Patent Publication Number: US-4059456-A

Title: Composition for accelerating the setting of calcined gypsum and the product formed thereby

Description:
BACKGROUND OF THE INVENTION 
     1. Field of Invention 
     The present invention relates to the process of setting a calcined gypsum slurry, is more particularly concerned with a composition for the delayed accelerating of the setting of an aqueous calcined gypsum slurry to form gypsum wallboard or plasterboard. 
     2. Prior Art 
     Gypsum board or plasterboard has long been a large volume commercial article of commerce. Generally, gypsum board is manufactured by dispersing calcined gypsum in water and adding thereto a lightweight pregenerated foam to control the finished density of the slurry and the subsequent board. Additives conventionally used in minor amounts include accelerators, bond protecting agents, fibrous reinforcements, and consistency reducers. Typical of accelerators are calcium sulfate dihydrate, potassium sulfate, ammonium sulfate, and aluminum sulfate. Bond protecting agents are usually cereal flours or starches. The fibrous reinforcements may be either cellulosic or glass. Consistency reducing agents are typified by the lignosulfonates, of which ammonium lignosulfonate is particularly advantageous. These additives are used in minor quantities in relation to the total weight of the board core, and represent, in total, less than 5%, usually less than 2%, of the weight of the finished core. 
     The calcined gypsum slurry containing the desired added ingredients is prepared in continuous mixers, as for example a primary-secondary mixer combination described in Lane et al., U.S. Pat. No. 3,359,146, or a multi-pass mixer described in Camp U.S. Pat. No. 2,660,416. The mixed slurry is continuously deposited on a paper cover sheet moving beneath the mixer. A second paper cover sheet is applied thereover and the board is passed under a roll or rolls to determine the thickness. The continuous strip thus formed is conveyed on a belt until the calcined gypsum has set, and the strip is thereafter cut to form boards of desired length, which boards are conveyed through a drying kiln to remove excess moisture. 
     The most common form of accelerator used for setting a calcined gypsum slurry is calcium sulfate dihydrate. This material appears in many forms many of which can be used when properly prepared by grinding to a high degree of fineness. This material has been found to be an excellent accelerator. However, it has been found that when the material is stored prior to use, it is highly susceptible to becoming calcined, particularly in the presence of calcined gypsum which has been bagged while still warm or in the presence of moisture or heat generally. U.S. Pat. Nos. 2,078,199 and 3,813,312 have disclosed that when sugar or soluble dextrin and ball-milled together with the calcium sulfate dihydrate, the material functions to prevent dehydration of the accelerator, even when subjected to various atmospheric conditions on storage. Additionally, U.S. Pat. No. 3,870,538 has disclosed that starch may be finely ground together with calcium sulfate dihydrate to serve as a preservative of the accelerator. However these materials, particularly sugar, have become very expensive to a degree almost prohibitive of their use. 
     SUMMARY OF THE INVENTION 
     Accordingly, it is an object of the present invention to provide a novel composition for accelerating the setting reaction of an aqueous calcined gypsum slurry. 
     It is a further object to provide a composition of the type described which maintains its effectiveness even under varying atmospheric conditions normally encountered during storage. 
     It is a further object to provide an accelerator composition which is relatively inexpensive. 
     It is another object to provide an accelerator composition which enhances the strength of the finished board. 
     It is a still further object of the invention to control the hydration of a calcined gypsum slurry to provide relatively slow temperature rise during the early portions of the hydration period as for example for the first three minutes, followed by a rapid temperature rise toward the end of the hydration period. 
     It is still another object of the invention to provide a method for preparing gypsum wallboard and to a product prepared by the said method having excellent strength and excellent adhesion between the hydrated gypsum core and the paper cover sheets affixed thereto. 
     Still further objects and advantages of the invention will appear from the following description. 
     According to the invention, a composition for accelerating the setting of a calcined gypsum slurry is prepared by finely mixing or grinding together calcium sulfate dihydrate and a lignosulfonate. The resulting accelerator composition may be stored for extended periods and subsequently added to a gypsum slurry. The accelerator composition substantially reduces the hydration period, and results in a gypsum board having excellent properties. The lignosulfonates are inexpensive materials and are commonly used in gypsum slurries to reduce water demand. If desired, the amount of lignosulfonate added to produce the accelerator may be subtracted from the amount used to reduce water demand, since the lignosulfonate added to the accelerator composition may also function to reduce water demand. However, the amount used to form the accelerator is of almost negligible amount and expense, so that a saving is accomplished even without the use of this expediency. Generally from about 0.5 to about 99% lignosulfonate based on total by weight of the accelerator composition may be used, although a preferred range is about 3 to about 25%. 
     DESCRIPTION OF THE PREFERRED EMBODIMENTS 
     The lignosulfonates, or lignin sulfonates as they are sometimes known, are anionic polyelectrolytes having molecular weights varying between 1,000 and 20,000. They are obtained as waste products from the sulfite pulping of wood, and are either used in the form obtained or else processed to increase purity and surface activity. The organic structure of the materials has not been completely determined but it is known that the basic lignin monomer unit is a substituted phenylpropane. It can be theorized that a repeating unit of the polymeric lignosulfonate could have the following structure, as shown in Table 1. 
     
