Patent Publication Number: US-4649002-A

Title: System for preventing decomposition of silicon carbide articles during sintering

Description:
BACKGROUND OF THE INVENTION 
     This invention relates to a system for preventing, retarding or reversing the decomposition of silicon carbide refractory or ceramic articles during high temperature sintering. 
     Silicon carbide has several physical and chemical properties which make it an excellent material for high temperature, structural uses. Mechanically, silicon carbide is a hard, rigid, brittle solid which does not yield to applied stresses even at temperatures approaching its decomposition temperature. Because of its high thermal conductivity, silicon carbide is an excellent material for heat exchangers, muffle type furnaces, crucibles, gas-turbine engines and retorts in the carbothermic production and distillation of zinc. Silicon carbide is also used in electrical resistance elements, ceramic tiles, boilers, around tapping holes, in heat treating, annealing and forging furnaces, in gas producers, and in other places where strength at high temperatures, shock resistance and slag resistance are required. Properties associated with silicon carbide refractory and ceramic materials are superior strength, high elastic modulus, high fracture toughness, corrosion resistance, abrasion resistance, thermal shock resistance, and low specific gravity. 
     Silicon carbide refractory or ceramic materials are generally sintered at temperatures above 1900° C. so that the silicon carbide articles will develop desirable physical and chemical properties such as high strength, high density and low chemical reactivity. A reducing or inert atmosphere is generally used for sintering silicon carbide to prevent formation of compounds which may have undesirable physical or chemical properties. Electric kilns are typically used to sinter silicon carbide ceramic or refractory materials under controlled atmospheres, but these tend to be energy inefficient and slow. In the case of a kiln equipped with graphite heating elements, the voltage can be controlled and the kiln can be heated to fairly high temperatures, yet there are several disadvantages: (1) The heating elements have a limited size, complex shape and must be kept under a strictly controlled atmosphere to maintain a long life; and (2) Furnace size is limited and it is difficult to achieve a uniform temperature in this type of kiln because the heating elements provide only radiant heat. Because of radiant heat transfer, as well as a size limit for heating elements, the kiln has a poor load density, limited productivity, and a poor energy efficiency. 
     Plasma arc technology has recently been applied to the production of refractory and ceramic materials to reduce the furnace energy requirements and retention times. However, plasma technology has generally only been used for the fusion of high temperature materials and not for sintering or reaction sintering. This is because the required sintering temperature for most ceramic or refractory materials is usually less than 2500° C., whereas the average temperature of gases heated through a plasma arc column is above about 4000° C. For instance, alpha silicon carbide is generally sintered at temperatures of between 1900° C. to 2350° C. At temperatures above around 2150° C., silicon carbide decomposes into silicon gas and solid carbon. The carbon may then react further with the silicon carbide and silicon gas to form other vapor species, such as SiC 2  and Si 2  C. This decomposition of silicon carbide could result in substantial shrinkage of the article being fired, as well as an undesirable change in surface chemistry. 
     Plasma arc fired gases differ greatly from ordinary furnace heated gases in that they become ionized and contain electrically charged particles capable of transferring electricity and heat; or, as in the case of nitrogen, become dissociated and highly reactive. For example, nitrogen plasma gas dissociates into a highly reactive mixture of N 2  -molecules, N-atoms, N +  -ions and electrons. This dissociation or ionization greatly increases the reaction rates for sintering ceramic or refractory materials. Nitrogen, for example, which dissociates at around 5000° C. and 1 atmosphere pressure, would not dissociate under the normal furnace sintering conditions of around 1500° C.-2000° C. Thus, the use of plasma gases results in a highly reactive environment, which greatly increases the reaction sintering rate. 
     However, this highly reactive plasma environment also increases the decomposition of the green body because of the buoyant forces involved in convective heat transfer which increase the flow of the gases in the furnace. These gases sweep away the decomposition products, allowing the decomposition reactions to proceed. In the case of silicon carbide, silicon is continually stripped from the surface of the green body, resulting in a decreased density and undesirable surface chemistry. 
     SUMMARY OF THE INVENTION 
     This invention relates to a system for the high temperature sintering of silicon carbide refractory or ceramic articles which prevents, retards or reverses decomposition of the silicon carbide articles. 
     In a preferred embodiment of the invention, sintering is performed in a furnace with at least one plasma torch positioned near the top of the furnace, and an exhaust outlet positioned near the bottom of the furnace. In large furnaces, it is preferable to position an additional torch (or torches) through the center of the furnace wall opposite the primary plasma torch or torches. This specific positioning of the plasma torch or torches and exhaust outlet serves two functions: (1) It provides maximum turbulence within the furnace for convective heat transfer and uniformity of heating, and (2) It prevents the silicon carbide decomposition reaction products from being swept away from the proximity of the silicon carbide articles being sintered, thus retarding or preventing further decomposition of the silicon carbide articles. 
     Preferably, the silicon carbide refractory or ceramic articles being sintered are placed into a crucible, and most preferably, into a covered crucible. When crucibles are employed, the silicon carbide decomposition reaction products are contained within the crucibles, thereby preventing further the decomposition of the silicon carbide articles. Preferably, the crucibles are made from graphite, but any crucible material, common to the art, may be used. 
     In another embodiment of the invention, a sacrificial source of silicon carbide is placed into the sintering furnace, preferably near the plasma gas inlet. Because of its higher surface area and a close proximity to the plasma gas inlet, the sacrificial source begins to decompose before the refractory or ceramic article being sintered, thereby saturating the furnace with silicon vapor species. Presence of these gases tends to reverse the silicon carbide decomposition reactions, thus preventing the silicon carbide refractory or ceramic article from decomposing. Very small particles of silicon carbide are preferable for use as the sacrificial source because of their high surface area. Use of a sacrificial source in accordance with the present invention results in a superior sintered product because there is little or no decomposition of the silicon carbide refractory or ceramic article. 
     Accordingly, it is an object of the present invention to provide an easy, efficient and inexpensive system for the prevention, retardation, or reversal of the decomposition of silicon carbide articles during plasma sintering. 
     It is a further object of the present invention to provide a system for preventing, retarding or reversing the decomposition of silicon carbide refractory or ceramic articles during sintering which results in high density products with low shrinkage. 
     Other objects and further scope of applicability of the present invention will become apparent from the detailed description to follow, taken in conjunction with the accompanying drawing. 
    
