Patent Publication Number: US-2009239748-A1

Title: Fungicidal Mixtures Based on 2,5-Disubstituted N-Biphenylpyrazolcarboxamides

Description:
The present invention relates to fungicidal mixtures comprising, as active components, 
     1) at least one 2,5-disubstituted N-biphenylpyrazolecarboxamide of the formula I 
     
       
         
         
             
             
         
       
         
         
           
             in which the substituents are as defined below: 
             X is oxygen or sulfur; 
             R 1  and R 2  independently of one another are cyano, nitro, halogen, C 1 -C 6 -alkyl, C 1 -C 6 -haloalkyl, methoxy, difluoromethoxy or trifluoromethoxy; 
             R 3  is halogen, C 1 -C 4 -alkyl or C 1 -C 4 -haloalkyl; 
             R 4  is hydrogen or halogen;
 
and
 
2) at least one active compound II selected from groups A) to F):
 
             A) azoles selected from the group consisting of bitertanol, bromuconazole, cyproconazole, difenoconazole, diniconazole, enilconazole, epoxiconazole, fluquinconazole, fenbuconazole, flusilazole, flutriafol, hexaconazole, imibenconazole, ipconazole, metconazole, myclobutanil, penconazole, propiconazole, prothioconazole, simeconazole, triadimefon, triadimenol, tebuconazole, tetraconazole, triticonazole, prochloraz, pefurazoate, imazalil, triflumizole, cyazofamid, benomyl, carbendazim, thiabendazole, fuberidazole, ethaboxam, etridiazole and hymexazole; 
             B) strobilurins selected from the group consisting of azoxystrobin, dimoxystrobin, enestroburin, fluoxastrobin, kresoxim-methyl, methominostrobin, orysastrobin, picoxystrobin, pyraclostrobin, trifloxystrobin, enestroburin, methyl (2-chloro-5-[1-(3-methylbenzyloxyimino)ethyl]benzyl)carbamate, methyl (2-chloro-5-[1-(6-methylpyridin-2-ylmethoxyimino)ethyl]benzyl)carbamate and methyl 2-(ortho-(2,5-dimethylphenyloxymethylene)phenyl)-3-methoxyacrylate; 
             C) carboxamides selected from the group consisting of carboxin, benalaxyl, boscalid, fenhexamid, flutolanil, furametpyr, mepronil, metalaxyl, mefenoxam, ofurace, oxadixyl, oxycarboxin, penthiopyrad, thifluzamide, tiadinil, 3,4-dichloro-N-(2-cyanophenyl)isothiazole-5-carboxamide, dimethomorph, flumorph, flumetover, fluopicolide (picobenzamid), zoxamide, carpropamid, diclocymet, mandipropamid, N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-methanesulfonylamino-3-methylbutyramide, N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-ethane-sulfonylamino-3-methylbutyramide, methyl 3-(4-chlorophenyl)-3-(2-isopropoxy-carbonylamino-3-methylbutyrylamino)propionate, compounds of the formula III 
           
         
       
    
     
       
         
         
             
             
         
       
         
         
           
             
               
                 in which R 5  is methyl or ethyl, N-(4′-bromobiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide, N-(4′-trifluoromethylbiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide, N-(4′-chloro-3′-fluorobiphenyl-2-yl)-4-difluoromethyl-2-methyl-thiazole-5-carboxamide, N-(3′,4′-dichloro-4-fluorobiphenyl-2-yl)-3-difluoro-methyl-1-methylpyrazole-4-carboxamide and N-(2-cyanophenyl)-3,4-dichloro-isothiazole-5-carboxamide; 
               
             
             D) heterocyclic compounds selected from the group consisting of fluazinam, pyrifenox, bupirimate, cyprodinil, fenarimol, ferimzone, mepanipyrim, nuarimol, pyrimethanil, triforine, fenpiclonil, fludioxonil, aldimorph, dodemorph, fenpropimorph, tridemorph, fenpropidin, iprodione, procymidone, vinclozolin, famoxadone, fenamidone, octhilinone, probenazole, 5-chloro-7-(4-methyl-piperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine, anilazine, diclomezine, pyroquilon, proquinazid, tricyclazole, the compound of the formula IV (2-butoxy-6-iodo-3-propylchromen-4-one) 
           
         
       
    
     
       
         
         
             
             
         
       
         
         
           
             
               
                 acibenzolar-S-methyl, captafol, captan, dazomet, folpet, fenoxanil, quinoxyfen and N,N-dimethyl-3-(3-bromo-6-fluoro-2-methylindole-1-sulfonyl)-[1,2,4]triazole-1-sulfonamide of the formula V 
               
             
           
         
       
    
     
       
         
         
             
             
         
       
         
         
           
             E) carbamates selected from the group consisting of mancozeb, maneb, metam, metiram, ferbam, propineb, thiram, zineb, ziram, diethofencarb, iprovalicarb, flubenthiavalicarb, propamocarb, 4-fluorophenyl N-(1-(1-(4-cyanophenyl)-ethanesulfonyl)but-2-yl)carbamate, methyl 3-(4-chlorophenyl)-3-(2-isopropoxy-carbonylamino-3-methylbutyrylamino)propanoate of the formula VI 
           
         
       
    
     
       
         
         
             
             
         
       
         
         
           
             
               
                 and carbamate oxime ethers of the formula VII 
               
             
           
         
       
    
     
       
         
         
             
             
         
       
         
         
           
             
               
                 in which Z is N or CH; 
               
             
             F) other fungicides selected from the group consisting of
           guanidines: dodine, iminoctadine, guazatine,   antibiotics: kasugamycin, streptomycin, polyoxin, validamycin A,   nitrophenyl derivatives: binapacryl, dinocap, dinobuton,   sulfur-containing heterocyclyl compounds: dithianon, isoprothiolane,   organometallic compounds: fentin salts, such as fentin acetate,   organophosphorus compounds: edifenphos, iprobenfos, fosetyl, fosetyl-aluminum, phosphorous acid and its salts, pyrazophos, tolclofos-methyl,   organochlorine compounds: chlorothalonil, dichlofluanid, flusulfamide, hexachlorobenzene, phthalide, pencycuron, quintozene, thiophanate-methyl, tolylfluanid,   inorganic active compounds: Bordeaux mixture, copper acetate, copper hydroxide, copper oxychloride, basic copper sulfate, sulfur,   others: cyflufenamid, cymoxanil, dimethirimol, ethirimol, furalaxyl, metrafenone and spiroxamine;
 
in a synergistically effective amount.
   
         
           
         
       
