Patent Publication Number: US-2012043569-A1

Title: Light emitting device and manufacturing method thereof

Description:
CROSS-REFERENCE TO RELATED APPLICATION 
     This application is based upon and claims the benefit of priority from Japanese Patent Application No. 2010-186548, filed on Aug. 23, 2010; the entire contents of which are incorporated herein by reference. 
     FIELD 
     Embodiments described herein relate generally to a light emitting device and a manufacturing method thereof. 
     BACKGROUND 
     Recently attention focuses on a so-called white-color Light Emitting Device (LED) in which a yellow phosphor such as YAG:Ce is combined with a blue LED to emit white-color light by single chip. Conventionally, the LED emits red, green, or blue light in monochromatic form, and it is necessary that the plural LEDs emitting monochrome wavelengths are driven in order to emit the white-color light or intermediate-color light. However, currently the combination of the light emitting diode and the phosphor removes the trouble to be obtain the white-color light with a simple structure. 
     An LED lamp in which the light emitting diode is used is applied to various display devices of a mobile device, a PC peripheral device, an OA device, various switches, a light source for backlight, and a display board. In the LED lamps, there is a strong demand for high efficiency. Additionally, there is a demand for high color rendering in general-purpose lighting applications, and there is a demand for high color gamut in backlight applications. High efficiency of the phosphor is required for the purpose of the high efficiency of the LED lamp, and a white-color light source in which a phosphor emitting blue excitation light, a phosphor excited by blue light to emit green light, and a phosphor excited by blue light to emit red light are combined is preferable to the high color rendering and the high color gamut. 
     The high-power LED generates heat by drive, and generally the phosphor is heated up to about 100 to about 200° C. Generally emission intensity of the phosphor is degraded when the temperature rise is generated. Therefore, desirably the degradation of the emission intensity (temperature quenching) is hardly generated even if the temperature rise is generated. 
     A sialon phosphor can be cited as an example of a phosphor that emits the green light when excited by blue light, and the sialon phosphor is properly used in the LED lamp. According to the sialon phosphor, the light emission is highly efficiently obtained with the small temperature quenching. Therefore, the high-efficiency, high-color-rendering, small-color-shift light emitting device is implemented by use of the sialon phosphor. 
     However, there is also a demand for further high efficiency in the light emitting device in which the sialon phosphor is used. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1  is a view illustrating dependence of a particle diameter on luminous efficiency of a phosphor. 
         FIG. 2  illustrates a SEM photograph of an example of a green phosphor (G) used in evaluation. 
         FIG. 3  is a schematic sectional view illustrating a light emitting device according to a first. 
         FIG. 4A  to  FIG. 4D  are schematic sectional views illustrating a method for manufacturing the light emitting device of the first embodiment. 
         FIG. 5  is a schematic sectional view illustrating a light emitting device according to a second embodiment. 
         FIG. 6A  to  FIG. 6D  are schematic sectional views illustrating a method for manufacturing the light emitting device of the second embodiment. 
         FIG. 7A  to  FIG. 7E  are schematic sectional views illustrating a method for manufacturing a light emitting device according to a third embodiment. 
         FIG. 8A  to  FIG. 8E  are schematic sectional views illustrating a method for manufacturing a light emitting device according to a fourth embodiment. 
         FIG. 9  is a schematic sectional view illustrating a light emitting device according to a fifth embodiment. 
         FIG. 10A  to  FIG. 10F  are schematic sectional views illustrating a method for manufacturing the light emitting device of the fifth embodiment. 
         FIG. 11  is a schematic sectional view illustrating a light emitting device according to a sixth embodiment. 
         FIG. 12A  to  FIG. 12F  are schematic sectional views illustrating a method for manufacturing the light emitting device of the sixth embodiment. 
         FIG. 13A  to  FIG. 13F  are schematic sectional views illustrating a method for manufacturing a light emitting device according to a seventh embodiment. 
         FIG. 14A  to  FIG. 14F  are schematic sectional views illustrating a method for manufacturing a light emitting device according to an eighth embodiment. 
         FIG. 15  is a schematic sectional view illustrating a light emitting device according to a ninth embodiment. 
         FIG. 16  is a schematic sectional view illustrating a light emitting device according to a tenth embodiment. 
         FIG. 17  is a schematic sectional view illustrating a light emitting device according to an eleventh embodiment. 
         FIG. 18  is a schematic sectional view illustrating a light emitting device according to a twelfth embodiment. 
         FIG. 19  is a schematic sectional view illustrating a light emitting device according to a thirteenth embodiment. 
         FIG. 20  is a schematic sectional view illustrating a light emitting device according to a fourteenth embodiment. 
         FIG. 21  is a wiring diagram of an LED chip of Example 1. 
     
    
    
     DETAILED DESCRIPTION 
     A light emitting device according to one embodiment includes a light emitting element that emits light having a wavelength of 250 nm to 500 nm and a fluorescent layer that is disposed on the light emitting element. The fluorescent layer includes a phosphor having a composition expressed by the following equation (1) and an average particle diameter of 12 μm or more. 
       (M 1−x1 Eu x1 ) 3−y Si 13−z Al 3+z O 2+u N 21−w   (1)
 
     (In the equation (1), M is an element that is selected from IA group elements, IIA group elements, IIIA group elements, IIIB group elements except Al, rare-earth elements, and IVB group elements. x1, y, z, u, and w satisfy the following relationship. 0&lt;x1≦1, −0.1≦y≦0.15, −1≦z≦1, −1&lt;u−w≦1.5) 
     A sialon phosphor having the composition expressed by the following equation (1) is a green phosphor (G). The green phosphor (G) emits light ranging from a blue-green color to a yellow-green color, that is, light having a peak at the wavelength of 490 to 580 nm, which is longer than the excitation light, when the green phosphor (G) is excited by light having the wavelength of 250 nm to 500 nm, that is, near-ultraviolet light or blue light. 
       (M 1−x1 Eu x1 ) 3−y Si 13−z Al 3+z O 2+u N 21−w   (1)
 
     (In the equation (1), M is an element that is selected from IA group elements, IIA group elements, IIIA group elements, IIIB group elements except Al, rare-earth elements, and IVB group elements. Eu is an emission center element. x1, y, z, u, and w satisfy the following relationship. 0&lt;x1≦1, −0.1≦y≦0.15, −1≦z≦1, −1&lt;u−w≦1.5) 
     A sialon phosphor having the composition expressed by the following equation (2) is a red phosphor (R). The green phosphor (R) emits light ranging from an orange color to a red color, that is, light having a peak at the wavelength of 580 to 700 nm, which is longer than the excitation light, when the red phosphor (R) is excited by the light having the wavelength of 250 nm to 500 nm, that is, the near-ultraviolet light or the blue light. 
       (M′ 1−x2 Eu x2 ) a Si b AlO c N d   (2)
 
     (In the equation (2), M′ is an element that is selected from IA group elements, IIA group elements, IIIA group elements, IIIB group elements except Al, rare-earth elements, and IVB group elements. Eu is the emission center element. x2, a, b, c, and d satisfy the following relationship. 0&lt;x≦1, 0.60&lt;a&lt;0.95, 2.0&lt;b&lt;3.9, 0.04≦c≦0.6, 4&lt;d&lt;5.7) 
     Embodiments will be described below with reference to the drawings. 
       FIG. 1  is a view illustrating dependence of a particle diameter on luminous efficiency of a phosphor. The LED including the fluorescent layer containing the phosphor in which the average particle diameter of the green phosphor (G) or red phosphor (R) is changed is produced, a total luminous flux is measured with an integrating sphere, and the total luminous flux is divided by a product of an injected current and an applied voltage to evaluate luminous efficiency. 
       FIG. 2  illustrates a SEM photograph of an example of a green phosphor (G) used in evaluation. As used herein, the average particle diameter means an average value of individually-measured maximum diameters of plural particles that are randomly extracted from fluorescent particles in a visual field of a SEM photograph. However, fine particles having particle diameters lower than 1 μm are excluded when the average value is computed. 
     When the phosphors are dispersed in resin or the like, the average particle diameter can be computed by observing a section of the phosphor with a SEM. 
     As is clear from  FIG. 1 , while the luminous efficiency depends dominantly on the particle diameter for the green phosphor, the clear dependence of the luminous efficiency on the particle diameter does not exist for the red phosphor. Referring to  FIG. 1 , from the viewpoint of obtaining the higher luminous efficiency, in the green phosphor, desirably the particle diameter is not lower than 12 μm, more desirably not lower than 20 μm, and most desirably not lower than 50 μm. 
     The green phosphor used in the embodiment has the composition of (Sr 0.92 Eu 0.08 )Si 4.75 AlON 7.33 . In the green phosphor expressed by the above-described equation (1), Sr 3 Al 3 Si 13 O 2 N 21  is used as a base material, and Sr, Si, Al, O, or N that is of the constituent element of Sr 3 Al 3 Si 13 O 2 N 21  is substituted with another element or solid solution of another metallic element such as Eu is performed. Accordingly, the green phosphor used in the embodiment has the substantially same structure as the green phosphor expressed by the above-described equation (1). Therefore, it is believed that the green phosphor used in the embodiment exerts the similar dependence of the luminous efficiency on the particle diameter. 
     The present invention is made based on knowledge on the dependence of the specific luminous efficiency on the particle diameter, found by the inventor, in the green phosphor expressed by the above-described equation (1). 
     First Embodiment 
     A light emitting device according to a first embodiment includes a light emitting element that is disposed on a board and emits light having a peak wavelength of 250 nm to 500 nm and a fluorescent layer that is disposed on the light emitting element. The fluorescent layer has the composition expressed by the following equation (1), and has the average particle diameter of 12 μm or more. 
       (M 1−x1 Eu x1 ) 3−y Si 13−z Al 3+z O 2+u N 21−w   (1)
 
     (In the equation (1), M is an element that is selected from IA group elements, IIA group elements, IIIA group elements, IIIB group elements except Al, rare-earth elements, and IVB group elements. Eu is an emission center element. x1, y, z, u, and w satisfy the following relationship. 0&lt;x1≦1, −0.1≦y≦0.15, −1≦z≦1, −1&lt;u−w≦1.5) 
       FIG. 3  is a schematic sectional view illustrating the light emitting device of the first embodiment. The light emitting device of the first embodiment includes plural blue LED chips  12  for a excitation light source mounted on a board  10 . For example, each LED chip  12  is connected to wiring (not illustrated) through a gold wire  14 . A driving current is supplied to the LED chip  12  from the outside through the wiring, whereby the LED chip  12  emits the blue light for excitation. 
     A hemispherical transparent resin layer  16  is provided on the LED chip  12 . A first fluorescent layer (red fluorescent layer)  18  is disposed such that the resin layer  16  is covered therewith. The first fluorescent layer  18  in which the red phosphors are dispersed in a transparent resin absorbs the blue light emitted from the LED chip  12  and converts the blue light into the red light. 
     For example, the red phosphor of the first fluorescent layer  18  has the composition expressed by the following equation (2). 
       (M′ 1−x2 Eu x2 ) a Si b AlO c N d   (2)
 
     (In the equation (2), M′ is an element that is selected from IA group elements, IIA group elements, IIIA group elements, IIIB group elements except Al, rare-earth elements, and IVB group elements. Eu is an emission center element. x2, y, z, u, and w satisfy the following relationship. 0&lt;x2≦1, 0.60&lt;a&lt;0.95, 2.0&lt;b&lt;3.9, 0.04 23  c≦0.6, 4&lt;d&lt;5.7) 
     Desirably, the element M′ is Sr. 
     A second fluorescent layer (green phosphor)  20  is disposed such that the first fluorescent layer  18  is covered therewith. The second fluorescent layer  20  in which the green phosphors are dispersed in the transparent resin absorbs the blue light emitted from the LED chip  12  and converts the blue light into the green light. In other words, the first fluorescent layer (red phosphor)  18  is disposed between the LED chip  12  and the second fluorescent layer (green phosphor)  20 . 
     The green phosphor in the second fluorescent layer has the composition expressed by the following equation (1), and the green phosphor has the average particle diameter of 12 μm or more. 
       (M 1−x1 Eu x1 ) 3−y Si 13−z Al 3+z O 2+u N 21−w   (1)
 
