Patent Publication Number: US-2022216430-A1

Title: Multi-component host material and an organic electroluminescence device comprising the same

Description:
CLAIM OF BENEFIT OF PRIOR APPLICATION 
     This application claims priority under 35 U.S.C. § 120 from U.S. patent application Ser. No. 15/301,975, filed Oct. 5, 2016, which is the National Stage Entry of PCT/KR2015/003890, filed Apr. 17, 2015, both of which are incorporated by reference herein in their entirety. 
    
    
     TECHNICAL FIELD 
     The present invention relates to a multi-component host material and an organic electroluminescence device comprising the same. 
     BACKGROUND ART 
     An electroluminescence device (EL device) is a self-light-emitting device which has advantages in that it provides a wider viewing angle, a greater contrast ratio, and a faster response time. An organic EL device was first developed by Eastman Kodak, by using small aromatic diamine molecules, and aluminum complexes as materials for forming a light-emitting layer [Appl. Phys. Lett. 51, 913, 1987]. 
     An organic EL device (OLED) is a device changing electronic energy to light by applying electricity to an organic electroluminescent material, and generally has a structure comprising an anode, a cathode, and an organic layer between the anode and the cathode. The organic layer of an organic EL device may be comprised of a hole injection layer, a hole transport layer, an electron blocking layer, a light-emitting layer (which comprises host and dopant materials), an electron buffer layer, a hole blocking layer, an electron transport layer, an electron injection layer, etc., and the materials used for the organic layer are categorized by their functions in hole injection material, hole transport material, electron blocking material, light-emitting material, electron buffer material, hole blocking material, electron transport material, electron injection material, etc. In the organic EL device, due to an application of a voltage, holes are injected from the anode to the light-emitting layer, electrons are injected from the cathode to the light-emitting layer, and excitons of high energies are formed by a recombination of the holes and the electrons. By this energy, luminescent organic compounds reach an excited state, and light emission occurs by emitting light from energy due to the excited state of the luminescent organic compounds returning to a ground state. 
     The most important factor determining luminous efficiency in an organic EL device is the light-emitting material. A light-emitting material must have high quantum efficiency, high electron and hole mobility, and the formed light-emitting material layer must be uniform and stable. Light-emitting materials are categorized into blue, green, and red light-emitting materials dependent on the color of the light emission, additionally yellow or orange light-emitting materials. In addition, Light-emitting materials can also be categorized into host and dopant materials according to their functions. Recently, the development of an organic EL device providing high efficiency and long lifespan is an urgent issue. In particular, considering EL characteristic requirements for a middle or large-sized panel of OLED, materials showing better characteristics than conventional ones must be urgently developed. The host material which acts as a solvent in a solid state and transfers energy needs to have high purity and a molecular weight appropriate for vacuum deposition. Furthermore, the host material needs to have high glass transition temperature and high thermal degradation temperature to achieve thermal stability, high electro-chemical stability to achieve long lifespan, ease of forming amorphous thin film, good adhesion to materials of adjacent layers, and non-migration to other layers. 
     A light-emitting material can be used as a combination of a host and a dopant to improve color purity, luminous efficiency, and stability. Generally, an EL device having excellent characteristics has a structure comprising a light-emitting layer formed by doping a dopant to a host. Since host materials greatly influence the efficiency and lifespan of the EL device when using a dopant/host material system as a light emitting material, their selection is important. 
     International Publication Nos. WO 2013/168688 A1 and WO 2009/060757 A1, and Japanese Patent Appln. Laying-Open No. 2013-183036 A1, etc. disclose organic electroluminescent devices using a biscarbazole derivative as a host material. However, the references fail to disclose an organic electroluminescent device using a multi-component host comprising a biscarbazole derivative and a carbazole derivative including a nitrogen-containing heteroaryl. 
     DISCLOSURE OF THE INVENTION 
     Problems to be Solved 
     The objective of the present invention is to provide an organic electroluminescent device having high efficiency and long lifespan. 
     Solution to Problems 
     The present inventors found that the above objective can be achieved by an organic electroluminescent device comprising at least one light-emitting layer between an anode and a cathode, wherein the light-emitting layer comprises a host and a phosphorescent dopant, the host consists of multi-component host compounds, at least a first host compound of the multi-component host compounds is represented by the following formula 1, and a second host compound is represented by the following formula 2: 
     
       
         
         
             
             
         
       
     
     wherein 
     A 1  and A 2  each independently represent a substituted or unsubstituted (C6-C30)aryl; 
     L 1  represents a substituted or unsubstituted (C6-C30)arylene; 
     X 1  to X 16  each independently represent hydrogen, deuterium, a halogen, a cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C2-C30)alkenyl, a substituted or unsubstituted (C2-C30)alkynyl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C6-C60)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, a substituted or unsubstituted tri(C1-C30)alkylsilyl, a substituted or unsubstituted tri(C6-C30)arylsilyl, a substituted or unsubstituted di(C1-C30)alkyl(C6-C30)arylsilyl, a substituted or unsubstituted (C1-C30)alkyldi(C6-C30)arylsilyl, or a substituted or unsubstituted mono- or di-(C6-C30)arylamino; or are linked to an adjacent substituent(s) to form a substituted or unsubstituted, mono- or polycyclic, (C3-C30) alicyclic or aromatic ring, whose carbon atom(s) may be replaced with at least one hetero atom selected from nitrogen, oxygen and sulfur; 
     
       
         
         
             
             
         
       
     
     wherein 
     Ma represents a substituted or unsubstituted nitrogen-containing (5- to 11-membered)heteroaryl; 
     La represents a single bond, or a substituted or unsubstituted (C6-C30)arylene; 
     Xa to Xh each independently represent hydrogen, deuterium, a halogen, a cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C2-C30)alkenyl, a substituted or unsubstituted (C2-C30)alkynyl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C6-C60)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, a substituted or unsubstituted tri(C1-C30)alkylsilyl, a substituted or unsubstituted tri(C6-C30)arylsilyl, a substituted or unsubstituted di(C1-C30)alkyl(C6-C30)arylsilyl, or a substituted or unsubstituted mono- or di-(C6-C30)arylamino; or are linked to an adjacent substituent(s) to form a substituted or unsubstituted, mono- or polycyclic, (C3-C30) alicyclic or aromatic ring, whose carbon atom(s) may be replaced with at least one hetero atom selected from nitrogen, oxygen and sulfur; and 
     the heteroaryl contains at least one hetero atom selected from B, N, O, S, P(═O), Si, and P. 
     EFFECTS OF THE INVENTION 
     According to the present invention, an organic electroluminescent device having high efficiency and long lifespan is provided, and it is possible to manufacture a display device or a lighting device using the organic electroluminescent device. 
    
