Patent Publication Number: US-2023134246-A1

Title: Circuit board, semiconductor device, and method of manufacturing circuit board

Description:
CROSS-REFERENCE TO RELATED APPLICATION 
     This application is based upon and claims the benefit of priority of the prior Japanese Patent Application No. 2021-178332, filed on Oct. 29, 2021, the entire contents of which are incorporated herein by reference. 
     FIELD 
     The embodiment discussed herein is related to a circuit board, a semiconductor device, and a method of manufacturing a circuit board. 
     BACKGROUND 
     A semiconductor device is formed, for example, by mounting electronic parts, such as a Si interposer and a die, in a mount area of a circuit board. For example, an encapsulating resin that is referred to as an underfill and that is used to increase connection reliability is poured into an intermediate area between the electronic parts and the mount area, thereby protecting connection terminals that electrically connect the electronic parts and the mount area. When pouring the underfill into the intermediate area, however, a bleeding out in which the underfill flows out of the intermediate area into an area not requiring the underfill sometimes occurs. Thus, a dam member that is formed on a surface of a solder resist layer such that an insulating layer surrounds the mount area in order to avoid the underfill from bleeding out is known. 
     Patent Literature 1: Japanese Laid-open Patent Publication No. 2009-010073 
     Patent Literature 2: Japanese Laid-open Patent Publication No. 2017-157701 
     In a conventional dam member, however, for example, when an angle at which an inner wall surface of each corner part of the dam member is set is a right angle or an acute angle when viewed from a surface of the solder resist layer, the underfill that is poured into the mount area does not reach the corner parts sufficiently and voids occur in the underfill. Furthermore, because of the effect of the shape of the dam member described above, voids tend to remain in the underfill. Furthermore, because of thermal expansion of the voids having occurred, a crack may occur near the solder resist layer or the dam member that is formed of the resin material. 
     SUMMARY 
     According to an aspect of an embodiment, a circuit board includes an insulating layer that is layered on a substrate; and a dam member in a form of a rectangular frame that is formed on the insulating layer. A corner part of the dam member includes a slope that slopes down from an inner wall surface to a surface of the insulating layer in a lower part that makes contact with the surface of the insulating layer; and a perpendicular part that is perpendicular to the surface of the insulating layer in an upper part separated from the surface of the insulating layer. 
     The object and advantages of the invention will be realized and attained by means of the elements and combinations particularly pointed out in the claims. 
     It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory and are not restrictive of the invention, as claimed. 
    
    
     
       BRIEF DESCRIPTION OF DRAWINGS 
         FIG.  1    is an illustration of an example of a semiconductor device of an embodiment; 
         FIG.  2    is an illustration of an example of a dam member in a circuit board; 
         FIG.  3    is a plane schematic view illustrating an example of the dam member; 
         FIG.  4    is a cross-sectional schematic view taken along the line A-A and illustrating an example of a corner part of the dam member; 
         FIG.  5    is a cross-sectional schematic view taken along the line B-B and illustrating an example of a straight line part of the dam member; 
         FIG.  6    is a flowchart illustrating an example of a procedure of a process of manufacturing a semiconductor device; 
         FIG.  7    is an illustration of an example of a circuit layer forming step; 
         FIG.  8    is an illustration of an example of a first SR forming step; 
         FIG.  9    is an illustration of an example of an opening forming step; 
         FIG.  10    is an illustration of an example of a second SR forming step; 
         FIG.  11    is an illustration of an example of a dam forming step; 
         FIG.  12    is an illustration of an example of a barrier layer forming step; 
         FIG.  13    is an illustration of an example of a bump forming step; 
         FIG.  14    is an illustration of an example of a mounting step; 
         FIG.  15    is an illustration of an example of a semiconductor device: 
         FIG.  16    is an illustration of an example of a semiconductor device of a comparative example; and 
         FIG.  17    is an illustration of an example of a semiconductor device of a comparative example. 
     
    
    
     DESCRIPTION OF EMBODIMENT 
     With reference to the accompanying drawings, an embodiment of a circuit board, a semiconductor device, and a method of manufacturing a circuit board disclosed herein will be described in detail below. Note that the embodiment does not limit the disclosure. 