                       Table 1                                                     
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 ##STR1##                                                                 
 
    
     Lignosulfonates are marketed by many companies under various trademarks. A number of lignosulfonate materials are manufactured and marketed by American Can Company, Greenich, Connecticut, and are listed under their trademarks together with their chemical analyses and physical characteristics, as follows in Table 2. The materials are prepared by refining crude lignosulfonate. 
     
                                           Table 2                                 
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TYPICAL ANALYSIS (Moisture-Free Basis)                                    
                           Marasperse                                     
                                 Marasperse                               
                                       Marasperse                         
                           C-21  CB    N-22                               
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pH--3% Solution            7.0-8.2                                        
                                 8.5-9.2                                  
                                       7.5-8.5                            
Total Sulfur as S. %       6.8   2.6   7.3                                
Sulfate Sulfur as S, %     .3    .1    1.0                                
Sulfite Sulfur as S, %     .09   0     .12                                
CaO, %                     5.2   .03   .55                                
MgO, %                     .3    Trace .3                                 
Na.sub.2 O, %              6.1   9.9   13.2                               
Reducing sugars, %         1.5   0     .8                                 
OCH.sub.3, %               7.9   12.7  7.7                                
PHYSICAL CHARACTERISTICS                                                  
                           Marasperse                                     
                                 Marasperse                               
                                       Marasperse                         
                           C-21  CB    N-22                               
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Usual Form                 Powder                                         
                                 Powder                                   
                                       Powder                             
Moisture Content (Max., % H.sub.2 O)                                      
                           7.5   8.0   7.0                                
Color                      Brown Black Brown                              
Bulk Density (lbs./cu. ft.)                                               
                           35-40 43-47 35-40                              
Solubility in Water (%)    100   100   100                                
Solubility in Oils and Most Organic Solvents (%)                          
                           0     0     0                                  
Surface Tension, 1% Sol&#39;n (in dynes/cm)                                   
                           49.4  51.4  52.8                               
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     The following lignosulfonates are also produced by the American Can Company and are unmodified or partially modified organics derived from the sulfite pulping of wood. These materials contain lignosulfonates of a broad range of molecular size, oligosaccharides, as well as wood sugars or wood sugar derivatives. The materials and their analysis and properties are produced below in Table 3 as obtained from Bulletin No. 131 of American Can Company. 
     
