Patent Publication Number: US-6709317-B2

Title: Method and apparatus for uniformly planarizing a microelectronic substrate

Description:
CROSS-REFERENCE TO RELATED APPLICATIONS 
     This application is a divisional of pending U.S. patent application Ser. No. 09/748,953, filed Dec. 26, 2000, which is continuation of U.S. patent application Ser. No. 09/244,948, filed Feb. 4, 1999, now issued as U.S. Pat. No. 6,176,763. 
    
    
     TECHNICAL FIELD 
     The present invention relates to methods and apparatuses for uniformly planarizing a microelectronic substrate using a chemical-mechanical planarization process. 
     BACKGROUND OF THE INVENTION 
     Mechanical and chemical-mechanical planarizing processes (collectively “CMP”) are used in the manufacture of microelectronic devices to form a flat surface on semiconductor wafers, field emission displays; and many other microelectronic substrates. FIG. 1 schematically illustrates a planarizing machine  10  with a table or platen  20 , a carrier assembly  30  above the platen  20 , a polishing pad  21  positioned on the platen  20 , and a planarizing fluid  23  on the polishing pad  21 . The planarizing machine  10  may also have an under-pad  25  attached to an upper surface  22  of the platen  20  for supporting the polishing pad  21 . In many planarizing machines, a platen drive assembly  26  rotates (arrow A) and/or reciprocates (arrow B) the platen  20  to move the polishing pad  21  during planarization. 
     The carrier assembly  30  controls and protects a substrate  80  during planarization. The carrier assembly  30  typically has a substrate holder  32  with a pad  34  that holds the substrate  80  via suction. A carrier drive assembly  36  typically translates (arrow C) and/or rotates (arrow D) the substrate holder  32 . Alternatively, the substrate holder  32  may be a weighted, free-floating disk (not shown) that slides over the polishing pad  21 . The combination of the polishing pad  21  and the planarizing fluid  23  generally defines a planarizing medium  28  that mechanically and/or chemically-mechanically removes material from the surface of the substrate  80 . The polishing pad  21  may be a conventional polishing pad composed of a polymeric material (e.g., polyurethane) without abrasive particles, or it may be an abrasive polishing pad with abrasive particles fixedly bonded to a suspension material. In a typical application, the planarizing fluid  23  may be a CMP slurry with abrasive particles and chemicals for use with a conventional non-abrasive polishing pad. In other applications, the planarizing fluid  23  may be a chemical solution without abrasive particles for use with an abrasive polishing pad. 
     To planarize the substrate  80  with the planarizing machine  10 , the carrier assembly  30  presses the substrate  80  against a planarizing surface  24  of the polishing pad  21  in the presence of the planarizing fluid  23 . The platen  20  and/or the substrate holder  32  move relative to one another to translate the substrate  80  across the planarizing surface  24 . As a result, the abrasive particles and/or the chemicals in the planarizing medium  28  remove material from the surface of the substrate  80 . 
     CMP processes must consistently and accurately produce a uniform planar surface on the substrate to enable precise fabrication of circuits and photo-patterns. Prior to being planarized, many substrates have large “step heights” that create a highly topographic surface across the substrate. Yet, as the density of integrated circuits increases, it is necessary to have a planar substrate surface at several stages of substrate processing because non-uniform substrate surfaces significantly increase the difficulty of forming sub-micron features or photo-patterns to within the tolerance of approximately 0.1 microns. Thus, CMP processes must typically transform a highly topographical substrate surface into a highly uniform, planar substrate surface (e.g., a “blanket surface”). 
     In one conventional apparatus for planarizing microelectronic substrates, the polishing pad  21  includes a relatively soft polyurethane material. For example, the polishing pad  21  can be a model number IC1000, manufactured by Rodel, Inc. of Newark, Del., and described in U.S. Pat. No. 5,489,233 to Cook et al. The polishing pad  21  can include surface features to increase the polishing rate, as described in Cook et al. and U.S. Pat. No. 5,177,908 to Tuttle. One drawback with the polishing pads described above is that they may tend to conform to the surface of the substrate  80  and may therefore not planarize the substrate surface uniformly. One approach to addressing this drawback is to increase the hardness and elastic modulus of the polishing pad. For example, model number OXP3000 polyurethane polishing pads, having a hardness and elastic modulus greater than the corresponding hardness and elastic modulus of the IC1000 polishing pad, are available from Rodel, Inc. 
