Patent Publication Number: US-2007111024-A1

Title: Metal complex compound and organic electroluminescence device containing the same

Description:
TECHNICAL FIELD  
      The present invention relates to a novel metal-complex compound and an organic electroluminescence device using the compound. Particularly, the present invention relates to an organic electroluminescence device (“electroluminescence” will be referred to as “EL”, hereinafter) having excellent efficiency of light emission and prolonged lifetime, and to a metal-complex compound realizing it.  
     BACKGROUND ART  
      The organic EL devices have been expected to be applied to color wide screen image display devices replacing liquid crystal display devices, and have been intensively developed. Recently, although displays using the organic EL devices have now been used in practical applications, full-color image display devices using the same are still in the course of development because they lack in sufficient light emitting property. Very high-efficiency green organic light-emitting devices based on electrophosphorescence employing ortho metalized iridium complex (fac-tris(2-phenylpyridine) iridium) as a phosphorus light emitting material for improving properties of the organic EL device are proposed. (refer to, for example, D. F. O&#39;Brien and M. A. Baldo et al “Improved energy transferring electrophosphorescent devices” Applied Physics letters Vol. 74 No. 3, pp 442-444, Jan. 18, 1999; and M. A. Baldo et al “Very high-efficiency green organic light emitting devices based on electrophosphorescence” Applied Physics letters Vol. 75 No. 1, pp 4-6, Jul. 5, 1999)  
      Because the current organic EL devices employing the phosphorus photoluminescence are limited to emitting only green light, coverage as the color display devices is narrow. Therefore, it has been demanded to develop organic EL devices which emit light of different colors from green with improved light emission property. Regarding particularly with EL devices which emit blue light, those having an external quantum yield exceeding 5% is not reported yet. Accordingly, an improvement in the EL devices which emit blue light, if possible, enables the display devices to display full colors or white light resultantly advancing toward practical use of phosphorus light EL device greatly.  
     DISCLOSURE OF THE INVENTION  
      The present invention has been made to overcome the above problems and has an object of providing an organic EL device having excellent efficiency of light emission and prolonged lifetime, and an object of providing a metal-complex compound realizing it.  
      As a result of intensive researches and studies to achieve the above object by the present inventors, it was found that an employment of a metal-complex compound having a partial structure represented by a following general formula (I) provides the EL device having excellent efficiency of light emission and prolonged lifetime, resultantly completing the present invention.  
      Namely, the present invention provides a metal-complex compound having a partial structure represented by a following general formula (I):  
                 
 
 wherein structure B represents a benzene ring structure having R 1  to R 4 ; R 1  to R 4  each independently represents a hydrogen atom, a cyano group, a halogen atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted amino group, a substituted or unsubstituted alkoxyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aromatic group having 1 to 30 carbon atoms; at least one among R 1  to R 4  is a cyano group; and a couple of R 1  and R 2 , a couple of R 2  and R 3 , and a couple of R 3  and R 4  may bond each other to form a ring structure; 
 
 structure A represents a ring structure having 3 to 20 carbon atoms, further having at least one carbon-nitrogen double bond and may have a substituent; which may form a ring structure having the foregoing R 4 ; and 
 
 M represents any one metal atom selected from iridium (Ir) atom, rhodium (Rh) atom, platinum (Pt) atom or palladium (Pd) atom. 
 
      Further, the present invention provides an organic EL device which comprises at least one organic thin film layer sandwiched between a pair of electrode consisting of an anode and a cathode, wherein the organic thin film layer comprises the above metal-complex compound, which emits light by applying an electric voltage between the pair of electrode.  
    
    
     THE PREFERRED EMBODIMENT TO CARRY OUT THE INVENTION  
      The present invention provides a metal-complex compound having a partial structure represented by a following general formula (I):  
                 
 
      In the general formula (I), the structure B represents a benzene ring structure having R 1  to R 4 ; R 1  to R 4  each independently represents a hydrogen atom, a cyano group, a halogen atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted amino group, a substituted or unsubstituted alkoxyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aromatic group having 1 to 30 carbon atoms; at least one among R 1  to R 4  is a cyano group; and a couple of R 1  and R 2 , a couple of R 2  and R 3 , and a couple of R 3  and R 4  may bond each other to form a ring structure.  
      Examples of the halogen atom include fluorine atom, chlorine atom, bromine atom and iodine atom, etc.  
      Examples of the alkyl group described above include methyl group, ethyl group, propyl group, isopropyl group, n-butyl group, s-butyl group, isobutyl group, t-butyl group, n-pentyl group, n-hexyl group, n-heptyl group, n-octyl group, etc. The alkoxy group is expressed as —OY, wherein Y represents the same as the foregoing description about the alkyl group.  
      Examples of the above aromatic group include benzene, naphthalene, anthracene, phenanthrene, pyrene, coronene, biphenyl, terphenyl, pyrrole, furan, thiophene, benzothiophene, oxadi azoline, diphenylanthracene, indoline, carbazole, pyridine, benzoquinone, fluoranthene, acenaphtho fluoranthene, etc.  
      Further, examples of the substituent for those groups include halogen atom, hydroxyl group, substituted or unsubstituted amino group, nitro group, cyano group, substituted or unsubstituted alkyl group, fluorination alkyl group, substituted or unsubstituted alkenyl group, a substituted or unsubstituted cycloalkyl group, substituted or unsubstituted alkoxyl group, substituted or unsubstituted heterocyclic group, substituted or unsubstituted arylalkyl group, a substituted or unsubstituted aryloxy group, substituted or unsubstituted alkoxycarbonyl group, carboxyl group, etc.  
      It is preferable that R 1  to R 4  each independently represents a hydrogen atom, a cyano group, a fluorine atom, a trifluoromethyl group, a dimethylamino group and a methoxy group.  
      Further, it is preferable that the above structure B represents a substituted benzene ring moiety represented by any one of following formulae:  
                 
 
      In the general formula (I), structure A represents a ring structure having 3 to 20 carbon atoms, further having at least one carbon-nitrogen double bond and may have a substituent; which may form a ring structure having the foregoing R 4 .  
      Examples of the ring structure include monovalent groups such as pyridine, chinoline, isoquinoline, pyrimidine, pyrazine, pyridazine, imidazole, oxaline, oxazole, isoxazole, thiazole, isothiazole, etc; and it is preferable that the above structure A represents a group represented by any one of following formulae:  
                 
 
      Substituents for the ring structure are the same as described about the substituents for the above structure B.  
      In the general formula (I), M represents any one metal atom selected from iridium (Ir) atom, rhodium (Rh) atom, platinum (Pt) atom or palladium (Pd) atom, while Ir being preferable.  
      Further, it is preferable that the partial structure represented by the general formula (I) is expressed by any one of following formulae:  
                 
 
      It is preferable that the metal-complex compound of the present invention has any one basic skeletal structure shown among following general formulae 1 to 8:  
                 
                 
 
      In the general formulae 1 to 8, R 1  to R 10  each independently represents a hydrogen atom, a cyano group, a halogen atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted amino group having 1 to 20 carbon atoms, a substituted or unsubstituted alkoxyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aromatic group having 1 to 30 carbon atoms; at least one among R 1  to R 4  being a cyano group. Further, a couple of R 1  and R 2 , a couple of R 2  and R 3 , a couple of R 3  and R 4 , a couple of R 4  and R 5 , a couple of R 5  and R 6 , a couple of R 6  and R 7 , a couple of R 7  and R 8 , a couple of R 8  and R 9 , or a couple of R 9  and R 10  may bond to form a ring structure.  
      Examples of the above halogen atom, alkyl group, alkoxyl group and aromatic group or those substituent are the same as explained about R 1  to R 4  in the general formula (I), and preferable examples include similarly.  
      In the general formulae 1 to 8, M represents the same as the foregoing description.  
      In the general formulae 1 to 8, L 1  and L 2  each independently has a structure shown by any one of following structures:  
                 
 
      In the general formulae 1 to 8, n represents an integer of 0 to 2, preferably 0 or 1, and m represents an integer of 0 or 1.  
      Specific examples of the metal-complex compound having any one basic skeletal structure among the general formulae 1 to 8 will be shown in Tables below, though not limited thereto.  
      In the Tables below, R 1  to R 8 , L 1  and L 2  (in the cases of the basic skeletal structures 1 and 5) or R 1  to R 10 , L 1  and L 2  (except the cases of the basic skeletal structures 1 and 5) are described within the columns righter to the basic skeletal structures.  
      In the Tables below, BSS means Basic Skeletal Structure.  
                                                                   TABLE 1                       No.   M   n   BSS   R 1     R 2     R 3     R 4     R 5     R 6     R 7     R 8     L 1     L 2                                                                                      1-1   Ir   1   1   H   CN   H   H   H   H   H   H   pic       1-1X   Ir   1   1   H   CN   H   H   H   H   H   H   acac                                                                     1-1Y   Ir   0   1   H   CN   H   H   H   H   H   H   —   —                                                                 1-2   Ir   1   1   H   H   CN   H   H   H   H   H   pic       1-2X   Ir   1   1   H   H   CN   H   H   H   H   H   acac                                                                     1-2Y   Ir   0   1   H   H   CN   H   H   H   H   H   —   —                                                                 1-3   Ir   1   1   H   H   H   CN   H   H   H   H   pic       1-3X   Ir   1   1   H   H   H   CN   H   H   H   H   acac                                                                     1-3Y   Ir   0   1   H   H   H   CN   H   H   H   H   —   —                                                                 1-4   Ir   1   1   CN   H   H   H   H   H   H   H   pic       1-4X   Ir   1   1   CN   H   H   H   H   H   H   H   acac                                                                     1-4Y   Ir   0   1   CN   H   H   H   H   H   H   H   —   —                                                                 1-5   Ir   1   1   H   CN   H   CN   H   H   H   H   pic       1-5X   Ir   1   1   H   CN   H   CN   H   H   H   H   acac                                                                     1-5Y   Ir   0   1   H   CN   H   CN   H   H   H   H   —   —                                                                 1-6   Ir   1   1   CN   H   CN   H   H   H   H   H   pic       1-6X   Ir   1   1   CN   H   CN   H   H   H   H   H   acac                                                                     1-6Y   Ir   0   1   CN   H   CN   H   H   H   H   H   —   —                                                                 1-7   Ir   1   1   CF 3     CN   CF 3     H   H   H   H   H   pic       1-7X   Ir   1   1   CF 3     CN   CF 3     H   H   H   H   H   acac                                                                     1-7Y   Ir   0   1   CF 3     CN   CF 3     H   H   H   H   H   —   —                                                                 1-8   Ir   1   1   H   CN   CF 3     H   H   H   H   H   pic       1-8X   Ir   1   1   H   CN   CF 3     H   H   H   H   H   acac                                                                     1-8Y   Ir   0   1   H   CN   CF 3     H   H   H   H   H   —   —                                                                 1-9   Ir   1   1   H   CN   H   F   H   H   H   H   pic       1-9X   Ir   1   1   H   CN   H   F   H   H   H   H   acac                                                                     1-9Y   Ir   0   1   H   CN   H   F   H   H   H   H   —   —                                                                 1-10   Ir   1   1   H   F   H   CN   H   H   H   H   pic       1-10X   Ir   1   1   H   F   H   CN   H   H   H   H   acac                                                                     1-10Y   Ir   0   1   H   F   H   CN   H   H   H   H   —   —                                                                 1-11   Ir   1   1   CN   F   CN   F   H   H   H   H   pic       1-11X   Ir   1   1   CN   F   CN   F   H   H   H   H   acac                                                                     1-11Y   Ir   0   1   CN   F   CN   F   H   H   H   H   —   —                                                                 1-12   Ir   1   1   CF 3     CN   CF 3     CN   H   H   H   H   pic       1-12X   Ir   1   1   CF 3     CN   CF 3     CN   H   H   H   H   acac                                                                     1-12Y   Ir   0   1   CF 3     CN   CF 3     CN   H   H   H   H   —   —                                                                 1-13   Ir   1   1   CF 3     H   CF 3     CN   H   H   H   H   pic       1-13X   Ir   1   1   CF 3     H   CF 3     CN   H   H   H   H   acac                                                                     1-13Y   Ir   0   1   CF 3     H   CF 3     CN   H   H   H   H   —   —                                                                 1-14   Ir   1   1   CF 3     H   H   CN   H   H   H   H   pic       1-14X   Ir   1   1   CF 3     H   H   CN   H   H   H   H   acac                                                                     1-14Y   Ir   0   1   CF 3     H   H   CN   H   H   H   H   —   —                                                                 1-15   Ir   1   1   H   CF 3     H   CN   H   H   H   H   pic       1-15X   Ir   1   1   H   CF 3     H   CN   H   H   H   H   acac                                                                     1-15Y   Ir   0   1   H   CF 3     H   CN   H   H   H   H   —   —                                                                 1-16   Ir   1   1   H   F   CN   F   H   H   H   H   pic       1-16X   Ir   1   1   H   F   CN   F   H   H   H   H   acac                                                                     1-16Y   Ir   0   1   H   F   CN   F   H   H   H   H   —   —                                                                 1-17   Ir   1   1   CF 3     F   CN   F   H   H   H   H   pic       1-17X   Ir   1   1   CF 3     F   CN   F   H   H   H   H   acac                                                                     1-17Y   Ir   0   1   CF 3     F   CN   F   H   H   H   H   —   —                                                                 1-18   Ir   1   1   CN   CN   CN   CN   H   H   H   H   pic       1-18X   Ir   1   1   CN   CN   CN   CN   H   H   H   H   acac                                                                     1-18Y   Ir   0   1   CN   CN   CN   CN   H   H   H   H   —   —                                                                 1-19   Ir   1   1   H   H   H   CN   H   N(CH 3 ) 2     H   H           1-19X   Ir   1   1   H   H   H   CN   H   N(CH 3 ) 2     H   H   acac                                                                     1-19Y   Ir   0   1   H   H   H   CN   H   N(CH 3 ) 2     H   H   —   —                                                                 1-20   Ir   1   1   H   CN   H   CN   H   N(CH 3 ) 2     H   H   pic       1-20X   Ir   1   1   H   CN   H   CN   H   N(CH 3 ) 2     H   H   acac                                                                     1-20Y   Ir   0   1   H   CN   H   CN   H   N(CH 3 ) 2     H   H   —   —                                                                 1-21   Ir   1   1   H   CN   CF 3     H   H   N(CH 3 ) 2     H   H   pic       1-21X   Ir   1   1   H   CN   CF 3     H   H   N(CH 3 ) 2     H   H   acac                                                                     1-21Y   Ir   0   1   H   CN   CF 3     H   H   N(CH 3 ) 2     H   H   —   —                                                                 1-22   Ir   1   1   CF 3     CN   CF 3     H   H   N(CH 3 ) 2     H   H   pic       1-22X   Ir   1   1   CF 3     CN   CF 3     H   H   N(CH 3 ) 2     H   H   acac                                                                     1-22Y   Ir   0   1   CF 3     CN   CF 3     H   H   N(CH 3 ) 2     H   H   —   —                                                                 1-23   Ir   1   1   H   H   H   CN   H   OCH 3     H   H   pic       1-23X   Ir   1   1   H   H   H   CN   H   OCH 3     H   H   acac                                                                     1-23Y   Ir   0   1   H   H   H   CN   H   OCH 3     H   H   —   —                                                                 1-24   Ir   1   1   H   CN   H   CN   H   OCH 3     H   H   pic       1-24X   Ir   1   1   H   CN   H   CN   H   OCH 3     H   H   acac                                                                     1-24Y   Ir   0   1   H   CN   H   CN   H   OCH 3     H   H   —   —                                                                 1-25   Ir   1   1   H   CN   CF 3     H   H   OCH 3     H   H   pic       1-25X   Ir   1   1   H   CN   CF 3     H   H   OCH 3     H   H   acac                                                                     1-25Y   Ir   0   1   H   CN   CF 3     H   H   OCH 3     H   H   —   —                                                                 1-26   Ir   1   1   CF 3     CN   CF 3     H   H   OCH 3     H   H   pic       1-26X   Ir   1   1   CF 3     CN   CF 3     H   H   OCH 3     H   H   acac                                                                     1-26Y   Ir   0   1   CF 3     CN   CF 3     H   H   OCH 3     H   H   —   —                  
 
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 2 
               
               
                   
               
               
                   
               
