Patent Publication Number: US-8534906-B2

Title: Vacuum kneading and deaerating device

Description:
This application is a U.S. National Phase Application under 35 USC 371 of Interrnational Application PCT/JP2011/062568 filed Jun. 1, 2011. 
     TECHNICAL FIELD 
     The present invention relates to a vacuum kneading and deaerating device. 
     BACKGROUND ART 
     For example, paste materials used as sealing compounds for liquid crystals, semiconductor elements, etc., conductive paste materials, resistor paste materials, or medical paste materials such as preparation pastes for ointments are required to be used in a state sufficiently kneaded and deaerated. Such a paste material is also often required to mix and disperse, for example, two or more liquids which are high in viscosity and different in specific gravity value, or a liquid and powder which are different in specific gravity. 
     Devices of various types are proposed as a kneading and deaerating device for kneading and deaerating a paste material at present. For example, there is proposed a device of the construction that a container holder detachably holding, for example, a cup-like paste container, in which a paste material to be kneaded has been contained, is rotated on an operating rotation axis parallel to a basic driving rotation axis extending in a vertical direction while being revolved around the basic driving rotation axis, thereby kneading the paste material and releasing (decorating) bubbles mixed in the paste material making good use of centrifugal force (see, for example, Patent Literature 1). 
     There is also proposed a kneading and deaerating device of the construction that the interior of a paste container is held under a pressure-reduced condition for efficiently releasing bubbles mixed in a paste material to conduct such a kneading and deaerating treatment as described above (see, for example, Patent Literature 2). 
     However, since these paste materials are generally used in a state filled into, for example, a syringe, a possibility that when the paste material subjected to the kneading and deaerating treatment is transferred from the paste container to the syringe, a gas may be entrained therein comes to be increased, so that there is a problem that the kneading and deaerating treatment already performed may possibly come to nothing. 
     In order to solve such a problem, there is proposed a kneading and deaerating device of the construction that after a paste material is contained in a closed syringe-like container, a kneading and deaerating treatment is conducted (see, for example, Patent Literature 3). 
     CITATION LIST 
     Patent Literature 
     
         
         Patent Literature 1: Japanese Patent Application Laid-Open No. 06-343913 
         Patent Literature 2: Japanese Patent No. 3627220 
         Patent Literature 3: Japanese Patent Application Laid-Open No. 2006-130492 
       
    
     SUMMARY OF INVENTION 
     Technical Problem 
     However, in the kneading and deaerating device of the construction that after the paste material is contained in the closed syringe-like container, the interior of the syringe-like container is held under a pressure-reduced condition to conduct the kneading and deaerating treatment, it is impossible to discharge the gas released in the syringe-like container by the deaerating action during the operation of the device to the outside of the syringe-like container, so that there is a problem that bubbles remain in the paste material even after the treatment, i.e., the deaeration is insufficient. 
     The present invention has been made on the basis of the foregoing circumstances and has as its object the provision of a vacuum kneading and deaerating device capable of uniformly and sufficiently kneading a paste material contained in a cylindrical paste container and sufficiently discharging (deaerating) bubbles mixed in the paste material with a high efficiency. 
     Solution to Problem 
     A vacuum kneading and deaerating device according to the present invention comprises a rotating body for revolution, which is provided rotationably in a horizontal plane around a basic driving rotation axis extending in a vertical direction in a chamber the internal space of which has been held under closed or pressure-reduced condition, a container holding means which is provided in the chamber rotationably on an operating rotation axis extending in a vertical direction in a revolution, edge portion of the rotating body for revolution and detachably holds a cylindrical paste container, in which a paste material to be kneaded and deaerated has been contained, in a state that a central axis of the paste container obliquely intersects the operating rotation axis, and a driving mechanism for rotating the rotating body for revolution and the container holding means, wherein 
     a deaeration valve for opening an internal space of the paste container to the internal space of the chamber by the action of centrifugal force going outward in a radial direction of the rotating body for revolution attending on the revolution and rotation of the paste container is provided in an opening portion of the paste container for placing the paste material in the paste container. 
     In the vacuum kneading and deaerating device according to the present invention, the deaeration valve may be so constructed that it comprises a holder installed in a state that an end portion having the opening portion of the paste container has been received and having a through-hole formed at its center, and a valve disc having a stem portion inserted into the through-hole through a minute interstice formed with an inner peripheral surface of the through-hole of the holder, and 
     the valve disc is slidably provided between a closing position brought into contact with an inner surface of the holder by the action of the centrifugal force going outward in the radial direction of the rotating body for revolution attending on the revolution and rotation of the paste container so as to block up the minute interstice, thereby closing the internal space of the paste container, and an opening position separated from the inner surface of the holder by the action of the centrifugal force going outward in the radial direction of the rotating body for revolution attending on the revolution and rotation of the paste container so as to cause the internal space of the paste container to communicate with the internal space of the pressure-reduced chamber through the minute interstice. 
     In the vacuum kneading and deaerating device according to the present invention, the valve disc may be so constructed that it further comprises a pressure-receiving plate in such a manner that the valve disc is moved to the closing position by the fact that the paste material contained in the paste container receives the centrifugal force going outward in the radial direction of the rotating body for revolution attending on the revolution and rotation of the paste container to press the pressure-receiving plate outward. 
     Another vacuum kneading and deaerating device according to the present invention comprises a rotating body for revolution, which is provided rotationably in a horizontal plane around a basic driving rotation axis extending in a vertical direction in a chamber the internal space of which has been held under a closed or pressure-reduced condition, a container holding means which is provided in the chamber rotationably on an operating rotation axis extending in a vertical direction in a revolution edge portion of the rotating body for revolution and detachably holds a cylindrical paste container, in which a paste material to be kneaded and deaerated has been contained, in a state that a central axis of the paste container obliquely intersects the operating rotation axis, and a driving mechanism for rotating the rotating body for revolution and the container holding means, wherein 
     a paste material-impermeable and gas-permeable membrane, through which the paste material in the paste container is not permeated, but a gas released from the paste material is permeated, is provided in an opening portion of the paste container for placing the paste material in the paste container. 
     In the vacuum kneading and deaerating device according to the present invention, the gas-permeable membrane may preferably have a thickness of at least 60 μm and a pore size ranging from at least 0.02 μm to at most 20 μm. 
     Advantageous Effects of Invention 
     According to the vacuum kneading and deaerating device of the present invention, the paste container conducts orbital motion and precession at the same time under, for example, reduced pressure, thereby achieving sufficient kneading and deaerating actions on the paste material in the paste container fundamentally, so that the paste material in the paste container can be uniformly and sufficiently kneaded as a whole. In addition, the deaeration valve operated by the action of the centrifugal force, or the paste material-impermeable and gas-permeable membrane is provided in the opening portion of the paste container for placing the paste material, whereby the gas released in the internal space of the paste container by the deaerating action can be discharged out of the paste container to maintain the interior of the paste container at a proper degree of vacuum, so that the deaeration can be sufficiently conducted with a high efficiency, and the paste material after the treatment is provided as an even- and high-quality product. 
     Further, after the predetermined treatment is conducted, the paste container containing the paste material can be used in the present state as it is, so that the working efficiency can be improved, and it can be avoided to cause such an inconvenience that the quality of a final product using the paste material is lowered by mixing gas in the paste material again. 
    
