Patent Publication Number: US-2017358767-A1

Title: Organic electroluminescence element

Description:
TECHNICAL FIELD 
     The present invention relates to an organic electroluminescent element. More specifically, the present invention relates to an organic electroluminescent element of high efficiency and long life. 
     BACKGROUND 
     In order to achieve an organic electroluminescence (EL) element of long life, it is known that one of the effective methods is to make a multi-unit type organic electroluminescent element (for example, refer to Non-patent document 1). 
     As applications of this organic electroluminescent element, there are many kinds of applications for outdoors as a single color light such as: an electric bulletin board, a traffic light, various lightings, a light for passenger car, motorbike, or bicycle, and a lighting source. From the viewpoint of efficiency, life, and reliability, LEDs, incandescent lamps, and fluorescent lamps have been used until now. 
     As a factor of decreased efficiency of an organic EL element and decreased light emission life with the same luminescence, the following are known. One is an absorption loss in which the emitting light from the light emitting layer located in the reflective electrode side is absorbed by the layer (in particular, organic layer) existing nearer to the transparent electrode than the light emitting layer that emits the light. The other is a light degradation of the materials produced when the emission light is absorbed by the materials such as emission dopants contained in the light emitting layer located nearer to the transparent electrode side than the light emitting layer that emits the light. 
     Particularly, in a multi-unit type organic electroluminescent element having an emitting light of the same emission color, the emitting light from the light emitting layer located in the reflective electrode side is absorbed by the emission dopant contained in the light emitting layer located in the light emitting layer nearer to the transparent electrode than the light emitting layer that emits the light. Further, by the light degradation of the dopant contained in the light emitting layer located in the transparent electrode side, decreased efficiency and decreased light emission life were produced. 
     PRIOR ART DOCUMENTS 
     Non-Patent Documents 
     Non-patent document 1: “Organic EL display” p. 51 (Ohmsha, Ltd.) 
     SUMMARY OF THE INVENTION 
     Problems to be Solved by the Invention 
     The present invention has been made in view of the above-described problems and situation. An object of the present invention is to provide an organic electroluminescent element of high efficiency and long life. 
     The present inventors have made investigation into the reasons of the above-described problems in order to solve the problems. As a result, it was found to provide an organic electroluminescent element of high efficiency and long life by making a constitution as follows: 
     a light emitting layer of a light emitting unit located in an N-th order from the semi-transparent electrode and a light emitting layer of a light emitting unit located in an (N+1)-th order from the semi-transparent electrode each contain an emission dopant to emit light of the same emission color; and 
     a largest maximum emission wavelength λ N(max)  in an EL spectrum of the emission dopant in the light emitting layer of the N-th light emitting unit and a largest maximum emission wavelength λ N+1(max)  in an EL spectrum of the emission dopant in the light emitting layer of the (N+1)-th light emitting unit were made to have a difference in a predetermined range. 
     Thus, the present invention was achieved. 
     That is, the above-described problems of the present invention are solved by the following embodiments. 
     1. An organic electroluminescent element comprising: a plurality of light emitting units interposed between a pair of a semi-transparent electrode and a reflective electrode; and a charge generating unit formed between the light emitting units, 
     wherein a light emitting layer of a light emitting unit located in an N-th order from the semi-transparent electrode and a light emitting layer of a light emitting unit located in an (N+1)-th order from the semi-transparent electrode each contain an emission dopant emitting light of the same emission color; and 
     a largest maximum emission wavelength λ N(max)  in an electroluminescent spectrum of the emission dopant in the light emitting layer of the N-th light emitting unit and a largest maximum emission wavelength λ N+1(max)  in an electroluminescent spectrum of the emission dopant in the light emitting layer of the (N+1)-th light emitting unit satisfy the following conditional expression (1). 
       1 nm≦λ N+1(max) −λ N(max) ≦50 nm.   Conditional expression (1):
 
     2. The organic electroluminescent element of the embodiment 1, 
     wherein an optical distance from the semi-transparent electrode to the light emitting layer of the N-th light emitting unit and an optical distance from the semi-transparent electrode to the light emitting layer of the (N+1)-th light emitting unit satisfy the following conditional expression (2). 
       1 nm≦ n   N+1   d   N+1 ×4/(2 m   N+1 +1)− n   N   d   N ×4/(2 m   N +1)≦50 nm, provided that  m   N   &lt;m   N+1 .   Conditional expression (2):
     (n N : a refractive index of the total layers interposed between the semi-transparent electrode and the light emitting layer of the N-th light emitting unit;   n N+1 : a refractive index of the total layers interposed between the semi-transparent electrode and the light emitting layer of the (N+1)-th light emitting unit;   d N  (nm) : an actual distance from the semi-transparent electrode to the light emitting layer of the N-th light emitting unit;   d N+1  (nm) : an actual distance from the semi-transparent electrode to the light emitting layer of the (N+1)-th light emitting unit;   m N : an integer of 0 or more; and   m N+1 : an integer of 1 or more.)   

     3. The organic electroluminescent element of the embodiments 1 or 2, 
     the largest maximum emission wavelength λ N(max)  in an electroluminescent spectrum of the emission dopant in the light emitting layer of the N-th light emitting unit and the largest maximum emission wavelength λ N+1(max)  in an electroluminescent spectrum of the emission dopant in the light emitting layer of the (N+1)-th light emitting unit satisfy the following conditional expression (3). 
       5 nm≦λ N+1(max) −λ N(max) ≦50 nm.   Conditional expression (3):
 
     4. The organic electroluminescent element of any one of the embodiments 1 to 3, 
     the largest maximum emission wavelength λ N(max)  in an electroluminescent spectrum of the emission dopant in the light emitting layer of the N-th light emitting unit and the largest maximum emission wavelength λ N+1(max)  in an electroluminescent spectrum of the emission dopant in the light emitting layer of the (N+1)-th light emitting unit satisfy the following conditional expression (4). 
       20 nm≦λ N+1(max) −λ N(max) ≦50 nm.   Conditional expression (4):
 
     5. An organic electroluminescent element of any one of the embodiments 1 to 4, 
     wherein all of the light emitting layers in the plurality of light emitting units contain the emission dopant having an emission light of the same emission color. 
     Effects of the Invention 
     By the above-described embodiments of the present invention, it is possible to provide an organic electroluminescent element of high efficiency and long life. 
     A formation mechanism or an action mechanism of the effects of the present invention is not clearly identified, but it is supposed as follows. 
       FIG. 1  illustrates an EL spectrum E N+1  of the emission dopant used in the light emitting layer of the (N+1)-th light emitting unit, an EL spectrum E N , and an absorption spectrum A N  of the emission dopant used in the light emitting layer of the N-th light emitting unit. An overlapped portion S is formed in a tail in the short wavelength side of the EL spectrum E N+1  and a tail in the long wavelength side of the absorption spectrum A N . 
     As describe above, the overlapped portion S illustrated in  FIG. 1  will be large in a known multi-unit type organic EL element emitting light of the same emission color. As a result, the emitting light from the light emitting layer located in the reflective electrode side is absorbed by the emission dopant contained in the light emitting layer located in the light emitting layer nearer to the transparent electrode than the light emitting layer that emits the light. Further, by the light degradation of the dopant contained in the light emitting layer located in the transparent electrode side, decreased efficiency and decreased light emission life were produced. 
     On the other hand, in the present invention, the largest maximum emission wavelength λ N(max)  in an EL spectrum of the emission dopant in the light emitting layer of the N-th light emitting unit and the largest maximum emission wavelength λ N+1(max)  in an EL spectrum of the emission dopant in the light emitting layer of the (N+1)-th light emitting unit were made to have a difference in a predetermined range by adjusting the optical distance from the light emitting layer of each light emitting unit to the semi-transparent electrode. By this, an area of the overlapped portion S was made small. As a result, the absorption loss of the emitting light from the light emitting layer of the (N+1)-th light emitting unit by the light emitting layer materials (including a host compound) was reduced. Further, the light degradation of the dopant material was restrained and this enabled to achieve an element of high efficiency and long life. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1  is a drawing illustrating an example of an EL spectrum and an absorption spectrum of an organic EL element of the present invention. 
         FIG. 2  is a schematic drawing illustrating an example of an organic EL element of the present invention. 
     
    
    
     EMBODIMENTS TO CARRY OUT THE INVENTION 
     An organic electroluminescent element of the present invention is characterized in the following: 
     a light emitting layer of a light emitting unit located in an N-th order from the semi-transparent electrode and a light emitting layer of a light emitting unit located in an (N+1)-th order from the semi-transparent electrode each contain an emission dopant emitting light of the same emission color; and 
     a largest maximum emission wavelength λ N(max)  in an EL spectrum of the emission dopant in the light emitting layer of the N-th light emitting unit and a largest maximum emission wavelength λ N+1(max)  in an EL spectrum of the emission dopant in the light emitting layer of the (N+1)-th light emitting unit satisfy the conditional expression (1). 
     These features are technical features commonly owned by the invention according to the above-described embodiments. 
     As an embodiment of the present invention, from the viewpoint of improving a light extraction efficiency, it is preferable that an optical distance from the semi-transparent electrode to the light emitting layer of the N-th light emitting unit and an optical distance from the semi-transparent electrode to the light emitting layer of the (N+1)-th light emitting unit satisfy the conditional expression (2). 
     From the viewpoint of improving a light emission efficiency and emission life, it is preferable that the largest maximum emission wavelength λ N(max)  in an EL spectrum of the emission dopant in the light emitting layer of the N-th light emitting unit and the largest maximum emission wavelength λ N+1(max)  in an EL spectrum of the emission dopant in the light emitting layer of the (N+1)-th light emitting unit satisfy the conditional expression (3). It is more preferable that these maximum emission wavelengths satisfy the conditional expression (4). 
     Further, from the viewpoint of acquiring a device of small color shift and high reliability, it is preferable that all of the light emitting layers in a plurality of light emitting units contain an emission dopant to emit light of the same emission color. 
     The present invention and the constitution elements thereof, as well as configurations and embodiments, will be detailed in the following. In the present description, when two figures are used to indicate a range of value before and after “to”, these figures themselves are included in the range as a lowest limit value and an upper limit value. 
     &lt;&lt;Constitution of Organic EL Element&gt;&gt; 
     An organic electroluminescent element of the present invention contains: a plurality of light emitting units interposed between a pair of a semi-transparent electrode (it is also called as an anode) and a reflective electrode (it is also called as a cathode); and a charge generating unit formed between the light emitting units. 
     It is characterized in that: a light emitting layer of a light emitting unit located in an N-th order from the semi-transparent electrode and a light emitting layer of a light emitting unit located in an (N+1)-th order from the semi-transparent electrode each contain an emission dopant emitting light of the same emission color; and 
     a largest maximum emission wavelength λ N(max)  in an EL spectrum of the emission dopant in the light emitting layer of the N-th light emitting unit and a largest maximum emission wavelength λ N+1(max)  in an EL spectrum of the emission dopant in the light emitting layer of the (N+1)-th light emitting unit satisfy the following conditional expression (1). 
       1 nm≦λ N+1(max) −λ N(max) ≦50 nm.   Conditional expression (1):
 
     As a method of achieving this property, it is possible to control the difference by changing the emission dopant contained in the light emitting layer of the N-th light emitting unit and the emission dopant contained in the light emitting layer of the (N+1)-th light emitting unit so as to have a longer wavelength of the EL spectrum of the light emitting layer of the (N+1)-th light emitting unit. 
     A preferable embodiment of the organic electroluminescent element of the present invention is as follows: an optical distance from the semi-transparent electrode to the light emitting layer of the N-th light emitting unit and an optical distance from the semi-transparent electrode to the light emitting layer of the (N+1)-th light emitting unit satisfy the following conditional expression (2). 
       1 nm≦ n   N+1   d   N+1 ×4/(2 m   N+1 +1)− n   N   d   N ×4/(2 m   N +1)≦50 nm, provided that  m   N   &lt;m   N+1 .   Conditional expression (2):
     (n N : a refractive index of the total layers interposed between the semi-transparent electrode and the light emitting layer of the N-th light emitting unit;   n N+1 : a refractive index of the total layers interposed between the semi-transparent electrode and the light emitting layer of the (N+1)-th light emitting unit;   d N (nm) : an actual distance from the semi-transparent electrode to the light emitting layer of the N-th light emitting unit;   d N+1 (nm) : an actual distance from the semi-transparent electrode to the light emitting layer of the (N+1)-th light emitting unit;   m N : an integer of 0 or more; and   m N+1 : an integer of 1 or more.)   

