Patent Publication Number: US-5021579-A

Title: Cyclohexane herbicides

Description:
This is a division of application Ser. No. 07/244,167, filed Sept. 14, 1988, now U.S. Pat. No. 4,981,971 which in turn is a division of application Ser. No. 07/071,662, filed Jul. 9, 1987, now U.S. Pat. No. 4,789,396, issued Dec. 6, 1988. 
    
    
     The present invention relates to a novel cyclohexane compound represented by the general formula (I), ##STR2## wherein R 1  represents a hydrogen atom or a (C 1  -C 6 )alkyl or (C 1  -C 4 )alkoxymethyl group, R 2  represents a (C 1  -C 12 )-alkyl, (C 3  -C 6 )alkenyl, (C 3  -C 6 )alkynyl, (C 3  -C 6 )cycloalkylmethyl, halo(C 3  -C 6 )alkenyl, cyano(C 1  -C 4 )alkyl, (C 1  -C 4 )alkoxymethyl, (C 1  -C 4 )alkylchiomethyl or benzyl group, R 3  represents a hydrogen atom or a methyl group, R 4  represents a hydrogen atom or a methyl group, R 5  is a hydrogen atom or a methyl group, and when R 5  is a hydrogen atom, R 6  is a hydrogen atom or a (C 1  -C 4 )alkoxycarbonyl group, and when R 5  is a methyl group, R 6  is a hydrogen atom, X represents a group represented by the formula CH or a nitrogen atom, Y represents a hydrogen or halogen atom (fluorine, chlorine, bromine or iodine atom), Z represents a trifluoromethyl, trifluoromethoxy or 1,1,2,2-tetrafluoroethoxy group and n is an integer of 0, 1 or 2 and its metal salt, ammonium salt and organic ammonium salt, its production and herbicides containing it as an active ingredient. 
     It is described in Japanese Patent Publication Kokai (Laid-open) Nos. 46749/1979 and 115349/1979 that cyclohexane derivatives can be used as an active ingredient for herbicides. These compounds, however, may not always be said to be satisfactory because of their poor herbicidal activity and poor selectivity between crops and weeds. 
     In view of the situation like this, the present inventors extensively studied to develop a compound having excellent herbicidal activity, and as a result, found a compound having excellent herbicidal activity at low dosage rates and showing no phytotoxicity to crops. The present inventors thus attained to the present invention. 
     The present compounds exhibit both excellent herbicidal activity and excellent selectivity between crops and weeds, as described below. The present compounds, in foliage treatment and soil treatment in plow field, have a herbicidal activity against various weeds in question, for example, broadleaf weeds such as common purslane (Portulaca oleracea), chickweed (Stellaria media), common lambsquarters (Chenopodium album), redroot pigweed (Amaranthus retroflexus), radish (Raphanus sativus), velvetleaf (Abutilon theophrasti), prickly sida (Sida spinosa), black nightshade (Solanum nigrum), persian speedwell (Veronica persica), common cocklebur (Xanthium strumarium), morningglories (Ipomoea spp.), etc.; grassy weeds such as Japanese millet (Echinochloa frumentacea), barnyardgrass (Echinochlod crus-galli), giant foxtail (Setaria faberi), green foxtail (Setaria viridis), large crabgrass (Digitaria sanguinalis), annual bluegrass (Poa annua), blackgrass (Alopecurus myosuroides), oat (Avena sativa), wild oat (Avena fatua), johnsongrass (Sorghum halepense), shattercane (Sorghum bicolor), downy brome (Bromus tectorum), cheat (Bromus sealinus), bermudagrass (Cynodon dactylon), goosegrass (Eleusine indica), quackgrass (Agropyron repens), fall panicum (Panicum dichotomiflorum), sedge weeds such as purple nutsedge (Cyperus rotundus) and yellow nutsedge (Cyperus esculentus), etc., and yet, their phytotoxicity to main crops such as corn, wheat, barley, rice, soybean, peanut, cotton, beet, sunflower, etc. is not such a one as to cause a problem. 
     Further, the present compounds, in treatment under flooded condition in paddy field, show a herbicidal activity against various weeds in question, for example grassy weeds such as barnyardgrass (Echinochloa oryzicola), etc., and broadleaf weeds such as common falsepimpernel (Lindernia procumbens), long stemmed waterwort (Elatine triandra), etc., and yet, their phytotoxicity to rice is not such a one as to cause a problem. 
     Of the present compounds represented by the general formula (I), those in which R 1  is a methyl group, R 2  is an ethyl or propyl group, preferably an ethyl group, R 3  is a hydrogen atom or a methyl group, R 4  is a hydrogen atom or a methyl group, R 5  is a hydrogen atom or a methyl group, R 6  is a hydrogen atom, X is a group represented by the formula CH, Y is a hydrogen atom, Z is a trifluoromethyl, trifluoromethoxy or 1,1,2,2-tetrafluoroethoxy group and n is an integer of 0, show particularly excellent selectivity between grassy crops such as corn, wheat, rice, etc. and grassy weeds such as barnyardgrass (Echinochloa crus-galli), green foxtail, giant foxtail, large crabgrass, oat, johnsongrass, barnyardgrass (Echinochloa oryzicola), etc., and they are particularly preferred as a herbicide used in corn and wheat fields. 
     Also, of the present compounds represented by the general formula (I), those in which R 1  is an ethyl or propyl group, R 2  is a (C 3  -C 6 )alkenyl group or halo(C 3  -C 6 )alkenyl group, preferably an allyl or 2-butenyl group, R 3  is a hydrogen atom or a methyl group, R 4  is a hydrogen atom or a methyl group, R 5  is a hydrogen atom or a methyl group, R 6  is a hydrogen atom, X is a group represented by the formula CH or a nitrogen atom, Y is a hydrogen atom, Z is a trifluoromethyl, trifluoromethoxy or 1,1,2,2-tetrafluoroethoxy group and n is an integer of 0, preferably a trifluoromethyl or trifluoromethoxy group, show particularly excellent selectivity between rice and various weeds in paddy field, so that they are preferred as a herbicide for paddy field. 
     Also, of the present compounds represented by the general formula (I), those in which R 1  is an ethyl or propyl group, R 2  is a (C 1  -C 6 )alkyl, (C 3  -C 6 )alkenyl or halo(C 3  -C 6 )alkenyl group, R 3  is a hydrogen atom or a methyl group, R 4  is a hydrogen atom or a methyl group, R 5  is a hydrogen atom or a methyl group, and when R 5  is a hydrogen atom, R 6  is a hydrogen atom or a (C 1  -C 4 )-alkoxycarbonyl group and when R 5  is a methyl group, R 6  is a hydrogen atom, X is a group represented by the formula CH or a nitrogen atom, Y is a hydrogen atom, Z is a trifluoromethyl or trifluoromethoxy group and n is an integer of 0, exhibit particularly excellent selectivity between broadleaf crops such as soybean, cotton, beet, peanut, sunflower, etc. and various grassy weeds, so that they are preferred as a herbicide for broadleaf crops. 
     Further, of the present compounds represented by the general formula (I), those in which R 1  is a methyl group, R 2  is a (C 1  -C 6 )alkyl, (C 3  -C 6 )alkenyl or halo(C 3  -C 6 )alkenyl group, R 3  is a hydrogen atom or a methyl group, R 4  is a hydrogen atom or a methyl group, R 5  is a hydrogen atom or a methyl group, R 6  is a hydrogen atom, X is a group represented by the formula CH, Y is a hydrogen atom, Z is a trifluoromethyl group and n is an integer of 0, have particularly a broad herbicidal spectrum, so that they are preferred as a herbicide used in orchards, forests, non-crop lands, etc. 
     Preferred compounds are 2-(1-propoxyaminoethylidene)- or 2-(1-ethoxyaminoethylidene)-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione, 2-(1-ethoxyaminoethylidene)-5-[2-(4-trifluoromethoxyphenylthio)ethyl]cyclohexane-1,3-dione, 2-(1-allyloxyaminobutylidene)- or 2-[1-(2-butenyl)oxyaminobutylidene]-5-[2-(5-trifluoromethyl-2-pyridylthio)ethyl]cyclohexane-1,3-dione and 2-(1-ethoxyaminopropylidene)- or 2-(1-allyloxyaminopropylidene)-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione. 
     Next, a method for producing the present compounds will be explained in detail. 
     The present compounds can be produced by reacting acylcyclohexane represented by the general formula (II), ##STR3## wherein R 1 , R 3 , R 4 , R 5 , R 6 , X, Y, Z and n are as defined above, with hydroxylamine represented by the general formula (III), 
     
         NH.sub.2 OR.sup.2                                          (III) 
    
     wherein R 2  is as defined above, 
     or its inorganic acid salt. 
     This reaction is generally carried out with or without a solvent, and as need arises, in the presence of a base, if necessary. The reaction temperature is in a range of from 0° to 100° C., and the reaction time is in a range of from 0.5 to 24 hours. The amount of the reagents used for reaction is from 1 to 2 equivalents for the amine (III) or its inorganic acid salt, and from 1 to 2 equivalents for the dehydrohalogenating agent based on 1 equivalent of acylcyclohexane (II). 
     The inorganic acid salt of the amine (III) includes hydrochloride, hydrobromide, sulfate, etc. 
     The solvent includes aliphatic hydrocarbons (e.g. hexane, heptane, ligroin, petroleum ether), aromatic hydrocarbons (e.g. benzene, toluene, xylene), halogenated hydrocarbons (e.g. chloroform, carbon tetrachloride, dichloroethane, chlorobenzene, dichlorobenzene), ethers (e.g. diethyl ether, diisopropyl ether, dioxane, tetrahydrofuran, diethylene glycol dimethyl ether), alcohols (e.g. methanol, ethanol, isopropanol, tert-butanol, octanol, cyclohexanol, methyl cellosolve, diethylene glycol, glycerin), esters (e.g. ethyl formate, ethyl acetate, butyl acetate, diethyl carbonate), nitro compounds (e.g. nitroethane, nitrobenzene), nitriles (e.g. acetonitrile, isobutyronitrile), tertiary amines (e.g. pyridine, triethylamine, N,N-diethylaniline, tributylamine, N-methylmorpholine), acid amides (e.g. formamide, N,N-dimethylformamide, acetamide), sulfur compounds (e.g. dimethyl sulfoxide, sulfolane), water and mixtures thereof. 
     The base includes organic bases (e.g. pyridine, triethylamine, N,N-diethylaniline), inorganic bases (e.g. sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium hydride), alkali metal alkoxides (e.g. sodium methoxide, sodium ethoxide), etc. 
     After completion of the reaction, the reaction solution is poured into water, made neutral to acidic, subjected to the usual after-treatment such as extraction with organic solvents, concentration, etc., and if necessary, purified by chromatography, distillation, recrystallization, etc. 
     The present compounds represented by the general formula (I) are considered to have the following tautomeric structures: ##STR4## wherein W represents ##STR5## 
     Similarly, acylcyclohexane represented by the general formula (II) are also considered to have the following tautomeric structures: ##STR6## wherein W represents ##STR7## 
     Next, examples of the present compound produced by the method of the present invention will be shown in Table 1. 
     
                                           TABLE 1                                 
__________________________________________________________________________
 ##STR8##                                                                 
X  Y  Z      R.sup.1 R.sup.2   R.sup.3                                    
                                  R.sup.4                                 
                                     R.sup.5                              
                                        R.sup.6                           
                                              n                           
__________________________________________________________________________
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                     CH.sub.3  H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR9## &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR10##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                     CH.sub.2 CHCH.sub.2                                  
                               H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CN                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.2 CH.sub.2 CH.sub.3                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.2 CH.sub.2 CH.sub.3                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCCH.sub.3                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.3  &#34;  &#34;  CH.sub.3                             
                                        &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                     CH.sub.2 CH.sub.3                                    
                               H  H  CH.sub.3                             
                                        H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR11##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR12##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                     CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               H  H  CH.sub.3                             
                                        H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;&#34; &#34;  &#34;  &#34;                                 
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.3  &#34;  &#34;  H  &#34;     1                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                      ##STR13##                                           
                               H  H  H  H     1                           
&#34;  &#34;  &#34;      &#34;                                                            
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR14##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                     CH.sub.3  H  H  H  H     2                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR15##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR16##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                     CH.sub.2 CHCCl.sub.2                                 
                               H  H  H  H     2                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.3  &#34;  CH.sub.3                                
                                     &#34;  &#34;     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.3 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                      ##STR17##                                           
                               H  CH.sub.3                                
                                     H  H     0                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR18##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.3  CH.sub.3                                   
                                  H  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                     CH.sub.2 CH.sub.3                                    
                               CH.sub.3                                   
                                  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub. 3                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR19##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR20##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                     CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               CH.sub.3                                   
                                  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      C.sub.2 H.sub.5                                              
                     CH.sub.3  H  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             C.sub.2 H.sub.5                                              
                      ##STR21##                                           
                               H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR22##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR23##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             C.sub.2 H.sub.5                                              
                     CH.sub.2 CCCH.sub.3                                  
                               H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.2 CH.sub.2 CH.sub.3                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.3  &#34;  &#34;  &#34;  &#34;     1                           
&#34;  &#34;  &#34;      &#34;       CH.sub. 2 CH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR24##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR25##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             C.sub.2 H.sub.5                                              
                     CH.sub.2 CHCHCH.sub.3                                
                               H  H  H  H     1                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.3  &#34;  &#34;  &#34;  &#34;     2                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             C.sub.2 H.sub.5                                              
                     CH(CH.sub.3).sub.2                                   
                               H  H  H  H     2                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR26##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR27##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;                                 
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;                                 
CH H  CF.sub.3                                                            
             C.sub.2 H.sub.5                                              
                     CH.sub.2 C.sub.6 H.sub.5                             
                               H  H  H  H     2                           
&#34;  &#34;  &#34;      &#34;       CH.sub.3  &#34;  &#34;  CH.sub.3                             
                                        &#34;     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR28##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR29##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             C.sub.2 H.sub. 5                                             
                     CH.sub.2 CHCHCl                                      
                               H  H  CH.sub.3                             
                                        H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.3  &#34;  CH.sub.3                                
                                     H  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             C.sub.2 H.sub.5                                              
                     CH.sub.2 CH(CH.sub.3).sub.2                          
                               H  CH.sub.3                                
                                     H  H     0                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR30##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR31##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             C.sub.2 H.sub.5                                              
                     CH.sub.3  CH.sub.3                                   
                                  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR32##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR33##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             C.sub.2 H.sub.5                                              
                     CH.sub.2 CHCCl.sub.2                                 
                               CH.sub.3                                   
                                  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      CH.sub.2 CH.sub.2 CH.sub.3                                   
                     CH.sub.3  H  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.2 CH.sub.2 CH.sub.3                                   
                      ##STR34##                                           
                               H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR35##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.2 CH.sub.2 CH.sub.3                                   
                     CH.sub.3  CH.sub.3                                   
                                  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR36##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR37##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.2 CH.sub.2 CH.sub.3                                   
                     CH.sub.2 CHCCl.sub.2                                 
                               CH.sub.3                                   
                                  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.3 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.3  H  CH.sub.3                                
                                     &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.2 CH.sub.2 CH.sub.3                                   
                      ##STR38##                                           
                               H  CH.sub.3                                
                                     H  H     0                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR39##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH(CH.sub.3).sub.2                                           
                     CH.sub.3  H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR40##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR41##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH(CH.sub.3).sub.2                                           
                     CH.sub.2 CHCCl.sub.2                                 
                               H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      CH.sub.2 CH(CH.sub.3).sub.2                                  
                     CH.sub.3  &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.2 CH(CH.sub.3).sub.2                                  
                      ##STR42##                                           
                               H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR43##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             H       CH.sub.3  H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3                                     
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR44##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR45##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
 
    
     
         __________________________________________________________________________
CH H  CF.sub.3                                                            
             H       CH.sub.2 CHCCl.sub.2                                 
                               H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      CH.sub.2 OCH.sub.3                                           
                     CH.sub.3  &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.2 OCH.sub.3                                           
                      ##STR46##                                           
                               H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR47##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                     CH.sub.3  H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR48##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR49##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                     CH.sub.2 CHCCl.sub.2                                 
                               H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      C.sub.2 H.sub.5                                              
                     CH.sub.3  &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  OCF.sub.3                                                           
             C.sub.2 H.sub.5                                              
                      ##STR50##                                           
                               H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR51##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  OCF.sub.3                                                           
             CH.sub.2 CH.sub.2 CH.sub.3                                   
                     CH.sub.3  H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR52##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR53##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  OCF.sub.3                                                           
             CH.sub.2 CH.sub.2 CH.sub.3                                   
                     CH.sub.2 CHCCl.sub.2                                 
                               H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                     CH.sub.3  &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                      ##STR54##                                           
                               H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR55##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub. 2                        
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  OCF.sub.2 CF.sub.2 H                                                
             C.sub.2 H.sub.5                                              
                     CH.sub.3  H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR56##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR57##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  OCF.sub.2 CF.sub.2 H                                                
             C.sub.2 H.sub.5                                              
                     CH.sub.2 CHCCl.sub.2                                 
                               H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      CH.sub.2 CH.sub.2 CH.sub.3                                   
                     CH.sub.3  &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.2 CH.sub.2 CH.sub.3                                   
                      ##STR58##                                           
                               H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR59##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
N  CH CF.sub.3                                                            
             CH.sub.3                                                     
                     CH.sub.3  H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR60##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR61##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
N  CH CF.sub.3                                                            
             CH.sub.3                                                     
                     CH.sub.2 CHCCl.sub.2                                 
                               H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  H  &#34;      C.sub.2 H.sub.5                                              
                     CH.sub.3  &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub. 2 CH.sub.2 CH.sub.3                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
N  H  CF.sub.3                                                            
             C.sub.2 H.sub.5                                              
                      ##STR62##                                           
                               H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR63##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
N  H  CF.sub.3                                                            
             CH.sub.2 CH.sub.2 CH.sub.3                                   
                     CH.sub.3  H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR64##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR65##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
N  H  CF.sub.3                                                            
             CH.sub.2 CH.sub.2 CH.sub.3                                   
                     CH.sub.2 CHCCl.sub.2                                 
                               H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  Cl &#34;      CH.sub.3                                                     
                     CH.sub.3  &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                      ##STR66##                                           
                               H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR67##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
N  Cl CF.sub.3                                                            
             C.sub.2 H.sub.5                                              
                     CH.sub.3  H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR68##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR69##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
N  Cl CF.sub.3                                                            
             C.sub.2 H.sub.5                                              
                     CH.sub.2 CHCCl.sub.2                                 
                               H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      CH.sub.2 CH.sub.2 CH.sub.3                                   
                     CH.sub.3  &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
N  Cl CF.sub.3                                                            
             CH.sub.2 CH.sub.2 CH.sub.3                                   
                      ##STR70##                                           
                               H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR71##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C CH                                        
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
H  H  CF.sub.3                                                            
             CH.sub.2 OCH.sub.3                                           
                     CH.sub.3  H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub. 2).sub.4 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR72##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR73##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
N  H  CF.sub.3                                                            
             CH.sub.2 OCH.sub.3                                           
                     CH.sub.2 CHCCl.sub.2                                 
                               H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      H       CH.sub.3  &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
N  H  CF.sub.3                                                            
             H                                                            
                      ##STR74##                                           
                               H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR75##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                     CH.sub.3  H  H  H  COOCH.sub.3                       
                                              0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR76##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR77##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
 
    
     