     In another conventional apparatus for planarizing substrates, the planarizing liquid  23  used with relatively soft polishing pads can include a suspension of abrasive fumed silica aggregates  27 , such as are shown in FIG.  2 . For example, model number ILD1300 planarizing liquids having a suspension of fumed silica aggregates  27  such as those shown in FIG. 2, are available from Rodel, Inc. The fumed silica aggregates  27  can be formed by reacting SiCl 4  and/or SiH x Cl y  with oxygen in a burning process to form SiO 2  particles. As the SiO 2  particles cool, they collide and adhere to each other, forming the three-dimensional aggregates  27  having a fractal configuration and a relatively large surface area. 
     One problem with the fumed silica aggregates  27  is that they can scratch or otherwise damage the substrate  80  as a result of their rough, three-dimensional shapes. One approach for addressing this problem has been to form abrasive particles having less surface area and less roughness than the silica aggregates  27 . For example, planarizing liquids having spherical abrasive particles are available from Rodel, Inc. under the trade name Klebosol. 
     One problem with the planarizing solutions having spherical abrasive particles occurs when they are used with relatively soft polishing pads and/or with polishing pads having a porous planarizing surface. The combination of relatively soft polishing pads and planarizing liquids with spherical particles may not uniformly planarize the surfaces of microelectronic substrates because the polishing pads may conform to the surface of the substrate, as discussed above. The porous polishing pad may not planarize the substrate at an acceptable rate because the pores reduce the surface area of the polishing pad that contacts the substrate. 
     SUMMARY OF THE INVENTION 
     The present invention is directed toward methods and apparatuses for uniformly removing material from a microelectronic substrate during planarization. In one aspect of the invention, the apparatus can include a planarizing medium having a polishing pad with a generally non-porous planarizing surface and a planarizing liquid. The polishing pad can have a Shore D hardness in the range of approximately 58 to approximately 70 and/or can have a modulus of elasticity in the range of approximately 5.0×10 8  pascals to approximately 1.5×10 9  pascals. The planarizing liquid can include colloidal particles having a generally smooth external surface and being dispersed in the planarizing liquid to form a colloidal suspension. 
     In one aspect of the invention, the colloidal particles can have a generally spherical shape. In another aspect of the invention, the colloidal particles can have other shapes with smooth external surfaces, such as a cylindrical shape, a generally cubic shape, a generally hexagonal shape, or other closed polyhedrons. The colloidal particles can be formed from silicon dioxide, manganese oxide and/or cerium oxide and/or can have a surface area that is less than the surface area of a fumed silica aggregate of approximately the same overall size. 
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS 
     FIG. 1 is a partial cross-sectional elevation view of a chemical-mechanical planarization machine in accordance with the prior art. 
     FIG. 2 is an isometric view of fumed silica aggregates in accordance with the prior art. 
     FIG. 3 is a partial cross-sectional elevation view of a chemical-mechanical planarization machine having a planarizing liquid with smooth-surfaced particles in accordance with an embodiment of the present invention. 
     FIG. 4A is a detailed isometric view of one of the particles shown in FIG. 3 having a spherical shape in accordance with one embodiment of the invention. 
     FIG. 4B is a detailed isometric view of one of the particles shown in FIG. 3 having a cylindrical shape in accordance with another embodiment of the invention. 
     FIG. 4C is an isometric view of one of the particles shown in FIG. 3 having a cubic shape in accordance with still another embodiment of the invention. 
     FIG. 4D is an isometric view of one of the particles shown in FIG. 3 having an elongated rectangular shape in accordance with yet another embodiment of the invention. 
     FIG. 4E is an isometric view of one of the particles shown in FIG. 3 having a hexagonal shape in accordance with yet another embodiment of the invention. 
     FIG. 4F is an isometric view of one of the particles shown in FIG. 3 having a triangular cross-sectional shape in accordance with still another embodiment of the invention. 
    
    
     DETAILED DESCRIPTION OF THE INVENTION 
     The present invention is directed toward methods and apparatuses for planarizing a microelectronic substrate. The apparatus can include a relatively hard polishing pad in combination with a planarizing liquid having a colloidal suspension of smooth-surfaced particles. Many specific details of certain embodiments of the invention are set forth in the following description and in FIGS. 3-4B to provide a thorough understanding of such embodiments. One skilled in the art, however, will understand that the present invention may have additional embodiments and that they may be practiced without several of the details described in the following description. 
