Patent Publication Number: US-4317897-A

Title: Process for the production of extensively amorphous homo- and/or copolymers of α-olefins of 3 or more carbon atoms

Description:
BACKGROUND OF THE INVENTION 
     It is known that α-olefins of 3 or more carbon atoms, such as propene and butene-1, can be polymerized using catalyst combinations of transition metal compounds and metal alkyls, i.e., to so-called Ziegler-Natta catalysts. 
     It is furthermore known that certain of these catalyst combinations, e.g., δ-TiCl 3  with AlEt 2  Cl [M. Ogushi, CEER 8:49 (1976)], are especially effective in achieving a high proportion of monomer units incorporated in an isotactic arrangement. Due to this stereospecific structure, the thus-produced polyolefins are able to crystallize. This has a favorable effect on a number of properties, e.g., hardness, rigidity, strength. Accordingly, such polymers, primarily polypropylene, have developed into synthetic resins which can be used with great versatility and are manufactured industrially in large amounts. 
     In addition to isotactic polymers, however, all of these catalysts also yield more or less large quantities of atactic components differing from the former, inter alia, by extensive amorphism, solubility in hydrocarbons and tackiness. The latter are ordinarily isolated during the work up step to which the solvents used in the polymerization are subjected. Originally, these atactic components represented an undesirable and unavoidable by-product, whose appearance was to be minimized. However, due to efforts directed toward exploiting this unavoidable by-product, numerous uses have since been discovered. For example, the atactic polymer produced can be utilized in coating textiles, primarily for carpet backing, and paper. In addition, they can be used in the production of noise-damping materials and adhesives, sealing and caulking compounds, road-marking compositions, as well as bituminous materials which are used in road construction and roof coverings. 
     The development of novel processes for the production of polyolefins, primarily polypropylene (see, e.g., DOS&#39;s [German Unexamined Laid-Open Applications] Nos. 2,621,874 and 2,635,163), has provided a greatly improved exploitation of the catalysts, and also enabled a higher stereospecificity. As a result, the amount of thus-produced atactic material was no longer sufficient to cover all the marketing needs. 
     Consequently, processes have also been developed for preparing extensively atactic polyolefins. In these methods, a lowering of the stereospecificity can be attained by several measures which sometimes are also employed in combination. For example, in place of the mentioned α-TiCl 3  catalyst component, a titanium compound can be employed which has been prepared in situ by the reduction of TiCl 4  and/or of titanium(IV) alcoholates (German Patent No. 1,795,483). In another option, aluminum trialkyls or fluorinated aluminum alkyls are employed in place of the diethyl aluminum monochloride (German Patent No. 1,931,421 and Belgian Patent No. 733,692) frequently utilized for the production of polyolefins of high stereospecificity. It is also possible to prepare amorphous products using a Ziegler-Natta catalyst containing magnesium chloride (DOS No. 2,153,520 and German Patent No. 2,329,641). Additionally, the titanium component can be replaced by VCl 4  (Japanese Patent No. 4,005,753). 
     However, all of these prior-art methods exhibit deficiencies. The exploitation of the catalyst, for example, leaves much to be desired; as a result, the content of catalyst residues in the polymer is relatively high unless more or less expensive scrubbing processes are employed. As is known, the consequence of such additional processes is that the stability of the products is impaired. 
     Often, the content of isotactic components is still so high that the desired degree of amorphism can be attained disadvantageously, only by polymerization at an elevated temperature of above 100° C. (German Patent No. 2,329,641). 
     SUMMARY OF THE INVENTION 
     Accordingly, it is an object of the present invention to provide a process for the production of homo- and/or copolymers of α-olefins of 3 or more carbon atoms, by means of which it is possible to increase catalyst utilization, e.g., lifetime and activity, and to increase the yield of amorphous polymers while employing low, economically beneficial temperatures during the polymerization. 
     Upon further study of the specification and appended claims, further objects and advantages of this invention will become apparent to those skilled in the art. 
     These objects have been attained by providing a process for the preparation of extensively amorphous homo- and/or copolymers of α-olefins of 3 or more carbon atoms by the polymerization of the α-olefins using a titanium-containing Ziegler-Natta catalyst, which comprises carrying out the polymerization using a catalyst comprising: 
     1. the reaction products of 
     1.1 μ-oxoalkoxides of formula (I) 
     
         Ti.sub.x O.sub.(x+y-1) M.sub.y.sup.m (OR.sup.1) (2x+1).sup.Z (m-1)y (I) 
    
      wherein 
     1.1.1 M is a metal of valence m, 
     1.1.2 R 1  is alkyl of 1-10 carbon atoms, 
     1.1.3 Z is a carboxylate or alcoholate residue, 
     1.1.4 x has a value of 1-4, 
     1.1.5 y has a value of 1-2, and 
     
         1.1.6 m is 2, 3 or 4, 
    
      with 
     1.2 halogen-containing organoaluminum compounds of formula (II) 
     
         R.sub.n.sup.2 AlX.sub.3-n                                  (II) 
    
      wherein 
     1.2.1 R 2  is alkyl of 1-16 carbon atoms, 
     1.2.2 X is chlorine, bromine or iodine, and 
     1.2.3 n has a value of 0.5-2.5, and 
     2. aluminum trialkyls of up to 16 carbon atoms in each alkyl residue. 
    
