Patent Publication Number: US-5159003-A

Title: Polyester-compatible alloys of polycarbonate

Description:
FIELD OF THE INVENTION 
     The present invention relates to thermoplastic, compatible alloys of polyester, such as polyethylene terephthalate (PET), and polycarbonate with effective amounts of compatibilization agents therein. 
     BACKGROUND 
     Heretofore, PET and polycarbonates have not been compatible and any blends thereof have contained very small amounts, i.e., less than 10 percent by weight, of one component. 
     U.S. Pat. No. 4,034,016, to Baron et al., relates to ternary polyblends consisting essentially of polybutylene terephthalates, polyurethanes, and aromatic polycarbonates in carefully delineated ranges so that they exhibit solvent stress cracking resistance. 
     U.S. Pat. No. 4,180,494, to Fromuth et al., relates to a high impact and solvent resistant composition comprising (a) about 25 to 95 percent by weight of an aromatic polymer, (b) about 1 to 8 percent by weight of an aromatic polycarbonate, and (c) and balance to make 100 percent of a core-shell polymer having a butadiene-based core. Preferably the composition also includes about 1 to 150 parts by weight of glass fiber reinforcement per 100 parts of (a), (b), and (c). 
     U.S. Pat. No. 4,280,949, to Dieck, relates to a modified thermoplastic polyester composition comprising (a) polybutylene terephthalate, (b) a modifier comprising a combination of an acrylic or methacrylic monomer grafted polymer of a conjugated diene alone or combined with a vinyl aromatic and an aromatic polycarbonate, (c) a mineral filler such as clay, mica, talc, alone or combined with glass fibers, and optionally (d) a flame retardant. 
     U.S. Pat. No. 4,320,212, to Liu, relates to ternary compositions which comprise a mixture of a high molecular weight thermoplastic, an aromatic polycarbonate, an acrylate copolymer, and a thermoplastic polyester. 
     U.S. Pat. No. 4,780,506, to Wefer, relates to high impact strength blends based on polyethylene terephthalate resin, aromatic polycarbonate resin and EPDM grated styrene-acrylonitrile copolymers. 
     U.S. Pat. No. 3,218,372, to Okamura et al., relates to a molding material comprising substantially 95 percent to 5 percent by weight of a polycarbonate derived from 4,4&#39;-dihydroxy-di(mononuclear aryl)alkylene and 5 percent to 95 percent by weight of polyalkylene terephthalate, and the molded articles obtained therefrom. 
     U.S. Pat. No. 3,752,866, to Doerr, relates to a process for the late addition of a polycarbonate to a fiber-forming polyester melt which results in a polyester having a lower level of carboxyl end groups. The improved polyester of this invention exhibits utility in reinforced rubber articles such as industrial belts and pneumatic tire structures. 
     U.S. Pat. No. 3,792,115, to Kishikawa et al., relates to a thermoplastic resin composition of polycarbonate improved in impact strength and heat deformation resistance which comprises 1 percent to 99 percent by weight of polycarbonate resin and 99 percent to 1 percent by weight of polyarylene ester on the basis of the total weight of the composition. 
     U.S. Pat. No. 3,956,229, to Bollen et al., relates to a film or sheet capable of being thermoformed into a shaped article and being formed from a blend of about 60 to 85 parts by weight of a polyethylene terephthalate polymer having an intrinsic viscosity of at least about 0.90 and correspondingly about 40 to 15 parts by weight of a polycarbonate polymer, the polyethylene terephthalate portion of the film or sheet having a degree of crystallinity in the range of about 20 percent to 40 percent. The film is essentially nonoriented. 
     U.S. Pat. No. 3,975,355, to Bollen et al., relates to a film or sheet capable of being thermoformed into a shaped article and being formed from a blend of about 60 to 85 parts by weight of a polyethylene terephthalate having an intrinsic viscosity of at least about 0.90, about 15 to 40 parts by weight of a polycarbonate and about 15 to 20 parts by weight of a nonacidic silica filler, such as novaculite, the polyethylene terephthalate portion of the film or sheet having a degree of crystallinity in the range of about 20 percent to 40 percent. 
     U.S. Pat. No. 4,123,473, to Amin et al., relates to a sheet formed from a uniform blend of from about 80 to 97 percent by weight of polyethylene terephthalate having an intrinsic viscosity of above about 0.9 and a melt viscosity at 525° F. of above about 10,000 poises and correspondingly from about 20 to 3 percent by weight of a polycarbonate resin having an intrinsic viscosity of about 0.4 to 0.6 and a melt viscosity at 500° F. of less than 50,000 poises; said sheet having a haze value as determined by ASTM-D-1003 of less than about 2 percent and being essentially amorphous and nonoriented. 
     U.S. Pat. No. 3,953,394, to Fox et al., relates to thermoplastic, stable, blended compositions comprising a combination of (a) a poly(ethylene terephthalate) resin and (b) a poly(1,4-butylene terephthalate) resin. The alloyed combination of resins can be reinforced with fillers and also rendered flame retardant. 
     U.S. Pat. No. 4,172,859, to Epstein, relates to a toughened multiphase thermoplastic composition consisting essentially of one phase containing 60 to 99 percent by weight of a polyester including polycarbonate matrix resin of inherent viscosity of at least 0.35  deciliter/gram, and 1 to 40 percent by weight of at least one other phase containing particles of at least one random copolymer having a particle size in the range of 0.01 to 3.0 microns and being adhered to the polyester, the at least one random copolymer having a tensile modulus in the range of 1.0 to 20,000 psi, the ratio of the tensile modulus of the polyester matrix resin to tensile modulus of said at least one polymer being greater than 10 to 1. The polymer is either a branched or straight chain polymer. 
     U.S. Pat. No. 4,217,427 to Falk et al., relates to compositions comprising from 70 percent to 95 weight percent polybutylene terephthalate modified by copolymerizing therewith from 30 to 5 weight percent of a diol-terminated polystyrene as pendant chains exhibit marked increase in heat deflection temperature at 264 psi stress, together with an increase in melt flowability. 
     U.S. Pat. No. 4,267,096, to Bussink et al., relates to compositions comprising (a) a selectively hydrogenated elastomeric block copolymer, (b) a polycarbonate and (c) an amorphous polyester. The use of the combination of (a) and (c) provides improvements in the melt flow characteristics, in resistance to brittle failure, and in the resistance to environmental stress crazing and cracking of the polycarbonate resin component (b). 
     SUMMARY OF THE INVENTION 
     The present invention relates to compatible alloys of polyester and polycarbonate containing small but effective amounts of a polyester compatibilization agent as well as a polycarbonate compatibilization agent. Transmission Electron Microscopy (TEM) micrographs of the alloy do not show any apparent phase separation. The amount of the polyester can generally range from about 10 parts to about 90 parts by weight and the amount of the polycarbonate generally ranges from about 90 parts to about 10 parts by weight. Optionally, up to 55 parts by weight of a non-compatible aloy polyester such as polybutylene terephthalate (PBT) can be utilized based upon a total of 100 parts by weight of the compatible polyester and the polycarbonate. The PBT is immiscible in the alloy. The polyester/polycarbonate alloys have excellent impact resistance, high heat deflection temperatures, and stable phase morphologies. 
    
