Patent Publication Number: US-2011076310-A1

Title: Antiperspirant/Deodorant Composition

Description:
BACKGROUND OF THE INVENTION 
     It is known that fatty acids can be selected as a gellant in an antiperspirant/deodorant composition. While fatty acids can be used, they are not used in practice because they result in products that create an undesired level of softness, which results in too much payout of the product. It would be desirable to use fatty acids because of the lower cost, but there needs to be a solution to the softness caused by the fatty acids. 
     SUMMARY OF THE INVENTION 
     A composition comprising at least one active chosen from an antiperspirant active and a deodorant active; a fatty acid in an amount of greater than 7 weight %; and a plant oil in an amount of at least 12 weight %. 
     A composition comprising greater than 7 weight % of a fatty acid; and at least 12 weight % of a plant oil, wherein the composition does not contain an antiperspirant active or a deodorant active. 
    
    
     DETAILED DESCRIPTION 
     As used throughout, ranges are used as a shorthand for describing each and every value that is within the range. Any value within the range can be selected as the terminus of the range. In addition, all references cited herein are hereby incorporated by reference in their entireties. In the event of a conflict in a definition in the present disclosure and that of a cited reference, the present disclosure controls. 
     Unless otherwise specified, all percentages and amounts expressed herein and elsewhere in the specification should be understood to refer to percentages by weight. The amounts given are based on the active weight of the material. 
     The present invention includes plant (natural) oils in an antiperspirant/deodorant composition that overcomes the expectation that the composition will have an oily feel and leave a white residue. 
     Fatty Acids 
     The composition includes a fatty acid. The fatty acid is present in its acid form. While fatty acids are present in plant oils, this is an additional amount of fatty acid that is added. In one embodiment, the fatty acid is a saturated fatty acid. In one embodiment, the fatty acid can be selected from any C16 to C18 saturated fatty acid. In one embodiment, the saturated fatty acid can be stearic acid and/or palmitic acid. In one embodiment, the saturated fatty acid is C16. The amount of fatty acid in the composition is greater than 7 weight % up to 30 weight % of the composition. In other embodiments, the amount of fatty acid is at least 7.5, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, or 25 weight %. In certain embodiments, the amount of saturated fatty acid is 15 to 21 weight %. In other embodiments, the amount of saturated fatty acid is 16 to 20 weight %. 
     Plant Oils 
     The composition includes a plant oil. By plant oil it is meant that the oil is obtained from a plant, or the plant oil can be made by blending of oil components to obtain an oil that is substantially similar in composition to a plant oil. By substantially similar, it is meant that the manufactured oil contains at least 50 weight % (or at least 60, 70, 80, 90, 95, 98, or 99 weight %) of the components that are found in the plant oil that it is designed to mimic. The term plant oil does not include fragrances. 
     In certain embodiments, the plant oil has a melting point below 40° C. or below 35° C. or below 30° C. 
     Examples of the plant oil include, but are not limited to, palm kernel, coconut, avocado, canola, corn, cottonseed, olive, palm, hi-oleic sunflower, mid-oleic sunflower, sunflower, palm stearin, palm kernel olein, safflower, and babassu oils. In one embodiment, palm kernel oil is the selected oil. In another embodiment, coconut oil is the selected oil. In another embodiment, the plant oil is a combination of palm kernel oil and coconut oil. 
     In certain embodiments, the plant oil is selected to be those that contain at least 40 weight % C12-C14 fatty acids. These oils will provide stick products with greater strength at the same level of oil. In other embodiments, the oil is selected as those oils with lower amounts of unsaturation. Higher levels of unsaturation could result in undesired fragrance when the unsaturated bonds become saturated over time. In certain embodiments, the amount of unsaturated components in the oil is no more than 20, 19, 18, 17, 16, 15, 14, 13, 12, 11, or 10 weight % of the oil. 
     The tables below show representative compositions of selected oils. 
     
       
         
           
               
               
               
               
               
               
               
               
             
               
                   
               
             
            
               
                   
                   
                 Palm 
                   
                   
                   
                   
                   
               
               
                 Chain Length 
                 Name 
                 Kernel 
                 Coconut 
                 Avocado 
                 Babassu 
                 Canola 
                 Corn 
               
               
                   
               
               
                 C6:0 
                 caproic 
                 &lt;0.8 
                 &lt;0.6 
                 0 
                   
                 0 
                 0 
               
               
                 C8:0 
                 caprylic 
                 2.4-6.2 
                 4.6-10  
                 0 
                   
                 0 
                 0 
               
               
                 C10:0 
                 capric 
                 2.6-5   
                 5.5-8   
                 0 
                   
                 0 
                 0 
               
               
                 C12:0 
                 lauric 
                 45-55 
                 45.1-50.3 
                 0 
                 50 
                 0 
                 0 
               
