Patent Publication Number: US-2023137279-A1

Title: Low intensity radiation curable silicone release coating composition and method for its preparation and use

Description:
CROSS REFERENCE 
     This application claims the benefit of U.S. Provisional Patent Application Ser. No. 63/042,253 filed on Jun. 22, 2020 under 35 U.S.C. § 119 (e). U.S. Provisional Patent Application Ser. No. 63/042,253 is hereby incorporated by reference. 
    
    
     TECHNICAL FIELD 
     A curable silicone release coating composition cures to form a silicone release coating by exposure to low intensity UV radiation. The curable silicone release coating composition has long pot life and short cure time. 
     INTRODUCTION 
     Silicone release coatings are often prepared by platinum catalyzed hydrosilylation of a curable composition including a vinyl terminated polydiorganosiloxane base polymer, a polyorganohydrogensiloxane crosslinker, a platinum catalyst, and other additives. The compositions may be stored under conditions to avoid premature cure and are typically mixed shortly before use. The curable composition can then begin to cure. 
     There is a need in the release coating industry for curable compositions to have relatively long bath life, i.e., it desirable for the curable composition to remain as a flowable liquid (without viscosity increase or with less than doubling in viscosity) during the time in which the curable composition is in coating bath for use with coating equipment. The coating equipment is used to coat the curable composition onto a surface of a substrate, such as a backing paper or plastic film. The curable composition is then cured, e.g., by heating and/or exposure to actinic radiation to form a release liner. 
     An inhibitor, such as 1-ethynyl-1-cyclohexanol (ETCH), is an additive typically included in the curable composition to increase pot life. However, adding the inhibitor can slow cure speed of the curable composition, such that after the curable composition is coated on the surface of the substrate, high temperatures and/or long heating times (for thermally cured compositions) or intense UV radiation exposure (for UV initiated systems) are needed to cure the composition to form the release coating on the substrate. Relatively high platinum loadings may also be needed, e.g., for high speed coating and curing equipment, and this can add significant cost. Therefore, there is an industry need for a cost effective curable silicone release coating composition, which is curable to form a silicone release coating, wherein the composition has both long pot life and short cure time. 
     SUMMARY 
     A composition is curable to form a silicone release coating. This curable silicone release coating composition comprises: 
     (A) a polyorganosiloxane having at least two aliphatically unsaturated groups per molecule,
 
(B) a polyorganohydrogensiloxane,
 
(C) a platinum hydrosilylation reaction catalyst package,
 
(D) an inhibitor selected from the group consisting of a fumarate and a maleate, and
 
(E) a primary or secondary alcohol.
 
    
    
     DETAILED DESCRIPTION 
     In addition to (A) polyorganosiloxane having at least two aliphatically unsaturated groups per molecule, (B) the polyorganohydrogensiloxane, (C) the platinum hydrosilylation reaction catalyst package, (D) the inhibitor, and (E) the primary or secondary alcohol, described above, the curable composition described above may optionally further comprise one or more additional starting materials selected from the group consisting of (F) an anchorage additive, (G) a solvent, (H) a release force modifier, and (I) a filler. 
     (A) Polyorganosiloxane Having at Least Two Aliphatically Unsaturated Groups Per Molecule 
     The polyorganosiloxane having at least two aliphatically unsaturated groups per molecule is present in the curable silicone release coating composition in an amount of 90 to 99 weight parts. 
     The polyorganosiloxane selected for starting material (A) may be linear, branched, or resinous (i.e., have a three-dimensional network), or may comprise a combination of different structures. Starting material (A) may comprise a branched polyorganosiloxane. The branched polyorganosiloxane may have formula (A-1): 
     
       
         
         
             
             
         
       
     
     where each R 1  is an independently selected monovalent hydrocarbon group free of aliphatic unsaturation; each R 2  is independently selected from the group consisting of R 1  and an aliphatically unsaturated monovalent hydrocarbon group; with the proviso that, on average per molecule, at least two instances of R 2  are the aliphatically unsaturated monovalent hydrocarbon group; subscript b is 0 or 1; R 3  is an independently selected monovalent hydrocarbon group free of aliphatic unsaturation; and each subscript a independently has a value of 30 to 60. 
     The monovalent hydrocarbon group free of aliphatic unsaturation for R 1  is exemplified by an alkyl group of 1 to 6 carbon atom or an aryl group of 6 to 12 carbon atoms. Suitable alkyl groups include methyl, ethyl, propyl, butyl, pentyl, hexyl, and branched isomers thereof. Suitable aryl groups include phenyl, tolyl, xylyl, naphthyl, 1-phenyl ethyl, and 2-phenyl ethyl. Alternatively, each R 1  may be an alkyl group. Alternatively, each R 1  may be independently selected from methyl, ethyl or propyl. Each instance of R 1  may be the same or different. Alternatively, each R 1  may be a methyl group. 
     The aliphatically unsaturated monovalent hydrocarbon group (for R 2 ) is capable of undergoing hydrosilylation reaction. Suitable aliphatically unsaturated hydrocarbon groups are exemplified by an alkenyl group such as vinyl, allyl, butenyl, and hexenyl; or alkynyl groups such as ethynyl and propynyl. Alternatively, each aliphatically unsaturated monovalent hydrocarbon group in formula (A-1) may be vinyl, allyl, or hexenyl. Alternatively, each aliphatically unsaturated monovalent hydrocarbon group in formula (A-1) may be a vinyl group. Alternatively, each R 2  in formula (A-1) may be aliphatically unsaturated. 
     Each R 3  in formula (A-1) may be an alkyl group of 1 to 6 carbon atoms. Alternatively, each R 3  may be independently selected from methyl, ethyl or propyl. Alternatively, each R 3  may be a methyl group. 
     Alternatively, the branched polyorganosiloxane of formula (A-1) may have a viscosity of 100 mPa·s to 600 mPa·s, alternatively 200 mPa·s to 400 mPa·s, as measured at RT by the test method described below for the linear or substantially linear polyorganosiloxane. 
     Alternatively, R 2  and the subscripts may be selected such that the branched polyorganosiloxane has an aliphatically unsaturated group (e.g., vinyl) content of 0.3% to 1.2%, alternatively 0.5% to 1%. Suitable branched polyorganosiloxanes for starting material (A-1) are exemplified by those disclosed in U.S. Pat. Nos. 4,374,967; 6,806,339; and U.S. Patent Publication 2007/0289495. 
     Alternatively, in addition to, or instead of, (A-1) the branched polyorganosiloxane, starting material (A) may comprise a linear polydiorganosiloxane. The linear polydiorganosiloxane may have formula (A-2): 
     