    
     DETAILED DESCRIPTION OF THE INVENTION 
     Compatible alloys of polyesters and polycarbonates are made by heating the polyester and polycarbonate in the presence of a polyester compatibilization agent and a polycarbonate compatibilization agent to a temperature generally at or desirably above the melting point of the polyester, and mixing under moderate to high shear. Optionally, an immiscible or incompatible polymer such as PBT can be utilized in the alloy, but the same forms an immiscible phase therewith. 
     Generally, any polyester can be utilized such as those known to the art and to the literature with the exception of a non-compatible alloy polyester such as PBT. Suitable polyesters for the invention are derived from a dicarboxylic acid, preferably an aromatic dicarboxylic acid, and a diol component, and are characterized in that their intrinsic viscosity is at least 0.4 and preferably at least 0.6 deciliters per gram measured in a 1 percent solution of phenol and tetrachloroethane (60/40) at 25° C. The polyesters are generally made from dicarboxylic acids having from about 2 to 15 carbon atoms and preferably from about 6 to 10 carbon atoms. More than one dicarboxylic acid can be utilized to produce a copolymer. Desirably, aromatic dicarboxylic acids are preferred and an aromatic component accounts for at least 85 mole percent of the total dicarboxylic acid component when two or more dicarboxylic acid monomers are utilized. Suitable aromatic dicarboxylic acids include terephthalic acid, isophthalic acid, naphthalene dicarboxylic acid, diphenylsulfone dicarboxylic acid, diphenoxyethane dicarboxylic acid, or combination thereof. The non-aromatic dicarboxylic acids include hydroxy-carboxylic acids and aliphatic dicarboxylic acids such as caprolactone, succinic acid, adipic acid and sebacic acid. 
     The diol component of the polyesters can be an aliphatic containing from 2 to 10 carbon atoms, preferably from 2 to 4 carbon atoms, or a cycloaliphatic diol having from 6 to 15 carbon atoms, or an aromatic diol having from 6 to 21 carbon atoms, or combinations thereof. Ethylene glycol is preferred. The polyesters can be branched or straight chain. However, as noted above, a non-compatible alloy polyester such as PBT is not utilized to form the compatible polycarbonate/polyester alloy. However, it can optionally be utilized in association therewith. 
     The amount of polyester, such as PET, in the alloy is generally from about 10 to about 90 parts by weight, desirably from about 15 to about 70 parts by weight, and preferably from about 30 to about 60 parts by weight based upon approximately 100 parts by weight of the polyester and the polycarbonate. The preparation of various polyesters is well known in the art and to the literature and the same are commercially available. 
     The polycarbonates of the present invention desirably are aromatic polycarbonates and contain the repetitive carbonate group ##STR1## In the case of aromatic polycarbonates, the following unit is contained in the polymer and is generally attached to the carbonate group: ##STR2## Preferred aromatic polycarbonates generally possess the following reoccurring structural units: ##STR3## wherein Z is a single bond, an alkylene or alkylidene radical with 1 to about 7 carbon atoms, a cycloalkylene or cycloalkylidene radical with 5 to 12 carbon atoms, --O--, --S--, --CO--, --SO--, or --SO2--, and preferably is methylene. A highly preferred polycarbonate includes units derived from bisphenol-A and hence Z is 2-propylidene (i.e. isopropylidene). R 1  and R 2 , independently, are hydrogen, a halogen such as bromine or chlorine, or an alkylene or alkylidene radical having from 1 to 7 carbon atoms; and n or m, independently, is 0 to 4. The aromatic polycarbonates generally have a melt flow rate range of from about 1 to about 24 grams/10 minutes at 300° C. as measured by ASTM D-1238. 
     Examples of aromatic polycarbonates are described in U.S. Pat. No. 4,034,016 to Barron and is hereby fully incorporated by reference. A highly preferred aromatic polycarbonate is the polycarbonate of bis(4-hydroxy-phenyl)-2,2-propane, generally known as bisphenol-A polycarbonate. 
     The polycarbonates utilized in the present invention can optionally be copolymers containing repeating units therein derived from alkyl diol carbonate monomers generally having from 3 to 8 carbon atoms with 3 carbon atoms, e.g. isopropyl, being preferred. The amount of the comonomer repeat units within the polycarbonate copolymer is generally from 1 to about 99 percent by weight and preferably from about 5 to about 85 percent by weight based upon the total weight of the copolymer. 
     Desirably, the aromatic polycarbonates of the present invention have a weight average molecular weight of from about 15,000 to about 100,000, and preferably from about 20,000 to about 50,000. The various polycarbonate homopolymers or copolymers can be straight chain, can contain branched groups therein, or can contain cyclic groups therein. The amount of the polycarbonate is generally from about 10 to about 90 parts by weight, desirably from about 30 to about 85 parts by weight, and preferably from about 40 to about 70 parts by weight based upon approximately 100 parts by weight of the polyester and the polycarbonate. 
     An important aspect of the present invention is the use of a polyester compatibilization agent, i.e., a compound which is compatible with the polyester polymer, as well as a polycarbonate compatibilization agent, i.e., a compound which is compatible with the polycarbonate. Another requirement is that both the polyester compatibilization agent and the polycarbonate compatibilization agent generally have an affinity for and are compatible with each other. 
     The various polycarbonate compatibilization agents are generally multiphase polymer systems containing at least one rubbery polymer phase and at least one thermoplastic phase made from one or more monoethylenically unsaturated monomers. It is to be understood that the polycarbonate compatibilizing multiphase polymer systems can exist in many forms or configurations with a core-shell configuration being desired wherein the shell is often grafted onto a flexible core which is optionally crosslinked. Considering the polycarbonate compatibilization agent, it is generally made from a multiple-stage polymerization in which at least one phase, such as the core, is a rubbery polymer or an elastomer. The amount of the rubber stage can be from about 40 to about 99 percent, desirably from about 50 to about 90 percent, and preferably from about 55 to about 80 percent by weight based upon the total weight of the polyester compatibilization agent. The Tg of the rubbery phase is generally 10° C. or less, and preferably 0° C. or lower. Such rubbery polymers or elastomers can be made from conjugated dienes having from 4 to 16 carbon atoms, desirably from 4 to 8 carbon atoms, such as isoprene, chloroprene, and the like, with polybutadiene being preferred. However, rubbery polymers made from the conjugated dienes are generally not desired. Rather, various alkyl acrylates are preferred wherein the alkyl portion contains from 1 to 12 carbon atoms, desirably from 1 to 8 carbon atoms, with specific examples of alkyl acrylates including methyl acrylate, ethyl acrylate, n-butyl acrylate, and 2-ethyl acrylate with generally ethyl acrylate and n-butyl acrylate being preferred. Other acrylic monomers include arylalkyl esters of acrylic acid wherein the cyclic portion contains 5, 6, or 7 carbon atoms with or without an additional alkyl bridge, and the alkyl portion of the arylalkyl group containing up to 15 carbon atoms may be used; substituted acrylates or methacrylates containing up to 20 carbon atoms including alkylthioalkyl acrylates containing up to 20 carbon atoms such as ethyl thioethyl acrylate, and the like; alkoxyalkyl acrylates such as methoxyethyl acrylate; and the like. Other monomers include acrylamide, methacrylamide and alkyl acrylamides and alkyl methacrylamides, etc., as well as the hydroxyalkyl, haloalkyl, cyanoalkyl, and nitroalkyl derivatives thereof, all of which can contain up to 20 carbon atoms. 
     The one or more thermoplastic phases generally exist in an amount of from about 0 or 1 to about 60 weight percent, desirably from about 10 to about 50 weight percent, and preferably from about 20 to about 45 percent by weight of generally a non-rubbery type phase based upon 100 parts by weight of the polycarbonate compatibilization agent. Such one or more thermoplastic phases are generally made from monoethylenically unsaturated monomers with one such group being the various alkyl, cycloalkyl, etc., methacrylates wherein the alkyl, cycloalkyl, etc., portion has a total of generally from 1 to 15 carbon atoms, preferably from 1 to 8 carbon atoms, with specific examples including methyl methacrylate, butyl methacrylate, t-butyl methacrylate, propyl methacrylate, and the like, with methyl methacrylate being preferred. Another group of monomers are the various vinyl substituted aromatics containing a total of from 8 to 20 carbon atoms such as styrene, alpha-methyl styrene, alpha-halogenated styrene, alkyl styrene, amino styrene, and the like. Still another group of monomers which can be utilized as the one or more thermoplastic phases of the various vinyl cyanide compounds or derivatives thereof containing a total of from about 2 to about 8 carbon atoms such as acrylonitrile, methacrylonitrile, alpha-halogenated acrylonitriles, and the like with acrylonitrile being preferred. 
     Other less desirable monoethylenically unsaturated monomers which can be used to form the one or more remaining thermoplastic phases or, more desirably, as a comonomer with any of the above types of thermo-plastic-forming monomers as in an amount up to about 50 percent by weight and desirably up to about 25 percent by weight of the total weight of the thermoplastic phase monomer, are various other alkyl or aryl methacrylates, various alkyl or aryl acrylates, various alkyl or aryl acrylamides, various substituted alkyl or aryl methacrylates and acrylates such as halogen, alkoxy, alkylthio, cyanoalkyl, amino, alkylthio esters, and the like. Still other types of unsaturated monomers may include various vinyl esters, vinyl ethers, vinyl amides, vinyl ketones, vinyl halides, vinylidene halides, and the like. All of such monomers generally contain up to 20 carbon atoms, and often up to 10 carbon atoms. 
     The multiphase polycarbonate compatibilization agents of the present invention can optionally, but desirably, contain from about 0.1 to about 1.0 percent by weight of at least one polyethylenically unsaturated crosslinking monomer unit and optionally, but desirably, from about 0.1 to about 1.0 percent by weight of a graph-linking monomer unit. Examples of crosslinking monomers include the various polyacrylates and polymethacrylates, and monomers capable of ionic and coordinate crosslinking such as acid groups and organic and inorganic bases and other electron-donating groups coordinating with suitable electrophilic agents. The crosslinked elastomers are referred to as gelled interpolymers to describe that physical characteristic of the polymers. The polyethylenically unsaturated monomers include polyacrylic and polymethacrylic esters of polyols such as butylene diacrylate and dimethacrylate, trimethylolpropane trimethacrylate, and the like, di- and trivinyl benzene, vinyl acrylate and methacrylate and other crosslinking monomers. 
     The graft-linking monomers of the present invention are compounds having two or more additional polymerizable unsaturated reactive groups which participate in the polymerization reaction at substantially different rates, unlike the above-noted crosslinking agents which participate at the same rate. It is preferred to include compounds where at least one reactive group polymerizes at about the same rate, or slightly slower than the other monomers, while the remaining reactive group or groups polymerize at a substantially different, that is, slower, rate. The differential polymerization rates result in a residual level of unsaturation in the elastomeric phase, particularly during the latter stages of polymerization and, consequently, at or near the surface of the elastomer particles. When the rigid thermoplastic phase is subsequently polymerized at the surface of the elastomer, the residual unsaturated additional polymerizable reactive groups contributed by the graft-linking monomer participate in the subsequent reaction so that at least a portion of the following stage or stages, particularly the rigid phase, is chemically attached to the surface of the elastomer. 
     The compounds particularly preferred for use as graft-linking monomers in the present invention are allyl methacrylate and allyl acrylate. Other compounds suitable for use as graft-linking monomers in the present invention include, by way of example, allyl, methallyl, and crotyl esters of acrylic acid, methacrylic acid, maleic acid (mono- and di- esters); fumaric acid (mono- and di- esters) and itaconic acid (mono- and di- esters); allyl, methallyl and crotyl vinyl ether; allyl, methallyl, and crotyl vinyl thioether; N-allyl, methallyl or crotyl maleimide; vinyl esters of 3-butanoic and 4-pentenoic acids; triallyl cyanurate; o-allyl, methallyl, crotyl, o-alkyl, aryl, alkaryl or aralkyl P-vinyl, allyl, or methallyl phosphonate, triallyl, trimethallyl or tricotyl phosphate; O-vinyl, O,O-diallyl, dimethallyl or dicrotyl phosphate, cycloalkenyl esters of acrylic acid, methacrylic acid, maleic acid (mono- or di- esters), fumaric acid (mono- or di- esters), itaconic acid (mono- or di-esters), such as 2; 3; or 4-cyclohexenyl acrylate, bicyclo (2,2,1) hept-5-ene-2-yl esters of acrylic acid, methacrylic acid, maleic acid (mono- or di- esters), fumaric acid (mono- and di- esters) and itaconic acid (mono- or di- esters); vinyl ethers and vinyl thioethers of cycloalkenols and cycloalkene thiols such as vinyl cyclohex-4-ene-1-yl ether, vinyl ether of bicyclo (2,2,1) hept-5-ene-2-ol, vinyl esters of cycloalkene carboxylic acids such as vinyl cyclohex-3-ene-1-carboxylic acid or vinyl bicyclo (2,2,1) hept-5-ene-2-carboxylate, and the like. 
     Among the effective graft-linking monomers, allyl group-containing compounds are preferred, particularly allyl esters of ethylenically unsaturated acids. Most preferred are allyl acrylate, allyl methacrylate, diallyl maleate, diallyl fumarate, diallyl itaconate, allyl acid maleate, allyl acid fumarate, and allyl acid itaconate. Another category of allyl compounds which are highly effective, but not as preferred as the foregoing materials, are the diallyl esters of polycarboxylic acids which do not contain polymerizable unsaturation. Where two or more allyl groups occur in a single compound, one will tend to polymerize with substantially greater ease than another. 
     The various multiphase polycarbonate compatibilization agents can be produced in a conventional manner such as by bulk polymerization, suspension polymerization, bulk-suspension polymerization, solution polymerization, emulsion polymerization, and the like. When a graft copolymer is produced having a major proportion by weight of the rubbery polymer, the emulsion polymerization technique is generally utilized. As noted, the monoethylenically unsaturated monomer preferably forms the shell; but more than one such monomer can be utilized so that the shell is a copolymer. Examples of preferred polycarbonate compatibilization agents include generally a core-type shell multiple phase system wherein the rubbery core is made from n- butyl acrylate or ethyl acrylate and the shell is made from ethyl methacrylate or methyl methacrylate. The polycarbonate compatibilization agent generally is of a small particle size, such as having an average diameter of from about 0.2 to about 5.0 microns, and preferably from about 0.5 to about 2.0 microns. 
     Such multi-stage, generally core-shell polycarbonate compatibilization agents are commercially available from Rohm &amp; Haas as Paraloid EXL-3330, 3386, 3339, and the like. 
     The amount of the polycarbonate compatibilization agent which is utilized is a effective amount which naturally has an affinity for polycarbonate and also for the polyester compatibilization agent. In other words, there is a chemical attraction as well as a chemical compatibility, as for example through hydrogen bonding, between the polycarbonate and the polyester compatibilization agent. Such effective amounts are generally from about 2.5 to about 40 parts by weight and preferably from about 5 to about 25 parts by weight for every 100 total parts by weight of the polycarbonate. 
     Another group of polycarbonate compatibilization agents are generally blends of multiphase systems containing at least one rubbery or elastomeric phase and generally two or more thermoplastic phases in association with a component which effectively increases adhesion of the compatibilization agent with the polycarbonate. Such compatibilization agents generally have a rubbery stage, desirably in the form of a core, which is made from conjugated dienes such as those set forth hereinabove and which are thus hereby fully incorporated by reference, with one or more thermoplastic phases such as a phase made from a monoethylenically unsaturated monomer such as those set forth hereinabove and which are thus fully incorporated by reference, e.g., an alkyl methacrylate, with still another thermoplastic phase such as made from various vinyl substituted aromatic monomers which have been set forth hereinabove and thus fully incorporated by reference, e.g., styrene, alphamethyl styrene, and the like. Such polycarbonate compatibilization agents are generally polyester compatibilization agents set forth hereinbelow and thus fully incorporated by reference and often referred to in the art as MBS-type systems, but contain effective amounts of a potentially reactive polycarbonate adhesive component or promotors in association therewith such that the resultant compatibilization agent mixture, blend, reaction, or combination thereof effectively acts, as a whole, as a polycarbonate compatibilization agent. Thus, the description of the polyester compatibilization agent set forth below is hereby fully incorporated by reference. Such polycarbonate adhesive components can generally be any type of component which has adhesion to the above-noted polycarbonate polymers. A desirable type of polycarbonate adhesive component is an antioxidant or heat stabilizer which is an aliphatic thioester such as ##STR4## wherein R 1  is an alkyl having from 2 to about 40 carbon atoms, desirably from about 10 to about 32 carbon atoms, and preferably 18 carbon atoms, and n is an integer of from 1 to 6, desirably from 1 to 4, and preferably 2. The alkyl groups can be straight, branched, or cyclic. A specific example of such a polycarbonate adhesive component is distearyl thio dipropionate. Such components are known to the art and to the literature and are commercially available. A specific example of such material in combination with a multiphase-type compatibilization agent, e.g., methyl methacrylate, butadiene, and styrene, is Paraloid EXL-3647 made by Rohm &amp; Haas, and the like. 
     Another type of a polycarbonate adhesive component is an antioxidant or heat stabilizer which is an aromatic phenol such as those having the formula ##STR5## wherein R 3  is an alkyl group having from 1 to 18 carbon atoms, desirably from 1 to 10, and preferably 1, and R 2  and R 4 , independently, are alkyl groups, desirably tertiary alkyl groups containing from 4 to 16 carbon atoms and preferably 4 carbon atoms. X is OH, ##STR6## or ##STR7## and the like. Such compounds are known to the art and to the literature and are commercially available. An example of a specific type of a polycarbonate adhesive component is ditertiary butyl hydroxy toluene. A speoific example of such a polycarbonate adhesive agent in association with a multiphase-type compatibilization agent, e.g., methyl methacrylate, butadiene, and styrene, is Paraloid EXL-3691, made by Rohm &amp; Haas. 
     The amount of the polycarbonate adhesive component, as noted above, is an effective amount to cause the generally MBS-type multiphase polymer system to act as a polycarbonate compatibilization agent. Such amounts are generally up to about 6 parts by weight, desirably from about 1 to about 5 parts by weight, and preferably from about 1 to about 3 parts by weight for every 100 parts of the generally MBS-type multiphase polymer system. 
     Examples of various polycarbonate compatibilization agents are set forth in the following Table wherein the abbreviations utilized relate to the following compounds: 
     BA=n-butyl acrylate 
     EA=ethyl acrylate 
     EHA=2-ethylhexyl acrylate 
     BDA=1,3-butylene diacrylate 
     AIMA=allyl methacrylate 
     St=styrene 
     MMA=methyl methacrylate 
     AN=acrylonitrile 
     DALM=diallyl maleate 
     BD=butadiene 
     AA=acrylic acid 
     DMAEMA=dimethylaminoethyl methacrylate 
     HEMA=2-hydroxyethyl methacrylate 
     ETEMA=ethylthioethyl methacrylate 
     ALMA=allyl methacrylate 
     DALM=diallyl maleate 
     MAA=methacrylic acid 
     