               
                 No. 
                 M 
                 n 
                 BSS 
                 R 1   
                 R 2   
                 R 3   
                 R 4   
                 R 5   
                 R 6   
                 R 7   
                 R 8   
                 L 1   
                 L 2   
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-1 
                 Rh 
                 1 
                 1 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 1′-1X 
                 Rh 
                 1 
                 1 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-1Y 
                 Rh 
                 0 
                 1 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-2 
                 Rh 
                 1 
                 1 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 1′-2X 
                 Rh 
                 1 
                 1 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-2Y 
                 Rh 
                 0 
                 1 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-3 
                 Rh 
                 1 
                 1 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 1′-3X 
                 Rh 
                 1 
                 1 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-3Y 
                 Rh 
                 0 
                 1 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-4 
                 Rh 
                 1 
                 1 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 1′-4X 
                 Rh 
                 1 
                 1 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-4Y 
                 Rh 
                 0 
                 1 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-5 
                 Rh 
                 1 
                 1 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 1′-5X 
                 Rh 
                 1 
                 1 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-5Y 
                 Rh 
                 0 
                 1 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-6 
                 Rh 
                 1 
                 1 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 1′-6X 
                 Rh 
                 1 
                 1 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-6Y 
                 Rh 
                 0 
                 1 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-7 
                 Rh 
                 1 
                 1 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 1′-7X 
                 Rh 
                 1 
                 1 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-7Y 
                 Rh 
                 0 
                 1 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-8 
                 Rh 
                 1 
                 1 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 1′-8X 
                 Rh 
                 1 
                 1 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-8Y 
                 Rh 
                 0 
                 1 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-9 
                 Rh 
                 1 
                 1 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 1′-9X 
                 Rh 
                 1 
                 1 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-9Y 
                 Rh 
                 0 
                 1 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-10 
                 Rh 
                 1 
                 1 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 1′-10X 
                 Rh 
                 1 
                 1 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-10Y 
                 Rh 
                 0 
                 1 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-11 
                 Rh 
                 1 
                 1 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 1′-11X 
                 Rh 
                 1 
                 1 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-11Y 
                 Rh 
                 0 
                 1 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-12 
                 Rh 
                 1 
                 1 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 1′-12X 
                 Rh 
                 1 
                 1 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-12Y 
                 Rh 
                 0 
                 1 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-13 
                 Rh 
                 1 
                 1 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 1′-13X 
                 Rh 
                 1 
                 1 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-13Y 
                 Rh 
                 0 
                 1 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-14 
                 Rh 
                 1 
                 1 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 1′-14X 
                 Rh 
                 1 
                 1 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-14Y 
                 Rh 
                 0 
                 1 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-15 
                 Rh 
                 1 
                 1 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 1′-15X 
                 Rh 
                 1 
                 1 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-15Y 
                 Rh 
                 0 
                 1 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-16 
                 Rh 
                 1 
                 1 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 1′-16X 
                 Rh 
                 1 
                 1 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-16Y 
                 Rh 
                 0 
                 1 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-17 
                 Rh 
                 1 
                 1 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 1′-17X 
                 Rh 
                 1 
                 1 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-17Y 
                 Rh 
                 0 
                 1 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-18 
                 Rh 
                 1 
                 1 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 1′-18X 
                 Rh 
                 1 
                 1 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-18Y 
                 Rh 
                 0 
                 1 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-19 
                 Rh 
                 1 
                 1 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                   
               
               
                 1′-19X 
                 Rh 
                 1 
                 1 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-19Y 
                 Rh 
                 0 
                 1 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-20 
                 Rh 
                 1 
                 1 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 pic 
               
               
                 1′-20X 
                 Rh 
                 1 
                 1 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-20Y 
                 Rh 
                 0 
                 1 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-21 
                 Rh 
                 1 
                 1 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 pic 
               
               
                 1′-21X 
                 Rh 
                 1 
                 1 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-21Y 
                 Rh 
                 0 
                 1 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-22 
                 Rh 
                 1 
                 1 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 pic 
               
               
                 1′-22X 
                 Rh 
                 1 
                 1 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-22Y 
                 Rh 
                 0 
                 1 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-23 
                 Rh 
                 1 
                 1 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 OCH 3   
                 H 
                 H 
                 pic 
               
               
                 1′-23X 
                 Rh 
                 1 
                 1 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 OCH 3   
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-23Y 
                 Rh 
                 0 
                 1 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 OCH 3   
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-24 
                 Rh 
                 1 
                 1 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 OCH 3   
                 H 
                 H 
                 pic 
               
               
                 1′-24X 
                 Rh 
                 1 
                 1 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 OCH 3   
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-24Y 
                 Rh 
                 0 
                 1 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 OCH 3   
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-25 
                 Rh 
                 1 
                 1 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 pic 
               
               
                 1′-25X 
                 Rh 
                 1 
                 1 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-25Y 
                 Rh 
                 0 
                 1 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-26 
                 Rh 
                 1 
                 1 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 pic 
               
               
                 1′-26X 
                 Rh 
                 1 
                 1 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 1′-26Y 
                 Rh 
                 0 
                 1 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 3 
               
               
                   
               
               
                   
               
               
                 No. 
                 M 
                 n 
                 BSS 
                 R 1   
                 R 2   
                 R 3   
                 R 4   
                 R 5   
                 R 6   
                 R 7   
                 R 8   
                 R 9   
                 R 10   
                 L 1   
                 L 2   
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-1 
                 Ir 
                 1 
                 2 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-1X 
                 Ir 
                 1 
                 2 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-1Y 
                 Ir 
                 0 
                 2 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-2 
                 Ir 
                 1 
                 2 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-2X 
                 Ir 
                 1 
                 2 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-2Y 
                 Ir 
                 0 
                 2 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-3 
                 Ir 
                 1 
                 2 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-3X 
                 Ir 
                 1 
                 2 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-3Y 
                 Ir 
                 0 
                 2 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-4 
                 Ir 
                 1 
                 2 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-4X 
                 Ir 
                 1 
                 2 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-4Y 
                 Ir 
                 0 
                 2 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-5 
                 Ir 
                 1 
                 2 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-5X 
                 Ir 
                 1 
                 2 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-5Y 
                 Ir 
                 0 
                 2 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-6 
                 Ir 
                 1 
                 2 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-6X 
                 Ir 
                 1 
                 2 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-6Y 
                 Ir 
                 0 
                 2 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-7 
                 Ir 
                 1 
                 2 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-7X 
                 Ir 
                 1 
                 2 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-7Y 
                 Ir 
                 0 
                 2 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-8 
                 Ir 
                 1 
                 2 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-8X 
                 Ir 
                 1 
                 2 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-8Y 
                 Ir 
                 0 
                 2 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-9 
                 Ir 
                 1 
                 2 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-9X 
                 Ir 
                 1 
                 2 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-9Y 
                 Ir 
                 0 
                 2 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-10 
                 Ir 
                 1 
                 2 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-10X 
                 Ir 
                 1 
                 2 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-10Y 
                 Ir 
                 0 
                 2 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-11 
                 Ir 
                 1 
                 2 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-11X 
                 Ir 
                 1 
                 2 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-11Y 
                 Ir 
                 0 
                 2 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-12 
                 Ir 
                 1 
                 2 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-12X 
                 Ir 
                 1 
                 2 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-12Y 
                 Ir 
                 0 
                 2 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-13 
                 Ir 
                 1 
                 2 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-13X 
                 Ir 
                 1 
                 2 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-13Y 
                 Ir 
                 0 
                 2 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-14 
                 Ir 
                 1 
                 2 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-14X 
                 Ir 
                 1 
                 2 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-14Y 
                 Ir 
                 0 
                 2 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-15 
                 Ir 
                 1 
                 2 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-15X 
                 Ir 
                 1 
                 2 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-15Y 
                 Ir 
                 0 
                 2 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-16 
                 Ir 
                 1 
                 2 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-16X 
                 Ir 
                 1 
                 2 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-16Y 
                 Ir 
                 0 
                 2 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-17 
                 Ir 
                 1 
                 2 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-17X 
                 Ir 
                 1 
                 2 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-17Y 
                 Ir 
                 0 
                 2 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-18 
                 Ir 
                 1 
                 2 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-18X 
                 Ir 
                 1 
                 2 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-18Y 
                 Ir 
                 0 
                 2 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-19 
                 Ir 
                 1 
                 2 
                 CN 
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-19X 
                 Ir 
                 1 
                 2 
                 CN 
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-19Y 
                 Ir 
                 0 
                 2 
                 CN 
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-20 
                 Ir 
                 1 
                 2 
                 CN 
                 H 
                 H 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-20X 
                 Ir 
                 1 
                 2 
                 CN 
                 H 
                 H 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-20Y 
                 Ir 
                 0 
                 2 
                 CN 
                 H 
                 H 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-21 
                 Ir 
                 1 
                 2 
                 H 
                 H 
                 CN 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-21X 
                 Ir 
                 1 
                 2 
                 H 
                 H 
                 CN 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-21Y 
                 Ir 
                 0 
                 2 
                 H 
                 H 
                 CN 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-22 
                 Ir 
                 1 
                 2 
                 H 
                 H 
                 CN 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-22X 
                 Ir 
                 1 
                 2 
                 H 
                 H 
                 CN 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-22Y 
                 Ir 
                 0 
                 2 
                 H 
                 H 
                 CN 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-23 
                 Ir 
                 1 
                 2 
                 CN 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-23X 
                 Ir 
                 1 
                 2 
                 CN 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2-23Y 
                 Ir 
                 0 
                 2 
                 CN 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 2-24 
                 Ir 
                 1 
                 2 
                 CN 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-24X 
                 Ir 
                 1 
                 2 
                 CN 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 2-24Y 
                 Ir 
                 0 
                 2 
                 CN 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 2-25 
                 Ir 
                 1 
                 2 
                 CN 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-25X 
                 Ir 
                 1 
                 2 
                 CN 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 2-25Y 
                 Ir 
                 0 
                 2 
                 CN 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 2-26 
                 Ir 
                 1 
                 2 
                 CN 
                 H 
                 CF 3   
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-26X 
                 Ir 
                 1 
                 2 
                 CN 
                 H 
                 CF 3   
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 2-26Y 
                 Ir 
                 0 
                 2 
                 CN 
                 H 
                 CF 3   
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 2-27 
                 Ir 
                 1 
                 2 
                 CN 
                 H 
                 H 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-27X 
                 Ir 
                 1 
                 2 
                 CN 
                 H 
                 H 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 2-27Y 
                 Ir 
                 0 
                 2 
                 CN 
                 H 
                 H 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 2-28 
                 Ir 
                 1 
                 2 
                 CN 
                 F 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-28X 
                 Ir 
                 1 
                 2 
                 CN 
                 F 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 2-28Y 
                 Ir 
                 0 
                 2 
                 CN 
                 F 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 2-29 
                 Ir 
                 1 
                 2 
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2-29X 
                 Ir 
                 1 
                 2 
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 2-29Y 
                 Ir 
                 0 
                 2 
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 4 
               
               
                   
               
               
                   
               
               
                 No. 
                 M 
                 n 
                 BSS 
                 R 1   
                 R 2   
                 R 3   
                 R 4   
                 R 5   
                 R 6   
                 R 7   
                 R 8   
                 R 9   
                 R 10   
                 L 1   
                 L 2   
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-1 
                 Rh 
                 1 
                 2 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2′-1X 
                 Rh 
                 1 
                 2 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-1Y 
                 Rh 
                 0 
                 2 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-2 
                 Rh 
                 1 
                 2 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2′-2X 
                 Rh 
                 1 
                 2 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-2Y 
                 Rh 
                 0 
                 2 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-3 
                 Rh 
                 1 
                 2 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2′-3X 
                 Rh 
                 1 
                 2 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-3Y 
                 Rh 
                 0 
                 2 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-4 
                 Rh 
                 1 
                 2 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2′-4X 
                 Rh 
                 1 
                 2 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-4Y 
                 Rh 
                 0 
                 2 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-5 
                 Rh 
                 1 
                 2 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2′-5X 
                 Rh 
                 1 
                 2 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-5Y 
                 Rh 
                 0 
                 2 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-6 
                 Rh 
                 1 
                 2 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2′-6X 
                 Rh 
                 1 
                 2 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-6Y 
                 Rh 
                 0 
                 2 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-7 
                 Rh 
                 1 
                 2 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2′-7X 
                 Rh 
                 1 
                 2 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-7Y 
                 Rh 
                 0 
                 2 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-8 
                 Rh 
                 1 
                 2 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2′-8X 
                 Rh 
                 1 
                 2 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-8Y 
                 Rh 
                 0 
                 2 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-9 
                 Rh 
                 1 
                 2 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2′-9X 
                 Rh 
                 1 
                 2 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-9Y 
                 Rh 
                 0 
                 2 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-10 
                 Rh 
                 1 
                 2 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2′-10X 
                 Rh 
                 1 
                 2 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-10Y 
                 Rh 
                 0 
                 2 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-11 
                 Rh 
                 1 
                 2 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2′-11X 
                 Rh 
                 1 
                 2 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-11Y 
                 Rh 
                 0 
                 2 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-12 
                 Rh 
                 1 
                 2 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2′-12X 
                 Rh 
                 1 
                 2 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-12Y 
                 Rh 
                 0 
                 2 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-13 
                 Rh 
                 1 
                 2 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2′-13X 
                 Rh 
                 1 
                 2 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-13Y 
                 Rh 
                 0 
                 2 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-14 
                 Rh 
                 1 
                 2 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2′-14X 
                 Rh 
                 1 
                 2 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-14Y 
                 Rh 
                 0 
                 2 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-15 
                 Rh 
                 1 
                 2 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2′-15X 
                 Rh 
                 1 
                 2 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-15Y 
                 Rh 
                 0 
                 2 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-16 
                 Rh 
                 1 
                 2 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2′-16X 
                 Rh 
                 1 
                 2 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-16Y 
                 Rh 
                 0 
                 2 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-17 
                 Rh 
                 1 
                 2 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2′-17X 
                 Rh 
                 1 
                 2 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-17Y 
                 Rh 
                 0 
                 2 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-18 
                 Rh 
                 1 
                 2 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 2′-18X 
                 Rh 
                 1 
                 2 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 2′-18Y 
                 Rh 
                 0 
                 2 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 5 
               
               
                   
               
               
                   
               
               
                 No. 
                 M 
                 n 
                 BSS 
                 R 1   
                 R 2   
                 R 3   
                 R 4   
                 R 5   
                 R 6   
                 R 7   
                 R 8   
                 R 9   
                 R 10   
                 L 1   
                 L 2   
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-1 
                 Ir 
                 1 
                 3 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-1X 
                 Ir 
                 1 
                 3 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-1Y 
                 Ir 
                 0 
                 3 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-2 
                 Ir 
                 1 
                 3 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-2X 
                 Ir 
                 1 
                 3 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-2Y 
                 Ir 
                 0 
                 3 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-3 
                 Ir 
                 1 
                 3 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-3X 
                 Ir 
                 1 
                 3 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-3Y 
                 Ir 
                 0 
                 3 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-4 
                 Ir 
                 1 
                 3 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-4X 
                 Ir 
                 1 
                 3 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-4Y 
                 Ir 
                 0 
                 3 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-5 
                 Ir 
                 1 
                 3 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-5X 
                 Ir 
                 1 
                 3 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-5Y 
                 Ir 
                 0 
                 3 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-6 
                 Ir 
                 1 
                 3 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-6X 
                 Ir 
                 1 
                 3 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-6Y 
                 Ir 
                 0 
                 3 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-7 
                 Ir 
                 1 
                 3 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-7X 
                 Ir 
                 1 
                 3 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-7Y 
                 Ir 
                 0 
                 3 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-8 
                 Ir 
                 1 
                 3 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-8X 
                 Ir 
                 1 
                 3 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-8Y 
                 Ir 
                 0 
                 3 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-9 
                 Ir 
                 1 
                 3 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-9X 
                 Ir 
                 1 
                 3 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-9Y 
                 Ir 
                 0 
                 3 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-10 
                 Ir 
                 1 
                 3 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-10X 
                 Ir 
                 1 
                 3 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-10Y 
                 Ir 
                 0 
                 3 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-11 
                 Ir 
                 1 
                 3 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-11X 
                 Ir 
                 1 
                 3 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-11Y 
                 Ir 
                 0 
                 3 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-12 
                 Ir 
                 1 
                 3 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-12X 
                 Ir 
                 1 
                 3 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-12Y 
                 Ir 
                 0 
                 3 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-13 
                 Ir 
                 1 
                 3 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-13X 
                 Ir 
                 1 
                 3 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-13Y 
                 Ir 
                 0 
                 3 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-14 
                 Ir 
                 1 
                 3 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-14X 
                 Ir 
                 1 
                 3 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-14Y 
                 Ir 
                 0 
                 3 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-15 
                 Ir 
                 1 
                 3 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-15X 
                 Ir 
                 1 
                 3 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-15Y 
                 Ir 
                 0 
                 3 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-16 
                 Ir 
                 1 
                 3 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-16X 
                 Ir 
                 1 
                 3 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-16Y 
                 Ir 
                 0 
                 3 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-17 
                 Ir 
                 1 
                 3 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-17X 
                 Ir 
                 1 
                 3 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-17Y 
                 Ir 
                 0 
                 3 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-18 
                 Ir 
                 1 
                 3 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-18X 
                 Ir 
                 1 
                 3 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-18Y 
                 Ir 
                 0 
                 3 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-19 
                 Ir 
                 1 
                 3 
                 CN 
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-19X 
                 Ir 
                 1 
                 3 
                 CN 
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-19Y 
                 Ir 
                 0 
                 3 
                 CN 
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-20 
                 Ir 
                 1 
                 3 
                 CN 
                 H 
                 H 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-20X 
                 Ir 
                 1 
                 3 
                 CN 
                 H 
                 H 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-20Y 
                 Ir 
                 0 
                 3 
                 CN 
                 H 
                 H 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-21 
                 Ir 
                 1 
                 3 
                 H 
                 H 
                 CN 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-21X 
                 Ir 
                 1 
                 3 
                 H 
                 H 
                 CN 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-21Y 
                 Ir 
                 0 
                 3 
                 H 
                 H 
                 CN 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-22 
                 Ir 
                 1 
                 3 
                 H 
                 H 
                 CN 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-22X 
                 Ir 
                 1 
                 3 
                 H 
                 H 
                 CN 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-22Y 
                 Ir 
                 0 
                 3 
                 H 
                 H 
                 CN 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-23 
                 Ir 
                 1 
                 3 
                 CN 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-23X 
                 Ir 
                 1 
                 3 
                 CN 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3-23Y 
                 Ir 
                 0 
                 3 
                 CN 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 3-24 
                 Ir 
                 1 
                 3 
                 CN 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-24X 
                 Ir 
                 1 
                 3 
                 CN 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 3-24Y 
                 Ir 
                 0 
                 3 
                 CN 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 3-25 
                 Ir 
                 1 
                 3 
                 CN 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-25X 
                 Ir 
                 1 
                 3 
                 CN 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 3-25Y 
                 Ir 
                 0 
                 3 
                 CN 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 3-26 
                 Ir 
                 1 
                 3 
                 CN 
                 H 
                 CF 3   
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-26X 
                 Ir 
                 1 
                 3 
                 CN 
                 H 
                 CF 3   
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 3-26Y 
                 Ir 
                 0 
                 3 
                 CN 
                 H 
                 CF 3   
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 3-27 
                 Ir 
                 1 
                 3 
                 CN 
                 H 
                 H 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-27X 
                 Ir 
                 1 
                 3 
                 CN 
                 H 
                 H 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 3-27Y 
                 Ir 
                 0 
                 3 
                 CN 
                 H 
                 H 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 3-28 
                 Ir 
                 1 
                 3 
                 CN 
                 F 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-28X 
                 Ir 
                 1 
                 3 
                 CN 
                 F 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 3-28Y 
                 Ir 
                 0 
                 3 
                 CN 
                 F 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 3-29 
                 Ir 
                 1 
                 3 
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3-29X 
                 Ir 
                 1 
                 3 
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 3-29Y 
                 Ir 
                 0 
                 3 
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 6 
               
