Patent Publication Number: US-2015076478-A1

Title: Luminescence device and display apparatus

Description:
This application is a division of Ser. No. 11/694,754, filed Mar. 30, 2007, which is a division of Ser. No. 11/329,181, filed Jan. 11, 2006, which is a division of application Ser. No. 10/073,012, filed Feb. 12, 2002, now U.S. Pat. No. 7,147,935, which is a continuation of International Application PCT/JP01/10487, filed Nov. 30, 2001. All prior applications are incorporated herein by reference. 
    
    
     TECHNICAL FIELD 
     The present invention relates to an organic luminescence device (also called an organic electroluminescence device or an organic EL device) for use in a planar light source, a planar display, and the like. Particularly, the present invention relates to a novel metal coordination compound and a luminescence device having a high luminescence efficiency and undergoing little change with time by using a metal coordination compound of a specific structure. 
     BACKGROUND ART 
     An example of a conventional organic luminescence device is e.g., one using luminescence of a vacuum-deposited anthracene film (Thin Solid Films, 94 (1982) 171). Recently, however, in view of the advantages, such as ease of providing a large-area device compared with an inorganic luminescence device, and a possibility of realizing desired luminescence colors due to the development of various new materials and drivability at low voltages, extensive studies thereof for the production of high-speed responsive and high efficiency luminescence devices have been conducted. 
     As precisely described in Macromol. Symp. 125, 1-48 (1997), for example, an organic EL device generally has an organization comprising a pair of upper and lower electrodes formed on a transparent substrate, and organic material layers including a luminescence layer disposed between the electrodes. 
     In the luminescence layer, aluminum quinolinol complexes (inclusive of Alq3 shown hereinafter as a representative example) having an electron-transporting characteristic and a luminescence characteristic, are used for example. In a hole-transporting layer, a material having an electron-donative property, such as a triphenyldiamine derivative (inclusive of α-NPD shown hereinafter as a representative example), is used for example. 
     Such a device shows a current-rectifying characteristic such that when an electric field is applied between the electrodes, holes are injected from the anode and electrons are injected from the cathode. 
     The injected holes and electrons are recombined in the luminescence layer to form excitons, which emit luminescence when they are transitioned to the ground state. 
     In this process, the excited states include a singlet state and a triplet state and a transition from the former to the ground state is called fluorescence and a transition from the latter is called phosphorescence. Materials in theses states are called singlet excitons and triplet excitons, respectively. 
     In most of the organic luminescence devices studied heretofore, fluorescence caused by the transition of a singlet exciton to the ground state, has been utilized. On the other hand, in recent years, devices utilizing phosphorescence via triplet excitons have been studied. 
     Representative published literature may include:
     Article 1: Improved energy transfer in electrophosphorescent device (D. F. O&#39;Brien, et al., Applied Physics Letters, Vol. 74, No. 3, p. 422 (1999)); and   Article 2: Very high-efficiency green organic light-emitting devices based on electrophosphorescence (M. A. Baldo, et al., Applied Physics Letters, Vol. 75, No. 1, p. 4 (1999)).   

     In these articles, a structure including four organic layers sandwiched between the electrodes, and the materials used therein include carrier-transporting materials and phosphorescent materials, of which the names and structures are shown below together with their abbreviations. 
     Alq3: aluminum quinolinol complex 
     α-NPD: N4,N4′-di-naphthalene-1-yl-N4,N4′-diphenyl-biphenyl-4,4′-diamine 
     CBP: 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline 
     PtOEP: platinum-octaethylporphyrin complex 
     Ir(ppy) 3 : iridium-phenylpyridine complex 
     
       
         
         
             
             
         
       
     
     The above-mentioned Articles 1 and 2 both have reported structures, as exhibiting a high efficiency, including a hole-transporting layer comprising α-NPD, an electron-transporting layer comprising Alq3, an exciton diffusion-preventing layer comprising BCP, and a luminescence layer comprising CBP as a host and ca. 6% of PtOEP or Ir(ppy) 3  as a phosphorescent material dispersed in mixture therein. 
     Such a phosphorescent material is particularly noted at present because it is expected to provide a high luminescence efficiency in principle for the following reasons. More specifically, excitons formed by carrier recombination comprise singlet excitons and triplet excitons in a probability ratio of 1:3. Conventional organic EL devices have utilized fluorescence of which the luminescence efficiency is limited to at most 25%. On the other hand, if phosphorescence generated from triplet excitons is utilized, an efficiency of at least three times is expected, and even an efficiency of 100%, i.e., four times, can be expected in principle, if a transition owing to intersystem crossing from a singlet state having a higher energy to a triplet state is taken into account. 
     However, like a fluorescent-type device, such an organic luminescence device utilizing phosphorescence is generally required to be further improved regarding the deterioration of luminescence efficiency and device stability. 
     The reason of the deterioration has not been fully clarified, but the present inventors consider as follows based on the mechanism of phosphorescence. 
     In the case where the luminescence layer comprises a host material having a carrier-transporting function and a phosphorescent guest material, a process of phosphorescence via triplet excitons may include unit processes as follows: 
     1. transportation of electrons and holes within a luminescence layer, 
     2. formation of host excitons; 
     3. excitation energy transfer between host molecules, 
     4. excitation energy transfer from the host to the guest, 
     5. formation of guest triplet excitons, and 
     6. transition of the guest triplet excitons to the ground state and phosphorescence. 
     Desirable energy transfer in each unit process and luminescence are caused in competition with various energy deactivation processes. 
     Needless to say, a luminescence efficiency of an organic luminescence device is increased by increasing the luminescence quantum yield of a luminescence center material. 
     Particularly, in a phosphorescent material, this may be attributable to a life of the triplet excitons which is longer by three or more digits than the life of a singlet exciton. More specifically, because it is held in a high-energy excited state for a longer period, it is liable to react with surrounding materials and cause polymer formation among the excitons, thus incurring a higher probability of deactivation process resulting in a material change or life deterioration. 
     Further, in view of the formation of a full-color display device, luminescence materials providing luminescence colors which are as close as possible to pure three primary colors of blue, green and red, are desired, but there have been few luminescence materials giving a luminescence, color of pure red, so that the realization of a good full-color display device has been restricted. 
     DISCLOSURE OF INVENTION 
     Accordingly, a principal object of the present invention is to provide a compound capable of high efficiency luminescence and showing a high stability as a luminescent material for use in a Phosphorescent luminescence device. Particularly, it is an object to provide a luminescence material compound which is less liable to cause energy deactivation in a long life of excited energy state and is also chemically stable, thus providing a longer device life. A further object of the present invention is to provide a red luminescence material compound capable of emitting pure red suitable for forming a full-color display device. 
     Inclusively, principal objects of the present invention are to provide a luminescence material which exhibits a high luminescence efficiency, retains a high luminance for a long period and is capable of red luminescence based on phosphorescent luminescence materials, and also provide a luminescence device and a display apparatus using the same. 
     In the present invention, a metal complex is used as a luminescence material, particularly a novel luminescent metal complex compound comprising iridium as a center metal and an isoquinolyl group as a ligand. 
     More specifically, the present invention uses as a luminescence material a metal coordination compound having at least one partial structure represented by formula (1) below: 
       ML  (1),
 
     wherein the partial structure ML is represented by formula (2) below: 
     
       
         
         
             
             
         
       
     
     wherein M is a metal atom of Ir, Pt, Rh or Pd; N and C are nitrogen and carbon atoms, respectively; A is a cyclic group capable of having a substituent, including the carbon atom and bonded to the metal atom M via the carbon atom; B is an isoquinolyl group capable of having a substituent, including the nitrogen atom and bonded to the metal atom M via the nitrogen atom, with the proviso that one or two of CH groups forming the isoquinolyl group can be replaced with a nitrogen atom and the cyclic group A is coordination-bonded to a position-1 carbon atom of the isoquinolyl group. 
     More specifically, the present invention uses a metal coordination compound having an entire structure represented by formula (3) below: 
       ML m L′ n   (3),
 
     wherein M is a metal atom of Ir, Pt, Rh or Pd; L and L′ are mutually different bidentate ligands; m is 1, 2 or 3, and n is 0, 1 or 2 with the proviso that m+n is 0.2 or 3; a partial structure ML′ n  is represented by formula (4), (5) or (6) shown below: 
     
       
         
         
             
             
         
       
     
     The present invention also uses as a luminescence material, a metal coordination compound which is entirely represented by formula (7) below: 
     
       
         
         
             
             
         
       
     
     wherein Cl denotes a chlorine atom, M′ denotes iridium Ir or rhodium Rh, and m′ is 2. 
     The present invention also provides high-performance organic luminescence device and display apparatus using the above-mentioned novel metal coordination compound as an organic luminescence material. 
     Preferred embodiments of the present invention include the following: 
     A metal coordination compound, wherein n is 0 in the above formula (3). 
     A metal coordination compound, wherein the cyclic groups A and A′ are independently selected from phenyl group, naphthyl group, thienyl group, fluorenyl group, thianaphthyl group, acenaphthyl group, anthranyl group, phenanthrenyl group, pyrenyl group, or carbazolyl group, as an aromatic cyclic group capable of having a substituent with the proviso that the aromatic cyclic group can include one or two CH groups that can be replaced with a nitrogen atom. 
     A metal coordination compound, wherein the cyclic groups A and A′ are selected from phenyl group, 2-naphthyl group, 2-thienyl group, 2-fluorenyl group, 2-thianaphthyl group, 2-anthranyl group, 2-phenanthrenyl group, 2-pyrenyl group, or 3-carbazolyl group, as an aromatic cyclic group capable of having a substituent with the proviso that the aromatic cyclic group can include one or two CH groups that can be replaced with a nitrogen atom. 
     A metal coordination compound, wherein the aromatic cyclic group is phenyl group capable of having a substituent. 
     A metal coordination compound, wherein a hydrogen atom is attached to a position-6 carbon atom of the phenyl group capable of having a substituent next to a position-1 carbon atom bonded to the cyclic group B. 
     A metal coordination compound, wherein the cyclic groups 8′ and B″ are independently selected from isoquinolyl group, quinolyl group, 2-azaanthranyl group, phenanthridinyl group, pyridyl group, oxazolyl group, thiazolyl group, bensoxazolyl group, or benzthiazolyl group, as an aromatic cyclic group capable of having a substituent with the proviso that the aromatic cyclic group can include one or two CH groups that can be replaced with a nitrogen atom. 
     A metal coordination compound, wherein the cyclic groups B′ and B″ are selected from isoquinolyl group or pyridyl group, as an aromatic cyclic group capable of having a substituent with the proviso that the aromatic cyclic group can include one or two CH groups that can be replaced with a nitrogen atom. 
     A metal coordination compound, wherein the cyclic group B′ in the formula (4) is isoquinolyl group capable of having a substituent. 
     A metal coordination compound, wherein the cyclic groups A, A′, B, B′ and B″ are independently non-substituted, or have a substituent selected from a halogen atom or a linear or branched alkyl group having 1 to 20 carbon atoms {of which the alkyl group can include one or non-neighboring two or more methylene groups that can be replaced with —O—, —S—, —CO—, —CO—O—, —O—CO—, —CH═CH—, —C≡C—, or a divalent aromatic group capable of having a substituent (that is a halogen atom, or a linear or branched alkyl group having 1 to 20 carbon atoms (of which the alkyl group can include one or non-neighboring two or more methylene groups that can be replaced with —O—, and the alkyl group can include a hydrogen atom that can be optionally replaced with a fluorine atom)), and the alkyl group can include a hydrogen atom that can be optionally replaced with a fluorine atom). 
     A metal coordination compound, wherein the cyclic group A in the formula (7) is selected from phenyl group, naphthyl group, thienyl group, fluorenyl group, thianaphthyl group, acenaphthyl group, anthranyl group, phenanthrenyl group, pyrenyl group, or carbazolyl group, as an aromatic cyclic group capable of having a substituent with the proviso that the aromatic cyclic group can include one or two CH groups that can be replaced with a nitrogen atom. 
     A metal coordination compound, wherein the aromatic cyclic group is selected from phenyl group, 2-naphthyl group, 2-thienyl group, 2-fluorenyl group, 2-thianaphthyl group, 2-anthranyl group, 2-phenanthrenyl group, 2-pyrenyl group or 3-carbazolyl group, each capable of having a substituent with the proviso that the aromatic cyclic group can include one or two CH groups that can be replaced with a nitrogen atom. 
     A metal coordination compound, wherein the aromatic cyclic group is phenyl group capable of having a substituent. 
     A metal coordination compound, wherein a hydrogen atom is attached to a position-6 carbon atom of the phenyl group capable of having a substituent next to a position-1 carbon atom bonded to the cyclic group B. 
     A metal coordination compound, wherein the cyclic groups A and B in the formula (7) are independently non-substituted, or have a substituent selected from a halogen atom or a linear or branched alkyl group having 1 to 20 carbon atoms (of which the alkyl group can include one or non-neighboring two or more methylene groups that can be replaced with —O—, —S—, —CO—, —CO—O—, —O—CO—, —CH═CH—, —C≡C—, or a divalent aromatic group capable of having a substituent (that is a halogen atom, a cyano atom, a nitro atom, a trialkylsilyl group (of which the alkyl groups are independently a linear or branched alkyl group), a linear or branched alkyl group having 1 to 20 carbon atoms (of which the alkyl group can include one or non-neighboring two or more methylene groups that can be replaced with —O—, and the alkyl group can include a hydrogen atom that can be optionally replaced with a fluorine atom)), and the alkyl group can include a hydrogen atom that can be optionally replaced with a fluorine atom}. 
     A metal coordination compound, wherein M in the formula (1) is iridium. 
     A metal coordination compound, wherein M in the formula (7) is iridium. 
     A metal coordination compound, having a partial structure ML represented by the formula (2) and represented by formula (8) below: 
       Ir[Rp-Ph-IsoQ-R′q] 3   (8),
 
     wherein Ir is iridium; partial structure Ph-IsoQ denotes 1-phenylisoquinolyl group; substituents R and R′ are selected from hydrogen, fluorine or a linear or branched alkyl group represented by C n H 2n+1  (wherein H can be replaced with F, a non-adjacent methylene group can be replaced with oxygen and n is an integer of 1 to 20), p and q are integers of at least 1 representing numbers of the substituents R and R′ bonded to the phenyl group and the isoquinolyl group, respectively, wherein a position-2 carbon atom of the phenyl group and a nitrogen atom of IsoQ are coordination-bonded to Ir. 
     A metal coordination compound, wherein the partial structure Rp-Ph is 4-alkylphenyl group in the formula (8), and the substituent R′ is hydrogen. 
     A metal coordination compound, wherein in the formula (8), the substituent R is hydrogen, and R′q represents a fluoro or trifluoromethyl group substituted at a 4- or 5-position. 
     A metal coordination compound, wherein in the formula (8), the partial structure Rp-Ph- is 5-fluorophenyl group, and R′q is a hydrogen atom or a fluorine atom or trifluoromethyl group substituted at a 4- or 5-position. 
     A metal coordination compound, wherein in the formula (8), the partial structure Rp-Ph- is 4-fluorophenyl group, and R′q is a hydrogen atom or a fluorine atom or trifluoromethyl group substituted at a 4- or 5-position. 
     A metal coordination compound, wherein in the formula (8), the partial structure Rp-Ph- is 3,5-difluorophenyl group, and R′q is a hydrogen atom or fluorine atom or trifluoromethyl group substituted at a 4- or 5-position. 
     A metal coordination compound, wherein in the formula (8), the partial structure Rp-Ph- is 3,4,5-trifluorophenyl group, and R′q is a hydrogen atom or a fluorine atom or trifluoromethyl group substituted at a 4- or 5-position. 
     A metal coordination compound, wherein in the formula (8), the partial structure Rp-Ph- is 4-trifluoromethylphenyl group, and R′q is a hydrogen atom or a fluorine atom or trifluoromethyl group substituted at a 4- or 5-position. 
     A metal coordination compound, wherein in the formula (8), the partial structure £p-Ph- is 5-trifluoromethylphenyl group, and R′q is a hydrogen atom or a fluorine atom or trifluoromethyl group substituted at a 4- or 5-position. 
     A metal coordination compound, wherein in the formula (8), the structure Rp-Ph is a 1-(3,4,5,6-tetrafluorophenyl) group, and in R′q is 1 or 6 and R′ is a hydrogen atom, a trifluoromethyl group substituted at a 4- or 5-position or such that IsoQ-R′q is a 3,4,5,6,7,8-hexafluoroisoquinoline group. 
     A metal coordination compound, wherein in the formula (8), the partial structure Rp-Ph- is 4-alkylphenyl group (wherein the alkyl group is a linear or branched alkyl group having 1 to 6 carbon atoms), and R′g is hydrogen. 
     A metal coordination compound, wherein in the formula (8), the partial structure Rp-Ph- is 4-alkoxyphenyl group (wherein the alkoxy group is a linear or branched alkoxy group having 1 to 6 carbon atoms), and R′q is hydrogen. 
     A metal coordination compound, wherein in the formula (8), the partial structure Rp-Ph- is a 4-trifluoromethyloxyphenyl group, and R′q is a hydrogen or fluoro group or trifluoromethyl group substituted at a 4- or 5-position. 
     A metal coordination compound, which is represented by the formula (3) and is also represented by formula (9) below: 
       IrL m L′ n   (9),
 
     wherein Ir represents iridium. 
     A metal coordination compound, represented by the formula (9), wherein L m  is represented by a formula of [4-alkylphenylisoquinoline] 2  (wherein the alkyl group is represented by C n H 2n+1  and n is an integer of 1 to 8), and L′ n  is 1-phenylisoquinoline. 
     A metal coordination compound, represented by the formula (9), wherein L m  is represented by a formula [1-phenylisoquinoline] 2 , and L′ n  is 4-alkylphenylisoquinoline (wherein the alkyl group has 1 to 8 carbon atoms). 
     A metal coordination compound, wherein one or two CH groups in the isoquinolyl group capable of having a substituent in the formula (1) are replaced with a nitrogen atom. 
     A metal coordination compound, wherein one or two CH groups in the isoquinolyl group capable of having a substituent in the formula (7) are replaced with a nitrogen atom. 
     An organic luminescence device, comprising: a pair of electrodes disposed on a substrate, and a luminescence unit comprising at least one organic compound disposed between the electrodes, wherein the organic compound comprises a metal coordination compound having at least one partial structure represented by the formula (1) in claim  1 . 
     An organic luminescence device, wherein the organic compound comprises a metal coordination compound having a structure represented by the formula (3). 
     An organic luminescence device, wherein the organic compound comprises a metal coordination compound having a structure represented by the formula (8). 
     An organic luminescence device, wherein the organic compound comprises a metal coordination compound having a structure represented by the formula (9). 
     An organic luminescence device, wherein a voltage is applied between the electrodes to emit phosphorescence. 
     An organic luminescence device, wherein the phosphorescence is red in luminescence color. 
     A picture display apparatus, comprising the above-mentioned organic luminescence device, and a means for supplying electric signals to the organic luminescence device. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1  illustrates embodiments of the luminescence device according to the present invention. 
         FIG. 2  illustrates a simple matrix-type organic EL device according to Example 8. 
         FIG. 3  illustrates drive signals used in Example 8. 
         FIG. 4  schematically illustrates a panel structure including an EL device and drive means. 
         FIG. 5  is a graph showing voltage-efficiency luminance characteristics of a device of Example 27. 
         FIG. 6  is a graph showing external Quantum efficiency of a device of Example 27. 
         FIG. 7  shows a  1 H-NMR spectrum of a solution in heavy chloroform of 1-phenylisoquinoline. 
         FIG. 8  shows a  1 H-NMR spectrum of a solution in heavy chloroform of tris(1-phenylisoquinoline-C 2 ,N)iridium (III). 
         FIG. 9  shows a  1 H-NMR spectrum of a solution in heavy chloroform of 1-(4-methylphenyl)-isoquinoline. 
         FIG. 10  shows a  1 H-NMR spectrum of a solution in heavy chloroform of tetrakis[1-4-methylphenyl)isoquinoline-C 2 ,N](μ-dichloro)-diiridium (III). 
         FIG. 11  shows a  1 H-NMR spectrum of a solution in heavy chloroform of bis[1-(4-methylphenyl)isoquinoline-C 2 ,N](acetylacetonato)-iridium (III). 
         FIG. 12  shows a  1 H-NMR spectrum of a solution in heavy chloroform of tris[1-(4-methylphenyl)isoquinoline-C 2 ,N]iridium (III). 
         FIG. 13  shows a  1 H-NMR spectrum of a solution in heavy chloroform of bis[1-(4-n-octylphenyl)isoquinoline-C 2 ,N](acetylacetonato)-iridium (III). 
     
    
    
     BEST MODE FOR PRACTICING THE INVENTION 
     Basic structures of organic EL devices formed according to the present invention are illustrated in  FIGS. 1(   a ), ( b ) and ( c ). 
     As shown in  FIG. 1 , an organic luminescence device generally comprises, on a transparent electrode  15 , a 50 to 200 nm-thick transparent electrode  14 , a plurality of organic film layers and a metal electrode  11  formed so as to sandwich the organic layers. 
       FIG. 1(   a ) shows an embodiment wherein the organic luminescence device comprises a luminescence layer  12  and a hole-transporting layer  13 . The transparent electrode  14  may comprise ITO, etc., having a large work function so as to facilitate hole injection from the transparent electrode  14  to the hole-transporting layer  13 . The metal electrode  11  comprises a metal material having a small work function, such as aluminum, magnesium or alloys of these elements, so as to facilitate electron injection into the organic luminescence device. 
     The luminescence layer  12  comprises a compound according to the present invention. The hole-transporting layer  13  may comprise, e.g., a triphenyldiamine derivative, as represented by α-NPD mentioned above, and also a material having an electron-donative property as desired. 
     A device organized above exhibits a current-rectifying characteristic, and when an electric field is applied between the metal electrode  11  as a cathode and the transparent electrode  14  as an anode, electrons are injected from the metal electrode  11  into the luminescence layer  12 , and holes are injected from the transparent electrode  15 . The injected holes and electrons are recombined in the luminescence layer  12  to form excitons, which cause luminescence. In this instance, the hole-transporting layer  13  functions as an electron-blocking layer to increase the recombination efficiency at the boundary between the luminescence layer  12  and the hole-transporting layer  13 , thereby providing an enhanced luminescence efficiency. 
     Further, in the structure of  FIG. 1(   b ), an electron-transporting layer  16  is disposed between the metal electrode  11  and the luminescence layer  12  in  FIG. 1(   a ). As a result, the luminescence function is separated from the functions of electron transportation and hole transportation to provide a structure exhibiting more effective carrier blocking, thus increasing the luminescence efficiency. The electron-transporting layer  16 , may comprise, e.g., an oxadiazole derivative. 
       FIG. 1(   c ) shows another desirable form of a four-layer structure, including a hole-transporting layer  13 , a luminescence layer  12 , an exciton diffusion prevention layer  17  and an electron-transporting layer  16 , successively from the side of the transparent electrode  14  as the anode. 
     The luminescence materials used in the present invention are most suitably metal coordination compounds represented by the above-mentioned formulae (1) to (9), which are found to cause high-efficiency luminescence in a red region around 600 mn, retain high luminance for a long period and show little deterioration by current passage. 
     The metal coordination compound used in the present invention emits phosphorescence, and its lowest excited state is believed to be an MLCT* (metal-to-ligand charge transfer) excited state or π-π* excited state in a triplet state, and phosphorescence is caused at the time of transition from such a state to the ground state. 
     &lt;&lt;Measurement Methods&gt;&gt; 
     Hereinbelow, methods for measurement of some properties and physical values described herein for characterizing the luminescence material of the present invention will be described. 
     (1) Judgment between phosphorescence and fluorescence 
     The identification of phosphorescence was effected depending on whether deactivation with oxygen was caused or not. A solution of a sample compound in chloroform after aeration with oxygen or with nitrogen is subjected to photoillumination to cause photo-luminescence. The luminescence is judged to be phosphorescence if almost no luminescence attributable to the compound is observed with respect to the solution aerated with oxygen but photo-luminescence is confirmed with respect to the solution aerated with nitrogen. In contrast thereto, in the case of fluorescence, luminescence attributable to the compound does not disappear even with respect to the solution aerated with oxygen. The phosphorescence of all the compounds of the present invention has been confirmed by this method unless otherwise noted specifically. 
     (2) Phosphorescence yield (a relative quantum yield, i.e., a ratio of an objective sample&#39;s quantum yield Φ(sample) to a standard sample&#39;s quantum yield Φ(st)) is determined according to the following formula: 
       Φ(sample)/Φ( st )=[Sem(sample)/ Iabs (sample)]/[Sem( st )/ Iabs ( st )],
 
     wherein Iabs(st) denotes an absorption coefficient at an excitation wavelength of the standard sample; Sem(st), a luminescence spectral areal intensity when excited at the same wavelength: Iabs(sample), an absorption coefficient at an excitation wavelength of an objective compound; and Sem(sample), a luminescence spectral areal intensity when excited at the same wavelength. 
     Phosphorescence yield values described herein are relative values with respect a phosphorescence yield Φ=1 of Ir(ppy) 3  as a standard sample. 
     (3) A method of measurement of phosphorescence life is as follows. 
     A sample compound is dissolved in chloroform and spin-coated onto a quartz substrate in a thickness of ca. 0.1 μm and is exposed to pulsative nitrogen laser light at an excitation wavelength of 337 nm at room temperature by using a luminescence life meter (made by Hamamatsu Photonics K.K.). After completion of the excitation pulses, the decay characteristic of luminescence intensity is measured. 
     When an initial luminescence intensity is denoted by I 0 , a luminescence intensity after t(sec) is expressed according to the following formula with reference to a luminescence life t(sec): 
         I=I   0 ·exp(− t /τ).
 