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POLYCARBONATE COMPATIBILIZATION AGENTS                                    
NO.                                                                       
   COMPOSITION                MONOMER WEIGHT RATIOS                       
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 1 BA/DBA/AIMA-MMA/AIMA       69.45/0.35/.28//19.95/9.97                  
 2 BA/BDA/DALM-MMA/AIMA       69.45/0.35/.28//19.95/9.97                  
 3 BA/BDA/AIMA-AIHA           89.19/0.45/.36//10.00                       
 4 BA/BDA/AIMA-MMA/AIMA       69.45/0.35/.28//9.97/19.95                  
 5 BA/BDA/AIMA/MMA/DALM       69.45/0.35/.28//19.95/9.97                  
 6 BA/BDA/AIMA-MMA/AIMA/EA    69.45/0.35/.28//17.95/9.97/2.00             
 7 BA/BDA/AIMA-MMA/AIMA       69.45/0.35/.28//19.95/9.97                  
 8 BA/BDA/AIMA-St-MMA/EA      59.48/0.30/.24//18/19.8/2.2                 
 9 BA/BDA/AIMA-St/MMA/EA      59.48/0.30/.24//17.99/19.79/2.2             
10 BA/BDA/AIMA-MMA/EA         59.48/0.30/.24//35.99/4                     
11 BA/BDA/AIMA-MMA/EA         72.61/0.37/.29//24.03/2.7                   
12 BA/St-St-MMA/EA            47/13/18//19.8/2.2                          
13 BA/BDA/DALM-MMA            69.3/0.35/.35//30                           
14 EA/BDA/AIMA-St-MMA/EA      59.47/0.30/.24//18.00-19.80/2.19            
15 BA/BDA/AIMA-St-MMA/EA      59.5/0.30/.24/18-19.8/2.2                   
16 EHA/BDA/AIMA-St-MMA/EA     59.49/0.30/.24//18.00-19.81/2.15            
17 BA/BDA/AIMA-MMA/DALM       69.36/0.35/.28//20/10                       
18 BA/BDA/AIMA-AN/MMA         69.34/0.35/.28//7.5/22.5                    
19 BA/BDA/AIMA-AN/St          69.34/0.35/.28//7.5/22.5                    
20 BA/BDA/AIMA-AIMA-MMA/EA    69.45/0.35/.28//9.97-17.95/2.00             
21 BA/BDA/AIMA-MMA/AA         69.37/0.35/.28//25/5                        
22 BA/BDA/AIMA-MMA/HEMA       69.37/0.35/.28//20/10                       
23 BA/BDA/AIMA-MMA/DMAEMA     69.37/0.35/.28//26.5/3.5                    
24 BA/BDA/AIMA-MMA/MAA        69.37/0.35/.28//26.5/3.5                    
25 BA/S/BDA/ALMA/MMA/AA       57/13/0.35/0.14//28/2                       
26 BA/S/ETEMA/BDA/ALMA/MMA/AA 56.5/13/0.50/0.35/0.14//25/5                
27 BA/S/BDA/ALMA/MMA/MAA      57/13/0.35/0.14//23/7                       
28 BA/S/ETEMA/BDA/DALM//MMA/MAA                                           
                              56.5/13/0.50/0.35/0.14//21/9                
29 BA/S/BDA/ALMA/MMA/MAA/ME   57/13/0.35/0.28//21/9/0.3                   
30 BA/S/BDMA/ALMA/MMA/MAA     40/9.5/0.5/0.35/0.14//35/15                 
31 BA/S/ETEMA/BDA/ALMA//MMA/ALMA//S/AA                                    
                              40/9.5/0.5/0.25/0.10//20/0.10//15/15        
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     The polyester compatibilization agent is also a multiphase polymer system containing an elastomer phase having a low Tg and at least one, but preferably two, thermoplastic phases having a higher Tg made from one or more vinyl monomers. 
     The polyester compatibilization agent is generally utilized in an amount of from about 2.5 to about 40 parts by weight and desirably from about 5 to about 25 parts by weight for every 100 parts by weight of the polyester polymer. As with the polycarbonate compatibilization agent, the polyester compatibilization agent can exist in many forms and configurations with generally a core-shell configuration being desired. The initial phase of the polyester compatibilization is generally one or more phases of a rubbery-type polymer or elastomer with one phase generally being preferred. The one or more elastomer phase is generally made from one or more conjugated diene monomers having from 4 to 12 carbon atoms, desirably from 4 to 6 carbon atoms with specific examples include butadiene, isoprene, hexadiene, and the like, with butadiene being highly preferred. The amount of one or more elastomer phases generally constitutes at least 40 percent by weight, generally from about 50 to about 90 percent by weight, desirably from about 65 to about 85 percent by weight, and preferably from about 70 to about 80 percent by weight based upon the total weight of the multiphase polyester compatibilization agent. 
     The remaining thermoplastic phases of the polyester compatibilization agent are generally made from a vinyl monomer and can be at least one or more phases with two phases made from two different types of vinyl monomers being preferred. The amount of the one or more remaining thermoplastic phases which are generally rigid and made from a vinyl monomer, is usually 60 percent by weight or less, generally from about 10 to about 50 percent by weight, desirably from about 15 to about 35 percent by weight, and preferably from about 20 to about 30 percent by weight. A preferred thermoplastic shell is made from a vinyl substituted aromatic monomer containing a total of from 8 to about 20 carbon atoms, and desirably from about 8 to about 12 carbon atoms with specific examples including alphamethyl styrene, α-halogenated styrene, ortho, para or meta mono-, di-, or tri- substituted styrene monomers wherein the substituent is an amine, an alkyl, an aryl, a ketone, an ether, a hydroxyl, a thio, an aldehyde, a halogen, and the like, with styrene being highly preferred. 
     Another type of preferred thermoplastic shell is made from the various alkyl methacrylate monomers wherein the alkyl portion has from 1 to 18 carbon atoms, preferably from 1 to 8 carbon atoms, such as methyl, ethyl, propyl, butyl, etc., with methyl methacrylate being highly preferred. Still another type of thermoplastic phase is that made from methacrylic acid esters and multi-functional alcohols having a total of up to 15 carbon atoms With specific examples including 1,3-butylene glycol dimethacrylate, trimethylol propane trimethacrylate, 1,3-butylenediacrylate, and the like. 
     Yet another type of thermoplastic phase are the various polymers made from vinyl cyanide monomers and derivatives thereof containing a total of up to 10 carbon atoms. Examples of such monomers are acrylonitrile, methacrylonitrile, alpha-halogen acrylonitrile, and the like. 
     When two or more thermoplastic phases are utilized to form a polyester compatibilization agent, the amount of each thermoplastic phase is generally from about 1 to about 25 percent by weight, desirably from about 5 to about 20 percent by weight, and preferably from about 10 to about 15 percent by weight. A highly preferred polyester compatibilization agent contains an elastomer phase made from butadiene and two thermoplastic phases made from styrene and methyl methacrylate. 
     The various polyester compatibilization agents described hereinabove are known to the art as well as to the literature and are commercially available. Included within such types of polyester compatibilization agents are the MBS-type compatibilization agents inasmuch as one thermoplastic phase or shell is generally an alkyl methacrylate, the rubbery phase is generally a butadiene core, with a remaining thermoplastic phase or shell being made from a vinyl substituted aromatic monomer such as styrene. Such multiphase compatabilization agents can be made by bulk polymerization, suspension polymerization, bulk-suspension polymerization, solution polymerization, or by emulsion polymerization. Often times, the one or more thermoplastic phases is grafted onto the butadiene stage which preferably exists as a rubbery core. In such an embodiment, conventional graft-linking monomers well known to the art and to the literature can be utilized, such as the various allyl esters of ethylenically unsaturated acids such as allyl acrylate, allyl methacrylate, diallyl maleate, diallyl fumarate, and the like. 
     Such polyester compatibilization agents in the form of a core-shell system are commercially available from Rohm &amp; Haas as Paraloid EXL-3607, and the like. 
     The compatible polyester/polycarbonate system of the present invention is a blend and a true alloy since, as noted above, phase separation cannot be detected between the polyester, the polycarbonate, the polyester compatibilization agent, and the polycarbonate compatibilization agent when utilizing TEM electron micrographs at 10,000 through 50,000 X magnification and typically at 25,000 X magnification. Thus, a four-component alloy generally exists. Although it is not fully understood why a miscible alloy is obtained, it is thought that the polyester compatibilization agent and the polycarbonate compatibilization agent generally have high Tg acrylic-rich outer shells, and they adhere to each other and have good adhesion affinity towards polyester and polycarbonate. 
     The compatible polyester/polycarbonate alloys of the present invention can optionally contain small amounts of a non-compatible alloy polyester, as noted above, such as PBT or solely aromatic polyesters, that is, made form solely aromatic dicarboxylic acids and solely aromatic diols. When PBT or the non-compatible alloy polyester is utilized, it forms an immiscible dispersed phase with the compatible alloy. The amount of the optional PBT, etc., is up to about 55 parts by weight and preferably up to about 35 parts by weight based upon 100 parts by weight of the polycarbonate, the PET, and PBT. 
     Various additives known to the art and to the literature can also be utilized in association with the above compatible alloy composition. Depending upon the type and function of additive, typically up to about 30 parts by weight can be utilized per 100 parts by weight of the PET polycarbonate alloy. Useful additives often include various antioxidants such as hindered phenols and/or phosphites; various flame retardants such as antimony oxide; and/or halogenated organic compounds such as dipentaerithritol, tetrabromobisphenol A carbonate oligomer, brominated polystyrene, melamine cyanurate, brominated phenoxy polymers, dioctyl tetrabromo terephthalate, decabromodiphenyloxide, tetrabromobisphenol A, brominated polymeric epoxy, polydibromophenylene oxide, and the like; various UV inhibitors such as hindered amines, substituted hydroxyphenyl benzotriazoles, carbon black, benzophenone, barium metaborate monohydrate, various phenylsalicylates, nickel dibutyl dithiocarbamate, phenylformamidine; various fillers such as clay, talc, silica, and pigments, for example carbon black, titanium dioxide, etc., typically in amounts up to about 50 parts by weight per 100 parts by weight of the polycarbonate and the PET; and the like. 
     Various fibers constitute an important class which can be optionally utilized as reinforcing agents in amounts up to about 60 parts by weight and preferably up to 50 parts by weight per 100 parts by weight of the polycarbonate and the polyester. Typical fibers, which can be chopped or continuous, include glass, carbon, graphite, aromatic nylons such as Kevlar, stainless steel, boron, and the like. The diameter of the various fibers can vary, with a desirable range being from about 4 to about 30 microns and preferably from about 8 to about 11 microns. 
     The compatible PET-polycarbonate alloys of the present invention are generally made by blending all of the various components together in the presence of heat and sufficient shear to achieve compatibilization. That is, all of the various components such as the PET polyester, the polycarbonate homopolymer or copolymer, the PET polyester compatibilization agent, and the polycarbonate compatibilization agent, the optional PBT, as well as any additives and reinforcing fibers are generally added to a suitable mixing device capable of producing moderate to high shear. Examples of specific mixing or blending devices generating sufficient shear to compatibilize the components include a Banbury mixer, a Buss kneader, a single screw extruder, a twin screw extruder, and the like. Suitable shear is generally at least 500 reciprocal seconds or greater, and often 2,000 reciprocal seconds or less. The mixing or blending is done in the presence of sufficient heat such that the PET is melted. Generally, the melting point of the PET will vary with the intrinsic viscosity, but typically is from about 250° C. to about 270° C. Blending is continued for a sufficient period of time such that a fully compatible alloy is produced. Often, the various fibers can be added during the mixing process to ensure that they are not unduly broken. While it is desirable to add all of the various components initially to a mixing device and then heat and blend, it is to be understood that only part of the various components can be added and blended, followed by subsequent addition and blending of the various remaining one or more components. 
     The compatible polyester/polycarbonate alloys of the present invention are thermoplastics and hence can be formed into final products utilizing conventional thermoplastic processing equipment as by extruding, injection molding, blow molding, and the like. The compatible alloys of the present invention have unexpectedly been found to have very good physical properties. Generally, the polycarbonate component has been found to impart good notched Izod impact strength and high heat deflection temperature properties to the compatible alloy, with the various favorable properties of PET such as solvent resistance, UV-resistance, good elongation, and the like, being retained. The compatible PET/polycarbonate alloys of the present invention generally have notched Izod impact properties of 7.0 ft.lb./in. or greater, desirably at least 14.0 or greater, preferably 20.0 or greater, and even greater than 25.0 ft.lb./in. according to ASTM Test No. D-256. It was unexpected that such high impact properties would be obtained when a composition was utilized containing fairly significant amounts of PET. 
     Another notable property is that of heat deflection temperature. Such temperatures tend to be inversely proportional with the amount of co-compatibilizing agents utilized. Generally, heat deflection temperatures of at least 65° C., desirably at least 75° C., and preferably from about 80° to about 90° C. at 264 psi are readily obtained. 
     Still another advantage of the compatible PET/polycarbonate alloys of the present invention is that they have good paint adhesion, generally requiring no primer, and have good solvent and chemical resistance. 
     In view of the thermoplastic nature of the alloys and their physical properties, they can be utilized as exterior body panels on various vehicles such as automobiles, for bumpers and bumper guards of various vehicles, in various sporting goods such as ski boots, and the like. 
     The invention will be better understood by reference to the following examples. 
     EXPERIMENTS 
     The following examples illustrate the invention wherein the percentages are by weight unless indicated. 
     The polycarbonate polyester alloys were prepared as follows: 
     The dried polycarbonate and/or polyester and the compatibilization agents were premixed by tumbling in a polyethylene bag before melt processing. The mixtures were then blended in either twin screw extruder, single screw extruder, or a continuous processor. The injection-molded samples of these alloys were then tested using the following test procedures in the dry-as-molded state: 
     
