cover parts other than the exposed part. 
     Specifically, a photoresist film (not shown) is formed on the p+ layer  14   p  through application, and the resist pattern PR is formed by patterning the photoresist film by lithography. 
     B-3. An Ion Implantation 
     Next, as shown in  FIG. 36 , the ion implantation is performed. 
     Here, as shown in  FIG. 36 , an impurity is ion-implanted into the photoelectric conversion film  13  by using the resist pattern PR as a mask. Thereby, the impurity is ion-implanted into the part where the pixel dividing portion PB is formed in the photoelectric conversion film  13  from the aperture of the resist pattern PR. 
     In this embodiment, a p type impurity such as Ga, In, As or P is ion-implanted into the part where the pixel dividing portion PB is formed in the photoelectric conversion film  13 , and the p type impurity is contained with a high concentration. 
     For example, the ion implantation is performed such that the concentration of the p type impurity is 10 17  to 10 19  cm −3  in the part where the pixel dividing portion PB is formed. 
     The resist pattern PR is removed from the upper surface of the p+ layer  14   p.    
     B-4. Formation of the Pixel Dividing Portion PB 
     Next, as shown in  FIG. 37 , the pixel dividing portion PB is formed. 
     Here, the pixel dividing portion PB is formed by activation through annealing. 
     Specifically, the pixel dividing portion PB is formed through the annealing at a temperature of 400° C. or more. 
     In this way, the pixel dividing portion PB is formed by selectively doping the part forming the pixel dividing portion PB inside the photoelectric conversion film  13  which is formed to include the part forming the pixel dividing portion PB on the silicon substrate  11 . 
     Also, as shown in  FIG. 32 , the respective portions such as the color filters CF and the on-chip lenses ML are formed on the upper surface (rear surface) of the silicon substrate  11 . Through the steps, the rear surface illumination type CMOS image sensor is completed. 
     C. Conclusion 
     In this embodiment, in the same manner as the first embodiment, the photoelectric conversion film  13  is provided at the side where the incident light H enters when seen from the respective portions such as the n type impurity areas  12  and  411  in the silicon substrate  11 , and thus blocks the incident light H from entering the n type impurity areas  12  and  411  (refer to  FIG. 32 ). For this reason, in this embodiment and in the same manner as the first embodiment, it is possible to realize a small size, prevent the generation of noise, and improve the image quality of a captured image. 
     In addition, in this embodiment, the pixel dividing portion PB is formed to be interposed between the plural pixels P. The pixel dividing portion PB is made of the compound semiconductor of which the doping concentration is controlled, so as to form potential barriers between the photoelectric conversion films  13  which are formed corresponding to the plural pixels P. 
     Thereby, in this embodiment, it is possible to prevent a color mixture using the pixel dividing portion PB. In the related art in which there is no pixel dividing portion PB, the electrons generated through the photoelectric conversion are freely moved between the pixels. Assuming that the electrons are moved equally in all directions, about 30% of the electrons in a pixel of 1.5 μm are moved to neighboring pixels. The movement almost disappears due to the pixel dividing portion PB formed between the pixels P. 
     Further, in this embodiment, the p+ layer  14   p , which is a diffusion layer of the impurity with high concentration, is formed on the surface of the photoelectric conversion film  13  at the side which the incident light enters. Therefore, it is possible to suppress the generation of a dark current. 
     Also, in this embodiment, the p+ layer  14   p  is formed to be connected to each other among the plural pixels P. For this reason, holes enters the p+ layer  14   p  from the photoelectric conversion film  13  and then are moved to the pixels P in the transverse direction, and electrons generated in the photoelectric conversion film  13  are moved to the silicon substrate  11  side. Thereby, the transparent electrode may not be formed on the upper surface of the photoelectric conversion film  13 . 
     3. A Third Embodiment (a Case of Forming a Pixel Dividing Portion which is Doped Through a Lateral Growth) 
     A. A Device Configuration and the Like 
       FIG. 38  is a diagram illustrating the main portions of a solid-state imaging device according to a third embodiment. 
       FIG. 38  shows a cross-section of the pixel P in the same manner as  FIG. 32 . 
     As shown in  FIG. 38 , in this embodiment, an insulating film  80  is provided. Except for this, this embodiment is the same as the second embodiment. Therefore, the description of the overlapping parts will be omitted. 
     As shown in  FIG. 38 , the insulating film  80  is provided on one surface of the silicon substrate  11 . 
     Here, in the silicon substrate  11 , the insulating film  80  is provided at the part forming the pixel dividing portion PB on the surface (rear surface) side opposite to the surface (front surface) on which the respective portions such as the gate MOS  41  and the like are provided. For example, a silicon oxide film is provided as the insulating film  80 . In addition, the insulating film  80  may be made of a material such as silicon nitride. 
     Details will be described later, and the insulating film  80  is provided on surfaces of parts other than the parts forming the photoelectric conversion film  13  such that the photoelectric conversion film  13  is selectively crystal-grown on the surface (rear surface) of the silicon substrate  11 . 
     The pixel dividing portion PB is provided on the silicon substrate  11  with the insulating film  80  interposed therebetween. 
     B. Manufacturing Method 
     The essence of the manufacturing method of the solid-state imaging device will be described. 
       FIGS. 39 to 41  are diagrams illustrating a manufacturing method of the solid-state imaging device according to the third embodiment. 
     Here,  FIGS. 39 to 41  show the cross-sections in the same manner as  FIG. 38 , and the solid-state imaging device shown in  FIG. 38  is manufactured through the respective steps shown in  FIGS. 39 to 41 . 
     B-1. Formation of the Insulating Film  80   
     First, the insulating film  80  is formed as shown in  FIG. 39 . 
     Here, the respective portions such as the gate MOS  41  are formed on the surface of the silicon substrate  11  before the insulating film  80  is formed in the same manner as the first embodiment. Further, the wire layer (not shown) is formed on the surface (front surface) of the silicon substrate  11  so as to cover the respective portions such as the gate MOS  41 . 
     Next, as shown in  FIG. 39 , the insulating film  80  is formed in the parts in which the pixel dividing portion PB is formed on the opposite surface (rear surface) to the surface on which the respective portions such as the gate MOS  41  are formed in the silicon substrate  11 . In other words, the insulating film  80  is formed to partition the plural pixels P. 
     Specifically, for example, a silicon oxide film (not shown) is formed to cover the rear surface (upper surface) of the silicon substrate  11 . Thereafter, the silicon oxide film is patterned to form the insulating film  80  by the photolithography method. 