    
     Moreover, the invention relates to a method for controlling harmful fungi using the mixture of at least one compound I and at least one of the active compounds II, the use of the compounds I and II for preparing such mixtures and also to compositions and seed comprising these mixtures. 
     EP-A 589 301 discloses inter alia some substituted N-biphenylpyrazolecarboxamides. 
     However, the individual compounds disclosed are unsubstituted or only monosubstituted in the biphenyl moiety. 
     Substituted biphenylamides which are only monosubstituted at the biphenyl radical are also known from WO 01/42223. 
     JP-A 09/132,567 discloses disubstituted biphenylamides which are substituted at the phenyl ring by trifluoromethyl. 
     WO 2005/34628 discloses mixtures of, inter alia, pyrazolecarboxamides and various other fungicidally active compounds. The pyrazolecarboxamides mentioned in this publication differ from the present compounds I in particular by the substitution pattern at the biphenyl radical. 
     2,4-disubstituted biphenylamides are known from WO 2005/123689 and WO 2005/123690, and 2,5-disubstituted biphenylamides are known from the earlier German application No. 102005007160.0. 
     However, the biphenylamides described and the known mixtures are, in particular at low application rates, not entirely satisfactory. 
     The active compounds II mentioned above as component 2), their preparation and their action against harmful fungi are generally known (cf., for example, http://www.hclrss.demon.co.uk/index.html); they are commercially available.
     Benalaxyl, methyl N-(phenylacetyl)-N-(2,6-xylyl)-DL-alaninate (DE 29 03 612);   metalaxyl, methyl N-(methoxyacetyl)-N-(2,6-xylyl)-DL-alaninate (GB 15 00 581);   ofurace, (RS)-α-(2-chloro-N-2,6-xylylacetamido)-γ-butyrolactone [CAS RN 58810-48-3];   oxadixyl; N-(2,6-dimethylphenyl)-2-methoxy-N-(2-oxo-3-oxazolidinyl)acetamide (GB 20 58 059);   aldimorph, “4-alkyl-2,5(or 2,6)-dimethylmorpholine”, comprising 65-75% of 2,6-dimethylmorpholine and 25-35% of 2,5-dimethylmorpholine, comprising more than 85% of 4-dodecyl-2,5(or 2,6)-dimethylmorpholine, where “alkyl” also includes octyl, decyl, tetradecyl and hexadecyl, with a cis/trans ratio of 1:1 [CAS RN 91315-15-0];   dodine, 1-dodecylguanidinium acetate (Plant Dis. Rep., Vol. 41, p. 1029 (1957));   dodemorph, 4-cyclododecyl-2,6-dimethylmorpholine (DE-A 1198125);   fenpropimorph; (RS)-cis-4-[3-(4-tert-butylphenyl)-2-methylpropyl]-2,6-dimethyl-morpholine (DE-A 27 52 096);   fenpropidin, (RS)-1-[3-(4-tert-butylphenyl)-2-methylpropyl]piperidine (DE-A 27 52 096);   guazatine, mixture of the reaction products from the amidation of technical grade iminodi(octamethylene)diamine, comprising various guanidines and polyamines [CAS RN 108173-90-6];   iminoctadine, 1,1′-iminodi(octamethylene)diguanidine (Congr. Plant Pathol., 1., p. 27 (1968));   spiroxamine, (8-tert-butyl-1,4-dioxaspiro[4.5]dec-2-yl)diethylamine (EP-A 281 842);   tridemorph, 2,6-dimethyl-4-tridecylmorpholine (DE-A 11 64 152);   pyrimethanil, 4,6-dimethylpyrimidin-2-ylphenylamine (DD-A 151 404);   mepanipyrim, (4-methyl-6-prop-1-ynylpyrimidin-2-yl)phenylamine (EP-A 224 339);   cyprodinil, (4-cyclopropyl-6-methylpyrimidin-2-yl)phenylamine (EP-A 310 550);   cycloheximide, 4-{(2R)-2-[(1S,3S,5S)-3,5-dimethyl-2-oxocyclohexyl]-2-hydroxyethyl}-piperidine-2,6-dione [CAS RN 66-81-9];   griseofulvin, 7-chloro-2′,4,6-trimethoxy-6′-methylspiro[benzofuran-2(3H), 1′-cyclohex-2′-ene]-3,4′-dione [CAS RN 126-07-8];   kasugamycin, 3-O-[2-amino-4-[(carboxyiminomethyl)amino]-2,3,4,6-tetradeoxy-α-D-arabino-hexopyranosyl]-D-chiro-inositol [CAS RN 6980-18-3];   natamycin, (8E,14E,16E,18E,20E)-(1R,3S,5R,7R,12R,22R,24S,25R,26S)-22-(3-amino-3,6-dideoxy-β-D-mannopyranosyloxy)-1,3,26-trihydroxy-12-methyl-10-oxo-6,11,28-trioxatricyclo[22.3.1.0 5,7 ]octacosa-8,14,16,18,20-pentaene-25-carboxylic acid [CAS RN 7681-93-8];   polyoxin, 5-(2-amino-5-O-carbamoyl-2-deoxy-L-xylonamido)-1-(5-carboxy-1,2,3,4-tetrahydro-2,4-dioxopyrimidin-1-yl)-1,5-dideoxy-β-D-allofuranuronic acid [CAS RN 22976-86-9];   streptomycin, 1,1′-{1-L-(1,3,5/2,4,6)-4-[5-deoxy-2-O-(2-deoxy-2-methylamino-α-L-glucopyranosyl)-3-C-formyl-α-L-lyxofuranosyloxy]-2,5,6-trihydroxycyclohex-1,3-ylene}diguanidine (J. Am. Chem. Soc. Vol. 69, p. 1234 (1947));   bitertanol, β-([1,1′-biphenyl]-4-yloxy)-α-(1,1-dimethylethyl)-1H-1,2,4-triazole-1-ethanol (DE 23 24 020),   bromuconazole, 1-[[4-bromo-2-(2,4-dichlorophenyl)tetrahydro-2-furanyl]methyl]-1H-1,2,4-triazole (Proc. 1990 Br. Crop. Prot. Conf.—Pests Dis. Vol. 1, p. 459);   cyproconazole, 2-(4-chlorophenyl)-3-cyclopropyl-1-[1,2,4]triazol-1-ylbutan-2-ol (U.S. Pat. No. 4,664,696);   difenoconazole, 1-{2-[2-chloro-4-(4-chlorophenoxy)phenyl]-4-methyl-[1,3]dioxolan-2-ylmethyl}-1H-[1,2,4]triazole (GB-A 2 098 607);   diniconazole, (βE)-β-[(2,4-dichlorophenyl)methylene]-α-(1,1-dimethylethyl)-1H-1,2,4-triazole-1-ethanol (Noyaku Kagaku, 1983, Vol. 8, p. 575);   enilconazole (imazalil), 1-[2-(2,4-dichlorophenyl)-2-(2-propenyloxy)ethyl]-1H-imidazole (Fruits, 1973, Vol. 28, p. 545);   epoxiconazole, (2RS,3SR)-1-[3-(2-chlorophenyl)-2,3-epoxy-2-(4-fluorophenyl)propyl]-1H-1,2,4-triazole (EP-A 196 038);   fenbuconazole, α-[2-(4-chlorophenyl)ethyl]-α-phenyl-1H-1,2,4-triazole-1-propanenitrile (Proc. 1988 Br. Crop Prot. Conf.—Pests Dis. Vol. 1, p. 33);   fluquinconazole, 3-(2,4-dichlorophenyl)-6-fluoro-2-[1,2,4]-triazol-1-yl-3H-quinazolin-4-one (Proc. Br. Crop Prot. Conf.—Pests Dis., 5-3, 411 (1992));   flusilazole, 1-{[bis(4-fluorophenyl)methylsilanyl]methyl}-1H-[1,2,4]triazole (Proc. Br. Crop Prot. Conf.—Pests Dis., vol. 1, p. 413 (1984));   flutriafol, α-(2-fluorophenyl)-α-(4-fluorophenyl)-1H-1,2,4-triazole-1-ethanol (EP-A 15 756);   hexaconazole, 2-(2,4-dichlorophenyl)-1-[1,2,4]triazol-1-ylhexan-2-ol (CAS RN 79983-71-4);   ipconazole, 2-[(4-chlorophenyl)methyl]-5-(1-methylethyl)-1-(1H-1,2,4-triazol-1-yl-methyl)cyclopentanol (EP-A 267 778),   metconazole, 5-(4-chlorobenzyl)-2,2-dimethyl-1-[1,2,4]triazol-1-ylmethylcyclopentanol (GB 857 383);   myclobutanil, 2-(4-chlorophenyl)-2-[1,2,4]triazol-1-ylmethylpentanenitrile (CAS RN 88671-89-0);   penconazole, 1-[2-(2,4-dichlorophenyl)pentyl]-1H-[1,2,4]triazole (Pesticide Manual, 12th Ed. 2000, p. 712);   propiconazole, 1-[[2-(2,4-dichlorophenyl)-4-propyl-1,3-dioxolan-2-yl]methyl]-1H-1,2,4-triazole (BE 835 579);   prochloraz, N-(propyl-[2-(2,4,6-trichlorophenoxy)ethyl])imidazole-1-carboxamide (U.S. Pat. No. 3,991,071);   prothioconazole, 2-[2-(1-chlorocyclopropyl)-3-(2-chlorophenyl)-2-hydroxypropyl]-2,4-dihydro[1,2,4]triazole-3-thione (WO 96/16048);   simeconazole, α-(4-fluorophenyl)-α-[(trimethylsilyl)methyl]-1H-1,2,4-triazole-1-ethanol [CAS RN 149508-90-7],   tebuconazole, 1-(4-chlorophenyl)-4,4-dimethyl-3-[1,2,4]triazol-1-ylmethylpentan-3-ol (EP-A 40 345);   tetraconazole, 1-[2-(2,4-dichlorophenyl)-3-(1,1,2,2-tetrafluoroethoxy)propyl]-1H-1,2,4-triazole (EP-A 234 242);   triadimefon, 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1H-1,2,4-triazol-1-yl)-2-butanone (BE 793 867);   triadimenol, β-(4-chlorophenoxy)-α-(1,1-dimethylethyl)-1H-1,2,4-triazole-1-ethanol (DE-A 23 24 010);   triflumizole, (4-chloro-2-trifluoromethylphenyl)-(2-propoxy-1-[1,2,4]triazol-1-ylethyliden)-amine (JP-A 79/119 462);   triticonazole, (5E)-5-[(4-chlorophenyl)methylene]-2,2-dimethyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol (FR 26 41 277);   iprodione, N-isopropyl-3-(3,5-dichlorophenyl)-2,4-dioxoimidazolidine-1-carboxamide (GB 13 12 536);   myclozolin, (RS)-3-(3,5-dichlorophenyl)-5-methoxymethyl-5-methyl-1,3-oxazolidine-2,4-dione [CAS RN 54864-61-8];   procymidone, N-(3,5-dichlorophenyl)-1,2-dimethylcyclopropane-1,2-dicarboximide (U.S. Pat. No. 3,903,090);   vinclozolin, 3-(3,5-dichlorophenyl)-5-methyl-5-vinyloxazolidine-2,4-dione (DE-A 22 07 576);   ferbam, iron(3+) dimethyldithiocarbamate (U.S. Pat. No. 1,972,961);   nabam, disodium ethylenebis(dithiocarbamate) (U.S. Pat. No. 2,317,765);   maneb, manganese ethylenebis(dithiocarbamate) (U.S. Pat. No. 2,504,404);   mancozeb, manganese ethylenebis(dithiocarbamate) polymer complex zinc salt (GB 996 264);   metam, methyldithiocarbamic acid (U.S. Pat. No. 2,791,605);   metiram, zinc ammoniate ethylenebis(dithiocarbamate) (U.S. Pat. No. 3,248,400);   propineb, zinc propylenebis(dithiocarbamate) polymer (BE 611 960);   polycarbamate, bis(dimethylcarbamodithioato-κS,κS′)[μ-[[1,2-ethanediylbis[carbamo-dithioato-κS,κS′]](2−)]]di[zinc] [CAS RN 64440-88-6];   thiram, bis(dimethylthiocarbamoyl)disulfide (DE-A 642 532);   ziram, dimethyldithiocarbamate [CAS RN 137-30-4];   zineb, zinc ethylenebis(dithiocarbamate) (U.S. Pat. No. 2,457,674);   anilazine, 4,6-dichloro-N-(2-chlorophenyl)-1,3,5-triazine-2-amine (U.S. Pat. No. 2,720,480);   benomyl, N-butyl-2-acetylaminobenzimidazole-1-carboxamide (U.S. Pat. No. 3,631,176);   boscalid, 2-chloro-N-(4′-chlorobiphenyl-2-yl)nicotinamide (EP-A 545 099);   carbendazim, methyl (1H-benzimidazol-2-yl)carbamate (U.S. Pat. No. 3,657,443);   carboxin, 5,6-dihydro-2-methyl-N-phenyl-1,4-oxathiin-3-carboxamide (U.S. Pat. No. 3,249,499);   oxycarboxin, 5,6-dihydro-2-methyl-1,4-oxathiin-3-carboxanilide 4,4-dioxide (U.S. Pat. No. 3,399,214);   cyazofamid, 4-chloro-2-cyano-N,N-dimethyl-5-(4-methylphenyl)-1H-imidazole-1-sulfon-amide (CAS RN 120116-88-3];   dazomet, 3,5-dimethyl-1,3,5-thiadiazinane-2-thione (Bull. Soc. Chim. Fr. Vol. 15, p. 891 (1897));   diflufenzopyr, 2-{1-[4-(3,5-difluorophenyl)semicarbazono]ethyl}nicotinic acid [CAS RN 109293-97-2];   dithianon, 5,10-dioxo-5,10-dihydronaphtho[2,3-b][1,4]dithiin-2,3-dicarbonitrile (GB 857 383);   famoxadone, (RS)-3-anilino-5-methyl-5-(4-phenoxyphenyl)-1,3-oxazolidine-2,4-dione [CAS RN 131807-57-3];   fenamidone, (S)-1-anilino-4-methyl-2-methylthio-4-phenylimidazolin-5-one [CAS RN 161326-34-7];   fenarimol, α-(2-chlorophenyl)-α-(4-chlorophenyl)-5-pyrimidinemethanol (GB 12 18 623);   fuberidazole, 2-(2-furanyl)-1H-benzimidazole (DE-A 12 09 799);   flutolanil, α,α,α-trifluoro-3′-isopropoxy-o-toluanilide (JP 1104514);   furametpyr, 5-chloro-N-(1,3-dihydro-1,1,3-trimethyl-4-isobenzofuranyl)-1,3-dimethyl-1H-pyrazole-4-carboxamide [CAS RN 123572-88-3];   isoprothiolane, diisopropyl 1,3-dithiolan-2-ylidenemalonate (Proc. Insectic. Fungic. Conf. 8. Vol. 2, p. 715 (1975));   mepronil, 3′-isopropoxy-o-toluanilide (U.S. Pat. No. 3,937,840);   nuarimol, α-(2-chlorophenyl)-α-(4-fluorophenyl)-5-pyrimidinemethanol (GB 12 18 623);   fluopicolide (picobenzamid), 2,6-dichloro-N-(3-chloro-5-trifluoromethylpyridin-2-yl-methyl)benzamide (WO 99/42447);   probenazole, 3-allyloxy-1,2-benzothiazole 1,1-dioxide (Agric. Biol. Chem. Vol. 37, p. 737 (1973));   proquinazid, 6-iodo-2-propoxy-3-propylquinazolin-4(3H)-one (WO 97/48684);   pyrifenox, 2′,4′-dichloro-2-(3-pyridyl)acetophenone (EZ)-O-methyloxime (EP 49 854);   pyroquilon, 1,2,5,6-tetrahydropyrrolo[3,2,1-ij]quinolin-4-one (GB 139 43 373);   quinoxyfen, 5,7-dichloro-4-(4-fluorophenoxy)quinoline (U.S. Pat. No. 5,240,940);   silthiofam, N-allyl-4,5-dimethyl-2-(trimethylsilyl)thiophene-3-carboxamide [CAS RN 175217-20-6];   thiabendazole, 2-(1,3-thiazol-4-yl)benzimidazole (U.S. Pat. No. 3,017,415);   thifluzamide, 2′,6′-dibromo-2-methyl-4′-trifluoromethoxy-4-trifluoromethyl-1,3-thiazole-5-carboxanilide [CAS RN 130000-40-7];   thiophanate-methyl, 1,2-phenylenebis(iminocarbonothioyl)bis(dimethylcarbamate) (DE-A 19 30 540);   tiadinil, 3′-chloro-4,4′-dimethyl-1,2,3-thiadiazole-5-carboxanilide [CAS RN 223580-51-6];   tricyclazole, 5-methyl-1,2,4-triazolo[3,4-b][1,3]benzothiazole [CAS RN 41814-78-2];   triforine, N,N′-{piperazine-1,4-diylbis[(trichloromethyl)methylene]}diformamide (DE-A 19 01 421);   5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]-pyrimidine (WO 98/46607);   Bordeaux mixture, mixture of CuSO 4 ×3Cu(OH) 2 ×3CaSO 4  [CAS RN 8011-63-0]   copper acetate, Cu(OCOCH 3 ) 2  [CAS RN 8011-63-0];   copper oxychloride, Cu 2 Cl(OH) 3  [CAS RN 1332-40-7];   basic copper sulfate, CuSO 4  [CAS RN 1344-73-6];   binapacryl, (RS)-2-sec-butyl-4,6-dinitrophenyl 3-methylcrotonate [CAS RN 485-31-4];   dinocap, the mixture of 2,6-dinitro-4-octylphenylcrotonate and 2,4-dinitro-6-octyl-phenylcrotonate, where “octyl” is a mixture of 1-methylheptyl, 1-ethylhexyl and 1-propylpentyl (U.S. Pat. No. 2,526,660);   dinobuton, (RS)-2-sec-butyl-4,6-dinitrophenyl isopropyl carbonate [CAS RN 973-21-7];   nitrothal-isopropyl, diisopropyl 5-nitroisophthalate (Proc. Br. Insectic. Fungic. Conf. 7., Vol. 2, p. 673 (1973));   fenpiclonil, 4-(2,3-dichlorophenyl)-1H-pyrrole-3-carbonitrile (Proc. 1988 Br. Crop Prot. Conf.—Pests Dis., Vol. 1, p. 65);   fludioxonil, 4-(2,2-difluorobenzo[1,3]dioxol-4-yl)-1H-pyrrole-3-carbonitrile (The Pesticide Manual, publ. The British Crop Protection Council, 10th ed. 1995, p. 482);   acibenzolar-S-methyl, methyl 1,2,3-benzothiadiazole-7-carbothioate [CAS RN 135158-54-2];   flubenthiavalicarb (benthiavalicarb), isopropyl {(S)-1-[(1R)-1-(6-fluorobenzothiazol-2-yl)-ethylcarbamoyl]-2-methylpropyl}carbamate (JP-A 09/323,984);   carpropamid, 2,2-dichloro-N-[1-(4-chlorophenyl)ethyl]-1-ethyl-3-methylcyclopropane-carboxamide [CAS RN 104030-54-8]; chlorothalonil, 2,4,5,6-tetrachloroisophthalonitrile (U.S. Pat. No. 3,290,353);   cyflufenamid, (Z)-N-[α-(cyclopropylmethoxyimino)-2,3-difluoro-6-(trifluoromethyl)-benzyl]-2-phenylacetamide (WO 96/19442);   cymoxanil, 1-(2-cyano-2-methoxyiminoacetyl)-3-ethylurea (U.S. Pat. No. 3,957,847);   diclomezine, 6-(3,5-dichlorophenyl-p-tolyl)pyridazin-3(2H)-one (U.S. Pat. No. 4,052,395)   diclocymet, (RS)-2-cyano-N-[(R)-1-(2,4-dichlorophenyl)ethyl]-3,3-dimethylbutyramide [CAS RN 139920-32-4];   diethofencarb, isopropyl 3,4-diethoxycarbanilate (EP-A 78 663);   edifenphos, O-ethyl S,S-diphenyl phosphorodithioate (DE-A 14 93 736)   ethaboxam, N-(cyano-2-thienylmethyl)-4-ethyl-2-(ethylamino)-5-thiazolecarboxamide (EP-A 639 574);   fenhexamid, N-(2,3-dichloro-4-hydroxyphenyl)-1-methylcyclohexanecarboxamide (Proc. Br. Crop Prot. Conf.—Pests Dis., 1998, Vol. 2, p. 327);   fentin acetate, triphenyltin (U.S. Pat. No. 3,499,086);   fenoxanil, N-(1-cyano-1,2-dimethylpropyl)-2-(2,4-dichlorophenoxy)propanamide (EP-A 262 393);   ferimzone, (Z)-2′-methylacetophenone-4,6-dimethylpyrimidin-2-ylhydrazone [CAS RN 89269-64-7];   fluazinam, 3-chloro-N-[3-chloro-2,6-dinitro-4-(trifluoromethyl)phenyl]-5-(trifluoromethyl)-2-pyridinamine (The Pesticide Manual, publ. The British Crop Protection Council, 10th ed. (1995), p. 474);   fosetyl, fosetyl-aluminum, ethylphosphonate (FR 22 54 276);   iprovalicarb, isopropyl[(1S)-2-methyl-1-(1-p-tolylethylcarbamoyl)propyl]carbamate (EP-A 472 996);   hexachlorobenzene (C. R. Seances Acad. Agric. Fr., Vol. 31, p. 24 (1945));   mandipropamid, (RS)-2-(4-chlorophenyl)-N-[3-methoxy-4-(prop-2-ynyloxy)phenethyl]-2-(prop-2-ynyloxy)acetamide (WO 03/042166);   metrafenone, 3′-bromo-2,3,4,6′-tetramethoxy-2′,6-dimethylbenzophenone (U.S. Pat. No. 5,945,567);   pencycuron, 1-(4-chlorobenzyl)-1-cyclopentyl-3-phenylurea (DE-A 27 32 257);   penthiopyrad, (RS)-N-[2-(1,3-dimethylbutyl)-3-thienyl]-1-methyl-3-(trifluoromethyl)-1H-pyrazole-4-carboxamide (JP 10/130,268);   propamocarb, isopropyl 3-(dimethylamino)propylcarbamate (DE-A 15 67 169);   phthalide (DE-A 16 43 347);   toloclofos-methyl, O-2,6-dichloro-p-tolyl O,O-dimethyl phosphorothioate (GB 14 67 561);   quintozene, pentachloronitrobenzene (DE-A 682 048);   zoxamide, (RS)-3,5-dichloro-N-(3-chloro-1-ethyl-1-methyl-2-oxopropyl)-p-toluamide [CAS RN 156052-68-5];   captafol, N-(1,1,2,2-tetrachloroethylthio)cyclohex-4-ene-1,2-dicarboximide (Phytopathology, Vol. 52, p. 754 (1962));   captan, N-(trichloromethylthio)cyclohex-4-ene-1,2-dicarboximide (U.S. Pat. No. 2,553,770);   dichlofluanid, N-dichlorofluoromethylthio-N′,N′-dimethyl-N-phenylsulfamide (DE-A 11 93 498);   folpet, N-(trichloromethylthio)phthalimide (U.S. Pat. No. 2,553,770);   tolylfluanid, N-dichlorofluoromethylthio-N′,N′-dimethyl-N-p-tolylsulfamide (DE-A 11 93 498);   dimethomorph, 3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)-1-morpholin-4-yl-propenone (EP-A 120 321);   flumetover, 2-(3,4-dimethoxyphenyl)-N-ethyl-α,α,α-trifluoro-N-methyl-p-toluamide [AGROW no. 243, 22 (1995)];   flumorph, 3-(4-fluorophenyl)-3-(3,4-dimethoxyphenyl)-1-morpholin-4-ylpropenone (EP-A 860 438),   N-(4′-bromobiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide,   N-(4′-trifluoromethylbiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide,   N-(4′-chloro-3′-fluorobiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide,   N-(3′,4′-dichloro-4-fluorobiphenyl-2-yl)-3-difluoromethyl-1-methylpyrazole-4-carboxamide (WO 03/66610),   N-(2-cyanophenyl)-3,4-dichloroisothiazole-5-carboxamide (WO 99/24413);   N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-methane-sulfonylamino-3-methylbutyramide, N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-ethanesulfonylamino-3-methylbutyramide (WO 04/49804);   3-[5-(4-chlorophenyl)-2,3-dimethylisoxazolidin-3-yl]pyridine (EP-A 10 35 122);   2-butoxy-6-iodo-3-propylchromen-4-one (WO 03/14103);   N,N-dimethyl-3-(3-bromo-6-fluoro-2-methylindole-1-sulfonyl)-[1,2,4]triazole-1-sulfonamide (EP-A 10 31 571);   methyl (2-chloro-5-[1-(3-methylbenzyloxyimino)ethyl]benzyl)carbamate,   methyl (2-chloro-5-[1-(6-methylpyridin-2-ylmethoxyimino)ethyl]benzyl)carbamate (EP-A 12 01 648);   methyl 3-(4-chlorophenyl)-3-(2-isopropoxycarbonylamino-3-methylbutyrylamino)-propionate (EP-A 10 28 125);   azoxystrobin, methyl 2-{2-[6-(2-cyano-1-vinylpenta-1,3-dienyloxy)pyrimidin-4-yloxy]-phenyl}-3-methoxyacrylate (EP-A 382 375),   dimoxystrobin, (E)-2-(methoxyimino)-N-methyl-2-[α-(2,5-xylyloxy)-o-tolyl]acetamide (EP-A 477 631);   fluoxastrobin, (E)-{2-[6-(2-chlorophenoxy)-5-fluoropyrimidin-4-yloxy]phenyl}(5,6-dihydro-1,4,2-dioxazin-3-yl)methanone O-methyloxime (WO 97/27189);   kresoxim-methyl, methyl (E)-methoxyimino[α-(o-tolyloxy)-o-tolyl]acetate (EP-A 253 213);   metominostrobin, (E)-2-(methoxyimino)-N-methyl-2-(2-phenoxyphenyl)acetamide (EP-A 398 692);   orysastrobin, (2E)-2-(methoxyimino)-2-{2-[(3E,5E,6E)-5-(methoxyimino)-4,6-dimethyl-2,8-dioxa-3,7-diazanona-3,6-dien-1-yl]phenyl}-N-methylacetamide (WO 97/15552);   picoxystrobin, methyl 3-methoxy-2-[2-(6-trifluoromethylpyridin-2-yloxymethyl)phenyl]-acrylate (EP-A 278 595);   pyraclostrobin, methyl N-{2-[1-(4-chlorophenyl)-1H-pyrazol-3-yloxymethyl]phenyl}(N-methoxy)carbamate (WO 96/01256);   trifloxystrobin, methyl (E)-methoxyimino-{(E)-α-[1-(α,α,α-trifluoro-m-tolyl)ethylidene-aminooxy]-o-tolyl}acetate (EP-A 460 575);   methyl 2-[ortho-(2,5-dimethylphenyloxymethylene)phenyl]-3-methoxyacrylate (EP-A 226 917);   5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]-pyrimidine (WO 98/46608);   3,4-dichloro-N-(2-cyanophenyl)isothiazole-5-carboxamide (WO 99/24413), compounds of the formula IV (WO 04/049804);   N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-methane-sulfonylamino-3-methylbutyramide and N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-ethanesulfonylamino-3-methylbutyramide (WO 03/66609);   2-butoxy-6-iodo-3-propylchromen-4-one of the formula V (WO 03/14103);   N,N-dimethyl-3-(3-bromo-6-fluoro-2-methylindole-1-sulfonyl)-[1,2,4]triazole-1-sulfonamide of the formula VI (WO 03/053145);   methyl 3-(4-chlorophenyl)-3-(2-isopropoxycarbonylamino-3-methylbutyrylamino)-propanoate of the formula VII (EP-A 1028125).   