     Embodiment 
       FIG.  1    is an illustration of an example of a semiconductor device  1 A of an embodiment. The semiconductor device  1 A illustrated in  FIG.  1    includes a circuit board  1  and electronic parts  5 . The circuit board  1  is, for example, a build-up board. The circuit board  1  includes a resin substrate  2 , a circuit layer  3 , a first solder resist (SR) layer  4 , and a dam member  6 . It is described below that the resin substrate  2  is the lowest layer and the first SR layer  4  is the top layer as illustrated in  FIG.  1   ; however, the circuit board  1  may be used in a vertically-flipped manner or may be used in any posture. Note that the circuit layer  3  is held in a given positon on the resin substrate  2 . The resin substrate  2  and the circuit layer  3  are covered with the first SR layer  4 . 
     The first SR layer  4  is a layer that covers the circuit layer  3  that is arranged on the surface of the resin substrate  2  and protects the circuit layer  3 . Note that the first SR layer  4  is one type of an insulating layer. An opening  4 A is provided in the first SR layer  4  in a mount area  4 B in which the electronic parts  5  are mounted and connection bumps  8  electrically connect the circuit layer  3  and the electronic parts  5 . The electronic parts  5  include an Si interposer  5 A and a die  5 B, such as a semiconductor chip, that is mounted on the Si interposer  5 A. 
       FIG.  2    is an illustration of an example of a dam member  6  in the circuit board  1  and  FIG.  3    is a plane schematic view illustrating an example of the dam member  6 . The dam member  6  is a dam member in a form of a rectangular frame that surrounds the rectangular mount area  4 B of the first SR layer  4  on which the electronic parts  5  are mounted and that dams an underfill  7  that is supplied to the mount area  4 B when the electronic parts  5  are mounted. The dam member  6  includes an inner wall surface  6 A that is a wall surface of a dam body on the side of the mount area  4 B, an outer wall surface  6 B that is a wall surface of the dam body on the side opposite to the mount area  4 B, and a top surface  6 C of the dam body. The dam member  6  is in a form of a rectangular frame and thus includes straight line parts  6 E of four sides and corner parts  6 D at four corners. 
       FIG.  4    is a cross-sectional schematic view t taken along the line A-A and illustrating an example of the corner part  6 D of the dam member  6 . The inner wall surface  6 A of each of the corner parts  6 D illustrated in  FIG.  4    has a perpendicular part  14  that is perpendicular to a surface of the first SR layer  4  in an upper part separated from the surface of the first SR layer  4  and a slope  11  in a shape of a skirt that slopes down from the inner wall surface  6 A toward the mount area  4 B to the surface of the first SR layer  4  in a lower part that makes contact with the surface of the first SR layer  4 . The slope  11  slopes down from one end of the inner wall surface  6 A to the mount area  4 B and therefore the underfill  7  that is supplied reaches also the corners of the corner parts  6 D. A maximum height dimension B between the slope  11  and the surface of the first SR layer  4  is equal to or smaller than 20% of a maximum height A between the top surface  6 C and the surface of the first SR layer  4 . An angle at which the slope  11  is set with respect to the surface of the first SR layer  4  is, for example, equal to or smaller than 20 degrees. The height dimension of the perpendicular part  14  is, for example, a difference of (the height dimension A - the height dimension B). The outer wall surface  6 B of the corner part  6 D has a receding part  12  in an undercut form that is formed in a lower part of the outer wall surface  6 B that makes contact with the surface of the first SR layer  4 . The receding part  12  recedes inward on the outer wall surface  6 B, for example, an encapsulating resin that is supplied when the circuit board  1  is encapsulated thus flows into the receding part  12 , and accordingly a sufficient anchor effect is obtained. 
       FIG.  5    is a cross-sectional schematic view taken along the line B-B and illustrating an example of a straight line part  6 E of the dam member  6 . The inner wall surface  6 A of the straight line part  6 E has a receding part  13  in an under-cut form that is formed in a lower part of the inner wall surface  6 A that makes contact with the surface of the first SR layer  4 . The receding part  13  recedes inward on the inner wall surface  6 A, the underfill  7  that is supplied thus flows into the receding part  13 , and accordingly a sufficient anchor effect is obtained. 
