Patent Publication Number: US-2023162956-A1

Title: Substrate processing apparatus and substrate processing method

Description:
CROSS-REFERENCE TO RELATED APPLICATIONS 
     This application claims priority to Japanese Patent Application No. 2021-188695, filed on Nov. 19, 2021, the entire contents of which are incorporated herein by reference. 
     TECHNICAL FIELD 
     The present disclosure relates to a substrate processing apparatus and a substrate processing method. 
     BACKGROUND 
     Patent Document 1 discloses an electrostatic chuck such that a dielectric layer for absorbing a substrate to be processed and a heat insulating plate are stacked, and that an upper surface and a side surface of the dielectric layer of the heat insulating plate are covered with a conductive film for charge escape. According to the electrostatic chuck disclosed in Patent Document 1, the dielectric layer is made of alumina ceramic or the like for attracting the substrate to be processed by using an electrostatic force. 
     PRIOR ART DOCUMENTS 
     Patent Documents 
     
         
         Patent Document 1: JP-A-2013-016554 
       
    
     SUMMARY 
     According to the technique of the present disclosure, a substrate is stably attracted and detached to and from the electrostatic chuck controlled to a high temperature. 
     An aspect of the present disclosure includes an electrostatic chuck that attracts a substrate, and includes: a dielectric and an attracting electrode for attracting the substrate inside of the dielectric, a heater electrode for heating the substrate; an attracting power source for applying an attraction voltage for attracting the substrate to the attracting electrode; and a heating power source for applying a heater voltage for heating the substrate to the heater electrode, wherein the attracting power source controls a magnitude of the attraction voltage that is applied to the attracting electrode based on a magnitude of the heater voltage. 
     According to the present disclosure, a substrate can be stably attracted and detached to and from the electrostatic chuck being controlled to a high temperature. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG.  1 A  is a graph illustrating a relationship between the attraction time of a substrate and the transfer amount of charges in a case where an electrostatic chuck is controlled to room temperature. 
         FIG.  1 B  is a graph illustrating a relationship between the attraction time of the substrate and the transfer amount of charges in a case where the electrostatic chuck is controlled to a high temperature. 
         FIG.  2    is a vertical sectional view illustrating an example of a configuration of a plasma processing system according to the present disclosure. 
         FIG.  3 A  is a vertical sectional view illustrating a schematic configuration of a substrate support according to a first embodiment. 
         FIG.  3 B  is a cross-sectional view illustrating a schematic configuration of the substrate support according to the first embodiment. 
         FIG.  4 A  is a graph illustrating a relationship between the temperature of the electrostatic chuck and the transfer amount of charges in a case where an attraction voltage is constant in the radial direction of the electrostatic chuck. 
         FIG.  4 B  is a graph illustrating a relationship between the temperature of the electrostatic chuck and the transfer amount of charges in a case where the attraction voltage is changed in the radial direction of the electrostatic chuck. 
         FIG.  5    is an explanatory view illustrating an example of a configuration of a plasma processing system according to another embodiment. 
         FIG.  6 A  is a vertical sectional view illustrating a schematic configuration of a substrate support according to a second embodiment. 
         FIG.  6 B  is a cross-sectional view illustrating a schematic configuration of the substrate support according to the second embodiment. 
         FIG.  6 C  is an explanatory view illustrating a relationship between the attraction time and the transfer amount of charges in a case where a direct-current voltage is applied to an attracting electrode of the electrostatic chuck and in a case where an alternating-current voltage is applied thereto. 
         FIG.  7 A  is a graph illustrating a relationship between a time and an attraction voltage in a case where a phase difference of the attraction voltage applied to each attracting electrode is 0° in the substrate support of the second embodiment. 
         FIG.  7 B  is a graph illustrating a relationship between a time and an attraction voltage in a case where the phase difference of the attraction voltage applied to each attracting electrode is 30° in the substrate support of the second embodiment. 
         FIG.  7 C  is a graph illustrating the relationship between a time and an attraction voltage in a case where the phase difference of the attraction voltage applied to each attracting electrode is 60° in the substrate support of the second embodiment. 
         FIG.  7 D  is a graph illustrating the relationship between a time and an attraction voltage in a case where the phase difference of the attraction voltage applied to each attracting electrode is 90° in the substrate support of the second embodiment. 
         FIG.  7 E  is a graph illustrating the relationship between a time and an attraction voltage in a case where the phase difference of the attraction voltage applied to each attracting electrode is 180° in the substrate support of the second embodiment. 
         FIG.  8    is an explanatory view illustrating a modification example of a plasma processing system according to the second embodiment. 
     
    
    
     DETAILED DESCRIPTION 
     In the manufacturing process of a semiconductor device, an etching target layer (for example, a silicon-containing film) formed by laminating on a surface of a semiconductor substrate (hereinafter, simply referred to as a “substrate”) is subjected to an etching process using a mask layer (for example, a resist film) in which a pattern is formed in advance as a mask. This etching process is generally performed in a plasma processing apparatus that includes an electrostatic chuck that attracts and holds a substrate by using an electrostatic force. 