    
     BRIEF DESCRIPTION OF THE DRAWING 
     The sole figure of the drawing is an illustration of the heat transfer mechanisms, and positioning of plasma torches, the exhaust outlet and crucibles, in a plasma arc furnace in accordance with the present invention. 
    
    
     DESCRIPTION OF THE PREFERRED EMBODIMENT 
     At the outset, the invention is described in its broadest overall aspects, with a more detailed description following. This invention relates to a system for preventing, retarding, or reversing the decomposition of silicon carbide refractory or ceramic green bodies at high sintering temperatures. The system comprises sintering a silicon carbide refractory or ceramic article in a plasma furnace by either: (1) Placing the silicon carbide article in a closed environment, such as a covered crucible; (2) Placing the silicon carbide article in a closed environment, such as a covered crucible, along with a sacrificial source of silicon carbide; (3) Placing the silicon carbide article in an open crucible; (4) Placing the silicon carbide article in an open crucible along with a sacrificial source of silicon carbide; (5) Placing the silicon carbide article in a completely open sintering environment along with a sacrificial source of silicon carbide; or (6) Sintering the silicon carbide article in a furnace designed to maximize buoyant convective heat transfer while minimizing decomposition of the silicon carbide article, with or without crucibles or a sacrificial source of silicon carbide. Preferably, sintering is performed in a furnace with at least one plasma torch positioned near the top of the furnace, an exhaust outlet positioned near the bottom of the furnace, and a space between crucibles. The specific positioning of the plasma torch, exhaust outlet, and crucibles, and the presence of the sacrificial source all tend to prevent decomposition of the silicon carbide ceramic or refractory article. 
     When silicon carbide is sintered at temperatures above around 2150° C., it decomposes according to the following reaction: 
     
         SiC.sub.(s) →Si.sub.(g) +C.sub.(s) 
    