     A process of manufacturing the semiconductor device  1 A will be described next.  FIG.  6    is a flowchart illustrating an example of a procedure of the process of manufacturing the semiconductor device  1 A. According to  FIG.  6   , a circuit layer forming step of forming the circuit layer  3  on the resin substrate  2  is executed as the process of manufacturing the circuit board  1  (step S 11 ). After the circuit layer forming step is executed, a first SR layer forming step of forming the first SR layer  4  on the resin substrate  2  and the circuit layer  3  is executed as the manufacturing process (step S 12 ). 
     Furthermore, after the first SR forming step is executed, an opening forming step of forming openings  4 A in the mount area  4 B on the first SR layer  4  is executed as the manufacturing process (step S 13 ). Note that the opening  4 A is an opening for forming a via for connection to the circuit layer  3 . After the opening forming step is executed, a second SR layer forming step of forming a second SR layer  21  on the first SR layer  4  is executed as the manufacturing process (step S 14 ). 
     Furthermore, after the second SR layer forming step is executed, a dam forming step of forming the dam member  6  in the second SR layer  21  around the mount area  4 B on the first SR layer  4  is executed as the manufacturing process (step S 15 ). After the dam forming step is executed, a barrier layer forming step of forming a barrier layer  3 A on the circuit layer  3  that is exposed from the opening  4 A of the first SR layer  4  is executed as the manufacturing process (step S 16 ). 
     After the barrier layer forming step is executed, a bump forming step of forming the connection bumps  8  on the barrier layer  3 A in the openings  4 A of the first SR layer  4  is executed as the manufacturing process (step S 17 ). Furthermore, after the bump forming step is executed, the electronic parts  5  are mounted on the connection bumps  8  in the mount area  4 B and the underfill  7  is poured into the mount area  4 B as the manufacturing process. By pouring the underfill  7 , a mounting step of mounting the electronic parts  5  in the mount area  4 B of the first SR layer  4  is executed (step S 18 ). Note that, even when the underfill  7  is poured into the mount area  4 B, the underfill  7  reaches the corner parts  6 D because of the slopes  11  of the corner parts  6 D in the dam member  6  and thus it is possible to prevent bleeding out while inhibiting occurrence of voids. 
       FIG.  7    is an illustration of an example of the circuit layer forming step. At the circuit layer forming step of step S 11 , as illustrated in  FIG.  7   , for example, the circuit layer  3  is formed on the resin substrate  2 . Specifically, a photosensitive resin layer is formed on the resin substrate  2  and exposure and development is performed. Accordingly, a plating resist pattern is formed on the resin substrate  2 . Furthermore, by executing electrolyte copper plating on the resin substrate  2  after formation of the plating resist pattern, a copper plating layer is formed on the resin substrate  2  that is exposed from the plating resist pattern. Removing the plating resist pattern from the resin substrate  2  forms, for example, the circuit layer  3  on the resin substrate  2 . 
       FIG.  8    is an illustration of an example of the first SR forming step. In the first SR forming step at step S 12 , as illustrated in  FIG.  8   , the first SR layer  4  is formed on the resin substrate  2  on which the circuit layer  3  is formed. Specifically, for example, insulating photosensitive resin, such as acrylic resin or polyimide resin, is laminated and is layered on the resin substrate  2 , so that the first SR layer  4  is formed on the resin substrate  2 . A thickness dimension of the first SR layer  4  is, for example, within a range of 10 to 30 µm. Note that, although the insulating photosensitive resin is exemplified, the first SR layer  4  may be formed using, for example, insulating non-photosensitive resin, such as epoxy resin. 
       FIG.  9    is an illustration of an example of the opening forming step. At the opening forming step of step S 13 , as illustrated in  FIG.  9   , the openings  4 A are formed in the first SR layer  4 . Specifically, for example, after the acrylic resin or polyimide resin is cured, the openings  4 A are formed in given positions on the first SR layer  4  by laser processing or photolithography. The openings  4 A that are formed on the first SR layer  4  expose part of the circuit layer  3  under the openings  4 A. Note that the opening dimension of the opening  4 A is, for example, within a range of 10 to 100 µm. 
       FIG.  10    is an illustration of an example of the second SR forming step on the circuit board  1 . At the second SR forming step of step S 14 , as illustrated in  FIG.  10   , the second SR layer  21  is formed on the first SR layer  4  in which the openings  4 A are formed. Specifically, for example, insulating photosensitive resin, such as acrylic resin or polyimide resin, is laminated and layered on the first SR layer  4 , so that the second SR layer  21  is formed on the first SR layer  4 . The thickness dimension of the second SR layer  21  is, for example, within a range of 10 to 30 µm. Note that the second SR layer  21  may be formed using an insulating non-photosensitive resin, such as epoxy resin. 