     It was an object of the present invention, with a view to reducing the application rates and broadening the activity spectrum of the active compounds I and II, to provide mixtures which, at a reduced total amount of active compounds applied, have improved activity against harmful fungi, in particular for certain indications. 
     We have accordingly found the mixtures, defined at the outset, of the active compounds I and II. Moreover, we have found that simultaneous, that is joint or separate, application of at least the compound I and at least one of the active compounds II or successive application of the compound(s) I and at least one of the active compounds II allows better control of harmful fungi than is possible with the individual compounds alone (synergistic mixtures). 
     The compounds I can be used as synergists for a large number of different fungicidally active compounds. By simultaneous, that is joint or separate, application of compound(s) I with at least one active compound II, the fungicidal activity is increased in a superadditive manner. 
     The compounds of the formula 1 may be present in various crystal modifications, which may differ in their biological activity. 
     In formula I, halogen is fluorine, chlorine, bromine or iodine, preferably fluorine or chlorine. 
     C 1 -C 4 -Alkyl is methyl, ethyl, n-propyl, 1-methylethyl, n-butyl, 1-methylpropyl, 2-methyl-propyl or 1,1-dimethylethyl, preferably methyl or ethyl. 
     C 1 -C 6 -Alkyl is a C 1 -C 4 -alkyl radical as mentioned above, or is n-pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 2,2-dimethylpropyl, 1-ethylpropyl, n-hexyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 1-methylpentyl, 2-methylpentyl, 3-methylpentyl, 4-methylpentyl, 1,1-dimethylbutyl, 1,2-dimethylbutyl, 1,3-dimethylbutyl, 2,2-dimethyl-butyl, 2,3-dimethylbutyl, 3,3-dimethylbutyl, 1-ethylbutyl, 2-ethylbutyl, 1,1,2-trimethyl-propyl, 1,2,2-trimethylpropyl, 1-ethyl-1-methylpropyl and 1-ethyl-2-methylpropyl; preferably a C 1 -C 4 -alkyl radical as mentioned above. 
     C 1 -C 4 -Haloalkyl is a partially or fully halogenated C 1 -C 4 -alkyl radical, where the halogen atom(s) is/are in particular fluorine, chlorine and/or bromine, i.e., for example, chloromethyl, bromomethyl, dichloromethyl, trichloromethyl, fluoromethyl, difluoro-methyl, trifluoromethyl, chlorofluoromethyl, dichlorofluoromethyl, chlorodifluoromethyl, 1-chloroethyl, 1-bromoethyl, 1-fluoroethyl, 2-fluoroethyl, 2,2-difluoroethyl, 2,2,2-tri-fluoroethyl, 2-chloro-2-fluoroethyl, 2-chloro-2,2-difluoroethyl, 2,2-dichloro-2-fluoroethyl, 2,2,2-trichloroethyl, pentafluoroethyl, heptafluoropropyl or nonafluorobutyl, in particular halomethyl, with particular preference CH 2 —Cl, CH(Cl) 2 , CH 2 —F, CH(F) 2 , CF 3 , CHFCl, CF 2 Cl or CF(Cl) 2 , especially difluoromethyl and trifluoromethyl. 
     C 1 -C 6 -Haloalkyl is a partially or fully halogenated C 1 -C 6 -alkyl radical, where the halogen atom(s) is/are in particular fluorine, chlorine and/or bromine, i.e., for example, a C 1 -C 4 -haloalkyl radical as mentioned above, or is 5-fluoropentyl, 5-chloropentyl, 5-bromopentyl, 5-iodopentyl, 5,5,5-trichloropentyl, undecafluoropentyl, 6-fluorohexyl, 6-chlorohexyl, 6-bromohexyl, 6-iodohexyl, 6,6,6-trichlorohexyl or dodecafluorohexyl; preferably a C 1 -C 4 -haloalkyl radical. 
     The 2,5-disubstituted N-biphenylpyrazolecarboxamides of the formula I where X=oxygen are known, for example, from WO 2005/123689, WO 2005/123690 and the earlier German application No. 102005007160.0, or they can be prepared by the processes described therein. 
     The compounds I in which X is sulfur can be prepared, for example, by sulfurization of the corresponding compounds I in which X is oxygen (cf., for example, D. Petrova &amp; K. Jakobcic, Croat. Chem. Acta 48, 49 (1976) and also WO 01/42223). 
     Among the 2,5-disubstituted N-biphenylpyrazolecarboxamides I, preference is firstly given to those in which X is oxygen. 
     Secondly, preference is given to those compounds I in which X is sulfur. 
     For the mixtures according to the invention, preference is given to compounds of the formula I in which R 1  and R 2  independently of one another are cyano, fluorine, chlorine, methyl, methoxy or trifluoromethyl, R 3  is fluorine, chlorine, methyl or C 1 -haloalkyl and R 4  is hydrogen or halogen. 
     Particular preference is given to compounds of the formula I in which R 1  and R 2  independently of one another are cyano, fluorine, chlorine or methoxy and R 3  is fluorine, chlorine, methyl, fluoromethyl, difluoromethyl, chlorofluoromethyl, chlorodifluoromethyl, dichlorofluoromethyl or trifluoromethyl and R 4  is hydrogen, fluorine or chlorine. 
     Very particular preference is given to compounds of the formula I in which R 1  and R 2  independently of one another are fluorine or chlorine, R 3  is methyl, fluoromethyl, difluoromethyl, chlorofluoromethyl, chlorodifluoromethyl, dichlorofluoromethyl or trifluoromethyl and R 4  is hydrogen. 
     Particular preference is given to the compounds 1a listed in the tables below 
     
       
         
           
               
             
               
                 TABLE A 
               
             
            
               
                   
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
            
           
           
               
               
               
            
               
                 Number 
                 R 2   
                 R 3   
               
               
                   
               
            
           
           
               
               
               
            
