Patent Publication Number: US-2021180176-A1

Title: Method for preparing bactericidal film having silicon nitride binding layer on glass and ceramics

Description:
TECHNICAL FIELD 
     This disclosure generally relates to the technical field of vacuum plating, and more particularly, to a method for preparing a bactericidal film having a silicon nitride binding layer on glass and ceramics. 
     BACKGROUND 
     Glass products such as glass screens are widely used on mobile phones, computers, televisions, and automobiles, and ceramic products such as tableware, tea wares, washbasins, and bathtubs are extensively applied in all fields, both of which play an increasingly important role in our daily lives. Due to the electrostatic absorption, dust in the air is easily absorbed on the surface of an electronic product, and the accumulation of dust provides a favorable environment for the breeding of bacteria, which may cause great harm to the user&#39;s health. Scientific research shows that bacteria such as  staphylococcus  and  Escherichia coli  carried on a mobile phone are 18 times that of a flushing toilet. Under such circumstances, it is necessary to regularly clean the glass screen to remove the dust and bacteria from the surface of the electronic product. The screens of mobile phones, televisions, and computers, as well as ceramic decorations, are the breeding ground of bacteria. Due to the peculiar properties of glass and ceramics, the removal of dust and bacteria cannot be simply achieved through wiping, and a long-term wiping may severely damage the appearance of the screens and ceramic products. As a result, special cleaners are required during cleaning. However, the cleaners sold on the market are merely used for removing dirt, unable to prevent bacteria from breeding. Thus, a method capable of protecting the glass screens and ceramic products from bacteria is particularly wanted. 
     Pat. No. CN201910500507.6 discloses a method for preparing a bactericidal film on glass using silicon oxide. The introduction of oxygen may damage a furnace body, and the generation of silver oxide caused by the residual oxygen in the furnace during silver target&#39;s sputtering may weaken the bactericidal ability. 
     SUMMARY 
     The purpose of the present disclosure is to provide a method for preparing a bactericidal film having a silicon nitride binding layer on glass and ceramics, which effectively avoids the furnace body from being damaged by oxygen introduced into the furnace for forming a silicon oxide bactericidal layer in the prior art, and significantly improves the bactericidal ability of the plated film by preventing the generation of silver oxide caused by a large amount of residual oxygen in the furnace during the silver target&#39;s sputtering. 
     To achieve the above purpose, the present disclosure adopts the following technical solution: a method for preparing a bactericidal film having a silicon nitride binding layer on glass and ceramics, including: cleansing and blow-drying workpieces; processing the workpieces with a vacuum furnace, wherein processing the workpieces with the vacuum furnace includes: hanging the workpieces on a hanging rack, and placing the hanging rack into the vacuum furnace, supplying a bias voltage to the hanging rack and vacuuming the furnace to a vacuum degree of 5.0×10−3 Pa, and initiating a rotating disc to make the workpieces rotate on the hanging rack and simultaneously make the hanging rack rotate within the vacuum furnace; plating a binding film layer on the workpiece, wherein plating a binding film layer on the workpiece includes: switching-on a power supply, wherein the power supply providing a regulated voltage from 30V to 40V, wherein a duty ratio is configured to control the power supply, wherein the duty ratio is between 20% to 30%, introducing argon at a first flow rate to enable the vacuum degree to reach 25×10−2 Pa, and forming a silicon nitride binding film layer on the surfaces of the workpieces by initiating a silicon sputtering target, and introducing nitrogen, which enables the vacuum degree to reach 35×10−2 Pa; forming a silicon carbide carrier layer on the surfaces of the workpieces by keep sputtering the silicon sputtering target, turning-off the nitrogen, introducing the argon at a second flow rate, and introducing acetylene gas at a third flow rate; forming a bactericidal film layer of silicon carbide and silver on the surfaces of the workpieces by keep sputtering the silicon sputtering target, continuously introducing the acetylene gas, and simultaneously initiating a silver sputtering target; completing the bactericidal film having a silicon nitride binding layer on glass and ceramics, wherein completing the bactericidal film includes: stop sputtering the silicon sputtering target and the sliver sputtering target, turning off gases, and cooling the workpieces from 5 minutes to 10 minutes, releasing the gases from the vacuum furnace section by section until pressure in the furnace and atmospheric pressure are balanced, and taking out the workpieces. 