         ______________________________________                                    
Notched Izod Toughness                                                    
               ASTM D256                                                  
Tensile Strength                                                          
               ASTM D638                                                  
Elongation to Break                                                       
               ASTM D638                                                  
Flexural Modulus                                                          
               ASTM D790                                                  
Flexural Strength                                                         
               ASTM D790                                                  
Melt Flow      ASTM D-1238-73 Condition G                                 
Particle Size  Transmission Electron Microscopy                           
               of very thin microtome slice                               
Heat Deflection                                                           
               ASTM D648-82                                               
Temperature    (at 264 psi)                                               
Mold Shrinkage ASTM D 955                                                 
Gardner Impact ASTM D 3029                                                
______________________________________                                    
CHEMICAL DESCRIPTION OF COMPATIBILIZING                                   
AGENTS (APPROXIMATE AMOUNTS - MOLE PERCENT)                               
______________________________________                                    
POLYCARBONATE                                                             
Paraloid                                                                  
EXL-3330 67.5 MMA; 35 BA                                                  
EXL-3386 59 MMA; 41 BA                                                    
EXL-3339 67.5 MMA; 35 BA                                                  
EXL-3647 14.2 MMA; 78.4 BD; 14.2 STYRENE;                                 
2.3 WEIGHT PERCENT DISTEARYL THIO                                         
DIPROPIONATE                                                              
EXL-3691 12.5 MMA; 77.4 BD; 10.1 STYRENE;                                 
1.6 WEIGHT PERCENT DITERTYL BUTYL HYDROXY                                 
TOLUENE                                                                   
POLYESTER                                                                 
Paraloid                                                                  
EXL-3607; 13.2 MMA; 75.5 BD; 11.2 Styrene                                 
______________________________________                                    
 