       
         
         
             
             
         
       
     
     where R 1  is as described above, each R 4  is an aliphatically unsaturated monovalent hydrocarbon group, and subscript g has a value such that 40 g 600. 
     Suitable aliphatically unsaturated hydrocarbon groups for R 4  are exemplified by an alkenyl group such as vinyl, allyl, butenyl, and hexenyl; or alkynyl groups such as ethynyl and propynyl. Alternatively, each R 4  in formula (A-2) may be vinyl, allyl, or hexenyl. Alternatively, each R 4  in formula (A-2) may be a vinyl group. 
     Alternatively, the subscripts in formula (A-2) above may have values sufficient to provide an aliphatically unsaturated group content (e.g., vinyl content) of 0.1% to 1.7%, alternatively 0.2% to 0.5%, based on the weight of the linear polydiorganosiloxane of formula (A-2). 
     Examples of linear polydiorganosiloxanes suitable for use as starting material (A-2) include i) α,ω-dimethylvinylsiloxy-terminated polydimethylsiloxane, ii) α,ω-dimethylvinylsiloxy-terminated poly(dimethylsiloxane/methylphenylsiloxane), iii) α,ω-dimethylvinylsiloxy-terminated poly(dimethylsiloxane/diphenylsiloxane), iv) α,ω-(phenyl,methyl,vinyl-siloxy-terminated) polydimethylsiloxane, v) α,ω-dimethylhexenylsiloxy-terminated polydimethylsiloxane, and vi) a combination of two or more of i) to v). 
     Methods of preparing polydiorganosiloxanes of formula (A-2), such as hydrolysis and condensation of the corresponding organohalosilanes or equilibration of cyclic polydiorganosiloxanes, are well known in the art. 
     Alternatively, starting material (A) may comprise resinous polyorganosiloxane. Resinous polyorganosiloxanes suitable for starting material (A) are known in the art. For example, U.S. Pat. No. 8,580,073 at col. 3, line 5 to col. 4, line 31, discloses silicone resins, which be prepared by any suitable method, such as cohydrolysis of the corresponding silanes or by silica hydrosol capping methods. The resinous polyorganosiloxane may be prepared by silica hydrosol capping processes such as those disclosed in U.S. Pat. No. 2,676,182 to Daudt, et al.; U.S. Pat. No. 4,611,042 to Rivers-Farrell et al.; and U.S. Pat. No. 4,774,310 to Butler, et al. The method of Daudt, et al. described above involves reacting a silica hydrosol under acidic conditions with a hydrolyzable triorganosilane such as trimethylchlorosilane, a siloxane such as hexamethyldisiloxane, or mixtures thereof, and recovering a copolymer having M-units and Q-units. The resulting copolymers generally contain from 2 to 5 percent by weight of hydroxyl groups. 
     When prepared, the resinous polyorganosiloxane comprises monofunctional (M) units of formula (R 1   2 R 2 SiO 1/2 ) and quadrifunctional (Q) units of formula (SiO 4/2 ), where R 1  and R 2  are as described above. For example, the resinous polyorganosiloxane may comprise unit formula (R 1 R 4 SiO 1/2 ) h (R 1   3 SiO 1/2 ) i (SiO 4/2 ) i , where R 1  and R 4  are as described above, subscripts h, i, and j represent mole fractions, subscript h&gt;0, subscript i≥0, subscript j&gt;0, a quantity (h+i+j)≤1. The resinous polyorganosiloxane may further comprises units with silanol (silicon bonded hydroxyl) groups and may comprise neopentamer of formula Si(OSiR 2   3 ) 4 , where R 2  is as described above. Si 29  Nuclear Magnetic Resonance (NMR) spectroscopy, as described in U.S. Pat. No. 9,593,209 at col. 32, Reference Example 2, may be used to measure molar ratio of M and Q units, where said ratio is expressed as {M(resin)+(M(neopentamer)}/{Q(resin)+Q(neopentamer)} and represents the molar ratio of the total number of M units of the resinous and neopentamer portions of the resinous polyorganosiloxane to the total number of Q units in the resinous and neopentamer portions. 
     The Mn of the resinous polyorganosiloxane depends on various factors including the types of hydrocarbyl groups represented by R 1  and R 2  that are present. The Mn of the resinous polyorganosiloxane refers to the number average molecular weight measured using gel permeation chromatography (GPC) according to the procedure in U.S. Pat. No. 9,593,209 at col. 31, Reference Example 1, when the peak representing the neopentamer is excluded from the measurement. The Mn of the resinous polyorganosiloxane may be 1,000 g/mol to 10,000 g/mol. Alternatively, Mn of the resinous polyorganosiloxane may be 1,500 g/mol to 5,000 g/mol. The 
     The resinous polyorganosiloxane prepared as described above typically contains silicon bonded hydroxyl groups, i.e., of formulae, HOSi 3/2  and/or (HO) k R 2   (3-k) SiO 1/2 , where subscript k is 1, 2, or 3. The resinous polyorganosiloxane may comprise up to 2% of silicon bonded hydroxyl groups. The concentration of silicon bonded hydroxyl groups present in the polyorganosilicate resin may be determined using Fourier Transform-Infra Red (FTIR) spectroscopy according to ASTM Standard E-168-16. For certain applications, it may desirable for the amount of silicon bonded hydroxyl groups to be below 0.7%, alternatively below 0.3%, alternatively less than 1%, and alternatively 0.3% to 0.8%. Silicon bonded hydroxyl groups formed during preparation of the resinous polyorganosiloxane can be converted to trihydrocarbyl siloxane groups by reacting the silicone resin with a silane, disiloxane, or disilazane containing the appropriate terminal group. Silanes containing hydrolyzable groups may be added in molar excess of the quantity required to react with the silicon bonded hydroxyl groups on the resinous polyorganosiloxane. 
     Alternatively, the resinous polyorganosiloxane may further comprises 2% or less, alternatively 0.7% or less, and alternatively 0.3% or less, and alternatively 0.3% to 0.8% of units represented by formula XSiO 3/2  and/or XR 2   2 SiO 1/2  where R 2  is as described above, and X represents a hydrolyzable substituent. 
     The resinous polyorganosiloxane typically has terminal aliphatically unsaturated groups. The resinous polyorganosiloxane having terminal aliphatically unsaturated groups may be prepared by reacting the product prepared as described above with an unsaturated organic group-containing endblocking agent and an endblocking agent free of aliphatic unsaturation, in an amount sufficient to provide from 1.2% to 6%, alternatively 1.5% to 6%, and alternatively 1.6% to 5.5%, of aliphatically unsaturated groups, based on weight of the resinous polyorganosiloxane. Examples of endblocking agents include, but are not limited to, silazanes, siloxanes, and silanes. Suitable endblocking agents are known in the art and exemplified in U.S. Pat. Nos. 4,584,355; 4,591,622; and 4,585,836. A single endblocking agent or a mixture of such agents may be used to prepare such resin. 
     Starting material (A) may comprise a combination or two or more different polyorganosiloxanes that differ in at least one property such as structure, molecular weight, monovalent groups bonded to silicon atoms and content of aliphatically unsaturated groups. 