     Thus, the luminescence life τ is a time period in which the luminescence intensity I is attenuated down to 1/e of the initial intensity I (I/I 0 =e −1 , e is a base of natural logarithm). A luminescence life of 80 nsec or longer, particularly 100 nsec or longer, is a second condition to be judged as phosphorescence, whereas fluorescence shows a shorter luminescence life on the order of several tens nsec or shorter. 
     The luminescence material exhibited high phosphorescence quantum yields of 0.15 to 0.9 and short phosphorescence lives of 0.1 to 10 μsec. A short phosphorescence life becomes a condition for causing little energy deactivation and exhibiting an enhanced luminescence efficiency. More specifically if the phosphorescence life is long, the number of triplet state molecules maintained for luminescence is increased, and the deactivation process is liable to occur, thus resulting in a lower luminescence efficiency particularly at the time of a high-current density. The material of the present invention has a relatively short phosphorescence life thus exhibiting a high phosphorescence quantum yield, and is therefore suitable as a luminescence material for an EL device. The present inventors further consider that the improved performance is attributable to the following. 
     A difference between a photo-absorption spectrum peak wavelength caused by transition from a single ground state to an excited triplet state and a maximum peak wavelength of luminescence spectrum is generally called a Stokes&#39; shift. The difference in peak wavelength is considered to be caused by a change in energy state of triplet excitons affected by other ground state energy levels. The change in energy state is associated with the Stokes&#39; shift, and a larger amount of the shift generally results in a lowering in maximum luminescence intensity and a broadening of luminescence spectrum leading to a deterioration in monochromaticity of luminescence color. This effect appears particularly remarkably in a red region having a short transition width from the singlet to the triplet. 
     For example, as for the isoquinoline-type iridium complexes of the present invention, tris(1-phenylisoquinoline-C 2 ,N)iridium (III) (Example Compound No. 1 in Tables 1 to 23 appearing hereafter; abbreviated as Ir(PiQ) 3 ), tris[1-(2-thienyl)-isoquinoline-C 3 ,N]iridium (III) (Example Compound No. 24, abbreviated as Ir(tiQ) 3 ), and tris[1-(9,9-dimethylfluorene-2-yl)isoquinoline-C 3 ,N]iridium (III) (Example Compound 28, abbreviated as Ir(FliQ) 3 ) exhibited Stokes&#39; shifts of 37 nm, 55 nm and 33 nm, respectively, and relative quantum yields of 0.66, 0.43 and 0.48, respectively. 
     On the other hand, as for non-isoquinoline-type red luminescence materials, tris[1-thianaphthene-2-yl)pyridine-C 3 ,N]iridium (III) (abbreviated as Ir(BrP) 3 ) and tris(1-(thianaphthene-2-yl)-4-trifluoromethylpyridine (abbreviated as Ir(Bt 5 CF 3 Py) 3 ) exhibited remarkably longer Stokes&#39; shifts of 132 nm and 85 nm, respectively, and lower relative quantum yields of 0.29 and 0.12, respectively, compared with the compounds of the present invention. 
     Even such non-isoquinoline-type red luminescence materials show high quantum yields not achieved by conventional materials, red luminescence materials showing a smaller Stokes&#39; shift, like isoquinoline-type iridium complexes of the present invention, are found to have a tendency of having a still higher quantum yield. A smaller Stokes&#39; shift is considered to provide a larger velocity constant of energy radiation, a shorter phosphorescence life and therefore a higher luminescence efficiency. Based on the above consideration, the introduction of isoquinoline is considered to result in a small Stokes&#39; shift, an enhanced luminescence quantum yield and a better chromaticity. 
     &lt;&lt;Nomenclature and Structural Expression of Compounds&gt;&gt; 
     Now, some explanation is added to the manner of structural identification of a metal coordination compound of the present invention and the manner of allotting atomic position number as a basis therefor with reference to Ir(PiQ) 3  (Example Compound No. 1), for example. The metal coordination compound has a ligand of 1-phenylisoquinoline of which position numbers are allotted as follows: 
     
       
         
         
             
             
         
       
     
     Accordingly, Ir(PiQ) 3  formed by coordination of three 1-phenylisoquinoline molecules, onto iridium with the position-2 carbon atom of the phenyl group and the nitrogen atom of the isoquinoline ring is named as tris(1-phenylisoquinoline-C 2 ,N)iridium (III). 
     Ir(PiQ) 3  exhibits a high quantum yield as mentioned above, but it has been also found that Ir(PiQ) 3  provided with an additional substituent shows a further higher quantum yield in a solution or a solid state film. For example, a class of tris[1-alkylphenyl)isoquinoline-C 2 ,N]iridium (III) formed by attaching alkyl substituents at position-4 of the basic ligand skeleton of 1-phenylisoquinoline exhibits still higher relative quantum yields (i.e., quantum yields when Ir(ppy) 3  in a dilute solution in toluene is taken to have a quantum yield of 1). More specifically, the class of compounds have been found to exhibit quantum yields as shown below depending on species of the alkyl substituents. Remarkable increases in quantum yield have been recognized at number of carbon atoms of 4 or more in the subsequent group. 
     (1) —CH 3 =0.64 
     (2) —C(CH 3 ) 3 =0.7 
     (3) —C 4 H 9 =0.82 
     (4) —C 6 H 13 =0.88 
     (5) —C 8 H 17 =0.72 
     From the above results, the addition of a substituent to the above skeleton to weaken the inter-molecular interaction is found to be effective for increasing the luminescence quantum yield. 
     On the other hand, in the case of using resistance heating vacuum deposition using a tungsten boat for device formation, a material having a molecular weight of at most 1000 has been found suitable in view of the device production process characteristic, such as possibility of vacuum deposition at a low current and a high rate. 
     More specifically, the above-mentioned class of alkyl chain-added iridium complexes have a tendency of exhibiting a higher vacuum deposition temperature at the time of device formation. The entire molecular weights of thus-alkyl-substituted Ir(PiQ) 3  derivatives are as follows depending on the species of alkyl substituents as follows. 
     (1) —CH 3 =847 
     (2) —C(CH 3 ) 3 =973 
     (3) —C 4 H 9 =973 
     (4) —C 6 H 13 =1058 
     (5) —C 8 H 17 =1141 
     At the time of resistance heating vacuum deposition at 10 −4  Pa, these materials required necessary currents for vacuum deposition as follows depending on the species of alkyl substituents. 
     (1) —CH 3 =58 amperes 
     (2) —C(CH 3 ) 3 =61 amperes 
     (3) —C 4 H 9 =61 amperes 
     (4) —C 6 H 13 =64 amperes 
     (5) —C 8 H 17 =67 amperes 
     Further, a metal coordination compound having a substituent of fluorine atom or a polyfluorinated alkyl can weaken the intermolecular interaction owing to fluorine atoms to lower the vacuum deposition temperature, and is advantageous in that a metal coordination compound of a larger molecular weight can be used as a luminescence material without impairing the vacuum deposition characteristic. For example, the substitution of a trifluoromethyl group for one methyl group can lower the vacuum deposition temperature by ca. 1° C. while the molecular weight is rather increased thereby. 
     By introducing an isoquinoline skeleton in a metal coordination compound having a structure of a type represented by the above formula (1) or (9), the luminescence wavelength can be adjusted, and it has been found that the metal coordination compound of the present invention wherein the isoquinoline skeleton is bonded to the cyclic group A at its position-1, is unexpectedly advantageous for increasing the luminescence wavelength (i.e., providing red luminescence). 
     On the other hand, while a known compound of tetrakis(2-phenylpyridine-C 2 ,N)(μ-dichloro)diiridium (III) does not provide a substantial luminescence spectrum, a metal coordination compound of the formula (7) having introduced an isoquinoline skeleton has exhibited a strong luminescence spectrum. From this fact, it is understood that a metal coordination compound of the formula (7) is also suited as a luminescence material for an EL device. 
     Further, by introducing an electron-attractive substituent or an electron-donative substituent to the metal coordination compound of the present invention, it is possible to adjust the luminescence wavelength. Further, by introducing a substituent group, such as an alkoxy group or a polyfluoroalkyl group, having a large electronic effect and also a stereo-scopically large bulk volume, it becomes possible to effect both a control of luminescence wavelength and a suppression of density extinction due to inter-molecular interaction. Further, the introduction of a substituent group having little electronic effect but having a stereoscopically large bulk volume, such as an alkyl group, is considered to be able to suppress the density extraction without changing the luminescence wavelength. 
     Further, by replacing one or two CH groups in the isoquinoline ring of a metal coordination compound represented by the formula (1) or (9), the luminescence wavelength can be adjusted without introducing a substituent group. 
     Also from the above viewpoints, the metal coordination compound of the present invention is suited as a luminescence material for an organic EL device. 
     Further, a thermal stability is an important property for an organic material constituting an organic EL device. The thermal stability seriously affects the production stability at the time of device production and device stability during operation under current supply. For preparation of organic EL devices, a process of vacuum deposition, spin coating or ink jetting is contemplated. Particularly, in the vacuum deposition process, an organic material is subjected to high temperature for certain period for vaporizing the organic material by sublimation or evaporation and is deposited onto the substrate. Accordingly, the thermal stability of a component material is very important. 
     Further, also at the time of supplying electricity to the device for causing luminescence, a Joule&#39;s heat is locally generated due to passage of a high current. If a component material has a low thermal stability, the material can cause a device deterioration due to such heat. For example, the above-mentioned Ir(PiQ) 3  and bis(1-phenylisoquinoline-C 2 ,N)(acetylacetonato)iridium (III) (Example Compound No. 42, abbreviated as Ir(PiQ) 2 acac) exhibited decomposition temperatures of 380° C. and 340° C., respectively, under nitrogen flow, thus providing a substantial difference in decomposition temperature. More specifically, under a certain vacuum deposition condition, Ir(PiQ) 3 acac caused an appreciable decomposition in a vacuum deposition chamber, but Ir(PiQ) 3  did not cause appreciable decomposition under the same condition. As a result of measurement of decomposition degree under various conditions of vacuum deposition, Ir(PiQ) 3  acac exhibited lower upper limits in vacuum deposition speed or degree of vacuum in vacuum deposition, thus exhibiting a narrower production margin at the time of mass production. In this way, a material thermal stability seriously affects the productivity. 
     In a comparative test, EL devices were prepared from the above-mentioned two luminescence materials through vacuum deposition under decomposition-free condition and subjected to evaluation of luminance deterioration. As a result, when electricity supply was started to provide an initial luminance of 5000 cd/m 2 , Ir(PiQ) 3  and Ir(PiQ) 2  acac exhibited luminance half-attenuation periods in a ratio of ca. 3:1, so that Ir(PiQ) 3  was substantially stable against electricity supply as represented by a longer luminance half-attenuation period. In this way, the thermal stability of a component material is a factor determining the production stability and performance stability of a device, so that a material having a high thermal stability is desired. 
     It is believed that the ligand of the present invention, as a result of introduction of isoquinoline skeleton, has a rigid molecular structure, so as to suppress the formation of an excitation-associated molecule resulting in thermal deactivation, thus suppressing energy deactivation due to molecular movement. Further, it is also believed that extinction processes are reduced to result in an improved device performance. In an actual current conduction test, the luminescence material of the present invention, i.e., a metal coordination compound having a ligand comprising en isoquinoline skeleton bonded to a cyclic group A at its 1-position, showed a high stability. 
     More specifically, a tris(1-substituted isoquinolyl)-metal coordination compound of n 0 in the formula (3) is generally preferred in view of excellent thermal stability. 
     Accordingly, a luminescence material having a luminescence wavelength of long-wavelength region (red luminescence) and a high chemical stability as well as a high luminescence efficiency has not been realized heretofore but can be realized by the luminescence material of the present invention. 
     A high-efficiency luminescence device having a layer structure as shown in  FIGS. 1(   a ), ( b ) and ( c ) of the present invention is applicable to a product requiring energy economization or a high luminance. More specifically, the luminescence device is applicable to a display apparatus, an illumination apparatus, a printer light source or a backlight for a luminescence layer display apparatus. As for a display apparatus, it allows a flat panel display which is light in weight and provides a highly recognizable display at a low energy consumption. As a printer light source, the luminescence device of the present invention can be used instead of a laser light source of a laser beam printer. For the illumination apparatus or backlight, the energy economization effect according to the present invention can be utilized. 
     For the application to a display, a drive system using a thin-film transistor (abbreviated as TFT) drive circuit according to an active matrix-scheme, may be used. Hereinbelow, an embodiment of using a device of the present invention in combination with an active matrix substrate is briefly described with reference to  FIG. 4 . 
       FIG. 4  illustrates an embodiment of panel structure comprising an EL device and drive means. The panel is provided with a scanning signal driver, a data signal driver and a current supply source which are connected to gate selection lines, data signal lines and current supply lines, respectively. At each intersection of the gate selection lines and the data signal lines, a display pixel electrode is disposed. The scanning signal drive sequentially selects the gate selection lines G1, G2, G3 . . . Gn, and in synchronism herewith, picture signals are supplied from the data signal driver to display a printer. 
     TFT switching devices are not particularly restricted, and devices of a single crystal-silicon substrate, MIM devices or devices of a-Si type can be easily applied. 
     On the ITO electrodes, one or more organic EL layers and a cathode layer are sequentially disposed to provide an organic EL display panel. By driving a display panel including a luminescence layer comprising a luminescence material of the present invention, it becomes possible to provide a display which exhibits a good picture quality and is stable even for a long period display. 
     &lt;&lt;Brief Description of Synthesis Path&gt;&gt; 
     Some synthetic paths for providing a metal coordination compound represented by the above-mentioned formula (1) are illustrated below with reference to an iridium coordination compound for example; 
     
       
         
         
             
             
         
       
     
     Some specific structural examples of metal coordination compounds used in the present invention are shown in Tables 1 to Tables 23 appearing hereinafter, which are however only representative examples and are not exhaustive. Ph to Iq10 shown in Tables 1 to 23 represent partial structures shown below, corresponding to the above-mentioned formula (3) (or partial structures therein represented by formulae (2), and (4)-(6)) or formula (3). Further, R1-R10 represent substituents in the Ph to Iq10, and E, G and J represent substituents in the formula (5). 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
             
               
                 TABLE 1 
               
             
            
               
                   
               
               
                   
                   
                   
                   
                   
                   
                 A 
                 B 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 M 
                 m 
                 n 
                 A 
                 B 
                 R1 
                 R2 
                 R3 
                 R4 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 2 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 3 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 H 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 4 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 5 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 H 
                 CH3 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 H 
                 H 
               
               
                 6 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 H 
                 H 
                 CH3 
                 H 
                 H 
                 CF3 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 7 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 8 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 H 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 9 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 10 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 H 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
             
               
                 TABLE 2 
               
               
                   
               
             
            
               
                   
                   
                   
                   
                   
                   
                 A 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 M 
                 m 
                 n 
                 A 
                 B 
                 R1 
                 R2 
                 R3 
                 R4 
               
               
                   
               
               
                 11 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 H 
                 CF3 
                 H 
                 H 
               
               
                 12 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 H 
                 H 
                 CF3 
                 H 
               
               
                   
               
               
                 13 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
               
               
                   
               
               
                 14 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 H 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
               
               
                   
               
               
                 15 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
               
               
                   
               
               
                 16 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
               
               
                   
               
               
                 17 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 H 
                 OCH3 
                 H 
                 H 
               
               
                   
               
               
                 18 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
               
               
                   
               
            
           
           
               
               
               
               
               
            
               
                   
                   
                   
                   
                 B 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                   
                 No 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
               
               
                   
               
               
                   
                   
                   
                 11 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                   
                   
                 12 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                   
                   
                 13 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                   
                   
                 14 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                   
                   
                 15 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                   
                   
                 16 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                   
                   
                 17 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                   
                   
                   
                 18 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
             
               
                   
                 TABLE 3 
               
               
                   
                   
               
             
            
               
                   
                 A 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 M 
                 m 
                 n 
                 A 
                 B 
                 A′ 
                 B′ 
                 E 
                 G 
                 J 
                 R1 
                 R2 
                 R3 
                 R4 
               
               
                   
               
               
                 19 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 CH3 
                 H 
                 H 
               
               
                 20 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 CH3 
                 H 
               
               
                 21 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 CH3 
                 CH3 
                 H 
               
               
                 22 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 F 
                 H 
                 H 
               
               
                 23 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 F 
                 H 
               
               
                 24 
                 Ir 
                 3 
                 0 
                 Tn1 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 — 
                 — 
               
               
                 25 
                 Ir 
                 3 
                 0 
                 Tn3 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 — 
                 — 
               
               
                 26 
                 Ir 
                 3 
                 0 
                 Tn4 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 — 
                 — 
               
               
                 27 
                 Ir 
                 3 
                 0 
                 Np2 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 — 
                 — 
               
               
                 28 
                 Ir 
                 3 
                 0 
                 Fl 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 — 
                 — 
               
               
                 29 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq5 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 30 
                 Ir 
                 3 
                 0 
                 Fl 
                 Iq5 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 31 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 32 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 CH3 
                 H 
                 H 
               
               
                 33 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 H 
                 CH3 
                 H 
               
               
                 34 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 CH3 
                 CH3 
                 H 
               
               
                 35 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 F 
                 H 
                 H 
               
               
                 36 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 H 
                 F 
                 H 
               
               
                 37 
                 Ir 
                 2 
                 1 
                 Tn1 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 H 
                 — 
                 — 
               
               
                 38 
                 Ir 
                 2 
                 1 
                 Tn3 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 H 
                 — 
                 — 
               
               
                 39 
                 Ir 
                 2 
                 1 
                 Tn4 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 H 
                 — 
                 — 
               
               
                 40 
                 Ir 
                 2 
                 1 
                 Np2 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 H 
                 — 
                 — 
               
               
                 41 
                 Ir 
                 2 
                 1 
                 Fl 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 H 
                 — 
                 — 
               
               
                 42 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 43 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 H 
                 CH3 
                 H 
                 H 
               
               
                 44 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 H 
                 H 
                 CH3 
                 H 
               
               
                 45 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 H 
                 CH3 
                 CH3 
                 H 
               
               
                 46 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 H 
                 F 
                 H 
                 H 
               
               
                 47 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 H 
                 H 
                 F 
                 H 
               
               
                 48 
                 Ir 
                 2 
                 1 
                 Tn1 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 49 
                 Ir 
                 2 
                 1 
                 Tn3 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 50 
                 Ir 
                 2 
                 1 
                 Tn4 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 51 
                 Ir 
                 2 
                 1 
                 Np2 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 52 
                 Ir 
                 2 
                 1 
                 Fl 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 53 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CF3 
                 CF3 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 54 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CF3 
                 CF3 
                 H 
                 H 
                 CH3 
                 H 
                 H 
               
               
                 55 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CF3 
                 CF3 
                 H 
                 H 
                 H 
                 CH3 
                 H 
               
               
                 56 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CF3 
                 CF3 
                 H 
                 H 
                 CH3 
                 CH3 
                 H 
               
               
                 57 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CF3 
                 CF3 
                 H 
                 H 
                 F 
                 H 
                 H 
               
               
                 58 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CF3 
                 CF3 
                 H 
                 H 
                 H 
                 F 
                 H 
               
               
                 59 
                 Ir 
                 2 
                 1 
                 Tn1 
                 Iq2 
                 — 
                 — 
                 CF3 
                 CF3 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 60 
                 Ir 
                 2 
                 1 
                 Tn3 
                 Iq2 
                 — 
                 — 
                 CF3 
                 CF3 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                   
               
            
           
           
               
               
               
               
            
               
                   
                 A′ 
                 B 
                 B′ 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                 No 
                 R1 
                 R2 
                 R3 
                 R4 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
                 R5 
                 R6 
                 R7 
                 R8 
               
               
                   
                   
               
               
                   
                 19 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 20 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 21 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 22 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 23 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 24 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 25 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 26 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 27 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 28 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 29 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 30 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 31 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 32 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 33 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 34 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 35 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 36 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 37 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 38 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 39 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 40 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 41 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 42 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 43 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 44 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 45 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 46 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 47 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 48 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 49 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 50 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 51 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 52 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 53 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 54 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 55 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 56 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 57 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 58 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 59 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 60 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
               
            
           
         
       
     
     
       
         
           
               
               
             
               
                   
                 TABLE 4 
               
               
                   
                   
               
             
            
               
                   
                 A 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 M 
                 m 
                 n 
                 A 
                 B 
                 A′ 
                 B′ 
                 E 
                 G 
                 J 
                 R1 
                 R2 
                 R3 
                 R4 
               
               
                   
               
               
                 61 
                 Ir 
                 2 
                 1 
                 Tn4 
                 Iq2 
                 — 
                 — 
                 CF3 
                 CF3 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 62 
                 Ir 
                 2 
                 1 
                 Np2 
                 Iq2 
                 — 
                 — 
                 CF3 
                 CF3 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 63 
                 Ir 
                 2 
                 1 
                 Fl 
                 Iq2 
                 — 
                 — 
                 CF3 
                 CF3 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 64 
                 Ir 
                 1 
                 2 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 65 
                 Ir 
                 1 
                 2 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 CH3 
                 H 
                 H 
               
               
                 66 
                 Ir 
                 1 
                 2 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 H 
                 CH3 
                 H 
               
               
                 67 
                 Ir 
                 1 
                 2 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 CH3 
                 CH3 
                 H 
               