    
     PROCESSING EQUIPMENT UTILIZED IN EXAMPLES 
     Single Screw Extruder 
     Berlyn 21/2&#34;, 30:1 L/D with vacuum vent high mixing screw design. 
     Twin Screw Extruder 
     Leistritz 34 mm, 28:1 L/D with counter-rotating intermeshing and with vacuum venting capability. 
     Twin Screw Extruder 
     Werner-Pfleiderer, 30 mm, 42:1 L/D, with corotating intermeshing and with vacuum venting capability. 
     Twin Screw Extruder 
     Welding Engineer, 30 mm, 42:1 L/D, with counter-rotating non-intermeshing and with vacuum venting capability. 
     Continuous Mixer 
     Farrel Continuous Mixer, CP-23, with vacuum venting capability. 
     Buss Kneader 
     46 mm, 20:1 L/D with vacuum venting capability. 
     Processing Shear Rate Range 
     500 to 2,000 sec. -1   
     Processing Temperature Range 
     490° F. to 470° F. 
     EXPERIMENT 1 
     The alloys of PET (IV=0.95) with polycarbonate (Examples 1 through 6 of Table I) were prepared by melt blending utilizing a counter-rotating twin screw extruder at 490° F. to 530° F. melting temperature. The alloys of PET (IV-0.95) with polycarbonate using EXL-3647 as a compatibilization agent for polycarbonate and EXL-3607 as a compatibilizing agent for PET which has higher acrylic outer shell content and which has affinity to polycarbonate were melt-mixed. As apparent from Table I, alloys which contain both the PET compatibilization agent as well as the polycarbonate compatibilization agent had an unexpected increase in the notched Izod properties inasmuch as a factor of at least approximately 3 was obtained. 
     EXPERIMENT 2 
     The alloys of PET (IV-0.95) with polycarbonate were prepared by melt-blending utilizing a counter-rotating twin screw extruder at 490° F. to 530° F. melting temperature. In this example, EXL-3691 was used as a compatibilization agent for polycarbonate and EXL-3607 as a compatibilization agent for PET in all of the six examples of Table II. Moreover, EXL-3647 was utilized as a PET co-compatibilization agent in Examples 4, 5 and 6. 
     As apparent from Table II, when no polyester compatibilization agent was utilized, as in Example 1, poor notched Izod impact properties were obtained. However, in Examples 2 and 3 wherein a PET compatibilization agent as well as a polycarbonate compatibilization was utilized, unexpected and dramatic improvements in the notched Izod impact properties were obtained. Again, in Examples 4, 5 and 6 wherein two different types of polycarbonate compatibilization agents were utilized, but no polyester compatibilization agents, once again poor notched Izod impact properties were obtained. 
     EXPERIMENT 3 
     Example 1 of Table III was prepared using PET (IV=0.95) with polycarbonate utilizing FCM-CP-23, whereas Example 2 utilized the single screw extruder. Example 3 of Table III was also prepared utilizing an FCM-CP-23 with a PET having an IV of 0.65. Examples 4, 5, and 6 of Table III were made utilizing a single screw extruder as in Example 2, but utilizing reground PET having an IV of 0.75 (bottle grade). All of the alloys were made in a manner similar to Experiment 1. 
     As apparent from Table III, the alloy made utilizing a single screw extruder provided a very high notched Izod impact value. Although Examples 3 through 6 utilized PET with lower IV&#39;s, high notched Izod impact values were still obtained. 
     EXPERIMENT 4 
     Various alloys of polycarbonate and PET (IV=0.95) were prepared as set forth in Table IV in a manner similar to Example 1. In Table IV, the amounts of the PET compatibilization agent as well as the polycarbonate compatibilization agent were varied. As apparent from Table IV, when the amount of both the PET compatibilization agent and the polycarbonate compatibilization agent were reduced to low levels, poor notched Izod impact properties were obtained, i.e. Examples 4 and 5. Although the amount of such agents were also reduced in Example 3, a major amount of polycarbonate existed such that a high notched Izod impact value was nevertheless still obtained. 
     EXPERIMENT 5 
     Table V relates to various alloys of PET (IV=0.95) with polycarbonate prepared utilizing a counter-rotating twin screw extruder at conditions similar to Experiment 1. 
     EXPERIMENT 6 
     The alloys set forth in Table VI relate to compatible blends of PET (IV=0.95) with polycarbonate which were prepared in a co-rotating twin screw extruder at 490° F. to 540° F. in a manner similar to Experiment 1. As apparent from Table VI, good notched Izod impact properties as well as good heat deflection temperature properties were obtained when the concentration of PET and polycarbonate were varied from 15 percent to 70 percent by weight. 
     EXPERIMENT 7 
     Table VII relates to alloys of PET (IV=0.95) with polycarbonate as well as various amounts of PBT. The alloys were prepared utilizing a co-rotating twin screw extruder at temperatures of 490° F. to 540° F. in a manner similar to Experiment 1. The amounts of the pET in polycarbonate were varied as was the amount of the PBT. As apparent from Table VII, good notched Izod properties were obtained although the heat deflection temperatures were not as good as those set forth in Table VI. The PBT existed as a separate phase within the compatible homogeneous phase of the PET-Polycarbonate alloy. 
     EXPERIMENT 8 
     Table VIII sets forth one example of an alloy of PET and PBT (RV=1.1) blended with polycarbonate. Inasmuch as the PET compatibilization agent EXL-3607 was not as good a compatibilization agent with respect to PBT, a true alloy was not obtained, but rather a blend containing phase separation therein. Moreover, as apparent from the data in Table VIII, low notched Izod impact properties as well as heat deflection properties were obtained in comparison with the examples of Table VII. 
     The alloys of Tables I through vI resulted in a homogeneous PET-polycarbonate alloy inasmuch as no microphase separation of PET and polycarbonate were detected by TEM MICROGRAPHS. 
     
