Patent Publication Number: US-5250499-A

Title: Delivery system for agricultural chemicals

Description:
This is a continuation of application Ser. No. 448,707, filed Dec. 11, 1989, now U.S. Pat. No. 5,071,463. 
    
    
     BACKGROUND OF THE INVENTION 
     I. Field of the Invention 
     The invention relates to a delivery system for agriculturally active chemicals. More particularly, the invention relates to an emulsifiable concentrate of difficult to dissolve agricultural chemicals. 
     II. Description of the Prior Art 
     Agricultural chemicals are most preferably applied in the form of aqueous emulsions, solutions, or suspensions. Occasionally, they may also be applied in the form of a dust wherein the active ingredient is adsorbed onto or mixed with a finely divided inert carrier material, such as, china clay, or the like. With such powdered or dust compositions, drift due to wind is a problem and consequently, liquid formulations are preferred. 
     One of the problems with such liquid formulations is the fact that chemicals having agricultural activity often exhibit extreme insolubility in water. This results in their having to be dissolved either in organic solvents or utilized in the form of emulsions or suspensions. With respect to the use of organic solvents, these are generally disadvantageous from an environmental and cost viewpoint. Particularly, such organic chemicals may exhibit toxicity or side-effects which may be adverse to the effect of the agricultural chemical itself or to the subsequent fruit or vegetable produced in the particular agricultural use. This toxicity may also be disadvantageous with respect to handling. 
     When attempts are made to provide emulsified or suspension formulations, difficulties are encountered with respect to providing a desirably high concentration of the agriculturally active ingredient. Thus, when such agriculturally active chemicals are formulated into an emulsion, it is difficult to maintain the emulsified state. This makes it difficult to maintain a uniform formulation, particularly, when the formulation is diluted with water for application to the plants. 
     Typically, for example, the agriculturally active ingredient is mixed with one or more of a variety of conventional solvents and an emulsifying agent to form a concentrate. This concentrate may be an emulsion, suspension, or solution. The concentrate is then stored until it is transported to the site of use or may simply be transported and stored at the site of use. In any event, the concentrate normally will undergo some period of storage until it is ready for use. Understandably, it is most desirable to be able to transport the agriculturally active ingredient at the highest concentration possible so as to minimize the volume of material which need be transported. By the same token, however, at the use site, it is normally not feasible to admix ingredients together or to process them other than to dilute the concentrate with water. Accordingly, it is important that the concentrate emulsify easily, i.e., exhibit good &#34;bloom&#34;, upon the addition of water. In addition, at the use site, it is often necessary to store the diluted concentrate for extended time periods until the actual application to the plants. Consequently, it is important that the diluted form of the concentrate exhibit good stability with respect to the uniformity of the emulsion and to avoid precipitation of the active ingredients. If non-uniformity or precipitation occurs in the diluted form, then non-uniformity will result in the application of the diluted formulation to the plants. 
     An attempt to provide concentrates of agriculturally useful chemicals is disclosed in South African Patent Application No. 695,393, filed Jul. 25, 1969. This application is directed to the formulation of a concentrate substantially water-insoluble pesticides for agricultural use. The pesticides, either in oil or solid form, are mixed with pyrrolidones having a hydrogen or a lower alkyl group containing from 1 to 4 carbon atoms attached to the nitrogen atom of the pyrrolidone ring. The application discloses that concentrated solutions of difficult to dissolve pesticides could be formulated and that such concentrates exhibited good stability The concentrates utilized are those containing the pesticidal active ingredient, the particular lower alkyl pyrrolidone, a co-solvent which is usually a common organic solvent, such as, an aromatic including xylene, methylated and polyalkylated naphthalenes and aliphatic solvents, and a dispersing or emulsifying agent, such as, a surfactant, including polyoxyethylene alkylphenols, polyoxyethylene fatty esters, polyoxyethylene sorbitan fatty esters which may be blended with oil-soluble sulfonates, calcium and amino-sulfonate salts, and the like. 
     This prior art does not offer a solution to the problem arising from the difficulty in maintaining the stability of the emulsion after the concentrate is diluted with water. Consequently, unless the diluted form of the concentrate is used immediately after emulsification, it is difficult to provide a stable diluted formulation for application to the plants. 
     U.S. Pat. No. 4,798,837 discloses an emulsifiable concentrate of the pesticidal compound (CGA): ##STR1## 
     This active concentrate contains 10% of the active ingredient using 30% cyclohexanone as the solvent. However, cyclohexanone is highly toxic. For such agricultural uses, it is desirable to avoid the use of toxic solvents, including those of Lists 1 and 2 of 40 C.F.R. 154.7 dated Apr. 22, 1987, which includes inerts of toxicological concern and solvents having high flash points, as well as to increase the amount of the agriculturally active material in the concentrate. 
     SUMMARY OF THE INVENTION 
     We have discovered a novel emulsifiable concentrate of an agriculturally active chemical, which concentrate provides, upon dilution, a highly stable emulsion. In addition, the inventive emulsifiable concentrates may contain relatively high concentrations of the agriculturally active ingredient making it advantageous from both economic and handling viewpoints. Also, the concentrates of the present invention utilize organic materials which do not pose environmental problems either in use or handling. 
     More particularly, the emulsifiable concentrate of the present invention is composed of an agriculturally active chemical, a surfactant, an organic diluent, and a solvent having a first component and a second component. 
     The first component of the solvent is selected from those compounds which have a sufficiently high hydrophilic property to solubilize the agriculturally active chemical. Preferably, the first component will have the following Hansens&#39; solvent parameters: 
     Dispersable component from about 40 to 50%; 
     Polar components of from about 25 to 40%; and 
     H-bonding components of 10 to 30%. 
     The second component is a hydrophobic solvent having the following Hansens&#39; solubility parameters: 
     Dispersive component from about 56 to 75%; 
     Polar component from about 8 to 24%; and 
     H-bonding component of from about 10 to 30%. 
     This second component should also have surfactant properties and act as a non-ionic surfactant with an HLB value ranging from about 2 to 8. 
     For a discussion of the solubility parameters, see C.R.C. Handbook of Solubility Parameters and Other Cohesion Parameters, Allan F. M. Barton, 1983, Table 9, p. 167-170. 
     DESCRIPTION OF THE PREFERRED EMBODIMENT 
     As used herein, the term &#34;agriculturally active chemical&#34; includes compounds and mixtures thereof which can be used as agricultural fertilizers, nutrients, plant growth accelerants, herbicides, plant growth controlling chemicals, and chemicals which are effective in killing plants, insects, microorganisms, fungi, bacteria and the like which are commonly referred to as insecticides, bactericides, fungicides, nematocides, fumigants, and the like, as well as any other chemicals having properties which are suitable for agricultural uses in terms of application to plants or domestic uses for controlling insects and pests. Particularly, such chemicals would normally take the form of water-immiscible or oily liquids and/or solids which is substantially insoluble in water. By the term &#34;substantially insoluble&#34;, it is meant that for all practical purposes, the solubility of the compound in water is insufficient to make the compound practicably usable in an agricultural end use without some modification either to increase its solubility or dispersability in water, so as to increase the compound&#39;s bioavailability or avoid the use of excessively large volumes of solvent. 
     Suitable agriculturally active chemicals which can be used with the present invention include insecticides, such as, cyclocompounds, carbamates, animal and plant derivatives, synthetic pyrethroids, diphenyl compounds, non-phosphates, organic phosphates, thiophosphates, and dithiophosphates. (See Agricultural Chemicals, Book I, Insecticides, 1989 Revision by W. T. Thomson, Thomson Publications.) Typical of the insecticides are: 
     
         ______________________________________                                    
cyclocompounds:                                                           
             6,7,8,9,10,10-hexachloro-                                    
             1,5,5a,6,9,9a-hexahydro-6,9-methano-                         
             2,4,3-benzodioxathiepin-3-oxide                              
carbamates:  2-isopropyl phenyl-N-methyl                                  
             carbamate;                                                   
             2-(1,3-dioxolan-2yl) phenylmethyl                            
             carbamate;                                                   
             2,3-isopropylidine dioxyphenyl                               
             methyl carbamate;                                            
animal and plant                                                          
             chlorinated hydrocarbons derived                             
derivatives: from Southern pine; naturally                                
             occuring lactone glycoside;                                  
synthetic    (±) α-cyano-3-phenoxybenzyl (±) cis,             
pyrethroids: trans 3-(2,2-dichlorovinyl)-2,2-di-                          
             methyl cyclopropane carboxylate;                             
             (±) cyano (3-phenoxyphenyl methyl                         
             (±)-4-(difluoromethyoxy) α-(-1-                     
             methylethyl) benzene acetate;                                
phenoxy compounds                                                         
             2,2-bis(p-methoxy phenyl)-1,1,1,tri-                         
and non-phosphate:                                                        
             chloroethane;                                                
             1,3,5,tri-n-propyl-1,3,5-triazine-                           
             2,4,6 (1H,3H,5H) trione;                                     
             ethyl (2E, 4E)-3,7,11-trimethyl-2,4-                         
             dodeca dienoate;                                             
             1-decycloxy 4-[(7-oxa-oct-4-ynyl)]-                          
             oxybenzene;                                                  
organic phosphates:                                                       
             dimethyl phophate ester of 3-hy-                             
             droxy-N,N-dimethyl-cis-crotonamide;                          
             2-chloro-1-(2,4-dichloro phenyl)                             
             vinyl diethylphosphate;                                      
             4-(methyl thio) phenyl dipropyl                              
             phosphate;                                                   
thiophosphates:                                                           
             0,0-diethyl-0-4-nitrophenyl phos-                            
             phorothioate;                                                
             0,0-diethyl-0-(2,isopropyl-6-methyl-                         
             5-pyrimidinyl) phosphorothioate;                             
             2-diethylamino-6-methyl pyrimidine-                          
             4-yl dimethyl phosphorothioate;                              
dithiophosphates:                                                         
             0,0-dimethyl phosphorodithioate                              
             ester of diethylmercapto succinate                           
             0-ethyl-S-phenyl ethyl phosphorodi-                          
             thioate.                                                     
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     Typical herbicides include phenoxy compounds, benzoic, acetic, and phthalic acids, aniline derivatives, nitriles, amides acetamides, anilides, carbamates, thiocarbamates, and heterocyclic nitrogen derivatives, e.g., triazines, pyridines, pyridazones, picolinic acid, and urea derivatives and phosphates. (See Agricultural Chemicals, Book II, Herbicides, 1986-87 Edition, W. T. Thomson, Thomson Publications, Fresno, Calif. 93791.) Exemplary of the above compounds are: 
     
