Patent Publication Number: US-2011062247-A1

Title: Flow regulating articles and methods of manufacture

Description:
CROSS REFERENCE TO RELATED APPLICATIONS 
     This application is a continuation of U.S. patent application Ser. No. 11/412,444, filed 27 Apr. 2006, which is herein incorporated by reference. 
    
    
     BACKGROUND 
     This invention relates generally to fluid flow regulating articles, and more particularly, to flow regulating articles that include shape memory alloys. 
     Air and other gaseous or liquid fluids, for example water or oil, are sometimes used for cooling structures when operating at elevated temperatures. The amount of fluid flow and the temperature of the cooling fluid can effect the rate of cooling of the structure. Typically, the fluid flow is controlled to increase at elevated operating temperatures to maintain the structure at or below predetermined maximum temperatures. 
     Known flow regulating systems include at least one sensor to monitor environmental changes. Flow regulation is typically provided by the use of hydraulic and/or pneumatic actuation systems. The control of the actuation systems is accomplished by electronic systems coupled to the sensors. These known flow regulating systems add complexity and cost to the overall system. 
     BRIEF DESCRIPTION OF THE INVENTION 
     In one aspect, a flow regulating article is provided. The flow regulating article comprises a patterned structure. The patterned structure includes a shape memory alloy capable of changing shape at predetermined temperatures. 
     In another aspect, a method of manufacturing a flow regulating article is provided. The method includes forming a patterned structure. The patterned structure includes a shape memory alloy capable of changing shape at predetermined temperatures. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1  is a schematic illustration of a flow regulating article at a baseline temperature in accordance with an embodiment of the present invention. 
         FIG. 2  is a schematic illustration of the flow regulating article shown in  FIG. 1  at an elevated temperature. 
         FIG. 3  is an enlarged view of a portion of the top surface of the flow regulating article shown in  FIG. 1 . 
         FIG. 4  is a schematic illustration of a flow regulating article in accordance with another embodiment of the present invention. 
         FIG. 5  is a schematic illustration of the flow regulating article shown in  FIG. 4  at a baseline temperature and at an elevated temperature. 
     
    
    