     FIG. 3 illustrates a CMP machine  110  having a platen  120  and a planarizing medium  128 . In the embodiment shown in FIG. 3, the planarizing medium  128  includes a polishing pad  121  releasably attached to the platen  120 , and a planarizing liquid  123  disposed on a planarizing surface  124  of the polishing pad  121 . The platen  120  can be movable by means of a platen drive assembly  126  that can impart rotational motion (indicated by arrow A) and/or translational motion (indicated by arrow B) to the platen  120 . As was discussed above, the CMP machine  110  can also include a carrier assembly  130  having a substrate holder  132  and a resilient pad  134  that together press a microelectronic substrate  180  against the planarizing surface  124  of the polishing pad  121 . A carrier drive assembly  136  can be coupled to the carrier assembly  130  to move the carrier assembly axially (indicated by arrow C) and/or rotationally (indicated by arrow D) relative to the platen  120 . 
     In one embodiment, the polishing pad  121  can be relatively hard and have a relatively high modulus of elasticity. For example, the polishing pad  121  can include a polyurethane material and can have a hardness, measured on the Shore D hardness scale, of between 58 and 70. In a further aspect of this embodiment, the polishing pad  121  can have a Shore D hardness of approximately 60. The polishing pad  121  can also have a modulus of elasticity of between 5.0×10 8  pascals (7.3×10 4  psi) and 1.5×10 9  pascals (2.2×10 5  psi). In a further aspect of this embodiment, the modulus of elasticity can be approximately 1.0×10 9  pascals (1.5×10 5  psi). In still a further aspect of this embodiment, the polishing pad  121  can have a generally non-porous planarizing surface  124 . In one embodiment, the polishing pad  121  can be a model number OXP3000 polishing pad available from Rodel, Inc. of Newark, Del., formed from generally non-porous polyurethane and having a hardness and a modulus of elasticity within the ranges identified above. In other embodiments, other polishing pads  121  from other sources can include materials other than polyurethane and can have a hardness and/or a modulus of elasticity outside the ranges identified above, so long as the polishing pads  121  are sufficiently rigid to uniformly planarize the microelectronic substrate  180 . 
     The planarizing liquid  123  atop the polishing pad  121  can include a liquid medium  129  having a suspension of colloidal particles  127 . For example, in one embodiment, the liquid medium  129  can include water and ammonia or other alkaline substances and can have a pH of approximately 11. In another embodiment, the liquid medium  129  can include acidic substances and can have a pH of approximately 2.6. 
     The colloidal particles  127  can have a variety of sizes, shapes and compositions. For example, in one embodiment, the colloidal particles  127  can be spherical and can have a diameter of between 10 nanometers and 300 nanometers. In one aspect of this embodiment, the colloidal particles  127  can have a diameter of between approximately 30 nanometers and approximately 70 nanometers. In a further aspect of this embodiment, the colloidal particles  127  can have a diameter of approximately 50 nanometers, slightly less than the overall size of the fumed silica aggregates  27  shown in FIG.  2 . In other embodiments, the colloidal particles  127  can have other sizes, so long as they are small enough to remain suspended in the liquid medium  129 . Planarizing liquids having liquid media  129  and colloidal particles  127  within the ranges identified above are available from Rodel, Inc. under the trade name Klebosol. 
     In one embodiment, the colloidal particles  127  can include silicon-based molecules, such as silicon dioxide. In other embodiments, the colloidal particles  127  can include aluminum oxide, manganese oxide and/or cerium oxide, so long as the colloidal particles  127  have a relatively small surface area, as will be discussed in greater detail below with reference to FIGS. 4A-4F. 
     FIG. 4A is an enlarged isometric view of one of the colloidal particles  127  shown in FIG. 3, having a generally spherical overall shape in accordance with an embodiment of the invention. As shown in FIG. 4A, the colloidal particle  127  has a smooth external surface. Accordingly, the surface area of the colloidal particle  127  shown in FIG. 4A is significantly less than the surface area of a fused aggregate having approximately the same overall dimensions, for example, the fused silica aggregates  27  shown in FIG.  2 . 