     This decomposition causes formation of a carbon layer on the silicon carbide surface, which may then react further with the silicon carbide and silicon gas to form other vapor species, such as SiC 2  and Si 2  C. These reactions result in a net mass loss and decreased density, in addition to a carbon layer on the surface which may give the silicon carbide product undesirable chemical and physical properties. Of course, if the environment around the SiC.sub.(s) is saturated with Si.sub.(g), the reaction tends to proceed to the left, that is towards SiC.sub.(s). 
     The present invention prevents, retards or reverses the decomposition of silicon carbide refractory or ceramic green bodies in three ways: (1) By placing the silicon carbide green body in a closed environment, such as a covered crucible, a partial pressure of silicon gas builds up within the closed environment. As the environment becomes supersaturated with silicon gas and other silicon vapor species, the decomposition of the silicon carbide green body is halted or retarded. (2) By positioning the plasma arc torch near the top of the furnace and positioning the exhaust outlet near the bottom of the furnace, the buoyant effects of convective heat transfer are minimized. Thus, the silicon vapor species are not swept away, but remain in the crucibles or the furnace, itself, keeping the crucible and furnace environment supersaturated with silicon vapor species. (3) By employing a sacrificial source of silicon carbon which decomposes before the silicon carbide green body, the furnace atmosphere (open or closed environment) becomes saturated with silicon gas and other silicon vapor species, thereby halting, retarding, preventing or reversing the decomposition of the silicon carbide green body. 
     The preferred starting material for the silicon carbide refractory or ceramic green bodies should be primarily alpha, non-cubic crystalline silicon carbide, since it is more readily available than beta silicon carbide. It is acceptable, however, to use alpha, beta, or amorphous silicon carbide or mixtures thereof. If beta silicon carbide is utilized, it should be of high purity. Boron, carbon or carbonizable organic materials, binders and other additives may be included in the green body mixture depending on product requirements. 
     The silicon carbide starting mixture may be shaped or formed into shaped green bodies by any conventional method, such as extrusion, injection molding, transfer molding, casting, cold pressing, isostatic pressing or by compression. 
     The shaped silicon carbide bodies are then sintered in a plasma arc furnace. The drawing is an illustration of the heat transfer mechanisms involved in a plasma arc sintering furnace useful for practicing this invention. The straight arrows 24 indicate heat transfer through radiation and the wavy arrows 26 indicate heat transfer through convection. With convective heat transfer, the plasma arc furnace has a lower cycle time than prior art furnaces. 
     Copending patent applications, Ser. No. 533,596, filed Sept. 19, 1983, now U.S. Pat. No. 4,559,312, entitled PLASMA HEATED SINTERING FURNACE, and Ser. No. 718,375 filed 4-1-875 entitled PLASMA ARC SINTERING OF SILICON CARBIDE, to Jonathan J. Kim et al, filed on even date herewith, the teachings of which are incorporated herein by reference, are useful in practicing the present invention. U.S. Ser. No. 533,596, filed 9-19-83 now U.S. Pat. No. 4,559,312 discloses a plasma heated furnace and method for sintering refractory or ceramic materials. In a preferred embodiment, the furnace comprises at least two plasma torch inlets, positioned asymmetrically through the walls of the sintering chamber, with one plasma torch inlet positioned near the top of the sintering chamber, the other plasma torch inlet positioned near the center of the furnace, and the exhaust outlet positioned near the bottom of the sintering chamber Ser. No. 718,375, filed 4-1-85 discloses a process for the sintering of silicon carbide refractory or ceramic articles in a plasma heated furnace, wherein the silicon carbide article is heated by a plasma gas having an energy capacity of 2000 BTU/lb-6000 BTU/lb to a sintering temperature of between 1500° C.-2500° C., at a heating rate of 300° C./hr-2000° C./hr, and held at the sintering temperature for 0.1-2 hours. A typical cycle time for the present invention operating in accordance with Ser. No. 533,596, filed 9-19-83, now U.S. Pat. No. 4,559,312, and Ser. No. 718,375 is around eight hours (including cooling), which compares to a total cycle time of around 24 hours for an electric kiln. It should be noted that in prior art electric kilns, such as a Centorr™ or Astro™ furnace, the only mode of heat transfer is through radiation. 
     A plasma sintering furnace is a turbulent flow system, unlike prior art radiant furnaces which are considered stagnant systems. Buoyant convective forces in a turbulent flow system increase the heat transfer rate and provide uniformity of heating. 
     It is preferable to sinter the silicon carbide green bodies in a closed environment, such as a covered crucible, to prevent the decomposition products from being swept away and thereby preventing, retarding or reversing the silicon carbide decomposition reaction. In such an embodiment, as illustrated in the drawing, the silicon carbide shaped green bodies 10 (shown as rotors in the drawing) are preferably placed into a closed environment, such as a covered crucible 12. As sintering proceeds, a partial pressure of silicon is built up within the crucible. (Thermodynamic calculations have shown that at 2325° C., the partial pressure of silicon in equilibrium with silicon carbide is 3×10 -3  atm.) As the silicon vapors build up, the decomposition of the silicon carbide is halted, retarded or reversed. 
     A space 14 should be allowed between the crucibles 12 to increase the available surface area for heat transfer through convection. The spaces enable flow of the furnace gases and thus better convective heat transfer. Crucibles may be stacked, as shown in the drawing. The space 14 between crucibles should be around at least 0.5 inches. A preferred crucible material is graphite, although any crucible material, common to the art, may be utilized. 