     During the aforesaid process, the water-cooling system of the vacuum furnace operates normally, which allows the temperature in the whole process to be controlled below 100° C., such that the plating process is completed without damaging the glass workpieces and ceramic workpieces. Additionally, when the workpieces rotate on the hanging rack, the hanging rack rotates in the vacuum furnace, meaning that the rotation and revolution of the workpieces during the plating process are simultaneously achieved. In this way, the workpieces are uniformly plated during the plating process while protected from being damaged by an excessive local temperature rise caused by the target&#39;s sputtering during the course. Moreover, carbon atoms in residual acetylene gas are removed through extraction, which effectively prevents carbon atoms from attaching to the bactericidal film layer, so that the color of the bactericidal film layer remains unaffected. 
     In another aspect of the present disclosure, cleansing and blow-drying the workpieces includes: applying a screen cleaner cleansing or an ultrasonic cleansing to the workpieces, and blow-drying the workpieces at a blow-drying temperature not exceeding 110° C. with a blow-drying duration longer than 30 minutes. 
     The workpieces may be cleansed in various ways. Through the cleansing, the surfaces of the workpieces are kept clean and dry before plating, which may strengthen the binding force of the film layer, and significantly improve the plating quality of the bactericidal film. 
     In another aspect of the present disclosure, the bias voltage is between 15V to 65V. 
     In another aspect of the present disclosure, the rotating disc rotates at a rotation speed of 30 s/r. 1111 In another aspect of the present disclosure, the first flow rate is between 100 sccm to 250 sccm. Initiating the silicon sputtering target includes supplying a first current at 8 A to the silicon sputtering target, and plating the binding film layer further includes plating the binding film layer between 2 minutes to 10 minutes. 
     In another aspect of the present disclosure, the second flow rate is between 40 sccm to 80 sccm and the third flow rate is between 150 sccm to 250 sccm. Introducing acetylene gas at the third flow rate includes introducing the acetylene gas with an introduction duration between 1 minute to 5 minutes. 
     In another aspect of the present disclosure, initiating the silver sputtering target includes supplying a second current between 0.5 A to 1 A to the silver sputtering target with a sputtering duration between 1 minute to 4 minutes. 
     The present disclosure provides the following advantages: through adopting the techniques of the present disclosure, the whole process does not need chemical processing, and the film layers are plated without damaging the surfaces of the glass workpieces and ceramic workpieces. After plating the binding film layer using a silicon target and nitrogen, the nitrogen is turned off and then a carrier layer is plated using acetylene gas. The silicon atoms in the plated film and the large number of silicon atoms contained in the glass and ceramics have good binding force. After the binding film layer and the carrier layer are plated, the carrier layer is kept active and a silver sputtering target is initiated, which enables silver ions with bactericidal effect to be uniformly distributed in the silicon carbide film layer, thereby forming a bactericidal film with bactericidal effect. Additionally, the workpieces are hung on the hanging rack during the plating process, which allows the rotation and revolution of the workpieces to be simultaneously achieved, thus realizing a uniform plating during the target&#39;s sputtering while avoiding damage to the workpieces due to local high temperature. Moreover, without the introduction of oxygen during production, the furnace body is protected from being damaged, and the generation of silver oxide caused by the residual oxygen in the furnace during the silver target&#39;s sputtering is avoided. The whole process is healthy and eco-friendly. The present disclosure remains the appearance and various properties of glass and ceramics, achieves an ideal bactericidal effect, a convenient preparation and a low investment of equipment, and has a wide application range. 
    