         __________________________________________________________________________
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                     CH.sub.2 CHCCl.sub.2                                 
                               H  H  H  COOCH.sub.3                       
                                              0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.3  &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                      ##STR78##                                           
                               H  H  H  COOCH.sub.3                       
                                              1                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR79##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                     CH.sub.3  H  H  H  COOCH.sub.3                       
                                              2                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR80##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR81##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                     CH.sub.2 CHCCl.sub.2                                 
                               H  H  H  COOCH.sub.3                       
                                              2                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub. 2 CCH                                        
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.3  CH.sub.3                                   
                                  &#34;  &#34;  &#34;     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                      ##STR82##                                           
                               CH.sub.3                                   
                                  H  H  COOCH.sub.3                       
                                              0                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR83##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub. 2 CHCHCl                                     
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                     CH.sub.3  H  CH.sub.3                                
                                     H  COOCH.sub.3                       
                                              0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR84##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR85##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                     CH.sub.2 CHCCl.sub.2                                 
                               H  CH.sub.3                                
                                     H  COOCH.sub.3                       
                                              0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      C.sub.2 H.sub.5                                              
                     CH.sub.3  &#34;  H  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             C.sub.2 H.sub.5                                              
                      ##STR86##                                           
                               H  H  H  COOCH.sub.3                       
                                              0                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR87##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             C.sub.2 H.sub.5                                              
                     CH.sub.3  H  CH.sub.3                                
                                     H  COOCH.sub.3                       
                                              0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR88##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR89##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             C.sub.2 H.sub.5                                              
                     CH.sub.2 CHCCl.sub.2                                 
                               H  CH.sub.3                                
                                     H  COOCH.sub.3                       
                                              0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.3  CH.sub.3                                   
                                  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             C.sub.2 H.sub.5                                              
                      ##STR90##                                           
                               CH.sub.3                                   
                                  H  H  COOCH.sub.3                       
                                              0                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR91##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.2 CH.sub.2 CH.sub.3                                   
                     CH.sub.3  H  H  H  COOCH.sub.3                       
                                              0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR92##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR93##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.2 CH.sub.2 CH.sub.3                                   
                     CH.sub.2 CHCCl.sub.2                                 
                               H  H  H  COOCH.sub.3                       
                                              0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.3  CH.sub.3                                   
                                  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.2 CH.sub.2 CH.sub.3                                   
                      ##STR94##                                           
                               CH.sub.3                                   
                                  H  H  COOCH.sub.3                       
                                              0                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR95##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.2 CH.sub.2 CH.sub.3                                   
                     CH.sub.3  H  CH.sub.3                                
                                     H  COOCH.sub.3                       
                                              0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;                                 
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR96##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR97##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH.sub.2 CH.sub.2 CH.sub.3                                   
                     CH.sub.2 CHCCl.sub.2                                 
                               H  CH.sub.3                                
                                     H  COOCH.sub.3                       
                                              0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      CH(CH.sub.3).sub.2                                           
                     CH.sub.3  &#34;  H  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             CH(CH.sub.3).sub.2                                           
                      ##STR98##                                           
                               H  H  H  COOCH.sub.3                       
                                              0                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR99##                                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             H       CH.sub.3  H  H  H  COOCH.sub.3                       
                                              0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR100##                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR101##                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  CF.sub.3                                                            
             H       CH.sub.2 CHCCl.sub.2                                 
                               H  H  H  COOCH.sub.3                       
                                              0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  OCF.sub.3                                                           
             CH.sub.3                                                     
                     CH.sub.3  &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub. 2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                      ##STR102##                                          
                               H  H  H  COOCH.sub.3                       
                                              0                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR103##                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  OCF.sub.3                                                           
             C.sub.2 H.sub.5                                              
                     CH.sub.3  H  H  H  COOCH.sub.3                       
                                              0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR104##                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR105##                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  OCF.sub.3                                                           
             C.sub.2 H.sub.5                                              
                     CH.sub.2 CHCCl.sub.2                                 
                               H  H  H  COOCH.sub.3                       
                                              0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      CH.sub.2 CH.sub.2 CH.sub.3                                   
                     CH.sub.3  &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub. 2 CH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
 
    
     
         __________________________________________________________________________
CH H  OCF.sub.3                                                           
             CH.sub.2 CH.sub.2 CH.sub.3                                   
                      ##STR106##                                          
                               H  H  H  COOCH.sub.3                       
                                              0                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR107##                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                     CH.sub.3  H  H  H  COOCH.sub.3                       
                                              0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR108##                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR109##                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                     CH.sub.2 CHCCl.sub.2                                 
                               H  H  H  COOCH.sub.3                       
                                              0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      C.sub.2 H.sub.5                                              
                     CH.sub.3  &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  OCF.sub.2 CF.sub.2 H                                                
             C.sub.2 H.sub.5                                              
                      ##STR110##                                          
                               H  H  H  COOCH.sub.3                       
                                              0                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR111##                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.2 CH.sub.2 CH.sub.3                                   
                     CH.sub.3  H  H  H  COOCH.sub.3                       
                                              0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR112##                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR113##                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.2 CH.sub.2 CH.sub.3                                   
                     CH.sub.2 CHCCl.sub.2                                 
                               H  H  H  COOCH.sub.3                       
                                              0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
N  &#34;  CF.sub.3                                                            
             CH.sub.3                                                     
                     CH.sub.3  &#34;  &#34;  &#34;  COOC.sub.2 H.sub.5                
                                              &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub. 3                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                      ##STR114##                                          
                               H  H  H  COOC.sub.2 H.sub.5                
                                              0                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR115##                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
N  H  CF.sub.3                                                            
             C.sub.2 H.sub.5                                              
                     CH.sub.3  H  H  H  COOC.sub.2 H.sub.5                
                                              0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR116##                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR117##                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
N  H  CF.sub.3                                                            
             C.sub.2 H.sub.5                                              
                     CH.sub.2 CHCCl.sub.2                                 
                               H  H  H  COOC.sub.2 H.sub.5                
                                              0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      CH.sub.2 CH.sub.2 CH.sub.3                                   
                     CH.sub.3  &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub. 3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
N  H  CF.sub.3                                                            
             CH.sub.2 CH.sub.2 CH.sub.3                                   
                      ##STR118##                                          
                               H  H  H  COOC.sub.2 H.sub.5                
                                              0                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR119##                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
N  H  CF.sub.3                                                            
             H       CH.sub.3  H  H  H  COOC.sub.2 H.sub.5                
                                              0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR120##                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR121##                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
N  H  CF.sub.3                                                            
             H       CH.sub.2 CHCCl.sub.2                                 
                               H  H  H  COOC.sub.2 H.sub.5                
                                              0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  Cl &#34;      CH.sub.3                                                     
                     CH.sub.3  &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                      ##STR122##                                          
                               H  H  H  COOC.sub.2 H.sub.5                
                                              0                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR123##                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C CH                                        
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
N  Cl CF.sub.3                                                            
             C.sub.2 H.sub.5                                              
                     CH.sub.3  H  H  H  COOC.sub.2 H.sub.5                
                                              0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR124##                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR125##                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub. 2 CHCHCl                                     
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
N  Cl CF.sub.3                                                            
             C.sub.2 H.sub.5                                              
                     CH.sub.2 CHCCl.sub.2                                 
                               H  H  H  COOC.sub.2 H.sub.5                
                                              0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      CH.sub.2 CH.sub.2 CH.sub.3                                   
                     CH.sub.3  &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.3                                    
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.3 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.4 CH.sub.3                            
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH(CH.sub.3).sub.2                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
N  Cl CF.sub.3                                                            
             CH.sub.2 CH.sub.2 CH.sub.3                                   
                      ##STR126##                                          
                               H  H  H  COOC.sub.2 H.sub.5                
                                              0                           
&#34;  &#34;  &#34;      &#34;                                                            
                      ##STR127##                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                                
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCHCl                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCCl.sub.2                                 
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CCH                                         
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CN                                          
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 OCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 SCH.sub.3                                   
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                             
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
CH F  CF.sub.3                                                            
             CH.sub.3                                                     
                     C.sub.2 H.sub.5                                      
                               H  H  H  H     0                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CH.sub.2 CH.sub.3                           
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      C.sub.2 H.sub.5                                              
                     C.sub.2 H.sub.5                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      CH.sub.2 CH.sub.2 CH.sub.3                                   
                     &#34;         &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  &#34;  &#34;      &#34;       CH.sub.2 CHCH.sub.2                                  
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
&#34;  Br &#34;      CH.sub.3                                                     
                     C.sub.2 H.sub.5                                      
                               &#34;  &#34;  &#34;  &#34;     &#34;                           
__________________________________________________________________________
 
    
     The compound represented by the general formula (I) can form a salt such as metal, ammonium and organic ammonium salt, which have a herbicidal activity. 
     The salt can be prepared by reacting a compound represented by the general formula (I) with potassium hydroxide or sodium hydroxide in solvent such as water, acetone and alcohol to form a potassium or sodium salt and following by reacting the potassium or sodium salt with another salt such as metal chloride, hydroxide, sulfate and nitrate. 
     The organic ammonium salt can be prepared by reacting a compound represented by the general formula (I) with organic ammonium hydroxide in solvent such as water, acetone and alcohol. 
     The organic ammonium salt includes a tetraalkylammonium salt, benzyltrialkylammonium salt, etc. 
    
    
     PRODUCTION EXAMPLE 1 
     0.6 Gram of 2-butyryl-5-[2-(5-trifluoromethyl-2-pyridylthio)ethyl]cyclohexane-1,3-dione was dissolved in a mixed solvent of 10 ml of ethanol and 1 ml of water, and 0.2 g of ethoxyamine hydrochloride and 0.07 g of sodium hydroxide were added to the resulting solution which was then stirred at room temperature for 2.5 hours. The reaction solution was poured into water, weakly acidified and extracted with ethyl acetate. After removing ethyl acetate, the residue was purified by thin layer chromatography (eluent, hexane:ethyl acetate=5:1) to obtain 0.45 g of 2-(1-ethoxyaminobutylidene)-5-[2-(5-trifluoromethyl-2-pyridylthio)ethyl]cyclohexane-1,3-dione. 
     n D   21 .5 : 1.5439. 
     Nuclear magnetic resonance spectrum (CDCl 3 ): δ (ppm) 14.58 (1H, s), 8.65 (1H, s), 7.65 (1H, dd), 7.23 (1H, d), 4.11 (2H, q), 3.25 (2H, t), 3.1-1.5 (11H, m), 1.29 (3H, t), 0.84 (3H, t). 
     PRODUCTION EXAMPLE 2 
     0.19 Gram of 2-propionyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione was dissolved in 5 ml of ethanol, and 0.07 g of allyloxyamine hydrochloride and 0.06 g of triethylamine were added to the resulting solution which was then stirred overnight at room temperature. The reaction solution was poured into water, acidified and extracted with chloroform. After removing chloroform, the residue was purified by thin layer chromatography (eluent, hexane:ethyl acetate=5:1) to obtain 0.13 g of 2-(1-allyloxyaminopropylidene)5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione. 
     n D   19 .5 : 1.5624. 
     Nuclear magnetic resonance spectrum (CDCl 3 ): δ (ppm) 14.63 (1H, s), 7.46 (4H, ABq), 6.35-5.71 (1H, m), 5.45 (2H, bd), 5.23 (1H, m), 4.54 (2H, d), 3.01 (2H, t), 3.0-1.5 (9H, m), 1.14 (3H, t). 
     PRODUCTION EXAMPLE 3 
     2.1 Grams of 2-acetyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione was dissolved in 10 ml of ethanol, and 0.71 g of ethoxyamine hydrochloride and 0.68 g of triethylamine were added to the resulting solution which was then stirred overnight at room temperature. The reaction solution was poured into water, acidified with dilute hydrochloric acid and extracted with chloroform. Chloroform was removed and the residue was purified by column chromatography on silica gel (eluent, ethyl acetate:hexane=1:5) to obtain 1.2 g of 2-(1-ethoxyaminoethylidene)-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione as white crystals. 
     m.p., 92°-93° C. 
     Nuclear magnetic resonance spectrum (CDCl 3 ): δ (ppm) 14.63 (1H, bs), 7.41 (4H, ABq), 4.09 (2H, q), 3.02 (2H, t), 2.36 (3H, s), 2.8-1.5 (7H, m), 1.31 (3H, t). 
     PRODUCTION EXAMPLE 4 
     0.19 Gram of 2-acetyl-5-[2-(4-trifluoromethoxyphenylthio)ethyl]cyclohexane-1,3-dione was dissolved in 10 ml of ethanol, and 0.07 g of ethoxyamine hydrochloride and 0.06 g of triethylamine were added to the resulting solution which was then stirred overnight at room temperature. The reaction solution was poured into water, acidified with dilute hydrochloric acid and extracted with chloroform. Chloroform was removed and the residue was purified by thin layer chromatography (eluent, hexane:ethyl acetate=5:1) to obtain 0.12 g of 2-(1-ethoxyaminoethylidene)-5 -[2-(4-trifluoromethoxyphenylthio)ethyl]cyclohexane-1,3-dione. 
     n D   26  : 1.5329. 
     Nuclear magnetic resonance spectrum (CDCl 3 ): δ (ppm) 7.22 (4H, ABq), 4.11 (2H, q), 3.05 (2H, t), 2.35 (3H, s), 2.8-1.5 (7H, m), 1.30 (3H, t), 15-14 (1H, br). 
     PRODUCTION EXAMPLE 5 
     0.21 Gram of 2-propionyl-5-[2-(4-α,α,β,β-tetrafluoroethoxyphenylthio)ethyl]cyclohexane-1,3-dione was dissolved in 10 ml of ethanol, and 0.06 g of ethoxyamine hydrochloride and 0.06 g of triethylamine were added to the resulting solution which was then stirred overnight at room temperature. The reaction solution was poured into water, acidified with dilute hydrochloric acid and extracted with chloroform. Chloroform was removed and the residue was purified by thin layer chromatography (developing solvent, hexane:ethyl acetate=5:1) to obtain 0.07 g of 2-(1-ethoxyaminopropylidene)-5-[2-(4-α,α,β,β-tetrafluoroethoxyphenylthio)ethyl]cyclohexane-1,3-dione. 
     n D   24  : 1.5119 
     Nuclear magnetic resonance spectrum (CDCl 3 ): δ (ppm) 7.28 (4H, ABq), 5.92 (1H, tt, J=54 Hz, 3 Hz), 4.13 (2H, q), 3.1-1.5 (9H, m), 1.31 (3H, t), 1.13 (3H, t), 15-14 (1H, br). 
     PRODUCTION EXAMPLE 6 
     0.27 Gram of 2-propionyl-5-[2-(4-trifluoromethylphenylthio)propyl]cyclohexane-1,3-dione was dissolved in 10 ml of ethyl acetate, and 0.08 g of ethoxyamine hydrochloride and 0.1 g of N,N-diethylaniline were added to the resulting solution which was then refluxed for 5 hours. The reaction solution was cooled to room temperature, poured into water, weakly acidified and extracted with ethyl acetate. The ethyl acetate layer was washed with dilute hydrochloric acid and water subsequently and dried over anhydrous magnsium sulfate. After removing ethyl acetate, the residue was purified by thin layer chromatography (eluent, hexane:ethyl acetate=5:1) to obtain 0.13 g of 2-(1-ethoxyaminopropylidene)-5-[2-(4-trifluoromethylphenylthio)propyl]cyclohexane-1,3-dione. 
     n D   24  : 1.5293. 
     Nuclear magnetic resonance spectrum (CDCl 3 ): δ (ppm) 15-14 (1H, br), 7.45 (4H, brs), 4.10 (2H, q), 3.32 (1H, m), 2.7-1.5 (9H, m), 1.35 (3H, d), 1.31 (3H, t), 1.14 (3H, t). 
     PRODUCTION EXAMPLE 7 
     0.4 Gram of 2-acetyl-5-[1-methyl-2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione and 0.1 g of ethoxyamine hydrochloride were dissolved in 10 ml of methanol and 0.15 g of potassium carbonate was added to the resulting solution which was then refluxed for 3 hours. The reaction solution was poured into water and extracted with chloroform. After removing chloroform, the residue was purified by thin layer chromatography (eluent, hexane:ethyl acetate=5:1) to obtain 0.3 g of 2-(1-ethoxyaminoethylidene)-5-[1-methyl-2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione. 
     n D   25 .5 : 1.5145. 
     Nuclear magnetic resonance spectrum (CDCl 3 ): δ (ppm) 15-14 (1H, br), 7.39 (4H, ABq), 4.11 (2H, q), 3.0-1.5 (6H, m), 2.93 (2H, t), 2.34 (3H, s), 1.30 (3H, t), 1.12 (3H, d). 
     PRODUCTION EXAMPLE 8 
     To the suspension of 0.3 g of sodium hydride (60% oil dispersion) in 10 ml of dimethylformamide, 0.09 g of 2-butenyloxyamine hydrochloride was added under cooling with ice-water bath and then stirred. After 30 minutes, 0.21 g of 2-acetyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione was added to the resulting solution which was then stirred for 7 hours under cooling with ice-water bath. The reaction solution was poured into water, acidified with dilute hydrochloric acid and extracted with ether. After removing ether, the residue was purified by thin layer chromatography (eluent, hexane:ethyl acetate=5:1) to obtain 0.22 g of 2-[1-(2-butenyloxyamino)ethylidene]5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione. 
     m.p. 72°-73° C. 
     Nuclear magnetic resonance (CDCl 3 ): δ (ppm) 15-14 (1H, br), 7.35 (4H, ABq), 5.55 (2H, m), 4.35 (2H, d), 2.91 (2H, t), 2.5-1.5 (7H, m), 2.34 (3H, s), 1.7 (3H, brd). 
     PRODUCTION EXAMPLE 9 
     0.2 Gram of 2-propionyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione was dissolved in 10 ml of chloroform and 0.07 g of propoxyamine hydrochloride and 0.5 ml of pyridine were added to the resulting solution which was then stirred at 50°-60° C. for 5 hours. The reaction solution was poured into water, acidified with dilute hydrochloric acid and extracted with chloroform. After removing chloroform, the residue was purified by thin layer chromatography (eluent, hexane:ethyl acetate=5:1) to obtain 0.11 g of 2-(1-propoxyaminopropylidene)-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione. 
     n D   24  : 1.5376. 
     Nuclear magnetic resonance spectrum (CDCl 3 ): δ (ppm) 15-14 (1H, br), 7.43 (4H, ABq), 4.00 (2H, t), 3.2-1.5 (13H, m), 1.15 (3H, t), 0.99 (3H, t). 
     Some of the present compounds produced by the methods described above will be shown in Table 2. 
     