     As the electrostatic chuck described above, as disclosed in Patent Document 1, a Coulomb type electrostatic chuck may be used. Usually, a direct-current voltage is applied to a coulomb type electrostatic chuck, and in order to realize stable attraction and detachment of a substrate, it is required to maintain the volume resistivity of the electrostatic chuck to a desired value or more, for example, 1e+15 cmΩ or more. 
     In recent years, due to the change of the material of a mask layer, a demand for performing substrate processing while controlling the electrostatic chuck to a high temperature has been increasing. Here, as illustrated in  FIG.  1 A , since the volume resistivity of the electrostatic chuck is high at room temperature, the transfer amount of charges with respect to the attraction time becomes slow, and the polarization between the substrate and the electrostatic chuck is appropriately maintained. In contrast, as illustrated in  FIG.  1 B , since the volume resistivity of the electrostatic chuck decreases at a high temperature, the transfer amount of charges with respect to the attraction time becomes steep. As a result, the polarization between the substrate and the electrostatic chuck may not be appropriately maintained, and it may be difficult to make stable attraction and detachment due to the influence of the residual charges. As an example, the influence of such residual charges starts to appear when the temperature of the electrostatic chuck becomes around 200° C., and becomes remarkable when the temperature exceeds 250° C. 
     As an electrostatic chuck that can cope with a high temperature, there is a Johnson-Rahbek (JR) type electrostatic chuck, and with a JR type electrostatic chuck, it is difficult to control residual attraction; further, the volume resistivity changes considerably with temperature, and thus the room temperature processing and the high temperature processing cannot be consecutively performed. In other words, a conventional electrostatic chuck has room for improvement, and it is required to control an electrostatic chuck such that a substrate can be stably attracted and detached even at a high temperature. 
     The technique according to the present disclosure has been made in consideration of the above-described circumstances, and a substrate is stably attracted and detached in an electrostatic chuck controlled to a high temperature. Hereinafter, a plasma processing system and a plasma processing method according to the present disclosure will be described with reference to drawings. The same reference numerals will be given to elements having substantially the same functional configurations throughout the specification and the drawings, and redundant description thereof will be omitted. 
     &lt;Plasma Processing Apparatus&gt; 
     First, a plasma processing system according to the present disclosure will be described.  FIG.  2    is a schematic cross-sectional view illustrating an example of the plasma processing system according to the present disclosure. 
     The plasma processing system includes a capacitively-coupled plasma processing apparatus  1  and a controller  2 . A plasma processing apparatus  1  includes a plasma processing chamber  10 , a gas supply  20 , a power source  30 , and an exhaust system  40 . Further, the plasma processing apparatus  1  includes a substrate support  11  and a gas introduction unit. The substrate support  11  is disposed inside the plasma processing chamber  10 . The gas introduction unit is configured to introduce at least one processing gas into the plasma processing chamber  10 . The gas introduction unit includes a shower head  13 . The shower head  13  is disposed above the substrate support  11 . In one embodiment, the shower head  13  constitutes at least a part of a ceiling of the plasma processing chamber  10 . A plasma processing space  10   s  defined by the shower head  13 , a sidewall  10   a  of the plasma processing chamber  10 , and the substrate support  11  is formed inside the plasma processing chamber  10 . The plasma processing chamber  10  has at least one gas supply port for supplying at least one processing gas into the plasma processing space  10   s , and at least one gas exhaust port for exhausting the gas from the plasma processing space  10   s . The plasma processing chamber  10  is grounded, including the sidewall  10   a . The shower head  13  and the substrate support  11  are electrically insulated from the plasma processing chamber  10 . 
     The substrate support  11  includes a main body  111  and a ring assembly  112 . The main body  111  includes a substrate support surface  111   a  for supporting a substrate (wafer) W, and a ring support surface  111   b  for supporting the ring assembly  112 . The ring support surface  111   b  of the main body  111  surrounds the substrate support surface  111   a  of the main body  111  in a plan view. The substrate W is disposed on the substrate support surface  111   a  of the main body  111 , and the ring assembly  112  is disposed on the ring support surface  111   b  of the main body  111  to surround the substrate W on the substrate support surface  111   a  of the main body  111 . The main body  111  includes a base  113  and an electrostatic chuck  114 . The base  113  includes a conductive member. The conductive member of the base  113  functions as a lower electrode. The electrostatic chuck  114  includes a dielectric such as ceramic and an attracting electrode disposed in the dielectric. The electrostatic chuck  114  is disposed on the base  113 . The upper surface of the electrostatic chuck  114  has a substrate support surface  111   a . The ring assembly  112  includes one or more annular members. At least one of the one or more annular members is an edge ring. Although not illustrated, the substrate support  11  may include a temperature control module configured to adjust at least one of the electrostatic chuck  114 , the ring assembly  112 , and the substrate W to a target temperature. The temperature control module includes a heater, a heat transfer medium, and a flow path. A heat transfer fluid, such as brine or gas, flows through the flow path. Further, the substrate support  11  may include a heat transfer gas supply configured to supply a heat transfer gas between the rear surface of the substrate W and the substrate support surface  111   a.    
     The detailed configuration of the substrate support  11  according to the embodiment will be described later. 
