Patent Publication Number: US-6335558-B1

Title: Complementary bipolar/CMOS epitaxial structure and method

Description:
CROSS REFERENCE TO RELATED APPLICATION 
     This is a division of application Ser. No. 09/149,353 filed on Sep. 8, 1998 of Vladimir F. Drobny and Kevin Bao for “COMPLEMENTARY BIPOLAR/CMOS EPITAXIAL STRUCTURE AND METHOD” now U.S. Pat. No. 6,080,644. 
     This application claims the benefit of prior filed U. S. Provisional Application Serial No. 60/073,883, filed Feb. 6, 1998, entitled “ENGINEERED EPI FOR HIGH SPEED CBCMOS TECHNOLOGY” by Vladimir F. Drobny and Kevin Bao. 
    
    
     BACKGROUND OF THE INVENTION 
     The invention relates to a high speed complementary bipolar/CMOS process that provides a doping profile in the collectors of NPN transistors formed in an epitaxial layer so as to avoid a “dip” in N type dopant concentration, which dip causes slow speed and other undesirable properties of the NPN transistors. 
     Those skilled in the art know that it is difficult to provide a process for manufacturing an epitaxial silicon layer that is satisfactory for use in a high speed complementary bipolar/CMOS process. In such a process a very thin, lightly doped N type epitaxial silicon layer must be grown on a silicon wafer including both pre-formed P+ boron doped buried layers and N+ arsenic doped buried layers formed in a P− substrate. In a typical prior art complementary bipolar/CMOS process the epitaxial layer is doped lightly in situ with arsenic to a concentration of approximately 2×10 15  cm −3  to achieve an optimal combination of characteristics of NPN, PNP and CMOS transistors to be formed. After the epitaxial deposition, the collector regions of the PNP and NPN transistors and the CMOS “wells” are further doped by a combination of low energy and high energy boron or phosphorous implants, with energies and doses tailored to the needs of various “families” of devices. During conventional epitaxial growth and subsequent conventional thermal processing, both the P type buried layers and the N type buried layers up diffuse into the epitaxial layer. That reduces the thickness of the useful portions of the collector regions for the transistors being fabricated. Since the P+ and N+ buried layers diffuse at significantly different rates, the PNP transistors end up having shallower collectors than the NPN transistor. 
     Since the diffusion of a P+ buried layer accelerates more rapidly than an N+ layer with respect to temperature, differences in the thicknesses of the collectors of the PNP transistors and the NPN transistors can be minimized by keeping the “Dt” of all high temperature process steps as low as possible. (“Dt” is a term referring to the cumulative amount of time that the wafer is subjected to high temperatures, usually exceeding 1000° C., after the epitaxial layer has been deposited.) The deep double implants used to form the collectors of the required depth for the NPN and PNP transistors, respectively, eliminate the need for high Dt diffusions after the formation of the epitaxial layer. 
     Note that a drawback associated with the large differential dopant diffusivity of arsenic buried layers and boron buried layers remains even for “low Dt processing”. For very low Dt processes, achieving the desirable PNP collector often results in producing an undesirable lightly doped N type subregion where an NPN collector region meets the N+ buried layer. 
     Furthermore, the value of N− dopant in the epitaxial layer must be selected to achieve the best characteristics of both the PNP and NPN transistors. If the N− concentration is as high as would be desirable for the NPN collector regions, then it would be far too high for the collectors of the PNP transistors. Therefore, a lower N-epitaxial dopant level, indicated by numeral  14  in FIG. 2, is selected instead. Then an N type ion implantation is applied to the surface, raising the N type dopant concentration to a suitable level for the NPN collectors. Unfortunately, it is impractical to provide the dose and energies needed to produce the “flat” N type epitaxial dopant concentration profile at the bottoms of the NPN collector regions. Consequently, the failure of the implanted ions to reach the bottoms of the NPN collector regions is a partial cause of the “dip”  20  in FIG.  2 . 
     The problem of such light doping is further aggravated by boron autodoping, wherein a large number of P type boron atoms escape from the large P+ buried layer area and then diffuse into the surface of the P− substrate and into the lightly doped N type epitaxial layer being grown, reducing or “compensating” its dopant concentration. This results in increased collector resistance and corresponding increased V CE(sat)  voltage, reduced f T  (i.e., the unity gain frequency or cutoff frequency), lower NPN switching speeds, and higher power dissipation. 
     FIGS. 1 and 2 show typical dopant concentration profiles for the PNP and NPN collector regions, respectively, made by a conventional complementary bipolar process after completion of a field oxidation step, during which most of the dopant diffusion occurs. 
