Patent Publication Number: US-2015083605-A1

Title: Semiconductor photoelectrode and method for splitting water photoelectrochemically using photoelectrochemical cell comprising the same

Description:
This is a continuation of International Application No. PCT/JP2014/002228, with an international filing date of Apr. 21, 2014, which claims priority of Japanese Patent Application No. 2013-093528, filed on Apr. 26, 2013, the contents of which are hereby incorporated by reference. 
    
    
     BACKGROUND 
     1. Field of the Invention 
     The present invention relates to a semiconductor photoelectrode and a method for splitting water photoelectrochemically using a photoelectrochemical cell comprising the same. 
     2. Description of the Related Art 
     In order to solve increasingly serious environmental problems and energy problems for a sustainable society, it is required to put renewable energy into practical use on a full scale. Recently, a system for storing an electric power generated by a solar cell in a secondary battery has been widely used. However, it is not easy to move a secondary battery due to its weight. For this reason, hydrogen is expected to be used as an energy medium in the future. The advantage of hydrogen as an energy medium is now described below. First, hydrogen is easy to be stored. It is also easy to transfer a tank containing hydrogen. Next, a final product generated after hydrogen is combusted is water, which is harmless, safe, and clean. Furthermore, hydrogen is supplied to a fuel cell to convert it into electric power and heat. Lastly, hydrogen is formed inexhaustible in water splitting. 
     For this reason, a technology for generating hydrogen by splitting water photoelectrochemically using photocatalyst and sunlight has attractiveness, since sunlight is converted easily into an easy-to-use energy medium using the technology. Research and development has been promoted to improve generation efficiency of hydrogen. 
     WO2011/058723 discloses a photoelectrochemical cell relative to the technology. In particular, as shown in  FIG. 1 , the photoelectrochemical cell  100  disclosed in WO2011/058723 comprises a semiconductor electrode  120  which includes a conductor  121 , a first n-type semiconductor layer  122  having a nanotube array structure, and a second n-type semiconductor layer  123 ; a counter electrode  130  connected to the conductor  121 ; an electrolyte solution  140  in contact with the second n-type semiconductor layer  123  and the counter electrode  130 ; and a container  110  which contains the semiconductor electrode  120 , the counter electrode  130 , and the electrolyte solution  140 . On the basis of a vacuum level, (I) the band edge levels of the conduction band and the valence band in the second n-type semiconductor layer  123  are higher than the band edge levels of the conduction band and the valence band in the first n-type semiconductor layer  122 , respectively, and (II) the Fermi level of the first n-type semiconductor layer  122  is higher than that of the second n-type semiconductor layer  123 , and (III) the Fermi level of the conductor  121  is higher than that of the first n-type semiconductor layer  122 . 
     SUMMARY 
     In order to improve the generation efficiency of hydrogen, it is necessary to improve quantum efficiency of the semiconductor electrode furthermore. 
     An object of the present invention is to provide a semiconductor photoelectrode having high quantum efficiency and a method for splitting water photoelectrochemically using a photoelectrochemical cell comprising the same to improve the hydrogen generation efficiency. 
     The present invention provides a semiconductor photoelectrode, comprising: 
     a conductive substrate;
         a first semiconductor photocatalyst layer provided on a surface of the conductive substrate;       

     a second semiconductor photocatalyst layer provided on a surface of the first semiconductor photocatalyst layer,
         wherein   an energy difference between Fermi level of the conductive substrate and vacuum level is smaller than an energy difference between Fermi level of the first semiconductor photocatalyst layer and the vacuum level;       

     an energy difference between Fermi level of the first semiconductor photocatalyst layer and the vacuum level is smaller than an energy difference between Fermi level of the second semiconductor photocatalyst layer and the vacuum level; 
     an energy difference between a top of a valence band of the first semiconductor photocatalyst layer and the vacuum level is greater than an energy difference between a top of a valence band of the second semiconductor photocatalyst layer and the vacuum level; 
     an energy difference between a bottom of a conduction band of the first semiconductor photocatalyst layer and the vacuum level is greater than an energy difference between a bottom of a conduction band of the second semiconductor photocatalyst layer and the vacuum level; 
     the semiconductor photoelectrode has a plurality of pillar protrusions on the surface thereof; and
         a surface of each of the pillar protrusions is formed of the second semiconductor photocatalyst layer.       

     The present invention provides a semiconductor photoelectrode having high quantum efficiency and a method for splitting water photoelectrochemically using a photoelectrochemical cell comprising the same to improve the generation efficiency of hydrogen. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1  shows the photoelectrochemical cell disclosed in WO2011/058723. 
         FIG. 2  shows a measurement result of a steady state polarization curve of water splitting using two flat-and-smooth platinum electrodes included in a dilute sulfuric acid aqueous solution. 
         FIG. 3  shows a band structure of a semiconductor photocatalyst used for a semiconductor photoelectrode. 
         FIG. 4A  shows a band structure before a conductive substrate  102  and a first semiconductor photocatalyst layer  202  form the junction in a case where the first semiconductor photocatalyst layer  202  is formed of n-type semiconductor. 
         FIG. 4B  shows a band structure after the conductive substrate  102  and the first semiconductor photocatalyst layer  202  have formed the junction in a case where the first semiconductor photocatalyst layer  202  is formed of n-type semiconductor. 
         FIG. 5A  shows a band structure before the conductive substrate  102  and the first semiconductor photocatalyst layer  202  form the junction in a case where the first semiconductor photocatalyst layer  202  is formed of p-type semiconductor. 
         FIG. 5B  shows a band structure after the conductive substrate  102  and the first semiconductor photocatalyst layer  202  have formed the junction in a case where the first semiconductor photocatalyst layer  202  is formed of p-type semiconductor. 
         FIG. 6  shows a semiconductor photoelectrode  200  according to the first embodiment. 
         FIG. 7A  shows a band structure before the conductive substrate  102 , the first semiconductor photocatalyst layer  202 , and a second semiconductor photocatalyst layer  203  form the junction in a case where both the first semiconductor photocatalyst layer  202  and the second semiconductor photocatalyst layer  203  are formed of n-type semiconductor. 
         FIG. 7B  shows a band structure after the conductive substrate  102 , the first semiconductor photocatalyst layer  202 , and the second semiconductor photocatalyst layer  203  have formed the junction in a case where both the first semiconductor photocatalyst layer  202  and the second semiconductor photocatalyst layer  203  are formed of n-type semiconductor. 
         FIG. 8A  shows a band structure before the conductive substrate  102 , the first semiconductor photocatalyst layer  202 , and the second semiconductor photocatalyst layer  203  form the junction in a case where both the first semiconductor photocatalyst layer  202  and the second semiconductor photocatalyst layer  203  are formed of p-type semiconductor. 
         FIG. 8B  shows a band structure after the conductive substrate  102 , the first semiconductor photocatalyst layer  202 , and the second semiconductor photocatalyst layer  203  have formed the junction in a case where both the first semiconductor photocatalyst layer  202  and the second semiconductor photocatalyst layer  203  are formed of p-type semiconductor. 
         FIG. 9  shows a photoelectrochemical cell according to the second embodiment. 
         FIG. 10  shows how to use the photoelectrochemical cell according to the second embodiment. 
         FIG. 11  is a graph showing the results of the calculated external quantum efficiency and internal quantum efficiency in the reference example 1. 
         FIG. 12A  shows a SEM image (5,000 magnifications) of the surface of the replica film patterned in the reference example 2. 
         FIG. 12B  shows a SEM image (50,000 magnifications) of the surface of the replica film patterned in the reference example 2. 
         FIG. 13  shows a relation between a thickness of a thin film made of TiO 2  and the film-forming time in the reference example 2. 
         FIG. 14  shows a SEM image of the surface of the obtained electrode in the reference example 2. 
         FIG. 15  shows the results of the photocurrent measurement in the reference example 2. 
         FIG. 16  shows the results of the photocurrent measurement in the reference example 3. 
         FIG. 17  shows an example of a plurality of pillar protrusions formed on the surface of the semiconductor photoelectrode. 
         FIG. 18  shows desirable pillar protrusions. 
         FIG. 19  shows pillar protrusions each having light scattering particles. 
         FIG. 20  is a graph showing the transmittance T, the reflectance R, and the absorptance of the TiO 2  film in the reference example 1. 
         FIG. 21  shows a top view of this Si pillar protrusion substrate used in the example 1. 
         FIG. 22  shows a cross-sectional photograph of the Si pillar protrusion substrate used in the example 1. 
         FIG. 23  shows a graph showing the results of the photocurrent measurement in the example 1. 
         FIG. 24  shows a graph showing the results of the photocurrent measurement in the example 1 and the comparative example 1. 
     