         ______________________________________                                    
phenoxy compounds:                                                        
             2,4-Dichlorophenoxy acetic acid                              
             2,4,5-trichloro phenoxyacetic acid;                          
             4-(2,4-dichlorophenoxy) butyric                              
             acid;                                                        
             S-ethyl 2 methyl-4-chlorophenoxy-                            
             thioacetate;                                                 
             2-methyl-4-chloro-phenoxy acetic                             
             acid;                                                        
             methyl 5-(2,4-dichloro-phenoxy)-2-                           
             nitrobenzoate;                                               
benzoic and acetic                                                        
             3,6-dichloro-o-anisic acid                                   
acids of phthalic                                                         
             4-chloro-2-oxo benzothiazolin-3-yl                           
compounds:   acetic acid;                                                 
             N-1-Naphthyl-phthalamic acid;                                
nitriles and aniline                                                      
             3-5-dibromo-4-hydroxybenzo-nitrile;                          
derivatives: α,α,α,trifluoro-2,6-dinitro-N,             
             N-dipropyl-p-tolinidine;                                     
             N-(1-ethylpropyl)-2,6-dinitro-3,4-                           
             xylidine;                                                    
amides, acetamides,                                                       
             N,N-diethyl-2-(1-naphthalenyl oxy)-                          
anilides:    propionamide;                                                
             2,6-dimethyl-N-2&#39; methoxy-ethyl-                             
             chloro-acetanilide;                                          
             3&#39;,4&#39;-dichloro-propionanilide;                               
             α-chloracetic-N-(3,5,5-trimethyl-                      
             cyclohexen-1-yl)-N-isopropylamide;                           
             4-benzyl-N-isopropyl trimethyl                               
             acetamide;                                                   
thiocarbamates:                                                           
             S-Ethyl dipropyl thiocarbamate;                              
urea derivatives:                                                         
             3-(5-tert-butyl-3-isoxazoyl)-1,1-                            
             dimethyl urea;                                               
             N-(2,6-trifluoro-benzoyl)-N&#39;-[2,5-                           
             dichloro-4-(1,1,2,3,3,3-hexafluoro-                          
             propyloxy) phenyl] urea;                                     
pyrrolidone  1-(m-trifluoro methyl phenyl)-3-                             
derivatives: chloro-4-chloromethyl-2-pyrrolidone;                         
amino acid   methyl N-benzoyl-N-(3-chloro-4-                              
derivatives: fluorophenyl)-DL alarinate;                                  
             N-chloroacetyl-N-(2,6-diethyl                                
             phenyl)-glycine ethyl ester;                                 
carbamates:  Isopropyl-m-chlorocarbanilate;                               
             3-Ethoxy (carbonyl aminophenyl)-N-                           
             phenyl carbamate;                                            
heterocyclics:                                                            
             4-amino-3,5-dichloro-6-fluoro-2-                             
             pyridyloxy acetic acid;                                      
             4-(1,2-Dimethyl-N-propyl amino)-2-                           
             ethyl amino-6-methyl thio-S-                                 
             triazine;                                                    
             2-[4,5-dihydro 4-methyl-4-(1-methyl                          
             ethyl)-5-oxo-1 H-imidazoyl-2yl-3-                            
             byridinecarboxylic acid;                                     
             2-[3,5-dichlorophenyl)-2-(2,2,2-                             
             trichloroethyl) oxinane;                                     
             Butyl-9-hydro-fluorene-(9)-                                  
             carboxylate;                                                 
             2-[1-(ethoxy imino) butyl]-3-                                
             hydroxy-5-(2H-tetra hydro thiopyran-                         
             3-yl)-2-cyclohexene-ione;                                    
             2-(2 chlorophenyl) methyl-4,4-                               
             dimethyl-3-iso oxazolidinone;                                
phosphates:  0-ethyl-0-(3-methyl-6-nitro phenyl)                          
             N-sec-butyl phosphoro thio amidate.                          
______________________________________                                    
 
    
     Typical fungicides include (See Agricultural Chemicals, Book IV, Fungicides, 1989 Revision, W. T. Thomson, Thomson Publications, Fresno, Calif. 93791): 
     
         ______________________________________                                    
organic compounds:                                                        
             2,5-dimethyl-N-Cyclohexyl-N-methoxy-                         
             3-furan carboxamide;                                         
             5-Ethyoxy-3-trichloromethyl-1,2,4-                           
             thiadiazole;                                                 
             3-(2-methyl piperidino) propyl 3,4-                          
             dichlorobenzoate;                                            
             N,N&#39;-(1,4-piperazinediyl bis (2,2,2-                         
             trichloro) ethylidene) bis                                   
             formamide;                                                   
             Tetramethyl thiuram disulfide:                               
             0-Ethyl-S,S,diphenyl-dithiophos-                             
             phate;                                                       
             5,10-dihydro-5,10-dioxo naphtho                              
             (2,3,9)-p-dithiin-2,3-dicarbo-                               
             nitrile;                                                     
             2-(Thiocyano methyl thio) benzothia-                         
             zole;                                                        
             α-2-(4-chlorophenyl) ethyl]-α-(1,1-              
             dimethyl ethyl)-1 H-1,2,4-triazole-                          
             1-ethanol;                                                   
morpholines: N-tridecyl-2,6-dimethyl morpholine;                          
             4-N-dodecyl-2,6-dimethyl morpholine;                         
______________________________________                                    
 
    
     Typical fumigants, growth regulators, repellants, and rodenticides include (See Agricultural Chemicals, Book III, Fumigants, 1988-1989 Revision, W. T. Thomson, Thomson Publications, Fresno, Calif. 93791): 
     
         ______________________________________                                    
growth regulants:                                                         
              1,2 Dihydro-6-ethyoxy-2,2,4-tri-                            
              methylquinoline;                                            
              (2-chloroethyl) phosphoric acid;                            
              4-[acetamino) methyl]-2-chloro-N                            
              (2,6-diethyl phenyl acetamide;                              
              Benzoic acid, 3,6 dichloro-2-                               
              methoxy,2-ethoxy-1-methyl-2-oxo                             
              ethyl ester;                                                
repellants:   0,0-dimethyl-0-[(4-methyl thio)-m-                          
              tolyl] phosphorothioate;                                    
              Tetriary butyl-sulfenyl dimethyl                            
              dithio carbamate;                                           
seed softener:                                                            
              2-chloro-6-(trichlomethyl) pyridine;                        
              5-ethoxy-3-trichloromethyl-1,2,4-                           
              thiadiazole;                                                
              N-phenyl-N&#39;-1,2,3-thiadiazol-5-yl                           
              urea;                                                       
______________________________________                                    
 