               
                 C14:0 
                 myristic 
                 14-18 
                 16.8-21   
                 0 
                 20 
                 0 
                 0 
               
               
                 C16:0 
                 palmitic 
                 6.5-10  
                  7.5-10.2 
                  5-15 
                 11 
                 4-5 
                 11 
               
               
                 C16:1 
                 palmitoleic 
                 0 
                 0 
                 5 
                   
                 0 
                 0 
               
               
                 C18:0 
                 stearic 
                 1-3 
                 2-4 
                 3 
                 3.5 
                 1.5-2.5 
                 2 
               
               
                 C18:1 
                 oleic 
                 12-19 
                  5-10 
                 59-74 
                 10 
                 53-6  
                 28 
               
               
                 C18:2 
                 linoleic 
                   1-3.5 
                   1-2.5 
                 10-20 
                   
                 20-23 
                 58 
               
               
                 C18:3 
                 alpha 
                 0 
                 0 
                 3 
                   
                  9-12 
                 1 
               
               
                   
                 linoleic 
               
               
                 C20:0 
                 arachidic 
                 0 
                 0 
                 0 
                   
                 0 
                 0 
               
               
                 C22:0 
                 behenic 
                 0 
                 0 
                 0 
                   
                 0 
                 0 
               
               
                 C22:1 
                 erucic 
                 0 
                 0 
                 0 
                   
                 &lt;2 
                 0 
               
               
                 Monounsaturates 
                   
                 12 
                 6 
                 71 
                   
                 62 
                 28 
               
               
                 (C18:1) 
               
               
                 Polyunsaturates 
                   
                 2 
                 2 
                 14 
                   
                 32 
                 59 
               
               
                 (C18:2 and C18:3) 
               
               
                 Saturates (C10:0. 
                   
                 86 
                 92 
                 12 
                   
                 6 
                 13 
               
               
                 C12:0, C14:0, 
               
               
                 C16:0, C18:0) 
               
               
                 Iodine value (cg/g) 
                   
                 14-21 
                  6.3-10.6 
                 75-95 
                   
                 110-120 
                 120-130 
               
               
                 Melting Point (° C.) 
                   
                 25-30 
                 20-28 
                 &lt;0 
                   
                 &lt;0 
                 &lt;0 
               
               
                   
               
            
           
           
               
               
            
               
                   
                 Sunflower 
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                   
                   
                   
                   
                   
                 Hi- 
                 Mid- 
                   
               
               
                 Chain Length 
                 Name 
                 Cottonseed 
                 Olive 
                 Palm 
                 oleic 
                 oleic 
                 Regular 
               
               
                   
               
               
                 C6:0 
                 caproic 
                 0 
                 0 
                 0 
                 0 
                 No 
                 0 
               
               
                   
                   
                   
                   
                   
                   
                 data 
               
               
                 C8:0 
                 caprylic 
                 0 
                 0 
                 0 
                 0 
                 No 
                 0 
               
               
                   
                   
                   
                   
                   
                   
                 data 
               
               
                 C10:0 
                 capric 
                 0 
                 0 
                 0 
                 0 
                 No 
                 0 
               
               
                   
                   
                   
                   
                   
                   
                 data 
               
               
                 C12:0 
                 lauric 
                 0 
                 0 
                 &lt;0.5 
                 0 
                 No 
                 0 
               
               
                   
                   
                   
                   
                   
                   
                 data 
               
               
                 C14:0 
                 myristic 
                 0.6-1   
                 0 
                 0.5-2   
                 0 
                 No 
                 0 
               
               
                   
                   
                   
                   
                   
                   
                 data 
               
               
                 C16:0 
                 palmitic 
                 21.4-26.4 
                 7.5-20  
                 39.3-47.5 
                 4 
                 No 
                   5-7.6 
               
               
                   
                   
                   
                   
                   
                   
                 data 
               
               
                 C16:1 
                 palmitoleic 
                   0-1.2 
                 0 
                 0 
                 0 
                 No 
                 0 
               
               
                   
                   
                   
                   
                   
                   
                 data 
               
               
                 C18:0 
                 stearic 
                 2.1-3.3 
                 0.5-5   
                 3.5-6   
                 6 
                 No 
                 2.7-6.5 
               
               
                   
                   
                   
                   
                   
                   
                 data 
               
               
                 C18:1 
                 oleic 
                 14.7-21.7 
                 55-83 
                 36-44 
                 85 
                 55-65 
                   14-39.4 
               
               
                 C18:2 
                 linoleic 
                 46.7-58.2 
                 3.5-21  
                  9-12 
                 5 
                 No 
                 48.3-74   
               
               
                   
                   
                   
                   
                   
                   
                 data 
               
               
                 C18:3 
                 alpha 
                   0-0.4 
                 &lt;1.5 
                 0.3 
                 0 
                 1 
                   0-0.3 
               