     (In the equation (1), M is an element that is selected from IA group elements, IIA group elements, IIIA group elements, IIIB group elements except Al, rare-earth elements, and IVB group elements. Eu is the emission center element. x1, y, z, u, and w satisfy the following relationship. 0&lt;x1≦1, −0.1≦y≦0.15, −1≦z≦1, −1&lt;u−w≦1.5) 
     Desirably, the element M is Sr. 
     As described above, the green phosphor in the second fluorescent layer  20  has the average particle diameter of 12 μm or more, which allows the high luminous efficiency to be obtained. From the viewpoint of obtaining the higher luminous efficiency, desirably the particle diameter is not lower than 20 μm, and more desirably not lower than 50 μm. The particle diameter may be less than 10 mm and more preferably less than 1 mm. 
     As to a ratio of the fluorescent particle and the resin, desirably the fluorescent particle is not lower than 10 weight percent with respect to the fluorescent layer, more desirably the fluorescent particle is not lower than 20 weight percent, and most desirably the fluorescent particle is not lower than 30 weight percent. This is because possibly the resin largely absorbs the light when the ratio of the resin in the fluorescent layer is increased. 
     According to the first embodiment, the high-efficiency light emitting device is implemented by the use of the green phosphor in which the composition and the average particle diameter are restricted as described above. 
     A hemispherical transparent resin layer  22  is provided such that the second fluorescent layer  20  is covered therewith. An outer surface of the transparent resin layer  22  is in contact with atmosphere (air). The transparent resin layer  22  has a function of suppressing total reflection of the blue light emitted from the LED chip  12 , the red light from the first fluorescent layer  18 , and the green light from the second fluorescent layer at the outer surface that becomes an interface with the atmosphere. 
     A stacked film having a four-layer structure including the transparent resin layer  16 , the first fluorescent layer  18 , the second fluorescent layer  20 , and the transparent resin layer  22  has a hemispherical shape. 
     In the light emitting device of the first embodiment, when the current is passed through the LED chip  12 , the light output from the transparent resin layer  22  becomes the white-color light. In the white-color light, the blue light emitted from the LED chip  12  to pass through the transparent resin layer  16 , first fluorescent layer  18 , second fluorescent layer  20 , and transparent resin layer  22 , the red light from the first fluorescent layer  18 , and the green light from the second fluorescent layer  20  are mixed. 
     In the light emitting device of the first embodiment having the above-described configuration, the stacked structure including the transparent resin layer  16 , the first fluorescent layer  18 , the first fluorescent layer  20 , and the transparent resin layer  22  is formed into the hemispherical shape, so that the emission color can be prevented from varying or a hue can be prevented from varying depending on a view angle. The blue light emitted from the LED chip  12  passes through the transparent resin layer  16 . In the first fluorescent layer  18 , the red phosphors that convert the blue light into the red light are dispersed in the transparent resin. In the first fluorescent layer  20 , the green phosphors that convert the blue light into the green light are dispersed in the transparent resin. The transparent resin layer  22  has the function of suppressing the total reflection of the blue light, red light, and green light at the outer surface that becomes the interface with the atmosphere. The excitation light from the LED chip  12  can be collected to enhance the light extracting efficiency. Additionally, an air layer can be prevented from being interposed among the layers, and the degradation of the transmittance of the resin and the luminous efficiency of the phosphor can be suppressed. 
     A method for manufacturing the light emitting device of the first embodiment will be described below. As described above, in the green phosphor using the first embodiment, the luminous efficiency depends on the particle diameter, and the luminous efficiency is improved with increasing particle diameter. At the same time, when the particle diameter of the phosphor is increased, a technique of falling in drops of the resin in which the phosphors are dispersed on the light emitting element with a dispenser (constant liquid delivery apparatus) is hardly adopted in forming the fluorescent layer. Because a diameter of a syringe of the dispenser is restricted, clogging is possibly generated when the particle diameter is increased. 
     In the method for manufacturing the light emitting device of the first embodiment, the light emitting element that emits the light having the wavelength of 250 nm to 500 nm is mounted on the surface of the board, a mask having an opening in a region where the light emitting element is mounted is placed on the board, the resin including the phosphor having the composition expressed by the following equation (1) and the average particle diameter of 12 μm or more is applied onto the mask, the resin except the resin with which the opening is filled is removed from the mask surface with squeeze, the mask is removed from the board, and a heat treatment is performed to cure the resin. 
       (M 1−x1 Eu x1 ) 3−y Si 13−z Al 3+z O 2+u N 21−w   (1)
 
     (In the equation (1), M is an element that is selected from IA group elements, IIA group elements, IIIA group elements, IIIB group elements except Al, rare-earth elements, and IVB group elements. Eu is the emission center element. x1, y, z, u, and w satisfy the following relationship. 0&lt;x1≦1, −0.1≦y≦0.15, −1≦z≦1, −1&lt;u−w≦1.5) 
     The light emitting device is produced with no use of the dispenser, because the method for manufacturing the light emitting device of the first embodiment has the above-described configuration. Therefore, the high-efficiency light emitting device can be produced by the stable manufacturing method. 
       FIG. 4A  to  FIG. 4D  are schematic sectional views illustrating a method for manufacturing the light emitting device of the first embodiment. The blue LED chips  12  for excitation light sources are mounted on the surface of the board  10 . Then, a metallic mask  24  having the opening in the region where the blue LED  12  is mounted is placed on the board  10 , and a transparent resin  26  is applied onto the mask  24  in a wide range of the mask  24  with no use of the dispenser. For example, the transparent resin  26  is a silicone resin. 
     The transparent resin  26  except the transparent resin  26  with which the opening is filled is removed from the surface of the mask  24  with a squeeze  28  ( FIG. 4A ). 
     The mask  24  is removed from the board  10 , and the board  10  is subjected to the heat treatment to cure the transparent resin  26 , thereby forming the transparent resin layer  16  ( FIG. 4B ). 
     Then, the metallic mask  30  having an opening corresponding to the region where the blue LED  12  is mounted is placed on the board  10 . The opening of the mask  30  is designed wider than that of the mask  24 . A binder resin  32  in which the red phosphors are dispersed is applied onto the mask  30  in the wide range of the mask  30  with no use of the dispenser. For example, the binder resin  32  is a silicone resin. 
     The binder resin  32  except the binder resin  32  with which the opening is filled is removed from the surface of the mask  30  with the squeeze  28  ( FIG. 4C ). 
     The mask  30  is removed from the board  10 , and the board  10  is subjected to the heat treatment to cure the binder resin  32 , thereby forming the first fluorescent layer  18  ( FIG. 4D ). 
     Then, the second fluorescent layer  20  and the transparent resin layer  22  are formed by repeating the similar process to produce the light emitting device illustrated in  FIG. 3 . 
     For example, the green phosphor that is included in the second fluorescent layer and expressed by the equation (1) can be synthesized using a nitride of the element M or a carbide of cyanamide of the nitride of the element M, a nitride, an oxide, or a carbide of an element of Al or Si, and an oxide, a nitride or a carbonate of an emission center element R as a starting material. 
     More specifically, when the phosphor that contains Sr as the element M and Eu as the emission center element is made, Sr 3 N 2 , AlN, Si 3 N 4 , Al 2 O 3 , and EuN can be used as the starting material. Ca 3 N 2 , Ba 3 N 2  and a mixture thereof may be used instead of Sr 3 N 2 , and Ca 3 N 2 , Ba 3 N 2 , Sr 2 N, SrN, and a mixture thereof may be used instead of the Sr 3 N 2 . 
     The starting material are weighed and mixed so as to obtain the desired composition, and the target phosphor can be obtained by burning the obtained mixture powders. For example, a technique of performing mortar mixing in a glove box can be cited as an example of the mixing. A boron nitride, a silicon nitride, a silicon carbide, carbon, an aluminum nitride, sialon, an aluminum oxide, molybdenum, or tungsten can be used as a material for a crucible. 
     Second Embodiment 
     Alight emitting device according to a second embodiment differs from the light emitting device of the first embodiment only in that the stacked film including the transparent resin layer, the first fluorescent layer, the second fluorescent layer, and the transparent resin layer is not separately formed on the individual LED chip, but formed into a sheet shape with which the plural LED chips are collectively covered. Therefore, the description overlapping with that of the first embodiment is omitted. 
       FIG. 5  is a schematic sectional view illustrating the light emitting device of the second embodiment. The stacked film including the transparent resin layer  16 , the first fluorescent layer  18 , the second fluorescent layer  20 , and the transparent resin layer  22  is formed into the flat sheet shape with which the LED chips  12  are collectively covered. 
       FIG. 6A  to  FIG. 6D  are schematic sectional views illustrating a method for manufacturing the light emitting device of the second embodiment. The blue LED chips  12  for excitation light sources are mounted on the surface of the board  10 . The region where the blue LED  12  is mounted is collectively opened, for example, a metallic mask  34  is placed on the board  10 , and the transparent resin  26  is applied onto the mask  34  in a wide range of the mask  34  with no use of the dispenser. For example, the transparent resin  26  is a silicone resin. 
     Then, the transparent resin  26  except the transparent resin  26  with which the opening is filled is removed from the surface of the mask  34  with the squeeze  28  ( FIG. 6A ). 
     Then, the mask  34  is removed from the board  10 , and the board  10  is subjected to the heat treatment to cure the transparent resin  26 , thereby forming the transparent resin layer  16  ( FIG. 6B ). 
     Then, the metallic mask  36  having an opening corresponding to the region where the blue LED  12  is mounted is placed on the board  10 . The opening of the mask  36  is designed wider than that of the mask  34 . The binder resin  32  in which the red phosphors are dispersed is applied onto the mask  36  in the wide range of the mask  36  with no use of the dispenser. For example, the binder resin  32  is a silicone resin. 
     Then, the binder resin  32  except the binder resin  32  with which the opening is filled is removed from the surface of the mask  36  with the squeeze  28  ( FIG. 6C ). 
     Then, the mask  36  is removed from the board  10 , and the board  10  is subjected to the heat treatment to cure the binder resin  32 , thereby forming the first fluorescent layer  18  ( FIG. 6D ). 
     Then, the second fluorescent layer  20  and the transparent resin layer  22  are formed by repeating the similar process to produce the light emitting device illustrated in  FIG. 5 . 
     According to the second embodiment, alignment of the mask with the board can be relaxed. Accordingly, productivity and a yield of the light emitting device are advantageously improved. 
     Third Embodiment 
     A method for manufacturing a light emitting device according to a third embodiment is another method for manufacturing the light emitting device of the first embodiment illustrated in  FIG. 3 . 
     In the method for manufacturing the light emitting device of the third embodiment, the light emitting element that emits the light having the wavelength of 250 nm to 500 nm is mounted on the surface of the board, a resin including the phosphor having the composition expressed by the following equation (1) and the average particle diameter of 12 μm or more is applied onto the die having a recess whose diameter larger than that of the light emitting element, the board and the die are pressed against each other while overlapping each other such that the light emitting element is fitted in the recess, the resin except the recess is removed from the surfaces of the board and die, the board and the die are separated from each other such that the resin of the recess is left on the light emitting element, and the board is subjected to the heat treatment to cure the resin. 
       (M 1−x1 Eu x1 ) 3−y Si 13−z Al 3+z O 2+u N 21−w   (1)
 
