Patent Publication Number: US-11047029-B2

Title: Stainless steel for polymer fuel cell separator and method for preparing same

Description:
CROSS REFERENCE TO RELATED APPLICATIONS 
     This application is a divisional of U.S. application Ser. No. 13/142,495, filed Aug. 12, 2011 (now U.S. Pat. No. 9,290,845, issued Mar. 22, 2016), which is a 371 of international patent application no, PCT/KR2009/007891, filed Dec. 29, 2009, and claims the benefit of Korean Patent Application No. 10- 2008-0135141, filed Dec. 29, 2008, and Korean Patent Application No. 10-2009- 0127397, filed Dec. 18, 2009, the content of each application being incorporated herein by reference. 
    
    
     TECHNICAL FIELD 
     An aspect of the present invention relates to a stainless steel for a fuel cell separator and method of manufacturing the same. More particularly, an aspect of the present invention relates to a stainless steel for a fuel cell separator, which has low interfacial contact resistance and excellent corrosion resistance by setting surface reforming conditions so as to remove an passive film of the stainless steel and control repassivation treatment even under various surface roughness conditions, and a manufacturing method of the stainless steel. 
     BACKGROUND ART 
     In recent years, the energy depletion, the environmental pollution and the like have issued as global problems, and therefore, hydrogen energy and fuel cells using the hydrogen energy have been increasingly used as a substitute of fossil fuel. A fuel cell is a device that transforms chemical energy of hydrogen into electrical energy. Since the fuel cell does not use an internal-combustion engine, there is no noise and vibration, and high efficiency can be achieved. Since pollutants are hardly generated, the fuel cell has come into the spotlight as a new energy source. 
     Fuel cells may be divided into a solid polymer fuel cell, a solid oxide fuel cell, a molten carbonate fuel cell, a phosphoric acid fuel cell, a direct methanol fuel cell and an alkaline fuel cell depending on the kind of an electrolyte. The fuel cells may be used as those for power generation, transportation, portable purposes, and the like. 
     In the solid polymer fuel cell (polymer electrolyte membrane fuel cell, or PEMFC), a solid polymer membrane is used as an electrolyte, and hence the solid polymer fuel cell can operate at a normal temperature and pressure. Further, the solid polymer fuel cell has come into the spotlight as a power source because of a lower operating temperature of about 70 to 80° C., a short operating time and a high power density. Recently, a polymer fuel cell operable even at 100 to 150° C. has been under development. 
       FIG. 1  is a perspective view of a fuel cell including a stainless steel separator. 
     Referring to  FIG. 1 , a solid polymer fuel cell stack  100  includes a membrane electrode assembly  110  including an electrolyte, electrodes (an anode and a cathode) and a gasket for gas sealing, a separator  120  having a flow channel, and an end plate including inlets and outlets  130  and  140  of air and inlets and outlets  150  and  160  of hydrogen gas. 
     The separator  120  is generally formed of any one of graphite, carbon, Ti alloy, stainless steel and conductive plastic. Preferably, the separator is formed of the stainless steel. The stainless steel has low interfacial contact resistance, excellent corrosion resistance, high heat conductivity, low gas transmittance. The stainless steel also has excellent mechanical strength and formability at a thin plate. Thus, the stainless steel has an advantage in that the volume and weight of the fuel cell stack can be reduced. 
     However, the separator  120  formed of the stainless steel has a problem in that the interfacial contact resistance between a material surface of the separator and a membrane electrode assembly (MEA) layer may be increased by semiconducting characteristics of an passive film formed on the surface of the separator  120  under fuel cell operating conditions. Further, the separator  120  requires excellent corrosion resistance in the fuel cell operating environmental atmosphere having a strong acidic atmosphere. 
     In order to solve such a problem, U.S. Pat. No. 6,835,487B2 and Korean Patent No. 0488922 disclose a method for obtaining surface characteristics of a stainless steel to a desired level by regulating the mean surface roughness Ra that shows a surface roughness to be 001 to 1.0 μm and regulating the maximum height Ry to be 0.01 to 20 μm so as to decrease the surface contact resistance of the stainless steel to 100 mΩcm 2  or lower. Here, the stainless steel contains Cr (16 to 45 wt %) and Mo (0.1 to 3.0 wt %) and additionally contains Ag (0.001 to 0.1 wt %). Japanese Laid-Open Publication No 2007-026694 discloses a method for obtaining surface characteristics of a stainless steel to a desired level by forming micro-pits of 0.01 to 1.0 μm on the entire surface of the stainless steel containing Cr and Mo. U.S. Pat. No. 6,379,476B1 discloses a method for preparing a ferritic stainless steel having a mean roughness of 0.06 to 5 μm by exposing carbide (carbide inclusion) and boride (boride inclusion) to a surface of the ferritic stainless steel. Here, the ferrite stainless steel contains 0.08% or more C for forming carbide. Japanese Laid-Open Publication No 2005-302713 discloses a technique for ensuring the locally calculated mean interval S=0.3 μm or less and the second-order mean-square slope Δq=0.05 or more in a stainless steel containing Cr (16 to 45 wt %) and Mo (0.1 to 5.0 wt %). 
     However, these methods are provided only for the purposes of decreasing contact resistance by regulating the surface roughness of the stainless steel, micro-pits or conductive inclusions. To this end, the surface roughness of the stainless steel should be strictly maintained. Therefore, productivity is lowered, and production cost is increased. Further, it is difficult to secure reproducibility. In these methods, a component containing Cr and Mo as essential elements is specified within a predetermined range, and Ag, C and B for forming other conductive inclusions are added as additional elements to the stainless steel. Therefore, the increase in preparation cost may be caused, and it is not necessary to ensure stability of contact resistance and elution resistance under the fuel cell operating condition (60 to 150° C.) in acidic environment. 
     Japanese Laid-Open Publication No 2004-149920 discloses a method for reducing contact resistance by regulating the Cr/Fe atomic ratio to be 1 or more in a stainless steel containing Cr (16 to 45 wt %) and Mo (0.1 to 5.0 wt %). Japanese Laid-Open Publication No 2008-091225 discloses a method for reducing contact resistance by forming micro-pits in a stainless steel containing Cr (16 to 45 wt %) and Mo (0.1 to 5.0 wt %) and by securing the Cr/Fe atomic ratio to be 4 or more. 
     However, these methods have difficulty in specifying a component containing Cr and Mo as essential elements and stably securing low interfacial contact resistance without ensuring a strict control process of a passive film even under conditions having various surface roughnesses. Further, it is not necessary to ensure stability of contact resistance and elution resistance under the fuel cell operating condition (60 to 150° C.) in an acidic environment. 
     DISCLOSURE OF INVENTION 
     Technical Problem 
     Accordingly, an object of the present invention is to provide a stainless steel for a polymer fuel cell separator having excellent long-term performance which can set surface reforming conditions so that it is possible to maintain excellent elution resistance and contact resistance even under a fuel cell operating environment of 60 to 150° C. in an acidic environment and to secure low interfacial contact resistance and corrosion resistance by controlling the removal of a passive film and repassivation treatment even under various surface roughness conditions, and a preparation method of the stainless steel. 
     Technical Solution 
     According to an aspect of the present invention, there is provided a stainless steel for a fuel cell separator, to which Mo is not added, the stainless steel comprising C: 0.02 wt % or less, N: 0.02 wt % or less, Si: 0.4 wt % or less, Mn: 0.2 wt % or less, P: 0.04 wt % or less, S: 0.02 wt % or less, Cr: 25.0 to 32.0 wt %, Cu: 0 to 2.0 wt %, Ni: 0.8 wt % or less, Ti: 0.5 wt % or less, Nb: 0.5 wt % or less, waste Fe and inevitably contained elements. In the stainless steel, a passive film formed on a surface of the stainless steel is formed to have a thickness of 2 to 4.5 nm, the Cr/Fe oxide ratio of the passive film is 1.5 or more in a region of 1.5 nm or less, and the Cr(OH) 3 /Cr oxide distribution of the passive film has a ratio of 0 to 0.7 in a region of 1 nm. 
     The stainless steel may include Mo: 5.0 wt % or less. 
     The stainless steel may further include one or two or more elements selected from the group consisting of V: 0.1 to 1.5 wt %, W: 0.1 to 2.0 wt %, La: 0.0005 to 1.0 wt %, Zr: 0.0005 to 1.0 wt % and B: 0.0005 to 1.0 wt %. 
     The contact resistance of the stainless steel may be 10 mΩcm 2  or less. 
     According to another aspect of the present invention, there is provided a preparation method of a stainless steel for a polymer fuel cell separator, comprising C: 0.02 wt % or less, N: 0.02 wt % or less, Si: 0.4 wt % or less, Mn: 0.2 wt % or less, P: 0.04 wt % or less, S: 0.02 wt % or less, Cr: 25.0 to 32.0 wt %, Cu: 0 to 2.0 wt %, Ni: 0.8 wt % or less, Ti: 0.5 wt % or less, Nb: 0.5 wt % or less, waste Fe and inevitably contained elements, in which a second passive film is formed on a surface of the stainless steel to which Mo is not added, the method comprising: forming a first passive film on the surface of the stainless steel by bright-annealing or annealing-pickling the stainless steel; removing the first passive film by pickling the stainless steel in a 10 to 20 wt % sulfuric acid solution at a temperature of 50 to 75° C. for a time controlled based on a surface roughness Ra; water-washing the stainless steel; and forming the second passive film by performing a passivation treatment on the stainless steel in the mixture of a 10 to 20 wt % nitric acid and a 1 to 10 wt % fluorine acid at a temperature of 40 to 60° C. for the time controlled based on the surface roughness Ra. 
     In the removing of the first passive film, the stainless steel may be pickled for a processing time according to the following expression:
 