    
     
       BRIEF DESCRIPTION OF DRAWINGS 
       [FIG. 1] is an explanatory sectional view schematically illustrating the fundamental construction of an exemplary vacuum kneading and deaerating device according to a first embodiment of the present invention. 
       [FIG. 2] is a plan view of the vacuum kneading and deaerating device illustrated in  FIG. 1  viewed from the above in a vertical direction. 
       [FIGS. 3](A) and (B) are an explanatory views for explaining the operation of a deaeration valve provided in a paste container used in the vacuum kneading and deaerating device according to the first embodiment of the present invention. 
       [FIGS. 4](A) and (B) are an explanatory views for explaining kneading and deaerating actions caused on a paste material contained in the paste container in the vacuum kneading and deaerating device according to the first embodiment of the present invention. 
       [FIGS. 5](A) and (B) are an explanatory views for explaining the action of a gas-permeable membrane provided in a paste container used in a vacuum kneading and deaerating device according to a second embodiment of the present invention. 
       [FIGS. 6](A) and (B) are an explanatory views for explaining the operation of another deaeration valve provided in the paste container in the vacuum kneading and deaerating device according to the first embodiment of the present invention. 
     
    
    
     DESCRIPTION OF EMBODIMENTS 
     Embodiments of the present invention will hereinafter be described in detail. 
     &lt;First Embodiment&gt; 
       FIG. 1  is an explanatory sectional view schematically illustrating the fundamental construction of an exemplary vacuum kneading and deaerating device according to the first embodiment of the present invention, and  FIG. 2  is a plan view of the vacuum kneading and deaerating device illustrated in FIG. viewed from the above in a vertical direction. 
     This vacuum kneading and deaerating device is equipped with a cylindrical chamber  10  forming a closed space in the interior thereof, a drive motor  18  having a driving rotation shaft  11  for revolution, which is rotationally driven on a central axis of rotation which is set as a basic driving rotation axis A, extending in a vertical direction, a disk-like rotating plate  15  for revolution, which is rotated in a horizontal plane on the basic driving rotation axis A, an operating rotation shaft  21  for rotation, which is provided rotationably on a central axis of rotation which is set as an operating rotation axis B 1 , extending in parallel with the basic driving rotation axis A, a plurality of driven rotation shafts  25  for rotation, which are respectively provided rotationably on central axes of rotation which are set as operating rotation axes B 2  to B 4  extending in parallel with the basic driving rotation axis A, a driving mechanism  30  of the operating rotation shaft for rotation for rotationally driving the operating rotation shaft  21  for rotation, a power transmission mechanism  40  for rotationaly driving the operating rotation shaft  21  for rotation and the respective driven rotation shafts  25  for rotation in a state synchronized with one another, and a pressure-reducing means (not illustrated) for rendering the interior of the chamber  10  a pressure-reduced condition, for example, a vacuum condition. 
     The drive motor  18  is arranged in such a mariner that the driving rotation shaft  11  for revolution extends airtightly through a bottom wail of the chamber  10  in a vertical direction (upward or downward direction in  FIG. 1 ). 
     The rotating plate  15  for revolution is fixed to an upper end of the driving rotation shaft  11  for revolution so as to extend along a direction perpendicular to the basic driving rotation axis A. 
     The operating rotation shaft  21  for rotation is provided in a state extending through the rotating plate  15  for revolution in a thickness-wise direction thereof via, for example, bearings (not illustrated) in a revolution edge portion (right edge portion in  FIG. 1 ) that conducts circular motion by the revolution of the rotating plate  15  for revolution. 
     The respective driven rotation shafts  25  for rotation are fixed at the proximal end portions thereof to the rotating plate  15  for revolution at positions separated at equal intervals in a circumferential direction from the operating rotation axis B 1  on a circumference, on which the operating rotation axis B 1  is located in the rotating plate  15  for revolution, via, for example, bearings (not illustrated). 
     The driving mechanism  30  of the operating rotation shaft for rotation is constructed by a fixed pulley  31  fixed to an upper surface of the bottom wall of the chamber  10  in a state that the driving rotation shaft  11  for revolution has been inserted (in a state independent of the driving rotation shaft  11  for revolution), a driving pulley  32  for rotation fixed at the same horizontal level position as the fixed pulley  31  in a proximal end portion of the operating rotation shaft  21  for rotation, and a decelerating timing belt  35  provided between the fixed pulley  31  and the driving pulley  32  for rotation by, for example, open belting. This driving mechanism  30  of the operating rotation shaft for rotation rotationally drives the operating rotation shaft  21  for rotation in such a manner that the direction of rotation thereof becomes a reverse direction (clockwise direction in  FIG. 2 ) to the direction (anticlockwise direction in  FIG. 2 ) of rotation of the rotating plate  15  for revolution. 
     The power transmission mechanism  40  is constructed by a driving pulley  41  fixed to the operating rotation shaft  21  for rotation at an upper level position on the rotating plate  15 , driven pulleys  42  fixed to the respective driven rotation shafts  25  for rotation, and an endless timing belt  45  provided under tension between the driving pulley  41  and the driven pulleys  42 . 