     (In the equation (1), M is an element that is selected from IA group elements, IIA group elements, IIIA group elements, IIIB group elements except Al, rare-earth elements, and IVB group elements. Eu is the emission center element. x1, y, z, u, and w satisfy the following relationship. 0&lt;x1≦1, −0.1≦y≦0.15, −1≦z≦1, −1&lt;u−w≦1.5) 
       FIG. 7A  to  FIG. 7E  are schematic sectional views illustrating a method for manufacturing the light emitting device of the third embodiment. The blue LED chips  12  for excitation light sources are mounted on the surface of the board  10  ( FIG. 7A ). A die  38  having a recess whose diameter is larger than that of the blue LED chip  12  is prepared ( FIG. 7B ). 
     Then, the transparent resin  26  is applied onto the die  38  in a wide range of the die  38  with no use of the dispenser ( FIG. 7C ). For example, the transparent resin  26  is a silicone resin. 
     The board  10  and the die  38  are pressed against each other while overlapping each other such that the LED chip  12  is fitted in the recess, and the transparent resin  26  except the recess is removed from the surfaces of the board  10  and die ( FIG. 7D ). 
     Then, the board  10  and the die  38  are separated from each other such that the transparent resin  26  is left on the LED chip  12 , and the board  10  is subjected to the heat treatment to cure the transparent resin, thereby forming the transparent resin layer  16 . 
     Then, a die  40  having a recess whose diameter is larger than that of the blue LED chip  12  is prepared. The die  40  is designed such that the diameter and a depth of the die  40  are larger than those of the die  38 . The binder resin  32  in which the red phosphors are dispersed is applied onto the die  40  in the wide range of the die  40  with no use of the dispenser ( FIG. 7E ). For example, the binder resin  32  is a silicone resin. 
     Then, the board  10  and the die  40  are pressed against each other while overlapping each other such that the LED chip  12  is fitted in the recess, and the binder resin  32  except the recess is removed from the surfaces of the board  10  and die  40 . 
     Then, the board  10  and the die  40  are separated from each other such that the binder resin  32  is left on the LED chip  12 , and the board is subjected to the heat treatment to cure the transparent resin, thereby forming the first fluorescent layer  18  illustrated in  FIG. 3 . 
     Then, the second fluorescent layer  20  and the transparent resin layer  22  are formed by repeating the similar process to produce the light emitting device illustrated in  FIG. 3 . 
     The light emitting device is also produced with no use of the dispense, because the method for manufacturing the light emitting device of the third embodiment has the above-described configuration. Therefore, the high-efficiency light emitting device can be produced by the stable manufacturing method. 
     Fourth Embodiment 
     A method for manufacturing a light emitting device according to a fourth embodiment is another method for manufacturing the light emitting device of the second embodiment illustrated in  FIG. 5 . 
       FIG. 8A  to  FIG. 8E  are schematic sectional views illustrating a method for manufacturing the light emitting device of the fourth embodiment. The blue LED chips  12  for excitation light sources are mounted on the surface of the board  10  ( FIG. 8A ). A die  42  having a recess is prepared, the diameter of the recess is larger than that of the blue LED chip  12 , and the plural blue LED chips  12  are collectively included in the recess ( FIG. 8B ). 
     Then, the transparent resin  26  is applied onto the die  42  in a wide range of the die  42  with no use of the dispenser ( FIG. 8C ). For example, the transparent resin  26  is a silicone resin. 
     The board  10  and the die  42  are pressed against each other while overlapping each other such that the plural LED chips  12  are fitted in the recess, and the transparent resin  26  except the recess is removed from the surfaces of the board  10  and die  42  ( FIG. 8D ). 
     Then, the board  10  and the die  42  are separated from each other such that the transparent resin  26  is left on the LED chips  12 , and the board  10  is subjected to the heat treatment to cure the transparent resin  26 , thereby forming the transparent resin layer  16 . 
     Then, a die  44  having a recess whose diameter is larger than that of the blue LED chip  12  is prepared. The die  44  is designed such that the diameter and depth of the die  44  are larger than those of the die  42 . The binder resin  32  in which the red phosphors are dispersed is applied onto the die  44  in the wide range of the die  44  with no use of the dispenser ( FIG. 8E ). For example, the binder resin  32  is a silicone resin. 
     Then, the board  10  and the die  44  are pressed against each other while overlapping each other such that the LED chips  12  are fitted in the recess, and the binder resin  32  except the recess is removed from the surfaces of the board  10  and die  44 . 
     Then, the board  10  and the die  44  are separated from each other such that the binder resin  32  is left on the LED chips  12 , and the board is subjected to the heat treatment to cure the transparent resin  26 , thereby forming the first fluorescent layer  18  illustrated in  FIG. 5 . 
     Then, the second fluorescent layer  20  and the transparent resin layer  22  are formed by repeating the similar process to produce the light emitting device illustrated in  FIG. 5 . 
     Fifth Embodiment 
     A light emitting device according to a fifth embodiment differs from the light emitting device of the first embodiment in that the hemispherical four-layer-structure stacked film including the transparent resin layer  16 , the first fluorescent layer  18 , the second fluorescent layer  20 , and the transparent resin layer  22  is formed on a deformable resin sheet shape. The description overlapped with that of the first embodiment is omitted. 
       FIG. 9  is a schematic sectional view illustrating the light emitting device of the fifth embodiment. The light emitting device of the fifth embodiment includes plural blue LED chips  12  for excitation light mounted on a board  10 . Plural recesses  46  are provided in the surface of the board  10 . Each LED chip  12  is disposed in the recess  46 . For example, each LED chip  12  in the recess  46  is connected to the wiring (not illustrated) through the gold wire  14 . The driving current is supplied to the LED chip  12  from the outside through the wiring, whereby the LED chip  12  emits the blue light for excitation. 
     The LED chip  12  is sealed in the recess  46  by a transparent resin layer  48 . A deformable transparent resin sheet  50  is provided such that the transparent resin layer  48  immediately above the LED chip  12  is covered therewith. 
     A reflection layer  52  is provided in a region except the region immediately above the recess  46  of the resin sheet  50 . In the reflection layer  52 , materials such as Ag fine particles and titanium oxide fine particles which reflect the light from a near-ultraviolet range to a visible range are dispersed in the resin. 
     The hemispherical transparent resin layer  16  is provided on the LED chip  12  of the resin sheet  50 . The first fluorescent layer  18  is disposed such that the resin layer  16  is covered therewith. In the first fluorescent layer  18 , the red phosphors that absorb the blue light emitted from the LED chip  12  and convert the blue light into the red light are dispersed in the transparent resin. 
     For example, the red phosphor of the first fluorescent layer  18  has the composition expressed by the following equation (2). 
       (M′ 1−x2 Eu x2 ) a Si b AlO c N d   (2)
 
     (In the equation (2), M′ is an element that is selected from IA group elements, IIA group elements, IIIA group elements, IIIB group elements except Al, rare-earth elements, and IVB group elements. Eu is the emission center element. x2, a, b, c, and d satisfy the following relationship. 0&lt;x2≦1, 0.60&lt;a&lt;0.95, 2.0&lt;b&lt;3.9, 0.04≦c≦0.6, 4&lt;d&lt;5.7) 
     Desirably, the element M′ is Sr. 
     The second fluorescent layer  20  is disposed such that the first fluorescent layer  18  is covered therewith. In the second fluorescent layer  20 , the green phosphors that absorb the blue light emitted from the LED chip  12  and convert the blue light into the green light are dispersed in the transparent resin. 
     The green phosphor in the second fluorescent layer has the composition expressed by the following equation (1), and has the average particle diameter of 12 μm or more. 
       (M 1−x1 Eu x1 ) 3−y Si 13−z Al 3+z O 2+u N 21−w   (1)
 
     (In the equation (1), M is an element that is selected from IA group elements, IIA group elements, IIIA group elements, IIIB group elements except Al, rare-earth elements, and IVA group elements. Eu is the emission center element. x1, y, z, u, and w satisfy the following relationship. 0&lt;x1≦1, −0.1≦y≦0.15, −1≦z≦1, −1&lt;u−w≦1.5) 
     Desirably, the element M is Sr. 
     As described above, the green phosphor in the second fluorescent layer  20  has the average particle diameter of 12 μm or more, which allows the high luminous efficiency to be obtained. From the viewpoint of obtaining the higher luminous efficiency, desirably the particle diameter is not lower than 20 μm, and more desirably not lower than 50 μm. 
     According to the fifth embodiment, the high-efficiency light emitting device is implemented by the use of the green phosphor in which the composition and the average particle diameter are restricted as described above. 
     The hemispherical transparent resin layer  22  is provided such that the second fluorescent layer  20  is covered therewith. The outer surface of the transparent resin layer  22  is in contact with atmosphere (air). The transparent resin layer  22  has a function of suppressing total reflection of the blue light emitted from the LED chip  12 , the red light from the first fluorescent layer  18 , and the green light from the second fluorescent layer  20  at the outer surface that becomes an interface with the atmosphere. 
     The four-layer structure including the transparent resin layer  16 , the first fluorescent layer  18 , the second fluorescent layer  20 , and the transparent resin layer  22  has the hemispherical shape. 
     In the light emitting device of the fifth embodiment, when the current is passed through the LED chip  12 , the light output from the transparent resin layer  22  becomes the white-color light. In the white-color light, the blue light emitted from the LED chip  12  to pass through the transparent resin layer  16 , first fluorescent layer  18 , second fluorescent layer  20 , and transparent resin layer  22 , the red light from the first fluorescent layer  18 , and the green light from the second fluorescent layer  20  are mixed. 
     In the light emitting device of the fifth embodiment having the above-described configuration, the hemispherical stacked structure including the transparent resin layer  16 , the first fluorescent layer  18 , the first fluorescent layer  20 , and the transparent resin layer  22  is formed on the resin sheet  50 , so that the emission color can be prevented from varying or the hue can be prevented from varying depending on the view angle. The blue light emitted from the LED chip  12  passes through the transparent resin layer  16 . In the first fluorescent layer  18 , the red phosphors that convert the blue light into the red light are dispersed in the transparent resin. In the second fluorescent layer  20 , the green phosphors that convert the blue light into the green light are dispersed in the transparent resin. The transparent resin layer  22  has the function of suppressing the total reflection of the blue light, red light, and green light at the outer surface that becomes the interface with the atmosphere. The excitation light from the LED chip  12  can be collected to enhance the light extracting efficiency. Additionally, the air layer can be prevented from being interposed among the layers, and the degradation of the transmittance of the resin and the luminous efficiency of the phosphor can be suppressed. 
     In the light emitting device of the fifth embodiment, the reflection layer  52  in which the materials reflecting the light ranging from the near-ultraviolet light to the visible light are dispersed is provided in the region except the region where the hemispherical stacked structure including the transparent resin layer  16 , the first fluorescent layer  18 , the second fluorescent layer  20 , and the transparent resin layer  22 , and the transparent resin layer  22  has the function of suppressing the total reflection of the blue light, red light, and green light at the outer surface that becomes the interface with the atmosphere. Therefore, the light emitting device of the fifth embodiment can emit the high-luminance light at high luminous efficiency. Thermal radiation performance can further be improved when thermal radiation fillers are dispersed in the reflection layer  52 . 
     A method for manufacturing the light emitting device of the fifth embodiment will be described below. As described above, in the green phosphor using the fifth embodiment, the luminous efficiency depends on the particle diameter, and the luminous efficiency is improved with increasing particle diameter. At the same time, when the particle diameter of the phosphor is increased, a technique of falling in drops of the resin in which the phosphors are dispersed on the light emitting element with a dispenser (constant liquid delivery apparatus) is hardly adopted in forming the fluorescent layer. Because a diameter of a syringe of the dispenser is restricted, clogging is possibly generated when the particle diameter is increased. 
     In the method for manufacturing the light emitting device of the fifth embodiment, the light emitting element that emits the light having the wavelength of 250 nm to 500 nm is mounted on the surface of the board, the deformable resin sheet having the region through which the light emitted from the light emitting element is transmitted is prepared, the mask having the opening in the region where the light emitting element is mounted is placed on the board, the resin including the phosphor having the composition expressed by the following equation (1) and the average particle diameter of 12 μm or more is applied onto the mask, the resin except the resin with which the opening is filled is removed from the mask surface with squeeze, the mask is removed from the resin sheet, the heat treatment is performed to cure the resin, and the resin sheet is bonded such that the region is located above the light emitting element. 
       (M 1−x1 Eu x1 ) 3−y Si 13−z Al 3+z O 2+u N 21−w   (1)
 