     The shower head  13  is configured to introduce at least one processing gas from the gas supply  20  into the plasma processing space  10   s . The shower head  13  has at least one gas supply port  13   a , at least one gas diffusion chamber  13   b , and a plurality of gas introduction ports  13   c . The processing gas supplied from the gas supply  20  to the gas supply port  13   a  passes through the gas diffusion chamber  13   b  and is introduced into the plasma processing space  10   s  from the plurality of gas introduction ports  13   c . Further, the shower head  13  includes a conductive member. The conductive member of the shower head  13  functions as an upper electrode. The gas introduction unit may include, in addition to the shower head  13 , one or a plurality of side gas injectors (SGI) that are attached to one or a plurality of openings formed in the sidewall  10   a.    
     The gas supply  20  may include at least one gas source  21  and at least one flow rate controller  22 . In one embodiment, the gas supply  20  is configured to supply at least one processing gas from the respective corresponding gas sources  21  to the shower head  13  via the respective corresponding flow rate controllers  22 . Each flow rate controller  22  may include, for example, a mass flow controller or a pressure-controlled flow rate controller. Further, the gas supply  20  may include one or more flow rate modulation devices that modulate or pulse flow rates of at least one processing gas. 
     The power source  30  includes an RF power source  31  coupled to plasma processing chamber  10  via at least one impedance matching circuit. The RF power source  31  is configured to supply at least one RF signal (RF power), such as the source RF signal and the bias RF signal, to the conductive member (lower electrode) of the substrate support  11  and/or the conductive member (upper electrode) of the shower head  13 . As a result, plasma is formed from at least one processing gas supplied into the plasma processing space  10   s . Accordingly, the RF power source  31  may function as at least a portion of a plasma generator configured to generate plasma from one or more processing gases in the plasma processing chamber  10 . Further, by supplying the bias RF signal to the lower electrode, a bias potential can be generated in the substrate W to draw an ionic component in the formed plasma to the substrate W. 
     In one embodiment, the RF power source  31  includes a first RF generator  31   a  and a second RF generator  31   b . The first RF generator  31   a  is configured to be coupled to the lower electrode and/or the upper electrode via at least one impedance matching circuit to generate a source RF signal (source RF power) for plasma generation. In one embodiment, the source RF signal has a frequency in the range of 13 MHz to 150 MHz. In one embodiment, the first RF generator  31   a  may be configured to generate a plurality of source RF signals having different frequencies. The one or the plurality of source RF signals generated are supplied to the lower electrode and/or the upper electrode. The second RF generator  31   b  is configured to be coupled to the lower electrode via at least one impedance matching circuit to generate the bias RF signal (bias RF power). In one embodiment, the bias RF signal has a lower frequency than the source RF signal. In one embodiment, the bias RF signal has a frequency in the range of 400 kHz to 13.56 MHz. In one embodiment, the second RF generator  31   b  may be configured to generate a plurality of bias RF signals having different frequencies. The one or the plurality of bias RF signals generated are supplied to the lower electrode. Further, in various embodiments, at least one of the source RF signal and the bias RF signal may be pulsed. 
     Further, the power source  30  may include a DC power source  32  coupled to the plasma processing chamber  10 . The DC power source  32  includes a first DC generator  32   a  and a second DC generator  32   b . In one embodiment, the first DC generator  32   a  is configured to be connected to the lower electrode and to generate the first DC signal. The generated first DC signal is applied to the lower electrode. In one embodiment, the first DC signal may be applied to another electrode, such as an electrode in an electrostatic chuck. In one embodiment, the second DC generator  32   b  is configured to be connected to the upper electrode to generate a second DC signal. The generated second DC signal is applied to the upper electrode. In various embodiments, at least one of the first and second DC signals may be pulsed. The first and second DC generators  32   a  and  32   b  may be provided in addition to the RF power source  31 , and the first DC generator  32   a  may be provided instead of the second RF generator  31   b.    
     The exhaust system  40  may be connected to, for example, a gas exhaust port  10   e  disposed at a bottom portion of the plasma processing chamber  10 . The exhaust system  40  may include a pressure adjusting valve and a vacuum pump. The pressure inside the plasma processing space  10   s  is adjusted by the pressure adjusting valve. The vacuum pump may include a turbo molecular pump, a dry pump, or a combination thereof. 
     The controller  2  processes computer-executable instructions for instructing the plasma processing apparatus  1  to execute various steps described herein below. The controller  2  may be configured to control the respective components of the plasma processing apparatus  1  to execute the various steps described herein below. In an embodiment, part or all of the controller  2  may be included in the plasma processing apparatus  1 . The controller  2  may include, for example, a computer  2   a . For example, the computer  2   a  may include a processor (central processing unit (CPU))  2   a   1 , a storage  2   a   2 , and a communication interface  2   a   3 . The processor  2   a   1  may be configured to perform various control operations based on a program stored in the storage  2   a   2 . The storage  2   a   2  may include a random access memory (RAM), a read only memory (ROM), a hard disk drive (HDD), a solid state drive (SSD), or a combination thereof. The communication interface  2   a   3  may communicate with the plasma processing apparatus  1  via a communication line such as a local area network (LAN). 
     While various exemplary embodiments have been described above, various additions, omissions, substitutions and changes may be made without being limited to the exemplary embodiments described above. Indeed, the embodiments described herein may be embodied in a variety of other forms. 