                                           TABLE 2                                 
__________________________________________________________________________
General formula:                                                          
 ##STR128##                                                               
Compound                                               Physical           
No.    X  Y Z      R.sup.1 R.sup.2   R.sup.3                              
                                        R.sup.4                           
                                           R.sup.5                        
                                              R.sup.6                     
                                                    n  properties         
__________________________________________________________________________
 1     CH H CF.sub.3                                                      
                   CH.sub.3                                               
                           CH.sub.3  H  H  H  H     0  mp 76-77°   
                                                       C.                 
 2     &#34;  &#34; &#34;      &#34;       C.sub.2 H.sub.5                                
                                     &#34;  &#34;  &#34;  &#34;     &#34;  mp 92-93°   
                                                       C.                 
 3     &#34;  &#34; &#34;      &#34;       n-C.sub.3 H.sub.7                              
                                     &#34;  &#34;  &#34;  &#34;     &#34;  mp 91-92°   
                                                       C.                 
 4     &#34;  &#34; &#34;      &#34;       n-C.sub.4 H.sub.9                              
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5092             
 5     &#34;  &#34; &#34;      &#34;       n-C.sub.5 H.sub.11                             
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5265             
 6     &#34;  &#34; &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                     
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.23     
                                                       1.5322             
 7     &#34;  &#34; &#34;      &#34;       CH(CH.sub.3).sub.2                             
                                     &#34;  &#34;  &#34;  &#34;     &#34;  mp 94-95°   
                                                       C.                 
 8     &#34;  &#34; &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                    
                                     &#34;  &#34;  &#34;  &#34;     &#34;  mp 76-77°   
                                                       C.                 
 9     &#34;  &#34; &#34;      &#34;                                                      
                            ##STR129##                                    
                                     &#34;  &#34;  &#34;  &#34;     &#34;  mp 86-87°   
                                                       C.                 
10     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCH.sub.2                            
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5165             
11     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                          
                                     &#34;  &#34;  &#34;  &#34;     &#34;  mp 72-73°   
                                                       C.                 
12     CH H CF.sub.3                                                      
                   CH.sub.3                                               
                           CH.sub.2 CHCHCl                                
                                     H  H  H  H     0  n.sub.D.sup.23.5   
                                                       1.5572             
13     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCCl.sub.2                           
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24.5   
                                                       1.5519             
14     &#34;  &#34; &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                   
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.22.5   
                                                       1.5450             
15     &#34;  &#34; &#34;      &#34;       CH.sub.2 CCH                                   
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5516             
16     &#34;  &#34; &#34;      &#34;       CH.sub.2 CN                                    
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5276             
17     &#34;  &#34; &#34;      &#34;       CH.sub.2 OCH.sub.3                             
                                     &#34;  &#34;  &#34;  &#34;     &#34;  mp                 
                                                       86.5-87.5°  
                                                       C.                 
18     &#34;  &#34; &#34;      &#34;       CH.sub.2 SCH.sub.3                             
                                     &#34;  &#34;  &#34;  &#34;     &#34;  mp 80-81°   
                                                       C.                 
19     &#34;  &#34; &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                       
                                     &#34;  &#34;  &#34;  &#34;     &#34;  mp 72-73°   
                                                       C.                 
20     &#34;  &#34; &#34;      &#34;       C.sub.2 H.sub.5                                
                                     &#34;  &#34;  CH.sub.3                       
                                              &#34;     &#34;  n.sub.D.sup.23     
                                                       1.5181             
21     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCH.sub.2                            
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.23     
                                                       1.5276             
22     &#34;  &#34; &#34;      &#34;       C.sub.2 H.sub.5                                
                                     &#34;  &#34;  H  &#34;     1  mp 103-104° 
                                                       C.                 
23     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCH.sub.2                            
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.22.5   
                                                       1.5384             
24     &#34;  &#34; &#34;      &#34;       C.sub.2 H.sub.5                                
                                     &#34;  &#34;  &#34;  &#34;     2  mp 120-121° 
                                                       C.                 
25     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCH.sub.2                            
                                     &#34;  &#34;  &#34;  &#34;     &#34;  mp 117-118° 
                                                       C.                 
26     CH H CF.sub.3                                                      
                   CH.sub.3                                               
                           C.sub.2 H.sub.5                                
                                     CH.sub.3                             
                                        H  H  H     0  n.sub.D.sup.24     
                                                       1.5347             
27     &#34;  &#34; &#34;      &#34;       n-C.sub.3 H.sub.7                              
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5336             
28     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCH.sub.2                            
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5372             
29     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCHCl                                
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5461             
30     &#34;  &#34; &#34;      &#34;       C.sub.2 H.sub.5                                
                                     H  CH.sub.3                          
                                           &#34;  &#34;     &#34;  n.sub.D.sup.25.5   
                                                       1.5371             
31     &#34;  &#34; &#34;      &#34;       n-C.sub.3 H.sub.7                              
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.25.5   
                                                       1.5145             
32     &#34;  &#34; &#34;      C.sub.2 H.sub.5                                        
                           CH.sub.3  &#34;  H  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5426             
33     &#34;  &#34; &#34;      &#34;       C.sub.2 H.sub.5                                
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.22     
                                                       1.5333             
34     &#34;  &#34; &#34;      &#34;       n-C.sub.3 H.sub.7                              
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5376             
35     &#34;  &#34; &#34;      &#34;       n-C.sub.4 H.sub.9                              
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5058             
36     &#34;  &#34; &#34;      &#34;       n-C.sub.5 H.sub.11                             
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5251             
37     &#34;  &#34; &#34;      &#34;       (CH.sub.2).sub.11 CH.sub.3                     
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.23     
                                                       1.5325             
38     &#34;  &#34; &#34;      &#34;       CH(CH.sub.3).sub.2                             
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.23     
                                                       1.5328             
39     &#34;  &#34; &#34;      &#34;       CH.sub.2 CH(CH.sub.3).sub.2                    
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.23     
                                                       1.5465             
40     &#34;  &#34; &#34;      &#34;                                                      
                            ##STR130##                                    
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5456             
41     CH H CF.sub.3                                                      
                   C.sub.2 H.sub.5                                        
                           CH.sub.2 CHCH.sub.2                            
                                     H  H  H  H     0  n.sub.D.sup.19.5   
                                                       1.5399             
42     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                          
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.21.5   
                                                       1.5344             
43     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCHCl                                
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5416             
44     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCCl.sub.2                           
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5549             
45     &#34;  &#34; &#34;      &#34;       CH.sub.2 CH.sub.2 CHCH.sub.2                   
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.23     
                                                       1.5365             
46     &#34;  &#34; &#34;      &#34;       CH.sub.2 CCH                                   
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5499             
47     &#34;  &#34; &#34;      &#34;       CH.sub.2 CN                                    
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5276             
48     &#34;  &#34; &#34;      &#34;       CH.sub.2 OCH.sub.3                             
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.21.5   
                                                       1.5352             
49     &#34;  &#34; &#34;      &#34;       CH.sub.2 SCH.sub.3                             
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5616             
50     &#34;  &#34; &#34;      &#34;       CH.sub.2 C.sub.6 H.sub.5                       
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5697             
51     &#34;  &#34; &#34;      &#34;       C.sub.2 H.sub.5                                
                                     CH.sub.3                             
                                        &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5293             
52     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCH.sub.2                            
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5249             
53     &#34;  &#34; &#34;      n-C.sub.3 H.sub.7                                      
                           CH.sub.3  H  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5391             
54     &#34;  &#34; &#34;      &#34;       C.sub.2 H.sub.5                                
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5345             
55     &#34;  &#34; &#34;      &#34;       n-C.sub.3 H.sub.7                              
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5320             
56     CH H CF.sub.3                                                      
                   n-C.sub.3 H.sub.7                                      
                           CH.sub.2 CHCH.sub.2                            
                                     H  H  H  H     0  n.sub.D.sup.19.5   
                                                       1.5402             
57     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCHCl                                
                                     &#34;  &#34;  &#34;  &#34;     0  n.sub.D.sup.25.5   
                                                       1.5152             
58     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCCl.sub.2                           
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5605             
59     &#34;  &#34; &#34;      &#34;       C.sub.2 H.sub.5                                
                                     CH.sub.3                             
                                        &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5229             
60     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCH.sub.2                            
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5298             
61     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                          
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5263             
62     &#34;  &#34; &#34;      CH(CH.sub.3).sub.2                                     
                           C.sub.2 H.sub.5                                
                                     H  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5278             
63     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                          
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5282             
64     &#34;  &#34; &#34;      CH.sub.2 CH(CH.sub.3).sub.2                            
                           CH.sub.3  &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5295             
65     &#34;  &#34; &#34;      &#34;       C.sub.2 H.sub.5                                
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5351             
66     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                          
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5306             
67     &#34;  &#34; &#34;      CH.sub.2 OCH.sub.3                                     
                           C.sub.2 H.sub.5                                
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.22     
                                                       1.5286             
68     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCH.sub.2                            
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.22     
                                                       1.5461             
69     &#34;  &#34; OCF.sub.3                                                     
                   CH.sub.3                                               
                           CH.sub.3  &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.26     
                                                       1.5376             
70     &#34;  &#34; &#34;      &#34;       C.sub.2 H.sub.5                                
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.26     
                                                       1.5329             
71     CH H OCF.sub.3                                                     
                   CH.sub.3                                               
                           n-C.sub.3 H.sub.7                              
                                     H  H  H  H     0  mp 57-58°   
                                                       C.                 
72     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCH.sub.2                            
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.26     
                                                       1.5406             
73     &#34;  &#34; &#34;      C.sub.2 H.sub.5                                        
                           CH.sub.3  &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.27.5   
                                                       1.5337             
74     &#34;  &#34; &#34;      &#34;       C.sub.2 H.sub.5                                
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.27.5   
                                                       1.5226             
75     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCH.sub.2                            
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.27.5   
                                                       1.5308             
76     &#34;  &#34; &#34;      n-C.sub.3 H.sub.7                                      
                           CH.sub.3  &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.26     
                                                       1.5059             
77     &#34;  &#34; &#34;      &#34;       C.sub.2 H.sub.5                                
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.26     
                                                       1.5196             
78     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCH.sub.2                            
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.26     
                                                       1.5283             
79     &#34;  &#34; OCF.sub.2 CF.sub.2 H                                          
                   CH.sub.3                                               
                           C.sub.2 H.sub.5                                
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24.5   
                                                       1.5244             
80     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCH.sub.2                            
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24.5   
                                                       1.5213             
81     &#34;  &#34; &#34;      C.sub.2 H.sub.5                                        
                           C.sub.2 H.sub.5                                
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5119             
82     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCH.sub.2                            
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5286             
83     &#34;  &#34; &#34;      n-C.sub.3 H.sub.7                                      
                           C.sub.2 H.sub.5                                
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5185             
84     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCH.sub.2                            
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5248             
85     N  &#34; CF.sub.3                                                      
                   CH.sub.3                                               
                           CH.sub.3  &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.22     
                                                       1.5402             
86     N  H CF.sub.3                                                      
                   CH.sub.3                                               
                           C.sub.2 H.sub.5                                
                                     H  H  H  H     0  n.sub.D.sup.22     
                                                       1.5518             
87     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCH.sub.2                            
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.21     
                                                       1.5405             
88     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCHCl                                
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.22     
                                                       1.5552             
89     &#34;  &#34; &#34;      C.sub.2 H.sub.5                                        
                           C.sub.2 H.sub.5                                
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.26     
                                                       1.5374             
90     &#34;  &#34; &#34;      &#34;       n-C.sub.3 H.sub.7                              
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.23     
                                                       1.5302             
91     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCH.sub.2                            
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.20     
                                                       1.5298             
92     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                          
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.20     
                                                       1.5271             
93     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCHCl                                
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.20     
                                                       1.5386             
94     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCCl.sub.2                           
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.23     
                                                       1.5175             
95     &#34;  &#34; &#34;      &#34;       CH.sub.2 C CH                                  
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.21     
                                                       1.5378             
96     &#34;  &#34; &#34;      &#34;       CH.sub.2 OCH.sub.3                             
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.21     
                                                       1.5172             
97     &#34;  &#34; &#34;      n-C.sub.3 H.sub.7                                      
                           CH.sub.3  &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.21     
                                                       1.5372             
98     &#34;  &#34; &#34;      &#34;       C.sub.2 H.sub.5                                
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.21.5   
                                                       1.5239             
99     &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCH.sub.2                            
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.21.5   
                                                       1.5331             
100    &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                          
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.21     
                                                       1.5361             
101    N  H CF.sub.3                                                      
                   n-C.sub.3 H.sub.7                                      
                           CH.sub.2 CHCHCl                                
                                     H  H  H  H     0  n.sub.D.sup.20     
                                                       1.5432             
102    &#34;  &#34; &#34;      &#34;       CH.sub.2 CCH                                   
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.20     
                                                       1.5517             
103    &#34;  &#34; &#34;      &#34;       CH.sub.2 CN                                    
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.20     
                                                       1.5192             
104    &#34;  &#34; &#34;      &#34;       CH.sub.2 OCH.sub.3                             
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.21     
                                                       1.5212             
105    &#34;  Cl                                                              
            &#34;      C.sub.2 H.sub.5                                        
                           CH.sub.2 CHCH.sub.2                            
                                     &#34;  &#34;  &#34;  &#34;     &#34;  mp 64-65°   
                                                       C.                 
106    &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCHCH.sub.3                          
                                     &#34;  &#34;  &#34;  &#34;     &#34;  mp 58-59°   
                                                       C.                 
107    &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCHCl                                
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.20     
                                                       1.5472             
108    &#34;  Cl                                                              
            &#34;      n-C.sub.3 H.sub.7                                      
                           CH.sub.2 CHCH.sub.2                            
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.19     
                                                       1.5287             
109    &#34;  H &#34;      CH.sub.2 OCH.sub.3                                     
                           CH.sub.2 CHCH.sub.2                            
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.20     
                                                       1.5397             
110    &#34;  &#34; &#34;      &#34;       CH.sub.2 CHCHCl                                
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.26     
                                                       1.5269             
111*   CH &#34; &#34;      CH.sub.3                                               
                           C.sub.2 H.sub.5                                
                                     &#34;  &#34;  &#34;  &#34;     &#34;  mp 175-178° 
                                                       C.                 
                                                       (dec.)             
112*   &#34;  &#34; &#34;      &#34;       &#34;         &#34;  &#34;  &#34;  &#34;     &#34;  mp 144-146° 
                                                       C.                 
                                                       (dec.)             
113*   &#34;  &#34; &#34;      &#34;       &#34;         &#34;  &#34;  &#34;  &#34;     &#34;  mp 182-185° 
                                                       C.                 
                                                       (dec.)             
114*   CH H CF.sub.3                                                      
                   CH.sub.3                                               
                           C.sub.2 H.sub.5                                
                                     H  H  H  H     0  mp 72-73°   
                                                       C.                 
115*   &#34;  &#34; &#34;      &#34;       &#34;         &#34;  &#34;  &#34;  &#34;     &#34;  mp 232-235° 
                                                       C.                 
                                                       (dec.)             
116*   &#34;  &#34; &#34;      &#34;       &#34;         &#34;  &#34;  &#34;  &#34;     &#34;  mp 58-61°   
                                                       C.                 
117    &#34;  &#34; &#34;      &#34;       &#34;         &#34;  &#34;  &#34;  COOCH.sub.3                 
                                                    &#34;  n.sub.D.sup.23.5   
                                                       1.5376             
118    &#34;  &#34; &#34;      C.sub.2 H.sub.5                                        
                           &#34;         &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5339             
119    &#34;  &#34; &#34;      n-C.sub.3 H.sub.7                                      
                           &#34;         &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5186             
120    &#34;  &#34; OCF.sub.3                                                     
                   CH.sub.3                                               
                           &#34;         &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.20.5   
                                                       1.5291             
121    &#34;  &#34; &#34;      &#34;       n-C.sub.3 H.sub.7                              
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.20.5   
                                                       1.5283             
122    &#34;  &#34; &#34;      C.sub. 2 H.sub.5                                       
                           C.sub.2 H.sub.5                                
                                     &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.20.5   
                                                       1.5301             
123    &#34;  &#34; CF.sub.3                                                      
                   &#34;       &#34;         CH.sub.3                             
                                        &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.25     
                                                       1.5212             
124    &#34;  &#34; &#34;      &#34;       &#34;         &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.25     
                                                       1.5087             
125    &#34;  &#34; &#34;      CH.sub.3                                               
                           &#34;         H  CH.sub.3                          
                                           &#34;  &#34;     &#34;  n.sub.D.sup.25.5   
                                                       1.5209             
126    &#34;  &#34; &#34;      C.sub.2 H.sub.5                                        
                           &#34;         &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.25.5   
                                                       1.5198             
127    &#34;  &#34; &#34;      CH.sub.3                                               
                           CH.sub.2 CHCH.sub.2                            
                                     &#34;  H  &#34;  &#34;     &#34;  n.sub.D.sup.23.5   
                                                       1.5347             
128    CH H CF.sub.3                                                      
                   C.sub.2 H.sub.5                                        
                           CH.sub.2 CHCH.sub.3                            
                                     H  H  H  COOCH.sub.3                 
                                                    0  n.sub.D.sup.24     
                                                       1.5315             
129    &#34;  &#34; &#34;      n-C.sub.3 H.sub.7                                      
                           &#34;         &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.24     
                                                       1.5291             
130    &#34;  &#34; OCF.sub.3                                                     
                   CH.sub.3                                               
                           &#34;         &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.20.5   
                                                       1.5341             
131    &#34;  &#34; &#34;      C.sub.2 H.sub.5                                        
                           &#34;         &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.20.5   
                                                       1.5329             
132    &#34;  &#34; CF.sub.3                                                      
                   CH.sub.3                                               
                           &#34;         CH.sub.3                             
                                        &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.25     
                                                       1.5268             
133    &#34;  &#34; &#34;      C.sub.2 H.sub.5                                        
                           &#34;         &#34;  &#34;  &#34;  &#34;     &#34;  n.sub.D.sup.25     
                                                       1.5208             
134    N  &#34; &#34;      &#34;       C.sub.2 H.sub.5                                
                                     H  H  H  COOC.sub.2 H.sub.5          
                                                    &#34;  n.sub.D.sup.20     
                                                       1.5423             
135    CH F &#34;      CH.sub.3                                               
                           &#34;         &#34;  &#34;  &#34;  H     &#34;  n.sub.D.sup.25     
                                                       1.5311             
__________________________________________________________________________
 *111 sodium salt                                                         
 *112 copper salt                                                         
 *113 calcium salt                                                        
 *114 tetrapropylammonium salt hydrate                                    
 *115 lithium salt                                                        
 *116 benzyltrimethylammonium salt hydrate                                
 
    
     Acylcyclohexane, a material, represented by the general formula (II) is produced, for example, by a series of reactions described below: ##STR131## wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , X, Y and Z are as defined above, R 7  is a (C 1  -C 4 )alkyl group and R 8  is a (C 1  -C 4 )-alkyl group. 
     The compound represented by the general formula (VI) is produced by reacting 1 mole of a thiol (IV) with 1 to 1.2 moles of an α,β-unsaturated aldehyde (V) without a solvent or in an inert solvent and under heating or cooling in the presence of a catalyst. The reaction temperature is from 0° C. to the boiling point of the solvent used, preferably from 0° C. to room temperature in the presence of a catalyst. For the catalyst, bases such as triethylamine, alkoxides, etc. are used in an amount of from 0.05 to 0.005 mole equivalent. The solvent includes organic solvents such as alcohol, diethyl ether, tetrahydrofuran (THF), benzene, toluene, chloroform, ethyl acetate, etc. The reaction time is generally from 30 minutes to several hours, and after completion of the reaction, water is added to the reaction solution which is then extracted with an organic solvent. The desired product obtained may be purified if necessary by recrystallization or column chromatography. 
     Examples of the compound of the general formula (VI) thus obtained are shown in Table 3. 
     
                       TABLE 3                                                     
______________________________________                                    
Compounds of the                                                          
general formula (VI):                                                     
 ##STR132##                                                               
X         Y       Z            R.sup.3                                    
                                      R.sup.4                             
______________________________________                                    
CH        H       CF.sub.3     H      H                                   
CH        H       CF.sub.3     CH.sub.3                                   
                                      H                                   
CH        H       CF.sub.3     H      CH.sub.3                            
CH        H       CF.sub.3     CH.sub.3                                   
                                      CH.sub.3                            
CH        H       OCF.sub.3    H      H                                   
CH        H       OCF.sub.3    CH.sub.3                                   
                                      H                                   
CH        H       OCF.sub.3    H      CH.sub.3                            
CH        H       OCF.sub.3    CH.sub.3                                   
                                      CH.sub.3                            
CH        H       OCF.sub.2 CF.sub.2 H                                    
                               H      H                                   
CH        H       OCF.sub.2 CF.sub.2 H                                    
                               CH.sub.3                                   
                                      H                                   
CH        H       OCF.sub.2 CF.sub.2 H                                    
                               H      CH.sub.3                            
CH        H       OCF.sub.2 CF.sub.2 H                                    
                               CH.sub.3                                   
                                      CH.sub.3                            
N         H       CF.sub.3     H      H                                   
N         H       CF.sub.3     CH.sub.3                                   
                                      H                                   
N         H       CF.sub.3     H      CH.sub.3                            
N         H       CF.sub.3     CH.sub.3                                   
                                      CH.sub.3                            
N         Cl      CF.sub.3     H      H                                   
N         Cl      CF.sub.3     CH.sub.3                                   
                                      H                                   
N         Cl      CF.sub.3     H      CH.sub.3                            
N         Cl      CF.sub.3     CH.sub.3                                   
                                      CH.sub.3                            
______________________________________                                    
 
    
     The compound represented by the general formula (VII) is produced by reacting 1 mole of the aldehyde compound (VI) with 1 to 1.1 moles of Wittig reagent represented by the formula, ##STR133## in an inert solvent. The reaction temperature is from 0° C. to the boiling point of the solvent used, preferably from 0° C. to room temperature. The reaction solvent includes organic solvents such as diethyl ether, THF, benzene, toluene, chloroform, dichloromethane, ethyl acetate, etc., and preferably solvents of high solubility such as THF, chloroform, ethyl acetate, etc. are used. The reaction time is generally from 1 to 10 hours, and after completion of the reaction, the solvent is removed and the residue is extracted with a solvent such as hexane, ether, etc. The desired product thus extracted may be purified if necessary by recrystallization or column chromatography. 
     Examples of the compound of the general formula (VII) thus obtained are shown in Table 4. 
     