    
     DETAILED DISCUSSION 
     Extensively amorphous homo- and copolymers are understood to mean, herein, products having a heptane solubility of &gt;50% by weight. For homo- and copolymers made up entirely or predominantly of α-olefins of at least 4 carbon atoms, a further criterion of amorphism is the ether solubility (diethyl ether). In the products produced by the process of this invention, this solubility generally is &gt;20% by weight, preferably &gt;50% by weight. The heptane- or ether-soluble proportions of the polymers are conventionally determined after 16 hours of extraction of samples in the Soxhlet apparatus and subsequent drying and weighing of the residue (e.g., per ASTM D 2765-68). 
     Suitable α-olefins of 3 or more carbon atoms are of the formula R 3  CH═CH 2  wherein R 3  is alkyl of 1-30 carbon atoms, preferably 1-8 carbon atoms. Propene and butene-1 are preferred. All monomers can be homopolymerized or copolymerized with one another in any desired ratio. Moreover, copolymerization of these monomers with ethylene is likewise possible in such an amount that up to 20% by weight, preferably 0.1-10% by weight, of ethylene is contained in the copolymer. 
     The μ-oxoalkoxides of formula I employed as transition metal components of the catalyst of this invention can be readily prepared by conventional methods. See, e.g., (F. Schmid, Houben-Weyl, 6/2 (1963) and Ph. Teyssie et al., Inorg. Chem. Acta 19 (1976): 2031). 
     Suitable metals are those in groups II to VIII of the periodic table. 
     In formula I, M is a metal of one of the valences m, i.e., 2, 3 or 4; for example for m=2: magnesium, manganese, zinc, chromium, molybdenum, iron, cobalt and nickel; for m=3: aluminium, lanthanum, cerium, vanadium, chromium and iron; and for m=4: titanium, zirconium, vanadium and cerium. m=2 is preferred, especially magnesium. R 1  is alkyl of 1-10 carbon atoms, preferably 2-4 carbon atoms. Z is a carboxylate residue of up to 18 carbon atoms, preferably 2-8 carbon atoms, more preferably an alkanoyloxy residue of these carbon atom ranges, especially acetate; an alcoholate residue of 1-10 carbon atoms, preferably 2-4 carbon atoms, more preferably an alkoxy residue of these carbon atom ranges. The Z residues can be unsaturated or substituted by halogen, alkoxy- and optionally substituted aminogroups. x can be a whole or fractional number of 1-4, preferably 1-2; and y can be a whole or fractional number of 1-2, preferably 1-1.5. 
     One method for the preparation of these μ-oxoalkoxides is by thermal ester cleavage from mixtures of titanium alcoholates of the formula Ti(OR 1 ) 4 , wherein the residues R 1  can be identical or different alkyl residues of 1-10 carbon atoms, preferably 2-4 carbon atoms, and anhydrous carboxylates, preferably acetates of divalent, trivalent or tetravalent metals, e.g., magnesium, manganese, zinc, aluminum, lanthanum, cerium, titanium and the like; or of mixtures of titanium carboxylates or titanium alcoholate carboxylates of the formula TiZ 4 , wherein Z is as defined for formula I, and metal alcoholates M m  (OR 1 ) m  wherein M, R 1  and m are also as defined for formula I. Generally, suitable temperatures are 150°-250° C. 
     Another way of producing μ-oxoalkoxides is by partial cohydrolysis of 2:1 alcoholate complexes of Meerwein or of alcoholate mixtures of Ti(OR 1 ) 4  and M m  (OR 1 ) m , wherein M, R 1  and m are as defined for formula I. The residues R 1  in the titanium alcoholate and metal alcoholate need not be identical. Especially suitable are μ-oxoalkoxides with M=magnesium and a molar ratio of Mg:Ti of 0.25-1.5. 
     The μ-oxoalkoxides may optionally be modified before they are reacted with component 1.2. For example, they can be fixed onto supports carrying hydroxy groups, such as, for example, silicic acid (SiO 2 ) and aluminum oxides, or onto halogen-containing supports, by combined grinding, e.g., in a ball mill for 1-15 hours, such as, for example, magnesium chloride, rare earth chlorides and aluminum chloride [K. H. Reichert, &#34;Chem.-Ing.-Tech.&#34; [Chemical Engineering] 49 (1977): 626-633 and J. C. W. Chien, J. T. T. Hsieh, Journ. of Polym. Sci., Poly., Chem. Ed. 14 (1976): 1915-1932]. They can also be modified by reaction, e.g., with vanadium oxytrichloride, vanadium tetrachloride or titanium tetrachloride, e.g., by reaction at 50°-200° C. for 0.5-10 hours. Suitable are molar ratios of modifying metal to titanium in the original μ-oxoalkoxide in the range of 0.5-4. The μ-oxoalkoxides previously soluble in the solvents which may be employed in the process of this invention are rendered heterogeneous by these modification methods. 
     A preferred modification is by reaction with TiCl 4  or any of the vanadium chlorides. In the reaction with the vanadium chloride, a molar ratio of 0.5 to 2 relative to the starting μ-oxoalkoxide is especially preferred. 
     Surprisingly, the separated μ-oxoalkoxides as well as their modified derivatives are far superior to the mixtures of the starting materials in their efficacy. 
     Suitable halogen-containing organoaluminum compounds have the formula R n   2  AlX 3-n  (II). R 2  is alkyl of 1-16 carbon atoms, preferably 2-4 carbon atoms and can be the same or different. X is chlorine, bromine or iodine, preferably chlorine. n is a whole or fractional number of 0.5-2.5, preferably 1-2. Suitable such compounds for the reaction with the μ-oxoalkoxides of formula I include, for example, diethyl aluminum monochloride, ethyl aluminum dichloride, isobutyl aluminum dichloride, etc., and mixtures thereof. 
     To react the catalyst component 1.1 with the catalyst component 1.2, 1.1 is dissolved in a saturated hydrocarbon, e.g., hexane, heptane, the hydrogenated petroleum ether customarily utilized in ethylene polymerizations, cyclohexane, isopropylcyclohexane and hydrogenated diesel oils, and combined in a concentration of 0.25-1.5 mole of transition metal per liter of solvent with a corresponding solution of 1.2. Generally, the 0.25-1.5 molar solution of 1.1 is first prepared, and then a 0.5-2.0 molar, preferably a 1-molar solution is 1.2 in one of the above-mentioned solvents is added dropwise thereto at a maximally constant temperature in the range of 0° to 100° C. over a period of time of 0.5-2 hours. Thereafter, the thus-obtained suspension is aged over a time period of 1-10 hours at temperatures in the range of 50°-200° C. Thereafter, the product is filtered, the precipitate is washed with a solvent mentioned above and finally suspended. 
     The polymerization-active catalyst is suitably prepared in the polymerization apparatus by reacting, i.e., mixing, the catalyst component 2 with the reaction product of 1.1 and 1.2. Suitable catalysts components 2 include aluminum trialkyls of up to 16, preferably 3-10 carbon atoms, in each alkyl residue. The alkyl groups may be the same or different. Especially preferred is triisobutyl aluminum. In general, the aluminum trialkyls are used in an approximately 1-molar solution, e.g., 0.5-10 molar, in a saturated hydrocarbon, e.g., those mentioned above, which is compatible with the polymerization solvent, in such a quantity that the ratio of Ti:Al (of catalyst component (2) is 1:2-1:20. 
     The polymerization can be conducted continuously or discontinuously. Solvents employed are ordinarily those which have been mentioned above, i.e., the saturated hydrocarbons. However, it is also possible to employ liquid C 3  - and/or C 4  -cuts or liquefied α-olefins as the solvents. The polymerization temperature is generally 30°-150° C., preferably 40°-90° C. 
     The molecular weight of the product can be regulated, as is conventional, by the addition of hydrogen. Moreover, the molecular weights are affected, as is known, by the polymerization temperature, the pressure and the composition of the individual catalyst components. The polymerization batches can be worked up by following the usual prior-art methods, such as, for example, precipitation with an alcohol or an alcohol-water mixture or by removing the solvent by distillation. The method selected depends on the viscosity of the polymer solution or suspension involved. In general, unless indicated otherwise herein, all details of the process of this invention are conventional and may be determined, for example, as described in High Polymers, Vol XXIX (1977), Ed. by C. E. Schildknecht and J. Skeist. 
     The polymers or copolymers obtained according to the process of this invention can be utilized for all purposes already recited and/or known for the utilization of atactic polyolefins. 
     Without further elaboration, it is believed that one skilled in the art can, using the preceding description, utilize the present invention to its fullest extent. The following preferred specific embodiments are, therefore, to be construed as merely illustrative, and not limitative of the remainder of the disclosure in any way whatsoever. In the following examples, all temperatures are set forth uncorrected in degrees Celsius; unless otherwise indicated, all parts and percentages are by weight. 
     In the following examples and comparative examples, the viscosity number I (cc/g) was determined according to DIN [German Industrial Standard] 53 728, and the heptane-or ether-soluble components of the polymers were determined by 16-hour extraction in a Soxhlet apparatus. 
     The abbreviations used herein have the following meanings: 
     TEA=triethylaluminum 
     TIBA=triisobutylaluminum 
     TNOA=tri-n-octylaluminum 
     TNDA=tri-n-decylaluminum 
     TNHA=tri-n-hexadecylaluminum 
     Bu=n-butyl 
     Et=ethyl 
     AcO=acetate 
     Preparation of μ-Oxoalkoxides by (a) Cohydrolysis and (b) Ester Condensation 
     In method (a), 600 millimoles of Ti(OBu) 4  and 300 millimoles of Mg(OEt) 2  were refluxed in 350 ml of n-butanol for one-half hour. Then 600 mmol of water in 250 ml of butanol was added dropwise, and the reaction mixture was heated under reflux for 10 hours. After cooling, the mixture was filtered and evaporated to dryness. The distillate was examined by gas chromatography; in addition to the solvent butanol, 500 mmol of ethanol was found from the magnesium ethylate. For further processing, the solid residue, containing 18.5% of titanium and 2.86% of magnesium, corresponding to a molar ratio of Mg:Ti=0.31, was taken up in 1 liter of a hydrogenated petroleum ether [benzine] fraction (boiling point about 68° C.). This μ-oxoalkoxide will be denoted by I hereinbelow. 
     In method (b), the reactants indicated in Table 1 were heated under reflux for the indicated time periods in the indicated amounts--dissolved in decahydronaphthalene. After distilling the ester and decahydronaphthalene, the remaining mixture was taken up in hydrogenated petroleum ether and optionally filtered. The concentration of titanium was about 0.4 mole per liter. In the distillates, the indicated amounts of butyl acetate were determined by gas chromatrography. 
     