                                           Table 3                                 
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TYPICAL ANALYSIS (Moisture-free Basis)                                    
            Norlig                                                        
                  Norlig                                                  
                       Norlig                                             
                            Norlig                                        
                                 Norlig                                   
                                     Norlig                               
                                         Norlig                           
                                             Norlig                       
                                                  Norlig                  
                                                      Norlig              
            11    11g  11h  41   41g 41h 11d 11da                         
                                                 12   21c                 
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pH, 3% solution                                                           
            4.0-4.5                                                       
                  6.0-7.5                                                 
                       6.0-7.5                                            
                            3.0-3.5                                       
                                 6.0-7.5                                  
                                     6.0-7.5                              
                                         7.5-9.2                          
                                             3.5-4.5                      
                                                 3.0-3.7                  
                                                      7.3-8.7             
Total Sulfur as S, %                                                      
            5.4   5.1  4.9  5.9  5.8 6.1 5.3 5.6 5.5  6.0                 
Sulfate Sulfur as S, %                                                    
            Trace 0.2  0.2  0.1  0.1 5.7 0.3 0.5 0.2  .3                  
CaO, %      6.3   5.8  7.5  5.1  5.7 7.7 12.6                             
                                             6.4 0.6  5.6                 
MgO, %      0.3   0.3  0.3  0.3  0.2 0.3 0.34                             
                                             0.3 0.2  .2                  
Na.sub.2 O, %                                                             
            --    2.5  --   --   3.3 --  --  Trace                        
                                                 5.4  4.8                 
Reducing Sugars, %                                                        
            21.4  18.0 18.0 17.3 16.2                                     
                                     16.0                                 
                                         2.0-5.0                          
                                             2.0-5.0                      
                                                 21.0 Less than 4.0       
OCH.sub.3, %                                                              
            8.8   8.6  8.7  9.3  8.8 8.8 8.2 9.2 8.7  7.8                 
PHYSICAL CHARACTERISTICS--Powder Form                                     
            Norlig                                                        
                  Norlig                                                  
                       Norling                                            
                            Norlig                                        
                                 Norlig                                   
                                     Norlig                               
                                         Norlig                           
                                             Norlig                       
                                                 Norlig                   
                                                      Norlig              
            11    11g  11h  41   41g 41h 11d 11da                         
                                                 12   21c                 
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Moisture Content                                                          
            4-6.5%                                                        
Max. % H.sub.2 O                                                          
            7.0   --   7.5  6.0  --  --  7.5 7.0 6.5  3.5-6.5             
Color       Brown --   Brown                                              
                            Brown                                         
                                 --  --  Brown                            
                                             Brown                        
                                                 Brown                    
                                                      Brown               
Bulk Density                                                              
(lbs./cu. ft.)                                                            
            33    --   33   36   --  --  32  32  35   33-35               
PHYSICAL CHARACTERISTICS--Liquid Form                                     
Solids Content, %                                                         
            50-60 50-58                                                   
                       50-52                                              
                            50-58                                         
                                 50-58                                    
                                     50-54                                
                                         --  --  47   40-50               
Viscosity, Brook-                                                         
field at 77° F., cps.                                              
            45-350                                                        
                  47-400                                                  
                       75-260                                             
                            61-450                                        
                                 72-450                                   
                                     110-300                              
                                         --  --  35   40-200              
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     Other lignosulfonates suitable for use in the present invention are produced by Crown Zellerbach, Chemical Products Division, Camas, Washington, and are listed below in Table 4 together with their physical properties and analyses. The data are listed in the Bulletin entitled &#34;The Orzan Products&#34; page 13. 
     
                                           Table 4                                 
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Physical Properties                                                       
           Orzan A                                                        
                  Orzan AL-50                                             
                         Orzan S                                          
                                Orzan SL-50                               
                                         Orzan P                          
                                                Orzan PL-40               
                                                        Orzan             
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                                                        AH-3              
Physical form                                                             
           powder liquid powder liquid   powder liquid  powder            
Color      lt.brown                                                       
                  brown  tan    brown    lt.brown                         
                                                brown   dk.brown          
pH of 25% solution                                                        
           4      4      7      7        5      7       2.5               
Water content, %                                                          
           6      50     5      50       5      60      4                 
Bulk density,                                                             
           31            31              20             18                
lbs./cu.ft.                                                               
Specific gravity, 1.22          1.25            1.18                      
77° F.                                                             
Viscosity,centipoises                                                     
                  180           130             190                       
77° F.                                                             
32° F.     7800          1800                                      
Heat value,btu/lb.                                                        
           9100                                                           
Solubility in water,%                                                     
           completely soluble                           99                
Freezing point    23° F. 14° F.   27° F.             
Components                                                                
Lignin sulfonic                                                           
           57            48              51                               
acids                                                                     
Reducing sugars                                                           
           15            12              12             10                
(as glucose).sup.1                                                        
Ash.sup.2  1.5           20              5              1.5               
Alkali-liberated                                                          
           3             0.1             2.5            2                 
ammonia                                                                   
Primary cation                                                            
           ammonia                                                        
                  ammonia                                                 
                         sodium sodium   ammonia                          
                                                ammonia ammonia           
Elemental Analyses                                                        
Carbon      45.6         41.8                                             
Hydrogen   5.6           5.0                                              
Sulfur     6.4           7.0                                              
Nitrogen   3.7           0.5                                              
Sodium     0.05          5.9                                              
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.sup.1 The following sugars make up the total sugar content               
Mannose         48%                                                       
Glucose         15                                                        
Xylose          15                                                        
Galactose       10                                                        
Arabinose        6                                                        
Fructose  less than                                                       
                2                                                         
P. K. Mulvaney, H. D. Agar, Q P. Peniston and                             
J. L. McCarthy, JACS 73, 1255-7 (1951)                                    
.sup.2 Orzan A and Orzan S contain the following additional               
components.                                                               
          Orzan A                                                         
                Orzan S                                                   
Calcium   0.2%  0.2%                                                      
Potassium 0.1   0.2                                                       
Silicon   0.1   0.02                                                      
Magnesium 0.05  0.02                                                      
Manganese 0.05  0.01                                                      
Tin       0.02  0.01                                                      
Vanadium  0.01  0.005                                                     
Traces aluminum, iron, chromium, nickel, titanium, boron,                 
copper, barium, strontium, silver.                                        
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     In addition to the materials listed above, a suitable lignosulfonate is marketed as LIGNISOL by Lignisol Chemicals Ltd., of Canada. 
    