                                           TABLE I                                 
__________________________________________________________________________
                          1     2     3     4      5     6                
__________________________________________________________________________
PET (wt. %)               45    60    45    60     45    45               
COMPATABILIZATION AGENT (PARALOID)                                        
                          EXL-3607                                        
                                EXL-3607                                  
                                      EXL-3607                            
                                            EXL-3607                      
                                                   EXL-3607               
                                                         EXL-3607         
COMPATABILIZATION AGENT (wt. %)                                           
                          15    20    15    20     7.5   5                
POLYCARBONATE (wt. %)     40    20    40    20     40    40               
POLYCARBONATE COMPATIBILIZATION                                           
                          --    --    --    --     EXL-3647               
                                                         EXL-3647         
AGENT (PARALOID)                                                          
POLYCARBONATE COMPATIBILIZATION                                           
                          --    --    --    --     7.5   10               
AGENT (wt. %)                                                             
PROPERTIES:                                                               
TENSILE STRENGTH (psi)    4500  5100  6400  5300   6300  6500             
ELONGATION TO YIELD (%)   --    5.6   6.3   5.5    6.1   5.8              
ELONGATION TO BREAK (%)   11.5  25.9  204   251    210   235              
FLEXURAL STRENGTH (psi)   10800 9200  11300 9500   1200  11700            
FLEXURAL MODULUS (kpsi)   287   256   291   274    301   309              
NOTCHED IZOD IMPACT (1/8&#34;)                                                
AT 73° F. (ft. lb/in)                                              
                          2.9   2.4   4.7   3.1    13.2  13.2             
AT -40° F. (ft. lb/in)                                             
                          --    --    1.8   --     3.4   2.3              
GARDNER IMPACT (1/8&#34;)                                                     
AT 73° F. (in. lb) 3     24    &gt;320  &gt;320   316   &gt;320             
AT -40° F. (in. lb)                                                
                          --    --    305   13     314   53               
HEAT DEFLECTION TEMPERATURE                                               
                          76    73    73    70     76    82               
AT 264 psi (°C.)                                                   
__________________________________________________________________________
 
    
     
                                           TABLE II                                
__________________________________________________________________________
                          1     2     3     4      5     6                
__________________________________________________________________________
PET (wt. %)               45    45    45    45     45    45               
COMPATABILIZATION AGENT (PARALOID)                                        
                          --    EXL-3607                                  
                                      EXL-3607                            
                                            --     --    --               
COMPATABILIZATION AGENT (wt. %)                                           
                          --    7.5   10    --     --    --               
POLYCARBONATE (wt. %)     40    40    40    40     40    40               
POLYCARBONATE COMPATIBILIZATION                                           
                          EXL-3691                                        
                                EXL-3691                                  
                                      EXL-3691                            
                                            EXL-3691                      
                                                   EXL-3691               
                                                         EXL-3691         
AGENT (PARALOID)                                                          
POLYCARBONATE COMPATIBILIZATION                                           
                          15    7.5   5     7.5    10    5                
AGENT (wt. %)                                                             
POLYCARBONATE COMPATIBILIZATION                                           
                          --    --    --    EXL-3647                      
                                                   EXL-3647               
                                                         EXL-3647         
AGENT (Paraolid)                                                          
POLYCARBONATE COMPATIBILIZATION                                           
                          --    --    --    7.5    5     10               
AGENT (wt. %)                                                             
PROPERTIES:                                                               
TENSILE STRENGTH (psi)    5500  6700  6400  6200   5900  6400             
ELONGATION TO YIELD (%)   --    6.5   6.7   6.9    6.8   --               
ELONGATION TO BREAK (%)   5.3   179   193   20.3   13.4  6.9              
FLEXURAL STRENGTH (psi)   10200 11800 11400 12000  11900 12400            
FLEXURAL MODULUS (kpsi)   274   303   298   307    298   308              
NOTCHED IZOD IMPACT (1/8&#34;)                                                
AT 73° F. (ft. lb/in)                                              
                          0.3   23.9  15.4  1.5    1.2   0.2              
AT -40° F. (ft. lb/in)                                             
                          --    4.1   3.4   --     --    --               
GARDNER IMPACT (1/8&#34;)                                                     
AT 73° F. (in. lb) 3     &gt;320  &gt;320  3      3     &lt;2               
AT -40° F. (in. lb)                                                
                          --    145   301   --     --    --               
HEAT DEFLECTION TEMPERATURE                                               
                          72    78    78    81     83    81               
AT 264 psi (°C.)                                                   
__________________________________________________________________________
 
    
     