99−3.18(1/Ra)≤processing time ( t , second) s≤ 153−3.18(1/Ra).
 
     In the forming of the second passive film, the stainless steel may be subjected to the passivation treatment for a processing time according to the following expression:
 
120+6.73(1/Ra)≤processing time( t , second)≤140+6.73(1/Ra).
 
     The contact resistance of the stainless steel may be 10 mΩcm 2  or less under an operating environment of 60 to 150° C. 
     In the forming of the second passive film, the second passive film may be formed to have a thickness of 2 to 4.5 nm. 
     In the forming of the second passive film, the Cr/Fe oxide ratio of the second passive film may be 1.5 or more in a region of 1.5 nm or less. 
     In the forming of the second passive film, the Cr(OH) 3 /Cr oxide distribution of the second passive film may have a ratio of 0 to 0.7 in a region of 1 nm. 
     Advantageous Effects 
     As described above, according to the present invention, surface reforming conditions are set so that it is possible to control the removal of a passive film of a stainless steel and repassivation treatment even under various surface roughness conditions. Thus, the stainless steel can secure low interfacial contact resistance and achieve excellent corrosion resistance with reduced elution resistance. Accordingly, it is possible to produce a stainless steel having excellent long-term performance of the polymer fuel cell. 
    
    
     
       DESCRIPTION OF DRAWINGS 
         FIG. 1  is a perspective view of a fuel cell including a general stainless separator. 
         FIG. 2  is a graph showing a change in initial interfacial contact resistance for each surface roughness. 
         FIG. 3  is a graph showing a change in potential obtained by immersing invention steel 12 in a 15 wt % sulfuric acid solution at 70° C. using a saturated calomel electrode (SCE) electrode as a reference electrode. 
         FIG. 4  is a graph showing a change in potential when washing the stainless steel that goes through  FIG. 3  and then immersing the invention steel 12 in the mixture of a nitric acid of 15 wt % and a fluorine acid of 5 wt % using the SCE electrode as a reference electrode. 
         FIG. 5  is a graph showing a change in contact resistance when heat-treating a stainless steel subjected to surface reforming treatment under an air atmosphere. 
         FIGS. 6A to 6C  are graphs showing examples of performing an X-ray photoelectron microscopy analysis on composition distributions of first and second passive films in an initial period, after performing a surface reforming treatment and after performing a potentiostatic polarization test according to embodiments of Table 2. 
         FIGS. 7A to 7C  are graphs showing Cr/Fe oxide distributions in the first and second passive films in the initial period, after performing the surface reforming treatment and after performing the potentiostatic polarization test according to the embodiments of Table 2. 
         FIG. 8  is a graph showing a Cr(OH) 3 /Cr oxide distribution in the first and second passive films in the initial period, after performing the surface reforming treatment and after performing the potentiostatic polarization test according to the embodiments of Table 2. 
         FIGS. 9A to 9C  are graphs showing performance estimation results measured by preparing stainless separators formed by performing an optimum two-step surface reforming treatment on invention steels 9 and 12 in Table 3 and then assembling the prepared stainless separator in a polymer fuel cell unit cell. 
     