               
                 68 
                 Ir 
                 1 
                 2 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 F 
                 H 
                 H 
               
               
                 69 
                 Ir 
                 1 
                 2 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 H 
                 F 
                 H 
               
               
                 70 
                 Ir 
                 1 
                 2 
                 Tn1 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 H 
                 — 
                 — 
               
               
                 71 
                 Ir 
                 1 
                 2 
                 Tn3 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 H 
                 — 
                 — 
               
               
                 72 
                 Ir 
                 1 
                 2 
                 Tn4 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 H 
                 — 
                 — 
               
               
                 73 
                 Ir 
                 1 
                 2 
                 Np2 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 H 
                 — 
                 — 
               
               
                 74 
                 Ir 
                 1 
                 2 
                 Fl 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 H 
                 — 
                 — 
               
               
                 75 
                 Ir 
                 1 
                 2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 76 
                 Ir 
                 1 
                 2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 H 
                 CH3 
                 H 
                 H 
               
               
                 77 
                 Ir 
                 1 
                 2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 H 
                 H 
                 CH3 
                 H 
               
               
                 78 
                 Ir 
                 1 
                 2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 H 
                 CH3 
                 CH3 
                 H 
               
               
                 79 
                 Ir 
                 1 
                 2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 H 
                 F 
                 H 
                 H 
               
               
                 80 
                 Ir 
                 1 
                 2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 H 
                 H 
                 F 
                 H 
               
               
                 81 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 82 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 83 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 84 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 F 
                 H 
               
               
                 85 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 F 
                 H 
               
               
                 86 
                 Rh 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 87 
                 Rh 
                 3 
                 0 
                 Tn1 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 — 
                 — 
               
               
                 88 
                 Rh 
                 3 
                 0 
                 Tn3 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 — 
                 — 
               
               
                 89 
                 Rh 
                 3 
                 0 
                 Np2 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 — 
                 — 
               
               
                 90 
                 Rh 
                 3 
                 0 
                 Fl 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 — 
                 — 
               
               
                 91 
                 Rh 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 92 
                 Rh 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 CH3 
                 H 
                 H 
               
               
                 93 
                 Rh 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 H 
                 CH3 
                 H 
               
               
                 94 
                 Rh 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 95 
                 Pt 
                 2 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 96 
                 Pt 
                 2 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 CH3 
                 H 
                 H 
               
               
                 97 
                 Pt 
                 2 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 CH3 
                 CH3 
                 H 
               
               
                 98 
                 Pt 
                 2 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 F 
                 H 
                 H 
               
               
                 99 
                 Pt 
                 2 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 F 
                 H 
               
               
                 100 
                 Pt 
                 2 
                 0 
                 Tn1 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 — 
                 — 
               
               
                   
               
            
           
           
               
               
               
               
            
               
                   
                 A′ 
                 B 
                 B′ 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                 No 
                 R1 
                 R2 
                 R3 
                 R4 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
                 R5 
                 R6 
                 R7 
                 R8 
               
               
                   
                   
               
               
                   
                 61 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 62 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 63 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 64 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 65 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 66 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 67 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 68 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 69 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 70 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 71 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 72 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 73 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 74 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 75 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 76 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 77 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 78 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 79 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 80 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 81 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 82 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 83 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 84 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 85 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 86 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 87 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 88 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 89 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 90 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 91 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 92 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 93 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 94 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 95 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 96 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 97 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 98 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 99 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 100 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
               
            
           
         
       
     
     
       
         
           
               
               
             
               
                   
                 TABLE 5 
               
               
                   
                   
               
             
            
               
                   
                 A 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 M 
                 m 
                 n 
                 A 
                 B 
                 A′ 
                 B′ 
                 E 
                 G 
                 J 
                 R1 
                 R2 
                 R3 
                 R4 
               
               
                   
               
               
                 101 
                 Pt 
                 2 
                 0 
                 Tn3 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 — 
                 — 
               
               
                 102 
                 Pt 
                 1 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 103 
                 Pt 
                 1 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 H 
                 CH3 
                 H 
               
               
                 104 
                 Pt 
                 1 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 CH3 
                 CH3 
                 H 
               
               
                 105 
                 Pt 
                 1 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 F 
                 H 
                 H 
               
               
                 106 
                 Pd 
                 2 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 107 
                 Pd 
                 2 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 CH3 
                 H 
               
               
                 108 
                 Pd 
                 2 
                 0 
                 Tn1 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 — 
                 — 
               
               
                 109 
                 Pd 
                 2 
                 0 
                 Tn3 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 — 
                 — 
               
               
                 110 
                 Pd 
                 1 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 111 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 H 
                 H 
                 H 
                 H 
               
               
                 112 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 113 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 H 
                 H 
                 H 
                 H 
               
               
                 114 
                 Ir 
                 2 
                 1 
                 Tn1 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 H 
                 H 
                 — 
                 — 
               
               
                 115 
                 Ir 
                 2 
                 1 
                 Tn1 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 116 
                 Ir 
                 2 
                 1 
                 Tn1 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C3H7 
                 CH3 
                 H 
                 H 
                 — 
                 — 
               
               
                 117 
                 Ir 
                 2 
                 1 
                 Tn2 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 H 
                 H 
                 — 
                 — 
               
               
                 118 
                 Ir 
                 2 
                 1 
                 Tn2 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 119 
                 Ir 
                 2 
                 1 
                 Tn2 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C6H13 
                 CH3 
                 H 
                 H 
                 — 
                 — 
               
               
                 120 
                 Ir 
                 2 
                 1 
                 Tn3 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 H 
                 H 
                 — 
                 — 
               
               
                 121 
                 Ir 
                 2 
                 1 
                 Tn3 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 122 
                 Ir 
                 2 
                 1 
                 Tn3 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 H 
                 H 
                 — 
                 — 
               
               
                 123 
                 Ir 
                 2 
                 1 
                 Tn4 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 H 
                 H 
                 — 
                 — 
               
               
                 124 
                 Ir 
                 2 
                 1 
                 Tn4 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 125 
                 Ir 
                 2 
                 1 
                 Tn4 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C5H11 
                 CH3 
                 H 
                 H 
                 — 
                 — 
               
               
                 126 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 H 
                 CH3 
                 H 
                 H 
               
               
                 127 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 H 
                 CH3 
                 H 
                 H 
               
               
                 128 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 H 
                 CH3 
                 H 
                 H 
               
               
                 129 
                 Ir 
                 2 
                 1 
                 Fl 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 H 
                 H 
                 — 
                 — 
               
               
                 130 
                 Ir 
                 2 
                 1 
                 Fl 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 131 
                 Ir 
                 2 
                 1 
                 Fl 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 H 
                 H 
                 — 
                 — 
               
               
                 132 
                 Ir 
                 2 
                 1 
                 Np1 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 H 
                 H 
                 — 
                 — 
               
               
                 133 
                 Ir 
                 2 
                 1 
                 Np1 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 134 
                 Ir 
                 2 
                 1 
                 Np1 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 H 
                 H 
                 — 
                 — 
               
               
                 135 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 C2H5 
                 H 
                 H 
               
               
                 136 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 H 
                 C2H5 
                 H 
                 H 
               
               
                 137 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 H 
                 C2H5 
                 H 
                 H 
               
               
                 138 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 H 
                 C2H5 
                 H 
                 H 
               
               
                 139 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 H 
                 C2H5 
                 H 
                 H 
               
               
                 140 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 H 
                 C2H5 
                 H 
                 H 
               
               
                   
               
            
           
           
               
               
               
               
            
               
                   
                 A′ 
                 B 
                 B′ 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                 No 
                 R1 
                 R2 
                 R3 
                 R4 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
                 R5 
                 R6 
                 R7 
                 R8 
               
               
                   
                   
               
               
                   
                 101 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 102 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 103 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 104 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 105 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 106 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 107 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 108 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 109 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 110 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 111 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 112 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 113 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 114 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 115 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 116 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 117 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 118 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 119 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 120 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 121 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 122 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 123 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 124 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 125 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 126 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 127 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 128 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 129 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 130 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 131 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 132 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 133 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 134 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 135 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 136 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 137 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 138 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 139 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 140 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 6-1 
               
             
            
               
                   
               
               
                 (continued to Table 6-2) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 M 
                 m 
                 n 
                 A 
                 B 
                 A′ 
                 B′ 
                 E 
                 G 
                 J 
                 B″ 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 141 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 142 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 143 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 144 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 145 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 146 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 147 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 148 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 149 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 150 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 — 
               
               
                 151 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 152 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 153 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 154 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 155 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 156 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 157 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 158 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 159 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 160 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 161 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 162 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 163 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 164 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 165 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 — 
               
               
                 166 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 167 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 168 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 169 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 170 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 171 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 172 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 173 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 174 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 175 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 176 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 — 
               
               
                 177 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 178 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 179 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 180 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
             
               
                 TABLE 6-2 
               
             
            
               
                   
               
               
                   
                 A 
                 A′ 
                 B 
                 B′ 
                 B″ 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 R1 
                 R2 
                 R3 
                 R4 
                 R1 
                 R2 
                 R3 
                 R4 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
                 R5 
                 R6 
                 R7 
                 R8 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 141 
                 H 
                 C2H5 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 142 
                 H 
                 C2H5 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                 143 
                 H 
                 C2H5 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 144 
                 H 
                 C3H7 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 145 
                 H 
                 C3H7 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 146 
                 H 
                 CH(CH3)2 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 147 
                 H 
                 C3H7 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 148 
                 H 
                 C3H7 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 149 
                 H 
                 C3H7 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 150 
                 H 
                 C3H7 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 151 
                 H 
                 C3H7 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 152 
                 H 
                 C3H7 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 153 
                 H 
                 C3H7 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                 154 
                 H 
                 C3H7 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 155 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 156 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 157 
                 H 
                 CH3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 158 
                 H 
                 CH3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 159 
                 H 
                 C4H9 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 160 
                 H 
                 C4H9 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 161 
                 H 
                 C4H9 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 162 
                 H 
                 C4H9 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 163 
                 H 
                 C4H9 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 164 
                 H 
                 C4H9 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 165 
                 H 
                 C4H9 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 166 
                 H 
                 C4H9 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 167 
                 H 
                 C4H9 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 168 
                 H 
                 C4H9 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                 169 
                 H 
                 C4H9 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 170 
                 H 
                 C(CH3)3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 171 
                 H 
                 C(CH3)3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 172 
                 H 
                 C(CH3)3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 173 
                 H 
                 C(CH3)3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 174 
                 H 
                 C(CH3)3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 175 
                 H 
                 C(CH3)3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 176 
                 H 
                 C(CH3)3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 177 
                 H 
                 C(CH3)3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 178 
                 H 
                 C(CH3)3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 179 
                 H 
                 C(CH3)3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                 180 
                 H 
                 C(CH3)3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 7-1 
               
             
            
               
                   
               
               
                 (continued to Table 7-2) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 M 
                 m 
                 n 
                 A 
                 B 
                 A′ 
                 B′ 
                 E 
                 G 
                 J 
                 B″ 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 181 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 182 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 183 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 184 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 185 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 186 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 187 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 — 
               
               
                 188 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 189 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 190 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 191 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 192 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 193 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 194 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 195 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 196 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 197 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 198 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 — 
               
               
                 199 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 200 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 201 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 202 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 203 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 204 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 205 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 206 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 207 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 208 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 209 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 — 
               
               
                 210 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 211 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 212 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 213 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 214 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 215 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 216 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 217 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 218 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 219 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 220 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
             
               
                 TABLE 7-2 
               
             
            
               
                   
               
               
                   
                 A 
                 A′ 
                 B 
                 B′ 
                 B″ 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 R1 
                 R2 
                 R3 
                 R4 
                 R1 
                 R2 
                 R3 
                 R4 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
                 R5 
                 R6 
                 R7 
                 R8 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 181 
                 H 
                 C5H11 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 182 
                 H 
                 C5H11 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 183 
                 H 
                 C5H11 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 184 
                 H 
                 C5H11 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 185 
                 H 
                 C5H11 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 186 
                 H 
                 C5H11 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 187 
                 H 
                 C5H11 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 188 
                 H 
                 C5H11 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 189 
                 H 
                 C5H11 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 190 
                 H 
                 C5H11 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                 191 
                 H 
                 C5H11 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 192 
                 H 
                 C6H13 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 193 
                 H 
                 C6H13 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 194 
                 H 
                 C6H13 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 195 
                 H 
                 C6H13 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 196 
                 H 
                 C6H13 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 197 
                 H 
                 C6H13 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 198 
                 H 
                 C6H13 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 199 
                 H 
                 C6H13 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 200 
                 H 
                 C6H13 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 201 
                 H 
                 C6H13 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                 202 
                 H 
                 C6H13 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 203 
                 H 
                 C7H15 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 204 
                 H 
                 C7H15 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 205 
                 H 
                 C7H15 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 206 
                 H 
                 C7H15 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 207 
                 H 
                 C7H15 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 208 
                 H 
                 C7H15 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 209 
                 H 
                 C7H15 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 210 
                 H 
                 C7H15 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 211 
                 H 
                 C7H15 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 212 
                 H 
                 C7H15 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                 213 
                 H 
                 C7H15 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 214 
                 H 
                 C8H17 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 215 
                 H 
                 C8H17 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 216 
                 H 
                 C8H17 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 217 
                 H 
                 C8H17 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 218 
                 H 
                 C8H17 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 219 
                 H 
                 C8H17 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 220 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 C8H17 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 8-1 
               
             
            
               
                   
               
               
                 (continued to Table 8-2) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 M 
                 m 
                 n 
                 A 
                 B 
                 A′ 
                 B′ 
                 E 
                 G 
                 J 
                 B″ 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 221 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 222 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 223 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 224 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 225 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 226 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 227 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 228 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 229 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 230 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 231 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 232 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 233 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 234 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 235 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 236 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 237 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 238 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 239 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 240 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 241 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 242 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 — 
               
               
                 243 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 244 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 245 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 246 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 247 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 248 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 249 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 250 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 251 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 252 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 253 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 254 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 255 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 256 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 257 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 258 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 259 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 260 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
             
               
                 TABLE 8-2 
               
             
            
               
                   
               
               
                   
                 A 
                 A′ 
                 B 
                 B′ 
                 B″ 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 R1 
                 R2 
                 R3 
                 R4 
                 R1 
                 R2 
                 R3 
                 R4 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
                 R5 
                 R6 
                 R7 
                 R8 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 221 
                 H 
                 C8H17 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 222 
                 H 
                 F 
                 CH3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 223 
                 H 
                 C8H17 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                 224 
                 H 
                 C8H17 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 225 
                 H 
                 C9H19 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 226 
                 H 
                 F 
                 CH3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 227 
                 H 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 228 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 229 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 230 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 231 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 232 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 233 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 234 
                 H 
                 C9H19 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                 235 
                 H 
                 C9H19 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 236 
                 H 
                 C10H21 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 237 
                 H 
                 C10H21 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 238 
                 H 
                 C10H21 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 239 
                 H 
                 C10H21 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 240 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 241 
                 H 
                 C10H21 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 242 
                 H 
                 C10H21 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 243 
                 H 
                 C10H21 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 244 
                 H 
                 C10H21 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 245 
                 H 
                 C10H21 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                 246 
                 H 
                 C10H21 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 247 
                 H 
                 C11H23 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 248 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 249 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 250 
                 F 
                 F 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 251 
                 F 
                 F 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 252 
                 F 
                 F 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 253 
                 F 
                 F 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 254 
                 H 
                 CF3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 255 
                 H 
                 CF3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 256 
                 H 
                 CF3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 257 
                 H 
                 C11H23 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 258 
                 H 
                 C12H25 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 259 
                 H 
                 C12H25 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 260 
                 H 
                 CF3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 9-1 
               
             
            
               
                   
               
               
                 (continued to Table 9-2) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 M 
                 m 
                 n 
                 A 
                 B 
                 A′ 
                 B′ 
                 E 
                 G 
                 J 
                 B″ 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 261 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 262 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 263 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 264 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 265 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 266 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 267 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 268 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 269 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 270 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 271 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 272 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 273 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 274 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 275 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 276 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 277 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 278 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 — 
               
               
                 279 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 280 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 281 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 282 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 283 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 284 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 285 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 286 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 287 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 288 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 289 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 290 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 291 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 292 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 293 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 294 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 295 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 296 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 297 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 298 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 299 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 300 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
             
               
                 TABLE 9-2 
               
               
                   
               
             
            
               
                   
                 A 
                 A′ 
                 B 
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 R1 
                 R2 
                 R3 
                 R4 
                 R1 
                 R2 
                 R3 
                 R4 
                 R5 
                 R6 
                 R7 
                 R8 
               
               
                   
               
               
                 261 
                 H 
                 C12H25 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 262 
                 H 
                 H 
                 CF3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 263 
                 H 
                 H 
                 CF3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 264 
                 H 
                 H 
                 CF3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 265 
                 H 
                 H 
                 CF3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
               
               
                 266 
                 H 
                 H 
                 CF3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 CF3 
               
               
                 267 
                 F 
                 F 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 268 
                 F 
                 F 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 269 
                 H 
                 C13H27 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 270 
                 H 
                 H 
                 C7H15O 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 271 
                 H 
                 C15H31 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 272 
                 F 
                 F 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 CF3 
               
               
                 273 
                 H 
                 CF3O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 274 
                 H 
                 C3H7O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 275 
                 H 
                 C4H9O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 276 
                 H 
                 C18H37 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 277 
                 H 
                 C19H39 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 278 
                 H 
                 C19H39 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 279 
                 H 
                 C20H41 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 280 
                 H 
                 C20H41 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 281 
                 H 
                 CH3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 282 
                 H 
                 C2H5 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 283 
                 H 
                 C3H7 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 284 
                 H 
                 C4H9 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 285 
                 H 
                 C(CH3)3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 286 
                 H 
                 C5H11 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 287 
                 H 
                 C6H13 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 288 
                 H 
                 C7H15 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 289 
                 H 
                 C8H17 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 290 
                 H 
                 C9H19 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 291 
                 H 
                 C10H21 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 292 
                 H 
                 C11H23 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 293 
                 H 
                 C12H25 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 F 
               
               
                 294 
                 H 
                 C15H31 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 295 
                 H 
                 C18H37 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 296 
                 H 
                 C20H41 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 —C≡CC4H9 
               
               
                 297 
                 H 
                 H 
                 H 
                 H 
                 H 
                 CH3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 298 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C2H5 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 299 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C3H7 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 300 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C4H9 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
            
           
           
               
               
               
               
            
               
                   
                 B 
                 B′ 
                 B″ 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                 No 
                 R9 
                 R10 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
                 R5 
                 R6 
                 R7 
                 R8 
               
               
                   
               
               
                   
                 261 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 262 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 263 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 264 
                 CF3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 265 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 266 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 267 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 268 
                 CF3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 269 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 270 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 271 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 272 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 273 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 274 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 275 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 276 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 277 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 278 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 279 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 280 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 281 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 282 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 283 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 284 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 285 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 286 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 287 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 288 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 289 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 290 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 291 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 292 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 293 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 294 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 295 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 296 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 297 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 298 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 299 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 300 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 10-1 
               
             
            
               
                   
               
               
                 (continued to Table 10-2) 
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                 No 
                 M 
                 m 
                 n 
                 A 
                 B 
                 A′ 
                 B′ 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                 301 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
               
               
                 302 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
               
               
                 303 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
               
               
                 304 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
               
               
                 305 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
               
               
                 306 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
               
               
                 307 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
               
               
                 308 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
               
               
                 309 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
               
               
                 310 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
               
               
                 311 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
               
               
                 312 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
               
               
                 313 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
               
               
                 314 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
               
               
                 315 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
               
               
                 316 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
               
               
                 317 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
               
               
                 318 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
               
               
                 319 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
               
               
                 320 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
               
               
                 321 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
               
               
                 322 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
               
               
                 323 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
               
               
                 324 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
               
               
                 325 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
               
               
                 326 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
               
               
                 327 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
               
               
                 328 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
               
               
                 329 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
               
               
                 330 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
               
               
                 331 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
               
               
                 332 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
               
               
                 333 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
               
               
                 334 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
               
               
                 335 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
               
               
                 336 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
               
               
                 337 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
               
               
                 338 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
               
               
                 339 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
               
               
                 340 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
             
               
                 TABLE 10-2 
               
               
                   
               
             
            
               
                   
                 A 
                 A′ 
                 B 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 R1 
                 R2 
                 R3 
                 R4 
                 R1 
                 R2 
                 R3 
                 R4 
                 R5 
                 R6 
               
               
                   
               
               
                 301 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C(CH3)3 
                 H 
                 H 
                 H 
                 H 
               
               
                 302 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C5H11 
                 H 
                 H 
                 H 
                 H 
               
               
                 303 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
                 H 
                 H 
                 H 
               
               
                 304 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C7H15 
                 H 
                 H 
                 H 
                 H 
               
               
                 305 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C8H17 
                 H 
                 H 
                 H 
                 H 
               
               
                 306 
                 H 
                 CH2OC5H11 
                 H 
                 H 
                 H 
                 C9H19 
                 H 
                 H 
                 H 
                 H 
               
               
                 307 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C10H21 
                 H 
                 H 
                 H 
                 H 
               
               
                 308 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C11H23 
                 H 
                 H 
                 H 
                 H 
               
               
                 309 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C12H25 
                 H 
                 H 
                 H 
                 H 
               
               
                 310 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C15H31 
                 H 
                 H 
                 H 
                 H 
               
               
                 311 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C18H37 
                 H 
                 H 
                 H 
                 H 
               
               
                 312 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C20H41 
                 H 
                 H 
                 H 
                 H 
               
               
                 313 
                 H 
                 H 
                 CH3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
               
               
                 314 
                 H 
                 H 
                 C2H5 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
               
               
                 315 
                 H 
                 H 
                 CH(CH3)2 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
               
               
                 316 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
               
               
                 317 
                 H 
                 H 
                 C(CH3)3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
               
               
                 318 
                 H 
                 H 
                 C5H11 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
               
               
                 319 
                 H 
                 H 
                 C6H13 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
               
               
                 320 
                 H 
                 H 
                 C7H15 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
               
               
                 321 
                 H 
                 H 
                 C8H17 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
               
               
                 322 
                 H 
                 H 
                 C9H19 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
               
               
                 323 
                 H 
                 H 
                 C10H21 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
               
               
                 324 
                 H 
                 H 
                 C11H23 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
               
               
                 325 
                 H 
                 H 
                 C12H25 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
               
               
                 326 
                 H 
                 H 
                 C15H31 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
               
               
                 327 
                 H 
                 H 
                 C18H37 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
               
               
                 328 
                 H 
                 H 
                 C20H41 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
               
               
                 329 
                 H 
                 H 
                 CH3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 330 
                 H 
                 H 
                 C2H5 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 331 
                 H 
                 H 
                 C3H7 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 332 
                 H 
                 H 
                 C4H9 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 333 
                 H 
                 H 
                 C(CH3)3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 334 
                 H 
                 H 
                 C5H11 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 335 
                 H 
                 H 
                 C6H13 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 336 
                 H 
                 H 
                 C7H15 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 337 
                 H 
                 H 
                 C8H17 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 338 
                 H 
                 H 
                 C9H19 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 339 
                 H 
                 H 
                 C10H21 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 340 
                 H 
                 H 
                 C11H23 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
            
           
           
               
               
               
            
               
                   
                 B 
                 B′ 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                 No 
                 R7 
                 R8 
                 R9 
                 R10 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
               
               
                   
               
               