     The operating rotation shaft  21  for rotation and the respective driven rotation shafts  25  for rotation each have a container holding portion (not illustrated) detachably holding a cylindrical paste container containing a paste material on upper end portions thereof, thereby forming a container holder. Here, the paste container is a container (hereinafter referred to as “the syringe-like container”)  50  having a form slender in an axial direction, in which a ratio of a length in the axial direction to a maximum inside diameter size of the container falls within a range of, for example, 2.5 to 20. The syringe-like container  50  in this embodiment has an opening portion for placing a paste material in the syringe-like container  50  at, for example, one end portion in the axial direction, and also has an electing portion  51  having a small diameter for ejecting the paste material subjected to a kneading and deaerating treatment at the other end portion. 
     The container holding portion holds the syringe-like container  50 , for example, in a state that the ejecting portion  51  of the syringe-like container  50  is located on a lower side in a vertical direction, and a central axis C of the syringe-like container  50  obliquely intersects the operating rotation axis B 1  (B 2  to B 4 ). 
     No particular limitation is imposed on an angle θ formed by the central axis C of the syringe-like container  50  and the operating rotation axis B 1  (B 2  to B 4 ). However, the angle is preferably within a range of, for example, 15 to 60° and is 45° in the illustrated embodiment. The angle θ formed by the central axis C of the syringe-like container  50  and the operating rotation axis B 1  (B 2  to B 4 ) may be set in a suitable range according to the kind of the paste material to be kneaded and deaerated, the rotating speed of the rotating plate  15  for revolution, the length in the axial direction and inside diameter of the syringe-like container  50 , the rotating velocity of the operating rotation shaft  21  for rotation (driven rotation shaft  25  for rotation) and other conditions. 
     The rotating speed of the rotating plate  15  for revolution (revolving velocity of the syringe-like container  50 ) can be adjusted within a range of, for example, 400 to 2,000 rpm. The rotating speed (rotating velocity of the syringe-like container  50 ) of the operating rotation shaft  21  for rotation (driven rotation shaft  25  for rotation) rotationally driven by the rotation of the rotating plate  15  for revolution is set so as to become about ½ down to 1/10 as much as the rotating speed of the rotating plate  15  for revolution. Here, the rotating velocity of the syringe-like container  50  can be adjusted by adjusting a diameter ratio between the fixed pulley  31  and the driving pulley  32  for rotation which make up the driving mechanism  30  of the operating rotation shaft for rotation. 
     In addition, the rotating speed of the rotating plate  15  for revolution is preferably set within the above range in such a manner that the temperature rise of the paste material is, for example, 2° C./min or less. 
     A deaeration valve operated by the action of centrifugal force is provided in an opening portion on one side of the syringe-like container  50  used in the vacuum kneading and deaerating device of the above construction. 
     As illustrated in  FIG. 3(A)  and  FIG. 3(B) , the deaeration valve  60  is equipped with a holder  61  detachably installed on an end portion of the syringe-like container  50  so as to receive the end portion of the syringe-like container  50  to close the opening portion of the syringe-like container  50 , and a valve disc  65  slidably provided in this holder  61 . The holder  61  is formed by, for example, a rubber material. 
     The valve disc  65  is formed of, for example, aluminum or a plastic, and has a stem portion  66  arranged in a state inserted into a through-hole  62  formed in a central portion of an end wall  61 A of the holder  61  in such a manner that a minute interstice G is formed with an inner peripheral surface of the through-hole  62 , a disk-like lock portion  67  continuing with an upper or outer end of this stem portion  66  and having an outside diameter larger than the inside diameter of the through-hole  62  of the holder  61 , and a body portion  68  continuing with a lower or inner end of the stem portion  66  and having an outside diameter larger than the inside diameter of the through-hole  62  of the holder  61 . 
     The valve disc  65  is slidably provided between a closing position where the valve disc is moved by the action of centrifugal force F going outward in a radial direction of the rotating plate  15  for revolution, said centrifugal force F being applied by the rotation of the operating rotation shaft  21  for rotation (driven rotation shaft  25  for rotation) when the syringe-like container  50  lies in a state fallen outward in such a manner that an upper side of the central axis C thereof is more separated than a lower side thereof from the basic driving rotation axis A as goes upward (see FIG.  4 (A)), in such a manner that an upper surface of the body portion  68  is brought into contact with an inner surface of the end wail  61 A of the holder  61  to block up the minute interstice G formed between the inner peripheral surface of the through-hole  62  of the holder  61  and an outer peripheral surface of the stem portion  66  of the valve disc  65 , so as to close the internal space S of the syringe-like container  50  as illustrated in  FIG. 3(A) ; and an opening position where the upper surface of the body portion  68  is separated from the inner surface of the end wall  61 A of the holder  61  by the action of the centrifugal force F going outward in the radial direction of the rotating plate  15  for revolution, said centrifugal force F being applied by the rotation of the operating rotation shaft  21  for rotation (driven rotation shaft  25  for rotation) when the syringe-like container  50  lies in a state fallen inward in such a manner that the upper side of the central axis C thereof is more approached than the lower side thereof to the basic driving rotation axis A as goes upward (see FIG.  4 (B)), so as to open the internal space S of the syringe-like container  50  to the internal space of the pressure-reduced chamber  10  through the minute interstice G as illustrated in  FIG. 3(B) . 