    
     DESCRIPTION OF SPECIFIC EMBODIMENTS 
     In order to test the efficacies of various commercially available lignosulfonates for use in making gypsum setting accelerator compositions according to the invention, the following tests designated as Examples 1-16, the results of which are shown in Table 5, were carried out. 
     In carrying out each test, a batch of 500 lbs. of a mixture of landplaster (calcium sulfate dihydrate) and the designated amount of lignosulfonate was ground together in a batch-type ball mill until the particle size was sufficiently reduced so that the mixture exhibited a surface area of at least 5,000 cm 2  /g, and preferably greater than 10,000 cm 2  /g, as measured by a Fischer Sub-sieve Sizer. Each accelerator composition was tested in a laboratory procedure developed for comparing the properties of various gypsum setting accelerator compositions. In carrying out the tests, in each case an amount of 180 c.c. of distilled water was placed in a 2-speed Waring Blender operated at high speed. A mixture of 200 g Southard molding plaster and 0.1 g accelerator composition was added to the blender and the lid closed. The slurry was mixed for 7 seconds and then emptied into an insulated plastic foam cup, and temperature vs. time was measured at intervals to obtain a temperature rise set (TRS) curve. From the curve the time at which the temperature stopped rising was determined and recorded as the TRS. Samples of each accelerator composition were then baked at 220° F. for 7 hours and retested in the same manner. The remaining samples of accelerator were exposed for 44 hours at 80° F., at 80% relative humidity and then tested by the same procedure described above. FIG. 5 shows the data obtained from the tests for the various materials tested. The Southard molding plaster used in each case is a very pure highly stable calcium sulfate hemihydrate (stucco). In each case 0.1 g accelerator composition was utilized with 200 g Southard molding plaster. These values were arbitrarily chosen and maintained constant for purposes of the test. In practice in forming plasterboard, other varying proportions of accelerator composition to stucco may be utilized depending on the magnitude of the set period desired. 
     The properties desired in a good gypsum-setting accelerator composition are, first of all, that the composition be one which delays setting of the gypsum composition slurry to which it is added for about 3 minutes, permitting the composition to be formed into board sheet. It is then desired that setting take place rapidly and reach completion as measured by the above-described procedure within a period of not more than about 20 minutes and preferably not more than 10 minutes, as determined by termination of temperature rise. 
     