               
                   
               
               
                   
               
               
                 No. 
                 M 
                 n 
                 BSS 
                 R 1   
                 R 2   
                 R 3   
                 R 4   
                 R 5   
                 R 6   
                 R 7   
                 R 8   
                 R 9   
                 R 10   
                 L 1   
                 L 2   
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-1 
                 Rh 
                 1 
                 3 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3′-1X 
                 Rh 
                 1 
                 3 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-1Y 
                 Rh 
                 0 
                 3 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-2 
                 Rh 
                 1 
                 3 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3′-2X 
                 Rh 
                 1 
                 3 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-2Y 
                 Rh 
                 0 
                 3 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-3 
                 Rh 
                 1 
                 3 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3′-3X 
                 Rh 
                 1 
                 3 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-3Y 
                 Rh 
                 0 
                 3 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-4 
                 Rh 
                 1 
                 3 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3′-4X 
                 Rh 
                 1 
                 3 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-4Y 
                 Rh 
                 0 
                 3 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-5 
                 Rh 
                 1 
                 3 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3′-5X 
                 Rh 
                 1 
                 3 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-5Y 
                 Rh 
                 0 
                 3 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-6 
                 Rh 
                 1 
                 3 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3′-6X 
                 Rh 
                 1 
                 3 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-6Y 
                 Rh 
                 0 
                 3 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-7 
                 Rh 
                 1 
                 3 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3′-7X 
                 Rh 
                 1 
                 3 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-7Y 
                 Rh 
                 0 
                 3 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-8 
                 Rh 
                 1 
                 3 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3′-8X 
                 Rh 
                 1 
                 3 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-8Y 
                 Rh 
                 0 
                 3 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-9 
                 Rh 
                 1 
                 3 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3′-9X 
                 Rh 
                 1 
                 3 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-9Y 
                 Rh 
                 0 
                 3 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-10 
                 Rh 
                 1 
                 3 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3′-10X 
                 Rh 
                 1 
                 3 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-10Y 
                 Rh 
                 0 
                 3 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-11 
                 Rh 
                 1 
                 3 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3′-11X 
                 Rh 
                 1 
                 3 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-11Y 
                 Rh 
                 0 
                 3 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-12 
                 Rh 
                 1 
                 3 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3′-12X 
                 Rh 
                 1 
                 3 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-12Y 
                 Rh 
                 0 
                 3 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-13 
                 Rh 
                 1 
                 3 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3′-13X 
                 Rh 
                 1 
                 3 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-13Y 
                 Rh 
                 0 
                 3 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-14 
                 Rh 
                 1 
                 3 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3′-14X 
                 Rh 
                 1 
                 3 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-14Y 
                 Rh 
                 0 
                 3 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-15 
                 Rh 
                 1 
                 3 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3′-15X 
                 Rh 
                 1 
                 3 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-15Y 
                 Rh 
                 0 
                 3 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-16 
                 Rh 
                 1 
                 3 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3′-16X 
                 Rh 
                 1 
                 3 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-16Y 
                 Rh 
                 0 
                 3 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-17 
                 Rh 
                 1 
                 3 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3′-17X 
                 Rh 
                 1 
                 3 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-17Y 
                 Rh 
                 0 
                 3 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-18 
                 Rh 
                 1 
                 3 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 3′-18X 
                 Rh 
                 1 
                 3 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 3′-18Y 
                 Rh 
                 0 
                 3 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 7 
               
               
                   
               
               
                   
               
               
                 No. 
                 M 
                 n 
                 BSS 
                 R 1   
                 R 2   
                 R 3   
                 R 4   
                 R 5   
                 R 6   
                 R 7   
                 R 8   
                 R 9   
                 R 10   
                 L 1   
                 L 2   
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-1 
                 Ir 
                 1 
                 4 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-1X 
                 Ir 
                 1 
                 4 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-1Y 
                 Ir 
                 0 
                 4 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-2 
                 Ir 
                 1 
                 4 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-2X 
                 Ir 
                 1 
                 4 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-2Y 
                 Ir 
                 0 
                 4 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-3 
                 Ir 
                 1 
                 4 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-3X 
                 Ir 
                 1 
                 4 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-3Y 
                 Ir 
                 0 
                 4 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-4 
                 Ir 
                 1 
                 4 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-4X 
                 Ir 
                 1 
                 4 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-4Y 
                 Ir 
                 0 
                 4 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-5 
                 Ir 
                 1 
                 4 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-5X 
                 Ir 
                 1 
                 4 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-5Y 
                 Ir 
                 0 
                 4 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-6 
                 Ir 
                 1 
                 4 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-6X 
                 Ir 
                 1 
                 4 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-6Y 
                 Ir 
                 0 
                 4 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-7 
                 Ir 
                 1 
                 4 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-7X 
                 Ir 
                 1 
                 4 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-7Y 
                 Ir 
                 0 
                 4 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-8 
                 Ir 
                 1 
                 4 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-8X 
                 Ir 
                 1 
                 4 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-8Y 
                 Ir 
                 0 
                 4 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-9 
                 Ir 
                 1 
                 4 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-9X 
                 Ir 
                 1 
                 4 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-9Y 
                 Ir 
                 0 
                 4 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-10 
                 Ir 
                 1 
                 4 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-10X 
                 Ir 
                 1 
                 4 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-10Y 
                 Ir 
                 0 
                 4 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-11 
                 Ir 
                 1 
                 4 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-11X 
                 Ir 
                 1 
                 4 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-11Y 
                 Ir 
                 0 
                 4 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-12 
                 Ir 
                 1 
                 4 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-12X 
                 Ir 
                 1 
                 4 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-12Y 
                 Ir 
                 0 
                 4 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-13 
                 Ir 
                 1 
                 4 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-13X 
                 Ir 
                 1 
                 4 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-13Y 
                 Ir 
                 0 
                 4 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-14 
                 Ir 
                 1 
                 4 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-14X 
                 Ir 
                 1 
                 4 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-14Y 
                 Ir 
                 0 
                 4 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-15 
                 Ir 
                 1 
                 4 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-15X 
                 Ir 
                 1 
                 4 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-15Y 
                 Ir 
                 0 
                 4 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-16 
                 Ir 
                 1 
                 4 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-16X 
                 Ir 
                 1 
                 4 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-16Y 
                 Ir 
                 0 
                 4 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-17 
                 Ir 
                 1 
                 4 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-17X 
                 Ir 
                 1 
                 4 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-17Y 
                 Ir 
                 0 
                 4 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-18 
                 Ir 
                 1 
                 4 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-18X 
                 Ir 
                 1 
                 4 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-18Y 
                 Ir 
                 0 
                 4 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-19 
                 Ir 
                 1 
                 4 
                 CN 
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-19X 
                 Ir 
                 1 
                 4 
                 CN 
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-19Y 
                 Ir 
                 0 
                 4 
                 CN 
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-20 
                 Ir 
                 1 
                 4 
                 CN 
                 H 
                 H 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-20X 
                 Ir 
                 1 
                 4 
                 CN 
                 H 
                 H 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-20Y 
                 Ir 
                 0 
                 4 
                 CN 
                 H 
                 H 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-21 
                 Ir 
                 1 
                 4 
                 H 
                 H 
                 CN 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-21X 
                 Ir 
                 1 
                 4 
                 H 
                 H 
                 CN 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-21Y 
                 Ir 
                 0 
                 4 
                 H 
                 H 
                 CN 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-22 
                 Ir 
                 1 
                 4 
                 H 
                 H 
                 CN 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-22X 
                 Ir 
                 1 
                 4 
                 H 
                 H 
                 CN 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-22Y 
                 Ir 
                 0 
                 4 
                 H 
                 H 
                 CN 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-23 
                 Ir 
                 1 
                 4 
                 CN 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-23X 
                 Ir 
                 1 
                 4 
                 CN 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4-23Y 
                 Ir 
                 0 
                 4 
                 CN 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 4-24 
                 Ir 
                 1 
                 4 
                 CN 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-24X 
                 Ir 
                 1 
                 4 
                 CN 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 4-24Y 
                 Ir 
                 0 
                 4 
                 CN 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 4-25 
                 Ir 
                 1 
                 4 
                 CN 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-25X 
                 Ir 
                 1 
                 4 
                 CN 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 4-25Y 
                 Ir 
                 0 
                 4 
                 CN 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 4-26 
                 Ir 
                 1 
                 4 
                 CN 
                 H 
                 CF 3   
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-26X 
                 Ir 
                 1 
                 4 
                 CN 
                 H 
                 CF 3   
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 4-26Y 
                 Ir 
                 0 
                 4 
                 CN 
                 H 
                 CF 3   
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 4-27 
                 Ir 
                 1 
                 4 
                 CN 
                 H 
                 H 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-27X 
                 Ir 
                 1 
                 4 
                 CN 
                 H 
                 H 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 4-27Y 
                 Ir 
                 0 
                 4 
                 CN 
                 H 
                 H 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 4-28 
                 Ir 
                 1 
                 4 
                 CN 
                 F 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-28X 
                 Ir 
                 1 
                 4 
                 CN 
                 F 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 4-28Y 
                 Ir 
                 0 
                 4 
                 CN 
                 F 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 4-29 
                 Ir 
                 1 
                 4 
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4-29X 
                 Ir 
                 1 
                 4 
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 4-29Y 
                 Ir 
                 0 
                 4 
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 8 
               
               
                   
               
               
                   
               
               
                 No. 
                 M 
                 n 
                 BSS 
                 R 1   
                 R 2   
                 R 3   
                 R 4   
                 R 5   
                 R 6   
                 R 7   
                 R 8   
                 R 9   
                 R 10   
                 L 1   
                 L 2   
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-1 
                 Rh 
                 1 
                 4 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4′-1X 
                 Rh 
                 1 
                 4 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-1Y 
                 Rh 
                 0 
                 4 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-2 
                 Rh 
                 1 
                 4 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4′-2X 
                 Rh 
                 1 
                 4 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-2Y 
                 Rh 
                 0 
                 4 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-3 
                 Rh 
                 1 
                 4 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4′-3X 
                 Rh 
                 1 
                 4 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-3Y 
                 Rh 
                 0 
                 4 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-4 
                 Rh 
                 1 
                 4 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4′-4X 
                 Rh 
                 1 
                 4 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-4Y 
                 Rh 
                 0 
                 4 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-5 
                 Rh 
                 1 
                 4 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4′-5X 
                 Rh 
                 1 
                 4 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-5Y 
                 Rh 
                 0 
                 4 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-6 
                 Rh 
                 1 
                 4 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4′-6X 
                 Rh 
                 1 
                 4 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-6Y 
                 Rh 
                 0 
                 4 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-7 
                 Rh 
                 1 
                 4 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4′-7X 
                 Rh 
                 1 
                 4 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-7Y 
                 Rh 
                 0 
                 4 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-8 
                 Rh 
                 1 
                 4 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4′-8X 
                 Rh 
                 1 
                 4 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-8Y 
                 Rh 
                 0 
                 4 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-9 
                 Rh 
                 1 
                 4 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4′-9X 
                 Rh 
                 1 
                 4 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-9Y 
                 Rh 
                 0 
                 4 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-10 
                 Rh 
                 1 
                 4 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4′-10X 
                 Rh 
                 1 
                 4 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-10Y 
                 Rh 
                 0 
                 4 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-11 
                 Rh 
                 1 
                 4 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4′-11X 
                 Rh 
                 1 
                 4 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-11Y 
                 Rh 
                 0 
                 4 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-12 
                 Rh 
                 1 
                 4 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4′-12X 
                 Rh 
                 1 
                 4 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-12Y 
                 Rh 
                 0 
                 4 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-13 
                 Rh 
                 1 
                 4 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4′-13X 
                 Rh 
                 1 
                 4 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-13Y 
                 Rh 
                 0 
                 4 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-14 
                 Rh 
                 1 
                 4 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4′-14X 
                 Rh 
                 1 
                 4 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-14Y 
                 Rh 
                 0 
                 4 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-15 
                 Rh 
                 1 
                 4 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4′-15X 
                 Rh 
                 1 
                 4 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-15Y 
                 Rh 
                 0 
                 4 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-16 
                 Rh 
                 1 
                 4 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4′-16X 
                 Rh 
                 1 
                 4 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-16Y 
                 Rh 
                 0 
                 4 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-17 
                 Rh 
                 1 
                 4 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4′-17X 
                 Rh 
                 1 
                 4 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-17Y 
                 Rh 
                 0 
                 4 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-18 
                 Rh 
                 1 
                 4 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 4′-18X 
                 Rh 
                 1 
                 4 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 4′-18Y 
                 Rh 
                 0 
                 4 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 9 
               
               
                   
               
               
                   
               
               
                 No. 
                 M 
                 m 
                 BSS 
                 R 1   
                 R 2   
                 R 3   
                 R 4   
                 R 5   
                 R 6   
                 R 7   
                 R 8   
                 L 1   
                 L 2   
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-1 
                 Pt 
                 1 
                 5 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5-1X 
                 Pt 
                 1 
                 5 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-1Y 
                 Pt 
                 0 
                 5 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-2 
                 Pt 
                 1 
                 5 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5-2X 
                 Pt 
                 1 
                 5 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-2Y 
                 Pt 
                 0 
                 5 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-3 
                 Pt 
                 1 
                 5 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5-3X 
                 Pt 
                 1 
                 5 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-3Y 
                 Pt 
                 0 
                 5 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-4 
                 Pt 
                 1 
                 5 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5-4X 
                 Pt 
                 1 
                 5 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-4Y 
                 Pt 
                 0 
                 5 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-5 
                 Pt 
                 1 
                 5 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5-5X 
                 Pt 
                 1 
                 5 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-5Y 
                 Pt 
                 0 
                 5 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-6 
                 Pt 
                 1 
                 5 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5-6X 
                 Pt 
                 1 
                 5 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-6Y 
                 Pt 
                 0 
                 5 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-7 
                 Pt 
                 1 
                 5 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5-7X 
                 Pt 
                 1 
                 5 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-7Y 
                 Pt 
                 0 
                 5 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-8 
                 Pt 
                 1 
                 5 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5-8X 
                 Pt 
                 1 
                 5 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-8Y 
                 Pt 
                 0 
                 5 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-9 
                 Pt 
                 1 
                 5 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5-9X 
                 Pt 
                 1 
                 5 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-9Y 
                 Pt 
                 0 
                 5 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-10 
                 Pt 
                 1 
                 5 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5-10X 
                 Pt 
                 1 
                 5 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-10Y 
                 Pt 
                 0 
                 5 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-11 
                 Pt 
                 1 
                 5 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5-11X 
                 Pt 
                 1 
                 5 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-11Y 
                 Pt 
                 0 
                 5 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-12 
                 Pt 
                 1 
                 5 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5-12X 
                 Pt 
                 1 
                 5 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-12AY 
                 Pt 
                 0 
                 5 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-13 
                 Pt 
                 1 
                 5 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5-13X 
                 Pt 
                 1 
                 5 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-13Y 
                 Pt 
                 0 
                 5 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-14 
                 Pt 
                 1 
                 5 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5-14X 
                 Pt 
                 1 
                 5 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-14Y 
                 Pt 
                 0 
                 5 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-15 
                 Pt 
                 1 
                 5 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5-15X 
                 Pt 
                 1 
                 5 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-15Y 
                 Pt 
                 0 
                 5 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-16 
                 Pt 
                 1 
                 5 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5-16X 
                 Pt 
                 1 
                 5 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-16Y 
                 Pt 
                 0 
                 5 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-17 
                 Pt 
                 1 
                 5 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5-17X 
                 Pt 
                 1 
                 5 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-17Y 
                 Pt 
                 0 
                 5 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-18 
                 Pt 
                 1 
                 5 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5-18X 
                 Pt 
                 1 
                 5 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-18Y 
                 Pt 
                 0 
                 5 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-19 
                 Pt 
                 1 
                 5 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                   
               
               
                 5-19X 
                 Pt 
                 1 
                 5 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-19Y 
                 Pt 
                 0 
                 5 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-20 
                 Pt 
                 1 
                 5 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 pic 
               