                                           TABLE 1                                 
__________________________________________________________________________
                               5                                          
Symbol for                                                                
      1    2     3     4       Reaction                                   
                                    6    7                                
μ-Oxo-                                                                 
      Ti(OBu).sub.4                                                       
           Mg(OEt).sub.2                                                  
                 Mg(OAc).sub.2                                            
                       &#34;Decalin&#34;                                          
                               Time AcOBu                                 
                                         Mg/Ti                            
alkoxide                                                                  
      (mmol.)                                                             
           (mmol.)                                                        
                 (mmol.)                                                  
                       (ml.)   (h.) (mmol.)                               
                                         (mol/mol)                        
__________________________________________________________________________
II    400        200     400   10   193  0.35                             
III   400        200     400   15   220  0.65                             
IV    200        600     200   10   221  0.91                             
V       100.sup.(1)                                                       
           100           100   10   .sup.(2)                              
                 100     100   10        1.37                             
VI    400        400     600   12     483.sup.(3)                         
                                         0.87                             
__________________________________________________________________________
 .sup.(1) Ti(OBu).sub.2 (OAc).sub.2 was used as the Ti compound, rather   
 than Ti(OBu).sub.4, and reacted in succession with respectively 100 mmol.
 of Mg(OEt).sub.2 and Mg(OAc).sub.2.                                      
 .sup.(2) Not determined.                                                 
 .sup.(3) Continuous removal of the ester by distillation.                
 