    
     EMBODIMENTS OF THE INVENTION 
     Hereinafter, the present invention will be described in detail. However, the following description is intended to explain the invention, and is not meant in any way to restrict the scope of the invention. 
     Hereinafter, the organic electroluminescent device comprising the organic electroluminescent compounds of formulae 1 and 2 will be described in detail. 
     The compound represented by formula 1 can be represented by formula 3, 4, 5, or 6: 
     
       
         
         
             
             
         
       
     
     wherein 
     A 1 , A 2 , L 1 , and X 1  to X16 are as defined in formula 1. 
     In formula 1 above, A 1  and A 2  each independently represent a substituted or unsubstituted (C6-C30)aryl, preferably, each independently represent a substituted or unsubstituted (C6-C18)aryl, more preferably, each independently represent a (C6-C18)aryl unsubstituted or substituted with a cyano, a (C1-C6)alkyl, a (C6-C12)aryl, or a tri(C6-C12)arylsilyl, and even more preferably, each independently represent phenyl, biphenyl, terphenyl, naphthyl, fluorenyl, phenanthrenyl, anthracenyl, indenyl, triphenylenyl, pyrenyl, tetracenyl, perylenyl, chrysenyl, or fluoranthenyl. 
     In formula 1 above, X 1  to X 16  each independently represent hydrogen, deuterium, a halogen, a cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C2-C30)alkenyl, a substituted or unsubstituted (C2-C30)alkynyl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C6-C60)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, a substituted or unsubstituted tri(C1-C30)alkylsilyl, a substituted or unsubstituted tri(C6-C30)arylsilyl, a substituted or unsubstituted di(C1-C30)alkyl(C6-C30)arylsilyl, a substituted or unsubstituted (C1-C30)alkyldi(C6-C30)arylsilyl, or a substituted or unsubstituted mono- or di-(C6-C30)arylamino; or are linked to an adjacent substituent(s) to form a substituted or unsubstituted, mono- or polycyclic, (C3-C30) alicyclic or aromatic ring, whose carbon atom(s) may be replaced with at least one hetero atom selected from nitrogen, oxygen and sulfur, preferably, each independently represent hydrogen, a cyano, a substituted or unsubstituted (C6-C20)aryl, a substituted or unsubstituted (5- to 20-membered)heteroaryl, or a substituted or unsubstituted tri(C6-C12)arylsilyl, and more preferably, each independently represent hydrogen, a cyano, a (C6-C20)aryl unsubstituted or substituted with a cyano, an unsubstituted (5- to 20-membered)heteroaryl, or an unsubstituted tri(C6-C12)arylsilyl. 
     In formula 1 above, L 1  represents a substituted or unsubstituted (C6-C30)arylene, preferably, represents a substituted or unsubstituted (C6-C15)arylene, and more preferably, represents a (C6-C15)arylene unsubstituted or substituted with a cyano, a (C1-C6)alkyl, or a tri(C6-C12)arylsilyl. 
     In addition, L 1  can be represented by one of formulae 7 to 19: 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     wherein 
     Xi to Xp each independently represent hydrogen, deuterium, a halogen, a cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C2-C30)alkenyl, a substituted or unsubstituted (C2-C30)alkynyl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C6-C60)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, a substituted or unsubstituted tri(C1-C30)alkylsilyl, a substituted or unsubstituted tri(C6-C30)arylsilyl, a substituted or unsubstituted di(C1-C30)alkyl(C6-C30)arylsilyl, a substituted or unsubstituted (C1-C30)alkyldi(C6-C30)arylsilyl, or a substituted or unsubstituted mono- or di-(C6-C30)arylamino; or are linked to an adjacent substituent(s) to form a substituted or unsubstituted, mono- or polycyclic, (C3-C30) alicyclic or aromatic ring, whose carbon atom(s) may be replaced with at least one hetero atom selected from nitrogen, oxygen and sulfur. 
     Preferably, Xi to Xp may each independently represent hydrogen, a halogen, a cyano, a (C1-C10)alkyl, a (C3-C20)cycloalkyl, a (C6-C12)aryl, a (C1-C6)alkyldi(C6-C12)arylsilyl, or a tri(C6-C12)arylsilyl, and more preferably, each independently represent hydrogen, a cyano, a (C1-C6)alkyl, or a tri(C6-C12)arylsilyl. 
     In formula 2 above, Ma represents a substituted or unsubstituted nitrogen-containing (5- to 11-membered)heteroaryl, preferably, represents a substituted or unsubstituted nitrogen-containing (6- to 10-membered)heteroaryl, and more preferably, represents a nitrogen-containing (6- to 10-membered)heteroaryl substituted with an unsubstituted (C6-C18)aryl, a (C6-C12)aryl substituted with a cyano, a (C6-C12)aryl substituted with a (C1-C6)alkyl, a (C6-C12)aryl substituted with a tri(C6-C12)arylsilyl, or a (6- to 15-membered)heteroaryl. 
     In addition, Ma may represent a monocyclic heteroaryl selected from the group consisting of pyrrolyl, imidazolyl, pyrazolyl, triazinyl, tetrazinyl, triazolyl, tetrazolyl, pyridyl, pyrazinyl, pyrimidinyl, and pyridazinyl, or a fused heteroaryl selected from the group consisting of benzoimidazolyl, isoindolyl, indolyl, indazolyl, benzothiadiazolyl, quinolyl, isoquinolyl, cinnolinyl, quinazolinyl, naphthyridinyl, and quinoxalinyl, and preferably may represent triazinyl, pyrimidinyl, pyridyl, quinolyl, isoquinolyl, quinazolinyl, naphthyridinyl, or quinoxalinyl. 