               
                 5-20X 
                 Pt 
                 1 
                 5 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-20Y 
                 Pt 
                 0 
                 5 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-21 
                 Pt 
                 1 
                 5 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 pic 
               
               
                 5-21X 
                 Pt 
                 1 
                 5 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-21Y 
                 Pt 
                 0 
                 5 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-22 
                 Pt 
                 1 
                 5 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 pic 
               
               
                 5-22X 
                 Pt 
                 1 
                 5 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-22Y 
                 Pt 
                 0 
                 5 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-23 
                 Pt 
                 1 
                 5 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 OCH 3   
                 H 
                 H 
                 pic 
               
               
                 5-23X 
                 Pt 
                 1 
                 5 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 OCH 3   
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-23Y 
                 Pt 
                 0 
                 5 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 OCH 3   
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-24 
                 Pt 
                 1 
                 5 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 OCH 3   
                 H 
                 H 
                 pic 
               
               
                 5-24X 
                 Pt 
                 1 
                 5 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 OCH 3   
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-24Y 
                 Pt 
                 0 
                 5 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 OCH 3   
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-25 
                 Pt 
                 1 
                 5 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 pic 
               
               
                 5-25X 
                 Pt 
                 1 
                 5 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-25Y 
                 Pt 
                 0 
                 5 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-26 
                 Pt 
                 1 
                 5 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 pic 
               
               
                 5-26X 
                 Pt 
                 1 
                 5 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-26Y 
                 Pt 
                 0 
                 5 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-27 
                 Pt 
                 1 
                 5 
                 CN 
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5-27X 
                 Pt 
                 1 
                 5 
                 CN 
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-27Y 
                 Pt 
                 0 
                 5 
                 CN 
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-28 
                 Pt 
                 1 
                 5 
                 CN 
                 H 
                 H 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5-28X 
                 Pt 
                 1 
                 5 
                 CN 
                 H 
                 H 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-28Y 
                 Pt 
                 0 
                 5 
                 CN 
                 H 
                 H 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-29 
                 Pt 
                 1 
                 5 
                 H 
                 H 
                 CN 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5-29X 
                 Pt 
                 1 
                 5 
                 H 
                 H 
                 CN 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-29Y 
                 Pt 
                 0 
                 5 
                 H 
                 H 
                 CN 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-30 
                 Pt 
                 1 
                 5 
                 H 
                 H 
                 CN 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5-30X 
                 Pt 
                 1 
                 5 
                 H 
                 H 
                 CN 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-30Y 
                 Pt 
                 0 
                 5 
                 H 
                 H 
                 CN 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-31 
                 Pt 
                 1 
                 5 
                 CN 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5-31X 
                 Pt 
                 1 
                 5 
                 CN 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5-31Y 
                 Pt 
                 0 
                 5 
                 CN 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 5-32 
                 Pt 
                 1 
                 5 
                 CN 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 pic 
                 — 
               
               
                 5-32X 
                 Pt 
                 1 
                 5 
                 CN 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 acac 
                 — 
               
               
                 5-32Y 
                 Pt 
                 0 
                 5 
                 CN 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 5-33 
                 Pt 
                 1 
                 5 
                 CN 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 pic 
                 — 
               
               
                 5-33X 
                 Pt 
                 1 
                 5 
                 CN 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 acac 
                 — 
               
               
                 5-33Y 
                 Pt 
                 0 
                 5 
                 CN 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 5-34 
                 Pt 
                 1 
                 5 
                 CN 
                 H 
                 CF 3   
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 pic 
                 — 
               
               
                 5-34X 
                 Pt 
                 1 
                 5 
                 CN 
                 H 
                 CF 3   
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 acac 
                 — 
               
               
                 5-34Y 
                 Pt 
                 0 
                 5 
                 CN 
                 H 
                 CF 3   
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 5-35 
                 Pt 
                 1 
                 5 
                 CN 
                 H 
                 H 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5-35X 
                 Pt 
                 1 
                 5 
                 CN 
                 H 
                 H 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 5-35Y 
                 Pt 
                 0 
                 5 
                 CN 
                 H 
                 H 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 5-36 
                 Pt 
                 1 
                 5 
                 CN 
                 F 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5-36X 
                 Pt 
                 1 
                 5 
                 CN 
                 F 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 5-36Y 
                 Pt 
                 0 
                 5 
                 CN 
                 F 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 5-37 
                 Pt 
                 1 
                 5 
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5-37X 
                 Pt 
                 1 
                 5 
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 5-37Y 
                 Pt 
                 0 
                 5 
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 10 
               
               
                   
               
               
                   
               
               
                 No. 
                 M 
                 m 
                 BSS 
                 R 1   
                 R 2   
                 R 3   
                 R 4   
                 R 5   
                 R 6   
                 R 7   
                 R 8   
                 L 1   
                 L 2   
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-1 
                 Pd 
                 1 
                 5 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5′-1X 
                 Pd 
                 1 
                 5 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-1Y 
                 Pd 
                 0 
                 5 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-2 
                 Pd 
                 1 
                 5 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5′-2X 
                 Pd 
                 1 
                 5 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-2Y 
                 Pd 
                 0 
                 5 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-3 
                 Pd 
                 1 
                 5 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5′-3X 
                 Pd 
                 1 
                 5 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-3Y 
                 Pd 
                 0 
                 5 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-4 
                 Pd 
                 1 
                 5 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5′-4X 
                 Pd 
                 1 
                 5 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-4Y 
                 Pd 
                 0 
                 5 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-5 
                 Pd 
                 1 
                 5 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5′-5X 
                 Pd 
                 1 
                 5 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-5Y 
                 Pd 
                 0 
                 5 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-6 
                 Pd 
                 1 
                 5 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5′-6X 
                 Pd 
                 1 
                 5 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-6Y 
                 Pd 
                 0 
                 5 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-7 
                 Pd 
                 1 
                 5 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5′-7X 
                 Pd 
                 1 
                 5 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-7Y 
                 Pd 
                 0 
                 5 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-8 
                 Pd 
                 1 
                 5 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5′-8X 
                 Pd 
                 1 
                 5 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-8Y 
                 Pd 
                 0 
                 5 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-9 
                 Pd 
                 1 
                 5 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5′-9X 
                 Pd 
                 1 
                 5 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-9Y 
                 Pd 
                 1 
                 5 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-10 
                 Pd 
                 1 
                 5 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5′-10X 
                 Pd 
                 1 
                 5 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-10Y 
                 Pd 
                 0 
                 5 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-11 
                 Pd 
                 1 
                 5 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5′-11X 
                 Pd 
                 1 
                 5 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-11Y 
                 Pd 
                 0 
                 5 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-12 
                 Pd 
                 1 
                 5 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5′-12X 
                 Pd 
                 1 
                 5 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-12Y 
                 Pd 
                 0 
                 5 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-13 
                 Pd 
                 1 
                 5 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5′-13X 
                 Pd 
                 1 
                 5 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-13Y 
                 Pd 
                 0 
                 5 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-14 
                 Pd 
                 1 
                 5 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5′-14X 
                 Pd 
                 1 
                 5 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-14Y 
                 Pd 
                 0 
                 5 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-15 
                 Pd 
                 1 
                 5 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5′-15X 
                 Pd 
                 1 
                 5 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-15Y 
                 Pd 
                 0 
                 5 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-16 
                 Pd 
                 1 
                 5 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5′-16X 
                 Pd 
                 1 
                 5 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-16Y 
                 Pd 
                 0 
                 5 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-17 
                 Pd 
                 1 
                 5 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5′-17X 
                 Pd 
                 1 
                 5 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-17Y 
                 Pd 
                 0 
                 5 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-18 
                 Pd 
                 1 
                 5 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 5′-18X 
                 Pd 
                 1 
                 5 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-18Y 
                 Pd 
                 0 
                 5 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 5′-19 
                 Pd 
                 1 
                 5 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-19X 
                 Pd 
                 1 
                 5 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-19Y 
                 Pd 
                 0 
                 5 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-20 
                 Pd 
                 1 
                 5 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 pic 
               
               
                 5′-20X 
                 Pd 
                 1 
                 5 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-20Y 
                 Pd 
                 0 
                 5 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-21 
                 Pd 
                 1 
                 5 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 pic 
               
               
                 5′-21X 
                 Pd 
                 1 
                 5 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-21Y 
                 Pd 
                 0 
                 5 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-22 
                 Pd 
                 1 
                 5 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 pic 
               
               
                 5′-22X 
                 Pd 
                 1 
                 5 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-22Y 
                 Pd 
                 0 
                 5 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 N(CH 3 ) 2   
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-23 
                 Pd 
                 1 
                 5 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 OCH 3   
                 H 
                 H 
                 pic 
               
               
                 5′-23X 
                 Pd 
                 1 
                 5 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 OCH 3   
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-23Y 
                 Pd 
                 0 
                 5 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 OCH 3   
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-24 
                 Pd 
                 1 
                 5 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 OCH 3   
                 H 
                 H 
                 pic 
               
               
                 5′-24X 
                 Pd 
                 1 
                 5 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 OCH 3   
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-24Y 
                 Pd 
                 0 
                 5 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 OCH 3   
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-25 
                 Pd 
                 1 
                 5 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 pic 
               
               
                 5′-25X 
                 Pd 
                 1 
                 5 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-25Y 
                 Pd 
                 0 
                 5 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-26 
                 Pd 
                 1 
                 5 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 pic 
               
               
                 5′-26X 
                 Pd 
                 1 
                 5 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 5′-26Y 
                 Pd 
                 0 
                 5 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 11 
               
               
                   
               
               
                   
               
               
                 No. 
                 M 
                 m 
                 BSS 
                 R 1   
                 R 2   
                 R 3   
                 R 4   
                 R 5   
                 R 6   
                 R 7   
                 R 8   
                 R 9   
                 R 10   
                 L 1   
                 L 2   
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-1 
                 Pt 
                 1 
                 6 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-1X 
                 Pt 
                 1 
                 6 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-1Y 
                 Pt 
                 0 
                 6 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-2 
                 Pt 
                 1 
                 6 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-2X 
                 Pt 
                 1 
                 6 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-2Y 
                 Pt 
                 0 
                 6 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-3 
                 Pt 
                 1 
                 6 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-3X 
                 Pt 
                 1 
                 6 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-3Y 
                 Pt 
                 0 
                 6 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-4 
                 Pt 
                 1 
                 6 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-4X 
                 Pt 
                 1 
                 6 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-4Y 
                 Pt 
                 0 
                 6 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-5 
                 Pt 
                 1 
                 6 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-5X 
                 Pt 
                 1 
                 6 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-5Y 
                 Pt 
                 0 
                 6 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-6 
                 Pt 
                 1 
                 6 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-6X 
                 Pt 
                 1 
                 6 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-6Y 
                 Pt 
                 0 
                 6 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-7 
                 Pt 
                 1 
                 6 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-7X 
                 Pt 
                 1 
                 6 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-7Y 
                 Pt 
                 0 
                 6 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-8 
                 Pt 
                 1 
                 6 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-8X 
                 Pt 
                 1 
                 6 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-8Y 
                 Pt 
                 0 
                 6 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-9 
                 Pt 
                 1 
                 6 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-9X 
                 Pt 
                 1 
                 6 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-9Y 
                 Pt 
                 0 
                 6 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-10 
                 Pt 
                 1 
                 6 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-10X 
                 Pt 
                 1 
                 6 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-10Y 
                 Pt 
                 0 
                 6 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-11 
                 Pt 
                 1 
                 6 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-11X 
                 Pt 
                 1 
                 6 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-11Y 
                 Pt 
                 0 
                 6 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-12 
                 Pt 
                 1 
                 6 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-12X 
                 Pt 
                 1 
                 6 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-12Y 
                 Pt 
                 0 
                 6 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-13 
                 Pt 
                 1 
                 6 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-13X 
                 Pt 
                 1 
                 6 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-13Y 
                 Pt 
                 0 
                 6 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-14 
                 Pt 
                 1 
                 6 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-14X 
                 Pt 
                 1 
                 6 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-14Y 
                 Pt 
                 0 
                 6 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-15 
                 Pt 
                 1 
                 6 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-15X 
                 Pt 
                 1 
                 6 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-15Y 
                 Pt 
                 0 
                 6 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-16 
                 Pt 
                 1 
                 6 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-16X 
                 Pt 
                 1 
                 6 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-16Y 
                 Pt 
                 0 
                 6 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-17 
                 Pt 
                 1 
                 6 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-17X 
                 Pt 
                 1 
                 6 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-17Y 
                 Pt 
                 0 
                 6 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-18 
                 Pt 
                 1 
                 6 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-18X 
                 Pt 
                 1 
                 6 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-18Y 
                 Pt 
                 0 
                 6 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-19 
                 Pt 
                 1 
                 6 
                 CN 
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-19X 
                 Pt 
                 1 
                 6 
                 CN 
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-19Y 
                 Pt 
                 0 
                 6 
                 CN 
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-20 
                 Pt 
                 1 
                 6 
                 CN 
                 H 
                 H 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-20X 
                 Pt 
                 1 
                 6 
                 CN 
                 H 
                 H 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-20Y 
                 Pt 
                 0 
                 6 
                 CN 
                 H 
                 H 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-21 
                 Pt 
                 1 
                 6 
                 H 
                 H 
                 CN 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-21X 
                 Pt 
                 1 
                 6 
                 H 
                 H 
                 CN 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-21Y 
                 Pt 
                 0 
                 6 
                 H 
                 H 
                 CN 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-22 
                 Pt 
                 1 
                 6 
                 H 
                 H 
                 CN 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-22X 
                 Pt 
                 1 
                 6 
                 H 
                 H 
                 CN 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-22Y 
                 Pt 
                 0 
                 6 
                 H 
                 H 
                 CN 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-23 
                 Pt 
                 1 
                 6 
                 CN 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-23X 
                 Pt 
                 1 
                 6 
                 CN 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6-23Y 
                 Pt 
                 0 
                 6 
                 CN 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 6-24 
                 Pt 
                 1 
                 6 
                 CN 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-24X 
                 Pt 
                 1 
                 6 
                 CN 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 6-24Y 
                 Pt 
                 0 
                 6 
                 CN 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 6-25 
                 Pt 
                 1 
                 6 
                 CN 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-25X 
                 Pt 
                 1 
                 6 
                 CN 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 6-25Y 
                 Pt 
                 0 
                 6 
                 CN 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 6-26 
                 Pt 
                 1 
                 6 
                 CN 
                 H 
                 CF 3   
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-26X 
                 Pt 
                 1 
                 6 
                 CN 
                 H 
                 CF 3   
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 6-26Y 
                 Pt 
                 0 
                 6 
                 CN 
                 H 
                 CF 3   
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 6-27 
                 Pt 
                 1 
                 6 
                 CN 
                 H 
                 H 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-27X 
                 Pt 
                 1 
                 6 
                 CN 
                 H 
                 H 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 6-27Y 
                 Pt 
                 0 
                 6 
                 CN 
                 H 
                 H 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 6-28 
                 Pt 
                 1 
                 6 
                 CN 
                 F 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-28X 
                 Pt 
                 1 
                 6 
                 CN 
                 F 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 6-28Y 
                 Pt 
                 0 
                 6 
                 CN 
                 F 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 6-29 
                 Pt 
                 1 
                 6 
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6-29X 
                 Pt 
                 1 
                 6 
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 6-29Y 
                 Pt 
                 0 
                 6 
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 12 
               
               
                   
               
               
                   
               
               
                 No. 
                 M 
                 m 
                 BSS 
                 R 1   
                 R 2   
                 R 3   
                 R 4   
                 R 5   
                 R 6   
                 R 7   
                 R 8   
                 R 9   
                 R 10   
                 L 1   
                 L 2   
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-1 
                 Pd 
                 1 
                 6 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6′-1X 
                 Pd 
                 1 
                 6 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-1Y 
                 Pd 
                 0 
                 6 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-2 
                 Pd 
                 1 
                 6 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6′-2X 
                 Pd 
                 1 
                 6 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-2Y 
                 Pd 
                 0 
                 6 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-3 
                 Pd 
                 1 
                 6 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6′-3X 
                 Pd 
                 1 
                 6 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-3Y 
                 Pd 
                 0 
                 6 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-4 
                 Pd 
                 1 
                 6 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6′-4X 
                 Pd 
                 1 
                 6 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-4Y 
                 Pd 
                 0 
                 6 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-5 
                 Pd 
                 1 
                 6 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6′-5X 
                 Pd 
                 1 
                 6 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-5Y 
                 Pd 
                 0 
                 6 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-6 
                 Pd 
                 1 
                 6 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6′-6X 
                 Pd 
                 1 
                 6 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-6Y 
                 Pd 
                 0 
                 6 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-7 
                 Pd 
                 1 
                 6 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6′-7X 
                 Pd 
                 1 
                 6 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-7Y 
                 Pd 
                 0 
                 6 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-8 
                 Pd 
                 1 
                 6 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6′-8X 
                 Pd 
                 1 
                 6 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-8Y 
                 Pd 
                 0 
                 6 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-9 
                 Pd 
                 1 
                 6 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6′-9X 
                 Pd 
                 1 
                 6 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-9Y 
                 Pd 
                 0 
                 6 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-10 
                 Pd 
                 1 
                 6 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6′-10X 
                 Pd 
                 1 
                 6 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-10Y 
                 Pd 
                 0 
                 6 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-11 
                 Pd 
                 1 
                 6 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6′-11X 
                 Pd 
                 1 
                 6 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-11Y 
                 Pd 
                 0 
                 6 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-12 
                 Pd 
                 1 
                 6 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6′-12X 
                 Pd 
                 1 
                 6 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-12Y 
                 Pd 
                 0 
                 6 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-13 
                 Pd 
                 1 
                 6 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6′-13X 
                 Pd 
                 1 
                 6 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-13Y 
                 Pd 
                 0 
                 6 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-14 
                 Pd 
                 1 
                 6 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6′-14X 
                 Pd 
                 1 
                 6 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-14Y 
                 Pd 
                 0 
                 6 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-15 
                 Pd 
                 1 
                 6 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6′-15X 
                 Pd 
                 1 
                 6 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-15Y 
                 Pd 
                 0 
                 6 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-16 
                 Pd 
                 1 
                 6 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6′-16X 
                 Pd 
                 1 
                 6 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-16Y 
                 Pd 
                 0 
                 6 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-17 
                 Pd 
                 1 
                 6 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6′-17X 
                 Pd 
                 1 
                 6 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-17Y 
                 Pd 
                 0 
                 6 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-18 
                 Pd 
                 1 
                 6 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 6′-18X 
                 Pd 
                 1 
                 6 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 6′-18Y 
                 Pd 
                 0 
                 6 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 13 
               
