Patent Publication Number: US-2009233795-A1

Title: Fungicidal Mixtres Based On 3-Monosubstituted N-Bipenyl-Pyrazolecarboxamides

Description:
The present invention relates to fungicidal mixtures comprising, as active components, 
     1) at least one 3-monosubstituted N-biphenyl-pyrazolecarboxamide of the formula I 
     
       
         
         
             
             
         
       
         
         
           
             in which the substituents are as defined below: 
             X is oxygen or sulfur; 
             R 1  is cyano, nitro, halogen, C 1 -C 6 -alkyl, C 1 -C 6 -haloalkyl, methoxy, difluoromethoxy, trifluoromethoxy, methylthio, difluoromethylthio or trifluoromethylthio; 
             R 2  is halogen, C 1 -C 4 -alkyl or C 1 -C 4 -haloalkyl; 
             R 3  is hydrogen or halogen; and
 
2) at least one active compound II selected from groups A) to F):
 
             A) azoles selected from the group consisting of bitertanol, bromuconazole, cyproconazole, difenoconazole, diniconazole, enilconazole, epoxiconazole, fluquinconazole, fenbuconazole, flusilazole, flutriafol, hexaconazole, imibenconazole, ipconazole, metconazole, myclobutanil, penconazole, propiconazole, prothioconazole, simeconazole, triadimefon, triadimenol, tebuconazole, tetraconazole, triticonazole, prochloraz, pefurazoate, imazalil, triflumizole, cyazofamid, benomyl, carbendazim, thiabendazole, fuberidazole, ethaboxam, etridiazole and hymexazole; 
             B) strobilurins selected from the group consisting of azoxystrobin, dimoxystrobin, enestroburin, fluoxastrobin, kresoxim-methyl, methominostrobin, orysastrobin, picoxystrobin, pyraclostrobin, trifloxystrobin, enestroburin, methyl (2-chloro-5-[1-(3-methylbenzyloxyimino)ethyl]benzyl)carbamate, methyl (2-chloro-5-[1-(6-methylpyridin-2-ylmethoxyimino)ethyl]benzyl)carbamate and methyl 2-(ortho-(2,5-dimethylphenyloxymethylene)phenyl)-3-methoxyacrylate; 
             C) carboxamides selected from the group consisting of carboxin, benalaxyl, boscalid, fenhexamid, flutolanil, furametpyr, mepronil, metalaxyl, mefenoxam, ofurace, oxadixyl, oxycarboxin, penthiopyrad, thifluzamide, tiadinil, 3,4-dichloro-N-(2-cyanophenyl)isothiazole-5-carboxamide, dimethomorph, flumorph, flumetover, fluopicolide (picobenzamid), zoxamide, carpropamid, diclocymet, mandipropamid, N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-methanesulfonylamino-3-methylbutyramide, N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-ethanesulfonylamino-3-methylbutyramide, methyl 3-(4-chlorophenyl)-3-(2-isopropoxycarbonylamino-3-methylbutyrylamino)propionate, compounds of the formula III 
           
         
       
    
     
       
         
         
             
             
         
       
         
         
           
             
               
                 in which R 4  is methyl or ethyl, N-(4′-bromobiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide, N-(4′-trifluoromethylbiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide, N-(4′-chloro-3′-fluorobiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide, N-(3′,4′-dichloro-4-fluorobiphenyl-2-yl)-3-difluoromethyl-1-methylpyrazole-4-carboxamide and N-(2-cyanophenyl)-3,4-dichloroisothiazole-5-carboxamide; 
               
             
             D) heterocyclic compounds selected from the group consisting of fluazinam, pyrifenox, bupirimate, cyprodinil, fenarimol, ferimzone, mepanipyrim, nuarimol, pyrimethanil, triforine, fenpiclonil, fludioxonil, aldimorph, dodemorph, fenpropimorph, tridemorph, fenpropidin, iprodione, procymidone, vinclozolin, famoxadone, fenamidone, octhilinone, probenazole, 5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine, anilazine, diclomezine, pyroquilon, proquinazid, tricyclazole, the compound of the formula IV (2-butoxy-6-iodo-3-propylchromen-4-one) 
           
         
       
    
     
       
         
         
             
             
         
       
         
         
           
             
               
                 acibenzolar-S-methyl, captafol, captan, dazomet, folpet, fenoxanil, quinoxyfen and N,N-dimethyl-3-(3-bromo-6-fluoro-2-methylindole-1-sulfonyl)-[1,2,4]triazole-1-sulfonamide of the formula V 
               
             
           
         
       
    
     
       
         
         
             
             
         
       
         
         
           
             E) carbamates selected from the group consisting of mancozeb, maneb, metam, metiram, ferbam, propineb, thiram, zineb, ziram, diethofencarb, iprovalicarb, flubenthiavalicarb, propamocarb, 4-fluorophenyl N-(1-(1-(4-cyanophenyl)ethanesulfonyl)but-2-yl)carbamate, methyl 3-(4-chlorophenyl)-3-(2-isopropoxycarbonylamino-3-methylbutyrylamino)propanoate of the formula VI 
           
         
       
    
     
       
         
         
             
             
         
       
         
         
           
             
               
                 and carbamate oxime ethers of the formula VII 
               
             
           
         
       
    
     
       
         
         
             
             
         
       
         
         
           
             
               
                 in which Z is N or CH; 
               
             
             F) other fungicides selected from the group consisting of guanidines: dodine, iminoctadine, guazatine, antibiotics: kasugamycin, streptomycin, polyoxins, validamycin A, nitrophenyl derivatives: binapacryl, dinocap, dinobuton, sulfur-containing heterocyclyl compounds: dithianon, isoprothiolane, organometallic compounds: fentin salts, such as fentin acetate, organophosphorus compounds: edifenphos, iprobenfos, fosetyl, fosetyl-aluminum, phosphorous acid and its salts, pyrazophos, tolclofos-methyl,
           organochlorine compounds: chlorothalonil, dichlofluanid, flusulfamide, hexachlorobenzene, phthalide, pencycuron, quintozene, thiophanate-methyl, tolylfluanid,   inorganic active compounds: Bordeaux mixture, copper acetate, copper hydroxide, copper oxychloride, basic copper sulfate, sulfur, others: cyflufenamid, cymoxanil, dimethirimol, ethirimol, furalaxyl, metrafenone and spiroxamine
 
in a synergistically effective amount.
   
         
           
         
       
    
     Moreover, the invention relates to a method for controlling harmful fungi using the mixture of at least one compound I and at least one of the active compounds II, the use of the compounds I and II for preparing such mixtures and also to compositions and seed comprising these mixtures. 
     Substituted biphenylanilides of the formula I are known from EP-A 589 301, which also discloses a process for their preparation and a list of possible mixing partners from the group of the fungicides, bactericides, acaricides, nematicides or insecticides. Substituted biphenylamides which are monosubstituted at the phenyl ring are also known from WO 01/42223. 
     JP-A 09/132,567 discloses mono- and disubstituted biphenylamides which are substituted at the phenyl ring by trifluoromethyl. 
     WO 2005/34628 discloses mixtures of, inter alia, pyrazolecarboxamides and various other fungicidally active compounds. The pyrazolecarboxamides differ from the present compounds I in particular by the substitution pattern at the biphenyl radical. 
     However, the biphenylamides described and the known mixtures are, in particular at low application rates, not entirely satisfactory. 
     The active compounds II mentioned above as component 2), their preparation and their action against harmful fungi are generally known (cf., for example, http://www.hclrss.demon.co.uk/index.html); they are commercially available. 
     Benalaxyl, methyl N-(phenylacetyl)-N-(2,6-xylyl)-DL-alaninate (DE 29 03 612);
 
metalaxyl, methyl N-(methoxyacetyl)-N-(2,6-xylyl)-DL-alaninate (GB 15 00 581);
 
ofurace, (RS)-α-(2-chloro-N-2,6-xylylacetamido)-γ-butyrolactone [CAS RN 58810-48-3]; oxadixyl; N-(2,6-dimethylphenyl)-2-methoxy-N-(2-oxo-3-oxazolidinyl)acetamide (GB 20 58 059);
 
aldimorph, “4-alkyl-2,5(or 2,6)-dimethylmorpholine”, comprising 65-75% of 2,6-dimethylmorpholine and 25-35% of 2,5-dimethylmorpholine, comprising more than 85% of 4-dodecyl-2,5(or 2,6)-dimethylmorpholine, where “alkyl” also includes octyl, decyl, tetradecyl and hexadecyl, with a cis/trans ratio of 1:1 [CAS RN 91315-15-0];
 
dodine, 1-dodecylguanidinium acetate (Plant Dis. Rep., Vol. 41, p. 1029 (1957));
 
dodemorph, 4-cyclododecyl-2,6-dimethylmorpholine (DE-A 1198125);
 
fenpropimorph, (RS)-cis-4-[3-(4-tert-butylphenyl)-2-methylpropyl]-2,6-dimethyl-morpholine (DE-A 27 52 096);
 
fenpropidin, (RS)-1-[3-(4-tert-butylphenyl)-2-methylpropyl]piperidine (DE-A 27 52 096);
 
guazatine, mixture of the reaction products from the amidation of technical grade iminodi(octamethylene)diamine, comprising various guanidines and polyamines [CAS RN 108173-90-6];
 
iminoctadine, 1,1′-iminodi(octamethylene)diguanidine (Congr. Plant Pathol., 1., p. 27 (1968);
 
spiroxamine, (8-tert-butyl-1,4-dioxaspiro[4.5]dec-2-yl)diethylamine (EP-A 281 842);
 
tridemorph, 2,6-dimethlyl-4-tridecylmorpholine (DE-A 11 64 152);
 
pyrimethanil, 4,6-dimethylpyrimidin-2-ylphenylamine (DD-A 151 404);
 
mepanipyrim, (4-methyl-6-prop-1-ynylpyrimidin-2-yl)phenylamine (EP-A 224 339);
 
cyprodinil, (4-cyclopropyl-6-methylpyrimidin-2-yl)phenylamine (EP-A 310 550);
 
cycloheximide, 4-{(2R)-2-[(1S,3S,5S)-3,5-dimethyl-2-oxocyclohexyl]-2-hydroxyethyl}piperidine-2,6-dione [CAS RN 66-81-9];
 
griseofulvin, 7-chloro-2′,4,6-trimethoxy-6′-methylspiro[benzofuran-2(3H),1′-cyclohex-2′-ene]-3,4′-dione [CAS RN 126-07-8]; kasugamycin, 3-O-[2-amino-4-[(carboxylminomethyl)amino]-2,3,4,6-tetradeoxy-α-D-arabino-hexopyranosyl]-D-chiro-inositol [CAS RN 6980-18-3]; natamycin, (8E,14E,16E,18E,20E)-(1R,3S,5R,7R,12R,22R,24S,25R,26S)-22-(3-amino-3,6-dideoxy-β-D-mannopyranosyloxy)-1,3,26-trihydroxy-12-methyl-10-oxo-6,11,28-trioxatricyclo[22.3.1.0 5,7 ]octacosa-8,14,16,18,20-pentaene-25-carboxylic acid [CAS RN 7681-93-8];
 