     The present invention will be described by taking an organic EL element having two light emitting units as an example. 
     An organic EL element  1  illustrated in  FIG. 2  is composed of: a semi-transparent electrode  2 ; a first light emitting unit  4 ; a charge generating unit  6 ; a second light emitting unit  8 ; and a reflective electrode  10 . The first light emitting unit  4  and the second light emitting unit  8  each respectively contain: a layer  4   a  and a layer  8   a  having a hole transport property composed of a hole injection layer, a hole transport layer, and an electron blocking layer; and a light emitting layer  4   b  and a light emitting layer  8   b ; and a layer  4   c  and a layer  8   c  having an electron transport property composed of a hole blocking layer, an electron transport layer, and an electron injection layer. 
     The organic EL element  1  contains a luminescent organic material in the light emitting layers  4   b  and  8   b . It is a light emitting element containing a plurality of light emitting layers having the emission dopant to emit light of the same emission color selected from Blue (B) , Green (G) , and Red (R) as an luminescent organic material. 
     The organic EL element  1  is a so-called bottom emission type having a constitution in which light is extracted from the side of the semi-transparent electrode  2 . 
     When the emitting light from the light emitting layers  4   b  and  8   b  enters the semi-transparent electrode  2 , the reflective light of that light will be phase-reversed. By this, interference of light will occur. In this case, when an optical distance (refractive ratio n 1 ×actual distance d 1 ) from the light emitting layer  4   b  to the semi-transparent electrode  2 , and an optical distance (refractive ratio n 2 ×actual distance d 2 ) from the light emitting layer  8   b  to the semi-transparent electrode  2  are (2m+1)/4 times of the emitting light (m is any integer of 0 or more), that is, when the optical distance is 1/4, 3/4, 5/4, and the following, the extraction efficiency of the emitting light will be high. On the other hand, when the optical distance is m/2 (m is any integer of 1 or more) times, that is, 1/2, 1, 3/2, and the following, the extraction efficiency of the emitting light will be low. 
     Therefore, an organic EL element of the present invention was made to improve the extraction efficiency of the emitting light by adjusting the following. 
     Optical distances of n 1 d 1  and n 2 d 2 , each respectively representing an optical distance from the semi-transparent electrode  2  to the light emitting layer  4   b , and a distance from the semi-transparent electrode  2  to the light emitting layer  8   b , were made to be (2m+1)/4 times of the emitting wavelength of the emission dopant. 
     At the same time, a largest maximum emission wavelength λ 1(max)  in an EL spectrum of the emission dopant in the light emitting layer  4   b  is made to be a shorter wavelength in the range of 1 to 50 nm than a largest maximum emission wavelength λ 2(max)  in an EL spectrum of the emission dopant in the light emitting layer  8   b.    
     An optical distance is adjusted by changing the layer thickness of any layer located between the light emitting layer and the semi-transparent electrode. For examples, it is adjusted by changing the layers  4   a  and  8   a  each having a hole transport property, the light emitting layer  4   b , or the layer  4   c  having an electron transport property. 
     In the present invention, a refractive ratio and an optical distance are measured and analyzed by considering that all of the layers interposed from the semi-transparent electrode to the light emitting layer to be one layer. 
     A refractive ratio and a layer thickness may be measured by using a spectroscopic ellipsometer (UVSEL/FUV-FGMS, made by HORIBA JYOBIN-YVON) and a refractive spectroscopic film thickness meter (FE3000, made by Otsuka Electronics, Co. Ltd.) 
     Analysis is made in the wavelength range of 500 to 800 nm, and Cauchy is carried out (n (refractive ratio) : variable, k (attenuation factor): none, fixed value) to measure a refractive ratio and a layer thickness. 
     A refractive ratio and a layer thickness may be measured by forming a target layer to be measured on a silicon wafer. Otherwise, the prescribed layer portion may be separated with a focused ion beam (FIB) after producing a panel. 
     A preferable organic EL element of the present invention is provided with the following property: the largest maximum emission wavelength in the EL spectrum of the emission dopant in the light emitting layer of the N-th light emitting unit is shorter by 5 to 50 nm than the largest maximum emission wavelength in the EL spectrum of the emission dopant in the light emitting layer of the (N+1)-th light emitting unit. More preferably, it is shorter by 20 to 50 nm. 
     It is preferable that all of the light emitting layers in the plurality of light emitting units of the organic EL element contain the emission dopant having an emission light of the same emission color. 
     N is preferably an integer of 1 to 4. 
     An organic EL element of the present invention may prevent Forster transition due to the sufficient separation of each light emitting unit by the charge generating unit. Therefore, it may be increased color purity of the same emission color. 
     Representative element constitutions of an organic EL element of the present invention are indicated in the following, however, the present invention is not limited to these.
     (I) Semi-transparent electrode/first light emitting unit/charge generating unit/second light emitting unit/reflective electrode   (II) Semi-transparent electrode/first light emitting unit/charge generating unit/second light emitting unit/charge generating unit/third light emitting unit/reflective electrode   (III) Semi-transparent electrode/first light emitting unit/charge generating unit/second light emitting unit/charge generating unit/third light emitting unit/charge generating unit/fourth light emitting unit/reflective electrode   (IV) Semi-transparent electrode/first light emitting unit/charge generating unit/second light emitting unit/charge generating unit/third light emitting unit/charge generating unit/fourth light emitting unit/charge generating unit/fifth light emitting unit/reflective electrode   

     Specific examples of a preferable layer constitution of each light emitting unit are indicated below, however, the present invention is not limited to these.
     (i) (Semi-transparent electrode side)/light emitting layer/electron transport layer/(reflective electrode side)   (ii) (Semi-transparent electrode side)/hole transport layer/light emitting layer/electron transport layer/(reflective electrode side)   (iii) (Semi-transparent electrode side)/hole transport layer/light emitting layer/electron transport layer/electron injection layer/(reflective electrode side)   (iv) (Semi-transparent electrode side)/hole injection layer/hole transport layer/light emitting layer/electron transport layer/electron injection layer/(reflective electrode side)   

     It may be placed a hole blocking layer between a light emitting layer and a reflective electrode or a charge generating unit when required. Further, it may be placed an electron blocking layer (it is also called as an electron barrier layer) between a light emitting layer and a semi-transparent electrode or a charge generating unit. 
     In addition, it may be formed a different second or third hole transport layer or electron transport layer. 
     In the above-described element constitutions, the embodiments of N being 1 to 4 are described. That is, the embodiments having light emitting units of 2 to 5 are described. However, the number of the light emitting units may be 6 or more. 
     The present invention is characterized in that a light emitting layer of a light emitting unit located in an N-th order from the semi-transparent electrode and a light emitting layer of a light emitting unit located in an (N+1)-th order from the semi-transparent electrode each contain an emission dopant to emit light of the same emission color. Here, “the same emission color” indicates a color belonging to the same color type. For example, light of red color is a red color light in the wavelength range of about 550 to 700 nm. A light of green color is a green color light in the wavelength range of about 480 to 600 nm. A light of blue color is a blue color light in the wavelength range of about 400 to 530 nm. Preferably, the lights of the same emission color each have a difference of a largest emission maximum wavelength of 50 nm or less in an absolute value with each other. 
     In the following, it will be described in detail the constituting members of an organic EL element of the present invention such as: a semi-transparent electrode, a first light emitting unit, a charge generating unit, a second light emitting unit, and a reflective electrode. Further, it will be described a substrate on which is placed an organic EL element of the present invention. In addition, each constitution of an organic EL element of the present invention described below is only an example. It may be suitably applied other constitution within the range enabling to constitute the above-described organic EL element. 
     &lt;Light Emitting Unit&gt; 
     An organic EL element of the present invention contains the two light emitting layers which are placed adjacently and emit light of the same emission color. When the organic EL element has three or more light emitting layers, it is preferable that all of the light emitting layers emit light of the same emission color. 
     A light emitting unit may contain the following organic layers according to circumstances in addition to a light emitting layer: a hole injection layer, a hole transport layer, an electron blocking layer, a hole blocking layer, an electron transport layer, and an electron injection layer. 
     (Light Emitting Layer) 
     A light emitting layer is a layer which provide a place of emitting light via an exciton produce by recombination of electrons and holes injected from an electrode or an adjacent layer. The light emitting portion may be either within the light emitting layer or at an interface between the light emitting layer and an adjacent layer thereof. 
     It is preferable that a light emitting layer contains at least one kind of organic light emitting material. 
     The light emitting layer may contain a mixture of a phosphorescent material and a fluorescent material. However, preferably, the light emitting layer is composed of a phosphorescent material only or a phosphorescent material only. 
     The fluorescence emitting layer and the phosphorescent emitting each are preferably a light emitting layer of host-dopant type. 
     Any number of layers may be used for constituting a light emitting layer. It may be contained a plurality of constituting layers having the same emitting spectrum and the same emission maximum wavelength. 
     A total thickness of the light emitting layer is not particularly limited. However, in view of layer homogeneity, required voltage during light emission, and stability of the emitted light color against a drive electric current, the total layer thickness is preferably adjusted to be in the range of 5 to 200 nm, more preferably, it is in the range of 10 to 150 nm. Each light emitting layer is preferably adjusted to be in the range of 5 to 200 nm, more preferably, it is in the range of 10 to 40 nm. 
     (1) Emission Dopant 
     As an emission dopant, it is preferable to employ: a fluorescence emitting dopant (also referred to as a fluorescent dopant and a fluorescent compound) and a phosphorescence emitting dopant (also referred to as a phosphorescent dopant and a phosphorescent emitting material). A concentration of a light emitting compound in a light emitting layer may be arbitrarily decided based on the specific compound employed and the required conditions of the device. A concentration of a light emitting compound may be uniform in a thickness direction of the light emitting layer, or it may have any concentration distribution. 
     The light emitting layer may contain other material than the host compound and the emission dopant. This material is served as an assist-dopant and aids the light emission. 
     (1.1) Phosphorescence Emitting Dopant 
     The phosphorescence emitting dopant is a compound which is observed emission from an excited triplet state thereof. Specifically, it is a compound which emits phosphorescence at a room temperature (25° C.) and exhibits a phosphorescence quantum yield of at least 0.01 at 25° C. The phosphorescence quantum yield is preferably at least 0.1. 
     The phosphorescence quantum yield will be determined via a method described in page 398 of Bunko II of Dai 4 Han Jikken Kagaku Koza 7 (Spectroscopy II of 4th Edition Lecture of Experimental Chemistry 7) (1992, published by Maruzen Co. Ltd.). The phosphorescence quantum yield in a solution will be determined using appropriate solvents. However, it is only necessary for the phosphorescent dopant of the present invention to exhibit the above phosphorescence quantum yield (0.01 or more) using any of the appropriate solvents. 
     Two kinds of principles regarding emission of a phosphorescent dopant are cited. One is an energy transfer-type, wherein carriers recombine on a host compound on which the carriers are transferred to produce an excited state of the host compound, and then via transfer of this energy to a phosphorescent dopant, emission from the phosphorescence-emitting dopant is realized. The other is a carrier trap-type, wherein a phosphorescence-emitting dopant serves as a carrier trap and then carriers recombine on the phosphorescent dopant to generate emission from the phosphorescent dopant. In each case, the excited state energy level of the phosphorescent dopant is required to be lower than that of the host compound. 
     A phosphorescence dopant may be suitably selected and employed from the known materials used for a light emitting layer for an organic EL element. 
     Examples of a known phosphorescence dopant are compounds described in the following publications. 
     Nature 395, 151 (1998), Appl. Phys. Lett. 78, 1622 (2001), Adv. Mater. 19, 739 (2007), Chem. Mater. 17, 3532 (2005), Adv. Mater. 17, 1059 (2005), WO 2009/100991, WO 2008/101842, WO 2003/040257, US 2006/835469, US 2006/0202194, US 2007/0087321, US 2005/0244673, Inorg. Chem. 40, 1704 (2001), Chem. Mater. 16, 2480 (2004), Adv. Mater. 16, 2003 (2004), Angew. Chem. Int. Ed. 2006, 45, 7800, Appl. Phys. Lett. 86, 153505 (2005), Chem. Lett. 34, 592 (2005) , Chem. Commun. 2906 (2005) , Inorg. Chem. 42, 1248 (2003), WO 2009/050290, WO 2002/015645, WO 2009/000673, US 2002/0034656, U.S. Pat. No. 7,332,232, US 2009/0108737, US 2009/0039776, U.S. Pat. No. 6,921,915, U.S. Pat. No. 6687266, US 2007/0190359, US 2006/0008670, US 2009/0165846, US 2008/0015355, U.S. Pat. No. 7250226, U.S. Pat. No. 7,396,598, US 2006/0263635, US 2003/0138657, US 2003/0152802, U.S. Pat. No. 7,090,928, Angew. Chem. Int. Ed. 47, 1 (2008), Chem. Mater. 18, 5119 (2006), Inorg. Chem. 46, 4308 (2007), Organometallics 23, 3745 (2004) , Appl. Phys. Lett. 74, 1361 (1999), WO 2002/002714, WO 2006/009024, WO 2006/056418, WO 2005/019373, WO 2005/123873, WO 2005/123873, WO 2007/004380, WO 2006/082742, US 2006/0251923, US 2005/0260441, U.S. Pat. No. 7,393,599, U.S. Pat. No. 7,534,505, U.S. Pat. No. 7,445,855, US 2007/0190359, US 2008/0297033, U.S. Pat. No. 7,338,722, US 2002/0134984, U.S. Pat. No. 7,279,704, US 2006/098120, US 2006/103874, WO 2005/076380, WO 2010/032663, WO 2008/140115, WO 2007/052431, WO 2011/134013, WO 2011/157339, WO 2010/086089, WO 2009/113646, WO 2012/020327, WO 2011/051404, WO 2011/004639, WO 2011/073149, US 2012/228583, US 2012/212126, JP-A 2012-069737, JP-A 2012-195554, JP-A 2009-114086, JP-A 2003-81988, JP-A 2002-302671 and JP-A 2002-363552. 
     In particular, preferable phosphorescence emitting dopants are compounds represented by Formulas (4) , (5) , or (6) described in paragraphs [0185] to [0235] of JP-A 2013-4245, and exemplified compounds (Pt-1 to Pt-3, Os-1, and Ir-1 to Ir-45). 
     Among them, preferable phosphorescence emitting dopants are organic metal complexes containing Ir as a center metal. More preferable are complexes containing at least one coordination mode selected from a metal-carbon bond, a metal-nitrogen bond, a metal-oxygen bond and a metal-sulfur bond. 
     (1.2) Fluorescence Emitting Dopant 
     The fluorescence emitting dopant is a compound which is observed emission from an excited singlet state thereof. The compound is not limited as long as emission from an excited singlet state is observed. 
     As specific known fluorescence emitting dopants usable in the present invention, listed are compounds such as: an anthracene derivative, a pyrene derivative, a chrysene derivative, a fluoranthene derivative, a perylene derivative, a fluorene derivative, an arylacetylene derivative, a styrylarylene derivative, a styrylamine derivative, an arylamine derivative, a boron complex, a coumarin derivative, a pyran derivative, a cyanine derivative, a croconium derivative, a squarylium derivative, an oxobenzanthracene derivative, a fluorescein derivative, a rhodamine derivative, a pyrylium derivative, a perylene derivative, a polythiophene derivative, and a rare earth complex compound. 
     In addition, it may be used an emission dopant utilizing delayed fluorescence. Specific examples of utilizing delayed fluorescence are compounds described in: WO 2011/156793, JP-A 2011-213643, and JP-A 2010-93181. However, the present invention is not limited to them. 
     (2) Host Compound 
     A host compound is a compound which mainly plays a role of injecting or transporting a charge in a light emitting layer. In an organic EL element, an emission from the host compound itself is substantially not observed. 
     Preferably, it is a compound exhibiting a phosphorescent emission yield of less than 0.1 at a room temperature (25° C.), more preferably a compound exhibiting a phosphorescent emission yield of less than 0.01. Among the compounds incorporated in the light emitting layer, a mass ratio of the host compound in the light emitting layer is preferably at least 20%. 
     It is preferable that the excited energy level of the host compound is higher than the excited energy level of the dopant contained in the same layer. 
     Host compounds may be used singly or may be used in combination of two or more compounds. By using a plurality of host compounds, it is possible to adjust transfer of charge, thereby it is possible to achieve an organic EL element of high efficiency. 
     A host compound used in a light emitting layer is not specifically limited. A known compound previously used in an organic EL element may be used. It may be a compound having a low molecular weight, or a polymer having a high molecular weight. Further, it may be a compound having a reactive group such as a vinyl group or an epoxy group. 
     As a known host compound, preferably, it has a hole transporting ability or an electron transporting ability, as well as preventing elongation of an emission wavelength. In addition, from the viewpoint of stably driving an organic EL element at high temperature, it is preferable that a host compound has a high glass transition temperature (T) of 90° C. or more, more preferably, has a Tg of 120° C. or more. 
     Here, a glass transition temperature (Tg) is a value obtained using DSC (Differential Scanning Colorimetry) based on the method in conformity to JIS-K-7121. 
     A host compound in a light emitting layer incorporating a phosphorescent dopant preferably has a lowest excited triplet level (T 1 ) of 2.1 eV or larger. When T 1  is 2.1 eV or larger, light emission of high efficiency may be obtained. The lowest excited triplet level (T 1 ) is a peak energy corresponding to the band transition of the lowest vibration in a phosphorescent spectrum of a host compound solution dissolved in a solvent measured at a liquid nitrogen temperature or a liquid helium temperature. 
     As specific examples of a known host compound used in an organic EL element of the present invention, the compounds described in the following Documents are cited. However, the present invention is not to them. 
     Japanese patent application publication (JP-A) Nos. 2001-257076, 2002-308855, 2001-313179, 2002-319491, 2001-357977, 2002-334786, 2002-8860, 2002-334787, 2002-15871, 2002-334788, 2002-43056, 2002-334789, 2002-75645, 2002-338579, 2002-105445, 2002-343568, 2002-141173, 2002-352957, 2002-203683, 2002-363227, 2002-231453, 2003-3165, 2002-234888, 2003-27048, 2002-255934, 2002-260861, 2002-280183, 2002-299060, 2002-302516, 2002-305083, 2002-305084 and 2002-308837; US Patent Application Publication (US) Nos. 2003/0175553, 2006/0280965, 2005/0112407, 2009/0017330, 2009/0030202, 2005/0238919; WO 2001/039234, WO 2009/021126, WO 2008/056746, WO 2004/093 207, WO 2005/089025, WO 2007/063796, WO 2007/063754, WO 2004/107822, WO 2005/030900, WO 2006/114966, WO 2009/086028, WO 2009/003898, WO 2012/023947, JP-A 2008-074939, JP-A 2007-254297, and EP 2034538. However, the host compounds in the present invention are not limited to them. 
     (Hole Injection Layer) 
     A hole injection layer (it is also called as “an anode buffer layer”) is a layer which is arranged between an anode and a light emitting layer to decrease an operating voltage and to improve an emission luminance. An example of a hole injection layer is detailed in volume 2, chapter 2 “Electrode materials” (pp. 123-166) of “Organic EL Elements and Industrialization Front thereof (Nov. 30, 1998, published by N.T.S. Co. Ltd.)”. 
     A hole injection layer is provided according to necessity, and as described above, it is placed between an anode and a light emitting layer, or between an anode or a charge generating layer and a light emitting layer or a hole transport layer. 
     A hole injection layer is also detailed in JP-A Nos. 9-45479, 9-260062 and 8-288069. 
     (1) Compound Having a Structure Represented by Formula (1) 
     As a constituting material for a hole injection layer, it may be suitably used a compound having a structure represented by Formula (1) described below. 
     