     The location of the plasma torch in the furnace is very important to obtain maximum turbulence, and thereby maximize heat extraction, obtain a high energy efficiency, and minimize temperature gradients in the furnace to obtain uniform sintering and thus consistent products. The plasma torch 16 is preferably positioned near the top of the furnace, as shown in the drawing, to avoid cold pockets. In large furnaces, an additional torch or torches 18 are preferably positioned through the center of the furnace wall opposite the primary torch 16, as is shown in the drawing. Preferably, the exhaust outlet 20 is positioned near the bottom of the furnace to minimize heat losses. 
     In another embodiment, the system of the present invention for preventing the decomposition of silicon carbide comprises the utilization of a sacrificial source of silicon carbide, which decomposes before the silicon carbide refractory or ceramic article being sintered. The decomposition products from the sacrificial source saturate the furnace environment with silicon gas and other vapor species, which reverse, prevent or retard the silicon carbide refractory or ceramic article from decomposing. Preferably, a closed environment is used, such as a covered crucible, in conjunction with a sacrificial source, wherein the sacrificial source is placed inside the crucible with the shaped green refractory or ceramic body. An open environment may also be used, wherein the shaped green bodies are placed into open crucibles or placed openly into the furnace along with a sacrificial source of silicon carbide. 
     Normally during sintering of alpha silicon carbide, or other ceramic articles, densification occurs through shrinkage; material from one area of the article is transported to another region of the same article. Usually, material is not exchanged between objects undergoing sintering. The mechanism of densification, important for sintering alpha silicon carbide using the system of the present invention, involves sublimation and condensation. In this mechanism, there is sublimation of the sacrificial source (source) and condensation on the article being sintered (sink). In order to achieve this preferential transport of mass, the chemical potential of the source must be higher than that of the sink. 
     A higher chemical potential and a transport of mass from the sacrificial source to the silicon carbide green bodies may be achieved in three manners: (1) By holding the source at a higher temperature than the sink. This can be effected by placing the sacrificial source in the furnace near the plasma gas inlet; (2) By making the source from a meta-stable form of material, such as a meta-stable crystal phase or an amorphous structure; or (3) By providing source particles having a very small radius of curvature as compared to the particles of the shaped green bodies. 
     Preferably, the sacrificial source should have a much higher surface area than the refractory article being sintered so that the sacrificial source decomposes at a faster rate. Small particles of silicon carbide are preferable since they have both a small radius of curvature and a high surface area. The particles should be spread out as thinly as possible to increase the available surface area and to minimize sintering of the sacrificial source which would lower the available surface area and increase the radius of curvature of the individual particles. 
     Preferably, the sacrificial source or particles are placed near the silicon carbide article to be sintered in a crucible, and most preferably in a covered crucible. A slurry of silicon carbide source particles may be used to coat the insides of the crucible. Alternatively, the article to be sintered may be coated with silicon carbide powder. As another alternative, silicon carbide powder may be placed as a layer in the bottom of the crucible. 
     In another embodiment, the shaped silicon carbide green bodies are stacked or placed openly in the furnace. The silicon carbide source particles may be placed openly in the furnace near the silicon carbide articles, or in a large shallow container to maximize the available surface area. In a completely open furnace environment, it is preferable to locate the sacrificial source material near the plasma gas inlet so that it will be at a higher temperature and thus decompose more quickly than the silicon carbide refractory or ceramic articles. Alternatively, a slurry containing the silicon carbide particles may be applied to the furnace walls. 
     It is preferable to use an oxygen-free gas for sintering silicon carbide articles, so that oxides will not be produced which may have undesirable physical and chemical properties. The preferred gases for sintering of silicon carbide are nitrogen, argon, helium, and/or neon, however, any plasma gas may be used in accordance with the present invention, depending upon product requirements. 
     The system of this invention is useful for sintering standard refractory or ceramic silicon carbide shapes or complex shapes such as backplates, rotors, scroll assemblies and nozzles. Use of the system of this invention results in a product with a good density and a good dimensional tolerance. 
     The invention is further illustrated by the following non-limiting examples. 
     EXAMPLES 1-20 
     Shaped green bodies were positioned at varying heights in an open sintering arrangement within a plasma fired furnace to determine their weight loss and density as a function of furnace position. The plasma torch was located near the top of the furnace and the exhaust outlet was located near the bottom of the furnace. The samples were heated at 300° C./hr to 2325° C. and held for 1 1/2 hours at 2325° C. The weight of each green body was measured before and after sintering to determine the weight loss. Density measurements were taken of the sintered bodies. Results are given in Table 1. Weight loss and density results for a cast silicon carbide body, extending the entire furnace height, are also given in Table 1 for comparison. 
     