polyoxin, 5-(2-amino-5-O-carbamoyl-2-deoxy-L-xylonamido)-1-(5-carboxy-1,2,3,4-tetrahydro-2,4-dioxopyrimidin-1-yl)-1,5-dideoxy-β-D-allofuranuronic acid [CAS RN 22976-86-9];
 
streptomycin, 1,1′-{1-L-(1,3,5/2,4,6)-4-[5-deoxy-2-1-(2-deoxy-2-methylamino-α-L-glucopyranosyl)-3-C-formyl-α-L-lyxofuranosyloxy]-2,5,6-trihydroxycyclohex-1,3-ylene}diguanidine (J. Am. Chem. Soc. Vol. 69, p. 1234 (1947));
 
bitertanol, β-([1,1′-biphenyl]-4-yloxy)-α-(1,1-dimethylethyl)-1H-1,2,4-triazole-1-ethanol (DE-A 23 24 020),
 
bromuconazole, 1-[[4-bromo-2-(2,4-dichlorophenyl)tetrahydro-2-furanyl]methyl]-1-H-1,2,4-triazole (Proc. 1990 Br. Crop. Prot. Conf.—Pests Dis. Vol. 1, p. 459); cyproconazole, 2-(4-chlorophenyl)-3-cyclopropyl-1-[1,2,4]triazol-1-ylbutan-2-ol (U.S. Pat. No. 4,664,696);
 
difenoconazole, 1-{2-[2-chloro-4-(4-chlorophenoxy)phenyl]-4-methyl-[1,3]dioxolan-2-ylmethyl}-1H-[1,2,4]triazole (GB-A 2 098 607); diniconazole, (βE)-α-[(2,4-dichlorophenyl)methylene]-α-(1,1-dimethylethyl)-1H-1,2,4-triazole-1-ethanol (Noyaku Kagaku, 1983, Vol. 8, p. 575);
 
enilconazole (imazalil), 1-[2-(2,4-dichlorophenyl)-2-(2-propenyloxy)ethyl]-1H-imidazole (Fruits, 1973, Vol. 28, p. 545); epoxiconazole, (2RS,3SR)-1-[3-(2-chlorophenyl)-2,3-epoxy-2-(4-fluorophenyl)propyl]-1H-1,2,4-triazole (EP-A 196 038); fenbuconazole, α-[2-(4-chlorophenyl)ethyl]-α-phenyl-1H-1,2,4-triazole-1-propanenitrile (Proc. 1988 Br. Crop Prot. Conf.—Pests Dis. Vol. 1, p. 33);
 
fluquinconazole, 3-(2,4-dichlorophenyl)-6-fluoro-2-[1,2,4]-triazol-1-yl-3H-quinazolin-4-one (Proc. Br. Crop Prot. Conf.—Pests Dis., 5-3, 411 (1992));
 
flusilazole, 1-{[bis(4-fluorophenyl)methylsilanyl]methyl}-1H-[1,2,4]triazole (Proc. Br. Crop Prot. Conf.—Pests Dis., 1, 413 (1984));
 
flutriafol, α-(2-fluorophenyl)-α-(4-fluorophenyl)-1H-1,2,4-triazole-1-ethanol (EP-A 15 756);
 
hexaconazole, 2-(2,4-dichlorophenyl)-1-[1,2,4]triazol-1-ylhexan-2-ol (CAS RN 79983-71-4);
 
ipconazole, 2-[(4-chlorophenyl)methyl]-5-(1-methylethyl)-1-(1H-1,2,4-triazol-1-yl-methyl)cyclopentanol (EP-A 267 778),
 
metconazole, 5-(4-chlorobenzyl)-2,2-dimethyl-1-[1,2,4]triazol-1-ylmethylcyclopentanol (GB 857 383);
 
myclobutanil, 2-(4-chlorophenyl)-2-[1,2,4]triazol-1-ylmethylpentanenitrile (CAS RN 88671-89-0);
 
penconazole, 1-[2-(2,4-dichlorophenyl)pentyl]-1H-[1,2,4]triazole (Pesticide Manual, 12 th  Ed. 2000, p. 712);
 
propiconazole, 1-[[2-(2,4-dichlorophenyl)-4-propyl-1,3-dioxolan-2-yl]methyl]-1H-1,2,4-triazole (BE 835 579);
 
prochloraz, N-(propyl-[2-(2,4,6-trichlorophenoxy)ethyl])imidazole-1-carboxamide (U.S. Pat. No. 3,991,071);
 
prothioconazole, 2-[2-(1-chlorocyclopropyl)-3-(2-chlorophenyl)-2-hydroxypropyl]-2,4-dihydro[1,2,4]triazole-3-thione (WO 96/16048); simeconazole, α-(4-fluorophenyl)-α-[(trimethylsilyl)methyl]-1H-1,2,4-triazole-1-ethanol [CAS RN 149508-90-7],
 
tebuconazole, 1-(4-chlorophenyl)-4,4-dimethyl-3-[1,2,4]triazol-1-ylmethylpentan-3-ol (EP-A 40 345);
 
tetraconazole, 1-[2-(2,4-dichlorophenyl)-3-(1,1,2,2-tetrafluoroethoxy)propyl]-1H-1,2,4-triazole (EP-A 234 242);
 
triadimefon, 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1H-1,2,4-triazol-1-yl)-2-butanone (BE 793 867);
 
triadimenol, β-(4-chlorophenoxy)-α-(1,1-dimethylethyl)-1H-1,2,4-triazole-1-ethanol (DE-A 23 24 010);
 
triflumizole, (4-chloro-2-trifluoromethylphenyl)-(2-propoxy-1-[1,2,4]triazol-1-ylethyliden)-amine (JP-A 79/119 462);
 
triticonazole, (5E)-5-[(4-chlorophenyl)methylene]-2,2-dimethyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol (FR 26 41 277);
 
iprodione, N-isopropyl-3-(3,5-dichlorophenyl)-2,4-dioxoimidazolidine-1-carboxamide (GB 13 12 536);
 
myclozolin, (RS)-3-(3,5-dichlorophenyl)-5-methoxymethyl-5-methyl-1,3-oxazolidine-2,4-dione [CAS RN 54864-61-8]; procymidone, N-(3,5-dichlorophenyl)-1,2-dimethylcyclopropane-1,2-dicarboximide (U.S. Pat. No. 3,903,090);
 
vinclozolin, 3-(3,5-dichlorophenyl)-5-methyl-5-vinyloxazolidine-2,4-dione (DE-A 22 07 576);
 
ferbam, iron(3+) dimethyldithiocarbamate (U.S. Pat. No. 1,972,961);
 
nabam, disodium ethylenebis(dithiocarbamate) (U.S. Pat. No. 2,317,765);
 
maneb, manganese ethylenebis(dithiocarbamate) (U.S. Pat. No. 2,504,404);
 
mancozeb, manganese ethylenebis(dithiocarbamate) polymer complex zinc salt (GB 996 264);
 
metam, methyldithiocarbamic acid (U.S. Pat. No. 2,791,605);
 
metiram, zinc ammoniate ethylenebis(dithiocarbamate) (U.S. Pat. No. 3,248,400);
 
propineb, zinc propylenebis(dithiocarbamate) polymer (BE 611 960);
 
polycarbamate, bis(dimethylcarbamodithioato-κS,κS)[μ-[[1,2-ethanediylbis[carbamo-dithioato-κS,κS]](2-)]]di[zinc] [CAS RN 64440-88-6];
 
thiram, bis(dimethylthiocarbamoyl) disulfide (DE-A 642 532);
 
ziram, dimethyldithiocarbamate [CAS RN 137-30-4];
 
zineb, zinc ethylenebis(dithiocarbamate) (U.S. Pat. No. 2,457,674);
 
anilazine, 4,6-dichloro-N-(2-chlorophenyl)-1,3,5-triazine-2-amine (U.S. Pat. No. 2,720,480);
 
benomyl, N-butyl-2-acetylaminobenzoimidazole-1-carboxamide (U.S. Pat. No. 3,631,176);
 
boscalid, 2-chloro-N-(4′-chlorobiphenyl-2-yl)nicotinamide (EP-A 545 099);
 
carbendazim, methyl (1H-benzimidazol-2-yl)carbamate (U.S. Pat. No. 3,657,443);
 
carboxin, 5,6-dihydro-2-methyl-N-phenyl-1,4-oxathiin-3-carboxamide (U.S. Pat. No. 3,249,499);
 
oxycarboxin, 5,6-dihydro-2-methyl-1,4-oxathiin-3-carboxanilide 4,4-dioxide (U.S. Pat. No. 3,399,214);
 
cyazofamid, 4-chloro-2-cyano-NA, dimethyl-5-(4-methylphenyl)-1H-imidazole-1-sulfon-amide (CAS RN 120116-88-3];
 
dazomet, 3,5-dimethyl-1,3,5-thiadiazinane-2-thione (Bull. Soc. Chim. Fr. Vol. 15, p. 891 (1897));
 
diflufenzopyr, 2-{1-[4-(3,5-difluorophenyl)semicarbazono]ethyl}nicotinic acid [CAS RN 109293-97-2];
 
dithianon, 5,10-dioxo-5,10-dihydronaphtho[2,3-b][1,4]dithiin-2,3-dicarbonitrile (GB 857 383);
 
famoxadone, (RS)-3-anilino-5-methyl-5-(4-phenoxyphenyl)-1,3-oxazolidine-2,4-dione [CAS RN 131807-57-3);
 
fenamidone, (S)-1-anilino-4-methyl-2-methylthio-4-phenyl]midazolin-5-one [CAS RN 161326-34-7];
 
fenarimol, α-(2-chlorophenyl)-α-(4-chlorophenyl)-5-pyrimidinemethanol (GB 12 18 623);
 
fuberidazole, 2-(2-furanyl)-1 benzimidazole (DE-A 12 09 799);
 
flutolanil, α,α,α-trifluoro-3′-isopropoxy-o-toluanilide (JP 1104514);
 
furametpyr, 5-chloro-N-(1,3-dihydro-1,1,3-trimethyl-4-isobenzofuranyl)-1,3-dimethyl-1H-pyrazole-4-carboxamide [CAS RN 123572-88-3];
 
isoprothiolane, diisopropyl 1,3-dithiolan-2-ylidenemalonate (Proc. Insectic. Fungic. Conf. 8. Vol. 2, p. 715 (1975));
 
mepronil, 3′-isopropoxy-o-toluanilide (U.S. Pat. No. 3,937,840);
 
nuarimol, α-(2-chlorophenyl)-α-(4-fluorophenyl)-5-pyrimidinemethanol (GB 12 18 623); fluopicolide (picobenzamid), 2,6-dichloro-N-(3-chloro-5-trifluoromethylpyridin-2-ylmethyl)benzamide (WO 99/42447);
 