                       TABLE 4                                                     
______________________________________                                    
Compounds of the                                                          
general formula (VII):                                                    
 ##STR134##                                                               
X         Y       Z            R.sup.3                                    
                                      R.sup.4                             
______________________________________                                    
CH        H       CF.sub.3     H      H                                   
CH        H       CF.sub.3     CH.sub.3                                   
                                      H                                   
CH        H       CF.sub.3     H      CH.sub.3                            
CH        H       CF.sub.3     CH.sub.3                                   
                                      CH.sub.3                            
CH        H       OCF.sub.3    H      H                                   
CH        H       OCF.sub.3    H      CH.sub.3                            
CH        H       OCF.sub.3    CH.sub.3                                   
                                      H                                   
CH        H       OCF.sub.3    CH.sub.3                                   
                                      CH.sub.3                            
CH        H       OCF.sub.2 CF.sub.2 H                                    
                               H      H                                   
CH        H       OCF.sub.2 CF.sub.2 H                                    
                               CH.sub.3                                   
                                      H                                   
CH        H       OCF.sub.2 CF.sub.2 H                                    
                               H      CH.sub.3                            
CH        H       OCF.sub.2 CF.sub.2 H                                    
                               CH.sub.3                                   
                                      CH.sub.3                            
N         H       CF.sub.3     H      H                                   
N         H       CF.sub.3     CH.sub.3                                   
                                      H                                   
N         H       CF.sub.3     H      CH.sub.3                            
N         H       CF.sub.3     CH.sub.3                                   
                                      CH.sub.3                            
N         Cl      CF.sub.3     H      H                                   
N         Cl      CF.sub.3     CH.sub.3                                   
                                      H                                   
N         Cl      CF.sub.3     H      CH.sub.3                            
N         Cl      CF.sub.3     CH.sub.3                                   
                                      CH.sub.3                            
______________________________________                                    
 
    
     The compound represented by the general formula (IX) is produced by reacting 1 mole of the α,β-unsaturated ketone (VII) with 1 to 1.1 moles of dialkyl malonate in the presence of 1 mole of a metal alkoxide and in alcohol or a mixed solvent of alcohol and an inert solvent. The reaction temperature is generally the boiling point of the solvent used. The reaction solvent includes a mixed solvent of an alcohol (e.g. methanol, ethanol) with THF or dioxane and a mixed solvent of an alcohol with benzene or toluene, among which a mixed solvent of methanol with THF is preferably used. The reaction time is generally from 30 minutes to several hours. After completion of the reaction, the precipitated crystals are collected by filtration to obtain the desired compound as a metal salt. 
     Examples of the compound of the general formula (IX) thus obtained are shown in Table 5. 
     
                       TABLE 5                                                     
______________________________________                                    
Compounds of the                                                          
general formula (IX):                                                     
 ##STR135##                                                               
X     Y      Z           R.sup.3                                          
                               R.sup.4                                    
                                    R.sup.5                               
                                         R.sup.6                          
______________________________________                                    
CH    H      CF.sub.3    H     H    H    COOCH.sub.3                      
CH    H      CF.sub.3    H     CH.sub.3                                   
                                    &#34;    COOC.sub.2 H.sub.5               
CH    H      CF.sub.3    CH.sub.3                                         
                               H    &#34;    &#34;                                
CH    H      CF.sub.3    CH.sub.3                                         
                               CH.sub.3                                   
                                    &#34;    &#34;                                
CH    H      OCF.sub.3   H     H    &#34;    &#34;                                
CH    H      OCF.sub.3   CH.sub.3                                         
                               H    &#34;    &#34;                                
CH    H      OCF.sub.3   H     CH.sub.3                                   
                                    &#34;    COOCH.sub.3                      
CH    H      OCF.sub.3   CH.sub.3                                         
                               CH.sub.3                                   
                                    &#34;    &#34;                                
CH    H      OCF.sub.2 CF.sub.2 H                                         
                         H     H    &#34;    &#34;                                
CH    H      OCF.sub.2 CF.sub.2 H                                         
                         CH.sub.3                                         
                               H    &#34;    &#34;                                
CH    H      OCF.sub.2 CF.sub.2 H                                         
                         H     CH.sub.3                                   
                                    &#34;    &#34;                                
CH    H      OCF.sub.2 CF.sub.2 H                                         
                         CH.sub.3                                         
                               CH.sub.3                                   
                                    &#34;    &#34;                                
N     H      CF.sub.3    H     H    &#34;    &#34;                                
N     H      CF.sub.3    CH.sub.3                                         
                               H    &#34;    &#34;                                
N     H      CF.sub.3    H     CH.sub.3                                   
                                    &#34;    &#34;                                
N     H      CF.sub.3    CH.sub.3                                         
                               CH.sub.3                                   
                                    &#34;    &#34;                                
N     Cl     CF.sub.3    H     H    &#34;    &#34;                                
N     Cl     CF.sub.3    CH.sub.3                                         
                               H    &#34;    COOC.sub.2 H.sub.5               
N     Cl     CF.sub.3    H     CH.sub.3                                   
                                    &#34;    &#34;                                
N     Cl     CF.sub.3    CH.sub.3                                         
                               CH.sub.3                                   
                                    &#34;    &#34;                                
CH    H      CF.sub.3    H     H    CH.sub.3                              
                                         COOC.sub.2 H.sub.5               
CH    H      CF.sub.3    H     CH.sub.3                                   
                                    &#34;    &#34;                                
CH    H      CF.sub.3    CH.sub.3                                         
                               H    &#34;    &#34;                                
CH    H      CF.sub.3    CH.sub.3                                         
                               CH.sub.3                                   
                                    &#34;    COOCH.sub.3                      
CH    H      OCF.sub.3   H     H    &#34;    &#34;                                
CH    H      OCF.sub.3   CH.sub.3                                         
                               H    &#34;    &#34;                                
CH    H      OCF.sub.3   H     CH.sub.3                                   
                                    &#34;    &#34;                                
CH    H      OCF.sub.3   CH.sub.3                                         
                               CH.sub.3                                   
                                    &#34;    &#34;                                
CH    H      OCF.sub.2 CF.sub.2 H                                         
                         H     H    &#34;    &#34;                                
CH    H      OCF.sub.2 CF.sub.2 H                                         
                         CH.sub.3                                         
                               H    &#34;    COOC.sub.2 H.sub.5               
CH    H      OCF.sub.2 CF.sub.2 H                                         
                         H     CH.sub.3                                   
                                    &#34;    &#34;                                
CH    H      OCF.sub.2 CF.sub.2 H                                         
                         CH.sub.3                                         
                               CH.sub.3                                   
                                    &#34;    &#34;                                
N     H      CF.sub.3    H     H    &#34;    &#34;                                
N     H      CF.sub.3    CH.sub.3                                         
                               H    &#34;    &#34;                                
N     H      CF.sub.3    H     CH.sub.3                                   
                                    &#34;    &#34;                                
N     H      CF.sub.3    CH.sub.3                                         
                               CH.sub.3                                   
                                    &#34;    &#34;                                
N     Cl     CF.sub.3    H     H    &#34;    &#34;                                
N     Cl     CF.sub.3    CH.sub.3                                         
                               H    &#34;    COOCH.sub.3                      
N     Cl     CF.sub.3    H     CH.sub.3                                   
                                    &#34;    &#34;                                
N     Cl     CF.sub.3    CH.sub.3                                         
                               CH.sub.3                                   
                                    &#34;    &#34;                                
______________________________________                                    
 
    
     The compound represented by the general formula (X) is obtained by hydrolyzing the metal salt of the compound represented by the general formula (IX) in water using from 1 to 5 equivalents of an alkali, followed by decarboxylation. The reaction temperature is generally from 90° to 100° C. The alkali used includes potassium hydroxide, sodium hydroxide, potassium carbonate, sodium carbonate, etc., and preferably, from 2 to 3 equivalents of sodium carbonate is used. The reaction time is from 1 to several hours. After completion of the reaction, the reaction solution is acidified with hydrochloric acid, and the separated oily product or precipitated crystals are extracted with an organic solvent or filtered off to obtain the desired product. The product may be purified if necessary by recrystallization or column chromatography. 
     Examples of the compound of the general formula (X) thus obtained are shown in Table 6. 
     
                       TABLE 6                                                     
______________________________________                                    
Compounds of the                                                          
general formula (X):                                                      
 ##STR136##                                                               
X       Y       Z           R.sup.3                                       
                                   R.sup.4                                
                                        R.sup.5                           
______________________________________                                    
CH      H       CF.sub.3    H      H    H                                 
CH      H       CF.sub.3    CH.sub.3                                      
                                   H    &#34;                                 
CH      H       CF.sub.3    H      CH.sub.3                               
                                        &#34;                                 
CH      H       CF.sub.3    CH.sub.3                                      
                                   CH.sub.3                               
                                        &#34;                                 
CH      H       OCF.sub.3   H      H    &#34;                                 
CH      H       OCF.sub.3   CH.sub.3                                      
                                   H    &#34;                                 
CH      H       OCF.sub.3   H      CH.sub.3                               
                                        &#34;                                 
CH      H       OCF.sub.3   CH.sub.3                                      
                                   CH.sub.3                               
                                        &#34;                                 
CH      H       OCF.sub.2 CF.sub.2 H                                      
                            H      H    &#34;                                 
CH      H       OCF.sub.2 CF.sub.2 H                                      
                            CH.sub.3                                      
                                   H    &#34;                                 
CH      H       OCF.sub.2 CF.sub.2 H                                      
                            H      CH.sub.3                               
                                        &#34;                                 
CH      H       OCF.sub.2 CF.sub.2 H                                      
                            CH.sub.3                                      
                                   CH.sub.3                               
                                        &#34;                                 
N       H       CF.sub. 3   H      H    &#34;                                 
N       H       CF.sub.3    CH.sub.3                                      
                                   H    &#34;                                 
N       H       CF.sub.3    H      CH.sub.3                               
                                        &#34;                                 
N       H       CF.sub.3    CH.sub.3                                      
                                   CH.sub.3                               
                                        &#34;                                 
N       Cl      CF.sub.3    H      H    &#34;                                 
N       Cl      CF.sub.3    H      CH.sub.3                               
                                        &#34;                                 
N       Cl      CF.sub.3    CH.sub.3                                      
                                   H    &#34;                                 
N       Cl      CF.sub.3    CH.sub.3                                      
                                   CH.sub.3                               
                                        &#34;                                 
CH      H       CF.sub.3    H      H    CH.sub.3                          
CH      H       CF.sub.3    CH.sub.3                                      
                                   H    &#34;                                 
CH      H       CF.sub.3    H      CH.sub.3                               
                                        &#34;                                 
CH      H       CF.sub.3    CH.sub.3                                      
                                   CH.sub.3                               
                                        &#34;                                 
CH      H       OCF.sub.3   H      H    &#34;                                 
CH      H       OCF.sub.3   CH.sub.3                                      
                                   H    &#34;                                 
CH      H       OCF.sub.3   H      CH.sub.3                               
                                        &#34;                                 
CH      H       OCF.sub.3   CH.sub.3                                      
                                   CH.sub.3                               
                                        &#34;                                 
CH      H       OCF.sub.2 CF.sub.2 H                                      
                            H      H    &#34;                                 
CH      H       OCF.sub.2 CF.sub.2 H                                      
                            CH.sub.3                                      
                                   H    &#34;                                 
CH      H       OCF.sub.2 CF.sub.2 H                                      
                            H      CH.sub.3                               
                                        &#34;                                 
CH      H       OCF.sub.2 CF.sub.2 H                                      
                            CH.sub.3                                      
                                   CH.sub.3                               
                                        &#34;                                 
N       H       CF.sub.3    H      H    &#34;                                 
N       H       CF.sub. 3   CH.sub.3                                      
                                   H    &#34;                                 
N       H       CF.sub.3    H      CH.sub.3                               
                                        &#34;                                 
N       H       CF.sub.3    CH.sub.3                                      
                                   CH.sub.3                               
                                        &#34;                                 
N       Cl      CF.sub.3    H      H    &#34;                                 
N       Cl      CF.sub.3    H      CH.sub.3                               
                                        &#34;                                 
N       Cl      CF.sub.3    CH.sub.3                                      
                                   H    &#34;                                 
N       Cl      CF.sub.3    CH.sub.3                                      
                                   CH.sub.3                               
                                        &#34;                                 
______________________________________                                    
 
    
     The compound represented by the general formula (XII) is produced by reacting 1 mole of the compound represented by the general formula (IX) or (X) with 1 to 1.1 moles of the acid chloride (XI) in an inert solvent in the presence of 1 to 1.1 moles of a base. The reaction temperature is from 0° C. to room temperature, and the solvent includes organic solverts such as ethers (e.g. diethyl ether, THF, dioxane), benzene, toluene, ethyl acetate, acetone, acetonitrile, etc., among which the ethers are preferably used. The base includes organic bases such as triethylamine, pyridine, N,N-diethylaniline, etc. The reaction time is from 30 minutes to several hours. After completion of the reaction, water is added to the reaction solution which is then extracted with an organic solvent to obtain the desired product. The product may be purified if necessary by recrystallization or column chromatography. 
     Examples of the compound of the general formula (XII) thus obtained are shown in Table 7. 
     
                                           TABLE 7                                 
__________________________________________________________________________
Compounds of the general formula (XII):                                   
 ##STR137##                                                               
X  Y Z       R.sup.3                                                      
                R.sup.4                                                   
                   R.sup.1   R.sup.5                                      
                                R.sup.6                                   
__________________________________________________________________________
CH H CF.sub.3                                                             
             H  H  H         H  H                                         
CH H CF.sub.3                                                             
             H  H  CH.sub.3  &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub.3  &#34;  &#34;                                         
CH H CF.sub.3                                                             
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             CH.sub.3                                                     
                H  H         &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.3  &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                             H  H                                         
CH H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   H         &#34;  &#34;                                         
CH H CF.sub.3                                                             
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3  &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  H  CH.sub.3  &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3  &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3  &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 OCH.sub.3                                     
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  H  CH.sub.3  &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  H  n-C.sub.3 H.sub.7                                      
                             H  H                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             CH.sub.3                                                     
                H  CH.sub.3  &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  CH.sub.3                                                  
                   CH.sub.3  &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  H  CH.sub.3  &#34;  &#34;                                         
N  H CF.sub. 3                                                            
             H  H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  H  H         &#34;  &#34;                                         
N  H CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub.3  H  H                                         
N  H CF.sub.3                                                             
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.3  &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  H  CH.sub.3  &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub.3  &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                             H  H                                         
N  H CF.sub.3                                                             
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3  &#34;  &#34;                                         
N  H CF.sub.3                                                             
             CH.sub.3                                                     
                CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3  &#34;  &#34;                                         
CH H CF.sub.3                                                             
             CH.sub.3                                                     
                CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.3  &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  H  H         CH.sub. 3                                    
                                H                                         
CH H CF.sub.3                                                             
             H  H  CH.sub.3  &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub.3  &#34;  &#34;                                         
CH H CF.sub.3                                                             
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                             CH.sub.3                                     
                                H                                         
CH H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.3  &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   C.sub. 2 H.sub.5                                       
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3  &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  H  CH.sub.3  &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3  &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3  &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                             CH.sub.3                                     
                                H                                         
CH H OCF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  H  CH.sub.3  &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             CH.sub.3                                                     
                H  CH.sub.3  &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  CH.sub.3                                                  
                   CH.sub.3  &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  H  CH.sub.3  &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  H  n-C.sub.3 H.sub.7                                      
                             CH.sub.3                                     
                                H                                         
N  H CF.sub.3                                                             
             H  H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  H  H         &#34;  &#34;                                         
N  H CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub.3  &#34;  &#34;                                         
N  H CF.sub.3                                                             
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.3  &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  H  CH.sub.3  &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub.3  CH.sub.3                                     
                                H                                         
N  Cl                                                                     
     CF.sub.3                                                             
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3  &#34;  &#34;                                         
N  H CF.sub.3                                                             
             CH.sub.3                                                     
                CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3  &#34;  &#34;                                         
CH H CF.sub.3                                                             
             CH.sub.3                                                     
                CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.3  &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  H  CH.sub.3  H  COOCH.sub.3                               
CH H CF.sub.3                                                             
             H  H  C.sub.2 H.sub.5                                        
                             &#34;  COOC.sub.2 H.sub.5                        
CH H CF.sub.3                                                             
             H  H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  COOCH.sub.3                               
CH H CF.sub.3                                                             
             H  H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  H  H         &#34;  &#34;                                         
CH H CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub.3  H  COOCH.sub.3                               
CH H CF.sub. 3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.3  &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  H  CH.sub.3  &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3  &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                             H  COOCH.sub.3                               
CH H OCF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3  &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
CH H OCF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  H  CH.sub.3  &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             CH.sub.3                                                     
                H  CH.sub.3  &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  CH.sub.3                                                  
                   CH.sub.3  &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                             H  COOCH.sub.3                               
CH H OCF.sub.2 CF.sub.2 H                                                 
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  H  CH.sub.3  &#34;  COOC.sub.2 H.sub.5                        
N  H CF.sub.3                                                             
             H  H  C.sub.2 H.sub.5                                        
                             &#34;  COOCH.sub.3                               
N  H CF.sub.3                                                             
             H  H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  H  CH(CH.sub.3).sub.2                                     
                             &#34;  COOC.sub.2 H.sub.5                        
N  H CF.sub.3                                                             
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub.3  &#34;  &#34;                                         
N  H CF.sub.3                                                             
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.3  &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             H  H  H         &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  H  CH.sub.3  &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  H  n-C.sub.3 H.sub.7                                      
                             H  COOC.sub.2 H.sub.5                        
N  Cl                                                                     
     CF.sub.3                                                             
             H  H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub.3  &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub. 2 CH(CH.sub.3).sub.2                           
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
N  H CF.sub.3                                                             
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3  &#34;  &#34;                                         
N  H CF.sub.3                                                             
             CH.sub.3                                                     
                CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
CH H CF.sub.3                                                             
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3  &#34;  &#34;                                         
CH H CF.sub.3                                                             
             CH.sub.3                                                     
                CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.3  &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                             &#34;  &#34;                                         
N  Cl                                                                     
     CF.sub.3                                                             
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                             &#34;  &#34;                                         
__________________________________________________________________________
 
    
     The compound represented by the general formula (II)&#39; is obtained by heating the compound represented by the general formula (XII) in the presence of a catalyst. The reaction temperature is from 50° to 150° C., preferably in the vicinity of 100° C. For the solvent, organic solvents such as THF, chloroform, acetonitrile, benzene, toluene, etc. are used. The catalyst includes Lewis acids (e.g. zinc chloride), bases (e.g. 4-dimethylaminopyridine) and acids (e.g. trifluoromethanesulfonic acid), among which the bases are preferably used. The reaction generally comes to an end in several hours. After completion of the reaction, the reaction solution is poured into water, acidified and then extracted with an organic solvent to obtain the desired product. This product may be purified if necessary by recrystallization or column chromatography. 
     Examples of the compound of the general formula (II)&#39; thus obtained are shown in Table 8. 
     