               
                   
               
               
                   
               
               
                 No. 
                 M 
                 m 
                 BSS 
                 R 1   
                 R 2   
                 R 3   
                 R 4   
                 R 5   
                 R 6   
                 R 7   
                 R 8   
                 R 9   
                 R 10   
                 L 1   
                 L 2   
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-1 
                 Pt 
                 1 
                 7 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-1X 
                 Pt 
                 1 
                 7 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-1Y 
                 Pt 
                 0 
                 7 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-2 
                 Pt 
                 1 
                 7 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-2X 
                 Pt 
                 1 
                 7 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-2Y 
                 Pt 
                 0 
                 7 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-3 
                 Pt 
                 1 
                 7 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-3X 
                 Pt 
                 1 
                 7 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-3Y 
                 Pt 
                 0 
                 7 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-4 
                 Pt 
                 1 
                 7 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-4X 
                 Pt 
                 1 
                 7 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-4Y 
                 Pt 
                 0 
                 7 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-5 
                 Pt 
                 1 
                 7 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-5X 
                 Pt 
                 1 
                 7 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-5Y 
                 Pt 
                 0 
                 7 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-6 
                 Pt 
                 1 
                 7 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-6X 
                 Pt 
                 1 
                 7 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-6Y 
                 Pt 
                 0 
                 7 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-7 
                 Pt 
                 1 
                 7 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-7X 
                 Pt 
                 1 
                 7 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-7Y 
                 Pt 
                 0 
                 7 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-8 
                 Pt 
                 1 
                 7 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-8X 
                 Pt 
                 1 
                 7 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-8Y 
                 Pt 
                 0 
                 7 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-9 
                 Pt 
                 1 
                 7 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-9X 
                 Pt 
                 1 
                 7 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-9Y 
                 Pt 
                 0 
                 7 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-10 
                 Pt 
                 1 
                 7 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-10X 
                 Pt 
                 1 
                 7 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-10Y 
                 Pt 
                 0 
                 7 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-11 
                 Pt 
                 1 
                 7 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-11X 
                 Pt 
                 1 
                 7 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-11Y 
                 Pt 
                 0 
                 7 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-12 
                 Pt 
                 1 
                 7 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-12X 
                 Pt 
                 1 
                 7 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-12Y 
                 Pt 
                 0 
                 7 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-13 
                 Pt 
                 1 
                 7 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-13X 
                 Pt 
                 1 
                 7 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-13Y 
                 Pt 
                 0 
                 7 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-14 
                 Pt 
                 1 
                 7 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-14X 
                 Pt 
                 1 
                 7 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-14Y 
                 Pt 
                 0 
                 7 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-15 
                 Pt 
                 1 
                 7 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-15X 
                 Pt 
                 1 
                 7 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-15Y 
                 Pt 
                 0 
                 7 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-16 
                 Pt 
                 1 
                 7 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-16X 
                 Pt 
                 1 
                 7 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-16Y 
                 Pt 
                 0 
                 7 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-17 
                 Pt 
                 1 
                 7 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-17X 
                 Pt 
                 1 
                 7 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-17Y 
                 Pt 
                 0 
                 7 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-18 
                 Pt 
                 1 
                 7 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-18X 
                 Pt 
                 1 
                 7 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-18Y 
                 Pt 
                 0 
                 7 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-19 
                 Pt 
                 1 
                 7 
                 CN 
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-19X 
                 Pt 
                 1 
                 7 
                 CN 
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-19Y 
                 Pt 
                 0 
                 7 
                 CN 
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-20 
                 Pt 
                 1 
                 7 
                 CN 
                 H 
                 H 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-20X 
                 Pt 
                 1 
                 7 
                 CN 
                 H 
                 H 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-20Y 
                 Pt 
                 0 
                 7 
                 CN 
                 H 
                 H 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-21 
                 Pt 
                 1 
                 7 
                 H 
                 H 
                 CN 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-21X 
                 Pt 
                 1 
                 7 
                 H 
                 H 
                 CN 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-21Y 
                 Pt 
                 0 
                 7 
                 H 
                 H 
                 CN 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-22 
                 Pt 
                 1 
                 7 
                 H 
                 H 
                 CN 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-22X 
                 Pt 
                 1 
                 7 
                 H 
                 H 
                 CN 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-22Y 
                 Pt 
                 0 
                 7 
                 H 
                 H 
                 CN 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-23 
                 Pt 
                 1 
                 7 
                 CN 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-23X 
                 Pt 
                 1 
                 7 
                 CN 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7-23Y 
                 Pt 
                 0 
                 7 
                 CN 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 7-24 
                 Pt 
                 1 
                 7 
                 CN 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-24X 
                 Pt 
                 1 
                 7 
                 CN 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 7-24Y 
                 Pt 
                 0 
                 7 
                 CN 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 7-25 
                 Pt 
                 1 
                 7 
                 CN 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-25X 
                 Pt 
                 1 
                 7 
                 CN 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 7-25Y 
                 Pt 
                 0 
                 7 
                 CN 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 7-26 
                 Pt 
                 1 
                 7 
                 CN 
                 H 
                 CF 3   
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-26X 
                 Pt 
                 1 
                 7 
                 CN 
                 H 
                 CF 3   
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 7-26Y 
                 Pt 
                 0 
                 7 
                 CN 
                 H 
                 CF 3   
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 7-27 
                 Pt 
                 1 
                 7 
                 CN 
                 H 
                 H 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-27X 
                 Pt 
                 1 
                 7 
                 CN 
                 H 
                 H 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 7-27Y 
                 Pt 
                 0 
                 7 
                 CN 
                 H 
                 H 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 7-28 
                 Pt 
                 1 
                 7 
                 CN 
                 F 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-28X 
                 Pt 
                 1 
                 7 
                 CN 
                 F 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 7-28Y 
                 Pt 
                 0 
                 7 
                 CN 
                 F 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 7-29 
                 Pt 
                 1 
                 7 
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7-29X 
                 Pt 
                 1 
                 7 
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 7-29Y 
                 Pt 
                 0 
                 7 
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 14 
               
               
                   
               
               
                   
               
               
                 No. 
                 M 
                 m 
                 BSS 
                 R 1   
                 R 2   
                 R 3   
                 R 4   
                 R 5   
                 R 6   
                 R 7   
                 R 8   
                 R 9   
                 R 10   
                 L 1   
                 L 2   
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-1 
                 Pd 
                 1 
                 7 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7′-1X 
                 Pd 
                 1 
                 7 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-1Y 
                 Pd 
                 0 
                 7 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-2 
                 Pd 
                 1 
                 7 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7′-2X 
                 Pd 
                 1 
                 7 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-2Y 
                 Pd 
                 0 
                 7 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-3 
                 Pd 
                 1 
                 7 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7′-3X 
                 Pd 
                 1 
                 7 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-3Y 
                 Pd 
                 0 
                 7 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-4 
                 Pd 
                 1 
                 7 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7′-4X 
                 Pd 
                 1 
                 7 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-4Y 
                 Pd 
                 0 
                 7 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-5 
                 Pd 
                 1 
                 7 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7′-5X 
                 Pd 
                 1 
                 7 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-5Y 
                 Pd 
                 0 
                 7 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-6 
                 Pd 
                 1 
                 7 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7′-6X 
                 Pd 
                 1 
                 7 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-6Y 
                 Pd 
                 0 
                 7 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-7 
                 Pd 
                 1 
                 7 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7′-7X 
                 Pd 
                 1 
                 7 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-7Y 
                 Pd 
                 0 
                 7 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-8 
                 Pd 
                 1 
                 7 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7′-8X 
                 Pd 
                 1 
                 7 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-8Y 
                 Pd 
                 0 
                 7 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-9 
                 Pd 
                 1 
                 7 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7′-9X 
                 Pd 
                 1 
                 7 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-9Y 
                 Pd 
                 0 
                 7 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-10 
                 Pd 
                 1 
                 7 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7′-10X 
                 Pd 
                 1 
                 7 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-10Y 
                 Pd 
                 0 
                 7 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-11 
                 Pd 
                 1 
                 7 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7′-11X 
                 Pd 
                 1 
                 7 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-11Y 
                 Pd 
                 0 
                 7 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-12 
                 Pd 
                 1 
                 7 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7′-12X 
                 Pd 
                 1 
                 7 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-12Y 
                 Pd 
                 0 
                 7 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-13 
                 Pd 
                 1 
                 7 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7′-13X 
                 Pd 
                 1 
                 7 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-13Y 
                 Pd 
                 0 
                 7 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-14 
                 Pd 
                 1 
                 7 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7′-14X 
                 Pd 
                 1 
                 7 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-14Y 
                 Pd 
                 0 
                 7 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-15 
                 Pd 
                 1 
                 7 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7′-15X 
                 Pd 
                 1 
                 7 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-15Y 
                 Pd 
                 0 
                 7 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-16 
                 Pd 
                 1 
                 7 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7′-16X 
                 Pd 
                 1 
                 7 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-16Y 
                 Pd 
                 0 
                 7 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-17 
                 Pd 
                 1 
                 7 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7′-17X 
                 Pd 
                 1 
                 7 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-17Y 
                 Pd 
                 0 
                 7 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-18 
                 Pd 
                 1 
                 7 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 7′-18X 
                 Pd 
                 1 
                 7 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 7′-18Y 
                 Pd 
                 0 
                 7 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 15 
               
               
                   
               
               
                   
               
               
                 No. 
                 M 
                 m 
                 BSS 
                 R 1   
                 R 2   
                 R 3   
                 R 4   
                 R 5   
                 R 6   
                 R 7   
                 R 8   
                 R 9   
                 R 10   
                 L 1   
                 L 2   
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-1 
                 Pt 
                 1 
                 8 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-1X 
                 Pt 
                 1 
                 8 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-1Y 
                 Pt 
                 0 
                 8 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-2 
                 Pt 
                 1 
                 8 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-2X 
                 Pt 
                 1 
                 8 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-2Y 
                 Pt 
                 0 
                 8 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-3 
                 Pt 
                 1 
                 8 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-3X 
                 Pt 
                 1 
                 8 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-3Y 
                 Pt 
                 0 
                 8 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-4 
                 Pt 
                 1 
                 8 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-4X 
                 Pt 
                 1 
                 8 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-4Y 
                 Pt 
                 0 
                 8 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-5 
                 Pt 
                 1 
                 8 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-5X 
                 Pt 
                 1 
                 8 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-5Y 
                 Pt 
                 0 
                 8 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-6 
                 Pt 
                 1 
                 8 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-6X 
                 Pt 
                 1 
                 8 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-6Y 
                 Pt 
                 0 
                 8 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-7 
                 Pt 
                 1 
                 8 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-7X 
                 Pt 
                 1 
                 8 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-7Y 
                 Pt 
                 0 
                 8 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-8 
                 Pt 
                 1 
                 8 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-8X 
                 Pt 
                 1 
                 8 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-8Y 
                 Pt 
                 0 
                 8 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-9 
                 Pt 
                 1 
                 8 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-9X 
                 Pt 
                 1 
                 8 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-9Y 
                 Pt 
                 0 
                 8 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-10 
                 Pt 
                 1 
                 8 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-10X 
                 Pt 
                 1 
                 8 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-10Y 
                 Pt 
                 0 
                 8 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-11 
                 Pt 
                 1 
                 8 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-11X 
                 Pt 
                 1 
                 8 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-11Y 
                 Pt 
                 0 
                 8 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-12 
                 Pt 
                 1 
                 8 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-12X 
                 Pt 
                 1 
                 8 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-12Y 
                 Pt 
                 0 
                 8 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-13 
                 Pt 
                 1 
                 8 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-13X 
                 Pt 
                 1 
                 8 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-13Y 
                 Pt 
                 0 
                 8 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-14 
                 Pt 
                 1 
                 8 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-14X 
                 Pt 
                 1 
                 8 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-14Y 
                 Pt 
                 0 
                 8 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-15 
                 Pt 
                 1 
                 8 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-15X 
                 Pt 
                 1 
                 8 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-15Y 
                 Pt 
                 0 
                 8 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-16 
                 Pt 
                 1 
                 8 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-16X 
                 Pt 
                 1 
                 8 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-16Y 
                 Pt 
                 0 
                 8 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-17 
                 Pt 
                 1 
                 8 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-17X 
                 Pt 
                 1 
                 8 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-17Y 
                 Pt 
                 0 
                 8 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-18 
                 Pt 
                 1 
                 8 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-18X 
                 Pt 
                 1 
                 8 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-18Y 
                 Pt 
                 0 
                 8 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-19 
                 Pt 
                 1 
                 8 
                 CN 
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-19X 
                 Pt 
                 1 
                 8 
                 CN 
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-19Y 
                 Pt 
                 0 
                 8 
                 CN 
                 H 
                 H 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-20 
                 Pt 
                 1 
                 8 
                 CN 
                 H 
                 H 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-20X 
                 Pt 
                 1 
                 8 
                 CN 
                 H 
                 H 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-20Y 
                 Pt 
                 0 
                 8 
                 CN 
                 H 
                 H 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-21 
                 Pt 
                 1 
                 8 
                 H 
                 H 
                 CN 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-21X 
                 Pt 
                 1 
                 8 
                 H 
                 H 
                 CN 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 B-21Y 
                 Pt 
                 0 
                 8 
                 H 
                 H 
                 CN 
                 OCH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-22 
                 Pt 
                 1 
                 8 
                 H 
                 H 
                 CN 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-22X 
                 Pt 
                 1 
                 8 
                 H 
                 H 
                 CN 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-22Y 
                 Pt 
                 0 
                 8 
                 H 
                 H 
                 CN 
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-23 
                 Pt 
                 1 
                 8 
                 CN 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-23X 
                 Pt 
                 1 
                 8 
                 CN 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8-23Y 
                 Pt 
                 0 
                 8 
                 CN 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 8-24 
                 Pt 
                 1 
                 8 
                 CN 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-24X 
                 Pt 
                 1 
                 8 
                 CN 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 8-24Y 
                 Pt 
                 0 
                 8 
                 CN 
                 H 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 8-25 
                 Pt 
                 1 
                 8 
                 CN 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-25X 
                 Pt 
                 1 
                 8 
                 CN 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 8-25Y 
                 Pt 
                 0 
                 8 
                 CN 
                 F 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 8-26 
                 Pt 
                 1 
                 8 
                 CN 
                 H 
                 CF 3   
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-26X 
                 Pt 
                 1 
                 8 
                 CN 
                 H 
                 CF 3   
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 8-26Y 
                 Pt 
                 0 
                 8 
                 CN 
                 H 
                 CF 3   
                 CH 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 8-27 
                 Pt 
                 1 
                 8 
                 CN 
                 H 
                 H 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-27X 
                 Pt 
                 1 
                 8 
                 CN 
                 H 
                 H 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 8-27Y 
                 Pt 
                 0 
                 8 
                 CN 
                 H 
                 H 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 8-28 
                 Pt 
                 1 
                 8 
                 CN 
                 F 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-28X 
                 Pt 
                 1 
                 8 
                 CN 
                 F 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 8-28Y 
                 Pt 
                 0 
                 8 
                 CN 
                 F 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                 8-29 
                 Pt 
                 1 
                 8 
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8-29X 
                 Pt 
                 1 
                 8 
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
               
                 8-29Y 
                 Pt 
                 0 
                 8 
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 16 
               
               
                   
               
               
                   
               