    
     Reaction of the μ-Oxoalkoxide Solutions (Hydrogenated Petroleum Ether as the Solvent) with Halogen-Containing Organo-aluminum Compounds 
     The μ-oxoalkoxides I through VI and the corresponding catalyst components indicated in the comparative examples of Table 2 were reacted with a 1-molar solution of halogen-containing organoaluminum compound of Formula II in hydrogenated petroleum ether in the respectively indicated molar ratios of aluminum:titanium per Table 2. The solution of catalyst component 1.2 was added dropwise to the provided solution of catalyst component 1.1 at 25°-30° C. Thereafter, an aging step was conducted for 1 hour, unless indicated otherwise, at 68° C. (boiling point of the hydrogenated petroleum ether). After filtration of the suspension, the precipitate was washed repeatedly with the indicated solvent, taken up in hydrogenated petroleum ether, and the thus-obtained suspension was used in the polymerization. 
     EXAMPLES 1-5 AND COMPARATIVE EXAMPLES A AND B 
     A 5-liter steel autoclave was charged respectively with 2.5 liters of hydrogenated petroleum ether, to which were added 6 ml of a 1-molar AlEt 3  solution in hydrogenated petroleum ether, and the respectively indicated amount of titanium (in mmol). The autoclave was then topped with hydrogen under normal pressure (=1 bar) and heated to 50° C. After this temperature had been reached, the propene conduit was opened up, and the thus-fed propene was polymerized for one-half hour under the initial excess pressure. The feed of propene was then terminated and the charge was further polymerized for another 11/2 hours under falling pressure. The final pressure is indicated in the column &#34;Pressure&#34; of Table 2. After the polymer solution or suspension had been cooled to room temperature (25° C.), it was forced out of the autoclave, and the polymer was precipitated with 5 liters of a mixture of isopropanol/methanol (volume ratio 1:2). The product was then freed of residual solvent by drying at 50° C. under vacuum. For comparison purposes, Comparative Example A deals with alcoholates which are not linked to oxygen, and Comparative Example B involves a commercially available α-TiCl 3  catalyst (ATR). The yield is indicated as the activity in g. of polypropylene per millimole of titanium (g. PP/mol. Ti). 
     