       
         
         
             
             
         
       
     
     In Formula (1), A represents C or N. X represents N or CR°. R° represents one selected from the group consisting of: a hydrogen atom, a halogen atom, a cyano group, a nitro group, a formyl group, an acetyl group, a benzoyl group, an amide group (—CONHR 1  or —CONR 1 R 2 ), a styryl group, an ethynyl group, a quinolyl group, a quinazolyl group, a phenanthrolyl group, a biquinolyl group, an anthraquinonyl group, a benzoquinonyl group, a quinonyl group, an acridinyl group, a substituted or unsubstituted alkyl group, aryl group, aralkyl group, alkylamino group, arylamino group, aralkylamino group, and heterocyclic group. R 1  and R 2  each independently represent: a substituted or unsubstituted al group having 1 to 60 carbon atoms, aryl group, or 5 to 7 membered heterocyclic group. Y, Y′ and Y″ each represent a substituted or unsubstituted 5 membered aromatic heterocyclic group including A and X as a ring member, or a substituted or unsubstituted 6 membered aromatic heterocyclic group including A and X as a ring member. Y, Y′ and Y″ may be the same or different with each other. 
     An alkyl group represented by R° in Formula (1) has preferably 1 to 20 carbon atoms. Examples thereof are: a straight alkyl group such as a methyl group, an ethyl group, a propyl group, and a hexyl group, and a branched alkyl group such as an isopropyl group, and a t-butyl group. 
     As an arylkyl group, it may be cited: a monocyclic aromatic hydrocarbon ring group such as a phenyl group; and a polycyclic aromatic hydrocarbon ring group such as a naphthyl group, an anthracenyl group, a pyrenyl group, and a perylenyl group. 
     As an aralkyl group, it may be cited: an alkyl group having 1 to 20 carbon atoms substituted with an aromatic hydrocarbon ring group such as a phenyl group, a biphenyl group, a naphthyl group, a terphenyl. group, an anthracenyl group, a pyrenyl group, or a perylenyl group. 
     As an alkylamino group, it may be cited: an amino group substituted with an aliphatic hydrocarbon group having 1 to 20 carbon atoms. 
     As an arylamino group, it may be cited: an amino group substituted with an aromatic hydrocarbon ring group such as a phenyl group, a biphenyl group, a naphthyl group, a terphenyl group, an anthracenyl group, a pyrenyl group, or a perylenyl group. 
     As an aralkylamino group, it may be cited: an amino group substituted with an aromatic hydrocarbon ring group such as a phenyl group, a biphenyl group, naphthyl group, terphenyl group, an anthracenyl group, a pyrenyl group, a perylenyl group, or an a phatic hydrocarbon group having 1 to 20 carbon atoms 
     As a heterocycic group, it may be cited: a pyrrolyl group, a thienyl group, an indolyl group, an oxazolyl group, an imidazolyl group, a thiazolyl group, a pyridyl group, a pyrimidinyl group, a piperazinyl group, a thiophenyl group, a furanyl group, and a pyridazinyl group. 
     As an alkyl group having 1 to 60 carbon atoms represented by R 1  or R 2  in Formula (1) , it may be cited: a straight alkyl group such as a methyl group, an ethyl group, a propyl group, and a hexyl group, and a branched alkyl group such as an isopropyl group, and a t-butyl group. 
     As an aryl group, it may be cited: a monocyclic aromatic hydrocarbon ring group such as a phenyl group; and a polycyclic aromatic hydrocarbon ring group such as a naphthyl group, an anthracenyl group, a pyrenyl group, and. a perlenyl group. 
     As a 5 to 7 membered heterocyclic group, it may be cited: a pyrrolyl group, a thienyl group, an indolyl group, an oxazolyl group, an imidazolyl group, a. thiazolyl group, a pyridyl group, a pyrimidinyl group, a piperazinyl group, a thiophenyl group, a furanyl group, and a pyridazinyl group. 
     As a 5 membered aromatic heterocyclic ring represented by Y, Y′ and Y″ in Formula (1) , it may be cited: a pyrazole ring, an imidazole ring, a triazole ring, an oxazole ring, an isoxazole ring, an indole ring, a triazole ring, a benzimidazole ring, a benzop razole ring, a benzothiazole ring, a benzozazole ring, and a benzisoxazole ring. 
     As a 6 membered aromatic heterocyclic ring, it may be cited: a pyridine ring, a pyridazine ring, a pyrimidine ring, a pyrazine ring, and a triazine ring. 
     In Formula (1) , R 0  to R 2 , Y, Y′, and Y″ may have a substituent. Examples of a substituent include: a straight or a branched alkyl group (for example, a methyl group, an ethyl group, a propyl group, an isopropyl group, a t-butyl group, a pentyl group, a hexyl group, an octyl group, a dodecyl group, a tridecyl group, a tetradecyl group, and a pentadecyl group); an alkenyl group (for example, a vinyl group, and an allyl group); an alkynyl group (for example, an ethynyl group and a propargyl group); an aromatic hydrocarbon ring group (also called an aromatic carbon ring group or an aryl group, for example, a group derived from a benzene ring, a biphenyl ring, a naphthalene ring, an azulene ring, an anthracene ring, a phenanthrene ring, a pyrene ring, a chrysene ring, a naphthacene ring, a triphenylene ring, an o-terphenyl ring, a m-terphenyl ring, a p-terphenyl ring, an acenaphthene ring, a coronene ring, an indene ring, a fluorene ring, a fluoranthene ring, a naphthacene ring, a pentacene ring, a perylene ring, a pentaphene ring, a picene ring, a pyrene ring, a pyranthrene ring, an anthanthrene ring, or a tetralin ring); an aromatic heterocyclic group (for example, a group derived from a furan ring, a dibenzofuran ring, a thiophene ring, a dibenzothiophene ring, an oxazole ring, a pyrrole ring, a pyridine ring, a pyridazine ring, a pyrimidine ring, a pyrazine ring, a triazine ring, a benzimidazole ring, an oxadiazole ring, a triazole ring, an imidazole ring, a pyrazole ring, thiazole ring, an indole ring, an indazole ring, a benzimidazole ring, a benzothiazole ring, a benzoxazole ring, a quinoxaline ring, quinazoline ring, cinnoline ring, a quinoline ring, an isoquinoline ring, a phthalazine ring, a naphthyridine ring, a carbazole ring, a carboline ring, or a diazacarbazole ring (indicating a ring structure in which one of the carbon atoms constituting the carboline ring of the carbolinyl group is replaced with nitrogen atoms, a carboline ring and a diazacarbazole ring may be called as an azacarbazole ring) ; a non-aromatic hydrocarbon ring group (for example, a cyclopentyl group, and a cyclohexyl group); a non-aromatic heterocyclic group (for example, a pyrrolidyl group, an imidazolidyl group, a morpholyl group, and an oxazolidyl group); an alkoxy group (for example, a methoxy group, an ethoxy group, a propyloxy group, a pentyloxy group, an hexyloxy group, an octyloxy group, and a dodecyloxy group); a cycloalkoxy group (for example, a cyclopentyloxy group and a cyclohexyloxy group); an aryloxy group (for example, a phenoxy group and a naphthyloxy group); an alkylthio group (for example, a methylthio group, an ethylthio group, a propylthio group, a pentylthio group, a hexylthio group, an octylthio group, and a dodecylthio group); a cycloalkylthio group (for example, a cyclopentylthio group and a cyclohexylthio group); an arylthio group (for example, a phenylthio group and a naphthylthio group); an alkoxycarbonyl group (for example, a methyloxycarbonyl group, an ethyloxycarbonyl group, a butyloxycarbonyl group, an octyloxycarbonyl group, and a dodecyloxycarbonyl group); an aryloxycarbonyl group (for example, a phenyloxycarbonyl group and a naphthyloxycarbonyl group); a sulfamoyl group (for example, an aminosulfonyl group, a methylaminosulfonyl group, a dimethylaminosulfonyl group, a butylaminosulfonyl group, a hexylaminosulfonyl group, a cyclohexylaminosulfonyl group, an octylaminosulfonyl group, a dodecylaminosulfonyl group, a phenylaminosulfonyl group, a naphthylaminosulfonyl group, and a 2-pyridylaminosulfonyl group); an acyl group (for example, an acetyl group, an ethylcarbonyl group, a propylcarbonyl group, a pentylcarbonyl group, a cyclohexylcarbonyl group, an octylcarbonyl group, a 2-ethylhexylcarbonyl group, a dodecylcarbonyl group, a phenylcarbonyl group, a naphthylcarbonyl group, and a pyridylcarbonyl group); an acyloxy group (for example, an acetyloxy group, an ethylcarbonyloxy group, a butylcarbonyloxy group, an octylcarbonyloxy group, a dodecylcarbonyloxy group, and a phenylcarbonyloxy group); an amido group (for example, a methylcarbonylamino group, an ethylcarbonylamino group, a dimethylcarbonylamino group, a propylcarbonylamino group, a pentylcarbonylamino group, a cyclohexylcarbonylamino group, a 2-ethyhexylcarbonylamino group, an octylcarbonylamino group, a dodecylcarbonylamino group, a phenylcarbonylamino group, and a naphthylcarbonylamino group); a carbamoyl group (for example, an aminocarbonyl group, a methylaminocarbonyl group, a dimethylaminocarbonyl group, a propylaminocarbonyl group, a pentylaminocarbonyl group, a cyclohexylaminocarbonyl group, an octylaminocarbonyl group, a 2-ethymexylaminocarbonyl group, a dodecylaminocarbonyl group, a phenylaminocarbonyl group, a naphthylaminocarbonyl group, and a 2-pyridylaminocarbonyl group); a ureido group (for example, a methylureido group, an ethylureido group, a pentylureido group, a cyclohexylureido group, an octylureido group, a dodecylureido group, a phenylureido group, a naphthylureido group, and a 2-pyridylaminoureido group); a sulfinyl group (for example, a methylsulfinyl group, an ethylsufinyl group, a butylsulfinyl group, a cyclohexylsulfinyl group, a 2-ethylhexylsulfinyl group, a dodecylsulfinyl group, a phenylsulfinyl group, a naphthylsulfinyl group, and a 2-pyridylsulfinyl group); an alkylsulfonyl group (for example, a methylsulfonyl group, an ethylsulfonyl group, a butylsulfinyl group, a cyclohexylsulfonyl group, a 2-ethylhexylsulfonyl group, and a dodecylsulfonyl group), an arylsulfonyl group or a heteroarylsulfonyl group (for example, a phenylsulfonyl group, a naphthylsulfonyl group, and a 2-pyridylsulfonyl group); an amino group (for example, an amino group, an ethylamino group, a dimethylamino group, a butylamino group, a cyclopentylamino group, a dodecylamino group, an anilino group, a naphthylamino group, and a 2-pyridylamino group); a halogen atom (for example, a fluorine atom, a chlorine atom and a bromine atom); a fluorinated hydrocarbon group (for example, a fluoromethyl group, trifluoromethyl group, a pentafluoroethyl group and a pentafluorophenyl group); a cyano group; a nitro group; a hydroxyl group; a mercapto group; a silyl group (for example, a trimethylsilyl group, a triisopropylsilyl group, a triphenylsilyl group, and a phenyldiethylsilyl group), and a deuterium atom. 
     A compound having a structure represented by Formula (1) is preferably a compound having a structure represented by Formula (2) described below. 
     