    
     Pesticides may be characterized by their physical properties, depending on their physical state at normal or ambient conditions, i.e., between 40° F. and 90° F. and their solubility or miscibility with water or other common organic solvents, e.g., aromatics, such as, toluene, xylene, methylated and polyalkylated naphthalenes, and aliphatic solvents. 
     Based on the physical properties, the pesticides may be classified into two groups. The first group includes those which are oily liquids at ambient temperatures and are immiscible with water. Specific pesticides include: 
     Common esters of 2,4-dichlorophenoxyacetic acid, 
     Common esters of 2,4,5-trichlorophenoxyacetic acid, 
     Common esters of 2-(2,4-dichlorophenoxy) propionic acid, 
     Common esters of 2-(2,4,5-trichlorophenozy) propionic acid, 
     Common esters of 2,4-dichlorobutyric acid, 
     Common esters of 2,methoxy-3,6-dichlorobenzoic acid, 
     Common esters of 2-methyl-4-chlorophenoxyacetic acid, 
     Piperonyl butoxide 3,4-methylenedioxy-6-propyl benzyl n-butyl diethylene glycol ether, 
     Bromophos ethyl: 0,0-diethyl-0-2,5-dichloro-4-bromophenyl thionophosphate, 
     N-(2-mercaptoethyl) benzene-sulfenamide (BETASAN®), 
     Isobornyl Thiocyanoacetate (Thanite®), 
     Ioxynil ester of octanoic acid, 
     Molinate S-ethyl hexahydro - 1 H - azepine-1-carbothioate, 
     PP 511 0,0-dimethyl-(2-diethylamine 4-methyl-6-pyrimidinyl) carbamate, 
     PP 211 0,0-diethyl 0-(2-diethylamine-4-methyl-6-pyrimidinyl) phosphorocarbamate, Chlordane 
     5-Ethoxy-3-(trichlorometyl)-1,2,4-thiadiazole (TERRAZALE®), 
     Ethyl-s-s-dipropyl-phosphodithioate (MOCAP®), 
     S-Ethyl dipropylthiocarbamate (EPTAM®), 
     S-Ethyl diisobutylthiocarbamate (SUTAN®), 
     S-n. propyl-di-n-propylthiocarbamate (VERNAM®), 
     S-propyl butylethylthiocarbamatae (TILLAM®), 
     S-ethyl ethylcyclohexylthiocarbamate (RO-NEET®), 
     Malathion (S-(1,2-dicarboxyethyl)-0,0-dimethyl phosphorodithioate), 
     Diazinon (0,0-diethyl,0-(2-isopropyl-4-methyl-6-pyrimidinyl) phosphorothioate, 
     O-Ethyl-S-phenyl-ethylphosphonodithioate (DYFONATE®), Toxaphene (Octachlorocamphene), 
     Bromoxynil (3,5-dibromo-4-hydroxy benzonitrile ester of n.octanoic acid, 
     2-chloro-N-2,6-diethylphenyl-N-methoxymethylacetamide (LASSO®), 
     Diallate S-2,3-dichloroallyl N,N-diisopropylthiolcarbamate, Triallate S-2,33-trichloroallyl N,N-diisopropylthiolcarbamate. 
     The second group comprises those pesticides which are solids at ambient temperatures and for all practical purposes, insoluble in water. 
     2,4,5-T (2,4,5-trichlorophenoxy acetic acid) 
     Monuron (3-(p-chlorophenyl)-1,1-dimethyl urea) 
     Diuron (3-(3,4-dichlorophenyl)-1,1-dimethyl urea) 
     Bromacil (5 bromo-3-sec. butyl-6-methyl uracil) 
     Isocil (5 bromo-3-isopropyl-6-methyl uracil) 
     Linuron (3-(3,4 dichlorophenyl)-1-methoxy-1 methyl urea 
     Atrazine (2-chloro-4-ethylamino-6 isopropylamino-s-trriazine) 
     Simazine (2-chloro-4,6,-bis (ethylamino)-s-triazine 
     Dodine (n-dodecylguanidine acetate) 
     Thiram (tetramethylthiuram disulfide) 
     N-(mercaptomethyl)phthalimide s-(o,o dimethylphosphorodithioate) (IMIDAN®) 
     Lindane (gamma 1,2,3,4,5,6 hexachlorocyclohexane) 
     Folpet (N-trichloromethylphthalimide) 
     Manazon (s-(4,6-diamino-1,3,5-triazin-2-yl methyl)dimethyl phosphorothiolthionate) 
     Barban (4-chloro-2 butynyl m-chlorocarbanilate) 
     Tricumba 2-methoxy-3,5,6-trichlorobenzoic acid 
     Trifluralin (2,6-dinitro-N,N-dipropyl-4-trifluoromethylamiline) (2,3 dihydro-5-carboxanilido-6-methyl-1,4-oxathiin) (VITAVAX®) 
     2,4-dichlorophenoxyacetic acid 
     4-(4-chloro-2 methylphenoxy) butyric acid 
     2-(2,4-dichlorophenoxy) propionic acid 
     Ioxynil: 3,5 diiodo-4-hydroxybenzonitrile 
     Bromoxynil: 3,5 dibromo-4-hydroxybenzonitrile 
     Carbaryl: 1-naphthyl-N-methylcarbamate 
     Methoxychlor: 2,2,-Bis(p-methoxyphenyl)-1,1-trichloroethane 
     PP 781: 4(2-chloro phenylhydrazono)-3-methyl-5-isoxazolone* 
     PP 675: 5-butyl-2-dimethylamino-4-hydroxy-6-methyl pyrimidine* 
     PP 062: 5,6-dimethyl-2-dimethylamino-4 pyrimidinyl dimethylcarbamate* 
     PP 149: 5-n-butyl-2 ethylamino-4-hydroxy-6 methylpyrimidine* 
    
     C 6313 N&#39;-(4-bromo-3-chlorophenyl)-N-methoxy-N-methylurea 
     C 6989 2,4&#39;dinitro-4-trifluoromethyl-diphenylether 
     Chloroxuron N&#39;-4-(chlorophenoxy) phenyl-NN-dimethylurea 
     Dichlobenil 2,6-dichlorobenzonitrile 
     Diphenamid NN-dimethyl-2,2-diphenylacetamide 
     Fenac 2,3,6-trichlorophenylacetic acid 
     Fluometuron N&#39;-(3-trifluoromethylphenyl)-NN-dimethylurea 
     GS 14260 4-ethylamino-2-methylthio-6-t-butyl-amino-1,3,5-triazine 
     PCP Pentachlorophenol 
     Lenacil 3-cyclohexyl-6,7-dihydro-1H-cyclo-pentapyrimidine-2,4-(3H,5H)-dione 
     Pyrazon 5-amino-4-chloro-2-phenyl-3-pyridazone 
     Metrobromuron N&#39;-(4-bromophenyl)-N-methoxy-N-methylurea 
     Metoxymarc N-(4-methoxybenzoyl)-N-(3,4-dichlorophenyl)-N&#39;,N&#39;-dimethylurea 
     Neburon N-butyl-N&#39;-(3,4-dichlorophenyl-N-methylurea 
     NIA 11092 1,1-dimethyl-3-[3-(n-t-butyl carbamyloxy)phenyl] urea 
     Mecoprop 2-(4-chloro-2 methylphenoxy)propionic acid 
     Monolinuron N&#39;-(4-chlorophenyl)-N-methoxy-N-methylurea 
     Nitrofen 2,4-dichlorphenyl 4-nitrophenylether 
     Propanil N-(3,4-dichlororphenyl)propionamide 
     Pyriclor 2,3,5-trichloro-4-pyridinol 
     Solan 3&#39;-chloro-2-methyl-p-volerotoluidide 
     Terbacil 5-chloro-3-t-butyl-6-methyluracil 
     UC 22463 (SIRMATE)-3,4-dichlorobenzyl N-methylcarbamate 
     WL 9385 2-Azido-4-ethylamino-6-t-butylamino-s-triazine 
     Propachlor 2-chloro-N-isopropylacetanilide 
     CP 50144 2-chloro-N-2,6-diethylphenyl-N-methoxymethylacetamide 
     CP 31675 2-chloro-N-(2 methyl-6-t-butylphenyl)acetamide 
     Cypromid 3&#39;,4&#39;-dichlorocyclopropane carboxanilide 
     Fenuron NN-dimethyl-N&#39;phenylurea 
     Chlorbromuron N&#39;-(4-bromo-3-chlorophenyl)-N-methoxy-N-methylurea 
     Ametryne 2-methylmercapto-4-ethylamino-6-isopropyl-amino-s-triazine 
     Prometryne 2-methylmercapto-4,6-bisisopropyl amino-s-triazine 
     DCPA dimethyl 2,3,5,6, tetrachloroterephthalate 
     Benefin N-butyl-N-ethyl-2,2,2-trifluoro-2,6-dinitro-p-toluidine 
     Nitralin 2,6-dinitro-4-methylsulfonyl-NN-dipropyl-aniline 
     PP 493 2,6-difluoro-3,5-dichloro-4-hydroxy pyridine 
     CNP 2,4,6-trichlorophenyl-4&#39;-nitrophenyl ether 
     Pentachloro nitrobenzine 
     1-(butile carbamoyl)-2-benzimidazol carbamic acid, methyl ester (BENLATE®) 
     Typical examples of first components suitable for use in the solvent are alkylpyrrolidones having from 1 to 4 carbon atoms in the alkyl group, cyclic lactones, e.g., gamma-butyrolactone, lower alkyl cyclic carbonates, i.e., ethylene carbonate, propylene carbonate, butylene carbonate, lower akylimidazolone, e.g., N-N,dimethylimidazolone, lower alkylamides of formic acid and acetic acid, e.g., dimethyl formamide and dimethylacetamide, and lower alkyl sulfoxides, e.g., dimethylsulfoxide. (The term &#34;lower alkyl&#34; in these examples means one or two carbons.) Mixtures of these may also be used as the first component. 
     Examples of appropriate second components include alkylpyrrolidones having an alkyl portion containing from 6 to 14 carbon atoms, e.g., octylpyrrolodone, dodecylpyrrolidone, or N-(2&#39;-ethylhexylpyrrolidone), alkyl gamma-butyrolactones, alkyl cyclic carbonates and combinations thereof, wherein the alkyl chains contain from 6 to 14 carbon atoms. The alkyl portion may be distributed at one or more sites on the ring so long as one portion contains at least 6 carbon atoms and the total number of alkyl carbon atoms does not exceed 14. For each of the above examples, the 6 to 14 carbon alkyl portions may be straight or branched. 
     Preferably, the first component is selected from the group consisting of pyrrolidones having the formula ##STR2## wherein R is hydrogen or lower alkyl having from 1 to 4 carbon atoms and R 1  is lower alkyl having from 1 to 4 carbon atoms. 
     The second component is preferably selected from pyrrolidones having the formula ##STR3## wherein R 2  is hydrogen or alkyl having from 6 to 14 carbon atoms and R 3  is alkyl having from 6 to 14 carbon atoms with the proviso that at least one of R 2  or R 3  must contain at least 6 carbon atoms and the sum of the carbon atoms in R 2  and R 3  cannot exceed 14. 
     The inventive composition further comprises an organic diluent which is a synthetic or naturally occurring oils having a high hydrophobic character or having a fractional dispersive solubility parameter of greater than 70% and preferably greater than 85% and a molar volume of greater than 90 cm 3  /mole. These properties are defined in the C.R.C. Handbook referred to hereinabove. Typical diluents include soybean oil, rapeseed oil, long chain alcohols, long chain ketones, long chain esters, and ethers. As used herein, &#34;long chain&#34; means with 6 or more carbon atoms. Also suitable as the organic diluent are aromatic petroleum oils including those which are commercially available distillates from crude oils having an average boiling point greater than 200° C. Typical of such materials are those sold under the trademarks Exxon 200 or Texaco 400. Of course, such aromatics should be approved for use as a carrier for agriculturally active chemicals. 
     The composition of the aromatic petroleum oil is generally: 
     Heavy aromatic solvent naphtha--about 60%; 
     Middle distillate solvent extractant--about 40%. 
     Normally, these oils contain predominantly the C 9  -C 15  aromatic hydrocarbons and primarily the C 10  -C 12  hydrocarbons having a flash point of about 203° F. 
     In the inventive composition, the amount of solvent is in the range from about 20 to 90%, and the amount of diluent is about 80 to 10%, based on the weight of solvent and diluent in the composition. With respect to the so)Vent, the amount of the first component is from about 5 to 95%, and preferably, 20 to 80%; and the amount of the second component is from about 5 to 95%, and preferably, 20 to 80%, based on the weight of the solvent. 
     The inventive composition also contains one or more additional emulsifier or surfactant which is generally selected on a case by case basis in order to optimize the solubility and stability of the emulsion. Typically, such emulsifiers include ethoxylated alkyl phenols, linear aliphatic polyesters, linear aromatic polyesters, polyethoxylated alcohols, linear aliphatic ethoxylates, polyethoxylated castor oil, polyethoxylated carboxylates, and polyethoxylated alkylamines. Anionic surfactants may be used as the emulsifier and include phosphate esters and their salts, alkyl sulfonamides, salts of sulfated nonylphenoxypoly(ethyleneoxy) ethanol, salts of alkylbenzene sulfonates, salts of alkylnaphthalene sulfonate, and sulfonated aliphatic polyesters and their salts. Also suitable are complex phosphate esters of nonionic surfactants of the ethylene oxide type which are mixtures of diesters of phosphoric acid. (See, for example, McCutcheon&#39;s, Emulsifiers and Detergents (1989), published by McCutcheon&#39;s Division of M.C. Publishing Co., Glen Rock, N.J.) Generally, the amount of emulsifier (surfactant) is from about 1 to 25% based on the total weight of the composition. 
     The agriculturally active chemical (sometimes referred to herein as AAC) concentration should be as high as possible so long as it does not precipitate out upon dilution of the concentrate with water for a reasonable period of time and achieves the desired effect. With the present invention, it is possible to obtain concentrates with agriculturally active chemical concentrations in excess of 5 weight percent which form a stable emulsion upon being diluted with water. Depending on the particular agriculturally active chemical, the concentration of the AAC is from about 5 to 60% based on the total weight of the composition before dilution. 
    