     (In the equation (1), M is an element that is selected from IA group elements, IIA group elements, IIIA group elements, IIIB group elements except Al, rare-earth elements, and IVB group elements. Eu is the emission center element. x1, y, z, u, and w satisfy the following relationship. 0&lt;x1≦1, −0.1≦y≦0.15, −1≦z≦1, −1&lt;u−w≦1.5) 
     The light emitting device is produced with no use of the dispenser, because the method for manufacturing the light emitting device of the fifth embodiment has the above-described configuration. Therefore, the high-efficiency light emitting device can be produced by the stable manufacturing method. 
       FIG. 10A  to  FIG. 10F  are schematic sectional views illustrating a method for manufacturing the light emitting device of the fifth embodiment. The blue LED chips  12  for excitation light sources are mounted on the recesses  46  of the board  10  by sealing the LED chips  12  using the transparent resin layer  48  ( FIG. 10A ). 
     Then, the deformable resin sheet  50  having the region through which the light emitted from the LED chip  12  is transmitted is prepared. As used herein, the region through which the light is transmitted means a region except the reflection layer  52  of the resin sheet  50 . 
     Then, a metallic mask  54  having the opening in the region where the blue LED  12  is mounted is placed on the resin sheet  50 , and a transparent resin  26  is applied onto the mask  54  in the wide range of the mask  54  with no use of the dispenser. For example, the transparent resin  26  is a silicone resin. 
     The transparent resin  26  except the transparent resin  26  with which the opening is filled is removed from the surface of the mask  54  with the squeeze  28  ( FIG. 10B ). 
     Then, the mask  54  is removed from the resin sheet  50 , and the resin sheet  50  is subjected to the heat treatment to cure the transparent resin  26 , thereby forming the transparent resin layer  16  ( FIG. 10C ). 
     Then, a metallic mask  56  having the opening in the region where the blue LED  12  is mounted is placed on the resin sheet  50 . The opening of the mask  56  is designed wider than that of the mask  54 . The binder resin  32  in which the red phosphors are dispersed is applied onto the mask  56  in the wide range of the mask  56  with no use of the dispenser. For example, the binder resin  32  is a silicone resin. 
     Then, the binder resin  32  except the binder resin  32  with which the opening is filled is removed from the surface of the binder resin  50  with the squeeze  28  ( FIG. 10D ). 
     Then, the mask  56  is removed from the resin sheet  50 , and the resin sheet  50  is subjected to the heat treatment to cure the binder resin  32 , thereby forming the first fluorescent layer  18  ( FIG. 10E ). 
     Then, the second fluorescent layer  20  and the transparent resin layer  22  are formed on the resin sheet  50  by repeating the similar process. Then, the board  10  and the resin sheet  50  are bonded such that the region through which the light is transmitted is located on the LED chip  12  ( FIG. 10F ). Thus, the light emitting device illustrated in  FIG. 9  is produced. 
     For example, the green phosphor that is included in the second fluorescent layer and expressed by the equation (1) can be synthesized using a nitride of the element M or a carbide of cyanamide of the nitride of the element M, a nitride, an oxide, or a carbide of an element of Al or Si, and an oxide, a nitride or a carbonate of an emission center element R as the starting material. 
     More specifically, when the phosphor that contains Sr as the element M and Eu as the emission center element is made, Sr 3 N 2 , AlN, Si 3 N 4 , Al 2 O 3 , and EuN can be used as the starting material. Ca 3 N 2 , Ba 3 N 2  and a mixture thereof may be used instead of Sr 3 N 2 , and Ca 3 N 2 , Ba 3 N 2 , Sr 2 N, SrN, and a mixture thereof may be used instead of the Sr 3 N 2 . 
     The starting material are weighed and mixed so as to obtain the desired composition, and the target phosphor can be obtained by burning the obtained mixture powders. For example, the technique of performing mortar mixing in a glove box can be cited as an example of the mixing. A boron nitride, a silicon nitride, a silicon carbide, carbon, an aluminum nitride, sialon, an aluminum oxide, molybdenum, or tungsten can be used as the material for the crucible. 
     Sixth Embodiment 
     A light emitting device according to a sixth embodiment differs from the light emitting device of the fifth embodiment only in that the stacked film including the transparent resin layer, the first fluorescent layer, the second fluorescent layer, and the transparent resin layer is not separately formed on the individual LED chip, but formed into a sheet shape with which the plural LED chips are collectively covered. Therefore, the description overlapping with that of the fifth embodiment is omitted. 
       FIG. 11  is a schematic sectional view illustrating the light emitting device of the fourth embodiment. The stacked film including the transparent resin layer  16 , the first fluorescent layer  18 , the second fluorescent layer  20 , and the transparent resin layer  22  is formed into the sheet shape with which the LED chips  12  are collectively covered. 
       FIG. 12A  to  FIG. 12F  are schematic sectional views illustrating a method for manufacturing the light emitting device of the sixth embodiment. The blue LED chips  12  for excitation light sources are mounted on the recesses  46  in the surface of the board  10  by sealing the LED chips  12  using the transparent resin layer  48  ( FIG. 12A ). 
     The deformable resin sheet  50  having the region through which the light emitted from the LED chip  12  is transmitted is prepared. Then, a metallic mask  58  having the opening in the region where the blue LED chip  12  is mounted is placed on the resin sheet  50 , and the transparent resin  26  is applied onto the mask  58  in the wide range of the mask  58  with no use of the dispenser. For example, the transparent resin  26  is a silicone resin. 
     The transparent resin  26  except the transparent resin  26  with which the opening is filled is removed from the surface of the mask  58  with the squeeze  28  ( FIG. 12B ). 
     Then, the mask  58  is removed from the resin sheet  50 , and the resin sheet  50  is subjected to the heat treatment to cure the transparent resin  26 , thereby forming the transparent resin layer  16  ( FIG. 12C ). 
     Then, a metallic mask  60  having the opening in the region where the blue LED chip  12  is mounted is placed on the resin sheet  50 . The opening of the mask  60  is designed wider than that of the mask  58 . The binder resin  32  in which the red phosphors are dispersed is applied onto the mask  60  in the wide range of the mask  60  with no use of the dispenser. For example, the binder resin  32  is a silicone resin. 
     Then, the binder resin  32  except the binder resin  32  with which the opening is filled is removed from the surface of the resin sheet  50  with the squeeze  28  ( FIG. 12D ). 
     The mask  60  is removed from the resin sheet  50 , and the resin sheet  50  is subjected to the heat treatment to cure the binder resin  32 , thereby forming the first fluorescent layer  18  ( FIG. 12E ). 
     Then, the second fluorescent layer  20  and the transparent resin layer  22  are formed by repeating the similar process to produce the light emitting device illustrated in  FIG. 11 . 
     According to the sixth embodiment, the alignment of the mask with the board can be relaxed. Accordingly, productivity and yield of the light emitting device are advantageously improved. 
     Seventh Embodiment 
     A method for manufacturing a light emitting device according to a seventh embodiment is another method for manufacturing the light emitting device of the fifth embodiment illustrated in  FIG. 9 . 
     In the method for manufacturing the light emitting device of the seventh embodiment, the light emitting element that emits the light having the wavelength of 250 nm to 500 nm is mounted on the surface of the board, the deformable resin sheet having the region through which the light emitted from the light emitting element is transmitted is prepared, the resin including the phosphor having the composition expressed by the following equation (1) and the average particle diameter of 12 μm or more is applied onto the die including the recess whose diameter is larger than that of the light emitting element, the resin sheet and the die are pressed against each other while overlapping each other, the resin except the resin of the recess is removed from the surfaces of the resin sheet and die, the resin sheet and the die are separated from each other such that the resin of the recess is left, the resin sheet is subjected to the heat treatment to cure the resin, and the resin sheet is bonded such that the region is located above the light emitting element. 
       (M 1−x1 Eu x1 ) 3−y Si 13−z Al 3+z O 2+u N 21−w   (1)
 
     (In the equation (1), M is an element that is selected from IA group elements, IIA group elements, IIIA group elements IIIB group elements except Al, rare-earth elements, and IVB group elements. Eu is the emission center element. x1, y, z, u, and w satisfy the following relationship. 0&lt;x1≦1, −0.1≦y≦0.15, −1≦z≦1, −1&lt;u−y≦1.5) 
       FIG. 13A  to  FIG. 13F  are schematic sectional views illustrating a method for manufacturing the light emitting device of the seventh embodiment. The blue LED chips  12  for excitation light sources are mounted on the recesses  46  of the board  10  by sealing the LED chips  12  using the transparent resin layer  48  ( FIG. 13A ). Then, the die  38  having the recess whose diameter is larger than that of the blue LED chip  12  is prepared ( FIG. 13B ). 
     The deformable resin sheet  50  having the region through which the light emitted from the LED chip  12  is transmitted is prepared. As used herein, the region through which the light is transmitted means the region except the reflection layer  52  of the resin sheet  50 . 
     Then, the transparent resin  26  is applied onto the die  38  in the wide range of the die  38  with no use of the dispenser ( FIG. 13C ). For example, the transparent resin  26  is a silicone resin. 
     The resin sheet  50  and the die  38  are pressed against each other while overlapping each other such that the region is located in the position corresponding to the recess, and the transparent resin  26  except the recess is removed from the surfaces of the resin sheet  50  and die  38  ( FIG. 13D ). 
     Then, the resin sheet  50  and the die  38  are separated from each other such that the transparent resin  26  in the portion of the die  38  is left on the resin sheet  50 , and the resin sheet  50  is subjected to the heat treatment to cure the resin, thereby forming the transparent resin layer  16 . 
     Then, the die  40  having a recess whose diameter is larger than that of the transparent resin layer  16  is prepared. The die  40  is designed such that the diameter of the die  40  is larger than that of the die  38 . The binder resin  32  in which the red phosphors are dispersed is applied onto the die  40  in the wide range of the die  40  with no use of the dispenser. For example, the binder resin  32  is a silicone resin. 
     Then, the resin sheet  50  and the die  40  are pressed against each other while overlapping each other such that the transparent resin layer  16  is fitted in the recess, and the binder resin  32  except the recess is removed from the surfaces of the resin sheet  50  and die  40  ( FIG. 13E ). 
     Then, the resin sheet  50  and the die  40  are separated from each other such that the binder resin  32  is left on the transparent resin layer  16 , and the board is subjected to the heat treatment to cure the binder resin, thereby forming the first fluorescent layer  18 . 
     Then, the second fluorescent layer  20  and the transparent resin layer  22  are formed on the resin sheet  50  by repeating the similar process. Then, the board  10  and the resin sheet  50  are bonded such that the region through which the light is transmitted is located on the LED chip  12  ( FIG. 13F ). Thus, the light emitting device illustrated in  FIG. 9  is produced. 
     The light emitting device is also produced with no use of the dispense, because the method for manufacturing the light emitting device of the seventh embodiment has the above-described configuration. Therefore, the high-efficiency light emitting device can be produced by the stable manufacturing method. 
     Eighth Embodiment 
     A method for manufacturing a light emitting device according to an eighth embodiment is another method for manufacturing the light emitting device of the sixth embodiment illustrated in  FIG. 11 . 
       FIG. 14A  to  FIG. 14F  are schematic sectional views illustrating a method for manufacturing the light emitting device of the eighth embodiment. The blue LED chips  12  for excitation light sources are mounted on the recesses  46  of the board  10  by sealing the LED chips  12  using the transparent resin layer  48  ( FIG. 14A ). The die  42  having a recess is prepared, the diameter of the recess is larger than that of the blue LED chip  12 , and the plural blue LED chips  12  are collectively included in the recess ( FIG. 14B ). 
     Then, the deformable resin sheet  50  having the region through which the light emitted from the LED chip  12  is transmitted is prepared. 
     Then, the transparent resin  26  is applied onto the die  42  in the wide range of the die  42  with no use of the dispenser ( FIG. 14C ). For example, the transparent resin  26  is a silicone resin. 
     Then, the resin sheet  50  and the die  42  are pressed against each other while overlapping each other, and the transparent resin  26  except the recess is removed from the surfaces of the resin sheet  50  and die  42  ( FIG. 14D ). 
     Then, the resin sheet  50  and the die  42  are separated from each other such that the transparent resin  26  in the portion of the die  42  is left on the resin sheet  50 , and the resin sheet  50  is subjected to the heat treatment to cure the resin, thereby forming the transparent resin layer  16 . 
     Then, the die  44  having the recess whose diameter is larger than that of the transparent resin layer  16  is prepared. The die  44  is designed such that the diameter of the die  44  are larger than that of the die  42 . The binder resin  32  in which the red phosphors are dispersed is applied onto the die  42  in the wide range of the die  44  with no use of the dispenser. For example, the binder resin  32  is a silicone resin. 
     Then, the resin sheet  50  and the die  44  are pressed against each other while overlapping each other such that the transparent resin layer  16  is fitted in the recess, and the binder resin  32  except the recess is removed from the surfaces of the resin sheet  50  and die  44  ( FIG. 14E ). 
     Then, the resin sheet  50  and the die  44  are separated from each other such that the binder resin  32  is left on the transparent resin layer  16 , and the board is subjected to the heat treatment to cure the resin, thereby forming the first fluorescent layer  18 . 
     Then, the second fluorescent layer  20  and the transparent resin layer  22  are formed on the resin sheet  50  by repeating the similar process. Then, the board  10  and the resin sheet  50  are bonded so as to be located on the LED chip  12  ( FIG. 14F ). Thus, the light emitting device illustrated in  FIG. 11  is produced. 
     The light emitting device is also produced with no use of the dispense, because the method for manufacturing the light emitting device of the eighth embodiment has the above-described configuration. Therefore, the high-efficiency light emitting device can be produced by the stable manufacturing method. 
     Ninth Embodiment 
     A light emitting device according to a ninth embodiment differs from the light emitting device of the fifth embodiment only in that the board is formed into a concave shape. Therefore, the description overlapping with that of the fifth embodiment is omitted. 
       FIG. 15  is a schematic sectional view illustrating the light emitting device of the ninth embodiment. The LED chips  12  are mounted on a concave board  62 . The high-efficiency light emitting device having the concave board  62  by the use of the deformable resin sheet  50  can be realized. 
     Tenth Embodiment 
     A light emitting device according to a tenth embodiment differs from the light emitting device of the ninth embodiment only in that the stacked film including the transparent resin layer, the first fluorescent layer, the second fluorescent layer, and the transparent resin layer is not separately formed on the individual LED chip, but formed into a sheet shape with which the plural LED chips are collectively covered. Therefore, the description overlapping with that of the ninth embodiment is omitted. 
       FIG. 16  is a schematic sectional view illustrating the light emitting device of the tenth embodiment. The LED chips  12  are mounted on the concave board  62 . The stacked film including the transparent resin layer  16 , the first fluorescent layer  18 , the second fluorescent layer  20 , and the transparent resin layer  22  is formed into the sheet shape with which the LED chips  12  are collectively covered. The high-efficiency light emitting device having the concave board  62  by the use of the deformable resin sheet  50  can be realized. 
     Eleventh Embodiment 
     A light emitting device according to an eleventh embodiment differs from the light emitting device of the fifth embodiment only in that the board is formed into a convex shape. Therefore, the description overlapping with that of the fifth embodiment is omitted.  FIG. 17  is a schematic sectional view illustrating the light emitting device of the eleventh embodiment. The LED chips  12  are mounted on the convex board  62 . The high-efficiency light emitting device having the convex board  64  by the use of the deformable resin sheet  50  can be realized. 
     Twelfth Embodiment 
     Alight emitting device according to a twelfth embodiment differs from the light emitting device of the eleventh embodiment only in that the stacked film including the transparent resin layer, the first fluorescent layer, the second fluorescent layer, and the transparent resin layer is not separately formed on the individual LED chip, but formed into a sheet shape with which the plural LED chips are collectively covered. Therefore, the description overlapping with that of the eleventh embodiment is omitted. 
       FIG. 18  is a schematic sectional view illustrating the light emitting device of the twelfth embodiment. The LED chips  12  are mounted on the convex board  64 . The stacked film including the transparent resin layer  16 , the first fluorescent layer  18 , the second fluorescent layer  20 , and the transparent resin layer  22  is formed into the sheet shape with which the LED chips  12  are collectively covered. The high-efficiency light emitting device having the convex board  64  by the use of the deformable resin sheet  50 . 
     Thirteenth Embodiment 
     A light emitting device according to a thirteenth embodiment differs from the light emitting device of the fifth embodiment only in that the board is formed into a cylindrical shape. Therefore, the description overlapping with that of the fifth embodiment is omitted.  FIG. 19  is a schematic sectional view illustrating the light emitting device of the thirteenth embodiment. The LED chips  12  are mounted on a cylindrical board  70 . The high-efficiency light emitting device having the cylindrical board  70  by the use of the deformable resin sheet  50  can be realized. 
     Fourteenth Embodiment 
     A light emitting device according to a fourteenth embodiment differs from the light emitting device of the thirteenth embodiment only in that the stacked film including the transparent resin layer, the first fluorescent layer, the second fluorescent layer, and the transparent resin layer is not separately formed on the individual LED chip, but formed into a sheet shape with which the plural LED chips are collectively covered. Therefore, the description overlapping with that of the thirteenth embodiment is omitted. 
       FIG. 20  is a schematic sectional view illustrating the light emitting device of the fourteenth embodiment. The LED chips  12  are mounted on the cylindrical board  70 . The stacked film including the transparent resin layer  16 , the first fluorescent layer  18 , the second fluorescent layer  20 , and the transparent resin layer  22  is formed into the sheet shape with which the LED chips  12  are collectively covered. 
     While certain embodiments have been described, these embodiments have been presented by way of example only, and are not intended to limit the scope of the inventions. Indeed, the light emitting device and the light emitting device manufacturing method described herein may be embodied in a variety of other forms; furthermore, various omissions, substitutions and changes in the form of the devices and methods described herein may be made without departing from the spirit of the inventions. The accompanying claims and their equivalents are intended to cover such forms or modifications as would fall within the scope and spirit of the inventions. 
     For example, a semiconductor light emitting device that emits the light in the ultraviolet region or the blue light may be used as the light emitting element that emits the excitation light used in the light emitting device. Although the LED in which the gallium nitride compound semiconductor is described in the embodiments and examples, the LED is not limited to the gallium nitride compound semiconductor. 
     When the blue LED is used as the light emitting element, the phosphor is not limited to the yellow phosphor, the combination of the yellow phosphor and the red phosphor, the combination of the red phosphor and the green phosphor, the combination of the red phosphor, the yellow phosphor, and the green phosphor, but the combination of the orange phosphor and the green phosphor, the combination of the red phosphor and the blue-green phosphor, and the combination of the orange phosphor and the blue-green phosphor may be used as the phosphor. When the near-ultraviolet LED is used as the phosphor, the combination of the red phosphor and the green phosphor and the combination of the red phosphor, the yellow phosphor, the green phosphor, and the blue phosphor may be used as the light emitting element. When at least two kinds of the phosphors are used, preferably a multi-layer structure application in which the phosphor emitting the longer-wavelength light is applied inside while the phosphor emitting the shorter-wavelength light is applied outside is adopted in order to prevent re-absorption between the phosphors. More preferably a multi-layer structure application in which the transparent resin layer is sandwiched between the phosphor emitting the longer-wavelength light and the phosphor emitting the shorter-wavelength light is adopted. 
     In the embodiments, the red phosphor and the green phosphor are individually included in the different fluorescent layers by way of example. Alternatively, the red phosphor and the green phosphor may be mixed and included in the same fluorescent layer. 
     In the embodiments, the sialon phosphor is applied to the red phosphor by way of example. From the viewpoint of suppressing the thermal quenching, desirably sialon phosphor, particularly, the phosphor expressed by the equation (2) is applied to the red phosphor. Alternatively, another red phosphor may be applied. 
     Any binder resin can be used as the binder resin that constitutes the base material of the sealing resin as long as the binder resin is substantially transparent in the neighborhood of the peak wavelength of the light emitting element (excitation element) and the wavelength range longer than the peak wavelength of the light emitting element. Generally examples of the binder resin include a silicone resin, an epoxy resin, a polydimethylcyclohexan derivative having a epoxy group, an oxetane resin, an acrylic resin, a cycloolefin resin, a urea resin, a fluorine resin, and a polyimide resin. 
     In the following examples and comparative examples, M in the equation (1) and M′ in the equation (2) are Sr (strontium). 
     Example 1 
     The light emitting device of the fifth embodiment illustrated in  FIG. 9  was produced by the method for manufacturing the light emitting device of the fifth embodiment illustrated in  FIG. 10 . At this point, the green phosphor having the composition, peak wavelength, and average particle diameter, which are illustrated in a field of Example 1 of TABLE 1, was applied to the second fluorescent layer (green fluorescent layer). At this point, the red phosphor having the composition, peak wavelength, and average particle diameter, which are illustrated in a field of Example 1 of TABLE 2, was applied to the first fluorescent layer (red fluorescent layer). A total luminous flux, which was obtained by driving the light emitting device of Example 1 at 800 mA, was evaluated using an integrating sphere. TABLE 3 illustrates the result. The single phosphor was irradiated with the excitation light of the blue LED, and the wavelength of the emitted light was measured to evaluate the peak wavelength. 
     TABLE 1 illustrates values of x1, y, z, u, and w in the equation (1). TABLE 2 illustrates values of x2, a, b, c, and d in the equation (2). 
     