     For example, the insulating film  80  is formed to have the film thickness of 50 to 100 nm. 
     B-2. Formation of the Photoelectric Conversion Film  13   
     Next, as shown in  FIG. 40 , the photoelectric conversion film  13  is formed. 
     Here, as shown in  FIG. 40 , the photoelectric conversion film  13  is sequentially formed on the opposite surface (rear surface) to the surface on which the respective portions such as the gate MOS  41  are formed in the silicon substrate  11 . In the same manner as the second embodiment, the photoelectric conversion film  13  is made of the compound semiconductor with the chalcopyrite structure. 
     The photoelectric conversion film  13  is formed on the silicon substrate  11  through the epitaxial growth of the compound semiconductor by the MOCVD method, the MBE method, or the like. 
     In this embodiment, unlike the case of the first embodiment, the compound semiconductor is epitaxially grown to selectively cover the parts forming the photoelectric conversion films on the upper surface of the silicon substrate  11 , and the photoelectric conversion films  13  are formed. 
     As shown in  FIG. 39 , the insulating film  80  is formed to partition the plural pixels P on the silicon substrate  11 . For this reason, on the surface of the silicon substrate  11 , the photoelectric conversion films  13  are formed on the exposed parts other than the parts forming the insulating films  80 . Here, the photoelectric conversion film  13  is formed to be thicker than the insulating film  80 . Thereby, trenches TR are provided between the photoelectric conversion films  13  provided to correspond to the respective pixels P. 
     B-3. Formation of the Pixel Dividing Portion PB and the p+ Layer  14   p    
     Next, the pixel dividing portion PB and the p+ layer  14   p  are formed as shown in  FIG. 41 . 
     Here, as shown in  FIG. 41 , the pixel dividing portion PB and the p+ layer  14   p  are formed on the opposite surface (rear surface) to the surface on which the respective portions such as the gate MOS  41  are formed in the silicon substrate  11 . In other words, the pixel dividing portion PB and the p+ layer  14   p  are formed such that the pixel dividing portion PB covers the insulating film  80  and the p+ layer  14   p  covers the photoelectric conversion film  13 . 
     For example, each of the pixel dividing portion PB and the p+ layer  14   p  is made of a compound semiconductor with the chalcopyrite structure. 
     Specifically, the compound semiconductor is laterally grown under the condition of including a lot of an impurity such as Ga, In, As, or P. Thereby, the compound semiconductor is implanted into the trench TR between the photoelectric conversion films  13 , thus the pixel dividing portion PB is formed and the p+ layer  14   p  is formed on the photoelectric conversion film  13 . 
     For example, the pixel dividing portion PB and the p+ layer  14   p  are formed to have the impurity concentration of 10 17  to 10 19  cm −3 . 
     In this way, on the silicon substrate  11 , the pixel dividing portion PB is formed through the crystal growth of the compound semiconductor so as to cover the part forming the pixel dividing portion PB. Along therewith, the p+ layer  14   p  is formed through the crystal growth of the compound semiconductor so as to cover the upper surface of the photoelectric conversion film  13 . 
     Also, as shown in  FIG. 38 , the respective portions such as the color filters CF and the on-chip lenses ML are formed on the upper surface (rear surface) of the silicon substrate  11 . Through these steps, the rear surface illumination type CMOS image sensor is completed. 
     C. Conclusion 
     As described above, in this embodiment, in the same manner as the second embodiment, the photoelectric conversion film  13  is provided at the side where the incident light H enters when seen from the respective portions such as the n type impurity areas  12  and  411  in the silicon substrate  11 , and thus blocks the incident light H from entering the n type impurity areas  12  and  411  (refer to  FIG. 38 ). For this reason, in this embodiment and in the same manner as the second embodiment, it is possible to realize a small size, prevent the generation of noise, and improve the image quality of a captured image. 
     In addition, in this embodiment, the pixel dividing portion PB is formed to be interposed between the pixels P in the same manner as the second embodiment. The pixel dividing portion PB is provide so as to form potential barriers between the photoelectric conversion films  13  which are formed corresponding to the plural pixels P. Thereby, in this embodiment, it is possible to prevent a color mixture using the pixel dividing portion PB. 
     This embodiment is appropriate in terms of manufacturing costs since the number of process steps such as the ion implantation and the annealing is reduced as compared with the above-described embodiments. Further, since the ion implantation or the annealing is not performed, there is no damage caused by the processes (for example, damage during the ion implantation or an adverse effect on the wire layer during the annealing). 
     4. A Fourth Embodiment (in a Case of Forming a Pixel Dividing Portion Through Control of Composition) (Non-Doping) 
     A. A Device Configuration and the Like 
       FIG. 42  is a diagram illustrating main portions of a solid-state imaging device according to a fourth embodiment. 
       FIG. 42  shows a cross-section of the pixel P in the same manner as  FIG. 38 . 
     As shown in  FIG. 42 , in this embodiment, a pixel dividing portion PBc is provided unlike the third embodiment. Except for this, this embodiment is the same as the third embodiment. Therefore, the description of the overlapping parts will be omitted. 
     The pixel dividing portion PBc, as shown in  FIG. 42 , is provided to cover the insulating film  80  between the plural photoelectric conversion films  13  formed corresponding to the pixels P. 
     In this embodiment, the pixel dividing portion PBc is made of a semiconductor which does not include p type impurities unlike the second embodiment. For example, the pixel dividing portion PBc is made of a chalcopyrite based compound semiconductor having a wide band gap. For example, the pixel dividing portion PBc is formed such that the band gap is kT=27 meV or more. In this way, potential barriers are formed between the plural photoelectric conversion films  13  formed corresponding to the pixels P, and the pixels P are divided by the pixel dividing portion PBc. 
     B. Manufacturing Method 
     The essence of the manufacturing method of the solid-state imaging device will be described. 
       FIGS. 43 and 44  are diagrams illustrating a manufacturing method of the solid-state imaging device according to the fourth embodiment. 
     Here,  FIGS. 43 and 44  show the cross-sections in the same manner as  FIG. 42 , and the solid-state imaging device shown in  FIG. 42  is manufactured through the respective steps shown in  FIGS. 43 and 44 . 
     B-1. Formation of the Pixel Dividing Portion PBc 
     First, as shown in  FIG. 43 , the pixel dividing portion PBc is formed. 
     Here, the insulating film  80  and the photoelectric conversion film  13  are formed in the same manner as the second embodiment before the pixel dividing portion PBc is formed (refer to  FIGS. 39 and 40 ). 