               
                 1 
                 fluorine 
                 difluoromethyl 
               
               
                 2 
                 chlorine 
                 difluoromethyl 
               
               
                 3 
                 bromine 
                 difluoromethyl 
               
               
                 4 
                 iodine 
                 difluoromethyl 
               
               
                 5 
                 methyl 
                 difluoromethyl 
               
               
                 6 
                 methoxy 
                 difluoromethyl 
               
               
                 7 
                 trifluoromethyl 
                 difluoromethyl 
               
               
                 8 
                 trifluoromethoxy 
                 difluoromethyl 
               
               
                 9 
                 cyano 
                 difluoromethyl 
               
               
                 10 
                 nitro 
                 difluoromethyl 
               
               
                 11 
                 fluorine 
                 trifluoromethyl 
               
               
                 12 
                 chlorine 
                 trifluoromethyl 
               
               
                 13 
                 bromine 
                 trifluoromethyl 
               
               
                 14 
                 iodine 
                 trifluoromethyl 
               
               
                 15 
                 methyl 
                 trifluoromethyl 
               
               
                 16 
                 methoxy 
                 trifluoromethyl 
               
               
                 17 
                 trifluoromethyl 
                 trifluoromethyl 
               
               
                 18 
                 trifluoromethoxy 
                 trifluoromethyl 
               
               
                 19 
                 cyano 
                 trifluoromethyl 
               
               
                 20 
                 nitro 
                 trifluoromethyl 
               
               
                   
               
            
           
         
       
     
     Table 1: 
     Compound 1.1-1.20 
     Compounds of the formula I in which R 1  is fluorine and R 2  and R 3  in each case have the meanings given in one row of Table A. 
     Table 2: 
     Compound 2.1-2.20 
     Compounds of the formula I in which R 1  is chlorine and R 2  and R 3  in each case have the meanings given in one row of Table A. 
     Table 3: 
     Compound 3.1-3.20 
     Compounds of the formula I in which R 1  is bromine and R 2  and R 3  in each case have the meanings given in one row of Table A. 
     Table 4: 
     Compound 4.1-4.20 
     Compounds of the formula I in which R 1  is iodine and R 2  and R 3  in each case have the meanings given in one row of Table A. 
     Table 5: 
     Compound 5.1-5.20 
     Compounds of the formula I in which R 1  is methyl and R 2  and R 3  in each case have the meanings given in one row of Table A. 
     Table 6: 
     Compound 6.1-6.20 
     Compounds of the formula I in which R 1  is methoxy and R 2  and R 3  in each case have the meanings given in one row of Table A. 
     Table 7: 
     Compound 7.1-7.20 
     Compounds of the formula I in which R 1  is trifluoromethyl and R 2  and R 3  in each case have the meanings given in one row of Table A. 
     Table 8: 
     Compound 8.1-8.20 
     Compounds of the formula I in which R 1  is trifluoromethoxy and R 2  and R 3  in each case have the meanings given in one row of Table A. 
     Table 9: 
     Compound 9.1-9.20 
     Compounds of the formula I in which R 1  is cyano and R 2  and R 3  in each case have the meanings given in one row of Table A. 
     Table 10: 
     Compound 10.1-10.20 
     Compounds of the formula I in which R 1  is nitro and R 2  and R 3  in each case have the meanings given in one row of Table A. 
     Very particularly preferred compounds of the formula I are N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide, N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide, N-(2′-fluoro-5′-chloro-biphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide, N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide, N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide, N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide, N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide and N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide. 
     Preference is given to mixtures of a compound of the formula I with at least one active compound selected from the group of the A) azoles. 
     Preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the B) strobilurins. 
     Preference is given to mixtures of a compound of the formula I with at least one active compound selected from the group of the C) carboxamides. 
     Preference is furthermore also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the D) heterocyclic compounds. 
     Preference is furthermore also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the E) carbamates. 
     Preference is furthermore also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the F) other fungicides. 
     Preference is furthermore also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the A) azoles selected from the group consisting of cyproconazole, difenoconazole, epoxiconazole, fluquinconazole, flusilazole, flutriafol, metconazole, myclobutanil, penconazole, propiconazole, prothioconazole, triadimefon, triadimenol, tebuconazole, tetraconazole, triticonazole, prochloraz, cyazofamid, benomyl, carbendazim and ethaboxam. 
     Particular preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the A) azoles selected from the group consisting of cyproconazole, difenoconazole, epoxiconazole, fluquinconazole, flusilazole, flutriafol, metconazole, myclobutanil, propiconazole, prothioconazole, triadimefon, triadimenol, tebuconazole, tetraconazole, triticonazole, prochloraz, cyazofamid, benomyl and carbendazim. 
     Very particular preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the A) azoles selected from the group consisting of epoxiconazole, fluquinconazole, flutriafol, metconazole, tebuconazole, triticonazole, prochloraz and carbendazim. 
     Preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the B) strobilurins selected from the group consisting of azoxystrobin, dimoxystrobin, fluoxastrobin, kresoxim-methyl, orysastrobin, picoxystrobin, pyraclostrobin and trifloxystrobin. 
     Particular preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the B) strobilurins selected from the group consisting of kresoxim-methyl, orysastrobin and pyraclostrobin. 
     Very particular preference is also given to mixtures of a compound of the formula I with pyraclostrobin. 
     Preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the C) carboxamides selected from the group consisting of fenhexamid, metalaxyl, mefenoxam, ofurace, dimethomorph, flumorph, fluopicolide (picobenzamid), zoxamide, carpropamid and mandipropamid. 
     Particular preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the C) carboxamides selected from the group consisting of fenhexamid, metalaxyl, mefenoxam, ofurace, dimethomorph, zoxamide and carpropamid. 
     Preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the D) heterocyclic compounds selected from the group consisting of fluazinam, cyprodinil, fenarimol, mepanipyrim, pyrimethanil, triforine, fludioxonil, dodemorph, fenpropimorph, tridemorph, fenpropidin, iprodione, vinclozolin, famoxadone, fenamidone, probenazole, 5-chloro-7-(4-methyl-piperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine, proquinazid, acibenzolar-S-methyl, captafol, folpet, fenoxanil and quinoxyfen, in particular fluazinam, cyprodinil, fenarimol, mepanipyrim, pyrimethanil, triforine, fludioxonil, dodemorph, fenpropimorph, tridemorph, fenpropidin, iprodione, vinclozolin, famoxadone, fenamidone, probenazole, proquinazid, acibenzolar-S-methyl, captafol, folpet, fenoxanil and quinoxyfen. 
     Particular preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the D) heterocyclic compounds selected from the group consisting of pyrimethanil, dodemorph, fenpropimorph, tridemorph, iprodione, vinclozolin, 5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluoro-phenyl)-[1,2,4]triazolo[1,5-a]pyrimidine and quinoxyfen. 
     Preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the E) carbamates selected from the group consisting of mancozeb, metiram, propineb, thiram, iprovalicarb, flubenthiavalicarb and propamocarb. 
     Particular preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the E) carbamates selected from the group consisting of mancozeb and metiram. 
     Preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the F) other fungicides selected from the group consisting of dithianon, fentin salts, such as fentin acetate, fosetyl, fosetyl-aluminum, phosphorous acid and its salts, chlorothalonil, dichlofluanid, thiophanate-methyl, copper acetate, copper hydroxide, copper oxychloride, basic copper sulfate, sulfur, cymoxanil, metrafenone and spiroxamine. 
     Particular preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the F) other fungicides selected from the group consisting of phosphorous acid and its salts, chlorothalonil and metrafenone. 
     Preference is also given to three-component mixtures of one compound of the formula I with two of the active compounds II mentioned above. 
     Preferred combinations of active compounds are listed in Tables 11 to 17 below: 
     
       
         
           
               
             
               
                 TABLE 11 
               
             
            
               
                   
               
               
                 Active compound combinations of compounds I with active compounds II of group A): 
               
            
           
           
               
               
               
            
               
                   
                   
                 Active 
               
               
                 Mixture 
                 Compound of the formula I 
                 compound II 
               
               
                   
               
               
                 No. A.1 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl- 
                 epoxiconazole 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.2 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl- 
                 epoxiconazole 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.3 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 epoxiconazole 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.4 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 epoxiconazole 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.5 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl- 
                 epoxiconazole 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.6 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3-difluoromethyl- 
                 epoxiconazole 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.7 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 epoxiconazole 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.8 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 epoxiconazole 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.9 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl- 
                 metconazole 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.10 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl- 
                 metconazole 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.11 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 metconazole 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.12 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 metconazole 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.13 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl- 
                 metconazole 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.14 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3-difluoromethyl- 
                 metconazole 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.15 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 metconazole 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.16 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 metconazole 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.17 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl- 
                 tebuconazole 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.18 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl- 
                 tebuconazole 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.19 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 tebuconazole 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.20 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 tebuconazole 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.21 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl- 
                 tebuconazole 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.22 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3-difluoromethyl- 
                 tebuconazole 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.23 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 tebuconazole 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.24 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 tebuconazole 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.25 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl- 
                 fluquinconazole 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.26 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl- 
                 fluquinconazole 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.27 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 fluquinconazole 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.28 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 fluquinconazole 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.29 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl- 
                 fluquinconazole 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.30 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3-difluoromethyl- 
                 fluquinconazole 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.31 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 fluquinconazole 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.32 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 fluquinconazole 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.33 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl- 
                 flutriafol 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.34 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl- 
                 flutriafol 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.35 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 flutriafol 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.36 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 flutriafol 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.37 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl- 
                 flutriafol 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.38 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3-difluoromethyl- 
                 flutriafol 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.39 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 flutriafol 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.40 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 flutriafol 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.41 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl- 
                 triticonazole 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.42 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl- 
                 triticonazole 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.43 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 triticonazole 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.44 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 triticonazole 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.45 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl- 
                 triticonazole 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.46 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3-difluoromethyl- 
                 triticonazole 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.47 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 triticonazole 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.48 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 triticonazole 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.49 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl- 
                 prochloraz 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.50 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl- 
                 prochloraz 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.51 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 prochloraz 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.52 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 prochloraz 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.53 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl- 
                 prochloraz 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.54 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3-difluoromethyl- 
                 prochloraz 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.55 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 prochloraz 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.56 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 prochloraz 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.57 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl- 
                 carbendazim 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.58 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl- 
                 carbendazim 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.59 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 carbendazim 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.60 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 carbendazim 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.61 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl- 
                 carbendazim 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.62 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3-difluoromethyl- 
                 carbendazim 
               
               
                   
                 1H-pyrazole-4-carboxamide 
               
               
                 No. A.63 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 carbendazim 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.64 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 carbendazim 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 12 
               
             
            
               
                   
               
               
                 Active compound combinations of compounds I with active compounds II of group B): 
               
            
           
           
               
               
               
            
               
                 Mixture 
                 Compound of the formula I 
                 Active compound II 
               
               
                   
               
               
                 No. B.1 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 kresoxim-methyl 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.2 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 kresoxim-methyl 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.3 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 kresoxim-methyl 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.4 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 kresoxim-methyl 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.5 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 kresoxim-methyl 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.6 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 kresoxim-methyl 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.7 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 kresoxim-methyl 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.8 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 kresoxim-methyl 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.9 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 pyraclostrobin 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.10 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 pyraclostrobin 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.11 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 pyraclostrobin 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.12 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 pyraclostrobin 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.13 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 pyraclostrobin 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.14 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 pyraclostrobin 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.15 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 pyraclostrobin 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.16 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 pyraclostrobin 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.17 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 orysastrobin 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.18 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 orysastrobin 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.19 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1- 
                 orysastrobin 
               
               
                   
                 methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.20 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 orysastrobin 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.21 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 orysastrobin 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.22 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 orysastrobin 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.23 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 orysastrobin 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.24 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 orysastrobin 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 13 
               
             
            
               
                   
               
               
                 Active compound combinations of compounds I with active 
               
               
                 compounds II of group C): 
               
            
           
           
               
               
               
            
               
                   
                   
                 Active 
               
               
                 Mixture 
                 Compound of the formula I 
                 compound II 
               
               
                   
               
               
                 No. C.1 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 dimethomorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. C.2 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 dimethomorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. C.3 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl- 
                 dimethomorph 
               
               
                   
                 3-trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. C.4 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl- 
                 dimethomorph 
               
               
                   
                 3-trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. C.5 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 dimethomorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. C.6 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 dimethomorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. C.7 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl- 
                 dimethomorph 
               
               
                   
                 3-difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. C.8 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl- 
                 dimethomorph 
               
               
                   
                 3-difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 14 
               
             
            
               
                   
               
               
                 Active compound combinations of compounds I with active compounds II of group D): 
               
            
           
           
               
               
               
            
               
                 Mixture 
                 Compound of the formula I 
                 Active compound II 
               
               
                   
               
               
                 No. D.1 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 pyrimethanil 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.2 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 pyrimethanil 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.3 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 pyrimethanil 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.4 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 pyrimethanil 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.5 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 pyrimethanil 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.6 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 pyrimethanil 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.7 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 pyrimethanil 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.8 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 pyrimethanil 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.9 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
                 piperidin-1-yl)-6-(2,4,6- 
               
               
                   
                   
                 trifluorophenyl)-[1,2,4]- 
               
               
                   
                   
                 triazolo[1,5-a]pyrimidine 
               
               
                 No. D.10 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
                 piperidin-1-yl)-6-(2,4,6- 
               
               
                   
                   
                 trifluorophenyl)-[1,2,4]- 
               
               
                   
                   
                 triazolo[1,5-a]pyrimidine 
               
               
                 No. D.11 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
                 piperidin-1-yl)-6-(2,4,6- 
               
               
                   
                   
                 trifluorophenyl)-[1,2,4]- 
               
               
                   
                   
                 triazolo[1,5-a]pyrimidine 
               
               
                 No. D.12 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
                 piperidin-1-yl)-6-(2,4,6- 
               