       
         
           
               
               
               
               
               
               
               
               
             
               
                 TABLE 1 
               
               
                   
               
               
                   
                   
                   
                   
                   
                   
                 Peak 
                 Average 
               
               
                   
                   
                   
                   
                   
                   
                 Wave- 
                 Particle 
               
               
                   
                   
                   
                   
                   
                   
                 length 
                 Diameter 
               
               
                   
                 x1 
                 y 
                 z 
                 u 
                 w 
                 (nm) 
                 (μm) 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                 Example 1 
                 0.10 
                 −0.08 
                 0.11 
                 −0.04 
                 1.43 
                 524 
                 51 
               
               
                 Example 2 
                 0.08 
                 −0.06 
                 0.13 
                 0.22 
                 0.06 
                 518 
                 53 
               
               
                 Example 3 
                 0.10 
                 −0.08 
                 0.03 
                 −0.06 
                 0.09 
                 520 
                 60 
               
               
                 Example 4 
                 0.07 
                 −0.07 
                 −0.23 
                 −0.03 
                 0.79 
                 511 
                 53 
               
               
                 Example 5 
                 0.08 
                 −0.06 
                 −0.15 
                 0.11 
                 −0.11 
                 516 
                 80 
               
               
                 Example 6 
                 0.10 
                 −0.08 
                 0.11 
                 −0.04 
                 1.43 
                 524 
                 45 
               
               
                 Comparative 
                 0.08 
                 −0.07 
                 −0.23 
                 −0.03 
                 0.79 
                 511 
                 5 
               
               
                 Example 1 
                   
                   
                   
                   
                   
                   
                   
               
               
                 Comparative 
                 0.07 
                 0.10 
                 −0.61 
                 0.03 
                 −5.27 
                 514 
                 10 
               
               
                 Example 2 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
             
               
                 TABLE 2 
               
               
                   
               
               
                   
                   
                   
                   
                   
                   
                 Peak 
               
               
                   
                   
                   
                   
                   
                   
                 Wavelength 
               
               
                   
                 x2 
                 a 
                 b 
                 c 
                 d 
                 (nm) 
               
               
                   
               
             
            
               
                 Example 1 
                 0.10 
                 0.858 
                 3.34 
                 0.350 
                 4.92 
                 622 
               
               
                 Example 2 
                 0.11 
                 0.935 
                 3.41 
                 0.418 
                 5.18 
                 631 
               
               
                 Example 3 
                 0.15 
                 0.911 
                 3.70 
                 0.272 
                 5.63 
                 642 
               
               
                 Example 4 
                 0.08 
                 0.680 
                 2.54 
                 0.332 
                 4.29 
                 616 
               
               
                 Example 5 
                 0.09 
                 0.680 
                 2.54 
                 0.332 
                 4.29 
                 616 
               
               
                 Example 6 
                 0.10 
                 0.858 
                 3.34 
                 0.350 
                 4.92 
                 622 
               
               
                 Comparative 
                 0.10 
                 0.858 
                 3.34 
                 0.350 
                 4.92 
                 622 
               
               
                 Example 1 
                   
                   
                   
                   
                   
                   
               
               
                 Comparative 
                 0.10 
                 0.858 
                 3.34 
                 0.350 
                 4.92 
                 622 
               
               
                 Example 2 
               
               
                   
               
            
           
         
       
     
     The method for manufacturing the light emitting device of Example 1 will be described with reference to  FIG. 9  and  FIG. 10 . 
     An InGaN compound semiconductor was used as an active layer, and 16 blue LED chips  12  ( FIG. 10 ) in which p-side/n-side electrodes were formed were prepared. The blue LED chip  12  is fixed to each of the plural recesses  46  of the flat-type mounting board  10  that is the stacked board of patterned Cu metal and an insulating layer by using Sn—Ag—Cu paste. The patterned Cu metal constitutes a lead electrode. 
       FIG. 21  is a wiring diagram of an LED chip of Example 1. As illustrated in  FIG. 21 , the fixed LED chips  12  are connected so as to become 4-by-4 array, and an anode electrode  60  and a cathode electrode  62  are formed. At this point, the lead electrode on the anode side and the p-side electrode of the blue LED chip  12  are electrically connected by the Au wire  14  ( FIG. 10 ), and the lead electrode on the cathode side and the n-side electrode of the blue LED chip  12  are electrically connected through Sn—Ag—Cu paste. Then, the LED chips  12  are sealed by applying the silicone resin, thereby protecting the Au wire  14 . 
     On the other hand, the silicone thin-film resin sheet  50  is loaded on a vacuum printing apparatus. In the resin sheet  50 , the region where the LED chips  12  are located is transparent, and the reflection layer  52  in which Ag fine particles are dispersed is formed in other portions. The resin sheet  50  has a thickness of 0.1 mm, and a bonding agent is applied to only one side of the resin sheet  50 . 
     Using the metal mask  54  whose opening diameter ranges from 1 mmφ to 3 mmφ, the silicone transparent resin  26  is formed into the hemispherical shape on the resin sheet  50  through a first-time printing process while the silicone transparent resin is defoamed at low pressure. Then, the resin sheet  50  in which the transparent resin  26  is formed is cured by retaining the resin sheet  50  at 150° C. for 30 minutes, thereby forming the transparent resin layer  16 . 
     Then, at the silicone resin which is the binder resin, using the metal mask  56  whose opening diameter is slightly larger than that of the first-time printing process, the resin  32  in which the red phosphors illustrated in the field of Example 1 of TABLE 2 are dispersed is formed into the hemispherical shape with an even thickness through a second-time printing process such that the whole of the hemispherical transparent resin layer  16  formed through the first-time printing process is covered with the resin. Then, the resin sheet  50  is cured by retaining the resin sheet  50  at 150° C. for 30 minutes at normal pressure in the atmosphere, thereby forming the first fluorescent layer  18 . 
     Then, using the metal mask whose opening diameter is slightly larger than that of the second-time printing process, the resin in which the green phosphors illustrated in the field of Example 1 of TABLE 1 are dispersed is formed into the hemispherical shape with the even thickness through a third-time printing process such that the whole of the hemispherical first fluorescent layer  18  formed through the second-time printing process is covered with the resin. Then, the resin sheet  50  is cured by retaining the resin sheet  50  at 150° C. for 30 minutes at normal pressure in the atmosphere, thereby forming the second fluorescent layer  20 . Therefore, the stacked structure including the transparent resin layer  16 , the first fluorescent layer  18 , and the second fluorescent layer  20  becomes the hemispherical shape. 
     Then, using the metal mask whose opening diameter is slightly larger than that of the third-time printing process, the silicone transparent resin is formed with the even thickness through a fourth-time printing process such that the second fluorescent layer  20  applied through the third-time printing process is covered with the silicone transparent resin. The transparent resin is formed through the fourth-time printing process such that a ratio (=a/b) of a layer thickness a in a direction immediately above the LED chip and a layer thickness b in the lateral direction becomes 1.0. 
     Then, the transparent resin applied through the fourth-time printing process is cured by retaining the transparent resin at 150° C. for 30 minutes, and drying at normal pressure whereby the transparent resin layer  22  is formed to prepare the phosphor application sheet having the multi-layer structure. Therefore, the stacked structure including the transparent resin layer  16 , the first fluorescent layer  18 , the second fluorescent layer  20 , and the transparent resin layer  22  becomes the hemispherical shape. 
     After the residual atmosphere is removed in a reduced-pressure chamber, the phosphor application sheet (resin sheet) is bonded to the flat-type mounting board  10  to prepare the light emitting device illustrated in  FIG. 9 . 
     Examples 2 to 6  
     The light emitting devices were produced in the way similar to that of Example 1 except that the green phosphors having the compositions, peak wavelengths, and average particle diameters, which are illustrated in fields of Examples 2 to 6 of TABLE 1, were applied to the second fluorescent layer and except that the red phosphors having the compositions and peak wavelengths, which are illustrated in fields of Examples 2 to 6 of TABLE 2, were applied to the first fluorescent layer. The evaluations similar to that of Example 1 were performed. TABLE 3 illustrates the result. 
     Comparative Examples 1 and 2 
     The light emitting devices were produced in the way similar to that of Example 1 except that the green phosphors having the compositions, peak wavelengths, and average particle diameters, which are illustrated in fields of Comparative examples 1 and 2 of TABLE 1, were applied to the second fluorescent layer and except that the red phosphors having the compositions and peak wavelengths, which are illustrated in fields of Comparative examples 1 and 2 of TABLE 2, were applied to the first fluorescent layer. The evaluations similar to that of Example 1 were performed. TABLE 3 illustrates the result. 
     It was confirmed that Examples 1 to 6 having the average particle diameter of 12 μm or more are higher than Comparative examples 1 and 2 in the luminous flux. The high-luminance flat-type light emitting devices were obtained by Examples 1 to 6. When a continuous lighting test was performed while the light emitting devices of Examples 1 to 6 were joined to heat sinks, the decrease in luminous flux caused by heat accumulation was able to be suppressed. Accordingly, the light emitting devices of Examples 1 to 6 had the small color shift, high luminance, high efficiency, and excellent heat-radiation performance. 
     