     Next, as shown in  FIG. 43 , the pixel dividing portion PBc is formed to cover the insulating film  80  between the plural photoelectric conversion films  13  formed corresponding to the pixels P. 
     In this step, the pixel dividing portion PBc is formed, for example, using a chalcopyrite based compound semiconductor having a wide band gap. 
     Specifically, unlike the third embodiment, the compound semiconductor is laterally grown under a condition of not including p type impurities. Thereby, the compound semiconductor is implanted into the trench TR between the photoelectric conversion films  13 . 
     For example, the pixel dividing portion PBc is formed such that a composition ratio of copper-aluminum-gallium-indium-sulfur-selenium is 1.0:0.36:0.64:0:1.28:0.72, or 1.0:0.24:0.23:0.53:2.0:0. That is to say, the pixel dividing portion PBc is formed to give CuAl 0.36 Ga 0.64 S 1.28 Se 0.72  Or CuAl 0.24 Ga 0.23 In 0.53 S 2 . 
     B-2. Formation of the p+ Layer  14   p    
     As shown in  FIG. 44 , the p+ layer  14   p  is formed. Here, as shown in  FIG. 44 , the p+ layer  14   p  is formed to cover the photoelectric conversion films  13  and the pixel dividing portions PBc on the rear surface (upper surface) side of the silicon substrate  11 . 
     For example, the p+ layer  14   p  is made of a compound semiconductor with the chalcopyrite structure in the same manner as the second embodiment. 
     Specifically, the compound semiconductor is crystal-grown under the condition of including a lot of an impurity such as Ga, In, As, or P, thereby forming the p+ layer  14   p.    
     Also, as shown in  FIG. 42 , the respective portions such as the color filters CF and the on-chip lenses ML are formed on the upper surface (rear surface) of the silicon substrate  11 . Through the steps, the rear surface illumination type CMOS image sensor is completed. 
     C. Conclusion 
     As described above, in this embodiment, in the same manner as the second embodiment, the photoelectric conversion film  13  is provided at the side where the incident light H enters when seen from the respective portions such as the n type impurity areas  12  and  411  in the silicon substrate  11 , and thus blocks the incident light H from entering the n type impurity areas  12  and  411  (refer to  FIG. 42 ). For this reason, in this embodiment in the same manner as the second embodiment, it is possible to realize a small size, prevent the generation of noise, and improve the image quality of a captured image. 
     In this embodiment, the pixel dividing portion PBc is made of the compound semiconductor of which the composition is controlled, so as to form potential barriers between the photoelectric conversion films  13  which are formed corresponding to the plural pixels P. Thereby, in this embodiment, it is possible to prevent a color mixture using the pixel dividing portion PBc. 
     Since the potential barriers are formed through the control of composition and the doping is not performed in this embodiment, the crystallinity of the pixel dividing portion PBc is good as compared with the cases of other embodiments. In addition, this embodiment is appropriate in terms of manufacturing costs since the number of process steps such as the ion implantation and the annealing is reduced as compared with other embodiments. 
     5. A Fifth Embodiment (in a Case of Reading Out Signal Charges Via Metal Electrodes (a Rear Surface Illumination Type)) 
     A. A Device Configuration and the Like 
       FIG. 45  is a diagram illustrating main portions of a solid-state imaging device according to a fifth embodiment. 
       FIG. 45  shows a cross-section of the pixel P in the same manner as  FIG. 3 . 
     As shown in  FIG. 45 , this embodiment is different from the modified example 1-5 of the first embodiment in that electrodes  511  and  531 , and a contact  521  are further provided. Except for this, this embodiment is the same as the modified example 1-5 of the first embodiment. Therefore, the description of the overlapping parts will be omitted. 
     A set of the electrodes  511  and  531  and the contact  521  are formed corresponding to each pixel P as shown in  FIG. 45 . Here, in the silicon substrate  11 , the electrodes  511  and  531  and the contact  521  are formed on the upper surface of the n type impurity area  12  formed for each pixel P. An insulating layer  54  is provided around the pixels P to insulate each other of the pixels P. 
     The electrodes  511  and  531  and the contact  521  make an electric connection between the photoelectric conversion film  13  and the n type impurity area  12 , and thus the signal charges generated in the photoelectric conversion film  13  are moved to the n type impurity area  12  via the electrodes  511  and  531  and the contact  521 . 
     The electrodes  511  and  531  are formed using metal materials, and block light from above. 
     B. Conclusion 
     In this embodiment, in the same manner as the first embodiment, the photoelectric conversion film  13  is provided at the side where the incident light H enters when seen from the respective portions such as the n type impurity areas  12  and  411  in the silicon substrate  11 , and thus blocks the incident light H from entering the n type impurity areas  12  and  411  (refer to  FIG. 45 ). Also, the electrodes  511  and  531  are formed as lower electrodes in the lower side of the photoelectric conversion film  13 , and the electrodes  511  and  531  block the incident light H from entering the n type impurity areas  12  and  411  and the like (refer to  FIG. 45 ). In other words, in this embodiment, due to the combination of the photoelectric conversion film  13  and the lower electrode  531 , the incident light H is blocked. 
     For this reason, in this embodiment in the same manner as the first embodiment, it is possible to realize a small size, prevent the generation of noise, and improve the image quality of a captured image. 
     Also, although the case where the photoelectric conversion film  13  has a light blocking function has been described, this embodiment is not limited thereto. Through the combination of the photoelectric conversion film  13  and the electrodes  511  and  531 , light may be blocked from entering the n type impurity area  12 . That is to say, the entire photoelectric conversion unit including the photoelectric conversion film  13  and the electrodes  511  and  531  functioning as the lower electrodes may realize the light blocking function. 
     6. A Sixth Embodiment (in a Case of Reading Out Signal Charges Via Metal Electrodes (a Front Surface Illumination Type)) 
     A. A Device Configuration and the Like 
       FIG. 46  is a diagram illustrating main portions of a solid-state imaging device according to a sixth embodiment. 
       FIG. 46  shows a cross-section of the pixel P in the same manner as  FIG. 45 . 
     As shown in  FIG. 46 , in this embodiment, a position of the gate MOS  41  is different. Also, the n type impurity area  12  is different. Except for this and parts related thereto, this embodiment is the same as the fifth embodiment. Therefore, the description of the overlapping parts will be omitted. 