               
                   
                   
                 trifluorophenyl)-[1,2,4]- 
               
               
                   
                   
                 triazolo[1,5-a]pyrimidine 
               
               
                 No. D.13 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
                 piperidin-1-yl)-6-(2,4,6- 
               
               
                   
                   
                 trifluorophenyl)-[1,2,4]- 
               
               
                   
                   
                 triazolo[1,5-a]pyrimidine 
               
               
                 No. D.14 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
                 piperidin-1-yl)-6-(2,4,6- 
               
               
                   
                   
                 trifluorophenyl)-[1,2,4]- 
               
               
                   
                   
                 triazolo[1,5-a]pyrimidine 
               
               
                 No. D.15 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
                 piperidin-1-yl)-6-(2,4,6- 
               
               
                   
                   
                 trifluorophenyl)-[1,2,4]- 
               
               
                   
                   
                 triazolo[1,5-a]pyrimidine 
               
               
                 No. D.16 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
                 piperidin-1-yl)-6-(2,4,6- 
               
               
                   
                   
                 trifluorophenyl)-[1,2,4]- 
               
               
                   
                   
                 triazolo[1,5-a]pyrimidine 
               
               
                 No. D.17 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 dodemorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.18 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 dodemorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.19 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 dodemorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.20 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 dodemorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.21 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 dodemorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.22 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 dodemorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.23 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 dodemorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.24 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 dodemorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.25 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 fenpropimorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.26 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 fenpropimorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.27 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 fenpropimorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.28 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 fenpropimorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.29 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 fenpropimorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.30 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 fenpropimorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.31 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 fenpropimorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.32 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 fenpropimorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.33 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 tridemorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.34 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 tridemorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.35 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 tridemorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.36 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 tridemorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.37 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 tridemorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.38 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 tridemorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.39 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 tridemorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.40 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 tridemorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.41 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 iprodione 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.42 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 iprodione 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.43 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 iprodione 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.44 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 iprodione 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.45 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 iprodione 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.46 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 iprodione 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.47 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 iprodione 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.48 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 iprodione 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.49 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 vinclozolin 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.50 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 vinclozolin 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.51 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 vinclozolin 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.52 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 vinclozolin 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.53 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 vinclozolin 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.54 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 vinclozolin 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.55 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 vinclozolin 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.56 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 vinclozolin 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 15 
               
             
            
               
                   
               
               
                 Active compound combinations of compounds I with 
               
               
                 active compounds II of group E): 
               
            
           
           
               
               
               
            
               
                   
                   
                 Active 
               
               
                   
                   
                 compound 
               
               
                 Mixture 
                 Compound of the formula I 
                 II 
               
               
                   
               
               
                 No. E.1 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 mancozeb 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.2 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 mancozeb 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.3 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 mancozeb 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.4 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 mancozeb 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.5 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 mancozeb 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.6 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 mancozeb 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.7 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 mancozeb 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.8 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 mancozeb 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.9 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 metiram 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.10 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 metiram 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.11 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 metiram 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.12 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 metiram 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.13 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 metiram 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.14 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 metiram 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.15 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 metiram 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.16 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 metiram 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 16 
               
             
            
               
                   
               
               
                 Active compound combinations of compounds I with active compounds II of group F): 
               
            
           
           
               
               
               
            
               
                 Mixture 
                 Compound of the formula I 
                 Active compound II 
               
               
                   
               
               
                 No. F.1 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 chlorothalonil 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.2 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 chlorothalonil 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.3 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 chlorothalonil 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.4 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 chlorothalonil 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.5 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 chlorothalonil 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.6 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 chlorothalonil 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.7 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 chlorothalonil 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.8 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1- 
                 chlorothalonil 
               
               
                   
                 methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.9 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 metrafenone 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.10 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 metrafenone 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.11 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 metrafenone 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.12 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 metrafenone 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.13 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 metrafenone 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.14 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 metrafenone 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.15 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 metrafenone 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.16 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 metrafenone 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.17 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 phosphorous acid 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.18 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 phosphorous acid 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.19 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 phosphorous acid 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.20 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 phosphorous acid 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.21 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3- 
                 phosphorous acid 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.22 
                 N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3- 
                 phosphorous acid 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.23 
                 N-(2′-fluoro-5′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 phosphorous acid 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.24 
                 N-(2′-chloro-5′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 phosphorous acid 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 17 
               
             
            
               
                   
               
               
                 Active compound combinations of compounds I with two active compounds II: 
               
            
           
           
               
               
               
               
            
               
                 Mixture 
                 Compound of the formula I 
                 Active compound II 
                 Active compound II 
               
               
                   
               
               
                 I-II-II.1 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 pyraclostrobin 
                 epoxiconazole 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.2 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 epoxiconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.3 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 pyraclostrobin 
                 epoxiconazole 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.4 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 epoxiconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.5 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 pyraclostrobin 
                 metconazole 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.6 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 metconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.7 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 pyraclostrobin 
                 metconazole 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.8 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 metconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.9 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 pyraclostrobin 
                 triticonazole 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.10 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 triticonazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.11 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 pyraclostrobin 
                 triticonazole 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.12 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 triticonazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.13 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 pyraclostrobin 
                 fluquinconazole 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.14 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 fluquinconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.15 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 pyraclostrobin 
                 fluquinconazole 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.16 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 fluquinconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.17 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 pyraclostrobin 
                 prothioconazole 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.18 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 prothioconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.19 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 pyraclostrobin 
                 prothioconazole 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.20 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 prothioconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.21 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 pyraclostrobin 
                 tebuconazole 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.22 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 tebuconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.23 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 pyraclostrobin 
                 tebuconazole 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.24 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 tebuconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.25 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 pyraclostrobin 
                 carbendazim 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.26 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.27 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 pyraclostrobin 
                 carbendazim 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.28 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.29 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 pyraclostrobin 
                 thiophanate-methyl 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.30 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.31 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 pyraclostrobin 
                 thiophanate-methyl 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.32 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.33 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 pyraclostrobin 
                 benomyl 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.34 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.35 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 pyraclostrobin 
                 benomyl 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.36 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.37 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 pyraclostrobin 
                 fenpropimorph 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.38 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.39 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 pyraclostrobin 
                 fenpropimorph 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.40 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.41 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 pyraclostrobin 
                 metrafenone 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.42 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.43 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 pyraclostrobin 
                 metrafenone 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.44 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.45 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 kresoxim-methyl 
                 epoxiconazole 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.46 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 epoxiconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.47 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 kresoxim-methyl 
                 epoxiconazole 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.48 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 epoxiconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.49 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 kresoxim-methyl 
                 metconazole 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.50 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 metconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.51 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 kresoxim-methyl 
                 metconazole 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.52 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 metconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.53 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 kresoxim-methyl 
                 triticonazole 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.54 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 triticonazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.55 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 kresoxim-methyl 
                 triticonazole 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.56 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 triticonazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.57 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 kresoxim-methyl 
                 fluquinconazole 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.58 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 fluquinconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.59 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 kresoxim-methyl 
                 fluquinconazole 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.60 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 fluquinconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.61 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 kresoxim-methyl 
                 prothioconazole 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.62 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 prothioconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.63 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 kresoxim-methyl 
                 prothioconazole 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.64 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 prothioconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.65 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 kresoxim-methyl 
                 tebuconazole 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.66 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 tebuconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.67 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 kresoxim-methyl 
                 tebuconazole 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.68 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 tebuconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.69 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 kresoxim-methyl 
                 carbendazim 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.70 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.71 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 kresoxim-methyl 
                 carbendazim 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.72 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.73 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 kresoxim-methyl 
                 thiophanate-methyl 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.74 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.75 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 kresoxim-methyl 
                 thiophanate-methyl 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.76 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.77 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 kresoxim-methyl 
                 benomyl 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.78 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.79 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 kresoxim-methyl 
                 benomyl 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.80 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.81 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 kresoxim-methyl 
                 fenpropimorph 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.82 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.83 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 kresoxim-methyl 
                 fenpropimorph 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.84 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.85 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 kresoxim-methyl 
                 metrafenone 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.86 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.87 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 kresoxim-methyl 
                 metrafenone 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.88 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.89 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 epoxiconazole 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
                   
                 piperidin-1-yl)-6- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 (2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidine 
               
               
                 I-II-II.90 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                   
                 piperidin-1-yl)-6- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 (2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]triazolo[1, 
               
               
                   
                   
                   
                 5-a]pyrimidine 
               
               
                 I-II-II.91 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 epoxiconazole 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
                   
                 piperidin-1-yl)-6- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 (2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidine 
               
               
                 I-II-II.92 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                   
                 piperidin-1-yl)-6- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 (2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidine 
               
               
                 I-II-II.93 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 epoxiconazole 
                 carbendazim 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.94 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.95 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 epoxiconazole 
                 carbendazim 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.96 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.97 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 epoxiconazole 
                 thiophanate-methyl 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.98 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.99 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 epoxiconazole 
                 thiophanate-methyl 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.100 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.101 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 epoxiconazole 
                 benomyl 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.102 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.103 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 epoxiconazole 
                 benomyl 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.104 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.105 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 epoxiconazole 
                 fenpropimorph 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.106 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.107 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 epoxiconazole 
                 fenpropimorph 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.108 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.110 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 epoxiconazole 
                 metrafenone 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.111 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.112 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 epoxiconazole 
                 metrafenone 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.113 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.114 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 epoxiconazole 
                 metalaxyl 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.115 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.116 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 epoxiconazole 
                 metalaxyl 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.117 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.118 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 epoxiconazole 
                 iprodione 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.119 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 iprodione 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.120 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 epoxiconazole 
                 iprodione 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.121 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 iprodione 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.122 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 epoxiconazole 
                 pyrimethanil 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.123 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.124 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 epoxiconazole 
                 pyrimethanil 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.125 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.126 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 metconazole 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
                   
                 piperidin-1-yl)-6- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 (2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidine 
               
               
                 I-II-II.127 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 metconazole 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                   
                 piperidin-1-yl)-6- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 (2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidine 
               
               
                 I-II-II.128 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 metconazole 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
                   
                 piperidin-1-yl)-6- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 (2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidine 
               
               
                 I-II-II.129 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 metconazole 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                   
                 piperidin-1-yl)-6- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 (2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidine 
               
               
                 I-II-II.130 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 metconazole 
                 carbendazim 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.131 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 metconazole 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.132 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 metconazole 
                 carbendazim 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.133 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 metconazole 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.134 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 metconazole 
                 thiophanate-methyl 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.135 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 metconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.136 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 metconazole 
                 thiophanate-methyl 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.137 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 metconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.138 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 metconazole 
                 benomyl 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.139 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 metconazole 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.140 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 metconazole 
                 benomyl 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.141 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 metconazole 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.142 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 metconazole 
                 fenpropimorph 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.143 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 metconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.144 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 metconazole 
                 fenpropimorph 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.145 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 metconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.146 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 metconazole 
                 metrafenone 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.147 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 metconazole 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.148 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 metconazole 
                 metrafenone 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.149 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 metconazole 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.150 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 metconazole 
                 metalaxyl 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.151 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 metconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.152 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 metconazole 
                 metalaxyl 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.153 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 metconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.154 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 metconazole 
                 iprodione 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.155 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 metconazole 
                 iprodione 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.156 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 metconazole 
                 iprodione 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.157 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 metconazole 
                 iprodione 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.158 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 metconazole 
                 pyrimethanil 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.159 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 metconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.160 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 metconazole 
                 pyrimethanil 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.161 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 metconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.162 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 triticonazole 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
                   
                 piperidin-1-yl)-6- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 (2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidine 
               
               
                 I-II-II.163 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                   
                 piperidin-1-yl)-6- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 (2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidine 
               
               
                 I-II-II.164 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 triticonazole 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
                   
                 piperidin-1-yl)-6- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 (2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidine 
               
               
                 I-II-II.165 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                   
                 piperidin-1-yl)-6- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 (2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidine 
               
               
                 I-II-II.166 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 triticonazole 
                 carbendazim 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.167 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.168 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 triticonazole 
                 carbendazim 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.169 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.170 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 triticonazole 
                 thiophanate-methyl 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.171 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.172 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 triticonazole 
                 thiophanate-methyl 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.173 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.174 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 triticonazole 
                 benomyl 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.175 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.176 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 triticonazole 
                 benomyl 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.177 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.178 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 triticonazole 
                 fenpropimorph 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.179 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.180 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 triticonazole 
                 fenpropimorph 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.181 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.182 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 triticonazole 
                 metrafenone 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.183 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.184 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 triticonazole 
                 metrafenone 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.185 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.186 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 triticonazole 
                 metalaxyl 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.187 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 metalaxyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.188 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 triticonazole 
                 metalaxyl 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.189 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 metalaxyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.190 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 triticonazole 
                 iprodione 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.191 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 iprodione 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.192 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 triticonazole 
                 iprodione 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.193 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 iprodione 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.194 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 triticonazole 
                 pyrimethanil 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.195 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.196 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 triticonazole 
                 pyrimethanil 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.197 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.198 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 fluquinconazole 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
                   
                 piperidin-1-yl)-6- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 (2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidine 
               
               
                 I-II-II.199 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                   
                 piperidin-1-yl)-6- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 (2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidine 
               
               
                 I-II-II.200 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 fluquinconazole 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
                   
                 piperidin-1-yl)-6- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 (2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidine 
               
               
                 I-II-II.201 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                   
                 piperidin-1-yl)-6- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 (2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidine 
               