    
    
     BEST MODE 
     Hereinafter, a stainless steel for a fuel cell separator according to the present invention will be described in detail with reference to the accompanying drawings. 
     A general stainless steel for a fuel cell separator having various surface roughness conditions, such as a bright annealing material or annealing pickling material of a stainless steel cold-rolled material, has high contact resistance due to a passive film formed on a surface of the stainless steel after annealing and pickling the stainless steel, and the surface roughness conditions are partially changed due to friction between the surface and a mold in the molding process of a portion of the separator. Accordingly, an appropriate surface reforming treatment is preferably performed on the stainless steel for the separator so as to satisfy requirements of a separator having low contact resistance and improved corrosion resistance under various surface roughness conditions. 
     To this end, in the present invention, a stainless steel for a polymer fuel cell separator, which has low interfacial contact resistance and excellent corrosion resistance, and a preparation method of the stainless steel, will be described. A separator is stamed or hydro-formed using a stainless steel having various surface roughnesses. In order to remove a first passive film formed on the separator, the stainless steel is pickled in a 10 to 20 wt % sulfuric acid solution at a temperature of 50 to 75° C. under an optimum processing condition while maintaining an appropriate time depending on a surface roughness condition. After water-washing the stainless steel, a repassivation treatment of the stainless steel is performed in the mixture of a 10 to 20 wt % nitric acid and a 1 to 10 wt % fluoric acid at a temperature of 40 to 601° C. while maintaining an appropriate time depending on a surface roughness condition so as to form a second passive film. Accordingly, the thickness of the passive film formed on the surface of the stainless steel is formed to 2 to 4.5 nm, and the Cr/Fe oxide ratio is 1.5 or more in a region of less than 1.5 nm. Also, the Cr(OH) 3 /Cr oxide ratio is 0 to 0.7 in a region of 1 nm, so that the contact resistance of the stainless steel can ensure 10 mΩcm 2  or less. 
     Hereinafter, the stainless steel for the polymer fuel cell separator, which has low interfacial contact resistance and excellent corrosion resistance, will be described in detail. 
     The stainless steel according to the present invention has a composition of elements including C: 0.02 wt % or less, N: 0.02 wt % or less, Si: 0.4 wt % or less, Mn: 0.2 wt % or less, P: 0.04 wt % or less, Cr: 25.0 to 32.0 wt %, Cu: 0 to 0.2 wt %, Ni: 0.8 wt % or less, and Ti: 0.5 wt % or less; one or two or more elements selected from the group consisting of V: 0 to 1.5 wt %, W: 0 to 2.0 wt %, La: 0 to 1.0 wt %, Zr: 0 to 1.0 wt % and B: 0 to 0.1 wt %; and waste Fe and inevitably contained elements. As described above, Mo is not added to the stainless steel according to the present invention. 
     Meanwhile, in a case where the Mo is added to the stainless steel, the content of the Mo is preferably 0.5 wt % or less. 
     A slab produced by steel making, refining and continuous casting an alloy with such a composition passes through processes of hot-rolling, annealing, pickling, cool-rolling, annealing and pickling, thereby preparing a cold-rolled product. 
     Hereinafter, the composition range and limitation reason of the present invention will be described in detail. The following percentages (%) are weight percentages in all cases. 
     C and N form a Cr carbon/nitride in the stainless steel. As a result, the corrosion resistance of a layer in which Cr is deficient is lowered, and therefore, both the elements are preferably contained as small as possible. Thus, in the present invention, their composition ratios are limited to C: 0.02% or less, and N: 0.02% or less, respectively. 
     Si is an element effective for deoxidation but constraints ductility and formability. Thus, in the present invention, the composition of the Si is limited to 0.4% or less. 
     Mn is an element that increases deoxidation, but MnS that is an inclusion decreases corrosion resistance. Thus, in the present invention, the composition ratio of the Mn is limited to 0.2% or less. 
     P decreases ductility in addition to corrosion resistance. Thus, in the present invention, the composition ratio of the P is limited to 0.04% or less. 
     S forms MnS, and the MnS becomes a starting point to decrease corrosion resistance. Thus, in the present invention, the composition ratio of the S is limited to 0.02% or less. 
     Cr increases corrosion resistance under an acidic atmosphere in which a fuel cell is operated. But Cr decreases ductility. Thus, in the present invention, the composition ratio of the Cr is limited to 25 to 32%. 
     Mo functions to increase corrosion resistance under the acidic atmosphere in which the fuel cell is operated. However, if the Mo is excessively added to the stainless steel, ductility is decreased, and the Mo is disadvantageous in terms of effect and economic efficiency. Thus, in the present invention, the Mo is not basically added to the stainless steel. The present invention can obtain a desired effect even when the Mo is not added to the stainless steel. In a case where it is particularly required to improve corrosion resistance, the Mo may be separately added to the stainless steel. In this case, the content of the Mo is preferably limited to the range of 5% or less. 
     Cu may increase corrosion resistance under the acidic atmosphere in which the fuel cell is operated, or the performance of the fuel cell and the formability of the stainless steel may be lowered due to the elution of the Cu and the effect of solid solution strength when the Cu is excessively added to the stainless steel. Thus, in the present invention, the composition ratio of the Cu is limited to the range from 0 to 2%. 
     Ni functions to decrease partial contact resistance, but the election of the Ni and the formability of the stainless steel may be lowered when the Ni is excessively added to the stainless steel. Thus, in the present invention, the composition ratio of the Ni is limited to 0.8% or less. 
     Ti and Nb are element effective for forming C and N as a carbon nitride in the stainless steel, but decrease ductility. Thus, in the present invention, the composition ratio of each of the Ti and Nb is limited to 0.5% or less. 
     In addition, one or two or more of V, W, La, Zr and B may be added to the stainless steel, and their composition ratios are as follows. 
     V increases corrosion resistance under the acidic atmosphere in which the fuel cell is operated, but the performance of the fuel cell may be lowered due to the elution of ions when the V is excessively added to the stainless steel. Thus, in the present invention, the composition ratio of the V is limited to 0.1 to 1.5%. 
     W increases corrosion resistance and decreases interfacial contact resistance under the acidic atmosphere in which the fuel cell is operated. However, when the W is excessively added to the stainless steel, tension is decreased. Thus, in the present invention, the composition ratio of the W is limited to 0.1 to 2.0%. 
     La may induce fine dispersion of a sulfide-based inclusion in the stainless steel and induce densification of a passive film. However, when the La is excessively added to the stainless steel, there occurs a problem of nozzle clogging, or the like. Thus, in the present invention, the composition ratio of the La is limited to 0.0005 to 1.0%. 
     Zr increases corrosion resistance under the acidic atmosphere in which the fuel cell is operated, but induces a surface defect when the Zr is excessively added to the stainless steel. Thus, in the present invention, the composition ratio of the Zr is limited to 0.0005 to 1.0%. 
     B forms a nitride in the stainless steel and improves its corrosion resistance. However, when the B is excessively added to the stainless steel, a surface defect is induced. Thus, in the present invention, the composition ratio of the B is limited to 0.0005 to 1.0%. 
     Hereinafter, a process of setting a processing condition for each surface roughness condition. 
     The compositions of stainless steels prepared in the present invention are shown in Table 1. 
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 1 
               
               
                   
               
               
                 Kind of steel 
                 C 
                 Si 
                 Mn 
                 P 
                 S 
                 Al 
                 Cr 
                 Ni 
                 Cu 
                 Ti 
                 Nb 
                 Mo 
                 Other 
                 N 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Invention 
                 0.009 
                 0.29 
                 0.142 
                 &lt;0.003 
                 &lt;0.002 
                 0.048 
                 26.26 
                 0.173 
                 0.437 
                 0.058 
                 0.241 
                 2.03 
                 — 
                 0.009 
               