     As shown in  FIG. 46 , in this embodiment, the electrodes  511  and  531  and the contact  521  are provided on the upper surface of the silicon substrate  11  in the same manner as the fifth embodiment. Unlike the fifth embodiment, the gate MOS  41  is also provided on the upper surface of the silicon substrate  11 . Although not shown, the gate MOS  42  and the readout circuit  51  are provided separately in addition to the gate MOS  41 . Wires connected to the respective portions such as the gate MOS  41  and the like are provided on one surface of the silicon substrate  11 . 
     The n type impurity area  12  is provided inside the silicon substrate  11  in the same manner as the fifth embodiment. However, unlike the fifth embodiment, the n type impurity area  12  is provided on the upper surface side of the silicon substrate  11  and is not provided around the lower surface. 
     The wire layer (not shown) is not provided on the upper surface of the silicon substrate  11  unlike the fifth embodiment. 
     In this embodiment, the photoelectric conversion film  13  senses the incident light H coming from the upper surface (front surface) on which the respective portions such as the photoelectric conversion film  13  are provided on the silicon substrate  11 . In other words, the solid-state imaging device in this embodiment is a “front surface illumination type CMOS image sensor.” 
     B. Conclusion 
     In this embodiment, in the same manner as the fifth embodiment, the photoelectric conversion film  13  is provided at the side where the incident light H enters when seen from the respective portions such as the n type impurity areas  12  and  411  in the silicon substrate  11 , and thus blocks the incident light H from entering the n type impurity areas  12  and  411  (refer to  FIG. 46 ). Also, the electrodes  511  and  531  are formed as lower electrodes in the lower side of the photoelectric conversion film  13 , and the electrodes  511  and  531  block the incident light H from entering the n type impurity areas  12  and  411  and the like (refer to  FIG. 46 ). In other words, in this embodiment, due to the combination of the photoelectric conversion film  13  and the lower electrode  531 , the incident light H is blocked. 
     For this reason, in this embodiment in the same manner as the fifth embodiment, it is possible to realize a small size, prevent the generation of noise, and improve the image quality of a captured image. 
     Also, although the case where the photoelectric conversion film  13  has a light blocking function has been described, this embodiment is not limited thereto. Through the combination of the photoelectric conversion film  13  and the electrodes  511  and  531 , light may be blocked from entering the n type impurity area  12 . That is to say, the entire photoelectric conversion unit including the photoelectric conversion film  13  and the electrodes  511  and  531  functioning as the lower electrodes may realize the light blocking function. 
     7. A Seventh Embodiment (in a Case of Using an Off Substrate) 
     A. A Configuration and the Like 
     In the above-described embodiments, the silicon substrate of which a main surface is the (100) plane is used, the above-described compound semiconductor is epitaxially grown in the main surface, thereby forming the photoelectric conversion film. In other words, the case of using the {100} substrate has been described. However, the present invention is not limited thereto. 
     When the above-described compound semiconductor is epitaxially grown using an ionic element as a material on a nonpolar silicon substrate with no ionic property, there are cases where a defect called an antiphase domain occurs. That is to say, cation and anion locally have antiphase and are grown, thereby generating the antiphase domain. 
     For this reason, as the silicon substrate, an off substrate may be used. It is possible to suppress the generation of the antiphase domain through the epitaxial growth on the off substrate (refer to Mitsuhisa Kawabe, Hidetoshi Takasugi, Toshio Ueda, and Akira Yokoyama, and Yoshio Bando: Initial Growth Process of GaAs on Si; Division of Crystals Science and Technology, 4th Crystal Engineering Symposium Text (1987 Jul. 17) pp. 1-8) 
       FIGS. 47 to 49  are diagrams illustrating atomic arrangements when a photoelectric conversion film  13   k  is formed on a silicon substrate  11   k  which is an off substrate in the seventh embodiment.  FIGS. 47 to 49  are respectively cross-sectional views of a crystal when seen from the &lt;0−1 1&gt;direction. 
     In  FIGS. 47 to 49 , for example, a group I atom is a copper (Cu) atom, a group III atom is a gallium (Ga) atom or an indium (In) atom, and a group VI atom is a sulfur (S) atom, a selenium (Se) atom, or the like. In  FIGS. 47 to 49 , “group I strings or group III strings” marked with the white rectangle indicate that the group I atom and the group III atom are alternately arranged in the direction perpendicular to the paper. Also, in  FIG. 49 , “antiphase arrangement of group I atom or group III atom” marked with the black rectangle indicates that the group I atom and the group III atom are arranged reversely to “the group I atom strings or the group III atom strings.” Specifically, in the &lt;0−1 1&gt;direction, the group I atom (for example, Cu) and the group III atom (for example, In) are alternately arranged via the group VI atom, but this positional relationship is reverse thereto. 
     Among the figures,  FIG. 47  shows that the growth starts from the group VI atom on the silicon substrate  11   k . FIG.  48  shows that the growth starts from the group I atom or the group III atom.  FIGS. 47 and 48  show a case where the antiphase domain between the cation (positive ionic atom) the group I atom or the group III atom and the anion (negative ionic atom) of the group VI atom is annihilated. In contrast,  FIG. 49  shows that the antiphase domain between the group I atom and the group III atom is annihilated. 
     As shown in  FIGS. 47 to 49 , in this embodiment, the off substrate in which, for example, the main surface is tilted with a predetermined tilted angle (off angle) θ 1  in the &lt;011&gt;direction from the (100) plane is used as the silicon substrate ilk. In other words, the off substrate in which a {100} substrate is off in the &lt;011&gt;direction is used as the silicon substrate ilk. For example, an off substrate of which the tilted angle (off angle) θ 1  is about 6° is used. 
     On the silicon substrate ilk which is an off substrate, the cation (positive ionic atom) of the group I or the group III and the anion (negative ionic atom) of the group VI are regularly arranged to form the photoelectric conversion film  13   k.    
     In this case, the cation and the anion are grown in the antiphase locally as in the area B (area marked with the chain lines), thereby generating the antiphase domain. 
     However, as shown in  FIGS. 47 to 49 , the crystal is grown on the main surface of the off substrate, and the area B in which the antiphase domain is generated is closed in the triangular shape. 
       FIG. 50  is an enlarged perspective view of the area B in which the antiphase domain is generated when the photoelectric conversion film  13   k  is formed on the silicon substrate  11   k  in the seventh embodiment. 
     As shown in  FIG. 50 , in the area B, the antiphase domain with the triangular cross-section is formed to consecutively extend in the depth direction (&lt;0−1 1&gt;direction). In other words, the antiphase domain is formed in such a shape that a triangular prism reclines in the side. 