     The operation of the vacuum kneading and deaerating device will hereinafter he described. 
     The syringe-like container  50  containing a paste material P to be kneaded and deaerated is held by the container holding portion in toe operating rotation shaft  21  for rotation (driven rotation shaft  25  for rotation), and the internal space of the chamber  10  is held under a pressure-reduced condition. When the drive motor  18  is driven, the driving rotation shaft  11  for revolution is rotated to rotationally drive the rotating plate  15  for revolution fixed thereto around the basic driving rotation axis A in a horizontal plane. 
     With the rotational drive of the rotating plate  15  for revolution, the operating rotation shaft  21  for rotation and the decelerating timing belt  35  are also revolved together with the rotating plate  15  for revolution around the basic driving rotation axis A. However, the fixed pulley  31  is fixed independently of the driving rotation shaft  11  for revolution, so that the driving pulley  32  for rotation fixed to the operating rotation shaft  21  for rotation is rotated on the operating rotation axis B 1  in a reverse direction to the direction of rotation of the rotating plate  15  for revolution. As a result, the operating rotation shaft  21  for rotation is driven rotationally on the operating rotation axis B 1 , and the respective driven rotation shafts  25  for rotation are driven rotationally on the respective operating rotation axes B 2  to B 4  in a state synchronized with one another by the timing belt  45 . 
     The syringe-like containers  50  are held on the operating rotation shaft  21  for rotation and the driven rotation shafts  25  for rotation, which are rotated on the respective operating rotation shafts B 1  to B 4 , in a state that a central axis C of each of the syringe-like containers  50  obliquely intersects the operating rotation axis B 1  (B 2  to B 4 ), so that each of the syringe-like containers  50  conducts precession on a intersected position between the central axis C of the syringe-like container  50  and the operating rotation axis B 1  (B 2  to B 4 ) by the rotation of the operating rotation shaft  21  for rotation (driven rotation shafts  25  for rotation) while revolving around the basic driving rotation axis A. In short, the syringe-like containers  50  conduct oscillating and rotating motion with a fixed angle to the operating rotation axis B 1  (B 2  to B 4 ) while revolving around the basic driving rotation axis A. 
     Each of the syringe-like containers  50  conducts such orbital motion and precession at the same time, so that the paste material P contained in the syringe-like container  50  receives the action of centrifugal force by the orbital motion and also receives an action by the precession at the same time to conduct not only double rotating motion in a horizontal direction, but also motion including components in upward and downward directions. More specifically, when the syringe-like container  50  lies in a state fallen outward in such a manner that an upper side of the central axis C is more separated than a lower side thereof from the basic driving rotation axis A as goes upward by the precession, the paste material P in the syringe-like container  50  is moved to the upper side by the centrifugal force F going outward in the radial direction of the rotating plate  15  for revolution in such a manner that the paste material P is brought to a state biased on one end side (on the side of the deaeration valve  60 ) of the syringe-like container  50  as illustrated in  FIG. 4(A) . On the other hand, when the syringe-like container  50  lies in a state fallen inward in such a manner that the upper side of the central axis C is more approached than the lower side thereof to the basic driving rotation axis A as goes upward by the precession, the paste material P in the syringe-like container  50  is moved to the lower side by the centrifugal force F going outward in the radial direction of the rotating plate  15  for revolution in such a manner that the paste material P is brought to a state biased on the other end side (on the side of the ejecting portion  51 ) of the syringe-like container  50  as illustrated in  FIG. 4(B) , whereby the paste material P receives a spiral kneading action. 
     The paste material P in the syringe-like container  50  receives the spiral kneading action, whereby bubbles mixed in the paste material P receives a deaerating action so as to be brought into intense contact with a vacuum interface in the syringe-like container  50 , so that the bubbles come to be released (deaerated) in the internal space S of the syringe like container  50 . However, in the vacuum kneading and deaerating device described above, the deaeration valve  60  provided in the syringe-like container  50  is opened and closed by the action of the centrifugal force F going outward in the radial direction of the rotating plate  15  for revolution by the revolution and rotation of the syringe-like container  50 , whereby the decoration of the paste material P is conducted in a state that the interior of the syringe-like container  50  has been maintained at a predetermined pressure-reduced condition. 