probenazole, 3-allyloxy-1,2-benzothiazole 1,1-dioxide (Agric. Biol. Chem. Vol. 37, p. 737 (1973));
 
proquinazid, 6-iodo-2-propoxy-3-propylquinazolin-4(3H)-one (WO 97/48684);
 
pyrifenox, 2′,4-d-ichloro-2-(3-pyridyl)acetophenone (EZ)-O-methyloxime (EP 49 854); pyroquilon, 1,2,5,6-tetrahydropyrrolo[3,2,1-ij]quinolin-4-one (GB 139 43 373); quinoxyfen, 5,7-dichloro-4-(4-fluorophenoxy)quinoline (U.S. Pat. No. 5,240,940); silthiofam, N-allyl-4,5-dimethyl-2-(trimethylsilyl)thiophene-3-carboxamide [CAS RN 175217-20-6];
 
thiabendazole, 2-(1,3-thiazol-4-yl)benzimidazole (U.S. Pat. No. 3,017,415);
 
thifluzamide, 2′,6′-dibromo-2-methyl-4′-trifluoromethoxy-4-trifluoromethyl-1,3-thiazole-5-carboxanilide [CAS RN 130000-40-7];
 
thiophanate-methyl, 1,2-phenylenebis(iminocarbonothioyl)bis(dimethylcarbamate) (DE-A 19 30 540);
 
tiadinil, 3′-chloro-4,4′-dimethyl-1,2,3-thiadiazole-5-carboxanilide [CAS RN 223580-51-6];
 
tricyclazole, 5-methyl-1,2,4-triazolo[3,4-b][1,3]benzothiazole [CAS RN 41814-78-2];
 
triforine, N,N-{piperazine-1,4-diylbis[(trichloromethyl)methylene]}diformamide (DE-A 19 01 421);
 
5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine (WO 98/46607);
 
Bordeaux mixture, mixture of CuSO 4 ×3Cu(OH) 2 ×3CaSO 4  [CAS RN 8011-63-0] copper acetate, Cu(OCOCH 3 ) 2  [CAS RN 8011-63-0];
 
copper oxychloride, Cu 2 Cl(OH) 3  [CAS RN 133240-7];
 
basic copper sulfate, CuSO 4  [CAS RN 1344-73-6];
 
binapacryl, (RS)-2-seo-butyl-4,6-dinitrophenyl 3-methylcrotonate [CAS RN 485-31-4];
 
dinocap, the mixture of 2,6-dinitro-4-octylphenylcrotonate and 2,4-dinitro-6-octyl-phenylcrotonate, where “octyl” is a mixture of 1-methylheptyl, 1-ethylhexyl and 1-propylpentyl (U.S. Pat. No. 2,526,660);
 
dinobuton, (RS)-2-seo-butyl-4,6-dinitrophenyl isopropyl carbonate [CAS RN 973-21-7];
 
nitrothal-isopropyl, diisopropyl 5-nitroisophthalate (Proc. Br. Insectic. Fungic. Conf. 7, Vol. 2, p. 673 (1973));
 
fenpiclonil, 4-(2,3-dichlorophenyl)-1H-pyrrole-3-carbonitrile (Proc. 1988 Br. Crop Prot. Conf.—Pests Dis., Vol. 1, p. 65);
 
fludioxonil, 4-(2,2-difluorobenzo[1,3]dioxol-4-yl)-1H-pyrrole-3-carbonitrile (The Pesticide Manual, publ. The British Crop Protection Council, 10 th  ed. 1995, p. 482);
 
acibenzolar-5-methyl, methyl 1,2,3-benzothiadiazole-7-carbothioate [CAS RN 135158-54-2];
 
flubenthiavalicarb (benthiavalicarb), isopropyl {(S)-1-[(1R)-1-(6-fluorobenzothiazol-2-yl)-ethylcarbamoyl]-2-methylpropyl}carbamate (JP-A 09/323,984);
 
carpropamid, 2,2-dichloro-N-[1-(4-chlorophenyl)ethyl]-1-ethyl-3-methylcyclopropane-carboxamide [CAS RN 104030-54-8];
 
chlorothalonil, 2,4,5,6-tetrachloroisophthalonitrile (U.S. Pat. No. 3,290,353); cyflufenamid, (2)-N-[α-(cyclopropylmethoxyimino)-2,3-difluoro-6-(trifluoromethyl)benzyl]-2-phenylacetamide (WO 96/19442);
 
cymoxanil, 1-(2-cyano-2-methoxyiminoacetyl)-3-ethylurea (U.S. Pat. No. 3,957,847);
 
diclocymet, (RS)-2-cyano-N-[1-1-(2,4-dichlorophenyl)ethyl]-3,3-dimethylbutyramide [CAS RN 139920-32-4];
 
diethofencarb, isopropyl 3,4-diethoxycarbanilate (EP-A 78 663); edifenphos, O-ethyl S,S-diphenyl phosphorodithioate (DE-A 14 93 736) ethaboxam, N-(cyano-2-thienylmethyl)-4-ethyl-2-(ethylamino)-5-thiazolecarboxamide (EP-A 639 574);
 
fenhexamid, N-(2,3-dichloro-4-hydroxyphenyl)-1-methylcyclohexanecarboxamide (Proc. Br. Crop Prot. Conf.—Pests Dis., 1998, Vol. 2, p. 327);
 
fentin acetate, triphenyltin (U.S. Pat. No. 3,499,086); fenoxanil, N-(1-cyano-1,2-dimethylpropyl)-2-(2,4-dichlorophenoxy)propanamide (EP-A 262 393);
 
ferimzone, (2)-2′-methylacetophenone-4,6-dimethylpyrimidin-2-ylhydrazone [CAS RN 89269-64-7];
 
fluazinam, 3-chloro-N-[3-chloro-2,6-dinitro-4-(trifluoromethyl)phenyl]-5-(trifluoromethyl)-2-pyridinamine (The Pesticide Manual, publ. The British Crop Protection Council, 10th ed. (1995), p. 474);
 
fosetyl, fosetyl-aluminum, ethylphosphonate (FR 22 54 276); iprovalicarb, isopropyl [(1S)-2-methyl-1-(1-p-tolylethylcarbamoyl)propyl]carbamate (EP-A 472 996);
 
hexachlorobenzene (C. R. Seances Acad. Agric. Fr., Vol. 31, p. 24 (1945));
 
mandipropamid, (RS)-2-(4-chlorophenyl)-N-[3-methoxy-4-(prop-2-ynyloxy)phenethyl]-2-(prop-2-ynyloxy)acetamide (WO 03/042166);
 
metrafenone, 3′-bromo-2,3,4,6′-tetramethoxy-2′,6-dimethylbenzophenone (U.S. Pat. No. 5,945,567);
 
pencycuron, 1-(4-chlorobenzyl)-1-cyclopentyl-3-phenylurea (DE-A 27 32 257);
 
penthiopyrad, (RS)-N-[2-(1,3-dimethylbutyl)-3-thienyl]-1-methyl-3-(trifluoromethyl)-1H-pyrazole-4-carboxamide (JP 10/130,268);
 
propamocarb, isopropyl 3-(dimethylamino)propylcarbamate (DE-A 15 67 169);
 
phthalide (DE-A 16 43 347);
         toloclofos-methyl, O-2,6-dichloro-p-tolyl O,O-dimethyl phosphorothioate (GB 14 67 561);
 
quintozene, pentachloronitrobenzene (DE-A 682 048);
 
zoxamide, (RS)-3,5-dichloro-N-(3-chloro-1-ethyl-1-methyl-2-oxopropyl)-p-toluamide [CAS RN 156052-68-5];
 
captafol, N-(1,1,2,2-tetrachloroethylthio)cyclohex-4-ene-1,2-dicarboximide (Phytopathology, Vol. 52, p. 754 (1962));
 
captan, N-(trichloromethylthio)cyclohex-4-ene-1,2-dicarboximide (U.S. Pat. No. 2,553,770); dichlofluanid, N-dichlorofluoromethylthio-N′,N′-dimethyl-N-phenylsulfamide (DE-A 11 93 498);
 
folpet, N-(trichloromethylthio)phthalimide (U.S. Pat. No. 2,553,770); tolylfluanid, N-dichlorofluoromethylthio-N′,N′-dimethyl-N-tolylsulfamide (DE-A 11 93 498);
 
dimethomorph, 3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)-1-morpholin-4-yl-propenone (EP-A 120 321);
 
flumetover, 2-(3,4-dimethoxyphenyl)-N-ethyl-α,α,α-trifluoro-N-methyl-p-toluamide [AGROW no. 243,22 (1995)];
 
flumorph, 3-(4-fluorophenyl)-3-(3,4-dimethoxyphenyl)-1-morpholin-4-ylpropenone (EP-A 860 438), N-(4′-bromobiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide, N-(4′-trifluoromethylbiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide, N-(4′-chloro-3′-fluorobiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide, N-(3′,4′-dichloro-4-fluorobiphenyl-2-yl)-3-difluoromethyl-1-methylpyrazole-4-carboxamide (WO 03/66610), N-(2-cyanophenyl)-3,4-dichloroisothiazole-5-carboxamide (WO 99/24413);
 
N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-methane-sulfonylamino-3-methylbutyramide, N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-ethanesulfonylamino-3-methylbutyramide (WO 04/49804);
 
3-[5-(4-chlorophenyl)-2,3-dimethylisoxazolidin-3-yl]pyridine (EP-A 10 35 122);
 
2-butoxy-6-iodo-3-propylchromen-4-one (WO 03/14103);
 
N,N-dimethyl-3-(3-bromo-6-fluoro-2-methylindole-1-sulfonyl)-[1,2,4]triazole-1-sulfonamide (EP-A 10 31 571);
 
methyl (2-chloro-5-[1-(3-methylbenzyloxyimino)ethyl]benzyl)carbamate, methyl (2-chloro-5-[1-(6-methylpyridin-2-ylmethoxyimino)ethyl]benzyl)carbamate (EP-A 12 01 648);
 
methyl 3-(4-chlorophenyl)-3-(2-isopropoxycarbonylamino-3-methylbutyrylamino)-propionate (EP-A 10 28 125);
 
azoxystrobin, methyl 2-{2-[6-(2-cyano-1-vinylpenta-1,3-dienyloxy)pyrimidin-4-yloxy]phenyl}-3-methoxyacrylate (EP-A 382 375), dimoxystrobin, (E)-2-(methoxyimino)-N-methyl-2-[α-(2,5-xylyloxy)-o-tolyl]acetamide (EP-A 477 631);
 
fluoxastrobin, (E)-{2-[6-(2-chlorophenoxy)-5-fluoropyrimidin-4-yloxy]phenyl}(5,6-dihydro-1,4,2-dioxazin-3-yl)methanone O-methyloxime (WO 97/27189);
 
kresoxim-methyl, methyl (E)-methoxyimino[α-(o-tolyloxy)-o-tolyl]acetate (EP-A 253 213);
 
metominostrobin, (E)-2-(methoxyimino)-N-methyl-2-(2-phenoxyphenyl)acetamide (EP-A 398 692);
 
orysastrobin, (2E)-2-(methoxyimino)-2-{2-[(3E,5E,6E)-5-(methoxyimino)-4,6-dimethyl-2,8-dioxa-3,7-diazanona-3,6-dien-1-yl]phenyl}-N-methylacetamide (WO 97/15552);
 
picoxystrobin, methyl 3-methoxy-2-[2-(6-trifluoromethylpyridin-2-yloxymethyl)phenyl]-acrylate (EP-A 278 595);
 
pyraclostrobin, methyl N-{2-[1-(4-chlorophenyl)-1H-pyrazol-3-yloxymethyl]phenyl}(N-methoxy)carbamate (WO 96/01256);
 
trifloxystrobin, methyl (E)-methoxyimino-{(E)-α-[1-(α,α,α-trifluoro-m-tolyl)ethylidene-aminooxy]-o-tolyl}aceate (EP-A 460 575);
 
methyl 2-[ortho-(2,5-dimethylphenyloxymethylene)phenyl]-3-methoxyacrylate (EP-A 226 917);
 
