Patent Publication Number: US-2022231483-A1

Title: Germanium-on-silicon laser in cmos technology

Description:
CROSS REFERENCE TO RELATED APPLICATION 
     This application is a divisional of U.S. patent application Ser. No. 16/867,666, filed May 6, 2020, which is a divisional of U.S. patent application Ser. No. 15/555,639, filed Sep. 5, 2017, which claims priority from PCT/FR2015/050555, filed Mar. 6, 2015, the disclosures of which are incorporated by reference herein. 
    
    
     BACKGROUND 
     The present disclosure relates to a germanium laser that can be formed on silicon in a way compatible with the forming of CMOS integrated circuits. 
     DISCUSSION OF THE RELATED ART 
     A germanium-on-silicon laser is formed of a desired length of a waveguide comprising an N-type germanium strip surrounded by P-type and N-type silicon strips. The P-type and N-type silicon strips should be able to be connected to respective positive and negative potentials to perform a planar electric injection into the germanium. The laser may operate at a wavelength comprised within a wavelength range from 1.55 to 2.2 μm, particularly according to the germanium strain level. 
     The forming of a silicon-germanium-silicon waveguide will here essentially be described. It should be understood that, to form a laser, this waveguide will be longitudinally delimited at its opposite ends by reflective surfaces which may for example correspond to trenches to obtain an air-germanium interface. It may be preferred to deposit a thin silicon nitride layer, SiN, to form an air-SiN-germanium interface or form a Bragg mirror adapted to the emission wavelength of the laser which is desired to be formed. These various options enable to associate on a photonic chip the germanium laser with a passive waveguide made of silicon or SiN, noting that silicon is transparent in infrared at the wavelengths at which a germanium laser operates. 
     The silicon-germanium-silicon assembly forms a double heterostructure. The N-doped germanium is the active area of the laser. The two other semiconductors play the role of potential barriers which enable to inject and to confine in the germanium the carriers necessary for the generation of radiative recombinations. Typically, the germanium strip is N-type doped with a density in the range from 0.8 to 4.10 19  atoms per cm 3 . 
     There is a need for a germanium laser which can be manufactured by only using current CMOS integrated circuit technologies, and particularly CMOS integrated circuits on silicon where some at least of the transistors have strained germanium or silicon-germanium channel areas. 
     SUMMARY 
     Thus, an embodiment provides a method of forming a germanium waveguide comprising the steps of delimiting an area of a P-type silicon substrate with trenches, coating this area with a heavily-doped N-type germanium strip and with a first N-type doped silicon strip; and coating the entire structure with a silicon nitride layer. 
     According to an embodiment, the method comprises the step of defining in the silicon nitride contact openings on the sides of the first silicon strip covering the germanium strip. 
     According to an embodiment, the method comprises, after the forming of the trenches and the coating with germanium and silicon, a step of widening the openings in the substrate so that the germanium strip rests on a silicon base. 
     An embodiment provides a germanium waveguide comprising a P-type silicon substrate strip delimited by lateral trenches coated with a heavily-doped N-type germanium strip and with a first N-type doped silicon strip, the assembly being coated with a silicon nitride layer. 
     According to an embodiment, the trenches are widened in their portion penetrating into the silicon substrate, whereby the germanium strip rests on a second silicon strip of decreased width. 
     An embodiment provides a method of forming a germanium waveguide comprising the steps of forming in a silicon substrate a heavily-doped N-type germanium strip, forming on each side of the strip respectively P-type and N-type doped silicon strips, etching so that the germanium strip and adjacent portions of the silicon strips are raised with respect to the substrate surface, and coating the structure with a silicon nitride layer. 
     An embodiment provides a germanium waveguide comprising, on a silicon substrate, a heavily-doped N-type germanium strip, surrounded with respectively P-type and N-type doped silicon strips, the assembly being coated with a silicon nitride layer. 