                                           TABLE 2                                 
__________________________________________________________________________
                          Amount              Heptane-                    
                          Ti in                                           
                               Pressure       Soluble                     
Example or                                                                
       μ-Oxoalkoxide                                                   
               Catalyst                                                   
                      Molar                                               
                          1.1 and                                         
                               initial-                                   
                                     Activity Compo-                      
Comparative                                                               
       (1.1) of Com-                                                      
               Component                                                  
                      Ratio                                               
                          1.2  final g. PP/                               
                                          I   nents                       
Example No.                                                               
       parison Product                                                    
               1.2    Al/Ti                                               
                          (mmol.)                                         
                               (bar) mmol. Ti                             
                                          (cc./g.)                        
                                              (%)                         
__________________________________________________________________________
1      I       AlEtCl.sub.2                                               
                      3   3    6.3-2.3                                    
                                     182  183 71                          
2      II      AlEtCl.sub.2                                               
                      3   2    4.9-1.3                                    
                                     246  115 70                          
3      III     AlEtCl.sub.2                                               
                      3   1.5  7.0-3.8                                    
                                     252  229 75                          
4      IV      AlEtCl.sub.2                                               
                      3   0.77 5.0-2.8                                    
                                     242  100 75                          
5      V       AlEtCl.sub.2                                               
                      3   1    5.3-3.7                                    
                                     132   70 78                          
A      2Ti(OBu).sub.4.sup.+                                               
               AlEtCl.sub.2                                               
                      3   1    7.3-6.3                                    
                                      30   81 84                          
       Mg(OEt).sub.2                                                      
B      α-TiCl.sub.3                                                 
               --     --  3    6.9-2.0                                    
                                      73  164 66                          
__________________________________________________________________________
 
    
     EXAMPLES 6-12 
     The procedure was the same as for Examples 1-5 except that modifications were made in component 1.2, in the solvent and in the aging temperature. The activation of the reaction products from 1.1 and 1.2 was effected respectively with 10 mmol of AlEt 3 . The results are indicated in Table 3. 
     
                                           TABLE 3                                 
__________________________________________________________________________
                            6               9                             
        2     3   4   5     Pressure                                      
                                  7         Heptane-                      
Ex-                                                                       
   1    Catalyst                                                          
              Molar                                                       
                  Aging                                                   
                      Amount Ti                                           
                            initial-                                      
                                  Activity                                
                                       8    Soluble                       
ample                                                                     
   μ-Oxo-                                                              
        Component                                                         
              Ratio                                                       
                  Temp.                                                   
                      in 1.1 and                                          
                            final g. PP/                                  
                                       I    Components                    
No.                                                                       
   alkoxide                                                               
        1.2   Al/Ti                                                       
                  (°C.)                                            
                      1.2 (mmol.)                                         
                            (bar) mmol. Ti                                
                                       (cc./g.)                           
                                            (%)                           
__________________________________________________________________________
6  IV   AlEtCl.sub.2                                                      
              3    98.sup.(1)                                             
                      0.81  4.9-1.3                                       
                                  528  106  78                            
7  IV   AlEtCl.sub.2                                                      
              3   145.sup.(2)                                             
                      0.82  5.1-3.6                                       
                                  126  77   80                            
8  V    AlEtCl.sub.2                                                      
              6   68  1.0   4.2-1.0                                       
                                  420  80   74                            
9  V    AlEtCl.sub.2                                                      
              6   68  1.46  4.5-0.4                                       
                                  420  111  70                            
10 V    AlEtCl.sub.2                                                      
              12  68  1.42  4.9-2.0                                       
                                   63  99   67                            
11 V    AlEt.sub.2 Cl                                                     
              6   68  2.0   3.8-0.9                                       
                                  140  72   76                            
12 V    AlEt.sub.2 Cl                                                     
              12  68  1.0   4.5-0.6                                       
                                  456  76   74                            
__________________________________________________________________________
 .sup.(1) Solvent = Heptane                                               
 .sup.(2) Solvent = &#34;Decalin                                              
 