               
                 steel 1 
               
               
                 Invention 
                 0.007 
                 0.273 
                 0.146 
                 &lt;0.003 
                 &lt;0.002 
                 0.058 
                 26.33 
                 0.167 
                 0.436 
                 0.059 
                 0.25 
                 4.04 
                 — 
                 0.009 
               
               
                 steel 2 
               
               
                 Invention 
                 0.008 
                 0.269 
                 0.145 
                 &lt;0.003 
                 &lt;0.002 
                 0.055 
                 30.01 
                 0.169 
                 0.43 
                 0.06 
                 0.245 
                 2.13 
                 — 
                 0.009 
               
               
                 steel 3 
               
               
                 Invention 
                 0.006 
                 0.293 
                 0.143 
                 &lt;0.003 
                 &lt;0.002 
                 0.041 
                 30.29 
                 0.168 
                 0.4 
                 0.046 
                 0.242 
                 4.03 
                 — 
                 0.008 
               
               
                 steel 4 
               
               
                 Invention 
                 0.006 
                 0.303 
                 0.14 
                 &lt;0.003 
                 &lt;0.002 
                 0.027 
                 28.55 
                 0.181 
                 0.412 
                 0.041 
                 0.241 
                 3.19 
                 — 
                 0.009 
               
               
                 steel 5 
               
               
                 Invention 
                 0.008 
                 0.341 
                 0.146 
                 &lt;0.003 
                 &lt;0.002 
                 0.039 
                 30.66 
                 0.181 
                 0.442 
                 0.041 
                 0.245 
                 2.03 
                 0.0013La 
                 0.012 
               
               
                 steel 6 
               
               
                 Invention 
                 0.008 
                 0.307 
                 0.14 
                 &lt;0.003 
                 &lt;0.002 
                 0.03 
                 29.68 
                 0.19 
                 0.421 
                 0.039 
                 0.24 
                 2.12 
                 0.420W 
                 0.008 
               
               
                 steel 7 
               
               
                 Invention 
                 0.008 
                 0.263 
                 0.145 
                 &lt;0.003 
                 &lt;0.002 
                 0.055 
                 29.68 
                 0.184 
                 0.429 
                 0.051 
                 0.243 
                 2 
                 0.002Zr 
                 0.008 
               
               
                 steel 8 
               
               
                 Invention 
                 0.007 
                 0.24 
                 0.151 
                 &lt;0.003 
                 &lt;0.002 
                 0.041 
                 30.42 
                 0.185 
                 0.964 
                 0.05 
                 0.247 
                 2.03 
                 — 
                 0.009 
               
               
                 steel 9 
               
               
                 Invention 
                 0.009 
                 0.267 
                 0.148 
                 &lt;0.003 
                 &lt;0.002 
                 0.04 
                 30.75 
                 0.183 
                 0.455 
                 0.049 
                 0.243 
                 2.03 
                 0.363V 
                 0.009 
               
               
                 steel 10 
               
               
                 Invention 
                 0.007 
                 0.308 
                 0.15 
                 &lt;0.003 
                 &lt;0.002 
                 0.021 
                 30.42 
                 0.183 
                 0.442 
                 0.036 
                 0.24 
                 2.01 
                 0.001B 
                 0.008 
               
               
                 steel 11 
               
               
                 Invention 
                 0.003 
                 0.107 
                 0.146 
                 0.003 
                 &lt;0.003 
                 0.057 
                 30.05 
                 0.192 
                 0.977 
                 0.05 
                 0.25 
                 2 
                 0.4W 
                 0.006 
               
               
                 steel 12 
               
               
                 Invention 
                 0.004 
                 0.199 
                 0.153 
                 0.003 
                 &lt;0.003 
                 0.043 
                 30.1 
                 0.193 
                 1.01 
                 0.045 
                 0.25 
                 1.98 
                 0.41W 
                 0.007 
               
               
                 steel 13 
               
               
                 Invention 
                 0.005 
                 0.222 
                 0.148 
                 0.003 
                 &lt;0.003 
                 0.056 
                 30.26 
                 0.207 
                 0.97 
                 0.048 
                 0.26 
                 2.03 
                 0.4V 
                 0.009 
               
               
                 steel 14 
               
               
                 Invention 
                 0.005 
                 0.162 
                 0.152 
                 0.003 
                 &lt;0.003 
                 0.946 
                 29.96 
                 0.747 
                 0.975 
                 0.052 
                 0.26 
                 2 
                 0 
                 0.005 
               
               
                 steel 15 
               
               
                 Invention 
                 0.006 
                 0.208 
                 0.138 
                 0.004 
                 &lt;0.003 
                 0.03 
                 30.07 
                 0.204 
                 0.973 
                 0.041 
                 0.25 
                 1.47 
                 0.41W 
                 0.007 
               
               
                 steel 16 
               
               
                 Invention 
                 0.004 
                 0.2 
                 0.145 
                 0.003 
                 &lt;0.003 
                 0.047 
                 28.01 
                 0.199 
                 0.993 
                 0.044 
                 0.25 
                 2.01 
                 0.41W 
                 0.008 
               
               
                 steel 17 
               
               
                 Invention 
                 0.006 
                 0.141 
                 0.152 
                 &lt;0.003 
                 &lt;0.003 
                 0.051 
                 30.25 
                 0.11 
                 1.00 
                 0.049 
                 0.26 
                 — 
                 0.39V 
                 0.011 
               
               
                 steel 18 
               
               
                 Invention 
                 0.011 
                 0.138 
                 0.167 
                 &lt;0.003 
                 &lt;0.003 
                 0.071 
                 30.58 
                 0.11 
                 0.96 
                 0.056 
                 0.27 
                 — 
                 0.40V 
                 0.012 
               
               
                 steel 19 
               
               
                 Invention 
                 0.006 
                 0.118 
                 0.151 
                 &lt;0.003 
                 &lt;0.003 
                 0.049 
                 30.20 
                 0.11 
                 0.97 
                 0.051 
                 0.26 
                 — 
                 — 
                 0.008 
               
               
                 steel 20 
               
               
                 Invention 
                 0.005 
                 0.136 
                 0.150 
                 &lt;0.003 
                 &lt;0.003 
                 0.034 
                 30.16 
                 0.12 
                 0.96 
                 0.051 
                 0.25 
                 0.98 
                 0.40W 
                 0.009 
               
               
                 steel 21 
               
               
                 Invention 
                 0.006 
                 0.126 
                 0.150 
                 &lt;0.003 
                 &lt;0.003 
                 0.043 
                 30.16 
                 0.10 
                 0.97 
                 0.050 
                 0.25 
                 — 
                 — 
                 0.009 
               