     An embodiment provides a method of manufacturing a germanium waveguide comprising the steps of forming on a substrate coated with a germanium layer a heavily-doped N-type germanium strip, depositing on either side of the germanium strip respectively P-type and N-type doped silicon/germanium strips, and coating the upper surface of the germanium strip with a silicon nitride layer. 
     According to an embodiment, the heavily-doped N-type germanium strip is coated with a more lightly doped N-type germanium strip. 
     An embodiment provides a germanium waveguide comprising above a silicon substrate coated with a germanium layer a heavily-doped N-type germanium strip, this strip being surrounded with silicon/germanium strips. 
     According to an embodiment, the heavily-doped N-type germanium strip is coated with a more lightly doped N-type germanium strip. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
       The foregoing and other features and advantages will be discussed in detail in the following non-limiting description of specific embodiments in connection with the accompanying drawings, among which: 
         FIGS. 1A to 1D  are simplified transverse cross-section views illustrating successive steps of the manufacturing of a first embodiment of a germanium laser; 
         FIGS. 2A to 2E  are simplified transverse cross-section views illustrating successive steps of the manufacturing of a variation of the first embodiment of a germanium laser; 
         FIGS. 3A to 3G  are simplified transverse cross-section views illustrating successive steps of the manufacturing of a second embodiment of a germanium laser; 
         FIGS. 4A to 4F  are simplified transverse cross-section views illustrating successive steps of the manufacturing of a first variation of a third embodiment of a germanium laser; and 
         FIGS. 5A to 5E  are simplified transverse cross-section views illustrating successive steps of the manufacturing of a second variation of a third embodiment of a germanium laser. 
     
    
    
     DETAILED DESCRIPTION 
     The same elements have been designated with the same reference numerals in the different drawings and, further, the various drawings are not to scale. For clarity, only those elements which are useful to the understanding of the described embodiments have been shown and are detailed. 
     In the following description, when reference is made to terms qualifying the position and orientation such as “above”, “under”, “upper”, “lower”, etc., reference is made to the representation of the concerned elements in the drawings. 
     1. Planar Injection Laser 
       FIGS. 1A to 1D  are simplified transverse cross-section views illustrating successive steps of the manufacturing of a first embodiment of a planar injection germanium laser. 
     As illustrated in  FIG. 1A , it is started from a P-type silicon substrate  1 , which may be a thin silicon-on-insulator layer (SOI). On this substrate  1 , a thin N-type germanium layer  3  is deposited and then covered with a thin N-type silicon layer  5 . It should be noted that layer  5  may be a polysilicon layer, the materials of layers  1  and  3  being monocrystalline. The waveguide is formed in the central portion of  FIG. 1A  delimited by trenches  7  which penetrate into substrate  1 , and extends orthogonally to the plane of the drawing. 
     At a next step illustrated in  FIG. 1B , a silicon nitride layer  9  is deposited. Conventionally, the silicon nitride layer is deposited by plasma-enhanced chemical vapor deposition (PECVD) at a temperature in the range from 300 to 700° C. The tensioning of the germanium is ensured by the fact that the silicon nitride layer (SiN) is placed under compressive strain on deposition thereof. This strain will relax and the nitride layer returns to a more stable state and stretches. As a result of this deformation, the layers located under the silicon nitride layer are under tensile strain. Preferably, the waveguide is oriented in the &lt;100&gt; crystallographic direction of the germanium. Silicon nitride layer  9  covers the structure and, preferably, penetrates into trenches  7 . Before the deposition of the silicon nitride layer, it is possible to deposit a silicon oxide layer having a thickness of some ten nanometers to improve the bonding and to passivate the free surfaces of the semiconductors. 
     At a next step illustrated in  FIG. 1C , openings  11  are formed in the silicon nitride layer to enable to form a contact on underlying silicon layer  5 . As shown, openings  11  are preferably arranged on either side of the guide width to avoid relaxing the strain caused by silicon nitride layer  9  in the underlying layers. 