               
                 I-II-II.202 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 fluquinconazole 
                 carbendazim 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.203 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.204 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 fluquinconazole 
                 carbendazim 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.205 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.206 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 fluquinconazole 
                 thiophanate-methyl 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.207 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.208 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 fluquinconazole 
                 thiophanate-methyl 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.209 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.210 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 fluquinconazole 
                 benomyl 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.211 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.212 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 fluquinconazole 
                 benomyl 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.213 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.214 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 fluquinconazole 
                 fenpropimorph 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.215 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.216 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 fluquinconazole 
                 fenpropimorph 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.217 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.218 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 fluquinconazole 
                 metrafenone 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.219 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.220 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 fluquinconazole 
                 metrafenone 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.221 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.222 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 fluquinconazole 
                 metalaxyl 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.223 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.224 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 fluquinconazole 
                 metalaxyl 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.225 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.226 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 fluquinconazole 
                 iprodione 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.227 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 iprodione 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.228 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 fluquinconazole 
                 iprodione 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.229 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 iprodione 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.230 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 fluquinconazole 
                 pyrimethanil 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.231 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.232 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 fluquinconazole 
                 pyrimethanil 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.233 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.234 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 prothioconazole 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
                   
                 piperidin-1-yl)-6- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 (2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidine 
               
               
                 I-II-II.235 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                   
                 piperidin-1-yl)-6- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 (2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidine 
               
               
                 I-II-II.236 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 prothioconazole 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
                   
                 piperidin-1-yl)-6- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 (2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidine 
               
               
                 I-II-II.237 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                   
                 piperidin-1-yl)-6- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 (2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidine 
               
               
                 I-II-II.238 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 prothioconazole 
                 carbendazim 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.239 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.240 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 prothioconazole 
                 carbendazim 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.241 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.242 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 prothioconazole 
                 thiophanate-methyl 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.243 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.244 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 prothioconazole 
                 thiophanate-methyl 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.245 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.246 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 prothioconazole 
                 benomyl 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.247 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.248 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 prothioconazole 
                 benomyl 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.249 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.250 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 prothioconazole 
                 fenpropimorph 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.251 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.252 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 prothioconazole 
                 fenpropimorph 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.253 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.254 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 prothioconazole 
                 metrafenone 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.255 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.256 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 prothioconazole 
                 metrafenone 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.257 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.258 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 prothioconazole 
                 metalaxyl 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.259 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.260 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 prothioconazole 
                 metalaxyl 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.261 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.262 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 prothioconazole 
                 iprodione 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.263 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 iprodione 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.264 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 prothioconazole 
                 iprodione 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.265 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 iprodione 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.266 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 prothioconazole 
                 pyrimethanil 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.267 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.268 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 prothioconazole 
                 pyrimethanil 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.269 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.270 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 tebuconazole 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
                   
                 piperidin-1-yl)-6- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 (2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidine 
               
               
                 I-II-II.271 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                   
                 piperidin-1-yl)-6- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 (2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidine 
               
               
                 I-II-II.272 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 tebuconazole 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
                   
                 piperidin-1-yl)-6- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 (2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidine 
               
               
                 I-II-II.273 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                   
                 piperidin-1-yl)-6- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 (2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidine 
               
               
                 I-II-II.274 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 tebuconazole 
                 carbendazim 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.275 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.276 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 tebuconazole 
                 carbendazim 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.277 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.278 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 tebuconazole 
                 thiophanate-methyl 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.279 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.280 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 tebuconazole 
                 thiophanate-methyl 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.281 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.282 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 tebuconazole 
                 benomyl 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.283 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.284 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 tebuconazole 
                 benomyl 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.285 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.286 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 tebuconazole 
                 fenpropimorph 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.287 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.288 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 tebuconazole 
                 fenpropimorph 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.289 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.290 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 tebuconazole 
                 metrafenone 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.291 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.292 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 tebuconazole 
                 metrafenone 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.293 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.294 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 tebuconazole 
                 metalaxyl 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.295 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.296 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 tebuconazole 
                 metalaxyl 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.297 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.298 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 tebuconazole 
                 iprodione 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.299 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 iprodione 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.300 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 tebuconazole 
                 iprodione 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.301 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 iprodione 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.302 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 tebuconazole 
                 pyrimethanil 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.303 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.304 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 tebuconazole 
                 pyrimethanil 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.305 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.306 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 5-chloro-7-(4- 
                 carbendazim 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                 azolo[1,5-a]- 
               
               
                   
                   
                 pyrimidine 
               
               
                 I-II-II.307 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                 azolo[1,5-a]- 
               
               
                   
                   
                 pyrimidine 
               
               
                 I-II-II.308 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 5-chloro-7-(4- 
                 carbendazim 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                 azolo[1,5-a]- 
               
               
                   
                   
                 pyrimidine 
               
               
                 I-II-II.309 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                 azolo[1,5-a]- 
               
               
                   
                   
                 pyrimidine 
               
               
                 I-II-II.310 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 5-chloro-7-(4- 
                 thiophanate-methyl 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                 azolo[1,5-a]- 
               
               
                   
                   
                 pyrimidine 
               
               
                 I-II-II.311 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                 azolo[1,5-a]- 
               
               
                   
                   
                 pyrimidine 
               
               
                 I-II-II.312 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 5-chloro-7-(4- 
                 thiophanate-methyl 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                 azolo[1,5-a]- 
               
               
                   
                   
                 pyrimidine 
               
               
                 I-II-II.313 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                 azolo[1,5-a]- 
               
               
                   
                   
                 pyrimidine 
               
               
                 I-II-II.314 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 5-chloro-7-(4- 
                 benomyl 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                 azolo[1,5-a]- 
               
               
                   
                   
                 pyrimidine 
               
               
                 I-II-II.315 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                 azolo[1,5-a]- 
               
               
                   
                   
                 pyrimidine 
               
               
                 I-II-II.316 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 5-chloro-7-(4- 
                 benomyl 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                 azolo[1,5-a]- 
               
               
                   
                   
                 pyrimidine 
               
               
                 I-II-II.317 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                 azolo[1,5-a]- 
               
               
                   
                   
                 pyrimidine 
               
               
                 I-II-II.318 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 5-chloro-7-(4- 
                 fenpropimorph 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                 azolo[1,5-a]- 
               
               
                   
                   
                 pyrimidine 
               
               
                 I-II-II.319 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                 azolo[1,5-a]- 
               
               
                   
                   
                 pyrimidine 
               
               
                 I-II-II.320 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 5-chloro-7-(4- 
                 fenpropimorph 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                 azolo[1,5-a]- 
               
               
                   
                   
                 pyrimidine 
               
               
                 I-II-II.321 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                 azolo[1,5-a]- 
               
               
                   
                   
                 pyrimidine 
               
               
                 I-II-II.322 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 5-chloro-7-(4- 
                 metrafenone 
               
               
                   
                 1-methyl-3-trifluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                 azolo[1,5-a]- 
               
               
                   
                   
                 pyrimidine 
               
               
                 I-II-II.323 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                 azolo[1,5-a]- 
               
               
                   
                   
                 pyrimidine 
               
               
                 I-II-II.324 
                 N-(2′,5′-dichlorobiphenyl-2-yl)- 
                 5-chloro-7-(4- 
                 metrafenone 
               
               
                   
                 1-methyl-3-difluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                 azolo[1,5-a]- 
               
               
                   
                   
                 pyrimidine 
               
               
                 I-II-II.325 
                 N-(2′,5′-difluorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                 azolo[1,5-a]- 
               
               
                   
                   
                 pyrimidine 
               
               
                   
               
            
           
         
       
     
     The mixtures of compound(s) I and at least one of the active compounds II, or at least one compound I and at least one of the active compounds II applied simultaneously, that is jointly or separately, have excellent activity against a broad spectrum of phytopathogenic fungi, in particular from the class of the Ascomycetes, Basidiomycetes, Deuteromycetes and Peronosporomycetes (syn. Oomycetes). Some of them are systemically effective and can be employed in crop protection as foliar fungicides, as fungicides for seed dressing and as soil fungicides. They can also be used for treating seed. 
     They are particularly important in the control of a multitude of fungi on various cultivated plants, such as wheat, rye, barley, oats, rice, corn, grass, bananas, cotton, soybeans, coffee, sugar cane, vines, fruits and ornamental plants, and vegetables, such as cucumbers, beans, tomatoes, potatoes and cucurbits, and on the seeds of these plants. 
     They are especially suitable for controlling the following plant diseases:
           Alternaria  species on vegetables, oilseed rape, sugar beet and fruit and rice, for example,  A. solani  or  A. alternata  on potatoes and tomatoes;     Aphanomyces  species on sugar beet and vegetables;     Ascochyta  species on cereals and vegetables;     Bipolaris  and  Drechslera  species on corn, cereals, rice and lawns, for example,  D. maydis  on corn;     Blumeria graminis  (powdery mildew) on cereals;     Botrytis cinerea  (gray mold) on strawberries, vegetables, flowers and grapevines;     Bremia lactucae  on lettuce;     Cercospora  species on corn, soybeans, rice and sugar beet;     Cochliobolus  species on corn, cereals, rice, for example  Cochliobolus sativus  on cereals,  Cochliobolus  miyabeanus on rice;     Colletotricum  species on soybeans and cotton;     Drechslera  species,  Pyrenophora  species on corn, cereals, rice and lawns, for example,  D. teres  on barley or  D. tritici - repentis  on wheat;   Esca on grapevines, caused by  Phaeoacremonium chlamydosporium, Ph. Aleophilum  and  Formitipora punctata  (syn.  Phellinus punctatus );     Exserohilum  species on corn;     Erysiphe cichoracearum  and  Sphaerotheca fuliginea  on cucumbers;     Fusarium  and  Verticillium  species on various plants, for example,  F graminearum  or  F. culmorum  on cereals or  F. oxysporum  on a multitude of plants, such as, for example, tomatoes;     Gaeumanomyces graminis  on cereals;     Gibberella  species on cereals and rice (for example  Gibberella fujikuroi  on rice);   Grainstaining complex on rice;     Helminthosporium  species on corn and rice;     Michrodochium nivale  on cereals;     Mycosphaerella  species on cereals, bananas and groundnuts, for example,  M. graminicola  on wheat or  M. fijiensis  on bananas;     Peronospora  species on cabbage and bulbous plants, for example,  P. brassicae  on cabbage or  P. destructor  on onions;   Phakopsara pachyrhizi and  Phakopsara meibomiae  on soybeans;     Phomopsis  species on soybeans and sunflowers;     Phytophthora infestans  on potatoes and tomatoes;     Phytophthora  species on various plants, for example,  P. capsici  on bell pepper;     Plasmopara viticola  on grapevines;     Podosphaera leucotricha  on apples;     Pseudocercosporella herpotrichoides  on cereals;     Pseudoperonospora  on various plants, for example,  P. cubensis  on cucumber or  P. humili  on hops;     Puccinia  species on various plants, for example,  P. triticina, P. striformins, P. hordei  or  P. graminis  on cereals or  P. asparagi  on asparagus;     Pyricularia oryzae, Corticium sasakii, Sarocladium oryzae, S. attenuatum, Entyloma oryzae  on rice;     Pyricularia grisea  on lawns and cereals;     Pythium  spp. on lawns, rice, corn, cotton, oilseed rape, sunflowers, sugar beet, vegetables and other plants, for example,  P. ultiumum  on various plants,  P. aphanidermatum  on lawns;     Rhizoctonia  species on cotton, rice, potatoes, lawns, corn, oilseed rape, sugar beet, vegetables and on various plants, for example,  R. solani  on beet and various plants;     Rhynchosporium secalis  on barley, rye and triticale;     Sclerotinia  species on oilseed rape and sunflowers;     Septoria tritici  and  Stagonospora nodorum  on wheat;     Erysiphe  (syn.  Uncinula )  necator  on grapevines;     Setospaeria  species on corn and lawns;     Sphacelotheca reilinia  on corn;     Thievaliopsis  species on soybeans and cotton;     Tilletia  species on cereals;     Ustilago  species on cereals, corn and sugar cane, for example,  U. maydis  on corn;     Venturia  species (scab) on apples and pears, for example,  V. inaequalis  on apples.       