                       TABLE 1                                                     
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Summary of Open Sintering                                                 
Ex-   Inches From                                                         
                 Green   Sintered                                         
                                % of    Density                           
ample Bottom     Wt (g)  Wt (g) Green Wt                                  
                                        (g/cm.sup.3)                      
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Cast  Furnace Ht.                                                         
                 1580    1320   83.5    2.95                              
 1    0.0        5.418   4.268  78.8    2.52                              
 2    0.0        5.405   4.549  84.2    2.801                             
 3    0.0        5.444   4.613  84.7    2.821                             
 4    0.0        5.433   4.616  85.0    2.795                             
 5    0.0        5.395   4.504  83.5    2.774                             
 6    0.0        5.450   4.648  85.3    2.852                             
 7    0.0        5.411   4.663  86.1    2.875                             
 8    0.0        5.415   4.508  83.3    2.763                             
 9    0.0        5.382   4.449  82.7    2.729                             
10    0.0        5.392   4.492  83.3    2.765                             
11    13.375     5.438   4.398  80.9    2.710                             
12    13.375     5.408   4.476  82.8    2.770                             
13    13.375     5.408   4.422  81.8    2.739                             
14    13.375     5.394   3.625  67.2    2.669                             
15    13.375     5.340   4.250  79.5    2.648                             
16    13.375     5.436   4.08   75.0    2.622                             
17    14.25      5.411   4.237  78.3    2.626                             
18    14.375     5.415   4.689  86.6    2.820                             
19    14.375     5.425   4.754  87.6    2.886                             
20    16.25      5.438   4.245  78.1    2.618                             
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     Table 1 shows that, in general, the green bodies positioned nearer the top of the furnace (where the plasma torch was positioned) had a lower density and a higher weight loss than samples positioned towards the bottom of the furnace. 
     EXAMPLES 21-25 
     Density measurements were taken of silicon carbide bodies after being sintered in an open sintering environment to compare the effects of furnace position and a sacrificial source of silicon carbide on density. The green bodies were placed at the top or bottom of a plasma fired furnace with the plasma torch located near the top of the furnace and the exhaust outlet located near the bottom of the furnace. A sacrificial source of silicon carbide was present in some of the runs. One of the silicon carbide bodies was placed very close to the plasma torch inlet (top impinged). The average densities obtained are shown in Table 2. 
     