    
     EXAMPLES 13-18 
     In these examples the μ-oxoalkoxides were treated, prior to reaction with component 1.2, with a metal halide of the type indicated. In Examples 13 and 14, the μ-oxoalkoxide solution was refluxed with VOCl 3  in the indicated molar ratio for one hour; in Examples 15-18, the μ-oxoalkoxide solution was ground together with the indicated metal halide for 3 hours in a ball mill at 25° C. Thereafter, reaction with component 1.2 was carried out at 68° C. Activation and polymerization took place as in Examples 1-5. The results are shown in Table 4. 
     
                                           TABLE 4                                 
__________________________________________________________________________
                                                 10                       
                           6      7              Heptane-                 
             3   4     5   Amount Ti                                      
                                  Pressure                                
                                        8        Soluble                  
Ex-                                                                       
   1     2   Molar                                                        
                 Catalyst                                                 
                       Molar                                              
                           in 1.1 initial-                                
                                        Activity                          
                                             9   Compo-                   
ample                                                                     
   μ-Oxoalk-                                                           
         Metal                                                            
             Ratio                                                        
                 Component                                                
                       Ratio                                              
                           and 1.2                                        
                                  final g. PP/                            
                                             I   nents                    
No.                                                                       
   oxide Halide                                                           
             M/Ti                                                         
                 1.2   Al/Ti                                              
                           (mmol.)                                        
                                  (bar) mmol. Ti                          
                                             (cc./g.)                     
                                                 (%)                      
__________________________________________________________________________
13 VI    VOCl.sub.3                                                       
             1   AlEtCl.sub.2                                             
                       6   1.1.sup.(1)                                    
                                  6.5-4.2                                 
                                        555.sup.(1)                       
                                             194 75                       
14 II    VOCl.sub.3                                                       
             2   AlEt.sub.2 Cl                                            
                       18  0.5.sup.(1)                                    
                                  4.9-1.7                                 
                                        804.sup.(1)                       
                                             123 68                       
15 II    MgCl.sub.2                                                       
             1   AlEtCl.sub.2                                             
                       3   1.05   8.4-6.1                                 
                                        342  123 77                       
16 II    MgCl.sub.2                                                       
             10  AlEtCl.sub.2                                             
                       3   0.98   8.2-3.5                                 
                                        700  157 75                       
17 VI    MgCl.sub.2                                                       
             1   AlEtCl.sub.2                                             
                       3   1.1    8.7-4.8                                 
                                        578   65 76                       
18 I     AlCl.sub.3                                                       
             5   AlEt.sub.2 Cl                                            
                       3   3.0    6.0-4.2                                 
                                         70  162 62                       
__________________________________________________________________________
 .sup.(1) Titanium and Vanadium                                           
 
    
     EXAMPLES 19-25 
     The mode of operation used in the polymerization with the catalysts of Examples 1-5 was repeated, with the modification that the activation of the washed catalysts in the autoclave was conducted, instead of with TEA as previously, with aluminum alkyls with hydrocarbon residues larger than 2 carbon atoms as recited in Table 5. Also, the ratio of Al/Ti of components 1.1 and 1.2, as well as the partial H 2  pressure (Examples 24 and 25) was modified in several examples. For activating purposes, 10 mmol of the indicated aluminum trialkyl was utilized. The results are shown in Table 5. 
     