     (B) Polyorganohydrogensiloxane 
     Starting material (B) in the curable silicone release coating composition is a polyorganohydrogensiloxane. The polyorganohydrogensiloxane may be linear, branched, or a combination thereof. The amount of polyorganohydrogensiloxane may be 1 weight part to 10 weight parts of polyorganohydrogensiloxane in the curable silicone release coating composition. 
     Starting material (B) may comprise a polydiorganohydrogensiloxane of unit formula (B-1) (R 1   3 SiO 1/2 ) p (R 1   2 SiO 2/2 ) q (R 1 HSiO 2/2 ) r (R 1   2 HSiO 1/2 ) s , where R 1  is as described above, and subscripts p, q, r, and s have values such that p is 0, 1, or 2, q≥1, r≥0, and s is 0, 1, or 2, with the proviso that a quantity (p+s)=2. A quantity (p+q+r+s) may have a value sufficient to provide the polydiorganohydrogensiloxane with a viscosity of 5 mPa·s to 200 mPa·s, alternatively 5 mPa·s to 100 mPa·s, at RT as measured by the test method described above for starting material (A). Alternatively, the subscripts may have values such that 5≤(p+q+r+s) 100. Alternatively, when r=0, then s≤3. 
     Alternatively, in unit formula (B-1) each R 1  may be selected from the group consisting of methyl and phenyl, subscript q may be 0 to 30, and subscript r may be 5 to 50. Alternatively, 10≤(q+r)≤50. Alternatively, the subscripts may be selected such that the polydiorganohydrogensiloxane of unit formula (B-1) has a silicon bonded hydrogen (SiH) content of 0.02% to 1.2%; alternatively 0.05% to 1.2%; and alternatively 0.02% to 0.3%. 
     Polydiorganohydrogensiloxanes of formula (B-1) are exemplified by: i) α,ω-dimethylhydrogensiloxy-terminated polydimethylsiloxane, ii) α,ω-dimethylhydrogensiloxy-terminated poly(dimethylsiloxane/methylhydrogensiloxane), iii) α,ω-dimethylhydrogensiloxy-terminated polymethylhydrogensiloxane, iv) α,ω-trimethylsiloxy-terminated poly(dimethylsiloxane/methylhydrogensiloxane), v) α,ω-trimethylsiloxy-terminated polymethylhydrogensiloxane, vi) α,ω-trimethylsiloxy-terminated poly(dimethylsiloxane/methylphenylsiloxane/methylhydrogensiloxane), vii) α,ω-dimethylhydrogen-siloxy-terminated polymethylphenylsiloxane, and viii) a combination of two or more of i), ii), iii), iv), v), vi), and vii). 
     Methods of preparing polydiorganohydrogensiloxanes, such as hydrolysis and condensation of organohalosilanes, are well known in the art. 
     Alternatively, starting material (B), the polyorganohydrogensiloxane may comprise a branched polyorganohydrogensiloxane (e.g., in addition to the polydiorganohydrogensiloxane described above). The branched polyorganohydrogensiloxane may have unit formula (B-2): (R 1   2 HSiO 1/2 ) t (R 1   3 SiO 1/2 ) (4-t) (R 1   2 SiO 2/2 ) u (SiO 4/2 ), where R 1  is as described above, subscript t is 1 to 4, and subscript u≥0. Alternatively, subscript u may be 0. Alternatively, subscript t may be 2 to 4, alternatively 3 to 4, and alternatively 4. The branched polyorganohydrogensiloxane may have an SiH content of 1% to 1.2% by weight of the branched polyorganohydrogensiloxane. The branched polyorganohydrogensiloxane may be prepared by known methods, such as equilibration of a branched organohydrogensiloxane oligomer and a cyclic polydiorganosiloxane, as disclosed, for example in U.S. Patent Application Publication 2019/0144752 or hydrolysis and condensation of an organohydrogensiloxane oligomer and an alkylorthosilicate. 
     (C) Platinum Hydrosilylation Reaction Catalyst Package 
     Starting material (C) in the curable silicone release coating composition is a platinum hydrosilylation reaction catalyst package comprising: 
     (C-1) a complex of platinum with an unsaturated siloxane in an amount sufficient to provide &lt;200 ppm of platinum metal, based on combined weights of starting materials (A), (B), (C), (D), and (E); and 
     (C-2) a platinum complex having a cyclopentadienyl group that is eta-bonded to the platinum atom and an alkyl group and/or an aryl group that is sigma-bonded to the platinum atom in an amount sufficient to provide 100 ppm of platinum, based on combined weights of starting materials (A), (B), (C), (D), and (E). Combined amounts of starting materials (C-1) and (C-2) are sufficient to provide a platinum content of 10 ppm to 200 ppm based on combined weights of starting materials (A), (B), (C), (D), and (E). Alternatively, the amount of starting material (C-1) may be sufficient to provide 20 ppm to 40 ppm platinum based on combined weights of starting materials (A), (B), (C), (D), and (E). Alternatively, the amount of starting material (C-2) may be sufficient to provide 10 ppm to 30 ppm platinum based on combined weights of starting materials (A), (B), (C), (D), and (E). 
     (C-1) Complex of Platinum with an Unsaturated Siloxane 
     Complexes of platinum with unsaturated siloxanes, and methods for their preparation, are disclosed, e.g., in U.S. Pat. No. 3,814,730 to Karstedt, which is hereby incorporated by reference. The complex of platinum with an unsaturated siloxane may be prepared by effecting contact between an unsaturated siloxane and a platinum halide, treating the resulting mixture to effect the removal of available inorganic halogen, and recovering the complex. The unsaturated siloxane may be a disiloxane of unit formula (R 1   v R 4   (3-v) SiO 1/2 ) 2 , where R 1  and R 4  are as described above, and each subscript v is 0 to 2. Examples of suitable disiloxanes include divinyltetramethyldisiloxane, hexavinyldisiloxane, trivinyltrimethyldimethoxysilane, and tetravinyldimethyldisiloxane. Alternatively, the unsaturated siloxane may be a cyclic siloxane of unit formula (R 1 R 4 SiO 2/2 ) w , where R 1  and R 4  are as described above, and subscript w is 3 to 12. The platinum halide that can be used is exemplified by H 2 PtCl 6 .nH 2 O, NaHPtCl 6  nH 2 O; KHPtCl 6 .nH 2 O or other platinum halides such as those disclosed in U.S. Pat. No. 3,159,601 to Ashby or U.S. Pat. No. 3,220,972 to Lamoreaux. Suitable catalysts for starting material (C-1) are commercially available and include 1,3-divinyl-1,1,3,3-tetramethyldisiloxane complexes with platinum (Karstedt&#39;s Catalyst). 
     (C-2) Platinum Complex Having a Cyclopentadienyl Group 
     Starting material (C-2) in the catalyst package is a platinum complex having a cyclopentadienyl group that is eta-bonded to the platinum atom and a group that is sigma-bonded to the platinum atom. Exemplary platinum complexes having a cyclopentadienyl group that is eta-bonded to the platinum atom and a group that is sigma-bonded to the platinum atom include a platinum complex having a cyclopentadienyl group that is eta-bonded to the platinum atom and 3 aliphatic groups that are sigma-bonded to the platinum atom. Such a platinum complex may be an (η-cyclopentadienyl)tri(σ-aliphatic)platinum complex of formula: 
     