     After this, as illustrated in  FIG. 1D , a layer of a conductive material  13  is deposited to form contacts on N-type silicon layer  5 . Further, an electrical contact, not shown, is conventionally created on P-type silicon substrate  1 . This contact may be laterally transferred to an area close to the waveguide. A metal strip may for example be deposited parallel to the guide in an area etched down to a depth close to some ten micrometers to form the contact on substrate  1 . 
     According to the choice of materials used and to the geometry of the structure (guide width, thickness of the layers, depth of the trenches, position of the openings) and to the characteristics of the silicon nitride layer deposited by PECVD, the uniaxial deformation in the germanium induced by the silicon nitride layer may reach a level in the range from 0.55 to 0.87%. The disclosed structure is adaptable to different type of stackings of materials. 
     The strain is homogeneously applied along the entire width of the guide, even for significant thicknesses of the germanium layer. This provides an active medium having a length of several micrometers, and accordingly a significant gain per unit length for the laser. 
     The waveguide may have a width in the range from 4 to 6 according to the desired optical properties, while ensuring a good transfer of the strain. 
     The thickness of N-type doped germanium layer  3  is in the range from 250 to 300 nm (close to λ/2n, where λ is the emission wavelength of the laser and n is the refraction index of germanium). Such a thickness provides a good guiding of the light in near infrared. Layer  5 , which is used as an electric injector, should be selected with a thickness sufficient to obtain an electric contact of good quality, but not too thick, to avoid for this layer to absorb the strain transmitted by the SiN layer. 
     Based on the above-discussed imperatives, digital finite element simulations of the mechanical behavior of the structure may be performed to optimize the different parameters of the topology of the waveguide (trench depth, guide width, positioning of the openings). The transfer of the strain in the structure may be simulated from the value of the initial strain of the silicon nitride layer deposited across a 300-nm thickness. The value of the initial hydrostatic strain of the SiN film in compressive mode is −4.5 GPa (in practice, −1.8 GPa is obtained in the plane of the layer at equilibrium). The strain level may be modified by modifying the silicon nitride layer deposition parameters. The uniaxial deformation values only take into account the effect of the SiN layer. According to the conditions of deposition of the germanium on silicon layer, it is possible to obtain an initial residual strain associated with the thermal expansion coefficient difference. This deformation, which is in the range from 0.15 to 0.25%, may add to the total deformation that can be transferred by the silicon nitride layer. 
     The silicon nitride layer deposited in the bottom of the trenches forms a compressive strain pocket. Such a pocket adversely affects the obtaining of the laser effect in the germanium. An etching of the trenches down to a 1.5-μm depth provides an optimal result to limit this effect, and this, for different guide widths which may range up to 5 μm. 
     Tests and simulations have shown that the dimensions of the elements of the waveguide should preferably be within the following ranges:
         guide width: from 4 to 6 μm,   thickness of germanium layer  3 : from 200 to 500 nm,   thickness of injector layer  5 : from 100 to 250 nm,   thickness of nitride layer  9 : from 300 to 500 nm,   trench width: from 0.5 to 1 μm,   trench depth: from 1 to 1.5 μm,   width of the openings: from 200 to 500 nm,   distance from the openings to the edges: from 200 to 500 nm.       

       FIGS. 2A to 2E  are transverse cross-section views illustrating successive steps of the manufacturing of a variation of the structure of  FIG. 1D . 
       FIG. 2A  shows the structure already described in relation with  FIG. 1A . 
     At a step illustrated in  FIG. 2B , a selective anisotropic etching of P-type silicon  1  is carried out so that trenches  7  widen under germanium layer  3  to form bowl-shaped openings  20 . Thus, under germanium  3 , only a narrowed portion or base  22  of silicon substrate  1  remains in place. Of course, base  22  extends in a strip orthogonal to the plane of the drawings. 
     The next steps illustrated in  FIGS. 2C to 2E  are respectively identical to the steps described in relation with  FIGS. 1B to 1D . 