     DETAILED DESCRIPTION OF THE INVENTION 
     Flow regulating articles and methods of manufacturing these flow regulating articles are described in detail below. The flow regulating article, in an exemplary embodiment, includes a patterned structure. The patterned structure includes a shape memory alloy member capable of actively or passively changing shape at predetermined environmental temperatures, for example, by environmental or other external stimuli such as electrical resistance heating, flow heating, and the like. The flow regulating articles use shape memory alloys to regulate fluid flow without the use of complex sensors, control systems, and/or actuation systems, including hydraulic and/or pneumatic actuation systems. Patterned features in the flow regulating articles coupled with shape memory alloys provide a system that senses environmental change, for example, temperature change, and that passively controls fluid flow by utilizing the ability of the shape memory alloy to change shape at targeted temperatures. Moreover, the flow regulating articles can actively control cooling fluid via external stimuli as desired. Manufacturing methods can utilize micro machining and manufacturing technology to fabricate patterned features, for example, holes, or other desirable shapes, in the flow regulating articles to enhance the effectiveness of flow regulation. The flow regulating articles utilize modular materials systems that can be assembled into a functional component, a device, and a structural component. The flow regulating articles can simulate the thermoregulation functions of the skin of a human body by utilizing a shape memory alloy&#39;s shape memory properties for sensing environmental change and for actuation to regulate flow. The flow regulating articles utilize an autonomous shape memory alloy material system that has fast, on-demand, and location-specific response. 
     Referring to the drawings,  FIG. 1  is a schematic illustration of a flow regulating article  10  at a baseline temperature in accordance with an exemplary embodiment of the present invention, and  FIG. 2  is a schematic illustration of flow regulating article  10  at an elevated temperature. Referring to  FIGS. 1 and 2 , flow regulating article  10  includes a patterned structure  12  and a shape memory alloy member  14  constrained by a biasing element  16 , for example a metallic or polymeric spring, a nonlinear elastic polymer member, or a super-elastic shape memory alloy member. Patterned structure  12  includes a plurality of cooling channels  18  arranged in a pattern in structure  12 , for example, as shown in  FIG. 3 . As shown in  FIG. 1 , at a normal or baseline temperature, shape memory alloy member  14  is adjacent to a bottom surface  20  of structure  12  and permits a low flow of cooling fluid through cooling channels  18 . As shown in  FIG. 2 , at an elevated temperature, the shape memory alloy of member  14  has contracted, for example about 1 percent to about 10 percent, and elastically deflects biasing element  16 . In this configuration, cooling channels become unobstructed, permitting a greater flow of cooling fluid through cooling channels. When the environmental temperature cools to the lower or baseline temperature, the shape memory alloy returns to its original shape, via a biasing force from biasing element  16 , causing member  14  to return to its original position shown in  FIG. 1 . 
     Patterned structure  12  can be formed from any suitable material, for example, but not limited to, Ti-based alloys, Ni-based alloys, Co-based alloys, Fe-based alloys, Al-based alloys, polymeric materials, and the like. The pattern of cooling channels  18  can be formed in structure  12  by any suitable micromachining technique, for example, but not limited to, photolithographic etching, laser micromachining techniques, electron beam micromachining techniques, electrochemical micromachining techniques, electrodischarge micromachining techniques, and combinations thereof. 
     Shape memory alloys can exist in one of several distinct temperature-dependent phases. The most commonly utilized of these phases are the so-called martensite and austenite phases. Upon heating through the transformation temperature, a shape memory alloy changes from the martensite phase into the austenite phase. The temperature at which this phenomenon starts is referred to as the austenite start temperature (A s ). The temperature at which this phenomenon is complete is called the austenite finish temperature (A f ). When the shape memory alloy is in the austenite phase and is cooled, it begins to change into the martensite phase, and the temperature at which this phenomenon starts is referred to as the martensite start temperature (M s ). The temperature at which the alloy finishes transforming to the martensite phase is called the martensite finish temperature (M f ). Generally, the shape memory alloys are soft and compliant in their martensitic phase and are hard and stiff in the austenitic phase. 
     Shape memory alloys can exhibit a one-way shape memory effect, an intrinsic two-way shape memory effect, or an extrinsic two-way shape memory effect, depending on the alloy composition and processing history. Annealed shape memory alloys typically exhibit the one-way shape memory effect. Heating subsequent to low-temperature (below M f ) deformation of the shape memory material will induce the martensite to austenite transition, and the material will recover the remembered, high-temperature (above A f ) shape. Upon cooling through the austenite to martensite temperature, the alloy will not change shape. Hence, one-way shape memory effects are only observed upon heating. 
     Intrinsic and extrinsic two-way shape memory materials are characterized by a shape transition both upon heating from the martensite phase to the austenite phase, as well as upon cooling from the austenite phase back to the martensite phase. Shape memory alloy structures that exhibit an intrinsic two-way shape memory effect are fabricated from a shape memory alloy composition that will revert to its “remembered” low-temperature shape. Intrinsic two-way shape memory behavior is imparted by training the shape memory material through processing. Such processing can include extreme deformation of the material while in the martensite phase, heating-cooling under constraint or load, or surface modification such as laser annealing, or shot-peening. Once the material has been trained to exhibit the two-way shape memory effect, the shape change between the low and high temperature states is generally reversible and persists through a high number of thermal cycles. In contrast, structures that exhibit the extrinsic two-way shape memory effects are composite or multi-component materials that combine a shape memory alloy composition that exhibits a one-way effect with another element that provides an elastic restoring force to return the structure to its original shape on cooling. 
     Shape memory alloys can exhibit superelastic behavior. Superelastic behavior results if the shape memory alloy is deformed at a temperature that is slightly above its transformation temperature, A s , with a stress or strain level within its recoverable range. The superelastic effect is caused by a stress-induced transformation of some martensite above its normal temperature, M s . Because it has been formed above its normal temperature, the martensite reverts immediately to an undeformed austenite when the stress is removed. As such, the shape memory alloy article can exhibit “rubber-like” elasticity. In addition, superelastic shape memory alloys can be strained several times more than ordinary metal alloys without being plastically deformed. Superelastic behavior, however, is only observed over a specific temperature range. The highest temperature at which martensite can no longer be stress induced is generally called M d . Above M d , shape memory alloys remain austenitic and are deformed and hardened like ordinary materials by dislocation, motion and multiplication. Below A s , the material is martensitic and exhibits no superelasticity. Thus, superelasticity appears in a temperature range from near A s  to M d . The largest ability to recover occurs close to A f . 
