Patent Publication Number: US-4650690-A

Title: Edible water-in-oil-in-water emulsion

Description:
There is an increasing demand for foodstuffs having a relatively low energy content. Therefore efforts have been made to produce foodstuffs having a reduced lipid and sugar content. As such are known: low calorie spreads, e.g. water-in-oil (w/o) emulsions, and oil-in-water (o/w) emulsions, such as sauces, in particular salad dressings of the mayonnaise type having a reduced lipid content. Still, in order to give these products, in particular sauces, a firm consistency and sufficient stability, it was necessary to incorporate in these products a rather large amount, viz up to 5 wt. % (dry matter), of a thickening agent, such as starch, gums, carboxymethylcellulose, etc. (GB-A-1 527 526). The disadvantage thereof is, however, that the sauces thus thickened contain an additional ingredient which often results in sauces with a slimy and/or pappy, less smooth and even somewhat grainy impression in the mouth. In some countries there are also limitations in this respect owing to Foods Regulations. 
     It is an object of the present invention to overcome these drawbacks by providing an edible water-in-oil-in-water (w/o/w) emulsion, the continuous aqueous phase of which has a pH between 6.5 and 2.0, preferably between 4.5 and 3.0 and which contains between 10 and 80 wt.%, preferably between 30 and 50 wt.%, calculated on the total w/o/w emulsion, of a triglyceride oil and of which the discontinuous aqueous phase is at least 10 wt.% of discontinuous aqueous phase and oil phase together (thus, calculated on the originally prepared w/o emulsion). Preferably that percentage amounts to at least 30%, more preferably a minimum of 50%. The required pH of the continuous aqueous phase is obtained by judicious addition of a &#34;food acid&#34;, such as acetic acid, citric acid, lactic acid etc. As was found, these low energy products can then possess a smooth, creamy impression in the mouth and they are excellent foodstuffs. 
     Triglyceride oils that are especially suitable for the present invention are vegetable oils having an iodine value between 70 and 110, such as soybean oil, including partially hydrogenated, sunflower oil, maize germ oil, olive oil, peanut oil, etc. Not only unsaturated fatty acid triglyceride esters can be used, but also their admixtures with sucrose esters containing 3-8 fatty acid radicals per sucrose molecule. 
     According to the invention, the oil preferably contains no solid phase at 20° C. 
     W/o/w emulsions are known from U.S. Pat. No. 4,254,105 (Hidenori Fukada). However, the double w/o/w-type emulsions known from this specification contain paraffin oil and, moreover, show a higher pH-value than those according to the present invention. These double emulsions known from the art are used as cosmetics and not as foodstuff. 
     Further, JA-A-175 475/82 (of QP Corporation) discloses double emulsions of the w/o/w type which, however, have a particularly small percentage of a discontinuous aqueous phase (maximum 3.2%). Moreover, these emulsions contain solid calcium carbonate. 
     In the case of the w/o/w emulsions according to the invention it is desirable that the continuous aqueous phase and the discontinuous aqueous phase have a different composition and they need not be isotonic. It is normal practice with double emulsions to use an emulsifier system in which at least one w/o emulsifier is present. W/o emulsifiers that are useful have an HLB-value of at most 6. In practice, sorbitan esters, sucrose esters and polyglycerol esters of fatty acids, optionally polymerized fatty acids, are preferred. 
     It is also customary to use in addition to the w/o emulsifier an o/w emulsifier having an HLB-value of at least 8. As such, polyoxyethylene sorbitan esters, protein and egg yolk are suitable. Of these, egg yolk is preferred according to the present invention in connection with the excellent stability of the double emulsion obtained therewith. 
     The amount of the w/o emulsifier in the emulsifier system is between 0.1 and 10, preferably between 0.2 and 5.0 wt.% of the total emulsion. In most cases the emulsifier system will contain an o/w emulsifier such as a protein, more particularly egg yolk, which optionally has been subjected to a pre-treatment (e.g. modified with phospholipase A 2 , which is preferred). Also milk protein, blood protein, etc. are suitable for this purpose. The amount of protein or egg yolk used is as a rule between 0.1 and 5.0 wt.%, preferably between 0.5 and 2.0 wt.% of the total emulsion. 
     In exceptional cases, e.g. with certain emulsions having a low oil content, it can be advantageous to use a small amount (up to 1%) of a thickening agent in the discontinuous aqueous phase. Certain proteins and polysaccharides such as gelatin and vegetable gums are suitable for this purpose. Furthermore, it is preferred that the aqueous phases contain a soluble salt, in particular common salt. The salt concentration in the aqueous phases ranges between 1 and 8%. The concentrations of the various constituents in both aqueous phases is mostly different. 
     Other conventional ingredients, such as sugar, flavours, colouring agents, preservatives, etc. will as a rule also be present, but no insoluble inorganic material. The w/o/w emulsions according to the invention can be prepared in a two-step process. A stable w/o emulsion is first of all prepared by emulsifying water, oil and an emulsifier of the w/o type in a mixer. This w/o emulsion is then added to an aqueous phase (the later aqueous phase) in which the o/w emulsifier is present, (pre-emulsion) and continuous homogenization is carried out. In this way a stable w/o/w emulsion is obtained, showing excellent organoleptical behaviour. 
     The edible w/o/w emulsions according to the present invention can especially be used as sauces, salad dressing, French-fry sauce, barbecue sauce, etc. and notwithstanding a smaller amount of lipids than is normally present in such products, they give a pleasant creamy mouth-feel also in e.g. soups and ice-cream. 
     The invention will be illustrated by the following Examples 
    