    
    
     DETAILED DESCRIPTION OF THE EMBODIMENTS 
     The embodiments of the present invention will be described below with reference to the drawings. The following embodiments are merely preferable instances of the present invention. The present invention is not limited to the following embodiments. In the following description, the same components are designated by the same reference numerals, and hence repetitive description is omitted. 
     First Embodiment 
       FIG. 6  shows a semiconductor photoelectrode  200  according to the first embodiment. The semiconductor photoelectrode  200  comprises a first semiconductor photocatalyst layer  202  disposed on the surface of a conductive substrate  102  and a second semiconductor photocatalyst layer  203  disposed on the surface of the first semiconductor photocatalyst layer  202 . The first semiconductor photocatalyst layer  202  has a surface shape similar to pillar protrusions formed on the surface of the conductive substrate  102 . The second semiconductor photocatalyst layer  203  also has a surface shape similar to pillar protrusions formed on the surface of the first semiconductor photocatalyst layer  202 . The first semiconductor photocatalyst layer  202  is sandwiched between the conductive substrate  102  and the second semiconductor photocatalyst layer  203 . The front surface of the first semiconductor catalyst layer  202  is in contact with the back surface of the second semiconductor photocatalyst layer  203 . The back surface of the first semiconductor photocatalyst layer  202  is in contact with the front surface of the conductive substrate  102 . In this manner, a semiconductor photocatalyst layer  201  is composed of a stacked structure of the first semiconductor photocatalyst layer  202  and the second semiconductor photocatalyst layer  203 . By appropriately configuring the relationship between the band structure of the two semiconductor photocatalyst layers thus stacked, realized is the semiconductor photocatalyst layer  201  having a band structure advantageous for charge separation of carriers generated due to light absorption. For this reason, such a semiconductor photoelectrode has high quantum efficiency. In  FIG. 6 , the two semiconductor photocatalyst layers which are made of different semiconductor material to each other are stacked. However, the semiconductor photocatalyst layer  201  may be composed of three or more semiconductor photocatalyst layers. 
     A plurality of pillar protrusions formed on the surface of the semiconductor photoelectrode  200  scatter light incident on the surface of the semiconductor photoelectrode  200  and increase the light-absorption area on the semiconductor photoelectrode  200 . For this reason, the light-absorption efficiency on the semiconductor photoelectrode  200  is improved, as compared to an electrode having a flat-and-smooth surface. Note that this effect can&#39;t be obtained by merely increasing a surface area of an electrode. For example, even if an agglomerate structure or a structure having secondary holes is used, the light-absorption efficiency is not improved, since light does not goes deeply into the hole. The “structure having a secondary hole” means a structure having a surface area increased by forming secondary holes in one hole. For this reason, it is desirable that a plurality of pillar protrusions as shown in  FIG. 6  are arranged regularly in order to increase the light absorption efficiency. It is desirable that a distance between two adjacent pillar protrusions is not too narrow. Since the incident light goes deeply into the space of the two adjacent pillar protrusions due to a suitable distance between two adjacent pillar protrusions, the light-absorption efficiency is improved more. In particular, it is desirable that a suitable distance between two adjacent pillar protrusions is equal to or more than a wavelength of the light incident on the semiconductor photoelectrode  200 . 
     The effect due to the pillar protrusions is provided more surely and positively by accurately controlling the arrangement and shape of the pillar protrusions. For example, as just described, a suitable distance between two adjacent pillar protrusions is provided. In addition, by forming pillar protrusions each having a finer projection-recess shape than a conventional semiconductor photoelectrode, a higher quantum efficiency than that of the conventional semiconductor photoelectrode having a projection-recess shape is realized. It is desirable that the distance between two adjacent pillar protrusions is not more than 5 micrometers. Three micrometers is more desirable. It is desirable that each pillar protrusion has an aspect ratio of not less than 2. The aspect ratio of not less than 4 is more desirable. The aspect ratio of not less than 10 is still more desirable. It is desirable that the plurality of the pillar protrusions are arranged regularly. It is desirable that a variability of the density of the pillar protrusions on the surface of the conductive substrate  102  is as small as possible. For example, at least one protrusion is provided per region having an area of 100 square micrometers on the surface of the conductive substrate  102 . In the case where the aspect ratio of the pillar protrusion is high and the density of the pillar protrusion is high, since the effect of light scattering is improved and the light-absorption area is increased, the light-absorption efficiency is improved. 
     A liquid phase deposition method (hereinafter, referred to as “LPD method”) is suitable for the formation of the semiconductor photocatalyst layer  101  to control the arrangement and the shape of the pillar protrusions accurately as above stated and to maintain the complex surface shape thereof. The LPD method is, for example, comprises the following three processes. In the first process, the predetermined arrangement of the plurality of the pillar protrusions is patterned on a replica film. In the second process, the semiconductor photocatalyst layer  101  is formed on the patterned replica film by the LPD method. In the third process, an electric conductor, namely, the conductive substrate  102 , is formed on the semiconductor photocatalyst layer  101 . In this way, the semiconductor photoelectrode  200  can be fabricated. 
     The semiconductor photoelectrode  200  according to the present embodiment is fabricated as below. First, the semiconductor photocatalyst layer  101 , namely, the first semiconductor photocatalyst layer  202 , is formed by the LPD method on the conductive substrate  102  having a projection-recess shape on the surface thereof. Then, the second semiconductor photocatalyst layer  203  is formed by a sputtering method on the first semiconductor photocatalyst layer  202 . In this way, the semiconductor photoelectrode  200  is fabricated. For more detail, see the example 1. 
     Japanese Patent Application Laid-open Publication No. 2006-297300 discloses a semiconductor photoelectrode having a projection-recess surface. Furthermore, Japanese Patent Application Laid-open Publication No. 2006-297300 discloses three methods for fabricating a semiconductor photoelectrode having a projection-recess surface. In the first method, the substrate is mechanically polished, and then the substrate is subjected to chemical etching. In the second method, metal particles are joined onto a metal substrate by applying pressure or heat. In the third method, a metal substrate patterned using a photoresist mask is etched. 
     However, projection-recess structure is formed randomly on the surface thereof in the first and second methods. For this reason, it is difficult to accurately control the distance between two adjacent pillar protrusions included in the projection-recess structure in the first and second methods. In the third method, the projection-recess structure is controlled technically; however, the third method causes high cost. For example, it is difficult to put the semiconductor photoelectrode obtained by the third method into practical use as a semiconductor photoelectrode for splitting water using solar energy. For this reason, it is difficult to form a semiconductor photoelectrode having a dense structure on the surface thereof in accordance with the disclosure of Japanese Patent Application Laid-open Publication No. 2006-297300. 
     On the other hand, for example, by fabricating the semiconductor photoelectrode  200  according to the present embodiment by a LPD method, problems in the conventional fabrication method of the semiconductor photoelectrode can be solved. 
     Since the semiconductor photoelectrode  200  according to the present embodiment has a plurality of pillar protrusions on the surface thereof, the semiconductor photoelectrode  200  according to the present embodiment has a larger surface area than an electrode having a flat-and-smooth surface. For this reason, the substantial current density of the flowing current is decreased. As a result, overvoltage is decreased. In this way, the reaction generated on the semiconductor photoelectrode  200  is promoted. For example, if the semiconductor photoelectrode  200  is used for water splitting, water splitting reaction is promoted. 
     Hereinafter, the present inventors discuss the relationship between the current density and the overvoltage in the reaction for splitting water using two electrodes. 
     Electrolysis of water requires a voltage of 1.23 volts theoretically. However, a voltage more than 1.23 volts is required for the electrolysis of water under a practicable current density. “Overvoltage” means voltage more than a theoretical value. The value of the overvoltage is varied depending on the material used for the electrode. The overvoltage is increased with an increase in the current density flowing through the electrode. 
       FIG. 2  shows a measurement result of a steady state polarization curve of water splitting using two flat-and-smooth platinum electrodes included in a dilute sulfuric acid aqueous solution. Since platinum has a high catalytic ability as an electrode for generating hydrogen, hydrogen is generated at a voltage of a theoretical electric potential. On the other hand, when platinum is used as an electrode for generating oxygen, a voltage more than theoretical voltage, namely, more than 1.23 volts, is required to generate oxygen. In other words, when platinum is used as an electrode for generating oxygen, overvoltage is high, as is clear from  FIG. 2 . 
     Then, the present inventors discuss the relationship between the current density and the overvoltage in the hydrogen generation using the semiconductor photoelectrode. The present inventors suppose in the following discussion that the following hypotheses (I)-(III) are true. 
     (I) The semiconductor photocatalyst used for the semiconductor photoelectrode has a band structure as shown in  FIG. 3 . 
     (II) The semiconductor photocatalyst used for the semiconductor photoelectrode absorbs all solar light having energy of not less than the bandgap. 
     (III) All the generated electrons and holes are used for water splitting. 
     In this case, the obtained current density is calculated to be approximately 24 mA/cm 2 . If the bandgap is supposed to be 1.65 eV (750 nanometers), the obtained current is 23.9 mA/cm 2 . See Smestad, G. P., Krebs, F. C., Lampert, C. M., Granqvist, C. G., Chopra, K. L., Mathew, X., &amp; Takakura, H. “Reporting solar cell efficiencies in Solar Energy Materials and Solar Cells” Solar Energy Materials &amp; Solar Cells, Vol. 92, (2008) 371-373. 
     When the present inventors suppose that the semiconductor photocatalyst has a catalytic ability equivalent to that of a platinum electrode, since an energy difference between valence band level and oxygen-generating level, which is oxidation potential of water, corresponds to the overvoltage in the oxygen-generating reaction, the limit of the current density in the case where oxygen is generated with a semiconductor photoelectrode using the semiconductor photocatalyst is believed to be approximately 0.2 mA/cm 2 . Under such circumstances, even when all the light having energy of not less than the bandgap is absorbed, since the water splitting reaction generated on the surface of the semiconductor photoelectrode limits the reaction rate, the current density of approximately 24 mA/cm 2  failed to be obtained. 
     In order to solve such a problem, a projection-recess structure can be formed on the surface of the semiconductor photoelectrode. Since the current density and the overvoltage are substantially decreased with an increase in the reaction area of the electrode, the water splitting reaction progress under a greater current density, as compared to the case using a flat-and-smooth electrode. For this reason, in order to generate hydrogen with high efficiency, it is important to control the surface structure of the semiconductor photoelectrode and to increase the surface area of the semiconductor photoelectrode. 
     Hereinafter, the present inventors discuss a case where the light source for optically generating hydrogen is sunlight. When the light source is sunlight, the current density that can flow to generate hydrogen optically on the semiconductor photocatalyst is unambiguously calculated from the bandgap of the semiconductor photocatalyst. For this reason, the surface area necessary to achieve the current density that can flow to generate hydrogen optically on the semiconductor photocatalyst can be estimated from the catalytic ability of the semiconductor photocatalyst and the overvoltage. For example, it is necessary to enlarge the surface area of the semiconductor photocatalyst around equal to or more than one hundred times to obtain the current density of approximately 24 mA/cm 2  using a semiconductor photocatalyst having a catalytic ability equal to that of the Pt electrode and having a bandgap shown in  FIG. 3 . 
     Various structures are suggested to enlarge the reaction area of the semiconductor photoelectrode. For example, when the semiconductor photoelectrode is formed of TiO 2 , a titania nanotube (hereinafter, referred to as “TNT”) structure provided by anodizing a Ti substrate is exemplified. Since an electrode having a TNT structure (hereinafter, referred to as “TNT electrode”) has a structure where a plurality of tubes each having a diameter of around some hundred nanometers and made of TiO 2  are arranged densely on the surface of the Ti substrate, the TNT structure has a larger surface area than a flat-and-smooth electrode. However, the distance between the upper end of the TNT and the Ti substrate increases, when the length of the TNT is increased to enlarge the surface area. 
     When the semiconductor photoelectrode is irradiated with light, a lot of pairs of electrons and holes are generated near the surface of the semiconductor photoelectrode. For this reason, the probability of the recombination between these electrons and holes is required to be decreased in order to generate hydrogen optically with high efficiency. However, since the TNT electrode has a long distance from the upper end of the TNT to the Ti substrate, the migration distance of the generated electrons is also long. For this reason, this causes a problem that the reaction efficiency is decreased due to increase of the probability of the recombination between electrons and holes. 