                   
                 301 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 302 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 303 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 304 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 305 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 306 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 307 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 308 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 309 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 310 
                 H 
                 —CH═CH—CH3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 311 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 312 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 313 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 314 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 315 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 316 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 317 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 318 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 319 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 320 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 321 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 322 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 323 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 324 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 325 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 326 
                 H 
                 COOC6H13 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 327 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 328 
                 H 
                 OCH2C3F7 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 329 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 330 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 331 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 332 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 333 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 334 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 335 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 336 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 337 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 338 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 339 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 340 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 11-1 
               
             
            
               
                   
               
               
                 (continued to Table 11-2) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 M 
                 m 
                 n 
                 A 
                 B 
                 A′ 
                 B′ 
                 E 
                 G 
                 J 
                 B″ 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 341 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 342 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 343 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 344 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 345 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 346 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 347 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 348 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 349 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 350 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 351 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 352 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 353 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 354 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 355 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 356 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 357 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 358 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 359 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 360 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 361 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 362 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 363 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 364 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 365 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 366 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 367 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 — 
               
               
                 368 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 369 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 370 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 371 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 372 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 373 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 374 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 375 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 376 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 377 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 — 
               
               
                 378 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 379 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 380 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
             
               
                 TABLE 11-2 
               
               
                   
               
             
            
               
                   
                 A 
                 A′ 
                 B 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 R1 
                 R2 
                 R3 
                 R4 
                 R1 
                 R2 
                 R3 
                 R4 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
               
               
                   
               
               
                 341 
                 H 
                 H 
                 C12H25 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 342 
                 H 
                 H 
                 C15H31 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 343 
                 H 
                 H 
                 C18H37 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 344 
                 H 
                 H 
                 C20H41 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 345 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 CH3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 346 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C2H5 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 347 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C3H7 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 348 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C4H9 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 349 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C(CH3)3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 350 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C5H11 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 351 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 352 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C7H15 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 353 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C8H17 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 354 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C9H19 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 355 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C10H21 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 356 
                 H 
                 H 
                 COCH3 
                 H 
                 H 
                 H 
                 C11H23 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 357 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C12H25 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 358 
                 H 
                 H 
                 C7H15O 
                 H 
                 H 
                 H 
                 C15H31 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 359 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C18H37 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 360 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 C20H41 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 361 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 362 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
               
               
                   
               
               
                 363 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
               
               
                   
               
               
                 364 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 365 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 366 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 367 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 368 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 369 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 370 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 371 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 372 
                 H 
                 CH3O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 373 
                 H 
                 CH3O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
               
               
                 374 
                 H 
                 CH3O 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 375 
                 H 
                 H 
                 CH3O 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 376 
                 H 
                 CH3O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 377 
                 H 
                 CH3O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 378 
                 H 
                 CH3O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 379 
                 H 
                 CH3O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 380 
                 H 
                 CH3O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
            
           
           
               
               
               
               
               
            
               
                   
                   
                   
                 B′ 
                 B″ 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                 No 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
               
               
                   
               
               
                   
                   
                 341 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 342 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 343 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 344 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 345 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 346 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 347 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 348 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 349 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 350 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 351 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 352 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 353 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 354 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 355 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 356 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 357 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 358 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 359 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 360 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 361 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 362 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 363 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 364 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 365 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 366 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 367 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 368 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 369 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                   
                   
                 370 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                   
                   
                 371 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                   
                 372 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 373 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 374 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 375 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 376 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 377 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 378 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 379 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 380 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 12-1 
               
             
            
               
                   
               
               
                 (Continued to Table 12-2) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 M 
                 m 
                 n 
                 A 
                 B 
                 A 
                 B 
                 E 
                 G 
                 J 
                 B 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 381 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 382 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 383 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 384 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 385 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 386 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 387 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 388 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 — 
               
               
                 389 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 390 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 391 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 392 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 393 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 394 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 395 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 396 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 397 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 399 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 400 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 401 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 402 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 403 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 404 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 405 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 406 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 407 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 408 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 409 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 410 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 411 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 412 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 413 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 414 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 415 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 416 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 417 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 418 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 419 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 420 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
             
               
                 TABLE 12-2 
               
             
            
               
                   
               
               
                   
                 A 
                 A′ 
                 B 
                 B′ 
                 B″ 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 R1 
                 R2 
                 R3 
                 R4 
                 R1 
                 R2 
                 R3 
                 R4 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
                 R5 
                 R6 
                 R7 
                 R8 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 381 
                 H 
                 CH3O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 382 
                 H 
                 C2H5O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 383 
                 H 
                 C2H5O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 384 
                 H 
                 C2H5O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 385 
                 H 
                 C2H5O 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 386 
                 H 
                 C2H5O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 387 
                 H 
                 C2H5O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 388 
                 H 
                 C2H5O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 389 
                 H 
                 C2H5O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 390 
                 H 
                 C2H5O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 391 
                 H 
                 C2H5O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                 392 
                 H 
                 C2H5O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 393 
                 H 
                 C6H13O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 394 
                 H 
                 C6H13O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 395 
                 H 
                 C6H13O 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 396 
                 H 
                 C6H13O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 397 
                 H 
                 C6H13O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 399 
                 H 
                 C6H13O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 400 
                 H 
                 C6H13O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 401 
                 H 
                 C6H13O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                 402 
                 H 
                 C6H13O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 403 
                 H 
                 C7H15O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 404 
                 H 
                 C7H15O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 405 
                 H 
                 C7H15O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 406 
                 H 
                 (CH3)3CO 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 407 
                 H 
                 C5H11O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 408 
                 H 
                 CF3O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 409 
                 H 
                 CF3O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 410 
                 H 
                 CF3O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 411 
                 H 
                 CF3O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 412 
                 H 
                 C7H15O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 413 
                 H 
                 C7H15O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 414 
                 H 
                 (C4H9)3Si 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 415 
                 H 
                 C12H25O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 416 
                 H 
                 C12H25O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 417 
                 H 
                 C12H25O 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 418 
                 H 
                 (CH3)3Si 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 419 
                 H 
                 C18H37O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                 420 
                 H 
                 C18H37O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 13-1 
               
             
            
               
                   
               
               
                 (continued to Table 13-2) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 M 
                 m 
                 n 
                 A 
                 B 
                 A′ 
                 B′ 
                 E 
                 G 
                 J 
                 B″ 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 421 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 422 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 423 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 424 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 425 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 426 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 427 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 — 
               
               
                 428 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 429 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 430 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 431 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 432 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 433 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 434 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 435 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 436 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 437 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 438 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 — 
               
               
                 439 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 440 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 441 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 442 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 443 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 444 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 445 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 446 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 447 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 448 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 449 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 — 
               
               
                 450 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 451 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 452 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 453 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 454 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 455 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 456 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 457 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 458 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 459 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
             
               
                 TABLE 13-2 
               
             
            
               
                   
               
               
                   
                 A 
                 A′ 
                 B 
                 B′ 
                 B″ 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 R1 
                 R2 
                 R3 
                 R4 
                 R1 
                 R2 
                 R3 
                 R4 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
                 R5 
                 R6 
                 R7 
                 R8 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 421 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 422 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 423 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 424 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 425 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 426 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 427 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 428 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 429 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 430 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                 431 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 432 
                 H 
                 F 
                 H 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 433 
                 H 
                 F 
                 H 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 434 
                 H 
                 F 
                 H 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 435 
                 H 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 436 
                 H 
                 F 
                 H 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 437 
                 H 
                 F 
                 H 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 438 
                 H 
                 F 
                 H 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 439 
                 H 
                 F 
                 H 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 440 
                 H 
                 F 
                 H 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 441 
                 H 
                 F 
                 H 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                 442 
                 H 
                 F 
                 H 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 443 
                 F 
                 F 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 444 
                 F 
                 F 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 445 
                 F 
                 F 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 446 
                 F 
                 F 
                 F 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 447 
                 F 
                 F 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 448 
                 F 
                 F 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 449 
                 F 
                 F 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 450 
                 F 
                 F 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 451 
                 F 
                 F 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 452 
                 F 
                 F 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                 453 
                 F 
                 F 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 454 
                 F 
                 F 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 F 
                 F 
                 F 
                 F 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 455 
                 F 
                 F 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 F 
                 F 
                 F 
                 F 
                 C6H13 
                 F 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 456 
                 F 
                 F 
                 F 
                 F 
                 H 
                 H 
                 H 
                 H 
                 F 
                 F 
                 F 
                 F 
                 F 
                 F 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 457 
                 F 
                 F 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 F 
                 F 
                 F 
                 F 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 458 
                 F 
                 F 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 F 
                 F 
                 F 
                 F 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 459 
                 F 
                 F 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 F 
                 F 
                 F 
                 F 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 14-1A 
               
             
            
               
                   
               
               
                 (continued to Table 14-2A) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 M 
                 m 
                 n 
                 A 
                 B 
                 A′ 
                 B′ 
                 E 
                 G 
                 J 
                 B″ 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 460 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 461 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 462 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 463 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 464 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 465 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 466 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 467 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 468 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 469 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 470 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 471 
                 Ir 
                 1 
                 2 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 472 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 473 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 474 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 475 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 476 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 477 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 478 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 479 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 480 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 481 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 482 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 483 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 484 
                 Ir 
                 1 
                 2 
                 Ph 
                 Iq2 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
               
               
                 485 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 14-1B 
               
             
            
               
                   
               
               
                 (continued to Table 14-2B) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 M 
                 m 
                 n 
                 A 
                 B 
                 A′ 
                 B′ 
                 E 
                 G 
                 J 
                 B″ 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 486 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 487 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 488 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 489 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 490 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 491 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 492 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 — 
               
               
                 493 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 494 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 495 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 496 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 497 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 498 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 499 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 500 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 501 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 502 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 503 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 — 
               
               
                 504 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 505 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 506 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 507 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 508 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 509 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
             
               
                   
                 TABLE 14-2A 
               
               
                   
                   
               
             
            
               
                   
                 A 
                 A′ 
                 B 
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 R1 
                 R2 
                 R3 
                 R4 
                 R1 
                 R2 
                 R3 
                 R4 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
               
               
                   
               
               
                 460 
                 F 
                 F 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 F 
                 F 
                 F 
                 F 
                 F 
                 F 
               
               
                 461 
                 F 
                 F 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 F 
                 F 
                 F 
                 F 
                 F 
                 F 
               
               
                 462 
                 F 
                 F 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 F 
                 F 
                 F 
                 F 
                 F 
                 F 
               
               
                 463 
                 F 
                 F 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 F 
                 F 
                 F 
                 F 
                 F 
                 F 
               
               
                 464 
                 H 
                 C2F5 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 465 
                 H 
                 C2F5 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
               
               
                 466 
                 H 
                 C3F7 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
               
               
                 467 
                 H 
                 C3F7 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 468 
                 H 
                 C4F9 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 469 
                 H 
                 C3F7CH2CH2O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 470 
                 H 
                 C3F7CH2CH2O 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 471 
                 H 
                 C3F7CH2CH2O 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 472 
                 H 
                 C5F11 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 473 
                 H 
                 C2F5 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 474 
                 H 
                 C3F7 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 475 
                 H 
                 C6F13 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 476 
                 H 
                 C6F13 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 H 
               
               
                 477 
                 H 
                 C6F13 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
               
               
                 478 
                 H 
                 C6F13 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 F 
                 H 
               
               
                 479 
                 H 
                 C6F13 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 F 
                 H 
               
               
                 480 
                 H 
                 H 
                 H 
                 H 
                 H 
                 C6F13 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 481 
                 H 
                 C6F13CH2O 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 482 
                 H 
                 C18F37 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 483 
                 H 
                 C6F13CH2O 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 484 
                 H 
                 C6F13CH2O 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 485 
                 H 
                 C20F41 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
            
           
           
               
               
               
            
               
                   
                 B′ 
                 B″ 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                 No 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
               
               
                   
                   
               
               
                   
                 460 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 461 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                   
                 462 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                   
                 463 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 464 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 465 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 466 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 467 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 468 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 469 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 470 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 471 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 472 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 CH3 
                 H 
                 H 
                 — 
                 — 
               
               
                   
                 473 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                   
                 474 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                 475 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 476 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 477 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 478 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 479 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 480 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 481 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 482 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 483 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 484 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                 485 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
             
               
                 TABLE 14-2B 
               
               
                   
               
             
            
               
                   
                 A 
                 A′ 
                 B 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 R1 
                 R2 
                 R3 
                 R4 
                 R1 
                 R2 
                 R3 
                 R4 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
               
               
                   
               
               
                 486 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 487 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
               
               
                   
               
               
                 488 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
               
               
                   
               
               
                 489 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 490 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 491 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 492 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 493 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 494 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 495 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 496 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 CH3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 497 
                 H 
                 H 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 498 
                 H 
                 H 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
               
               
                 499 
                 H 
                 H 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
               
               
                 500 
                 H 
                 H 
                 F 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 501 
                 H 
                 H 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 502 
                 H 
                 H 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 503 
                 H 
                 H 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 504 
                 H 
                 H 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 505 
                 H 
                 H 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 506 
                 H 
                 H 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 507 
                 H 
                 H 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 508 
                 H 
                 CH3 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 H 
               
               
                 509 
                 H 
                 CH3 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
               
               
                   
               
            
           
           
               
               
               
               
               
            
               
                   
                   
                   
                 B′ 
                 B″ 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                 No 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
               
               
                   
               
               
                   
                   
                 486 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 487 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 488 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 489 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 490 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 491 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 492 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 493 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 494 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                   
                   
                 495 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C2H5 
                 H 
                 — 
                 — 
               
               
                   
                   
                 496 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                   
                 497 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 498 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 499 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 500 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 501 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 502 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 503 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 504 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 505 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                   
                   
                 506 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                   
                   
                 507 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
                   
                 508 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
                   
                 509 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 15-1 
               
             
            
               
                   
               
               
                 (continued to Table 15-2) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 M 
                 m 
                 n 
                 A 
                 B 
                 A′ 
                 B′ 
                 E 
                 G 
                 J 
                 B″ 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 510 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 511 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 512 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 513 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 514 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 — 
               
               
                 515 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 516 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 517 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 518 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 519 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 520 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 521 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 522 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 523 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 524 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 525 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 — 
               
               
                 526 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 527 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 528 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 529 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 530 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 531 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 532 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 533 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 534 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 535 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 536 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 — 
               
               
                 537 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 538 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 539 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 540 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 541 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 542 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 543 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 544 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 545 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 F 
                 — 
               
               
                 546 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 547 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 — 
               
               
                 548 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 549 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
             
               
                   
                 TABLE 15-2 
               
             
            
               
                   
                   
               
               
                   
                 A 
                 A′ 
                 B 
                 B′ 
                 B″ 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 R1 
                 R2 
                 R3 
                 R4 
                 R1 
                 R2 
                 R3 
                 R4 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
                 R5 
                 R6 
                 R7 
                 R8 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 510 
                 H 
                 CH3 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 511 
                 H 
                 CH3 
                 F 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 512 
                 H 
                 CH3 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 513 
                 H 
                 CH3 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 514 
                 H 
                 CH3 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 515 
                 H 
                 CH3 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 516 
                 H 
                 CH3 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 517 
                 H 
                 CH3 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                 518 
                 H 
                 CH3 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 519 
                 H 
                 C2H5 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 520 
                 H 
                 C2H5 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 521 
                 H 
                 C2H5 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 522 
                 H 
                 C2H5 
                 F 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 523 
                 H 
                 C2H5 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 524 
                 H 
                 C2H5 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 525 
                 H 
                 C2H5 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 526 
                 H 
                 C3H7 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 527 
                 H 
                 C3H7 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 528 
                 H 
                 C3H7 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                 529 
                 H 
                 C3H7 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 530 
                 H 
                 C4H9 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 531 
                 H 
                 C4H9 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 532 
                 H 
                 C4H9 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 533 
                 H 
                 C4H9 
                 F 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 534 
                 H 
                 C4H9 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 535 
                 H 
                 C4H9 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 536 
                 H 
                 C4H9 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 537 
                 H 
                 C4H9 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 538 
                 H 
                 C4H9 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 539 
                 H 
                 C4H9 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 CH3 
                 H 
                 — 
                 — 
               
               
                 540 
                 H 
                 C4H9 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 541 
                 H 
                 C(CH3)3 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 542 
                 H 
                 C(CH3)3 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 543 
                 H 
                 C(CH3)3 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 544 
                 H 
                 C(CH3)3 
                 F 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 545 
                 H 
                 C5H11 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 546 
                 H 
                 C5H11 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 547 
                 H 
                 C5H11 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 548 
                 H 
                 C5H11 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 549 
                 H 
                 C5H11 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 16-1 
               
             
            
               
                   
               
               
                 (continued to Table 16-2) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 M 
                 m 
                 n 
                 A 
                 B 
                 A′ 
                 B′ 
                 E 
                 G 
                 J 
                 B″ 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 550 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 551 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 552 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 553 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 554 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 555 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 556 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CF3 
                 CF3 
                 H 
                 — 
               
               
                 557 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 558 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 — 
               
               
                 559 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 560 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 561 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 562 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 563 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 564 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 565 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 566 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 567 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 568 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 569 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 — 
               
               
                 570 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 571 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 572 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 573 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 574 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 575 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 576 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 577 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 578 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 579 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 580 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 — 
               
               
                 581 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 582 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 583 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 584 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 585 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 586 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 587 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 588 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 589 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
             
               
                   
                 TABLE 16-2 
               
             
            
               
                   
                   
               
               
                   
                 A 
                 A′ 
                 B 
                 B′ 
                 B″ 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 R1 
                 R2 
                 R3 
                 R4 
                 R1 
                 R2 
                 R3 
                 R4 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
                 R5 
                 R6 
                 R7 
                 R8 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 550 
                 H 
                 C6H13 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                 551 
                 H 
                 C6H13 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 552 
                 H 
                 C6H13 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 553 
                 H 
                 C6H13 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 554 
                 H 
                 C6H13 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 555 
                 H 
                 C6H13 
                 F 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 556 
                 H 
                 C6H13 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 557 
                 H 
                 C6H13 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 558 
                 H 
                 C7H15 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 559 
                 H 
                 C7H15 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 560 
                 H 
                 C7H15 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 561 
                 H 
                 C8H17 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                 562 
                 H 
                 C8H17 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 563 
                 H 
                 C8H17 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 564 
                 H 
                 C9H19 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 565 
                 H 
                 C9H19 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 566 
                 H 
                 C10H21 
                 F 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 567 
                 H 
                 C10H21 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 568 
                 H 
                 C11H23 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 569 
                 H 
                 C12H25 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 570 
                 H 
                 C13H27 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 571 
                 H 
                 C14H29 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 572 
                 H 
                 C15H31 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                 573 
                 H 
                 C15H31 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 574 
                 H 
                 C16H33 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 575 
                 H 
                 C17H35 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 576 
                 H 
                 C17H35 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 577 
                 H 
                 C17H35 
                 F 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 578 
                 H 
                 C17H35 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 579 
                 H 
                 C17H35 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 580 
                 H 
                 C18H37 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 581 
                 H 
                 C18H37 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 582 
                 H 
                 C18H37 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 583 
                 H 
                 C19H39 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C2H5 
                 H 
                 — 
                 — 
               
               
                 584 
                 H 
                 C20H41 
                 F 
                 F 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 585 
                 F 
                 F 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 586 
                 F 
                 F 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 587 
                 F 
                 F 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 C6H13 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 588 
                 F 
                 F 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 589 
                 F 
                 F 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 17-1 
               
             
            
               
                   
               
               
                 (continued to Table 17-2) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 M 
                 m 
                 n 
                 A 
                 B 
                 A′ 
                 B′ 
                 E 
                 G 
                 J 
                 B″ 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 590 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 591 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 — 
               
               
                 592 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 593 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 594 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 595 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 596 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 597 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 598 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 599 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 600 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 601 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 602 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 C(CH3)3 
                 C═(CH3)3 
                 H 
                 — 
               
               
                 603 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 604 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 605 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 606 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 607 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 608 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 609 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq5 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 610 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq5 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 611 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq5 
                 Ph 
                 Pr 
                 — 
                 — 
                 — 
                 — 
               
               
                 612 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq5 
                 — 
                 — 
                 CH3 
                 CH3 
                 H 
                 — 
               
               
                 613 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq5 
                 — 
                 — 
                 CH3 
                 CH3 
                 CH3 
                 — 
               
               
                 614 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq5 
                 — 
                 — 
                 C(CH3)3 
                 C(CH3)3 
                 H 
                 — 
               
               
                 615 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq5 
                 — 
                 — 
                 CH3 
                 C4H9 
                 CH3 
                 — 
               
               
                 616 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq5 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 617 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq5 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Pr 
               
               
                 618 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq5 
                 — 
                 — 
                 — 
                 — 
                 — 
                 Iq2 
               
               
                 619 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pi 
                 — 
                 — 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
             
               
                   
                 TABLE 17-2 
               
             
            
               
                   
                   
               
               
                   
                 A 
                 A′ 
                 B 
                 B′ 
                 B″ 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 R1 
                 R2 
                 R3 
                 R4 
                 R1 
                 R2 
                 R3 
                 R4 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
                 R5 
                 R6 
                 R7 
                 R8 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 590 
                 F 
                 F 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 591 
                 F 
                 F 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 592 
                 F 
                 F 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 593 
                 F 
                 F 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 594 
                 F 
                 F 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 C4H9 
                 H 
                 — 
                 — 
               
               
                 595 
                 F 
                 F 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 596 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 597 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
                 CF3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 598 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 599 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 600 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 601 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 602 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 603 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 604 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 605 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 CH3 
                 H 
                 — 
                 — 
               
               
                 606 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 607 
                 H 
                 CF3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 608 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 609 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 610 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 611 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 612 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 613 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 614 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 615 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 616 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 617 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 CH3 
                 H 
                 — 
                 — 
               
               
                 618 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 619 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 18-1 
               
               
                   
               
               
                 No 
                 M 
                 m 
                 n 
                 A 
                 B 
                 A′ 
                 B′ 
                 B″ 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
            
               
                 620 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Py1 
                 — 
               
               
                 621 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Py2 
                 — 
               
               
                 622 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pz 
                 — 
               
               
                 623 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Qn3 
                 — 
               
               
                 624 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Xa 
                 — 
               
               
                 625 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Bz 
                 — 
               
               
                 626 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Bo 
                 — 
               
               
                 627 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Oz 
                 — 
               
               
                 628 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Sz 
                 — 
               
               
                 629 
                 Ir 
                 2 
                 1 
                 Tn4 
                 Iq2 
                 Ph 
                 Pr 
                 — 
               
               
                 630 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 Pr 
               
               
                 631 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 Pr 
               
               
                 632 
                 Ir 
                 2 
                 1 
                 Ph 
                 Iq2 
                 — 
                 — 
                 Iq2 
               
               
                 633 
                 Rh 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
               
               
                 634 
                 Rh 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
               
               
                 635 
                 Rh 
                 3 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
               
               
                 636 
                 Rh 
                 2 
                 1 
                 Ph 
                 Iq2 
                 Ph 
                 Pr 
                 — 
               
               
                 637 
                 Pt 
                 2 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
               
               
                 638 
                 Pt 
                 2 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
               
               
                 639 
                 Pd 
                 2 
                 0 
                 Ph 
                 Iq2 
                 — 
                 — 
                 — 
               
               
                 640 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq6 
                 — 
                 — 
                 — 
               
               
                 641 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq6 
                 — 
                 — 
                 — 
               
               
                 642 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq6 
                 — 
                 — 
                 — 
               
               
                 643 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq6 
                 — 
                 — 
                 — 
               
               
                 644 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq6 
                 — 
                 — 
                 — 
               