               
                 steel 22 
               
               
                 Invention 
                 0.008 
                 0.110 
                 0.151 
                 &lt;0.003 
                 &lt;0.003 
                 0.083 
                 30.19 
                 0.11 
                 0.98 
                 0.056 
                 0.26 
                 — 
                 0.37W 
                 0.009 
               
               
                 steel 23 
               
               
                 Invention 
                 0.004 
                 0.124 
                 0.121 
                 &lt;0.003 
                 &lt;0.003 
                 0.037 
                 30.10 
                 0.12 
                 — 
                 0.051 
                 0.24 
                 — 
                 0.4V 
                 0.008 
               
               
                 steel 24 
               
               
                 Invention 
                 0.005 
                 0.113 
                 0.143 
                 &lt;0.003 
                 &lt;0.003 
                 0.035 
                 30.11 
                 0.11 
                 — 
                 0.050 
                 0.25 
                 — 
                 — 
                 0.009 
               
               
                 steel 25 
               
               
                 Invention 
                 0.007 
                 0.128 
                 0.128 
                 &lt;0.003 
                 &lt;0.003 
                 0.941 
                 30.01 
                 — 
                 0.97 
                 0.050 
                 0.25 
                 — 
                 0.4V 
                 0.009 
               
               
                 steel 26 
               
               
                 Invention 
                 0.006 
                 0.111 
                 0.137 
                 &lt;0.003 
                 &lt;0.003 
                 0.025 
                 30.00 
                 — 
                 0.98 
                 0.056 
                 0.26 
                 — 
                 — 
                 0.09 
               
               
                 steel 27 
               
               
                 Comparative 
                 0.008 
                 0.4 
                 0.34 
                 0.003&lt; 
                 &lt;0.002 
                 0.003 
                 19.33 
                 0.14 
                 0.45 
                 — 
                 0.43 
                 0.01 
                 0.98V 
                 0.008 
               
               
                 steel 
               
               
                   
               
            
           
         
       
     
     The inventor measured an initial interfacial contact resistance at a contact pressure of 140 N/cm 2  with respect to each of the steels in Table 1, and measured its interfacial contact resistance after completing chemical surface reforming according to the present invention. The measurement of the interfacial contact resistance will be illustrated in the following description. 
     In order to observe a change in contact resistance depending on a surface roughness, the inventor prepared stainless steel plates having different surface roughnesses with respect to the invention steel 12 in Table 1 as a representative example and then measured the interfacial contact resistance in the state of a passive film formed in the air. 
     The measurement of the interfacial contact resistance is measured by the DC 4-terminal method. Two separators are sandwiched between carbon papers (SGL Co., GDL 10-BA), and a copper end plate is mounted together with the carbon papers. Then, a current applying terminal is connected to the copper end plate, and voltage terminals are connected to the respective two separators, thereby measuring a contact resistance according to pressure. In this instance, the measurement of the interfacial contact resistance for each of the slabs was performed four times or more. 
       FIG. 2  is a graph showing a change in initial interfacial contact resistance for each surface roughness. 
     Referring to  FIG. 2 , the surface contact resistance of a stainless steel is decreased as the mean roughness Ra of a surface of the stainless steel, measured by surface roughness tester, is increased. Although stainless steels have the same kind of steel, they show a considerable difference according to their surface roughnesses. The change in interfacial contact resistance depending on surface roughness has a correlation in that the contact resistance is in proportion to 1/Ra, 1/Rq, 1/Rp, 1/Rt or 1/dp. However, the contact resistances of stainless steels of which mean roughnesses Ra are 0.350, 0.055 and 0.040, respectively, are high in applying the stainless steels as polymer fuel cell separators. When the contact resistance of a stainless steel is generally 10 mΩcm 2  or less, the stainless steel is suitable for the separator. 
     That is, such a result means that it is difficult to secure a contact resistance of 10 mΩcm 2  or less only through the control of the surface roughness. As the result studied by the inventor, it has been found that this is result from a thin protective passive film formed on the surface of the stainless steel. The passive film is formed of a Fe—Cr-based oxide and has a high content of Fe. Since the thickness of the passive film is thick, the contact resistance of the stainless steel is high. The stainless steel having a passive film formed thereon is not suitable to be used as a separator for a polymer fuel cell. Accordingly, the invention has found that the passive film is necessarily removed from the stainless steel. Particularly, it is required to develop a technique for controlling the composition and thickness of a passive film regardless of an initial surface roughness condition. 
     Thus, in the present invention, a stainless steel having a first passive film formed thereon was pickled in a 10 to 20 wt % sulfuric acid solution at a temperature of 50 to 75° C. under optimum processing conditions while maintaining the following processing time according to surface roughness conditions, thereby removing the first passive film. 
       FIG. 3  is an embodiment of an optimum pickling condition for each surface roughness according to the present invention.  FIG. 3  is a graph showing a change in potential obtained by immersing invention steel 12 in a 15 wt % sulfuric acid solution at 70° C. using a saturated calomel electrode (SCE) electrode as a reference electrode. 
     As shown in  FIG. 3 , the potential of the stainless steel in a state that the first passive film is formed on a surface of the invention steel 12 is higher than that in a state that an oxide is not formed on the surface of the invention steel 12. If the first passive film is removed by immersing the first passive film in the sulfuric acid solution, the potential of the stainless steel is rapidly decreased within 25 seconds. This means that the removal of the first passive film composed of an oxide formed on the surface of the stainless steel is started, and as a result, the potential of the stainless steel is gradually decreased within 25 seconds. After a certain period of time elapses, the oxide formed on the surface of the immersed stainless steel is removed, so that the potential of the stainless steel is not decreased any more but saturated. Thus, the stainless steel is immersed in the sulfuric acid solution from the potential lower than that in the initial period of immersion to the saturation time, thereby removing the first passive film (oxide) formed on the surface of the stainless steel. 
     Through the graph of  FIG. 3 , it can be seen that the aspect in which stainless steel plate reacts in the sulfuric acid solution is different for each surface roughness condition, and accordingly, the processing condition for removing an oxide in the sulfuric acid solution is also different for each of the surface roughness conditions. Therefore, in the invention steel, the appropriate processing time for removing the first passive film in a 10 to 20 wt % sulfuric acid solution at a temperature of 50 to 75° C. is increased as the surface roughness is increased. The appropriate processing time satisfies the following expression 1.
 