    
     The following examples illustrate the present invention*: 
    
     EXAMPLE 1 
     A series of twelve compositions wherein the amount of a first pyrrolidone component (N-methylpyrrolidone), second pyrrolidone component (N-octylpyrrolidone) and aromatic solvent were varied using a surface-active agent from 14.3% to 22.2% by weight and agriculturally active chemical from 25.8% to 41.6% by weight. (See Table 1.) The surface-active agent was Gafac RE-610 (ethoxylated phosphate ester), and the agriculturally active chemical (AAC) was N-(1-ethylpropy)-2,6-dinitro-3,4-xylidine (PRL). 
     FORMULATIONS 
     Formulations were made by mixing together the components comprising of each composition by weighing the exact proportion of ingredients in a bottle. The solvents were weighed in first. The AAC was dissolved completely in the solvent system followed by addition of the wetting agent or emulsifying agent. Typically, about 20 g of each of the formulations was prepared. As an illustration, formulation #11 included in Table 1-2 was prepared by weighing together the following ingredients in a one ounce bottle: 
     
                       TABLE 1-1                                                   
______________________________________                                    
N-methylpyrrolidone 2.75 g  20.4%                                         
N-octylpyrrolidone  1.25 g  9.3%                                          
Aromatic Petroleum oil -                                                  
                    1.00 g  7.4%                                          
Exxon 200                                                                 
PRL                 5.50 g  40.7%                                         
(N-1 ethyl propyl)-2,6-                                                   
dinitro-3,4-xylidine                                                      
(92% Tech.)                                                               
Phosphate ester     3.00 g  22.2%                                         
(Gafac RE-610)                                                            
TOTAL:              13.50 g 100.0%                                        
______________________________________                                    
 
    
     The contents were stirred well in an automatic rocking shaker for about 30 minutes when the AAC dissolved completely. The samples thus prepared were evaluated for freeze-thaw stability on storage and ease of emulsification and emulsion stability on dilution. 
     FREEZE-THAW STABILITY 
     The concentrates were stored for a period of 24 hours in the cold (temperature 5° C.) in a refrigerator and taken out and thawed to room temperature and then stored at 55° C. in an oven for a period of 24 hours. The alternate storage in the cold (5° C.) and warm condition at 55° C. was repeated for three cycles. Any separation during the storage was recorded. A concentrate is &#34;stable&#34; if there is no substantial separation after the 24 hour cycles at each temperature. 
     Evaluation of Emulsion Stability and Ease of Emulsification 
     A Nessler tube (1.8 cm diameter; 28 cm long) was filled with appropriate quantity (47-48 g) of World Health Organization (WHO) standard (6 g of CaCl 2  and 2.78 g of MgCl 2  6H 2  O dissolved in 20L) hard water having a hardness of 342 ppm expressed as Na equivalent. Using a serological pipette, 0.5-2.5 g of emulsion concentrate was dropped into the Nessler tube containing 47.5-49.5 g water. The initial bloom was observed at zero time without stirring and the quality of the bloom was graded by visual appearance as shown below. The Nessler tube was stopped and inverted 20 times; the bloom was again recorded and so also stability as judged by volume or height of the sedimentation (cream/ppt/oil) followed at different intervals of time: 0, 1 hour, 2 hours, up to 24 hours. 
     Stability of Diluted Concentrate 
     The composition of the cencentrate (EC) diluted with water was considered &#34;stable&#34; if at EC concentrations of from 0.2 to 1%, the composition after mixing (twenty inversions) exhibited two mm or less cream and no oil in one hour. Both top and bottom should be checked. 
     
         ______________________________________                                    
Bloom:  Excellent Thick emulsion cloud with no                            
                  separation                                              
        Good      Emulsion cloud may be thin, or may                      
                  exhibit trailing, small number of oil                   
                  droplets within cloud                                   
        Poor      Many oil droplets within cloud, some                    
                  droplets separate from cloud                            
______________________________________                                    
 
    
     Each of the emulsifiable concentrates thus prepared were analyzed for ease of emulsification (bloom) upon addition of water and after twenty inversion of the sample as well as emulsion stability upon dilution with water. The composition of the samples are set forth in Table 1-2 and the results of the analysis are set forth in Table 1-3. The freeze-thaw stability was measured as follows: Compositions 1 through 7 included in Table 1-2 passed freeze-thaw stability test when stored at -10° C. to 55° C. for 3 cycles of 24 hour periods. Compositions 8 through 12 included in Table 1-2 passed freeze-thaw stability test when stored at 5° C. to 55° C. for 3 cycles of 24 hour periods. Formulations 11 showed maximum freeze-thaw stability with PRL at 40.7%. 
     