               
                 No. 
                 M 
                 m 
                 BSS 
                 R 1   
                 R 2   
                 R 3   
                 R 4   
                 R 5   
                 R 6   
                 R 7   
                 R 8   
                 R 9   
                 R 10   
                 L 1   
                 L 2   
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-1 
                 Pd 
                 1 
                 8 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8′-1X 
                 Pd 
                 1 
                 8 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-1Y 
                 Pd 
                 0 
                 8 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-2 
                 Pd 
                 1 
                 8 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8′-2X 
                 Pd 
                 1 
                 8 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-2Y 
                 Pd 
                 0 
                 8 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-3 
                 Pd 
                 1 
                 8 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8′-3X 
                 Pd 
                 1 
                 8 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-3Y 
                 Pd 
                 0 
                 8 
                 H 
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-4 
                 Pd 
                 1 
                 8 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8′-4X 
                 Pd 
                 1 
                 8 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-4Y 
                 Pd 
                 0 
                 8 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-5 
                 Pd 
                 1 
                 8 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8′-5X 
                 Pd 
                 1 
                 8 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-5Y 
                 Pd 
                 0 
                 8 
                 H 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-6 
                 Pd 
                 1 
                 8 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8′-6X 
                 Pd 
                 1 
                 8 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-6Y 
                 Pd 
                 0 
                 8 
                 CN 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-7 
                 Pd 
                 1 
                 8 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8′-7X 
                 Pd 
                 1 
                 8 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-7Y 
                 Pd 
                 0 
                 8 
                 CF 3   
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-8 
                 Pd 
                 1 
                 8 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8′-8X 
                 Pd 
                 1 
                 8 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-8Y 
                 Pd 
                 0 
                 8 
                 H 
                 CN 
                 CF 3   
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-9 
                 Pd 
                 1 
                 8 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8′-9X 
                 Pd 
                 1 
                 8 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-9Y 
                 Pd 
                 0 
                 8 
                 H 
                 CN 
                 H 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-10 
                 Pd 
                 1 
                 8 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8′-10X 
                 Pd 
                 1 
                 8 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-10Y 
                 Pd 
                 0 
                 8 
                 H 
                 F 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-11 
                 Pd 
                 1 
                 8 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8′-11X 
                 Pd 
                 1 
                 8 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-11Y 
                 Pd 
                 0 
                 8 
                 CN 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-12 
                 Pd 
                 1 
                 8 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8′-12X 
                 Pd 
                 1 
                 8 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-12Y 
                 Pd 
                 0 
                 8 
                 CF 3   
                 CN 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-13 
                 Pd 
                 1 
                 8 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8′-13X 
                 Pd 
                 1 
                 8 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-13Y 
                 Pd 
                 0 
                 8 
                 CF 3   
                 H 
                 CF 3   
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-14 
                 Pd 
                 1 
                 8 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8′-14X 
                 Pd 
                 1 
                 8 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-14Y 
                 Pd 
                 0 
                 8 
                 CF 3   
                 H 
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-15 
                 Pd 
                 1 
                 8 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8′-15X 
                 Pd 
                 1 
                 8 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-15Y 
                 Pd 
                 0 
                 8 
                 H 
                 CF 3   
                 H 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-16 
                 Pd 
                 1 
                 8 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8′-16X 
                 Pd 
                 1 
                 8 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-16Y 
                 Pd 
                 0 
                 8 
                 H 
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-17 
                 Pd 
                 1 
                 8 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8′-17X 
                 Pd 
                 1 
                 8 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-17Y 
                 Pd 
                 0 
                 8 
                 CF 3   
                 F 
                 CN 
                 F 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-18 
                 Pd 
                 1 
                 8 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 pic 
               
               
                 8′-18X 
                 Pd 
                 1 
                 8 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 acac 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 8′-18Y 
                 Pd 
                 0 
                 8 
                 CN 
                 CN 
                 CN 
                 CN 
                 H 
                 H 
                 H 
                 H 
                 H 
                 H 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
      The metal-complex compound of the present invention is preferably a material for a light emitting element and in particular, more preferably a material for the organic EL device.  
      The present invention provides an organic EL device which comprises at least one organic thin film layer sandwiched between a pair of electrode consisting of an anode and a cathode, wherein the organic thin film layer comprises the above metal-complex compound, which emits light by applying an electric voltage between the pair of electrode.  
      With regard to the amount of the metal-complex compound of the present invention contained in the organic thin film layer, it is usually 0.1 to 100% by weight, preferably 1 to 30% by weight of total mass of the light emitting layer.  
      It is preferable for the organic EL device of the present invention that the light emitting layer comprises the metal-complex compound of the present invention. Further, the light emitting layer is usually formed to a thin film by means of vapor deposition process or coating process, however, it is preferable that the layer comprising the metal-complex compound of the present invention is formed into film by coating orocess because it simplifies the production process.  
      In the organic EL device of the present invention, a monolayer-type organic thin layer consists of a light emitting layer, which comprises the metal-complex compound of the present invention. Typical examples of the construction of a multilayer-type organic EL device include (an anode/a hole injecting layer (a hole transporting layer)/ a light emitting layer/a cathode); (an anode/a light emitting layer/an electron injecting layer (an electron transporting layer)/ a cathode); (an anode/a hole injecting layer (a hole transporting layer)/ a light emitting layer/an electron injecting layer (an electron transporting layer)/ a cathode).  
      The anode in the organic EL device covers a role of supplying holes into a hole injecting layer, a hole transporting layer or into a light emitting layer, and it is effective that the anode has a work function of 4.5 eV or greater. As the material for the anode, metals, alloys, metal oxides, electroconductive compounds, or these mixtures may be employable. Specific examples of the material for the anode include electroconductive metal oxides such as tin oxide, zinc oxide, indium oxide, indium oxide tin (ITO), etc.; metals such as gold, silver, chromium, nickel, etc.; mixtures or laminated materials of these electroconductive metal oxide and metals; inorganic electroconductive substance such as copper iodide, chalocite, etc.; organic electroconductive materials such as polyaniline, polythiophene, polypyrrole, etc.; and laminated materials of the above materials with ITO; preferably are the electroconductive metal oxides. Particularly, it is preferable to employ ITO from viewpoints such as productivity, enhanced electroconductivity, transparency, etc. Regarding with a film thickness of the anode, it is possible to be appropriately selected depending on the material.  
      The cathode in the organic EL device covers a role of supplying electronds into an electrom injecting layer, an electron transporting layer or into a light emitting layer and examples of the material for the cathode include alkali metals (for example, Li, Na, K, etc.) and their fluoride or oxidate, alkaline earth metals (for example, Mg, Ca, etc.) and their fluoride or oxidate, gold, silver, lead, aluminium, sodium-potassium alloy or sodium-potassium mixed metals, lithium-aluminium alloy or lithium-aluminium mixed metals, magnesium-silver alloy or the magnesium-silver mixed metals, or rare earth metals such as indium, ytterbium, etc. Among those, preferable examples are aluminum, lithium-aluminum alloy or lithium-aluminum mixed metals, magnesium-silver alloy or magnesium-silver mixed metals, etc. The cathode may be a monolayer structure of the above material, and may be a laminated structure of the layer containing the above material. For example, the laminated structure such as aluminum/lithium fluoride, aluminum/lithium oxide or the like is preferable.  
      It may be appropriate that the hole injecting layer and the hole transporting layer of the organic EL device of the present invention have any function of injecting holes from the anode, transporting holes, or barriering the electrons injected from the cathode. Specific examples include carbazole derivatives, triazole derivatives, oxazole derivatives, oxadiazole derivatives, imidazole derivatives, polyarylalkane derivatives, pyrazoline derivatives, pyrazolone derivatives, phenylenediamine derivatives, arylamine derivatives, amino substituted chalcone derivatives, styryl anthracene derivatives, fluorenone derivatives, hydrazone derivatives, stilbene derivatives, silazane derivatives, aromatic tertiary amine compounds, styryl amine compound, aromaticdimethylidene-based compounds, porphyrin-based compounds, polysilane-based compounds, poly(N-vinyl carbazole) derivatives, aniline-based copolymer; electroconductive polymer oligomer such as thiophene oligomer, polythiophene, etc.; organosilane derivatives, metal-complex compound of the present invention, etc. The hole injecting layer and the hole transporting layer may be composed of single layer comprising one or more kind of these hole injecting materials and these hole transporting materials or may be laminated with themselves or a layer comprising another kind of compound.  
      It may be appropriate that the electron injecting layer and the electron transporting layer of the organic EL device of the present invention have any function of injecting electrons from the cathode, transporting electrons, or barriering the holes injected from the anode. Specific examples include triazole derivatives, oxazole derivatives, oxadiazole derivatives, midazole derivatives, fluorenone derivatives, anthraquinodimethane derivatives, anthrone derivatives, diphenylchinone derivatives, thiopyrandioxide derivatives, carbodiimide derivatives, fluorenylidene methane derivatives, distyrylpyrazine derivatives; aromatic ring tetracarboxylic acid anhydride such as naphthalene, perylene, etc.; phthalocyanine derivatives, various metallic complexes represented by metallic complexes of 8-quinolinol derivatives or metallic complexes having benz oxazole or benzothiazole as ligand; organosilane derivatives, metal-complex compound of the present invention, etc. The electron injecting layer may be composed of single layer comprising one or more kind of these electron injecting materials or may be laminated with an electron injecting layer comprising another kind of compound.  
      Further, following compounds are employable for the electron injecting layer and the electron transporting layer.  
                 
                 
                 
                 
                 
                 
 
      It is preferable for the organic EL device of the present invention that the electron injectiing layer and/or the electron transporting layer cmprises a π-electron lacking heteroring derivative having a nitrogen atom as its essential component.  
      Preferable examples of the π-electron lacking heteroring derivative having a nitrogen atom include derivatives of five-member ring having a nitrogen atom selected from among benzimidazole ring, benztriazole ring, pyridino imidazole ring, pyrimidino imidazole ring, pyridazino imidazole ring; or derivatives of six-member ring having a nitrogen atom consisting of pyridine ring, pyrimidine ring, pyrazine ring or triazine ring. A structure expressed by general formula B-I below is preferable as the derivatives of five-member ring having a nitrogen atom. Structures expressed by general formulae C-I, C-II, C-III, C-IV, C-V and C-VI below are preferable as the derivatives of six-member ring having a nitrogen atom, while general formulae C-I and C-II are more preferable.  
                 
 
      In general formula (B-I), L B  represents a connecting group of divalent or more, preferably the connecting group formed with a carbon atom, a silicon atom, a nitrogen atom, a boron atom, an oxygen atom, a sulfur atom, metals, metal ions, etc.; more preferably the connecting group formed with a carbon atom, a silicon atom, a nitrogen atom, a boron atom, an oxygen atom, a sulfur atom, an aromatic hydrocarbon ring, an aromatic heteroring; and the most preferably the connecting group formed with a carbon atom, a silicon atom, an aromatic hydrocarbon ring and an aromatic heteroring.  
      L b  may have a substituent, and preferable examples of the substituent are alkyl group, alkenyl group, alkynyl group, aromatic hydrocarbon group, amino group, alkoxy group, aryloxy group, acyl group, alkoxycarbonyl group, aryloxy carbonyl group, acyl oxy group, acylamino group, alkoxycarbonylamino group, aryloxy carbonylamino group, sulfonyl amino group, sulfamoyl group, carbamoyl group, alkylthio group, arylthio group, sulphonyl group, halogen atom, cyano group and aromatic heterocycle group; more preferable examples are alkyl group, aryl group, alkoxy group, aryloxy group, halogen atom, cyano group and aromatic heterocycle group; furthermore preferable examples are alkyl group, aryl group, alkoxy group, aryloxy group and aromatic heterocycle group; and particularly preferable examples are alkyl group, aryl group, alkoxy group and aromatic heterocycle group.  
      Followings are the specific examples of the connecting group represented by Lb:  
                 
                 
 
      In the general formula (B-I), X B2  represents —O—, —S— or ═N—R B2 . R B2  represents a hydrogen atom, an aliphatic hydrocarbon group, an aryl group and a heteroring group.  
      The aliphatic hydrocarbon group represented by R B2  is straight chain, branched or circular alkyl group (alkyl group preferably having 1 to 20 carbon atoms, more preferably having 1 to 12 carbon atoms and particularly preferably having 1 to 8 carbon atoms; examples include methyl group, ethyl group, iso-propyl group, tert-butyl group, n-octyl group, n-decyl group, n-hexadecyl group, cyclopropyl group, cyclopentyl group, cyclohexyl group, etc.); alkenyl group (alkenyl group preferably having 2 to 20 carbon atoms, more preferably having 2 to 12 carbon atoms and particularly preferably having 2 to 8 carbon atoms; examples include vinyl group, allyl group, 2-butenyl group, 3-pentenyl group, etc.); and alkynyl group (alkynyl group preferably having 2 to 20 carbon atoms, more preferably having 2 to 12 carbon atoms and particularly preferably having 2 to 8 carbon atoms; examples include propargyl group, 3-pentynyl group, etc.), while the above alkyl group being more preferable.  
      The aryl group represented by R B2  is a monocyclic or condensed ring aryl group, preferably the aryl group having 6 to 30 carbon atoms, more preferably 6 to 20 carbon atoms and further preferably 6 to 12 carbon atoms; examles include phenyl group, 2-methylphenyl group, 3-methylphenyl group, 4-methylphenyl group, 2-methoxyphenyl group, 3-trifluoromethylphenyl group, pentafluorophenyl group, 1-naphthyl group, 2-naphthyl group, etc.  
      The heteroring group represented by R B2  is a monocyclic or condensed ring heteroring group, preferably the hetero ring group having 1 to 20 carbon atoms, more preferably 1 to 12 carbon atoms and further preferably 2 to 10 carbon atoms; examles include pyrrolidine, piperidine, piperazine, morpholine, thiophene, selenophene, furan, pyrrole, imidazole, pyrazole, pyridine, pyrazine, pyridazine, pyrimidine, triazole, triazine, indole, indazole, purine, thiazoline, thiazole, thiadiazole, oxazoline, oxazole, oxadi azole, chinoline, isoquinoline, phthalazine, naphthyridine, quinoxaline, quinazoline, quinoliine, pteridine, acridine, phenanthroline, phenazine, tetrazole, benzimidazole, benz oxazole, benzothiazole, benz triazole, tetrazaindene, carbazole, azepin, etc.; while furan, thiophene, pyridine, pyrazine, pyrimidine, pyridazine, triazine, quinoline, phthalazine, naphthyridine, quinoxaline and quinazoline are preferable; furan, thiophene, pyridine and chinoline are more preferable; and quinoline is further more preferable.  
      The aliphatic hydrocarbon group, the aryl group and the heteroring group represented by R B2  may have a substituent whose examples are the same as the above preferable examples of the substituent of L B .  
      The aliphatic hydrocarbon group, the aryl group and the heteroring group are preferable as R B2 , the aryl group and the heteroring group are more preferable and the aryl group is further more preferable.  
      In the general formula (B-I), X B2  is preferably —O— or ═N—R B2 , more preferably ═N—R B2  and particularly prferably ═N—Ar B2 ; while Ar B2  is an aryl group (preferably the aryl group having 6 to 30 carbon atoms, more preferably 6 to 20 carbon atoms and further more preferably 6 to 12 carbon atoms); or an aromatic hetero ring group (preferably the aromatic hetero ring group having 1 to 20 carbon atoms, more preferably 1 to 12 carbon atoms and further more preferably 2 to 10 carbon atoms).  
      In the general formula (B-I), Z B2  represents an atomic group necessary for forming aromatic group rings. The aromatic group ring formed by Z B2  may be any of an aromatic hydrocarbon ring or an aromatic heteroring; examplles include benzene ring, pyridine ring, pyrazine ring, pyrimidine ring, pyridazine ring, triazine ring, pyrrole ring, furan ring, thiophene ring, selenophene ring, tellurophene ring, imidazole ring, thiazole ring, selenazole ring, tellurazole ring, thiadiazole ring, oxadi azole ring, pyrazole ring, etc.; while benzene ring, pyridine ring, pyrazine ring, pyrimidine ring and pyridazine ring are preferable; benzene ring, pyridine ring and pyrazine ring are more preferable; benzene ring and pyridine ring are further more preferable; and pyridine ring is particularly preferable. The aromatic group ring formed by Z B2  may form a condensed ring with other ring or may have a substituent. Preferable substituents for Z B2  are alkyl group, alkenyl group, alkynyl group, aryl group, amino group, alkoxy group, aryloxy group, acyl group, alkoxycarbonyl group, aryloxy carbonyl group, acyl oxy group, acylamino group, alkoxycarbonylamino group, aryloxy carbonylamino group, sulfonyl amino group, sulfamoyl group, carbamoyl group, alkylthio group, arylthio group, sulphonyl group, halogen atom, cyano group and heteroring group; more preferable substituents for Z B2  are alkyl group, aryl group, alkoxy group, aryloxy group, halogen atom, cyano group and heteroring group; further more preferable substituents for Z B2  are alkyl group, aryl group, alkoxy group, aryloxy group and heteroring group; particularly preferable substituents for Z B2  are alkyl group, aryl group, alkoxy group and heteroring group.  
      In the general formula (B-I), n B2  represents an integer of 1 to 4, preferably an integer of 2 or 3.  
      Among the compounds expressed by the general formula (B-I), further preferable compounds are expressed by a following general formula (B-II):  
                 
 
      In the general formula (B-II), R B71 , R B72  and R B73  each represents the same as R B2  in the general formula (B-I), wherein the preferable range is also the same.  
      In the general formula (B-II), Z B71 , Z B72  and Z B73  each represents the same as Z B2  in the general formula (B-I), wherein the preferable range is also the same.  
      In general formula (B-II), L B71 , L B72  and L B73  each represents a connecting group of divalent or more described as the examples of L B  in the general formula (B-I); preferably a single bond, a divalent aromatic hydrocarbon ring group, a divalent aromatic heteroring group; and the connecting group formed by those combination; more preferably a single bond. L B71 , L B72  and L B73  may have a substituent, whose examples are the same as described as the substituent for L B  in the general formula (B-I).  
      Y represents a nitrogen atom, a 1,3,5-benzenetriyl group or a 2,4,6-triazinetriyl group. The 1,3,5-benzenetriyl group may have substituent at 2, 4 and 6-positions, examples of the substituent include alkyl group, aromatic hydrocarbon ring group, halogen atom, etc. Specific examples of the derivatives of five-member ring having a nitrogen atom represented by the general formula (B-I) or the general formula (B-II) include the following compounds, though not limited thereto.  
                 