99−3.18(1/Ra)≤processing time( t , second)≤153−3.18(1/Ra)  (1)
 
     In a case where the temperature and concentration of the sulfuric acid solution is extremely low, the oxide formed on the surface is not easily removed. On the contrary, in a case where temperature and concentration of the sulfuric acid solution is extremely high, damage of a base material may be caused. Thus, the temperature of the sulfuric acid solution is limited to 50 to 750° C., and the concentration of the sulfuric acid solution is limited to 10 to 20 wt %. If the processing time is over the aforementioned conditions, it is difficult to remove the passive film with high interfacial contact resistance. If the processing time is below the aforementioned conditions, it is difficult to secure a contact resistance of 10 mΩcm 2  or less due to the damage of the base material and the formation of the passive film with high interfacial contact resistance. 
     Then, the stainless steel having the first passive film removed therefrom is water-washed. 
     A repassivation treating process is performed in a mixture of a 10 to 20 wt % nitric acid and a 1 to 10 wt % fluoric acid at a temperature of 40 to 60° C. while maintaining the processing time according to the surface roughness condition, thereby forming a second passive film on the surface of the stainless steel. 
       FIG. 4  is an embodiment in which an optimum second passive film is formed for each surface roughness.  FIG. 4  is a graph showing a change in potential when washing the stainless steel that goes through  FIG. 3  and then immersing the invention steel 12 in a mixture of a nitric acid of 15 wt % and a fluorine acid of 5 wt % using the SCE electrode as a reference electrode. 
     Referring to  FIG. 4 , slabs with different surface roughness conditions are water-washed by applying the optimum immersion condition of the sulfuric acid solution, derived from  FIG. 3 , and the second passive film is formed on the surface of the stainless steel in the mixture of the nitric acid of 15 wt % and the fluorine acid of 5 wt %. 
     In a case where the stainless steel is immersed in an oxidizing acid such as the mixture of the nitric acid and the fluoric acid, a passive film is formed on the surface of the stainless steel. If the passive film is formed on the surface of the stainless steel, the potential of the stainless steel is increased as time elapses. As described above, if the stainless steel according to the present invention is immersed in the mixture of the nitric acid and the fluoric acid from the potential higher than that in the initial period of immersion to the saturation, the second passive film is formed on the surface of the stainless steel. 
     In this process, the inventor has found that it takes much time to perform passivation treatment as the temperature of the passivation treatment is decreased, and it is harmful to contact resistance and corrosion resistance due to surface damage as the temperature of the passivation treatment is increased. Thus, in the second passivation treatment, the second passive film is preferably formed in a mixture of a 10 to 20 wt % nitric acid and a 1 to 10 wt % fluoric acid at a temperature of 40 to 60° C. The inventor has also found that the second passive film is necessarily formed differently depending on the surface roughness condition, and it is possible to prepare a separator having characteristics in which the processing time is decreased as the surface roughness is increased and the contact resistance is low at the following processing time t. The preferred processing time satisfies the following expression 2.
 
120−6.73(1/Ra)≤processing time( t , second)≤140−6.73(1/Ra)  (2)
 
     In the present invention, the concentration of the nitric acid is limited to 10 to 20 wt %. In a case where the concentration of the nitric acid is less than 10 wt %, it is difficult to perform the passive treatment. In a case where the concentration of the nitric acid is extremely high, there is no effect of reduction in contact resistance. 
     In the present invention, the concentration of the fluoric acid is limited to 1 to 10 wt %. In a case where the concentration of the fluoric acid is less than 1 wt %, the passive film may be unstable. On the contrary, in a case where the fluoric acid is excessively added to the stainless steel, it is harmful to contact resistance and corrosion resistance due to surface damage. In the present invention, the inventor has found that when the processing time is deviated from an appropriate time for each of the surface roughnesses, the passive film is unstable or the thickness of the passive film is excessively increased, and therefore, the contact resistance is increased. 
     Accordingly, the stainless steel according to the present invention can secure the initial contact resistance of 10 mΩcm 2  or less and the contact resistance after performing a corrosion test under environmental conditions of the fuel cell. Particularly, in the corrosion resistance when chemical surface reforming treatment is performed on these invention steels, the corrosion current density of the stainless steel is low, and the elution resistance of the stainless steel is excellent. The corrosion resistance will be described later in Table 3. 
     In the process of preparing a real fuel cell separator, the separator can be exposed up to 250 degrees in the bonding process of a sealing portion, and the temperature of the separator is increased by heat generated in separator welding such as laser welding. As a high-temperature electrolyte has recently been developed, the operating temperature is increased up to 150° C. Thus, in a case where the surface reforming treatment is performed on the invention steel under the development condition, the stability of contact resistance is observed. As a result, all the invention steels can secure the contact resistance of 10 mΩcm 2  or less. An example of the invention steel 18 is shown in  FIG. 5 . 
     As an embodiment of the present invention, table 2 shows a change in interfacial contact resistance according to each processing time for each surface roughness condition of the invention steel 12. 
     
       
         
           
               
               
               
               
               
             
               
                 TABLE 2 
               
               
                   
               
               
                   
                   
                 Processing time 
                 Contact 
                   
               
               
                   
                 Processing time 
                 (second) of 
                 resistance 
               
               
                   
                 (second) of 
                 15 wt % nitric 
                 (mΩcm 2 ) at 
               
               
                   
                 15 wt % sulfuric 
                 acid + 5 wt % 
                 pressure of 
               
               
                 Ra 
                 acid 
                 fluoric acid 
                 140 N/m 2   
                 Remark 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
            
               
                 0.350 
                 0 
                 0 
                 28.26 
                 Comparative 
               
               
                   
                   
                   
                   
                 example 
               
               
                   
                 100 
                 150 
                 3.89 
                 Invention 
               
               
                   
                   
                   
                   
                 example 
               
               
                 0.055 
                 0 
                 0 
                 75.37 
                 Comparative 
               
               
                   
                   
                   
                   
                 example 
               
               
                   
                 0 
                 250 
                 22.51 
                 Comparative 
               
               
                   
                   
                   
                   
                 example 
               
               
                   
                 30 
                 250 
                 15.01 
                 Comparative 
               
               
                   
                   
                   
                   
                 example 
               
               
                   
                 60 
                 250 
                 3.94 
                 Invention 
               
               
                   
                   
                   
                   
                 example 
               
               
                   
                 90 
                 250 
                 8.72 
                 Invention 
               
               
                   
                   
                   
                   
                 example 
               
               
                 0.040 
                 0 
                 0 
                 102.44 
                 Comparative 
               
               
                   
                   
                   
                   
                 example 
               
               
                   
                 30 
                 300 
                 3.89 
                 Invention 
               
               
                   
                   
                   
                   
                 example 
               
               
                   
               
            
           
         
       
     