     &lt;Substrate Support According to First Embodiment&gt; 
     Hereinafter, a configuration of a substrate support according to a first embodiment will be described.  FIG.  3 A  is a vertical sectional view illustrating an example of a configuration of a substrate support  11  according to a first embodiment.  FIG.  3 B  is a cross-sectional view taken along a line IIIB-IIIB in  FIG.  3 A . 
     Inside of the electrostatic chuck  114 , a central heater electrode  115   a  and a peripheral heater electrode  115   b  are provided to be configured to adjust at least the electrostatic chuck  114  to a target temperature. Further, inside of the electrostatic chuck  114 , a central attracting electrode  116   a  and a peripheral attracting electrode  116   b  for attracting and holding the substrate W onto the substrate support surface  111   a  are provided on the upper surface side (the substrate W side) of the central heater electrode  115   a  and the peripheral heater electrode  115   b . The electrostatic chuck  114  is configured as a Coulomb type electrostatic chuck in which the central heater electrode  115   a , the peripheral heater electrode  115   b , the central attracting electrode  116   a , and the peripheral attracting electrode  116   b  are interposed between dielectrics. 
     As illustrated in  FIG.  3 B , the substrate support surface  111   a  of the electrostatic chuck  114  includes a first temperature control region Z 1  formed inward in the radial direction and a second temperature control region Z 2  formed to surround the first temperature control region Z 1  in a plan view. 
     The central heater electrode  115   a  is provided below the central attracting electrode  116   a  (IIIB-IIIB cross-section) at a position corresponding to the first temperature control region Z 1  (the base  113  side). Further, the peripheral heater electrode  115   b  is provided below the peripheral attracting electrode  116   b  (IIIB-IIIB cross-section) and at a position corresponding to the second temperature control region Z 2 . That is, the electrostatic chuck  114  of the first embodiment is configured to adjust the temperature of the substrate W independently for each of a plurality of temperature control regions Z (for each of the two temperature control regions Z in the example illustrated in  FIG.  3 A ). 
     In an example, a heating power source (not illustrated) is connected to each of the central heater electrode  115   a  and the peripheral heater electrode  115   b , and a heater voltage is applied from each of the heating power sources to each heater electrode. In another example, a single heating power source is connected to the central heater electrode  115   a  and the peripheral heater electrode  115   b , and a heater voltage is applied from the heating power source to each heater electrode. In either case, the heater voltages applied from the heating power source to the central heater electrode  115   a  and the peripheral heater electrode  115   b  are configured to be independently controllable. Then, the central heater electrode  115   a  and the peripheral heater electrode  115   b  are heated by the application of the heater voltage from the heating power source, and thus the substrate W held on the electrostatic chuck  114  and the substrate support surface  111   a  is heated. 
     The central attracting electrode  116   a  is provided corresponding to the first temperature control region Z 1 . Further, the peripheral attracting electrode  116   b  is provided corresponding to the second temperature control region Z 2 . That is, the electrostatic chuck  114  of the first embodiment is configured such that the attraction voltage of the substrate W is independently applicable to each of the plurality of temperature control regions Z (each of the two temperature control regions Z in the examples illustrated in  FIGS.  3 A and  3 B ). 
     In an example, an attracting power source  117  is connected to each of the central attracting electrode  116   a  and the peripheral attracting electrode  116   b , and an attraction voltage is applied from each attracting power source to each attracting electrode. In another example, the single attracting power source  117  is connected to the central attracting electrode  116   a  and the peripheral attracting electrode  116   b , and an attraction voltage is applied from the attracting power source  117  to each attracting electrode. In either case, the attraction voltages applied from the attracting power source  117  to the central attracting electrode  116   a  and the peripheral attracting electrode  116   b  are configured to be independently controllable. Then, the substrate W is attracted and held onto the substrate support surface  111   a  by an electrostatic force to be generated by the application of the attraction voltage from the attracting power source  117 . 
     &lt;Processing Method of Substrate by Plasma Processing Apparatus&gt; 
     Next, an example of the processing method of the substrate W in the plasma processing apparatus  1  configured as described above will be described. In the plasma processing apparatus  1 , the substrate W is subjected to an etching process, for example, using a mask layer in which a pattern is formed in advance as a mask. In the present embodiment, the temperature of the electrostatic chuck  114  is raised to a target temperature (for example, 200° C. or more) before or after the substrate W is placed. 
     First, the substrate W is carried into the plasma processing chamber  10 , and the substrate W is placed on the electrostatic chuck  114  of the substrate support  11 . Next, an alternating-current voltage is applied to the central attracting electrode  116   a  and the peripheral attracting electrode  116   b  of the electrostatic chuck  114 , and the substrate W is attracted and held onto the electrostatic chuck  114  by an electrostatic force to be thus generated. The method of holding the substrate W by the electrostatic chuck  114  will be described in detail later. 
     When the substrate W is attracted and held onto the electrostatic chuck  114 , the inside of the plasma processing chamber  10  is decompressed to a predetermined vacuum level. Further, the processing gas is supplied from the gas supply  20  to the plasma processing space  10   s  via the shower head  13 . Further, the source RF power for generating plasma is supplied from the first RF generator  31   a  to the conductive member of the substrate support  11 , thereby exciting the processing gas to generate plasma. At this time, the bias RF power may be supplied from the second RF generator  31   b . Then, in the plasma processing space  10   s , the substrate W is subjected to an etching process by the action of the generated plasma. 