               
                   
                 linoleic 
               
               
                 C20:0 
                 arachidic 
                 0.2-0.5 
                 0.8 
                 0 
                 0 
                 No 
                 0.1-0.5 
               
               
                   
                   
                   
                   
                   
                   
                 data 
               
               
                 C22:0 
                 behenic 
                   0-0.6 
                 0 
                 0 
                 0 
                   
                 0.3-1.5 
               
               
                 C22:1 
                 erucic 
                 0 
                 0 
                 0 
                 0 
                 No 
                 0 
               
               
                   
                   
                   
                   
                   
                   
                 data 
               
               
                 Monounsaturates 
                   
                 19 
                 77 
                 39 
                 85 
                 58 
                 20 
               
               
                 (C18:1) 
               
               
                 Polyunsaturates 
                   
                 55 
                 9 
                 10 
                 5 
                 31 
                 69 
               
               
                 (C18:2 and C18:3) 
               
               
                 Saturates (C10:0, 
                   
                 26 
                 14 
                 51 
                 10 
                 9 
                 11 
               
               
                 C12:0, C14:0, 
               
               
                 C16:0, C18:0) 
               
               
                 Iodine value (cg/g) 
                   
                 100-115 
                 75-94 
                 50-55 
                 88 
                 100-112 
                 118-141 
               
               
                 Melting Point (° C.) 
                   
                 &lt;0 
                 &lt;0 
                 37.3 
                 &lt;0 
                 &lt;0 
                 &lt;0 
               
               
                   
               
            
           
         
       
     
     The amount of plant oil in the composition is at least 12 weight % up to 20 weight % of the composition. In certain embodiments, the amount is greater than 13, 14, 15, 16, 17, 18, or 19 weight % in the composition. In certain embodiments, the amount of plant oil is greater than the amount of volatile silicone in the composition. In one embodiment, there is no volatile silicone in the composition. In other embodiments, the amount of plant oil is more than 10, 15, 20, 25, 30, 35, 40, 45, 50, 55, 60, 65, 70, 75, 80, 85, 90, or 95 weight % of the combined weight of plant oil and volatile silicone (if present). 
     Combination of Saturated Fatty Acid and Plant Oil 
     In certain embodiments, the combination of a saturated fatty acid (in particular a C16 fatty acid) in an amount of 15-21 weight % (or 16-20 weight %) with a plant oil (in particular palm kernel or coconut oil) in an amount of 12-20 weight % provides a structure with a commercially acceptable compression value, which can be at least 3500 g. 
     Additional Gellants 
     In certain embodiments, additional (second) gellants can optionally be included in the composition. Gellants are those materials known in the art that structure the composition. Examples include, but are not limited to, waxes, fatty alcohol, hydrogenated vegetable oil, a hydrocarbon wax, esters of fatty acid and fatty alcohol, triglycerides, or other cosmetically acceptable materials, which are solid or semi solid at room temperature and provide a consistency suitable for application to the skin. 
     In one embodiment, the hydrogenated oil is hydrogenated soybean oil. In one embodiment, the hydrogenated soybean oil is almost, but not fully hydrogenated. The amount of hydrogenation is measured by the iodine value. The iodine value can be measured by ASTM D5554-95 (2006). In one embodiment, the iodine value of the hydrogenated soybean oil used herein is greater than 0 to 20. In one embodiment, the iodine value is 1 to 5. In another embodiment, the soybean oil is fully hydrogenated with an iodine value of 0. In another embodiment, the iodine value is up to 20. Reference is made to United States Patent Publication No. 2008/0187504A1. 
     In one embodiment, the gellant includes a partially hydrogenated soybean oil having an iodine value in the range of about 75 to about 80. This partially hydrogenated soybean oil can be obtained from Cargill under the product designation S-500. Reference is made to United States Patent Publication No. 2008/0187503A1. This material has a typical fatty acid distribution shown in the table below. Amounts shown are in % by weight. 
     
       
         
           
               
               
               
             
               
                   
                   
               
             
            
               
                   
                 C16:0 
                 10.5-11.2 
               
               
                   
                 C18:0 
                 6.8-7.5 
               
               
                   
                 C18:1 
                 61-65 
               
               
                   
                 C18:2 
                 16-19 
               
               
                   
                 C18:3 
                   0-0.2 
               
               
                   
                 Saturates 
                 17.5-19.5 
               
               
                   
                 Trans 
                 34-39 
               
               
                   
                   
               
            
           
         
       