                                           TABLE 8                                 
__________________________________________________________________________
 ##STR138##                                                               
X  Y  Z      R.sup.3                                                      
                R.sup.4                                                   
                   R.sup.1  R.sup.5                                       
                               R.sup.6                                    
__________________________________________________________________________
CH H  CF.sub.3                                                            
             H  H  CH.sub.3 H  H                                          
CH H  CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  H  CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  H  H        &#34;  &#34;                                          
CH H  CF.sub. 3                                                           
             CH.sub.3                                                     
                H  CH.sub.3 &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  H        &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                            H  H                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   H        &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                H  CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H  CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H  n-C.sub.3 H.sub.7                                      
                            H  H                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H  CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  H  CH.sub.3 &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  H  CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  H  CH.sub.3 &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3 H  H                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  H  CH.sub.3 &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  H  CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3 &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                            H  H                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  H  CH.sub.3 CH.sub.3                                      
                               &#34;                                          
CH H  CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  H  CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  H  H        &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3 &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub. 3                                    
                            CH.sub.3                                      
                               H                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                H  CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             CH.sub. 3                                                    
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                            CH.sub.3                                      
                               H                                          
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H  CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub. 2 CF.sub.2 H                                               
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H  CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub. 2 H                                               
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  H  CH.sub.3 &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  H  CH(CH.sub.3).sub.2                                     
                            CH.sub.3                                      
                               H                                          
N  H  CF.sub.3                                                            
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  H  CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  H  H        &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3 &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  H  CH.sub.3 &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  H  CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3 &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            CH.sub.3                                      
                               H                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  H  CH.sub.3 H  COOCH.sub.3                                
CH H  CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  COOC.sub.2 H.sub.5                         
CH H  CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  COOCH.sub.3                                
CH H  CF.sub.3                                                            
             H  H  CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  H  H        &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3 &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            H  COOCH.sub.3                                
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  CH.sub. 3                                              
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                H  CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                            H  COOCH.sub.3                                
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H  CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H  CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                            H  COOCH.sub.3                                
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  H  CH.sub.3 &#34;  COOC.sub.2 H.sub.5                         
N  H  CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  COOCH.sub.3                                
N  H  CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  H  CH(CH.sub.3).sub.2                                     
                            &#34;  COOC.sub.2 H.sub.5                         
N  H  CF.sub.3                                                            
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  H  CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  H  H        &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3 &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  H  CH.sub.3 H  COOC.sub.2 H.sub.5                         
N  Cl CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  H  CH.sub.2 OCH.sub.2                                     
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3 &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 OCH.sub.3                                     
                            &#34;  &#34;                                          
__________________________________________________________________________
 
    
     The compound represented by the formula (II)&#34; is produced by oxidation of the acylcyclohexane represented by the general formula (II)&#39;. The oxidation reaction can be performed by using a usual method, for example, m-chloroperbenzoic acid in chloroform, hydrogen peroxide in acetic acid, etc. 
     The number of n is controlled by amount of the oxidant used and the reaction temperature. After completion of the reaction, which is generally required one to several hours, the reaction solution is poured into water, extracted with an organic solvent to obtain the desired product. This product may be purified, if necessary, by recrystallization or column chromatography. 
     Examples of the compound of the general formula (II)&#34; thus obtained are shown in Tables 9 and 10. 
     
                                           TABLE 9                                 
__________________________________________________________________________
Compounds of the                                                          
general formula (II):                                                     
 ##STR139##                                                               
X   Y Z      R.sup.3                                                      
                R.sup.4                                                   
                   R.sup.1  R.sup.5                                       
                                R.sup.6                                   
__________________________________________________________________________
CH  H CF.sub.3                                                            
             H  H  CH.sub.3 H   H                                         
CH  H CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             H  H  CH(CH.sub.3).sub.2                                     
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             H  H  H        &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3 &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             CH.sub.3                                                     
                H  H        &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             H  CH.sub.3                                                  
                   H        &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3 &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             H  H  CH.sub.3 &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             H  H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             H  H  n-C.sub.3 H.sub.7                                      
                            H   H                                         
CH  H OCF.sub.3                                                           
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             CH.sub.3                                                     
                H  CH.sub.3 &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                            &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             H  H  CH.sub.3 &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             H  H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             H  H  CH(CH.sub.3).sub.2                                     
                            &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  CH.sub.3 &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  H(CH.sub.3).sub.2                                      
                            &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                            &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                            H   H                                         
N   H CF.sub.3                                                            
             H  H  CH.sub.3 &#34;   &#34;                                         
N   H CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
N   H CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
N   H CF.sub. 3                                                           
             H  H  CH(CH.sub.3).sub.2                                     
                            &#34;   &#34;                                         
N   H CF.sub.3                                                            
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;   &#34;                                         
N   H CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3 &#34;   &#34;                                         
N   H CF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
N   H CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
N   H CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH(CH.sub.3).sub.2                                     
                            &#34;   &#34;                                         
N   H CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;   &#34;                                         
N   H CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;   &#34;                                         
N   H CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
N   H CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
N   H CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                            &#34;   &#34;                                         
N   H CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             H  H  CH.sub.3 &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             H  H  CH(CH.sub.3).sub.2                                     
                            &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3 &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            H   H                                         
N   H CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3 &#34;   &#34;                                         
N   H CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3 &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                            &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             H  H  H        CH.sub.3                                      
                                &#34;                                         
CH  H CF.sub.3                                                            
             H  H  CH.sub.3 &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             H  H  CH(CH.sub.3).sub.2                                     
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3 &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH(CH.sub.3).sub.2                                     
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.2 CH(CH.sub.3).sub.2                            
                            CH.sub.3                                      
                                H                                         
CH  H CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3 &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             H  H  CH.sub.3 &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             H  H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             CH.sub.3                                                     
                H  CH.sub.3 &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             H  H  CH.sub.3 CH.sub.3                                      
                                H                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             H  H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  CH.sub.3 &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
N   H CF.sub.3                                                            
             H  H  CH.sub.3 &#34;   &#34;                                         
N   H CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
N   H CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
N   H CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3 CH.sub.3                                      
                                H                                         
N   H CF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
N   H CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
N   H CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;   &#34;                                         
N   H CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
N   H CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             H  H  CH.sub.3 &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3 &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
N   H CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3 &#34;   &#34;                                         
N   H CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3 &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             H  H  CH.sub.3 H   COOCH.sub.3                               
CH  H CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;   COOC.sub.2 H.sub.5                        
CH  H CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3 &#34;   COOCH.sub.3                               
CH  H CF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            H   COOCH.sub.3                               
CH  H CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3 &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             H  H  CH.sub.3 &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             H  H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             CH.sub.3                                                     
                H  CH.sub.3 &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             H  H  CH.sub.3 &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             H  H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  CH.sub.3 &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub. 7                                     
                            &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            H   COOCH.sub.3                               
N   H CF.sub.3                                                            
             H  H  CH.sub.3 &#34;   COOC.sub.2 H.sub.5                        
N   H CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;   COOCH.sub.3                               
N   H CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
N   H CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3 &#34;   COOC.sub.2 H.sub.5                        
N   H CF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
N   H CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
N   H CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;   &#34;                                         
N   H CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
N   H CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             H  H  CH.sub.3 &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3 &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
N   H CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3 &#34;   &#34;                                         
N   H CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3 &#34;   &#34;                                         
CH  H CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;   &#34;                                         
N   Cl                                                                    
      CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;   &#34;                                         
__________________________________________________________________________
 
    
     
                                           TABLE 10                                
__________________________________________________________________________
 ##STR140##                                                               
X  Y  Z      R.sup.3                                                      
                R.sup.4                                                   
                   R.sup.1  R.sup.5                                       
                               R.sup.6                                    
__________________________________________________________________________
CH H  CF.sub.3                                                            
             H  H  CH.sub.3 H  H                                          
CH H  CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  H  CH(CH.sub.3).sub.2                                     
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  H  CH.sub.2 CH(CH.sub.3).sub.2                            
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  H  H        &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3 &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub. 2 H.sub.5                                       
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                H  CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H  CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H  n-C.sub.3 H.sub.7                                      
                            H  H                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  H  CH.sub.3 &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3 &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub. 3                                                    
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  H  CH.sub.3 &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3 &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            H  H                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH N  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub. 3                                                 
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  H  CH.sub.3 CH.sub.3                                      
                               &#34;                                          
CH H  CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3 &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH.sub.3                                                                  
   H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  CH.sub. 3                                              
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                H  CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            CH.sub.3                                      
                               H                                          
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H  CH.sub.3 CH.sub.3                                      
                               H                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  H  CH.sub.3 &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3 &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  H  CH.sub.3 &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3 CH.sub.3                                      
                               H                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  H  CH.sub.3 H  COOCH.sub.3                                
CH H  CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  COOC.sub.2 H.sub.5                         
CH H  CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3 &#34;  COOCH.sub.3                                
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                H  CH.sub.3 H  COOCH.sub.3                                
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.3                                                           
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H  CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH H  CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  H  CH.sub.3 &#34;  COOC.sub.2 H.sub.5                         
N  H  CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  COOCH.sub.3                                
N  H  CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3 &#34;  COOC.sub.2 H.sub.5                         
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            H  COOC.sub.2 H.sub.5                         
N  H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            H  &#34;                                          
N  Cl CF.sub.3                                                            
             H  H  CH.sub.3 H  &#34;                                          
N  Cl CF.sub.3                                                            
             H  H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  CH.sub.3 &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             CH.sub.3                                                     
                H  n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
N  H  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   CH.sub.3 &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   C.sub.2 H.sub.5                                        
                            &#34;  &#34;                                          
N  Cl CF.sub.3                                                            
             H  CH.sub.3                                                  
                   n-C.sub.3 H.sub.7                                      
                            &#34;  &#34;                                          
__________________________________________________________________________
 
    
     PRODUCTION EXAMPLE 10 
     Production of the compound (VI) Production of 3-(4-trifluoromethylphenylthio)propionaldehyde 
     Ten grams of 4-trifluoromethylthiophenol was dissolved in 15 ml of THF, and after adding 4.0 g of 95% acrolein under ice-cooling, 0.1 g of triethylamine was added while thoroughly stirring the reaction solution. After stirring for 1.5 hours under ice-cooling, the reaction solution was poured into water and extracted with ether. The ether layer was washed with water and dried over anhydrous magnesium sulfate. The solvent was removed under reduced pressure to obtain 13.1 g of 3-(4-trifluoromethylphenylthio)propionaldehyde. 
       1  H-NMR (CDCl 3 ): δ (ppm) 9.81 (1H, s), 7.47 (4H, ABq), 3.25 (2H, t), 2.84 (2H, t). 
     Examples of the compound of the general formula (VI) thus produced are shown in Table 11. 
     
                       TABLE 11                                                    
______________________________________                                    
 ##STR141##                                                               
                                      Physical                            
X      Y      Z           R.sup.3                                         
                                R.sup.4                                   
                                      property                            
______________________________________                                    
CH     H      CF.sub.3    CH.sub.3                                        
                                H     n.sub.D.sup.21 1.5043               
CH     H      CF.sub.3    H     CH.sub.3                                  
                                      n.sub.D.sup.22 1.5020               
CH     H      OCF.sub.3   H     H     n.sub.D.sup.29 1.4886               
CH     H      OCF.sub.2 CF.sub.2 H                                        
                          H     H     n.sub.D.sup.23 1.4771               
N      H      CF.sub.3    H     H     n.sub.D.sup.22 1.5228               
N      Cl     CF.sub.3    H     H     n.sub.D.sup.19 1.5262               
______________________________________                                    
 
    
     PRODUCTION EXAMPLE 11 
     Production of the compound (VII) Production of 6-(4-trifluoromethylphenylthio)-3-hexene-2-one 
     Ten grams of 3-(4-trifluoromethylphenylthio)propionaldehyde and 15 g of triphenylphosphine acetylmethylene were dissolved in 50 ml of chloroform, followed by stirring for 8 hours under ice-cooling. After removing chloroform, ether was added to the residue, and ether-insoluble products were removed by filtration. The ether-soluble product was purified by column chromatography (eluent; ethyl acetate:hexane=1:3) to obtain 9.9 g of 6-(4-trifluoromethylphenylthio)-3-hexene-2-one. 
       1  H-NMR (CDCl 3 ): δ (ppm) 7.46 (4H, ABq), 6.79 (1H, dt), 6.11 (1H, d), 3.3-2.5 (4H, m), 2.22 (3H, s). 
     Examples of the compound of the general formula (VII) thus produced are shown in Table 12. 
     
                       TABLE 12                                                    
______________________________________                                    
 ##STR142##                                                               
                                      Physical                            
X      Y      Z           R.sup.3                                         
                                R.sup.4                                   
                                      property                            
______________________________________                                    
CH     H      CF.sub.3    CH.sub.3                                        
                                H     n.sub.D.sup.21 1.5101               
CH     H      CF.sub.3    H     CH.sub.3                                  
                                      n.sub.D.sup.23 1.5077               
CH     H      OCF.sub.3   H     H     n.sub.D.sup.26 1.5011               
CH     H      OCF.sub.2 CF.sub.2 H                                        
                          H     H     n.sub.D.sup.23 1.5002               
N      H      CF.sub.3    H     H     n.sub.D.sup.22 1.5162               
N      Cl     CF.sub.3    H     H     n.sub.D.sup.19 1.5332               
______________________________________                                    
 
    
     PRODUCTION EXAMPLE 12 
     Production of the compound (IX) Production of the sodium salt of 6-methoxycarbonyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione 
     2.32 Grams of sodium was dissolved in 30 ml of methanol, and 300 ml of THF and 13.5 g of dimethyl malonate were added in this order. Heating under reflux was then carried out for 15 minutes, removed oil bath, and after adding 27.42 g of 6-(4-trifluoromethylphenylthio)-3-hexene-2-one, heating under reflux was again carried out for 30 minutes. The reaction solution was cooled to room temperature, and the precipitated crystals were filtered off and thoroughly washed with ether and hexane to obtain 34.3 g of the sodium salt of 6-methoxycarbonyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione. 
       1  H-NMR (D 2  O): δ (ppm) 7.45 (4H, ABq), 5.35 (1H, s), 3.88 (3H, s), 3.01 (2H, t), 2.5-1.5 (6H, m). 
     Examples of the compound of the general formula (IX) thus produced are shown in Table 13. 
     
                                           TABLE 13                                
__________________________________________________________________________
 ##STR143##                                                               
                          Physical property                               
X  Y  Z      R.sup.3                                                      
                R.sup.4                                                   
                    R.sup.5                                               
                       R.sup.7                                            
                          (.sup.1 H-NMR)                                  
__________________________________________________________________________
CH H  CF.sub.3                                                            
             H  H   H  CH.sub.3                                           
                          7.45(4H,ABq),5.35                               
                          (1H,s),3.88 (3H,                                
                          s),3.01(2H, t),                                 
                          2.5-1.5(6H, m)                                  
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H   H  CH.sub.3                                           
                          7.43(4H, brs),5.21                              
                          (1H, s),3.87(3H, s),                            
                          3.35(1H, q),                                    
                          1.29(3H, d),2.5-1.5                             
                          (6H, m)                                         
CH H  CF.sub.3                                                            
             H  CH.sub. 3                                                 
                    H  CH.sub.3                                           
                          7.40(4H, ABq),                                  
                          5.15(1H, s),3.78                                
                          (3H, s),2.90                                    
                          (2H, d),1.10(3H,                                
                          d), 2.5-1.5                                     
                          (5H, m)                                         
CH H  OCF.sub.3                                                           
             H  H   H  CH.sub.3                                           
                          7.42(4H, ABq),                                  
                          5.11(1H, s),                                    
                          3.82(3H, s),                                    
                          3.00(2H, t), 2.5-                               
                          1.5 (6H, m)                                     
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H   H  CH.sub.3                                           
                          7.40(4H, ABq),                                  
                          5.85(1H, tt),                                   
                          5.10(1H, s),                                    
                          3.79(3H, s),                                    
                          3.05(2H, t),                                    
                          2.5-1.5(6H, m)                                  
N  H  CF.sub.3                                                            
             H  H   H  CH.sub.3                                           
                          8.62(1H, s), 7.76(1H,                           
                          dd), 7.22(1H,d), 5.22                           
                          (1H, s), 3.81(3H,                               
                          s), 3.01(2H, s),                                
                          2.5-1.5(6H, m)                                  
N  Cl CF.sub.3                                                            
             H  H   H  CH.sub.3                                           
                          8.65(1H, brs),7.80                              
                          (1H, brs), 5.25(1H,s)                           
                          3.78(3H, s), 3.02                               
                          (2H, t),                                        
                          2.5-1.5(6H, m)                                  
CH H  CF.sub.3                                                            
             H  H   CH.sub.3                                              
                       CH.sub.3                                           
                          7.42(4H, ABq)                                   
                          5.34(1H, s),                                    
                          3.86(3H, s),2.99                                
                          (2H, t),                                        
                          2.5-1.5(5H, m),                                 
                          1.10(3H, s)                                     
__________________________________________________________________________
 
    
     PRODUCTION EXAMPLE 13 
     Production of the compound (X) Production of 5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione 
     2.00 Grams of 6-methoxycarbonyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione was dissolved in 30 ml of water, and 1.6 g of sodium carbonate was added to the resulting solution which was then heated under reflux for 5 hours. After thoroughly cooling the reaction solution, the reaction solution was extracted with ether to remove impurities, and the aqueous layer was acidified with hydrochloric acid and extracted with ethyl acetate to separate the desired product. The ethyl acetate layer was dried over anhydrous magnesium sulfate, and after removing ethyl acetate, the resulting crystals were washed with hexane to obtain 1.5 g of 5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione. 
       1  H-NMR (CDCl 3  +DMSO-d 6 ): δ (ppm) 7.44 (4H, q), 5.32 (1H, s), 2.99 (2H, t), 2.5-1.5 (7H, m). 
     Examples of the compound of the general formula (X) thus produced are shown in Table 14. 
     
                                           TABLE 14                                
__________________________________________________________________________
 ##STR144##                                                               
X  Y  Z      R.sup.3                                                      
                R.sup.4                                                   
                    R.sup.5                                               
                       Physical property (.sup.1 H-NMR)                   
__________________________________________________________________________
CH H  CF.sub.3                                                            
             H  H   H  7.44(4H, ABq) , 5.32(1H, s),                       
                       2.99(2H, t), 2.5-1.5                               
                       (7H, m)                                            
CH H  CF.sub.3                                                            
             CH.sub.3                                                     
                H   H  7.45(4H, brs), 5.15(1H, s),                        
                       3.25(1H, m), 1.17(3H,                              
                       d), 2.5-1.5(7H, m)                                 
CH H  CF.sub.3                                                            
             H  CH.sub.3                                                  
                    H  7.42(4H, ABq), 5.10(1H, s),                        
                       2.95(2H, d), 1.11(3H,                              
                       d), 2.5-1.5(6H, m)                                 
CH H  OCF.sub.3                                                           
             H  H   H  7.40(4H, ABq), 5.21(1H, s),                        
                       3.03(2H, t), 2.5-1.5                               
                       (7H, m)                                            
CH H  OCF.sub.2 CF.sub.2 H                                                
             H  H   H  7.41(3H, s), 5.82(1H, tt),                         
                       5.22(1H, s), 3.08(2H, t),                          
                       2.5-1.5(7H, m)                                     
N  H  CF.sub.3                                                            
             H  H   H  8.60(1H, s), 7.75(1H, dd),                         
                       7.24(1H, s), 3.01(2H, s),                          
                       2.5-1.5(7H, m)                                     
N  Cl CF.sub.3                                                            
             H  H   H  8.63(1H, brs), 7.75(1H,                            
                       brs), 3.02(2H, t),                                 
                       2.5-1.5(7H, m)                                     
CH H  CF.sub.3                                                            
             H  H   CH.sub.3                                              
                       7.43(4H, ABq), 5.31(1H,                            
                       s), 2.95(2H, t), 2.5-1.5                           
                       (6H, m),1.15(3H, d)                                
__________________________________________________________________________
 
    
     PRODUCTION EXAMPLE 14 
     Production of the compound (XII) Production of 1-acetoxy-5-[2-(4-trifluoromethylphenylthio)ethyl]-1-cyclohexene-3-one 
     6.32 Grams of 5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione was dissolved in 50 ml of tetrahydrofuran, and 2.12 g of triethylamine was added. Thereafter, 1.73 g of acetyl chloride was added dropwise with thorough stirring under ice-cooling. After continuing stirring for further 2 hours at room temperature, the precipitated solid was filtered off. The solvent was removed from the filtrate, and the residue was dissolved in ether. The ether layer was successively washed with dilute hydrochloric acid, aqueous sodium hydrogencarbonate and water and dried over anhydrous magnesium sulfate. Ether was removed to obtain 7.13 g of 1-acetoxy-5-[2-(4-trifluoromethylphenylthio)ethyl]-1-cyclohexene-3-one. 
       1  H-NMR (CDCl 3 ): δ (ppm) 7.39 (4H, q), 5.86 (1H, s), 3.07 (2H, t), 2.16 (3H, s), 2.5-1.5 (7H, m). 
     Examples of the compound of the general formula (XII) thus produced are shown in Table 15. 
     