     Suitable shape memory alloy materials include, but are not intended to be limited to, nickel-titanium based alloys, nickel-titanium-platinum based alloys, nickel-titanium-palladium based alloys, nickel-titanium-hafnium based alloys, nickel-titanium-zirconium based alloys, indium-titanium based alloys, nickel-aluminum based alloys, nickel-platinum-aluminum based alloys, nickel-gallium based alloys, copper based alloys (e.g., copper-zinc alloys, copper-aluminum alloys, copper-gold alloys, and copper-tin alloys), gold-cadmium based alloys, silver-cadmium based alloys, indium-cadmium based alloys, manganese-copper based alloys, iron-platinum based alloys, iron-palladium based alloys, ruthenium-niobium based alloys, ruthenium-tantalum based alloys, titanium based alloys, iron-based alloys, and the like. The alloys can be binary, ternary, or any higher order so long as the alloy composition exhibits a shape memory effect upon heating or cooling through the martensite/austenite phase transition temperatures or a superelastic effect upon stress or strain induced phase transition. Selection of a suitable shape memory alloy composition depends on the temperature range where the component will operate and other property requirements characteristic to the specific application. 
     The term “shape memory alloy” is also intended to include shape memory alloy composites, wherein the shape memory alloy based composite comprises a matrix of shape memory alloy and at least one hard particulate phase. The hard particulate phase comprises borides, oxides, nitrides, carbides, or combinations comprising at least one of the foregoing particulates. In alternate embodiments, the shape memory alloy composites comprises a multilayer structure of the shape memory alloy alternating with a metallic or a ceramic layer. The ceramic layer is selected from the group consisting of borides, oxides, nitrides, and carbides. The metallic layer is selected from the group consisting of Ti, Ni, Co, Ti-based alloys, Ni-based alloys, Co-based alloys, Fe-based alloys, particles or fibers of the shape memory alloy in a polymeric matrix, and the like. Further, shape memory alloy composites can include multilayers of shape memory alloy with super-elastic shape memory alloy. 
     In yet another alternative embodiment, the composite may further include ultra-fine grained materials such as may be produced by severe plastic deformation processes generally known by those skilled in the art. For example, suitable severe plastic deformation processes for obtaining the desired grains sizes include, but are not intended to be limited to, ball milling, impact deformation, shot peening, high pressure torsion processing, and the like. Preferred grain sizes are less than 1 micrometer, with grain sizes less than 0.1 micrometer more preferred. Suitable ultra-fine grained materials are characterized by high hardness, resistance to recrystallization, slow grain growth upon annealing, and low dislocation density interior of grains. 
     The shape memory alloy can be affixed to flow regulating article  12  by method of mechanical, adhesive, or metallurgical bonding. The specific method of metallurgical bonding will depend on shape memory alloy composition, the composition of the flow regulating article, as well as other design and application parameters. Suitable methods include, but are not intended to be limited to, brazing, fusion welding, solid-state welding, deformation induced joining by co-extrusion or co-forging, diffusion bonding (explosion bonding, hot-isotactic-pressing), cladding (laser, electron beam, plasma transfer arc), physical vapor deposition (sputtering, ion plasma, electron beam), thermal spraying (vacuum, air plasma, cold spraying, high-velocity oxy-fuel), and the like. In another embodiment, the shape memory alloy can be formed into an insert and/or coupon, which can then be attached to flow regulating article  12 . In another embodiment, flow regulating article  12  is formed directly from the shape memory alloy. 
       FIG. 4  is a schematic illustration of a self actuating flow regulating article  50  in accordance with another exemplary embodiment of the present invention and  FIG. 2  is a sectional schematic illustration of self actuating flow regulating article  50  at a base temperature and at an elevated temperature. Referring to  FIGS. 4 and 5 , flow regulating article  50  includes a patterned structure  52 . Patterned structure  52  includes a plurality of louvers  54  arranged in a pattern in structure  52 . Patterned structure  52  is a composite that includes an elastic (or superelastic) membrane layer  55  joined to a shape memory alloy layer  56 . The left side of  FIG. 5  shows structure  52  at a base temperature with louvers  54  in a closed position. Louvers  54  include flow channels  58  which permit some flow of fluid through louvers  54  at the base temperature. The right side of  FIG. 5  shows structure  52  at an elevated temperature where shape memory alloy layer  56  has changed shape due to the elevated temperature which moves louvers  54  into an open position with flow channels enlarged (larger flow area) to permit a high flow rate through structure  52 . When the temperature returns to the base temperature, shape memory alloy layer  56  is restored to the position shown on the left side of  FIG. 5  by elastic membrane layer  55 . In another exemplary embodiment, flow regulating article  50  has a smooth outer surface  60  at the base temperature and a rough outer surface at the elevated temperature. The change in surface roughness alters the surface drag coefficient and changes the fluid flow over outer surface  60  which changes the heat transfer coefficients. 
     The activation of the shape memory alloy can occur by environmental conditions (passive), for example, changes in temperature or pressure. Also, the activation of the shape memory alloy can be actively accomplished by external heat sources that a user can raise and/or lower. Examples of external heat sources include, but are not limited to, electrical elements, electric current passing through the shape memory alloy, radiant heat sources. Further, the shape memory alloy configurations described above which are in a closed position (or base line position) at a base line temperature and then open when heated can be configured to be open at the base line temperature and then close when heated. 
     The flow regulating articles and methods of manufacture are not limited to the specific embodiments described herein. In addition, components of each flow regulating article and each method described can be practiced independent and separate from other components and methods described herein. Each component and methods also can be used in combination with other assembly packages and methods. 
     While the invention has been described in terms of various specific embodiments, those skilled in the art will recognize that the invention can be practiced with modification within the spirit and scope of the claims.