     The mixtures according to the invention are also suitable for controlling harmful fungi in the protection of materials (for example wood, paper, paint dispersions, fibers or fabrics) and in the protection of stored products. In the protection of wood, particular attention is paid to the following harmful fungi: Ascomycetes, such as  Ophiostoma  spp.,  Ceratocystis  spp.,  Aureobasidium pullulans, Sclerophoma  spp.,  Chaetomium  spp.,  Humicola  spp.,  Petriella  spp.,  Trichurus  spp.; Basidiomycetes, such as  Coniophora  spp.,  Coriolus  spp.,  Gloeophyllum  spp.,  Lentinus  spp.,  Pleurotus  spp.,  Poria  spp.,  Serpula  spp. and  Tyromyces  spp., Deuteromycetes, such as  Aspergillus  spp.,  Cladosporium  spp.,  Penicillium  spp.,  Trichoderma  spp.,  Alternaria  spp.,  Paecilomyces  spp. and Zygomycetes, such as  Mucor  spp., additionally in the protection of materials the following yeasts:  Candida  spp. and  Saccharomyces cerevisae.    
     The compound(s) I and at least one of the active compounds II can be applied simultaneously, that is jointly or separately, or in succession, the order in the case of separate application generally not having any effect on the control result. 
     When providing the mixtures, preference is given to using the pure active compounds I to II, to which further active compounds against harmful fungi or against other pests such as insects, arachnids or nematodes or else herbicidally active or growth-regulating active compounds or fertilizers may be added. 
     Such mixtures of three active compounds consist, for example, of a compound of the formula I, in particular N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide, N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide, N-(2′,5′-difluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide or N-(2′,5′-dichlorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide, an azole from the group A), in particular epoxiconazole, metconazole, triticonazole or fluquinconazole, and an insecticide, suitable insecticides being in particular fipronil and neonicotinoids, such as acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid and thiamethoxam. 
     Usually, mixtures of at least one compound I and at least one active compound II are employed. Here, mixtures of at least one compound I with two or, if desired, more active components may offer particular advantages. 
     Suitable further active components in the above sense are in particular the active compounds II, mentioned at the outset, and in particular the preferred active compounds II mentioned above. 
     The compound(s) I and the active compound(s) II are usually employed in a weight ratio of from 100:1 to 1:100, preferably from 20:1 to 1:20, in particular from 10:1 to 1:10. 
     The further active components are, if desired, added in a ratio of from 20:1 to 1:20 to the compound 1. 
     Depending on the type of compounds I and II and the desired effect, the application rates of the mixtures according to the invention, in particular in the case of agricultural crop areas, are from 5 g/ha to 2000 g/ha, preferably from 20 to 1500 g/ha, in particular from 50 to 1000 g/ha. 
     Correspondingly, the application rates for the compound(s) I are generally from 1 to 1000 g/ha, preferably from 10 to 900 g/ha, in particular from 20 to 750 g/ha. 
     Correspondingly, the application rates for the active compounds II are generally from 1 to 2000 g/ha, preferably from 10 to 1500 g/ha, in particular from 40 to 1000 g/ha. 
     In the treatment of seed, application rates of mixture are generally from 1 to 1000 g per 100 kg of seed, preferably from 1 to 750 g per 100 kg, in particular from 5 to 500 g per 100 kg of seed. 
     The method for controlling harmful fungi is carried out by the separate or joint application of compound(s) I and at least one of the active compounds II or a mixture of compound(s) I and at least one of the active compounds II by spraying or dusting the seeds, the plants or the soils before or after sowing of the plants or before or after emergence of the plants. 
     The fungicidal, synergistic mixtures according to the invention, or the compound(s) I and at least one of the active compounds II, can be converted into the customary formulations, for example solutions, emulsions, suspensions, dusts, powders, pastes or granules. The use form depends on the particular intended purpose; in each case, it should ensure as fine and even a distribution as possible of the mixture according to the invention. 
     The formulations are prepared in a manner known per se, for example by extending the active compounds with solvents and/or carriers, if desired using emulsifiers and dispersants. Solvents/auxiliaries suitable for this purpose are essentially:
         water, aromatic solvents (for example Solvesso® products, xylene), paraffins (for example mineral oil fractions), alcohols (for example methanol, butanol, pentanol, benzyl alcohol), ketones (for example cyclohexanone, gamma-butyrolactone), pyrrolidones (N-methylpyrrolidone, N-octylpyrrolidone), acetates (glycol diacetate), glycols, fatty acid dimethylamides, fatty acids and fatty acid esters. In principle, solvent mixtures may also be used,   carriers such as ground natural minerals (for example kaolins, clays, talc, chalk) and ground synthetic minerals (for example finely divided silica, silicates); emulsifiers such as nonionogenic and anionic emulsifiers (for example polyoxyethylene fatty alcohol ethers, alkylsulfonates and arylsulfonates) and dispersants such as lignosulfite waste liquors and methylcellulose.       

     Suitable surfactants are alkali metal, alkaline earth metal and ammonium salts of lignosulfonic acid, naphthalenesulfonic acid, phenolsulfonic acid, dibutylnaphthalene-sulfonic acid, alkylarylsulfonates, alkyl sulfates, alkylsulfonates, fatty alcohol sulfates, fatty acids and sulfated fatty alcohol glycol ethers, furthermore condensates of sulfonated naphthalene and naphthalene derivatives with formaldehyde, condensates of naphthalene or of naphthalenesulfonic acid with phenol and formaldehyde, polyoxyethylene octylphenol ether, ethoxylated isooctylphenol, octylphenol, nonylphenol, alkylphenol polyglycol ethers, tributylphenyl polyglycol ether, tristearylphenyl polyglycol ether, alkylaryl polyether alcohols, alcohol and fatty alcohol/ethylene oxide condensates, ethoxylated castor oil, polyoxyethylene alkyl ethers, ethoxylated polyoxypropylene, lauryl alcohol polyglycol ether acetal, sorbitol esters, lignosulfite waste liquors and methylcellulose. 
     Suitable for the preparation of directly sprayable solutions, emulsions, pastes or oil dispersions are mineral oil fractions of medium to high boiling point, such as kerosene or diesel oil, furthermore coal tar oils and oils of vegetable or animal origin, aliphatic, cyclic and aromatic hydrocarbons, for example toluene, xylene, paraffin, tetrahydronaphthalene, alkylated naphthalenes or their derivatives, methanol, ethanol, propanol, butanol, cyclohexanol, cyclohexanone, isophorone, strongly polar solvents, for example dimethyl sulfoxide, N-methylpyrrolidone and water. 
     Powders, materials for spreading and dustable products can be prepared by mixing or concomitantly grinding the active substances with at least one solid carrier. 
     Granules, for example coated granules, impregnated granules and homogeneous granules, can be prepared by binding the active compounds to at least one solid carrier. Examples of solid carriers are mineral earths such as silica gels, silicates, talc, kaolin, attaclay, limestone, lime, chalk, bole, loess, clay, dolomite, diatomaceous earth, calcium sulfate, magnesium sulfate, magnesium oxide, ground synthetic materials, fertilizers, such as ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas, and products of vegetable origin, such as cereal meal, tree bark meal, wood meal and nutshell meal, cellulose powders and other solid carriers. 
     In general, the formulations comprise from 0.01 to 95% by weight, preferably from 0.1 to 90% by weight, of the compound(s) I and at least one of the active compounds II or of the mixture of the compound(s) I with at least one active compound II. The active compounds are employed in a purity of from 90% to 100%, preferably 95% to 100% (according to NMR or HPLC spectrum). 
     The following are examples of formulations: 
     1. Products for Dilution with Water 
     A) Water-Soluble Concentrates (SL) 
     10 parts by weight of a mixture according to the invention are dissolved in 90 parts by weight of water or a water-soluble solvent. As an alternative, wetting agents or other auxiliaries are added. The active compound dissolves upon dilution with water. This gives a formulation having an active compound content of 10% by weight. 
     B) Dispersible Concentrates (DC) 
     20 parts by weight of a mixture according to the invention are dissolved in 70 parts by weight of cyclohexanone with addition of 10 parts by weight of a dispersant, for example polyvinylpyrrolidone. Dilution with water gives a dispersion. The active compound content is 20% by weight. 
     C) Emulsifiable Concentrates (EC) 
     15 parts by weight of a mixture according to the invention are dissolved in 75 parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight). Dilution with water gives an emulsion. The formulation has an active compound content of 15% by weight. 
     D) Emulsions (EW, EO) 
     25 parts by weight of a mixture according to the invention are dissolved in 35 parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight). This mixture is introduced into 30 parts by weight of water by means of an emulsifying machine (e.g. Ultraturrax) and made into a homogeneous emulsion. Dilution with water gives an emulsion. The formulation has an active compound content of 25% by weight. 
     E) Suspensions (SC, OD) 
     In an agitated ball mill, 20 parts by weight of a mixture according to the invention are comminuted with addition of 10 parts by weight of dispersants and wetting agent and 70 parts by weight of water or an organic solvent to give a fine active compound suspension. Dilution with water gives a stable suspension of the active compound. The active compound content in the formulation is 20% by weight. 
     F) Water-Dispersible Granules and Water-Soluble Granules (WG, SG) 
     50 parts by weight of a mixture according to the invention are ground finely with addition of 50 parts by weight of dispersants and wetting agent and prepared as water-dispersible or water-soluble granules by means of technical appliances (for example extrusion, spray tower, fluidized bed). Dilution with water gives a stable dispersion or solution of the active compound. The formulation has an active compound content of 50% by weight. 
     G) Water-Dispersible Powders and Water-Soluble Powders (WP, SP) 
     75 parts by weight of a mixture according to the invention are ground in a rotor-stator mill with addition of 25 parts by weight of dispersants, wetting agent and silica gel. Dilution with water gives a stable dispersion or solution of the active compound. The active compound content of the formulation is 75% by weight. 
     2. Products to be Applied Undiluted 
     H) Dustable Powders (DP) 
     5 parts by weight of a mixture according to the invention are ground finely and mixed intimately with 95 parts by weight of finely divided kaolin. This gives a dustable product having an active compound content of 5% by weight. 
     J) Granules (GR, FG, GG, MG) 
     0.5 part by weight of a mixture according to the invention is ground finely and associated with 99.5 parts by weight of carriers. Current methods are extrusion, spray-drying or the fluidized bed. This gives granules to be applied undiluted having an active compound content of 0.5% by weight. 
     K) ULV Solutions (UL) 
     10 parts by weight of a mixture according to the invention are dissolved in 90 parts by weight of an organic solvent, for example xylene. This gives a product to be applied undiluted having an active compound content of 10% by weight. 
     The active compounds can be used as such, in the form of their formulations or the use forms prepared therefrom, for example in the form of directly sprayable solutions, powders, suspensions or dispersions, emulsions, oil dispersions, pastes, dustable products, materials for spreading, or granules, by means of spraying, atomizing, dusting, spreading or pouring. The use forms depend entirely on the intended purposes; they are intended to ensure in each case the finest possible distribution of the active compounds. 
     Aqueous use forms can be prepared from emulsion concentrates, pastes or wettable powders (sprayable powders, oil dispersions) by adding water. To prepare emulsions, pastes or oil dispersions, the substances, as such or dissolved in an oil or solvent, can be homogenized in water by means of a wetting agent, tackifier, dispersant or emulsifier. However, it is also possible to prepare concentrates composed of active substance, wetting agent, tackifier, dispersant or emulsifier and, if appropriate, solvent or oil, and such concentrates are suitable for dilution with water. 
     The active compound concentrations in the ready-to-use preparations can be varied within relatively wide ranges. In general, they are between 0.0001 and 10%, preferably between 0.01 and 1%. 
     The active compounds may also be used successfully in the ultra-low-volume (ULV) process, by which it is possible to apply formulations comprising over 95% by weight of active compound, or even to apply the active compound without additives. 
     Various types of oils, wetting agent, adjuvants, herbicides, other pesticides, or bactericides may be added to the active compounds, if desired not until immediately prior to use (tank mix). These agents are usually admixed with the mixtures according to the invention in a weight ratio of 1:100 to 100:1, preferably 1:10 to 10:1. 
     Suitable adjuvants in this sense are in particular: organically modified polysiloxanes, for example Break Thru S 240®; alcohol alkoxylates, for example Atplus 245®, Atplus MBA 1303®, Plurafac LF 300® and Lutensol ON 30®; EO/PO block polymers, for example Pluronic RPE 2035® and Genapol B®; alcohol ethoxylates, for example Lutensol XP 80®; and sodium dioctylsulfosuccinate, for example Leophen RA®. 
     The compounds I and II or the mixtures or the corresponding formulations are applied by treating the harmful fungi, their habitat or the plants, seeds, soils, areas, materials or spaces to be kept free from them with a fungicidally effective amount of the mixture or, in the case of separate application, of the compounds I and II. Application can be carried out before or after infection by the harmful fungi. 
    
    
     PREPARATION EXAMPLES 
     1.) Synthesis of ortho-(2,5-difluorophenyl)aniline 
     A spatula tip of tetrakistriphenylphosphinepalladium(0) was added to a solution of 1.55 g of 2-bromoaniline, 2.13 g of 2,5-difluorophenylboronic acid and 1.91 g of sodium carbonate in a mixture of 12 ml of water and 36 ml of ethylene glycol dimethyl ether. The mixture was stirred under reflux for 18 hours and then concentrated under reduced pressure. The residue was taken up in methyl tert-butyl ether, washed once with aqueous sodium bicarbonate solution and four times with water, dried over sodium sulfate and concentrated under reduced pressure. Chromatographic purification using a mixture of toluene and cyclohexane (1:1) gave 0.77 g of the product as a clear oil. 
     2.) Synthesis of N-(ortho-(2,5-difluorophenyl)phenyl)-1-methyl-3-trifluoromethylpyrazole-4-carboxamide 
     0.24 g of 1-methyl-3-trifluoromethylpyrazole-4-carbonyl chloride, 0.23 g of ortho-(2,5-difluorophenyl)aniline and 0.13 g of pyridine were dissolved in 7.5 ml of toluene. After 16 hours of stirring at room temperature, methyl tert-butyl ether was added and the mixture was washed twice with 5% strength hydrochloric acid, twice with 5% strength aqueous sodium hydroxide solution and once with water. The organic phase was dried over sodium sulfate and concentrated under reduced pressure. Recrystallization from diisopropyl ether gave 0.31 g of the product as a colorless powder; m.p.=110-112° C. 
     In addition to the compound described above, Table 18 lists, in an examplary manner, further 2,5-disubstituted N-biphenylpyrazolecarboxamides of the formula I which were prepared or are preparable in the same manner. 
     
       
         
           
               
               
               
               
               
               
               
             
               
                 TABLE 18 
               
               
                   
               
               
                 Compound 
                 X 
                 R 1   
                 R 2   
                 R 3   
                 R 4   
                 m.p. 
               
               
                   
               
             
            
               
                 No. I.1 
                 O 
                 F 
                 F 
                 CF 3   
                 H 
                 110-112° C. 
               