               
                 645 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq6 
                 — 
                 — 
                 — 
               
               
                 646 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq6 
                 — 
                 — 
                 — 
               
               
                 647 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq6 
                 — 
                 — 
                 — 
               
               
                 648 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq6 
                 — 
                 — 
                 — 
               
               
                 649 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq6 
                 — 
                 — 
                 — 
               
               
                 650 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq7 
                 — 
                 — 
                 — 
               
               
                 651 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq7 
                 — 
                 — 
                 — 
               
               
                 652 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq7 
                 — 
                 — 
                 — 
               
               
                 653 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq7 
                 — 
                 — 
                 — 
               
               
                 654 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq7 
                 — 
                 — 
                 — 
               
               
                 655 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq7 
                 — 
                 — 
                 — 
               
               
                 656 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq7 
                 — 
                 — 
                 — 
               
               
                 657 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq7 
                 — 
                 — 
                 — 
               
               
                 658 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq7 
                 — 
                 — 
                 — 
               
               
                 659 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq7 
                 — 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
             
               
                   
                 TABLE 18-2 
               
               
                   
                   
               
             
            
               
                   
                 A 
                 A′ 
                 B 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 R1 
                 R2 
                 R3 
                 R4 
                 R1 
                 R2 
                 R3 
                 R4 
                 R5 
                 R6 
                 R7 
                 R8 
               
               
                   
               
               
                 620 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 621 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 622 
                 H 
                 CF3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 623 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 624 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 625 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 626 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 627 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 628 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 629 
                 H 
                 H 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 630 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 631 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 632 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 633 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
               
               
                 634 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
               
               
                 635 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 F 
               
               
                 636 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 F 
               
               
                 637 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 638 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 639 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 640 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 — 
               
               
                 641 
                 H 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 — 
               
               
                 642 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 — 
               
               
                 643 
                 H 
                 CF3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 — 
               
               
                 644 
                 H 
                 CH3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 — 
               
               
                 645 
                 H 
                 C4H9 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 — 
               
               
                 646 
                 H 
                 C3F7 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 — 
               
               
                 647 
                 H 
                 OC6H13 
                 C3H7 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 — 
               
               
                 648 
                 F 
                 F 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 — 
               
               
                 649 
                 H 
                 OCF3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 — 
               
               
                 650 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 651 
                 H 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 652 
                 F 
                 H 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 653 
                 H 
                 CF3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 CF3 
               
               
                 654 
                 H 
                 CH3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 655 
                 H 
                 C4H9 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 656 
                 H 
                 C3F7 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 657 
                 H 
                 OC6H13 
                 C3H7 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 658 
                 F 
                 F 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 659 
                 H 
                 OCF3 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
            
           
           
               
               
               
               
               
            
               
                   
                 B 
                 B′ 
                   
                 B″ 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 R9 
                 R10 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
               
               
                   
               
               
                 620 
                 H 
                 H 
                 H 
                 H 
                 — 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 621 
                 H 
                 H 
                 — 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 622 
                 H 
                 H 
                 H 
                 — 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 623 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 624 
                 H 
                 H 
                 H 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 625 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 626 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 627 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 628 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 629 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 630 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 631 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 CH3 
                 H 
                 — 
                 — 
               
               
                 632 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 633 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 634 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 635 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 636 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 637 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 638 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 639 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 640 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 641 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 642 
                 F 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 643 
                 CF3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 644 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 645 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 646 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 647 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 648 
                 CF3 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 649 
                 H 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 650 
                 — 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 651 
                 — 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 652 
                 — 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 653 
                 — 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 654 
                 — 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 655 
                 — 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 656 
                 — 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 657 
                 — 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 658 
                 — 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                 659 
                 — 
                 H 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
             
               
                   
                 TABLE 19 
               
             
            
               
                   
                   
               
               
                   
                 A 
                 B 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 M 
                 m′ 
                 A 
                 B 
                 R1 
                 R2 
                 R3 
                 R4 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 660 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 661 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 CH3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 662 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C2H5 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 663 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C3H7 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 664 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C4H9 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 665 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C(CH3)3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 666 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C5H11 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 667 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C6H13 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 668 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C7H15 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 669 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C8H17 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 670 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C9H19 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 671 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C10H21 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 672 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C11H23 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 673 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C12H25 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 674 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C13H27 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 675 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C14H29 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 676 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C15H31 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 677 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C16H33 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 678 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C17H35 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 679 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C18H37 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 680 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C19H39 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 681 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C20H41 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 682 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 683 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 684 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 685 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 686 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 687 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 F 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 688 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 689 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 F 
                 F 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
             
               
                   
                 TABLE 20 
               
             
            
               
                   
                   
               
               
                   
                 A 
                 B 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 M 
                 m′ 
                 A 
                 B 
                 R1 
                 R2 
                 R3 
                 R4 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 690 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 F 
                 F 
                 F 
                 F 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 H 
               
               
                 691 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 CF3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
               
               
                 692 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 CF3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
               
               
                 693 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 694 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 CF3 
                 H 
                 CF3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
               
               
                 695 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 CH3 
                 F 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 696 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C2H5 
                 F 
                 F 
                 H 
                 H 
                 H 
                 H 
                 F 
                 H 
               
               
                 697 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C3H7 
                 F 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 698 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C4H9 
                 F 
                 F 
                 H 
                 H 
                 H 
                 H 
                 F 
                 H 
               
               
                 699 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C5H11 
                 F 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 700 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C6H13 
                 F 
                 F 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
               
               
                 701 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C12H25 
                 F 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 702 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C15H31 
                 F 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 703 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C20H41 
                 F 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 704 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
               
               
                 705 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 F 
                 H 
               
               
                 706 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
                 H 
               
               
                 707 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
               
               
                 708 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 H 
                 H 
                 F 
                 F 
                 F 
                 F 
                 F 
                 F 
               
               
                 709 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 F 
                 F 
                 F 
                 F 
                 F 
                 F 
                 F 
                 F 
                 F 
                 F 
               
               
                 710 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 CF3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 F 
                 H 
                 H 
               
               
                 711 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C2F5 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 712 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C3F7 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 713 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C4F9 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
               
               
                 714 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C5F11 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 715 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C6F13 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 716 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C7F15 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 H 
               
               
                 717 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C8F17 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 718 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C10F21 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 719 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 C15F31 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
             
               
                 TABLE 21 
               
             
            
               
                   
               
               
                   
                   
                   
                   
                   
                 A 
                 B 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 M 
                 m′ 
                 A 
                 B 
                 R1 
                 R2 
                 R3 
                 R4 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
               
               
                   
               
               
                 720 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 721 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 CH3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 722 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 
                   
                     
                     
                         
                         
                     
                   
                 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
               
                 723 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 C2H5 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 724 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 C3H7 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 725 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 C4H9 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 726 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 C(CH3)3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 727 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 C5H11 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 728 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 C6H13 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 729 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 C7H15 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 730 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 C8H17 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 731 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 C9H19 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 732 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 C10H21 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 733 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 C11H23 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 734 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 C12H25 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 735 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 C15H31 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 736 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 C18H37 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 737 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 C20H41 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 738 
                 Ir 
                 2 
                 Ph 
                 Iq2 
                 H 
                 H 
                 CH3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 739 
                 Ir 
                 2 
                 Fl 
                 Iq2 
                 H 
                 H 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 740 
                 Ir 
                 2 
                 Tn1 
                 Iq2 
                 H 
                 H 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 741 
                 Ir 
                 2 
                 Tn2 
                 Iq2 
                 H 
                 H 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 742 
                 Ir 
                 2 
                 Tn3 
                 Iq2 
                 H 
                 H 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 743 
                 Ir 
                 2 
                 Tn4 
                 Iq2 
                 H 
                 H 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 744 
                 Ir 
                 2 
                 Np1 
                 Iq2 
                 H 
                 H 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 745 
                 Ir 
                 2 
                 Np2 
                 Iq2 
                 H 
                 H 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 746 
                 Ir 
                 2 
                 Cn1 
                 Iq2 
                 H 
                 H 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 747 
                 Ir 
                 2 
                 Cn2 
                 Iq2 
                 H 
                 H 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 748 
                 Ir 
                 2 
                 Pe 
                 Iq2 
                 H 
                 H 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 749 
                 Ir 
                 2 
                 Qn1 
                 Iq2 
                 H 
                 H 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 750 
                 Ir 
                 2 
                 Qn2 
                 Iq2 
                 H 
                 H 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
             
               
                   
                 TABLE 22 
               
             
            
               
                   
                   
               
               
                   
                 A 
                 B 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 M 
                 m′ 
                 A 
                 B 
                 R1 
                 R2 
                 R3 
                 R4 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 751 
                 Ir 
                 2 
                 Cz 
                 Iq2 
                 H 
                 C2H5 
                 — 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 752 
                 Ir 
                 2 
                 Ph 
                 Iq5 
                 H 
                 H 
                 CF3 
                 H 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 753 
                 Ir 
                 2 
                 Ph 
                 Iq5 
                 H 
                 H 
                 H 
                 CF3 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 754 
                 Ir 
                 2 
                 Ph 
                 Iq5 
                 CF3 
                 H 
                 CF3 
                 H 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 755 
                 Ir 
                 2 
                 Ph 
                 Iq5 
                 H 
                 H 
                 H 
                 H 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 756 
                 Ir 
                 2 
                 Ph 
                 Iq5 
                 H 
                 CH3 
                 F 
                 F 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 757 
                 Ir 
                 2 
                 Ph 
                 Iq5 
                 H 
                 C2H5 
                 F 
                 F 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 758 
                 Ir 
                 2 
                 Ph 
                 Iq5 
                 H 
                 C3H7 
                 F 
                 F 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 759 
                 Ir 
                 2 
                 Ph 
                 Iq5 
                 H 
                 C4H9 
                 F 
                 F 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 760 
                 Ir 
                 2 
                 Ph 
                 Iq5 
                 H 
                 C5H11 
                 F 
                 F 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 761 
                 Ir 
                 2 
                 Ph 
                 Iq5 
                 H 
                 C6H13 
                 F 
                 F 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 762 
                 Ir 
                 2 
                 Ph 
                 Iq5 
                 H 
                 C6F13 
                 H 
                 H 
                 — 
                 H 
                 H 
                 H 
                 H 
                 H 
               
               
                 763 
                 Ir 
                 2 
                 Ph 
                 Iq6 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 H 
                 H 
               
               
                 764 
                 Ir 
                 2 
                 Ph 
                 Iq6 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 — 
                 H 
                 H 
               
               
                 765 
                 Ir 
                 2 
                 Ph 
                 Iq6 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 — 
                 F 
                 H 
               
               
                 766 
                 Ir 
                 2 
                 Ph 
                 Iq6 
                 H 
                 CF3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 CF3 
                 H 
               
               
                 767 
                 Ir 
                 2 
                 Ph 
                 Iq6 
                 H 
                 CH3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 H 
                 H 
               
               
                 768 
                 Ir 
                 2 
                 Ph 
                 Iq6 
                 H 
                 C4H9 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 H 
                 H 
               
               
                 769 
                 Ir 
                 2 
                 Ph 
                 Iq6 
                 H 
                 C3F7 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 H 
                 H 
               
               
                 770 
                 Ir 
                 2 
                 Ph 
                 Iq6 
                 H 
                 OC6H13 
                 C3H7 
                 H 
                 H 
                 H 
                 H 
                 — 
                 H 
                 H 
               
               
                 771 
                 Ir 
                 2 
                 Ph 
                 Iq6 
                 F 
                 F 
                 F 
                 H 
                 H 
                 H 
                 H 
                 — 
                 CF3 
                 H 
               
               
                 772 
                 Ir 
                 2 
                 Ph 
                 Iq6 
                 H 
                 OCF3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 H 
                 H 
               
               
                 773 
                 Ir 
                 2 
                 Ph 
                 Iq7 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 H 
               
               
                 774 
                 Ir 
                 2 
                 Ph 
                 Iq7 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 H 
               
               
                 775 
                 Ir 
                 2 
                 Ph 
                 Iq7 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 H 
               
               
                 776 
                 Ir 
                 2 
                 Ph 
                 Iq7 
                 H 
                 CF3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 — 
                 H 
               
               
                 777 
                 Ir 
                 2 
                 Ph 
                 Iq7 
                 H 
                 CH3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 H 
               
               
                 778 
                 Ir 
                 2 
                 Ph 
                 Iq7 
                 H 
                 C4H9 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 H 
               
               
                 779 
                 Ir 
                 2 
                 Ph 
                 Iq7 
                 H 
                 C3F7 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 H 
               
               
                 780 
                 Ir 
                 2 
                 Ph 
                 Iq7 
                 H 
                 OC6H13 
                 C3H7 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 H 
               
               
                 781 
                 Ir 
                 2 
                 Ph 
                 Iq7 
                 F 
                 F 
                 F 
                 H 
                 H 
                 H 
                 H 
                 F 
                 — 
                 H 
               
               
                 782 
                 Ir 
                 2 
                 Ph 
                 Iq7 
                 H 
                 OCF3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 H 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
             
               
                   
                 TABLE 23 
               
             
            
               
                   
                   
               
               
                   
                 A 
                 B 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No 
                 M 
                 m 
                 n 
                 A 
                 B 
                 R1 
                 R2 
                 R3 
                 R4 
                 R5 
                 R6 
                 R7 
                 R8 
                 R9 
                 R10 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 783 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq8 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 784 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq8 
                 H 
                 H 
                 F 
                 H 
                 H 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 785 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq8 
                 F 
                 H 
                 F 
                 H 
                 H 
                 — 
                 H 
                 H 
                 F 
                 H 
               
               
                 786 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq8 
                 H 
                 CF3 
                 H 
                 H 
                 H 
                 — 
                 H 
                 H 
                 CF3 
                 H 
               
               
                 787 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq8 
                 H 
                 CH3 
                 H 
                 H 
                 H 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 788 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq8 
                 H 
                 C4H9 
                 H 
                 H 
                 H 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 789 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq8 
                 H 
                 C3F7 
                 H 
                 H 
                 H 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 790 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq8 
                 H 
                 OC6H13 
                 C3H7 
                 H 
                 H 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 791 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq8 
                 F 
                 F 
                 F 
                 H 
                 H 
                 — 
                 H 
                 H 
                 CF3 
                 H 
               
               
                 792 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq8 
                 H 
                 OCF3 
                 H 
                 H 
                 H 
                 — 
                 H 
                 H 
                 H 
                 H 
               
               
                 793 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq9 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 H 
                 H 
                 H 
               
               
                 794 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq9 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 — 
                 H 
                 H 
                 H 
               
               
                 795 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq9 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 — 
                 H 
                 F 
                 H 
               
               
                 796 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq9 
                 H 
                 CF3 
                 H 
                 H 
                 H 
                 H 
                 — 
                 H 
                 CF3 
                 H 
               
               
                 797 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq9 
                 H 
                 CH3 
                 H 
                 H 
                 H 
                 H 
                 — 
                 H 
                 H 
                 H 
               
               
                 798 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq9 
                 H 
                 C4H9 
                 H 
                 H 
                 H 
                 H 
                 — 
                 H 
                 H 
                 H 
               
               
                 799 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq9 
                 H 
                 C3F7 
                 H 
                 H 
                 H 
                 H 
                 — 
                 H 
                 H 
                 H 
               
               
                 800 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq9 
                 H 
                 OC6H13 
                 C3H7 
                 H 
                 H 
                 H 
                 — 
                 H 
                 H 
                 H 
               
               
                 801 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq9 
                 F 
                 F 
                 F 
                 H 
                 H 
                 H 
                 — 
                 H 
                 CF3 
                 H 
               
               
                 802 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq9 
                 H 
                 OCF3 
                 H 
                 H 
                 H 
                 H 
                 — 
                 H 
                 H 
                 H 
               
               
                 803 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq10 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
               
               
                 804 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq10 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
               
               
                 805 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq10 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 F 
                 — 
               
               
                 806 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq10 
                 H 
                 CF3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 — 
               
               
                 807 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq10 
                 H 
                 CH3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
               
               
                 808 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq10 
                 H 
                 C4H9 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
               
               
                 809 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq10 
                 H 
                 C3F7 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
               
               
                 810 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq10 
                 H 
                 OC6H13 
                 C3H7 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
               
               
                 811 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq10 
                 F 
                 F 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 CF3 
                 — 
               
               
                 812 
                 Ir 
                 3 
                 0 
                 Ph 
                 Iq10 
                 H 
                 OCF3 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
               
               
                   
               
            
           
         
       
     
     EXAMPLES 
     Hereinbelow, the present invention will be described more specifically based on Examples. 
     Examples 1 and 2 
     In these Examples, a device (effective display area=3 mm 2 ) having a device structure including 4 organic layers as shown in  FIG. 1(   c ) was prepared. An alkali-free glass sheet was used as a transparent substrate  15  and a 100 nm-thick indium oxide (ITO) film was formed by sputtering and patterned as a transparent electrode  14 . Further, α-NPD represented by the above-mentioned structural formula was vacuum-deposited in a layer thickness of 40 nm thereon as a hole-transporting layer  13 . Then, as an organic luminescence layer  12 , the above-mentioned CBP as a host material and a prescribed metal coordination compound in an amount of providing 8 wt. % were co-vacuum deposited in a layer thickness of 30 nm. Further, as an exciton diffusion-prevention layer  17 , BCP was vacuum-deposited in a thickness of 10 nm. Then, as an electron-transporting layer  16 , the above-mentioned Alq3 was subjected to resistance heating vacuum deposition at a vacuum of 10 −4  Pa to form an organic film in a thickness of 30 nm. 
     On the above, as a lower layer of a metal electrode layer  11 , an AlLi alloy film was disposed in a thickness of 15 nm, and a 100 nm-thick Al film was vacuum-deposited thereon to form a patterned metal electrode  11  disposed opposite to the transparent electrode  14  and having an electrode area of 3 mm 2 . 
     As the ligands, Example Compound No. 1 (Example 1) and Example Compound No. 28 (Example 2) shown in Table 1 were used respectively. 
     The performances of the thus-obtained EL devices were measured by using a micro-current meter (“4140B”, made by Hewlett-Packard Corp.) for a current-voltage characteristic and “BM7” (made by Topcon K.K.) for an emission luminance. The devices using the respective coordination compounds respectively exhibited a good rectifying characteristic. 
     At an applied voltage of 12 volts, the EL devices exhibited luminances as follows: 
     Device of Example 1 (Compound No. 1): 8000 cd/m 2    
     Device of Example 2 (Compound No. 28): 3500 cd/m 2    
     For examining luminescence characteristics of the Coordinate Compounds No. 1 and No. 28, the solutions were subjected to measurement of a luminescence spectrum. More specifically, each solution having a coordination compound concentration of 10 −4  mol/1 in toluene (or chloroform) was illuminated with excitation light of around 350 nm to measure a luminescence spectrum by using a spectral fluorophotometer (“F4500”, made by Hitachi K.K.). The luminescence spectra almost coincided with the spectra from the EL devices at the time of voltage application, whereby it was confirmed that the luminescences of the EL devices were emitted from the coordination compounds. (Refer to Example 7 and 8 described hereinafter.) 
     Examples 3-5, Comparative Example 1 
     Luminescence devices were prepared in the same manner as in Examples 1 and 2 except for using luminescence materials (Example Compounds) shown in Table 24 below. In Comparative Example 1, the above-mentioned Ir(ppy) 3  was used as a representative of conventional luminescence material. 
     A current conduction durability test was performed for each device by applying a DC voltage of 12 volts between the ITO electrode as the anode and the Al electrode as the cathode to measure a time within which the luminance was attenuated to a half. 
     The measurement results are shown in Table 24 and the Example materials exhibited a luminance half-attenuation period which was clearly longer than the Conventional luminescence material, thus providing a device having a high durability attributable to the material of the present invention. 
     
       
         
           
               
               
               
             
               
                 TABLE 24 
               
               
                   
               
               
                   
                 Luminescence 
                 Luminance half- 
               
               
                   
                 material 
                 attenuation period 
               
               
                 Example 
                 No. 
                 (hours) 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
            
               
                 3 
                 1 
                 1550 
               
               
                 4 
                 24 
                 1100 
               
               
                 5 
                 28 
                 1350 
               
               
                 Comp. 1 
                 Ir(ppy) 3   
                 350 
               
               
                   
               
            
           
         
       
     
     Example 6 
     A simple matrix type organic EL device as shown in  FIG. 2  was prepared in the following manner. 
     On a glass substrate  21  measuring 100 nm-length, 100 mm-width and 1.1 mm-thickness, a ca. 100 nm-thick ITO film was formed by sputtering and patterned into 100 lines of 100 μm-wide transparent electrodes  22  (anode side) with a spacing of 40 μm as simple matrix electrodes. Then, formed layers of identical organic materials were found under identical conditions as in Example 1 to form an organic compound layer  23 . 
     Then, 100 lines of 100 μm-wide Al electrodes  24  were formed with a spacing of 40 μm by mask vacuum deposition so as to be perpendicular to the transparent electrodes  22  by vacuum deposition at a vacuum of 2.7×10 −3  Pa. The metal electrodes (cathode)  24  were formed as a lamination of 10 nm-thick layer of Al/Li alloy (Li: 1.3 wt. %) and then 150 nm-thick layer of Al. 
     The thus-obtained 100×100-simple matrix-type organic EL device was subjected to a simple matrix drive in a glove box filled with nitrogen at voltages of 7 volts to 13 volts by using a scanning signal of 10 volts and data signals of ±3 volts. As a result of an interlaced drive at a frame efficiency of 30 Hz, respectively, luminescence images could be confirmed. 
     Example 7 
     Synthesis of Example Compound No. 1 
     
       
         
         
             
             
         
       
     
     69.3 g (448 mmol) of isoquinoline N-oxide (made by Tokyo Kasei) and 225 ml of chloroform were placed and dissolved in a 1 liter-three-necked flask, and under stirring and cooling with ice, 219.6 g (1432 mmol) of phosphorus oxychloride was gradually added dropwise thereto while the internal temperature was held at 15-20° C. Thereafter, the temperature was raised, and reflux under stirring was performed for 3 hours. The reaction product was cooled by standing to room temperature and poured into iced water. After extraction with ethyl acetate, the organic layer washed with water until neutrality, and the solvent was removed under a reduced pressure to provide a dry solid, which was then purified by silica gel column chromatography (eluent: chloroform/hexane=5/1) to obtain 35.5 g (yield: 44.9%) of 1-chloroisoquinoline white crystal. 
     
       
         
         
             
             
         
       
     
     In a 100 ml-three-necked flask, 3.04 g (24.9 mole) of phenylboronic acid (made by Tokyo Kasei), 4.0 g of (25.0 mmole) of 1-chloroisoquinoline, 25 ml of toluene, 12.5 ml of ethanol and 25 ml of 2M-sodium carbonate aqueous solution were placed and stirred at room temperature under nitrogen stream, and 0.98 g (0.85 mmole) of tetrakis(triphenylphosphine)palladium (0) was added thereto. Thereafter, reflux under stirring was performed for 8 hours under nitrogen stream. After completion of the reaction, the reaction product was cooled and extracted by addition of cold water and toluene. The organic layer was washed with saline water and dried on magnesium sulfate, followed by removal of the solvent under a reduced pressure to provide dry solid. The residue was purified by silica gel column chromatography (eluent: chloroform/methanol=10/1) to obtain 2.20 g (yield=43.0%) of 1-phenylisoquinoline.  FIG. 7  shows a  1 H-NMR spectrum of a solution of the compound in heavy chloroform. 
     