     Thus, in the structure of  FIG. 1D , silicon substrate  1  extends under the entire portion of germanium layer  3  while in the structure of  FIG. 2E , the germanium layer portion only partly rests on a silicon base  22 . The disengaging of the germanium layer allows a deformation of greater amplitude and enables to obtain a more efficient strain transfer. 
     The variation of  FIGS. 2A to 2E , where the germanium is suspended on a base, enables to obtain the following advantages over the case of  FIGS. 1A to 1D :
         greater strain in the structure,   confinement of the optical mode at the center of the structure, and   confinement of the carriers at the center of the structure during the electric injection.       

     For a guide having a 5 μm thickness without the base, a uniaxial tensile deformation of 0.5% can be obtained in the germanium. The underetching enables to amplify this value up to 0.75%. The thinner the base, the more significant the deformation that can be achieved in the structure will be, but the maximum is located at the interface between the SiN layer and the semiconductor for the electric injection. This effect is due to the bend of the structure. A good tradeoff is given for a ratio from 0.5 to 0.7, for example, 0.6, between the width of the waveguide and the size of the base. 
     Tests and simulations have shown that the dimensions of the elements of the waveguide could preferably be within the following ranges:
         guide width: from 3 to 5 μm,   base height: from 1 to 1.5 μm,   base width: from 0.55 to 0.65 times the width of the germanium strip,   width of the openings: from 200 to 500 nm,   distance from the openings to the edges: from 200 to 500 nm.       

     2. First Example of Lateral Injection Laser 
       FIGS. 3A to 3G  are simplified transverse cross-section views illustrating successive steps of the manufacturing of a second embodiment of a lateral injection germanium laser. 
     As illustrated in  FIG. 3A , it is started from a silicon substrate  1 , possibly of SOI type. This substrate is preferably lightly doped, and practically insulating, or P-type doped. 
     At the step illustrated in  FIG. 3B , a groove  30  has been formed in the substrate. 
     At the step illustrated in  FIG. 3C , the groove has been filled by local epitaxy of a heavily-doped N-type germanium strip  32 . 
     At the step illustrated in  FIG. 3D , one has formed in substrate  1 , on either side of germanium strip  32 , parallel strips  34  and  36  doped by implantation, respectively of type P and of type N. 
     At the step illustrated in  FIG. 3E , the upper surface of germanium strip  32  and a neighboring portion of parallel doped silicon strips  34  and  36  has been masked. After this, an etching has been carried out to form a raised area comprising an upper portion  35  of strip  34  and an upper portion  37  of strip  36  which surround germanium strip  32 . The recessed portions of strips  34  and  36  are offset from the sides of strip  32  and may, for example, example, have an upper surface coplanar with the substrate  1  (also recessed by the etching). The upper surface of the recessed strips and substrate may, for example, be substantially coplanar with the lower surface of the strip  32 . The strips on either side of the strip  32  have an L shape in cross section with one leg formed by the recessed portions  34  and a perpendicular leg formed by the portion  35  and  37 . 
     At the step illustrated in  FIG. 3F , the entire structure is coated with a silicon nitride layer  40  which generates the desired strain effect as previously described. It should be noted that, in this embodiment, the nitride is directly deposited on the germanium and thus that the strain is directly applied thereto and is thus even more efficient than in the previously-described embodiments of planar injection guides. Before the deposition of the silicon nitride layer, it is possible to deposit a silicon oxide layer having a thickness of some ten nanometers to improve the bonding and to passivate the free surfaces of the semiconductors. 
     At the step illustrated in  FIG. 3G , the nitride layer has been only maintained on the upper surface of the guide and outside of the structure. After this, metallizations  42  and  44  in contact, respectively, with silicon strips  34  and  36  have been formed. Metallization  42  is intended to be connected, in operation, to a positive potential and metallization  44  is intended to be connected, in operation, to a negative or zero potential. 