       
         
         
             
             
         
       
     
     In Formula (2) , R 3  to R 8  each independently represent one selected from the group consisting of: a hydrogen atom, a halogen atom, a cyano group, a nitro group, a sulfonyl group (—SO 2 R 9 ) , a sulfinyl group (—SOR 9 ) , a sulfonamido group (—SO 2 NR 9 R 10 ) , a sulfonato group (—S 3 R 9 ) , a trifluoromethyl group, an ester group (—COOR 9 ) , an amide group (—CONHR 9  or —CONR 9 R 10 ), a substituted or unsubstituted straight or branched alkoxy group having 1 to 12 carbon atoms, a substituted or unsubstituted straight or branched alkyl group having 1 to 12 carbon atoms, aromatic hydrocarbon ring group, arylamino group, non-aromatic heterocyclic group, aromatic heterocyclic group, and aralkylamino group. R 9  and R 10  each independently represent: a substituted or unsubstituted alkyl group having 1 to 60 carbon atoms, aryl group, or 5 to 7 membered heterocyclic group. 
     R 9  and R 10  in Formula (2) are synonymous with R 1  and R 2  in Formula (2). 
     R 9  and R 10  in Formula (2) may be substituted with a substituent. As a substituent, the same substituent cited for Formula (1) may be cited. 
     A compound having a structure represented by Formula (1) is preferably a compound having a structure represented by Formula (3) described below. 
     
       
         
         
             
             
         
       
     
     In Formula (3), R 11  to R 22  each independently represent one selected from the group consisting of: a halogen atom, an amino group, cyano group, a nitro group, an alkoxy group, an aryloxy group, an alkyithio group, an arylthio group, an. acyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, an alkylsulfonyl group, a substituted or unsubstituted aliphatic hydrocarbon group, aromatic hydrocarbon ring group, aliphatic heterocyclic group, and aromatic heterocyclic group. R 11  to R 22  each may form a ring with a neighboring group with each other. 
     As an alkoxy group represented by R 11  to R 22  in Formula (3), it may be cited an alkoxy group having 1 to 18 carbon atoms such as: a methoxy group, an ethoxy group, a propoxy group, an isopropoxy group, a butoxy group, an isobutoxy group, a test-butoxy group, a pentyloxy group, a hexyloxy group, an octyloxy group, a test-octyloxy group, a 2-bornyloxy group, 2-isobornyloxy group, and 1-adamantyloxy group. 
     As an aryloxy group, it may be cited an aryloxy group having 6 to 30 carbon atoms such as: a phenoxy group, 4-test-butylphenoxy group, 1-naphthyloxy group, 2-naphthyloxy group, 9-anthryloxy group, 2-phenanthryloxy group, 1-naphthacenyl group, 1-pyrenyl group, 2-chrycenyl group, 3-perylenyl group, and 1-pentacenyl group. 
     As an alkylthio group, it may be cited an alkylthio group having 1 to 18 carbon atoms such as: a methylthio group, an ethylthio group, a propylthio group, a butylthio group, an isobutylthio group, a tert-butylthio group, a pentylthio group, an isopentylthio group, a hexylthio group, an isohexylthio group, a heptylthio group, and an octylthio group. 
     As an arylthio group, it may be cited an arylthio group having 6 to 30 carbon atoms such as: a phenylthio group, 4-methylphenylthio group, 4-tert-butylphenyithio group, and 1-naphthylthio group. 
     As an acyl group, it may be cited an acyl group having 2 to 18 carbon atoms such as: an acetyl group, a propionyl group, a pivaloyl group, a cyclohexylcarbonyl group, a benzoyl group, a toluoyl group, an anisoyl group, and a cinnamoyl group. 
     As an alkoxycarbonyl group, it may be cited an alkoxycarbonyl group having 2 to 18 carbon atoms such as: a methoxycarbonyl group, an ethoxycarbonyl group, a propoxycarbonyl group, a butoxycarbonyl group, a pentyloxycarbonyl group, a hexyloxycarbonyl group, a heptyloxycarbonyl group, an octylcarbonyl group, and benzyloxycarbonyl group. 
     As an aryloxycarbonyl group, it may be cited an aryloxycarbonyl group having 7 to 30 carbon atoms such as: a phenoxycarbonyl group, a 1-naphthyloxycarbonyl group, and a 2-phenanthryloxycarbonyl group. 
     As an alkylsufonyl group, it maybe cited an alkylsufonyl group having 1 to 18 carbon atoms such as: a mesyl group, an ethylsulfonyl group, a propylsulfonyl group, a butylsulfonyl group, a pentylsulfonyl group, a hexylsulfonyl group, a heptylsulfonyl group, an octylsulfonyl group, and a nonylsulfonyl group. 
     As an arylsufonyl group, it may be cited an arylsufonyl group having 6 to 30 carbon atoms such as: a benzenesulfonyl group, a p-toluenesulfonyl group, and a 1-naphthylsulfonyl group. 
     As an aliphatic hydrocarbon group, it may be cited a monovalent aliphatic hydrocarbon group having 1 to 18 carbon atoms described in the following: an alkyl group (for example, an alkyl group having 1 to 18 carbon atoms such as a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, a sec-butyl group, a tert-butyl group, a pentyl group, an isopentyl group, a hexyl group, an isohexyl group, a heptyl group, an octyl group, a nonyl group, a decyl group, a dodecyl group, a pentadecyl group, and an octadecyl group) , an alkenyl group (for example, an alkenyl group having 2 to 18 carbon atoms such as a vinyl group, a 1-propenyl group, 2-propenyl group, an isopropenyl group, a 1-butenyl group, a 2-butenyl group, a 3-butenyl group, a 1-octenyl group, a 1-decenyl group, and a 1-octadecenyl group) , an alkynyl group (for example, an alkynyl group having 2 to 18 carbon atoms such as an ethynyl group, a 1-propynyl group, a 2-propynyl group, a 1-butynyl group, a 2-butynyl group, a 3-butynyl group, a 1-octynyl group, a 1-decynyl group, and a 1-octadecynyl group) , a cycloalkyl group (for example, a cycloalkyl group having 3 to 18 carbon atoms such as a cyclopropyl group, a. cyclobutyl group, a cvclopentyl group, a cyclohexyl group, a cycloheptyl group, a cyclooctyl group, a cyclooctadecyl group, a 2-bornyl group, a 2-isobornyl group, and a 1-adamantyl group). 
     As an aromatic hydrocarbon ring group, it may be cited a condensed ring hydrocarbon group having 10 to 30 carbon atoms such as: a naphthyl group, a 2-naphthyl group, a 1-anthryl group, a 2-anthryl group, a 5-anthryl group, a 1-phenanthryl group, a 9-phenanthryl group, a 1-acenaphthyl group, a 2-triphenylenyl group, a 1-chrysenyl group, a 2-azulenyl group, a 1-pyrenyl group, a 2-triphenylyl group, a 1-pyrenyl group, a 2-pyrenyl group, a 1-perylenyl group, a 2-perylenyl group, a 3-perylenyl group, a 2-indenyl group, a 1-acenaphthylenyl group, a 2-naphthacenyl group, and a 2-pentacenyl group); and a ring assembly hydrocarbon group having 12 to 30 carbon atoms such as: an o-biphenylyl group, a m-biphenylyl group, a p-biphenylyl group, a terphenylyl group, and a 7-(2-naphthyl)-2-naphthyl group. 
     As an aliphatic heterocyclic group, it may be cited a monovalent aliphatic heterocyclic group having 3 to 18 carbon atoms such as: a 3-isochromanyl group, a 7-chromanyl group, a 3-coumarinyl group, a piperidino group, a morpholino group, and a 2-morpholinyl group. 
     As an aromatic heterocyclic group, it may be cited a monovalent aromatic heterocyclic group having 3 to 30 carbon atoms such as: a 2-furyl group, a 3-furyl group, a 2-thienyl group, a 3-thienyl group, a 2-benzofuryl group, a 2-benzothienyl group, a 2-pyridyl group, a 3-pyridyl group, a 4-pyridyl group, a 2-quinolyl group, and an 5-isoquinolyl group. 
     R 11  and R 22  in Formula (3) may be substituted with a substituent. As a substituent, the same substituent cited for Formula (1) may be cited. 
     (2) Compound Having a Structure Represented by Formula (4) 
     As a constituting material for a hole injection layer, it may be also suitably used a compound having a structure represented by Formula (4) described below. 
     
       
         
         
             
             
         
       
     