                 
                 
                 
                 
 
 wherein Cz represents a substituted or unsubstituted carbazolyl group, an aryl carbazolyl group or a carbazolylalkylene group; 
 
      A represents a group formed by a portion expressed by a following general formula (A); and n and m each represents an integer of 1 to 3. 
 
(M) p -(L) q -(M′) r   (A) 
 
 wherein M and M′ each independently represents a heteroaromatic ring having a nitrogen atom and further having 2 to 40 carbon atoms, which forms a ring with or without a substituent; further, M and M′ may be the same with or different from each other. L represents a single bond, an arylene group having 6 to 30 carbon atoms, a cycloalkylene group of having 5 to 30 carbon atoms or a heteroaromatic ring having 2 to 30 carbon atoms, each may have or may not have a substituent which bonds to the ring. p represents an integer of 0 to 2, q represents an integer of 1 or 2 and r represents an integer of 0 to 2. However, p+r is 1 or greater. 
 
      Coupling styles of the general formula (C-I) and the general formula (C -II) are expressed in the following table concretely depending on a number of parameters n and m.  
                                               n = m = 1   n = 2   n = 3   m = 2   m = 3                                          Cz—A   Cz—A—Cz                         A—Cz—A                                        
 
      Further, coupling styles of the groups represented by general formula (A) are expressed in the following tables (1) to (16) concretely depending on a number of parameters p, q and r.  
                                               No.   p   q   r   Coupling styles                  (1)   0   1   1   L—M′       (2)   0   1   2   L—M′—M′, M′—L—M′       (3)   0   2   1   L—L—M′, L—M′—L               (4)   0   2   2   L—L—M′—M′, M′—L—L—M′                                                                                                   (5)   1   1   0   The same as (1). (Read M′ as M.)       (6)   1   1   1   M—L—M′               (7)   1   1   2                                     (8)   1   2   0   The same as (3). (Read M′ as M.)       (9)   1   2   1   M—L—L—M′, L—M—L—M′, M—L—M′—L               (10)   1   2   2   M—L—L—M′—M′, M′—L—M—L—M′,                       M′—M′—L—M—L,                                                                                                                                             (11)   2   1   0   The same as (2). (Read M′ as M.)       (12)   2   1   1   The same as (7). (Read M′ as M.)               (13)   2   1   2   M—M—L—M′—M′,                                                         (14)   2   2   0   The same as (4). (Read M′ as M.)       (15)   2   2   1   The same as (10.) (Read M′ as M.)               (16)   2   2   2   M—M—L—L—M′—M′,                                                                                                                                                                                          
 
      In the general formulae (C-I) and (C-II), when Cz couples with A, Cz may bond at any portion of M, L or M′ expressing A. For example, in a case where p=q=r=1 ((6) in table) in Cz-A wherein m=n=1, A becomes as M-L-M′ and expressed by three coupling styles of Cz-M-L-M′, M-L (-Cz)-M′ and M-L-M′-Cz. In the same way, in a case where p=q=1 and r=2 ((7) in table) in Cz-A-Cz wherein n=2 in the general formula (C-I), A becomes as M -L-M′-M′ or M-L(-M′)-M′ and expressed by following coupling styles:  
                 
 
      Specific examples of the structure represented by general formulae (C-I) and (C-II) include the structures shown in the following, however, they are not limited to the following.  
                 
                 
                 
                 
                 
 
 wherein Ar 11  to Ar 13  each represents the same group as R B2  in the general formula (B-I), specific examples are also same as those of R B2 ; Ar 1  to Ar 3  represents a divalent group of the same group as R B2  in the general formula (B-I), specific examples being the same. 
 
      Specific examples of the structure represented by general formula (C-III) include the structures shown in the following, however, they are not limited to the following.  
                 
 
 wherein R 11  to R 14  each represents the same group as R B2  in the general formula (B-I), specific examples are also same as those of R B2  
 
      Specific examples of the structure represented by general formula (C-IV) include the structures shown in the following, however, they are not limited to them.  
                 
 
 wherein Ar 1  to Ar 3  each represents the same group as R B2  in the general formula (B-I), specific examples are also same as those of R B2  
 
      Specific examples of the structure represented by general formula (C-V) include the structures shown in the following, however, they are not limited to them.  
                 
 
 wherein Ar 1  to Ar 4  each represents the same group as R B2  in the general formula (B-I), specific examples are also same as those of R B2 . 
 
      Specific examples of the structure represented by general formula (C-VI) include the structures shown in the following; however, they are not limited to them.  
                 
 
      Further in the organic EL device of the present invention, it is preferable to employ an inorganic compound such as an insulating material or a semiconductor for an electron injecting or transporting layer. The electron injecting or transporting layer employing an insulating material or a semiconductor effectively prevents leak in the electric current and improves the electron injecting capability. It is preferable that at least one metal compound selected from the group consisting of alkali metal chalcogenides, alkaline earth metal chalcogenides, alkali metal halides and alkaline earth metal halides is used as the insulating material. It is preferable that the electron injecting or transporting layer is constituted with the above alkali metal chalcogenide since the electron injecting property can be improved.  
      Preferable examples of the alkali metal chalcogenide include Li 2 O, LiO, Na 2 S and Na 2 Se and NaO. Preferable examples of the alkaline earth metal chalcogenide include CaO, BaO, SrO, BeO, BaS and CaSe. Preferable examples of the alkali metal halide include LiF, NaF, KF, LiCl, KCl, NaCl, etc. Preferable examples of the alkaline earth metal halide include fluorides such as CaF 2 , BaF 2 , SrF 2 , MgF 2  and BeF 2  and halides other than the fluorides.  
      Examples of the semiconductor constituting the electron injecting or transporting layer include oxides, nitrides and nitriding oxides containing at least one element selected from Ba, Ca, Sr, Yb, Al, Ga, In, Li, Na, Cd, Mg, Si, Ta, Sb and Zn, which are used singly or in combination of two or more. It is preferable that the inorganic compound constituting the electron injecting or transporting layer is in the form of a fine crystalline or amorphous insulating thin film. When the electron injecting or transporting layer is constituted with the above insulating thin film, a more uniform thin film can be formed and defective pixels such as dark spots can be decreased. Examples of the inorganic compound include the alkali metal chalcogenides, the alkaline earth metal chalcogenides, the alkali metal halides and the alkaline earth metal halides which are described above.  
      In the present invention, a reductive dopant with a work function of 2.9 eV or smaller may be added in the electron injecting or transporting layer. The reductive dopant used in the present invention is defined as a substance which reduces the electron transporting compound. In the present invention, it is preferable that the reductive dopant is added in the interfacial zone between the cathode and the organic thin film layer of the organic EL device, and the reductive dopant reduces at least a part of the organic layer resultantly making it anion. Examples of the reductive dopant include at least one compound selected from alkali metals, alkali metal complexes, alkali metal compounds, alkaline earth metals, alkaline earth metal complexes, alkaline earth metal compounds, rare earth metals, rare earth metal complexes and rare earth metal compounds. Examples of the preferable reductive dopant include at least one alkali metal selected from a group consisting of Li (the work function: 2.93 ev), Na (the work function: 2.36 eV), K (the work function: 2.28 eV), Rb (the work function: 2.16 eV) and Cs (the work function: 1.95 eV) or at least one alkaline earth metals selected from a group consisting of Ca (the work function: 2.9 eV), Sr (the work function: 2.0 to 2.5 eV) and Ba (the work function: 2.52 eV); whose work function of 2.9 eV is particularly preferable. Among those, more preferable reductive dopants include at least one kind selected from the group consisting of K, Rb and Cs, the latter Rb or Cs being farther more preferable and the last Cs being the most preferable. Those alkaline metals have particularly high reducing capability, and only an addition of relatively small amount of them into an electron injection zone enables to expect both improvement of luminance and lifetime extension of the organic EL device.  
      Examples of the alkaline earth metal compound described above include BaO, SrO, CaO and mixtures thereof such as Ba x Sr 1-x O (0&lt;x&lt;1) and Ba x Ca 1-x O (0&lt;x&lt;1). Examples of the alkali oxide or alkali fluoride include LiF, Li 2 O, Na F, etc. The alkali metal complex, the alkaline earth metal complex and the rare earth metal complex are not particularly limited as long as the complexes contain at least one of the alkali metal ions, the alkaline earth metal ions and rare earth metal ions, respectively, as the metal ion. As the ligand, quinolinol, benzoquinolinol, acridinol, phenanthridinol, hydroxyphenyloxazole, hydroxyphenylthiazole, hydroxydiaryloxadiazoles, hydroxydiarylthiadiazoles, hydroxyphenylpyridine, hydroxyphenyl- benzimidazole, hydroxybenzotriazole, hydroxyfulvorane, bipyridyl, phenanthroline, phthalocyanine, porphyrin, cyclopentadiene, β-diketones, azomethines and derivatives of these compounds are preferable. However, the ligand is not limited to the ligands described above.  
      As for the addition form of the reductive dopant, it is preferable that the reductive dopant is added in a manner such that a layer or islands are formed in the interfacial zone described above. In the case where the layer of the reductive dopant is formed, a preferable film thickness is from 0.05 to 8 nm.  
      As the process for adding the reductive dopant, it is preferable that an organic material which is the light emitting material or the electron injecting material forming the interfacial region is vaporized while the reductive dopant is simultaneously vapor deposited in accordance with the resistance heating deposition method so that the reductive dopant is dispersed in the organic material. The concentration of the dispersion expressed as the ratio of the amounts by mole of the organic substance to the reductive dopant is in the range of 100:1 to 1:100 and preferably in the range of 5:1 to 1:5. When the reductive dopant is added to form a layer, the reductive dopant alone is vapor deposited in accordance with the resistance heating deposition method to form a layer preferably having a thickness of 0.1 to 15 nm after a layer of the organic material such as the light emitting material and the electron injecting material is formed as the interfacial region. When the reductive dopant is added to form islands, the reductive dopant alone is vapor deposited in accordance with the resistance heating deposition method to form islands preferably having a thickness of 0.1 to 15 nm after islands of the organic material such as the light emitting material and the electron injecting material were formed as the interfacial region.  
      It is preferable that the light emitting layer in the organic EL device of the present invention has functions capable of injecting holes from the anode or the hole injecting layer when an electric field is applied, of injecting electrons from the cathode or the electron injecting layer, of mobilizing the injected electric charges (electrons and holes) by means of the electric field, and of providing a space for recombination of the electrons and holes thereby urging the light emission. It is preferable for the organic EL device of the present invention that the light emitting layer at least comprises the metal complex compound of the present invention, and it may comprise a host material which employs the metal complex compound as a guest material. Examples of the above host material include such as those having a carbazole skeletal structure, those having a diarylamine skeletal structure, those having a pyridine skeletal structure, those having a pyrazine skeletal structure, those having a triazine skeletal structure, those having an arylsilane skeletal structure, etc. It is preferable that T1 (energy level in the minimum triplet excitation state) of the host material is larger than T1 level of the guest material. The host material may be either a low molecular weight compound or a high molecular weight compound. Further, the light emitting layer in which the above light emitting materials are doped into thr above host materials can be formed by codeposition of the host materials and the light emitting materials such as the above metal-complex compound, etc.  
      In the organic EL device of the present invention, although a process for forming each layers are not particularly specified, various kinds of process such as a vacuum vapor deposition process, a LB process, a resistance heating deposition process, an electron beam process, a sputtering process, a molecular lamination process, a coating process (a spin coating process, a casting process, a dip coating process), an ink-jet process, a printing process are employable and the coating process of applying the materials over a substrate is preferable in the present invention.  
      The organic thin film layer comprising the metal-complex compound of the present invention can be formed in accordance with the vacuum vapor deposition process, a molecular beam epitaxy process (the MBE process) or, using a solution prepared by dissolving the compound into a solvent, in accordance with a conventional coating process such as the dip coating process, the spin with a conventional coating process such as the dip coating process, the spin coating process, the casting process, a bar coating process and a roller coating process.  
      In the above coating process, preparing a coating solution by dissolving the metal-complex compound of the present invention into a solvent, and by applying the coating solution over the surface of a predetermined layer (or, electrode), followed by drying may form the organic thin film layer. In the coating solution, a resin may be contained either by dissolved in a solvent or by dispersing into the solvent. Regarding with the resin, both non-conjugate high polymer (for example, polyvinylcarbazole) and conjugate high polymer (for example, polyolefin-based high polymer) are employable. Specific examples include polyvinylchloride, polycarbonate, polystyrene, polymethyl methacrylate, poly butylmethacrylate, polyester, polysulfone, polyphenylene oxide, polybutadiene, poly (N-vinyl carbazole), hydrocarbon resin, ketone resin, phenoxy resin, polyamide, ethyl cellulose, vinyl acetate, ABS resin, polyurethane, melamine resin, unsaturated polyester resin, alkyd resin, epoxide resin, silicone resin, etc.  
      The thickness of each layer in the organic thin film layer in the organic EL device of the present invention is not particularly limited. In general, an excessively thin layer tends to have defects such as pin holes, and an excessively thick layer requires a high applied voltage results in decreasing the efficiency. Therefore, a thickness within the range of several nanometers to 1 μm is preferable.  
      The present invention will be described in more detail by reference to the following examples. However, it should be noted that these examples are only illustrative and not intended to limit the invention thereto.  
     SYNTHESIS EXAMPLE 1  
     Synthesis of Metal-Complex Compound 1-1  
      The route for synthesis of Metal-Complex Compound 1-1 is shown as the following.  
                 
 
 ※ Structural Formula of Intermediate 1-1a Expresses Dimer Configuration. 
 
 (1) Synthesis of Intermediate 1-1b 
 
      Placing 4-cyanophenyl boronic acid in an amount of 11.7 g (75.3 mmol) and Pd(PPh 3 ) in an amount of 42.26 g (1.95 mmol) into a flask, replacing the atmosphere with argon gas, and adding ethylene glycol dimethylether in an amount of 500 milliliter, 1.3M Na 2 CO 3  aqueous solution in an amount of 150 milliliter, followed by further adding 2-bromopyridine in an amount of 11.9 g (75.3 mmol), the resultant mixture was reacted for 7 hours under refluxing. Distillating away the solvent from the reacted solution, dichloromethane was extracted. After washing the separated organic layer with water several times, the layer was dried with the use of magnesium sulfate. After concentration, the resultant crystals were purified by means of a silica column chromatography (developing solution: CH 2 Cl 2 /hexane=1/1) and as a result, 9.9 g of Intermediate 1-1b as white crystals was obtained (yield: 73%). The white crystals were confirmed as the aimed compound from  1 H-NMR spectrum. The measurement result is shown as follows:  
       1 H-NMR (CDCl 3 ): δ 8.69-8.77 (m,1H), δ 7.7-8.2 (m,6H), δ 7.24-7.39 (m, 1H)  
      (2) Synthesis of Intermediate 1-1a  
      Placing Intermediate 1-1b in an amount of 4.34 g (24.1 mmol) and IrCl 3  hydrate (available from Strem Chemicals, Inc.) in an amount of 1.8 g (6.02 mmol) into a flask, replacing the atmosphere with argon gas, and after pouring 2-ethoxyethanol in an amount of 30 milliliter, the resultant mixture was reacted for 7 hours under refluxing. A resultant brown precipitation was separated by filtration, followed by washing twice with the use of ethanol in an amount of 5 milliliter. Further, it was dissolved in 400 milliliter of methylene chloride, and the resultant solution was washed with the use of HCl aqueous solution in an amount of 200 milliliter, followed by washing twice with the use of water in an amount of 200 milliliter. After drying the resultant solution with the use of magnesium sulfate, the solvent was distillated away and as a result, 1.72 g of Intermediate 1-1a as brown crystals was obtained (yield: 49%).  
      (3) Synthesis of Metal-Complex Compound 1-1  
      Placing Intermediate 1-1a in an amount of 1.72 g (1.46 mmol) and 2-pyridinecarboxylic acid in an amount of 0.722 g (5.86 mmol) into a flask, replacing the atmosphere with argon gas, and after pouring 1,2-dichloroethane in an amount of 35 milliliter, the resultant mixture was reacted for 7 hours under refluxing. Distillating away the solvent from the reacted solution and dissolving the resultant dark yellow crystals into 300 milliliter of methylene chloride, the resultant solution was washed with the use of water in an amount of 150 milliliter and then, an organic layer was dried and after distillating away the solvent, yellow crystals were obtained. Washing the resultant crystals with the use of extremely slight amount of methylene chloride, and after drying them, 0.4 g of Metal-Complex Compound 1-1 was obtained (yield: 20%). The yellow crystals were confirmed as the aimed compound from  1 H-NMR spectrum and from the result in accordance with Field Desorption Mass Spectrum (FD-MS) analysis. The measurement result is shown as follows:  
       1 H-NMR (CD 2 Cl 2 ): δ 8.75 (d,1H), δ 7.0-8.25 (m,15H), δ 6.52 (d, 2H)  
      FD-MS: m/z=673  
      Further, by measuring phosphorus light (methylene chloride solution) of the resultant Metal-Complex Compound 1-1, it was found that λ max (wave length of peak light emission intensity) of phosphorus light was 528 nm.  
     SYNTHESIS EXAMPLE 2  
     Synthesis of Metal-Complex Compound 1-6  
      The route of synthesis of Metal-Complex Compound 1-6 is shown in the following.  
                 