                                           TABLE 5                                 
__________________________________________________________________________
                                                    Heptane-              
                                                    Sol-                  
                  Amount Ti   Pressure              uble                  
Ex-      Catalyst                                                         
              Molar                                                       
                  in 1.1 Catalyst                                         
                              initial-                                    
                                    Polym. Activity Compo-                
ample                                                                     
   μ-Oxoalk-                                                           
         Compo-                                                           
              Ratio                                                       
                  and 1.2                                                 
                         Compo-                                           
                              final Temp.                                 
                                        H.sub.2                           
                                           g. PP/                         
                                                I   nents                 
No.                                                                       
   oxide nent 1.2                                                         
              Al/Ti                                                       
                  (mmol.)                                                 
                         nent 2                                           
                              (bar) (°C.)                          
                                        (bar)                             
                                           mmol. Ti                       
                                                (cc./g.)                  
                                                    (%)                   
__________________________________________________________________________
19 IV    AlEtCl.sub.2                                                     
              3   0.5    TIBA 5.0-0.9                                     
                                    50  1.0                               
                                           912  87  85                    
20 IV    AlEtCl.sub.2                                                     
              3   0.5    TNOA 4.4-0.7                                     
                                    50  1.0                               
                                           696  87  83                    
21 IV    AlEtCl.sub.2                                                     
              3   0.5    TNDA 5.0-0.9                                     
                                    50  1.0                               
                                           672  71  86                    
22 IV    AlEtCl.sub.2                                                     
              3   0.5    TIBA 5.2-0.8                                     
                                    70  1.0                               
                                           866  92  85                    
23 IV    AlEtCl.sub.2                                                     
              3   0.5    TIBA 5.6-2.1                                     
                                    85  1.0                               
                                           510  74  81                    
24 VI    AlEtCl.sub.2                                                     
              6   1.0    TEA  4.6-0.5                                     
                                    50  1.5                               
                                           504  63  74                    
25 VI    AlEtCl.sub.2                                                     
              6   1.0    TEA  4.6-0.9                                     
                                    50  2.0                               
                                           350  43  78                    
__________________________________________________________________________
 
    
     EXAMPLES 26-29 AND COMPARATIVE EXAMPLES C AND D 
     The mode of operation in polymerization Examples 1 through 5 was repeated, with the modification that 2.5 liters of hydrogenated petroleum ether was provided in the autoclave, and the activator, 10 ml of a 1-molar TIBA-hexane solution, and the catalyst suspension (1.1 and 1.2) were added by pipetting in the indicated quantities. After topping off with hydrogen, 800 ml of propene was then added under pressure and the polymerization was started up by heating to 50° C. After 2 hours, the mixture was cooled to 25° C.; and the viscous polymer solution was forced out of the autoclave and worked up analogously to Examples 1-5. In comparative Example C, the indicated compounds of catalyst components, which had not reacted with each other, were utilized and tested under the same conditions. It can clearly be seen from a comparison of Examples 26 and C that the condensed oxoalkoxide forms a substantially more active catalyst than do the unreacted starting compounds. The results are set forth in Table 6. 
     
                                           TABLE 6                                 
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                                                  8                       
                             4     5              Heptane-                
                         3   Amount of                                    
                                   Pressure                               
                                         6        Soluble                 
Ex-                                                                       
   1             2       Molar                                            
                             Ti in 1.1                                    
                                   Drop  Activity                         
                                              7   Compo-                  
ample                                                                     
   μ-Oxoalkoxide (1.1)                                                 
                 Catalyst                                                 
                         Ratio                                            
                             and 1.2                                      
                                   pC.sub.3                               
                                         g. PP/                           
                                              I   nents                   
No.                                                                       
   or Comparison Product                                                  
                 Component 1.2                                            
                         Al/Ti                                            
                             (mmol.)                                      
                                   (bar) mmol. Ti                         
                                              (cc./g.)                    
                                                  (%)                     
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26 V             AlEtCl.sub.2                                             
                         6   0.28  6.4-1.1                                
                                         1240 77  75                      
27 VI            AlEtCl.sub.2                                             
                         6   0.3   6.4-2.4                                
                                          946 76  79                      
28 VI            AlEt.sub.1.5 Cl.sub.1.5                                  
                         6   0.35  6.4-1.3                                
                                          930 79  83                      
29 VI + VOCl.sub.3 (Ti:V = 1)                                             
                 AlEt.sub.2 Cl                                            
                         12  0.13  6.5-1.7                                
                                         2480.sup.(1)                     
                                              97  74                      
C  Ti(OBu).sub.4 + Mg(OAc).sub.2                                          
                 AlEtCl.sub.2                                             
                         6   0.75  6.0-0.1                                
                                          507 61  85                      
D  α-TiCl.sub.3                                                     
                 --      --  1.0   6.3-3.8                                
                                          149 96  71                      
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 .sup.(1) g. PP/mmol. (Ti + V)                                            
 
    
     EXAMPLES 30-42 AND COMPARATIVE EXAMPLES E-H 
     A 5-liter steel autoclave was charged in succession with 2.5 liters of hydrogenated petroleum ether, with the aluminum trialkyl indicated in Table 7, in the respective amount, and furthermore with the respectively indicated quantity of titanium. After topping off with nitrogen (1 bar), 400 ml of liquid butene-1, abbreviated as C 4  in the tables, was added, and the charge was heated in each case to 50° C. After 2 hours, the highly viscous polymer was discharged and worked up as described in Examples 1-5. The results are indicated in Table 7. 
     