     The dopant profiles of FIGS. 1 and 2 were obtained from a simulation of the dopant diffusions for the conventional epitaxial deposition process. The process simulation was calibrated to match experimental results measured from a substrate with a large percentage (for example 80%) of the wafer surface area implanted with a dose of approximately 1×10 15  cm −2  of boron followed by a P+ buried layer diffusion. (As those skilled in the art will recognize, the reason the large percentage of the P+ wafer substrate area has P+ “buried layer material” therein is to reduce substrate resistance and increase latch-up immunity of bipolar transistors and CMOS transistors.) 
     The prior art epitaxial process referred to above includes a high temperature H 2  pre-bake followed by a high temperature purge and then by a 1.5 micron deposition of an epitaxial layer of lightly arsenic (N type) doped single crystal silicon. The large amount of P+ surface area of the substrate causes a large amount of boron auto-doping into the lightly doped N type epitaxial layer being formed. The amount of corresponding boron (PF) autodoping in the dopant concentration profile of prior art FIGS. 1 and 2 was computed using simulated TSUPREM-4 profiles, and the simulated profiles were calibrated to match the measured experimental results. The TSUPREM-4 simulation program is a commercially available software package “Two-dimensional Process Simulation Program”, sold by Avant! Corporation, formerly Technology Modeling Associates. 
     For thin epitaxial layers (e.g., less than two microns in thickness), the autodoping strongly influences the transistor collector dopant concentration profiles. The large P+ substrate surface area mentioned above contributes a significant amount of boron autodoping during the epitaxial growth, which aggravates the above-mentioned problems with the performance of the NPN transistors, further reduces the depth of the PNP collector regions, and increases the difference between the breakdown characteristics of NPN and PNP transistors. The standard flat dopant profile epitaxial process techniques used to generate the profiles in prior art FIGS. 1 and 2 are not able to correct these problems. 
     Referring to FIGS. 1 and 2, the dopant concentration profiles of the prior art NPN and PNP collector regions are noticeably different when a standard epitaxial process is used. The differences between the peak implant concentration depths (commonly referred to as Rp) for phosphorus and boron implants is another cause of the large difference in the dopant concentration profiles of the NPN and PNP collector regions when practical implant energies are used. This difference is further aggravated by the boron autodoping. The NPN collector region, doped by a combination of low and high energy implants, shows a significant dopant concentration dip at its bottom, indicated by reference arrows  20  in FIG.  1 . This very lightly doped region adversely affects both the AC and DC performance of the NPN transistor by raising its collector region resistivity. This increases its collector resistance and thereby reduces f T  and increases the collector-to-emitter saturation voltages of the NPN transistor. 
     Prior experimentation in forming arsenic doped N+ epitaxial caps in the hope of increasing the doping concentration at the bottoms of the NPN collector regions has failed to adequately compensate for the boron autodoping at the epitaxial/substrate interface. 
     Thus, there is a need for an improved epitaxial process for complementary bipolar/CMOS for providing bipolar transistors, especially NPN transistors, with more ideal collector profiles leading to lower collector resistances and higher values of f T  than has been previously achievable. 
     SUMMARY OF THE INVENTION 
     Accordingly, it is an object of the invention to provide a high speed complementary bipolar/CMOS epitaxial process that provides NPN transistors in which undesirable effects of a dip or decrease in the N type collector dopant concentration profile close to an N+ buried layer are avoided. 
     It is another object of the invention to provide a high speed complementary bipolar/CMOS epitaxial process in which the NPN and PNP transistors have similar performance characteristics. 
     It is another object of the invention to provide a high speed complementary bipolar/CMOS process in which the NPN transistors have higher f T , lower collector resistance, and lower collector-to-emitter saturation voltage than has been previously achievable. 
     It is another object of the invention to provide a high speed complementary bipolar/CMOS process with a very uniform collector dopant concentration profile which leads to a high cutoff frequency f T  that is higher than previously has been achieved. 
     It is another object of the invention to provide a high speed complementary bipolar/CMOS process wherein process techniques that allow eliminating an undesirable dip in the dopant concentration profile of the collectors of the NPN transistors also allow optimization of the dopant concentration profile of the collectors of the PNP transistors. 
