Patent Publication Number: US-RE47435-E

Title: Electrolytes for use in a capacitor

Description:
CROSS-REFERENCE TO RELATED APPLICATION APPLICATIONS  
     The present application is a reissue of U.S. application Ser. No. 09/384,099, filed on Aug. 27, 1999, now U.S. Pat. No. 6,219,222, which claims priority based on U.S. provisional application Ser. No. 60/098,330, filed on Aug. 28, 1998, now abandoned. 
     BACKGROUND OF THE INVENTION 
     The present invention generally relates to the conversion of chemical energy to electrical energy and, more particularly, to an electrolyte solution having high conductivity and high breakdown voltage. 
     SUMMARY OF THE INVENTION 
     The present invention relates to an electrolyte suitable for activating an electrolytic or electrochemical capacitor. The electrolyte has a solvent which includes water and ethylene glycol having an ammonium salt dissolved therein. An acid or acids is used as an additive to achieve the appropriate pH, conductivity, and breakdown voltage for a particular capacitor application. 
     An exemplary capacitor includes an anode of a base metal such as aluminum or tantalum provided with an oxidized surface. The oxidized anode surface is a dielectric layer typically formed by an anodizing process. The thusly formed anode is electrochemically associated with a cathode having a separator disposed there between and activated with the present electrolyte. The electrolyte has a relatively high conductivity and breakdown voltage, which ensures that the capacitor exhibits low series resistance. 
     These and other aspects and advantages of the present invention will become increasingly more apparent to those skilled in the art by reference to the following description and the accompanying drawings. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIGS. 1 to 5  are the cyclic voltammetry scans of various electrolytes according to the present invention. 
     
    
    
     DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS 
     An electrolyte according to the present invention preferably contains the following ingredients, by weight: 0% to 85% de-ionized water, 0% to 95% ethylene glycol, 0% to 80% acetic acid, 0% to 6% phosphoric acid and 0% to 50% ammonium acetate. Suitable substitutes or co-solvents for the solvent ingredients of water and ethylene glycol are polyethylene glycol, formamide, dimethyl formamide and γ-butyrolactone. Ammonium acetate can be substituted by ammonium formate, ammonium hydrogen maleate and ammonium hydrogen phosphate. Besides phosphoric acid, citric, oxalic, formic, maleic, malonic, malic, sulfuric, adipic, succinic and nitric acids are also useful in the electrolyte. 
     The present electrolyte is compatible with components and materials used in many electrical storage devices including electrolytic and electrochemical capacitors. These types of capacitors include a cathode of a conductive metal such as titanium or tantalum provided with a semiconductive or pseudocapacitive coating. The coating can be an oxide, nitride, carbide or carbon nitride. A preferred cathode electrode is comprised of a porous ruthenium oxide film provided on a titanium substrate. The anode is of a valve metal consisting of the group vanadium, niobium and tantalum. The preferred anode is of sintered tantalum. The cathode and anode electrodes are segregated from each other by a suitable separator material. Such a capacitor is described in U.S. Pat. Nos. 5,894,403, 5,920,455 and 5,926,362. These patents are assigned to the assignee of the present invention and incorporated herein by reference. 
     The preferred ruthenium oxide/tantalum capacitor is useful at relatively high voltages of at least 250V, such as is required when the capacitor is incorporated into an implantable medical device, for example, a cardiac defibrillator. For this type of usage, it is important that the electrolyte have a high breakdown voltage, low resistivity, low pH and a wide operating temperature range. A preferred pH is between about 1 to about 7. This is particularly true for an ethylene glycol based electrolyte such as in the present invention. An electrolyte having a pH greater than about 7 is too neutral to allow hydrogen ions to interact with the cathode material, such as the ruthenium oxide cathode material, to achieve maximum capacitance. 
     A suitable electrolyte according to the present invention preferably has a resistively lower than 45 Ωcm. The resistivity can only be greater than 45 Ωcm if the viscosity of the solution is relatively low, however, ethylene glycol, a primary component of the present electrolyte has a relatively high viscosity. 
     The electrolyte of the present invention also has a CV window of 0.70 volts or greater. 
     The present electrolyte has a freezing point lower than −30° C. Should the capacitor be exposed to temperatures below −30° C., whether in use or during storage, it is important that the electrolyte not freeze. 
     It is another characteristic of the present electrolyte that it is chemically stable at elevated temperatures as high as 85° C. This means that the electrolyte does not generate gas at that temperature. If it did, the capacitor would swell and could be destroyed. Importantly, the physical characteristics of the electrolyte including its pH and resistivity do not change significantly over time, even at elevated temperatures up to about 85° C. 
     The electrolyte is also useful for activating a broad range of capacitors, preferably having an operating voltage in the range of 175 volts to 250 volts. For safety reasons, a guardband is required above the 250 volt rating at which the capacitor will operate. 
     The following examples describe the manner and process of an electrochemical cell according to the present invention, and they set forth the best mode contemplated by the inventors of carrying out the invention, but they are not to be construed as limiting. 
     EXAMPLE I 
     One preferred embodiment according to the present invention is an electrolyte designated CAL  22 C consisting of the ingredients listed in Table 1. This electrolyte is intended for use in activating a 175 volt capacitor. 
     