                                           TABLE 7                                 
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                       Amount                                             
   Reaction            of                                                 
   Product                                                                
         Amount Ti     Catalyst                                           
                             Pressure             Ether-                  
Ex-                                                                       
   1.1 and                                                                
         in 1.1 Catalyst                                                  
                       Compo-                                             
                             Drop   Activity      Soluble                 
ample                                                                     
   1.2 Acc.                                                               
         and 1.2                                                          
                Component                                                 
                       nent 2                                             
                             pC.sub.4                                     
                                    g. PB-.sup.(1)                        
                                             I    Proportions             
No.                                                                       
   to Ex. No.                                                             
         (mmol.)                                                          
                2      (mmol.)                                            
                             (bar)  /mmol. Ti                             
                                             (cc./g.)                     
                                                  (%)                     
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30 1     2.53   TEA     6    1.5-1.2                                      
                                    28       417  21                      
31 2     3.0    TEA     6    1.2-0.4                                      
                                    68       291  38                      
32 4     0.76   TEA    10    1.1-1.0                                      
                                    71       185  59                      
33 5     2.0    TEA    10    1.3-1.2                                      
                                    13       533  23                      
34 6     0.81   TEA    10    1.2-0.7                                      
                                    201      391  44                      
35 8     1.0    TEA    10    1.2-0.2                                      
                                    273      161  51                      
36 9     2.0    TEA    10    1.1-0.2                                      
                                    103      188  54                      
37 10    1.42   TEA    10    1.2-0.7                                      
                                    127      304  44                      
38 11    2.0    TEA    10    1.1-0.8                                      
                                    61       221  51                      
39 12    1.0    TEA    10    1.2-0.6                                      
                                    213      283  39                      
40 8     0.11   TIBA   10    1.2-0.8                                      
                                    1018     381  48                      
41 8     0.5    TNOA   10    1.0-0.0                                      
                                    526      251  64                      
42 8     0.28   TNHA   10    1.2-0.6                                      
                                    774      345  60                      
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                                                    Ether                 
                 Amount Ti   Amount of                                    
                                    Pressure        Soluble               
Comp.            in Comp.                                                 
                       Catalyst                                           
                             Catalyst                                     
                                    Drop  Activity  Compo-                
Example          Product                                                  
                       Component                                          
                             Component 2                                  
                                    pC.sub.4                              
                                          g. PB-.sup.(1)                  
                                                I   nents                 
No.  Comparison Products                                                  
                 (mmol.)                                                  
                       2     (mmol.)                                      
                                    (bar) /mmol. Ti                       
                                                (cc./g.)                  
                                                    (%)                   
__________________________________________________________________________
E    A           2.0   TEA   6      1.7-1.6                               
                                          1     --  --                    
F    Ti(OBu).sub.4 + Mg(OEt).sub.2                                        
                 0.8   TEA   10     1.1-0.8                               
                                          107   200 49                    
G    C           0.75  TIBA  10     1.1-0.4                               
                                          254   285 60                    
H    α-TiCl.sub.3                                                   
                 3.0   TIBA  6      1.6-0.7                               
                                          85    463 49                    
__________________________________________________________________________
 
    
     EXAMPLES 43-46 
     The apparatus described in the preceding examples was charged with 2.5 liters of hydrogenated petroleum ether, 10 mmol of TIBA and 0.38 mmol of Ti in the form of the reaction products of catalyst components 1.1 and 1.2 of Example 6. The liquid monomers propene and butene-1 were added in succession and in metered amounts to this reaction mixture in the respectively indicated quantities. A hydrogen pressure of 1.5 bar was applied, and the mixture was polymerized for 2 hours at 50° C. After cooling to 25° C., the copolymer solution was forced out of the autoclave, and the solvent was removed by distillation. The results are indicated in Table 8. 
     
                       TABLE 8                                                     
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                                       Ether-                             
                                       Sol-                               
                                       uble                               
Ex-                                    Compo-                             
ample                                                                     
     Propene  Butene-1  g. Polymer/                                       
                                 I     nents                              
No.  (g.)     (g.)      mmol. Ti (cc/g)                                   
                                       (%)                                
______________________________________                                    
43    26      331       794      69    78.7                               
44    52      301       710      61    91                                 
45   105      240       780      61    95.4                               
46   157      180       850      62    93.4                               
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     The preceding examples can be repeated with similar success by substituting the generically or specifically described reactants and/or operating conditions for those used in the preceding examples. 
     From the foregoing description, one skilled in the art can easily ascertain the essential characteristics of this invention, and without departing from the spirit and scope thereof, can make various changes and modifications of the invention to adapt it to various usages and conditions.