     
     The hydrocarbon wax can be a hydrocarbon of the formula C n H 2n+2 , wherein n is 20-100, and the hydrocarbon is at least 90% linear. In one embodiment, the hydrocarbon is a paraffin. In another embodiment, the hydrocarbon is polyethylene. An example of a polyethylene can be found in U.S. Pat. No. 6,503,491. In another embodiment, the polyethylene has a weight average molecular weight in of about 300 to about 3000 and a melting point of about 50 to about 129° C. In one embodiment, he hydrocarbon is synthetically made from methylene to form a polymethylene. 
     The fatty alcohol can be any fatty alcohol. In one embodiment, the fatty alcohol is stearyl alcohol. 
     In another embodiment, the gellant includes hydrogenated castor oil (castor wax). In certain embodiments, the melting point of the castor wax is 70 to 90, or it can be 70, 80, or 90. 
     In one embodiment, the gellant is a combination of the hydrogenated soybean oil with a fatty alcohol or the hydrocarbon. Reference is made to United States Patent Publication No. 2008/0187504A1. 
     Antiperspirant Active Materials 
     When the composition includes an antiperspirant active, any of the known antiperspirant active materials can be utilized in the composition. Antiperspirant actives include, but are not limited to, aluminum chlorhydrate, aluminum chloride, aluminum sesquichlorohydrate, aluminum-zirconium hydroxychlorides, complexes or adducts of the above-mentioned active ingredients with glycol, such as propylene glycol (for example, “Rehydrol” II from Reheis Chemical Co.), and combinations thereof. Known aluminum-zirconium salts in combination with neutral amino acids, such as glycine (e.g., aluminum-zirconium tetrachlorohydrex Gly) can also be used. Generally, any of the Category I active antiperspirant ingredients, listed in the Food and Drug Administration&#39;s Monograph on Antiperspirant Drug Products for overall-the-counter human use (Oct. 10, 1973) can be used. 
     In other embodiments, the antiperspirant active is an aluminum salt and/or an aluminum-zirconium salt, such as those described above, that are further stabilized by betaine and a calcium salt. More information about betaine and calcium salt stabilized antiperspirant salts can be found in U.S. Patent Application Publication No. 2006/0204463 to Tang et al., which is incorporated herein by reference only for the disclosure of the antiperspirant actives. 
     In other embodiments, the antiperspirant active, such as those described above, is selected to have a low metal to chloride ratio. Examples of these antiperspirant actives can be found in U.S. Pat. No. 6,375,937 to Chopra et al. and in U.S. Patent Application Publication No. 2004/0109833 to Tang et al., which are incorporated herein by reference only for their disclosure of the antiperspirant active. 
     In other embodiments, the type of salt of interest, an aluminum zirconium tetrasalt or octasalt free of glycine are used wherein aluminum zirconium salt is stabilized by Betaine and has a metal to chloride ratio of about 0.9:1 to about 1.3:1 (and in other embodiments of about 0.9:1 to about 1.2:1 or about 0.9:1 to about 1.1:1). For the tetrasalt, the Al/Zr atomic ratio can be about 3.2:1 to about 4.1:1.0 and the Betaine:zirconium mole ratio can be about 0.2:1 to about 3.0:1 (or in other embodiments of about 0.4:1 to about 1.5:1). Another salt that can be used is an aluminum chloride salt buffered by Betaine, wherein the salt has a metal to chloride ratio of 0.9:1 to 1.3:1 (and in other embodiments of about 0.9:1 to about 1.2:1 or about 0.9:1 to about 1.1:1). For the octasalt the Al/Zr atomic ratio is about 6.2:1 to about 10.0:1 and the Betaine:Zr mole ratio is about 0.2:1 to about 3.0:1 (or in other embodiments of about 0.4:1 to about 1.5:1). In one embodiment, in the case of a salt that contains zirconium, the Betaine is incorporated during the synthesis of the salt so as to maximize the stabilizing effect this ingredient has (especially on the zirconium species). Alternatively, it can be post added to a glycine-free salt along with additional active phase ingredients to form a Betaine stabilized active. 