 
 (1) Synthesis of Intermediate Product B 
 
      Placing Compound A in an amount of 25.2 g (136 mmol) and KMnO 4  in an amount of 86.1 g (544 mmol) into a flask, and the resultant solution was reacted in water for 9 hours under refluxing. After the reaction terminated, a precipitate was filtered and the filtrate was processed with 6N hydrochloric acid at room temperature. A deposit was washed with the use of 0.1N hydrochloric acid and dried, resultantly obtaining 11.4 g of Intermediate B (yield: 34%).  
      (2) Synthesis of Intermediate C  
      Placing Intermediate B in an amount of 25.0 g (102 mmol) and thionyl chloride in an amount of 250 g into a flask, the resultant solution was reacted for 7 hours under refluxing. Dissolving a resultant solid into 250 milliliter of toluene, a solution prepared by dissolving t-butylamine in an amount of 37.7 g (515 mmol) into toluene was dripped into the former solution at a temperature of 5 to 18° C. The temperature of the resultant solution was elevated little by little up to the room temperature, and adding 200 milliliter of water, the solution was stirred. A deposit was separated by filtration and as a result, 35.0 g of Compound C was obtained (yield: 96%).  
      (3) Synthesis of Intermediate D  
      Placing Intermediate C in an amount of 34.5 g (97.1 mmol) and thionyl chloride in an amount of 250 g into a flask, the resultant solution was refluxed for about 1.5 hours. Distillating away an excesst of thionyl chloride, a resultant yellow solid was purified by means of silica column (toluene). Distillating away the solvent from a resultant mixture, 14.7 g of Intermediate D as white crystals was obtained (yield: 73.1%).  
      (4) Synthesis of Intermediate 1-6b  
      Placing 2-bromopyridine in an amount of 58.9 g (373 mmol) and tetrahydrofuran (THF) in an amount of 58.9 g into a flask, a THF solution of 2.5M isopropyl magnesium chloride in an amount of 150 g (375 mmol) was dripped under cooling with ice, and the resultant solution was reacted at room temperature for 2 hours. Subsequently, Grignard agent prepared above was added into THF solution of anhydrous zinc bromide in an amount of 84.8 g (377 mmol) spending 15 minutes, the resultant solution was further reacted for 2.5 hours at room temperature. Throwing Compound D in an amount of 13.9 g (67.1 mmol) and Pd(PPh 3 ) 4  in an amount of 0.97 g (0.84 mmol) into the reacted solution, the resultant solution was further reacted at a temperature of 50° C. for 6 hours. After condensing the resultant reacted solution, it was extracted with the use of methylen chloride and a separated organic layer was washed several times with the use of water, followed by drying with the use of magnesium sulfate. After condensation, the resultant crystals were purified by means of a silica column chromatography (developing solution: toluene/ethyl acetate=10/1), and as a result, 6.5 g of Intermediate 1-6b as white crystals were obtained (yield: 47%). Further, the white crystals were confirmed as the aimed compound from the result in accordance with Gas Chromatography-Mass Spectrometry (GC-MS). The measurement result is shown as follows:  
      GC-MS: m/z=206(H 30 )  
      (5) Synthesis of Intermediate 1-6a  
      Placing Intermediate 1-6b in an amount of 41 g (20.0 mmol) and IrCl 3  hydrate (available from Strem Chemicals, Inc.) in an amount of 1.5 g (5.0 mmol) into a flask, the atmosphere was replaced with argon gas. Pouring 25 milliliter of 2-ethoxyethanol into the resultant solution, it was reacted for 16 hours under refluxing. A resultant yellow precipitation was separated by filtration, followed by washing with the use of methanol in an amount of 100 milliliter. Drying the separated precipitation, 1.74 g of Intermediate 1-6a as yellow crystals was obtained yield: 55%).  
      (6) Synthesis of Metal-Complex Compound 1-6  
      Placing Intermediate 1-6a in an amount of 1.72 g (1.35 mmol) and 2-pyridinecarboxylic acid in an amount of 0.666 g (5.4 mmol) into a flask, the atmosphere was replaced with argon gas. Pouring 50 milliliter of 1,2-dichloroethane into the resultant solution, it was reacted for 18 hours under refluxing. Distillating away the solvent from the reacted solution and dissolving the resultant dark yellow crystals into 800 milliliter of methylene chloride, the resultant solution was washed with the use of water in an amount of 200 milliliter and then, an organic layer was dried and after distillating away the solvent, pale yellow crystals were obtained. Washing the resultant crystals with the use of extremely slight amount of methylene chloride, and after drying them, 0.5 g of Compound 1-6 was obtained (yield: 40%). It was confirmed in accordance with FD-MS that Compound 1-6 was the aimed compound. The measurement result is shown as follows:  
      FD-MS: m/z=723  
      Further, by measuring phosphorus light (methylene chloride solution) of the resultant Metal-Complex Compound 1-6, it was found that λ max of phosphorus light was 471 nm.  
     SYNTHESIS EXAMPLE 3  
     Synthesis of Metal-Complex Compound 1-5  
      The route of synthesis of Metal-Complex Compound 1-5 is shown in the following.  
                 
 
 (1) Synthesis of Intermediate F 
 
      Placing Compound E in an amount of 35.1 g(143 mmol) and thionyl chloride in an amount of 407 g into a flask, the resultant solution was reacted for 4.5 hours under refluxing. Dissolving the resultant yellow oil into 700 milliliter of toluene, a toluene solution of t-n-butylamine in an amount of 52.4 g (716 mmol) was dripped slowly under cooling with ice, the resultant solution was warmed up to room temperature, and as a result, a resultant precipitate was separated by filtration. After drying, 50.2 g of Intermediate F was obtained (yield: 98%).  
      (2) Synthesis of Intermediate G  
      Placing Compound F in an amount of 42.0 g(118 mmol) and thionyl chloride in an amount of 285 milliliter into a flask, the resultant solution was reacted for 4.5 hours under refluxing. Distillating away an excess of thionyl chloride, a resultant yellow solid was washed with a use of ethyl acetate and toluene. After drying, 20.1 g of Intermediate G as white crystals was obtained (yield: 82.1%).  
      (3) Synthesis of Intermediate 1-5b  
      Placing 2-bromopyridine in an amount of 83.7 g (530 mmol) and tetrahydrofuran (THF) in an amount of 83.7 g into a flask, a THF solution of 2.5M isopropyl magnesium chloride in an amount of 214 g (530 mmol) was dripped under cooling with ice, and the resultant solution was reacted at room temperature for 3 hours. Subsequently, Grignard agent prepared above was added into THF solution of anhydrous zinc bromide in an amount of 120.5 g (535 mmol), the resultant solution was further reacted for 2 hours at room temperature. Throwing Conpound G in an amount of 18.5 g (89.4 mmol) and Pd(PPh 3 ) 4  in an amount of 1.2 g (1.0 mmol) into the reacted solution, the resultant solution was further reacted at a temperature of 50° C. for 10 hours. After condensing the resultant reacted solution, it was extracted with the use of methylen chloride and a separated organic layer was washed several times with the use of water, followed by drying with the use of magnesium sulfate. After condensation, the resultant crystals were purified by means of a silica column chromatography (developing solution: toluene/ethyl acetate=10/1), and as a result, 8.28 g of Intermediate 1-5b as white crystals were obtained (yield: 45.2%). It was confirmed in accordance with GC-MS that Intermediate 1-5b was the aimed compound. The measurement result is shown as follows:  
      GC-MS: m/z=205  
      (4) Synthesis of Intermediate 1-5a  
      Placing Intermediate 1-5b in an amount of 41 g (20.0 mmol) and IrCl3 hydrate (available from Strem Chemicals, Inc.) in an amount of 15 g (5.0 mmol) into a flask, the atmosphere was replaced with argon gas. Pouring 25 milliliter of 2-ethoxyethanol into the resultant solution, it was reacted for 24 hours under refluxing. A resultant yellow ocher precipitation was separated by filtration, followed by washing with the use of methanol in an amount of 200 milliliter. Drying the separated precipitation, 1.1 g of Intermediate 1-5a as yellow crystals was obtained (yield: 35%).  
      (5) Synthesis of Metal-Complex Compound 1-5  
      Placing Intermediate 1-5a in an amount of 1.1 g (0.86 mmol) and 2-pyridinecarboxylic acid in an amount of 0.43 g (35 mmol) into a flask, the atmosphere was replaced with argon gas. Pouring 60 milliliter of 1,2-dichloroethane into the resultant solution, it was reacted for 24 hours under refluxing. Distillating away the solvent from the reacted solution and dissolving the resultant orange crystals into 900 milliliter of methylene chloride, the resultant solution was washed with the use of water in an amount of 300 milliliter and then, an organic layer was dried with the use of magnesium sulfate and after distillating away the solvent, orange crystals were obtained. After drying, 0.45 g of Compound 1-5 was obtained (yield: 36%). It was confirmed in accordance with FD-MS that Compound 1-5 was the aimed compound. The measurement result is shown as follows:  
      FD-MS: m/z=723  
      Further, by measuring phosphorus light (methylene chloride solution) of the resultant Metal-Complex Compound 1-5, it was found that λ max of phosphorus light was 545 nm  
     SYNTHESIS EXAMPLE 4  
     Synthesis of Metal-Complex Compound 1-6X  
     
       
         
         
             
             
         
       
     
      Placing the above Intermediate 1-6a in an amount of 320 g (2.52 mmol) into a flask, replacing the atmosphere with argon gas, and after pouring 1,2-dichloroethane in an amount of 150 milliliter, the resultant mixture was stirred at the room temperature. On the other hand, dissolving acetylacetone in an amount of 0.55 g (5.5 mmol) into 10 milliliter of ethanol was reacted with 28% sodium methoxide methanol solution in an amount of 10 g (5.5 mmol equivalent) at the room temperature. Adding the resultant solution into the above Intermediate 1-6a solution, it was reacted for 17 hours under refluxing. Distillating away the solvent from the reacted solution and dissolving the resultant dark yellow crystals into 1000 milliliter of methylene chloride, the resultant solution was washed with the use of water in an amount of 500 milliliter and then, an organic layer was dried with the use of magnesium sulfate and again, the solvent was distillated away. The resultant crystals were purified by means of a silica column chromatography (developing solution: ethyl acetate/methylene chloride=1/4) and as a result, 0.7 g of pale yellow Compound 1-6X was obtained (yield: 20%). It was confirmed in accordance with FD-MS that Compound 1-6X was the aimed compound. The measurement result is shown as follows:  
      FD-MS: m/z=700  
      Further, by measuring phosphorus light (methylene chloride solution) of the resultant Metal-Complex Compound 1-6X, it was found that λ max of phosphorus light was 478 nm  
     EXAMPLE 1  
     Fabrication of Organic EL Device  
      A glass substrate of 25 mm×75 mm×1.1 mm thickness having an ITO transparent electrode was cleaned by application of ultrasonic wave in isopropyl alcohol for 5 minutes and then by exposure to ozone generated by ultraviolet light for 30 minutes. The cleaned substrate having the transparent electrode lines was attached to a substrate holder, and on the surface of the cleaned substrate at the side having the transparent electrode, a film of 4,4′-bis [N-(4-biphenyl)-N-(4-biphenyl)amino] bipheny having a thickness of 40 nm was formed so that the formed film covered the transparent electrode. The formed film worked as the hole transporting layer. Further, a host material (CBP) below together with additioning a photoluminescent Ir-Complex Compound 1-1 as a dopant were deposited obtaining a film thickness of 30 nm on the formed fimd. The formed film worked as a light emitting layer. A concentration of Compound 1-1 in the light emitting layer was 5% by weight. On the light emitting layer, a film of (1,1′-bisphenyl)-4-olate)bis(2-methyl-8-quinolinolato) aluminium (BAlq) below having a thickness of 10 nm was formed. The formed film of BAlq worked as the hole barrier layer. On the film formed above, a film of 8-hydroxyquinoline (Alq) having a thickness of 30 nm was formed. The film of Alq worked as the electron injecting layer. Subsequently, lithium fluoride being alkali metal halide was deposited up to 0.15 nm in thickness and then, aluminum was deposited up to 150 nm in thickness. The Al/LiF worked as a cathode. An organic EL device was fabricated in the manner described above. The device fabricated above was examined by passing electric current. Yellowish green light was emitted at a luminance of 107 cd/m 2  under a voltage of 6.6 V and a current density of 4.15 mA/cm 2 . The CIE chromaticity coordinates were (0.401, 0.568), and the current efficiency was 2.58 cd/A. Additionally, λ max of light emission was 531 nm.  
                 
 
     4,4′-bis [N-(4-biphenyl)-N-(4-biphenyl)amino]biphenyl  
     
       
         
         
             
             
         
       
     
     EXAMPLE 2  
     Fabrication of Organic EL Device  
      A glass substrate of 25 mm×75 mm×1.1 mm thickness having an ITO transparent electrode was cleaned by application of ultrasonic wave in isopropyl alcohol for 5 minutes and then by exposure to ozone generated by ultraviolet light for 30 minutes. The glass substrate having the transparent electrode which had been cleaned was attached to a substrate holder of a vacuum vapor deposition apparatus. On the surface of the cleaned substrate at the side having the transparent electrode, a film of TPD232 having a thickness of 100 nm was formed so that the formed film covered the transparent electrode. The formed film of TPD232 worked as the hole injecting layer. Further on the formed film, 4,4′,4″-tris(carbazole-9-yl)-triphenylamine (TCTA) below was film-formed obtaining a film thickness of 10 nm. The formed film of TCTA film worked as a hole transporting layer. Further, Compound (A) below was deposited obtaining a film thickness of 30 nm on the above TCTA film, simultaneously adding a phosphorous photoluminescent Ir Metal-Complex Compound 1-6X as a dopant. A concentration of Compound 1-6X in the light emitting layer was 7.5% by weight. The formed film worked as a light emitting layer. On the formed film, Compound (C-12) below was film-formed obtaining a film thickness of 25 nm. The formed film worked as an electron transport assisting layer. On the film formed above, a film of Alq having a thickness of 5 nm was formed. The film of Alq worked as the electron injecting layer. Subsequently, lithium fluoride was deposited up to 0.1 nm in thickness and then, aluminum was deposited up to 150 nm in thickness. The Al/LiF worked as a cathode. An organic EL device was fabricated in the manner descried above.  
      The device fabricated above was examined by passing electric current. Blueish green light was emitted at a luminance of 104 cd/m 2  under a voltage of 3.9 V and a current density of 0.26 mA/cm 2 , and the current efficiency was 39.6 cd/A.  
                 
                 
 
     COMPARATIVE EXAMPLE 1  
      An organic EL devices was fabricated similarly as Example 2 except that CFIracac below was used instead of the phosphorus photoluminescent Metal-Complex Compound 1-6X. Measuring voltage, current density, luminance and current efficiency, the measured results are shown in Table 1 together with colors of light emission.  
                 
 
     COMPARATIVE EXAMPLE 2  
      An organic EL devices was fabricated similarly as Example 2 except that FIracac below was used instead of the phosphorus photoluminescent Metal-Complex Compound 1-6 X. Measuring voltage, current density, luminance and current efficiency, the measured results are shown in Table 1 together with colors of light emission.  
                 
 
     EXAMPLE 3  
      An organic EL devices was fabricated similarly as Example 2 except that phosphorus photoluminescent Metal-Complex Compound 1-6 was used instead of the phosphorus photoluminescent Metal-Complex Compound 1-6X. Measuring voltage, current density, luminance and current efficiency, the measured results are shown in Table 1 together with colors of light emission.  
     COMPARATIVE EXAMPLE 3  
      An organic EL devices was fabricated similarly as Example 2 except that FIrpic below was used instead of the phosphorus photoluminescent Metal-Complex Compound 1-6 X. Measuring voltage, current density, luminance and current efficiency, the measured results are shown in Table 1 together with colors of light emission.  
                 
 
     COMPARATIVE EXAMPLE 4  
      An organic EL devices was fabricated similarly as Example 2 except that CFIrpic below was used instead of the phosphorus photoluminescent Metal-Complex Compound 1-6 X.  
      Measuring voltage, current density, luminance and current efficiency, the measured results are shown in Table 1 together with colors of light emission.  
               TABLE 1                                                                                                          Dopant in               Current               Light emitting   Voltage   Current Dencity   Luminance   efficiency   Color of Light           layer   (V)   (mA/cm 2 )   (cd/m 2 )   (cd/A)   Emission                                                     Ex. 2   1-6X   3.9   0.26   103   39.6   Bluish Green       Ex. 3   1-6   5.0   0.33   104   31.5   Bluish Green       Co. Ex. 1   CFIracac   7.2   0.51   100   19.6   Bluish Green       Co. Ex. 2   FIracac   7.0   0.50   103   19.5   Bluish Green       Co. Ex. 3   FIrpic   6.1   0.75   106   13.8   Bluish Green       Co. Ex. 4   CFIrpic   6.6   0.63   98   15.5   Bluish Green                  
 
      As shown in Table 1, it is verified that the organic EL devices of Examples 2 to 3 employing of Metal-Complex Compound of the present invention become capable of working at low driving voltage and emitting bluish green light with enhanced current efficiency relative to Comparative Examples 1-4.  
     INDUSTRIAL APPLICABILITY  
      As described above in detail, the organic EL device employing the novel metal-complex compound of the present invention emits various phosphorous lights including blue light having an enhanced current efficiency and prolonged lifetime. Accordingly, the present invention is applicable for a field such as various display devices, display panels, backlights, illuminating light sources, beacon lights, signboards, and interior designs, particularly suitable as display device for color displays.