     Also, as shown in  FIGS. 47 to 49 , the epitaxial growth is performed to generate only the area A in which the antiphase domain is not generated, in the upper side of the area B. 
     For this reason, in this embodiment, it is possible to suppress the antiphase domain from being generated. 
     In  FIGS. 47 to 49 , although the case of the tilted angle θ 1 =6° is shown, the present invention is not limited thereto. As long as there is a slight tilt, it achieves the operation and the effect due to the closeness in the triangular shape as described above. As the tilted angle θ 1  is increased, the area B is smaller, but the tilted angle θ 1  of 2° or more is preferable. Due to this, the area B is settled in the size of about three times the size in FIGS.  47  and  48 , and thus it is possible to achieve a sufficient effect. 
     For example, the height of the triangle of the area B becomes about 5 nm. At present, the thickness necessary for the photoelectric conversion film is equal to or more than about 120 nm at the light absorption coefficient of 10 5  cm −1  (at this time, 70° or more of light is absorbed). If the tilted angle θ 1  is 2° C., the height of the triangle of the area B is settled to a degree of about 15 nm. In this case, since areas with no defect such as the antiphase domain exist at least 100 nm or more from the surface, it is possible to achieve the effect of reducing a dark current. Also, the upper limit value is an angle until a stepwise substrate structure can be maintained. Specifically, θ 1  allows 90° to the maximum. 
     B. Conclusion 
     As described above, unlike other embodiments, the photoelectric conversion film  13   k  is formed by epitaxially growing the compound semiconductor on the silicon substrate ilk which is an off substrate. Thereby, as described above, it is possible to suppress the antiphase domain from being generated. 
     8. An Eighth Embodiment (in a Case of a Lamination Type) 
     A. A Configuration and the Like 
       FIG. 51  is a diagram illustrating main portions of a solid-state imaging device according to an eighth embodiment. 
     Here,  FIG. 51  schematically shows a cross-section of the pixel P. 
     As shown in  FIG. 51 , in this embodiment, as the photoelectric conversion film  13 , a red photoelectric conversion film  13 R, a green photoelectric conversion film  13 G, and a blue photoelectric conversion film  13 B are provided. The red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B are respectively provided with upper electrodes  14 R,  14 G and  14 B and lower electrodes  53 R,  53 G and  53 B. In addition, the accumulator  12 R,  12 G and  12 B which are the n type impurity area  12  are respectively provided in the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B. Further, the color filter CF is not provided. Except for this and parts related thereto, this embodiment is the same as the sixth embodiment. Therefore, the description of the overlapping parts will be omitted. 
     As shown in  FIG. 51 , the photoelectric conversion film  13  includes the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B, which are sequentially laminated on the front surface of the silicon substrate  11 . 
     The red photoelectric conversion film  13 R of the photoelectric conversion film  13  is provided in the upper side of the surface of the silicon substrate  11  as shown in  FIG. 51 . The red photoelectric conversion film  13 R selectively disperses a red light beam of the incident light beams H coming from above and photoelectric-converts the red light beam. In other words, the red photoelectric conversion film  13 R is provided to sense with high sensitivity a light beam in a red wavelength band of light beams passing through the respective portions and generate charges through the photoelectric conversion. 
     The green photoelectric conversion film  13 G of the photoelectric conversion film  13  is provided on the upper side of the surface of the silicon substrate  11  with the red photoelectric conversion film  13 R interposed between it and the substrate as shown in  FIG. 51 . The green photoelectric conversion film  13 G selectively disperses a green light beam of the incident light beams H coming from above and photoelectric-converts the green light beam. In other words, the green photoelectric conversion film  13 G is provided to sense with high sensitivity a light beam in a green wavelength band of light beams passing through the respective portions and generate charges through the photoelectric conversion. 
     As shown in  FIG. 51 , the blue photoelectric conversion film  13 B of the photoelectric conversion film  13  is provided on the upper side of the surface of the silicon substrate  11  with the red photoelectric conversion film  13 R and the green photoelectric conversion film  13 G interposed between it and the substrate as shown in  FIG. 51 . The blue photoelectric conversion film  13 B selectively disperses a blue light beam of the incident light beams H coming from above and photoelectric-converts the blue light beam. In other words, the blue photoelectric conversion film  13 B is provided to sense with high sensitivity a light beam in a blue wavelength band of light beams passing through the respective portions and generate charges through the photoelectric conversion. 
     The red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B are respectively provided with the upper electrodes  14 R,  14 G and  14 B and the lower electrodes  53 R,  53 G and  53 B between them and the silicon substrate  11  in the depth direction z of the silicon substrate  11 . 
     Here, as shown in  FIG. 51 , the upper electrodes  14 R,  14 G and  14 B are respectively provided on the upper surfaces of the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B, and are electrically connected to the ground. 
     Also, as shown in  FIG. 51 , the lower electrodes  53 R,  53 G and  53 B are respectively on the lower surfaces of the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B, and are electrically connected to the n type impurity area  12  which is provided as accumulators  12 R,  12 G and  12 B in the silicon substrate  11 . 
     Although not shown, insulating films are interposed between the combinations of the respective red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B, and the upper electrodes  14 R,  14 G and  14 B and the lower electrodes  53 R,  53 G and  53 B. 
     In the above description, the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B are respectively formed using, for example, organic materials. 
       FIGS. 52A to 52C  are diagrams illustrating examples used as materials when the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B are formed in the eighth embodiment.  FIG. 52A  shows an example of a material used when the red photoelectric conversion film  13 R is formed.  FIG. 52B  shows an example of a material used when the green photoelectric conversion film  13 G is formed.  FIG. 52C  shows an example of a material used when the blue photoelectric conversion film  13 B is formed. 
     As shown in  FIG. 52A , the red photoelectric conversion film  13 R is formed using, for example, ZnPc. As shown in  FIG. 52B , the green photoelectric conversion film  13 G is formed using, for example, quinacridone. As shown in  FIG. 52C , the blue photoelectric conversion film  13 B is formed using, for example, BCzVBi. Each of the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B is formed to have the film thickness of 100 nm or more. 
     Each of the upper electrodes  14 R,  14 G and  14 B and the lower electrodes  53 R,  53 G and  53 B is a transparent electrode, and allows light to pass therethrough. For example, each of them is formed by forming a film of metal oxide such as indium tin oxide (ITO) using a film forming method such as a sputtering method. 
     As described above, the solid-state imaging device in this embodiment is a “photoelectric conversion film laminated type” image sensor, and disperses the incident light H into the respective colors of red, green and blue in the depth direction z for the photoelectric conversion. 