                                           TABLE III                               
__________________________________________________________________________
                          1     2     3     4      5     6                
__________________________________________________________________________
PET (wt. %)               45    45    45    45     45    45               
COMPATABILIZATION AGENT (PARALOID)                                        
                          EXL-3607                                        
                                EXL-3607                                  
                                      EXL-3607                            
                                            EXL-3607                      
                                                   EXL-3607               
                                                         EXL-3607         
COMPATABILIZATION AGENT (wt. %)                                           
                          7.5   7.5   7.5   7.5    7.5   7.5              
POLYCARBONATE (wt. %)     40    40    40    40     40    40               
POLYCARBONATE COMPATIBILIZATION                                           
                          EXL-3647                                        
                                EXL-3647                                  
                                      EXL-3647                            
                                            EXL-3647                      
                                                   EXL-3647               
                                                         EXL-3647         
AGENT (PARALOID)                                                          
POLYCARBONATE COMPATIBILIZATION                                           
                          7.5   7.5   7.5   7.5    7.5   10.0             
AGENT (wt. %)                                                             
PROPERTIES:                                                               
TENSILE STRENGTH (psi)    7844  6754  6686  7000   7205  7340             
ELONGATION TO YIELD (%)   186   5.7   53    5.1    5.4   5.3              
ELONGATION TO BREAK (%)   187   94.6  100.6 13.0   22.8  22.2             
FLEXURAL STRENGTH (psi)   10040 9830  9880  10700  10500 10990            
FLEXURAL MODULUS (kpsi)   292   286   284   293    292   296              
NOTCHED IZOD IMPACT (1/8&#34;)                                                
AT 73° F. (ft. lb/in)                                              
                          12.4  &gt;25   10.9  9.1    9.1   9.6              
AT -40° F. (ft. lb/in)                                             
                          3.4   9.1   3.3   2.04   2.27  2.1              
GARDNER IMPACT (1/8&#34;)                                                     
AT 73° F. (in. lb) &gt;320  &gt;320  &gt;320  &gt;320   &gt;320  &gt;320             
AT -40° F. (in. lb)                                                
                          &gt;320  &gt;320  &gt;320  50     16    10               
HEAT DEFLECTION TEMPERATURE                                               
                          74    74    74    74     78    76               
AT 264 psi (°C.)                                                   
__________________________________________________________________________
 
    
     
                                           TABLE IV                                
__________________________________________________________________________
                          1     2     3     4      5     6                
__________________________________________________________________________
PET (wt. %)               40    42.35 44.7  52     50.3  47.65            
COMPATABILIZATION AGENT (PARALOID)                                        
                          EXL-3607                                        
                                EXL-3607                                  
                                      EXL-3607                            
                                            EXL-3607                      
                                                   EXL-3607               
                                                         EXL-3607         
COMPATABILIZATION AGENT (wt. %)                                           
                          7.5   5.0   2.5   1.0    2.5   5.0              
POLYCARBONATE (wt. %)     45    47.65 50.3  46     44.7  42.35            
POLYCARBONATE COMPATIBILIZATION                                           
                          EXL-3647                                        
                                EXL-3647                                  
                                      EXL-3647                            
                                            EXL-3647                      
                                                   EXL-3647               
                                                         EXL-3647         
AGENT (PARALOID)                                                          
POLYCARBONATE COMPATIBILIZATION                                           
                          7.5   5.0   2.5   1.0    2.5   5.0              
AGENT (wt. %)                                                             
PROPERTIES:                                                               
TENSILE STRENGTH (psi)    7808  8593  8859  8857   8967  8212             
ELONGATION TO YIELD (%)   195.8 204.1 151.9 190    235   225              
ELONGATION TO BREAK (%)   196.8 207.3 174.4 192    238   227              
FLEXURAL STRENGTH (psi)   10330 11500 12620 13360  12510 10980            
FLEXURAL MODULUS (kpsi)   280   310   336   357    335   304              
NOTCHED IZOD IMPACT (1/8&#34;)                                                
AT 73° F. (ft. lb/in)                                              
                          11.3  11.2  10.3  1.48   1.34  13.8             
AT -40° F. (ft. lb/in)                                             
                          5.2   2.1   1.3   1.4    1.30  1.7              
GARDNER IMPACT (1/8&#34;)                                                     
AT 73° F. (in. lb) &gt;320  &gt;320  &gt;320  &gt;320   &gt;320  &gt;320             
AT -40° F. (in. lb)                                                
                          &gt;320  &gt;320  &gt;320  &gt; 320  &gt;320  &gt;320             
HEAT DEFLECTION TEMPERATURE                                               
                          83    89    95    83.0   80.5  80.0             
AT 264 psi (°C.)                                                   
__________________________________________________________________________
 
    
     
                                           TABLE V                                 
__________________________________________________________________________
                                1     2     3     4                       
__________________________________________________________________________
PET (wt. %)                     45    45    45    45                      
COMPATABILIZATION AGENT (PARALOID)                                        
                                EXL-3647                                  
                                      EXL-3647                            
                                            EXL-3607                      
                                                  EXL-3607                
COMPATABILIZATION AGENT (wt. %) 5     7.5   5     7.5                     
POLYCARBONATE (wt. %)           40    40    40    40                      
POLYCARBONATE COMPATIBILIZATION AGENT                                     
                                EXL-3339                                  
                                      EXL-3339                            
                                            EXL-3339                      
                                                  EXL-3339                
(PARALOID)                                                                
POLYCARBONATE COMPATIBILIZATION AGENT (wt. %)                             
                                10    7.5   10    7.5                     
PROPERTIES:                                                               
TENSILE STRENGTH (psi)          5261  6541  6506  6859                    
ELONGATION TO YIELD (%)         5.7   10.4  10.9  10.4                    
ELONGATION TO BREAK (%)         23    65.7  170.1 285.8                   
FLEXURAL STRENGTH (psi)         11760 11290 11130 11250                   
FLEXURAL MODULUS (kpsi)         326   301   301   310                     
NOTCHED IZOD IMPACT (1/8&#34;)                                                
AT 73° F. (ft. lb/in)    17.1  11.36 14.0  14.3                    
AT -40° F. (ft. lb/in)   1.0   1.01  2.03  1.79                    
GARDNER IMPACT (1/8&#34;)                                                     
AT 73° F. (in. lb)       &gt;320  &gt;320  &gt;320  &gt;320                    
AT -40° F. (in. lb)      &gt;320  &gt;320  &gt;320  &gt;320                    
HEAT DEFLECTION TEMPERATURE     80    81    72    73                      
AT 264 psi (°C.)                                                   
__________________________________________________________________________
 
    
     