       
         
           
               
               
             
               
                   
                 TABLE 3 
               
               
                   
                   
               
               
                   
                 Total Luminous Flux 
               
               
                   
                 (Normalized) 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
            
               
                   
                 Example 1 
                 94 
               
               
                   
                 Example 2 
                 96 
               
               
                   
                 Example 3 
                 97 
               
               
                   
                 Example 4 
                 93 
               
               
                   
                 Example 5 
                 100 
               
               
                   
                 Example 6 
                 88 
               
               
                   
                 Comparative 
                 61 
               
               
                   
                 Example 1 
               
               
                   
                 Comparative 
                 70 
               
               
                   
                 Example 2 
               
               
                   
                   
               
            
           
         
       
     
     Example 7 
     The light emitting device of the fifth embodiment illustrated in  FIG. 9  was produced by the method for manufacturing the light emitting device of the seventh embodiment illustrated in  FIG. 13 . At this point, the green phosphor having the composition, peak wavelength, and average particle diameter, which are illustrated in the field of Example 7 of TABLE 4, was applied to the second fluorescent layer. The red phosphor having the composition and peak wavelength, which are illustrated in the field of Example 7 of TABLE 5, was applied to the first fluorescent layer. 
     The total luminous flux, which was obtained by driving the light emitting device of Example 7 at 800 mA, was evaluated using the integrating sphere. TABLE 6 illustrates the result. The single phosphor was irradiated with the excitation light of the blue LED, and the wavelength of the emitted light was measured to evaluate the peak wavelength. 
     TABLE 1 illustrates values of x1, y, z, u, and w in the equation (1). TABLE 2 illustrates values of x2, a, b, c, and d in the equation (2). 
     
       
         
           
               
               
               
               
               
               
               
               
             
               
                 TABLE 4 
               
               
                   
               
               
                   
                   
                   
                   
                   
                   
                 Peak 
                 Average Particle 
               
               
                   
                   
                   
                   
                   
                   
                 Wavelength 
                 Diameter 
               
               
                   
                 x1 
                 y 
                 z 
                 u 
                 w 
                 (nm) 
                 (μm) 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                 Example 7 
                 0.10 
                 −0.08 
                 0.11 
                 −0.04 
                 1.43 
                 524 
                 51 
               
               
                 Example 8 
                 0.08 
                 −0.0625 
                 0.1250 
                 0.2188 
                 0.0625 
                 518 
                 53 
               
               
                 Example 9 
                 0.10 
                 −0.0818 
                 0.0303 
                 −0.0606 
                 0.0909 
                 520 
                 60 
               
               
                 Example 10 
                 0.07 
                 1.06 
                 4.78 
                 0.71 
                 7.3 
                 511 
                 53 
               
               
                 Example 11 
                 0.08 
                 1.03 
                 4.61 
                 0.74 
                 7.4 
                 516 
                 80 
               
               
                 Example 12 
                 0.10 
                 −0.0796 
                 0.1068 
                 −0.0427 
                 1.4272 
                 524 
                 45 
               
               
                 Comparative 
                 0.08 
                 −0.0657 
                 −0.2318 
                 −0.0346 
                 0.7924 
                 511 
                 5 
               
               
                 Example 3 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
             
               
                 TABLE 5 
               
               
                   
               
               
                   
                   
                   
                   
                   
                   
                 Peak 
               
               
                   
                   
                   
                   
                   
                   
                 Wavelength 
               
               
                   
                 x2 
                 a 
                 b 
                 c 
                 d 
                 (nm) 
               
               
                   
               
             
            
               
                 Example 7 
                 0.10 
                 0.858 
                 3.34 
                 0.350 
                 4.92 
                 622 
               
               
                 Example 8 
                 0.11 
                 0.935 
                 3.41 
                 0.418 
                 5.18 
                 631 
               
               
                 Example 9 
                 0.15 
                 0.911 
                 3.70 
                 0.272 
                 5.63 
                 642 
               
               
                 Example 10 
                 0.08 
                 0.680 
                 2.54 
                 0.332 
                 4.29 
                 616 
               
               
                 Example 11 
                 0.09 
                 0.680 
                 2.54 
                 0.332 
                 4.29 
                 616 
               
               
                 Example 12 
                 0.10 
                 0.858 
                 3.34 
                 0.350 
                 4.92 
                 622 
               
               
                 Comparative 
                 0.10 
                 0.858 
                 3.34 
                 0.350 
                 4.92 
                 622 
               
               
                 Example 3 
               
               
                   
               
            
           
         
       
     
     The method for manufacturing the light emitting device of Example 7 will be described with reference to  FIG. 9  and  FIG. 13 . 
     The InGaN compound semiconductor was used as the active layer, and 16 blue LED chips  12  ( FIG. 13 ) in which p-side/n-side electrodes were formed were prepared. The blue LED chip  12  is fixed to each of the plural recesses  46  of the flat-type mounting board  10  that is the stacked board of the patterned Cu metal and the insulating layer by using Sn—Ag—Cu paste. The patterned Cu metal constitutes the lead electrode. 
     As illustrated in  FIG. 21 , similarly to Example 1, the fixed LED chips  12  are connected so as to become the 4-by-4 array, and the anode electrode  60  and the cathode electrode  62  are formed. At this point, the lead electrode on the anode side and the p-side electrode of the blue LED chip  12  are electrically connected by the Au wire  14  ( FIG. 13 ), and the lead electrode on the cathode side and the n-side electrode of the blue LED chip  12  are electrically connected through Sn—Ag—Cu paste. Then, the LED chips  12  are sealed by applying the silicone resin, thereby protecting the Au wire  14 . 
     On the other hand, the silicone thin-film resin sheet  50  is loaded on the molding apparatus. In the resin sheet  50 , the region where the LED chips  12  are located is transparent, and the reflection layer  52  in which Ag fine particles are dispersed is formed in other portions. The resin sheet  50  has the thickness of 0.1 mm, and the bonding agent is applied to only one side of the resin sheet  50 . 
     Using the hemispherical die  38  whose diameter ranges from 1 mmφ to 3 mmφ, the silicone transparent resin  26  is formed into the hemispherical shape on the resin sheet  50  through a first-time molding process while the silicone transparent resin  26  is defoamed at low pressure. Then, the resin sheet  50  in which the transparent resin  26  is formed is cured by retaining the resin sheet  50  at 150° C. for 30 minutes at normal pressure, thereby forming the transparent resin layer  16 . 
     Then, at the silicone resin which is the binder resin, using the die  40  whose opening diameter is slightly larger and deeper than that of the first-time printing process, the resin  32  in which the red phosphors illustrated in the field of Example 7 of TABLE 5 are dispersed is formed into the hemispherical shape with the even thickness through a second-time molding process such that the whole of the hemispherical transparent resin layer  16  formed through the first-time molding process is covered with the resin  32 . Then, the resin sheet  50  is cured by retaining the resin sheet  50  at 150° C. for 30 minutes at normal pressure in the atmosphere, thereby forming the first fluorescent layer  18 . 
     Then, using the die whose opening diameter is slightly larger and deeper than that of the second-time molding process, the resin in which the green phosphors illustrated in the field of Example 7 of TABLE 4 are dispersed is formed into the hemispherical shape with the even thickness through a third-time molding process such that the whole of the hemispherical first fluorescent layer  18  formed through the second-time molding process is covered with the resin. Then, the resin sheet  50  is cured by retaining the resin sheet  50  at 150° C. for 30 minutes at normal pressure in the atmosphere, thereby forming the second fluorescent layer  20 . Therefore, the stacked structure including the transparent resin layer  16 , the first fluorescent layer  18 , and the second fluorescent layer  20  becomes the hemispherical shape. 
     Then, using the die whose opening diameter is slightly larger and deeper than that of the third-time molding process, the silicone transparent resin is formed with the even thickness through a fourth-time molding process such that the second fluorescent layer  20  applied through the third-time molding process is covered with the silicone transparent resin. The transparent resin is formed through the fourth-time molding process such that the ratio (=a/b) of the layer thickness a in the direction immediately above the LED chip and the layer thickness b in the lateral direction becomes 1.0. 
     Then, the transparent resin applied through the fourth-time molding process is cured by retaining the transparent resin at 150° C. for 30 minutes, and drying at normal pressure whereby the transparent resin layer  22  is formed to prepare the phosphor application sheet having the multi-layer structure. Therefore, the stacked structure including the transparent resin layer  16 , the first fluorescent layer  18 , the second fluorescent layer  20 , and the transparent resin layer  22  becomes the hemispherical shape. 
     After the residual atmosphere is removed in the reduced-pressure chamber, the phosphor application sheet (resin sheet) is bonded to the flat-type mounting board  10  to prepare the light emitting device illustrated in  FIG. 9 . 
     Examples 8 to 12  
     The light emitting devices were produced in the way similar to that of Example 7 except that the green phosphors having the compositions, peak wavelengths, and average particle diameters, which are illustrated in fields of Examples 8 to 12 of TABLE 4, were applied to the second fluorescent layer and except that the red phosphors having the compositions and peak wavelengths, which are illustrated in fields of Examples 8 to 12 of TABLE 5, were applied to the first fluorescent layer. The evaluations similar to that of Example 7 were performed. TABLE 6 illustrates the result. 
     Comparative Example 3 
     The light emitting devices were produced in the way similar to that of Example 7 except that the green phosphors having the compositions, peak wavelengths, and average particle diameters, which are illustrated in fields of Comparative example 3 of TABLE 4, were applied to the second fluorescent layer and except that the red phosphors having the compositions and peak wavelengths, which are illustrated in fields of Comparative example 3 of TABLE 5, were applied to the first fluorescent layer. The evaluations similar to that of Example 7 were performed. TABLE 6 illustrates the result. 
     It was confirmed that Examples 7 to 12 having the average particle diameter of 12 μm or more are higher than Comparative example 3 in the luminous flux. The high-luminance flat-type light emitting devices were obtained by Examples 7 to 12. When a continuous lighting test was performed while the light emitting devices of Examples 7 to 12 were joined to heat sinks, the decrease in luminous flux caused by heat accumulation was able to be suppressed. Accordingly, the light emitting devices of Examples 7 to 12 had the small color shift, high luminance, high efficiency, and excellent heat-radiation performance. 
     
       
         
           
               
               
             
               
                   
                 TABLE 6 
               
               
                   
                   
               
               
                   
                 Total Luminous Flux 
               
               
                   
                 (Normalized) 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
            
               
                   
                 Example 7 
                 95 
               
               
                   
                 Example 8 
                 94 
               
               
                   
                 Example 9 
                 96 
               
               
                   
                 Example 10 
                 94 
               
               
                   
                 Example 11 
                 100 
               
               
                   
                 Example 12 
                 86 
               
               
                   
                 Comparative 
                 59 
               
               
                   
                 Example 3 
               
               
                   
                   
               
            
           
         
       
     
     Comparative Examples 4 to 6  
     The light emitting device of the fifth embodiment illustrated in  FIG. 9  was to be produced by adopting the method for manufacturing the light emitting device of the seventh embodiment illustrated in  FIG. 13 . At this point, the green phosphor having the composition, peak wavelength, and average particle diameter, which are illustrated in the fields of Comparative Examples 4 to 6 of TABLE 7, was applied to the second fluorescent layer. The red phosphor having the composition and peak wavelength, which are illustrated in the fields of Comparative Examples 4 to 6 of TABLE 8, was applied to the first fluorescent layer. 
     TABLE 7 illustrates values of x1, y, z, u, and w in the equation (1). TABLE 8 illustrates values of x2, a, b, c, and d in the equation (2). 
     The phosphors of Comparative examples 4 to 6 of TABLE 7 and the phosphors of Comparative examples 4 and 5 of TABLE 8 do not satisfy the conditions of the equations (1) and (2), although Comparative examples 4 to 6 of TABLE 7 and Comparative examples 4 and 5 of TABLE 8 are made based on the sialon compounds. Comparative example 6 of TABLE 8 is not made based on the sialon compound. 
     