     When the plasma processing is ended, the supply of the source RF power from the first RF generator  31   a  and the supply of the processing gas from the gas supply  20  are stopped. In a case where the bias RF power is supplied during the plasma processing, the supply of the bias RF power is also stopped. 
     Next, the attraction and holding of the substrate W by the electrostatic chuck  114  is stopped, and the charge neutralization of the substrate W and the electrostatic chuck  114  after the plasma processing is performed. Thereafter, the substrate W is detached from the electrostatic chuck  114 , and the substrate W is carried out from the plasma processing apparatus  1 . In this way, a series of plasma processing is completed. 
     &lt;Method of Holding Substrate by Substrate Support of First Embodiment&gt; 
     In the plasma processing apparatus  1 , plasma processing is performed on the substrate W as described above. Next, the method of holding the substrate W by the electrostatic chuck  114  described above will be described in detail. 
     In the substrate support  11  according to the present embodiment, the temperatures of the two temperature control regions Z 1  and Z 2  of the electrostatic chuck  114  are controlled independently of each other as described above. At this time, when the temperature of the electrostatic chuck  114  is set to a high temperature, the volume resistivity of the electrostatic chuck  114  decreases as described above. Therefore, as illustrated in  FIG.  4 A , the transfer amount of charges in the region (in the illustrated example, the peripheral portion of the substrate W) where the temperature of the electrostatic chuck  114  is high increases compared with the transfer amount of charges in the region (in the illustrated example, the central portion of the substrate W) where the temperature is low. As a result, stable attraction and detachment of the substrate W may be lost. 
     To cope with such a drawback, in the present embodiment, the transfer amount of charges in the electrostatic chuck  114  is controlled by adjusting the attraction voltage applied to the central attracting electrode  116   a  and the peripheral attracting electrode  116   b  according to the temperature of the electrostatic chuck  114 . For example, as illustrated in  FIG.  4 B , the attraction voltage applied to the peripheral attracting electrode  116   b  in the second temperature control region Z 2  where the temperature of the electrostatic chuck  114  is high is lowered as compared with the attraction voltage applied to the central attracting electrode  116   a , whereby the transfer amount of charges is maintained to be substantially constant, and the occurrence of residual attraction is suppressed. 
     As described above, the temperature of the electrostatic chuck  114  is controlled by the heater voltage that is applied from the heating power source to the central heater electrode  115   a  and the peripheral heater electrode  115   b . Therefore, instead of the temperature of the electrostatic chuck  114 , the voltage applied to the central attracting electrode  116   a  and the peripheral attracting electrode  116   b  may be adjusted according to the voltage applied to the central heater electrode  115   a  and the peripheral heater electrode  115   b.    
     Further, the following configuration is acceptable: the correlation between the temperature of the electrostatic chuck  114  and the attraction voltage applied to the central attracting electrode  116   a  and the peripheral attracting electrode  116   b  is obtained in advance, and the attraction voltage applied to the central attracting electrode  116   a  and the peripheral attracting electrode  116   b  is controlled based on the correlation. Further, for example, the temperature of the electrostatic chuck  114  may be measured over time during the plasma processing, and the attraction voltage applied to the central attracting electrode  116   a  and the peripheral attracting electrode  116   b  may be feedback-controlled according to the measured temperature. 
     &lt;Operations and Effects of Technique According to First Embodiment&gt; 
     In the plasma processing apparatus  1  according to the first embodiment described above, the attraction voltage applied from the attracting power source  117  to the central attracting electrode  116   a  and the peripheral attracting electrode  116   b  is controlled according to the temperature of the electrostatic chuck  114  in the substrate support  11 . Accordingly, the increase in the transfer amount of charges caused by the increase in the temperature of the electrostatic chuck  114  is suppressed, and the transfer amount of charges is lowered below a threshold value that takes a risk occurrence of the residual attraction. 
     At this time, control is performed such that the transfer amount of charges between the substrate W and the central attracting electrode  116   a  or the peripheral attracting electrode  116   b  is uniform (constant) and lower than the threshold value that takes a risk of occurrence of the residual attraction in the entire surface of the electrostatic chuck  114  (the substrate W), whereby the substrate W can be more stably attracted and detached. The threshold value that takes a risk of occurrence of the residual attraction may be experimentally obtained in advance, or may be obtained by simulation or the like. 
     Further, according to the first embodiment, as illustrated in  FIG.  3   , an attraction voltage can be independently applied to each of the central attracting electrode  116   a  and the peripheral attracting electrode  116   b . Accordingly, it is possible to apply thereto the attraction voltage according to the temperature of each of the temperature control regions of the electrostatic chuck  114 , and it is possible to more stably attract and detach the substrate W while lowering the risk of occurrence of the residual attraction. 
     In the above embodiment, the case where the electrostatic chuck  114  is divided into two temperature control regions Z in a plan view has been described by way of example; however, the number of divided temperature control regions Z is not limited thereto, and the electrostatic chuck  114  may be divided into three or more temperature control regions. In this case, an attracting electrode may be disposed for each temperature control region Z. 