       
         
         
             
             
         
       
     
     In a 100 ml-four-necked flask, 50 ml of glycerol was placed and heated at 130-140° C. under stirring and bubbling with nitrogen for 2 hours. Then, the glycerol was cooled by standing down to 100° C., and 1.03 g (5.02 mmole) of 1-phenylisoquinoline and 0.50 g (1.02 mmole) of iridium (III) acetylacetonate (made by Strem Chemicals, Inc.) were added, followed by 7 hours of heating around ±210° C. under stirring and nitrogen stream. The reaction product was cooled to room temperature and injected into 300 ml of 1N-hydrochloric acid to form a precipitate, which was filtered out and washed with water. The precipitate was purified by silica gel column chromatography with chloroform as the eluent to obtain 0.22 g (yield=26.8%) of red powdery tris(1-phenylisoquinoline-C 2 ,N)iridium (III). According to MALDI-TOF MS (matrix-assisted laser desorption ionization-time of fight mass spectroscopy), the compound exhibited M +  (mass number of the corresponding cation formed by removal of 1 electron) of 805.2. 
     A solution in heavy chloroform of the compound provided a  1 H-NMR spectrum as shown in  FIG. 8 . A chloroform solution of the compound exhibited a luminescence spectrum showing λmax=619 nm and a quantum yield of 0.66 relative to 1.0 of Ir(ppy) 3 . 
     An EL device of Example 1 prepared by using the compound exhibited red luminescence showing λmax=620 nm under voltage application. 
     Example 8 
     Synthesis of Example Compound No. 28 
     
       
         
         
             
             
         
       
     
     In a 100 ml-three-necked flask, 2.91 g (12.2 mmole) of 9,9-dimethylfluorene-2-boronic acid, 2.00 g (12.2=mole) of 1-chloroisoquinoline, 10 ml of toluene, 5 ml of ethanol and 10 ml of 2M-sodium carbonate aqueous solution were placed and stirred at room temperature under nitrogen stream, and 0.44 g (0.38 mmole) of tetrakis(triphenylphosphine)palladium (0) was added thereto. Thereafter, reflux under stirring was performed for 5 hours under nitrogen stream. After completion of the reaction, the reaction product was cooled and extracted by addition of cold water and toluene. The organic layer was washed with saline water and dried on magnesium sulfate, followed by removal of the solvent under a reduced pressure to provide dry solid. The residue was purified by silica gel column chromatography (eluent: toluene/ethyl acetate=50/1) to obtain 2.13 g (yield=54.2%) of 1-(9,9-dimethylfluorene-2-yl) isoquinoline. 
     
       
         
         
             
             
         
       
     
     In a 100 ml-four-necked flask, 50 ml of glycerol was placed and heated at 130-140° C. under stirring and bubbling with nitrogen for 2 hours. Then, the glycerol was cooled by standing down to 100° C., and 1.61 g (5.01 mmole) of 1-(9,9-dimethylfluorene-2-yl)isoquinoline and 0.50 g (1.02 mmole) of iridium (III) acetylacetonate were added, followed by 8 hours of reflux under stirring and nitrogen stream. The reaction product was cooled to room temperature and injected into 600 ml of 1N-hydrochloric acid to form a precipitate, which was filtered out and washed with water. The precipitate was purified by silica gel column chromatography with chloroform as the eluent to obtain 0.38 g (yield 32.3%) of red powdery tris[1-(9,9-dimethylfluorene-2-yl)isoquinoline-C 3 ,N]iridium (III). According to MALDI-TOF MS, the compound exhibited M +  of 1153.4. 
     A toluene solution of the compound exhibited a luminescence spectrum showing λmax=648 nm and a quantum yield of 0.66 relative to 1.0 of Ir(ppy) 3 . 
     An EL device of Example 2 prepared by using the compound exhibited red luminescence showing λmax=650 nm under voltage application. 
     Example 9 
     Synthesis of Example Compound No. 25 
     
       
         
         
             
             
         
       
     
     In a 100 ml-three-necked flask, 4.45 g (25.0 mmole) of thianaphthene-2-boronic acid (made by Aldrich Chemical Co., Inc.), 4.09 g (25.0 mmole) of 1-chloroisoquinoline, 25 ml of toluene, 12.5 ml of ethanol and 25 mol of 2M-sodium carbonate aqueous solution were placed and stirred at room temperature under nitrogen stream, and 0.98 g (0.85 mmole) of tetrakis(triphenylphosphine)palladium (0) was added thereto. Thereafter, reflux under stirring was performed for 8 hours under nitrogen stream. After completion of the reaction, the reaction product was cooled and extracted by addition of cold water and toluene. The organic layer was washed with saline water and dried on magnesium sulfate, followed by removal of the solvent under a reduced pressure to provide dry solid. The residue was purified by silica gel column chromatography (eluent: chloroform) to obtain 4.20 g (yield=64.3.%) of 1-(thianaphthene-2-yl)isoquinoline. 
     
       
         
         
             
             
         
       
     
     In a 100 ml-four-necked flask, 50 ml of glycerol was placed and heated at 130-140° C. under stirring and bubbling with nitrogen for 2 hours. Then, the glycerol was cooled by standing to 100° C., and 1.31 g (5.01 mmole) of 1-(thianaphthene-2-yl)-isoquinoline, and 0.50 g (1.02 mmole) of iridium (III) acetylacetone, were added, followed by 5 hours of heating around 210° C. under stirring and nitrogen stream. The reaction product was cooled to room temperature and poured into 300 ml of 1N-hydrochloric acid to form a precipitate, which was then filtered out and washed with water. The precipitate was purified by silica gel column chromatography with chloroform as the eluent to obtain 0.25 g (yield=25.2%) of red powdery tris[1-(thianaphthene-2-yl)-isoquinoline-C 3 ,N]iridium (III). According to MALDI-TOF MS, M +  of the compound of 973.1 was confirmed. A toluene solution of the compound exhibited a luminescence spectrum showing λmax=686 nm and a quantum yield of 0.07 relative to 1.0 of Ir(ppy) 3 . 
     An EL device was prepared in the same manner as in Example 1 except for using the compound instead of Compound No. 1 and was confirmed to emit deep red luminescence under voltage application. 
     Example 10 
     Synthesis of Example Compound No. 24 
     
       
         
         
             
             
         
       
     
     In a 100 ml-three-necked flask, 2.56 g (20.0 mmole) of 2-thiophene-2-boronic acid (made by Aldrich Co.), 3.27 g (20.0 mmole) of 1-chloroisoquinoline, 18 ml of toluene, 9 ml of ethanol and 18 mol of 2M-sodium carbonate aqueous solution were placed and stirred at room temperature under nitrogen stream, and 0.72 g (0.62 mmole) of tetrakis(triphenylphosphine)palladium (0) was added thereto. Thereafter, reflux under stirring was performed for 9 hours under nitrogen stream. After completion of the reaction, the reaction product was cooled and extracted by addition of cold water and toluene. The organic layer was washed with saline water and dried on magnesium sulfate, followed by removal of the solvent under a reduced pressure to provide dry solid. The residue was purified by silica gel column chromatography (eluent: chloroform) to obtain 2.40 g (yield=56.8%) of 1-(2-thienyl)isoquinoline. 
     
       
         
         
             
             
         
       
     
     In a 100 ml-four-necked flask, 50 ml of glycerol was placed and heated at 130-140° C. under stirring and bubbling with nitrogen for 2 hours. Then, the glycerol was cooled by standing to 100° C., and 1.05 g (4.97 mmole) of 1-(2-thienyl)isoquinoline, and 0.50 g (1.02 mmole) of iridium (III) acetylacetone, were added, followed by 8 hours of reflux under stirring and nitrogen stream. The reaction product was cooled to room temperature and poured into 600 ml of 1N-hydrochloric acid to form a precipitate, which was then filtered out and washed with water. The precipitate was purified by silica gel column chromatography with chloroform as the eluent to obtain 0.38 g (yield=45.2%) of red powdery tris[1-(2-thienyl)isoquinoline-C 3 ,N]iridium (III). According to MALDI-TOF MS, M +  of the compound of 823.1 was confirmed. A toluene solution of the compound exhibited a luminescence spectrum showing λmax=642 nm and a quantum yield of 0.43 relative to 1.0 of Ir(ppy) 3 . 
     An EL device was prepared in the same manner as in Example 1 except for using the compound instead of Compound No. 1 and was confirmed to emit red luminescence showing λmax=G40 nm under voltage application. 
     Example 11 
     
       
         
         
             
             
         
       
     
     In a 200 ml-three-necked flask, 3.40 g (25.0 mmole) of 4-methylphenyl-boronic acid (made by Aldrich Co.), 4.09 g (25.0 mmole) of 1-chloroisoquinoline, 25 ml of toluene, 12.5 ml of ethanol and 25 mol of 2M-sodium carbonate aqueous solution were placed and stirred at room temperature under nitrogen stream, and 0.98 g (0.85 mmole) of tetrakis(triphenylphosphine)-palladium (0) was added thereto. Thereafter, reflux under stirring was perforated for 8 hours under nitrogen stream. After completion of the reaction, the reaction product was cooled and extracted by addition of cold water and toluene. The organic layer was washed with saline water and dried on magnesium sulfate, followed by removal of the solvent under a reduced pressure to provide dry solid. The residue was purified by silica gel column chromatography (eluent: chloroform/methanol=10/1) to obtain 2.80 g (yield=51.1%) of 1-(4-methylphenyl)isoquinoline. 
     
       
         
         
             
             
         
       
     
     In a 200 ml-three-necked flask, 0.58 mg (1.64 mmole) of iridium (111) chloride-trihydrate (made by Acros Organics Co.), 1.61 g (7.34 mmole) of 1-(4-methylphenyl)isoquinoline, 45 ml of ethanol and 15 ml of water were placed and stirred for 30 min. at room temperature under nitrogen stream, followed by 24 hours of reflux under stirring. The reaction product was cooled to room temperature, and the precipitate was recovered by filtration and washed with water, followed successive washing with ethanol and acetone. After drying under a reduced pressure at room temperature, 1.02 g (yield=93.4%) of red powdery tetrakis[1-(4-methylphenyl)isoquinoline-C 2 ,N]-(μ-dichloro)diiridium (III) (Example Compound No. 661) was obtained.  FIG. 10  shows a  1 H-NMR spectrum of a heavy chloroform solution of the compound. A toluene solution of the compound exhibited a luminescence spectrum showing λmax=617 n and a quantum yield of 0.46 relative to 1.0 of Ir(ppy) 3 . 
     
       
         
         
             
             
         
       
     
     In a 200 ml-three-necked flask, 70 ml of ethoxyethanol, 0.95 g (0.72 mmole) of tetrakis[1-(4-methylphenyl)isoquinoline-C 2 ,N](μ-dichloro)-diiridium (III), 0.22 g (2.10 mmole) of acetylacetone and 1.04 g (9.91 mmole) of sodium carbonate, were placed and stirred for 1 hour at room temperature under nitrogen stream and then refluxed under stirring for 15 hours. The reaction product was cooled with ice, and the precipitate was filtered out and washed with water. The precipitate was then purified by silica gel column chromatography (eluent: chloroform/methanol=30/1) to obtain 0.43 g (yield=41.3%) of red powdery bis[1-(4-methylphenyl)isoquinoline-C 2 ,N](acetylacetonato)-iridium (III) (Example Compound No. 43). According to MALDI-TOF MS, M +  of 728.2 of the compound was confirmed.  FIG. 11  shows a  1 H-NMR of a heavy chloroform solution of the compound. A toluene solution of the compound exhibited a luminescence spectrum showing λmax=622 nm and a quantum yield of 0.70 relative to 1.0 of Ir(ppy) 3 . 
     
       
         
         
             
             
         
       
     
     In a 100 ml-three-necked flask, 0.27 g (1.27 mmole) of 1-(4-methylphenyl)isoquinoline, 0.36 g (0.49 mmole) of bis[1-(4-methylphenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium (Iii) and 25 ml of glycerol, were placed and heated around 180° C. under stirring and nitrogen stream. The reaction product was cooled to room temperature and poured info 170 ml of 1N-hydrochloric acid, and the precipitate was filtered out, washed with water and dried at 100° C. under a reduced pressure for 5 hours. The precipitate was purified by silica gel column chromatography with chloroform as the eluent to obtain 0.27 g (yield 64.5%) of red powdery tris[1-(4-methylphenyl)-isoquinoline-C 2 ,N]iridium (III) (Example Compound No. 19). According to MALDI-TOF MS, M +  of 847.3 of the compound was confirmed.  FIG. 12  shows a  1 H-NMR spectrum of a heavy chloroform solution of the compound. A toluene solution of the compound exhibited a luminescence spectrum showing λmax=619 nm and a quantum yield of 0.65 relative to 1.0 of Ir(ppy) 3 . 
     Example 12 
     The following compounds were successively produced in the same manner as in Example 11 except for using 4-n-hexylphenylboronic acid instead of the 4-methylphenylboronic acid. 
     Tetrakis[1-(4-n-hexylphenyl)isoquinoline-C 2 ,N[(μ-dichloro)diiridium (Example Compound No. 667) 
     luminescence spectrum of toluene solution: λmax=616 nm 
     quantum yield=0.40 relative to 1.0 of Ir(ppy) 3 . 
     Bis(1-(4-n-hexylphenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium (III) (Example Compound No. 196) 
     MALDI-TOF MS: M + =868.4 luminescence spectrum of toluene solution: λmax=625 nm 
     quantum yield=0.87 relative to 1.0 of Ir(ppy) 3    
     Tris[1-(4-n-hexylphenyl)isoquinoline-C 2 ,N]-iridium (III) (Example Compound. No. 192) 
     MALDI-TOF MS: M + =1057.5 
     luminescence spectrum of toluene solution: λmax=621 nm 
     quantum yield=0.88 relative to 1.0 of Ir(ppy) 3    
     Example 13 
     The following compounds were successively produced in the same manner as in Example 11 except for using 4-n-octylphenylboronic acid instead of the 4-methylphenylboronic acid. 
     Tetrakis[1-(4-n-octylphenyl)isoquinoline-C 2 ,N[(μ-dichloro)diiridium (Example Compound No. 669) 
     luminescence spectrum of toluene solution: λmax=617 nm 
     quantum yield=0.47 relative to 1.0 of Ir(ppy) 3 . 
     Bis[1-(4-n-octylphenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium (III) (Example Compound No. 218) 
     MALDI-TOF MS: M + =924.4 
     luminescence spectrum of toluene solution: λmax=625 nm 
     quantum yield=1.05 relative to 1.0 of Ir(ppy) 3    
       FIG. 13  shows a  1 H-NMR spectrum of a heavy chloroform solution of the compound. 
     Tris[1-(4-n-octylphenyl)isoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 214) 
     MALDI-TOF MS: M + =1141.6. 
     luminescence spectrum of toluene solution: λmax=620 nm 
     quantum yield=0.75 relative to 1.0 of Ir(ppy) 3    
     Example 14 
     The following compounds were successively produced in the same manner as in Example 11 except for using 4-tart-butylphenylboronic acid (made by Aldrich Co.) instead of the 4-methylphenylboronic acid. 
     Tetrakis[1-(4-t-butylphenyl)isoquinoline-C 2 ,N](μ-dichloro)diiridium (Example Compound No. 665) 
     luminescence spectrum of toluene solution: λmax=614 nm 
     quantum yield=0.39 relative to 1.0 of Ir(PPY) 3 . 
     Bis[1-(4-t-butylphenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium (III) (Example Compound No. 174) 
     MALDI-TOF MS: M + =812.3 
     luminescence spectrum of toluene solution: λmax=626 nm 
     quantum yield=0.66 relative to 1.0 of Ir(ppy) 3    
     Tris[1-(4-t-butylphenyl)isoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 170) 
     MALDI-TOF MS: M + =973.4 
     luminescence spectrum of toluene solution: λmax=618 nm 
     quantum yield=0.73 relative to 1.0 of Ir(ppy) 3    
     Example 15 
     The following compounds were successively produced in the same manner as in Example 11 except for using 3-fluorophenylboronic acid (made by Aldrich Co.) instead of the 4-methylphenylboronic acid. 
     Tetrakis[1-(5-fluorophenyl)isoquinoline-C 2 ,N](μ-dichloro)diiridium (Example Compound No. 684) 
     luminescence spectrum of toluene solution: λmax=625 nm 
     quantum yield=0.22 relative to 1.0 of Ir(ppy) 3 . 
     Bis[1-(5-fluorophenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium (III) (Example Compound No. 47) 
     MALDI-TOF MS: M + =736.2 
     luminescence spectrum of toluene solution: λmax=629 nm 
     quantum yield=0.65 relative to 1.0 of Ir(PPY) 3    
     Tris[1-(5-fluorophenyl)isoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 23) 
     MALDI-TOF MS: M + =859.2 
     luminescence spectrum of toluene solution: λmax=626 nm 
     quantum yield=0.62 relative to 1.0 of Ir(ppy) 3    
     Example 16 
     The following compounds were successively produced in the same manner as in Example 11 except for using 4-phenoxyphenylboronic acid instead of the 4-methylphenylboronic acid. 
     Bis[1-(4-phenoxyphenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium (III) (Example Compound No. 365) 
     MALDI-TOF MS: M + =884.2 
     luminescence spectrum of toluene solution: λmax=608 nm 
     quantum yield=0.65 relative to 1.0 of Ir(ppy) 3    
     Tris[1-(4-phenoxyphenyl)isoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 361) 
     MALDI-TOF MS: M + =1081.3 
     luminescence spectrum of toluene solution: λmax=604 nm 
     quantum yield=0.54 relative to 1.0 of Ir(PPY) 3    
     Example 17 
     The following compounds were successively produced in the same manner as in Example 11 except for using 3-methylphenylboronic acid instead of the 4-methylphenylboronic acid. 
     Bis[1-(4-5-methylphenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium (III) (Example Compound No. 44) 
     MALDI-TOF MS: M + =728.2 
     luminescence spectrum of toluene solution: λmax=638 nm 
     quantum yield=0.78 relative to 1.0 of Ir(ppy) 3    
     Tris[1-(4-5-methylphenyl)isoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 20) 
     MALDI-TOF MS: M + =847.3 
     luminescence spectrum of toluene solution: λmax=631 nm 
     quantum yield=0.71 relative to 1.0 of Ir(PPY) 3    
     Example 18 
     1-phenylisoquinoline synthesized in Example 7 was used instead of the 1-(4-methylphenyl)isoquinoline used in Example 11, and the following compound was prepared in a similar manner as in Example 11 via tetrakis(1-phenylisoquinoline-C 2 ,N)(μ-dichloro)-diiridium (III) (Example Compound No. 660). 
     Bis(1-phenylisoquinoline-C 2 ,N)(acetylacetonato)-iridium (III) (Example Compound No. 42) 
     MALDI-TOF MS: M + =700.2 
     luminescence spectrum of toluene solution: λmax=604 am 
     quantum yield=0.54 relative to 1.0 of Ir(PPY) 3    
     Example 19 
     1-(biphenyl-3-yl)isoquinoline was synthesized by using 3-biphenylboronic acid (made by Frontier Scientific, Inc.) instead of phenylboronic acid in Example 7, and similarly as in Example 7, tris[1-(biphenyl-3-yl)isoquinoline-C 2 ,N]iridium (III) (Example Compound No. 3) was prepared from the 1-(biphenyl-3-yl)isoquinoline and iridium (III) acetylacetonate. According to MALDI-TOF MS, M +  of the compound of 1033.3 was confirmed. A toluene solution of the compound exhibited a luminescence spectrum showing λmax=621 nm and a quantum yield of 0.53 relative to 1.0 of Ir(ppy) 3 . 
     Example 20 
     3-methyl-2,4-pentanedione (made by Aldrich Co.) instead of acetylacetone in Example 11, and similarly as in Example 11, bis[1-(4-methylphenyl)-isoquinoline-C 2 ,N](3-methyl-2,4-pentanedionato)-iridium (III) (Example Compound No. 126) was synthesized. According to MALDI-TOF MS, M +  of the compound of 742.2 was confirmed. A toluene solution of the compound exhibited a luminescence spectrum showing λmax=627 nm and a quantum yield of 0.81 relative to 1.0 of Ir(ppy) 3 . 
     Example 21 
     2,2,6,6-tetramethyl-3,5-heptanedione (made by Tokyo Kasei Kogyo) was used instead of acetylacetone in Example 11, and similarly as in Example 11, bis[1-(4-methylphenyl)isoquinoline-C 2 ,N](2,2,6,6-tetramethyl-3,5-heptanedionato)iridium (III) (Example Compound No. 127) was synthesized. According to MALDI-TOF MS, M +  of the compound of 812.3 was confirmed. A toluene solution of the compound exhibited a luminescence spectrum showing λmax=624 nm and a quantum yield of 0.76 relative to 1.0 of Ir(PPY) 3 . 
     Example 22 
     2-Phenylpyridine was used instead of the 1-(4-methylphenyl)isoquinoline used in Example 11, and similarly as in Example 11, bis(2-phenylpyridine-C 2 ,N)(acetylacetonato)iridium (III) was synthesized via (2-phenylpyridine-C 2 ,N)(μ-dichloro)diiridium (III). The compound was reacted with 1-phenylisoquinoline synthesized in Example 7 in a similar manner as in Example 11 to obtain bis(2-phenylpyridine-C 2 ,N)(1-phenylisoquinoline-C 2 ,N)iridium (III) (Example Compound No. 64). According to MALDI-TOF MS, M +  of the compound of 705.2 was confirmed. A toluene solution of the compound exhibited a luminescence spectrum showing λmax=618 nm and a quantum yield of 0.43 relative to 1.0 of Ir(ppy) 3 . 
     Example 23 
     Bis(1-phenylisoquinoline-C 2 ,N)(acetyl-acetonato)iridium (III) synthesized in Example 18 and 2-phenylpyridine were reacted in a similar manner as in Example 22 to obtain bis(1-phenylisoquinoline-C 2 ,N)(2-phenylpyridine-C 2 ,N)iridium (III) (Example Compound No. 31). According to MALDI-TOF MS, M +  of the compound of 755.2 was confirmed. A toluene solution of the compound exhibited a luminescence spectrum showing λmax=617 nm and a quantum yield of 0.46 relative to 1.0 of Ir(ppy) 3 . 
     Example 24 
     The following compounds were successively produced in the same manner as in Example 11 except for using 4-butylphenylboronic acid (made by Lancaster Synthesis Co.) instead of the 4-methylphenylboronic acid. 
     Tetrakis[1-(4-n-butylphenyl)isoquinoline-C 2 ,N](μ-dichloro)diiridium (Example Compound No. 664) 
     luminescence spectrum of toluene solution: λmax=629 nm 
     quantum yield=0.44 relative to 1.0 of Ir(ppy) 3 . 
     Bis[1-(4-butylphenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium (III) (Example Compound No. 163) 
     MALDI-TOF MS: M + =812.0 
     luminescence spectrum of toluene solution: λmax=626 nm 
     quantum yield=0.81 relative to 1.0 of Ir(ppy) 3    
     Tris[1-(4-butylphenyl)isoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 159) 
     MALDI-TOF MS: M + =973.3 
     luminescence spectrum of toluene solution: λmax=621 nm 
     quantum yield=0.82 relative to 1.0 of Ir(PPY) 3 . 
     Example 25 
     5-Aminoisoquinoline (made by Tokyo Kasei Kogyo K.K.) was used to synthesize 1-chloro-5-fluoroisoquinoline along the following path with yields as indicated. 
     