     Examples of commercially available glycine-free low M:Cl ratio tetrasalts and octasalts include, but are not limited to, REZAL™ AZP 955 CPG and REZAL™ AZP 885 respectively (both from Reheis Chemical Company, Berkeley Heights. NJ). A more detailed description of making such commercially available salts can be found for example, in U.S. Pat. Nos. 7,074,394 and 6,960,338. Further examples of making these types of salt complexes are described in U.S. Patent Application Publication No. 2004/0198998 and U.S. Pat. No. 7,105,691. 
     In addition to the anti-irritation properties of Betaine, it has also been found that antiperspirant formulations preserve their fragrance stability upon ageing when the Al/Zr salt is used in association with Betaine. 
     Additionally, the antiperspirant active can be a calcium salt stabilized antiperspirant active. Examples of calcium salt stabilized antiperspirant actives can be found in U.S. Patent Application Publication No. 2006/0204463, which is incorporated herein by reference only for the disclosure of the calcium salt stabilized antiperspirant actives. 
     In addition, any new ingredient, not listed in the Monograph, such as aluminum nitratohydrate and its combination with zirconyl hydroxychlorides and nitrates, or aluminum-stannous chlorohydrates, can be incorporated as an antiperspirant active. Antiperspirant actives can include, but are not limited to, the following: astringent salt of aluminum, astringent salt of zirconium, aluminum bromohydrate, aluminum chlorohydrate, aluminum dichlorohydrate, aluminum sesquichlorohydrate, aluminum chlorohydrex PG, aluminum dichlorohydrex PG, aluminum sesquichlorohydrex PG, aluminum chlorohydrex PEG, aluminum dichlorohydrex PEG, aluminum sesquichlorohydrex PEG, aluminum chloride, aluminum sulfate, aluminum zirconium chlorohydrate, aluminum zirconium trichlorohydrate, aluminum zirconium tetrachlorohydrate, aluminum zirconium pentachlorohydrate, aluminum zirconium octachlorohydrate, aluminum zirconium tetrachlorhydrex propylene glycol, aluminum zirconium trichlorohydrex Gly, aluminum zirconium tetrachlorohydrex Gly, aluminum zirconium pentachlorohydrex Gly, aluminum zirconium octachlorohydrex Gly, buffered aluminum sulfate, potassium alum, sodium aluminum chlorohydroxy lactate. In one embodiment, the antiperspirant active is aluminum chlorhydrate. In another embodiment, the antiperspirant active is aluminum zirconium tetrachlorhydrex propylene glycol. 
     Deodorant Active Materials 
     Any known deodorant active can be used. Examples of deodorant active include, but are not limited to, antimicrobial actives, alcohols, 2,4,4′-trichloro-2′-hydroxy diphenyl ether (Triclosan), benzethonium chloride, polyhexamethylene biguanides, triethylcitrate, 2-amino-2-methyl-1-propanol (AMP), cetyl-trimethylammomium bromide, cetyl pyridinium chloride, farnesol (3,7,10-trimethyl-2,6,10-dodecatrien-1-ol), bactericides, and/or bacteriostats. 
     Volatile Silicone 
     Compositions according to the present invention can include a volatile silicone. In some embodiments, volatile silicone is excluded from the composition. In one embodiment, the volatile silicone is a volatile cyclic polydimethylsiloxane (cyclomethicone), e.g. cyclopentasiloxane. By volatile material it is meant that the material has a measurable vapor pressure at ambient temperature. Preferably, the volatile cyclic polydimethylsiloxane is cyclomethicone. Various types of cyclomethicones may be used. Illustratively, and not by way of limitation, the volatile silicones are one or more members selected from cyclic polydimethylsiloxanes such as those represented by Formula I: 
     