                                           TABLE 1-2                               
__________________________________________________________________________
Ingredient  1   2   3   4    5   6   7   8    9   10  11  12              
__________________________________________________________________________
N-methylpyrrolidone                                                       
            30.0                                                          
                33.0                                                      
                    0   30.0 24.0                                         
                                 60.0                                     
                                     0   18.2 22.2                        
                                                  29.7                    
                                                      20.4                
                                                          14.8            
(M-Pyrol)                                                                 
N-octylpyrrolidone                                                        
            30.0                                                          
                15.0                                                      
                    0   0    18.0                                         
                                 0   60.0                                 
                                         7.3  6.7 3.7 9.3 11.0            
(LP-100)                                                                  
Aromatic oil                                                              
            0   12.0                                                      
                    60.0                                                  
                        30.0 18.0                                         
                                 0   0   11.0 8.2 3.7 7.4 11.0            
(Exxon 200)                                                               
Gafac RE-610                                                              
            14.3                                                          
                14.3                                                      
                    14.3                                                  
                        14.3 14.3                                         
                                 14.3                                     
                                     14.3                                 
                                         21.9 22.2                        
                                                  22.2                    
                                                      22.0                
                                                          22.0            
PRL, 92% Tech.                                                            
            25.9                                                          
                25.9                                                      
                    25.8                                                  
                        25.8 25.8                                         
                                 25.8                                     
                                     25.8                                 
                                         41.6 40.7                        
                                                  40.7                    
                                                      40.7                
                                                          41.2            
Solvent ratio                                                             
M-pyrol     50  55  0   50   40  100 0   50   60  80  55  40              
LP-100      50  25  0   0    30  0   100 20   18  10  25  30              
Ar. Exxon 200                                                             
            0   20  100 50   30  0   0   30   22  10  20  30              
Water used for                                                            
            WHO WHO WHO WHO  WHO WHO WHO WHO  WHO WHO WHO WHO             
dilution                                                                  
hardness ppm                                                              
            342 342 342 342  342 342 342 342  342 342 342 342             
Concentration                                                             
            0.65                                                          
                0.65                                                      
                    0.65                                                  
                        0.65 0.65                                         
                                 0.65                                     
                                     0.65                                 
                                         0.83 0.83                        
                                                  0.83                    
                                                      0.83                
                                                          0.83            
of AAC (% in                                                              
diluted sample)                                                           
__________________________________________________________________________
 
    
     
                                           TABLE 1-3                               
__________________________________________________________________________
EMULSION STABILITY AND BLOOM CHARACTERISTICS                              
               Stability                                                  
               Thickness of                                               
Bloom          Separation                                                 
                      Separation after                                    
Bloom at After 20                                                         
               cream, oil or                                              
                      Mixing and standing for:                            
Zero Time                                                                 
         Inversions                                                       
               precipitation                                              
                      1    2    24                                        
*        **    at 0 time                                                  
                      hours                                               
__________________________________________________________________________
1  poor-fair                                                              
         excellent                                                        
                20 mm &lt;1 mm                                               
                           &lt;1 mm                                          
                                crystals                                  
               cream ppt        to the top                                
2  excellent                                                              
         excellent                                                        
               0      0    0    0                                         
   spont.                                                                 
3  excellent                                                              
         excellent                                                        
                2 mm   2 mm                                               
                            2 mm                                          
                                  2.5 mm                                  
4  excellent                                                              
         excellent                                                        
               &lt;1 mm  &lt;1 mm                                               
                            1 mm                                          
                                 1 mm                                     
5  excellent                                                              
         excellent                                                        
               0      0    0    0                                         
   spont.                                                                 
6  excellent                                                              
         excellent                                                        
               0      0    0    &lt;1 mm                                     
7  poor  excellent                                                        
                1 mm  &lt;1 mm                                               
                            1 mm                                          
                                 4 mm                                     
                                cream on                                  
                                bottom                                    
                                 4 mm                                     
                                oil on top                                
8  excellent                                                              
         excellent                                                        
               &lt;1 mm  trace                                               
                           trace                                          
                                trace                                     
9  excellent                                                              
         excellent                                                        
               0      0    0    trace                                     
10 excellent                                                              
         excellent                                                        
               trace  0    0    &lt;1 mm                                     
   spont.                                                                 
11 excellent                                                              
         excellent                                                        
               trace  0    0    trace                                     
   spont.                                                                 
12 excellent                                                              
         excellent                                                        
               &lt;1 mm  trace                                               
                           trace                                          
                                trace                                     
   spont.                                                                 
__________________________________________________________________________
 *The descriptions have the following meanings:                           
 poor-fair  emulsion produced between one and five minutes                
 excellent  emulsion produced after two seconds                           
 spontaneous  emulsion produced instantly                                 
 **excellent  complete emulsification obtained. Thick emulsion cloud with 
 no separation.                                                           
 **good  emulsion cloud may be thin, or may exhibit trailing, small number
 of oil droplets within cloud                                             
 **poor  many oil droplets within cloud, some droplets separate from cloud
 
    
     EXAMPLE 2 
     A second series of two experiments was carried out using the following formulation: 
     
                       TABLE 2-1                                                   
______________________________________                                    
1.         CGA (98% Tech.)   22.2%                                        
2.         N-methylpyrrolidone                                            
                             33.3%                                        
3.         N-octylpyrrolidone                                             
                             16.7%                                        
4.         Texaco Aromatic 400                                            
                             16.7%                                        
5.         Gafac RE-610 (GAF)                                             
                             11.1%                                        
                             100.0%                                       
______________________________________                                    
 
    
     This composition was prepared by weighing out the individual quantities of the ingredients and adding the anionic emulsifier (5) to the N-methylpyrrolidone, admixing the agriculturally active chemical to this mixture, adding the N-octylpyrrolidone to the resulting mixture, and finally, adding the aromatic diluent (4) and mixing the entire composition to make it uniform. The formulation thus prepared was clear. Samples of the formulation were stored at -10° C. and 55° C. for each of three 24 hr. periods. No precipitation nor separation of any of the ingredients was observed for the samples. 
     The concentrate thus prepared was diluted in a standard 37 cm×2 cm Nessler&#39;s tube using WHO standard water. Two dilutions of emulsifiable concentrate to water of 5:100 and 0.6:100 were prepared. The bloom characteristics and emulsion stabilities of each of these dilutions are set forth in Table 3. 
     
                       TABLE 2-2                                                   
______________________________________                                    
EMULSION STABILITY AND                                                    
BLOOM CHARACTERISTICS                                                     
             Formulation                                                  
             I.         II.                                               
______________________________________                                    
Conc. of active                                                           
               22%          22%                                           
Dilution:      2.5:47.5     0.3:49.8                                      
               (1/20)       (1/167)                                       
Water used for dilution                                                   
               WHO standard WHO standard                                  
               342 ppm      342 ppm                                       
Con. of active in the                                                     
               1.11%        0.13%                                         
diluted sample                                                            
Bloom at 0 time                                                           
               spontaneous  spontaneous                                   
After 20 inversions                                                       
               excellent    excellent                                     
Separation or Precipita-                                                  
tion after mixing and                                                     
standing for:                                                             
 1 hour        none         none                                          
 2 hours       none         none                                          
 4 hours       none         none                                          
10 hours       none         none                                          
24 hours       none         none                                          
______________________________________                                    
 
    
     EXAMPLE 3 
     A third series of experiments were carried out using the following compositions: 
     
                       TABLE 3-1                                                   
______________________________________                                    
                    3.I   3.II                                            
______________________________________                                    
1.     CGA (98% Tech)     20.4%   10.3%                                   
2.     N-methylpyrrolidone                                                
                          34.2%   38.5%                                   
3.     N-octylpyrrolidone 17.0%   19.2%                                   
4.     Soybean oil        17.0%   19.2%                                   
       (White Rose polyunsaturated                                        
       vegetable oil)                                                     
5.     Gafac E-610 (GAF)  11.4%   12.8%                                   
                          100.0%  100.0%                                  
______________________________________                                    
 
    
     The compositions were prepared by weighing out individual ingredients 1 through 4 and dissolving the anionic emulsifier (5) in the admixture. The entire composition was mixed in an automatic rocking shaker to obtain a uniform and clear composition. Samples of the formulations I and II were stored at -10° C. and 55° C. for each of three 24 hour periods. No separation or precipitation of any ingredients was observed in the two samples. The concentrates thus obtained were each diluted in a standard 37 cm×2 cm Nessler&#39;s tube with two different diluents. In one case, the diluent was deionized water and in the other case, acetic acid at pH 2.5. Two dilutions of emulsifiable concentrate to diluent at 1:20 and 1:66 were prepared for each diluent. The bloom characteristics and emulsion stabilities of each of these dilutions are set forth in Table 4. 
     
                                           TABLE 3-2                               
__________________________________________________________________________
EMULSION STABILITY AND BLOOM CHARACTERISTICS                              
       Formulation                                                        
       I      II     III    IV     V      VI     VII    VIII              
__________________________________________________________________________
Emulsifiable                                                              
       3.I    3.I    3.II   3.II   3.I    3.I    3.II   3.II              
concentrate                                                               
used                                                                      
conc. of AAC                                                              
       20.4%  20.4%  10.3%  10.3%  20.4%  20.4%  10.3%  10.3%             
water used                                                                
       deionized                                                          
              deionized                                                   
                     deionized                                            
                            deionized                                     
                                   acetic acid at pH 2.5                  
for dilution                                                              
       water  water  water  water                                         
dilution                                                                  
       2.5/50 0.3/50 2.5/50 0.3/50 2.5/50 0.3/50 2.5/50 10.3/50           
factor                                                                    
conc. in the                                                              
       1.02%  0.12%  1.02%  0.12%  1.02%  0.12%  1.02%  0.12%             
diluted                                                                   
sample                                                                    
Bloom  spontaneous                                                        
              spontaneous                                                 
                     spontaneous                                          
                            spontaneous                                   
                                   spontaneous                            
                                          spontaneous                     
                                                 spontaneous              
                                                        spontaneous       
before mixing                                                             
       Excellent                                                          
              Excellent                                                   
                     Excellent                                            
                            Excellent                                     
                                   Excellent                              
                                          Excellent                       
                                                 Excellent                
                                                        Excellent         
after 20                                                                  
       Excellent                                                          
              Excellent                                                   
                     Excellent                                            
                            Excellent                                     
                                   Excellent                              
                                          Excellent                       
                                                 Excellent                
                                                        Excellent         
inversions                                                                
separation                                                                
after mixing                                                              
and standing                                                              
for:                                                                      
30 min.                                                                   
       *      *      *      *      yes, &lt;1 mm                             
                                          none   none   none              
 1 hour                                                                   
       none   none   none   none   *      none   none   1 mm oil          
 2 hour                                                                   
       yes, 1-2 mm                                                        
              none   none   none   *      none   none   *                 
 3 hour                                                                   
       *      *      *      *      *      1 mm   1 mm   *                 
 4 hour                                                                   
       yes    yes, 1-2 mm                                                 
                     none   none   *      *      *      *                 
 5 hour                                                                   
       yes    yes    yes    yes    *      *      *      *                 
__________________________________________________________________________
 *Not measured.                                                           
 