       
         
           
               
               
               
               
             
               
                 TABLE 1 
               
               
                   
               
               
                   
                 Components 
                 Wt. Percent 
                 Amount 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
            
               
                   
                 water 
                 49.41 
                 680 
                 (ml) 
               
               
                   
                 ethylene glycol 
                 19.45 
                 241 
                 (ml) 
               
               
                   
                 ammonium acetate 
                 15.55 
                 214 
                 (g) 
               
               
                   
                 phosphoric acid 
                  0.31 
                 2.5 
                 (ml) 
               
               
                   
                 acetic acid 
                 15.28 
                 200 
                 (ml) 
               
               
                   
               
            
           
         
       
     
     It was determined that electrolyte CAL  22 C had the physical characteristics listed in Table 2. 
     
       
         
           
               
               
               
             
               
                 TABLE 2 
               
               
                   
               
             
            
               
                   
                 pH 
                 4.89 
               
            
           
           
               
               
               
               
            
               
                   
                 Conductivity 
                 47.5 
                 mS/cm 
               
               
                   
                 Resistivity 
                 21.0 
                 Ωcm 
               
               
                   
                 CV Window 
                 0.7 
                 volts 
               
               
                   
                 Anode Breakdown 
                 245 
                 volts 
               
               
                   
               
            
           
         
       
     
     In order to determine the compatibility of electrolyte CAL  22 C with other typically used capacitor components, the electrolyte was filled into 22 glass bottles. Two of the bottles contained one of the nine different component materials. Two bottles contained all nine capacitor materials and two bottles served as controls and did not contain any capacitor materials. The capacitor consists of a ruthenium oxide cathode supported on a titanium cathode substrate, a tantalum oxide anode, separator materials of CELGARD 5550 and CELGARD 3501, a glass-to-metal seal consisting of a titanium ferrule enclosing ELAN 88 glass surrounding a titanium terminal pin, a polyethylene insulating ring, a MasterSil 151 elastomer material and a MasterSil 702 elastomer material. 
     The capacitor component materials were weighed three times prior to being placed in the appropriate bottles. Each bottle was then filled with electrolyte CAL  22 C and sealed with aluminum and polytetrafluoroethylene seal caps. Eleven of the bottles were stored at 60° C. while the remaining eleven bottles were stored at 85° C. The capacitor component materials contained in the bottles were rinsed, dried and weighed on a monthly basis for three months. 
     There was no discoloration in any of the electrolyte samples after storing at 60° C. and 85° C. for three months. 
     The polyethylene insulation ring turned beige in the sample stored at 85° C. 
     Most electrolyte samples had less than one percent weight change with the exception of the CELGARD and MasterSil materials. The observed weight loss was attributed to the rinsing and drying process. 
     It was determined that electrolyte CAL  22 C is compatible with the capacitor. The significant weight loss noted in the separator material was determined to be caused by the rinsing process. 
     EXAMPLE II 
     In order to determine the effect various temperatures have on the physical properties of electrolyte CAL  22 C, the electrolyte was filled into eight glass bottles. Specifically, four glass bottles were filled with electrolyte CAL  22 C and stored at −35° C., 37° C., 60° C. and 85° C., respectively. The samples were tested on a monthly basis for three months for pH, conductivity, voltage breakdown, voltage window and discoloration. 
     The remaining four glass bottles were filled with electrolyte CAL  22 C and pieces of one of the capacitor component materials were placed in respective ones of the bottles. The samples were stored at −35° C., 37° C., 60° C. and 85° C. and tested on a monthly basis for pH, conductivity, voltage breakdown, voltage window and discoloration. 
     There was no discoloration in the samples stored at −35° C., 37° C. or 60° C. after three months. However, there was discoloration in the electrolyte stored at 85° C. This sample turned yellow by month two and a slightly darker yellow by month three. 
     The electrolyte samples stored at 60° C. and 85° C. had a higher pH than the samples stored at −35° C. and 37° C. From this, the conclusion was drawn that an increase in temperature results in an increase in pH for electrolyte CAL  22 C. 
     There was no significant change in resistivity for the electrolyte samples stored at −35° C., 37° C. and 60° C. However, the 85° C. sample showed an increase in resistivity over time. 
     There was no significant difference in the control electrolyte samples compared to the electrolyte samples containing the component pieces of the capacitor. 
     As shown in  FIG. 1  for a representative CAL  22 C sample, there was no change in the cyclic voltammetry (CV) scan. The working electrode was a cathode, the counter electrode was platinum and the reference electrode was SCE. The CV scan was run from −2.0 volts to 0.9 volts at a rate of 10 mV/sec. 
     It was concluded that the physical properties of the CAL  22 C electrolyte are not significantly affected at −35° C., 37° C., 60° C. and 85° C. over a three month period. However, there is a slight increase in resistivity and a yellow discoloration at 85° C., but that is typical of ethylene glycol based electrolytes. 
     EXAMPLE III 
     Another preferred embodiment of an electrolyte according to the present invention is designated CAL  34 A and consists of the ingredients listed in Table 3. This electrolyte is intended for use in activating a 200 volt capacitor. 
     