     In formula 2 above, La represents a single bond, or a substituted or unsubstituted (C6-C30)arylene, preferably, represents a single bond, or a substituted or unsubstituted (C6-C12)arylene, and more preferably, represents a single bond, or a (C6-C12)arylene unsubstituted or substituted with a tri(C6-C10)arylsilyl. 
     In addition, La can represent a single bond, or be represented by one of formulae 7 to 19 as above. 
     In formula 2 above, Xa to Xh each independently represent hydrogen, deuterium, a halogen, a cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C2-C30)alkenyl, a substituted or unsubstituted (C2-C30)alkynyl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C6-C60)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, a substituted or unsubstituted tri(C1-C30)alkylsilyl, a substituted or unsubstituted tri(C6-C30)arylsilyl, a substituted or unsubstituted di(C1-C30)alkyl(C6-C30)arylsilyl, or a substituted or unsubstituted mono- or di-(C6-C30)arylamino; or are linked to an adjacent substituent(s) to form a substituted or unsubstituted, mono- or polycyclic, (C3-C30) alicyclic or aromatic ring, whose carbon atom(s) may be replaced with at least one hetero atom selected from nitrogen, oxygen and sulfur, preferably, each independently represent hydrogen, a cyano, a substituted or unsubstituted (C6-C15)aryl, a substituted or unsubstituted (10- to 20-membered)heteroaryl, or a substituted or unsubstituted tri(C6-C10)arylsilyl; or are linked to an adjacent substituent(s) to form a substituted or unsubstituted, mono- or polycyclic, (C6-C20) aromatic ring, and more preferably, each independently represent hydrogen; a cyano; a (C6-C15)aryl unsubstituted or substituted with a tri(C6-C10)arylsilyl; a (10- to 20-membered)heteroaryl unsubstituted or substituted with a (C6-C12)aryl or a cyano(C6-C12)aryl; or an unsubstituted tri(C6-C10)arylsilyl; or are linked to an adjacent substituent(s) to form a substituted or unsubstituted benzene, a substituted or unsubstituted indole, a substituted or unsubstituted benzoindole, a substituted or unsubstituted indene, a substituted or unsubstituted benzofuran, or a substituted or unsubstituted benzothiophene. 
     Herein, “(C1-C30)alkyl” is meant to be a linear or branched alkyl having 1 to 30 carbon atoms, in which the number of carbon atoms is preferably 1 to 20, more preferably 1 to 10, and includes methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, etc.; “(C2-C30)alkenyl” is meant to be a linear or branched alkenyl having 2 to 30 carbon atoms, in which the number of carbon atoms is preferably 2 to 20, more preferably 2 to 10, and includes vinyl, 1-propenyl, 2-propenyl, 1-butenyl, 2-butenyl, 3-butenyl, 2-methylbut-2-enyl, etc.; “(C2-C30)alkynyl” is meant to be a linear or branched alkynyl having 2 to 30 carbon atoms, in which the number of carbon atoms is preferably 2 to 20, more preferably 2 to 10, and includes ethynyl, 1-propynyl, 2-propynyl, 1-butynyl, 2-butynyl, 3-butynyl, 1-methylpent-2-ynyl, etc.; “(C3-C30)cycloalkyl” is a mono- or polycyclic hydrocarbon having 3 to 30 carbon atoms, in which the number of carbon atoms is preferably 3 to 20, more preferably 3 to 7, and includes cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, etc.; “(3- to 7-membered)heterocycloalkyl” is a cycloalkyl having 3 to 7 ring backbone atoms, preferably 5 to 7, including at least one heteroatom selected from B, N, 0, S, P(=0), Si and P, preferably O, S and N, and includes tetrahydrofuran, pyrrolidine, thiolan, tetrahydropyran, etc.; “(C6-C30)aryl(ene)” is a monocyclic or fused ring derived from an aromatic hydrocarbon having 6 to 30 carbon atoms, in which the number of carbon atoms is preferably 6 to 20, more preferably 6 to 15, and includes phenyl, biphenyl, terphenyl, naphthyl, binaphthyl, phenyl naphthyl, naphthylphenyl, fluorenyl, phenylfluorenyl, benzofluorenyl, dibenzofluorenyl, phenanthrenyl, phenylphenanthrenyl, anthracenyl, indenyl, triphenylenyl, pyrenyl, tetracenyl, perylenyl, chrysenyl, naphthacenyl, fluoranthenyl, etc.; “(3- to 30-membered)heteroaryl” is an aryl having 3 to 30 ring backbone atoms, including at least one, preferably 1 to 4 heteroatoms selected from the group consisting of B, N, O, S, P(=0), Si and P; is a monocyclic ring, or a fused ring condensed with at least one benzene ring; may be partially saturated; may be one formed by linking at least one heteroaryl or aryl group to a heteroaryl group via a single bond(s); and includes a monocyclic ring-type heteroaryl including furyl, thiophenyl, pyrrolyl, imidazolyl, pyrazolyl, thiazolyl, thiadiazolyl, isothiazolyl, isoxazolyl, oxazolyl, oxadiazolyl, triazinyl, tetrazinyl, triazolyl, tetrazolyl, furazanyl, pyridyl, pyrazinyl, pyrimidinyl, pyridazinyl, etc., and a fused ring-type heteroaryl including benzofuranyl, benzothiophenyl, isobenzofuranyl, dibenzofuranyl, dibenzothiophenyl, benzoimidazolyl, benzothiazolyl, benzoisothiazolyl, benzoisoxazolyl, benzoxazolyl, isoindolyl, indolyl, benzoindolyl, indazolyl, benzothiadiazolyl, quinolyl, isoquinolyl, cinnolinyl, quinazolinyl, quinoxalinyl, carbazolyl, phenoxazinyl, phenanthridinyl, benzodioxolyl, etc.; “nitrogen-containing (5- to 30-membered)heteroaryl” is an aryl having 5 to 30 ring backbone atoms, preferably 5 to 20, and more preferably 5 to 15, including at least one heteroatom, N; is a monocyclic ring, or a fused ring condensed with at least one benzene ring; may be partially saturated; may be one formed by linking at least one heteroaryl or aryl group to a heteroaryl group via a single bond(s); and includes a monocyclic ring-type heteroaryl including pyrrolyl, imidazolyl, pyrazolyl, triazinyl, tetrazinyl, triazolyl, tetrazolyl, pyridyl, pyrazinyl, pyrimidinyl, pyridazinyl, etc., and a fused ring-type heteroaryl including benzoimidazolyl, isoindolyl, indolyl, indazolyl, benzothiadiazolyl, quinolyl, isoquinolyl, cinnolinyl, quinazolinyl, quinoxalinyl, carbazolyl, phenanthridinyl, etc. Further, “halogen” includes F, CI, Br, and I. 
     Herein, “substituted” in the expression “substituted or unsubstituted” means that a hydrogen atom in a certain functional group is replaced with another atom or group, i.e. a substituent. The substituents of the substituted alkyl, the substituted alkenyl, the substituted alkynyl, the substituted cycloalkyl, the substituted aryl(ene), the substituted heteroaryl, the substituted trialkylsilyl, the substituted triarylsilyl, the substituted dialkylarylsilyl, the substituted alkyldiarylsilyl, the substituted mono- or di- arylamino, and the substituted nitrogen-containing heteroaryl in A 1 , A 2 , L 1 , X 1  to X 16 , Ma, La, and Xa to Xh in formulae 1 and 2 each independently are at least one selected from the group consisting of deuterium, a halogen, a cyano, a carboxyl, a nitro, a hydroxyl, a (C1-C30)alkyl, a halo(C1-C30)alkyl, a (C2-C30)alkenyl, a (C2-C30)alkynyl, a (C1-C30)alkoxy, a (C1-C30)alkylthio, a (C3-C30)cycloalkyl, a (C3-C30)cycloalkenyl, a (3- to 7-membered)heterocycloalkyl, a (C6-C30)aryloxy, a (C6-C30)arylthio, a (3- to 30-membered)heteroaryl unsubstituted or substituted with a (C6-C30)aryl, a (C6-C30)aryl unsubstituted or substituted with a cyano, a (3- to 30-membered)heteroaryl, or a tri(C6-C30)arylsilyl, a tri(C1-C30)alkylsilyl, a tri(C6-C30)arylsilyl, a di(C1-C30)alkyl(C6-C30)arylsilyl, a (C1-C30)alkyldi(C6-C30)arylsilyl, an amino, a mono- or di-(C1-C30)alkylamino, a mono- or di-(C6-C30)arylamino, a (C1-C30)alkyl(C6-C30)arylamino, a (C1-C30)alkylcarbonyl, a (C1-C30)alkoxycarbonyl, a (C6-C30)arylcarbonyl, a di(C6-C30)arylboronyl, a di(C1-C30)alkylboronyl, a (C1-C30)alkyl(C6-C30)arylboronyl, a (C6-C30)aryl(C1-C30)alkyl, and a (C1-C30)alkyl(C6-C30)aryl, and preferably are at least one selected from the group consisting of a cyano, a (C1-C6)alkyl, a (5- to 15-membered)heteroaryl, a (C6-C18)aryl unsubstituted or substituted with a cyano or a tri(C6-C12)arylsilyl, a tri(C6-C12)arylsilyl, and a (C1-C6)alkyl(C6-C12)aryl. 
     In formula 1, a triarylsilyl as Xi to X16 is preferably a triphenylsilyl. 
     The first host compound represented by formula 1 includes the following compounds, but is not limited thereto: 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     The second host compound represented by formula 2 includes the following compounds, but is not limited thereto: 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     The organic electroluminescent device according to the present invention comprises an anode; a cathode; and at least one organic layer between the anode and the cathode. The organic layer comprises a light-emitting layer, and the light-emitting layer comprises a host and a phosphorescent dopant. The host consists of multi-component host compounds, at least a first host compound of the multi-component host compounds is represented by formula 1, and a second host compound is represented by formula 2. 
     The light-emitting layer is a layer from which light is emitted, and can be a single layer or a multi layer of which two or more layers are stacked. In the light-emitting layer, it is preferable that the doping concentration of the dopant compound based on the host compound is less than 20 wt %. 
     The organic layer comprises a light-emitting layer, and may further comprise at least one layer selected from the group consisting of a hole injection layer, a hole transport layer, an electron transport layer, an electron injection layer, an interlayer, a hole blocking layer, and an electron blocking layer. 
     According to the organic electroluminescent device of the present invention, the weight ratio of the first host material to the second host material is in the range of 1:99 to 99:1. 
     The dopant is preferably at least one phosphorescent dopant. The dopant materials applied to the organic electroluminescent device according to the present invention are not limited, but may be preferably selected from metallated complex compounds of iridium, osmium, copper and platinum, more preferably selected from ortho-metallated complex compounds of iridium, osmium, copper and platinum, and even more preferably ortho-metallated iridium complex compounds. The phosphorescent dopant is preferably selected from compounds represented by the following formulae 101 to 103. 
     