     The lateral doped silicon layers enable to transfer the contacting area laterally with respect to the waveguide. The metal contacts have no influence upon the transfer of the strain into the germanium via the silicon nitride layer. This also enables to avoid for the optical mode to be disturbed by the metal, and to avoid for a possible heating of the current supply metal conductors to affect the active area of the waveguide. 
     For a waveguide having a 5-μm width with an active area having a 4.6-μm width, the deformation reaches a 0.5% level. The results are close to a planar injection guide. However, when the guide width is decreased to 2 μm, the ratio between the width of the guide and that of the SiN layer is modified, and the uniaxial deformation may reach a level of 1.3%. 
     Tests and simulations have shown that the dimensions of the waveguide elements could preferably be within the following ranges:
         guide width: from 1.6 to 3 μm,   width of the Ge layer: from 1.5 to 2.5 μm,   width of the Si layers: 2×200 nm,   guide height: from 300 nm to 1   width of the SiN layer: from 300 to 500 nm.       

     3. Second Example of Lateral Injection Laser 
       FIGS. 4A to 4F  are simplified transverse cross-section views illustrating successive steps of the manufacturing of a first variation of a third embodiment of a lateral injection germanium laser. 
     As illustrated in  FIG. 4A , it is started from a silicon substrate  1 , possibly of SOI type, coated with a germanium layer  50 . Germanium layer  50  comprises a heavily-doped N-type central area  51 . This is obtained by successive epitaxies or by implantation. 
     At the step illustrated in  FIG. 4B , an etching is performed to delimit a strip  52  of the heavily-doped germanium resting on a more lightly doped germanium layer  54 . The upper heavily-doped germanium portion is removed. 
     At the step illustrated in  FIG. 4C , a local epitaxy of strained Si x Ge 1-x  (x being a number smaller than 1) on germanium  54 , is carried out on either side of strip  52 . Si x Ge 1-x  strips extending on either side of heavily-doped N-type central germanium strip  52  are thus obtained. These Si x Ge 1-x  strips are doped, for example, by implantation, to form respectively P-type and N-type doped silicon/germanium strips  56  and  58 . 
     At the step illustrated in  FIG. 4D , portions of each of silicon/germanium strips  56  and  58  which are not adjacent to germanium strip  52  are etched to decrease their thickness. The etching depth is approximately ⅓ of the thickness of SiGe layers  56  and  58  (that is, from 20 to 100 nm, for SiGe layers from 50 to 300 nm). The lateral dimension of the SiGe layers is from 1 to 2 μm. Thus, the total width of the guide is from 1.05-1.3 μm to 2.05-2.3 μm, according to the width of the central germanium layer. 
     At the step illustrated in  FIG. 4E , one has formed on the central portion of the guide, that is, on germanium strip  52  and on the raised portions of strips  56 ,  58 , a strained SiN layer  60  to enhance the deformation at the center of the structure. The SiN layer is directly in contact with the germanium, which provides an optimized strain transfer. 
     After this, as illustrated in  FIG. 4F , electric contacts  62 ,  64  are formed on SiGe strips  56 ,  58 . 
       FIGS. 5A to 5E  are simplified transverse cross-section views illustrating successive steps of the manufacturing of a second variation of a third embodiment of a lateral injection germanium laser. 
       FIG. 5A  is identical to  FIG. 4A . 
     At the step illustrated in  FIG. 5B , an etching is performed to delimit a strip  72  of the heavily-doped germanium resting on a more lightly doped germanium layer  54 . The upper lightly-doped germanium portion is maintained in place and forms a strip  74  on strip  72 . 
     At the step illustrated in  FIG. 5C , a local epitaxy of strained Si x Ge 1-x  (x being a number smaller than 1) on germanium  54 , is carried out on either side of strip  72 . The epitaxy is interrupted at the level of the limit between strips  72  and  74  (so that, for example, strips  56 ,  58  do not reach and make contact with the strip  74 ). Si x Ge 1-x  strips extending on either side of heavily-doped N-type central germanium strip  72  are thus obtained. These Si x Ge 1-x  strips are doped, for example, by implantation, to form respectively P-type and N-type doped silicon/germanium strips  56  and  58 . 