       
         
         
             
             
         
       
     
     In the process of Example 11, phenylboronic acid was used instead of the 4-methylphenyl-boronic acid and 1-chloro-5-fluoroisoquinoline was used instead of the 1-chloroisoquinoline to synthesize 1-phenyl-5-fluoroisoquinoline, which was used instead of the 1-(4-methylphenyl)isoquinoline otherwise in a similar manner as in Example 11 to synthesize the following compounds successively. 
     Tetrakis(1-phenyl-5-fluoroisoquinoline-C 2 ,N)(μ-dichloro)diiridium (III) (Example Compound No. 704) 
     luminescence spectrum of toluene solution: λmax=620 nm 
     quantum yield=0.38 relative to 1.0 of Ir(PPY) 3 . 
     Bis(1-phenyl-5-fluoroisoquinoline-C 2 ,N)-(acetylacetonato)iridium (III) (Example Compound No. 240) 
     MALDI-TOF MS: M + =735.8 
     luminescence spectrum of toluene solution: λmax=636 nm 
     quantum yield=0.70 relative to 1.0 of Ir(ppy) 3    
     Tris(1-phenyl-5-fluoroisoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 155) 
     MALDI-TOF MS: M + =858.9 
     luminescence spectrum of toluene solution: λmax=628 nm 
     quantum yield=0.55 relative to 1.0 of Ir(PPY) 3    
     Example 26 
     3-Nitro-2-hydroxypyridine (made by Aldrich Co.) was used to synthesize 1-chloro-8-azaisoquinoline along the following path. “Sulfo mix” used for the ring closure was prepared through a process described in J. Org. Chem., 1943, 8, 544-549. 
     
       
         
         
             
             
         
       
     
     The above-obtained 1-chloro-8-azaisoquinoline was used instead of the 1-chloroisoquinoline in Example 7 to synthesize 1-phenyl-8-azaisoquinoline, which was used instead of the 1-(4-methylphenyl)-isoquinoline otherwise in the same manner as in Example 11 to prepare the following compounds successively. 
     Tetrakis(1-phenyl-8-azaphenylisoquinoline-C 2 ,N)(μ-dichloro)diiridium (III) (Example Compound No. 755) 
     luminescence spectrum of toluene solution: λmax=635 nm 
     quantum yield=0.40 relative to 1.0 of Ir(PPY) 3 . 
     Bis(1-phenyl-8-azaphenylisoquinoline-C 2 ,N)-(acetylacetonato)iridium (III) (Example Compound No. 612) 
     MALDI-TOF MS: M + =701.1 
     luminescence spectrum of toluene solution: λmax=631 nm 
     Tris(1-phenyl-8-azaphenylisoquinoline-C 2 ,N)-iridium (III) (Example Compound No. 609) MALDI-TOF MS: M + =807.9 
     luminescence spectrum of toluene Solution: λmax=622 nm 
     Example 27 
     An EL device having a laminate structure as shown in  FIG. 1(   b ) was prepared. On an ITO electrode  14  patterned on a 1.1 mm-thick alkali-free glass substrate  15 , α-NPD was deposited in a thickness of 40 nm at a vacuum deposition rate of 0.1 nm/sec at a vacuum pressure of 10 −4  Pa to form a hole-transporting layer  13 , and then CBP and tris(1-phenylisoquinoline-C 2 ,N)iridium (III) (Example. Compound No. 1) in an amount of providing a concentration of 9% were co-vacuum-deposited to form a 40 nm-thick luminescence layer  12  while controlling the heating conditions of the vacuum deposition boats so as to provide vacuum deposition rates of 0.1 nm/sec for CBP and 0.09 nm/sec for the iridium complex. 
     Then, an electron-transporting layer was formed in a thickness of 40 nm by vacuum deposition of bathophenanthroline Bphen represented by a structural formula shown below at a rate of 0.1 nm/sec. 
     
       
         
         
             
             
         
       
     
     Thereon, a ca. 1 nm-thick potassium fluoride layer was formed as an electron-transporting layer  16  by vacuum deposition at a rate of 0.5 nm/sec, and then aluminum was vacuum-deposited in a thickness of 150 nm at a rate of 1 nm/sec to provide a cathode metal 11. 
     The device of this Example was prepared while aiming at the effects of (1) increased supply of electrons and suppression of hole leakage by use of Bphen, (2) improved electron-injection characteristic by use of KF and (3) optimization of optical layer thickness. The voltage-efficiency-luminance characteristics of the thus-obtained device are shown in  FIG. 5 . 
     The device of this Example succeeded in realizing efficiencies of 6.2 lm/W and 5.2 lm/W at luminances of 100 cd/m 2  and 300 cd/m 2 , respectively. CIE coordinates were (0.68, 0.317) at 40 cd/m 2 , (0.682, 0.315) at 113 cd/m 2  and (0.678, 0.317) at 980 cd/m 2 , thus showing that a sufficient color purity was provided according to a color standard of the NTSC. Thus, the luminescence color was substantially unchanged at different luminances and voltages. 
     Tris(1-phenylisoquinoline-C 2 ,N)iridium (III) having a ligand of 1-phenylisoquinoline can provide red luminescence according to the NTSC standard even without adding a substituent to the ligand skeleton for luminescence color adjustment of the complex, and is thus excellent as a red luminescence material. Further, it is also a desirable luminescence material from a practical viewpoint of shorter synthesis steps as the effect is attained by using a ligand having no substituent. 
     The drive conditions included an application voltage V=5 volts and a current J=1.5 mA/cm 2  at a luminance of 300 cd/m 2 , and also 10 volts and 520 mA/cm 2  at 14000 cd/m 2 . The external quantum efficiency (E.Q.E.) values (%) of the thus-prepared EL device are plotted on  FIG. 6  and showing efficiencies remarkably improving the efficiency of the conventional EL device, e.g., over 10% at 100 cd/m 2 . 
     Example 28 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 4-ethylphenylboronic acid (made by Lancaster Co.) instead of the 4-methylphenylboronic acid in Example 11. 
     Tetrakis[1-(4-ethylphenyl)isoquinoline-C 2 ,N(μ-dichloro)iridium (III) (Example Compound No. 662), 
     Bis[1-(4-ethylphenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium (III) (Example Compound No. 137), 
     Tris[1-(4-ethylphenyl)isoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 135). 
     Example 29 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 4-propylphenylboronic acid instead of the 4-methylphenylboronic acid in Example 11. 
     Tetrakis[1-(4-propylphenyl)isoquinoline-C 2 ,N](μ-dichloro)iridium (III) (Example Compound No. 663); 
     Bis[1-(4-propylphenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium (III) (Example Compound No. 148), 
     Tris[1-(4-propylphenyl)isoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 144). 
     Example 30 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 4-isopropylphenylboronic acid (made by Lancaster Co.) instead of the 4-methylphenylboronic acid in Example 11. 
     Tetrakis[1-(4-isopropylphenyl)isoquinoline-C 2 ,N](μ-dichloro)iridium (III), 
     Bis[1-(4-isopropylphenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium (III), 
     Tris[1-(4-isopropylphenyl)isoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 146). 
     Example 31 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 4-n-pentylphenylboronic acid instead of the 4-methylphenylboronic acid in Example 11. 
     Tetrakis[1-(4-n-pentylphenyl)isoquinoline-C 2 ,N](μ-dichloro)iridium (III) (Example Compound No. 666), 
     Bis[1-(4-n-pentylphenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium (III) (Example Compound No. 185), 
     Tris[1-(4-n-pentylphenyl)isoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 181). 
     Example 32 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 4-n-heptylphenylboronic acid instead of the 4-methylphenylboronic acid in Example 11. 
     Tetrakis[1-(4-n-heptylphenyl)isoquinoline-C 2 ,N](μ-dichloro)iridium (III) (Example Compound No. 660), 
     Bis[1-(4-n-heptylphenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium (III) (Example Compound No. 207), 
     Tris[1-(4-n-heptylphenyl)isoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 203). 
     Example 33 
     The following compounds were successively produced in the same manner as in Example 11 except for using 4-fluorophenylboronic acid (made by Aldrich Co.) instead of the 4-methylphenylboronic′acid. 
     Tetrakis[1-(4-n-hexylphenyl)isoquinoline-C 2 ,N](μ-dichloro)diiridium (Example Compound No. 683) 
     luminescence spectrum of toluene solution: λmax=602 nm 
     quantum yield=0.40 relative to 1.0 of Ir(ppy) 3 . 
     Bis[1-(4-fluorohexylphenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium (III) (Example Compound No. 46) 
     MALDI-TOF MS: M + =737.2 
     luminescence spectrum of toluene solution: λmax=603 nm 
     quantum yield=0.95 relative to 1.0 of Ir(ppy) 3    
     Tris[1-(4-fluorophenyl)isoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 22) 
     MALDI-TOF MS: M + =859.2 
     luminescence spectrum of toluene solution: λmax=596 nm 
     quantum yield=0.92 relative to 1.0 of Ir(ppy) 3    
     Example 34 
     The following compounds were successively produced in the same manner as in Example 11 except for using 4-fluoro-3-methylphenylboronic acid (made by Aldrich Co.) instead of the 4-methylphenylboronic acid. 
     Tetrakis[1-(4-fluoro-5-methylphenyl)isoquinoline-C 2 ,N](μ-dichloro)diiridium (Example Compound No. 738) 
     luminescence spectrum of toluene solution: λmax=618 nm 
     Bis[1-(4-fluoro-5-methylphenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium (III) (Example Compound No. 222) 
     MALDI-TOF MS: M + =765.2 
     luminescence spectrum of toluene solution: λmax=615 nm 
     Tris[1-(4-fluoro-5-methylphenyl)isoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 226) 
     MALDI-TOF MS: M + =901.1 
     luminescence spectrum of toluene solution: λmax=616 nm 
     Example 35 
     The following compounds were successively produced in the same manner as in Example 11 except for using 4-trifluoromethylphenylboronic acid (made by Lancaster Co.) instead of the 4-methylphenylboronic acid. 
     Tetrakis[1-(4-trifluoromethylphenyl)isoquinoline-C 2 ,N[(μ-dichloro)diiridium 
     luminescence spectrum of toluene solution: λmax=614 nm 
     Bis[1-(4-trifluoromethylphenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium (III) 
     MALDI-TOF MS: M + =836.1 
     luminescence spectrum of toluene solution: λmax=623 nm 
     quantum yield=0.23 relative to 1.0 of Ir(PPY) 3    
     Tris[1-(4-trifluoromethylphenyl)isoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 11) 
     MALDI-TOF MS: M + =1009.2 
     luminescence spectrum of toluene solution: λmax=608 nm 
     quantum yield=0.48 relative to 1.0 of Ir(ppy) 3 . 
     Example 36 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 3-trifluoromethylphenylboronic acid (made by. Lancaster Co.) instead of the 4-methylphenylboronic acid in Example 11. 
     Tetrakis[1-(5-trifluoromethylphenyl)isoquinoline-C 2 ,N](μ-dichloro)iridium (III) 
     Bis[1-(5-trifluoromethylphenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium (III) 
     Tris[1-(5-trifluoromethylphenyl)isoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 12). 
     Example 37 
     The following compounds were successively produced in the same manner as in Example 11 except for using 3,5-difluoro-3-methylphenylboronic acid (made by Aldrich Co.) instead of the 4-methylphenylboronic acid. 
     Tetrakis[1-(3,5-difluoro-3-methylphenyl)isoquinoline-C 2 ,N](μ-dichloro)diiridium (Example Compound No. 686) 
     luminescence spectrum of toluene solution: λmax=618 nm 
     Bis[1-(3,5-fluoro-3-methylphenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium (III) (Example Compound No. 425) 
     MALDI-TOF MS: M + =765.2 
     luminescence spectrum of toluene solution: λmax=625 nm 
     Tris[1-(3,5-difluoro-3-methylphenyl)isoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 421) 
     MALDI-TOF MS: M + =901.2 
     luminescence spectrum of toluene solution: λmax=616 nm 
     Example 38 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 2,3-difluorophenylboronic acid instead of the 4-methylphenylboronic acid in Example 11. 
     Tetrakis[1-(5,6-difluorophenyl)isoquinoline-C 2 ,N](μ-dichloro)iridium (III) 
     Bis[1-(5,6-difluorophenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium (III) (Example Compound No. 501), 
     Tris[1-(5,6-difluorophenyl)isoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 497). 
     Example 39 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 2,3-difluoro-4-n-butylphenylboronic acid instead of the 4-methylphenylboronic acid in Example 11. 
     Tetrakis[1-(4-n-butyl-5,6-difluorophenyl)-isoquinoline-C 2 ,N](μ-dichloro)iridium (III) (Example Compound No. 698), 
     Bis[1-(4-n-butyl-5,6-difluorophenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium(III) (Example Compound No. 534), 
     Tris[1-(4-n-butyl-5,6-difluorophenyl)isoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 530). 
     Example 40 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 1-phenyl-5-trifluoromethylisoquinoline, synthesized in the same manner as in Example 7 by using 1-chloro-5-trifluoromethylisoquinoline instead of the 1-chloroisoquinoline in Example 7. 
     Tetrakis[1-phenyl-5-trifluoromethylisoquinoline-C 2 ,N](μ-dichloro)iridium (III) (Example Compound No. 706). 
     Bis[1-phenyl-5-trifluoromethylisoquinoline-C 2 ,N]-(acetylacetonato)iridium (III), 
     Tris[1-phenyl-5-trifluoromethylisoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 83). 
     Example 41 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 1-phenyl-4-trifluoromethylisoquinoline, synthesized in the same manner as in Example 7 by using 1-chloro-4-trifluoromethylisoquinoline instead of the 1-chloroisoquinoline in Example 7. 
     Tetrakis[1-phenyl-4-trifluoromethylisoquinoline-C 2 ,N](μ-dichloro)iridium (III) (Example Compound No. 706), 
     Bis[1-phenyl-4-trifluoromethylisoquinoline-C 2 ,N]-(acetylacetonato)iridium (III), 
     Tris(1-phenyl-4-trifluoromethylisoquinoline-C 2 ,N)-iridium (III) (Example Compound No. 82). 
     Example 42 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 1-phenyl-4-trifluoromethylisoquinoline, synthesized in the same manner as in Example 7 by using 1-chloro-4-trifluoromethylisoquinoline instead of the 1-chloroisoquinoline in Example 7. 
     Tetrakis[1-phenyl-4-trifluoroisoquinoline-C 2 ,N](μ-dichloro)iridium (III) (Example Compound No. 705). 
     Bis[1-phenyl-4-trifluoroisoquinoline-C 2 ,N]-(acetylacetonato)iridium (III), 
     Tris[1-phenyl-4-trifluoroisoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 81). 
     Example 43 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 3,5-difluorophenylboronic acid and 1-chloro-5-fluoroisoquinoline instead of the 4-methylphenylboronic acid and 1-chloroisoquinoline, respectively, in Example 11. 
     Tetrakis[1-(3,5-difluorophenyl)-5-fluoroisoquinoline-C 2 ,N](μ-dichloro)diiridium (III). 
     Bis[1-(3,5-difluorophenyl)-5-fluoroisoquinoline-C 2 ,N](acetylacetonato)iridium (III). 
     Tris[1-(3,5-difluorophenyl)-5-fluoroisoquinoline-C 2 ,N]iridium (III) (Example Compound No. 232). 
     Example 44 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 4-difluorophenylboronic acid and 1-chloro-4-fluoroisoquinoline instead of the 4-methylphenylboronic acid and 1-chloroisoquinoline, respectively, in Example 11. 
     Tetrakis[1-(4-difluorophenyl)-4-fluoroisoquinoline-C 2 ,N](μ-dichloro)diiridium (III): 
     Bis[1-(4-difluorophenyl)-4-fluoroisoquinoline-C 2 ,N](acetylacetonato)iridium (III). 
     Tris[1-(4-difluorophenyl)-4=fluoroisoquinoline-C 2 ,N]iridium (III) (Example Compound No. 230). 
     Example 45 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 4-difluorophenylboronic acid and 1-chloro-5-fluoroisoquinoline instead of the 4-methylphenylboronic acid and 1-chloroisoquinoline, respectively, in Example 11. 
     Tetrakis[1-(4-difluorophenyl)-5-fluoroisoquinoline-C 2 ,N](μ-dichloro)diiridium (III). 
     Bis[1-(4-difluorophenyl)-5-fluoroisoquinoline-C 2 ,N](acetylacetonato)iridium (III). 
     Tris[1-(4-difluorophenyl)-5-fluoroisoquinoline-C 2 ,N]iridium (III) (Example Compound No. 228). 
     Example 46 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 4-trifluoromethylphenylboronic acid and 1-chloro-4-fluoroisoquinoline instead of the 4-methylphenylboronic acid and 1-chloroisoquinoline, respectively, in Example 11. 
     Tetrakis[1-(4-trifluorofluorophenyl)-4-fluoroisoquinoline-C 2 ,N](μ-dichloro)diiridium (III). 
     Bis[1-(4-trifluoromethylphenyl)-4-fluoroisoquinoline-C 2 ,N](acetylacetonato)iridium (III). 
     Tris[1-(4-trifluoromethylphenyl)-4-fluoroisoquinoline-C 2 ,N]iridium (III) (Example Compound No. 256). 
     Example 47 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 4-fluorophenylboronic acid and 1-chloro-4-trifluoromethylisoquinoline instead of the 4-methylphenylboronic acid and 1-chloroisoquinoline, respectively, in Example 11. 
     Tetrakis[1-(4-fluorophenyl)-4-trifluoromethylquinoline-C 2 ,N](μ-dichloro)diiridium (III). 
     Bis[1-(4-fluorophenyl)-4-trifluoromethylquinoline-C 2 ,N](acetylacetonato)iridium (III). 
     Tris[1-(4-fluorophenyl)-4-trifluoromethylisoquinoline-C 2 ,N]iridium (III) (Example Compound No. 231). 
     Example 48 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 4-fluorophenylboronic acid and 1-chloro-5-fluoroisoquinoline instead of the 4-methylphenylboronic acid and 1-chloroisoquinoline, respectively, in Example 11. 
     Tetrakis[1-(4-fluorophenyl)-5-trifluoromethylisoquinoline-C 2 ,N](μ-dichloro)diiridium (III). 
     Bis[1-(4-fluorophenyl)-5-trifluoromethylisoquinoline-C 2 ,N](acetylacetonato)iridium (III). 
     Tris[1-(4-fluorophenyl)-5-trifluoromethylisoquinoline-C 2 ,N]iridium (III) (Example Compound No. 229). 
     Example 49 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 4-trifluoromethylphenylboronic acid and 1-chloro-4-trifluoromethylisoquinoline instead of the 4-methylphenylboronic acid and 1-chloroisoquinoline, respectively, in Example 11. 
     Tetrakis[1-(4-trifluoromethylphenyl)-4-trifluoromethylisoquinoline-C 2 ,N](μ-dichloro)diiridium (III) (Example Compound No. 691). 
     Bis[1-(4-trifluoromethylphenyl)-4-trifluoromethylisoquinoline-C 2 ,N](acetylacetonato)iridium (III). 
     Tris[1-(4-trifluoromethylphenyl)-4-trifluoromethylisoquinoline-C 2 ,N]iridium (III) (Example Compound No. 260). 
     Example 50 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 4-trifluoromethylphenylboronic acid and 1-chloro-5-trifluoromethylisoquinoline instead of the 4-methylphenylboronic acid and 1-chloroisoquinoline, respectively, in Example 11. 
     Tetrakis[1-(4-trifluoromethylphenyl)-5-trifluoromethylisoquinoline-C 2 ,N](μ-dichloro)diiridium (III). 
     Bis[1-(4-trifluoromethylphenyl)-5-trifluoromethylisoquinoline-C 2 ,N](acetylacetonato)iridium (III). 
     Tris[1-(4-trifluoromethylphenyl)-5-trifluoromethylisoquinoline-C 2 ,N]iridium (III) (Example Compound No. 255). 
     Example 51 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 3,4,5-trifluorophenylboronic acid (made by Lancaster Co.) and 1-chloro-4-trifluoromethylisoquinoline instead of the 4-methylphenylboronic acid and 1-chloroisoquinoline, respectively, in Example 11. 
     Tetrakis[1-(3,4,5-trifluorophenyl)-4-trifluoromethylquinoline-C 2 ,N](μ-dichloro)diiridium (III). 
     Bis[1-(3,4,5-trifluorophenyl)-4-trifluoromethylisoquinoline-C 2 ,N](acetylacetonato)iridium (III). 
     Tris[1-(3,4,5-trifluorophenyl)-4-trifluoromethylisoquinoline-C 2 ,N]iridium (III) (Example Compound No. 253). 
     Example 52 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 3,4,5-trifluorophenylboronic acid (made by Lancaster Co.) and 1-chloro-5-trifluoromethylisoquinoline instead of the 4-methylphenylboronic acid and 1-chloroisoquinoline, respectively, in Example 11. 
     Tetrakis[1-(3,4,5-trifluorophenyl)-5-trifluoromethylisoquinoline-C 2 ,N](μ-dichloro)diiridium (III). 
     Bis[1-(3,4,5-trifluorophenyl)-5-trifluoromethylisoquinoline-C 2 ,N](acetylacetonato)iridium (III). 
     Tris[1-(3,4,5-trifluorophenyl)-5-trifluoromethylisoquinoline-C 2 ,N]iridium (III) (Example Compound No. 250). 
     Example 53 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 3,4,5,6-tetrafluorophenylboronic acid and 1-chloro-4-trifluoromethylisoquinoline instead of the 4-methylphenylboronic acid and 1-chloroisoquinoline, respectively, in Example 11. 
     Tetrakis[1-(3,4,5,6-tetrafluorophenyl)-4-trifluoromethylisoquinoline-C 2 ,N](μ-dichloro)diiridium (III). 
     Bis[1-(3,4,5,6-trifluorophenyl)-4-trifluoromethylisoquinoline-C 2 ,N](acetylacetonato)iridium (III). 
     Tris[1-(3,4,5,6-tetrafluorophenyl)-4-trifluoromethylisoquinoline-C 2 ,N]iridium (III) (Example Compound No. 268). 
     Example 54 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 3,4,5,6-tetrafluorophenylboronic acid and 1-chloro-5-trifluoromethylisoquinoline instead of the 4-methylphenylboronic acid and 1-chloroisoquinoline, respectively, in Example 11. 
     Tetrakis[1-(3,4,5,6-tetrafluorophenyl)-5-trifluoromethylisoquinoline-C 2 ,N](μ-dichloro)diiridium (III) (Example Compound No. 690). 
     Bis[1-(3,4,5,6-tetrafluorophenyl)-5-trifluoromethylisoquinoline-C 2 ,N](acetylacetonato)iridium (III). 
     Tris[1-(3,4,5,6-tetrafluorophenyl)-5-trifluoromethylisoquinoline-C 2 ,N]iridium (III) (Example Compound No. 272). 
     Example 55 
     It is easy to synthesize 1-chloro-3,4,5,6,7,8-hexafluoroisoquinoline along the following path according to processes described in references: J. Chem. Soc. C, 1966, 2328-2331; J. Chem. Soc. C, 1971, 61-67; J. Org. Chem., 1971, 29, 329-332 and Org, Syn., 1960, 40, 7-10: 
     
       
         
         
             
             
         
       
     