    
     DETAILED DESCRIPTION 
     Detailed embodiments are combined hereinafter to clearly and completely describe the techniques of the present disclosure. Obviously, the described embodiments are merely a part but not all of the embodiments of the present disclosure. The specification of the present disclosure may allow those skilled in the art to obtain other embodiments without paying creative labor, and thus all of which shall fall into the scope of the present disclosure. 
     A method for preparing a bactericidal film having a silicon nitride binding layer on glass and ceramics, comprising the steps of: 
     Preprocessing: cleansing workpieces and blow-drying at a low temperature. 
     Vacuum processing: hanging the preprocessed workpieces on a hanging rack, and placing into a vacuum furnace; supplying a bias voltage to the metal hanging rack, and vacuuming the furnace to a vacuum degree of 5.0×10 −3  Pa; initiating a rotating disc, thus making the workpieces rotate on the hanging rack, and simultaneously making the hanging rack rotate within the vacuum furnace. 
     Plating a binding film layer: switching-on a power supply and regulating the voltage to 30-40V, wherein the duty ratio is 20-30%; introducing argon, thereby enabling the vacuum degree to reach 25×10 −2  Pa; subsequently, initiating a silicon sputtering target, and introducing nitrogen, which enables the vacuum degree to reach 35×10 −2  Pa, thus forming a silicon nitride binding film layer on the surfaces of the workpieces. 
     Plating a carrier layer: keeping the silicon target sputtering, turning-off the nitrogen, reducing the flow of argon, and introducing acetylene gas, thus forming a silicon carbide carrier layer on the surfaces of the workpieces. 
     Plating a bactericidal film layer: keeping the silicon target sputtering, continuously introducing acetylene gas, and simultaneously initiating a silver sputtering target, thus forming a bactericidal film layer of silicon carbide and silver on the surfaces of the workpieces. 
     Completing the film plating: stopping the silicon target and the sliver target first, and then turning off all the gases; cooling after 5-10 minutes; subsequently, releasing the gases from the vacuum furnace section by section until the pressure in the furnace and the atmospheric pressure are balanced; finally, taking out the workpieces, thereby completing the whole plating process. During the aforesaid process, the water-cooling system of the vacuum furnace operates normally, which allows the temperature in the whole process to be controlled below 100° C., such that the plating process is completed without damaging the glass workpieces and ceramic workpieces. Additionally, when the workpieces rotate on the hanging rack, the hanging rack rotates in the vacuum furnace, meaning that the rotation and revolution of the workpieces during the plating process are simultaneously achieved. In this way, the workpieces are uniformly plated during the plating process while protected from being damaged by an excessive local temperature rise caused by the target&#39;s sputtering during the course. Moreover, carbon atoms in residual acetylene gas are removed through extraction, which effectively prevents carbon atoms from attaching to the bactericidal film layer, so that the color of the bactericidal film layer remains unaffected. 
     In one of the embodiments, in step (1), the workpieces are cleansed by using a cleaner for glass and ceramics or by ultrasonic. The blow-drying temperature does not exceed a temperature of 110° C., and the blow-drying duration is longer than 30 minutes. The workpieces may be cleansed in various ways. Through the cleansing, the surfaces of the workpieces are kept clean and dry before plating, which may strengthen the binding force of the film layer, and significantly improve the plating quality of the bactericidal film. 
     In one of the embodiments, the bias voltage supplied to the metal hanging rack in step (2) is 15V-65V. 
     In one of the embodiments, the rotation speed within the vacuum furnace in step (2) is 30 s/r. 
     In one of the embodiments, in step (3), the flow rate of argon is 100-250 sccm, the current supplied to the target material is 8 A, and the plating duration is 2-10 minutes. The thickness of the binding film layer may be controlled through regulating the plating duration. A shorter plating duration may generate a transparent yellow plating film, and a longer plating duration may thicken the film layer, thus making the film layer turn brown and lowering its transparency. The plating duration may be controlled according to the actual needs of the products. 