       
         
         
             
             
         
       
     
     wherein L is selected from the following structures: 
     
       
         
         
             
             
         
       
     
     R 100  represents hydrogen, a substituted or unsubstituted (C1-C30)alkyl, or a substituted or unsubstituted (C3-C30)cycloalkyl; 
     R 101  to R 109 , and R 111  to R 123  each independently represent hydrogen, deuterium, a halogen, a (C1-C30)alkyl unsubstituted or substituted with deuterium or a halogen(s), a cyano, a substituted or unsubstituted (C1-C30)alkoxy, a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted (C3-C30)cycloalkyl; adjacent substituents of R106 to R109 may be linked to each other to form a substituted or unsubstituted fused ring, e.g., fluorene unsubstituted or substituted with alkyl, dibenzothiophene unsubstituted or substituted with alkyl, or dibenzofuran unsubstituted or substituted with alkyl; and adjacent substituents of R 120  to R 123  may be linked to each other to form a substituted or unsubstituted fused ring, e.g., quinoline unsubstituted or substituted with halogen, alkyl, or aryl; 
     R 124  to R 127  each independently represent hydrogen, deuterium, a halogen, a substituted or unsubstituted (C1-C30)alkyl, or a substituted or unsubstituted (C6-C30)aryl; and adjacent substituents of R 124  to R 127  may be linked to each other to form a substituted or unsubstituted fused ring, e.g., fluorene unsubstituted or substituted with alkyl, dibenzothiophene unsubstituted or substituted with alkyl, or dibenzofuran unsubstituted or substituted with alkyl; 
     R 201  to R211 each independently represent hydrogen, deuterium, a halogen, a (C1-C30)alkyl unsubstituted or substituted with deuterium or a halogen(s), a substituted or unsubstituted (C3-C30)cycloalkyl, or a substituted or unsubstituted (C6-C30)aryl; and adjacent substituents of R 208  to R 211  may be linked to each other to form a substituted or unsubstituted fused ring, e.g., fluorene unsubstituted or substituted with alkyl, dibenzothiophene unsubstituted or substituted with alkyl, or dibenzofuran unsubstituted or substituted with alkyl; 
     r and s each independently represent an integer of 1 to 3; where r or s is an integer of 2 or more, each of R 100  may be the same or different; and e represents an integer of 1 to 3. 
     Specifically, the phosphorescent dopant materials include the following: 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     The organic electroluminescent device according to the present invention may further comprise at least one compound selected from the group consisting of arylamine-based compounds and styrylarylamine-based compounds in the organic layer. 
     In addition, in the organic electroluminescent device according to the present invention, the organic layer may further comprise at least one metal selected from the group consisting of metals of Group 1, metals of Group 2, transition metals of the 4th period, transition metals of the 5th period, lanthanides and organic metals of d-transition elements of the Periodic Table, or at least one complex compound comprising said metal. 
     According to the present invention, at least one layer (hereinafter, “a surface layer”) is preferably placed on an inner surface(s) of one or both electrode(s); selected from a chalcogenide layer, a metal halide layer and a metal oxide layer. Specifically, a chalcogenide (including oxides) layer of silicon or aluminum is preferably placed on an anode surface of an electroluminescent medium layer, and a metal halide layer or a metal oxide layer is preferably placed on a cathode surface of an electroluminescent medium layer. Such a surface layer provides operation stability for the organic electroluminescent device. Preferably, said chalcogenide includes SiO x (1≤X≤2), AlO x (1≤X≤1 .5), SiON, SiAION, etc.; said metal halide includes LiF, MgF 2 , CaF 2 , a rare earth metal fluoride, etc.; and said metal oxide includes Cs 2 O, Li 2 O, MgO, SrO, BaO, CaO, etc. 
     Between the anode and the light-emitting layer, a layer selected from a hole injection layer, a hole transport layer, or an electron blocking layer, or formed by a combination thereof can be used. Multi layers can be used for the hole injection layer in order to lower the hole injection barrier (or hole injection voltage) from the anode to the hole transport layer or the electron blocking layer. Two compounds can be simultaneously used in each layer. The hole transport layer and the electron blocking layer can also be formed of multi layers. 
     Between the light-emitting layer and the cathode, a layer selected from an electron buffer layer, a hole blocking layer, an electron transport layer, or an electron injection layer, or formed by a combination thereof can be used. Multi layers can be used for the electron buffer layer in order to control the injection of the electrons and enhance the interfacial characteristics between the light-emitting layer and the electron injection layer. Two compounds can be simultaneously used in each layer. The hole blocking layer and the electron transport layer can also be formed of multi layers, and each layer can comprise two or more compounds. 
     In the organic electroluminescent device according to the present invention, a mixed region of an electron transport compound and a reductive dopant, or a mixed region of a hole transport compound and an oxidative dopant is preferably placed on at least one surface of a pair of electrodes. In this case, the electron transport compound is reduced to an anion, and thus it becomes easier to inject and transport electrons from the mixed region to an electroluminescent medium. Further, the hole transport compound is oxidized to a cation, and thus it becomes easier to inject and transport holes from the mixed region to the electroluminescent medium. Preferably, the oxidative dopant includes various Lewis acids and acceptor compounds; and the reductive dopant includes alkali metals, alkali metal compounds, alkaline earth metals, rare-earth metals, and mixtures thereof. A reductive dopant layer may be employed as a charge generating layer to prepare an electroluminescent device having two or more electroluminescent layers and emitting white light. 
     In order to form each layer of the organic electroluminescent device of the present invention, dry film-forming methods such as vacuum evaporation, sputtering, plasma and ion plating methods, or wet film-forming methods such as ink jet printing, nozzle printing, slot coating, spin coating, dip coating, and flow coating methods can be used. The first and second host compounds of the present invention may be co-evaporated or mixture-evaporated. 
     When using a wet film-forming method, a thin film can be formed by dissolving or diffusing materials forming each layer into any suitable solvent such as ethanol, chloroform, tetrahydrofuran, dioxane, etc. The solvent can be any solvent where the materials forming each layer can be dissolved or diffused, and where there are no problems in film-formation capability. 
     Herein, a co-evaporation indicates a process for two or more materials to be deposited as a mixture, by introducing each of the two or more materials into respective crucible cells, and applying an electric current to the cells for each of the materials to be evaporated. Herein, a mixture-evaporation indicates a process for two or more materials to be deposited as a mixture, by mixing the two or more materials in one crucible cell before the deposition, and applying an electric current to the cell for the mixture to be evaporated. 
     By using the organic electroluminescent device of the present invention, a display system or a lighting system can be produced. 
     Hereinafter, the luminescent properties of the device comprising the host compound of the present invention will be explained in detail with reference to the following examples. 
     Device Examples 1-1 to 1-6: Preparation of an OLED Device by Co-Evaporating the First Host Compound and the Second host Compound of the Present Invention 
     An OLED device was produced using the organic electroluminescent compound according to the present invention. A transparent electrode indium tin oxide (ITO) thin film (10 Ω/sq) on a glass substrate for an organic light-emitting diode (OLED) device (Geomatec) was subjected to an ultrasonic washing with trichloroethylene, acetone, ethanol, and distilled water, sequentially, and then was stored in isopropanol. The ITO substrate was then mounted on a substrate holder of a vacuum vapor depositing apparatus. N 4 ,N 4 ′-diphenyl-N 4 , -bis(9-phenyl-9H-carbazol-3-yl)-[1,1′-biphenyl]-4,4′-diamine (compound HI-1) was introduced into a cell of said vacuum vapor depositing apparatus, and then the pressure in the chamber of said apparatus was controlled to 10 −6  torr. Thereafter, an electric current was applied to the cell to evaporate the above introduced material, thereby forming a first hole injection layer having a thickness of 80 nm on the ITO substrate. Next, 1,4,5,8,9,12-hexaazatriphenylene-hexacarbonitrile (compound HI-2) was introduced into another cell of said vacuum vapor depositing apparatus, and was evaporated by applying an electric current to the cell, thereby forming a second hole injection layer having a thickness of 5 nm on the first hole injection layer. N-([1,1′-biphenyl]-4-yl)-9,9-dimethyl-N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-fluorene-2-amine (compound HT-1) was then introduced into another cell of said vacuum vapor depositing apparatus, and was evaporated by applying an electric current to the cell, thereby forming a first hole transport layer having a thickness of 10 nm on the second hole injection layer. Afterwards, N,N-di([1,1′-biphenyl]-4-yl)-4′-(9H- carbazol-9-yl)[1,1′-biphenyl]-4-amine (compound HT-2) was introduced into another cell of said vacuum vapor depositing apparatus, and was evaporated by applying an electric current to the cell, thereby forming a second hole transport layer having a thickness of 60 nm on the first hole transport layer. As a host material, a first host compound and a second host compound were introduced into two cells of the vacuum vapor depositing apparatus, respectively. A dopant compound D-96 was introduced into another cell. The two host materials were evaporated at 1:1 rate, while the dopant was evaporated at a different rate from the host materials, so that the dopant was deposited in a doping amount of 3 wt % based on the total amount of the host and dopant to form a light-emitting layer having a thickness of 40 nm on the hole transport layer. 2,4-bis(9,9-dimethyl-9H-fluoren-2-yl)-6-(naphthalen-2-yl)-1,3,5-triazine (compound ET-1) and lithium quinolate (compound EI-1) were then introduced into two cells of the vacuum vapor depositing apparatus, respectively, and evaporated at 1:1 rate to form an electron transport layer having a thickness of 30 nm on the light-emitting layer. After depositing lithium quinolate (compound EI-1) as an electron injection layer having a thickness of 2 nm on the electron transport layer, an AI cathode having a thickness of 80 nm was deposited by another vacuum vapor deposition apparatus. Thus, an OLED device was produced. 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     Comparative Examples 1-1 to 1-3: Preparation of an OLED Device Using Only the Second Host Compound as a Host 
     An OLED device was produced in the same manner as in Device Examples 1-1 to 1-6, except for using only the second host compound as a host of the light-emitting layer. 
     The driving voltage at 1,000 nit, luminous efficiency, CIE color coordinate, and the time taken for the luminance at 5,000 nit to be reduced from 100% to 80% at a constant current of the OLEDs produced as above were measured. 
     Table 1 below shows the luminous characteristics of the organic electroluminescent devices produced as in the examples above. 
     