       
         
           
               
               
               
               
               
               
               
             
               
                 TABLE 7 
               
               
                   
               
               
                   
                   
                   
                   
                   
                   
                 Peak 
               
               
                   
                   
                   
                   
                   
                   
                 Wavelength 
               
               
                   
                 x1 
                 y 
                 z 
                 u 
                 w 
                 (nm) 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
            
               
                 Comparative 
                 0.08 
                 0.0306 
                 1.4568 
                 2.9916 
                 4.1532 
                 Weak 
               
               
                 Example 4 
                   
                   
                   
                   
                   
                 emission 
               
               
                 Comparative 
                 0.08 
                 −0.1048 
                 0.0476 
                 3.1200 
                 3.9638 
                 Weak 
               
               
                 Example 5 
                   
                   
                   
                   
                   
                 emission 
               
               
                 Comparative 
                 0.10 
                 −0.3731 
                 −0.3466 
                 2.6434 
                 3.8060 
                 Weak 
               
               
                 Example 6 
                   
                   
                   
                   
                   
                 emission 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
             
               
                 TABLE 8 
               
               
                   
               
               
                   
                   
                   
                   
                   
                   
                 Peak 
               
               
                   
                   
                   
                   
                   
                   
                 Wavelength 
               
               
                   
                 x2 
                 a 
                 b 
                 c 
                 d 
                 (nm) 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
            
               
                 Comparative 
                 0.50 
                 0.350 
                 4.61 
                 0.613 
                 2.23 
                 Weak 
               
               
                 Example 4 
                   
                   
                   
                   
                   
                 emission 
               
               
                 Comparative 
                 0.14 
                 1.12 
                 1.35 
                 0.580 
                 6.34 
                 Weak 
               
               
                 Example 5 
                   
                   
                   
                   
                   
                 emission 
               
               
                 Comparative 
                 0.10 
                 0.450 
                 5.00 
                 0.00 
                 8.00 
                 Weak 
               
               
                 Example 6 
                   
                   
                   
                   
                   
                 emission 
               
               
                   
               
            
           
         
       
     
     As illustrated in TABLES 7 and 8, because the light emission is weak and insufficient for manufacturing the light emitting device in any phosphor, the light emitting device was not produced using the phosphors illustrated in TABLES 7 and 8. 
     Example 13  
     The light emitting device of the sixth embodiment illustrated in  FIG. 11  was produced by the method for manufacturing the light emitting device of the sixth embodiment illustrated in  FIG. 12 . At this point, the green phosphor having the composition, peak wavelength, and average particle diameter, which are illustrated in the field of Example 13 of TABLE 9, was applied to the second fluorescent layer. The red phosphor having the composition and peak wavelength, which are illustrated in the field of Example 13 of TABLE 10, was applied to the first fluorescent layer. 
     The total luminous flux, which was obtained by driving the light emitting device of Example 13 at 800 mA, was evaluated using the integrating sphere. TABLE 11 illustrates the result. The single phosphor was irradiated with the excitation light of the blue LED, and the wavelength of the emitted light was measured to evaluate the peak wavelength. 
     TABLE 1 illustrates values of x1, y, z, u, and w in the equation (1). TABLE 2 illustrates values of x2, a, b, c, and d in the equation (2). 
     
       
         
           
               
               
               
               
               
               
               
               
             
               
                 TABLE 9 
               
               
                   
               
               
                   
                   
                   
                   
                   
                   
                 Peak 
                   
               
               
                   
                   
                   
                   
                   
                   
                 Wave- 
                 Average 
               
               
                   
                   
                   
                   
                   
                   
                 length 
                 Particle 
               
               
                   
                 x1 
                 y 
                 z 
                 u 
                 w 
                 (nm) 
                 Diameter 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                 Example 13 
                 0.10 
                 −0.08 
                 0.11 
                 −0.04 
                 1.43 
                 524 
                 51 
               
               
                 Example 14 
                 0.08 
                 −0.06 
                 0.13 
                 0.22 
                 0.06 
                 518 
                 53 
               
               
                 Example 15 
                 0.10 
                 −0.08 
                 0.03 
                 −0.06 
                 0.09 
                 520 
                 60 
               
               
                 Example 16 
                 0.07 
                 −0.07 
                 −0.23 
                 −0.03 
                 0.79 
                 511 
                 53 
               
               
                 Example 17 
                 0.08 
                 −0.06 
                 −0.15 
                 0.11 
                 −0.11 
                 516 
                 80 
               
               
                 Example 18 
                 0.10 
                 −0.08 
                 0.11 
                 −0.04 
                 1.43 
                 524 
                 45 
               
               
                 Comparative 
                 0.08 
                 −0.07 
                 −0.23 
                 −0.03 
                 0.79 
                 511 
                 5 
               
               
                 Example 7 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
             
               
                 TABLE 10 
               
               
                   
               
               
                   
                   
                   
                   
                   
                   
                 Peak 
               
               
                   
                   
                   
                   
                   
                   
                 Wavelength 
               
               
                   
                 x2 
                 a 
                 b 
                 c 
                 d 
                 (nm) 
               
               
                   
               
             
            
               
                 Example 13 
                 0.10 
                 0.858 
                 3.34 
                 0.350 
                 4.92 
                 622 
               
               
                 Example 14 
                 0.11 
                 0.935 
                 3.41 
                 0.418 
                 5.18 
                 631 
               
               
                 Example 15 
                 0.15 
                 0.911 
                 3.70 
                 0.272 
                 5.63 
                 642 
               
               
                 Example 16 
                 0.08 
                 0.680 
                 2.54 
                 0.332 
                 4.29 
                 616 
               
               
                 Example 17 
                 0.09 
                 0.680 
                 2.54 
                 0.332 
                 4.29 
                 616 
               
               
                 Example 18 
                 0.10 
                 0.858 
                 3.34 
                 0.350 
                 4.92 
                 622 
               
               
                 Comparative 
                 0.10 
                 0.858 
                 3.34 
                 0.350 
                 4.92 
                 622 
               
               
                 Example 7 
               
               
                   
               
            
           
         
       
     
     The method for manufacturing the light emitting device of Example 13 will be described below with reference to  FIG. 11  and  FIG. 12 . 
     The InGaN compound semiconductor was used as the active layer, and 16 blue LED chips  12  ( FIG. 12 ) in which p-side/n-side electrodes were formed were prepared. The blue LED chip  12  is fixed to each of the plural recesses  46  of the flat-type mounting board  10  that is the stacked board of the patterned Cu metal and the insulating layer by using Sn—Ag—Cu paste. The patterned Cu metal constitutes the lead electrode. 
     As illustrated in  FIG. 21 , the fixed LED chips  12  are connected so as to become the 4-by-4 array, and the anode electrode  60  and the cathode electrode  62  are formed. At this point, the lead electrode on the anode side and the p-side electrode of the blue LED chip  12  are electrically connected by the Au wire  14  ( FIG. 11 ), and the lead electrode on the cathode side and the n-side electrode of the blue LED chip  12  are electrically connected through the Sn—Ag—Cu paste. Then, the LED chips  12  are sealed by applying the silicone resin, thereby protecting the Au wire  14 . 
     On the other hand, the silicone thin-film resin sheet  50  is loaded on a vacuum printing apparatus. In the resin sheet  50 , the region where the LED chips  12  are located is transparent, and the reflection layer  52  in which Ag fine particles are dispersed is formed in other portions. The resin sheet  50  has the thickness of 0.1 mm, and the bonding agent is applied to only one side of the resin sheet  50 . 
     Using the metal mask  58  whose opening diameter ranges from 25 mm to 30 mm, the silicone transparent resin  26  is formed into the flat shape at low pressure on the resin sheet  50  through the first-time printing process while the silicone transparent resin is defoamed. Then, the resin sheet  50  in which the transparent resin  26  is formed is cured by retaining the resin sheet  50  at 150° C. for 30 minutes, thereby forming the transparent resin layer  16 . 
     Then, at the silicone resin which is the binder resin, using the metal mask  60  whose opening diameter is slightly larger than that of the first-time printing process, the resin  32  in which the red phosphors illustrated in the field of Example 13 of TABLE 10 are dispersed is formed into the flat shape with the even thickness through the second-time printing process such that the whole of the flat transparent resin layer  16  formed through the first-time printing process is covered with the resin  32 . Then, the resin sheet  50  is cured by retaining the resin sheet  50  at 150° C. for 30 minutes at normal pressure in the atmosphere, thereby forming the first fluorescent layer  18 . 
     Then, using the metal mask whose opening diameter is slightly larger than that of the second-time printing process, the resin in which the green phosphors illustrated in the field of Example 13 of TABLE 9 are dispersed is formed into the flat shape with the even thickness through the third-time printing process such that the whole of the flat first fluorescent layer  18  formed through the second-time printing process is covered with the resin. Then, the resin sheet  50  is cured by retaining the resin sheet  50  at 150° C. for 30 minutes at normal pressure in the atmosphere, thereby forming the second fluorescent layer  20 . Therefore, the stacked structure including the transparent resin layer  16 , the first fluorescent layer  18 , and the second fluorescent layer  20  becomes the flat shape. 
     Then, using the metal mask whose opening diameter is slightly larger than that of the third-time printing process, the silicone transparent resin is formed with the even thickness through the fourth-time printing process such that the second fluorescent layer  20  applied through the third-time printing process is covered with the silicone transparent resin. The transparent resin is formed through the fourth-time printing process such that the ratio (=a/b) of a layer thickness a in the direction immediately above the LED chip and the layer thickness b in the lateral direction becomes 1.0. 
     Then, the transparent resin applied through the fourth-time printing process is cured by retaining the transparent resin at 150° C. for 30 minutes, and drying at normal pressure whereby the transparent resin layer  22  is formed to prepare the phosphor application sheet having the multi-layer structure. Therefore, the stacked structure including the transparent resin layer  16 , the first fluorescent layer  18 , the second fluorescent layer  20 , and the transparent resin layer  22  becomes the flat shape. 
     After the residual atmosphere is removed in the reduced-pressure chamber, the phosphor application sheet (resin sheet) is bonded to the flat-type mounting board  10  to prepare the light emitting device illustrated in  FIG. 11 . 
     Examples 14 to 18  
     The light emitting devices were produced in the way similar to that of Example 13 except that the green phosphors having the compositions, peak wavelengths, and average particle diameters, which are illustrated in fields of Examples 14 to 18 of TABLE 9, were applied to the second fluorescent layer and except that the red phosphors having the compositions and peak wavelengths, which are illustrated in fields of Examples 14 to 18 of TABLE 10, were applied to the first fluorescent layer. The evaluations similar to that of Example 13 were performed. TABLE 11 illustrates the result. 
     Comparative Example 7 
     The light emitting device was produced in the way similar to that of Example 13 except that the green phosphors having the compositions, peak wavelengths, and average particle diameters, which are illustrated in fields of Comparative example 7 of TABLE 9, were applied to the second fluorescent layer and except that the red phosphors having the compositions and peak wavelengths, which are illustrated in fields of Comparative example 7 of TABLE 10, were applied to the first fluorescent layer. The evaluations similar to that of Example 13 were performed. TABLE 11 illustrates the result. 
     It was confirmed that Examples 13 to 18 having the average particle diameter of 12 μm or more are higher than Comparative example 7 in the luminous flux. The high-luminance flat-type light emitting devices were obtained by Examples 13 to 18. When a continuous lighting test was performed while the light emitting devices of Examples 13 to 18 were joined to heat sinks, the decrease in luminous flux caused by heat accumulation was able to be suppressed. Accordingly, the light emitting devices of Examples 13 to 18 had the small color shift, high luminance, high efficiency, and excellent heat-radiation performance. 
     
       
         
           
               
               
             
               
                   
                 TABLE 11 
               
               
                   
                   
               
               
                   
                 Total Luminous Flux 
               
               
                   
                 (Normalized) 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
            
               
                   
                 Example 13 
                 94 
               
               
                   
                 Example 14 
                 96 
               
               
                   
                 Example 15 
                 98 
               
               
                   
                 Example 16 
                 93 
               
               
                   
                 Example 17 
                 100 
               
               
                   
                 Example 18 
                 88 
               
               
                   
                 Comparative 
                 61 
               
               
                   
                 Example 7 
               
               
                   
                   
               
            
           
         
       
     
     Example 19 
     The light emitting device of the sixth embodiment illustrated in  FIG. 11  was produced by the method for manufacturing the light emitting device of the eighth embodiment illustrated in  FIG. 14 . At this point, the green phosphor having the composition, peak wavelength, and average particle diameter, which are illustrated in the field of Example 19 of TABLE 12, was applied to the second fluorescent layer. The red phosphor having the composition and peak wavelength, which are illustrated in the field of Example 19 of TABLE 13, was applied to the first fluorescent layer. 
     The total luminous flux, which was obtained by driving the light emitting device of Example 19 at 800 mA, was evaluated using the integrating sphere. TABLE 14 illustrates the result. The single phosphor was irradiated with the excitation light of the blue LED, and the wavelength of the emitted light was measured to evaluate the peak wavelength. 
     TABLE 1 illustrates values of x1, y, z, u, and w in the equation (1). TABLE 2 illustrates values of x2, a, b, c, and d in the equation (2). 
     