       
         
         
             
             
         
       
     
     where n is an integer with a value of 3-7, particularly 5-6. Illustrative examples of suitable cyclomethicones are DC-345 and DC-245, manufactured by Dow Corning Corporation, Midland, Mich. These types include a tetramer (octylmethylcyclotetrasiloxane) and a pentamer (decamethylcyclopentasiloxane). In one embodiment, the amount of volatile silicone in the composition is greater than 0 up to 40 weight % of the composition. In another embodiment, the amount is less than 40, 35, 30, 25, 20, 15, 10, 5, or 1 weight % of the composition. In one embodiment, there is no volatile silicone in the composition. In another embodiment, there is no silicone in the composition. In another embodiment, the combined amount of the plant oil and volatile silicone is up to 50, 45, 40, 35, 30, 25, or 20 weight %. 
     Talc 
     In certain embodiments, the composition can contain talc. In one embodiment, the amount of talc in the composition is 1 to 10 weight % of the composition. 
     Emollients 
     The composition can contain emollients in any desired amount to achieve a desired emollient effect. Emollients are known in the art and are used to impart a soothing effect on the skin. Non-volatile emollients are preferable in the present invention. Classes of non-volatile emollients include non-silicone and silicone emollients. Non-volatile, non-silicone emollients include C 12-15  alkyl benzoate. The non-volatile silicone material can be a polyethersiloxane, polyalkyarylsiloxane or polyethersiloxane copolymer. An illustrative non-volatile silicone material in the present invention is phenyl trimethicone. Non-limiting examples of emollients can be found in U.S. Pat. No. 6,007,799. Examples include, but are not limited to, PPG-14 butyl ether, PPG-3 myristyl ether, stearyl alcohol, stearic acid, glyceryl monoricinoleate, isobutyl palmitate, glyceryl monostearate, isocetyl stearate, sulphated tallow, oleyl alcohol, propylene glycol, isopropyl laurate, mink oil, sorbitan stearate, cetyl alcohol, hydrogenated castor oil, stearyl stearate, hydrogenated soy glycerides, isopropyl isostearate, hexyl laurate, dimethyl brassylate, decyl oleate, diisopropyl adipate, n-dibutyl sebacate, diisopropyl sebacate, 2-ethyl hexyl palmitate, isononyl isononanoate, isodecyl isononanoate, isotridecyl isononanoate, 2-ethyl hexyl palmitate, 2-ethyl hexyl stearate, Di-(2-ethyl hexyl)adipate), Di-(2-ethyl hexyl)succinate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, octacosanol, butyl stearate, glyceryl monostearate, polyethylene glycols, oleic acid, triethylene glycol, lanolin, castor oil, acetylated lanolin alcohols, acetylated lanolin, petrolatum, isopropyl ester of lanolin, fatty acids, mineral oils, butyl myristate, isostearic acid, palmitic acid, PEG-23 oleyl ether, olelyl oleate, isopropyl linoleate, cetyl lactate, lauryl lactate, myristyl lactate, quaternised hydroxy alkyl, aminogluconate, vegetable oils, isodecyl oleate, isostearyl neopentanoate, myristyl myristate, oleyl ethoxy myristate, diglycol stearate, ethylene glycol monostearate, myristyl stearate, isopropyl lanolate, paraffin waxes, glycyrrhizic acid, hydrocyethyl stearate amide. 
     The composition can additionally include ionizable inorganic salts. These ionizable salts are of the form M a X b  where a=1, or 2 and b=1 or 2; M is a member chosen from Na +1 , Li +1 , K +1 , Mg +2 , Ca +2 , Sr +2 , and Zn +2  and X is a member chosen chloride, bromide, iodide, citrate, gluconate, lactate, glycinate, glutamate, ascorbate, aspartate, nitrate, phosphate, hydrogenphosphate, dihydrogenphosphate, formate, maloneate, maleate, succinate, carbonate, bicarbonate, sulfate, and hydrogensulfate. In certain embodiments, the selected salts are chosen from NaCl and ZnCl 2 . As will be appreciated by those skilled in the art, while it may be possible under certain circumstances to add a salt directly to a portion of the mixture during manufacturing, it is desired to add the salt as a mixture or solution of the salt in a carrier or solvent, particularly water. Of course various concentrations of the salt premix can be made. 
     The composition may also contain particulates which include but are not limited to talc, mica, fragrance encapsulates, or hydrophobically modified starches, such as aluminum starch octenyl succinate (MACKADERM™ ASTRO-DRY™ from McIntyre Group Ltd.). If the composition is in a liquid form and dispensed through a roll-on applicator, the average particle size of the suspended material is sized so that it can pass through the application to prevent the ball applicator from malfunctioning. Usually, the average particle size does not exceed 150 microns. 
     In certain embodiments, the composition may also contain as an optional ingredient at least one malodor counteracting alpha, beta-unsaturated ester or mixtures of such materials. In certain embodiments, the level of malodor counteracting composition to deliver a perceivable odor control benefit when delivered from an antiperspirant and/or deodorant composition is about 0.05 to about 0.45 weight % based on the entire composition. The alpha, beta-unsaturated ester malodor counteracting materials are incorporated within the oil phase of an antiperspirant composition. Example of these malodor counteracting components can be found in U.S. Pat. No. 6,610,648 and U.S. Pat. No. 6,495,097, which are incorporated herein only for their disclosure of the alpha, beta unsaturated esters. For example, in this invention the odor neutralizing alpha, beta unsaturated ester mixture demonstrates unexpected stability in antiperspirant compositions containing low metal:chloride (M:Cl) ratio salts free of glycine. Examples of the alpha, beta unsaturated ester can be found in WO2005/025523, which was filed in the United States as U.S. application Ser. No. 10/571,488, both of which are incorporated herein by reference to the extent that they do not conflict with the disclosure in this specification. 
     Examples of the alpha, beta unsaturated ester include, but are not limited to:
         (1) 3-phenyl-2-propenoic acid alkyl esters wherein R 1  is a substituent on the benzene ring and is chosen from an alkyl, an alkoxy, an aryl, or a substituted aryl. In certain embodiments, R 1  is chosen from H, a C 1  to C 8  alkyl, a C 1  to C 8  alkoxy, or an aryl; and R 2  is a subsistent group replacing the carboxylic acid hydrogen to form the ester where R 2  has greater than 6 carbon atoms, an aryl, or a substituted aryl group, in certain embodiments R 2  is a C 6  to C 12  alkyl or is a benzyl group; and   (2) an ester of fumaric or maleic acid having linear ester carbon chains from 3-9 carbons, for example dihexyl fumarate;   (3) e-phenyl propenoic acid ester chosen from octyl methoxy cinnamate, phenylethyl cinnamate, benzyl cinnamate;   (4) an aliphatic unsaturated ester, such as dihexyl fumarate.       