       
         
           
               
               
               
               
             
               
                 TABLE 3 
               
               
                   
               
               
                   
                 Components 
                 Wt. Percent 
                 Amount 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
            
               
                   
                 water 
                 44.46 
                 630 
                 (ml) 
               
               
                   
                 ethylene glycol 
                 34.61 
                 441 
                 (ml) 
               
               
                   
                 ammonium acetate 
                 10.04 
                 142 
                 (g) 
               
               
                   
                 phosphoric acid 
                  0.51 
                 4.2 
                 (ml) 
               
               
                   
                 acetic acid 
                 10.39 
                 140 
                 (ml) 
               
               
                   
               
            
           
         
       
     
     It was determined that electrolyte CAL  34 A had the physical characteristics listed in Table 4. 
     
       
         
           
               
               
               
             
               
                 TABLE 4 
               
               
                   
               
             
            
               
                   
                 pH 
                 4.87 
               
            
           
           
               
               
               
               
            
               
                   
                 Conductivity 
                 29.6 
                 mS/cm 
               
               
                   
                 Resistivity 
                 33.8 
                 Ωcm 
               
               
                   
                 CV Window 
                 0.7 
                 volts 
               
               
                   
                 Anode Breakdown 
                 270 
                 volts 
               
               
                   
               
            
           
         
       
     