     In one of the embodiments, in step (5), the flow rate of argon is reduced to 40-80 sccm, the flow rate of acetylene gas is 150-250 sccm, and the introduction duration of acetylene gas is 1-5 minutes. 
     In one of the embodiments, in step (5), the current supplied to the silver target is 0.5-1 A, and the sputtering duration of the sliver target is 1-4 minutes. 
     Embodiment 1 
     A method for preparing a bactericidal film having a silicon nitride binding layer on glass and ceramics, comprising the steps of: 
     Preprocessing: cleansing glass workpieces and ceramic workpieces, and then blow-drying at a temperature of 100° C. for 45 minutes, wherein the workpieces are cleansed by using a cleaner for glass and ceramics. 
     Vacuum processing: hanging the preprocessed workpieces on a hanging rack, and placing into a vacuum furnace; supplying a 15V bias voltage to the metal hanging rack, and vacuuming the furnace to a vacuum degree of 5.0×10 −3  Pa; subsequently, initiating a rotating disc, thus making the workpieces rotate on the hanging rack, and simultaneously making the hanging rack rotate within the vacuum furnace. 
     Plating a binding film layer: switching-on a power supply and regulating the voltage to 30V, wherein the duty ratio is 20%; introducing argon with a flow rate of 100 sccm, thereby enabling the vacuum degree to reach 25×10 −2  Pa; subsequently, initiating a silicon sputtering target, and introducing nitrogen, enabling the vacuum degree to reach 35×10 −2  Pa, wherein the current supplied to the silicon target is 8 A, and the plating duration is 2 minutes, thus forming a silicon nitride binding film layer on the surfaces of the workpieces. 
     Plating a carrier layer: switching-on the power supply and regulating the voltage to 32V, wherein the duty ratio is 25%; keeping the silicon target sputtering, turning-off the nitrogen, reducing the flow rate of argon to 90 sccm, and introducing acetylene gas, enabling the vacuum degree to reach 27×10 −2  Pa, wherein the current supplied to the silicon target is 8 A, and the plating duration is 2 minutes, thus forming a silicon carbide carrier layer on the surfaces of the workpieces. 
     Plating a bactericidal film layer: keeping the silicon target sputtering, continuously introducing acetylene gas with a flow rate of 90 sccm for 1 minute, and simultaneously initiating a silver sputtering target, thus forming a bactericidal film layer of silicon carbide and silver on the surfaces of the workpieces, wherein the current supplied to the silver target is 0.5 A, and the sputtering duration of the silver target is 1 minute. 
     Completing the film plating: stopping the silicon target, then stopping the silver target, and then turning off all the gases; cooling after waiting for 6 minutes; subsequently, releasing the gases from the vacuum furnace section by section until the pressure in the furnace and the atmospheric pressure are balanced; finally, taking out the workpieces, thereby completing the whole plating process. 
     Embodiment 2 
     A method for preparing a bactericidal film having a silicon nitride binding layer on glass and ceramics, comprising the steps of: 
     Preprocessing: cleansing glass workpieces and ceramic workpieces, and then blow-drying at a temperature of 103° C. for 40 minutes, wherein the workpieces are cleansed by using a cleaner for glass and ceramics. 
     Vacuum processing: hanging the preprocessed workpieces on a hanging rack, and placing into a vacuum furnace; supplying a 30V bias voltage to the metal hanging rack, and vacuuming the furnace to a vacuum degree of 5.0×10 −3  Pa; subsequently, initiating a rotating disc, thus making the workpieces rotate on the hanging rack, and simultaneously making the hanging rack rotate within the vacuum furnace. 
     Plating a binding film layer: switching-on a power supply and regulating the voltage to 32V, wherein the duty ratio is 25%; introducing argon with a flow rate of 170 sccm, thereby enabling the vacuum degree to reach 25×10 −2  Pa; subsequently, initiating a silicon sputtering target, and introducing nitrogen, enabling the vacuum degree to reach 35×10 −2  Pa, wherein the current supplied to the silicon target is 8 A, and the plating duration is 4 minutes, thus forming a silicon nitride binding film layer on the surfaces of the workpieces. 
     Plating a carrier layer: switching-on the power supply and regulating the voltage to 32V, wherein the duty ratio is 25%; keeping the silicon target sputtering, turning-off the nitrogen, reducing the flow rate of argon to 90 sccm, and introducing acetylene gas, enabling the vacuum degree to reach 27×10 −2  Pa, wherein the current supplied to the silicon target is 8 A, and the plating duration is 2 minutes, thus forming a silicon carbide carrier layer on the surfaces of the workpieces. 