       
         
         
             
             
         
       
     
     where each R M  is an independently selected monovalent aliphatic hydrocarbon group of 1 to 18 carbon atoms that is sigma bonded to the platinum atom, and RCP is a group which is eta-bonded to the platinum atom and which is selected from the group consisting of a cyclopentadienyl group or a cyclopentadienyl group functionalized with a substituent selected from the group consisting of a halogen atom, an alkyl group, an aromatic group, and an organosilyl group bonded to a carbon atom in the cyclopentadienyl ring. R M  may be a hydrocarbyl group or an acyl group. The groups for R M  can be straight-chain, branched-chain, and, if sufficiently large, cyclic. Examples of such (q-cyclopentadienyl)tri(σ-aliphatic)platinum complexes include trimethyl(methylcyclopentadienyl)platinum(IV); trimethyl(cyclopentadienyl)platinum(IV); ethyl,dimethyl(cyclopentadienyl)platinum(IV); triethyl(cyclopentadienyl)platinum(IV); triallyl(cyclopentadienyl)platinum(IV); trimethyl(trimethylsilylcyclopentadienyl)platinum(IV); trimethyl(dimethylphenylsilylcyclopentadienyl)platinum(IV); trimethyl[1-methyl-3-(2′-naphthyl)cyclopentadienyl]platinum(IV), and acetyl,dimethyl(cyclopentadienyl)platinum(IV). Alternatively, starting material (C-2) may be trimethyl(methylcyclopentadienyl)platinum(IV). Suitable examples of such catalysts and methods for their preparation have been disclosed, for example, in U.S. Pat. No. 4,510,094 to Drahnak; U.S. Pat. No. 4,916,169 to Boardman, et al.; U.S. Pat. No. 6,376,569 to Oxman, et al.; U.S. Pat. No. 6,451,869 to Butts; and U.S. Pat. No. 8,088,878 to Koellnberger. 
     (D) Inhibitor 
     Starting material (D) in the curable silicone release coating composition is an inhibitor selected from the group consisting of a fumarate and a maleate. The inhibitor may be used in an amount of &gt;300 ppm to &lt;1,000 ppm, alternatively &gt;300 ppm to &lt;900 ppm, alternatively 400 ppm to 800 ppm, based combined weights of starting materials (A), (B), (C), (D), and (E). 
     