     Briefly described, and in accordance with one embodiment thereof, the invention provides a method of making an epitaxial layer on a P type silicon substrate having a P+ field layer region in most of a major surface of the substrate. The method includes loading the substrate in a reactor with a carrier gas therein, pre-baking the substrate, further heating the substrate, providing N+ dopant gas with the carrier gas, deoxidizing the substrate in the presence of the N+ dopant gas, depositing a first intrinsic epitaxial cap layer, performing a first bake cycle, depositing a second intrinsic epitaxial cap layer, performing a second bake cycle, and depositing an N− epitaxial layer having a thickness substantially greater than the thickness of either of the first and second cap layers. The process avoids an undesirable dip in the dopant concentration profile of the collector of PNP transistors formed in the epitaxial layer and results in higher f T , lower V SAT  devices. 
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS 
     FIG. 1 is a doping profile of the collector region of a PNP transistor for a standard prior art epitaxial process. 
     FIG. 2 is a doping profile of the collector region of an NPN transistor fabricated using the standard prior art epitaxial process. 
     FIG. 3 is a flow chart useful in describing the process of the present invention. 
     FIG. 4 is a doping profile of the collector region of an NPN transistor formed using the process of the present invention. 
     FIG. 5 is a doping profile of the collector region of a PNP transistor formed in an epitaxial region grown using the process of the present invention. 
     FIG. 6 is a plan view of a wafer showing locations of P+ and N+ buried layer regions and the deep N+ regions. 
     FIG. 7 is a partial section view of a wafer illustrating the structure of a chip manufactured using the complementary bipolar/CMOS process of the present invention. 
     FIG. 8 is a partial section view of the wafer shown in FIG. 7 after deposition of the two intrinsic epi layers and a lightly doped N type epi layer in accordance with the invention. 
    
    
     DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS 
     In accordance with the present invention, numerous experiments have been performed to evaluate effects of the durations and temperatures of pre-bake cycles and HCl cycles on the amount of released or “escaped” boron dopant atoms from the P+ regions in an P− substrate and the resulting P type autodoping of adjacent regions of the wafer. Intrinsic epitaxial “cap” layers and arsenic doped epitaxial cap layers were evaluated for their ability to reduce or suppress the P type autodoping and to increase the N type dopant concentration near the bottom of the NPN collectors. Low temperature purges and high temperature purges were evaluated with respect to their effectiveness in reducing the concentration of the undesired P type dopant during the epitaxial deposition. 
     As a result, the epitaxial growth cycle technique of the present invention was developed and was shown to reduce the amount of the previously mentioned “dip”  20  (FIG. 2) in the NPN collector doping profile by selectively providing N type dopant ions at depths deeper than achieved during an N type implantation process, and also suppressing the P type autodoping. The technique developed introduces dopant during the H 2  high temperature bake cycle. That is followed by deposition of an intrinsic epitaxial cap layer, followed by a high temperature gas purging cycle. This technique proved to be the most effective in reducing the amount of autodoping and correcting the above mentioned dip in the NPN collector profile doping to thereby provide the desired NPN collector dopant concentration profile. 
     The basic epitaxial growth cycle of the present invention introduces an N type dopant (arsenic) into the H 2  high temperature bake cycle. Then an intrinsic epitaxial layer cap is deposited, followed with a high temperature purge and then completed with the final arsenic doped epitaxial layer deposition. This basic process suppresses the boron autodoping and at the same time tends to correct the NPN collector doping profile. The introduction of the N type dopant during the H 2  high temperature bake cycle proved to be very effective in correction of the NPN collector profile, as shown in FIG. 4, wherein the substantial dip  20  of prior art FIG. 1 has been corrected. 
     The process offers very good control over the dopant level at the bottom of the NPN collector. The epitaxial high temperature bake cycle of the present invention improves the NPN collector N type dopant concentration profile; this occurs without adversely affecting the P type dopant concentration profile of the PNP collectors. The described process also has a benefit in improving the PNP collector profile, especially when heavier N type compensation is required. 
     In the process flow chart of FIG. 3, blocks  1 - 4  of the illustrated process refer to conventional steps for growth of a lightly doped N type epitaxial silicon layer on a lightly doped P type silicon substrate. The low temperature step of block  4  is performed at 850° C. for roughly 10 minutes, including ramp-up. Steps  5 - 11  of FIG. 3 are performed at high temperatures in the presence of hydrogen which is used as a carrier gas. 
     Referring to FIGS. 3 and 6, note that the wafers referred to in block  1  include the numerous P+ buried layers  31  for the collectors of PNP transistors to be formed, N+ buried layers  32  of NPN transistors to be formed, and the “field” P+ region  33  such that the large (e.g., approximately 80%) of the surface area of each wafer contains a heavy concentration of P+ (boron) dopant atoms. FIG. 6 shows a single chip  30  of one of the silicon wafers. A number of P+ buried layers  31  and N+ buried layers  32  are formed in the P− substrate, as shown. An N+ “ring”  32  around each N− well  34  and P+ buried layer  31  therein as it appears in FIG. 6 is formed by a “deep N+” regions  34  in which the P+ buried layer is found. Each of the N type layers  32  and  34  is surrounded by a “ring”  35  of P− substrate material between that layer and the P+ layer  33 . 