    
     The above experiment was performed for evaluation of the formulation to be used as a direct feed to host animals as an insecticide. The compositions 3.I and 3.II were also diluted with soybean oil to result in 1000 ppm in AAC and did not form any ppt or separation. Thus, the formulation could be fed to the host animal (dogs) as is, or as a diluted sample in vegetable oil, e.g. soybean oil. 
     EXAMPLE 4 
     Use of N-octylpyrrolidone and N-dodecylpyrrolidone in combination. 
     A fourth series of experiments were carried out using the following five compositions: 
     
                       TABLE 4-1                                                   
______________________________________                                    
           4.1   4.2     4.3     4.4   4.5                                
______________________________________                                    
1. N-methylpyrroli-                                                       
             33.0%   33.0%   33.0% 33.0% 33.0%                            
   done                                                                   
2. N-octylpyrrolidone                                                     
             0%      10.0%   5.0%  7.5%  15.0%                            
3. N-dodecylpyrroli-                                                      
             15.? %  5.0%    1.0%  7.5%  0%                               
   done                                                                   
4. Aromatic petroleum                                                     
             12.%    12.0%   12.%  12.0% 12.0%                            
   oil - Exxon-200                                                        
5. Gafac RE-610                                                           
             14.2%   14.2%   14.2% 14.2% 14.2%                            
   (GAF)                                                                  
6. PRL (same as in                                                        
             25.8%   25.8%   25.8% 25.8% 25.8%                            
   Example 1):                                                            
   92% Tech                                                               
______________________________________                                    
             100.0%  100.0%  100.0%                                       
                                   100.0%                                 
                                         100.0%                           
______________________________________                                    
 
    
     The compositions were prepared as explained in Example 1. Each of the emulsified concentrates thus prepared was analyzed for ease of emulsification and emulsion stability as explained under Example 1. Results are summarized in Table 4-2. These formulations passed three cycles of freeze-thaw between -10° C. and 55° C. 
     
                                           TABLE 4-2                               
__________________________________________________________________________
EMULSION STABILITY AND BLOOM CHARACTERISTICS                              
           Formulation                                                    
           I    II   III  IV   V                                          
__________________________________________________________________________
Emulsifiable                                                              
           4.1  4.2  4.3  4.4  4.5                                        
concentrate used                                                          
conc. of AAC                                                              
           25.8%                                                          
                25.8%                                                     
                     25.8%                                                
                          25.8%                                           
                               25.8%                                      
water used for                                                            
           WHO 342 ppm hardness                                           
dilution                                                                  
dilution factor                                                           
           1.2/48.8                                                       
                1.2/48.8                                                  
                     1.2/48.8                                             
                          1.2/48.8                                        
                               1.2/48.8                                   
conc. of CGA in                                                           
           0.6% 0.6% 0.6% 0.6% 0.6%                                       
diluted sample                                                            
Bloom before mixing                                                       
           Fair Excellent                                                 
                     Fair Excellent                                       
                               Excellent                                  
Bloom after                                                               
           Excellent                                                      
                Excellent                                                 
                     Excellent                                            
                          Excellent                                       
                               Excellent                                  
20 inversions                                                             
separation after mixing                                                   
and standing for:                                                         
 1 hour    &lt;1 mm                                                          
                0    Trace                                                
                          0    Trace                                      
 2 hour     1 mm                                                          
                0    Trace                                                
                          0    Trace                                      
 3 hour     1 mm                                                          
                0    &lt;1 mm                                                
                          0    Trace                                      
24 hour     2 mm                                                          
                0     1 mm                                                
                          0    Trace                                      
__________________________________________________________________________
 
    
     EXAMPLE 5 
     Tank Mix Compatibility 
     A formulation containing 16.6% of the ammonium salt of 2-[4,5-dihydro-4-methyl-4-(1-methyl ethyl)-5 OXO-1 H-imidazol-2-yl]-3 quinoline carboxylic acid, (referred to herein as SCP) in the water was prepared by dissolving an appropriate quantity of the free acid in an ammonium hydroxide solution containing a stoichiometric amount of the base. The final pH was adjusted to 7.2. It is customary to use the PRL of Example 1 in conjunction with SCP in the ratio of 6:1 for better weed control. The following experiment demonstrates the compatibility of different AAC&#39;s in the composition of the invention. 
     Formulations 4.1, 4.2, 4.3, 4.4, and 4.5 were diluted as shown in Example 4 and summarized in Table 4-2, except that 0.5 g of SCP (16.6%) was also added to the water. The effect on stability and emulsion bloom from the two AAC&#39;s present are summarized in Table 5-1. 
     
                                           TABLE 5-1                               
__________________________________________________________________________
EMULSION STABILITY AND BLOOM CHARACTERISTICS                              
Mixed AAC&#39;s-Tank Mix Capability                                           
Formulation                                                               
           I    II   III  IV   V                                          
__________________________________________________________________________
Emulsifiable                                                              
           4.1  4.2  4.3  4.4  4.5                                        
concentrate used                                                          
(Example 4)                                                               
conc. of AAC                                                              
           25.8%                                                          
                25.8%                                                     
                     25.8%                                                
                          25.8%                                           
                               25.8%                                      
(Example 1)                                                               
water used for                                                            
           WHO 342 ppm hardness                                           
dilution                                                                  
conc. of PRL-SCP                                                          
           1.05%                                                          
                1.05%                                                     
                     1.05%                                                
                          1.05%                                           
                               1.05%                                      
in diluted sample                                                         
conc. of PRL                                                              
           1.00%                                                          
                1.00%                                                     
                     1.00%                                                
                          1.00%                                           
                               1.00%                                      
in diluted sample                                                         
conc. of SCP                                                              
           0.5% 0.5% 0.5% 0.5% 0.5%                                       
in diluted sample                                                         
Bloom at 0-time                                                           
           Excellent                                                      
                Excellent                                                 
                     Excellent                                            
                          Excellent                                       
                               Excellent                                  
before mixing                                                             
Bloom after                                                               
           Excellent                                                      
                Excellent                                                 
                     Excellent                                            
                          Excellent                                       
                               Excellent                                  
20 inversions                                                             
separation after mixing                                                   
and standing for:                                                         
 1 hour    &lt;2 mm                                                          
                &lt;2 mm                                                     
                     &lt;1 mm                                                
                          1 mm 2 mm                                       
 3 hour     2 mm                                                          
                 4 mm                                                     
                      1 mm                                                
                          2 mm 4 mm                                       
18 hour     2 mm                                                          
                 4 mm                                                     
                      2 mm                                                
                          2 mm 4 mm                                       
__________________________________________________________________________
 
    
     Conclusion 
     Use of the two component system of the invention is advantages compared to using either component alone in terms of ACC stability. 
     EXAMPLE 6 
     Tank mix compatibility was also demonstrated by making the following formulations using PRL and a freezed-dried SCP. The following formulation was prepared as explained in Example 1. 
     
                                           TABLE 6-1                               
__________________________________________________________________________
              6.1  6.2  6.3  6.4  6.5                                     
__________________________________________________________________________
1. N-methylpyrrolidone                                                    
              35.3%                                                       
                   35.3%                                                  
                        35.3%                                             
                             35.3%                                        
                                  35.3%                                   
2. N-octylpyrrolidone                                                     
              16.1%                                                       
                   12.0%                                                  
                        8.0% 4.0% 0%                                      
3. N-dodecylpyrrolidone                                                   
              0%   4.0% 8.0% 12.0%                                        
                                  16.0%                                   
4. Aromatic petroleum                                                     
              12.8%                                                       
                   12.8%                                                  
                        12.8%                                             
                             12.8%                                        
                                  12.8%                                   
   oil-Exxon-200                                                          
5. Gafac RE-610 (GAF)                                                     
              9.2% 9.2% 9.2% 9.2% 9.2%                                    
6. PRL: 92% Tech                                                          
              23.0%                                                       
                   23.0%                                                  
                        23.0%                                             
                             23.0%                                        
                                  23.0%                                   
7. SCP        3.7% 3.7% 3.7% 3.7% 3.7%                                    
   (See Example 6A)                                                       
              100.0%                                                      
                   100.0%                                                 
                        100.0%                                            
                             100.0%                                       
                                  100.0%                                  
__________________________________________________________________________
 
    
     The formulations shown in Example 6, i.e., 6.1 through 6.5 were diluted and the emulsion bloom and stability were evaluated as shown earlier. The results are summarized in Table 6-2. These formulations, i.e., 6.1 through 6.5, passed three cycles of freeze-thaw at 5° C. to 55° C. 
     EXAMPLE 6A 
     16.8 g of SCP 97.4% Tech. were stirred with 52 ml in ammonium hydroxide until complete solution resulted. The sample was filtered over a Whatman #4 filter under suction. The filtrate was freeze-dried at 80° C. and ≦1000 milliliter vacuum for a period of 24 hours. 
     