     More specifically, when the syringe-like, container  50  lies in a state fallen outward in such a manner that the upper side of the central axis C thereof is more separated than the lower side thereof from the basic driving rotation axis A as goes upward by the precession as illustrated in  FIG. 3(A) , the valve disc  65  is moved to the closing position by the action of the centrifugal force F going outward in the radial direction of the rotating plate  15  for revolution by the orbital motion and precession of the syringe-like container  50  in such a manner that an upper surface of the body portion  68  thereof is brought into contact with an inner surface of the end wall  61 A of the holder  61  to block up the minute interstice C, thereby closing the internal space of the syringe-like container  50  to prevent the paste material P from flowing out to the outside. On the other hand, when the syringe-like container  50  lies in a state fallen inward in such a manner that the upper side of the central axis C thereof is more approached than the lower side thereof to the basic driving rotation axis A as goes upward by the precession as illustrated in  FIG. 3(B) , the valve disc  65  is moved to the opening position by the action of the centrifugal force F going outward in the radial direction of the rotating plate  15  for revolution by the orbital motion and precession of the syringe-like container  50  in such a manner that the upper surface of the body portion  68  thereof is separated from the inner surface of the end wall  61 A of the holder  61 . When the valve disc  65  is located at the opening position that the internal space S of the syringe-like container  50  is opened, the internal space S of the syringe-like container  50  is caused to communicate with the internal space of the pressure-reduced chamber  10  through the minute interstice G formed between the outer peripheral surface of the stem portion  66  of the valve disc  65  and the inner peripheral surface of the through-hole  62  of the holder  61 , whereby the gas released from the paste material P into the internal space of the syringe-like container  50  by the deaerating action on the paste material P is discharged to the outside of the syringe-like container  50 , and the interior of the syringe-like container  50  is maintained at the predetermined pressure-reduced condition. 
     According to the vacuum kneading and deaerating device described above, the syringe-like container  50  conducts orbital motion and precession under reduced pressure, thereby achieving sufficient kneading and deaerating actions on the paste material P in the syringe-like container  50  fundamentally, so that the paste material P in the syringe-like container  50  can be uniformly and sufficiently kneaded as a whole. In addition, the deaeration valve  60  operated by the action of the centrifugal force is provided in the syringe-like container  50 , whereby the gas released in the internal space S of the syringe-like container  50  by the deaerating action can be discharged to the outside of the syringe-like container  50  to maintain the interior of the syringe-like container  50  at a proper pressure-reduced condition, so that the deaeration of the paste material P can be sufficiently conducted with a high efficiency, and the paste material after the treatment is provided as an even- and high-quality product. 
     In addition, after the predetermined treatment is conducted, the syringe-like container  50  containing the paste material P can be used in the present state as it is, so that the working efficiency can be improved, and it can be avoided to cause such an inconvenience that the quality of a final product using the paste material P is lowered by mixing the gas in the paste material again. 
     &lt;Second Embodiment&gt; 
     In a vacuum kneading and deaerating device according to the second embodiment of the present invention, a container of the construction that a lid member  70  having a degassing function is provided in an opening portion on one end side for placing the paste material P in the syringe-like container  50  is used as the syringe-like container  50 . 
     As illustrated in  FIG. 5(A)  and  FIG. 5(B) , the lid member  70  is constructed by a cylindrical closed-end holder  61  detachably installed on the opening portion on one end side of the syringe-like container  50  so as to receive the one end portion of the syringe-like container  50  to close the opening portion of the syringe-like container  50  and a paste material-impermeable and gas-permeable membrane  75  provided on an inner surface of an end wall  61 A of this holder  61  so as to cover a through-hole  62  formed in a central portion of the end wall  61 A. 
     The gas-permeable membrane  75  is of, for example, a filmy form and can be formed by, for example, a polymeric separation membrane having a nature that the paste material P in the interior of the syringe-like container  50  is not permeated, but a gas released from the paste material P is permeated. 
     A membrane having a thickness of 60 μm or more and a pore size within a range of, for example, from 0.02 μm or more to 20 μm or less is preferably used as the gas-permeable membrane  75 . 
     The reason why the membrane whose pore size falls within the above range is preferably used as the gas-permeable membrane  75  will hereinafter be described. 
     For example, assuming that a maximum mass of the paste material contained in the syringe-like container  50  is m [kg], an orbital radius (a distance between the basic driving rotation axis A and the operating rotation axis B 1  (B 2  to B 4 )) of the syringe-like container  50  is r [m], an orbital frequency of the syringe-like container  50  is f [Hz], and a rotation angle (an angle formed between the central axis C and the operating rotation axis B 1  (B 2  to B 4 ) of the syringe-like container  50 ) of the syringe-like container  50  is θ [°], a maximum value F max  [N] of the centrifugal force acted on the paste material P is represented by the following expression (1).
 