                                           TABLE 5                                 
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                                               % Combined                 
Accelerator Additive     Temperature Rise Set In Minutes                  
                                               Water After                
                             After Baking                                 
                                      After 44 hrs.                       
                                               Baking At                  
                % By Weight of                                            
                             at 220° F for                         
                                      Exposure to                         
                                               220° F              
                                                       Surface Area       
Ex.                                                                       
   Type         Accelerator                                               
                         Fresh                                            
                             7 hrs.   80° F, 80%                   
                                               7 hrs.  cm.sup.2 /gm       
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1  NORLIG-11    25%      15.16                                            
                             15.41    15.50    27.8    14,240             
2  NORLIG-11    10%      15.33                                            
                             16.66    15.75    18.2    12,240             
3  NORLIG-11    5%       15.50                                            
                             16.25    16.84    15.5    12,837             
4  NORLIG-11    3%       16.00                                            
                             17.35    17.00    13.1    11,961             
5  MARASPERSE C-21                                                        
                3%       16.00                                            
                             18.16    19.25    10.6    12,531             
6  SUGAR        5%       16.16                                            
                             16.32    16.84    18.3    13,157             
7  LIGNOSOL     3%       16.50                                            
                             23.50    18.67    8.0     13,850             
8  ORZAN-G      3%       16.58                                            
                             18.66    17.75    14.3    11,696             
9  NORLIG-11    1%       16.75                                            
                             20.25    18.00    9.7     11,961             
10 ORZAN A      3%       17.50                                            
                             18.75    19.25    13.4    10,121             
11 NORLIG 21-C  3%       17.75                                            
                             20.58    19.90    11.6    11,696             
12 MARASPERSE B-22                                                        
                3%       17.58                                            
                             18.50    19.25    13.6    11,696             
13 MARASPERSE CBOS-3                                                      
                3%       20.16                                            
                             23.85    23.25    9.6     10,526             
14 C-211 Starch 10%      16.15                                            
                             16.00    18.15                               
15 C-211 Starch 25%      16.35                                            
                             16.40    19.45                               
16 C-211 Starch 50%      17.05                                            
                             17.30    19.15                               
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     The examples set out in Table 5 above are arranged with the various commercial trademarked lignosulfonates in decreasing order of efficacy, that is, with increasing fresh TRS values. Although all the examples exhibited accelerator properties suitable for commercial use in producing wallboard, those having the shortest TRS values are preferable. Additionally, when comparing various percentages of a particular lignosulfonate (Norlig 11) to landplaster by weight, the 25% composition appeared to have the lowest TRS, and the 1% composition the highest, although all proved to be sufficiently good for use in making plasterboard. Example 6 utilizing an accelerator composition in which conventional suger replaced lignosulfonates, and Examples 14-16 in which C-211 Starch, a commercially available acid-processed starch was used, as disclosed in U.S. Pat. 3,087,538, are provided as comparison examples. As can be seen, both 3 and 5% Norlig 11 accelerator compositions were materially superior to that formed with 5% sugar, or 10-50% starch. 
     In order to correlate the results shown in Table 5 with practical gypsum board fabrication, gypsum board was produced on standard factory machinery utilizing those accelerator compositions shown in Table 5 which exhibited excellent properties. In carrying out the tests standard factory machinery, methods, and formulations were utilized. The formulations were tailored for the particular size of the equipment. In formulating commercial gypsum slurries, generally a larger amount of accelerator composition in proportion to the stucco is required in order that the temperature rise set will be complete before the formed gypsum wallboard enteres the kiln where it is dried, since once the board enters the kiln and is heated, hydration resulting in setting terminates. Various additives commonly used in making gypsum board were also utilized, but are not all emunerated since they do not affect the action of the accelerator composition. Table 6 below shows the formulations and results obtained from the indicated accelerator composition utilizing the particular percentages listed. In every case gypsum wallboard acceptable for commercial use was obtained. 
     
                                           TABLE 6                                 
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                   Example 14                                             
                           Example 15                                     
                                    Example 16 Example 17                 
ACCELERATOR ADDITIVE                                                      
                   3% Norlig 11                                           
                           25% Norlig 11                                  
                                    3% Marasperse C-21                    
                                               3% Norlig                  
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                                               11                         
Gauging Water                                                             
           #/MS&#39;   1069    1069     1069       1069                       
Foam Water #/MS&#39;   216     216      205        205                        
Total Water                                                               
           #/MS&#39;   1285    1285     1274       1274                       
Temp. Rise Set                                                            
           No. Minutes                                                    
                   10.8    9.5      10.2       10.5                       
Fiber      #/MS&#39;   5.2     5.2      5.2        5.2                        
Starch     #/MS&#39;   6.8     6.8      6.8        6.8                        
Accelerator                                                               
           #/MS&#39;   2.2     2.2      2.4        2.4                        
Foaming Agent                                                             
           #/MS&#39;   .49     .49      .49        .50                        
Foam Air   Cu. Ft./MS&#39;                                                    
                   13.32   13.32    12.14      12.07                      
Foam Weight                                                               
           #/Ft.3  12.90   12.90    13.59      13.59                      
Wetting Agent                                                             
           #MS&#39;    1.7     1.97     1.97       1.97                       
Retarder   Oz/MS&#39;  1.0 est 1.0 est  1.0 est    1.0 est                    
Dry Stucco Weight                                                         
           No./MS&#39; 1487    1583     1564       1584                       
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     In order to compare accelerator compositions according to present invention with prior art accelerators, accelerator composition were prepared as described above, one utilizing 3% Norlig 11 and the other utilizing 5% sucrose, a prior art accelerator composition disclosed and claimed in U.S. Pat. No. 3,813,312. The results are shown below in Table 7. In each case commercially acceptable gypsum wallboard was obtained having good strength properties and good paper cover sheet adhesion. Since equally good wallboard was obtained from both accelerator compositions, the economy resulting from utilizing 3% Norlig 11 at 7.5 cents per pound over that of utilizing 5% sucrose at 54 cents per pound can be readily seen. 
     