       
         
         
             
             
         
       
     
     The inhibitor may be (D-1) a fumarate. The fumarate may have formula where each R is independently selected from the group consisting of an alkyl group of 1 to 4 carbon atoms and an alkenyl group of 2 to 4 carbon atoms. 
     Alternatively, the inhibitor may be (D-2) a maleate. The maleate may have formula 
     
       
         
         
             
             
         
       
     
     where each R is independently selected from the group consisting of an alkyl group of 1 to 4 carbon atoms and an alkenyl group of 2 to 4 carbon atoms. 
     Alternatively, starting material (D) may be selected from the group consisting of dimethyl fumarate, diethyl fumarate, diallyl fumarate, dimethyl maleate, diethyl maleate, dipropyl maleate, and diallyl maleate. Alternatively, starting material (D) may be selected from the group consisting of diethyl maleate, diallyl maleate, diethyl fumarate, diallyl fumarate, and a combination of two or more thereof. Suitable maleates and fumarates are commercially available. 
     (E) Primary or Secondary Alcohol 
     Starting material (E) in the curable silicone release coating composition is a primary or secondary alcohol in an amount of &gt;0.3 parts by weight &lt;0.8 parts by weight, alternatively 0.4 parts by weight to 0.7 parts by weight, alternatively 0.5 parts by weight to 0.6 parts by weight, and alternatively 0.5 parts by weight; based on combined weights of starting materials (A), (B), (C), (D), and (E). Starting material (E) may be selected from the group consisting of an alkanol and an aromatic alcohol. Exemplary alkanols include methanol, ethanol, 1-butanol, 2-butanol, tetradecanol, iso-propanol, and iso-butanol. Exemplary aromatic alcohols include benzyl alcohol, phenol, methylphenyl carbinol, and 2-phenylethyl alcohol. Alternatively, starting material (E) may be an aromatic alcohol. Alternatively, starting material (E) may be benzyl alcohol. Suitable primary and secondary alcohols for starting material (E) are commercially available. 
     The curable silicone release coating composition may optionally further comprise one or more additional starting materials selected from the group consisting of (F) an anchorage additive, (G) a solvent, (H) a release force modifier, (I) a filler, and (J) a combination of two or more of (F), (G), (H), and (I). 
     (F) Anchorage Additive 
     Starting material (F) is an anchorage additive. Suitable anchorage additives are exemplified by a reaction product of a vinyl alkoxysilane and an epoxy-functional alkoxysilane; a reaction product of a vinyl acetoxysilane and epoxy-functional alkoxysilane; and a combination (e.g., physical blend and/or a reaction product) of a polyorganosiloxane having at least one aliphatically unsaturated hydrocarbon group and at least one hydrolyzable group per molecule and an epoxy-functional alkoxysilane (e.g., a combination of a hydroxy-terminated, vinyl functional polydimethylsiloxane with glycidoxypropyltrimethoxysilane). Suitable anchorage additives and methods for their preparation are disclosed, for example, in U.S. Pat. No. 9,562,149; U.S. Patent Application Publication Numbers 2003/0088042, 2004/0254274, 2005/0038188; 2012/0328863 at paragraph [0091] and 2017/0233612 at paragraph [0041]; and European Patent 0 556 023. Anchorage additives are commercially available. For example, SYL OFF™ 297 and SYL-OFF™ 397 are available from Dow Silicones Corporation of Midland, Mich., USA. Other exemplary anchorage additives include (F-1) vinyltriacetoxysilane, (F-2) glycidoxypropyltrimethoxysilane, and (F-3) a combination of (F-1) and (F-2). This combination (F-3) may be a mixture and/or a reaction product. 
     The exact amount of anchorage additive depends on various factors including the type of substrate and whether a primer is used, however, the amount of anchorage additive in the curable silicone release coating composition may be 0 to 2 parts by weight, per 100 parts by weight of starting material (A). Alternatively, the amount of anchorage additive, may be 0.01 to 2 parts by weight, per 100 parts by weight of starting material (A). 
     (G) Solvent 
     Starting material (G) is a solvent. Suitable solvents are exemplified by polyalkylsiloxanes, alcohols, ketones, aromatic hydrocarbons, aliphatic hydrocarbons, glycol ethers, tetrahydrofuran, mineral spirits, naphtha, tetrahydrofuran, mineral spirits, naphtha, or a combination thereof. Polyalkylsiloxanes with suitable vapor pressures may be used as the solvent, and these include hexamethyldisiloxane, octamethyltrisiloxane, hexamethylcyclotrisiloxane and other low molecular weight polyalkylsiloxanes, such as 0.5 to 1.5 cSt DOWSIL™ OS FLUIDS, which are commercially available from Dow Silicones Corporation of Midland, Mich., U.S.A. 
     Alternatively, starting material (G) may comprise an organic solvent. The organic solvent can be an alcohol such as methanol, ethanol, isopropanol, butanol, or n-propanol; a ketone such as acetone, methylethyl ketone, or methyl isobutyl ketone; an aromatic hydrocarbon such as benzene, toluene, or xylene; an aliphatic hydrocarbon such as heptane, hexane, or octane; a glycol ether such as propylene glycol methyl ether, dipropylene glycol methyl ether, propylene glycol n-butyl ether, propylene glycol n-propyl ether, or ethylene glycol n-butyl ether, tetrahydrofuran; mineral spirits; naphtha; or a combination thereof. 
     The amount of solvent will depend on various factors including the type of solvent selected and the amount and type of other starting materials selected for the release coating composition. However, the amount of solvent may be 0% to 99%, alternatively 2% to 50%, based on the weight of all starting materials in the curable silicone release coating composition. The solvent may be added during preparation of the curable silicone release coating composition, for example, to aid mixing and delivery of one or more starting materials (e.g., one or both of starting materials (C-1) and (C-2), or a resin, when a resin is used). All or a portion of the solvent may optionally be removed after the curable silicone release coating composition is prepared. 
     (H) Release Modifier 
     The curable silicone release coating composition may contain a release modifier to control (decrease) the level of release force (the adhesive force between the release coating and an adherend thereto, such as a label including a pressure sensitive adhesive). Curable silicone release coating compositions having the required release force can be formulated from a modifier-free release coating composition by adjusting the level of modifier. Examples of suitable release modifiers include trimethylsiloxy-terminated dimethyl, phenylmethylsiloxanes. Alternatively, the release modifier may be a condensation reaction product of an organopolysiloxane resin having hydroxyl or alkoxy groups and a diorganopolysiloxane with at least one hydroxyl or hydrolyzable group. If used, a release modifier can, for example, be used at 0 to 85 parts by weight, alternatively 25 to 85 parts, per 100 parts of starting material (A). Examples of suitable release modifiers are disclosed, for example, in U.S. Pat. No. 8,933,177 and U.S. Patent Application Publication 2016/0053056. 