5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine (WO 98/46608);
 
3,4-dichloro-N-(2-cyanophenyl)isothiazole-5-carboxamide (WO 99/24413), compounds of the formula III (WO 04/049804);
 
N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-methanesulfonylamino-3-methylbutyramide and N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxyphenyl)ethyl)-2-ethanesulfonylamino-3-methylbutyramide (WO 03/66609);
 
2-butoxy-6-iodo-3-propylchromen-4-one of the formula IV (WO 03/14103);
 
N,N-dimethyl-3-(3-bromo-6-fluoro-2-methylindole-1-sulfonyl)-[1,2,4]triazole-1-sulfonamide of the formula V (WO 03/053145);
 
methyl 3-(4-chlorophenyl)-3-(2-isopropoxycarbonylamino-3-methylbutyrylamino)-propanoate of the formula VI (EP-A 1028125).
       

     It was an object of the present invention, with a view to reducing the application rates and broadening the activity spectrum of the active compounds I and II, to provide mixtures which, at a reduced total amount of active compounds applied, have improved activity against harmful fungi, in particular for certain indications. 
     We have accordingly found the mixtures, defined at the outset, of the active compounds I and II. Moreover, we have found that simultaneous, that is joint or separate, application of at least the compound I and at least one of the active compounds II or of the compound(s) I and at least one of the active compounds II successively allows better control of harmful fungi than is possible with the individual compounds alone (synergistic mixtures). 
     The compounds I can be used as synergists for a large number of different fungicidally active compounds. By simultaneous, that is joint or separate, application of compound(s) I with at least one active compound II, the fungicidal activity is increased in a superadditive manner. 
     The compounds I may be present in various crystal modifications whose biological activity may differ. 
     In formula I, halogen is fluorine, chlorine, bromine or iodine, preferably fluorine or chlorine. 
     C 1 -C 4 -Alkyl is methyl, ethyl, n-propyl, 1-methylethyl, n-butyl, 1-methylpropyl, 2-methylpropyl or 1,1-dimethylethyl, preferably methyl or ethyl. 
     C 1 -C 6 -Alkyl is a C 1 -C 4 -alkyl radical as mentioned above, or is n-pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 2,2-dimethylpropyl, 1-ethylpropyl, n-hexyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 1-methylpentyl, 2-methylpentyl, 3-methylpentyl, 4-methylpentyl, 1,1-dimethylbutyl, 1,2-dimethylbutyl, 1,3-dimethylbutyl, 2,2-dimethyl-butyl, 2,3-dimethylbutyl, 3,3-dimethylbutyl, 1-ethylbutyl, 2-ethylbutyl, 1,1,2-trimethyl-propyl, 1,2,2-trimethylpropyl, 1-ethyl-1-methylpropyl and 1-ethyl-2-methylpropyl; preferable a C 1 -C 4 -alkyl radical as mentioned above. 
     C 1 -C 4 -Haloalkyl is a partially or fully halogenated C 1 -C 4 -alkyl radical, where the halogen atom(s) is/are in particular fluorine, chlorine and/or bromine, i.e., for example, chloromethyl, bromomethyl, dichloromethyl, trichloromethyl, fluoromethyl, difluoromethyl, trifluoromethyl, chlorofluoromethyl, dichlorofluoromethyl, chlorodifluoromethyl, 1-chloroethyl, 1-bromoethyl, 1-fluoroethyl, 2-fluoroethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, 2-chloro-2-fluoroethyl, 2-chloro-2,2-difluoroethyl, 2,2-dichloro-2-fluoroethyl, 2,2,2-trichloroethyl, pentafluoroethyl, heptafluoropropyl or nonafluorobutyl, in particular halomethyl, with particular preference CH 2 —Cl, CH(Cl) 2 , CH 2 —F, CH(F) 2 , CF 3 , CHFCl, CF 2 Cl or CF(Cl) 2 . 
     C 1 -C 6 -Haloalkyl is a partially or fully halogenated C 1 -C 6 -alkyl radical, where the halogen atom(s) is/are in particular fluorine, chlorine and/or bromine, i.e., for example, a C 1 -C 4 -haloalkyl radical as mentioned above, or is 5-fluoropentyl, 5-chloropentyl, 5-bromopentyl, 5-iodopentyl, 5,5,5-trichloropentyl, undecafluoropentyl, 6-fluorohexyl, 6-chlorohexyl, 6-bromohexyl, 6-iodohexyl, 6,6,6-trichlorohexyl or dodecafluorohexyl; preferably a C 1 -C 4 -haloalkyl radical. 
     The 3-monosubstituted N-biphenylpyrazolecarboxamides of the formula I where X=oxygen are known, for example, from EP-A 589 301, or they can be prepared by the method described therein. 
     The compounds I in which X is sulfur can be prepared, for example, by sulfurization of the corresponding compounds I in which X is oxygen (cf., for example, D. Petrova &amp; K. Jakobcic, Croat. Chem. Acta 48, 49 (1976) and also WO 01/42223). 
     Among the 3-monosubstituted N-biphenylpyrazolecarboxamides I, preference is firstly given to those in which X is oxygen. 
     Secondly, preference is given to those compounds I in which X is sulfur. 
     For the mixtures according to the invention, preference is given to compounds of the formula I in which R 1  is fluorine, chlorine, cyano, methyl, methoxy or trifluoromethyl, R 2  is fluorine, chlorine, methyl or halomethyl and R 3  is hydrogen or halogen. 
     Particular preference is given to compounds of the formula I in which R 1  is fluorine, chlorine, cynao or methoxy and R 2  is fluorine, chlorine, methyl, fluoromethyl, difluoromethyl, chlorofluoromethyl, chlorodifluoromethyl, dichlorofluoromethyl or trifluoromethyl and R 3  is hydrogen, fluorine or chlorine. 
     Very particular preference is given to compounds of the formula I in which R 1  is fluorine or chlorine, R 2  is methyl, fluoromethyl, difluoromethyl, chlorofluoromethyl, chlorodifluoromethyl, dichlorofluoromethyl or trifluoromethyl and R 3  is hydrogen. 
     From among the compounds I according to the invention, preference is given to the compounds listed in Table 1 below. 
     
       
         
           
               
               
               
               
               
               
             
               
                   
                 TABLE 1 
               
               
                   
                   
               
               
                   
                 Number 
                 X 
                 R 1   
                 R 2   
                 R 3   
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
            
               
                   
                 1 
                 ◯ 
                 fluorine 
                 CHF 2   
                 H 
               
               
                   
                 2 
                 ◯ 
                 chlorine 
                 CHF 2   
                 H 
               
               
                   
                 3 
                 ◯ 
                 bromine 
                 CHF 2   
                 H 
               
               
                   
                 4 
                 ◯ 
                 iodine 
                 CHF 2   
                 H 
               
               
                   
                 5 
                 ◯ 
                 methyl 
                 CHF 2   
                 H 
               
               
                   
                 6 
                 ◯ 
                 methoxy 
                 CHF 2   
                 H 
               
               
                   
                 7 
                 ◯ 
                 trifluoromethyl 
                 CHF 2   
                 H 
               
               
                   
                 8 
                 ◯ 
                 trifluoromethoxy 
                 CHF 2   
                 H 
               
               
                   
                 9 
                 ◯ 
                 cyano 
                 CHF 2   
                 H 
               
               
                   
                 10 
                 ◯ 
                 nitro 
                 CHF 2   
                 H 
               
               
                   
                 11 
                 ◯ 
                 fluorine 
                 CF 3   
                 H 
               
               
                   
                 12 
                 ◯ 
                 chlorine 
                 CF 3   
                 H 
               
               
                   
                 13 
                 ◯ 
                 bromine 
                 CF 3   
                 H 
               
               
                   
                 14 
                 ◯ 
                 iodine 
                 CF 3   
                 H 
               
               
                   
                 15 
                 ◯ 
                 methyl 
                 CF 3   
                 H 
               
               
                   
                 16 
                 ◯ 
                 methoxy 
                 CF 3   
                 H 
               
               
                   
                 17 
                 ◯ 
                 trifluoromethyl 
                 CF 3   
                 H 
               
               
                   
                 18 
                 ◯ 
                 trifluoromethoxy 
                 CF 3   
                 H 
               
               
                   
                 19 
                 ◯ 
                 cyano 
                 CF 3   
                 H 
               
               
                   
                 20 
                 ◯ 
                 nitro 
                 CF 3   
                 H 
               
               
                   
                   
               
            
           
         
       