     FIG. 7 shows a cross sectional area of a portion of the wafer  30  before the beginning of the process of FIG.  3 . Deep N− regions  34  and P− rings  35  separate and electrically isolate each P+ buried layer  31  from the rest of the P+ layer  33  of chip  30 , which includes diffused P+ material identical to that of the P+ buried layers  31 . 
     That means that when the wafers are raised to the processing temperatures of 1050° C. to 1080° C. shown in FIG. 3, many boron atoms escape from the large P+ surface area  33  of the wafer into the H 2  carrier gas and then act as a P+ dopant gas so as to “auto-dope” the N type epitaxial layer being grown, unless something is done to prevent that from occurring. If not for the present invention, the resulting decrease or decreased dip in the collector dopant concentration profiles would increase the resistivities of the collector regions of the NPN transistors subsequently formed over the N+ buried layer regions, making them slower and causing the other above mentioned performance degradation. 
     The combination of steps indicated in blocks  5 - 9  of FIG. 3 is new in an epitaxial silicon growth process. Specifically, the step of block  5 , to include N+ type dopant (arsenic) molecules in the H 2  carrier gas during such a heating step in an epitaxial growth process is novel, and is necessary to counteract the escaped “P+” boron atoms involved in the autodoping. 
     Although it is conventional to perform the high temperature bake step of a prior art epitaxial silicon growth process in the presence of hydrogen at high temperature, it is novel to include N+ dopant molecules in the hydrogen carrier gas during such high temperature bake step as indicated in block  6 . This high temperature bake step is performed at 1050° C. for two minutes. In blocks  5  and  6  the amount of N+ dopant gas injected is approximately 280 sccm (standard cubic centimeters per minute) in a total H 2  flow of 280 slm (standard liters per minute). 
     As indicated in block  7  of FIG. 3, a very thin 0.3 micron layer or “cap” layer  36  of intrinsic, i.e., undoped, epitaxial silicon, shown in FIG. 8, is deposited over the entire surface of the wafer to form a “seal” or cap over the large percentage of the wafer which has P+ “field” diffusion and P+ buried layers therein. This intrinsic “cap” layer  36  prevents the above mentioned P+ boron atoms from escaping from the large P+ area into the hydrogen carrier gas. Intrinsic cap layer  36  also inhibits P+ boron atoms in the carrier gas form entering the N+ buried layers  32 . Thus, the intrinsic cap layer  36  inhibits above mentioned P type “auto-doping” that reduces N type dopant concentration in the collectors of the subsequently formed NPN transistors and reduces their operating speeds. 
     Block  8  refers to a high temperature gas purge cycle at 1080° C. for approximately 5-10 minutes, depending on the ratio of P+ field area  33  to the total wafer area to cause redistribution of the dopant molecules in the wafer in accordance with the above mentioned ratio of the P+ field diffusion area to the “non-P+” area. The high temperature gas purge cycle of block  8  also causes outgassing of arsenic molecules previously diffused during the high temperature bake cycle of blocks  5  and  6  into the susceptor (on which the substrates are supported) and into other surfaces of the inside of the reactor. The high temperature gas purge cycle of block  8  prevents these outgassed N type dopant molecules from doping the next intrinsic cap layer  37 , shown in FIG. 8, deposited according to block  9  of FIG. 3, and was found to be necessary to achieve the desired NPN collector dopant concentration profile without a substantial dip  20  (FIG.  2 ). 
     The second high temperature gas purge cycle at 1080° C. indicated in block  10  is not nearly as critical as the first high temperature gas purge cycle of block  8 , because the first high temperature gas purge cycle eliminates a majority of the dopant molecules that otherwise would enter the carrier gas from the various inner surfaces of the reactor and susceptor and then reenter the wafer surface and therefore affect the dopant concentration profiles of the NPN and PNP transistors. 
     The main reason for depositing the second intrinsic cap layer  37  according to block  9  is to provide a “sharper” transition in the dopant concentration profile than would be achieved if only a single intrinsic cap layer were provided. The elimination of the undesired autodoping species by the first high temperature gas purge cycle of block  8  is what makes it possible for the second intrinsic cap layer  37  to continue the initial sharp transition that would be made into a more gradual transition if the extraneous dopant species from the inner surfaces of the reactor were not first removed. 