     Due to the combination of the plural laminated photoelectric conversion films  13 R,  13 G and  13 B, the incident light H is blocked from entering the silicon substrate  11 . 
       FIGS. 53A and 53B  are diagrams illustrating the characteristics of the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B in the eighth embodiment.  FIG. 53A  shows a relationship between the wavelength of the incident light and the photoelectric conversion efficiency regarding each of the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B.  FIG. 53B  shows a relationship between the wavelength of the incident light and the light transmittance regarding each of the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B. In  FIGS. 53A and 53B , the chain line denotes the case of the red photoelectric conversion film  13 R, the solid line denotes the case of the green photoelectric conversion film  13 G, and the broken line denotes the case of the blue photoelectric conversion film  13 B. 
     As shown in  FIG. 53A , if the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B are combined, the photoelectric conversion is performed with the high photoelectric conversion efficiency throughout the visible region. 
     For this reason, as shown in  FIG. 53B , if the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B are combined, the light transmittance is nearly zero throughout the visible region. 
     Therefore, the visible light does not enter the accumulators  12 R,  12 G and  12 B provided in the lower side of the photoelectric conversion film  13  but is blocked by the photoelectric conversion film  13 . In addition, light in the infrared region is cut by forming an infrared cutoff filter in the upper side of the photoelectric conversion film  13 . Further, light in the ultraviolet region is cut by forming an ultraviolet cutoff filter in the upper side of the photoelectric conversion film  13 . 
     B. Conclusion 
     As described above, the plural photoelectric conversion films  13 R,  13 G and  13 B having different absorption spectra are provided, and the plural photoelectric conversion films  13 R,  13 G and  13 B are laminated. Due to the combination of the plural laminated photoelectric conversion films  13 R,  13 G and  13 B, the incident light H is blocked from entering the silicon substrate  11 . 
     For this reason, in this embodiment, since the plural photoelectric conversion films  13 R,  13 G and  13 B block the incident light H from entering the n type impurity area  12  and the like, in the same manner as other embodiments, it is possible to realize a small size, prevent the generation of noise, and improve the image quality of a captured image. 
     9. A Ninth Embodiment (in a Case of a Lamination Type) 
     A. A Configuration and the Like 
       FIG. 54  is a diagram illustrating main portions of a solid-state imaging device according to a ninth embodiment. 
     Here,  FIG. 54  shows a cross-section of the pixel P in the same manner as  FIG. 45 . 
     As shown in  FIG. 54 , this embodiment is different from the fifth embodiment in a configuration of the photoelectric conversion film  13 . Except for this, this embodiment is the same as the fifth embodiment. The photoelectric conversion film  13  has the same configuration as that in the eighth embodiment. Therefore, the description of the overlapping parts will be omitted. 
     As shown in  FIG. 54 , the photoelectric conversion film  13  includes the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B, which are sequentially laminated on the front surface of the silicon substrate  11 . 
     As shown in  FIG. 54 , the red photoelectric conversion film  13 R is provided in the upper side of the surface of the silicon substrate  11 , and selectively disperses a red light beam of the incident light beams H coming from above and photoelectric-converts the red light beam. The green photoelectric conversion film  13 G is provided on the upper side of the surface of the silicon substrate  11  with the red photoelectric conversion film  13 R interposed between it and the substrate, and selectively disperses a green light beam of the incident light beams H coming from above and photoelectric-converts the green light beam. The blue photoelectric conversion film  13 B is provided on the upper side of the surface of the silicon substrate  11  with the red photoelectric conversion film  13 R and the green photoelectric conversion film  13 G interposed between it and the substrate, and selectively disperses a blue light beam of the incident light beams H coming from above and photoelectric-converts the blue light beam. 
     In this embodiment, the color filters CF are provided over the photoelectric conversion film  13 . For this reason, the light passing through the color filters CF is sensed by the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B. For example, in the color filters CF, a red light beam passing through a red filter layer (not shown) is sensed by the red photoelectric conversion film  13 R and undergoes the photoelectric conversion. Also, in the color filters CF, a green light beam passing through a green filter layer (not shown) is sensed by the green photoelectric conversion film  13 G and undergoes the photoelectric conversion. Further, in the color filters CF, a blue light beam passing through a blue filter layer (not shown) is sensed by the blue photoelectric conversion film  13 B and undergoes the photoelectric conversion. 
     In the above description, the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B are respectively are formed using, for example, organic materials in the same manner the eighth embodiment. In addition, materials such as a chalcopyrite based material may be used. 
     As described above, the solid-state imaging device in this embodiment is a “photoelectric conversion film laminated type” image sensor, and disperses the incident light H into the respective colors of red, green and blue in the depth direction z for the photoelectric conversion. 
     Due to the combination of the plural laminated photoelectric conversion films  13 R,  13 G and  13 B, the incident light H is blocked from entering the silicon substrate  11 . 
       FIG. 55  is a diagram illustrating the characteristics of the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B in the ninth embodiment.  FIG. 55  shows a relationship between the wavelength of the incident light and the light absorption coefficient regarding each of the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B. In  FIG. 55 , the chain line denotes the case of the red photoelectric conversion film  13 R, the solid line denotes the case of the green photoelectric conversion film  13 G, and the broken line denotes the case of the blue photoelectric conversion film  13 B. 
     As shown in  FIG. 55 , if the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B are combined, the light is absorbed throughout the visible region. Therefore, the visible light does not enter the n type impurity area  12  provided in the lower side of the photoelectric conversion film  13  but is blocked by the photoelectric conversion film  13 . 
     Particularly, in this embodiment, since the light passing through the color filters CF is absorbed by the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B, the light is efficiently blocked. 
     B. Conclusion 
     As described above, in this embodiment, the plural photoelectric conversion films  13 R,  13 G and  13 B having different absorption spectra are provided, and the plural photoelectric conversion films  13 R,  13 G and  13 B are laminated. Due to the combination of the plural laminated photoelectric conversion films  13 R,  13 G and  13 B, the incident light H is blocked from entering the silicon substrate  11 . 
     For this reason, in this embodiment, since the plural photoelectric conversion films  13 R,  13 G and  13 B block the incident light H from entering the n type impurity area  12  and the like, in the same manner as other embodiments, it is possible to realize a small size, prevent the generation of noise, and improve the image quality of a captured image. 
     10. A Tenth Embodiment (in a Case of a Lamination Type) 
     A. A Configuration and the Like 
       FIG. 56  is a diagram illustrating main portions of a solid-state imaging device according to a tenth embodiment. 