     Plating a bactericidal film layer: keeping the silicon target sputtering, continuously introducing acetylene gas with a flow rate of 90 sccm for 1 minute, and simultaneously initiating a silver sputtering target, thus forming a bactericidal film layer of silicon carbide and silver on the surfaces of the workpieces, wherein the current supplied to the silver target is 0.6 A, and the sputtering duration of the silver target is 1 minute. 
     Completing the film plating: stopping the silicon target, then stopping the silver target, and then turning off all the gases; cooling after waiting for 7 minutes; subsequently, releasing the gases from the vacuum furnace section by section until the pressure in the furnace and the atmospheric pressure are balanced; finally, taking out the workpieces, thereby completing the whole plating process. 
     Embodiment 3 
     A method for preparing a bactericidal film having a silicon nitride binding layer on glass and ceramics, comprising the steps of: 
     Preprocessing: cleansing glass workpieces and ceramic workpieces, and then blow-drying at a temperature of 105° C. for 38 minutes, wherein the workpieces are cleansed by using a cleaner for glass and ceramics. 
     Vacuum processing: hanging the preprocessed workpieces on a hanging rack, and placing into a vacuum furnace; supplying a 50V bias voltage to the metal hanging rack, and vacuuming the furnace to a vacuum degree of 5.0×10 −3  Pa; subsequently, initiating a rotating disc, thus making the workpieces rotate on the hanging rack, and simultaneously making the hanging rack rotate within the vacuum furnace. 
     Plating a binding film layer: switching-on a power supply and regulating the voltage to 34V, wherein the duty ratio is 27%; introducing argon with a flow rate of 200 sccm, thereby enabling the vacuum degree to reach 25×10 −2  Pa; subsequently, initiating a silicon sputtering target, and introducing nitrogen, enabling the vacuum degree to reach 35×10 −2  Pa, wherein the current supplied to the silicon target is 8 A, and the plating duration is 6 minutes, thus forming a silicon nitride binding film layer on the surfaces of the workpieces. 
     Plating a carrier layer: switching-on the power supply and regulating the voltage to 36V, wherein the duty ratio is 32%; keeping the silicon target sputtering, turning-off the nitrogen, reducing the flow rate of argon to 90 sccm, and introducing acetylene gas, enabling the vacuum degree to reach 27×10 −2  Pa, wherein the current supplied to the silicon target is 8 A, and the plating duration is 6 minutes, thus forming a silicon carbide carrier layer on the surfaces of the workpieces. 
     Plating a bactericidal film layer: keeping the silicon target sputtering, continuously introducing acetylene gas with a flow rate of 90 sccm for 1 minute, and simultaneously initiating a silver sputtering target, thus forming a bactericidal film layer of silicon carbide and silver on the surfaces of the workpieces, wherein the current supplied to the silver target is 0.7 A, and the sputtering duration of the silver target is 3 minutes. 
     Completing the film plating: stopping the silicon target, then stopping the silver target, and then turning off all the gases; cooling after waiting for 8 minutes; subsequently, releasing the gases from the vacuum furnace section by section until the pressure in the furnace and the atmospheric pressure are balanced; finally, taking out the workpieces, thereby completing the whole plating process. 
     Embodiment 4 
     A method for preparing a bactericidal film having a silicon nitride binding layer on glass and ceramics, comprising the steps of: 
     Preprocessing: cleansing glass workpieces and ceramic workpieces, and then blow-drying at a temperature of 106° C. for 35 minutes, wherein the workpieces are cleansed by using a cleaner for glass and ceramics. 
     Vacuum processing: hanging the preprocessed workpieces on a hanging rack, and placing into a vacuum furnace; supplying a 60V bias voltage to the metal hanging rack, and vacuuming the furnace to a vacuum degree of 5.0×10 −3  Pa; subsequently, initiating a rotating disc, thus making the workpieces rotate on the hanging rack, and simultaneously making the hanging rack rotate within the vacuum furnace. 