     As shown in Table 2, when the mean surface roughness Ra is 0.055, the contact resistance is changed by constantly maintaining the processing time of the mixture of the nitric acid and the fluorine acid and modifying the process of sulfuric acid pickling. Accordingly, the inventor has found that the process of sulfuric acid pickling has great influence on the contact resistance. As the processing time is long or short, the contact resistance is increased. Thus, the inventor has found that the processing time for each surface roughness condition has important influence on the contact resistance. 
     For each of the steels in Table 1, the inventor performed a pickling process of a first passive film in a 10 to 20 wt % sulfuric acid solution at a temperature of 50 to 75° C. for an appropriate processing time [99−3.18(1/Ra)≤processing time (t, second)≤153−3.18(1/Ra)] and then performed a water-washing process. Then, the inventor performed a forming process of a second passive film in the mixture of a 10 to 20 wt % nitric acid and a 1 to 10 wt % fluoric acid at a temperature of 40 to 60° C. for an appropriate time [120−6.73(1/Ra)≤processing time (t, second)≤140−6.73(1/Ra)]. Table 3 shows results for a contact resistance measured in the aforementioned process, a corrosion current density after performing a condition similar to a cathode atmosphere condition in the atmosphere of the polymer fuel cell, i.e., a potentiostatic polarization test, a contact resistance after performing the potentiostatic polarization test, and a corrosion-resistance experiment with respect to each of the invention steels. Here, the potentiostatic polarization test is performed by applying a voltage of 0.6V for 9 hours using an SCE as a reference electrode while bubbling air in a mixed solution of a sulfuric acid of IM and a fluorine acid of 2 ppm at a temperature of 70° C. The corrosion-resistance experiment is performed by measuring Fe, Cr and Ni elution ions in a corrosion solution using an inductively coupled plasma spectroscopy (ICP). 
     
       
         
           
               
               
               
             
               
                   
                 TABLE 3 
               
             
            
               
                   
                   
               
               
                   
                 Contact 
                   
               
            
           
           
               
               
               
               
               
               
            
               
                   
                 Contact 
                 resistance (mΩcm 2 ) 
                   
                   
                 Elution ion 
               
               
                   
                 resistance (mΩcm 2 ) 
                 at 140 N/cm 2  after 
                 Corrosion 
                 Interfacial contact 
                 concentration (mg/L) 
               
               
                   
                 at 140 N/cm 2  after 
                 heat treatment in 
                 current 
                 resistance (mΩcm 2 ) 
                 after polarization 
               
               
                 Kind of 
                 chemical surface 
                 air atmosphere of 200 
                 density 
                 at 140 N/cm 2  after 
                 experiment 
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                 steel 
                 reforming 
                 degrees for 20 minutes 
                 (μA/cm 2 ) 
                 polarization experiment 
                 Fe 
                 Cr 
                 Ni 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                 Invention 
                 5.17 
                 5.40 
                 0.08 
                 5.84 
                 0.023 
                 No 
                 No 
               
               
                 steel 1 
               
               
                 Invention 
                 4.32 
                 5.1 
                 0.02 
                 4.92 
                 0.033 
                 No 
                 No 
               
               
                 steel 2 
               
               
                 Invention 
                 4.09 
                 4.30 
                 0.07 
                 4.71 
                 0.024 
                 No 
                 No 
               
               
                 steel 3 
               
               
                 Invention 
                 4.35 
                 4.55 
                 0.03 
                 4.52 
                 0.017 
                 No 
                 No 
               
               
                 steel 4 
               
               
                 Invention 
                 4.16 
                 4.20 
                 0.02 
                 4.10 
                 0.021 
                 No 
                 No 
               
               
                 steel 5 
               
               
                 Invention 
                 4.16 
                 4.30 
                 0.02 
                 5.66 
                 0.025 
                 No 
                 No 
               
               
                 steel 6 
               
               
                 Invention 
                 3.70 
                 4.55 
                 0.04 
                 4.99 
                 0.018 
                 No 
                 No 
               
               
                 steel 7 
               
               
                 Invention 
                 3.77 
                 4.54 
                 0.09 
                 4.78 
                 0.017 
                 No 
                 No 
               
               
                 steel 8 
               
               
                 Invention 
                 3.89 
                 4.12 
                 0.08 
                 4.28 
                 0.016 
                 No 
                 No 
               
               
                 steel 9 
               
               
                 Invention 
                 3.74 
                 4.31 
                 0.03 
                 4.23 
                 0.019 
                 No 
                 No 
               
               
                 steel 10 
               
               
                 Invention 
                 3.87 
                 4.55 
                 0.03 
                 4.38 
                 0.027 
                 No 
                 No 
               
               
                 steel 11 
               
               
                 Invention 
                 5.84 
                 5.90 
                 0.10 
                 5.56 
                 0.021 
                 No 
                 No 
               
               
                 steel 12 
               
               
                 Invention 
                 4.06 
                 5.10 
                 0.12 
                 8.52 
                 0.024 
                 No 
                 No 
               
               
                 steel 13 
               
               
                 Invention 
                 4.25 
                 4.95 
                 0.09 
                 5.68 
                 0.040 
                 No 
                 No 
               
               
                 steel 14 
               
               
                 Invention 
                 4.45 
                 5.12 
                 0.12 
                 5.58 
                 0.045 
                 No 
                 No 
               
               
                 steel 15 
               
               
                 Invention 
                 5.33 
                 5.78 
                 0.12 
                 6.07 
                 0.049 
                 No 
                 No 
               
               
                 steel 16 
               
               
                 Invention 
                 5.64 
                 5.99 
                 0.12 
                 6.87 
                 0.031 
                 No 
                 No 
               
               
                 steel 17 
               
               
                 Invention 
                 4.67 
                 4.78 
                 0.04 
                 5.56 
                 0.021 
                 No 
                 No 
               
               
                 steel 18 
               
               
                 Invention 
                 5.82 
                 5.97 
                 0.08 
                 6.52 
                 0.022 
                 No 
                 No 
               
               
                 steel 19 
               
               
                 Invention 
                 4.25 
                 4.32 
                 0.09 
                 6.05 
                 0.020 
                 No 
                 No 
               
               
                 steel 20 
               
               
                 Invention 
                 4.50 
                 5.12 
                 0.03 
                 7.10 
                 0.017 
                 No 
                 No 
               
               
                 steel 21 
               
               
                 Invention 
                 5.12 
                 5.78 
                 0.06 
                 5.45 
                 0.023 
                 No 
                 No 
               
               
                 steel 22 
               
               
                 Invention 
                 5.75 
                 5.90 
                 0.04 
                 6.10 
                 0.027 
                 No 
                 No 
               
               
                 steel 23 
               
               
                 Invention 
                 4.35 
                 4.44 
                 0.03 
                 5.78 
                 0.017 
                 No 
                 No 
               
               
                 steel 24 
               
               
                 Invention 
                 4.67 
                 4.78 
                 0.02 
                 5.99 
                 0.020 
                 No 
                 No 
               
               
                 steel 25 
               
               
                 Invention 
                 4.89 
                 5.12 
                 0.05 
                 6.00 
                 0.019 
                 No 
                 No 
               
               
                 steel 26 
               
               
                 Invention 
                 5.01 
                 5.09 
                 0.03 
                 5.79 
                 0.021 
                 No 
                 No 
               