       
         
           
               
               
               
               
               
               
               
               
             
               
                 TABLE 1 
               
               
                   
               
               
                   
                   
                   
                   
                   
                   
                 Color 
                   
               
               
                   
                   
                   
                   
                 Voltage 
                 Efficiency 
                 Coordinate  
                 Lifespan 
               
               
                 Device No. 
                 HTL 
                 Host 
                 Dopant 
                 [V] 
                 [cd/A] 
                 (x, y) 
                 [hr] 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                 Example 1-1 
                 HT-1/HT-2 
                 H1-1:H2-2 
                 D-96 
                 4.4 
                 27.5 
                 0.664, 0.335 
                 1,280 
               
               
                 Example 1-2 
                 HT-1/HT-2 
                 H1-7:H2-29 
                 D-96 
                 3.9 
                 27.7 
                 0.665, 0.332 
                 550 
               
               
                 Example 1-3 
                 HT-1/HT-2 
                 H1-19:H2-29 
                 D-96 
                 4.1 
                 24.6 
                 0.664, 0.332 
                 470 
               
               
                 Example 1-4 
                 HT-1/HT-2 
                 H1-36:H2-154 
                 D-96 
                 4.6 
                 27.8 
                 0.663, 0.335 
                 1,530 
               
               
                 Example 1-5 
                 HT-1/HT-2 
                 H1-36:H2-29 
                 D-96 
                 3.7 
                 28.2 
                 0.666, 0.331 
                 780 
               
               
                 Example 1-6 
                 HT-1/HT-2 
                 H1-36:H2-155 
                 D-96 
                 4.6 
                 26.9 
                 0.664, 0.335 
                 970 
               
               
                 Comp. Ex. 1-1 
                 HT-1/HT-2 
                 H2-2  
                 D-96 
                 4.1 
                 28.2 
                 0.662, 0.337 
                 300 
               
               
                 Comp. Ex. 1-2 
                 HT-1/HT-2 
                 H2-154 
                 D-96 
                 4.5 
                 27.1 
                 0.662, 0.337 
                 420 
               
               
                 Comp. Ex. 1-3 
                 HT-1/HT-2 
                 H2-29  
                 D-96 
                 3.6 
                 27.5 
                 0.668, 0.331 
                 310 
               
               
                   
               
            
           
         
       
     