       
         
           
               
               
               
               
               
               
               
               
             
               
                 TABLE 12 
               
               
                   
               
               
                   
                   
                   
                   
                   
                   
                 Peak 
                 Average 
               
               
                   
                   
                   
                   
                   
                   
                 Wave- 
                 Particle 
               
               
                   
                   
                   
                   
                   
                   
                 length 
                 Diameter 
               
               
                   
                 x1 
                 y 
                 z 
                 u 
                 w 
                 (nm) 
                 (μm) 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                 Example 19 
                 0.1  
                 −0.08 
                 0.11 
                 −0.04 
                 1.43 
                 524 
                 51 
               
               
                 Example 20 
                 0.08 
                 −0.06 
                 0.13 
                 0.22 
                 0.06 
                 518 
                 53 
               
               
                 Example 21 
                 0.10 
                 −0.08 
                 0.03 
                 −0.06 
                 0.10 
                 520 
                 60 
               
               
                 Example 22 
                 0.07 
                 −0.07 
                 −0.23 
                 −0.03 
                 0.07 
                 511 
                 53 
               
               
                 Example 23 
                 0.08 
                 −0.06 
                 −0.15 
                 0.11 
                 0.08 
                 516 
                 80 
               
               
                 Example 24 
                 0.10 
                 −0.08 
                 0.11 
                 −0.04 
                 0.10 
                 524 
                 45 
               
               
                 Comparative 
                 0.08 
                 −0.07 
                 −0.23 
                 −0.03 
                 0.08 
                 511 
                 5 
               
               
                 Example 8 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
             
               
                 TABLE 13 
               
               
                   
               
               
                   
                   
                   
                   
                   
                   
                 Peak 
               
               
                   
                   
                   
                   
                   
                   
                 Wavelength 
               
               
                   
                 x2 
                 a 
                 b 
                 c 
                 d 
                 (nm) 
               
               
                   
               
             
            
               
                 Example 19 
                 0.10 
                 0.858 
                 3.34 
                 0.350 
                 4.92 
                 622 
               
               
                 Example 20 
                 0.11 
                 0.935 
                 3.41 
                 0.418 
                 5.18 
                 631 
               
               
                 Example 21 
                 0.15 
                 0.911 
                 3.70 
                 0.272 
                 5.63 
                 642 
               
               
                 Example 22 
                 0.08 
                 0.680 
                 2.54 
                 0.332 
                 4.29 
                 616 
               
               
                 Example 23 
                 0.09 
                 0.680 
                 2.54 
                 0.332 
                 4.29 
                 616 
               
               
                 Example 24 
                 0.10 
                 0.858 
                 3.34 
                 0.350 
                 4.92 
                 622 
               
               
                 Comparative 
                 0.10 
                 0.858 
                 3.34 
                 0.350 
                 4.92 
                 622 
               
               
                 Example 8 
               
               
                   
               
            
           
         
       
     
     The method for manufacturing the light emitting device of Example 19 will be described below with reference to  FIG. 11  and  FIG. 14 . 
     The InGaN compound semiconductor was used as the active layer, and 16 blue LED chips  12  ( FIG. 14 ) in which p-side/n-side electrodes were formed were prepared. The blue LED chip  12  is fixed to each of the plural recesses  46  of the flat-type mounting board  10  that is the stacked board of the patterned Cu metal and the insulating layer by using Sn—Ag—Cu paste. The patterned Cu metal constitutes the lead electrode. 
     As illustrated in  FIG. 21 , similarly to Example 13, the fixed LED chips  12  are connected so as to become the 4-by-4 array, and the anode electrode  60  and the cathode electrode  62  are formed. At this point, the lead electrode on the anode side and the p-side electrode of the blue LED chip  12  are electrically connected by the Au wire  14  ( FIG. 13 ), and the lead electrode on the cathode side and the n-side electrode of the blue LED chip  12  are electrically connected through Sn—Ag—Cu paste. Then, the LED chips  12  are sealed by applying the silicone resin, thereby protecting the Au wire  14 . 
     On the other hand, the silicone thin-film resin sheet  50  is loaded on the molding apparatus. In the resin sheet  50 , the region where the LED chips  12  are located is transparent, and the reflection layer  52  in which Ag fine particles are dispersed is formed in other portions. The resin sheet  50  has the thickness of 0.1 mm, and the bonding agent is applied to only one side of the resin sheet  50 . 
     Using the square die  42  having the size of 25 mm to 30 mm and the depth of 0.3 mm to 1.0 mm, the silicone transparent resin  26  is formed into the flat shape on the resin sheet  50  through the first-time molding process while the silicone transparent resin  26  is defoamed. Then, the resin sheet  50  in which the transparent resin  26  is formed is cured by retaining the resin sheet  50  at 150° C. for 30 minutes, thereby forming the transparent resin layer  16 . 
     Then, at the silicone resin which is the binder resin, using the die  44  whose opening diameter is slightly larger and deeper than that of the first-time molding process, the resin  32  in which the red phosphors illustrated in the field of Example 19 of TABLE 13 are dispersed is formed into the flat shape with the even thickness through the second-time molding process such that the whole of the flat transparent resin layer  16  formed through the first-time molding process is covered with the resin  32 . Then, the resin sheet  50  is cured by retaining the resin sheet  50  at 150° C. for 30 minutes at normal pressure in the atmosphere, thereby forming the first fluorescent layer  18 . 
     Then, using the die whose opening diameter is slightly larger and deeper than that of the second-time molding process, the resin in which the green phosphors illustrated in the field of Example 19 of TABLE 12 are dispersed is formed into the flat shape with the even thickness through the third-time molding process such that the whole of the flat first fluorescent layer  18  formed through the second-time molding process is covered with the resin. Then, the resin sheet  50  is cured by retaining the resin sheet  50  at 150° C. for 30 minutes at normal pressure in the atmosphere, thereby forming the second fluorescent layer  20 . Therefore, the stacked structure including the transparent resin layer  16 , the first fluorescent layer  18 , and the second fluorescent layer  20  becomes the flat shape. 
     Then, using the die whose opening diameter is slightly larger and deeper than that of the third-time molding process, the silicone transparent resin is formed with the even thickness through the fourth-time molding process such that the second fluorescent layer  20  applied through the third-time molding process is covered with the silicone transparent resin. The transparent resin is formed through the fourth-time molding process such that the ratio (=a/b) of the layer thickness a in the direction immediately above the LED chip and the layer thickness b in the lateral direction becomes 1.0. 
     Then, the transparent resin applied through the fourth-time molding process is cured by retaining the transparent resin at 150° C. for 30 minutes, and drying at normal pressure whereby the transparent resin layer  22  is formed to prepare the phosphor application sheet having the multi-layer structure. Therefore, the stacked structure including the transparent resin layer  16 , the first fluorescent layer  18 , the second fluorescent layer  20 , and the transparent resin layer  22  becomes the flat shape. 
     After the residual atmosphere is removed in the reduced-pressure chamber, the phosphor application sheet (resin sheet) is bonded to the flat-type mounting board  10  to prepare the light emitting device illustrated in  FIG. 11 . 
     Examples 20 to 24  
     The light emitting devices were produced in the way similar to that of Example 19 except that the green phosphors having the compositions, peak wavelengths, and average particle diameters, which are illustrated in fields of Examples 20 to 24 of TABLE 12, were applied to the second fluorescent layer and except that the red phosphors having the compositions and peak wavelengths, which are illustrated in fields of Examples 20 to 24 of TABLE 13, were applied to the first fluorescent layer. The evaluations similar to that of Example 19 were performed. TABLE 14 illustrates the result. 
     Comparative Example 8 
     The light emitting devices were produced in the way similar to that of Example 19 except that the green phosphors having the compositions, peak wavelengths, and average particle diameters, which are illustrated in fields of Comparative example 8 of TABLE 12, were applied to the second fluorescent layer and except that the red phosphors having the compositions and peak wavelengths, which are illustrated in fields of Comparative example 8 of TABLE 13, were applied to the first fluorescent layer. The evaluations similar to that of Example 19 were performed. TABLE 14 illustrates the result. 
     It was confirmed that Examples 19 to 24 having the average particle diameter of 12 μm or more are higher than Comparative example 8 in the luminous flux. The high-luminance flat-type light emitting devices were obtained by Examples 19 to 24. When a continuous lighting test was performed while the light emitting devices of Examples 19 to 24 were joined to heat sinks, the decrease in luminous flux caused by heat accumulation was able to be suppressed. Accordingly, the light emitting devices of Examples 19 to 24 had the small color shift, high luminance, high efficiency, and excellent heat-radiation performance. 
     
       
         
           
               
               
             
               
                   
                 TABLE 14 
               
               
                   
                   
               
               
                   
                 Total Luminous Flux 
               
               
                   
                 (Normalized) 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
            
               
                   
                 Example 19 
                 95 
               
               
                   
                 Example 20 
                 94 
               
               
                   
                 Example 21 
                 96 
               
               
                   
                 Example 22 
                 94 
               
               
                   
                 Example 23 
                 100 
               
               
                   
                 Example 24 
                 86 
               
               
                   
                 Comparative 
                 59 
               
               
                   
                 Example 8 
               
               
                   
                   
               
            
           
         
       
     
     Comparative Examples 9 to 11  
     The light emitting device of the sixth embodiment illustrated in  FIG. 11  was to be produced by adopting the method for manufacturing the light emitting device of the eighth embodiment illustrated in  FIG. 14 . At this point, the green phosphor having the composition, peak wavelength, and average particle diameter, which are illustrated in the fields of Comparative Examples 9 to 11 of TABLE 15, was applied to the second fluorescent layer. The red phosphor having the composition and peak wavelength, which are illustrated in the fields of Comparative Examples 9 to 11 of TABLE 16, was applied to the first fluorescent layer. 
     TABLE 15 illustrates values of x1, y, z, u, and w in the equation (1). TABLE 16 illustrates values of x2, a, b, c, and d in the equation (2). 
     The phosphors of Comparative examples 9 and 10 do not satisfy the conditions of the equations (1) and (2), although Comparative examples 9 and 10 are made based on the sialon compounds. Comparative example 11 of TABLE 16 is not made based on the sialon compound. 
     
       
         
           
               
               
               
               
               
               
               
             
               
                 TABLE 15 
               
               
                   
               
               
                   
                   
                   
                   
                   
                   
                 Peak 
               
               
                   
                   
                   
                   
                   
                   
                 Wavelength 
               
               
                   
                 x1 
                 y 
                 z 
                 u 
                 w 
                 (nm) 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
            
               
                 Comparative 
                 0.08 
                 0.03 
                 1.46 
                 2.99 
                 0.08 
                 Weak 
               
               
                 Example 9 
                   
                   
                   
                   
                   
                 emission 
               
               
                 Comparative 
                 0.08 
                 −0.11 
                 0.05 
                 3.12 
                 0.08 
                 Weak 
               
               
                 Example 10 
                   
                   
                   
                   
                   
                 emission 
               
               
                 Comparative 
                 0.10 
                 −0.37 
                 −0.35 
                 2.64 
                 0.1 
                 Weak 
               
               
                 Example 11 
                   
                   
                   
                   
                   
                 emission 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
             
               
                 TABLE 16 
               
               
                   
               
               
                   
                   
                   
                   
                   
                   
                 Peak 
               
               
                   
                   
                   
                   
                   
                   
                 Wavelength 
               
               
                   
                 X2 
                 a 
                 b 
                 c 
                 d 
                 (nm) 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
            
               
                 Comparative 
                 0.50 
                 0.350 
                 4.61 
                 0.613 
                 2.23 
                 Weak 
               
               
                 Example 9 
                   
                   
                   
                   
                   
                 emission 
               
               
                 Comparative 
                 0.14 
                 1.12 
                 1.35 
                 0.580 
                 6.34 
                 Weak 
               
               
                 Example 10 
                   
                   
                   
                   
                   
                 emission 
               
               
                 Comparative 
                 0.10 
                 0.450 
                 5.00 
                 0.00 
                 8.00 
                 Weak 
               
               
                 Example 11 
                   
                   
                   
                   
                   
                 emission 
               
               
                   
               
            
           
         
       
     
     As illustrated in TABLES 15 and 16, because the light emission is weak and insufficient for manufacturing the light emitting device in any phosphor, the light emitting device was not produced using the phosphors illustrated in TABLES 15 and 16.