     Other optional starting materials which may also be added to the curable silicone release coating composition described herein include, for example, reactive diluents, fragrances, preservatives and fillers, for example, silica, quartz or chalk. 
     When selecting starting materials for the curable silicone release coating composition, there may be overlap between types of starting materials because certain starting materials described herein may have more than one function. For example, certain particulates may be useful as fillers and as pigments, and even as flame retardants, e.g., carbon black. When adding additional starting materials to the curable silicone release coating composition, the additional starting materials are distinct from starting materials (A) to (E) and from one another. 
     Alternatively, the curable silicone release coating composition may be free of filler or contains only a limited amount of filler, such as 0 to 30% by weight of the release coating composition. Without wishing to be bound by theory, it is thought that fillers can agglomerate or otherwise stick to the coater equipment used to apply the curable silicone release coating composition to a substrate and/or hinder optical properties, for example transparency, of the release coating and of the release liner formed therewith, if optical transparency is desired. The fillers may be prejudicial to the adherence of an adherend. 
     The curable silicone release coating composition described herein may be free from fluoroorganosilicone compounds. It is believed that, during the cure, a fluorocompound, because of its low surface tension, will rapidly migrate to the interface of a coating composition and a substrate, for example a polyorganosiloxane release coating composition/PET film interface, and prevent adherence of the release coating (prepared by curing the curable silicone release coating composition) to the substrate by making a fluorine containing barrier. By making a barrier, the fluorocompound prevents any component from reacting at the interface. Moreover, fluorosilicone compounds are usually expensive. 
     The curable composition may be prepared by combining starting materials comprising (A), (B), (C), (D), and (E) along with any optional additional starting materials, in any order of addition, optionally with a master batch, and optionally under shear. 
     A method for preparing a coated substrate with the curable silicone release coating composition is also provided. The method comprises coating the curable silicone release coating composition on the substrate. The method further comprises curing the curable composition on the substrate. Curing may be performed by exposure to ultraviolet radiation at low intensity, i.e., ultra-violet radiation at an intensity 1 J/cm 2  is sufficient to cure the curable silicone release coating composition on the substrate. 
     The curable silicone release coating composition described herein may be stored in a coating bath before and/or during coating on the substrate. The coating bath is typically at RT. The curable silicone release coating composition has a pot life 6 hours at RT in the coating bath. The curable silicone release coating composition may be coated on the substrate in any suitable manner. Typically, the curable silicone release coating composition is applied in wet form via a wet coating technique. In certain embodiments, the curable composition is applied by i) spin coating; ii) brush coating; iii) drop coating; iv) spray coating; v) dip coating; vi) roll coating; vii) flow coating; viii) slot coating; ix) gravure coating; x) Meyer bar coating; or xi) a combination of any of i) to x). Typically, coating the curable silicone release coating composition on the substrate results in a wet deposit on the substrate, which is subsequently cured to give the coated substrate, which comprises a cured film formed from the curable silicone release coating composition on the substrate. 
     The substrate is not limited and may be any substrate useful for preparing a release liner. In certain embodiments, the substrate comprises a plastic, which maybe a thermosetting and/or thermoplastic. However, the substrate may alternatively comprise paper. 
     Specific examples of suitable substrates include paper substrates such as Kraft paper, polyethylene coated Kraft paper (PEK coated paper), and regular papers; polymeric substrates such polyamides (PA); polyesters such as polyethylene terephthalates (PET), polybutylene terephthalates (PET), polytrimethylene terephthalates (PTT), polyethylene naphthalates (PEN), liquid crystalline polyesters, and the like; polyolefins such as polyethylenes (PE), polypropylenes (PP), polybutylenes, and the like; styrenic resins; polyoxymethylenes (POM); polycarbonates (PC); polymethylenemethacrylates (PMMA); polyvinyl chlorides (PVC); polyphenylene sulfides (PPS); polyphenylene ethers (PPE); polyimides (PI); polyamideimides (PAI); polyetherimides (PEI); polysulfones (PSU); polyethersulfones; polyketones (PK); polyetherketones; polyvinyl alcohols (PVA); polyetheretherketones (PEEK); polyetherketoneketones (PEKK); polyarylates (PAR); polyethernitriles (PEN); phenolic resins; phenoxy resins; thermoplastic elastomers, such as polystyrene types, polyolefin types, polyurethane types, polyester types, polyamide types, polybutadiene types, polyisoprene types, and fluoro types; and copolymers, modifications, and combinations thereof. 
     The curable silicone release coating composition, or wet deposit, is typically cured at low temperature with exposure to low intensity ultraviolet radiation. Low temperature may be, e.g., 22° C. to 25° C. The exposure conditions are sufficient to effect curing, i.e., cross-linking, of the curable silicone release composition. The exposure depends on various factors including on the elevated temperature is utilized, the temperature selected, desired film thickness, and the presence of absence of any solvent. 
     The coated substrate may be utilized as a release liner, e.g. for a tape or adhesive, including any pressure-sensitive adhesives, including acrylic resin-type pressure-sensitive adhesives, rubber-type pressure-sensitive adhesives, and silicone-type pressure-sensitive adhesives, as well as acrylic resin-type adhesives, synthetic rubber-type adhesives, silicone-type adhesives, epoxy resin-type adhesives, and polyurethane-type adhesives. Each major surface of the substrate may having a film disposed thereon for double sided tapes or adhesives. 
     Examples 
     These examples are intended to illustrate the invention to one skilled in the art and are not to be interpreted as limiting the scope of the invention set forth in the claims. Starting materials used in the following examples are described below in Table 1. 
     