    
     EXAMPLE I 
     By means of an Ultra-Turrax, a high speed stirring motor of the rotor/stator type (ex Janke and Kunkel, Germany), a solution of 
     8.9 g sucrose 
     22.3 g common salt 
     2.2 g sorbic acid 
     32.2 g acetic acid (10%) 
      in 816.0 g of water was added slowly, i.e. in 3 minutes, to a mixture of 893.0 g of soybean oil (iodine value 105) and 25.0 g of a w/o emulsifier (a polyglycerol ester of polymerized castor oil fatty acids) and this was vigorously stirred for 2 minutes to obtain a stable w/o emulsion which contained 49% aqueous phase and 51% oil phase. This w/o emulsion was slowly, i.e. in 3 minutes, added to a mixture of: 
     90.0 g fresh egg yolk 
     6.5 g sucrose 
     20.0 g common salt 
     2.0 g sorbic acid 
     11.0 g acetic acid (10%) 
     70.0 g water 
      while mixing with the aid of a kitchen mixer (Kenwood Chef) in the 4-position. The pre-emulsion thus obtained was de-aerated and homogenized with the aid of a Presto-Mill (homogenizer of the rotor/stator type on a laboratory scale). The final product obtained showed a mayonnaise-like character and gave a smooth, creamy impression in the mouth. 
     EXAMPLE II 
     In accordance with the method of Example I, a mixture of 
     15.0 g sucrose 
     15.0 g common salt 
     1.0 g potassium sorbate 
     45.0 g acetic acid (10%) 
     924.0 g water 
      was added to 775.0 g of soybean oil and 25.0 g of the w/o emulsifier of Example I. The water-in-oil emulsion thus obtained was added to a mixture consisting of 
     90.0 g fresh egg yolk 
     15.0 g sucrose 
     15.0 g common salt 
     1.0 g potassium sorbate 
     15.0 g acetic acid (10%) 
     64.0 g water 
      in order to obtain a pre-emulsion of the w/o/w/-type. 
     After homogenization, a dressing-like product was obtained which left an excellent creamy impression in the mouth. 
     EXAMPLE III 
     In a way analogous to that described in Example I a solution of 
     9.0 g sucrose 
     22.6 g common salt 
     3.0 g potassium sorbate 
     70.0 g acetic acid (10%) in 
     774.4 g of water 
      was added to a mixture of 
     887.0 g soybean oil 
     4.0 g beta-carotene solution (0.2%) 
     2.0 g mustard oil 
     25.0 g of the w/o emulsifier of Example I 
      in such a way that a w/o emulsion was formed containing 49% by weight of aqueous phase and 51% by weight of oil phase which was then added to a mixture of 
     98.0 g technical egg yolk (92% egg yolk; 
     7% NaCl; 1% potassium sorbate) 
     6.5 g sucrose 
     13.2 g common salt 
     2.0 g potassium sorbate 
     25.0 g acetic acid (10%) 
     0.4 g flavour 
     1.0 g mustard flavour 
     53.9 g water 
      in order to obtain a pre-emulsion of the w/o/w-type. 
     After homogenization, the product had a mayonnaise-like, creamy character, both physically and organoleptically. 
     EXAMPLE IV 
     In a way analogous to that described in Example I, a solution of 
     8.0 g sucrose 
     22.1 g common salt 
     2.7 g potassium sorbate 
     62.2 g acetic acid (10%) 
      in 689 g of water was added to 793.8 g of soybean oil and 22.2 g of Homodan PT (a w/o emulsifier, polyglycerol ester of polymerized soybean oil) so as to obtain a stable w/o emulsion. The w/o emulsion formed was then added to a mixture of 
     50.0 g fresh egg yolk 
     30.0 g concentrated whey protein preparation 
     20.0 g sucrose 
     3.0 g potassium sorbate 
     80.0 g acetic acid (10%) 
     217.0 g water. 
     The in w/o/w pre-emulsion thus formed, after homogenization showed dressing-like properties and a good behaviour in the mouth. 
     