     On the other hand, in the present first embodiment, pillar protrusions used for forming a projection-recess structure on the surface of the semiconductor photoelectrode  200  are formed on the surface of the conductive substrate  102 . Then, the first semiconductor photocatalyst layer  202  and the second semiconductor photocatalyst layer  203  are disposed on the surface of the conductive substrate  102 . For this reason, the distance between the second semiconductor photocatalyst layer  203  and the conductive substrate  102  is equal to the thickness of the first semiconductor photocatalyst layer  202  irrespective of aspect ratio, even if the aspect ratio of the pillar protrusion is increased to enlarge the surface area. For this reason, the migration distance of the electrons generated in the second semiconductor photocatalyst layer  203  is minimized. In this way, by using the semiconductor photoelectrode  200 , the probability of the recombination between the electrons and the holes is decreased, while the surface area is enlarged. For this reason, hydrogen is generated optically with high efficiency. 
     The first semiconductor photocatalyst layer  202  has a thickness of not less than 10 nanometers and not more than 100 nanometers. Since the first semiconductor photocatalyst layer  202  has a thickness that falls within this range, both the internal quantum efficiency and the external quantum efficiency improve. The internal quantum efficiency improves significantly. The term “quantum efficiency” used in the instant specification includes the term “external quantum efficiency” and the term “internal quantum efficiency”. In the instant specification, these two kinds of quantum efficiencies are defined as below. 
     The term “external quantum efficiency” is defined as a rate of the number of the electrons extracted as the photocurrent to the number of the photons incident on the semiconductor photoelectrode. The external quantum efficiency is an index usable for analyzing how much the photons incident on the semiconductor photoelectrode from the light source contribute as the photocurrent. 
     The term “internal quantum efficiency” is defined as a rate of the number of the electrons extracted as the photocurrent to the number of the photons absorbed by the semiconductor photoelectrode. The internal quantum efficiency is usable as an index for analyzing how much the carriers generated on or injected into the semiconductor photocatalyst layer contribute as the photocurrent. 
     Then, the materials of the conductive substrate  102  and the first semiconductor photocatalyst layer  202  will be described. 
     The materials of the conductive substrate  102  are not limited, as long as the materials of the conductive substrate  102  are metal. The conductive substrate  102  is fabricated using materials which form ohmic contact with the first semiconductor photocatalyst layer  202  to be formed thereon. For this reason, it is desirable that the energy difference between the vacuum level and the Fermi level of the conductive substrate  102  is smaller than the energy difference between the vacuum level and the Fermi level of the first semiconductor photocatalyst layer  202 , when the first semiconductor photocatalyst layer  202  is made of n-type semiconductor. These relations are described with reference to  FIG. 4A  and  FIG. 4B . 
       FIG. 4A  shows a band structure before the conductive substrate  102  and the first semiconductor photocatalyst layer  202  form the junction.  FIG. 4B  shows a band structure after the conductive substrate  102  and the first semiconductor photocatalyst layer  202  have formed the junction. In the drawings, Ec means the bottom of the conduction band of the n-type semiconductor which forms the first semiconductor photocatalyst layer  202 . Ev means the top of the valence band of the n-type semiconductor. 
     As shown in  FIG. 4A , in the case where the conductive substrate  102  and the first semiconductor photocatalyst layer  202  do not form the junction, the energy difference between the vacuum level and the Fermi level of the conductive substrate  102  (hereinafter, referred to as “EFC”) is smaller than the energy difference between the vacuum level and the Fermi level of the first semiconductor photocatalyst layer  202  (hereinafter, referred to as “EFN”). When the conductive substrate  102  and the first semiconductor photocatalyst layer  202  form the junction under the condition where such a positional relationship of the Fermi level is satisfied, carriers transfer in such a manner that these Fermi levels are equal to each other at the junction plane therebetween. As a result, the edge of the band is bent as shown in  FIG. 4B . In this case, a Schottky barrier does not occur in the first semiconductor photocatalyst layer  202 , and an ohmic contact is formed between the first semiconductor photocatalyst layer  202  and the conductive substrate  102 . Since the ohmic contact is formed between the first semiconductor photocatalyst layer  202  and the conductive substrate  102 , the migration of the electrons from the first semiconductor photocatalyst layer  202  to the conductive substrate  102  is not disturbed by the Schottky barrier. For this reason, the efficiency of the charge separation in the semiconductor photoelectrode  200  is improved, and the semiconductor photoelectrode  200  has high quantum efficiency. 
     The conductive substrate  102  may be composed of a plurality of metal layers. In this case, it is desirable that a metal thin film having a small work function is used as an uppermost metal layer which forms a junction with the first semiconductor photocatalyst layer  202  so as to form an ohmic contact between the conductive substrate  102  and the first semiconductor photocatalyst layer  202 . An example of the material of the uppermost metal layer is Al, Ti, V, Zr, Nb, Ag, In, or Ta. 
     The material of the first semiconductor photocatalyst layer  202  is appropriately selected from semiconductor photocatalyst materials capable of forming an ohmic contact with the conductive substrate  102  and having a band structure suitable for the utility of the semiconductor photoelectrode  200 , namely, suitable for the reaction generated on the semiconductor photoelectrode  200 . For example, if the semiconductor photoelectrode  200  is used for water splitting, the following materials are selected to generate hydrogen by splitting water photoelectrochemically. The bottom of the conduction band of the semiconductor material is not more than 0 volts. For example, the bottom of the conduction band of the semiconductor material is −0.1 volt. The standard reduction potential of water is equal to 0 volts. The top of the valence band of the semiconductor material is not less than 1.23 volts. For example, the top of the valence band of the semiconductor material is 1.24 volts. The standard oxidation potential of water is equal to 1.23 volts. In this case, it is desirable that the first semiconductor photocatalyst layer  202  is formed of at least one compound selected from the group consisting of oxide, nitride, and oxynitride, and that the at least one compound contains at least one element selected from the group consisting of Ti, Nb, and Ta. Such a material is poorly dissolved in an electrolyte solution and used for the semiconductor photoelectrode capable of splitting water using light such as sunlight. 
     An example of the combination of the first semiconductor photocatalyst layer  202  and the conductive substrate  102  both of which can form an ohmic contact is TiO 2 /Ti, Nb 2 O 5 /Ti, Ta 2 O 5 /Ti, TiO 2 /Nb, Nb 2 O 5 /Nb, Ta 2 O 5 /Nb, TiO 2 /Ta, Nb 2 O 5 /Ta, or Ta 2 O 5 /Ta. 
     If the first semiconductor photocatalyst layer  202  is composed of p-type semiconductor, it is desirable that the energy difference between the vacuum level and the Fermi level of the conductive substrate  102  is greater than the energy difference between the vacuum level and the Fermi level of the first semiconductor photocatalyst layer  202 . These relations are described with reference to  FIG. 5A  and  FIG. 5B . 
     As shown in  FIG. 5A , the energy difference between the vacuum level and the Fermi level of the conductive substrate  102  (EFC) is greater than the energy difference between the vacuum level and the Fermi level of the first semiconductor photocatalyst layer  202  (EFP), before the conductive substrate  102  and the first semiconductor photocatalyst layer  202  form the junction therebetween. When the conductive substrate  102  and the first semiconductor photocatalyst layer  202  form the junction under the condition where such a positional relationship of the Fermi level is satisfied, carriers transfer in such a manner that these Fermi levels are equal to each other at the junction plane therebetween. As a result, the edge of the band is bent as shown in  FIG. 5B . In this case, a Schottky barrier does not occur in the first semiconductor photocatalyst layer  202 , and an ohmic contact is formed between the first semiconductor photocatalyst layer  202  and the conductive substrate  102 . Since the ohmic contact is formed between the first semiconductor photocatalyst layer  202  and the conductive substrate  102 , the migration of the holes from the first semiconductor photocatalyst layer  202  to the conductive substrate  102  is not disturbed by the Schottky barrier. For this reason, the efficiency of the charge separation in the semiconductor photoelectrode  200  is improved, and the semiconductor photoelectrode  200  has high quantum efficiency. 
       FIG. 7A  shows a band structure before the conductive substrate  102 , the first semiconductor photocatalyst layer  202 , and the second semiconductor photocatalyst layer  203  form the junction in a case where both the first semiconductor photocatalyst layer  202  and the second semiconductor photocatalyst layer  203  are made of n-type semiconductor.  FIG. 7B  shows a band structure after the conductive substrate  102 , the first semiconductor photocatalyst layer  202 , and the second semiconductor photocatalyst layer  203  have formed the junction in a case where both the first semiconductor photocatalyst layer  202  and the second semiconductor photocatalyst layer  203  are made of n-type semiconductor. In the drawings, Ec1 and Ec2 mean the bottoms of the conduction bands of the first semiconductor photocatalyst layer  202  and the second semiconductor photocatalyst layer  203 , respectively. Ev1 and Ev2 mean the tops of the valence bands of the first semiconductor photocatalyst layer  202  and the second semiconductor photocatalyst layer  203 , respectively. 
     As shown in  FIG. 6 , the semiconductor photocatalyst layer  201  has a structure where the second semiconductor photocatalyst layer  203  is stacked on the first semiconductor photocatalyst layer  202 . As shown in  FIG. 7A , in the case where both the first semiconductor photocatalyst layer  202  and the second semiconductor photocatalyst layer  203  are made of n-type semiconductor, before the junction is not yet formed, it is desirable that the following relations (i)-(iv) are satisfied. 
     (i) The energy difference between the vacuum level and the Fermi level of the conductive substrate  102  (EFC) is smaller than the energy difference between the vacuum level and the Fermi level of the first semiconductor photocatalyst layer  202  (EFN1). 
     (ii) The energy difference between the vacuum level and the Fermi level of the first semiconductor photocatalyst layer  202  (EFN1) is smaller than the energy difference between the vacuum level and the Fermi level of the second semiconductor photocatalyst layer  203  (EFN2). 
     (iii) The energy difference between the vacuum level and the top Ev1 of the valence band of the first semiconductor photocatalyst layer  202  is greater than the energy difference between the vacuum level and the top Ev2 of the valence band of the second semiconductor photocatalyst layer  203 . 
     (iv) The energy difference between the vacuum level and the bottom Ec1 of the conduction band of the first semiconductor photocatalyst layer  202  is greater than the energy difference between the vacuum level and the bottom Ec2 of the conduction band of the second semiconductor photocatalyst layer  203 . 
     As shown in  FIG. 7B , after the conductive substrate  102 , the first semiconductor photocatalyst layer  202 , and the second semiconductor photocatalyst layer  203  which satisfy the (i)-(iv) relations have formed the junction, a band bending advantageous for the charge separation is formed at the junction plane between the first semiconductor photocatalyst layer  202  and the second semiconductor photocatalyst layer  203 , and an ohmic contact is formed at the junction plane between the conductive substrate  102  and the first semiconductor photocatalyst layer  202 . For this reason, since the charge separation of the carriers generated in the second semiconductor photocatalyst layer  203  due to light-absorption is performed efficiently, the semiconductor photoelectrode  200  has high quantum efficiency. 
     The first semiconductor photocatalyst layer  202  also has a thickness of not less than 10 nanometers and not more than 100 nanometers in the embodiment shown in  FIG. 6 . Desirably, the first semiconductor photocatalyst layer  202  has a thickness of not less than 10 nanometers and not more than 80 nanometers. As understood from  FIG. 11 , when the first semiconductor photocatalyst layer  202  has a thickness of not more than 80 nanometers, the internal quantum efficiency is more than approximately 20 percent. The first semiconductor photocatalyst layer  202  serves as a charge separation layer, however, since the first semiconductor photocatalyst layer  202  has a thickness of not less than 10 nanometers and not more than 100 nanometers, the first semiconductor photocatalyst layer  202  fulfills a function of the charge separation adequately. In order not to generate the recombination during the migration of the electrons generated due to light absorption, it is desirable that the first semiconductor photocatalyst layer  202  is as thin as possible. 
     It is desirable that the materials of the first semiconductor photocatalyst layer  202  and the second semiconductor photocatalyst layer  203  satisfy the above-mentioned (i)-(iv) relations. It is desirable that the first semiconductor photocatalyst layer  202  and the second semiconductor photocatalyst layer  203  are also formed of at least one compound selected from the group consisting of oxide, nitride and oxynitride, and that the at least one compound contains at least one element selected from the group consisting of Ti, Nb, and Ta. Such a material is poorly dissolved in an electrolyte solution and used for the semiconductor photoelectrode capable of splitting water with light such as sunlight. 
     An example of the combination of the materials of the second semiconductor photocatalyst layer  203 , the first semiconductor photocatalyst layer  202 , and the conductive substrate  102  (i.e., the second semiconductor photocatalyst layer/the first semiconductor photocatalyst layer/the conductive substrate) is Nb 3 N 5 /TiO 2 /Ti, Nb 3 N 5 /Nb 2 O 5 /Ti, Nb 3 N 5 /Ta 2 O 5 /Ti, Nb 3 N 5 /TiO 2 /Nb, Nb 3 N 5 /Nb 2 O 5 /Nb, Nb 3 N 5 /Ta 2 O 5 /Nb, Nb 3 N 5 /TiO 2 /Ta, Nb 3 N 5 /Nb 2 O 5 /Ta, Nb 3 N 5 /Ta 2 O 5 /Ta, NbON/TiO 2 /Ti, NbON/Nb 2 O 5 /Ti, NbON/Ta 2 O 5 /Ti, NbON/TiO 2 /Nb, NbON/Nb 2 O 5 /Nb, NbON/Ta 2 O 5 /Nb, NbON/TiO 2 /Ta, NbON/Nb 2 O 5 /Ta, or NbON/Ta 2 O 5 /Ta. Regarding Nb 3 N 5 , See WO 2013/084447. WO 2013/084447 is equivalent to U.S. patent application Ser. No. 13/983,729, the entire contents of which is hereby incorporated by reference. Regarding NbON, see the example 1, which is described later. NbON means Nb c O d N e  (where c=d=e=1). 
     In a case where the first semiconductor photocatalyst layer  202  and the second semiconductor photocatalyst layer  203  are made of p-type semiconductor, as shown in  FIG. 8A , before these layers form the junction, it is desirable that the following relations (I)-(IV) are satisfied. 