       
         
           
               
               
               
               
               
             
               
                 TABLE 1 
               
               
                   
               
               
                   
                   
                   
                 H on 
                   
               
               
                   
                   
                 Vinyl 
                 Si 
                   
               
               
                   
                   
                 on Si 
                 atom 
                 Pt 
               
               
                 Name 
                 Description 
                 atom % 
                 % 
                 wt % 
               
               
                   
               
             
            
               
                 (A-1) 
                 M Vi   4 D 160 Q from Dow Silicones Corporation 
                 0.903 
                   
                   
               
               
                 (B-1)) 
                 MDHM with viscosity 20 cs from Dow Silicones 
                   
                 1.6 
                   
               
               
                   
                 Corporation 
                   
                   
                   
               
               
                 (C-1) 
                 1,3-diethenyl-1,1,3,3-tetramethyldisiloxane 
                   
                   
                  4 
               
               
                   
                 complexes platinum (Karstedt&#39;s Catalyst) 
                   
                   
                   
               
            
           
           
               
               
               
               
            
               
                 (C-2) 
                 Trimethyl(methylcyclopentadienyl)platinum(IV) 
                 Supplied from 
                 61 
               
               
                 [Pt(Me) 3 (CpMe)] 
                   
                 TCI Korea 
                   
               
               
                 (D-1) ETCH 
                 1-ethynyl-1-cyclohexanol 
                   
                   
               
               
                 Omnirad 102 
                 2-hydroxy-2-methylpropiophenone 
                   
                   
               
               
                 TTMSS 
                 Tris(trimethylsilyl)silane 
                   
                   
               
               
                 (D-2) Diethyl 
                 (IUPAC:diethyl (E)-but-2-enedioate) C 8 H 12 O 4   
                   
                   
               
               
                 fumarate 
                   
                   
                   
               
               
                 (D-3) Diethyl 
                 (IUPAC:diethyl (Z)-but-2-enedioate) C 8 H 12 O 4   
                   
                   
               
               
                 maleate 
                   
                   
                   
               
               
                 (D-4) Diallyl 
                 (IUPAC:bis(prop-2-enyl) (Z)-but-2-enedioate) 
                   
                   
               
               
                 maleate 
                 C 10 H 12 O 4   
                   
                   
               
               
                 (E-1) Benzyl 
                 (IUPAC:phenylmethanol) C 6 H 5 CH 2 OH 
                   
                   
               
               
                 alcohol 
               
               
                   
               
            
           
         
       
     
     In this Reference Example 1, samples of curable silicone release coating compositions were prepared by mixing starting materials from Table 1 in the amounts shown below in Tables 2 and 3. 
     In this Reference Example 2, curability of each sample prepared as described in Reference Example 1 was evaluated as follows. A 1 μm coating of a sample was made on a PET substrate. The coating was exposed to UV light (Source: Metal halide D-bulb). After exposure the curability was recorded as required UV intensity for phase changing from liquid state to solid state. The results are shown in Tables 2 and 3. 
     In this Reference Example 3, pot life of each sample prepared as described in Reference Example 1 was evaluated as follows. Pot life was the time when the viscosity doubled as measured using a Brookfield DV-1 viscometer, Temperature 25° C., Spindle: CPA-40Z, Torque &gt;70%). The results are shown in Tables 2 and 3. 
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 2 
               
               
                   
               
               
                   
                   
                 Test-16 
                 Test-17 
                 Test-18 
                 Test-19 
                 Test-20 
                 Test-21 
                 Test-22 
                 Test-24 
                 Test-25 
                 Test-26 
                 Test-27 
                 Test-28 
               
               
                   
               
             
            
               
                 Starting Material 
                 Unit 
                 CE1 
                 CE2 
                 CE3 
                 CE4 
                 CE5 
                 CE6 
                 CE7 
                 CE8 
                 CE9 
                 WE10 
                 CE11 
                 CE12 
               
               
                   
               
               
                 (A-1) 
                 pbw 
                 97.95 
                 97.95 
                 97.95 
                 97.95 
                 97.95 
                 97.95 
                 97.95 
                 97.95 
                 97.95 
                 97.95 
                 97.95 
                 97.95 
               
               
                 (B-1) 
                   
                 2.05 
                 2.05 
                 2.05 
                 2.05 
                 2.05 
                 2.05 
                 2.05 
                 2.05 
                 2.05 
                 2.05 
                 2.05 
                 2.05 
               
               
                 (C-1) 
                 Pt ppm 
                 30 
                 30 
                 30 
                 30 
                 30 
                 30 
                 30 
                 30 
                 30 
                 30 
                 30 
                 30 
               
               
                 (C-2) 
                   
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
                 20 
                 20 
                 20 
               
               
                 (D-2) 
                 ppm 
                 150 
                 300 
                 600 
                 900 
                 1200 
                 600 
                 600 
                 600 
                 600 
                 600 
                 600 
                 600 
               
               
                 (E-1) 
                 pbw 
                 0.5 
                 0.5 
                 0.5 
                 0.5 
                 0.5 
                 0.1 
                 0.3 
                 0.8 
                 1.0 
                 0.5 
                 0.8 
                 1.0 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Calculation 
                 CE1 
                 CE2 
                 CE3 
                 CE4 
                 CE5 
                 CE6 
                 CE7 
                 CE8 
                 CE9 
                 WE10 
                 CE11 
                 CE12 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 (D-2)/Pt 
                 ratio 
                 5 
                 10 
                 20 
                 30 
                 40 
                 20 
                 20 
                 20 
                 20 
                 20 
                 20 
                 20 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Results 
                 CE1 
                 CE2 
                 CE3 
                 CE4 
                 CE5 
                 CE6 
                 CE7 
                 CE8 
                 CE9 
                 WE10 
                 CE11 
                 CE12 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Req&#39;d UV intensity 
                 J/cm 2   
                 1 
                 1 
                 2 
                 3 
                 5 
                 1 
                 1.5 
                 4 
                 8 
                 1 
                 2 
                 5 
               
               
                 for cure 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Pot life 
                 hr 
                 0.5 
                 3 
                 6 
                 10 
                 24 
                 0.5 
                 4 
                 8 
                 12 
                 6 
                 8 
                 12 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 3 
               
             
            
               
                   
               
               
                 Additional Comparative Examples 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 Test 
                   
                 Test 
               
               
                   
                   
                 Test 1 
                 Test 3 
                 Test 4 
                 Test 5 
                 Test 7 
                 Test 8 
                 Test 9 
                 10 
                 Test 11 
                 12 
               
               
                   
               
               