               
                 steel 27 
               
               
                 Comparative 
                 8.5 
                 25.78 
                 0.16 
                 5 
                 2.135 
                 0.505 
                 0.005 
               
               
                 steel 
               
               
                   
               
            
           
         
       
     
     As shown in Table 3, the contact resistance of the stainless steel for the separator according to the embodiment of the present invention, obtained by exposing an invention steel subjected to chemical surface reforming treatment at a temperature of 200° C. for 20 minutes under an air atmosphere, is measured at a contact pressure of 140 N/cm 2 . As a result, the stainless steel has a low contact resistance of 10 mΩcm 2  as compared with the comparative steel. The contact resistance measured after performing the polarization experiment is lower than that of the comparative steel. The corrosion current density measured after performing the polarization experiment also has a low value of 0.12 μA/cm 2 . As the result obtained by measuring elution ions, only Fe elution ions of 0.05 mg/L or less are detected in the stainless steel as compared with the comparative steel. Particularly, although Mo was used as an essential element in the conventional patent, the invention steel to which the Mo is not added shows excellent contact resistance and elution resistance in the present invention. As an example, it can be seen that the invention steels 18, 19, 20, 22 and 23 have excellent contact resistance and corrosion resistance in the present invention. 
     According to the embodiment of the present invention, an X-ray photoelectron microscopy (XPS) analysis is performed on the second passive film obtained by performing two-step chemical surface reforming under the aforementioned surface roughness condition and then performing the potentiostatic polarization test. 
       FIGS. 6A to 6C  are graphs showing examples of performing an X-ray photoelectron microscopy analysis on composition distributions of first and second passive films in an initial period, after performing a surface reforming treatment and after performing a potentiostatic polarization test according to embodiments of Table 2. 
     Referring to  FIGS. 6A to 6C , the thickness of the initial first passive film is about 5.5 nm, and the thickness of the second passive film produced after performing the two-step chemical surface reforming is about 2.2 nm. It can be seen that the thickness of the second passive film after performing the potentiostatic polarization test is about 2.3 nm, which is hardly different from the thickness of the second passive film produced after performing the two-step chemical surface reforming. Particularly, the thickness of the second passive film after performing the chemical surface reforming on the invention steel in Table 3 was measured within the range from 2 to 3.5 nm. 
       FIGS. 7A to 7C  are graphs showing Cr/Fe oxide distributions in the first and second passive films in the initial period, after performing the surface reforming treatment and after performing the potentiostatic polarization test according to the embodiments of Table 2. 
     Referring to  FIGS. 7A to 7C , it can be seen that in addition to a decrease in thickness, the Cr/Fe oxide ratio in the second passive film after performing a surface reforming treatment and then performing a potentiostatic polarization test secures 1.5 or more in a region of 1 nm, as compared with the Cr/Fe oxide ratio in the initial first passive film. Particularly, it can be seen that the Cr/Fe oxide ratio after performing the chemical surface reforming on the invention steel in Table 3 secures 1.5 or more in a region of less than 1.5 nm. 
       FIG. 8  is a graph showing a Cr(OH) 3 /Cr oxide distribution in the first and second passive films in the initial period, after performing the surface reforming treatment and after performing the potentiostatic polarization test according to the embodiments of Table 2. 
     As shown in  FIG. 8 , it can be seen that the Cr(OH) 3 /Cr oxide distribution in the second passive film after performing the two-step surface reforming and then performing the potentiostatic polarization test has a ratio of 0 to 0.52 in a region of less than 1 nm as compared with the Cr(OH) 3 /Cr oxide ratio of the initial first air-formed film within a region in which the thickness of the passive film is less than 1 nm. Particularly, it can be seen that the Cr(OH) 3 /Cr oxide distribution after performing the two-step chemical surface reforming on the invention steel in Table 3 has a ratio of 0 to 0.7 in a region of less than 1 nm. 
     From the aforementioned experiment, it can be seen that the initial surface roughness acts as a primary factor for setting conditions such as processing time in the two-step surface reforming including a pickling process of removing the first passive film in the sulfuric acid solution of the stainless steel with the composition range of the present invention and a passivation treatment process of forming the second passive film in the mixed solution of the nitric acid and the fluorine acid after water-washing. The thickness of the second passive film of the stainless steel processed by the two-step chemical surface reforming is formed in the range from 2 to 4.5 nm. Further, it can be seen that the Cr/Fe oxide ratio is 1.5 or more in a region of less than 1.5 nm, and it is possible to ensure a stainless steel having excellent contact resistance and corrosion resistance when the Cr(OH) 3 /Cr oxide distribution has a ratio of 0 to 0.7 in a region of less than 1 nm. 
       FIGS. 9A to 9C  are graphs showing performance estimation results measured by preparing stainless separators formed by performing an optimum two-step surface reforming treatment on invention steels 9 and 12 in Table 3 and then assembling the prepared stainless separator in a polymer fuel cell unit cell. 
     Referring to  FIGS. 9A to 9C , the operating temperature of the fuel cell was maintained as 70, and the entire pressure of reactive gas was maintained as 1 atmospheric pressure. The amounts of hydrogen and oxygen supplied to an anode and a cathode were measured by supplying 1.5 of the amount of electrochemically consumed hydrogen and 2 of the amount of electrochemically consumed oxygen, respectively. A membrane electrode assembly (produced by Gore Co.) was used as the used membrane electrode assembly was used. In the long-term measurement, the voltage of a unit cell was measured under a standard condition while maintaining the current density to 0.7 mA/cm 2  (17.5 A). 
     As shown in  FIG. 9A , the initial performance shows a performance result almost similar to that of a graphite material. As shown in  FIG. 9B , the ohmic resistance and the polarization resistance are almost similar to or partially lower than those of the graphite material in the impedance analysis result. Referring to  FIG. 9C , in terms of the long-term performance measured for 600 hours, the open circuit voltage (OCV) is maintained constant, and the voltage drop at a constant current density of 0.7 mA/cm 2  (17.5 A) is identical to or partially higher than that of the graphite material. 
     That is, according to the embodiments of the invention steel, surface reforming conditions are set so that it is possible to control the removal of the passive film of the stainless steel and the repassivation treatment of the stainless steel. Thus, the stainless steel can secure low interfacial contact resistance and achieve excellent corrosion resistance with reduced elution resistance. Accordingly, it is possible to produce a stainless steel having excellent long-term performance of the polymer fuel cell. 
     In the aforementioned embodiment, the polymer fuel cell separator has been illustrated as an example. However, it will be apparent that the present invention may be applied to other various fuel cell separators. 
     While the present invention has been described in connection with certain exemplary embodiments, it is to be understood that the invention is not limited to the disclosed embodiments, but, on the contrary, is intended to cover various modifications and equivalent arrangements included within the spirit and scope of the appended claims, and equivalents thereof.