     
     Very particularly preferred compounds of the formula I are N-(3′-fluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide, N-(3′-chlorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide, N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide, N-(3′-cyanobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide, N-(3′-fluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide, N-(3′-chlorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide, N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide, N-(3′-cyanobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide, N-(3′-chlorobiphenyl-2-yl)-1,3-dimethyl-1H-pyrazole-4-carboxamide, N-(3′-chlorobiphenyl-2-yl)-1-methyl-3-fluoromethyl-1H-pyrazole-4-carboxamide, N-(3′-fluorobiphenyl-2-yl)-1-methyl-3-fluoromethyl-1H-pyrazole-4-carboxamide, N-(3′-cyanobiphenyl-2-yl)-1,3-dimethyl-5-fluoro-1H-pyrazole-4-carboxamide, N-(3′-nitrobiphenyl-2-yl)-1,3-dimethyl-5-fluoro-1H-pyrazole-4-carboxamide and N-(3′-trifluoromethylbiphenyl-2-yl)-1,3-dimethyl-5-fluoro-1H-pyrazole-4-carboxamide. 
     Preference is given to mixtures of a compound of the formula I with at least one active compound selected from the group of the A) azoles. 
     Preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the B) strobilurins. 
     Preference is given to mixtures of a compound of the formula I with at least one active compound selected from the group of the C) carboxamides. 
     Preference is furthermore also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the D) heterocyclic compounds. 
     Preference is furthermore also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the E) carbamates. 
     Preference is furthermore also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the F) other fungicides. 
     Preference is furthermore also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the A) azoles selected from the group consisting of cyproconazole, difenoconazole, epoxiconazole, fluquinconazole, flusilazole, flutriafol, metconazole, myclobutanil, penconazole, propiconazole, prothioconazole, triadimefon, triadimenol, tebuconazole, tetraconazole, triticonazole, prochloraz, cyazofamid, benomyl, carbendazim and ethaboxam. 
     Particular preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the A) azoles selected from the group consisting of cyproconazole, difenoconazole, epoxiconazole, fluquinconazole, flusilazole, flutriafol, metconazole, myclobutanil, propiconazole, prothioconazole, triadimefon, triadimenol, tebuconazole, tetraconazole, triticonazole, prochloraz, cyazofamid, benomyl and carbendazim. 
     Very particular preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the A) azoles selected from the group consisting of epoxiconazole, fluquinconazole, flutriafol, metconazole, tebuconazole, triticonazole, prochloraz and carbendazim. 
     Preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the B) strobilurins selected from the group consisting of azoxystrobin, dimoxystrobin, fluoxastrobin, kresoxim-methyl, orysastrobin, picoxystrobin, pyraclostrobin and trifloxystrobin. 
     Particular preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the B) strobilurins selected from the group consisting of kresoxim-methyl, orysastrobin and pyraclostrobin. 
     Very particular preference is also given to mixtures of a compound of the formula I with pyraclostrobin. 
     Preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the C) carboxamides selected from the group consisting of fenhexamid, metalaxyl, mefenoxam, ofurace, dimethomorph, flumorph, fluopicolide (picobenzamid), zoxamide, carpropamid and mandipropamid. 
     Particular preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the C) carboxamides selected from the group consisting of fenhexamid, metalaxyl, mefenoxam, ofurace, dimethomorph, zoxamide and carpropamid. 
     Preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the D) heterocylic compounds selected from the group consisting of fluazinam, cyprodinil, fenarimol, mepanipyrim, pyrimethanil, triforine, fludioxonil, dodemorph, fenpropimorph, tridemorph, fenpropidin, iprodione, vinclozolin, famoxadone, fenamidone, probenazole, 5-chloro-7-(4-methyl-piperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine, proquinazid, acibenzolar-S-methyl, captafol, folpet, fenoxanil, quinoxyfen, in particular fluazinam, cyprodinil, fenarimol, mepanipyrim, pyrimethanil, triforine, fludioxonil, dodemorph, fenpropimorph, tridemorph, fenpropidin, iprodione, vinclozolin, famoxadone, fenamidone, probenazole, proquinazid, acibenzolar-S-methyl, captafol, folpet, fenoxanil and quinoxyfen. 
     Particular preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the D) heterocylic compounds selected from the group consisting of pyrimethanil, dodemorph, fenpropimorph, tridemorph, iprodione, vinciozoiin, 5-chloro-7-(4-metnyipiperidin-1-yl)-6-(2,4,6-trifluoro-phenyl)-[1,2,4]triazolo[1,5-a]pyrimidine and quinoxyfen. 
     Preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the E) carbamates selected from the group consisting of mancozeb, metiram, propineb, thiram, iprovalicarb, flubenthiavalicarb and propamocarb. 
     Particular preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the E) carbamates selected from the group consisting of mancozeb and metiram. 
     Preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the F) other fungicides selected from the group consisting of dithianon, fentin salts, such as fentin acetate, fosetyl, fosetyl-aluminum, phosphorous acid and its salts, chlorothalonil, dichlofluanid, thiophanate-methyl, copper acetate, copper hydroxide, copper oxychloride, basic copper sulfate, sulfur, cymoxanil, metrafenone and spiroxamine. 
     Particular preference is also given to mixtures of a compound of the formula I with at least one active compound selected from the group of the F) other fungicides selected from the group consisting of phosphorous acid and its salts, chlorothalonil and metrafenone. 
     Preference is also given to three-component mixtures of one compound of the formula I with two of the active compounds II mentioned above. 
     Preferred combinations of active compounds are listed in Tables 2 to 8 below: 
     
       
         
           
               
             
               
                 TABLE 2 
               
             
            
               
                   
               
               
                 Active compound combinations of compounds I with active compounds II of group A): 
               
            
           
           
               
               
               
            
               
                   
                   
                 Active 
               
               
                 Mixture 
                 Compounds of the formula I 
                 compound II 
               
               
                   
               
               
                 No. A.1 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H- 
                 epoxiconazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.2 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H- 
                 epoxiconazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.3 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 epoxiconazole 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.4 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H- 
                 epoxiconazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.5 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H- 
                 epoxiconazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.6 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H- 
                 epoxiconazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.7 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 epoxiconazole 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.8 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H- 
                 epoxiconazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.9 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H- 
                 metconazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.10 
                 N-(3-chlorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H- 
                 metconazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.11 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 metconazole 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.12 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H- 
                 metconazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.13 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H- 
                 metconazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.14 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H- 
                 metconazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.15 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 metconazole 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.16 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H- 
                 metconazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.17 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H- 
                 tebuconazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.18 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H- 
                 tebuconazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.19 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 tebuconazole 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.20 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H- 
                 tebuconazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.21 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H- 
                 tebuconazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.22 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H- 
                 tebuconazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.23 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 tebuconazole 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.24 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H- 
                 tebuconazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.25 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H- 
                 fluquinconazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.26 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H- 
                 fluquinconazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.27 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 fluquinconazole 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.28 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H- 
                 fluquinconazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.29 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H- 
                 fluquinconazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.30 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H- 
                 fluquinconazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.31 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 fluquinconazole 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.32 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H- 
                 fluquinconazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.33 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H- 
                 flutriafol 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.34 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H- 
                 flutriafol 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.35 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 flutriafol 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.36 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H- 
                 flutriafol 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.37 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H- 
                 flutriafol 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.38 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H- 
                 flutriafol 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A. 39 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 flutriafol 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.40 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H- 
                 flutriafol 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.41 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H- 
                 triticonazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.42 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H- 
                 triticonazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.43 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 triticonazole 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.44 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H- 
                 triticonazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.45 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H- 
                 triticonazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.46 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H- 
                 triticonazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.47 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 triticonazole 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.48 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H- 
                 triticonazole 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.49 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H- 
                 prochloraz 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.50 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H- 
                 prochloraz 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.51 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 prochloraz 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.52 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H- 
                 prochloraz 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.53 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H- 
                 prochloraz 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.54 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H- 
                 prochloraz 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.55 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 prochloraz 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.56 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H- 
                 prochloraz 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.57 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H- 
                 carbendazim 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.58 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H- 
                 carbendazim 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.59 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 carbendazim 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.60 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H- 
                 carbendazim 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.61 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H- 
                 carbendazim 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.62 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H- 
                 carbendazim 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 No. A.63 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 carbendazim 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. A.64 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H- 
                 carbendazim 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 3 
               
             
            
               
                   
               
               
                 Active compound combinations of compounds I with active compounds II 
               
               
                 of group B): 
               
            
           
           
               
               
               
            
               
                   
                   
                 Active 
               
               
                 Mixture 
                 Compounds of the formula I 
                 compound II 
               
               
                   
               
               
                 No. B.1 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 kresoxim- 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
                 methyl 
               
               
                 No. B.2 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 kresoxim- 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
                 methyl 
               
               
                 No. B.3 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1- 
                 kresoxim- 
               
               
                   
                 methyl-3-trifluoromethyl-1H-pyrazole-4- 
                 methyl 
               
               
                   
                 carboxamide 
               
               
                 No. B.4 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 kresoxim- 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
                 methyl 
               
               
                 No. B.5 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 kresoxim- 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
                 methyl 
               
               
                 No. B.6 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 kresoxim- 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
                 methyl 
               
               
                 No. B.7 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1- 
                 kresoxim- 
               
               
                   
                 methyl-3-difluoromethyl-1H-pyrazole-4- 
                 methyl 
               
               
                   
                 carboxamide 
               
               
                 No. B.8 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 kresoxim- 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
                 methyl 
               
               
                 No. B.9 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 pyraclostrobin 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.10 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 pyraclostrobin 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.11 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1- 
                 pyraclostrobin 
               
               
                   
                 methyl-3-trifluoromethyl-1H-pyrazole-4- 
               
               
                   
                 carboxamide 
               
               
                 No. B.12 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 pyraclostrobin 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.13 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 pyraclostrobin 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.14 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 pyraclostrobin 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.15 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1- 
                 pyraclostrobin 
               
               
                   
                 methyl-3-difluoromethyl-1H-pyrazole-4- 
               
               
                   
                 carboxamide 
               
               
                 No. B.16 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 pyraclostrobin 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.17 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 orysastrobin 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.18 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 orysastrobin 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.19 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1- 
                 orysastrobin 
               
               
                   
                 methyl-3-trifluoromethyl-1H-pyrazole-4- 
               
               
                   
                 carboxamide 
               
               
                 No. B.20 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 orysastrobin 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.21 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 orysastrobin 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.22 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 orysastrobin 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. B.23 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1- 
                 orysastrobin 
               
               
                   
                 methyl-3-difluoromethyl-1H-pyrazole-4- 
               
               
                   
                 carboxamide 
               
               
                 No. B.24 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 orysastrobin 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 4 
               
             
            
               
                   
               
               
                 Active compound combinations of compounds I with active compounds 
               
               
                 II of group C): 
               
            
           
           
               
               
               
            
               
                   
                   
                 Active 
               
               
                 Mixture 
                 Compounds of the formula I 
                 compound II 
               
               
                   
               
               
                 No. C.1 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 dimethomorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. C.2 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 dimethomorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. C.3 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 dimethomorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. C.4 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 dimethomorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. C.5 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 dimethomorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. C.6 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 dimethomorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. C.7 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 dimethomorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. C.8 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 dimethomorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 5 
               
             
            
               
                   
               
               
                 Active compound combinations of compounds I with active compounds II of group D): 
               
            
           
           
               
               
               
            
               
                 Mixture 
                 Compounds of the formula I 
                 Active compound II 
               
               
                   
               
               
                 No. D.1 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 pyrimethanil 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.2 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 pyrimethanil 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.3 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 pyrimethanil 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.4 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 pyrimethanil 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.5 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 pyrimethanil 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.6 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 pyrimethanil 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.7 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 pyrimethanil 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.8 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 pyrimethanil 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.9 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
                 piperidin-1-yl)-6-(2,4,6- 
               
               
                   
                   
                 trifluorophenyl)-[1,2,4]- 
               
               
                   
                   
                 triazolo[1,5-a]pyrimidine 
               
               
                 No. D.10 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
                 piperidin-1-yl)-6-(2,4,6- 
               
               
                   