     Device Examples 2-1 to 2-7: Preparation of an OLED Device by Co-Evaporating the First Host Compound and the Second Host Compound of the Present Invention 
     An OLED device was produced in the same manner as in Device Examples 1-1 to 1-6, except for forming the second hole injection layer of 3 nm; forming the first hole transport layer of 40 nm; not forming the second hole transport layer; doping compound D-25 as the dopant of the light-emitting layer in a doping amount of 15 wt % based on the total amount of the host and dopant; forming the electron transport layer of 35 nm by evaporating 2,4-bis(9,9-dimethyl-9H-fluoren-2-yl)-6-(naphthalen-2-yl)-1,3,5-triazine and lithium quinolate at a rate of 4:6; and using other combinations for the first host compound and the second host compound used in the host of the light-emitting layer. 
     Device Examples 2-8 to 2-9: Preparation of an OLED Device by Co-Evaporating the First Host Compound and the Second Host Compound of the Present Invention 
     An OLED device was produced in the same manner as in Device Examples 1-1 to 1-6, except for forming the second hole injection layer of 3 nm; forming the first hole transport layer of 40 nm; not forming the second hole transport layer; doping compound D-1 as the dopant of the light-emitting layer in a doping amount of 15 wt % based on the total amount of the host and dopant; forming the electron transport layer of 35 nm by evaporating 2,4-bis(9,9-dimethyl-9H-fluoren-2-yl)-6-(naphthalen-2-yl)-1,3,5-triazine and lithium quinolate at a rate of 4:6; and using other combinations for the first host compound and the second host compound used in the host of the light-emitting layer. 
     Device Example 2-10: Preparation of an OLED Device by Co-Evaporating the First Host Compound and the Second Host Compound of the Present Invention 
     An OLED device was produced in the same manner as in Device Examples 1-1 to 1-6, except for forming the second hole injection layer of 3 nm; forming the first hole transport layer of 40 nm; not forming the second hole transport layer; doping compound D-136 as the dopant of the light-emitting layer in a doping amount of 15 wt % based on the total amount of the host and dopant; forming the electron transport layer of 35 nm by evaporating 2,4-bis(9,9-dimethyl-9H-fluoren-2-yl)-6-(naphthalen-2-yl)-1,3,5-triazine and lithium quinolate at a rate of 4:6; and using other combinations for the first host compound and the second host compound used in the host of the light-emitting layer. 
     Device Examples 3-1 to 3-3: Preparation of an OLED Device by Co-Evaporating the First Host Compound and the Second Host Compound of the Present Invention 
     An OLED device was produced in the same manner as in Device Examples 2-1 to 2-7, except for forming the first hole injection layer of 10 nm; forming the second hole transport layer of 30 nm using compound HT-3; using compound D-136 as the dopant of the light-emitting layer; and using other combinations for the first host compound and the second host compound used in the host of the light-emitting layer. 
     Device Example 3-4: Preparation of an OLED Device by Co-Evaporating the First Host Compound and the Second Host Compound of the Present Invention 
     An OLED device was produced in the same manner as in Device Examples 2-1 to 2-7, except for forming the first hole injection layer of 10 nm; forming the second hole transport layer of 30 nm using compound HT-3; using compound D-168 as the dopant of the light-emitting layer; and using other combinations for the first host compound and the second host compound used in the host of the light-emitting layer. 
     Comparative Examples 2-1 to 2-3: Preparation of an OLED Device Using Only the First Host Compound as a Host 
     An OLED device was produced in the same manner as in Device Examples 2-1 to 2-7, except for using only the first host compound as a host of the light-emitting layer. 
     Comparative Examples 3-1 to 3-3: Preparation of an OLED Device Using Only the Second Host Compound as a Host 
     An OLED device was produced in the same manner as in Device Examples 2-1 to 2-7, except for using only the second host compound as a host of the light-emitting layer. 
     Comparative Examples 3-4 to 3-6: Preparation of an OLED Device Using only the Second Host Compound as a Host 
     An OLED device was produced in the same manner as in Device Examples 2-8 to 2-9, except for using only the second host compound as a host of the light-emitting layer. 
     Comparative Examples 4-1 to 4-3: Preparation of an OLED Device Using Only the Second Host Compound as a Host 
     An OLED device was produced in the same manner as in Device Examples 3-1 to 3-3, except for using only the second host compound as a host of the light-emitting layer. 
     The driving voltage at 1,000 nit, luminous efficiency, CIE color coordinate, and the time taken for the luminance at 15,000 nit to be reduced from 100% to 80% at a constant current of the OLEDs produced as above were measured. 
     Table 2 below shows the luminous characteristics of the organic electroluminescent devices produced as in the examples above. 
     
       
         
           
               
               
               
               
               
               
               
               
             
               
                 TABLE 2 
               
               
                   
               
               
                   
                   
                   
                   
                   
                   
                 Color 
                   
               
               
                   
                   
                   
                   
                 Voltage 
                 Efficiency 
                 Coordinate  
                 Lifespan 
               
               
                 Device No. 
                 HTL 
                 Host 
                 Dopant 
                 [V] 
                 [cd/A] 
                 (x, y) 
                 [hr] 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                 Example 2-1  
                 HT-1 
                 H1-1:H2-25 
                 D-25  
                 3.2 
                 49.8 
                 0.301, 0.658 
                 350 
               
               
                 Example 2-2  
                 HT-1 
                 H1-1:H2-31 
                 D-25  
                 3 
                 57.1 
                 0.308, 0.655 
                 380 
               
               
                 Example 2-3  
                 HT-1 
                 H1-1:H2-48 
                 D-25  
                 2.9 
                 56.8 
                 0.305, 0.656 
                 400 
               
               
                 Example 2-4  
                 HT-1 
                 H1-1:H2-101 
                 D-25  
                 3 
                 55.5 
                 0.303, 0.657 
                 230 
               
               
                 Example 2-5  
                 HT-1 
                 H1-1:H2-34 
                 D-25  
                 3.1 
                 58.1 
                 0.306, 0.655 
                 440 
               