     Block  9  of FIG. 3 illustrates the growth of the above-mentioned second intrinsic 0.3 micron cap layer  37  of undoped epitaxial silicon at 1080° C. on top of the first 0.3 micron intrinsic layer  36  grown in step  7 . Second cap layer  37  further helps to prevent undesired P type and N type auto-doping. Then, after a short, high temperature bake process at 1080° C. for 1 minute as indicated in block  10 , a conventional 0.9 micron Nepitaxial deposition of silicon layer  38 , shown in FIG. 8, is formed on the top of the second intrinsic cap at 1080° C., as indicated in block  11 . The total thickness of the composite epitaxial silicon layer  36 ,  37 ,  38  formed on the wafer substrate therefore is 0.3+0.3+0.9=1.5 microns. 
     In accordance with the present invention, the presence of the N+ dopant during the steps of blocks  5  and  6  provides enough N+ atoms which, during the growth of the first and second intrinsic epitaxial layers  36  and  37 , respectively, of FIG. 8 provides a graded increase in the N type concentration at the bottoms of the NPN collector regions to compensate for a decrease in N type concentration in the region which the implanted N type dopant ions failed to reach. This reduces the collector resistance, increasing the cutoff frequency f T . 
     It should be appreciated that those skilled in the art know that even if the ratio of area of P+ “field” diffusion and P+ buried layer area on the surface of a wafer to the total area of the wafer amount both the P+ is substantially less than the 80% ratio in the above described example, a serious P+ autodoping problem nevertheless will exist and need to be compensated according to the present invention. If a higher number or “density” of transistors in the wafer surface is increased, the ratio of the P+ “field” area  33  to the total wafer area may decrease to values far lower than 80%. Nevertheless, a sufficient number of P+ atoms may escape and cause autodoping that, without the present invention, result in a significant dip in the N type dopant concentration profile at the “bottoms” of the NPN collector regions. Therefore, the high temperature bake cycle in the presence of N+ dopant to compensate such P+ autodoping and at least one, and preferably two, intrinsic epi cap layers will suppress the P− autodoping as described herein. 
     Note that the high temperature gas purge cycle of block  8  can be used to “fine tune” the shape of the N type dopant concentration profile for the NPN transistors as a function of the above-mentioned ratio of the P+ “field” diffusion area  33  to the total area of the wafer surface in which the integrated circuit is formed by adjusting the duration and temperature of the temperature of that high temperature bake cycle. 
     As a result of the foregoing process, doping profiles shown in FIG. 4 for the collectors of NPN transistors formed in the 1.5 micron epitaxial layer are achieved. This doping profile avoids the “dip”  20  in the N type dopant concentration shown in prior art FIG. 2 representing the previously described undesirably low concentration of N type impurities at the bottoms of the NPN collector regions. 
     Thus, the invention provides an epitaxial process engineered specifically to (1) reduce the boron autodoping effect and (2) correct the differences in profiles of the PNP and NPN collector regions. Thin, intrinsic epitaxial layers are formed on a lightly doped P type silicon substrate having a large percentage of its surface area occupied by P+ regions, and a smaller percentage by N+ regions, for the purpose of preventing outgassing of P type impurity atoms during growth of an epitaxial N− layer and preventing such P type atoms from auto-doping the bottom portions of the N− Epitaxial layers above N+ buried layer regions formed in the substrate. 
     By way of definition, the term “intrinsicly-formed” is used to refer to an epitaxial layer that is formed without dopant being introduced from an external or outside source into the reactant gas, even though dopant impurities are formed in the “intrinsicly-formed” epitaxial layers because such dopant impurities are introduced into the reactant gas from ambient internal sources. Such ambient internal sources include autodoping from heavily doped regions formed earlier in the substrate and also include N+ atoms introduced into surfaces of the system earlier during the temperature ramp up of block  5  of FIG. 3 in the presence of N+ gas and the high temperature bake of block  6  of FIG. 3 in the presence of N+ gas. 
     Appendix 1, attached hereto and incorporated herein, is a copy of a related unpublished paper by the inventors to be publicly presented by the inventors approximately Sep. 20, 1998. 
     While the invention has been described with reference to several particular embodiments thereof, those skilled in the art will be able to make the various modifications to the described embodiments of the invention without departing from the true spirit and scope of the invention. It is intended that all elements or steps which are insubstantially different or perform substantially the same function in substantially the same way to achieve the same result as what is claimed are within the scope of the invention.