     In Formula (4) , R 23  to R 28  each independently represent a substituted or unsubstituted alkyl group, aryl group, aralkyl group, or heterocyclic group. R 23  to R 28  each may be the same or different. R 23  and R 24 , R 25  and R 26 , R 27  and R 28 , or R 23  and R 28 , R 24  and R 25 , R 26  and R 27 , each pair may be combined form a condensed ring 
     As an alkyl group represented by R 23  to R 28  in Formula (4) , it may be cited: a straight alkyl group such as a methyl group, an ethyl group, a propyl group, a hexyl group; and a branched alkyl group such as an isopropyl group and t-butyl group. 
     As an aryl group, it may be cited: a monocyclic aromatic hydrocarbon ring group such as a phenyl group; and a polycyclic aromatic hydrocarbon ring group such as a naphthyl group and an anthracenyl group. 
     As an aralkyl group, it may be cited: a benzyl group, a phenylpropyl group, and a naphthylmethyl group. 
     As a heterocyclic group, it may be cited: a mono-heterocyclic group and a condensed heterocyclic group such as a pyrrolyl group, a thienyl group, a pyridyl group, a phenazyl group, a pyridazyl group, and an acridyl group. 
     As a substituent on R 23  to R 28  in Formula (4), it may be cited: a halogen atom, a cyano group, a nitro group, a formyl group, an acetyl group, a benzoyl group, an amide group, a styryl group, an ethynyl group, a monocyclic aromatic ring and a polycyclic condensed ring such as a phenyl group, a naphthyl group, and an anthranyl group, a pyridyl group, a pyridazyl group, a phenazyl group, a pyrrolyl group, an imidazolyl group, and a polycyclic condensed ring such as a quinolyl group and an acridyl group. 
     As a condensed ring formed with R23 and R 24 , R 25  and R 26 , R 27  and R 28 , or R 23  and R 28 , R 24  and R 25 , R 26  and R 27 , it may be cited: a benzo group, a naphtho group, and a pyrido group. 
     (3) Other Material 
     In the present invention, a compound containing a structure represented by one of Formulas (5) to (12) indicated below is also suitably used. 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     R′s in Formulas (5) to (12) each independently represents a hydrogen atom, a substituted os unsubstituted aryl group having 5 to 60 core atoms, or alkyl group having 1 to 50 core atoms. 
     As an aryl group having 5 to 60 core atoms, it may be cited: a phenyl group, a naphthyl group, a biphenylyl group, an anthranyl group, a phenanthryl group, a pyrenyl group, a chrysenyl group, a fluoranthenyl group, a fluorenyl group, a pyridinyl group, a quinolyl group, an isoquinolyl group, and a phenanthryl group. 
     As an alkyl group having 1 to 50 core atoms, it may be cited: a methyl group, an ethyl group, a butyl group, a pentyl group, a hexyl group, a trifluoromethyl group, and a trifluroethyl group. 
     R′ in Formulas (5) to (12) may be substituted with a substituent. As a substituent, the same substituent cited for Formula (1) may be cited. 
     Specific compounds containing a structure represented by one of Formulas (5) to (12) are listed in the following. In addition, in the exemplified compounds, “Tol” represents any one of o-, m-, and p-methylphenyl group. 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     Materials used in the hole injection layer may be the same materials used in the hole transport layer describe later. Among them, preferable materials are: a phthalocyanine derivative represented by copper phthalocyanine; a hexaazatriphenylene derivative described in JP-A Nos. 2003-519432 and 2006-135145; a metal oxide represented by vanadium oxide; a conductive polymer such as amorphous carbon, polyaniline (or called as emeraldine) and polythiophene; an orthometalated complex represented by tris(2-phenylpyridine) iridium complex; and a triarylamine derivative. 
     The above-described materials used in a hole injection layer may be used singly or plural kinds may be co-used. In the hole injection layer of the present invention, it is preferable that it is made of a single material. 
     There are generally three types of materials used for a hole injection layer. Cited materials are: (i) a single organic compound; (ii) a single metal oxide; and (iii) a p-type doping material composed of an organic compound with a metal, a metal oxide or biferrocenium-F-TCNQ 
     From the viewpoint of stability (mass production) of the material itself, it is most preferable to use a single organic compound for a hole injection layer. However, when a single organic compound is used, there may appear a defect that a hole transport property in the hole injection layer becomes small compared with a hole transport layer material. Further, as the temperature becomes lower, the hole transport property becomes remarkably a rate limiting process rather than the electron transport property in view of the law of hopping conduction (μ=eR 2 v/k B T×exp (−2αR)). As a result, the color of the emission light shifted to the color of the emission light of the light emitting unit having a light emitting layer of high electron transport peoperty among the first light emitting unit and the second light emitting unit. 
     In view of the above-described points, it is preferable that a thickness ratio (d HIL /d HL ) is 0.20 or less, more preferably, it is 0.10 or less, provided that, d HIL  is a thickness of a hole injection layer; d HL  is a total thickness of the hole transport layers interposed between a semi-transparent electrode or a charge generating unit and a light emitting layer (for example, a hole injection layer, a hole transport layer, and an electron transport layer). Otherwise, it is preferable that a hole injection layer has a thickness in the range of 1 to 15 nm, more preferably, in the range of 1 to 10 nm. Thereby, a marked decrease of the hole transport property in the hole injection layer under a low temperature condition will be minimized, and it is possible to realize an emitting device achieving a stable recombination of carriers in the light emitting units. 
     (Hole Transport Layer) 
     A hole transport layer contains a material having a function of transporting a hole. A hole transport layer is a layer having a function of transporting a hole injected from an anode to a light emitting layer. 
     A layer thickness of a hole transport layer of an organic EL element of the present invention is not specifically limited, however, it is generally in the range of 5 nm to 5 μm, preferably in the range of 2 to 500 nm, and more preferably in the range of 5 to 200 nm. 
     A hole transport layer may be made of a single layer, two layers, or three layers. 
     A material used in a hole transport layer (hereafter, it is called as a hole transport material) is only required to have any one of properties of injecting a hole, transporting a hole, and a barrier property to an electron. A hole transport material may be suitably selected from the conventionally known compounds. A hole transport material may be used singly or may be used in combination of plural kinds of compounds. 
     Examples of a hole transport material include: a porphyrin derivative, a phthalocyanine derivative, an oxazole derivative, an oxadiazole derivative, a triazole derivative, an imidazole derivative, a pyrazoline derivative, a pyrazolone derivative, a phenylenediamine derivative, a hydrazone derivative, a stilbene derivative, a polyarylalkane derivative, a triarylamine derivative, a carbazole derivative, an indolocarbazole derivative, an isoindole derivative, an acene derivative of anthracene or naphthalene, a fluorene derivative, a fluorenone derivative, polyvinyl carbazole, a polymer or an oligomer containing an aromatic amine in a side chain or amain chain, polysilane, and a conductive polymer or an oligomer (e.g., PEDOT: PSS, an aniline type copolymer, polyaniline and polythiophene). 
     Examples of a triarylamine derivative include: a benzidine type represented by α-NPD, a star burst type represented by MTDATA, and a compound having fluorene or anthracene in a triarylamine bonding core. 
     A hexaazatriphenylene derivative described in JP-A Nos. 2003-519432 and 2006-135145 may be also used as a hole transport material. 
     In addition, it is possible to employ an electron transport layer of a higher p property which is doped with impurities. As examples, the constitutions described in JP-A Nos. 4-297076, 2000-196140, and 2001-102175, as well as in J. Appl. Phys., 95, 5773 (2004) may be used for an electron transport layer. 
     Further, it is possible to employ so-called p-type hole transport materials, and inorganic compounds such as p-type Si and p-type SiC, as described in JP-A No. 11-251067, and J. Huang et al. reference (Applied Physics Letters 80 (2002), p. 139). Moreover, an orthometal compounds having Ir or Pt as a center metal represented by Ir(ppy) 3  are also preferably used. 
     Although the above-described compounds may be used as a hole transport material, preferably used are: a triarylamine derivative, a carbazole derivative, an indolocarbazole derivative, an azatriphenylene derivative, an organic metal complex, a polymer or an oligomer incorporated an aromatic amine in a main chain or in a side chain. 
     Specific examples of a hole transport material are compounds in the aforesaid publications and in the following publications. However, the present invention is not limited to them. 
     Examples of a publication are: Appl. Phys. Lett. 69, 2160(1996), J. Lumin. 72-74, 985(1997), Appl. Phys. Lett. 78, 673(2001), Appl. Phys. Lett. 90, 183503(2007), Appl. Phys. Lett. 51, 913(1987), Synth. Met. 87, 171(1997), Synth. Met. 91, 209(1997), Synth. Met. 111, 421(2000), SID Symposium Digest, 37, 923(2006), J. Mater. Chem. 3, 319(1993), Adv. Mater. 6, 677(1994), Chem. Mater. 15, 3148(2003), US 2003/0162053, US 2002/0158242, US 2006/0240279, US 2008/0220265, U.S. Pat. No. 5,061,569, WO 2007/002683, WO 2009/018009, EP 650955, US 2008/0124572, US 2007/0278938, US 2008/0106190, US 2008/0018221, WO 2012/115034, JP-A 2003-519432, JP-A 2006-135145, and U.S. Pat. application No. 13/585981. 
     (Electron Blocking Layer) 
     An electron blocking layer is a layer provided with a function of a hole transport layer in a broad meaning. Preferably, it contains a material having a function of transporting a hole, and having very small ability of transporting an electron. It will improve the recombination probability of an electron and a hole by blocking an electron while transporting a hole. 
     Further, a composition of a hole transport layer described above may be appropriately utilized as an electron blocking layer of an organic EL element when needed. An electron blocking layer placed in an organic EL element is preferably arranged at a location in the light emitting layer adjacent to the anode side. 
     A thickness of an electron blocking layer is preferably in the range of 3 to 100 nm, and more preferably, it is in the range of 5 to 30 nm. 
     With respect to a material used for an electron blocking layer, the material used in the aforesaid hole transport layer is suitably used, and further, the material used as the aforesaid host compound is also suitably used for an electron blocking layer. 
     (Hole Blocking Layer) 
     A hole blocking layer is a layer provided with a function of an electron transport layer in a broad meaning. Preferably, it contains a material having a function of transporting an electron, and having very small ability of transporting a hole. It will improve the recombination probability of an electron and a hole by blocking a hole while transporting an electron. 
     When the hole blocking layer further has a function of preventing the route to the triplet energy level, it is further effective. 
     Further, a composition of an electron transport layer described above may be appropriately utilized as a hole blocking layer of the present invention when needed. 
     A hole blocking layer placed in an organic EL element of the present invention is preferably arranged at a location in the light emitting layer adjacent to the cathode side. 
     A thickness of a hole blocking layer according to the present invention is preferably in the range of 3 to 100 nm, and more preferably, in the range of 5 to 30 nm. 
     With respect to a material used for a hole blocking layer, the material used in the electron transport layer described later is suitably used, and further, the material used as the aforesaid host compound is also suitably used for a hole blocking layer. 
     (Electron Transport Layer) 
     An electron transport layer used in an organic EL element is composed of a material having a function of transferring an electron. It has a function of transporting an injected electron from a cathode to a light emitting layer. 
     An electron transport material may be used singly or may be used in combination of plural kinds of compounds. 
     A total layer thickness of the electron transport layer is not specifically limited, however, it is generally in the range of 2 nm to 5 μm, and preferably, it is in the range of 2 to 500 nm, and more preferably, it is in the range of 5 to 200 nm. 
     In an organic EL element, it is known that there occurs interference between the light directly taken from the light emitting layer and the light reflected at the electrode located at the opposite side of the electrode from which the light is taken out at the moment of taking out the light which is produced in the light emitting layer. 
     Consequently, it is preferable to suitably adjust the total thickness of the hole transport layers (e.g., hole injection layer, hole transport layer, and electron blocking layer) and the electron transport layers (e.g., electron injection layer, electron transport layer, and hole blocking layer) in the range of several nm to several μm. 
     On the other hand, the voltage will be increased when the layer thickness of the electron transport layer is made thick. Therefore, especially when the layer thickness is large, it is preferable that the electron mobility in the electron transport layer is 1×10 −5  cm 2 /Vs or more. 
     As a material used for an electron transport layer (hereafter, it is called as an electron transport material), it is only required to have either a property of ejection or transport of electrons, or a barrier to holes. Any of the conventionally known compounds may be selected and they may be employed. Examples of an electron transport material are: a nitrogen-containing aromatic heterocyclic derivative, an aromatic hydrocarbon ring derivative, a dibenzofuran derivative, a dibenzothiophene derivative, and a silole derivative. 
     Examples of the nitrogen-containing aromatic heterocyclic derivative are: a carbazole derivative, an azacarbazole derivative (a compound in which one or more carbon atoms constituting the carbazole ring are substituted with nitrogen atoms) , a pyridine derivative, a pyrimidine derivative, a pyrazine derivative, a pyridazine derivative, a triazine derivative, a quinoline derivative, a quinoxaline derivative, a phenanthroline derivative, an azatriphenylene derivative, an oxazole derivative, a thiazole derivative, an oxadiazole derivative, a thiadiazole derivative, a triazole derivative, a benzimidazole derivative, a benzoxazole derivative, and a benzothiazole derivative. 
     Examples of the aromatic hydrocarbon ring derivative are: a naphthalene derivative, an anthracene derivative, and a triphenylene derivative. 
     Further, metal complexes having a ligand of a 8-quinolinol structure or dibenzoquinolinol structure such as
     tris (8-quinolinol) aluminum (Alq 3 ),   tris (5, 7-dichloro-8-quinolinol) aluminum,   tris (5, 7-dibromo-8-quinolinol) aluminum,   tris (2-methyl-8-quinolinol) aluminum,   tris (5-methyl-8-quinolinol) aluminum, and   bis(8-quinolinol)zinc (Znq); and metal complexes in which a central metal of the aforesaid metal complexes is substituted by In, Mg, Cu, Ca, Sn, Ga or Pb, maybe also utilized as an electron transport material.   

     Further, a metal-free or metal phthalocyanine, or a compound whose terminal is substituted by an alkyl group or a sulfonic acid group, maybe preferably utilized as an electron transport material. A distyryl pyrazine derivative, which is exemplified as a material for a light emitting layer, may be used as an electron transport material. Further, in the same manner as used for a hole injection layer and a hole transport layer, an inorganic semiconductor such as an n-type Si and an n-type SiC may be also utilized as an electron transport material. 
     It may be used a polymer material introduced these compounds in the polymer side-chain or a polymer material having any one of these substance in a polymer main chain. 
     In an organic EL element, it may be formed an electron transport layer of a higher n property (electron rich) by doping a dope material as a guest material into an electron transport layer. Examples of a dope material are: a metal compound such as a metal complex and a metal halide; and an n-type dopant. As specific examples of a dope material, listed are those described in each of JP-A Nos. 4-297076, 10-270172, 2000-196140, 2001-102175, as well as in J. Appl. Phys., 95, 5773 (2004). 
     Although the present invention is not limited thereto, preferable examples of a known electron transport material used in an organic EL element of the present invention are compounds described in the following publications. 
     U.S. Pat. No. 6,528,187, U.S. Pat. No. 7,230,107, US 2005/0025993, US 2004/0036077, US 2009/0115316, US 2009/0101870, US 2009/0179554, WO 2003/060956, WO2008/132085, Appl. Phys. Lett. 75, 4 (1999), Appl. Phys. Lett. 79, 449 (2001) , Appl. Phys. Lett. 81, 162 (2002), Appl. Phys. Lett. 81, 162 (2002), Appl. Phys. Lett. 79, 156 (2001), U.S. Pat. No. 7,964,293, US 2009/030202, WO 2004/080975, WO 2004/063159, WO 2005/085387, WO 2006/067931, WO 2007/086552, WO 2008/114690, WO 2009/069442, WO 2009/066779, WO 2009/054253, WO 2011/086935, WO 2010/150593, WO 2010/047707, EP 2311826, JP-A 2010-251675, JP-A 2009-209133, JP-A 2009-124114, JP-A 2008-277810, JP-A 2006-156445, JP-A 2005-340122, JP-A 2003-45662, JP-A 2003-31367, JP-A 2003-282270, and WO 2012/115034. 
     As a preferable electron transport material, it may be cited: a pyridine derivative, a pyrimidine derivative, a pyrazine derivative, a triazine derivative, a dibenzofuran derivative, a dibenzothiophene derivative, a carbazole derivative, an azacarbazole derivative, and a benzimidazole derivative. 
     (Electron Injection Layer) 
     An electron injection layer (it is also called as “a cathode buffer layer”) is a layer which is arranged between a cathode and a light emitting layer to decrease an operating voltage and to improve an emission luminance. An example of an electron injection layer is detailed in volume 2, chapter 2 “Electrode materials” (pp. 123-166) of “Organic EL Elements and Industrialization Front thereof (Nov. 30, 1998, published by N.T.S. Co. Ltd.)”. 
     In an organic EL element of the present invention, an electron injection layer is provided according to necessity, and as described above, it is placed between a cathode or a charge generating unit and a light emitting layer, or between a cathode or a charge generating unit and an electron transport layer. 
     An electron injection layer is preferably a very thin layer. The layer thickness thereof is preferably in the range of 0.1 to 5 nm depending on the materials used. It may be an unhomogeneous layer in which the composing material is located intermittently. 
     An election injection layer is detailed in JP-A Nos. 6-325871, 9-17574, and 10-74586. Examples of a material preferably used in an election injection layer include: a metal such as strontium and aluminum; an alkaline metal compound such as lithium fluoride, sodium fluoride, or potassium fluoride; an alkaline earth metal compound such as magnesium fluoride; a metal oxide such as aluminum oxide; and a metal complex such as lithium 8-hydroxyquinolate (Liq). It is possible to use the aforesaid electron transport materials. 
     The above-described materials may be used singly or plural kinds may be used together in an election injection layer. 
     &lt;Charge Generating Unit&gt; 
     In an organic EL element of the present invention, a non-light-emitting charge generating unit is provided between the light emitting units. The charge generating unit is a layer having an interface with an organic compound layer which electrical connects a plurality of light emitting units in series in an electric field. 
     As a charge generating unit, an organic compound or an inorganic compound may be used singly or in combination with several kinds. 
     The charge generating unit is composed of at least one layer. However, it is preferably composed of at least two layers. It is particularly preferable to contain a p-type semiconductor layer, or an n-type semiconductor layer, or both of them. 
     The charge generating unit may be a bipolar layer that can generate and transport holes and electrons inside of the layer by an outer electric field. It is suitable to use a metal, a metal oxide, or an alloy thereof, which maybe used as a usual electrode material. 
     As described above, the charge generating unit maybe made to be a charge generating layer having a function of injecting electrons to one light emitting unit, and also having a function of injecting holes to another light emitting unit. 
     Further, the charge generating unit may be formed with the same material as the semi-transparent electrode or the reflective electrode, and it may be formed with a material having lower conductivity than the semi-transparent electrode or the reflective electrode. 
     In the charge generating unit, it may be used an insulator or a semiconductor such as lithium oxide, thlum fluorid.e, and cesium carbonate as a layer having a function of injecting holes. Alternatively, it may be used a material containing a substance having a high electron transport property added with an electron donating substance. 
     Examples of an organic compound used in a charge generating layer include: a nanocarbon material, an organic metal complex compound functioning as an organic semiconductor material (an organic acceptor, and an organic donor), an organic salt, an aromatic hydrocarbon compound and a derivative thereof, heteroaromatic hydrocarbon compound and a derivative thereof. 
     Examples of an inorganic compound include: a metal, a metal oxide, and an inorganic salt. 
     As a substance having a high electron transport property, it may be used a metal complex containing a quinoline structure or a benzoquinoline structure such as:
     tris (8-quinolinolato) aluminum (Alq 3 )   tris (4-methyl-8-quinolinolato) aluminum (Almq 3 )   bis (10-hydroxybenzo [h] quinolinato) beryllium (BeBq 2 ) , and   bis (2-methyl-8-quinolinolato) (4-phenylphenolato) aluminum (BAlq).   