     Here,  FIG. 56  shows a cross-section of the pixel P in the same manner as  FIG. 46 . 
     As shown in  FIG. 56 , this embodiment is different from the sixth embodiment in a configuration of the photoelectric conversion film  13 . Except for this, this embodiment is the same as the sixth embodiment. The photoelectric conversion film  13  has the same configuration as that in the ninth embodiment. Therefore, the description of the overlapping parts will be omitted. 
     As shown in  FIG. 56 , in this embodiment, in the same manner as the sixth embodiment, the photoelectric conversion film  13  senses the incident light H coming from the upper surface (front surface) on which the respective portions such as the gate MOS  41  are provided on the silicon substrate  11 . In other words, the solid-state imaging device in this embodiment is a “front surface illumination type CMOS image sensor.” 
     As shown in  FIG. 56 , in the same manner as the ninth embodiment, the photoelectric conversion film  13  includes the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B, which are sequentially laminated on the front surface of the silicon substrate  11  (refer to  FIG. 54 ). 
     In other words, the solid-state imaging device in this embodiment is a “photoelectric conversion film laminated type” image sensor, and disperses the incident light H into the respective colors of red, green and blue in the depth direction z for the photoelectric conversion. 
     Further, in the same manner as the ninth embodiment, due to the combination of the plural laminated photoelectric conversion films  13 R,  13 G and  13 B, the incident light H is blocked from entering the silicon substrate  11 . 
     For this reason, if the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B are combined, the light is absorbed throughout the visible region. Therefore, the visible light does not enter the n type impurity area  12  provided in the lower side of the photoelectric conversion film  13  but is blocked by the photoelectric conversion film  13 . 
     B. Conclusion 
     As described above, in this embodiment, in the same manner as the ninth embodiment, the plural photoelectric conversion films  13 R,  13 G and  13 B having different absorption spectra are provided, and the plural photoelectric conversion films  13 R,  13 G and  13 B are laminated. Due to the combination of the plural laminated photoelectric conversion films  13 R,  13 G and  13 B, the incident light H is blocked from entering the silicon substrate  11 . 
     For this reason, in this embodiment, since the plural photoelectric conversion films  13 R,  13 G and  13 B block the incident light H from entering the n type impurity area  12  and the like, in the same manner as other embodiments, it is possible to realize a small size, prevent the generation of noise, and improve the image quality of a captured image. 
     11. An Eleventh Embodiment 
     A. A Configuration and the Like 
       FIG. 57  is a diagram illustrating main portions of a solid-state imaging device according to an eleventh embodiment. 
     Here,  FIG. 57  shows a cross-section of the pixel P in the same manner as  FIG. 45 . 
     As shown in  FIG. 57 , this embodiment is different from the fifth embodiment in a configuration of the photoelectric conversion film  13 . Except for this, this embodiment is the same as the fifth embodiment. Therefore, the description of the overlapping parts will be omitted. 
     As shown in  FIG. 57 , the photoelectric conversion film  13  includes the red photoelectric conversion film  13 R and the green photoelectric conversion film  13 G, which are provided to be arranged along the front surface of the silicon substrate  11 . Although not shown in  FIG. 57 , the photoelectric conversion film  13  further includes the blue photoelectric conversion film  13 B in addition to the red photoelectric conversion film  13 R and the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B is arranged along with the red photoelectric conversion film  13 R and the green photoelectric conversion film  13 G. 
     In this embodiment, the photoelectric conversion film  13  blocks the incident light H due to the combination of the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B, the red filter layer CFR, the green filter layer CFG, and the blue filter layer CFB. 
     Specifically, as shown in  FIG. 57 , the red color filter layer CFR as the color filter CF is provided over the red photoelectric conversion film  13 R, and a red light beam passing through the red color filter layer CFR enters the red photoelectric conversion film  13 R. 
     Further, as shown in  FIG. 57 , the green color filter layer CFG as the color filter CF is provided over the green photoelectric conversion film  13 G, and a green light beam passing through the green color filter layer CFG enters the green photoelectric conversion film  13 G. 
     Also, although not shown in  FIG. 57 , the blue color filter layer CFB as the color filter CF is provided over the blue photoelectric conversion film  13 B, and a blue light beam passing through the blue color filter layer CFB enters the blue photoelectric conversion film  13 B. 
     In this way, the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B are arranged in the Bayer arrangement in the same manner as the red filter layer CFR, the green filter layer CFG, and the blue filter layer CFB constituting the color filter CF. 
       FIG. 58  is a diagram illustrating the characteristics of the green photoelectric conversion film  13 G and the green filter layer CFG in the eleventh embodiment.  FIG. 58  shows a relationship between the wavelength of the incident light and the light absorption coefficient regarding each of the green photoelectric conversion film  13 G and the green filter layer CFG. In  FIG. 58 , the solid line denotes the case of the green photoelectric conversion film  13 G, and the broken line denotes the case of the green filter layer CFG. 
     As shown in  FIG. 58 , the green photoelectric conversion film  13 G has the high light absorption coefficient with respect to light in the wavelength region corresponding to the green. In contrast, the green filter layer CFG has the high light absorption coefficient with respect to light in the visible region other than the wavelength region corresponding to the green. 
     For this reason, as shown in  FIG. 58 , if the green photoelectric conversion film  13 G and the green filter layer CFG are combined, the light is absorbed throughout the visible region. Therefore, the visible light does not enter the n type impurity area  12  provided in the lower side of the green photoelectric conversion film  13 G but is blocked by the photoelectric conversion film  13 . 
     In the same manner as the combination of the green photoelectric conversion film  13 G and the green filter layer CFG, if the red photoelectric conversion film  13 R and the red filter layer CFR are combined as well, the light is absorbed throughout the visible region. Therefore, the visible light does not enter the n type impurity area  12  provided in the lower side of the red photoelectric conversion film  13 R but is blocked by the photoelectric conversion film  13 . 
     Likewise, if the blue photoelectric conversion film  13 B and the blue filter layer CFB are combined as well, the light is absorbed throughout the visible region. Therefore, the visible light does not enter the n type impurity area  12  provided in the lower side of the blue photoelectric conversion film  13 B but is blocked by the photoelectric conversion film  13 . 
     B. Conclusion 
     As described above, in this embodiment, the photoelectric conversion film  13  blocks the incident light H due to the combination of the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B, the red filter layer CFR, the green filter layer CFG, and the blue filter layer CFG. 
