Patent Publication Number: US-4369719-A

Title: Vermiculite as a deposit modifier in coal fired boilers

Description:
Use of the present invention facilitates removal of deposits that form on the walls and heat-exchange surfaces in an industrial furnace or utility boiler burning coal. This is accomplished by injecting uncalcined vermiculite into the flue gas stream where the stream has a temperature of about 3000° F. to 1200° F., at a rate of 0.05 to 10.0 pounds of vermiculite (preferably 1-3 lbs.) per short ton of coal burned. The vermiculite increases the friability of the deposits, making them easier to remove by conventional soot blowers (i.e., probes located within the boiler blowing in air or steam at about 200 psig.) 
     The mineral matter (ash) in coal leads to deposits in the heat absorbing regions of the boiler, particularly the superheater and convection passes. These sintered fly ash deposits can be stronger than the potential of conventional cleaning equipment. We have discovered that the injection of vermiculite will reduce the strength of deposits in order to maintain clean heat exchange surfaces and prevent the eventual blockage of these passages. 
     Vermiculite, a natural occurring mineral, expands 15-20 times its original volume when exposed to temperatures in excess of approximately 1200° F. This greatly reduces the strength of sintered (bonded) deposits in which vermiculite is present. In the past, the chemical and physical properties of materials such as magnesium oxide, alumina, etc., have been employed to interfere with sintered deposits. Vermiculite is superior to these additives. 
     Vermiculite, a hydrated magnesium-aluminum-iron silicate, consists of 14 closely related micaceous minerals. When unexfoliated vermiculite is applied in such a manner as to be incorporated in the ash deposit and subjected to temperatures in the range encountered in superheater and convection regions, a dramatic reduction in the strength of the bonded deposit is evident. The unique properties which account for this activity include thermally induced exfoliation (expansion) and the presence of a naturally occurring platelet structure (silica sheets) which acts as a cleave plane. Deposits can be removed with greater ease as a result of this treatment. 
    
    
     EXAMPLE I 
     The boiler has a 347 megawatt design capacity. It is cyclone fired and burns Eastern bituminous c coal. It is equipped with soot blowers. Unexpanded vermiculite is blown into the furnace at 2600° F. at the rate of 0.6-0.8 lbs./ton of coal. The additive causes the in-line deposits to be relatively friable and readily removed by the soot blowers at 200 psig. 
     In contrast, in a comparable run but omitting the vermiculite, the deposits are hard, sintered, and bonded, making them difficult to loosen and dislodge with the steam probes. 
     We prefer that the vermiculite be relatively finely divided, e.g., mostly 3 to 325 mesh (Tyler screen), and even more preferably, mostly 28 to 200 mesh. The product in the above example is and in the Tables was mostly about 80-150 mesh. 
     SOLIDS ADDITION APPARATUS 
     In the above example a water-cooled probe is used to inject the vermiculite into the furnace. The probe is about 5 feet long and consists of 3 concentric tubes made of 3/16&#34; stainless steel. The outer tube is 2.5 inches outer diameter, the middle tube 2 inches, the center tube 1 inch. Water flows down the annulus formed by the outer and middle tubes and returns via the annulus formed by the middle and center tubes. There is about 0.277 inches clearance between the terminus of the outer tube and the terminus of the middle tube to permit water return. Water is introduced in the front end of the outer tube, outside the boiler. The incoming flow is lateral, so that the water spins tangentially on its way down the tube. The vermiculite is taken off a hopper with a screw feeder which meters the vermiculite into an air conveying system, which delivers the vermiculite to the center tube of the probe. The air flow helps cool the center tube and may also contribute to cooling the water jacketed areas of the probe. 
     The Sintering Test developed by Babcock and Wilcox has been employed to determine the fouling tendency (formation of bonded deposits) of various ashes and the effect of additives. See &#34;The Sintering Test, An Index to Ash-Fouling Tendency&#34; by D. H. Barnhart and P. C. Williams, Transactions of the ASME, August, 1956, p. 1229. Briefly, the test consists of forming the ash into pellets, heating to various elevated temperatures for 15 hours, and measuring the force required to crush the resulting sintered samples. Table 1 summarizes the results obtained without additive, with various levels of vermiculite, and with magnesium oxide. Magnesium oxide was found to have the greatest effect in work done by Babcock and Wilcox and is included for comparison. Table 2 lists the corresponding percent reduction in sinter strength for the samples tested. The results show the dramatic effect that vermiculite has in deposit modifications. 
     
                       TABLE 1                                                     
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Sinter Strength of Pellets, psi                                           
             1800° F.                                              
                        2000° F.                                   
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Blank          10,800  15,200   13,400                                    
                                      25,600                              
(no treatment) 13,000  14,500   7,756 22,400                              
               11,200  15,300   24,900                                    
                                      19,300                              
Average Blank  13,333       18,893                                        
Vermiculite, 0.5%                                                         
               6,570   9,810    12,800                                    
                                      14,100                              
               9,980   10,300   12,200                                    
                                      14,300                              
               7,650            8,660                                     
Average 0.5%   8,862        12,412                                        
Vermiculite, 1.0%                                                         
               6,490   7,190    6,140  6,130                              
               5,190   5,300    6,090  6,810                              
               6,560   10,000   5,850  6,930                              
Average 1.0%   6,788         6,325                                        
Vermiculite, 1.5%                                                         
               4,960   4,510    4,880  4,480                              
               4,990   3,950    4,950  3,890                              
               5,540   3,770    4,190  4,270                              
Average 1.5%   4,620         4,443                                        
Magnesium Oxide, 1.5%                                                     
               8,300   8,100    12,900                                    
                                      13,500                              
               6,720   6,470    10,300                                    
                                      10,500                              
               8,500   5,170    14,500                                    
Average 1.5% MgO                                                          
               7,210        12,340                                        
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                       TABLE 2                                                     
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Average Reduction in Sinter Strength, %                                   
                 1800° F.                                          
                        2000° F.                                   
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Blank              --       --                                            
Vermiculite, 0.5%  33.5     34.3                                          
Vermiculite, 1.0%  49.1     66.5                                          
Vermiculite, 1.5%  65.4     76.5                                          
Magnesium Oxide, 1.5%                                                     
                   45.9     34.7                                          
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