     It may be used a metal complex containing an oxazole or a thiazole ligand other than these. Examples thereof are:
     bis[2-(2-hydroxyphenyl)benzoxazolato]zinc(Zn(BOX) 2 ),   bis[2-(2-hydroyphenyl)benzothlazolato]zinc (Zn(BTZ) 2 ))   

     It may be used the following compounds other than a metal complex:
     2- (4-biphenylyl) -5- (4-tert-butylphenyl) -1,3,4-oxadiazole (PBD),   1,3-bis [5- (p-tert-butylphenyl) -1,3,4-oxadiazol-2-yl]benzene (OXD-7),   3- (4 -biphenylyl)-4-phenyl-5- (4-tert-butylphenyl) -1,2,4-triazole (TAZ) bathophenanthroline (BPhen) , and bathocuproin (BCP).   

     The above-described substance having a high electron transport property designates a compound having an electron mobility of 1×10 −6  cm 2 /Vs or more. Any compound exhibiting a higher transport property of electron than hole may be used instead of the above-described substances. 
     It is possible to increase an electron injection property by adding an electron donating substance to the substance having a high electron transport property. By this, a driving voltage of a light emitting element may be decreased. As an electron donating substance, it may be cited: an alkali metal, an alkaline earth metal, a rare earth metal, a metal belonging to Group 13 of the Periodic Table of the Elements, an oxide thereof, and a carbonate thereof. 
     Specifically preferable examples are: lithium (Li) cesium (Cs) , magnesium (Mg) , calcium (Ca) , ytterbium (Yb) indium (In) , lithium oxide, and cesium carbonate. Further, it may be used an organic compound such as tetrathianaphthacene as a donor. 
     Semiconductors such as molybdenum oxide, vanadium oxide, rhenium oxide, ruthenium oxide or an insulator may be used as a layer having a function of injecting holes among the charge generating unit. Alternatively, it may be used a material containing a substance having a high hole transport property added with a substance having a high electron accepting property. Further, it may be used a layer composed of an electron accepting substance. 
     Examples of a substance having high hole transport property include aromatic amine compounds as follows:
     (4,4′-bis[N-(1-naphthyl)-N-phenyamino]biphenyl) (NBP or α-NPD);   N,N′-bis(3-methylphenyl)-N,N′-diphenyl-(1,1′-biphenyl)-4,4′-diamine (TPD);   (4,4′,4″-tris(N, N-diphenylamino)triphenylamine) (TDATA); and   (4,4′,4″-tris(N-(3-methylphenyl)-N-phenylamino) triphenylamine) (MTDATA).   

     The above-described substance having a high hole transport property designates a compound having a hole mobility of 1×10 −6  cm 2 /Vs or more. Any compound exhibiting a higher transport property of hole than electron may be used instead of the above-described substances. In addition, the above-described host compound may be used. 
     It is possible to increase a hole injection property by adding an electron accepting substance to the substance having a high hole transport property. By this, a driving voltage of a light emitting element may be decreased. As an electron accepting substance, it may be cited:
     7,7,8,8-tetracyano-2,3,5,6-tetrafluoroquinodimethane (F4-TCNQ) and Chloranil. It may be used a transition metal oxide. Further, it may be used an oxide of a metal belonging to Group 4 to Group 8 of the Periodic Table of the Elements. Specific examples are: vanadium oxide, niobium oxide, tantalum oxide, chromium oxide, molybdenum. oxide, tungsten oxide, manganese oxide, and rhenium oxide. These substances are preferable since they have a high electron accepting property. In particular, molybdenum oxide is preferable since it is stable in the air and it has low hygroscopic property, and it is easy to handle.   

     An increase of a driving voltage maybe avoided even when the thickness of the charge generating unit is increased by adopting one or both of the following constitutions. One constitution is to add an electron accepting substance to a substance having a high hole transport property. The other constitution is to add an electron accepting substance to a substance having a high electron transport property. Therefore, it can prevent a short circuit caused by a minute foreign substance or an impact by increasing the thickness of the charge generating unit. As a result, it can achieve alight emitting element of high reliability without increasing the driving voltage. 
     In the charge generating unit, may be introduced another layer between the layer having the function of injecting holes and the layer having the function of injecting electrons, when needed. For example, it may be placed an conductive layer such as ITO, or an electron relay layer. The electron relay layer has a function of reducing a voltage loss generated between a layer having a function of injecting holes and a layer having a function of injecting electrons. Specifically, it is preferable to use a material having a LUMO level of about −5.0 eV or more. It is more preferable to use a material having a LUMO level of about −5.0 eV to −3.0 eV. For example, it may be used: 3, 4, 9, 10-perylenetetracarboxylic dianhydride (PTCDA) and 3, 4, 9, 10-perylenetetracarboxylic bisbenzimidazole (PTCBI). 
     (Other Additive) 
     The light emitting unit composing the organic EL element may further contain other additive. 
     Examples of an additive are: halogen elements such as bromine, iodine and chlorine, and a halide compound; and a compound, a complex and a salt of an alkali metal, an alkaline earth metal and a transition metal such as Pd, Ca and Na. 
     Although a content of an additive may be arbitrarily decided, preferably, it is 1,000 ppm or less based on the total mass of the layer containing the additive, more preferably, it is 500 ppm or less, and still more preferably, it is 50 ppm or less. 
     In order to improve a transporting property of an electron or a hole, or to facilitate energy transport of an exciton, the content of the additive is not necessarily within these range, and other range of content may be used. 
     &lt;Semi-Transparent Electrode&gt; 
     As a semi-transparent electrode of an organic EL element, a metal having a large work function (4 eV or more, preferably, 4.3 eV or more) , an alloy, and a conductive compound and a mixture thereof are utilized as an electrode substance. 
     Specific examples of an electrode substance are:
     transparent substances such as silver (Ag), aluminum (Al), indium tin oxide (ITO), indium tin oxide containing silicon oxide (it may be called as ITSO), and indium oxide containing zinc oxide in an amount of 2 to 20%. Further, it may be also used: metal substances such as, gold (Au), platinum (Pt), nickel (Ni) , tungsten (W), chromium (Cr) , molybdenum (Mo) , iron (Fe), cobalt (Co), copper (Cu), and palladium (Pd) , and laminated structure of these materials.   