     (I) The energy difference between the vacuum level and the Fermi level of the conductive substrate  102  (EFC) is greater than the energy difference between the vacuum level and the Fermi level of the first semiconductor photocatalyst layer  202  (EFP1). 
     (II) The energy difference between the vacuum level and the Fermi level of the first semiconductor photocatalyst layer  202  (EFP1) is greater than the energy difference between the vacuum level and the Fermi level of the second semiconductor photocatalyst layer  203  (EFP2). 
     (III) The energy difference between the vacuum level and the top Ev1 of the valence band of the first semiconductor photocatalyst layer  202  is smaller than the energy difference between the vacuum level and the top Ev2 of the valence band of the second semiconductor photocatalyst layer  203 . 
     (IV) The energy difference between the vacuum level and the bottom Ec1 of the conduction band of the first semiconductor photocatalyst layer  202  is smaller than the energy difference between the vacuum level and the bottom Ec2 of the conduction band of the second semiconductor photocatalyst layer  203 . 
     As shown in  FIG. 8B , after the conductive substrate  102 , the first semiconductor photocatalyst layer  202 , and the second semiconductor photocatalyst layer  203  which satisfy the (I)-(IV) relations have formed the junction, a band bending advantageous for the charge separation is formed at the junction plane between the first semiconductor photocatalyst layer  202  and the second semiconductor photocatalyst layer  203 . An ohmic contact is formed at the junction plane between the conductive substrate  102  and the first semiconductor photocatalyst layer  202 . For this reason, since the charge separation of the carriers generated in the second semiconductor photocatalyst layer  203  due to light-absorption is performed efficiently, the semiconductor photoelectrode  200  has high quantum efficiency. 
     (Still More Desirable Semiconductor Photoelectrode) 
     Next, a still more desirable semiconductor photoelectrode  200  according to the present first embodiment will be described below. 
     As shown in  FIG. 6 , the still more desirable semiconductor photoelectrode  200  according to the present first embodiment comprises the conductive substrate  102  made of niobium, the first semiconductor photocatalyst layer  202  made of niobium oxide represented by the chemical formula Nb 2 O 5 , and the second semiconductor photocatalyst layer  203  made of niobium nitride represented by the chemical formula Nb 3 N 5 . 
     An incident light is absorbed by niobium nitride represented by the chemical formula Nb 3 N 5  included in the second semiconductor photocatalyst layer  203  to generate electrons and holes. Since niobium nitride represented by the chemical formula Nb 3 N 5  has a bandgap of approximately 780 nanometers, almost all the portion of the incident visible light can be used for the generation of hydrogen due through water splitting. Since water splitting requires some overvoltage for both hydrogen generation reaction and oxygen generation reaction, it is desirable that the second semiconductor photocatalyst layer  203  has a bandgap of not less than approximately 780 nanometers for high efficiency. For this reason, it is believed that niobium nitride represented by the chemical formula Nb 3 N 5  is most suitable for the material of the second semiconductor photocatalyst layer  203 . 
     The first semiconductor photocatalyst layer  202  forms the band bending suitable for the separation of the electrons and the holes generated in the niobium nitride represented by the chemical formula Nb 3 N 5 , and has a role of a path for the electrons transferring to the conductive substrate  102 . For this reason, from a viewpoint of the Fermi level, the position of the bottom of the conduction band, and the position of the top of the valence band, and from a viewpoint that the second semiconductor photocatalyst layer  203  is made of niobium nitride represented by the chemical formula Nb 3 N 5 , it is believed that niobium oxide represented by the chemical formula Nb 2 O 5  is most suitable for the material of the first semiconductor photocatalyst layer  202 . It is desirable that the first semiconductor photocatalyst layer  202  is as thin as possible to decrease the probability of the recombination between the electrons transferring in the first semiconductor photocatalyst layer  202  and the holes. In light of an actual fabrication process, it is desirable that the first semiconductor photocatalyst layer  202  has a thickness of not less than 10 nanometers and not more than 100 nanometers. 
     The conductive substrate  102  is required to form an ohmic contact with the first semiconductor photocatalyst layer  202  made of niobium oxide represented by the chemical formula Nb 2 O 5 . For this reason, from a viewpoint of the work function, and from a viewpoint of the process for forming the first semiconductor photocatalyst layer  202  made of niobium oxide represented by the chemical formula Nb 2 O 5 , it is believed that niobium is most suitable for the material of the conductive substrate  102 . 
     As described above, the still more desirable semiconductor photoelectrode  200  comprises the conductive substrate  102  made of niobium, the first semiconductor photocatalyst layer  202  made of niobium oxide represented by the chemical formula Nb 2 O 5 , and the second semiconductor photocatalyst layer  203  made of niobium nitride represented by the chemical formula Nb 3 N 5 . 
     As shown in  FIG. 17 , each pillar protrusion formed on the surface of the semiconductor photoelectrode  200  may have a shape of a circular cylinder, a circular cone, a circular truncated corn, an ellipse, an elliptic cylinder, an elliptic cylinder cone, an elliptic truncated corn, a polygonal column, a polygonal columnar cone, or a polygonal truncated cone. It is desirable to be a shape of a circular cylinder. An example of the polygonal column is a triangular prism, a quadrangular prism, a pentagonal prism, or a hexagonal prism. An example of the polygonal columnar cone is a triangular pyramid, a quadrangular pyramid, a pentagonal pyramid, or a hexagonal pyramid. 
     As shown in  FIG. 18 , it is desirable that the plurality of the pillar protrusions formed on the surface of the semiconductor photoelectrode  200  are each composed of a circular or polygonal columnar stem  210  and a top end  220  which has a shape of a cone or a truncated cone. In other words, it is desirable that the top end  220  of each pillar protrusion sharpens. Unlike in a case where each pillar protrusion is formed only of a circular or polygonal columnar stem, if each pillar protrusion has the top end  220  having a shape of a cone or a truncated cone, as shown in  FIG. 18 , portion of light incident on the top end  220  is reflected off the top end  220  to reach the surface of another pillar protrusion. In this way, the incident light can be used more efficiently. 
     As shown in  FIG. 19 , each pillar protrusion may comprise a light scattering particle  230  on the surface thereof. The light incident on the light scattering particle  230  is scattered on the light scattering particle  230  to reach the surface of another pillar protrusion. In this way, the incident light can be used more efficiently. An example of the light scattering particle  230  is a particle made of SiO 2 . 
     In the semiconductor photoelectrode according to the first embodiment, the semiconductor photoelectrode has the plurality of the pillar protrusions on the surface thereof, and the surface of each pillar protrusion is formed of the second semiconductor photocatalyst layer  203 . Since the light incident on the second semiconductor photocatalyst layer  203  is scattered, the ability of the second semiconductor photocatalyst layer  203  to absorb the light is improved, as compared to an electrode having a flat-and-smooth surface. In other words, the light incident on the surface of one pillar protrusion from an inclined direction with respect to the pillar protrusion is scattered to reach another pillar protrusion. In this way, the ability of the second semiconductor photocatalyst layer  203  to absorb the light is improved. Since the plurality of the pillar protrusions are provided, the semiconductor photoelectrode  200  has a larger area than a flat-and-smooth electrode. For this reason, a substantial current density of the flowing current can be decreased. As a result, an overvoltage can be lowered. In this way, the reaction which occurs on the electrode, for example, a water splitting reaction, is promoted. When the first semiconductor photocatalyst layer  202  has a significantly thin thickness of not less than 10 nanometers and not more than 100 nanometers, the probability of the recombination between the electrons and the holes generated due to the light absorption is significantly decreased to improve the quantum efficiency. Since the first semiconductor photocatalyst layer  202  forms an ohmic contact with the conductive substrate  102 , the migration of the electrons from the first semiconductor photocatalyst layer  202  to the conductive substrate  102  is not disturbed by the Schottky barrier. Therefore, the quantum efficiency is more improved. 
     Second Embodiment 
       FIG. 9  shows a photoelectrochemical cell according to the second embodiment of the present invention. As shown in  FIG. 9 , the photoelectrochemical cell  300  according to the second embodiment comprises a container  31 , a semiconductor photoelectrode  200 , a counter electrode  32 , and a separator  35 . The semiconductor photoelectrode  200 , the counter electrode  32 , and the separator  35  are contained in the container  31 . The inside of the container  31  is divided into a first chamber  36  and a second chamber  37  by the separator  35 . The semiconductor photoelectrode  200  is disposed in the first chamber  36 , whereas the counter electrode  32  is disposed in the second chamber  37 . A liquid such as an aqueous electrolyte solution  33  is stored in both the first chamber  36  and the second chamber  37 . The separator  35  is not need to be provided. 
     The semiconductor photoelectrode  200  is disposed in the first chamber  36  so as to be in contact with the aqueous electrolyte solution  33 . The semiconductor photoelectrode  200  comprises the conductive substrate  102  having a surface where the plurality of the pillar protrusions are arranged, the first semiconductor photocatalyst layer  202  provided on the conductive substrate  102 , and the second semiconductor photocatalyst layer  203 . The conductive substrate  102 , the first semiconductor photocatalyst layer  202 , and the second semiconductor photocatalyst layer  203  are described in the first embodiment. 
     The first chamber  36  comprises a first outlet  38  for discharging oxygen generated in the first chamber  36  and an inlet  40  for supplying water to the first chamber  36 . The container  31  is provided with a light-entrance portion  31   a . The light-entrance portion  31   a  is disposed opposite to the second semiconductor photocatalyst layer  203  of the semiconductor photoelectrode  200  disposed in the first chamber  36 . The light-entrance portion  31   a  is made of a material through which light such as sunlight can travel. In other words, the light-entrance portion  31   a  is transparent. An example of the material of the container  31  is Pyrex (registered trademark) glass or an acrylic resin. 
     The counter electrode  32  is disposed in the second chamber  37  so as to be in contact with the aqueous electrolyte solution  33 . The second chamber  37  comprises a second outlet  39  for discharging hydrogen generated in the second chamber  37 . 
     The conductive substrate  102  is electrically connected with the counter electrode  32  through an electric wire  34 . 
     The conductive substrate  102 , the first semiconductor photocatalyst layer  202 , and the second semiconductor photocatalyst layer  203  included in the semiconductor photoelectrode  200  according to the second embodiment fulfill the effect similar to the effect described in the first embodiment. 
     The term “counter electrode” means an electrode for accepting electrons from the semiconductor photoelectrode without the electrolyte solution. As long as the counter electrode  32  is electrically connected with the conductive substrate  102  included in the semiconductor photoelectrode  200 , a positional relation between the counter electrode  32  and the semiconductor photoelectrode  200  is not limited. 
     The aqueous electrolyte solution  33  has either acidity or alkalinity, as far as the aqueous electrolyte solution  33  is an aqueous electrolyte solution. Water may be used instead of the aqueous electrolyte solution. The aqueous electrolyte solution  33  is always stored in the container  31 . Alternatively, the aqueous electrolyte solution  33  is supplied only in use. An example of the aqueous electrolyte solution  33  is dilute sulfuric acid, sodium sulfate, sodium carbonate, or sodium hydrogen carbonate. 
     The separator  35  is formed of a material capable of maintaining the aqueous electrolyte solution  33  transferable between the first chamber  36  and the second chamber  37 , however, capable of stopping the flow of gas generated in the first chamber  36  and the second chamber  37 . An example of the material of the separator  35  is a solid electrolyte such as a polymer electrolyte. An example of the polymer solid electrolyte is an ion-exchange membrane such as Nafion (registered trademark). Such a separator  35  allows the internal space of the container  31  to be divided into the first chamber  36  and the second chamber  37 . The aqueous electrolyte solution  33  is in contact with the surface of the semiconductor photoelectrode  200 , namely, the second semiconductor photocatalyst layer  203  in the first chamber  36 . The aqueous electrolyte solution  33  is in contact with the surface of the counter electrode  32  in the second chamber  37 . Such a structure allows hydrogen and oxygen generated in the container  31  to be divided easily. 
     The electric wire  34  is used for electrically connecting the counter electrode  32  with the conductive substrate  102 . The electrons generated in the semiconductor photoelectrode  200  transfer through the electric wire  34  without applying an electric potential from the outside. 
     Next, how to use the photoelectrochemical cell  300  according to the second embodiment will be described below. 
     As shown in  FIG. 10 , the second semiconductor photocatalyst layer  203  included in the semiconductor photoelectrode  200  disposed in the container  31  is irradiated with light  400  such as sunlight through the light-entrance portion  31   a . In the case where both the first semiconductor photocatalyst layer  202  and the second semiconductor photocatalyst layer  203  are made of n-type semiconductor, in the portion of the second semiconductor photocatalyst layer  203  irradiated with the light, the electrons and the holes are generated in the conduction band and in the valence band, respectively. The generated holes transfer to the surface of the second semiconductor photocatalyst layer  203 . In this way, water is split as shown in the following reaction formula (V) on the surface of the second semiconductor photocatalyst layer  203 . In this way, oxygen is generated. 
       4 h   + +2H 2 O→O 2 ↑+4H +   (V)
 