       FIG.  11    is an illustration of an example of the dam forming step. As illustrated in  FIG.  11   , using the second SR layer  21 , the dam member  6  is formed on the first SR layer  4  such that the dam member  6  surrounds the mount area  4 B in the first SR layer  4 . Specifically, for example, the dam member  6  is formed on the first SR layer  4   using the second SR layer  21  through exposure, development, and the process of curing the acrylic resin. The slope  11  is formed on the inner wall surface  6 A of the corner part  6 D by making an adjustment such that a first exposure on the inner wall surface  6 A of the corner part  6 D of the dam member  6  is larger than a second exposure on the straight line part  6 E and making an exposure by the first exposure. The receding part  12  is formed in the lower part of the outer wall surface  6 B by making an adjustment such that the second exposure on the outer wall surface  6 B of the corner part  6 D is lower than the first exposure and making an exposure by the second exposure. As a result, the slope  11  that is a downslope at a slope angle within 20 degrees with respect to the surface of the first SR layer  4  is formed on the inner wall surface  6 A of the dam member  6 . Note that the width dimension of the top surface  6 C of the dam member  6  is, for example, 100 to 1000 µm, the length dimension of the slope  11  is, for example, 30 µm or smaller, and the depth dimension (undercut length) of the receding part  12  is, for example, 30 µm or smaller. The distance dimension from the end of the mount area  4 B to the slope  11  is, for example, within the range of 50 µm to 5 mm. 
       FIG.  12    is an illustration of an example of the barrier layer forming step. At the barrier layer forming step of step S 16 , as illustrated in  FIG.  12   , the barrier layer  3 A is formed on the circuit layer  3  that is exposed in each of the openings  4 A in the mount area  4 B. Specifically, the barrier layer  3 A is formed by forming an organic film for preventing oxidation, electroless NiPdAu plating, or the like. 
       FIG.  13    is an illustration of an example of the bump forming step. At the bump forming step of step S 17 , after the barrier layer forming step is executed, as illustrated in  FIG.  13   , the connection bumps  8  are formed in the openings  4 A in the first SR layer  4 . Note that the connection bumps  8  are formed by the same manufacturing method as the method of manufacturing the circuit layer  3 . 
       FIG.  14    is an illustration of an example of the mounting step. The semiconductor device  1 A is configured by mounting the electronic parts  5  on the circuit board  1  illustrated in  FIG.  14   . The electrodes on the bottom surface of the electronic parts  5  are joined to the connection bumps  8  by solder, or the like. Furthermore, the joints between the electrodes of the electronic parts  5  in the mount area  4 B and the connection bumps  8  on the circuit board  1  are encapsulated by the underfill  7 , so that the electronic parts  5  are mounted on the circuit board  1 . Even when the underfill  7  is poured into the mount area  4 B, the dam member  6  dams the underfill  7 . Pouring the underfill  7  into the intermediate area between the mount area  4 B and the Si interposer  5 A enables protection of the connection bumps  8 . The underfill  7  reaches the corner parts  4 D sufficiently because of presence of the slopes  11  in the corner parts  6 D of the dam member  6  and therefore occurrence of voids can be inhibited. Note that the underfill material used herein is normal liquid thermoset resin (epoxy resin is the base resin). 
       FIG.  15    is an illustration of an example of the semiconductor device  1 A. It is a configuration in which external connection terminals  31  and an insulating layer  32  are provided on pads P on the side of a bottom surface of the resin substrate  2  in a lower part of the semiconductor device  1 A illustrated in  FIG.  14   . The semiconductor device  1 A illustrated in  FIG.  15    is formed in a way that the insulating layer  32  is formed by layering on the side of the bottom surface of the resin substrate  2  at the same timing as that at which the first SR layer  4  is formed, openings are provided in the insulating layer  32  such that the pads P on the side of the bottom surface of the resin substrate  2  are exposed, and the external connection terminals  31  are formed using solder balls, or the like. 