     As for a semi-transparent electrode, these electrode substances may be made into a thin layer by a method such as a vapor deposition method or a sputtering method; followed by making a pattern of a desired form by a photolithography method. Otherwise, when the requirement of pattern precision is not so severe (about 100 μm or more), a pattern may be formed through a mask of a desired form at the time of layer formation with a vapor deposition method or a sputtering method using the above-described material. 
     Alternatively, when a coatable substance such as an organic conductive compound is employed, it is possible to employ a wet film forming method such as a printing method or a coating method. 
     An optical transmittance of a semi-transparent electrode is preferably in the range of 10 to 100% at a wavelength of 450 nm. An optical reflectance is preferably in the range of 5 to 80%. In addition, an absorption ratio (=100% −(optical transmittance)−(optical reflectance)) is preferably 50% or less. 
     A sheet resistance of a semi-transparent electrode is preferably a few hundred Ω/sq or less. Further, although a layer thickness of the semi-transparent electrode depends on a material, it is generally selected in the range of 10 nm to 1 μm, and preferably in the range of 10 nm to 200 nm. 
     When an optical transmittance is required for a semi-transparent electrode, it may be used a construction in which the above-described metal material is made to be a thin film for achieving transparency and then a translucent material is laminated thereon. A metal material having a semi-transparent property may be used in a single layer. However, the materials for a semi-transparent electrode are not limited to the above-described materials. 
     A layer thickness of a metal substance is preferably in the range of 1 to 50 nm. More preferably, it is in the range of 5 to 40 nm. From the viewpoint of stability of layer thickness, and layer quality, it is preferably 5 nm or more. Further, from the viewpoint of extracting the inner emission light, the layer thickness is preferably 40 nm or less. Although, a resonance mechanism may be strengthen. 
     &lt;Reflective Electrode&gt; 
     As a reflective electrode, a metal having a small work function (4 eV or less) (it is called as an electron injective metal), an alloy, a conductive compound and a mixture thereof are utilized as an electrode substance. Specific examples of the aforesaid electrode substance includes: sodium, sodium-potassium alloy, magnesium, lithium, a magnesium/copper mixture, a magnesium/silver mixture, a magnesium/aluminum mixture, a magnesium/indium mixture, an aluminum/aluminum oxide (Al 2 O 3 ) mixture, indium, a lithium/aluminum mixture, aluminum, silver, a silver alloy containing silver as a main component, an aluminum/solver mixture, and a rare earth metal. 
     A reflective electrode may be made by using these electrode substances with a method such as a vapor deposition method or a sputtering method to form a thin film. A sheet resistance of the reflective electrode is preferably a few hundred Ω/sq or less. A layer thickness of the reflective electrode is generally selected in the range of 10 nm to 5 μm, and preferably in the range of 50 to 200 nm. 
     &lt;Substrate&gt; 
     A substrate which may be used for an organic EL element is not specifically limited with respect to types such as glass and plastics. They may be transparent or opaque. However, a transparent substrate is preferable when the emitting light is taken from the side of the substrate. Transparent substrates preferably utilized includes such as glass, quartz and transparent resin film. A specifically preferable substrate is a resin film which is capable of providing an organic EL element with a flexible property. 
     Examples of a resin film include: polyesters such as polyethylene terephthalate (PET) and polyethylene naphthalate (PEN), polyethylene, polypropylene, cellophane, cellulose esters and their derivatives such as cellulose diacetate, cellulose triacetate (TAC), cellulose acetate butyrate, cellulose acetate propionate (CAP), cellulose acetate phthalate, and cellulose nitrate, polyvinylidene chloride, polyvinyl alcohol, polyethylene vinyl alcohol, syndiotactic polystyrene, polycarbonate, norbornene resin, polymethyl pentene, polyether ketone, polyimide, polyether sulfone (PES), polyphenylene sulfide, polysulfones, polyether imide, polyether ketone imide, polyamide, fluororesin, Nylon, polymethyl methacrylate, acrylic resin, polyallylates and cycloolefin resins such as ARTON (trade name, made by JSR Co. Ltd.) and APEL (trade name, made by Mitsui Chemicals, Inc.). 
     On the surface of a resin film, it may be formed a film incorporating an inorganic or an organic compound or a hybrid film incorporating both compounds. Barrier films are preferred with a water vapor permeability of 0.01 g/(m 2 ·24h) or less (at 25±0.5° C., and 90±2% RH) determined based on JIS K 7129-1992. Further, high barrier films are preferred to have an oxygen permeability of 1×10 −3  ml/(m 2 ·24h·atm) or less determined based on JIS K 7126-1987, and a water vapor permeability1 of 1×10 −5  g/(m 2 ·24h) or less. 
     As materials that form a gas barrier film, employed may be those which retard penetration of moisture and oxygen, which deteriorate the element. For example, it is possible to employ silicon oxide, silicon dioxide, and silicon nitride. Further, in order to improve the brittleness of the gas barrier film, it is more preferable to achieve a laminated layer structure of inorganic layers and organic layers. The laminating order of the inorganic layer and the organic layer is not particularly limited, but it is preferable that both are alternatively laminated a plurality of times. 
     Gas barrier film forming methods are not particularly limited, and examples of employable methods include a vacuum deposition method, a sputtering method, a reactive sputtering method, a molecular beam epitaxy method, a cluster ion beam method, an ion plating method, a plasma polymerization method, a plasma CVD method, a laser CVD method, a thermal CVD method, and a coating method. Of these, specifically preferred is a method employing an atmospheric pressure plasma polymerization method, described in JP-A No. 2004-68143. 
     Examples of opaque support substrates include metal plates such aluminum or stainless steel films, opaque resin substrates, and ceramic substrates. 
     &lt;Sealing&gt; 
     As sealing means employed in the present invention, listed may be, for example, a method in which sealing members, electrodes, and a supporting substrate are subjected to adhesion via adhesives. The sealing members may be arranged to cover the display region of an organic EL element, and may be a concave plate or a flat plate. Neither transparency nor electrical insulation is limited. 
     Specifically listed are glass plates, polymer plate-films, and metal plate-films. 
     Specifically listed glass plates are: soda-lime glass, barium-strontium containing glass, lead glass, aluminosilicate glass, borosilicate glass, barium borosilicate glass, and quartz. 
     Further, as polymer plates and polymer films, listed are: polycarbonate, acryl, polyethylene terephthalate, polyether sulfide, and polysulfone. 
     As metal plates, listed are: those composed of at least one metal selected from the group consisting of stainless steel, iron, copper, aluminum magnesium, nickel, zinc, chromium, titanium, molybdenum, silicon, germanium, and tantalum, or alloys thereof. 
     Since it is possible to achieve a thin organic EL element, it is preferable to employ a polymer film or a metal film. Further, it is preferable that the polymer film has an oxygen permeability of 1×10 −3  ml/(m 2 ·24h·atm) or less, and a water vapor permeability of 1×10 −3  g/(m 2 ·24h) or less. It is more preferable that the polymer film has a water vapor permeability of 1×10 −5  g/(m 2 ·24h) or less, and an oxygen permeability of 1×10 −5  ml/(m 2 ·24h·atm) or less. 
     Conversion of the sealing member into concave is carried out by employing a sand blast process or a chemical etching process. In practice, as adhesives, listed may be photo-curing and heat-curing types having a reactive vinyl group of acrylic acid based oligomers and methacrylic acid, as well as moisture curing types such as 2-cyanoacrylates. Further listed may be thermal and chemical curing types (mixtures of two liquids) such as epoxy based ones. Still further listed may be hot-melt type polyamides, polyesters, and polyolefins. Yet further listed may be cationically curable type UV curable epoxy resin adhesives. 
     In addition, since an organic EL element is occasionally deteriorated via a thermal process, preferred are those which enable adhesion and curing between a room temperature (25° C.) and 80° C. Further, desiccating agents may be dispersed into the aforesaid adhesives. Adhesives maybe applied onto sealing portions via a commercial dispenser or printed on the same in the same manner as screen printing. 
     It is preferable to inject a gas phase and a liquid phase material of inert gases such as nitrogen or argon, and inactive liquids such as fluorinated hydrocarbon or silicone oil into the space between the space formed with the sealing member and the display region of the organic EL element. Further, it is possible to form vacuum in the space. Still further, it is possible to enclose hygroscopic compounds in the interior of the space. 
     Examples of a hygroscopic compound include: metal oxides (for example, sodium oxide, potassium oxide, calcium oxide, barium oxide, magnesium oxide, and aluminum oxide); sulfates (for example, sodium sulfate, calcium sulfate, magnesium sulfate, and cobalt sulfate); metal halides (for example, calcium chloride, magnesium chloride, cesium fluoride, tantalum fluoride, cerium bromide, magnesium bromide, barium iodide, and magnesium iodide); perchlorates (for example, barium perchlorate and magnesium perchlorate). In sulfates, metal halides, and perchlorates, suitably employed are anhydrides. For sulfate salts, metal halides and perchlorates, suitably used are anhydrous salts. 
     &lt;Protective Film and Protective Plate&gt; 
     On the outer surface of the sealing, a protective or a protective plate may be arranged to enhance the mechanical strength of the organic EL element. Specifically, when sealing is achieved via the aforesaid sealing film, the resulting mechanical strength is not always high enough, therefore it is preferable to arrange the protective film or the protective plate described above. Usable materials for these include glass plates, polymer plate-films, and metal plate-films which are similar to those employed for the aforesaid sealing. However, from the viewpoint of reducing weight and thickness, it is preferable to employ a polymer film. 
     &lt;Improving Method of Light Extraction&gt; 
     It is generally known that an organic EL element emits light in the interior of the layer exhibiting the refractive index (being about 1.6 to 2.1) which is greater than that of air, whereby only about 15% to 20% of light generated in the light emitting layer is extracted. This is due to the fact that light incident to an interface (being an interlace of a transparent substrate to air) at an angle of ⊖ which is at least critical angle is not extracted to the exterior of the element due to the resulting total reflection, or light is totally reflected between the transparent electrode or the light emitting layer and the transparent substrate, and light is guided via the transparent electrode or the light emitting layer, whereby light escapes in the direction of the element side surface. 
     Means to enhance the efficiency of the aforesaid light extraction include, for example: a method in which roughness is formed on the surface of a transparent substrate, whereby total reflection is minimized at the interface of the transparent substrate to air (U.S. Pat. No. 4,774,435), a method in which efficiency is enhanced in such a manner that a substrate results in light collection (JP-A No. 63-314795), a method in which a reflection surface is formed on the side of the element (JP-A No. 1-220394), a method in which a flat layer of a middle refractive index is introduced between the substrate and the light emitting body and an antireflection film is formed (JP-A No. 62-172691), a method in which a flat layer of a refractive index which is equal to or less than the substrate is introduced between the substrate and the light emitting body (JP-A No. 2001-202827), and a method in which a diffraction grating is formed between the substrate and any of the layers such as the transparent electrode layer or the light emitting layer (including between the substrate and the outside) (JP-A No. 11-283751). 
     &lt;&lt;Production Method of Organic EL Element&gt;&gt; 
     Subsequently, it is described an example of a production method of an organic EL element having a constitution of: 
     semi-transparent electrode/first light emitting unit/charge generating unit/second light emitting unit/reflective electrode. 
     First, a thin film made of an anode substance is formed on an appropriate substrate using a required electrode substance with a vapor deposition method or a sputtering method in such a manner to have a thickness of 1 μm or less, preferably to have a thickness of 10 to 200 nm. Thus a semi-transparent electrode is formed. 
     Then, on this, it is formed a first light emitting unit composed of: a hole injection layer, a hole transport layer, an electron blocking layer, a light emitting layer, an electron injection layer, and an electron transport layer. 
     Examples of a method of forming an organic compound thin are: a vapor deposition method, a wet process (a spin coating method, a cast method, an inkjet method, a printing method, a LB method (Langmuir Blodgett method), a spray coating method, a printing method, and a slot coater method. From the viewpoint of getting a uniform thin layer and hardly generating pinholes, specifically preferable methods are: a vacuum vapor deposition method, a spin coating method, an inkjet method, a printing method, and a slot coater method. A different film forming method may be applied to every organic layer. 
     When a vapor deposition method is adopted for forming each layer, the vapor deposition conditions may be changed depending on the compounds used. Generally, the following ranges are suitably selected for the conditions, heating temperature of boat: 50 to 450° C., level of vacuum: 1×10 −6  to 1×10 −2  Pa, vapor deposition rate: 0.01 to 50 nm/sec, temperature of substrate: −50 to 300° C., and layer thickness: 0.1 nm to 5 μm, preferably in the range of 5 to 200 nm. 
     Subsequently, a charge generating unit is formed on the first light emitting unit. 
     A method of forming a charge generating unit is not specifically limited as long as a thin film is formed. Examples thereof are: a vapor deposition method, a sputtering method, a wet process (a spin coating method, a cast method, an inkjet method, a LB method, a spray coating method, a printing method, and a slot coater method. 
     Subsequently, a second light emitting unit is formed on the charge generating unit in the same way as forming the first light emitting unit. 
     Then, a thin film made of a cathode substance is formed thereon with a vapor deposition method or a sputtering method in such a manner to have a thickness of 1 μm or less, preferably to have a thickness of in the range of 50 to 200 nm. Thus a reflective electrode is formed. 
     By this, a required organic EL element is obtained. 
     Formation of this organic El element of the present invention is preferably continuously carried out from a first light emitting layer to a cathode with one time vacuuming. It maybe taken out on the way, and a different layer forming method maybe employed. In that case, it is required to make attention that the operation is done under a dry inert gas atmosphere. 
     Next, the organic El element maybe sealed and protected. For example, the organic El element is covered with a heat curable resin under the condition that a part of or a whole portion of the semi-transparent electrode and the reflective electrode is exposed. The heat curable resin is heated to be cured, and the organic El element is sealed. 
     Then, the sealed body of the organic El element and the part of or the whole portion of the semi-transparent electrode and the reflective electrode exposed are covered with a protective member. The overlapped portion of the protective member is heated at a predetermined temperature with giving pressure. It may be used two sheets of protective members to cover the sealed body of the organic El element, and the edge portions of the protective members may be heated and pressed. Otherwise, it maybe used one sheet of protective member to cover the sealed body of the organic El element by folding the protective member, and the edge portions (in particular, the opened portion) of the protective members may be heated and pressed. 
     By the above-described process, it may be produced an organic EL module containing an organic EL element sealed and protected. 
     &lt;&lt;Other Constitution&gt;&gt; 
     In the embodiment as described above, it is described an organic EL element of a bottom emission type. It has a constitution sequentially laminated on a substrate with: a semi-transparent electrode, a first light emitting unit, a charge generating unit, a second light emitting unit, and a reflective electrode. The present invention is not limited to this constitution. For example, the order of layers may be reverse, and the position of the semi-transparent electrode and the reflective electrode maybe switched. It is sufficient that the organic EL element has at least two light emitting layers. 
     Therefore, the layer constitution of the light emitting layer and laminated number are not limited in particular as long as the above-described conditions are satisfied. It maybe use a constitution enabling to achieve a required organic EL element. 
     For example, the light emitting layers constituting the organic EL element may be two layers, or they may be three layers. In the light emitting layers, the light emitting material may be a single species, or a plurality of light emitting layers may be laminated directly or through an organic layer. 
     They may be suitably made in combination of these structures. 
     &lt;&lt;Light Emitting Device-1&gt;&gt; 
     As one embodiment of an electronic device provided with an organic EL element of the present invention, it is described a light emitting device. 
     An organic EL element used for a light emitting device may be provided with a rasonator structure on the organic EL element having the above-described configuration. The intended uses of the organic EL element provided with a rasonator structure are: a light source of a light memory media, alight source of an electrophotographic copier, a light source of a light communication processor, and a light source of a light sensor, however, it is not limited to them. It may be used for the above-described purposes by making to emit a laser. 
     A combination of the light emitting materials may be the following: a combination of a plurality of materials that emit phosphorescence or fluorescence; or a combination of a plurality of materials that emit phosphorescence or fluorescence and a color material that emits light excited by the light from the light emitting material. In the organic EL element of the present invention, it may be used a combination of a plurality of emission dopant in the light emitting layer. 
     The above-described organic EL element emits light by itself. This is different from the array constitution for obtaining an emission light by arranging the organic EL elements that emit each color light in parallel. Therefore, it is not required a mask for forming layers that compose the element. As a result, for example, a conductive layer may be formed with a vapor deposition method, a cast method a spin coating method, an inkjet method, or a printing method on the whole surface. This increases productivity of the element. 
     By employing the organic EL element described above, it is possible to produce a light emitting device having an emission light of substantially the same emission color. 
     &lt;&lt;Light Emitting Device-2&gt;&gt; 
     A light emitting device maybe formed in a state of a large area by using a plurality of organic EL elements. In this case, the state of a large area is achieved: by making a plurality of light emitting panels placed on a substrate, then, by arranging these panels on a support substrate (namely, by tiling). The support substrate may be served as a sealing member. Each light emitting panel is tiled in a manner that the organic EL elements are interposed between the support substrate and the substrate of the light emitting panel. In the space between the support substrate and the substrate, it may be filled with an adhesive. The organic EL elements may be sealed by this adhesive. 
     In addition, terminals of the semi-transparent electrode and the reflective electrode are made exposed in the surroundings of the light emitting panel. 
     In the light emitting device having the above-described constitution, the center of each light emitting panel becomes a light emitting area, and there are produced non-light emitting areas between the light emitting panels. Therefore, a light extraction member may be placed in the non-light emitting areas of the light extraction surface for increasing the amount of light extraction from the non-light emitting areas. A light collection sheet or a light diffusion sheet may be used for a light extraction member. 
     EXAMPLES 
     Hereafter, the present invention will be described specifically by referring to examples, however, the present invention is not limited to them. In examples, the indication of “%” is used. Unless particularly mentioned, it represents “mass %”. 
     &lt;&lt;Preparation of Organic EL Element&gt;&gt; 
     Each sample was prepared to have a light emitting are of 5 cm ×5 cm. 
     (1) Preparation of Organic EL Element  101  (Red Color Type) 
     (1.1) Formation of Semi-Transparent Electrode 
     As a transparent support substrate, it was arranged a glass substrate with a thickness of 0.7 mm. The transparent support substrate was subjected to ultrasonic washing with isopropyl alcohol, followed by drying with desiccated nitrogen gas, and it was subjected to UV ozone washing for 5 minutes. On this transparent support substrate Ag (silver) was vapor-deposited using a mask with a thickness of 20 nm. Thus, a cathode being a semi-transparent electrode was formed. 
     (1.2) First Light Emitting Unit 
     Subsequently, the transparent support substrate formed an anode thereon was fixed to a substrate holder of a commercial vacuum deposition apparatus. The constituting materials for each layer of an organic EL element were loaded in each heating boat for vapor deposition in the vacuum deposition apparatus with an optimum amount. As a heating boat for vapor deposition, it was used a resistance heating boat made of molybdenum or tungsten. 
     (1.2.1) Formation of First Hole Injection Layer 
     Then, after reducing the pressure of a vacuum tank to 4×10 −4  Pa, the heating boat containing an exemplified compound HI-145 (HAT-CN) was heated via application of electric current and vapor deposition was made onto the anode at a deposition rate of 0.1 nm/second, whereby it was produced a first hole injection layer having a thickness of 5 nm. 
     (1.2.2) Formation of First Hole Transport Layer 
     Subsequently, a compound 1-A (glass transition temperature (Tg)=140° C.) having the following structure was vapor-deposited to form a layer having a thickness of 65 nm. Thus it was produced a first hole transport layer. 
     
       
         
         
             
             
         
       
     
     (1.2.3) Formation of First Electron Blocking Layer 
     Subsequently, a compound 1-B having the following structure was vapor-deposited to form a layer having a thickness of 20 nm. Thus it was produced a first electron blocking layer. 
     
       
         
         
             
             
         
       
     
     By the above-described processes, there was formed a layer having a hole transport property. The layer was made by sequentially laminating on the anode side: the exemplified compound HI-145; the compound 1-A; and the compound 1-B. 
     (1.2.4) Formation of First Light Emitting Layer 
     Subsequently, there were vapor-deposited: a compound 2-A (Tg=143° C.) having the following structure as a host compound to be 77 vol %; a compound 2-B (Ir(bzq) 3 ) having the following structure as an assist dopant to be 15 vol %; and a compound pq (Orange 1) having the following structure as an emission dopant emitting orange phosphorescence to be 8 vol %. Thus it was produced a first phosphorescence emitting layer having a thickness of 30 nm that emitted orange color. 
     