                                           TABLE 6-2                               
__________________________________________________________________________
EMULSION STABILITY AND BLOOM CHARACTERISTICS                              
Formulation                                                               
           I     II    III   IV    V                                      
__________________________________________________________________________
Emulsifiable                                                              
           6.1   6.2   6.3   6.4   6.5                                    
concentrate used                                                          
conc. of PRL                                                              
           23.0% 23.0% 23.0% 23.0% 23.0%                                  
    SCP    3.7%  3.7%  3.7%  3.7%  3.7%                                   
water used for                                                            
           WHO 342 ppm hardness                                           
dilution                                                                  
dilution   2.5/47.5                                                       
                 2.5/47.5                                                 
                       2.5/47.5                                           
                             2.5/47.5                                     
                                   2.5/47.5                               
factor                                                                    
conc. of PRL                                                              
           1.15% 1.15% 1.15% 1.15% 1.15%                                  
in diluted sample                                                         
conc. of SCP                                                              
           0.185%                                                         
                 0.185%                                                   
                       0.185%                                             
                             0.185%                                       
                                   0.185%                                 
in diluted sample                                                         
Bloom upon Good  Good  Good  Fair  Excellent                              
addition                                                                  
Bloom after                                                               
           Excellent                                                      
                 Excellent                                                
                       Excellent                                          
                             Excellent                                    
                                   Excellent                              
20 inversions                                                             
separation 4 mm  4 mm  4 mm  4 mm  2 mm                                   
before mixing                                                             
separation after mixing                                                   
and standing for:                                                         
 1 hour    4 mm  4 mm  2 mm  2 mm  2 mm                                   
 4 hour    4 mm  4 mm  2 mm  2 mm  3 mm                                   
18 hour    4 mm  4 mm  2 mm  2 mm  3 mm                                   
__________________________________________________________________________
 
    
     Formulations 6.3 and 6.4 produced improved stability on dilution. The cream re-emulsified after 10 inversions and reappeared 15 minutes after the 10 inversions. 
     EXAMPLE 7 
     The following formulations 7.1 through 7.5 were prepared exactly as explained in Example 1, except that N 3 ,N 3 , di-N-propyl-2,3-dinitro-6-trifluoromethyl-M-phenylenediamine (PRO) was used. These formulations passed three cycles of freeze-thaw at 5° C. to 55° C. 
     
                                           TABLE 7-1                               
__________________________________________________________________________
              7.1  7.2  7.3  7.4  7.5                                     
__________________________________________________________________________
1  N-methylpyrrolidone                                                    
              34.7%                                                       
                   34.7%                                                  
                        34.7%                                             
                             34.7%                                        
                                  34.7%                                   
2. N-octylpyrrolidone                                                     
              15.8%                                                       
                   11.8%                                                  
                        7.9% 4.0% 0%                                      
3. N-dodecylpyrrolidone                                                   
              0%   4.0% 7.9% 11.8%                                        
                                  15.8%                                   
4. Aromatic petroleum                                                     
              12.6%                                                       
                   12.6%                                                  
                        12.6%                                             
                             12.6%                                        
                                  12.6%                                   
   oil-Exxon-200                                                          
5. Gafac RE-610 (GAF)                                                     
              10.6%                                                       
                   10.6%                                                  
                        10.6%                                             
                             10.6%                                        
                                  10.6%                                   
6. PRO: 94.7% Tech                                                        
              26.3%                                                       
                   26.3%                                                  
                        26.3%                                             
                             26.3%                                        
                                  26.3%                                   
              100.0%                                                      
                   100.0%                                                 
                        100.0%                                            
                             100.0%                                       
                                  100.0%                                  
__________________________________________________________________________
 
    
     The above formulations were diluted and the emulsion characteristics were evaluated as before. The results are summarized in Table 8. The results show that the use of dodecylpyrrolidone or a mixture of 75:25 N-dodecylpyrrolidone and N-octylpyrrolidone used as the second component resulted in better emulsion stability when compared to use of N-octylpyrrolidone alone. 
     
                                           TABLE 7-2                               
__________________________________________________________________________
EMULSION STABILITY AND BLOOM CHARACTERISTICS                              
Formulation                                                               
           I    II   III   IV   V                                         
__________________________________________________________________________
Emulsifiable                                                              
           7.1  7.2  7.3   7.4  7.5                                       
concentrate used                                                          
conc. of PRO                                                              
           26.3%                                                          
                26.3%                                                     
                     26.3% 26.3%                                          
                                26.3%                                     
water used for                                                            
           WHO 342 ppm hardness                                           
dilution                                                                  
dilution factor                                                           
           2.5/47.5                                                       
                2.5/47.5                                                  
                     2.5/47.5                                             
                           2.5/47.5                                       
                                2.5/47.5                                  
conc. of PRO in                                                           
           1.31%                                                          
                1.31%                                                     
                     1.31% 1.31%                                          
                                1.31%                                     
diluted sample                                                            
Bloom at 0-time                                                           
           Excellent                                                      
                Excellent                                                 
                     Excellent                                            
                           Excellent                                      
                                Excellent                                 
before mixing                                                             
Bloom after                                                               
           Excellent                                                      
                Excellent                                                 
                     Excellent                                            
                           Excellent                                      
                                Excellent                                 
20 inversions                                                             
separation 1 mm 1 mm Trace 0    0                                         
before mixing                                                             
separation after mixing                                                   
and standing for:                                                         
0 hour     2 mm 2 mm 0     0    0                                         
1 hour     2 mm 2 mm &lt;1 mm Trace                                          
                                Trace                                     
2 hour     3 mm 3 mm 1.5                                                  
                        mm 1 mm 1 mm                                      
3 hour     3 mm 3 mm 1.5                                                  
                        mm 1 mm 1 mm                                      
4 hour     4 mm 4 mm 2  mm 1 mm 1 mm                                      
__________________________________________________________________________
 
    
     EXAMPLE 8 
     The following formulations 8.1 through 8.16 were prepared exactly as explained in Example 1 except that a fungicide N,N&#39;-(1,4-piperazinediyl bis (2,2,2-trichloro) ethylidene)bisformamide (TRI) was used. 
     
                                           TABLE 8-1                               
__________________________________________________________________________
              8.1 8.2 8.3 8.4 8.5 8.6 8.7 8.8 8.9                         
__________________________________________________________________________
  N-methylpyrrolidone                                                     
              42.6%                                                       
                  42.6%                                                   
                      42.6%                                               
                          42.6%                                           
                              42.6%                                       
                                  42.6%                                   
                                      42.6%                               
                                          44.0%                           
                                              15.0%                       
  N-octylpyrrolidone                                                      
              19.4%                                                       
                  19.4%                                                   
                      9.7%                                                
                          9.7%                                            
                              --  --  --  10.0%                           
                                              40.0%                       
  N-dodecylpyrrolidone                                                    
              --  --  9.7%                                                
                          9.7%                                            
                              19.4%                                       
                                  19.4%                                   
                                      19.4%                               
                                          10.0%                           
                                              --                          
  Aromatic petroleum                                                      
              15.5%                                                       
                  15.5%                                                   
                      15.5%                                               
                          15.5%                                           
                              15.5%                                       
                                  15.5%                                   
                                      15.5%                               
                                          16.0%                           
                                              --                          
  oil - Exxon-200                                                         
  Gafac RE-610                                                            
              6.4%                                                        
                  --  6.4%                                                
                          --  6.4%                                        
                                  --  --  10.0%                           
                                              --                          
  Gafac RM-710                                                            
              --  6.4%                                                    
                      --  6.4%                                            
                              --  6.4%                                    
                                      --  --  5.0%                        
  TRI         16.1%                                                       
                  16.1%                                                   
                      16.1%                                               
                          16.1%                                           
                              16.1%                                       
                                  16.1%                                   
                                      16.1%                               
                                          10.0%                           
                                              7.5%                        
  Dodecyl benzene                                                         
              --  --  --  --  --  --  6.4%                                
                                          --  --                          
  sulfonic acid Tech: 97%                                                 
  Aromatic petroleum                                                      
              --  --  --  --  --  --  --  --  32.5%                       
  oil - Texaco-150                                                        
10.                                                                       
  Iso octylpyrrolidone                                                    
              --  --  --  --  --  --  --  6.4%                            
                                              --                          
  (N-2&#39;ethyl hexyl-                                                       
  pyrrolidone)                                                            
              100.0%                                                      
                  100.0%                                                  
                      100.0%                                              
                          100.0%                                          
                              100.0%                                      
                                  100.0%                                  
                                      100.0%                              
                                          100.0%                          
                                              100.0%                      
__________________________________________________________________________
                      8.10                                                
                          8.11                                            
                              8.12                                        
                                  8.13                                    
                                      8.14                                
                                          8.15                            
                                              8.16                        
__________________________________________________________________________
        1.                                                                
          N-methylpyrrolidone                                             
                      24.0%                                               
                          24.0%                                           
                              24.0%                                       
                                  32.0%                                   
                                      32.0%                               
                                          32.0%                           
                                              24.0%                       
        2.                                                                
          N-octylpyrrolidone                                              
                      32.0%                                               
                          16.0%                                           
                              --  32.0%                                   
                                      16.0%                               
                                          --  --                          
        3.                                                                
          N-dodecylpyrrolidone                                            
                      --  16.0%                                           
                              32.0%                                       
                                  --  16.0%                               
                                          32.0%                           
                                              --                          
        4.                                                                
          Aromatic petroleum                                              
                      24.0%                                               
                          24.0%                                           
                              24.0%                                       
                                  16.0%                                   
                                      16.0%                               
                                          16.0%                           
                                              24.0%                       
          oil - Exxon-200                                                 
        5.                                                                
          Gafac RE-610                                                    
                      8.0%                                                
                          8.0%                                            
                              8.0%                                        
                                  8.0%                                    
                                      8.0%                                
                                          8.0%                            
                                              8.0%                        
        6.                                                                
          Gafac RM-710                                                    
                      --  --  --  --  --  --  --                          
        7.                                                                
          TRI         12.0%                                               
                          12.0%                                           
                              12.0%                                       
                                  12.0%                                   
                                      12.0%                               
                                          12.0%                           
                                              12.0%                       
        8.                                                                
          Dodecyl benzene                                                 
                      --  --  --   -- --  --  --                          
          sulfonic acid Tech: 97%                                         
        9.                                                                
          Aromatic petroleum                                              
                      --  --  --  --  --  --  --                          
          oil - Texaco-150                                                
        10.                                                               
          Iso octylpyrrolidone                                            
                      --  --  --  --  --  --  32.0%                       
          (N-2&#39;ethyl hexyl-                                               
          pyrrolidone)                                                    
                      100.0%                                              
                          100.0%                                          
                              100.0%                                      
                                  100.0%                                  
                                      100.0%                              
                                          100.0%                          
                                              100.0%                      
__________________________________________________________________________
 