               
                 No. I.2 
                 O 
                 F 
                 F 
                 CHF 2   
                 H 
                 139-141° C. 
               
               
                 No. I.3 
                 O 
                 Cl 
                 Cl 
                 CH 2 F 
                 H 
                 123-125° C. 
               
               
                 No. I.4 
                 O 
                 Cl 
                 Cl 
                 CHF 2   
                 H 
                 130-132° C. 
               
               
                 No. I.5 
                 O 
                 Cl 
                 Cl 
                 CF 3   
                 H 
                 131-135° C. 
               
               
                 No. I.6 
                 O 
                 F 
                 Cl 
                 CH 2 F 
                 H 
                 137-139° C. 
               
               
                 No. I.7 
                 O 
                 F 
                 Cl 
                 CHF 2   
                 H 
                 148-150° C. 
               
               
                 No. I.8 
                 O 
                 F 
                 Cl 
                 CF 3   
                 H 
                 117-120° C. 
               
               
                 No. I.9 
                 O 
                 Cl 
                 F 
                 CH 2 F 
                 H 
               
               
                 No. I.10 
                 O 
                 Cl 
                 F 
                 CHF 2   
                 H 
                 118-120° C. 
               
               
                 No. I.11 
                 O 
                 Cl 
                 F 
                 CF 3   
                 H 
               
               
                 No. I.12 
                 O 
                 F 
                 CN 
                 CH 3   
                 F 
                 143-145° C. 
               
               
                 No. I.13 
                 O 
                 F 
                 OCH 3   
                 CH 3   
                 F 
                  94-97° C. 
               
               
                 No. I.14 
                 O 
                 F 
                 Cl 
                 CH 3   
                 F 
                 100-102° C. 
               
               
                 No. I.15 
                 O 
                 Cl 
                 Cl 
                 CH 3   
                 F 
                 123-124° C. 
               
               
                 No. I.16 
                 O 
                 CH 3   
                 NO 2   
                 CH 3   
                 F 
                 117-118° C. 
               
               
                 No. I.17 
                 O 
                 CH 3   
                 CH 3   
                 CH 3   
                 F 
                  96-97° C. 
               
               
                 No. I.18 
                 O 
                 F 
                 OCH 3   
                 CF 3   
                 H 
                 128-129° C. 
               
               
                 No. I.19 
                 O 
                 OCH 3   
                 CH(CH 3 ) 2   
                 CF 3   
                 H 
                 127-129° C. 
               
               
                   
               
            
           
         
       
     
     USE EXAMPLE 
     The synergistic action of the mixtures according to the invention was demonstrated by the following tests: 
     The active compounds, separately or jointly, were prepared as a stock solution comprising 25 mg of active compound which was made up to 10 ml using a mixture of acetone and/or dimethyl sulfoxide and the emulsifier Uniperol® EL (wetting agent having an emulsifying and dispersing action based on ethoxylated alkylphenols) in a ratio by volume of solvent/emulsifier of 99:1. The mixture was then made up to 100 ml with water. This stock solution was diluted with the solvent/emulsifier/water mixture described to give the concentration of active compound stated below. 
     Alternatively, the active compounds epoxiconazole and pyraclostrobin were used as a commercial formulation and diluted with water to the stated active compound concentrations. 
     The visually determined percentages of infected leaf areas were converted into efficacies in % of the untreated control. 
     The efficacy (E) is calculated as follows using Abbot&#39;s formula: 
         E =(1−α/β)·100 
     α corresponds to the fungicidal infection of the treated plants in % and
 
β corresponds to the fungicidal infection of the untreated (control) plants in %
 
     An efficacy of 0 means that the infection level of the treated plants corresponds to that of the untreated control plants; an efficacy of 100 means that the treated plants were not infected. 
     The expected efficacies of active compound mixtures were determined using Colby&#39;s formula [R. S. Colby, “Calculating synergistic and antagonistic responses of herbicide combinations”, Weeds 15, 20-22 (1967)] and compared with the observed efficacies. 
     Colby&#39;s Formula: 
         E=x+y−x·y/ 100     E expected efficacy, expressed in % of the untreated control, when using the mixture of the active compounds A and B at the concentrations a and b;   x efficacy, expressed in % of the untreated control, when using the active compound A at the concentration a;   y efficacy, expressed in % of the untreated control, when using the active compound B at the concentration b.   
     USE EXAMPLE 1 
     Activity Against Gray Mold on Bell Pepper Leaves Caused by  Botrytis cinerea,  1 Day Protective Application 
     Bell pepper seedlings of the cultivar “Neusiedler Ideal Elite” were, after 2-3 leaves were well developed, sprayed to runoff point with an aqueous suspension having the active compound concentration stated below. The next day, the treated plants were inoculated with a spore suspension of  Botrytis cinerea  which contained 1.7×10 6  spores/ml in a 2% strength aqueous biomalt solution. The test plants were then placed in a dark climatized chamber at 22 to 24° C. and high atmospheric humidity. After 5 days, the extent of the fungal infection on the leaves could be determined visually in %. 
     
       
         
           
               
               
               
               
               
             
               
                   
               
               
                   
                   
                   
                   
                 Effect 
               
               
                   
                   
                   
                   
                 calculated 
               
               
                   
                   
                   
                 Observed 
                 according 
               
               
                   
                 Concentration 
                   
                 effect (% 
                 to 
               
               
                 Active compound 
                 [mg/l] 
                 Ratio 
                 infection) 
                 Colby (%) 
               
               
                   
               
             
            
               
                 (Control) 
                 — 
                 — 
                 0 (100% 
                 — 
               
               
                   
                   
                   
                 infection) 
               
               
                 No. I.1 
                 1 
                 — 
                  0 
                 — 
               
               
                 5-chloro-7-(4-methyl- 
                 4 
                 — 
                 40 
                 — 
               
               
                 piperidin-1-yl)-6-(2,4,6- 
               
               
                 trifluorophenyl)- 
               
               
                 [1,2,4]triazolo[1,5-a]- 
               
               
                 pyrimidine 
               
               
                 No. I.1 + 5-chloro-7-(4- 
                 1 + 4 
                 1:4 
                 70 
                 40 
               
               
                 methylpiperidin-1-yl)-6- 
               
               
                 (2,4,6-trifluorophenyl)- 
               
               
                 [1,2,4]triazolo[1,5-a]- 
               
               
                 pyrimidine 
               
               
                   
               
            
           
         
       
     
     USE EXAMPLE 2 
     Protective Activity Against  Puccinia recondita  on Wheat (Brown Rust of Wheat) 
     Leaves of potted wheat seedlings of the cultivar “Kanzler” were sprayed to runoff point with an aqueous suspension having the active compound concentration stated below. The next day, the treated plants were inoculated with a spore suspension of brown rust of wheat ( Puccinia recondita ). The plants were then placed in a chamber with high atmospheric humidity (90 to 95%) at 20 to 22° C. for 24 hours. During this time, the spores germinated and the germ tubes penetrated into the leaf tissue. The next day, the test plants were returned to the greenhouse and cultivated at temperatures between 20 and 22° C. and at 65 to 70% relative atmospheric humidity for a further 7 days. The extent of the rust fungus development on the leaves was then determined visually. 
     
       
         
           
               
               
               
               
               
             
               
                   
               
               
                   
                   
                   
                   
                 Effect 
               
               
                   
                   
                   
                   
                 calculated 
               
               
                   
                   
                   
                   
                 according 
               
               
                   
                 Concentration 
                   
                 Observed effect 
                 to 
               
               
                 Active compound 
                 [mg/l] 
                 Ratio 
                 (% infection) 
                 Colby (%) 
               
               
                   
               
             
            
               
                 (Control) 
                 — 
                 — 
                 0 (90% infection) 
                 — 
               
               
                 No. I.1 
                 1 
                 — 
                 5 
                 — 
               
               
                 No. I.2 
                 1 
                 — 
                 52 
                 — 
               
               
                 epoxiconazole 
                 0.25 
                 — 
                 5 
                 — 
               
               
                 metrafenone 
                 4 
                 — 
                 0 
                 — 
               
               
                 No. I.1 + 
                 1 + 0.25 
                 4:1 
                 100 
                 9 
               
               
                 epoxiconazole 
               
               
                 No. I.1 + 
                 1 + 4   
                 1:4 
                 40 
                 5 
               
               
                 metrafenone 
               
               
                 No. I.2 + 
                 1 + 0.25 
                 4:1 
                 96 
                 55 
               
               
                 epoxiconazole 
               
               
                 No. I.2 + 
                 1 + 4   
                 1:4 
                 76 
                 52 
               
               
                 metrafenone 
               
               
                   
               
            
           
         
       
     
     USE EXAMPLE 3 
     Activity Against Net Blotch of Barley Caused by  Pyrenophora teres,  1 Day Protective Application 
     Leaves of potted barley seedlings were sprayed to runoff point with an aqueous suspension having the active compound concentration stated below. 24 hours after the spray coating had dried on, the test plants were inoculated with an aqueous spore suspension of  Pyrenophora  [syn.  Drechslera] teres , the net blotch pathogen. The test plants were then placed in a greenhouse at temperatures between 20 and 24° C. and at 95 to 100% relative atmospheric humidity. After 6 days, the extent of the development of the disease was determined visually in % infection of the entire leaf area. 
     
       
         
           
               
               
               
               
               
             
               
                   
               
               
                   
                   
                   
                   
                 Effect 
               
               
                   
                   
                   
                   
                 calculated 
               
               
                 Active 
                 Concen- 
                   
                   
                 according 
               
               
                 compound/Wirkstoff- 
                 tration 
                   
                 Observed effect 
                 to 
               
               
                 mischung 
                 [mg/l] 
                 Ratio 
                 (% infection) 
                 Colby (%) 
               
               
                   
               
             
            
               
                 (Control) 
                 — 
                 — 
                 0 (90% 
                 — 
               
               
                   
                   
                   
                 infection) 
               
               
                 No. I.2 
                 0.25 
                 — 
                 0 
                 — 
               
               
                 pyraclostrobin 
                 0.25 
                 — 
                 33 
                 — 
               
               
                 No. I.2 + 
                 0.25 + 0.25 
                 1:1 
                 72 
                 33 
               
               
                 pyraclostrobin 
               
               
                   
               
            
           
         
       
     
     USE EXAMPLE 4 
     Curative Activity Against Soybean Rust Caused by  Phakopsora pachyrhizi    
     Leaves of potted soybean seedlings of the cultivar “Oxford” were inoculated with a spore suspension of soybean rust ( Phakopsora pachyrhizi ). The pots were then placed in a chamber with high atmospheric humidity (90 to 95%) at 23 to 27° C. for 24 hours. During this time, the spores germinated and the germ tubes penetrated into the leaf tissue. After 2 days, the infected plants were sprayed to runoff point with the above-described active compound solution at the active compound concentration stated below. After the spray coating had dried on, the test plants were cultivated in a greenhouse at temperatures between 23 and 27° C. and at 60 to 80% relative atmospheric humidity for 14 days. The extent of the rust fungus development on the leaves was then determined. 
     
       
         
           
               
               
               
               
               
             
               
                   
               
               
                   
                   
                   
                   
                 Effect 
               
               
                   
                   
                   
                   
                 calculated 
               
               
                 Active 
                   
                   
                 Observed 
                 according 
               
               
                 compound/active 
                 Concentration 
                   
                 effect (%  
                 to 
               
               
                 compound mixture 
                 [mg/l] 
                 Ratio 
                 infection) 
                 Colby (%) 
               
               
                   
               
             
            
               
                 (Control) 
                 — 
                 — 
                 0 (90% 
                 — 
               
               
                   
                   
                   
                 infection) 
               
               
                 No. I.1 
                 0.25 
                 — 
                 29 
                 — 
               
               
                 pyraclostrobin 
                 0.25 
                 — 
                 29 
                 — 
               
               
                 No. I.1 + pyraclostrobin 
                 0.25 + 0.25 
                 1:1 
                 71 
                 49 
               
               
                   
               
            
           
         
       
     
     USE EXAMPLE 5 
     Activity Against the  Septoria  Leaf Spot Pathogen  Septoria tritici  in the Microtiter Test 
     For this test, the active compounds were formulated separately as a stock solution having a concentration of 10 000 ppm in dimethyl sulfoxide. 
     The stock solution was mixed according to the ratio, pipetted into a microtiter plate (MTP) and diluted with an aqueous malt-based fungus nutrient medium to the stated active compound concentration. An aqueous spore suspension of  Septoria tritici  was then added. The plates were placed in a water vapor-saturated chamber at temperatures of 18° C. Using an absorbtion photometer, the MTPs were measured at 405 nm on day 7 after the inoculation. 
     The measured parameters were compared to the growth of the active compound-free control variant (100%) and the fungus- and active compound-free blank value to determine the relative growth in % of the pathogens in the individual active compounds. 
     
       
         
           
               
               
               
               
               
             
               
                   
               
               
                 Active 
                   
                   
                   
                   
               
               
                 compound/ 
               
               
                 active 
                   
                   
                 Observed 
                 Effect calculated 
               
               
                 compound 
                 Concentration 
                   
                 effect 
                 according to 
               
               
                 mixture 
                 [mg/l] 
                 Ratio 
                 (% infection) 
                 Colby (%) 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
            
               
                 No. I.1 
                 1 
                 — 
                  0 
                 — 
               
               
                 dimethomorph 
                 4 
                 — 
                 20 
                 — 
               
               
                 No. I.1 + 
                 1 + 4 
                 1:4 
                 80 
                 20 
               
               
                 dimethomorph