[Math. 1]
 
 F   max   =m×r× (2 πf ) 2 ×cos θ  Expression (1)
 
     Accordingly, assuming that an inner radius of the syringe-like container  50  is b [m], and an average value of the centrifugal force is F, an average value P [Pa] of a pressure acted on the gas-permeable membrane  75  is represented by the following expression (2). 
     
       
         
           
             
               
                 
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     On the other hand, assuming that a pore radius (an average radius or a radius of a suspended particle) of the gas-permeable membrane  75  is a [m], a membrane thickness of the gas-permeable membrane  75  is L [m], and a viscosity of the paste material P is η [Pa·s], a flow rate q [m 3 /s] of the paste material flowing through pores of the gas-permeable membrane  75  is represented by the following expression (3) according to the Hagen-Poiseuille&#39;s law. 
     
       
         
           
             
               
                 
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     In addition, assuming that a maximum value of a kneading time is t max  [min], a maximum value of a rotational speed of the revolution is N max  [rpm], and a pressurizing time per one revolution by the centrifugal force acted on the gas-permeable membrane  75  is tp [s], a critical flow rate q min  [m 3 /s] that the paste material P does not flow out through the pores of the gas-permeable membrane  75  is represented by the following expression (4). 
     
       
         
           
             
               
                 
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                   ⁢ 
                   
                     ( 
                     4 
                     ) 
                   
                 
               
               
                 
                     
                 
               
             
             
               
                 
                   
                     q 
                     min 
                   
                   = 
                   
                     
                       π 
                       × 
                       
                         a 
                         2 
                       
                       × 
                       L 
                     
                     
                       
                         t 
                         max 
                       
                       × 
                       
                         N 
                         max 
                       
                       × 
                       tp 
                     
                   
                 
               
               
                 
                   [ 
                   
                     Math 
                     . 
                     
                         
                     
                     ⁢ 
                     4 
                   
                   ] 
                 
               
             
           
         
       
     
     Accordingly, when q is smaller than q min , the paste material P is not discharged through the pores of the gas-permeable membrane  75 , so that the relationship of the following expression (5) is derived from the expression (3) and the expression (4). 
     
       
         
           
             
               
                 
                   Expression 
                   ⁢ 
                   
                       
                   
                   ⁢ 
                   
                     ( 
                     5 
                     ) 
                   
                 
               
               
                 
                     
                 
               
             
             
               
                 
                   
                     
                       a 
                       L 
                     
                     &lt; 
                     
                       α 
                       × 
                       
                         η 
                         
                           1 
                           2 
                         
                       
                     
                   
                   , 
                   
                     α 
                     = 
                     
                       
                         [ 
                         
                           8 
                           
                             P 
                             × 
                             
                               t 
                               max 
                             
                             × 
                             
                               N 
                               max 
                             
                             × 
                             tp 
                           
                         
                         ] 
                       
                       
                         1 
                         2 
                       
                     
                   
                 
               
               
                 
                   [ 
                   
                     Math 
                     . 
                     
                         
                     
                     ⁢ 
                     5 
                   
                   ] 
                 
               
             
           
         
       
     