     In the embodiment described above, the case where the alternating-current voltage is applied from the attracting power source  117  to the central attracting electrode  116   a  and the peripheral attracting electrode  116   b  has been described by way of example; however, instead of this, as illustrated in  FIG.  5   , a direct-current voltage may be applied from the DC power source  32  to the central attracting electrode  116   a  and the peripheral attracting electrode  116   b.    
     &lt;Substrate Support According to Second Embodiment&gt; 
     Next, a configuration of a substrate support according to a second embodiment will be described with reference to drawings. In the substrate support according to the second embodiment, elements having substantially the same functions as those of the substrate support  11  illustrated in  FIGS.  3 A and  3 B  are denoted by the same reference numerals, and descriptions thereof will be simplified or omitted. 
       FIG.  6 A  is a vertical sectional view illustrating an example of a configuration of a substrate support  200  according to the second embodiment. The substrate support  200  includes a main body  211  and a ring assembly  112 . The upper surface of the main body  211  includes a substrate support surface  211   a  for supporting the substrate W, and a ring support surface  211   b  for supporting the ring assembly  112 . The ring support surface  211   b  surrounds the substrate support surface  211   a  in a plan view. The main body  211  includes a base  113  and an electrostatic chuck  214 . The electrostatic chuck  214  is disposed on the base  113 . The upper surface of the electrostatic chuck  214  includes a substrate support surface  211   a  and a ring support surface  211   b . Inside of the electrostatic chuck  214 , at least a central heater electrode  115   a  and a peripheral heater electrode  115   b  are provided to be configured to adjust the electrostatic chuck  214  to a target temperature. Further, inside of the electrostatic chuck  214 , provided are a central attracting electrode  216   a  for attracting and holding the substrate W onto the substrate support surface  211   a , and a peripheral attracting electrode  216   b  for attracting and holding the ring assembly  112  onto the ring support surface  211   b.    
       FIG.  6 B  is a cross-sectional view taken along a line VIB-VIB in  FIG.  6 A . In an example, the central attracting electrode  216   a  includes a first central attracting electrode  216   a   1  and a second central attracting electrode  216   a   2  which are alternately disposed in the first temperature control region Z 1 . Further, the peripheral attracting electrode  216   b  includes a first peripheral attracting electrode  216   b   1  and a second peripheral attracting electrode  216   b   2  that are alternately disposed in the second temperature control region Z 2 . That is, the electrostatic chuck  214  in the second embodiment is configured as a Coulomb-type bipolar electrostatic chuck configured to attract the substrate W independently for each of the plurality of temperature control regions Z in a plan view, and of two temperature control regions Z in the examples of  FIGS.  6 A and  6 B . 
     An attraction voltage is applied from the attracting power source  217   a  of the substrate W to the first central attracting electrode  216   a   1  and the second central attracting electrode  216   a   2 , and an attraction voltage is applied from the attracting power source  217   b  of the substrate W to the first central attracting electrode  216   b   1  and the second central attracting electrode  216   b   2 . In an example, the attracting power sources  217   a  and  217   b  are AC power sources. The waveforms of the voltages applied from the attracting power sources  217   a  and  217   b  to the first central attracting electrode  216   a   1  and the second central attracting electrode  216   a   2  may be a sine wave or a rectangular wave, or may be other waveforms. The attraction voltages applied from the attracting power source  217   a  to the first central attracting electrode  216   a   1  and the second central attracting electrode  216   a   2  are configured to be independently controllable. Further, the attraction voltages applied from the attracting power source  217   b  to the first peripheral attracting electrode  216   b   1  and the second peripheral attracting electrode  216   b   2  are configured to be independently controllable. Then, in the electrostatic chuck  214 , the substrate W is attracted and held onto the substrate support surface  211   a  by an electrostatic force to be generated by the application of the attraction voltage from the attracting power source  217 . 
     In the present embodiment, as described above, the attracting power source  217   a  is connected to the first central attracting electrode  216   a   1  and the second central attracting electrode  216   a   2 , and the attracting power source  217   b  is connected to the first peripheral attracting electrode  216   b   1  and the second peripheral attracting electrode  216   b   2 , whereby the attraction voltage is independently applied to the corresponding electrode; however, the number of the attracting power sources  217  provided in the plasma processing apparatus  1  is not limited thereto. For example, the first central attracting electrode  216   a   1  and the second central attracting electrode  216   a   2  may be connected to the same attracting power source  217   a , and the first peripheral attracting electrode  216   b   1  and the second peripheral attracting electrode  216   b   2  may be connected to the same attracting power source  217   b . Further, for example, each of the first central attracting electrode  216   a   1 , the second central attracting electrode  216   a   2 , the first peripheral attracting electrode  216   b   1 , and the second peripheral attracting electrode  216   b   2  may be connected to the same attracting power source. 