                                           TABLE 15                                
__________________________________________________________________________
 ##STR145##                                                               
                                   Physical                               
X  Y Z      R.sup.3                                                       
               R.sup.4                                                    
                  R.sup.5                                                 
                     R.sup.6                                              
                           R.sup.1 property                               
__________________________________________________________________________
CH H CF.sub.3                                                             
            H  H  H  H     CH.sub.3                                       
                                   n.sub.D.sup.20 1.5115                  
CH H CF.sub.3                                                             
            H  H  CH.sub.3                                                
                     H     CH.sub.3                                       
                                   n.sub.D.sup.20 1.5098                  
CH H CF.sub.3                                                             
            H  H  H  H     C.sub.2 H.sub.5                                
                                   m.p. 47-48° C.                  
CH H CF.sub.3                                                             
            H  H  H  COOCH.sub.3                                          
                           CH.sub.3                                       
                                   n.sub.D.sup.20 1.5058                  
CH H CF.sub.3                                                             
            H  H  H  H     n-C.sub.3 H.sub.7                              
                                   n.sub.D.sup.19 1.4995                  
CH H CF.sub.3                                                             
            H  H  H  COOCH.sub.3                                          
                           C.sub.2 H.sub.5                                
                                   n.sub.D.sup.19 1.5216                  
CH H CF.sub.3                                                             
            H  H  H  H     CH(CH.sub.3).sub.2                             
                                   n.sub.D.sup.20 1.5383                  
CH H CF.sub.3                                                             
            H  H  H  H     CH.sub.2 CH(CH.sub.3).sub.2                    
                                   m.p. 64-65° C.                  
CH H CF.sub.3                                                             
            H  H  H  H     CH.sub.2 OCH.sub.3                             
                                   n.sub.D.sup.22.5 1.5341                
CH H CF.sub.3                                                             
            H  H  H  COOCH.sub.3                                          
                           n-C.sub.3 H.sub.7                              
                                   n.sub.D.sup.20 1.5401                  
CH H CF.sub.3                                                             
            CH.sub.3                                                      
               H  H  COOCH.sub.3                                          
                           CH.sub.3                                       
                                   n.sub.D.sup.23 1.5512                  
CH H CF.sub.2                                                             
            CH.sub.3                                                      
               H  H  H     CH.sub.3                                       
                                   n.sub.D.sup.22.5 1.5326                
CH H CF.sub.3                                                             
            CH.sub.3                                                      
               H  H  COOCH.sub.3                                          
                           C.sub.2 H.sub.5                                
                                   n.sub.D.sup.23 1.5486                  
CH H CF.sub.3                                                             
            CH.sub.3                                                      
               H  H  H     C.sub.2 H.sub.5                                
                                   n.sub.D.sup.22.5 1.5162                
CH H CF.sub.3                                                             
            CH.sub.3                                                      
               H  H  H     n-C.sub.3 H.sub.7                              
                                   n.sub.D.sup.23 1.4979                  
CH H CF.sub.3                                                             
            H  CH.sub.3                                                   
                  H  COOCH.sub.3                                          
                           CH.sub.3                                       
                                   n.sub.D.sup.24 1.5429                  
CH H CF.sub.3                                                             
            H  CH.sub.3                                                   
                  H  H     CH.sub.3                                       
                                   n.sub.D.sup.24 1.5416                  
CH H CF.sub.3                                                             
            H  CH.sub.3                                                   
                  H  H     C.sub.2 H.sub.5                                
                                   n.sub.D.sup.24 1.5326                  
CH H CF.sub.3                                                             
            H  CH.sub.3                                                   
                  H  COOCH.sub.3                                          
                           C.sub.2 H.sub.5                                
                                   n.sub.D.sup.24 1.5433                  
CH H CF.sub.3                                                             
            H  CH.sub.3                                                   
                  H  H     n-C.sub.3 H.sub.7                              
                                   n.sub.D.sup.22 1.4165                  
CH H OCF.sub.3                                                            
            H  H  H  COOCH.sub.3                                          
                           CH.sub.3                                       
                                   n.sub.D.sup.26 1.5501                  
CH H OCF.sub.3                                                            
            H  H  H  H     CH.sub.3                                       
                                   n.sub.D.sup.26 1.5385                  
CH H OCF.sub.3                                                            
            H  H  H  H     C.sub.2 H.sub.5                                
                                   n.sub.D.sup.27.5 1.5118                
CH H OCF.sub.3                                                            
            H  H  H  H     n-C.sub.3 H.sub.7                              
                                   n.sub.D.sup.27.5 1.4911                
CH H OCF.sub.3                                                            
            H  H  H  COOCH.sub.3                                          
                           C.sub.2 H.sub.5                                
                                   n.sub.D.sup.25 1.5281                  
CH H OCF.sub.2 CF.sub.2 H                                                 
            H  H  H  H     CH.sub.3                                       
                                   n.sub.D.sup.24 1.5211                  
CH H OCF.sub.2 CF.sub.2 H                                                 
            H  H  H  H     C.sub.2 H.sub.5                                
                                   n.sub.D.sup.24 1.5081                  
CH H OCF.sub.2 CF.sub.2 H                                                 
            H  H  H  H     n-C.sub.3 H.sub.7                              
                                   n.sub.D.sup.24 1.4944                  
N  H CF.sub.3                                                             
            H  H  H  H     CH.sub.3                                       
                                   n.sub.D.sup.21 1.5561                  
N  H CF.sub.3                                                             
            H  H  H  H     C.sub.2 H.sub.5                                
                                   n.sub.D.sup.21 1.5537                  
N  H CF.sub.3                                                             
            H  H  H  H     n-C.sub.3 H.sub.7                              
                                   n.sub.D.sup.21 1.5121                  
N  Cl                                                                     
     CF.sub.3                                                             
            H  H  H  H     CH.sub.3                                       
                                   n.sub.D.sup.22.5 1.5485                
N  Cl                                                                     
     CF.sub.3                                                             
            H  H  H  H     C.sub.2 H.sub.5                                
                                   n.sub.D.sup.22.5 1.5315                
N  Cl                                                                     
     CF.sub.3                                                             
            H  H  H  H     n-C.sub.3 H.sub.7                              
                                   n.sub.D.sup.22.5 1.5067                
N  H CF.sub.3                                                             
            H  H  H  H     CH.sub.2 OCH.sub.3                             
                                   n.sub.D.sup.23 1.5135                  
N  H CF.sub.3                                                             
            H  H  H  COOC.sub.2 H.sub.5                                   
                           C.sub.2 H.sub.5                                
                                   n.sub.D.sup.24 1.5417                  
__________________________________________________________________________
 
    
     PRODUCTION EXAMPLE 15 
     Production of the compound (II)&#39; Production of 2-acetyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione 
     3.3 Grams of 1-acetoxy-5-[2-(4-trifluoromethylphenylthio)ethyl]-1-cyclohexene-3-one and 0.8 g of 4-dimethylaminopyridine were dissolved in acetonitrile, followed by heating under reflux for 2.5 hours. After removing acetonitrile, the residue was dissolved in ethyl acetate, and the ethyl acetate layer was washed with dilute hydrochloric acid and then with water, and dried over anhydrous magnesium sulfate. Ethyl acetate was removed to obtain 3.3 g of 2-acetyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione. 
       1  H-NMR (CDCl 3 ): δ (ppm) 18.16 (1H, s), 7.46 (4H, q), 3.03 (2H, t), 2.58 (3H, s), 2.8-1.6 (7H, m). 
     Examples of the compound of the general formula (II)&#39; thus produced are shown in Table 16. 
     
                                           TABLE 16                                
__________________________________________________________________________
 ##STR146##                                                               
                                   Physical                               
X  Y Z      R.sup.3                                                       
               R.sup.4                                                    
                  R.sup.5                                                 
                     R.sup.6                                              
                           R.sup.1 property                               
__________________________________________________________________________
CH H CF.sub.3                                                             
            H  H  CH.sub.3                                                
                     H     CH.sub.3                                       
                                   n.sub.D.sup.24 1.5231                  
CH H CF.sub.3                                                             
            H  H  H  H     CH.sub.3                                       
                                   m.p. 60-61° C.                  
CH H CF.sub.3                                                             
            H  H  H  COOCH.sub.3                                          
                           CH.sub.3                                       
                                   n.sub.D.sup.24 1.5465                  
CH H CF.sub.3                                                             
            H  H  H  H     C.sub.2 H.sub.5                                
                                   n.sub.D.sup.25 1.5161                  
CH H CF.sub.3                                                             
            H  H  H  COOCH.sub.3                                          
                           C.sub.2 H.sub.5                                
                                   n.sub.D.sup.24 1.5399                  
CH H CF.sub. 3                                                            
            H  H  H  H     n-C.sub.3 H.sub.7                              
                                   n.sub.D.sup.25 1.5017                  
CH H CF.sub.3                                                             
            H  H  H  COOCH.sub.3                                          
                           n-C.sub.3 H.sub.7                              
                                   n.sub.D.sup.23 1.5178                  
CH H CF.sub.3                                                             
            H  H  H  H     CH(CH.sub.3).sub.2                             
                                   n.sub.D.sup.23 1.5261                  
CH H CF.sub.3                                                             
            H  H  H  H     CH.sub.2 CH(CH.sub.3).sub.2                    
                                   n.sub.D.sup.24 1.5362                  
CH H CF.sub.3                                                             
            H  H  H  H     CH.sub.2 OCH.sub.3                             
                                   n.sub.D.sup.23 1.5412                  
CH H CF.sub.3                                                             
            CH.sub.3                                                      
               H  H  COOCH.sub.3                                          
                           CH.sub.3                                       
                                   n.sub.D.sup.23 1.5450                  
CH H CF.sub.3                                                             
            CH.sub.3                                                      
               H  H  H     CH.sub.3                                       
                                   n.sub.D.sup.25.5 1.5288                
CH H CF.sub.3                                                             
            CH.sub.3                                                      
               H  H  COOCH.sub.3                                          
                           C.sub.2 H.sub.5                                
                                   n.sub.D.sup.23 1.5392                  
CH H CF.sub.3                                                             
            CH.sub.3                                                      
               H  H  H     C.sub.2 H.sub.5                                
                                   n.sub.D.sup.25.5 1.5026                
CH H CF.sub.3                                                             
            CH.sub.3                                                      
               H  H  H     n-C.sub.3 H.sub. 7                             
                                   n.sub.D.sup.22.5 1.4879                
CH H CF.sub.3                                                             
            H  CH.sub.3                                                   
                  H  COOCH.sub.3                                          
                           CH.sub.3                                       
                                   n.sub.D.sup.23 1.5410                  
CH H CF.sub.3                                                             
            H  CH.sub.3                                                   
                  H  H     CH.sub. 3                                      
                                   n.sub.D.sup.25.5 1.4852                
CH H CF.sub.3                                                             
            H  CH.sub.3                                                   
                  H  H     C.sub.2 H.sub.5                                
                                   D.sub.D.sup.25.5 1.4967                
CH H CF.sub.3                                                             
            H  CH.sub.3                                                   
                  H  COOCH.sub.3                                          
                           C.sub.2 H.sub.5                                
                                   n.sub.D.sup.23 1.5351                  
CH H CF.sub.3                                                             
            H  CH.sub.3                                                   
                  H  H     n-C.sub.3 H.sub.7                              
                                   n.sub.D.sup.26 1.4801                  
CH H OCF.sub.3                                                            
            H  H  H  COOCH.sub.3                                          
                           CH.sub.3                                       
                                   n.sub.D.sup.25 1.5320                  
CH H OCF.sub.3                                                            
            H  H  H  H     CH.sub.3                                       
                                   n.sub.D.sup.26 1.5239                  
CH H OCF.sub.3                                                            
            H  H  H  H     C.sub.2 H.sub.5                                
                                   n.sub.D.sup.26.5 1.5113                
CH H OCF.sub.3                                                            
            H  H  H  COOCH.sub.3                                          
                           C.sub.2 H.sub.5                                
                                   n.sub.D.sup.25 1.5448                  
CH H OCF.sub.3                                                            
            H  H  H  H     n-C.sub.3 H.sub.7                              
                                   n.sub.D.sup.26.5 1.5099                
CH H OCF.sub.2 CF.sub.2 H                                                 
            H  H  H  H     CH.sub.3                                       
                                   n.sub.D.sup.26.5 1.5276                
CH H OCF.sub.2 CF.sub.2 H                                                 
            H  H  H  H     C.sub.2 H.sub.5                                
                                   n.sub.D.sup.26.5 1.5146                
CH H OCF.sub.2 CF.sub.2 H                                                 
            H  H  H  H     n-C.sub.3 H.sub.7                              
                                   n.sub.D.sup.26.5 1.4878                
N  H CF.sub.3                                                             
            H  H  H  H     CH.sub.3                                       
                                   n.sub.D.sup.25.5 1.5325                
N  H CF.sub.3                                                             
            H  H  H  H     C.sub.2 H.sub.5                                
                                   n.sub.D.sup.25.5 1.5150                
N  H CF.sub.3                                                             
            H  H  H  H     n-C.sub.3 H.sub.7                              
                                   n.sub.D.sup.25.5 1.4949                
N  Cl                                                                     
     CF.sub.3                                                             
            H  H  H  H     CH.sub.3                                       
                                   n.sub.D.sup.26 1.5437                  
N  Cl                                                                     
     CF.sub.3                                                             
            H  H  H  H     C.sub.2 H.sub.5                                
                                   n.sub.D.sup.26 1.5339                  
N  Cl                                                                     
     CF.sub.3                                                             
            H  H  H  H     n-C.sub.3 H.sub.7                              
                                   n.sub.D.sup.26 1.5201                  
N  H CF.sub.3                                                             
            H  H  H  H     CH.sub.2 OCH.sub.3                             
                                   n.sub.D.sup.25 1.5286                  
N  H CF.sub.3                                                             
            H  H  H  COOC.sub.2 H.sub.5                                   
                           C.sub.2 H.sub.5                                
                                   n.sub.D.sup.25 1.5472                  
__________________________________________________________________________
 
    
     PRODUCTION EXAMPLE 16 
     Production of the compound (II)&#34; Production of 2-acetyl-5-[2-(4-trifluoromethylphenylsulfonyl)ethyl]cyclohexane-1,3-dione 
     To a solution of 2.0 g of 2-acetyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione in 10 ml of acetic acid, 3.2 g of 30% hydrogen peroxide was added. The solution was stirred for 3 hours at 80° C. The solution was poured into water and extracted with ethyl acetate. Removal of solvent afforded 1.6 g of 2-acetyl-5-[2-(4-trifluoromethylphenylsulfonyl)ethyl]cyclohexane-1,3-dione. m.p. 135.5°-136.5° C. 
       1  H-NMR (acetone-d 6 ): δ (ppm) 18-19 (1H, br), 7.75 (4H, ABq), 3.12 (2H, t), 2.20 (3H, s), 2.2-1.4 (7H, m). 
     Production of 2-acetyl-5-[2-(4-trifluoromethylphenylsulfinyl)ethyl]cyclohexane-1,3-dione 
     To a solution of 2.3 g of 2-acetyl-5-[2-(4-trifluoromethylphenylthio)ethyl]cyclohexane-1,3-dione in 10 ml of acetic acid, 1.8 g of 30% H 2  O 2  was dropped under cooling with ice-water bath. After stirring for 1 hour at room temperature, the reaction solution was poured into water and extracted with ethyl acetate. Removal of solvent afforded 1.83 g of 2-acetyl-5-[2-(4-trifluoromethylphenylsulfinyl)ethyl]cyclohexane-1,3-dione. m.p. 99°-100° C. 
       1  H-NMR (acetone-d 6 ): δ (ppm) 18.10 (1H, s), 7.84 (4H, s), 2.90 (2H, t), 2.59 (3H, s), 3-1.6 (7H, m). 
     Examples of the compound of the general formula (II)&#34; thus produced are shown in Table 17. 
     
                       TABLE 17                                                    
______________________________________                                    
 ##STR147##                                                               
                                               Physical                   
X    Y     Z      R.sub.1                                                 
                       R.sub.2                                            
                           R.sub.3                                        
                               R.sub.4                                    
                                   R.sub.5                                
                                       R.sub.6                            
                                           n   properties                 
______________________________________                                    
CH   H     CF.sub.3                                                       
                  CH.sub.3                                                
                       H   H   H   H   H   1   m.p.99-100°  C.     
CH   H     CF.sub.3                                                       
                  CH.sub.3                                                
                       H   H   H   H   H   2   m.p.                       
                                               135.5-136.5° C.     
CH   H     CF.sub.3                                                       
                  C.sub.2 H.sub.5                                         
                       H   H   H   H   H   1   m.p.105-106° C.     
CH   H     CF.sub.3                                                       
                  C.sub.2 H.sub.5                                         
                       H   H   H   H   H   2   m.p.140-141°        
______________________________________                                    
                                               C.                         
 