                       TABLE 7                                                     
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                   Example 18  Example 19                                 
ACCELERATOR ADDITIVE                                                      
                   3% Norlig 11                                           
                               5% Sugar                                   
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Gauging Water                                                             
            #/MS&#39;      1099        1099                                   
Foam Water   /MS&#39;      215         215                                    
Total Water #/MS&#39;      1312        1312                                   
Temp. Rise Set                                                            
            Minutes    10          10                                     
Fiber       #/MS&#39;      6           6                                      
Starch      #/MS&#39;      6.2         6.2                                    
Accelerator #/MS&#39;      3.5         3.5                                    
Foaming Agent                                                             
            #MS&#39;       .47         .47                                    
Foam Air    Cu. Ft./MS&#39;                                                   
                       10.97       10.97                                  
Foam Weight #Ft.3      12.19       12.19                                  
Wetting Agent                                                             
            #/MS&#39;      2.9         2.9                                    
Retarder    Oz/MS&#39;     2.4         2.4                                    
Dry Stucco Weight                                                         
            #/MS&#39;      1526        1498                                   
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 *Designates pounds/thousand square feet of 1/2inch board                 
 
    
     As described above, in carrying out the laboratory tests to determine the relative efficacy of various accelerator compositions in terms of Temperature Rise Set, an amount of 0.1 g of accelerator composition was arbitrarily utilized with 200 g of calcined gypsum, the accelerator composition being 0.05% by weight with respect to the weight of the calcined gypsum. However, where longer setting times can be tolerated, as little as 0.01% by weight of the accelerator composition with respect to the weight of calcined gypsum may be utilized. 
     In the large scale tests from which the data for Tables 6 and 7 were obtained, approximately 0.15% by weight of accelerator composition with respect to the weight of dry calcined gypsum was utilized. This proportion appears to be a suitable value for general production. However, under particular conditions, as low as 0.05% by weight of accelerator composition to calcined gypsum could be used for factory production. The relative amounts used in factory production could be increased to about 1.5% by weight of accelerator composition to calcined gypsum in order to obtain a more rapid Temperature Rise Set. However, when the amount is increased above 1.5%, no substantial benefit is obtained and additionally the material cost increases. Further, when a proportion greater than 1.5% is utilized, the accelerator composition may reduce the period of low temperature rise which is normally desired for the first 3 minutes, and result in a set before the gypsum slurry has been adequately poured onto the forming belt and shaped to desired form and thickness. Generally a proportion range of about 0.05 to about 1.5% of accelerator composition to calcined gypsum for factory production is suitable, and 0.15 to 1.5% preferred. 
     In preparing the accelerator compositions according to the invention described above, finely ground landplaster was used. However, if desired other forms of gypsum may be used including by-product gypsum such as that resulting from the citric acid process. 
     The term #/MS&#39; where used denotes pounds per thousand square feet of 1/2 inch board. 
     Although in the description of the invention above the accelerator composition of the invention was tested for use in the setting of gypsum slurries, the catalyst may also be used in setting inorganic cementitious mixtures wherever a gypsum accelerator is utilized, as for example, in hydraulic cements such as portland cement. 
     The accelerator composition of the present invention has several advantages over prior art compositions. The lignosulfonates are extremely inexpensive, and much more so that sugar or starch. They are readily available in large quantities even in periods of severe food shortage when sugar or starch would not be available for commercial processing of gypsum. Further, as shown in the results of the experiments, the efficacy of lignosulfonate-containing accelerator compositions may in some cases be greater than that of conventional materials even when used in smaller amounts. Further, the material is easy to use and does not involve any hazards to the health of factory workers. 
     It is to be understood that the invention is not to be limited to the exact details of operation or compositions shown and described as obvious modifications and equivalent will be apparent to one skilled in the art.