     In the substrate support  200  according to the present embodiment, the magnitudes of the attraction voltages applied from the attracting power source  217   a  to the first central attracting electrode  216   a   1  and the second central attracting electrode  216   a   2  periodically change, and the phase of the attraction voltage applied to the first central attracting electrode  216   a   1  is different from the phase of the attraction voltage applied to the second central attracting electrode  216   a   2 . Further, the magnitudes of the attraction voltages applied from the attracting power source  217   b  to the first peripheral attracting electrode  216   b   1  and the second peripheral attracting electrode  216   b   2  periodically change, and the phase of the attraction voltage applied to the first peripheral attracting electrode  216   b   1  is different from the phase of the attraction voltage applied to the second peripheral attracting electrode  216   b   2 . The application of the attraction voltages from the attracting power sources  217   a  and  217   b  is controlled by the controller  2 . In the following description, the first central attracting electrode  216   a   1  and the first peripheral attracting electrode  216   b   1  correspond to the “first attracting electrode” according to the technique of the present disclosure, and the second central attracting electrode  216   a   2  and the second peripheral attracting electrode  216   b   2  respectively correspond to the “second attracting electrode” according to the technique of the present disclosure. 
     Further, in the following description, a case where an alternating-current voltage is applied from the attracting power source  217   a  to the first central attracting electrode  216   a   1  and the second central attracting electrode  216   a   2  will be described by way of example; however, a case where the alternating-current voltage is applied from the attracting power source  217   b  to the first peripheral attracting electrode  216   b   1  and the second peripheral attracting electrode  216   b   2  can also be performed in the same manner. 
       FIG.  6 C  is a graph illustrating a relationship between the attraction time (horizontal axis) and the transfer amount of charges (vertical axis) in a case where the electrostatic chuck  214  is controlled to a high temperature. In  FIG.  6 C , the solid line represents the relationship between the attraction time and the transfer amount of charges in a case where an alternating-current voltage is applied to the first central attracting electrode  216   a   1  and the second central attracting electrode  216   a   2  of the electrostatic chuck  214 . Further, in  FIG.  6 C , the dotted line represents the relationship between the attraction time and the transfer amount of charges in a case where a direct-current voltage is applied to the first central attracting electrode  216   a   1  and the second central attracting electrode  216   a   2  of the electrostatic chuck  214 . 
     As described above, in a case where the electrostatic chuck  214  is controlled to a high temperature, the volume resistivity of the electrostatic chuck  214  decreases. Therefore, in a case where a direct-current voltage is applied to the first central attracting electrode  216   a   1  and the second central attracting electrode  216   a   2  of the electrostatic chuck  214 , the transfer amount of charges increases over time, so that attraction and holding of the substrate W may be lost. In contrast, in a case where an alternating-current voltage is applied to the first central attracting electrode  216   a   1  and the second central attracting electrode  216   a   2  of the electrostatic chuck  214 , the polarity of the attraction voltage periodically changes, and thus the transfer amount of charges is reset each time. As a result, it is possible to suppress the unstable attraction and holding of the substrate W due to the increase in the transfer amount of charges. 
     Here, as illustrated in  FIG.  7 A , in a case where the alternating-current voltage A applied to the first central attracting electrode  216   a   1  is in phase (with a phase difference of 0°) with the alternating-current voltage B applied to the second central attracting electrode  216   a   2 , there is a timing such that the total voltage applied to the two attracting electrodes becomes 0 V, and at this timing, the substrate W may be detached from the electrostatic chuck  214 . Therefore, in the second embodiment, the detaching of the substrate W from the electrostatic chuck  214  is suppressed by applying to the first central attracting electrode  216   a   1  an alternating-current voltage A having a phase different from the phase of an alternating-current voltage B that is applied to the second central attracting electrode  216   a   2 . 
       FIGS.  7 B to  7 E  are graphs illustrating a relationship between time (horizontal axis) and voltage (vertical axis) in a case where an alternating-current voltage A having a phase difference of 30°, 60°, 90°, or 180° from the alternating-current voltage B that is applied to the second central attracting electrode  216   a   2  is applied to the first central attracting electrode  216   a   1 . 
     As illustrated in  FIGS.  7 B to  7 D , in a case where the alternating-current voltage A having a phase different from the phase of the alternating-current voltage B applied to the second central attracting electrode  216   a   2  is applied to the first central attracting electrode  216   a   1 , there is no timing such that the total voltage applied from the two attracting electrodes to the substrate W becomes 0 V. Therefore, it is possible to suppress the substrate W from being detached from the electrostatic chuck  214 . 
     In particular, as illustrated in  FIG.  7 D , in a case where the alternating-current voltage A having a phase difference of 90° from the alternating-current voltage B applied to the second central attracting electrode  216   a   2  is applied to the first central attracting electrode  216   a   1 , the average value of the total voltage applied to the substrate W becomes the highest, and also the variation width of the total voltage may be minimized. 
     Meanwhile, as illustrated in  FIG.  7 E , in a case where the alternating-current voltage A having a phase difference of 180° from the alternating-current voltage B applied to the second central attracting electrode  216   a   2  is applied to the first central attracting electrode  216   a   1 , there is a timing such that the total voltage applied to the two attracting electrodes become 0 V, as in the case illustrated in  FIG.  7 A . 