    
     The ease of emulsification and emulsion stability of the above six formulations were evaluated after dilution, as before, and the results are summarized in Table 8-2. 
     
                                           TABLE 8-2                               
__________________________________________________________________________
EMULSION STABILITY AND BLOOM CHARACTERISTICS                              
__________________________________________________________________________
            Formulation                                                   
            I    II   III  IV   V    VI   VII  VIII IX                    
__________________________________________________________________________
Emulsifiable                                                              
            8.1  8.2  8.3  8.4  8.5  8.6  8.7  8.8  8.9                   
concentrate used                                                          
conc. of TRI                                                              
            16.1%                                                         
                 16.1%                                                    
                      16.1%                                               
                           16.1%                                          
                                16.1%                                     
                                     16.1%                                
                                          16.1%                           
                                               10%  7.5%                  
water used for dilution                                                   
            WHO 342 ppm hardness                                          
dilution factor                                                           
            2.45/47.5                                                     
                 2.45/47.5                                                
                      2.45/47.5                                           
                           2.45/47.5                                      
                                2.45/47.5                                 
                                     2.45/47.5                            
                                          2.45/47.5                       
                                               0.8/49.2                   
                                                    1.0/49                
conc. of TRI in                                                           
            0.81%                                                         
                 0.81%                                                    
                      0.81%                                               
                           0.81%                                          
                                0.81%                                     
                                     0.81%                                
                                          0.81%                           
                                               0.16%                      
                                                    0.15%                 
the diluted sample                                                        
Bloom before mixing                                                       
            Fair-                                                         
                 Fair Fair-                                               
                           Fair Fair-                                     
                                     Fair-                                
                                          Poor Poor Poor                  
            Good      Good      Good Good                                 
after 20 inversions                                                       
            Excellent                                                     
                 Excellent                                                
                      Excellent                                           
                           Excellent                                      
                                Excellent                                 
                                     Excellent                            
                                          Excellent                       
                                               Excellent                  
                                                    Excellent             
separation at 0 time                                                      
            4 mm 5 mm 3 mm 5 mm 3.5 mm                                    
                                     --   8 mm                            
ppt/separations after                                                     
mixing and standing for:                                                  
 0 hour     0    0    0    0    0    0    0                               
 1 hour     2 mm 2 mm   2 mm                                              
                           4 mm   2 mm                                    
                                       2 mm                               
                                          4 mm, oil                       
                                               --   --                    
 2 hour     2 mm 2 mm   2 mm                                              
                           4 mm   2 mm                                    
                                       3 mm                               
                                          4 mm, oil                       
                                               Trace                      
                                                    0                     
 4 hour     4 mm 4 mm 3.5 mm                                              
                           5 mm 3.5 mm                                    
                                     3.5 mm    &lt;1 mm                      
                                                    0                     
24 hour                                         1 mm                      
                                                    1 mm                  
                                                    oil on top            
*after 24 hour settling,                                                  
filtered through screens                                                  
 60 mesh                                       +    -                     
100 mesh                                       +    -                     
250 mesh                                       ++   -                     
__________________________________________________________________________
                      Formulation                                         
                      X    XI   XII  XIII XIV  XV   XVI                   
__________________________________________________________________________
          Emulsifiable                                                    
                      8.10 8.11 8.12 8.13 8.14 8.15 8.16                  
          concentrate used                                                
          conc. of TRI                                                    
                      12%  12%  12%  12%  12%   12% 12%                   
          water used for dilution                                         
                      WHO 342 ppm hardness                                
          dilution factor                                                 
                      0.7/49.3                                            
                           0.7/49.3                                       
                                0.7/49.3                                  
                                     0.7/49.3                             
                                          0.7/49.3                        
                                               0.7/49.3                   
                                                    0.7/49.3              
          conc. of TRI in                                                 
                      0.17%                                               
                           0.17%                                          
                                0.17%                                     
                                     0.17%                                
                                          0.17%                           
                                               0.17%                      
                                                    0.17%                 
          the diluted sample                                              
          Bloom before mixing                                             
                      Fair Good Fair Fair Fair Fair Fair                  
          after 20 inversions                                             
                      Excellent                                           
                           Excellent                                      
                                Excellent                                 
                                     Excellent                            
                                          Excellent                       
                                               Excellent                  
                                                    Excellent             
          separation at 0 time                                            
          ppt/separations after                                           
          mixing and standing for:                                        
           0 hour                                                         
           1 hour     Trace                                               
                           Trace                                          
                                0    Trace                                
                                          Trace                           
                                               Trace                      
                                                    Trace                 
           2 hour     --   --   --   --   --   --   --                    
           4 hour     Trace                                               
                           Trace                                          
                                Trace                                     
                                     &lt;1 mm                                
                                          &lt;1 mm                           
                                               Trace                      
                                                    &lt;1 mm                 
          24 hour     1.5 mm                                              
                           1 mm &lt;1 mm                                     
                                      1.5 mm                              
                                           1 mm                           
                                               1 mm &lt;1 mm                 
          *after 24 hour settling,                                        
          filtered through screens                                        
           60 mesh    -    ++   ++   +    -    -    +                     
          100 mesh    +    +    +    +    +    -    +                     
          250 mesh    +    ++   ++   ++   ++   +    ++                    
__________________________________________________________________________
 * - means no sediment; + means trace; ++ means more than trace sediment  
 but unmeasurable by weighing.                                            
 
    
     EXAMPLE 9 
     The following formulation 9.1 was prepared exactly as explained in Example 1, except that N-(2&#39;-ethylhexylpyrrolidone) was used in the place of N-octylpyrrolidone. 
     
                       TABLE 9-1                                                   
______________________________________                                    
Formulation and % Composition                                             
                        9.1                                               
______________________________________                                    
1.       N-methylpyrrolidone  33.0%                                       
2.       N-(2&#39;-ethylhexylpyrrolidone)                                     
                              15.0%                                       
3.       Aromatic Petroleum                                               
         oil - Exxon 200      12.0%                                       
4.       PRL Tech. 92% (see                                               
         Example 1)           26.0%                                       
5.       Gafac RE-610 (GAF)   14.0%                                       
         TOTAL                100.0%                                      
______________________________________                                    
 
    
     This formulation did not freeze at 5° C. The ease of emulsification and stability on dilution are shown in Table 9-2. 
     
                       TABLE 9-2                                                   
______________________________________                                    
                Formulation                                               
                9.1                                                       
______________________________________                                    
Conc. of PRL:     26.0%                                                   
Water used for dilution                                                   
                  WHO 342 PPM hardness                                    
Dilution factor   2.5 g/47.5 g                                            
Conc. of PRL in the                                                       
                  1.3%                                                    
diluted sample                                                            
Bloom at 0 time   Excellent                                               
Bloom after 20    Excellent                                               
inversions                                                                
Separation of cream                                                       
after 20 inversions                                                       
and on standing after:                                                    
 1 hour           Trace                                                   
 3 hours          &lt;1 mm                                                   
 4 hours          &lt;1 mm                                                   
24 hours          &lt;1 mm                                                   
______________________________________                                    
 
    
     After standing for 24 hours, 20 inversions and filtration through 60 mesh, 100 mesh and 250 mesh screens, no sediment was left, even on a 250 mesh screen.