       
         
         
             
             
         
       
     
     (1.2.5) Formation of First Electron Transport Layer 
     Subsequently, there were vapor-deposited: a compound 3 having the following structure to be 86 vol %; and LiF to be 14 vol %. A layer having a thickness of 10 nm was formed. Further, there were vapor-deposited: a compound 3 to be 98 vol %; and Li to be 2 vol %. Another layer having a thickness of 10 nm was formed. By this, it was produced a first electron transport layer (also served as an electron injection layer) composed of 2 layers, one layer being composed of the compound 3 and LiF, and another layer being composed of the compound 3 and Li. 
     
       
         
         
             
             
         
       
     
     By the above-described processes, it was prepared a first light emitting unit composed of: a first hole injection layer, a first hole transport layer, a first electron blocking layer, a first light emitting layer, and a first electron transport layer. 
     (1.3) Charge Generating Unit 
     Subsequently, a charge generating unit was formed by forming a layer made of Ag with a thickness of 1 nm on the first light emitting unit. 
     (1.4) Second Light Emitting Unit 
     (1.4.1) Layer Having a Hole Transport Property 
     Subsequently, in the same manner as forming the layer having a hole transport property in the first light emitting unit, the heating boat containing an exemplified compound HI-145 (HAT-CN) was heated via application of electric current and vapor deposition was made onto the charge generating unit at a deposition rate of 0.1 nm/second, whereby it was produced a second hole injection layer having a thickness of 15 nm. 
     Then, the compound 1-A was vapor-deposited to have a thickness of 100 nm, and a second hole transport layer was formed. 
     Further, the compound 1-B was vapor-deposited to have a thickness of 10 nm, and a second electron blocking layer was formed. 
     By the above-described processes, there was formed a layer having a hole transport property. The layer was made by sequentially laminating on the charge generation unit side: the exemplified compound HI-145; the compound 1-A; and the compound 1-B. 
     (1.4.2) Second Light Emitting Layer 
     Subsequently, there were vapor-deposited: a compound 2-A (Tg=143° C.) as a host compound to be 77 vol %; a compound 2-B as an assist dopant to be 15 vol %; and a compound pq (Orange 1) as an emission dopant emitting orange phosphorescence to be 8 vol %. Thus it was produced a second phosphorescence emitting layer having a thickness of 20 nm that emitted orange color. 
     (1.4.3) Second Electron Transport Layer 
     Subsequently, in the same manner as forming the electron transport layer of the first light emitting unit, there were vapor-deposited: a compound 3 to be 86 vol %; and LiF to be 14 vol %. A layer having a thickness of 10 nm was formed. Further, there were vapor-deposited: a compound 3 to be 98 vol %; and Li to be 2 vol %. Another layer having a thickness of 10 nm was formed. By this, it was produced a second electron transport layer composed of 2 layers, one layer being composed of the compound 3 and LiF, and another layer being composed of the compound 3 and Li. 
     (1.5) Cathode and Sealing 
     Subsequently, aluminum was vapor-deposited with a thickness of 150 nm to form a cathode. 
     Subsequently, the non-light emitting surface of the organic EL element which had been formed till the cathode was covered with a glass case, and glass case was contacted with the glass substrate on which was prepared the organic EL element. An epoxy based light curable type adhesive (LUXTRACK LC0629B produced by Toagosei Co., Ltd.) was employed in the periphery of the glass case as a sealing material. The sealing material was superimposed on the cathode side of the organic EL element to be brought into close contact with the glass substrate. Then, curing and sealing of the organic EL element were carried out via exposure of UV radiation onto the glass case side. Thus, an organic EL element  101  was prepared. 
     Incidentally, the sealing operation by the glass case was carried out in a glove box under nitrogen ambience (under an ambience of high purity nitrogen gas at a purity of at least 99.999%) so that the organic EL element was not brought into contact with the atmosphere. 
     (2) Preparation of Organic EL Element  102  (Red Color Type) 
     An organic EL element  102  was prepared in the same manner as preparation of the organic EL element  101  except that the layer thickness of the second hole transport layer was changed to 110 nm. 
     (3) Preparation of Organic EL Element  201  (Yellow Color Type) 
     An organic EL element  201  was prepared in the same manner as preparation of the organic EL element  101  except that the layer thickness of the first hole transport layer was changed to 55 nm, and the layer thickness of the second hole transport layer was changed to 75 nm, and the first and the second light emitting layers were formed as described below. 
     (3.1) First Light Emitting Layer 
     There were vapor-deposited: a compound 2-A (Tg=143° C.) as a host compound to be 85 vol %; and a compound 2-B as an emission dopant emitting yellow phosphorescence to be 15 vol %. Thus it was produced a first phosphorescence emitting layer having a thickness of 30 nm that emitted yellow color. 
     (3.2) Second Light Emitting Layer 
     There were vapor-deposited: a compound 2-A (Tg=143° C.) as a host compound to be 85 vol %; and a compound 2-B as an emission dopant emitting yellow phosphorescence to be 15 vol %. Thus it was produced a second phosphorescence emitting layer having a thickness of 20 nm that emitted yellow color. 
     (4) Preparation of Organic EL Element  202  (Yellow Color Type) 
     An organic EL element  202  was prepared in the same manner as preparation of the organic EL element  201  except that the layer thickness of the second hole transport layer was changed to 85 nm. 
     (5) Preparation of Organic EL Element  301  (Blue Color Type) 
     An organic EL element  301  was prepared in the same manner as preparation of the organic EL element  101  except that the layer thickness of the first hole transport layer was changed to 41 nm, and the layer thickness of the second hole transport layer was changed to 53 nm, and the first and the second light emitting layers were formed as described below. 
     (5.1) First Light Emitting Layer 
     There were vapor-deposited: a compound 4-A (Tg=189° C.) as a host compound to be 98 vol %; and a compound 4-B having the following structure as an emission dopant emitting blue fluorescence to be 2 vol %. Thus it was produced a first fluorescence emitting layer having a thickness of 30 nm that emitted blue color. 
     
       
         
         
             
             
         
       
     
     (5.2) Second Light Emitting Layer 
     There were vapor-deposited: a compound 4-A (Tg=189° C.) as a host compound to be 85 vol %; and a compound 4-B as an emission dopant emitting blue fluorescence to be 15 vol %. Thus it was produced a second fluorescence emitting layer having a thickness of 20 nm that emitted blue color. 
     (6) Preparation of Organic EL Element  302  (Blue color type) 
     An organic EL element  302  was prepared in the same manner as preparation of the organic EL element  301  except that the layer thickness of the second hole transport layer was changed to 63 nm. 
     &lt;&lt;Evaluation of Organic EL Element&gt;&gt; 
     The prepared organic EL elements were subjected to the following evaluation tests. 
     The obtained evaluation results are listed in Table 1. 
     (1) Measurement and Analysis of Refractive Ratio and Actual Distance 
     All of the layers interposed from the anode (the semi-transparent electrode) to the first and the second light emitting layers were considered to be one layer. 
     Refractive ratios n 1  and n 2 , each being a refractive ratio of the emission dopant in each light emitting layer, and actual distances d1 and d2, each being an actual distance from the anode (the semi-transparent electrode) to the first or the second light emitting layer, were measured by using a spectroscopic ellipsometer (UVSEL/FUV-FGMS, made by HORIBA JYOBIN-YVON). 
     Analysis was made in the wavelength range of 500 to 800 nm, and Cauchy was carried out (n (refractive ratio): variable, k (attenuation factor): none, fixed value) to measure a refractive ratio and a layer thickness. 
     A refractive ratio and a layer thickness were measured with a target sample to be measured by forming to the first and the second light emitting layer on a silicon wafer. 
     (2) Measurement of Power Efficiency 
     The prepared organic EL elements were lighted. A front brightness of each organic EL element at a different voltage was measured with Spectroradiometer CS-1000 (made by Konica Minolta Inc.). A current efficiency of the organic EL element at a front brightness of 1,000 cd/m 2  was measured. 
     Here, the power efficiency values of the organic EL elements  102 ,  202 , and  302  were indicated as a relative value when the power efficiency of the organic EL elements  101 ,  201 , and  301  each were set to be 100. 
     (2) Lifetime at Normal Temperature 
     The prepared organic EL elements were lighted at normal temperature (25° C.) to exhibit an initial brightness of 4,000 cd/m 2 . A lifetime of reaching the residual rate (brightness) of 70% of the initial brightness was measured. 
     Here, the lifetime at normal temperature values of the organic EL elements  102 ,  202 , and  302  were indicated as a relative value when the lifetime value of the organic EL elements  101 ,  201 , and  301  each were set to be 100. 
     (4) Driving Lifetime at 85° C. 
     The prepared organic EL elements were stored in a thermostatic chamber. The temperature of the thermostatic chamber was set to be 85° C., and the organic EL elements were continuously driven with an initial front brightness of 1,000 cd/m 2 . A lifetime of reaching the residual rate (brightness) of 70% of the initial brightness was measured. 
     Here, the driving lifetime values of the organic EL elements  102 ,  202 , and  302  were indicated as a relative value when the driving lifetime value of the organic EL elements  101 ,  201 , and  301  each were set to be 100. 
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 1 
               
               
                   
               
               
                   
                 Layer 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Organic 
                 thickness 
               
               
                 EL 
                 (nm) of 
                   
                   
                 n 1 d 1  × 
                   
                   
                 n 2 d 2  × 
                   
                   
                 Lifetime at 
                 Driving 
               
               
                 element 
                 Second hole 
                   
                 d 1   
                 4/1:A 
                   
                 d 2   
                 4/3:B 
                 B − A 
                 Power 
                 normal 
                 lifetime 
               
               
                 No. 
                 transport layer (nm) 
                 n 1   
                 (nm) 
                 (nm) 
                 n 2   
                 (nm) 
                 (nm) 
                 (nm) 
                 efficiency 
                 temperature 
                 (85° C.) 
                 Remarks 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 101 
                 100 
                 1.72 
                 90 
                 619 
                 1.73 
                 266 
                 614 
                 −5 
                 100 
                 100 
                 100 
                 Comp. 
               
               
                 102 
                 110 
                 1.72 
                 90 
                 619 
                 1.73 
                 276 
                 637 
                 28 
                 106 
                 109 
                 130 
                 Inv. 
               
               
                   
               
               
                 Comp.: Comparative example 
               
               
                 Inv.: Inventive example 
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 2 
               
               
                   
               
               
                   
                 Layer 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Organic 
                 thickness 
               
               
                 EL 
                 (nm) of 
                   
                   
                 n 1 d 1  × 
                   
                   
                 n 2 d 2  × 
                   
                   
                 Lifetime at 
                 Driving 
               
               
                 element 
                 Second hole 
                   
                 d 1   
                 4/1:A 
                   
                 d 2   
                 4/3:B 
                 B − A 
                 Power 
                 normal 
                 lifetime 
               
               
                 No. 
                 transport layer (nm) 
                 n 1   
                 (nm) 
                 (nm) 
                 n 2   
                 (nm) 
                 (nm) 
                 (nm) 
                 efficiency 
                 temperature 
                 (85° C.) 
                 Remarks 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 201 
                 75 
                 1.74 
                 80 
                 557 
                 1.75 
                 231 
                 539 
                 −18 
                 100 
                 100 
                 100 
                 Comp. 
               
               
                 202 
                 85 
                 1.74 
                 80 
                 557 
                 1.75 
                 241 
                 562 
                 5 
                 105 
                 106 
                 125 
                 Inv. 
               
               
                   
               
               
                 Comp.: Comparative example 
               
               
                 Inv.: Inventive example 
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 3 
               
               
                   
               
               
                   
                 Layer 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Organic 
                 thickness 
               
               
                 EL 
                 (nm) of 
                   
                   
                 n 1 d 1  × 
                   
                   
                 n 2 d 2  × 
                   
                   
                 Lifetime at 
                 Driving 
               
               
                 element 
                 Second hole 
                   
                 d 1   
                 4/1:A 
                   
                 d 2   
                 4/3:B 
                 B − A 
                 Power 
                 normal 
                 lifetime 
               
               
                 No. 
                 transport layer (nm) 
                 n 1   
                 (nm) 
                 (nm) 
                 n 2   
                 (nm) 
                 (nm) 
                 (nm) 
                 efficiency 
                 temperature 
                 (85° C.) 
                 Remarks 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 301 
                 53 
                 1.80 
                 66 
                 475 
                 1.81 
                 195 
                 471 
                 −4 
                 100 
                 100 
                 100 
                 Comp. 
               
               
                 302 
                 63 
                 1.80 
                 66 
                 475 
                 1.81 
                 205 
                 495 
                 20 
                 104 
                 113 
                 122 
                 Inv. 
               
               
                   
               
               
                 Comp.: Comparative example 
               
               
                 Inv.: Inventive example 
               
            
           
         
       
     
     (6) Summary 
     As is apparent from the results indicated in Tables 1 to 3, the organic EL element of the present invention is superior to the organic EL element of the comparative example in terms of power efficiency, driving lifetime at normal temperature, and driving lifetime at 85° C. 
     From the above-described results, it is proved that it is useful to make the following embodiment: 
     a largest maximum emission wavelength λ N(max)  in an EL spectrum of the emission dopant in the light emitting layer of the N-th light emitting unit and a largest maximum emission wavelength λ N+1(max)  in an EL spectrum of the emission dopant in the light emitting layer of the (N+1)-th light emitting unit are made to have a difference (λ N+1(max) −λ N(max) ) in the range of 1 to 50 nm. 
     INDUSTRIAL APPLICABILITY 
     The present invention may be suitably applied to provide an organic EL element of high efficiency and long life. 
     DESCRIPTION OF SYMBOLS 
     
         
           1 : Organic EL element 
           2 : Semi-transparent electrode 
           4 : First light emitting unit
         4   a : Layer having a hole transport property     4   b : Light emitting layer     4   c : Layer having an electron transport property     
           6 : Charge generating unit 
           8 : Second light emitting unit
         8   a : Layer having a hole transport property     8   b : Light emitting layer     8   c : Layer having an electron transport property     
           10 : Reflective electrode 
         A N : Absorption spectrum 
         E N  and E N+1 : EL spectrum 
         S: Overlapped portion