     where h +  represents a hole. 
     On the other hand, the electrons transfer to the conductive substrate  102  along the curve of the band edge of the conduction band of the first semiconductor photocatalyst layer  202  and the second semiconductor photocatalyst layer  203 . The electrons which have transferred to the conductive substrate  102  further transfer through the conducting wire  34  to the counter electrode  32  electrically connected with the conductive substrate  102 . In this way, hydrogen is generated as shown in the following reaction formula (VI) on the surface of the counter electrode  32 . 
       4 e   − +4H + →2H 2 ↑  (VI)
 
     Since the photoelectrochemical cell  300  according to the second embodiment comprises the semiconductor photoelectrode  200  described in the first embodiment, the photoelectrochemical cell  300  according to the second embodiment has high quantum efficiency for water splitting reaction. 
     REFERENTIAL EXAMPLES 
     Referential Example 1 
     In order to discuss a desirable thickness of the first semiconductor layer  202 , a semiconductor photocatalyst layer formed of a TiO 2  film was used. The present inventors discussed the relationship between the thickness of the TiO 2  film and the quantum efficiency as below. 
     First, a TiO 2  film having a thickness of 22 nanometers was formed on a transparent electrode substrate made of indium tin oxide (hereinafter, referred to as “ITO”) by a sputtering method to provide a sample A1. Similarly, provided were samples A2, A3, and A4 having a TiO 2  film having a thickness of 110 nanometers, 220 nanometers, and 660 nanometers, respectively. Since the samples A1-A4 were used for discussion of the relationship between the semiconductor photocatalyst layer and the quantum efficiency, the transparent electrode substrate did not have pillar protrusions on the surface thereof. In other words, the surface of the transparent electrode substrate was flat-and-smooth. 
     The photocurrent of the samples A1-A4 was measured as below, and the quantum efficiencies of the samples A1-A4 were calculated. First, a container made of silica glass was prepared. A sulfuric acid aqueous solution having a concentration of 0.1M was supplied to this container as the aqueous electrolyte solution. One sample selected from the samples A1-A4 was disposed as the semiconductor photoelectrode in the container such that the one sample is brought into contact with the aqueous electrolyte solution. A platinum electrode was disposed as a counter electrode such that the platinum electrode was brought into contact with the aqueous electrolyte solution. Light from a xenon lamp (150 W) was dispersed using a diffracting grating to give monochromatic light having a wavelength of 300 nanometers. The sample which was in contact with the aqueous electrolyte solution was irradiated with this monochromatic light, and a current value flowing between the sample and the platinum electrode was measured using a potentiostat (available from Solartron, trade name: SI-1278). 
     The external quantum efficiency and the internal quantum efficiency were calculated as the quantum efficiency on the basis of the following mathematical formulae (VII) and (VIII), respectively. 
       (External quantum efficiency)=(the number of the electrons extracted as the photocurrent)/(the number of photons incident on the sample)  (VII)
 