     In order to determine the compatibility of electrolyte CAL  34 A with the capacitor, the electrolyte was filled into 22 glass bottles in a similar manner as previously described in Example I. 
     The capacitor component materials were weighed three times prior to being placed in the appropriate bottles. Each bottle was then filled with electrolyte CAL  34 C and the bottles were sealed with aluminum seal caps. Eleven of the bottles were stored at 60° C. while the remaining eleven bottles were stored at 85° C. The capacitor contents of the bottles were rinsed, dried and weighed on a monthly basis for three months. 
     There was no discoloration in any of the electrolyte samples after storing at 60° C. for three months. However, there was discoloration in the electrolyte stored at 85° C. as the samples were white after three months. The 85° C. electrolyte sample containing the titanium cathode substrate was slightly more yellow in color. Yellow discoloration is a normal characteristic of ethylene glycol based electrolytes that have been stored at 85° C. 
     The polyethylene machined insulation ring turned tan around the hole in the ring in the sample stored at 85° C. 
     Most electrolyte samples had less than one percent weight change with the exception of the CELGARD and MasterSil materials. The observed weight changes were attributed to the rinsing and drying process. 
     It was determined that electrolyte CAL  34 A is compatible with the capacitor. The significant weight loss noted in the CELGARD separator materials was determined to be caused by the rinsing process. 
     EXAMPLE IV 
     In order to determine the effect various temperatures have on the physical properties of CAL  34 A, the electrolyte was filled into eight glass bottles. Specifically, four glass bottles were filled with electrolyte CAL  34 A and stored at −35° C., 37° C., 60° C. and 85° C., respectively The samples were tested on a monthly basis for three months for pH, conductivity, voltage breakdown, voltage window and discoloration. 
     The remaining four glass bottles were filled with electrolyte CAL  34 A and pieces of one of the component materials of the capacitor were placed in respective ones of the bottles. The samples were stored at −35° C., 37° C., 60° C. and 85° C. and tested on a monthly basis for pH, conductivity, voltage breakdown, voltage window and discoloration. 
     There was no discoloration in the samples stored at −35° C., 37° C. or 60° C. after three months. However, there was discoloration in the electrolyte stored at 85° C. This electrolyte turned slightly yellow after the first month. 
     The electrolyte samples stored at 60° C. and 85° C. had a higher pH than the samples stored at −35° C. and 37° C. From this, the conclusion was drawn that an increase in temperature results in an increase in pH for electrolyte CAL  34 A. 
     There was no significant change in resistivity for the electrolyte samples stored at −35° C., 37° C. and 60° C. However, the 85° C. sample showed an increase in resistivity over time. 
     There was no significant difference in the control electrolyte samples compared to the electrolyte samples containing the component pieces of the capacitor. 
     Foil voltage breakdown was consistent throughout the electrolyte samples stored at the various temperatures. 
     There was no change in cyclic voltammetry scans for the various electrolyte samples. An exemplary CV scan is shown in  FIG. 2  and was conducted in a similar manner as described in Example II. 
     It was concluded that the physical properties of the CAL  34 A electrolyte are not significantly affected at −35° C., 37° C., 60° C. and 85° C. over a three month period. However, there is a slight increase in resistivity and a yellow discoloration at 85° C., but that is typical of ethylene glycol based electrolytes. 
     EXAMPLE V 
     Another preferred embodiment of an electrolyte according to the present invention is designated LAC  15 A and consists of the ingredients listed in Table 5. This electrolyte is intended for use in activating a 250 volt capacitor. 
     
       
         
           
               
               
               
               
             
               
                 TABLE 5 
               
               
                   
               
               
                   
                 Components 
                 Wt. Percent 
                 Amount 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
            
               
                   
                 water 
                 46.52 
                 647 
                 (ml) 
               
               
                   
                 ethylene glycol 
                 36.05 
                 451 
                 (ml) 
               
               
                   
                 ammonium acetate 
                  8.29 
                 115 
                 (g) 
               
               
                   
                 phosphoric acid 
                  0.44 
                 3.5 
                 (ml) 
               
               
                   
                 acetic acid 
                  8.70 
                 115 
                 (ml) 
               
               
                   
               
            
           
         
       
     
     It was determined that electrolyte LAC  15 A had the physical characteristics listed in Table 6 
     
       
         
           
               
               
               
             
               
                 TABLE 6 
               
               
                   
               
             
            
               
                   
                 pH 
                 4.83 
               
            
           
           
               
               
               
               
            
               
                   
                 Conductivity 
                 25.6 
                 mS/cm 
               
               
                   
                 Resistivity 
                 39.1 
                 Ωcm 
               
               
                   
                 CV Window 
                 0.7 
                 volts 
               
               
                   
                 Anode Breakdown 
                 275 
                 volts 
               
               
                   
               
            
           
         
       
     