                                           TABLE VI                                
__________________________________________________________________________
                          1     2     3     4      5     6*               
__________________________________________________________________________
PET (wt. %)               70    65    60    55     50    45               
COMPATABILIZATION AGENT (PARALOID)                                        
                          EXL-3607                                        
                                EXL-3607                                  
                                      EXL-3607                            
                                            EXL-3607                      
                                                   EXL-3607               
                                                         EXL-3607         
COMPATABILIZATION AGENT (wt. %)                                           
                          7.5   7.5   7.5   7.5    7.5   7.5              
POLYCARBONATE (wt. %)     15    20    25    30     35    40               
POLYCARBONATE COMPATIBILIZATION                                           
                          EXL-3647                                        
                                EXL-3647                                  
                                      EXL-3647                            
                                            EXL-3647                      
                                                   EXL-3647               
                                                         EXL-3647         
AGENT (PARALOID)                                                          
POLYCARBONATE COMPATIBILIZATION                                           
                          7.5   7.5   7.5   7.5    7.5   7.5              
AGENT (wt. %)                                                             
PROPERTIES:                                                               
TENSILE STRENGTH (psi)    6453  6550  6902  6768   6885  7034             
ELONGATION TO YIELD (%)   9.0   9.6   9.7   9.4    9.5   9.9              
ELONGATION TO BREAK (%)   526   468   387   317    367   327              
FLEXURAL STRENGTH (psi)   10720 11220 11730 11410  11580 11710            
FLEXURAL MODULUS (kpsi)   307   324   348   330    318   323              
NOTCHED IZOD IMPACT (1/8&#34;)                                                
AT 73° F. (ft. lb/in)                                              
                          24.3  25.2  26.2  22.0   25.7  25.4             
AT -40° F. (ft. lb/in)                                             
                          1.1   1.1   1.1   5.2    3.6   4.2              
GARDNER IMPACT (1/8&#34;)                                                     
AT 73° F. (in. lb) &gt;320  &gt;320  &gt;320  &gt;320   &gt;320  &gt;320             
AT -40° F. (in. lb)                                                
                          3.5   --    --    &gt;320   &gt;320  &gt;320             
HEAT DEFLECTION TEMPERATURE                                               
                          74    75    75.5  76.5   74    79.5             
AT 264 psi (°C.)                                                   
__________________________________________________________________________
                           7     8     9     10    11    12               
__________________________________________________________________________
PET (wt. %)                40    35    30    25    20    15               
COMPATABILIZATION AGENT (PARALOID)                                        
                           EXL-3607                                       
                                 EXL-3607                                 
                                       EXL-3607                           
                                             EXL-3607                     
                                                   EXL-3607               
                                                         EXL-3607         
COMPATABILIZATION AGENT (wt. %)                                           
                           7.5   7.5   7.5   7.5   7.5   7.5              
POLYCARBONATE (wt. %)      45    50    55    60    65    70               
POLYCARBONATE COMPATIBILIZATION                                           
                           EXL-3647                                       
                                 EXL-3647                                 
                                       EXL-3647                           
                                             EXL-3647                     
                                                   EXL-3647               
                                                         EXL-3647         
AGENT (PARALOID)                                                          
POLYCARBONATE COMPATIBILIZATION                                           
                           7.5   7.5   7.5   7.5   7.5   7.5              
AGENT (wt. %)                                                             
PROPERTIES:                                                               
TENSILE STRENGTH (psi)     7366  7491  7631  7702  7866  7434             
ELONGATION TO YIELD (%)    10.2  9.7   9.9   10.1  10.4  10.7             
ELONGATION TO BREAK (%)    291   149   223   200   182   192              
FLEXURAL STRENGTH (psi)    12150 13270 12840 13520 13530 13020            
FLEXURAL MODULUS (kpsi)    336   370   350   363   369   346              
NOTCHED IZOD IMPACT (1/8&#34;)                                                
AT 73° F. (ft. lb/in)                                              
                           20.8  11.6  14.4  13.4  12.2  10.4             
AT -40° F. (ft. lb/in)                                             
                           4.7   2.0   5.8   5.2   7.9   7.6              
GARDNER IMPACT (1/8&#34;)                                                     
AT 73° F. (in. lb)  &gt;320  &gt;320  &gt;320  &gt;320  &gt;320  &gt;320             
AT -40° F. (in. lb) &gt; 320 &gt;320  &gt;320  &gt;320  &gt;320  &gt;320             
HEAT DEFLECTION TEMPERATURE                                               
                           86    87    88    95.5  99    95.5             
AT 264 psi (°C.)                                                   
__________________________________________________________________________
 *Control Formulation                                                     
 
    
     
                                           TABLE VII                               
__________________________________________________________________________
                          1     2     3     4      5     6*               
__________________________________________________________________________
PET (wt. %)               35    32.5  30    27.5   25    22.5             
COMPATABILIZATION AGENT (PARALOID)                                        
                          EXL-3607                                        
                                EXL-3607                                  
                                      EXL-3607                            
                                            EXL-3607                      
                                                   EXL-3607               
                                                         EXL-3607         
COMPATABILIZATION AGENT (wt. %)                                           
                          7.5   7.5   7.5   7.5    7.5   7.5              
POLYCARBONATE (wt. %)     15    20    25    30     35    40               
POLYCARBONATE COMPATIBILIZATION                                           
                          EXL-3647                                        
                                EXL-3647                                  
                                      EXL-3647                            
                                            EXL-3647                      
                                                   EXL-3647               
                                                         EXL-3647         
AGENT (PARALOID)                                                          
POLYCARBONATE COMPATIBILIZATION                                           
                          7.5   7.5   7.5   7.5    7.5   7.5              
AGENT (wt. %)                                                             
PBT (wt %)                35    32.5  30    27.5   25    22.5             
PROPERTIES:                                                               
TENSILE STRENGTH (psi)    5858  5537  5353  5833   6349  6443             
ELONGATION TO YIELD (%)   5.1   4.9   4.8   5.6    6.3   6.5              
ELONGATION TO BREAK (%)   548   530   633   528    482   413              
FLEXURAL STRENGTH (psi)   9738  9364  9071  1070   10490 10720            
FLEXURAL MODULUS (kpsi)   281   279   279   292    293   295              
NOTCHED IZOD IMPACT (1/8&#34;)                                                
AT 73° F. (ft. lb/in)                                              
                          22.3  22.2  20.64 25.0   25.0  19.9             
AT -40° F. (ft. lb/in)                                             
                          20    12.7  7.28  19.0   20.0  13.0             
GARDNER IMPACT (1/8&#34;)                                                     
AT 73° F. (in. lb) &gt;320  &gt;320  &gt;320  &gt;320   &gt;320  &gt;320             
AT -40° F. (in. lb)                                                
                          &gt;320  316   316   313    &gt;320  &gt;320             
HEAT DEFLECTION TEMPERATURE                                               
                          69.5  68.5  59    63     64    68.5             
AT 264 psi (°C.)                                                   
__________________________________________________________________________
                           7     8     9     10    11    12               
__________________________________________________________________________
PET (wt. %)                20    17.5  15    12.5  10.0  7.5              
COMPATABILIZATION AGENT (PARALOID)                                        
                           EXL-3607                                       
                                 EXL-3607                                 
                                       EXL-3607                           
                                             EXL-3607                     
                                                   EXL-3607               
                                                         EXL-3607         
COMPATABILIZATION AGENT (wt. %)                                           
                           7.5   7.5   7.5   7.5   7.5   7.5              
POLYCARBONATE (wt. %)      45    50    55    60    65    70               
POLYCARBONATE COMPATIBILIZATION                                           
                           EXL-3647                                       
                                 EXL-3647                                 
                                       EXL-3647                           
                                             EXL-3647                     
                                                   EXL-3647               
                                                         EXL-3647         
AGENT (PARALOID)                                                          
POLYCARBONATE COMPATIBILIZATION                                           
                           7.5   7.5   7.5   7.5   7.5   7.5              
AGENT (wt. %)                                                             
PBT (wt %)                 20    17.5  15    12.5  10.0  7.5              
PROPERTIES:                                                               
TENSILE STRENGTH (psi)     7052  6850  7154  7088  7101  7192             
ELONGATION TO YIELD (%)    6.7   6.6   7.0   7.2   7.6   8.0              
ELONGATION TO BREAK (%)    254   186   227   211   195   62.8             
FLEXURAL STRENGTH (psi)    11210 11400 11870 12000 12180 12530            
FLEXURAL MODULUS (kpsi)    302   303   317   315   313   308              
NOTCHED IZOD IMPACT (1/8&#34;)                                                
AT 73° F. (ft. lb/in)                                              
                           14.7  13.83 13.3  11.1  9.7   8.5              
AT 40° F. (ft. lb/in)                                              
                           3.2   1.2   8.41  1.7   3.5   3.9              
GARDNER IMPACT (1/8&#34;)                                                     
AT 73° F. (in. lb)  &gt;320  &gt;320  &gt; 320 &gt;320  &gt;320  &gt;320             
AT -40° F. (in. lb) 167   &gt;320  &gt;320  316   &gt;320  100              
HEAT DEFLECTION TEMPERATURE                                               
                           76.5  73    82    89    93    94.5             
AT 264 psi (°C.)                                                   
__________________________________________________________________________
 *Control Formulation                                                     
 
    
     
                       TABLE VIII                                                  
______________________________________                                    
                         1                                                
______________________________________                                    
PBT (wt. %)                45                                             
COMPATABILIZATION AGENT (PARALOID)                                        
                           EXL-3607                                       
COMPATABILIZATION AGENT (wt. %)                                           
                           7.5                                            
POLYCARBONATE (wt. %)      40                                             
POLYCARBONATE COMPATIBILIZATION                                           
                           EXL-3647                                       
AGENT (PARALOID)                                                          
POLYCARBONATE COMPATIBILIZATION                                           
                           7.5                                            
AGENT (wt. %)                                                             
PROPERTIES:                                                               
TENSILE STRENGTH (psi)     6120                                           
ELONGATION TO YIELD (%)    8.4                                            
ELONGATION TO BREAK (%)    344                                            
FLEXURAL STRENGTH (psi)    9885                                           
FLEXURAL MODULUS (kpsi)    285                                            
NOTCHED IZOD IMPACT (1/8&#34;)                                                
AT 73° F. (ft. lb/in)                                              
                           2.4                                            
AT 40° F. (ft. lb/in)                                              
                           1.9                                            
GARDNER IMPACT (1/8&#34;)                                                     
AT 73° F. (in. lb)  &gt;320                                           
AT -40° F. (in. lb) &gt;320                                           
HEAT DEFLECTION TEMPERATURE                                               
                           58                                             
AT 264 psi (°C.)                                                   
______________________________________                                    
 
    
     While in accordance with the Patent Statutes, the best mode and preferred embodiment has been set forth, the scope of the invention is not limited thereto, but rather by the scope of the attached claims.