     Plating a binding film layer: switching-on a power supply and regulating the voltage to 36V, wherein the duty ratio is 23%; introducing argon with a flow rate of 230 sccm, thereby enabling the vacuum degree to reach 25×10 −2  Pa; subsequently, initiating a silicon sputtering target, and introducing nitrogen, enabling the vacuum degree to reach 35×10 −2  Pa, wherein the current supplied to the silicon target is 8 A, and the plating duration is 8 minutes, thus forming a silicon nitride binding film layer on the surfaces of the workpieces. 
     Plating a carrier layer: switching-on the power supply and regulating the voltage to 36V, wherein the duty ratio is 33%; keeping the silicon target sputtering, turning-off the nitrogen, reducing the flow rate of argon to 90 sccm, and introducing acetylene gas, enabling the vacuum degree to reach 27×10 −2  Pa, wherein the current supplied to the silicon target is 8 A, and the plating duration is 8 minutes, thus forming a silicon carbide carrier layer on the surfaces of the workpieces. 
     Plating a bactericidal film layer: keeping the silicon target sputtering, continuously introducing acetylene gas with a flow rate of 90 sccm for 1 minute, and simultaneously initiating a silver sputtering target, thus forming a bactericidal film layer of silicon carbide and silver on the surfaces of the workpieces, wherein the current supplied to the silver target is 0.8 A, and the sputtering duration of the silver target is 4 minutes. 
     Completing the film plating: stopping the silicon target, then stopping the silver target, and then turning off all the gases; cooling after waiting for 9 minutes; subsequently, releasing the gases from the vacuum furnace section by section until the pressure in the furnace and the atmospheric pressure are balanced; finally, taking out the workpieces, thereby completing the whole plating process. 
     Embodiment 5 
     A method for preparing a bactericidal film having a silicon nitride binding layer on glass and ceramics, comprising the steps of: 
     Preprocessing: cleansing glass workpieces and ceramic workpieces, and then blow-drying at a temperature of 108° C. for 33 minutes, wherein the workpieces are cleansed by using a cleaner for glass and ceramics. 
     Vacuum processing: hanging the preprocessed workpieces on a hanging rack, and placing into a vacuum furnace; supplying a 65V bias voltage to the metal hanging rack, and vacuuming the furnace to a vacuum degree of 5.0×10 −3  Pa; subsequently, initiating a rotating disc, thus making the workpieces rotate on the hanging rack, and simultaneously making the hanging rack rotate within the vacuum furnace. 
     Plating a binding film layer: switching-on a power supply and regulating the voltage to 38V, wherein the duty ratio is 33%; introducing argon with a flow rate of 270 sccm, thereby enabling the vacuum degree to reach 25×10 −2  Pa; subsequently, initiating a silicon sputtering target, and introducing nitrogen, enabling the vacuum degree to reach 35×10 −2  Pa, wherein the current supplied to the silicon target is 8 A, and the plating duration is 2-10 minutes, thus forming a silicon nitride binding film layer on the surfaces of the workpieces. 
     Plating a carrier layer: switching-on the power supply and regulating the voltage to 40V, wherein the duty ratio is 35%; keeping the silicon target sputtering, turning-off the nitrogen, reducing the flow rate of argon to 90 sccm, and introducing acetylene gas, enabling the vacuum degree to reach 27×10 −2  Pa, wherein the current supplied to the silicon target is 8 A, and the plating duration is 2-10 minutes, thus forming a silicon carbide carrier layer on the surfaces of the workpieces. 
     Plating a bactericidal film layer: keeping the silicon target sputtering, continuously introducing acetylene gas with a flow rate of 90 sccm for 1 minute, and simultaneously initiating a silver sputtering target, thus forming a bactericidal film layer of silicon carbide and silver on the surfaces of the workpieces, wherein the current supplied to the silver target is 1 A, and the sputtering duration of the silver target is 4 minutes. 
     Completing the film plating: stopping the silicon target, then stopping the silver target, and then turning off all the gases; cooling after waiting for 10 minutes; subsequently, releasing the gases from the vacuum furnace section by section until the pressure in the furnace and the atmospheric pressure are balanced; finally, taking out the workpieces, thereby completing the whole plating process. 
     Embodiment 6 
     After respectively measuring the film layer binding force of the bactericidal film on each of the glass workpieces and ceramic workpieces obtained from the aforesaid embodiments 1-5, the measurement results are shown in the following table: 
     