     As described above, the phase difference between the alternating-current voltages that are applied to the first central attracting electrode  216   a   1  and the second central attracting electrode  216   a   2  is preferably greater than 0° and less than 180°, and is more preferably 30° to 150°. Further, this phase difference is set to 90° or in the vicinity thereof, for example, 70° to 110° or 80° to 100°, whereby the substrate W is more stably held by the electrostatic chuck  214 . 
     &lt;Operations and Effects of Technique According to Second Embodiment&gt; 
     In the substrate support  200  according to the second embodiment, alternating-current voltages having different phases are applied from the attracting power source  217   a  to the first central attracting electrode  216   a   1  and the second central attracting electrode  216   a   2 , respectively. 
     According to the second embodiment, the polarity of the attraction voltage periodically changes, and thus the transfer amount of charges is reset when the polarity changes. Therefore, even in a case where the electrostatic chuck  214  is controlled to a high temperature (for example, 200° C. or more) and the volume resistivity thereof is reduced, an increase in the transfer amount of charges is suppressed, and it is possible to suppress the occurrence of the unstable attraction and holding of the substrate W due to the influence of residual charges or the like. 
     Further, according to the second embodiment, in a case where an alternating-current voltage having a different phase is applied to each of the first central attracting electrode  216   a   1  and the second central attracting electrode  216   a   2 , the total voltage applied to the two attracting electrodes does not become 0 V, and it is possible to suppress the substrate W from being detached from the electrostatic chuck  214  during the plasma processing. 
     Specifically, as described above, the phase difference between the alternating-current voltages to be applied to each of the first central attracting electrode  216   a   1  and the second central attracting electrode  216   a   2  is set to be more than 0 degree and less than 180°, or 30° to 150°, whereby the substrate W can be suppressed from being detached from the electrostatic chuck  214 . 
     Further, according to the present embodiment, in addition to the application of an alternating-current voltage having a different phase to each of the first central attracting electrode  216   a   1  and the second central attracting electrode  216   a   2 , the magnitude of the alternating-current voltages applied from the attracting power source  217   a  to the first central attracting electrode  216   a   1  and the second central attracting electrode  216   a   2  is controlled according to the temperature of the electrostatic chuck  214  as described in the first embodiment, whereby the substrate W can be more stably attracted and detached in the electrostatic chuck  214  during the control to a high temperature. 
     In the embodiment described above, the case where the alternating-current voltage is applied from the attracting power source  217   a  to the first central attracting electrode  216   a   1  and the second central attracting electrode  216   a   2  has been described by way of example; however, as described above, the application of an alternating-current voltage from the attracting power source  217   b  to the first peripheral attracting electrode  216   b   1  and the second peripheral attracting electrode  216   b   2  can also be performed in the same manner. 
     In the embodiment described above, a case where the alternating-current voltage is applied from the attracting power source  217  to the first central attracting electrode  216   a   1 , the second central attracting electrode  216   a   2 , the first peripheral attracting electrode  216   b   1 , and the second peripheral attracting electrode  216   b   2  has been described by way of example; however, the voltage applied to these attracting electrodes is not limited to an alternating-current voltage. 
     For example, the attraction voltage applied to each attracting electrode may be a direct-current voltage whose magnitude periodically changes. Specifically, as illustrated in  FIG.  8   , the following configuration is acceptable: a switching type direct-current power source is used as the attracting power sources  217   a  and  217   b , and the magnitude of the voltage applied to each attracting electrode is periodically switched between a first voltage value and a second voltage value having a different polarity from the first voltage value. In this case, the transfer amount of charges can be reset each time the polarities of the attraction voltages applied to the attracting electrodes are periodically switched. Therefore, even in a case where the volume resistivity is reduced by controlling the electrostatic chuck  214  to a high temperature, the substrate W can be stably attracted and detached. 
     In this case, the phase of an attraction voltage A that is applied to the first central attracting electrode  216   a   1  may be different from the phase of an attraction voltage B that is applied to the second central attracting electrode  216   a   2 . Further, the phase of an attraction voltage A′ that is applied to the first peripheral attracting electrode  216   b   1  may be different from the phase of an attraction voltage B′ that is applied to the second peripheral attracting electrode  216   b   2 . As a result, the total voltage applied to the first central attracting electrode  216   a   1  and the second central attracting electrode  216   a   2  or the total voltage applied to the first peripheral attracting electrode  216   b   1  and the second peripheral attracting electrode  216   b   2  is suppressed from being 0 V, and it is thus possible to suppress the substrate W from being detached from the electrostatic chuck  214  during the plasma processing. 
     In the embodiments described above, a case where the substrate support  200  includes the coulomb-type bipolar electrostatic chuck  214  has been described by way of example, but the substrate support  200  may include three or more attracting electrodes for each temperature control region Z of the electrostatic chuck  214 . Even in this case, in response to applying an attraction voltage whose magnitude periodically changes for each attracting electrode, the substrate W can be stably attracted and detached to and from the electrostatic chuck  214 . Further, in response to applying an attraction voltage having a different phase to each of the attracting electrodes, it is possible to suppress the substrate W from being detached from the electrostatic chuck  214  during the plasma processing. 
     It shall be understood that the embodiments disclosed herein are illustrative and are not restrictive in all aspects. The embodiment described above may be omitted, replaced, or modified in various forms without departing from the scope and spirit of the appended claims.