       (Internal quantum efficiency)=(the number of the electrons extracted as the photocurrent)/(the number of photons absorbed in the sample)  (VIII)
 
     The number of the electrons extracted as the photocurrent was calculated by dividing the current value flowing between the sample and the platinum electrode by elementary charge (e: 1.602×10 −19  (C)). 
     The number of the photons incident on the sample was calculated by measuring the energy of the light incident on the sample using a power meter (available from New Port Company, trade name: model 1931-c) and then by dividing the measured energy of the light by the energy per photon. 
     The number of the photons absorbed in the sample was calculated on the basis of the following mathematical formula (IX). 
       (The number of the photons absorbed in the sample)=(the absorptance  A  of the sample)·(the number of the photons incident on the sample)  (IX)
 
     The absorptance A of the sample was calculated on the basis of the following mathematical formula (X). 
       (The absorptance  A  of the sample)=1−(the transmittance  T  of the sample)−(the reflectance  R  of the sample)  (X)
 
     A method for measuring the absorptance A of the sample is described below. 
     First, fabricated was a sample where a semiconductor photocatalyst layer made of a TiO 2  film having the same thickness as the thickness of the semiconductor photoelectrode was formed on a sapphire substrate. The transmittance T and the reflectance R of the sample were measured with an UV-Vis spectrophotometer (available from JASCO Corporation, trade name: V-670) and an absolute reflectance measurement system (available from JASCO Corporation, trade name: ARMN-735), respectively. 
     The reason why the sapphire substrate was used is to eliminate the effect of the light absorption by the substrate when the transmittance T of the sample was measured. The sapphire substrate is transparent within a broad wavelength range. Since the sapphire substrate does not absorb light having a wavelength of 300 nanometers, it is suitably used as a substrate for measuring the transmittance T. 
       FIG. 20  shows an example of the transmittance T, the reflectance R, and the absorptance of the TiO 2  film having a thickness of 300 nanometers. In  FIG. 20 , the sapphire substrate having a thickness of 110 nanometers was used. Similarly, transmission factors T, reflectance rates R, and absorption ratios A of other TiO 2  films were calculated. 
     Table 1 and  FIG. 11  show the results of the calculated external quantum efficiency and internal quantum efficiency. 
     
       
         
           
               
               
               
               
               
             
               
                   
                 TABLE 1 
               
               
                   
                   
               
               
                   
                   
                 Thickness of 
                 External 
                 Internal 
               
               
                   
                   
                 the semiconductor 
                 Quantum 
                 Quantum 
               
               
                   
                   
                 photocatalyst layer 
                 efficiency 
                 efficiency 
               
               
                   
                 Sample 
                 (nanometer) 
                 (%) 
                 (%) 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
            
               
                   
                 A1 
                 22 
                 12.6 
                 35.7 
               
               
                   
                 A2 
                 110 
                 12.0 
                 15.9 
               
               
                   
                 A3 
                 220 
                 4.2 
                 5.5 
               
               
                   
                 A4 
                 660 
                 0.8 
                 1.0 
               
               
                   
                   
               
            
           
         
       