                       TABLE 2                                                     
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Effects of Furnace Position and Presence of a Sacrificial                 
Source on Density in an Open Sintering Environment                        
        Location in  Sacrificial                                          
                               Average Density                            
Example Furnace      Source    (g/cm.sup.3)                               
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21      Bottom       No        2.770                                      
22      Top          No        2.711                                      
23      Bottom       Yes       2.907                                      
24      Top          Yes       2.728                                      
25      Top Impinged Yes       2.651                                      
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     Table 2 shows that samples located at the top of the furnace (where the plasma torch was positioned) had a lower density than those located on the bottom of the furnace. Also, the presence of a sacrificial source resulted in higher densities. 
     EXAMPLES 26-30 
     Density measurements were taken of silicon carbide bodies after being sintered within open crucibles to compare the effects of furnace position and a sacrificial source on density. The green bodies were placed at the top or bottom of a plasma fired furnace with the plasma torch located near the top of the furnace and the exhaust outlet located near the bottom of the furnace. A sacrificial source of silicon carbide was present in some of the runs. One of the samples was impinged by the plasma torch. The average densities obtained are shown in Table 3. 
     
                       TABLE 3                                                     
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Effects of Furnace Position and Presence of a Sacrificial                 
Source on Density in an Open Crucible Arrangement                         
        Location in  Sacrificial                                          
                               Average Density                            
Example Furnace      Source    (g/cm.sup.3)                               
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26      Bottom       No        3.143                                      
27      Top          No        3.109                                      
28      Bottom       Yes       3.152                                      
29      Top          Yes       3.155                                      
30      Top Impinged Yes       2.826                                      
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     Comparing the results of Table 3 with those of Table 2 demonstrate that placing the silicon carbide green bodies in an open crucible yields much higher densities than when using a complete open sintering environment. Table 3 also shows higher densities being obtained when a sacrificial source was present except when the sample was impinged by the plasma torch. 
     EXAMPLES 31-36 
     Density measurements were taken of silicon carbide bodies sintered in several runs within an open crucible and containing a silicon carbide sacrificial source, and sintered within a closed crucible not containing a sacrificial source, to compare the effects on density of (1) furnace position, (2) a sacrificial source, and (3) covering the crucible. The green bodies were placed in crucibles at the top and bottom of a plasma fired furnace with the plasma torch located near the top of the furnace and the exhaust outlet located near the bottom of the furnace. A sacrificial source of silicon carbide was placed into the open crucibles only. One of the samples was impinged by the plasma torch. The average densities obtained are shown in Table 4. 
     
                       TABLE 4                                                     
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Effects of Furnace Position, Closed Sintering, and Open                   
Sintering With a Sacrificial Source on Density                            
Ex-   Location in Sacrificial                                             
                            Cruci-                                        
                                  Average Density                         
ample Furnace     Source    ble   (g/cm.sup.3)                            
______________________________________                                    
31    Bottom      No        Closed                                        
                                  3.157                                   
32    Top         No        Closed                                        
                                  3.149                                   
33    Bottom      Yes       Open  3.152                                   
34    Top         Yes       Open  3.155                                   
35    Top Impinged                                                        
                  No        Closed                                        
                                  3.140                                   
36    Top Impinged                                                        
                  Yes       Open  3.004                                   
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     Table 4 shows that impingement of the samples by the plasma torch results in the lowest densities. Table 4 also shows that positioning of the green body in the bottom of the plasma furnace (away from the plasma torch) results in higher densities. Table 4 also shows that similar densities are obtained using an open crucible containing a sacrificial source, and using a closed crucible not containing a sacrificial source. 
     EXAMPLES 37-42 
     Silicon carbide articles were sintered in three different arrangements in a plasma furnace: (1) Two covered crucibles, coated on the inside with a slurry of silicon carbide powder having a surface area of 129 m 2  /g, one positioned at the top of the furnace and the other positioned at the bottom of the furnace; (2) Two covered crucibles, containing silicon carbide powder with a surface area of 36 m 2  /g, one positioned at the top of the furnace and the other positioned at the bottom of the furnace; and (3) Two covered crucibles, containing no sacrificial source, one positioned at the top of the furnace and the other positioned at the bottom of the furnace. A plasma torch was located near the top of the furnace and the exhaust outlet was located near the bottom of the furnace. Density measurements were taken of all the samples. Results are given in Table 5. 
     
                       TABLE 5                                                     
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Effect of Sacrificial Source on Closed Sintering Environment              
          Location in   Type of  Density                                  
Example   Furnace       Source   (g/cm.sup.3)                             
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37        Bottom        None     3.137                                    
38        Bottom        Coating  3.143                                    
39        Bottom        Powder   3.128                                    
40        Top           Coating  3.135                                    
41        Top Impinged  Powder   3.089                                    
42        Top Impinged  None     3.116                                    
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     Table 5 shows that samples located at the bottom of the furnace had a higher density than those located at the top of the furnace (where the plasma torch was positioned). The lowest densities were obtained when they were impinged by the plasma torch. Use of a coating as the sacrificial source, in general, resulted in higher densities. 
     Accordingly, a system has been provided for preventing, retarding or reversing the decomposition of silicon carbide articles during high temperature plasma sintering. The system comprises, in one embodiment, positioning of the plasma torch near the top of the furnace and the exhaust outlet near the bottom of the furnace, leaving a space between crucibles and covering the crucibles. In another embodiment, the system comprises the use of a sacrificial source of silicon carbide which decomposes before the silicon carbide refractory or ceramic article. 
     Although the invention has been described with reference to its preferred embodiment, other embodiments can achieve the same results. Variations and modifications of the present invention will be obvious to those skilled in the art and it is intended to cover in the appended claims all such modifications and equivalents.