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Physical/analytical measurements                                          
         C-value  Bostwick    moisture                                    
                                      pH                                  
Example  (g/cm.sup.2)                                                     
                  value (cm)  separation                                  
                                      (%)                                 
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I        111      0.2         3.9     4.2                                 
II        99      2.7         9.9     4.1                                 
III      107      0.7         4.1     3.9                                 
IV        88      6.7         6.1     3.9                                 
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     C-value: Measured with a cone penetrometer ex Sommer und Ruhe Berlin-Friedemann Cone 40° and weighing 80 g 
     Bostwick value: Bostwick consistometer ex Cenco Instruments Co, Chicago, USA in operation: 30 seconds 
     % Moisture separation: After centrifugation for 10 minutes at 1500×g 
     EXAMPLES V, VI, VII, AND VIII 
     In a way analogous to that described in Example I, double emulsions of the W/O/W type were prepared from the following ingredients. 
     
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Soya bean oil  1356.0   1259.0   466.9 774.0                              
Carotene solution                                                         
               7.4      7.1      --    6.0                                
W/O Emulsifier of Ex.I                                                    
               36.6     33.9     13.1  20.0                               
Sucrose        25.9     87.4     84.0  146.0                              
Common salt    6.6      8.3      84.0  11.4                               
Potassium sorbate                                                         
               0.4      0.9      5.6   --                                 
Maltodextrin   5.6      14.4     --    --                                 
10% Acetic acid                                                           
               6.5      13.8     84.0  --                                 
Citric acid    0.6      1.4      --    --                                 
Skimmed milk yoghurt                                                      
               --       163.9    --    --                                 
Water          154.2    209.9    862.4 642.6                              
Ratio aqueous to oil phase:                                               
               12.5:87.5                                                  
                        28:72    70:30 50:50                              
Technical egg yolk (Ex.III)                                               
               174.3    89.7     180.0 60.0                               
(fresh egg yolk)                                                          
Sucrose        --       --       30.0  --                                 
Common salt    6.2      3.2      30.0  11.0                               
Potassium sorbate                                                         
               3.0      1.5      2.0   2.0                                
Maltodextrin   27.8     14.3     --    --                                 
10% Acetic acid                                                           
               17.4     9.0      30.0  40.0                               
Citric acid    0.9      0.5      --    --                                 
Mustard        92.7     --       --    13.8                               
Water          77.5     81.9     128.0 273.4                              
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 *added to the preemulsion                                                
 
    
     The emulsions so obtained showed dressing-like properties and a mayonnaise-like mouth feel.