     
     As is clear from Table 1, if the semiconductor photocatalyst layer has a thickness of not more than 110 nanometers, the external quantum efficiency is improved. On the other hand, the external quantum efficiency is decreased with an increase in the thickness of the semiconductor photocatalyst layer. The reason is believed to be that the efficiency of the light absorption is improved with an increase in the thickness of the semiconductor photocatalyst layer; however, the probability of the recombination is increased, since the migration distance of the electrons generated in the semiconductor photocatalyst layer to the electric conductor made of ITO is increased. The results shown in  FIG. 1  reveal that, when the semiconductor photocatalyst layer is formed of one semiconductor material, the thickness optimum for surely maximizing the external quantum efficiency of the semiconductor photoelectrode is not more than 100 nanometers. 
     On the other hand, when the semiconductor photoelectrode is actually fabricated, if the semiconductor photocatalyst layer is too thin, a pin-hole is generated in the semiconductor photocatalyst layer. When the semiconductor photoelectrode is used, such a pinhole causes a failure. For this reason, when the semiconductor photocatalyst layer is formed of one semiconductor material, it is desirable that the semiconductor photocatalyst layer has a thickness of not less than 10 nanometers and not more than 100 nanometers in order to surely maximize the external quantum efficiency of the semiconductor photoelectrode. 
     When the semiconductor photocatalyst layer has a thickness of not more than 110 nanometers, the internal quantum efficiency is increased sharply. When the semiconductor photocatalyst layer has a thickness of 22 nanometers, the internal quantum efficiency is increased significantly. The reason is that the probability of the recombination is significantly decreased, since the migration distance of the electron generated in the thin semiconductor photocatalyst layer is short. For this reason, also from a viewpoint of the internal quantum efficiency, it is desirable that the semiconductor photocatalyst layer has a thickness of not more than 100 nanometers. 
     Next, the present inventors discuss the case where the semiconductor photocatalyst layer is formed of two semiconductor layers, as shown in  FIG. 6 . Since the first semiconductor photocatalyst layer  202  is not exposed on the surface of the semiconductor photoelectrode  200 , the first semiconductor photocatalyst layer  202  hardly contributes to light-absorption. The first semiconductor photocatalyst layer  202  functions as a charge-separation layer for forming a band bending optimum for charge-separation. In other words, the first semiconductor photocatalyst layer  202  is a path for the electrons which are generated in the second semiconductor photocatalyst layer  203  and which travel to the conductive substrate  102 . For this reason, it is believed that the quantum efficiency as the semiconductor photoelectrode is increased with an increase in the internal quantum efficiency of the first semiconductor photocatalyst layer  202 . Hence, when the semiconductor photocatalyst layer is formed of two kinds of semiconductor materials, it is desirable that the first semiconductor photocatalyst layer has a thickness of not more than 100 nanometers. 
     On the other hand, the semiconductor photocatalyst layer has a thickness of not less than 10 nanometers to avoid the failure. For this reason, when the semiconductor photocatalyst layer is formed of two kinds of semiconductor materials, it is desirable that the first semiconductor photocatalyst layer has a thickness of not less than 10 nanometers and not more than 100 nanometers. 
     Reference Example 2 
     In the reference example 2, the semiconductor photoelectrode comprising the semiconductor photocatalyst layer formed of a TiO 2  film was fabricated. A method for fabricating a semiconductor photoelectrode having a surface on which a plurality of pillar protrusions were arranged will be described below. The semiconductor photoelectrode thus fabricated by the method was evaluated as below. 
     &lt;Method for Fabricating Semiconductor Photoelectrode&gt; 
     The method for fabricating the semiconductor photoelectrode is divided roughly into the following three processes A-C. 
     (Process A) patterning onto a replica film 
     (Process B) forming a TiO 2  film on the replica film by an LPD method, and 
     (Process C) forming an electrode 
     First, in the process A, an arrangement pattern having a shape identical to the shape of a plurality of pillar protrusions is transcribed on the replica film in accordance with a nanoimprint method. Next, in the process B, a TiO 2  film is formed on the replica film by an LPD method. Finally, in the process C, a conductive substrate is formed on the TiO 2  film by non-electrolytic nickel plating. After the process C, the replica film is removed to provide an electrode formed of nickel. The processes A-C are described below in more detail. 
     (Process A/Patterning on the Replica Film) 
     In the process A, a replica film (available from Okenshoji Co., Ltd. Trade name: Bioden RFA acetyl cellulose film, thickness: 0.126 millimeters) and a silicon mold (available from KYODO INTERNATIONAL, INC.) were prepared. A plurality of nanorods were arranged on the surface of the silicon mold. This silicon mold was fabricated by a photolithography method. When viewed in a top view, one nanorod was surrounded by six nanorods, which corresponded to corners of a regular hexagon. The one nanorod was positioned at the center of the regular hexagon. Two adjacent nanorods had a pitch of 1 micrometer. Each nanorod had a diameter of 500 nanometers and a height of 1 micrometer. 
     Then, ethyl acetate was dropped on the replica film to soften the replica film. Subsequently, the silicon mold was pressed onto the replica film. Ethyl acetate was removed under a temperature of 70 degrees Celsius for 15 minutes by drying. After ethyl acetate was completely removed, the silicon mold was peeled from the replica film. Thus, the pattering onto the replica film was conducted. 
       FIG. 12A  shows a SEM image (5,000 magnifications) of the surface of the replica film thus patterned.  FIG. 12B  shows a SEM image (50,000 magnifications) of the surface of the replica film thus patterned. As is clear from  FIG. 12A  and  FIG. 12B , a plurality of nanorods formed on the surface of the silicon mold were transcribed accurately onto the replica film. Thus, a plurality of holes were formed on the surface of the replica film. 
     The shape of the nanorods formed on the surface of the silicon mold may be changed so that the shape of the holes was varied. However, it is more difficult to peel the replica film from the silicon mold with an increase in the aspect ratio of the pillar protrusions. For this reason, a suitable mold-release agent may be applied on the surface of the silicon mold. For a similar reason, each nanorod may have a tapered shape. 
     The process A allows a patterning to be given to a lot of replica films using one silicon mold. Accordingly, the process A contributes low cost. 
     (Process B/Forming a TiO 2  Film on the Replica Film by an LPD Method) 
     First, the LPD method used in the present referential example is described. In the LPD method, used is a hydrolysis equilibrium reaction of metal fluoride complex contained in an aqueous solution. The LPD method is suitable for forming a thin film made of metal oxide on various kinds of substrates. 
     The following reaction formula (XI) shows the hydrolysis equilibrium reaction of metal fluoride complex contained in the aqueous solution. Boric acid is added to this reaction system. Boric acid has a high reactivity with fluorine ion, and generates more stable compound. Thus, the fluorine-consumption reaction represented by the following reaction formula (XII) progresses. For this reason, the equilibrium of the reaction formula (XI) shifts to the right. In other words, the equilibrium of the reaction formula (XI) shifts to the right so that a more amount of metal oxide precipitates. A substrate such as a replica film is immersed in the aqueous solution having a condition where both the reaction formulae (XI) and (XII) are established to form a thin film formed of metal oxide on the surface of the substrate. 
       MF x   (x-2n)-   +n H 2 O⇄MO n   +x F − +2 n H +   (XI)
 
       H 3 BO 3 +4H + +4F − →HBF 4 +3H 2 O  (XII)
 