     At the step illustrated in  FIG. 5D , one has formed on the central portion of the guide, that is, on germanium strip  74 , a strained SiN layer  80  to enhance the deformation at the center of the structure. The SiN layer is directly in contact with the germanium, which provides an optimized strain transfer. 
     After this, as illustrated in  FIG. 5E , electric contacts  62 ,  64  are formed on SiGe strips  56 ,  58 . 
     The structures of  FIGS. 4F and 5E  use lateral epitaxial Si x Ge 1-x  strips  56  and  58  strained and doped around the central guide or band. Such epitaxial strips enable to: 
     1) create a local tensile strain against the germanium band in the N-type doped area, 
     2) performing the electric injection of the carriers into the N doped germanium, by taking advantage of the discontinuities of the energy bands between the Ge and the SiGe for the confinement of the carriers. 
     The tensile strain in the SiGe layer will transfer by laterally pulling the germanium layer. The strain depends on the silicon concentration in the Si x Ge 1-x  layer. It is due to the mesh parameter difference between the silicon and the germanium. 
     Regarding the strain transfer, the critical parameter is the thickness of the Si x Ge 1-x  layer which can be grown by epitaxy according to its composition. The strain obtained in Si x Ge 1-x  layer is proportional to the product of the composition by the relative mesh parameter difference between the silicon and the germanium. The larger the silicon concentration, the more the Si x Ge 1-x  layer will be strained. As a counterpart, however, the maximum thickness which can be obtained decreases. Typically, the critical thicknesses, emax, and the biaxial strains, ε//, of the Si x Ge 1-x  layers are:
         Si 0.4 Ge 0.6 : emax=50-70 nm, ε//=1.6%   Si 0.3 Ge 0.7 : emax=100-150 nm, ε//=1.2%   Si 0.2 Ge 0.8 : emax=250-300 nm, ε//=0.8%       

     The thickness of the active germanium layer should be identical to that of the Si x Ge 1-x  layer for an optimal strain transfer. The applicants have studied the strain transfer for these three cases and have also considered the effect of the addition of a strained SiN layer to amplify the transferred strain. 
     Si 0.2 Ge 0.8    
     An active germanium layer of 250×250 nm is considered. The initial strain in the Si 0.2 Ge 0.8  layer is ε//=0.8%. The average uniaxial deformation in the active germanium area is 0.5%, the addition of a SiN layer enables to amplify the average uniaxial deformation in germanium up to a value of 0.6%. 
     Si 0.3  Ge 0.7    
     An active germanium layer of 125×125 nm is considered. The initial strain in the Si 0.3 Ge 0.7  layer is ε//=1.2%. The average uniaxial deformation in the active germanium area is 0.9%, by using Si 0.3 Ge 0.7  layers. The addition of a SiN layer enables to increase the average uniaxial deformation up to 0.98%. 
     Si 0.4 Ge 0.6    
     An active germanium layer of 50×50 nm is considered. The average uniaxial strain in the active germanium area in the Si 0.4 Ge 0.6  layer is ε//=1.6%. The average uniaxial deformation in the active germanium area is 1.13%, by using Si 0.4 Ge 0.6  layers. The addition of a SiN layer enables to obtain an average uniaxial deformation of 1.42%. 
     Various embodiments with different variations have been described hereabove. It should be noted that those skilled in the art may combine various elements of these various embodiments and variations without showing any inventive step. It should be understood that, for the sake of brevity, certain explanations and numerical indications given for certain embodiments have not been repeated for other embodiments. 
     Further, each of the materials described as an example may be replaced with a material having the same properties and the same function in the devices and methods described hereabove as an example only.