                   
                 trifluorophenyl)-[1,2,4]- 
               
               
                   
                   
                 triazolo[1,5-a]pyrimidine 
               
               
                 No. D.11 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
                 piperidin-1-yl)-6-(2,4,6- 
               
               
                   
                   
                 trifluorophenyl)-[1,2,4]- 
               
               
                   
                   
                 triazolo[1,5-a]pyrimidine 
               
               
                 No. D.12 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
                 piperidin-1-yl)-6-(2,4,6- 
               
               
                   
                   
                 trifluorophenyl)-[1,2,4]- 
               
               
                   
                   
                 triazolo[1,5-a]pyrimidine 
               
               
                 No. D.13 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
                 piperidin-1-yl)-6-(2,4,6- 
               
               
                   
                   
                 trifluorophenyl)-[1,2,4]- 
               
               
                   
                   
                 triazolo[1,5-a]pyrimidine 
               
               
                 No. D.14 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
                 piperidin-1-yl)-6-(2,4,6- 
               
               
                   
                   
                 trifluorophenyl)-[1,2,4]- 
               
               
                   
                   
                 triazolo[1,5-a]pyrimidine 
               
               
                 No. D.15 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
                 piperidin-1-yl)-6-(2,4,6- 
               
               
                   
                   
                 trifluorophenyl)-[1,2,4]- 
               
               
                   
                   
                 triazolo[1,5-a]pyrimidine 
               
               
                 No. D.16 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 5-chloro-7-(4-methyl- 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
                 piperidin-1-yl)-6-(2,4,6- 
               
               
                   
                   
                 trifluorophenyl)-[1,2,4]- 
               
               
                   
                   
                 triazolo[1,5-a]pyrimidine 
               
               
                 No. D.17 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 dodemorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.18 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 dodemorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.19 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 dodemorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.20 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 dodemorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.21 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 dodemorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.22 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 dodemorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.23 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 dodemorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.24 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 dodemorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.25 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 fenpropimorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.26 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 fenpropimorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.27 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 fenpropimorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.28 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 fenpropimorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.29 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 fenpropimorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.30 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 fenpropimorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.31 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 fenpropimorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.32 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 fenpropimorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.33 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 tridemorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.34 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 tridemorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.35 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 tridemorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.36 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 tridemorph 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.37 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 tridemorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.38 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 tridemorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.39 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 tridemorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.40 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 tridemorph 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.41 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 iprodione 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.42 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 iprodione 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.43 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 iprodione 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.44 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 iprodione 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.45 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 iprodione 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.46 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 iprodione 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.47 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 iprodione 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.48 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 iprodione 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.49 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 vinclozolin 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.50 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 vinclozolin 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.51 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 vinclozolin 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.52 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 vinclozolin 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.53 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 vinclozolin 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.54 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 vinclozolin 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.55 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 vinclozolin 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. D.56 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 vinclozolin 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 6 
               
             
            
               
                   
               
               
                 Active compound combinations of compounds I with active compounds 
               
               
                 II of group E): 
               
            
           
           
               
               
               
            
               
                   
                   
                 Active 
               
               
                 Mixture 
                 Compounds of the formula I 
                 compound II 
               
               
                   
               
               
                 No. E.1 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 mancozeb 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.2 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 mancozeb 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.3 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 mancozeb 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.4 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 mancozeb 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.5 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 mancozeb 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.6 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 mancozeb 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.7 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 mancozeb 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.8 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 mancozeb 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.9 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 metiram 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.10 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 metiram 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.11 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 metiram 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.12 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 metiram 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.13 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 metiram 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.14 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 metiram 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.15 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1-methyl-3- 
                 metiram 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. E.16 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 metiram 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 7 
               
             
            
               
                   
               
               
                 Active compound combinations of compounds I with active compounds 
               
               
                 II of group F): 
               
            
           
           
               
               
               
            
               
                   
                   
                 Active 
               
               
                 Mixture 
                 Compounds of the formula I 
                 compound II 
               
               
                   
               
               
                 No. F.1 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 chlorothalonil 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.2 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 chlorothalonil 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.3 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1- 
                 chlorothalonil 
               
               
                   
                 methyl-3-trifluoromethyl-1H-pyrazole-4- 
               
               
                   
                 carboxamide 
               
               
                 No. F.4 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 chlorothalonil 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.5 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 chlorothalonil 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.6 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 chlorothalonil 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.7 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1- 
                 chlorothalonil 
               
               
                   
                 methyl-3-difluoromethyl-1H-pyrazole-4- 
               
               
                   
                 carboxamide 
               
               
                 No. F.8 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 chlorothalonil 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.9 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 metrafenone 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.10 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 metrafenone 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.11 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1- 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H-pyrazole-4- 
               
               
                   
                 carboxamide 
               
               
                 No. F.12 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 metrafenone 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.13 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 metrafenone 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.14 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 metrafenone 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.15 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1- 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H-pyrazole-4- 
               
               
                   
                 carboxamide 
               
               
                 No. F.16 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 metrafenone 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
               
               
                 No. F.17 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 phosphorous 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
                 acid 
               
               
                 No. F.18 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 phosphorous 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
                 acid 
               
               
                 No. F.19 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1- 
                 phosphorous 
               
               
                   
                 methyl-3-trifluoromethyl-1H-pyrazole-4- 
                 acid 
               
               
                   
                 carboxamide 
               
               
                 No. F.20 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 phosphorous 
               
               
                   
                 trifluoromethyl-1H-pyrazole-4-carboxamide 
                 acid 
               
               
                 No. F.21 
                 N-(3′-fluorobiphenyl-2-yl)-1-methyl-3- 
                 phosphorous 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
                 acid 
               
               
                 No. F.22 
                 N-(3′-chlorobiphenyl-2-yl)-1-methyl-3- 
                 phosphorous 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
                 acid 
               
               
                 No. F.23 
                 N-(3′-trifluoromethylbiphenyl-2-yl)-1- 
                 phosphorous 
               
               
                   
                 methyl-3-difluoromethyl-1H-pyrazole-4- 
                 acid 
               
               
                   
                 carboxamide 
               
               
                 No. F.24 
                 N-(3′-cyanobiphenyl-2-yl)-1-methyl-3- 
                 phosphorous 
               
               
                   
                 difluoromethyl-1H-pyrazole-4-carboxamide 
                 acid 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 8 
               
             
            
               
                   
               
               
                 Active compound combinations of compounds I with two active compounds II: 
               
            
           
           
               
               
               
               
            
               
                   
                   
                 Active compound 
                   
               
               
                 Mixture 
                 Compound of the formula I 
                 II 
                 Active compound II 
               
               
                   
               
               
                 I-II-II.1 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 epoxiconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.2 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 epoxiconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.3 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 epoxiconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.4 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 epoxiconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.5 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 metconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.6 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 metconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.7 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 metconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.8 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 metconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.9 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 triticonazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.10 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 triticonazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.11 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 triticonazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.12 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 triticonazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.13 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 fluquinconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.14 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 fluquinconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.15 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 fluquinconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.16 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 fluquinconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.17 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 prothioconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.18 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 prothioconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.19 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 prothioconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.20 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 prothioconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.21 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 tebuconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.22 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 tebuconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.23 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 tebuconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.24 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 tebuconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.25 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.26 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.27 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.28 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.29 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.30 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.31 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.32 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.33 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.34 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.35 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.36 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.37 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.38 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.39 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.40 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.41 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.42 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.43 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.44 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 pyraclostrobin 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.45 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 epoxiconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.46 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 epoxiconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.47 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 epoxiconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.48 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 epoxiconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.49 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 metconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.50 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 metconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.51 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 metconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.52 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 metconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.53 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 triticonazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.54 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 triticonazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.55 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 triticonazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.56 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 triticonazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.57 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 fluquinconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.58 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 fluquinconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.59 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 fluquinconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.60 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 fluquinconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.61 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 prothioconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.62 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 prothioconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.63 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 prothioconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.64 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 prothioconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.65 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 tebuconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.66 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 tebuconazole 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.67 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 tebuconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.68 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 tebuconazole 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.69 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.70 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.71 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.72 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.73 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.74 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.75 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.76 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.77 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.78 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.79 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.80 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.81 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.82 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.83 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.84 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.85 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.86 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.87 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.88 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 kresoxim-methyl 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.89 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 5-chloro-7-(4- 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                   
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidin 
               
               
                 I-II-II.90 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 5-chloro-7-(4- 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                   
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidin 
               
               
                 I-II-II.91 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 5-chloro-7-(4- 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                   
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidin 
               
               
                 I-II-II.92 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 5-chloro-7-(4- 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                   
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidin 
               
               
                 I-II-II.93 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.94 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.95 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.96 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.97 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.98 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.99 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.100 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.101 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.102 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.103 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.104 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.105 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.106 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.107 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.108 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.110 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.111 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.112 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.113 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.114 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.115 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.116 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.117 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.118 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 iprodione 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.119 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 iprodione 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.120 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 iprodione 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.121 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 iprodione 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.122 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.123 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.124 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.125 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 epoxiconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.126 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 metconazole 
                 5-chloro-7-(4- 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                   
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidin 
               
               
                 I-II-II.127 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 metconazole 
                 5-chloro-7-(4- 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                   
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidin 
               
               
                 I-II-II.128 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 metconazole 
                 5-chloro-7-(4- 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                   
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidin 
               
               
                 I-II-II.129 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 metconazole 
                 5-chloro-7-(4- 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                   
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidin 
               
               
                 I-II-II.130 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 metconazole 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.131 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 metconazole 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.132 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 metconazole 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.133 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 metconazole 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.134 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 metconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.135 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 metconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.136 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 metconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.137 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 metconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.138 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 metconazole 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.139 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 metconazole 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.140 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 metconazole 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.141 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 metconazole 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.142 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 metconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.143 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 metconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.144 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 metconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.145 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 metconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.146 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 metconazole 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.147 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 metconazole 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.148 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 metconazole 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.149 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 metconazole 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.150 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 metconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.151 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 metconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.152 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 metconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.153 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 metconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.154 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 metconazole 
                 iprodione 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.155 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 metconazole 
                 iprodione 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.156 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 metconazole 
                 iprodione 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.157 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 metconazole 
                 iprodione 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.158 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 metconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.159 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 metconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.160 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 metconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.161 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 metconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.162 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 triticonazole 
                 5-chloro-7-(4- 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                   
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidin 
               
               
                 I-II-II.163 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 5-chloro-7-(4- 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                   
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidin 
               
               
                 I-II-II.164 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 triticonazole 
                 5-chloro-7-(4- 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                   
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidin 
               
               
                 I-II-II.165 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 5-chloro-7-(4- 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                   
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidin 
               