               
                 Example 2-6  
                 HT-1 
                 H1-4:H2-31 
                 D-25  
                 3 
                 53.3 
                 0.304, 0.656 
                 120 
               
               
                 Example 2-7  
                 HT-1 
                 H1-37:H2-31 
                 D-25  
                 3 
                 53.7 
                 0.306, 0.655 
                 300 
               
               
                 Example 2-8  
                 HT-1 
                 H1-1:H2-31 
                 D-1   
                 2.9 
                 53 
                 0.321, 0.656 
                 560 
               
               
                 Example 2-9  
                 HT-1 
                 H1-1:H2-48 
                 D-1   
                 2.8 
                 55.3 
                 0.319, 0.657 
                 550 
               
               
                 Example 2-10 
                 HT-1 
                 H1-H113:H2-31 
                 D-136 
                 2.8 
                 59.4 
                 0.331, 0.655 
                 600 
               
               
                 Example 3-1  
                 HT-1/HT-3 
                 H1-1:H2-48 
                 D-136 
                 3.1 
                 67.5 
                 0.326, 0.658 
                 590 
               
               
                 Example 3-2  
                 HT-1/HT-3 
                 H1-1:H2-273 
                 D-136 
                 3.1 
                 66.2 
                 0.328, 0.657 
                 700 
               
               
                 Example 3-3  
                 HT-1/HT-3 
                 H1-113:H2-125 
                 D-136 
                 3.1 
                 65.8 
                 0.329, 0.657 
                 700 
               
               
                 Example 3-4  
                 HT-1/HT-3 
                 H1-1:H2-273 
                 D-168 
                 3.0 
                 57.2 
                 0.288, 0.665 
                 450 
               
               
                 Comp. Ex. 2-1 
                 HT-1 
                 H1-1  
                 D-25  
                 6.8 
                 3.1 
                 0.301, 0.653 
                 x 
               
               
                 Comp. Ex. 2-2 
                 HT-1 
                 H1-4  
                 D-25  
                 7.2 
                 3.6 
                 0.295, 0.658 
                 x 
               
               
                 Comp. Ex. 2-3 
                 HT-1 
                 H1-37  
                 D-25  
                 7.0 
                 3.0 
                 0.302, 0.653 
                 x 
               
               
                 Comp. Ex. 3-1 
                 HT-1 
                 H2-31  
                 D-25  
                 2.9 
                 42.8 
                 0.314, 0.652 
                 100 
               
               
                 Comp. Ex. 3-2 
                 HT-1 
                 H2-101 
                 D-25  
                 2.8 
                 50.3 
                 0.315, 0.651 
                 60 
               
               
                 Comp. Ex. 3-3 
                 HT-1 
                 H2-34  
                 D-25  
                 2.7 
                 49.2 
                 0.312, 0.652 
                 100 
               
               
                 Comp. Ex. 3-4 
                 HT-1 
                 H2-31  
                 D-1  
                 2.9 
                 33.5 
                 0.323, 0.653 
                 390 
               
               
                 Comp. Ex. 3-5 
                 HT-1 
                 H2-48  
                 D-1  
                 2.6 
                 41.2 
                 0.325, 0.653 
                 380 
               
               
                 Comp. Ex. 3-6 
                 HT-1 
                 H2-87  
                 D-1  
                 2.8 
                 37.9 
                 0.323, 0.653 
                 420 
               
               
                 Comp. Ex. 4-1 
                 HT-1/HT-3 
                 H2-48  
                 D-136 
                 2.6 
                 51.9 
                 0.334, 0.652 
                 490 
               
               
                 Comp. Ex. 4-2 
                 HT-1/HT-3 
                 H2-125 
                 D-136 
                 3.0 
                 64.9 
                 0.337, 0.649 
                 360 
               
               
                 Comp. Ex. 4-3 
                 HT-1/HT-3 
                 H2-273 
                 D-136 
                 3.3 
                 68.2 
                 0.332, 0.654 
                 440 
               
               
                   
               
            
           
         
       
     
     Device Example 4-1: Preparation of an OLED Device by Co-Evaporatinq the First Host Compound and the Second Host Compound of the Present Invention 
     An OLED device was produced in the same manner as in Device Examples 1-1 to 1-6, except for using compound HT-4 for the second hole transport layer, and using the compounds as listed in Table 3 below for the first host compound and the second host compound used in the host of the light-emitting layer. 
     Comparative Example 5-1: Preparation of an OLED Device Using Only the Second Host Compound as a Host 
     An OLED device was produced in the same manner as in Device Example 4-1, except for using only the second host compound of Table 3 as a host of the light-emitting layer. 
     The driving voltage at 1,000 nit, luminous efficiency, CIE color coordinate, and the time taken for the luminance at 5,000 nit to be reduced from 100% to 90% at a constant current of the OLEDs produced as above were measured. 
     Table 3 below shows the luminous characteristics of the organic electroluminescent devices produced as in the examples above. 
     
       
         
           
               
               
               
               
               
               
               
               
             
               
                 TABLE 3 
               
               
                   
               
               
                   
                   
                   
                   
                   
                   
                 Color 
                   
               
               
                   
                   
                   
                   
                 Voltage 
                 Efficiency 
                 Coordinate  
                 Lifespan 
               
               
                 Device No. 
                 HTL 
                 Host 
                 Dopant 
                 [V] 
                 [cd/A] 
                 (x, y) 
                 [hr] 
               
               
                   
               
             
            
               
                 Example 4-1 
                 HT-1/HT-4 
                 H1-7:H2-41 
                 D-96 
                 3.4 
                 30.7 
                 0.665, 0.333 
                 400 
               
               
                 Comp. Ex. 5-1 
                 HT-1/HT-4 
                 H2-41 
                 D-96 
                 3.1 
                 28.3 
                 0.668, 0.331 
                 300 
               
               
                   
               
            
           
         
       
     
     The organic electroluminescent device of the present invention comprises a light-emitting layer comprising a host and a phosphorus dopant, and the host consists of a specific combination of multi-component host compounds. The device of the present invention provides superior lifespan characteristics to conventional devices.