       FIG.  16    is an illustration of an example of a semiconductor device  100  of a comparative example. Note that a circuit board of the semiconductor device  100  of the comparative example is different from the circuit board  1  of the semiconductor device  1 A of the embodiment in that, for example, the angle at which an inner wall surface  111 A of a corner part of a dam member  111  with respect to the surface of the first SR layer  4  is a right angle. In the circuit board of the semiconductor device  100  of the comparative example illustrated in  FIG.  16   , voids X may occur because the angle at which the inner wall surface  111 A is set with respect to the surface of the first SR layer  4  is a right angle and thus the underfill  7  would not reach the corner parts of the inner wall surface  111 A. On the other hand, the circuit board  1  of the embodiment has the slope  11  that slopes down from the inner wall surface  6 A of the corner part  6 D of the dam member  6  surrounding the mount area  4 B to the surface of the first SR layer  4 . As a result, the underfill  7  sufficiently reaches the corner parts  6 D of the inner wall surface  6 A and thus occurrence of voids X can be prevented. 
       FIG.  17    is an illustration of a semiconductor device  100 A of a comparative example. Note that a circuit board of the semiconductor device  100 A of the comparative example is different from the circuit board  1  of the semiconductor device  1 A of the embodiment in that, for example, the angle at which an inner wall surface  121 A of a corner part of a dam member  121  with respect to the surface of the first SR layer  4  is an acute angle. In the circuit board of the semiconductor device  100 A of the comparative example illustrated in  FIG.  17   , voids X may occur because the angle at which the inner wall surface  121 A is set with respect to the surface of the first SR layer  4  is an acute angle and thus the underfill  7  would not reach the corner parts of the inner wall surface  121 A. On the other hand, the circuit board  1  of the embodiment has the slope  11  that slopes down from the inner wall surface  6 A of the corner part  6 D of the dam member  6  surrounding the mount area  4 B to the surface of the first SR layer  4 . As a result, the underfill  7  sufficiently reaches the corner parts  6 D of the inner wall surface  6 A and thus occurrence of voids X can be prevented. 
     Also when the dam member surrounding the mount area is tapered with the angle at which the inner wall surface is set exceeding 90 degrees when viewed from the mount area, voids X may occur because the underfill would not reach the corner part of the inner wall surface of the dam member. On the other hand, the circuit board  1  of the embodiment has the slope  11  that slopes down from the inner wall surface  6 A of the corner part  6 D of the dam member  6  surrounding the mount area  4 B to the surface of the first SR layer  4 . As a result, the underfill  7  sufficiently reaches the corner parts  6 D of the inner wall surface  6 A and thus occurrence of voids X can be prevented. 
     In the circuit board  1  of the present embodiment, the inner wall surface  6 A of each corner part  6 D of the dam member  6  has the slope  11  sloping down from the inner wall surface  6 A toward the mount area  4 B to the surface of the first SR layer  4 . Forming the slopes  11  on the inner wall surface  6 A of the corner parts  6 D causes the underfill  7  that is poured into the mount area  4 B to reach each corner part  6 D along the slope  11 . As a result, occurrence of voids X can be inhibited. 
     The inner wall surface  6 A of the straight line part  6 E of the dam member  6  has the receding part  13  that is formed in the lower part of the inner wall surface  6 A that makes contact with the surface of the first SR layer  4 . As a result, the underfill  7  that is supplied flows into the receding part  13  and thus a sufficient anchor effect is obtained. Moreover, bubbles that occur flow into the corner parts  6 D and this reduces the concern about remaining of voids X. 
     The outer wall surface  6 B of each corner part  6 D of the dam member  6  has the receding part  12  that is formed in the lower part of the outer wall surface  6 B that makes contact with the surface of the first SR layer  4 . As a result, the encapsulating resin that is supplied to encapsulate the circuit board  1  flows into the receding part  12  and thus a sufficient anchor effect is obtained. 
     The maximum height dimension B between the slope  11  and the surface of the first SR layer  4  is equal to or smaller than 20% of the maximum height A between the top surface  6 C of the dam member  6  and the surface of the first SR layer  4 . As a result, it is possible to form the slope  11  that is a downslope from the inner wall surface  6 A to the surface of the first SR layer  4  such that the underfill  7  reaches the inside of the corner part  6 D. 
     The dam member  6  is formed of the same material as that of the first SR layer  4 . As a result, the binding force between the dam member  6  and the first SR layer  4  is increased and thus it is possible to inhibit occurrence of cracks between the first SR layer  4  and the dam member  6 . 