     In other embodiments, the colloidal particle  127  can have other shapes that similarly have smooth external surfaces with relatively low total surface area. The surfaces can be generally flat or convex, as opposed to concave, and/or can be generally free of convolutions. For example, the planarizing liquid  123  shown in FIG. 3 can include generally cylindrical colloidal particles  127   b  as shown in FIG. 4B, generally cubic colloidal particles  127   c  as shown in FIG. 4C, and/or generally rectangular colloidal particles  127   d  as shown in FIG.  4 D. In still further embodiments, the planarizing liquid  123  shown in FIG. 3 can include colloidal particles  127   e  having a generally hexagonal shape as shown in FIG. 4E, and/or colloidal particles  127   f  having a generally triangular cross-sectional shape as shown in FIG.  4 F. In still further embodiments, the colloidal particles  127  can have other closed polyhedral shapes, so long as the colloidal particles have generally smooth exterior surfaces with a relatively low surface area. The shapes of specific colloidal particles  127  can depend on the material properties of the particles, the manufacturing processes used to form the particles, and other variables. For example, the colloidal particles  127  can be formed in-situ by “growing” the colloidal particles  127  in solution. Alternatively, the colloidal particles  127  can be formed ex-situ, using a process such as pyrolysis, ablation, vapor phase condensation, grinding or milling, and can then be added to a liquid solution. In any case, the overall length or diameter of the particles shown in FIGS. 4A-4F can be within the ranges discussed above with reference to FIG.  3 . 
     An advantage of the combination of the hard polishing pad  121  and the smooth-surfaced colloidal particles  127  shown in FIGS. 3-4F is that together they can uniformly planarize the microelectronic substrate  180  without scratching or otherwise damaging the surface of the substrate  180 . For example, it has been observed in some cases that planarizing with the hard polishing pad  121  together with the smooth-surfaced colloidal particles  127  can produce a surface finish on the substrate  180  that is smoother than that obtained by planarizing with a hard polishing pad in combination with fumed silica aggregates. It is believed that this effect may result because the smooth-surfaced colloidal particles  127  may have a lesser tendency than the silica aggregates to gel or otherwise form agglomerations. 
     A further advantage of the combination of the hard polishing pad  121  and the smooth-surfaced colloidal particles  127  is that they can reduce the potential for scratching the microelectronic substrate  180  during planarization. It is believed that scratches in the microelectronic substrate  180  may be caused by the rough surfaces of the fumed silica aggregates  27  (FIG. 2) and/or by large agglomerations of the aggregates  27  that become caught between the microelectronic substrate  180  and the polishing pad  121  (FIG.  3 ). The colloidal particles  127  may reduce the likelihood of damaging the microelectronic substrate  180  because individual colloidal particles  127  have smooth surfaces that tend not to scratch the surface of the microelectronic substrate. Furthermore, the colloidal particles  127  may be less likely to form agglomerations because they do not have fractal shapes that tend to link together. 
     Still another advantage is that, by reducing the likelihood for forming scratches on the microelectronic substrate  180 , the combination of the hard polishing pad  121  and the smooth-surfaced colloidal particles  127  may also reduce the likelihood for forming cracks in the microelectronic substrate  180 . Such cracks can damage structures of the microelectronic substrate  180 , and can also create channels through which chemicals, such as those used during CMP processing, can damage structures beneath the surface of the microelectronic substrate  180 . 
     Yet another advantage of an embodiment having a polishing pad  121  with a non-porous planarizing surface  124  is that the combination of such a polishing pad with the smooth-surfaced colloidal particles can increase the rate at which the microelectronic substrate  180  is planarized while reducing the likelihood of scratching or otherwise damaging the microelectronic substrate  180 . Such a combination may be particularly advantageous when compared with a porous polishing pad such as an ESM polishing pad, available from James H. Rhodes and Co. of Franklin Springs, N.Y. Such porous polishing pads have a reduced surface area in contact with the microelectronic substrate  180  and accordingly can have a slower planarization rate. 
     From the foregoing it will be appreciated that, although specific embodiments of the invention have been described herein for purposes of illustration, various modifications may be made without deviating from the spirit and scope of the invention. Accordingly, the invention is not limited except as by the appended claims.