    
     When the present compounds are used as an active ingredient for herbicides, they are generally formulated into emulsifiable concentrates, wettable powders, suspension formulations, granules, etc. by mixing with solid carriers, liquid carriers, surface active agents and other auxiliaries for formulation. 
     These preparations contain from 0.1 to 90% by weight, preferably from 0.2 to 80% by weight, more preferably from 1 to 80% by weight of the present compounds as an active ingredient. 
     The solid carriers include fine powders or granules of kaolin clay, attapulgite clay, bentonite, terra abla, pyrophyllite, talc, diatomaceous earth, calcite, walnut powder, urea, ammonium sulfate, synthetic hydrated silicon dioxide, etc. The liquid carriers include aromatic hydrocarbons (e.g. xylene, methylnaphthalene), alcohols (e.g. isopropanol, ethylene glycol, cellosolve), ketones (e.g. acetone, cyclohexanone, isophorone), vegetable oils (e.g. soybean oil, cotton seed oil), dimethyl sulfoxide, N,N-dimethylformamide, acetonitrile, water, etc. 
     The surface active agents used for emulsification, dispersion, wetting, etc. include anionic surface active agents such as the salt of alkyl sulfates, alkylsulfonates, alkylarylsulfonates, dialkyl sulfosuccinates, the salt of polyoxyethylene alkylaryl ether phosphoric acid ester, etc., and nonionic surface active agents such as polyoxyethylene alkyl ether, polyoxyethylene alkylaryl ether, polyoxyethylene polyoxypropylene block copolymers, sorbitan fatty acid esters, polyoxyethylene sorbitan fatty acid esters, etc. 
     The auxiliaries for formulation include lignosulfonates, alginates, polyvinyl alcohol, gum arabic, CMC (carboxymethyl cellulose), PAP (isopropyl acid phosphate), etc. 
     Next, formulation examples will be shown. The present compounds are shown by Compound No. in Table 2. Parts in the examples are by weight. 
     FORMULATION EXAMPLE 1 
     Fifty parts of the present compound (4) or (7), 3 parts of calcium lignoinsulfonate, 2 parts of sodium lauryl sulfate and 45 parts of synethetic hydrated silicon dioxide are well pulverized and mixed together to obtain a wettable powder. 
     FORMULATION EXAMPLE 2 
     Ten parts of each of the present compound (1)-(134), 14 parts of polyoxyethylene styryl phenyl ether, 6 parts of calcium dodecylbenzenesulfonate, 30 parts of xylene and 40 parts of cyclohexanone are well mixed to obtain an emulsifiable concentrate. 
     FORMULATION EXAMPLE 3 
     One part of the present compound (9) or (10), 1 part of synthetic hydrated silicon dioxide, 2 parts of calcium lignosulfonate, 31 parts of bentonite and 65 parts of kaolin clay are well pulverized and mixed together, well kneaded with water, granulated and dried to obtain a granule. 
     FORMULATION EXAMPLE 4 
     Twenty-five parts of the present compound (11), 3 parts of polyoxyethylene sorbitan monooleate, 3 parts of CMC and 69 parts of water are mixed and wet-pulverized until the particle size is reduced to 5 microns or less to obtain a suspension formulation. 
     FORMULATION EXAMPLE 5 
     Eighty parts of the present compound (1), 3 parts of calcium lingnosulfonate, 2 parts of sodium lauryl sulfate and 15 parts of synethetic hydrated silicon dioxide are well pulverized and mixed together to obtain a wettable powder. 
     FORMULATION EXAMPLE 6 
     Twenty parts of the present compound (76), 2 parts of calcium lignosulfonate, 3 parts of alkylsulfonate and 10 parts of synthetic hydrated silicon dioxide are well pulverized and mixed together to obtain a wettable powder. 
     FORMULATION EXAMPLE 7 
     Two parts of the present compound (82), 1 part of polyoxyethylene sorbitan monooleate, 5 parts of polyvinyl alcohol and 92 parts of water are mixed and wet-pulverized until the particle size is reduced to 5 microns or less to obtain a suspension formulation. 
     FORMULATION EXAMPLE 8 
     Twenty parts of the present compound (5), 14 parts of polyoxyethylene styryl phenyl ether, 6 parts of calcium dodecylbenzenesulfonate, 30 parts of xylene and 30 parts of isophorone are well mixed to obtain an emulsifiable concentrate. 
     Generally, the present compounds are formulated and used in soil treatment, foliage treatment or treatment under flooded condition before or after the emergence of weeds. The soil treatment includes soil surface treatment, soil incorporation treatment, etc., and the foliage treatment includes, in addition to the treatment of plants over the top, directed treatment wherein herbicides are applied to weeds only so as not to attach to crops. 
     Further, the present compounds can be used as a herbicide for paddy fields, plow fields, orchards, pastures, turfs, forests, non-crop lands, etc., and also an increase in herbicidal activity can be expected by using them in mixture with other herbicides. In addition, they can be used in mixture with insecticides, acaricides, nematocides, plant growth regulators, fertilizers, soil improvers, etc. 
     When the present compounds are used as an active ingredient for herbicides, their dosage rate varies with weather conditions, preparation forms, when, how and where the treatments are applied, weeds and crops aimed at, etc., but it is generally from 0.05 to 200 g/are, preferably from 0.1 to 100 g/are. The usual dosage is from 0.6 to 10 g/are before the emergence of weeds. It is from 0.1 to 4 g/are after the emergence of weeds and is preferably from 0.2 to 2 g/are especially in corn and wheat field. It is from 0.1 to 4 g/are in paddy field and is from 10 to 100 g/are in orchards, forests and non-crop lands. In the case of emulsifiable concentrates, wettable powders, suspension formulations, etc., their prescribed amount is generally diluted with water of from 1 to 10 liters/are (if necessary, auxiliaries such as spreading agents are added). Granules, etc. are generally used as such without dilution. 
     The spreading agents include, in addition to the foregoing surface active agents, polyoxyethylene resin acid (ester), lignosulfonates, abietates, dinaphthylmethanedisulfonates, paraffin, etc. 
     Next, the usefulness of the present compounds as an active ingredient for herbicides will be illustrated with reference to the following test examples. In the test examples, the present compounds are shown by Compound No. in Table 2, and compounds used as a control are shown by Compound symbol in Table 18. 
     
                                           TABLE 18                                
__________________________________________________________________________
Compound                                                                  
Symbol                                                                    
     Structural formula              Remark                               
__________________________________________________________________________
(A)                                                                       
      ##STR148##                     Compound described in Japanese       
                                     Patent Publication Kokai (Laid-open) 
                                     No. 46749/1979.                      
(B)                                                                       
      ##STR149##                     Compound described in Japanese       
                                     Patent Publication Kokai (Laid-open) 
                                     o. 115349/1979.                      
(C)                                                                       
      ##STR150##                     Compound described in Japanese       
                                     Patent Publication Kokai (Laid-open) 
                                     No. 115349/1979.                     
(D)                                                                       
      ##STR151##                     Atrazine                             
(E)                                                                       
      ##STR152##                     Simetryn                             
(F)                                                                       
      ##STR153##                     Sethoxydim                           
__________________________________________________________________________
 
    
     The herbicidal activity and phytotoxicity were evaluated in six stages, 0, 1, 2, 3, 4, 5, according to the states of the emergence and growth of test plants (weeds and crops) at the time of examination. A stage &#34;0&#34; means there being little or no difference in the states between the treated test plants and untreated ones; a stage &#34;5&#34; means the complete death of test plants or complete inhibition of the emergence or growth thereof; and the states between &#34;0&#34; and &#34;5&#34; were divided into four stages, 1, 2, 3 and 4. 
     TEST EXAMPLE 1 
     Soil surface treatment test in plow field 
     Plow-field soil was filled in a cylindrical plastic pot (diameter, 10 cm; depth, 10 cm), and the weeds of Japanese millet and oat were sowed and covered with the soil. The prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with water of an amount corresponding to 10 liters/are, and applied to the soil surface by means of a small-sized sprayer. After treatment, the test plants were cultivated for 20 days in a greenhouse to examine the herbicidal activity. The results are shown in Table 19. 
     
                       TABLE 19                                                    
______________________________________                                    
Compound  Dosage      Herbicidal activity                                 
No.       (g/are)     Japanese millet                                     
                                  Oat                                     
______________________________________                                    
2         40          5           5                                       
3         40          5           --                                      
10        40          5           5                                       
11        40          5           5                                       
12        40          5           5                                       
13        40          5           --                                      
20        40          5           5                                       
21        40          5           5                                       
22        40          5           5                                       
23        40          5           5                                       
24        40          5           --                                      
25        40          5           --                                      
26        40          5           5                                       
27        40          5           --                                      
28        40          5           --                                      
30        40          5           5                                       
31        40          5           5                                       
32        40          5           5                                       
33        40          5           5                                       
34        40          5           --                                      
41        40          5           --                                      
43        40          5           --                                      
44        40          5           5                                       
51        40          5           5                                       
52        40          5           --                                      
53        40          5           5                                       
54        40          5           5                                       
55        40          5           5                                       
56        40          5           5                                       
57        40          5           --                                      
58        40          5           --                                      
59        40          5           5                                       
60        40          5           5                                       
67        40          5           5                                       
68        40          5           5                                       
69        40          5           5                                       
70        40          5           5                                       
71        40          5           5                                       
72        40          5           5                                       
73        40          5           5                                       
74        40          5           5                                       
75        40          5           5                                       
76        40          5           5                                       
77        40          5           5                                       
78        40          5           5                                       
79        40          5           5                                       
80        40          5           5                                       
81        40          5           5                                       
82        40          5           5                                       
83        40          5           5                                       
84        40          5           5                                       
85        40          5           5                                       
86        40          5           5                                       
87        40          5           5                                       
88        40          5           5                                       
89        40          5           5                                       
90        40          5           5                                       
91        40          5           5                                       
92        40          5           5                                       
93        40          5           5                                       
94        40          5           --                                      
95        40          5           5                                       
97        40          5           5                                       
98        40          5           5                                       
99        40          5           5                                       
100       40          5           5                                       
101       40          5           5                                       
102       40          5           5                                       
103       40          5           5                                       
104       40          5           5                                       
105       40          5           5                                       
106       40          5           5                                       
107       40          5           5                                       
108       40          5           5                                       
109       40          5           5                                       
110       40          5           5                                       
111       40          5           5                                       
112       40          5           5                                       
114       40          5           5                                       
______________________________________                                    
 
    
     TEST EXAMPLE 2 
     Foliage treatment test in plow field 
     Plow-field soil was filled in a cylindrical plastic pot (diameter, 10 cm; depth, 10 cm), and the seeds of Japanese millet and oat were sowed and cultivatied for 10 days in a greenhouse. Thereafter, the prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with a spreading agent-containing water of an amount corresponding to 10 liters/are, and foliage-applied to the test plants over the top by means of a small-sized sprayer. After treatment, the test plants were cultivated for 20 days in a greenhouse to examine the herbicidal activity. The results are shown in Table 20. 
     
                       TABLE 20                                                    
______________________________________                                    
Compound  Dosage      Herbicidal activity                                 
No.       (g/are)     Japanese millet                                     
                                  Oat                                     
______________________________________                                    
1         40          5           5                                       
2         40          5           5                                       
3         40          5           5                                       
4         40          5           5                                       
5         40          5           5                                       
6         40          5           5                                       
7         40          5           5                                       
8         40          5           5                                       
9         40          5           5                                       
10        40          5           5                                       
11        40          5           5                                       
12        40          5           5                                       
13        40          5           5                                       
14        40          5           5                                       
15        40          5           5                                       
16        40          5           5                                       
17        40          5           5                                       
18        40          5           5                                       
19        40          5           5                                       
20        40          5           5                                       
21        40          5           5                                       
22        40          5           5                                       
23        40          5           5                                       
24        40          5           5                                       
25        40          5           5                                       
26        40          5           5                                       
27        40          5           5                                       
28        40          5           5                                       
29        40          5           5                                       
30        40          5           5                                       
31        40          5           5                                       
32        40          5           5                                       
33        40          5           5                                       
34        40          5           5                                       
35        40          5           5                                       
36        40          5           5                                       
37        40          5           5                                       
38        40          5           5                                       
39        40          5           5                                       
40        40          5           5                                       
41        40          5           5                                       
42        40          5           5                                       
43        40          5           5                                       
44        40          5           5                                       
45        40          5           5                                       
46        40          5           5                                       
47        40          5           5                                       
48        40          5           5                                       
49        40          5           5                                       
50        40          5           5                                       
51        40          5           5                                       
52        40          5           5                                       
53        40          5           5                                       
54        40          5           5                                       
55        40          5           5                                       
56        40          5           5                                       
57        40          5           5                                       
58        40          5           5                                       
59        40          5           5                                       
60        40          5           5                                       
61        40          5           5                                       
62        40          5           5                                       
63        40          5           5                                       
64        40          5           5                                       
65        40          5           5                                       
66        40          5           5                                       
67        40          5           5                                       
68        40          5           5                                       
69        40          5           5                                       
70        40          5           5                                       
71        40          5           5                                       
72        40          5           5                                       
73        40          5           5                                       
74        40          5           5                                       
75        40          5           5                                       
76        40          5           5                                       
77        40          5           5                                       
78        40          5           5                                       
79        40          5           5                                       
80        40          5           5                                       
81        40          5           5                                       
82        40          5           5                                       
83        40          5           5                                       
84        40          5           5                                       
85        40          5           5                                       
86        40          5           5                                       
87        40          5           5                                       
88        40          5           5                                       
89        40          5           5                                       
90        40          5           5                                       
91        40          5           5                                       
92        40          5           5                                       
93        40          5           5                                       
94        40          5           5                                       
95        40          5           5                                       
96        40          5           5                                       
97        40          5           5                                       
98        40          5           5                                       
99        40          5           5                                       
100       40          5           5                                       
101       40          5           5                                       
102       40          5           5                                       
103       40          5           5                                       
104       40          5           5                                       
105       40          5           5                                       
106       40          5           5                                       
107       40          5           5                                       
108       40          5           5                                       
109       40          5           5                                       
110       40          5           5                                       
111       40          5           5                                       
112       40          5           5                                       
113       40          5           5                                       
114       40          5           5                                       
115       40          5           5                                       
116       40          5           5                                       
117       40          5           5                                       
118       40          5           5                                       
119       40          5           5                                       
120       40          5           5                                       
121       40          5           5                                       
122       40          5           5                                       
123       40          5           5                                       
124       40          5           5                                       
125       40          5           5                                       
126       40          5           5                                       
127       40          5           5                                       
128       40          5           5                                       
129       40          5           5                                       
130       40          5           5                                       
131       40          5           5                                       
132       40          5           5                                       
133       40          5           5                                       
134       40          5           5                                       
______________________________________                                    
 
    
     TEXT EXAMPLE 3 
     Foliage treatment test in plow field 
     Plow-field soil was filled in a cylindrical plastic pot (diameter, 10 cm; depth, 10 cm), and the seeds of Japanese millet, oat, radish and velvetleaf were sowed and cultivated for 10 days in a greenhouse. Thereafter, the prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with a spreading agent-containing water of an amount corresponding to 10 liters/are, and foliage-applied to the test plants over the top by means of a small-sized sprayer. After treatment, the test plants were cultivated for 20 days in a greenhouse to examine the herbicidal activity. The results are shown in Table 21. 
     
                       TABLE 21                                                    
______________________________________                                    
            Herbicidal activity                                           
Compound                                                                  
        Dosage    Japanese                                                
No.     (g/are)   millet   Oat  Radish Velvetleaf                         
______________________________________                                    
2       40        5        5    5      5                                  
3       40        5        5    5      --                                 
11      40        5        5    5      5                                  
12      40        5        5    5      5                                  
13      40        5        5    5      5                                  
20      40        5        5    5      5                                  
21      40        5        5    5      5                                  
22      40        5        5    5      5                                  
23      40        5        5    5      5                                  
24      40        5        5    5      5                                  
25      40        5        5    5      5                                  
26      40        5        5    5      --                                 
28      40        5        5    5      --                                 
29      40        5        5    5      --                                 
30      40        5        5    5      --                                 
33      40        5        5    5      4                                  
41      40        5        5    5      --                                 
54      40        5        5    5      4                                  
56      40        5        5    5      4                                  
86      40        5        5    5      5                                  
87      40        5        5    5      5                                  
88      40        5        5    5      5                                  
89      40        5        5    5      4                                  
91      40        5        5    5      --                                 
92      40        5        5    5      5                                  
93      40        5        5    5      4                                  
95      40        5        5    5      4                                  
97      40        5        5    4      --                                 
98      40        5        5    5      --                                 
99      40        5        5    5      --                                 
100     40        5        5    5      --                                 
101     40        5        5    5      4                                  
102     40        5        5    5      4                                  
103     40        5        5    --     --                                 
105     40        5        5    5      --                                 
106     40        5        5    5      --                                 
107     40        5        5    5      --                                 
108     40        5        5    4      4                                  
109     40        5        5    --     --                                 
110     40        5        5    --     --                                 
111     40        5        5    5      5                                  
114     40        5        5    5      --                                 
______________________________________                                    
 
    
     TEST EXAMPLE 4 
     Foliage treatment test in plow field 
     Plow-field soil was filled in a cylindrical plastic pot (diameter, 10 cm; depth, 10 cm), and the seeds of radish and velvetleaf were sowed and cultivated for 10 days in a greenhouse. Thereafter, the prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with a spreading agent-containing water of an amount corresponding to 10 liters/are, and foliage-applied to the test plants over the top by means of a small-sized sprayer. After treatment, the test plants were cultivated for 20 days in a greenhouse to examine the herbicidal activity. The results are shown in Table 22. 
     
                       TABLE 22                                                    
______________________________________                                    
Compound   Dosage      Herbicidal activity                                
No.        (g/are)     Radish  Velvetleaf                                 
______________________________________                                    
11         20          5       5                                          
12         20          5       5                                          
13         20          5       5                                          
20         20          5       5                                          
21         20          5       5                                          
22         20          5       5                                          
23         20          5       5                                          
24         20          5       5                                          
25         20          5       5                                          
B          20          0       0                                          
______________________________________                                    
 
    
     TEST EXAMPLE 5 
     Treatment test under flooded condition in paddy field 
     Paddy-field soil was filled in a cylindrical plastic pot (diameter, 8 cm; depth, 12 cm), and the seeds of barnyardgrass were incorporated from 1 to 2 cm deep in the soil. After creating the state of paddy field by flooding, the test plants were cultivated in a greenhouse. After 6 days (initial stage of emergence of weeds), the prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with 5 ml of water, and applied to the water surface. After treatment, the test plants were cultivated for 20 days in a greenhouse to examine the herbicidal activity. The results are shown in Table 23. 
     
                       TABLE 23                                                    
______________________________________                                    
Compound      Dosage   Herbicidal activity                                
No.           (g/are) Barnyardgrass                                       
______________________________________                                    
1             40      5                                                   
2             40      5                                                   
3             40      5                                                   
4             40      5                                                   
5             40      5                                                   
6             40      5                                                   
7             40      5                                                   
8             40      5                                                   
9             40      5                                                   
10            40      5                                                   
11            40      5                                                   
12            40      5                                                   
13            40      5                                                   
14            40      5                                                   
15            40      5                                                   
16            40      5                                                   
17            40      5                                                   
18            40      5                                                   
19            40      5                                                   
20            40      5                                                   
21            40      5                                                   
22            40      5                                                   
23            40      5                                                   
24            40      5                                                   
25            40      5                                                   
26            40      5                                                   
27            40      5                                                   
28            40      5                                                   
29            40      5                                                   
30            40      5                                                   
31            40      5                                                   
32            40      5                                                   
33            40      5                                                   
34            40      5                                                   
35            40      5                                                   
36            40      5                                                   
37            40      5                                                   
38            40      5                                                   
39            40      5                                                   
40            40      5                                                   
41            40      5                                                   
42            40      5                                                   
43            40      5                                                   
44            40      5                                                   
45            40      5                                                   
46            40      5                                                   
47            40      5                                                   
48            40      5                                                   
49            40      5                                                   
50            40      5                                                   
51            40      5                                                   
52            40      5                                                   
53            40      5                                                   
54            40      5                                                   
55            40      5                                                   
56            40      5                                                   
57            40      5                                                   
58            40      5                                                   
59            40      5                                                   
60            40      5                                                   
61            40      5                                                   
62            40      5                                                   
63            40      5                                                   
64            40      5                                                   
65            40      5                                                   
66            40      5                                                   
67            40      5                                                   
68            40      5                                                   
69            40      5                                                   
70            40      5                                                   
71            40      5                                                   
72            40      5                                                   
73            40      5                                                   
74            40      5                                                   
75            40      5                                                   
76            40      5                                                   
77            40      5                                                   
78            40      5                                                   
79            40      5                                                   
80            40      5                                                   
81            40      5                                                   
82            40      5                                                   
83            40      5                                                   
84            40      5                                                   
85            40      5                                                   
86            40      5                                                   
87            40      5                                                   
88            40      5                                                   
89            40      5                                                   
90            40      5                                                   
91            40      5                                                   
92            40      5                                                   
93            40      5                                                   
94            40      5                                                   
95            40      5                                                   
96            40      5                                                   
97            40      5                                                   
98            40      5                                                   
99            40      5                                                   
100           40      5                                                   
101           40      5                                                   
102           40      5                                                   
103           40      5                                                   
104           40      5                                                   
105           40      5                                                   
106           40      5                                                   
107           40      5                                                   
108           40      5                                                   
109           40      5                                                   
110           40      5                                                   
111           40      5                                                   
112           40      5                                                   
113           40      5                                                   
114           40      5                                                   
115           40      5                                                   
116           40      5                                                   
117           40      5                                                   
118           40      5                                                   
119           40      5                                                   
120           40      5                                                   
121           40      5                                                   
122           40      5                                                   
123           40      5                                                   
124           40      5                                                   
125           40      5                                                   
126           40      5                                                   
127           40      5                                                   
128           40      5                                                   
129           40      5                                                   
130           40      5                                                   
131           40      5                                                   
132           40      5                                                   
133           40      5                                                   
134           40      5                                                   
______________________________________                                    
 
    
     TEST EXAMPLE 6 
     Soil treatment test in plow field 
     Plow-field soil was filled in a vat (area, 33×23 cm 2  ; depth, 11 cm), and the seeds of soybean, cotton, barnyardgrass, johnsongrass and green foxtail were sowed and covered from 1 to 2 cm deep with the soil. The prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with water of an amount corresponding to 10 liters/are, and applied to the soil surface by means of a small-sized sprayer. After treatment, the test plants were cultivated for 20 days in a greenhouse to examine the herbicidal activity. The results are shown in Table 24. 
     