     In the vacuum kneading and deaerating device described above, it is determined that the maximum mass m of the paste material P contained in the syringe-like container  50  is 5 to 50 [g] (60 to 80% of the capacity of the syringe-like container  50 ), the orbital radius r of the syringe-like container  50  is 80 to 120 [mm], the orbital frequency f of the syringe-like container  50  is 5 to 20 [Hz], the rotation angle θ of the syringe-like container  50  is 15 to 60 [°], the inner radius b of the syringe-like container  50  is 4 to 12 [mm], the orbital period T of the syringe-like container  50  is 50 to 200 [ms], the orbital time is within 10 minutes, and a ratio (rotational speed ratio) a of the orbital speed to the rotational speed of the syringe-like container  50  is ½ to 1/10. Accordingly, an α value that the paste material P does not flow out through the pores under conditions of maximum centrifugal force and a maximum orbital time is 0.37×10 −3  or less. 
     In addition, a lower limit value of the η min  viscosity of the paste material P treated in the vacuum kneading and deaerating device is, for example, about 0.2 [Pa·s], so that a lower limit value a min  of the pore radius in the gas-permeable membrane  75  when the thickness of the gas-permeable membrane  75  is 60 [μm] or more (the minimum value L min  is 60 [μm]) is a min =L min ×α max +η min   (1/2) ≈0.01 [μm] according to above expression (5), and so the lower limit value of the pore size of the gas-permeable membrane  75  is 0.02 [μm]. 
     On the other hand, when the paste material P to be treated is a material in which a liquid and a particulate matter are mixed, such as a sealing compound for LED production prepared by mixing a particulate fluorescent material in a pasty thermosetting resin material, an upper limit value of the pore size in the gas-permeable membrane  75  is only required not to discharge the particulate matter (fluorescent material) through the pores. For example, the particle size of the fluorescent material in the sealing compound for LED production is generally larger than, for example, 10 [μm], so that the upper limit value of the pore size in the gas-permeable membrane  75  may be set to 10 [μm]. 
     In the vacuum kneading and deaerating device of such construction, bubbles mixed in the paste material P receive a deaerating action so as to be brought into intense contact with a vacuum interface in the syringe-like container  50  in a process from a state the syringe-like container  50  has fallen outward in such a manner that an upper side of the central axis C thereof is more separated than a lower side thereof from the basic driving rotation axis A as goes upward by the precession as illustrated in  FIG. 5(A)  to a state that the syringe-like container  50  has fallen inward in such a manner that the upper side of the central axis C thereof is more approached than the lower side thereof to the basic driving rotation axis A as goes upward by the precession as illustrated in  FIG. 5(B) , so that the bubbles are released (decorated) in the internal space S of the syringe-like container  50 . 
     The paste material P in the syringe-like container  50  is then moved to the upper end side in the axial direction of the syringe-like container  50  while pressing the gas (air) released in the internal space S o the syringe-like container  50  by the action of the centrifugal force F going outward in the radial direction of the rotating plate  15  for revolution by the orbital motion and precession of the syringe-like container  50  in a process from the state illustrated in  FIG. 5(B)  to the state illustrated in  FIG. 5(A) , whereby the gas in the internal space S of the syringe-like container  50  is caused to permeate through the gas-permeable membrane  75  and discharged to the outside of the syringe-like container  50  through the through-hole  62 , and the interior of the syringe-like container  50  is maintained at the predetermined pressure-reduced condition. Here, even in a state that the centrifugal force F acted on the paste material P becomes maximum (a stare illustrated in FIG.  5 (A)), the paste material P is not discharged through the pores of the gas-permeable membrane  75  by virtue of the viscosity of the paste material P itself. 
     The same effects as in the first embodiment can be achieved in the vacuum kneading and deaerating device described above. More specifically, the paste material P in the syringe-like container  50  can be uniformly and sufficiently kneaded as a whole. In addition, by the construction that the lid member  70  equipped with the gas-permeable membrane  75  having the specific pore size is provided on the opening portion on one end side of the syringe-like container  50 , the gas released in the internal space S of the syringe-like container  50  by the deaerating action can be discharged to the outside of the syringe-like container  50  through the gas-permeable membrane  75  to maintain the interior of the syringe-like container  50  at a proper pressure-reduced condition, so that the deaeration of the paste material P can be sufficiently conducted with a high efficiency, and the paste material after the treatment is provided as an even- and high-quality product. 
     The embodiments of the present invention have been described above. However, the present invention is not limited to the above-described embodiments, and various changes or modifications may be added thereto. 
     For example, in the vacuum kneading and deaerating device according to the first embodiment, the deaeration valve provided in the syringe-like container is not limited to the construction operated by the centrifugal force acted on the mass of the body portion itself. For example, a construction operated by a pressure of the paste material P, which is caused by the action of the centrifugal force received by the paste material P contained in the syringe-like container  50 , as illustrated in  FIG. 6(A)  and  FIG. 6(B) , may also be adopted. Even in such construction, the same effects as in the above-described embodiments can be achieved. 
     This deaeration valve  60 A has the same construction as the deaeration valve  60  in the above-described embodiment except that the valve disc  65  in the deaeration valve  60  further has a disk-like pressure-receiving plate  69  continuing with a lower end of the body portion  68  through a stem portion  66 A and having an outside diameter smaller than the inside diameter of the syringe-like container  50 . Here, a minute interstice K through which only the gas deaerated from the paste material P is passed is formed between a peripheral surface of the pressure-receiving plate  69  in the valve disc  65  and an inner peripheral surface of the syringe-like container  50 . 
     This deaeration valve  60 A is slidably provided between a closing position where the valve disc is moved by pressing the pressure-receiving plate  69  of the valve disc  65  outward by the paste material P by the action of centrifugal force F going outward in a radial direction of the rotating plate  15  for revolution, said centrifugal force F being applied to the paste material P in the syringe-like container  50  by the rotation of the operating rotation shaft  21  for rotation (driven rotation shaft  25  for rotation) when the syringe-like container  50  lies in a state fallen outward in such a manner that an upper side of central axis C thereof is more separated than a lower side thereof from the basic driving rotation axis A as goes upward, in such a manner that an upper surface of the body portion  68  is brought into contact with an inner surface of the end wall  61 A of the holder  61  to block up the minute interstice G formed between an inner peripheral surface of the through-hole  62  and an outer peripheral surface of the stem portion  66  of the valve disc  65 , so as to close the internal space S of the syringe-like container  50  as illustrated in  FIG. 6(A) ; and an opening position where the upper surface of the body portion  68  is separated from the inner surface of the end wall  61 A of the holder  61  by the action of the centrifugal force F going outward in the radial direction of the rotating plate  15  for revolution, said centrifugal force F being applied by the rotation of the operating rotation shaft  21  for rotation (driven rotation shaft  25  for rotation) when the syringe-like container  50  lies in a state fallen inward in such a manner that the upper side of the central axis C thereof is more approached than the lower side thereof to the basic driving rotation axis A goes upward, so as to open the internal space S of the syringe-like container  50  to the internal space of the pressure-reduced chamber  10  through the minute interstice G as illustrated in  FIG. 6(B) . When the valve disc  65  is located at the opening position, the internal space S of the syringe-like container  50  is caused to communicate with the internal space of the pressure-reduced chamber  10  through the minute interstice k formed between the peripheral surface of the pressure-receiving plate  69  and the inner peripheral surface of the syringe-like container and the minute interstice G formed between the outer peripheral surface of the stem portion  66  of the valve disc  65  and the inner peripheral surface of the through-hole  62  of the holder  61 , whereby the gas released from the paste material P into the internal space S of the syringe-like container  50  by the deaerating action on the paste material P is discharged to the outside of the syringe-like container  50 , and the interior of the syringe-like container  50  is maintained at the predetermined pressure-reduced condition. 
     In the vacuum kneading and deaerating devices according to the present invention, the number of the container holding portions each holding the syringe-like container is not particularly limited. 
     In addition, the driving mechanism of the operating rotation shaft for rotation is not, limited to the above-described construction so far as the orbital motion and precession of the syringe-like container are achieved. For example, the mechanism may also he constructed by a planetary gear mechanism. The fact that the power source of the orbital motion and precession is common is also not always required. 
     Industrial Applicability 
     As described above, the vacuum kneading and deaerating devices according to the present invention can uniformly and sufficiently knead a paste material contained in the syringe-like container and sufficiently discharge (deaerate) bubbles mixed in the paste material with a high efficiency, and thus are extremely useful when the paste material is required to be used by making the bubbles extremely small up to a size of, for: example, 1 μm or smaller. Specific examples of such requirements include a kneading and deaerating treatment of a sealing compound used upon the production of an LED constructed by molding chip-like blue LED elements by a fluorescent material layer formed of a transparent thermosetting resin (sealing compound) with a YAG fluorescent material (yellow fluorescent material) mixed therein, said LED emitting white light by blue light transmitted through the fluorescent material layer from the blue LED elements and yellow light emitted from the fluorescent material layer by exciting the fluorescent material by the blue light from the blue LED elements. 
     