     The composition may optionally further comprise absorbent materials such as corn starch, talc, clay, sodium polyacrylate and/or cotton fiber; and/or other materials such as fragrances, bacteriostats and/or bacteriosides, colorants, etc. Known bacteriostats include bacteriostatic quaternary ammonium compounds such as 2-amino-2-methyl-1-propanol (AMP), cetyl-trimethylammomium bromide, cetyl pyridinium chloride, 2,4,4N-trichloro-2N-hydroxydiphenylether (Triclosan), etc. and various zinc salts. 
     Antioxidants may be added to the composition, preferably to act as ingredient protectants and for maintenance of long-term stability of the composition. Suitable antioxidants include Tinogard, manufactured by Ciba Specialty Chemicals, Basel, Switzerland. 
     The compositions as provided herein are described and claimed with reference to their ingredients, as is usual in the art. As would be evident to one skilled in the art, ingredients may in some instances react with one another, so that the true composition of the final formulation may not correspond exactly to the ingredients listed. Thus, it should be understood that the invention extends to the product of the combination of the listed ingredients. 
     The compositions of the present invention may be manufactured using methods known in the art. Typically, the ingredients are combined and heated to melt the components (other than inert tiller), and the melted components (together with particulate inert filler) are mixed. Desirably, volatile materials, such as the fragrance materials, are incorporated in the composition in the latter stages of the mixing cycle, in order to avoid volatilization thereof. After mixing, the molten composition can be poured directly into the dispensers, after which the compositions harden into a solid, and the container is capped to preserve the product until use. 
     In one embodiment, the composition is a solid stick or soft solid when at ambient room temperature of about 25° C. The stick form is an example of a solid form, and the soft solid is a thickened form that may or may not be solid. The stick form can be distinguished from a soft solid in that, in a stick, the formulated product can retain its shape for extended time periods outside the package, the product not loosing its shape significantly (allowing for some shrinkage due to solvent evaporation). Adjustment of amounts of gelling or thickening agents can be used in order to form a soft solid or stick. 
     Soft solids can be suitably packaged in containers that have the appearance of a stick, but which dispense through apertures (for example, slots or pores) on the top surface of the package. The soft solid products have also been called soft sticks or “smooth-ons”, and hereinafter are generically called “soft solids”. Reference is made to U.S. Pat. No. 5,102,656, U.S. Pat. No. 5,069,897, and U.S. Pat. No. 4,937,069. 
     In one embodiment, the composition is an anhydrous stick. By anhydrous it is meant that no separate water is added but there could be moisture associated with materials that are added to the composition. In certain embodiments, the amount of water is zero or less than 3, 2, 1, 0.5, or 0.1 weight % of the composition. 
     In one embodiment, the compression force of the composition is at least 3500 g. In other embodiments, the compression force is at least 4000 g, at least 4500 g, at least about 5000 g, at least 6000 g, at least 7000 g, at least about 8000 g, at least 9000 g. In another embodiment, the compression force is 3500 g to 10,000 g. 
     In one embodiment, the composition can provide a payout of about 0.7 to about 0.9 g according to the payout test on the Payout, Glide, and Flakeoff Test Machine, which is the machine and method described in WO2009/045557. In another embodiment, the composition can provide a glide of about 0.8 to about 1.4 g according to the glide test on the Payout, Glide, and Flakeoff Test Machine. In anther embodiment, the composition can provide a flakeoff of less that about 25%. In other embodiments, the flake off is less than about 20, about 15, about 10, or about 5%. In other embodiments, the amount of flakeoff is about 1 to about 6%. 
     Compression strength of a stick product is measured using a Texture Analyzer Model # TA-ZT21 from Texture Technologies. The compression probe is a 19 mm square end probe. A 42.5 g (1.5 oz) antiperspirant stick is selected. The antiperspirant stick is removed from the barrel and placed in a hardness sample holder. The stick is positioned such that 2.54 cm (1 inch) of the sample, measured at the edge of the domed portion, is exposed for the test. The cover on the hardness holder is closed and the holder positioned so that the blade comes in contact with the midpoint of the exposed sample. The instrument is set to the following parameters: 
     Measured Force—compression (speed set at 1.0 mm/s) 
     Option—RETURN TO START 
     Distance—5.0 mm 
     Unit selection—grams.
 
The measurements to be recorded are peak force and distance required to break the stick. The higher the force reading, the stronger the stick. The longer the distance to break, the more elastic the stick.
 
     In another embodiment, the composition is a stick that does not contain an antiperspirant active or deodorant active. In this embodiment, the stick can be formulated to be a lip balm, lipstick, or a cosmetic. 
     SPECIFIC EMBODIMENTS OF THE INVENTION 
     The invention is further described in the following examples. The examples are merely illustrative and do not in any way limit the scope of the invention as described and claimed. 
     The stick compositions below are made by standard methods of melting the materials and mixing them together. The comparative examples are typical antiperspirant stick compositions. The examples use the high levels of fatty acid in combination with plant oil. 
     