     For this reason, in this embodiment, since the plural photoelectric conversion film  13  blocks the incident light H from entering the n type impurity area  12  and the like, in the same manner as other embodiments, it is possible to realize a small size, prevent the generation of noise, and improve the image quality of a captured image. 
     12. A Twelfth Embodiment 
     A. A Configuration and the Like 
       FIG. 59  is a diagram illustrating main portions of a solid-state imaging device according to a twelfth embodiment. 
     Here,  FIG. 59  shows a cross-section of the pixel P in the same manner as  FIG. 46 . 
     As shown in  FIG. 59 , this embodiment is different from the sixth embodiment in a configuration of the photoelectric conversion film  13 . Except for this, this embodiment is the same as the sixth embodiment. The photoelectric conversion film  13  has the same configuration as that in the eleventh embodiment. Therefore, the description of the overlapping parts will be omitted. 
     As shown in  FIG. 59 , in this embodiment, in the same manner as the sixth embodiment, the photoelectric conversion film  13  senses the incident light H coming from the upper surface (front surface) on which the respective portions such as the gate MOS  41  are provided on the silicon substrate  11 . In other words, the solid-state imaging device in this embodiment is a “front surface illumination type CMOS image sensor.” 
     As shown in  FIG. 59 , in the same manner as the case of the eleventh embodiment, the photoelectric conversion film  13  includes the red photoelectric conversion film  13 R and the green photoelectric conversion film  13 G, and the like, which are provided to be arranged along the front surface of the silicon substrate  11 . Although not shown in  FIG. 59 , the photoelectric conversion film  13  further includes the blue photoelectric conversion film  13 B in addition to the red photoelectric conversion film  13 R and the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B is arranged along with the red photoelectric conversion film  13 R and the green photoelectric conversion film  13 G. 
     In the same manner as the eleventh embodiment, the photoelectric conversion film  13  blocks the incident light H due to the combination of the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B, the red filter layer CFR, the green filter layer CFG, and the blue filter layer CFB. 
     In this way, the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B are arranged in the Bayer arrangement in the same manner as the red filter layer CFR, the green filter layer CFG, and the blue filter layer CFB constituting the color filter CF. 
     B. Conclusion 
     As described above, in this embodiment, the photoelectric conversion film  13  blocks the incident light H due to the combination of the red photoelectric conversion film  13 R, the green photoelectric conversion film  13 G, and the blue photoelectric conversion film  13 B, the red filter layer CFR, the green filter layer CFG, and the blue filter layer CFB. 
     For this reason, in this embodiment, since the photoelectric conversion film  13  blocks the incident light H from entering the n type impurity area  12  and the like, in the same manner as other embodiments, it is possible to realize a small size, prevent the generation of noise, and improve the image quality of a captured image. 
     13. Others 
     In practice, the present invention is not limited to the above-described embodiments, but may have a variety of modifications. 
     In the embodiments, although the case where the present invention is applied a camera has been described, it is not limited thereto. The present invention may be applied to other electronic devices including a solid-state imaging device such as a scanner or a copier. 
     Further, in the embodiments, although the case where the solid-state imaging device is the CMOS image sensor has been described, the present invention is not limited thereto. If necessary, the present invention may be applied to a CCD type image sensor in addition to the CMOS image sensor. 
     In the embodiments, although the case where the readout circuit is singly provided for each photoelectric conversion unit has been described, the present invention is not limited thereto. For example, a readout circuit may be singly provided in a plurality of photoelectric conversion units. That is to say, plural pixels may share transistors so as to reduce the number of the transistors. Thereby, finer pixels can be realized. 
     Also, in the embodiments, although the case where a second conductivity type (for example, an n type) impurity area is formed in a first conductivity type (for example, a p type) silicon substrate has been described (refer to  FIG. 3  and the like), the present invention is not limited thereto. A first conductivity type (for example, a p type) well may be formed in a second conductivity type (for example, an n type) silicon substrate, and the second conductivity type (for example, the n type) impurity region may be formed in the well. 
     In the embodiments, although the case where “electrons” are read out as a signal has been described, the present invention is not limited thereto. There may be a configuration where “holes” are read out as a signal. In this case, the conductivity type for each portion shown in each embodiment is made reverse, and thus the “holes” can be read out as a signal. 
     Further, the structures or the operations disclosed in Japanese Unexamined Patent Application Publications No. 2009-268083 and the like may be appropriately employed. For example, as shown in FIG. 45 in Japanese Unexamined Patent Application Publications No. 2009-268083, the present invention may be applied in a case of not forming the PD reset transistor M 11  (refer to  FIG. 12  and the like in this application). Specifically, first, a charge draining operation is performed in all pixels P at the same time, and an exposure starts at the same time. Thereby, generated photoinduced charges are accumulated in the n type impurity area  12  (refer to  FIG. 12  and the like in this specification). Further, the gate MOS  41  is turned on in all the pixels P at the same time, and thus the accumulated photoinduced charges are transferred to the n type impurity region  411 . Then, the reset transistor is turned on and charges in the n type impurity region  421  functioning as an FD (floating diffusion) are drained. Further, a signal with a reset level is read out from the n type impurity region  421  via an amplification transistor (period P). Next, the gate MOS  42  is turned on so as to transfer the charges to the n type impurity region  421  functioning as the FD. Also, a signal level Vpd corresponding to charges Qpd in the FD is read out through the amplification transistor (period D). Through the correlated double sampling (CDS) process, noise included in the signal level Vpd are removed by a difference between the reset level Vrst and the signal level Vpd. At this time, since the reset noise included in the signal level correspond with the reset noise read out through the readout of the reset level, it is possible to reduce noise including the kTC noise. 
     In addition to the typical CDS driving, an operation by a DDS driving may be performed. Particularly, if the photoelectric conversion unit does not have a HAD structure like a case of using an organic photoelectric conversion film, the FD is reset after the signal charges are accumulated, which is preferable since the generation of noise can be suppressed. In other words, through the readout of the reset level after the readout of the signal level, it is possible to reduce image quality deterioration due to an after-image phenomenon when the reset operation is performed, since random noise or unevenness in a surface at the time of the reset decreases. 
     In addition, the above-described respective embodiments may be appropriately combined. 
     It should be understood by those skilled in the art that various modifications, combinations, sub-combinations and alterations may occur depending on design requirements and other factors insofar as they are within the scope of the appended claims or the equivalents thereof. 
     Although modifications and changes may be suggested by those skilled in the art, it is the intention of the inventors to embody within the patent warranted hereon all changes and modifications as reasonably and properly come within the scope of their contribution to the art.