     Tests of pH, conductivity, resistivity, cyclic voltammetry scan, and breakdown voltage were performed on LAC  15 A. The CV scan was done in a similar manner as described in Example II. As shown in  FIG. 3  for a representative LAC  15 A sample, the CV window was determined to be 0.70 volts. 
     The pH of LAC  15 A is 4.84, which is in the acceptable pH range. Acetic acid lowers the pH of the electrolyte and was used because it has a higher breakdown voltage than malonic, malic, maleic, citric and succinic acids. 
     The resistivity of LAC  15 A is 39.1 Ωcm. This resistivity meets the requirements for an electrolyte with an ethylene glycol solvent. Ammonium acetate is the solute responsible for lowering the resistivity. 
     The compatibility of electrolyte CAL  34 A with the capacitor was tested in a similar manner as previously described in Example I. LAC  15 A was determined to be compatible with all capacitor component materials of the capacitor. 
     An open cell capacitor was built containing a ruthenium oxide cathode and a sintered tantalum anode segregated from each other by a CELGARD 5550 separator and activated with LAC  15 A. From this test it was determined that the cell resistivity was 639.34 Ωm, which is below the 1.0 Ω requirement. Additionally, charge/discharge data showed that the cell will withstand 280 volts, which is above the breakdown voltage requirement of 275 volts. 
     The dc leakage of the open cell after 5 minutes at 24 μamps was determined to be an acceptable value. The dc leakage of an open cell is typically higher than in a closed capacitor. 
     Long term testing of this electrolyte was performed at temperatures of −35° C., room temperature, 60° C. and 85° C. Low temperature testing of LAC  15 A showed that LAC  15 A is liquid at −35° C. which meets the low temperature requirement for the electrolyte. Also, LAC  15 A was stable after seven months at −35° C. in terms of both pH and resistivity. 
     The greatest change in pH occurred at 60° C. That sample had a 0.25 increase in pH, which is not detrimental to the performance of the electrolyte as it falls in the acceptable pH range of 1 to 7. The pH of LAC  15 A stored at all temperatures leveled off at approximately 5.0. 
     There was a slight increase in resistivity in LAC  15 A at all storage temperatures. The greatest increase in resistivity was observed in the electrolyte stored at 85° C. The maximum resistivity was 41.8 Ωcm. 
     Accordingly, it was determined that electrolyte LAC  15 A is useful as an electrolyte for a 250 volt capacitor. It has a breakdown voltage of 275 volts, a pH of 4.84 and a CV window of 0.7 volts. The electrolyte performs well at high temperatures with no gas generation nor significant changes in pH and resistivity. The freezing point is well below the acceptable limit of −30° C. It is compatible with all materials in the capacitor. The resistivity is acceptable at 39.1 Ωcm. It performed well in both an open cell capacitor and a prototype ruthenium oxide/tantalum capacitor in terms of resistivity, charge/discharge, and do leakage tests. Finally, long term testing at elevated temperatures indicated that LAC  15 A is a stable electrolyte which changes little in terms of its physical or functional properties. 
     EXAMPLE VI 
     Another preferred embodiment of an electrolyte according to the present invention is designated LAC  38 I and consists of the ingredients listed in Table 7. This electrolyte is intended for use in activating a 250 volt capacitor. 
     
       
         
           
               
               
               
               
             
               
                 TABLE 7 
               
               
                   
               
               
                   
                 Components 
                 Wt. Percent 
                 Amount 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
            
               
                   
                 water 
                 46.59 
                 650 
                 (ml) 
               
               
                   
                 ethylene glycol 
                 41.45 
                 520 
                 (ml) 
               
               
                   
                 ammonium acetate 
                  5.60 
                 78 
                 (g) 
               
               
                   
                 phosphoric acid 
                  0.48 
                 3.9 
                 (ml) 
               
               
                   
                 acetic acid 
                  5.88 
                 78 
                 (ml) 
               
               
                   
               
            
           
         
       
     
     It was determined that electrolyte LAC  38 I had the physical characteristics listed in Table 8. 
     
       
         
           
               
               
               
             
               
                 TABLE 8 
               
               
                   
               
             
            
               
                   
                 pH 
                 4.80 
               
            
           
           
               
               
               
               
            
               
                   
                 Conductivity 
                 18.8 
                 mS/cm 
               
               
                   
                 Resistivity 
                 53.3  
                 Ωcm 
               
               
                   
                 Foil Breakdown 
                 270 
                 volts 
               
               
                   
                 CV Window 
                 0.7 
                 volts 
               
               
                   
                 Anode Breakdown 
                 300 
                 volts 
               
               
                   
               
            
           
         
       
     