       
         
           
               
               
             
               
                   
                   
               
             
            
               
                   
                 Embodiment (Screen Workpiece) 
               
            
           
           
               
               
               
               
               
               
            
               
                   
                 1 
                 2 
                 3 
                 4 
                 5 
               
               
                   
               
               
                 Binding Force (N) 
                 63 
                 65 
                 67.5 
                 70 
                 72 
               
               
                   
               
            
           
           
               
               
            
               
                   
                 Embodiment (Ceramic Workpiece) 
               
            
           
           
               
               
               
               
               
               
            
               
                   
                 1 
                 2 
                 3 
                 4 
                 5 
               
               
                   
               
               
                 Binding Force (N) 
                 64 
                 65 
                 68 
                 72 
                 74 
               
               
                   
               
            
           
         
       
     
     From the above results, it can be seen that, the film layer binding force of the bactericidal film on each of the glass workpieces and ceramic workpieces through adopting the techniques of the present disclosure is greater than 60N, which indicates that the film layer binding force is strong enough to meet the requirements of ordinary glass and ceramic products. 
     Embodiment 7 
     The glass workpieces obtained from embodiments 1-5 are all mobile screens made of the same material, which are respectively numbered as groups 1-5, and a conventional mobile screen made of the same material is taken as a comparison group. The number of bacterial colonies on the surface of the six groups of samples is respectively observed after 5, 7 and 10 hours under the same using condition. The results are shown in the following table: 
     
       
         
           
               
               
               
               
               
               
               
             
               
                   
               
               
                 Samples 
                   
                   
                   
                   
                   
                   
               
               
                 (Mobile 
                   
                   
                   
                   
                   
                 Comparison 
               
               
                 Screen) 
                 Group 1 
                 Group 2 
                 Group 3 
                 Group 4 
                 Group 5 
                 Group 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
            
               
                 5 hours 
                 8 
                 9 
                 10 
                 7 
                 6 
                 40 
               
               
                 (number/ 
               
               
                 cm 2 ) 
               
               
                 7 hours 
                 1 
                 4 
                 5 
                 3 
                 2 
                 53 
               
               
                 (number/ 
               
               
                 cm 2 ) 
               
               
                 10 hours  
                 0 
                 0 
                 0 
                 0 
                 0 
                 70 
               
               
                 (number/ 
               
               
                 cm 2 ) 
               
               
                   
               
            
           
         
       
     
     From the above results, it can be seen that the bactericidal film of the present disclosure significantly improves the bactericidal effect of the mobile screen. 
     Additionally, the ceramic workpieces obtained from embodiments 1-5 are all spoons made of the same material, which are respectively numbered as groups 1-5, and a conventional spoon made of the same material is taken as a comparison group. The number of bacterial colonies on the surface of the six groups of samples is respectively observed after 5, 7 and 10 hours under the same using condition. The results are shown in the following table: 
     
       
         
           
               
               
               
               
               
               
               
             
               
                   
               
               
                 Samples 
                   
                   
                   
                   
                   
                 Comparison 
               
               
                 (Spoon) 
                 Group 1 
                 Group 2 
                 Group 3 
                 Group 4 
                 Group 5 
                 Group 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
            
               
                 5 hours 
                 7 
                 8 
                 9 
                 6 
                 5 
                 38 
               
               
                 (number/ 
               
               
                 cm 2 ) 
               
               
                 7 hours 
                 1 
                 2 
                 3 
                 2 
                 1 
                 50 
               
               
                 (number/ 
               
               
                 cm 2 ) 
               
               
                 10 hours  
                 0 
                 0 
                 0 
                 0 
                 0 
                 60 
               
               
                 (number/ 
               
               
                 cm 2 ) 
               
               
                   
               
            
           
         
       
     
     From the above results, it can be seen that the bactericidal film of the present disclosure significantly improves the bactericidal effect of the spoon and thus possesses a high practical value. 
     The above is merely a description of preferred embodiments of the present disclosure, which cannot be understood as a limitation of the claims. Any equivalent modifications of the structure or process described in the specification of the present disclosure shall fall into the scope of the present disclosure.