               
                 I-II-II.166 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 triticonazole 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.167 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.168 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 triticonazole 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.169 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.170 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 triticonazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.171 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.172 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 triticonazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.173 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.174 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 triticonazole 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.175 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.176 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 triticonazole 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.177 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.178 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 triticonazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.179 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.180 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 triticonazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.181 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.182 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 triticonazole 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.183 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.184 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 triticonazole 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.185 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.186 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 triticonazole 
                 metalaxyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.187 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 metalaxyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.188 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 triticonazole 
                 metalaxyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.189 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 metalaxyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.190 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 triticonazole 
                 iprodione 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.191 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 iprodione 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.192 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 triticonazole 
                 iprodione 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.193 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 iprodione 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.194 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 triticonazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.195 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.196 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 triticonazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.197 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 triticonazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.198 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 5-chloro-7-(4- 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                   
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidin 
               
               
                 I-II-II.199 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 5-chloro-7-(4- 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                   
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidin 
               
               
                 I-II-II.200 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 5-chloro-7-(4- 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                   
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidin 
               
               
                 I-II-II.201 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 5-chloro-7-(4- 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                   
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidin 
               
               
                 I-II-II.202 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.203 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.204 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.205 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.206 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.207 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.208 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.209 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.210 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.211 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.212 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.213 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.214 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.215 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.216 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.217 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.218 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.219 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.220 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.221 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.222 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.223 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.224 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.225 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.226 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 iprodione 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.227 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 iprodione 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.228 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 iprodione 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.229 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 iprodione 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.230 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.231 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.232 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.233 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 fluquinconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.234 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 5-chloro-7-(4- 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                   
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidin 
               
               
                 I-II-II.235 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 5-chloro-7-(4- 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                   
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidin 
               
               
                 I-II-II.236 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 5-chloro-7-(4- 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                   
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidin 
               
               
                 I-II-II.237 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 5-chloro-7-(4- 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                   
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidin 
               
               
                 I-II-II.238 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.239 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.240 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.241 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.242 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.243 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.244 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.245 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.246 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.247 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.248 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.249 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.250 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.251 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.252 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.253 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.254 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.255 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.256 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.257 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.258 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.259 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.260 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.261 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.262 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 iprodione 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.263 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 iprodione 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.264 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 iprodione 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.265 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 iprodione 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.266 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.267 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.268 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.269 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 prothioconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.270 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 5-chloro-7-(4- 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                   
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidin 
               
               
                 I-II-II.271 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 5-chloro-7-(4- 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                   
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidin 
               
               
                 I-II-II.272 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 5-chloro-7-(4- 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                   
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidin 
               
               
                 I-II-II.273 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 5-chloro-7-(4- 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                   
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                   
                 yl)-6-(2,4,6-trifluoro- 
               
               
                   
                   
                   
                 phenyl)-[1,2,4]tri- 
               
               
                   
                   
                   
                 azolo[1,5-a]pyrimidin 
               
               
                 I-II-II.274 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.275 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.276 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.277 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.278 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.279 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.280 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.281 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.282 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.283 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.284 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.285 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.286 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.287 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.288 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.289 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.290 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.291 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.292 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.293 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.294 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.295 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.296 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.297 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 metalaxyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.298 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 iprodione 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.299 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 iprodione 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.300 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 iprodione 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.301 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 iprodione 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.302 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.303 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.304 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.305 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 tebuconazole 
                 pyrimethanil 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
               
               
                   
                 pyrazole-4-carboxamide 
               
               
                 I-II-II.306 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-tri- 
               
               
                   
                   
                 fluorophenyl)- 
               
               
                   
                   
                 [1,2,4]triazolo[1,5- 
               
               
                   
                   
                 a]pyrimidine 
               
               
                 I-II-II.307 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 carbendazim 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-tri- 
               
               
                   
                   
                 fluorophenyl)- 
               
               
                   
                   
                 [1,2,4]triazolo[1,5- 
               
               
                   
                   
                 a]pyrimidine 
               
               
                 I-II-II.308 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-tri- 
               
               
                   
                   
                 fluorophenyl)- 
               
               
                   
                   
                 [1,2,4]triazolo[1,5- 
               
               
                   
                   
                 a]pyrimidine 
               
               
                 I-II-II.309 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 carbendazim 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-tri- 
               
               
                   
                   
                 fluorophenyl)- 
               
               
                   
                   
                 [1,2,4]triazolo[1,5- 
               
               
                   
                   
                 a]pyrimidine 
               
               
                 I-II-II.310 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-tri- 
               
               
                   
                   
                 fluorophenyl)- 
               
               
                   
                   
                 [1,2,4]triazolo[1,5- 
               
               
                   
                   
                 a]pyrimidine 
               
               
                 I-II-II.311 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-tri- 
               
               
                   
                   
                 fluorophenyl)- 
               
               
                   
                   
                 [1,2,4]triazolo[1,5- 
               
               
                   
                   
                 a]pyrimidine 
               
               
                 I-II-II.312 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-tri- 
               
               
                   
                   
                 fluorophenyl)- 
               
               
                   
                   
                 [1,2,4]triazolo[1,5- 
               
               
                   
                   
                 a]pyrimidine 
               
               
                 I-II-II.313 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 thiophanate-methyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-tri- 
               
               
                   
                   
                 fluorophenyl)- 
               
               
                   
                   
                 [1,2,4]triazolo[1,5- 
               
               
                   
                   
                 a]pyrimidine 
               
               
                 I-II-II.314 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-tri- 
               
               
                   
                   
                 fluorophenyl)- 
               
               
                   
                   
                 [1,2,4]triazolo[1,5- 
               
               
                   
                   
                 a]pyrimidine 
               
               
                 I-II-II.315 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 benomyl 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-tri- 
               
               
                   
                   
                 fluorophenyl)- 
               
               
                   
                   
                 [1,2,4]triazolo[1,5- 
               
               
                   
                   
                 a]pyrimidine 
               
               
                 I-II-II.316 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-tri- 
               
               
                   
                   
                 fluorophenyl)- 
               
               
                   
                   
                 [1,2,4]triazolo[1,5- 
               
               
                   
                   
                 a]pyrimidine 
               
               
                 I-II-II.317 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 benomyl 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-tri- 
               
               
                   
                   
                 fluorophenyl)- 
               
               
                   
                   
                 [1,2,4]triazolo[1,5- 
               
               
                   
                   
                 a]pyrimidine 
               
               
                 I-II-II.318 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-tri- 
               
               
                   
                   
                 fluorophenyl)- 
               
               
                   
                   
                 [1,2,4]triazolo[1,5- 
               
               
                   
                   
                 a]pyrimidine 
               
               
                 I-II-II.319 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 fenpropimorph 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-tri- 
               
               
                   
                   
                 fluorophenyl)- 
               
               
                   
                   
                 [1,2,4]triazolo[1,5- 
               
               
                   
                   
                 a]pyrimidine 
               
               
                 I-II-II.320 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-tri- 
               
               
                   
                   
                 fluorophenyl)- 
               
               
                   
                   
                 [1,2,4]triazolo[1,5- 
               
               
                   
                   
                 a]pyrimidine 
               
               
                 I-II-II.321 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 fenpropimorph 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-tri- 
               
               
                   
                   
                 fluorophenyl)- 
               
               
                   
                   
                 [1,2,4]triazolo[1,5- 
               
               
                   
                   
                 a]pyrimidine 
               
               
                 I-II-II.322 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-tri- 
               
               
                   
                   
                 fluorophenyl)- 
               
               
                   
                   
                 [1,2,4]triazolo[1,5- 
               
               
                   
                   
                 a]pyrimidine 
               
               
                 I-II-II.323 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 metrafenone 
               
               
                   
                 methyl-3-trifluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-tri- 
               
               
                   
                   
                 fluorophenyl)- 
               
               
                   
                   
                 [1,2,4]triazolo[1,5- 
               
               
                   
                   
                 a]pyrimidine 
               
               
                 I-II-II.324 
                 N-(3′-chlorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-tri- 
               
               
                   
                   
                 fluorophenyl)- 
               
               
                   
                   
                 [1,2,4]triazolo[1,5- 
               
               
                   
                   
                 a]pyrimidine 
               
               
                 I-II-II.325 
                 N-(3′-fluorobiphenyl-2-yl)-1- 
                 5-chloro-7-(4- 
                 metrafenone 
               
               
                   
                 methyl-3-difluoromethyl-1H- 
                 methylpiperidin-1- 
               
               
                   
                 pyrazole-4-carboxamide 
                 yl)-6-(2,4,6-tri- 
               
               
                   
                   
                 fluorophenyl)- 
               
               
                   
                   
                 [1,2,4]triazolo[1,5- 
               
               
                   
                   
                 a]pyrimidine 
               
               
                   
               
            
           
         
       
     
     The mixtures of compound(s) I and at least one of the active compounds II, or at least one compound I and at least one of the active compounds II applied simultaneously, that is jointly or separately, have excellent activity against a broad spectrum of phytopathogenic fungi, in particular from the class of the Ascomycetes, Basidiomycetes, Deuteromycetes and Peronosporomycetes (syn. Oomycetes). Some of them are systemically effective and can be employed in crop protection as foliar fungicides, as fungicides for seed dressing and as soil fungicides. They can also be used for treating seed. 
     They are particularly important in the control of a multitude of fungi on various cultivated plants, such as wheat, rye, barley, oats, rice, corn, lawns, bananas, cotton, soybean, coffee, sugar cane, grapevines, fruits and ornamental plants, and vegetables such as cucumbers, beans, tomatoes, potatoes and cucurbits, and on the seeds of these plants. 
     They are especially suitable for controlling the following plant diseases:
           Alternaria  species on vegetables, oilseed rape, sugar beet and fruit and rice, for example,  A. solani  or  A. alternata  on potatoes and tomatoes;     Aphanomyces  species on sugar beet and vegetables;     Ascochyta  species on cereals and vegetables;     Bipolaris  and  Drechslera  species on corn, cereals, rice and lawns, for example,  D. maydis  on corn;     Blumeria graminis  (powdery mildew) on cereals;     Botrytis cinerea  (gray mold) on strawberries, vegetables, flowers and grapevines;     Bremia lactucae  on lettuce;     Cercospora  species on corn, soybeans, rice and sugar beet;     Cochliobolus  species on corn, cereals, rice, for example  Cochliobolus sativus  on cereals,  Cochliobolus miyabeanus  on rice;     Colletotricum  species on soybeans and cotton;     Drechslera  species,  Pyrenophora  species on corn, cereals, rice and lawns, for example,  D. teres  on barley or  D. tritici - repentis  on wheat;     Esca  on grapevines, caused by  Phaeoacremonium chlamydosporium, Ph. Aleophilum  and  Formitipora punctata  (syn.  Phellinus punctatus );     Exserohilum  species on corn;     Erysiphe cichoracearum  and  Sphaerotheca fuliginea  on cucumbers;     Fusarium  and  Verticillium  species on various plants, for example,  F. graminearum  or  F. culmorum  on cereals or  F. oxysporum  on a multitude of plants, such as, for example, tomatoes;     Gaeumanomyces graminis  on cereals;     Gibberella  species on cereals and rice (for example  Gibberella fujikuroi  on rice);     Grainstaining  complex on rice;     Helminthosporium  species on corn and rice;     Michrodochium nivale  on cereals;     Mycosphaerella  species on cereals, bananas and peanuts, for example,  M. graminicola  on wheat or  M. fijiensis  on bananas;     Peronospora  species on cabbage and bulbous plants, for example,  P. brassicae  on cabbage or  P. destructor  on onions;     Phakopsara pachyrhizi  and  Phakopsara meibomiae  on soybeans;     Phomopsis  species on soybeans and sunflowers;     Phytophthora infestans  on potatoes and tomatoes;     Phytophthora  species on various plants, for example,  P. capsici  on bell pepper;     Plasmopara viticola  on grapevines;     Podosphaera leucotricha  on apples;     Pseudocercosporella herpotrichoides  on cereals;     Pseudoperonospora  on various plants, for example,  P. cubensis  on cucumber or  P. humili  on hops;     Puccinia  species on various plants, for example,  P. triticina, P. striformins, P. hordei  or  P. graminis  on cereals or  P. asparagi  on asparagus;     Pyricularia oryzae, Corticium sasakii, Sarocladium oryzae, S. aftenuatum, Entyloma oryzae  on rice;     Pyricularia grisea  on lawns and cereals;     Pythium  spp. on lawns, rice, corn, cotton, oilseed rape, sunflowers, sugar beet, vegetables and other plants, for example,  P. ultiumum  on various plants,  P. aphanidermatum  on lawns;     Rhizoctonia  species on cotton, rice, potatoes, lawns, corn, oilseed rape, sugar beet, vegetables and on various plants, for example,  R. solani  on beet and various plants;     Rhynchosporium secalis  on barley, rye and triticale;     Sclerotinia  species on oilseed rape and sunflowers;     Septoria tritici  and  Stagonospora nodorum  on wheat;     Erysiphe  (syn.  Uncinula ) necator on grapevines;     Setospaeria  species on corn and lawns;     Sphacelotheca reilinia  on corn;     Thievaliopsis  species on soybeans and cotton;     Tilletia  species on cereals;     Ustilago  species on cereals, corn and sugar cane, for example,  U. maydis  on corn;     Venturia  species (scab) on apples and pears, for example,  V. inaequalis  on apples.       