     LAC  38 I was tested at a temperature of 24.5° C. for: conductivity, resistivity, pH, foil breakdown voltage and CV window. LAC  38 I was also subjected to −38° C. for one week at a volume of approximately 80 mL. The CV scan was run in a similar manner as described in Example II. 
     Compatibility testing was performed on LAC  38 I. This test consisted of filling the electrolyte into 22 glass bottles in a similar manner as described in Example I. The bottles were monitored monthly for color and each capacitor component material was rinsed, dried and weighed. No apparent change in electrolyte composition based on color and clarity were detected. 
     An open cell capacitor was built in a similar manner to the open cell capacitor described in Example VI, and activated with LAC  38 I. It was determined that LAC  38 I met the pH, CV window ( FIG. 4 ), low temperature, and breakdown requirements for the 250 volt capacitor. The resistivity cf LAC  38 I was 54.4 Ωcm, which is higher than the resistivity of LAC  15 A at 39.1 Ωcm. The higher resistivity of LAC  38 I means that the Rs is higher and the energy efficiency is lower in comparison to the open cell activated with LAC  15 A. The tradeoff is that LAC  38 I has a breakdown voltage that is 25 volts higher than LAC  15 A. 
     LAC  38 I was subjected to a three month temperature test at 37° C., 60° C., 85° C., and −35° C. The test bottles contained LAC  38 I and the component materials of the capacitor while a control bottle contained only the electrolyte. Both the control and test samples of LAC  38 I were tested monthly for pH, conductivity, resistivity, foil breakdown voltage and color. The results of the three month temperature test were similar to those for LAC  15 A. There were no significant differences between the control and the test samples. At −35° C., the various tested properties remained the same over the three month period. At 37° C., 60° C. and 85° C., the pH and resistivity increased slightly with time. The foil breakdown voltage remained unaffected. The electrolyte color changed at 85° C. in the control bottle, but it is common for ethylene glycol based electrolytes to turn yellow at elevated temperatures. The yellow color is not an indication of an unstable electrolyte. 
     Accordingly, LAC  38 I is an alternative choice for an electrolyte in a 250 volt capacitor. The electrolyte meets the pH, CV window, low temperature and breakdown requirements for the capacitor. No compatibility problems were identified between LAC  38 I and the components used in the capacitor and long term testing showed that the electrolyte is stable. 
     EXAMPLE VII 
     Another embodiment of an electrolyte according to the present invention is designated CAL  23 H and consists of the ingredients listed in Table 9. This electrolyte is intended for use in activating a 300 volt capacitor. 
     
       
         
           
               
               
               
               
             
               
                 TABLE 9 
               
               
                   
               
               
                   
                 Components 
                 Wt. Percent 
                 Amount 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
            
               
                   
                 water 
                 51.94 
                 720 
                 (ml) 
               
               
                   
                 ethylene glycol 
                 40.29 
                 502 
                 (ml) 
               
               
                   
                 ammonium acetate 
                  3.54 
                 50 
                 (g) 
               
               
                   
                 phosphoric acid 
                  0.59 
                 4.8 
                 (ml) 
               
               
                   
                 acetic acid 
                  3.64 
                 48 
                 (ml) 
               
               
                   
               
            
           
         
       
     
     It was determined that electrolyte CAL  23 H had the physical characteristics listed in Table 10. 
     
       
         
           
               
               
               
             
               
                 TABLE 10 
               
               
                   
               
             
            
               
                   
                 pH 
                 4.70 
               
            
           
           
               
               
               
               
            
               
                   
                 Conductivity 
                 13.7 
                 mS/cm 
               
               
                   
                 Resistivity 
                 72.8 
                 Ωcm 
               
               
                   
                 Foil Breakdown 
                 250 
                 volts 
               
               
                   
                 CV Window 
                 0.7 
                 volts 
               
               
                   
                 Anode Breakdown 
                 320 
                 volts 
               
               
                   
               
            
           
         
       
     
     An open cell capacitor was built in a similar manner as the open cell described in Example VI and activated with CAL  23 H. The open cell capacitor was tested for capacitance, resistance, dc leakage and charge/discharge performance. 
     The pH, conductivity, and CV window met the criteria for the 300 volt electrolyte. The pH was less than 8 and the CV window was below the 0.7 volt minimum ( FIG. 5 ). 
     The open cell capacitor had a breakdown voltage of 320 volts which is above the minimum 15 volts charge guardband. 
     A sample of the CAL  23 H electrolyte remained liquid at −38° C. after 24 hours. 
     The resistivity of the electrolyte was stable after 26 days at 60° C. and 85° C. 
     There was an increase in pH at 60° C. and 85° C., which is a normal characteristic of electrolytes containing water, ethylene glycol, ammonium acetate, acetic acid and phosphoric acid. 
     Accordingly, it was determined that CAL  23 H meets the 300 volt electrolyte criteria. 
     It is appreciated that various modifications to the present inventive concepts described herein may be apparent to those of ordinary skill in the art without departing from the spirit and scope of the present invention as defined by the herein appended claims.