                 Starting Material 
                 Unit 
                 CE13 
                 CE14 
                 CE15 
                 CE16 
                 CE17 
                 CE18 
                 CE19 
                 CE20 
                 CE21 
                 CE22 
               
               
                   
               
               
                 (A-1) 
                 pbw 
                 97.95 
                 97.95 
                 97.95 
                 97.95 
                 97.95 
                 97.95 
                 97.95 
                 97.95 
                 97.95 
                 97.95 
               
               
                 (B-1) 
                   
                 2.05 
                 2.05 
                 2.05 
                 2.05 
                 2.05 
                 2.05 
                 2.05 
                 2.05 
                 2.05 
                 2.05 
               
               
                 (C-1) 
                 Pt ppm 
                 30 
                 30 
                 30 
                   
                 30 
                 30 
                 68 
                 68 
                 68 
                 30 
               
               
                 (C-2) 
                   
                   
                   
                   
                 30 
                   
                   
                   
                   
                   
                   
               
               
                 (D-1) 
                 ppm 
                 600 
                   
                   
                   
                   
                   
                 120 
                   
                 600 
                   
               
               
                 (D-2) 
                   
                   
                   
                   
                   
                   
                   
                   
                 120 
                   
                 600 
               
               
                 (D-3) 
                   
                   
                 600 
                   
                   
                 600 
                   
                   
                   
                   
                   
               
               
                 (D-4) 
                   
                   
                   
                 600 
                   
                   
                 600 
                   
                   
                   
                   
               
               
                 (E-1) 
                 pbw 
                   
                   
                   
                   
                 0.5 
                 0.5 
                   
                   
                   
                   
               
               
                 Omnirad 201 
                 ppm 
                   
                   
                   
                   
                   
                   
                 310 
                 310 
                 310 
                   
               
               
                 TTMSS 
                 ppm 
                   
                   
                   
                   
                   
                   
                 4.6 
                 4.6 
                 4.6 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Results 
                 CE13 
                 CE14 
                 CE15 
                 CE16 
                 CE17 
                 CE18 
                 CE19 
                 CE20 
                 CE21 
                 CE22 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Req&#39;d UV intensity for cure 
                 J/cm 2   
                 Not 
                 2 
                 4 
                 4 
                 2 
                 4 
                 1 
                 — 
                 6 
                 2 
               
               
                   
                   
                 Cured 
                   
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Pot life 
                 hr 
                 &gt;8 
                 2 
                 3 
                 no 
                 6 
                 7 
                 &lt;5 min* 
                 0 
                 4 
                 2 
               
               
                   
                   
                   
                   
                   
                 viscosity 
                   
                   
                   
                   
                   
                   
               
               
                   
                   
                   
                   
                   
                 increase 
               
               
                   
               
            
           
         
       
     
     In Tables 2 and 3, ‘CE’ means comparative example, ‘WE’ means working example, ‘pbw’ means parts by weight, ‘ppm’ means parts per million by weight, and ‘hr’ means hours. 
     Comparative example 13 shows that when (D-1) ETCH was used as the inhibitor with only one of the two catalysts (C-1), the sample would not cure under the conditions tested. 
     Comparative Example 14 shows that that when diethyl maleate (D-3) was used as the inhibitor, and the benzyl alcohol (E-1) was omitted, then pot life was not sufficiently extended even with only one of the two catalysts from the catalyst package present. Comparative example 17 shows that when benzyl alcohol was added to the composition of comparative example 14, the sample had insufficient curability under the conditions tested. 
     Comparative Example 15 shows that when diallyl maleate (D-4) was used as the inhibitor, and the benzyl alcohol was omitted, then the sample failed both the curability and pot life tests. Comparative example 18 shows that when benzyl alcohol was added to the composition of comparative example 15, the sample still had insufficient curability under the conditions tested. 
     Comparative example 16 shows that when one catalyst from the catalyst package, i.e., (C-2) but not (C-1) was used without inhibitor and without benzyl alcohol, the sample failed the curability test. 
     Comparative examples 19-21 show that when a composition including starting materials disclosed by WO2015/090551, sufficient pot life and curability could not be obtained under the conditions tested. 
     Comparative Example 22 shows that when diethyl fumarate (D-2) was used as the inhibitor with only one of the two catalysts (C-1) and without benzyl alcohol, sufficient pot life and curability could not be obtained under the conditions tested. Comparative example 3 shows that when benzyl alcohol was added to the composition of comparative example 22, insufficient curability was obtained. Comparative examples 1-5 show that when diethyl fumarate (D-2) was used as the inhibitor with only one of the two catalysts (C-1), sufficient pot life and curability could not be obtained simultaneously under the conditions tested. Comparative examples 6-9 show that when adding different amounts of benzyl alcohol to the composition of comparative example 22, sufficient pot life and curability could not be obtained simultaneously under the conditions tested. 
     Comparative examples 11 and 12 show that when too much benzyl alcohol was added, curability was insufficient. The inventors surprisingly found that benzyl alcohol acts as a catalyst inhibitor at loading 0.8 pbw based on combined weights of starting materials (A), (B), (C), (D) and (E) under the conditions tested. Working example 10 shows that when a curable silicone release coating composition contains all of starting materials (A), (B), (C), (D) and (E) in the amounts described herein, both sufficient pot life and curability with low intensity radiation can be achieved, e.g., the radiation intensity for cure may be 1 J/cm 2  and pot life may be 6 hours. 
     INDUSTRIAL APPLICABILITY 
     The inventors surprisingly found that starting material (E), the primary or secondary alcohol (e.g., benzyl alcohol in the examples above) can have an inhibiting effect on the catalyst package when used in an amount that is too high. Without wishing to be bound by theory, it is thought that when the amount of benzyl alcohol is too high (i.e., 0.8 parts by weight), then the benzyl alcohol acts as a catalyst inhibitor, which detrimentally impacts curability by increasing the radiation intensity needed to cure the composition (e.g., to &gt;1 J/cm 2 ). Without wishing to be bound by theory, it is thought that when the amount of benzyl alcohol is too low (i.e. &lt;0.3%), a sufficient increase in pot life is not achieved.