                                           TABLE 24                                
__________________________________________________________________________
Compound                                                                  
      Dosage                                                              
          Herbicidal activity                                             
No.   (g/are)                                                             
          Soybean                                                         
               Cotton                                                     
                   Barnyardgrass                                          
                           Johnsongrass                                   
                                  Green foxtail                           
__________________________________________________________________________
 2    2.5 0    0   5       5      5                                       
      0.63                                                                
          0    0   4       --     4                                       
32    2.5 0    0   5       4      5                                       
      0.63                                                                
          0    0   --      3      5                                       
33    2.5 0    0   5       5      5                                       
41    2.5 0    0   5       4      5                                       
      0.63                                                                
          0    0   4       --     5                                       
59    2.5 0    0   5       4      5                                       
70    2.5 0    0   5       5      5                                       
      0.63                                                                
          0    0   3       --     --                                      
74    2.5 0    0   5       5      5                                       
      0.63                                                                
          0    0   3       3      --                                      
77    2.5 0    0   5       4      4                                       
98    2.5 0    0   5       5      5                                       
      0.63                                                                
          0    0   5       4      5                                       
99    2.5 0    0   5       4      5                                       
      0.63                                                                
          0    0   4       --     4                                       
100   2.5 0    0   4       4      5                                       
      0.63                                                                
          0    0   --      3      3                                       
A     2.5 0    0   0       1      0                                       
      0.63                                                                
          0    0   0       0      0                                       
B     2.5 0    0   2       1      2                                       
      0.63                                                                
          0    0   0       0      0                                       
__________________________________________________________________________
 
    
     TEST EXAMPLE 7 
     Soil treatment test in plow field 
     Plow-field soil was filled in a vat (area, 33×23 cm 2  ; depth, 11 cm), and the seeds of corn, barnyardgrass, large crabgrass, johnsongrass, green foxtail, oat and fall panicum were sowed and covered from 1 to 2 cm deep with the soil. The prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with water of an amount corresponding to 10 liters/are, and applied to the soil surface by means of a small-sized sprayer. After treatment, the test plants were cultivated for 20 days in a greenhouse to examine the herbicidal activity. The results are shown in Table 25. 
     
                                           TABLE 25                                
__________________________________________________________________________
Compound                                                                  
      Dosage                                                              
          Herbicidal activity                                             
No.   (g/are)                                                             
          Corn                                                            
             Barnyardgrass                                                
                     Large crabgrass                                      
                             Johnsongrass                                 
                                    Green foxtail                         
                                           Oat                            
                                              Fall panicum                
__________________________________________________________________________
 2    2.5 0  5       5       4      5      4  5                           
26    2.5 0  5       5       5      5      -- --                          
70    2.5 0  5       4       5      5      5  5                           
A     2.5 0  0       1       1      0      0  1                           
C     2.5 0  3       1       1      1      0  5                           
__________________________________________________________________________
 
    
     TEST EXAMPLE 8 
     Soil treatment test in plow field 
     Plow-field soil was filled in a vat (area, 33×23 cm 2  ; depth, 11 cm), and the seeds of wheat, barley, wild oat, blackgrass and annual bluegrass were sowed and covered from 1 to 2 cm deep with the soil. The prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with water of an amount corresponding to 10 liters/are, and applied to the soil surface by means of a small-sized sprayer. After treatment, the test plants were cultivated for 30 days in a greenhouse to examine the herbicidal activity. The results are shown in Table 26. 
     
                       TABLE 26                                                    
______________________________________                                    
          Herbicidal activity                                             
Compound                                                                  
        Dosage                Wild  Black-                                
                                          Annual                          
No.     (g/are) Wheat   Barley                                            
                              oat   grass bluegrass                       
______________________________________                                    
2       2.5     --      0     5     5     5                               
         0.63   1       0     4     5     5                               
26      2.5     0       0     --    5     4                               
70      2.5     1       0     4     4     5                               
B       2.5     1       0     0     2     0                               
         0.63   0       0     0     0     0                               
______________________________________                                    
 
    
     TEST EXAMPLE 9 
     Foliage treatment test in plow field 
     Plow-field soil was filled in a vat (area, 33×23 cm 2  ; depth, 11 cm), and the seeds of soybean, cotton, barnyardgrass, large crabgrass, johnsongrass, green foxtail, oat and annual bluegrass were sowed and cultivated for 18 days. Thereafter, the prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with a spreading agent-containing water of an amount corresponding to 5 liters/are, and uniformly applied to the entire foliage of the test plants over the top by means of a small-sized sprayer. The state of growth of the weeds and crops at that time varied with the kind thereof, but they were in a cotyledonous stage to 3-leaf stage and from 5 to 19 cm in height. Twenty days after treatment, the herbicidal activity was examined. The results are shown in Table 27. These tests were carried out in a greenhouse through the entire period of test. 
     
                                           TABLE 27                                
__________________________________________________________________________
Compound                                                                  
      Dosage                                                              
           Herbicidal activity                                            
No.   (g/are)                                                             
           Soybean                                                        
                Cotton                                                    
                    Barnyardgrass                                         
                            Large crabgrass                               
                                    Johnsongrass                          
                                           Green foxtail                  
                                                  Oat Annual              
__________________________________________________________________________
                                                      bluegrass           
32    2.5  0    0   5       5       5      5      5   3                   
      0.63 0    0   4       4       5      4      4   --                  
41    2.5  0    0   5       5       5      5      5   4                   
      0.63 0    0   5       4       4      4      5   3                   
51    2.5  0    0   5       5       5      5      5   3                   
      0.63 0    0   5       4       --     5      4   --                  
54    2.5  0    0   5       5       5      5      5   --                  
      0.63 0    0   5       4       5      5      5   --                  
59    2.5  0    0   5       5       5      5      5   --                  
      0.63 0    0   5       5       5      4      4   --                  
70    2.5  0    0   5       5       5      5      5   3                   
      0.63 0    0   5       4       4      3      4   --                  
74    2.5  0    0   5       5       5      5      4   4                   
      0.63 0    0   5       4       5      4      4   3                   
75    2.5  0    0   5       5       5      5      4   4                   
      0.63 0    0   5       4       5      3      4   3                   
79    2.5  0    0   5       4       4      3      5   --                  
      0.63 0    0   5       --      3      --     4   --                  
A     2.5  0    0   3       1       2      3      3   2                   
      0.63 0    0   1       0       0      1      0   0                   
B     2.5  0    0   3       1       2      3      3   3                   
      0.63 0    0   2       0       0      2      0   0                   
__________________________________________________________________________
 
    
     TEST EXAMPLE 10 
     Foliage treatment test in plow field 
     Plow-field soil was filled in a vat (area, 33×23 cm 2  ; depth, 11 cm), and the seeds of soybean, cotton, large crabgrass, johnsongrass, green foxtail, oat and annual bluegrass were sowed and cultivated for 18 days. Thereafter, the prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with a spreading agent-containing water of an amount corresponding to 10 liters/are, and uniformly applied to the entire foliage of the test plants over the top by means of a small-sized sprayer. The state of growth of the weeds and crops at that time varied with the kind thereof, but they were in a cotyledonous stage to 3-leaf stage and from 5 to 19 cm in height. Twenty days after treatment, the herbicidal activity was examined. The results are shown in Table 28. These tests were carried out in a greenhouse through the entire period of test. 
     
                                           TABLE 28                                
__________________________________________________________________________
Compound                                                                  
      Dosage                                                              
          Herbicidal activity                                             
No.   (g/are)                                                             
          Soybean                                                         
               Cotton                                                     
                   Large crabgrass                                        
                           Johnsongrass                                   
                                  Green foxtail                           
                                         Oat                              
                                            Annual bluegrass              
__________________________________________________________________________
33    2.5 0    0   5       5      5      5  4                             
      0.63                                                                
          0    0   5       5      5      5  4                             
56    2.5 0    0   5       4      5      5  3                             
      0.63                                                                
          0    0   --      4      4      5  --                            
C     2.5 0    0   4       3      4      4  0                             
      0.63                                                                
          0    0   3       1      3      3  0                             
__________________________________________________________________________
 
    
     TEST EXAMPLE 11 
     Foliage treatment test in plow field 
     Plow-field soil was filled in a vat (area, 33×23 cm 2  ; depth, 11 cm), and the seeds of soybean, cotton, barnyardgrass, large crabgrass, johnsongrass, green foxtail, oat, annual bluegrass and blackgrass were sowed and cultivated for 18 days. Thereafter, the prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with a spreading agent-containing water of an amount corresponding to 5 liters/are, and uniformly applied to the entire foliage of the test plants over the top by means of a small-sized sprayer. The state of growth of the weeds and crops at that time varied with the kind thereof, but they were in a cotyledonous stage to 3-leaf stage and from 5 to 19 cm in height. Twenty days after treatment, the herbicidal activity was examined. The results are shown in Table 29. These tests were carried out in a greenhouse through the entire period of test. 
     
                                           TABLE 29                                
__________________________________________________________________________
          Herbicidal activity                                             
Compound                                                                  
      Dosage                                       Annual                 
No.   (g/are)                                                             
          Soybean                                                         
               Cotton                                                     
                   Barnyardgrass                                          
                           Crabgrass                                      
                                 Johnsongrass                             
                                        Green foxtail                     
                                               Oat bluegrass              
                                                         Blackgrass       
__________________________________________________________________________
89    2.5 0    0   5       5     5      5      5   4     5                
      0.63                                                                
          0    0   5       4     4      4      5   --    4                
91    2.5 0    0   5       5     5      5      5   4     5                
      0.63                                                                
          0    0   5       5     4      5      4   --    --               
92    2.5 0    0   5       5     5      5      5   4     5                
      0.63                                                                
          0    0   5       4     5      5      4   --    4                
93    2.5 0    0   5       5     5      5      5   4     5                
      0.63                                                                
          0    0   5       5     5      4      5   4     4                
97    2.5 0    0   5       5     5      5      5   --    5                
      0.63                                                                
          0    0   5       4     4      5      4   --    4                
98    2.5 0    0   5       5     5      5      5   --    5                
      0.63                                                                
          0    0   5       4     5      5      5   --    4                
A     2.5 0    0   3       1     2      3      3   2     2                
      0.63                                                                
          0    0   1       0     0      1      0   0     0                
B     2.5 0    0   3       1     2      3      3   3     3                
      0.63                                                                
          0    0   2       0     0      2      0   0     0                
D     2.5 --   --  1       0     0      0      0   0     0                
      0.63                                                                
          --   --  0       0     0      0      0   0     0                
__________________________________________________________________________
 
    
     TEST EXAMPLE 12 
     Foliage treatment test in plow field 
     Plow-field soil was filled in a vat (area, 33×23 cm 2  ; depth, 11 cm), and the seeds of cotton, barnyardgrass, large crabgrass, johnsongrass, green foxtail, oat, annual bluegrass and blackgrass were sowed and cultivated for 18 days. Thereafter, the prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with a spreading agent-containing water of an amount corresponding to 10 liters/are, and uniformly applied to the entire foliage of the test plants over the top by means of a small-sized sprayer. The state of growth of the weeds and crops at that time varied with the kind thereof, but they were in a cotyledonous stage to 3-leaf stage and from 7 to 15 cm in height. Twenty days after treatment, the herbicidal activity was examined. The results are shown in Table 30. These tests were carried out in a greenhouse through the entire period of test. 
     
                                           TABLE 30                                
__________________________________________________________________________
Compound                                                                  
      Dosage                                                              
          Herbicidal activity                                             
No.   (g/are)                                                             
          Cotton                                                          
              Barnyardgrass                                               
                      Large crabgrass                                     
                              Johnsongrass                                
                                     Green foxtail                        
                                            Oat Annual bluegrass          
                                                         Blackgrass       
__________________________________________________________________________
2     2.5 0   5       5       5      5      5   4        5                
      0.63                                                                
          0   5       4       5      5      5   --       4                
A     2.5 0   3       1       2      3      3   2        2                
      0.63                                                                
          0   1       0       0      1      0   0        0                
B     2.5 0   3       1       2      3      3   3        3                
      0.63                                                                
          0   2       0       0      2      0   0        0                
D     2.5 --  1       0       0      0      0   0        0                
      0.63                                                                
          --  0       0       0      0      0   0        0                
__________________________________________________________________________
 
    
     TEST EXAMPLE 13 
     Foliage treatment test in plow field 
     Plow-field soil was filled in a vat (area, 33×23 cm 2  ; depth, 11 cm), and the seeds of corn, barnyardgrass, large crabgrass, johnsongrass, green foxtail and oat were sowed and cultivated for 18 days. Thereafter, the prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with water of an amount corresponding to 10 liters/are, and uniformly applied to the entire foliage of the test plants over the top by means of a small-sized sprayer. The state of growth of the weeds and crops at that time varied with the kind thereof, but they were in a 1 to 2-leaf stage and from 7 to 15 cm in height. Twenty days after treatment, the herbicidal activity was examined. The results are shown in Table 31. These tests were carried out in a greenhouse through the entire period of test. 
     
                       TABLE 31                                                    
______________________________________                                    
        Herbicidal activity                                               
Com-                 Barn-        John-                                   
pound Dosage         yard- Large  son-  Green                             
No.   (g/are) Corn   grass crabgrass                                      
                                  grass foxtail                           
                                              Oat                         
______________________________________                                    
 2    0.63    1      5     4      5     5     4                           
      0.16    0      4     --     4     4     4                           
 3    0.63    0      5     4      3     4     3                           
26    0.63    1      5     4      3     5     4                           
70    0.63    1      5     3      4     5     4                           
79    0.63    0      5     4      4     4     4                           
C     0.63    3      5     2      1     4     3                           
      0.16    1      4     0      1     3     0                           
______________________________________                                    
 
    
     TEST EXAMPLE 14 
     Foliage treatment test in plow field 
     Plow-field soil was filled in a vat (area, 15×10 cm 2  ; depth, 7 cm), and the seeds of corn, barnyardgrass, large crabgrass, and green foxtail were sowed and cultivated for 14 days. Thereafter, the prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with water of an amount corresponding to 6 liters/are, and uniformly applied to the entire foliage of the test plants over the top by means of a small-sized sprayer. The state of growth of the weeds and crops at that time varied with the kind thereof, but they were in a 1 to 4-leaf stage and from 2 to 42 cm in height. Fifteen days after treatment, the herbicidal activity was examined. The results are shown in Table 32. These tests were carried out in a greenhouse through the entire period of test. 
     
                       TABLE 32                                                    
______________________________________                                    
          Herbicidal activity                                             
Compound                                                                  
        Dosage                    Large  Green                            
No.     (g/are) Corn    Barnyardgrass                                     
                                  crabgrass                               
                                         foxtail                          
______________________________________                                    
2       0.75    0       5         5      5                                
70      0.75    0       5         4      5                                
A       0.75    1       1         0      0                                
C       0.75    2       5         3      4                                
______________________________________                                    
 
    
     TEST EXAMPLE 15 
     Foliage treatment test in plow field 
     Plow-field soil was filled in a vat (area, 33×23 cm 2  ; depth, 11 cm), and the seeds of tall morningglory, common cocklebur, velvetleaf, common chickweed, black nightshade and redroot pigweed were sowed and cultivated for 18 days. Thereafter, the prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with a spreading agent-containing water of an amount corresponding to 10 liters/are, and uniformly applied to the entire foliage of the test plants over the top by means of a small-sized sprayer. The state of growth of the weeds and crops at that time varied with the kind thereof, but they were in a 1 to 2-leaf stage and from 3 to 10 cm in height. Twenty days after treatment, the herbicidal activity was examined. The results are shown in Table 33. These tests were carried out in a greenhouse through the entire period of test. 
     
                                           TABLE 33                                
__________________________________________________________________________
           Herbicidal activity                                            
Compound                                                                  
      Dosage                                                              
           Tall                                                           
No.   (g/are)                                                             
           morningglory                                                   
                  Common cocklebur                                        
                            Velvetleaf                                    
                                   Common chickweed                       
                                             Black nightshade             
                                                      Redroot             
__________________________________________________________________________
                                                      pigweed             
2     10   5      4         4      5         4        4                   
B     10   0      0         0      0         0        0                   
__________________________________________________________________________
 
    
     TEST EXAMPLE 16 
     Treatment test under flooded condition in paddy field 
     Paddy-field soil was filled in 1/5000 area Wagner&#39;s pots, and the seeds of barnyardgrass were incorporated from 1 to 2 cm deep in the soil. After creating the state of paddy field by flooding, rice plants in a 3-leaf stage were transplanted and cultivated in a greenhouse. After 4 days, the prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with 10 ml of water and applied to the water surface, and the depth of water was made 4 cm. After treatment, the test plants were cultivated for 20 days in a greenhouse to examine the herbicidal activity and phytotoxicity. The results are shown in Table 34. In this test, water leakage corresponding to a water level of 3 cm/day was carried out for 2 days from the day subsequent to the treatment. 
     
                       TABLE 34                                                    
______________________________________                                    
Compound  Dosage      Herbicidal activity                                 
No.       (g/are)     Rice   Barnyardgrass                                
______________________________________                                    
 2        1.25        0      5                                            
          0.32        0      4                                            
10        1.25        0      5                                            
          0.32        0      4                                            
28        1.25        1      5                                            
          0.32        0      4                                            
29        1.25        0      5                                            
          0.32        0      4                                            
30        1.25        0      5                                            
          0.32        0      5                                            
51        1.25        1      5                                            
          0.32        0      4                                            
70        1.25        1      5                                            
          0.32        0      5                                            
74        1.25        1      5                                            
          0.32        0      5                                            
87        1.25        0      5                                            
          0.32        0      5                                            
98        1.25        0      5                                            
          0.32        0      5                                            
99        1.25        0      5                                            
          0.32        0      5                                            
100       1.25        0      5                                            
          0.32        0      5                                            
E         1.25        1      2                                            
          0.32        0      0                                            
______________________________________                                    
 
    
     TEST EXAMPLE 17 
     Foliage treatment test in plow field 
     Plow-field soil was filled in a concrete-pot (area, 40×35 cm 2  ; depth, 35 cm), and the seeds of wheat, annual bluegrass, wild oat and blackgrass were sowed and cultivated for 41 days. Thereafter, the prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with water of an amount corresponding to 7 liters/are, and uniformly applied to the entire foliage of the test plants over the top by means of a small-sized sprayer. The state of growth of the weeds and crops at that time varied with the kind thereof, but they were in a 2 to 3-leaf stage. Twenty-one days after treatment, the herbicidal activity was examined. The results are shown in Table 35. These tests were carried out in outdoors through the entire period of test. 
     
                       TABLE 35                                                    
______________________________________                                    
            Herbicidal activity                                           
Compound Dosage           Annual Wild                                     
No.      (g/are)  Wheat   bluegrass                                       
                                 oat   Blackgrass                         
______________________________________                                    
2        0.3      0       4      4     4                                  
F        0.3      0       0      1     1                                  
______________________________________                                    
 
    
     TEST EXAMPLE 18 
     Foliage treatment test in plow field 
     In plow-field wherein ridging was carried out so that the upper row space was 1 meter were sowed the seeds of corn, johnsongrass, green foxtail, large crabgrass and barnyardgrass. When the corn grew to a 4-leaf stage and the weeds grew to a 2 to 4-leaf stage, the rows were partitioned into test plots of 3 m 2  in area. Thereafter, the prescribed amount of the emulsifiable concentrates of the test compounds prepared according to Formulation example 2 was diluted with water of an amount corresponding to 3 liters/are and foliage-applied to the whole surface of the test plots by means of a small-sized sprayer (three replications). After 30 days, the herbicidal activity was examined. The results are shown in Table 36. 
     
                       TABLE 36                                                    
______________________________________                                    
Com-          Herbicidal activity                                         
pound Dosage         Johnson-                                             
                            Green Large  Barnyard-                        
No.   (g/are) Corn   grass  foxtail                                       
                                  crabgrass                               
                                         grass                            
______________________________________                                    
2      1      0      4      5     5      5                                
D     20      0      0      4     4      3                                
______________________________________