     The lower part of the inner wall surface  6 A of the dam member  6  is the slope  11  that is curved and therefore the air comes out easier than in the case where the inner wall surface  6 A is straight or has an inverse tapered shape. In other words, reducing the angle at which the inner wall surface  6 A of the dam member  6  is set with respect to the surface of the first SR layer  4  as according to the present application causes the air to go out easily and increases, which increases the effect of inhibiting voids X. 
     In the dam forming step of forming the dam member  6 , the inner wall surface  6 A and the outer wall surface  6 B are formed using the second SR layer  21 . Furthermore, in the dam forming step, using the second SR layer  21 , the slope  11  that slopes down from the inner wall surface  6 A of each corner part  6 D of the dam member  6  toward the mount area  4 B to the surface of the first SR layer  4  is formed on the inner wall surface  6 A of each corner part  6 D. As a result, it is possible to increase the binding force between the dam member  6  and the surface of the first SR layer  4  using the second SR layer  21  of which material is the same as that of the first SR layer  4 . 
     In the dam forming step, the slope  11  is formed by the first exposure on the inner wall surface  6 A of the corner part  6 D and the receding part  12  is formed in the lower part of the outer wall surface  6 B making contact with the first SR layer  4  by the second exposure smaller than the first exposure on the outer wall surface  6 B. Changing the exposure enables formation of the slope  11  and the receding part  12 . 
     It is necessary to provide a margin between the openings  4 A in the mount area  4 B on which the electronic parts  5  are mounted and the dam member  6 ; however, tapering both the inner wall surface and the outer wall surface of the dam member narrows the margin between the openings  4 A  and the dam member, which limits the design. On the other hand, the dam member  6  of the embodiment has the configuration in which only the corner parts  6 D are provided with the slopes  11  and thus a margin between the openings  4 A and the dam member  6  is ensured, which reduces the limitation on the design. 
     For convenience of description, the case where the dam member  6  is formed of the SR material is illustrated; however, for example, there are also a coverlay material (an adherent film member) or a liquid insulating material (a material with a high viscosity). A material with openings that are formed by punching may be positioned on and attached to the substrate as the coverlay material. The liquid insulating material may be applied and formed into a shape of a dam with a width/height of few hundreds mm to few mm. When the dam member  6  is formed of the SR material, positioning accuracy of positioning the slopes  11  is high, which increases dimensional accuracy of the dam member  6 . 
     The configuration in which the inner wall surface  6 A of each corner part  6 D has the slope  11  is exemplified as the dam member  6 ; however, the inner wall surface  6 A of every corner part  6 D need not necessarily have the slope  11 . For example, depending on the direction and flow in which the underfill  7  is injected, the presence of the slope  11  on the inner wall surface  6 A of at least one corner part  6 D makes it possible to inhibit voids X in the underfill  7 . 
     The case where the Si interposer  5 A and the die  5 B are included as the electronic parts  5  is exemplified; however, the die  5 B may be mounted in the mount area  4 B and changes can be made as appropriate. 
     In one embodiment as described above, a method of manufacturing a circuit board, the method includes:
     forming a first solder resist layer on a substrate;   forming a second solder resist layer on the first solder resist layer; and   forming a dam member in a form of a rectangular frame by performing exposure and development on the second resist layer,   wherein the forming the dam member includes forming a slope that slopes down from an inner wall surface of a corner part of the dam member to a surface of the first solder resist layer by   exposing the inner wall surface of the corner part of the dam member by a first exposure, and   exposing an outer wall surface of the corner part of the dam member by a second exposure smaller than the first exposure.   

     According to a mode of the circuit board disclosed herein, for example, because the underfill that is poured into the mount area reaches the corner parts along the slopes, it is possible to inhibit occurrence of voids X. 
     All examples and conditional language recited herein are intended for pedagogical purposes of aiding the reader in understanding the invention and the concepts contributed by the inventor to further the art, and are not to be construed as limitations to such specifically recited examples and conditions, nor does the organization of such examples in the specification relate to a showing of the superiority and inferiority of the invention. Although the embodiment of the present invention has been described in detail, it should be understood that the various changes, substitutions, and alterations could be made hereto without departing from the spirit and scope of the invention.