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 3,4,5,6-tetrafluorophenylboronic acid and the above-synthesized 1-chloro-3,4,5,6,7,8-hexafluoroisoquinoline instead of the 4-methylphenylboronic acid and 1-chloroisoquinoline, respectively, in Example 11. 
     Tetrakis[1-(3,4,5,6-tetrafluorophenyl)-3,4,5,6,7,8-hexafluoroisoquinoline-C 2 ,N](μ-dichloro)diiridium (III) (Example Compound No. 709). 
     Bis[1-(3,4,5,6-tetrafluorophenyl)-3,4,5,6,7,8-hexafluoroisoquinoline-C 2 ,N](acetylacetonato)iridium (III) (Example Compound No. 457). 
     Tris[1-(3,4,5,6-tetrafluorophenyl)-3,4,5,6,7,8-hexafluoroisoquinoline-C 2 ,N]iridium (III) (Example Compound No. 454). 
     Example 56 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 3-isopropylphenylboronic acid (made by Lancaster Co.) instead of the 4-methylphenylboronic acid in Example 11. 
     Tetrakis[1-(5-isopropylphenyl)isoquinoline-C 2 ,N](μ-dichloro)iridium (III), 
     Bis[1-(5-isopropylphenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium (III), 
     Tris[1-(5-isopropylphenyl)isoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 315). 
     Example 57 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 3-butylphenylboronic acid instead of the 4-methylphenylboronic acid in Example 11. 
     Tetrakis[1-(5-butylphenyl)isoquinoline-C 2 ,N](μ-dichloro)iridium (III) (Example Compound No. 725), 
     Bis[1-(5-butylphenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium (III), 
     Tris[1-(5-butylphenyl)isoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 316). 
     Example 58 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 3-octylphenylboronic acid (made by Lancaster Co.) instead of the 4-methylphenylboronic acid in Example 11. 
     Tetrakis[1-(5-octylphenyl)isoquinoline-C 2 N(μ-dichloro)iridium (III) (Example Compound No. 730), 
     Bis[1-(5-octylphenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium (III), 
     Tris[1-(5-octylphenyl)isoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 321). 
     Example 59 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 3-methoxyphenylboronic acid (made by Lancaster Co.) instead of the 4-methylphenylboronic acid in Example 11. 
     Tetrakis[1-(5-methoxyphenyl)isoquinoline-C 2 ,N(μ-dichloro)iridium (III), 
     Bis[1-(5-methoxyphenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium (III), 
     Tris[1-(5-methoxyphenyl)isoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 375). 
     Example 61 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 4-trifluoromethoxyphenylboronic acid (made by Aldrich Co.) and 1-chloro-4-trifluoromethylisoquinoline instead of the 4-methylphenylboronic acid and 1-chloroisoquinoline, respectively, in Example 11. 
     Tetrakis[1-(4-trifluoromethoxyphenyl)-4-trifluoromethylisoquinoline-C 2 ,N](μ-dichloro)diiridium (III). 
     Bis[1-(4-trifluoromethoxyphenyl)-4-trifluoromethylisoquinoline-C 2 ,N](acetylacetonato)iridium (III). 
     Tris[1-(trifluoromethoxyphenyl)-4-trifluoromethylisoquinoline-C 2 ,N]iridium (III) (Example Compound No. 411). 
     Example 62 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 4-trifluoromethoxyphenylboronic acid and 1-chloro-5-trifluoromethylisoquinoline instead of the 4-methylphenylboronic acid and 1-chloroisoquinoline, respectively, in Example 11. 
     Tetrakis[1-(4-trifluoromethoxyphenyl)-5-trifluoromethylisoquinoline-C 2 ,N](μ-dichloro)diiridium (111). 
     Bis[1-(4-trifluoromethoxyphenyl)-5-trifluoromethylisoquinoline-C 2 ,N](acetylacetonato)iridium (III). 
     Tris[1-(4-trifluoromethoxyphenyl)-5-trifluoromethylisoquinoline-C 2 ,N]iridium (III) (Example Compound No. 410). 
     Example 63 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 4-trifluoromethoxyphenylboronic acid and 1-chloro-4-fluoroisoquinoline instead of the 4-methylphenylboronic acid and 1-chloroisoquinoline, respectively, in Example 11. 
     Tetrakis[1-(4-trifluoromethoxyphenyl)-4-fluoroisoquinoline-C 2 ,N](μ-dichloro)diiridium (III). 
     Bis[1-(4-trifluoromethoxyphenyl)-4-fluoroisoquinoline-C 2 ,N](acetylacetonato)iridium (III). 
     Tris[1-(4-trifluoromethoxyphenyl)-4-fluoroisoquinoline-C 2 ,N]iridium (III) (Example Compound No. 409). 
     Example 64 
     Bis[1-(4-propylphenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium (III) is synthesized in a similar manner as in Example 11 by using 1-(4-propylphenyl)isoquinoline of Example 29 and via tetrakis[1-(4-propylphenyl)isoquinoline-C 2 ,N](μ-dichloro)diiridium (III). It is easy to synthesize bis[1-(4-propylphenyl)isoquinoline-C 2 ,N](1-phenylisoquinoline-C 2 ,N)iridium (III) (Example Compound No. 283) by reacting the compound with 1-phenylisoquinoline of Example 7. 
     Example 65 
     Bis[1-phenylisoquinoline-C 2 ,N]-(acetylacetonato)iridium (III) is synthesized in a similar manner as in Example 11 by using 1-phenylisoquinoline instead of 1-(4-methylphenyl)isoquinoline of Example 11 and via tetrakis[1-phenylisoquinoline-C 2 ,N](μ-dichloro)diiridium (III). It is easy to synthesize bis(1-isoquinoline-C 2 ,N)[1-(4-propylphenyl)-isoquinoline-C 2 ,N)iridium (III) (Example Compound No. 299) by reacting the compound with 1-(4-propylphenyl)-isoquinoline of Example 29. 
     Example 66 
     It is easy to synthesize the following compound in a similar manner as in Example 22 except for using 1-(4-hexylphenyl)isoquinoline instead of the 2-phenylpyridine used in Example 22. 
     Bis[1-(4-hexylphenyl)isoquinoline-C 2 ,N](1-phenylisoquinoline-C 2 ,N)iridium (III) (Example Compound No. 287). 
     Example 67 
     It is easy to synthesize the following compound in a similar manner as in Example 22 except for using 1-phenylisoquinoline and 1-(4-hexylphenyl)-isoquinoline instead of the 2-phenylpyridine and 1-phenylisoquinoline, respectively, in Example 22. 
     Bis(1-phenylisoquinoline-C 2 ,N)[1-(4-hexyphenyl)isoquinoline-C 2 ,N]iridium (III) (Example Compound No. 303). 
     Example 68 
     It is easy to synthesize the following compound in a similar manner as in Example 22 except for using 1-(4-octylphenyl)isoquinoline instead of the 2-phenylpyridine in Example 22. 
     Bis[1-(4-octylphenyl)isoquinoline-C 2 ,N](1-phenylisoquinoline-C 2 ,N)iridium (III) (Example Compound No. 289). 
     Example 69 
     It is easy to synthesize the following compound in a similar manner as in Example 22 except for using 1-phenylisoquinoline and 1-(4-octylphenyl)-isoquinoline instead of the 2-phenylpyridine and 1-phenylisoquinoline, respectively, in Example 22. 
     Bis(1-phenylisoquinoline-C 2 ,N)[1-(4-octylphenyl)isoquinoline-C 2 ,N]iridium (III) (Example Compound No. 305). 
     Example 70 
     Preparation of Activated Copper Powder 
     400 g (2.5 mmole) of copper sulfate is dissolved in 2500 ml of hot water and then cooled, and 219 mg (3.35 mole) of zinc powder is added thereto at the same temperature. After washing with water by decantation, 5%-hydrochloric acid is added thereto until hydrogen gas generation is terminated to dissolve the zinc. Copper powder is recovered by filtration, washed with water and then with methanol and dried to obtain 149 g of activated copper powder. 
     It is easy to synthesize 4-perfluorohexylphenylboronic acid by using the activated copper powder along the following path: 
     
       
         
         
             
             
         
       
     
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 4-perfluorohexylphenylboronic acid instead of the 4-methylphenylboronic acid in Example 11. 
     Tetrakis[1-(4-perfluorohexylphenyl)isoquinoline-C 2 ,N](μ-dichloro)iridium (III) (Example Compound No. 715), 
     Bis[1-(4-perfluorohexylphenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium (III), 
     Tris[1-(4-perfluorohexylphenyl)isoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 475). 
     Example 71 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 4-perfluorohexylphenylboronic acid and 1-chloro-4-fluoroisoquinoline instead of the 4-methylphenylboronic acid and 1-chloroisoquinoline, respectively, in Example 11. 
     Tetrakis[1-(4-perfluorohexylphenyl)-4-fluoroisoquinoline-C 2 ,N](μ-dichloro)diiridium (III). 
     Bis[1-(4-perfluorohexylphenyl)-4-fluoroisoquinoline-C 2 ,N](acetylacetonato)iridium (III). 
     Tris[1-(4-perfluorohexylphenyl)-4-fluoroisoquinoline-C 2 ,N]iridium (III) (Example Compound No. 478). 
     Example 72 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 4-perfluorohexylphenylboronic acid and 1-chloro-4-trifluoromethylisoquinoline instead of the 4-methylphenylboronic acid and 1-chloroisoquinoline, respectively, in Example 11. 
     Tetrakis[1-(4-perfluorohexylphenyl)-4-trifluoromethylisoquinoline-C 2 ,N](μ-dichloro)diiridium (III). 
     Bis[1-(4-perfluorohexylphenyl)-4-trifluoromethylisoquinoline-C 2 ,N](acetylacetonato)iridium (III). 
     Tris[1-(4-perfluorohexylphenyl)-4-trifluoromethylisoquinoline-C 2 ,N]iridium (III) (Example Compound No. 477). 
     Example 73 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 4-perfluorohexylphenylboronic acid and 1-chloro-5-fluoroisoquinoline instead of the 4-methylphenylboronic acid and 1-chloroisoquinoline, respectively, in Example 11. 
     Tetrakis[1-(4-perfluorohexylphenyl)-5-trifluoromethylisoquinoline-C 2 ,N](μ-dichloro)diiridium (III). 
     Bis[1-(4-perfluorohexylphenyl)-5-trifluoromethylisoquinoline-C 2 ,N](acetylacetonato)iridium (III). 
     Tris[1-(4-perfluorohexylphenyl)-5-trifluoromethylisoquinoline-C 2 ,N]iridium (III) (Example Compound No. 476). 
     Example 74 
     It is easy to synthesize the following compound in a similar manner as in Example 22 except for using 1-(4-perfluorohexylphenyl)isoquinoline instead of the 2-phenylpyridine in Example 22. 
     Bis[1-(4-perfluorohexylphenyl)isoquinoline-C 2 ,N](1-phenylisoquinoline-C 2 ,N)iridium (III) (Example Compound No. 479). 
     Example 75 
     It is easy to synthesize the following compound in a similar manner as in Example 22 except for, using 1-phenylisoquinoline and 1-(4-perfluorohexylphenyl)isoquinoline instead of the 2-phenylpyridine and 1-phenylisoquinoline, respectively, in Example 22. 
     Bis(1-phenylisoquinoline-C 2 ,N)[1-(4-perfluorohexylphenyl)isoquinoline-C 2 ,N]iridium (III) (Example Compound No. 480). 
     Example 76 
     It is easy to synthesize 4-(1H,1H,2H,2H-perfluoropentyloxy)phenylboronic acid along the following the path: 
     
       
         
         
             
             
         
       
     
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 4-(1H,1H,2H,2H-perfluoropentyloxy)-phenylboronic acid instead of the 4-methylphenylboronic acid in Example 11. 
     Tetrakis{1-[4-(1H,1H,2H,2H-perfluoropentyloxy)phenyl]isoquinoline-C 2 ,N}(μ-dichloro)iridium (III), 
     Bis{1-[4-(1H,1H,2H,2H-perfluoropentyloxy)phenyl]-isoquinoline-C 2 ,N}-(acetylacetonato)iridium (III), 
     Tris{1-[4-(1H,1H,2H,2H-perfluoropentyloxyethylphenyl]isoquinoline-C 2 ,N}-iridium (III) (Example Compound No. 469). 
     Example 77 
     It is easy to synthesize the following compound in a similar manner as in Example 22 except for using 1-[4-(1H,1H,2H,2H-perfluoropentyloxy)isoquinoline instead of the 2-phenylpyridine in Example 22. 
     Bis{1-[4-(1H,1H,2H,2H-perfluoropentyloxy)-phenyl]isoquinoline-C 2 ,N}(1-phenylisoquinoline-C 2 ,N)-iridium (III) (Example Compound No. 470). 
     Example 78 
     It is easy to synthesize the following compound in a similar manner as in Example 22 except for using 1-phenylisoquinoline and 1-[4-(1H,1H,2H,2H-perfluoropentyloxy)phenyl]isoquinoline instead of the 2-phenylpyridine and 1-phenylisoquinoline, respectively, in Example 22. 
     Bis(1-phenylisoquinoline-C 2 ,N){1-(4-(1H,1H,2H,2H-perfluoropentyloxy)phenyl]isoquinoline-C 2 ,N}iridium (III) (Example Compound No. 471). 
     Example 79 
     It is easy to synthesize 4-(1H,1H-perfluoroheptyloxy)phenylboronic acid along the following path: 
     
       
         
         
             
             
         
       
     
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 4-(1H,1H-perfluoroheptyloxy)-phenylboronic acid instead of the 4-methylphenylboronic acid in Example 11. 
     Tetrakis{1-[4-(1H,1H-perfluoroheptyloxy)phenyl]-isoquinoline-C 2 ,N}(μ-dichloro)iridium (III), 
     Bis{1-[4-(1H,1H-perfluoroheptyloxy)phenyl]-isoquinoline-C 2 ,N}-(acetylacetonato)iridium (III), 
     Tris{1-[4-(1H,1H-perfluoroheptyloxy)phenyl]-isoquinoline-C 2 ,N}-iridium (III) (Example Compound No. 481). 
     Example 80 
     It is easy to synthesize the following compound in a similar manner as in Example 22 except for using 1-[4-(1H,1H-perfluoroheptyloxy)phenyl]-isoquinoline instead of the 2-phenylpyridine in Example 22. 
     Bis{1-[4-(1H,1H-perfluoroheptyloxy)phenyl]-isoquinoline-C 2 ,N}(1-phenylisoquinoline-C 2 ,N)iridium (III) (Example Compound No. 483). 
     Example 81 
     It is easy to synthesize the following compound in a similar manner as in Example 22 except for using 1-phenylisoquinoline and 1-[4-(1H,1H-perfluoroheptyloxy)phenyl]isoquinoline instead of the 2-phenylpyridine and 1-phenylisoquinoline, respectively, in Example 22. 
     Bis(1-phenylisoquinoline-C 2 ,N){1-[4-(1H,1H-perfluoroheptyloxy)phenyl]isoquinoline-C 2 ,N}iridium (III) (Example Compound No. 484). 
     Example 82 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using phenylboronic acid and 1-chloro-4-hexylisoquinoline instead of the 4-methylphenylboronic acid and 1-chloroisoquinoline, respectively, in Example 11. 
     Tetrakis[1-phenyl-4-hexylisoquinoline-C 2 ,N](μ-dichloro)diiridium (III). 
     Bis[1-phenyl-4-hexylisoquinoline-C 2 ,N](acetylacetonato)iridium (III). 
     Tris[1-phenyl-4-hexylisoquinoline-C 2 ,N]iridium (III) (Example Compound No. 156). 
     Example 83 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using phenylboronic acid and 1-chloro-5-fluoroisoquinoline instead of the 4-methylphenylboronic acid and 1-chloroisoquinoline, respectively, in Example 11. 
     Tetrakis(1-phenyl-5-octylisoquinoline-C 2 ,N)(μ-dichloro)diiridium (III). 
     Bis(1-phenyl-5-octylisoquinoline-C 2 ,N)(acetylacetonato)iridium (III). 
     Tris(1-phenyl-5-octylisoquinoline-C 2 ,N)iridium (III) (Example Compound No. 220). 
     Example 84 
     It is easy to successively synthesize the following compounds in the same manner as in Example 11 except for using 3-heptyloxyphenylboronic acid (made by Lancaster co.) instead of the 4-methylphenylboronic acid in Example 
     Tetrakis[1-(5-heptyloxyphenyl)isoquinoline-C 2 ,N](μ-dichloro)iridium (III), 
     Bis[1-(5-heptyloxyphenyl)isoquinoline-C 2 ,N]-(acetylacetonato)iridium (III), 
     Tris[1-(5-heptyloxyphenyl)isoquinoline-C 2 ,N]-iridium (III) (Example Compound No. 270). 
     Example 85 
     It is easy to synthesize 1-chloro-7-azaisoquinoline by using 2,6-dihydroxy-4-methyl-3-pyridylcarbonitrile (made by Aldrich Co., catalog 37, 947-6) along the following path described in U.S. Pat. No. 4,859,671: 
     
       
         
         
             
             
         
       
     
     It is easy to synthesize 1-phenyl-7-azaisoquinoline by using 1-chloro-7-azaisoquinoline instead of the 1-chloroisoquinoline in Example 7, and successively synthesize tetrakis(1-phenyl-7-azaisoquinoline-C 2 ,N)(μ-dichloro)diiridium (III) and bis(1-phenyl-7-azaisoquinoline-C 2 ,N)(acetylacetonato)-iridium (III) to obtain tris(1-phenyl-7-azaisoquinoline-C 2 ,N)iridium (III) (Example Compound No. 783) in a similar manner as in Example 11. 
     Example 66 
     It is easy to synthesize 1-hydroxy-5-azaisoquinoline by using 3-methyl-picolinonitrile (made by Aldrich Co., catalog 51, 273-7) along the following path described in U.S. Pat. No. 4,176,183 and synthesize 1-chloro-5-azaisoquinoline in a similar manner as in Example 85. 
     
       
         
         
             
             
         
       
     
     It is easy to synthesize 1-phenyl-5-azaisoquinoline by using 1-chloro-5-azaisoquinoline instead of the 1-chloroisoquinoline in Example 7, and successively synthesize tetrakis(1-phenyl-5-azaisoquinoline-C 2 ,N)(μ-dichloro)diiridium (III) (Example Compound No. 763) and bis(1-phenyl-5-azaisoquinoline-C 2 ,N)(acetylacetonato)iridium (III) to obtain tris(1-phenyl-5-azaisoquinoline-C 2 ,N)iridium (III) (Example Compound No. 640) in a similar Manner as in Example 11. 
     Examples 87-95 
     Devices having a similar structure as in Example 1 were prepared and evaluated. Details, of device structures, layer thicknesses and evaluation results are shown in Table 25. 
     
       
         
           
               
               
               
               
               
             
               
                   
                 TABLE 25 
               
             
            
               
                   
                   
               
               
                   
                 Device structure * 
                   
                   
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
            
               
                 Exam- 
                   
                 luminescence 
                   
                   
                 current 
                 luminance 
                 current efficiency 
                 power efficiency 
               
               
                 ple No. 
                 H.T.L. 
                 layer 
                 E.D.P.L. 
                 E.T.L. 
                 mA/cm2 
                 cd/m2 
                 cd/A 
                 lm/W 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 87 
                 αNPD 
                 CBP: Compound 
                 BCP 
                 Alq 3 
                 10 
                 volts 
                 10 
                 volts 
                 100 
                 cd/m2 
                 300 
                 cd/m2 
                 100 
                 cd/m2 
                 300 
                 cd/m2 
               
               
                   
                   
                 No. 413(7%) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                 40 nm 
                 40 nm 
                 10 nm 
                 20 nm 
                 114 
                 800 
                 1 
                 0.86 
                 0.4 
                 0.3 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 88 
                 αNPD 
                 CBP: Compound 
                 BCP 
                 Alq 3 
                 10 
                 V 
                 10 
                 V 
                 100 
                 cd 
                 300 
                 cd 
                 100 
                 cd 
                 300 
                 cd 
               
               
                   
                   
                 No. 432(7%) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                 40 
                 40 
                 10 
                 20 
                 26 
                 1248 
                 6.9 
                 6.5 
                 2.8 
                 2.1 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 89 
                 αNPD 
                 CBP: Compound 
                 BCP 
                 Alq 3 
                 10 
                 V 
                 10 
                 V 
                 100 
                 cd 
                 300 
                 cd 
                 100 
                 cd 
                 300 
                 cd 
               
               
                   
                   
                 No. 408(5%) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                 40 
                 40 
                 10 
                 60 
                 9 
                 480 
                 6.5 
                 5.6 
                 2.4 
                 1.8 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 90 
                 αNPD 
                 CBP: Compound 
                 BCP 
                 Alq 3 
                 10 
                 V 
                 10 
                 V 
                 100 
                 cd 
                 300 
                 cd 
                 100 
                 cd 
                 300 
                 cd 
               
               
                   
                   
                 No. 433(5%) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                 40 
                 40 
                 10 
                 60 
                 12 
                 700 
                 6.69 
                 6.4 
                 2.93 
                 2.32 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 91 
                 αNPD 
                 CBP: Compound 
                 BCP 
                 Alq 3 
                 10 V 
                 100 
                 cd 
                 300 
                 cd 
                 100 
                 cd 
                 300 
                 cd 
               
               
                   
                   
                 No. 433(7%) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                 40 
                 40 
                 10 
                 60 
                 12.2 
                 876 
                 8.6 
                 7.8 
                 3.82 
                 2.9 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 92 
                 αNPD 
                 CBP: Compound 
                 BCP 
                 Alq 3 
                 10 V 
                 100 
                 cd 
                 300 
                 cd 
                 100 
                 cd 
                 300 
                 cd 
               
               
                   
                   
                 No. 433(9%) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                 40 
                 40 
                 10 
                 60 
                 18 
                 1180 
                 7.5 
                 7.2 
                 3.86 
                 2.9 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 93 
                 αNPD 
                 CBP: Compound 
                 BCP 
                 Alq 3 
                 10 V 
                 100 
                 cd 
                 300 
                 cd 
                 100 
                 cd 
                 300 
                 cd 
               
               
                   
                   
                 No. 517(7%) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                 40 
                 40 
                 10 
                 60 
                 3.3 
                 185 
                 5.75 
                 5.42 
                 1.95 
                 1.54 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 94 
                 αNPD 
                 CBP: Compound 
                 Balq 
                 Alq 3 
                 10 V 
                 100 
                 cd 
                 300 
                 cd 
                 100 
                 cd 
                 300 
                 cd 
               
               
                   
                   
                 No. 516(7%) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                 40 
                 40 
                 10 
                 60 
                 12.5 
                 611 
                 5.85 
                 5.26 
                 2.42 
                 1.80 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 95 
                 αNPD 
                 CBP: Compound 
                 Balq 
                 Alq 3 
                 10 V 
                 100 
                 cd 
                 100 
                 cd 
                 100 
                 cd 
                 300 
                 cd 
               
               
                   
                   
                 No. 412(7%) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                 40 
                 40 
                 10 
                 60 
                 15 
                 778 
                 5.3 
                 5.4 
                 2.2 
                 1.9 
               
               
                   
                   
               
               
                   
                 * H.T.L. = hole-transporting layer 
               
               
                   
                 E.D.P.L. = exciton diffusion-prevention layer 
               
               
                   
                 E.T.L. = electron-transporting layer 
               
            
           
         
       
     
     Balq used in the exciton diffusion-prevention layer used in Examples 94 and 95 has a structure shown below. 
     
       
         
         
             
             
         
       
     
     INDUSTRIAL APPLICABILITY 
     As described above, the luminescence device of the present invention using, as a luminescence center material, a metal coordination compound having a partial structure of the above formula (1) and particularly represented by the above formula (3) is an excellent device which not only allows high-efficiency luminescence but also retains a high luminance for a long period and allows luminescence of longer wavelength. Further, the luminescence device of the present invention shows excellent performances as a red display device.