       
         
           
               
               
               
               
               
               
             
               
                   
               
               
                 Material 
                 Comparative 1 
                 1 
                 2 
                 Comparative 2 
                 3 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
            
               
                 C12-15 Alkyl Benzoate 
                 12 
                 0 
                 0 
                 12 
                 0 
               
               
                 Stearyl Alcohol 
                 20 
                 0 
                 0 
                 20 
                 0 
               
               
                 Castor Wax (80° C. melt point) 
                 4 
                 4 
                 4 
                 4 
                 4 
               
               
                 PEG-8 distearate 
                 4 
                 4 
                 4 
                 4 
                 4 
               
               
                 Aluminum Zirconium 
                 22 
                 22 
                 22 
                 22 
                 22 
               
               
                 Tetrachlorohydrex Gly (Z576 
               
               
                 from Summit) 
               
               
                 Cyclomethicone 
                 37 
                 29 
                 29 
                 36.5 
                 28.5 
               
               
                 Fragrance 
                 1 
                 1 
                 1 
                 1.5 
                 1.5 
               
               
                 Palmitic Acid 
                 0 
                 20 
                 20 
                 0 
                 20 
               
               
                 Coconut Oil 
                 0 
                 20 
                 0 
                 0 
                 20 
               
               
                 Palm Kernel Oil 
                 0 
                 0 
                 20 
                 0 
                 0 
               
               
                 Compression (g) 
                 2968 
                 2638 
                 2740 
                 3682 
                 3162 
               
               
                   
               
            
           
         
       
     
     The results show that sticks of comparable hardness can be obtained using fatty acid as a gellant. Also, flake off measurements were run on Example 1 and Comparative 1. Example 1 had a flake off of 7±2 and Comparative 1 had a flake off of 15±2. The results show that high fatty acid level gellant can be used and still deliver low levels of flake off. 
     The stick compositions below are made by standard methods of melting the materials and mixing them together. The compositions below contain talc. 
     
       
         
           
               
               
               
               
             
               
                   
               
               
                 Material 
                 Comparative 3 
                 4 
                 5 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
            
               
                 Cyclomethicone 
                 35 
                 30 
                 30 
               
               
                 Aluminum Zirconium 
                 20 
                 20 
                 20 
               
               
                 Tetrachlorohydrex Gly 
               
               
                 (AZP908 from Reheis) 
               
               
                 Stearyl Alcohol 
                 16 
                 0 
                 0 
               
               
                 C12-15 Alkyl Benzoate 
                 10 
                 0 
                 0 
               
               
                 PPG-14 Butyl Ether 
                 6 
                 0 
                 0 
               
               
                 Castor Wax (80° C. melt point) 
                 5 
                 5 
                 5 
               
               
                 Hydrogenated Soybean Oil 
                 2 
                 2 
                 2 
               
               
                 iodine value up to 20 
               
               
                 PEG-8 Distearate 
                 3 
                 3 
                 3 
               
               
                 Talc 
                 2 
                 2 
                 2 
               
               
                 Coconut Oil 
                 0 
                 21 
                 0 
               
               
                 Palm Kernel Oil 
                 0 
                 0 
                 21 
               
               
                 Palmitic Acid 
                 0 
                 16 
                 16 
               
               
                 Fragrance 
                 1 
                 1 
                 1 
               
               
                 Compression (g) 
                 1125 
                 2352 
                 2703 
               
               
                   
               
            
           
         
       
     
     Below are stick examples using stearic acid and are made by standard methods of melting the materials and mixing them together. 
     
       
         
           
               
               
               
               
             
               
                   
               
               
                 Material 
                 6 
                 7 
                 8 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
            
               
                 PPG-14 Butyl Ether 
                 10 
                 10 
                 10 
               
               
                 Stearic Acid 
                 10 
                 8 
                 19 
               
               
                 Hydrogenated Soybean Oil 
                 6 
                 6 
                 0 
               
               
                 iodine value up to 20 
               
               
                 Castor Wax (80° C. melt point) 
                 4 
                 4 
                 4 
               
               
                 PEG-8 Distearate 
                 4 
                 4 
                 4 
               
               
                 Stearyl Alcohol 
                 15 
                 16 
                 9 
               
               
                 Behenyl Alcohol 
                 0.153 
                 0.153 
                 0.153 
               
               
                 Cyclomethicone 
                 29 
                 30 
                 32 
               
               
                 Aluminum Zirconium 
                 21.847 
                 21.847 
                 21.847 
               
               
                 Tetrachlorohydrex Gly 
               
               
                 (AZP908 from Reheis) 
               
               
                 Compression (g) 
                 7441 
                 4354 
                 3729