     where M represents metal. 
     The thin film made of metal oxide can be made easily and at lower cost, as compared to a vapor deposition method, a sputtering method, a chemical vapor deposition method, an electrodeposition method, and a sol-gel method, which are conventional methods for forming a thin film. Even if the substrate has a large area and the substrate has a surface where a complicated shape has been formed, the thin film made of metal oxide can be formed easily by the LPD method. As described in the referential example 2, since the thin film made of metal oxide is made uniformly by the LPD method on the replica film having a surface where a plurality of pillar protrusions have been arranged, the LPD method is significantly suitable for forming such a thin film made of metal oxide. 
     In the referential example 2, a LPD aqueous solution was prepared by dissolving ammonium hexafluorotitanate (available from MORITA CHEMICAL INDUSTRIES, CO., LTD.) represented by a chemical formula (NH 4 ) 2 TiF 6  and boric acid (available from NACALAI TESQUE, INC.) represented by a chemical formula H 3 BO 3  into distilled water. This LPD solution had an ammonium hexafluorotitanate concentration of 0.1M and a boric acid concentration of 0.2M. The replica film provided according to the process A was immersed in the LPD solution during a predetermined period, and a thin film made of TiO 2  was formed on the replica film. TiO 2  went into the hole formed on the surface of the replica film. In this way, formed was the TiO 2  thin film having a plurality of protrusions on the surface thereof, namely, on the front surface thereof. On the other hand, the back surface of the TiO 2  thin film had recesses each overlapped by the holes formed on the surface of the replica film. In the LPD solution, the replica film was fixed on a glass slide and disposed perpendicular to the surface of the LPD solution. A water bath was used to maintain the temperature of the LPD solution at 30 degrees Celsius. 
     Since the thickness of the thin film made of TiO 2  is increased with an increase in film-forming time, the thickness of the thin film made of TiO 2  is variable depending on the film-forming time. In the present referential example 2, the thus-formed thin film made of TiO 2  had a thickness of 90 nanometers.  FIG. 13  shows a relationship between the thickness of the thin film made of TiO 2  and the film-forming time. 
     (Process C) 
     An electrode was formed by the following procedure using the metal oxide thin film formed on the replica film. 
     First, a Ni film was formed under a temperature of 80 degrees Celsius for two hours by non-electrolytic nickel plating on the TiO 2  thin film formed on the replica film. In this way, a metal (Ni)-semiconductor (TiO 2 ) junction was formed. Since the TiO 2  thin film had a thickness of 90 nanometers, the formed Ni film played a role of holding the TiO 2  thin film. A plating solution (available from Japan Kanigen Co., Ltd., Trade name: SEK-797) was used in the non-electrolytic nickel plating. The plating solution went into the recess formed on the back surface of the TiO 2  thin film. In this way, formed was a Ni film having a plurality of protrusions made of Ni on the surface thereof, namely on the front surface thereof. The back surface of the Ni film was flat. 
     The obtained multilayer structure was a structure of the replica film/TiO 2 /Ni. The obtained multilayer was thereafter immersed in acetone. Thus, the replica film was dissolved in acetone. In this way, the replica film was removed. A Ti metal sheet was adhered on the back surface of the Ni film. In this way, the electrode was obtained. 
     (Observation of the Electrode Surface) 
       FIG. 14  shows a SEM image of the surface of the obtained electrode. A plurality of pillar protrusions similar to these of the silicon mold were arranged on the surface of the obtained electrode at a high density. It was observed from  FIG. 14  that the obtained electrode had a larger area than a flat-and-smooth electrode. Hence, a semiconductor photoelectrode having a surface structure similar to the pillar protrusions of the used mold can be fabricated according to the electrode fabrication method of the referential example 2. 
     (Measurement of the Photocurrent) 
     In order to confirm that the semiconductor photoelectrode fabricated according to the reference example 2 served as an electrode, a photocurrent was measured while the semiconductor photoelectrode was irradiated with ultraviolet light. The light source was a high-pressure mercury lamp having an emission line of 365 nanometers. The aqueous electrolyte solution was a 0.1M sulfuric acid aqueous solution. The counter electrode was a Pt electrode.  FIG. 15  shows the result of the photocurrent measurement. As is clear from  FIG. 15 , when the surface of the semiconductor photoelectrode fabricated according to the referential example 2 was irradiated with the ultraviolet light, a photocurrent was measured with response to the irradiation. 
     Referential Example 3 
     A semiconductor photoelectrode where a TiO 2  thin film was used as a semiconductor photocatalyst layer was fabricated in the referential example 3. A method for fabricating a semiconductor photoelectrode where a plurality of pillar protrusions are formed on the surface thereof will be described particularly. The evaluation results of the fabricated semiconductor photoelectrode are also described. 
     (Fabrication of a Conductive Substrate Having Pillar Protrusions on the Surface Thereof) 
     A Ti film was formed by a sputtering on the surface of a silicon mold similar to that of the referential example 2. A distance between two adjacent pillar protrusions was 2.7 micrometers. Each pillar protrusion had a diameter of 2.1 micrometers. Each pillar protrusion had a height of 21 micrometers. In the sputtering, metal titanium was used as a target. A supply rate of argon to the chamber was 3.38×10 −3  Pa·m 3 /s (20 sccm). The total pressure was 1.0 Pa. The power was 150 W. In this way, the Ti film was formed on the silicon mold. A plurality of pillar protrusions were formed on the surface of the Ti film. In other words, in the reference example 3, the Ti film corresponds to a conductive substrate having a plurality of pillar protrusions on the surface thereof. A cross-sectional SEM observation revealed that the Ti film covered the silicon mold completely. 
     (Formation of a TiO 2  Film on the Conductive Substrate by a LPD Method) 
     Subsequently, a TiO 2  film was formed on the Ti film by the LPD method described in the referential example 2. The TiO 2  film had a thickness of 90 nanometers. A portion of the Ti film was not immersed in the LPD solution. The TiO 2  film was not formed on the surface of the portion of the Ti film which had not been immersed in the LPD solution. This portion where the TiO 2  film was not formed served as a current extraction portion of the semiconductor photoelectrode. Thus, an electrode composed of a stacked structure of TiO 2 /Ti was obtained. 
     Similarly to the case of the referential example 2, the photocurrent of the semiconductor photoelectrode according to the referential example 3 was measured.  FIG. 16  shows the results of the photocurrent measurement. As is clear from  FIG. 16 , when the surface of the semiconductor photoelectrode fabricated according to the present referential example 3 was irradiated with the ultraviolet light, a photocurrent was measured with response to the irradiation. The obtained photocurrent had a current density of approximately 0.3 milliampere/cm 2 . No dark current was observed. This result reveals that the electrode according to the referential example 3 served as a semiconductor photoelectrode. 
     Example 
     Example 1 
     A Si pillar protrusion substrate (available from KYODO INTERNATIONAL, INC.) fabricated by a photolithography method was prepared.  FIG. 21  shows a top view of this Si pillar protrusion substrate.  FIG. 22  is a cross-sectional photograph of this Si pillar protrusion substrate. 
     One Si pillar protrusion positioned at the center was surrounded by six Si pillar protrusions, which corresponded to corners of a regular hexagon. The Si pillar protrusion substrate had a plurality of Si pillar protrusions. Each Si pillar protrusion was circular cylindrical. The top of each Si pillar protrusion was tapered. In other words, the top of each Si pillar protrusion was sharpened. The bottom of each Si pillar protrusion had a diameter of 2 micrometers. A pitch h between the centers of two adjacent Si pillar protrusions was 4 micrometers. Each Si pillar protrusion had a height of 32 micrometers. The aspect ratio (=height/diameter) of each Si pillar protrusion was approximately 16. 
     A conductive film made of titanium was formed by a sputtering method on the surface of the Si pillar protrusion substrate. In the sputtering method, a metal Ti was used as a target. The total pressure was 0.1 Pa. The power was 1 kW. In this way, a Ti film was formed on the Si pillar protrusion substrate. It was observed by a cross-sectional SEM observation and Auger measurement method that the Ti film was formed not only on the top and middle of the Si pillar protrusions but also on the bottom of the Si pillar protrusions. 
     The Ti film was formed in such a manner that the Ti film had a thickness of 400 nanometers in a case where the Ti film was formed on a flat-and-smooth Si wafer surface under a similar sputtering condition. 
     (Formation of a TiO 2  Film on the Conductive Substrate by the LPD Method) 
     Subsequently, a TiO 2  film was formed on the Ti film by the LPD method, which has been described above. The LPD condition was similar to the condition where a TiO 2  film having a thickness of 90 nanometers was formed by the LPD method on the surface of the flat-and-smooth Ti film. In the LPD method, a film having a uniform thickness along the surface shape can be formed. In this way, a TiO 2  film having a thickness of 90 nanometers was formed on the Ti film. 
     A part of the Ti film was not immersed in the LPD solution. The TiO 2  film was not formed on the surface of the part of the Ti film which had not been immersed in the LPD solution. The part where the TiO 2  film was not formed functioned as an electric current extraction part of the semiconductor photoelectrode. In this way, an electrode comprised of a stacked structure of TiO 2 /Ti was obtained. 
     The formed TiO 2  film contained a lot of water. Furthermore, the TiO 2  film contained titanium hydroxide. The TiO 2  film was subjected to heat treatment in the air for two hours under a temperature of 450 degrees Celsius to improve the crystallinity of the TiO 2  film. In this way, the TiO 2  film was crystallized. 
     (Formation of a NbON Film on the TiO 2  Film by a Sputtering &amp; Ammonia Nitriding Method) 
     A Nb 2 O 5  film was formed as a precursor of a NbON film on the surface of the TiO 2  film by a sputtering method. In the sputtering method, Nb 2 O 5  was used as a target. The total pressure was 1.0 Pa. The power was 150 W. The Nb 2 O 5  film was formed in such a manner that the Nb 2 O 5  film having a thickness of 100 nanometers was formed in a case where the Nb 2 O 5  film was formed on the flat-and-smooth quartz substrate under a similar condition. In this way, a stacked structure of Nb 2 O 5 /TiO 2 /Ti/Si pillar protrusions was fabricated. 
     In order to turn the Nb 2 O 5  film formed at the uppermost surface into the NbON film, the fabricated stacked structure was subjected to sintering under gas current containing ammonia to nitride the Nb 2 O 5  film. Specifically, the stacked structure was put into a furnace. While gaseous mixture containing 20 volume % of ammonia, 0.12 volume % of oxygen, and 79.88 volume % of nitrogen flows through the furnace, the temperature of the inside of the furnace was raised from room temperature to 750 degrees Celsius at a temperature rising rate of 100 degrees Celsius/hour. Then, the Nb 2 O 5  film was maintained at a temperature of 750 degrees Celsius. Finally, the temperature of the inside of the furnace was lowered at a temperature cooling rate of 100 degrees Celsius/hour. Thus, a stacked structure of NbON/TiO 2 /Ti/Si pillar protrusions was fabricated. 
     Since a surface oxide film was formed on the part of the Ti film which had not been immersed in the LPD solution, the part of the Ti film was polished so that the surface oxide film was removed. In this way, the part of the Ti film was exposed. A copper wire was electrically connected to the exposed Ti film with a silver paste. The copper wire was fixed with an epoxy resin. In this way, a semiconductor photoelectrode having a stacked structure of NbON/TiO 2 /Ti/Si pillar protrusions was obtained. 
     (Measurement of the Photocurrent) 
     In order to evaluate the photocurrent property of the obtained semiconductor photoelectrode, while the semiconductor photoelectrode was irradiated with visible light having a wavelength of 436 nanometers, the photocurrent was measured. The light source was a high-pressure mercury lamp having an emission line of 436 nanometers. The energy of the incident light was 37.6 mW/cm 2 . The aqueous electrolyte solution was a 0.1M sulfuric acid aqueous solution. The counter electrode was a Pt electrode. 
     First, a photocurrent was measured without applying an external bias to the semiconductor photoelectrode. Then, the photocurrent was measured, while an external bias of 0.5 volts was applied to the semiconductor photoelectrode.  FIG. 23  shows these results. 
     As is clear from  FIG. 23 , when the surface of the obtained semiconductor photoelectrode was irradiated with the visible light, the photocurrent was measured so as to response to the irradiation. Furthermore, the value of the photocurrent was increased by the external bias. The maximum value of the photocurrent was approximately 32 microampere/cm 2 . 
     It was believed that the reason why the external bias increased the photocurrent was that the charge separation of the photo-excited carrier was promoted and that the external bias was used as a part of the energy required for water splitting reaction. 
     Comparative Example 1 
     A semiconductor photoelectrode was fabricated in the same manner as in the example 1, expect that a Si wafer which did not have a plurality of pillar protrusions was used as a substrate. Using this semiconductor photoelectrode according to the comparative example 1, the photocurrent was measured, while the external bias of 0.5 volts was applied. The maximum value of the photocurrent in the comparative example 1 was approximately 7 microampere/cm 2 .  FIG. 24  shows the results of the photocurrent in the case of using the semiconductor photoelectrodes according to the example 1 and the comparative example 1. 
     As is clear from  FIG. 24 , as compared to the case where the semiconductor photoelectrode according to the comparative example 1, a higher photocurrent was obtained in the case of the semiconductor photoelectrode according to the example 1. The present inventors observed that a higher photocurrent was obtained in the case of using the semiconductor photoelectrode according to the example 1, as compared to the case of using the semiconductor photoelectrode according to the comparative example 1, even when the external bias was not applied. 
     INDUSTRIAL APPLICABILITY 
     The semiconductor photoelectrode according to the present invention has a larger surface area, since the semiconductor photoelectrode has a surface where a plurality of pillar protrusions are arranged. For this reason, improved is the quantum efficiency of hydrogen-generating reaction generated by irradiating with light. The semiconductor photoelectrode according to the present invention can be used for an energy system such as a hydrogen-generating device using water splitting, and is thus industrially useful. 
     REFERENTIAL SIGNS LIST 
     
         
           200  semiconductor photoelectrode 
           102  conductive substrate 
         EFC Fermi level of the conductive substrate 
           201  semiconductor photocatalyst layer 
           202  first semiconductor layer 
         EFN1 Fermi level of the first semiconductor layer 
         EV1 top of the valence band of the first semiconductor layer 
         EC1 bottom of the conduction band of the first semiconductor layer 
           203  second semiconductor layer 
         EFN2 Fermi level of the second semiconductor layer 
         EV2 top of the valence band of the second semiconductor layer 
         EC2 bottom of the conduction band of the second semiconductor layer 
           300  photoelectrochemical cell 
           31  container 
           31   a  light-entrance portion 
           32  counter electrode 
           33  aqueous electrolyte solution or water 
           34  electric wire 
           35  separator 
           36  first chamber 
           37  second chamber 
           38  first outlet 
           39  second outlet 
           40  inlet 
           400  light