       
         
           
               
             
               
                   
               
               
                 REFERENCE SIGNS LIST 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
            
               
                 10 
                 Chamber 
               
               
                 11 
                 Driving rotation shaft for revolution 
               
               
                 15 
                 Rotating plate for revolution 
               
               
                 18 
                 Drive motor 
               
               
                 21 
                 Operating rotation shaft for rotation 
               
               
                 25 
                 Driven rotation shaft for rotation 
               
               
                 30 
                 Driving mechanism of the operating rotation 
               
               
                   
                 shaft for rotation 
               
               
                 31 
                 Fixed pulley 
               
               
                 32 
                 Driving pulley for rotation 
               
               
                 35 
                 Decelerating timing belt 
               
               
                 40 
                 Power transmission mechanism 
               
               
                 41 
                 Driving pulley 
               
               
                 42 
                 Driven pulley 
               
               
                 45 
                 Timing belt 
               
               
                 50 
                 Syringe-like container 
               
               
                 51 
                 Ejecting portion 
               
               
                 60, 60A 
                 Deaeration valves 
               
               
                 61 
                 Holder 
               
               
                 61A 
                 End wall 
               
               
                 62 
                 Through-hole 
               
               
                 65 
                 Valve disc 
               
               
                 66, 66A 
                 Stem portions 
               
               
                 67 
                 Lock portion 
               
               
                 68 
                 Body portion 
               
               
                 69 
                 Pressure-receiving plate 
               
               
                 70 
                 Lid member 
               
               
                 75 
                 Gas-permeable membrane 
               
               
                 A 
                 Basic driving rotation axis 
               
               
                 B1-B4 
                 Operating rotation axes 
               
               
                 C 
                 Central axis of a syringe-like container 
               
               
                 G 
                 Minute interstice 
               
               
                 K 
                 Minute interstice 
               
               
                 P 
                 Paste material 
               
               
                 S 
                 Internal space of a syringe-like container