     The mixtures according to the invention are also suitable for controlling harmful fungi in the protection of materials (for example wood, paper, paint dispersions, fibers or fabrics) and in the protection of stored products. In the protection of wood, particular attention is paid to the following harmful fungi: Ascomycetes, such as  Ophiostoma  spp.,  Ceratocystis  spp.,  Aureobasidium pullulans, Sclerophoma  spp.,  Chaetomium  spp.,  Humicola  spp.,  Petriella  spp.,  Trichurus  spp.; Basidiomycetes, such as  Coniophora  spp.,  Coriolus  spp.,  Gloeophyllum  spp.,  Lentinus  spp.,  Pleurotus  spp.,  Poria  spp.,  Serpula  spp. and  Tyromyces  spp., Deuteromycetes, such as  Aspergillus  spp.,  Cladosporium  spp.,  Penicillium  spp.,  Trichoderma  spp.,  Alternaria  spp.,  Paecilomyces  spp. and Zygomycetes, such as  Mucor  spp., additionally in the protection of materials the following yeasts:  Candida  spp. and  Saccharomyces cerevisae.    
     The compound(s) I and at least one of the active compounds II can be applied simultaneously, that is jointly or separately, or in succession, the order in the case of separate application generally not having any effect on the control result. 
     When providing the mixtures, preference is given to using the pure active compounds I to II, to which further active compounds against harmful fungi or against other pests such as insects, arachnids or nematodes or else herbicidally active or growth-regulating active compounds or fertilizers may be added. 
     Such mixtures of three active compounds consist, for example, of a compound of the formula I, in particular N-(3′-fluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide, N-(3′-chlorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide, N-(3′-fluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide or N-(3′-chlorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide, an azole from group A), in particular epoxiconazole, metconazole, triticonazole or fluquinconazole, and an insecticide, particularly suitable insecticides being fipronil and neonicotinoides such as acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid and thiamethoxam. 
     Usually, mixtures of at least one compound I and at least one active compound II are employed. Here, mixtures of at least one compound I with two or, if desired, more active components may offer particular advantages. 
     Suitable further active components in the above sense are in particular the active compounds II, mentioned at the outset, and in particular the preferred active compounds II mentioned above. 
     The compound(s) I and the active compound(s) II are usually employed in a weight ratio of from 100:1 to 1:100, preferably from 20:1 to 1:20, in particular from 10:1 to 1:10. 
     The further active components are, if desired, added in a ratio of from 20:1 to 1:20 to the compound I. 
     Depending on the type of compounds I and II and the desired effect, the application rates of the mixtures according to the invention, in particular in the case of agricultural crop areas, are from 5 g/ha to 2000 g/ha, preferably from 20 to 1500 g/ha, in particular from 50 to 1000 g/ha. 
     Correspondingly, the application rates for the compound(s) I are generally from 1 to 1000 g/ha, preferably from 1 to 900 g/ha, in particular from 20 to 750 g/ha. 
     Correspondingly, the application rates for the active compounds II are generally from 1 to 2000 g/ha, preferably from 10 to 1500 g/ha, in particular from 40 to 1000 g/ha. 
     In the treatment of seed, application rates of mixture are generally from 1 to 1000 g per 100 kg of seed, preferably from 1 to 750 g per 100 kg, in particular from 5 to 500 g per 100 kg of seed. 
     The method for controlling harmful fungi is carried out by the separate or joint application of compound(s) I and at least one of the active compounds II or a mixture of compound(s) I and at least one of the active compounds II by spraying or dusting the seeds, the plants or the soils before or after sowing of the plants or before or after emergence of the plants. 
     The fungicidal, synergistic mixtures according to the invention, or the compound(s) I and at least one of the active compounds II, can be converted into the customary formulations, for example solutions, emulsions, suspensions, dusts, powders, pastes or granules. The use form depends on the particular intended purpose; in each case, it should ensure as fine and even a distribution as possible of the mixture according to the invention. 
     The formulations are prepared in a manner known per se, for example by extending the active compounds with solvents and/or carriers, if desired using emulsifiers and dispersants. Solvents/auxiliaries suitable for this purpose are essentially:
         water, aromatic solvents (for example Solvesso® products, xylene), paraffins (for example mineral oil fractions), alcohols (for example methanol, butanol, pentanol, benzyl alcohol), ketones (for example cyclohexanone, gamma-butyrolactone), pyrrolidones (N-methylpyrrolidone, N-octylpyrrolidone), acetates (glycol diacetate), glycols, fatty acid dimethylamides, fatty acids and fatty acid esters. In principle, solvent mixtures may also be used,   carriers such as ground natural minerals (for example kaolins, clays, talc, chalk) and ground synthetic minerals (for example finely divided silica, silicates); emulsifiers such as nonionogenic and anionic emulsifiers (for example polyoxyethylene fatty alcohol ethers, alkylsulfonates and arylsulfonates) and dispersants such as lignosulfite waste liquors and methylcellulose.       

     Suitable surfactants are alkali metal, alkaline earth metal and ammonium salts of lignosulfonic acid, naphthalenesulfonic acid, phenolsulfonic acid, dibutylnaphthalene-sulfonic acid, alkylarylsulfonates, alkyl sulfates, alkylsulfonates, fatty alcohol sulfates, fatty acids and sulfated fatty alcohol glycol ethers, furthermore condensates of sulfonated naphthalene and its derivatives with formaldehyde, condensates of naphthalene or of naphthalenesulfonic acid with phenol and formaldehyde, polyoxyethylene octylphenol ether, ethoxylated isooctylphenol, octylphenol, nonylphenol, alkylphenol polyglycol ethers, tributylphenyl polyglycol ether, tristearylphenyl polyglycol ether, alkylaryl polyether alcohols, alcohol and fatty alcohol/ethylene oxide condensates, ethoxylated castor oil, polyoxyethylene alkyl ethers, ethoxylated polyoxypropylene, lauryl alcohol polyglycol ether acetal, sorbitol esters, lignosulfite waste liquors and methylcellulose. 
     Suitable for the preparation of directly sprayable solutions, emulsions, pastes or oil dispersions are mineral oil fractions of medium to high boiling point, such as kerosene or diesel oil, furthermore coal tar oils and oils of vegetable or animal origin, aliphatic, cyclic and aromatic hydrocarbons, for example toluene, xylene, paraffin, tetrahydronaphthaiene, alkylated naphthaienes or their derivatives, methanol, ethanol, propanol, butanol, cyclohexanol, cyclohexanone, isophorone, strongly polar solvents, for example dimethyl sulfoxide, N-methylpyrrolidone and water. 
     Powders, materials for spreading and dustable products can be prepared by mixing or concomitantly grinding the active substances with at least one solid carrier. 
     Granules, for example coated granules, impregnated granules and homogeneous granules, can be prepared by binding the active compounds to at least one solid carrier. Examples of solid carriers are mineral earths such as silica gels, silicates, talc, kaolin, attaclay, limestone, lime, chalk, bole, loess, clay, dolomite, diatomaceous earth, calcium sulfate, magnesium sulfate, magnesium oxide, ground synthetic materials, fertilizers, such as, ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas, and products of vegetable origin, such as cereal meal, tree bark meal, wood meal and nutshell meal, cellulose powders and other solid carriers. 
     In general, the formulations comprise from 0.01 to 95% by weight, preferably from 0.1 to 90% by weight, of the compound(s) I and at least one of the active compounds II or if the mixture of the compound(s) I with at least one active compound II. The active compounds are employed in a purity of from 90% to 100%, preferably 95% to 100% (according to NMR or HPLC spectrum). 
     The following are examples of formulations according to the invention: 1. Products for dilution with water 
     A) Water-Soluble Concentrates (SL) 
     10 parts by weight of a mixture according to the invention are dissolved in 90 parts by weight of water or a water-soluble solvent. As an alternative, wetting agents or other auxiliaries are added. The active compound dissolves upon dilution with water. This gives a formulation having an active compound content of 10% by weight. 
     B) Dispersible Concentrates (DC) 
     20 parts by weight of a mixture according to the invention are dissolved in 70 parts by weight of cyclohexanone with addition of 10 parts by weight of a dispersant, for example polyvinylpyrrolidone. Dilution with water gives a dispersion. The active compound content is 20% by weight. 
     C) Emulsifiable Concentrates (EC) 
     15 parts by weight of a mixture according to the invention are dissolved in 75 parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight). Dilution with water gives an emulsion. The formulation has an active compound content of 15% by weight. 
     D) Emulsions (EW, EO) 
     25 parts by weight of a mixture according to the invention are dissolved in 35 parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight). This mixture is introduced into 30 parts by weight of water by means of an emulsifying machine (e.g. Ultraturrax) and made into a homogeneous emulsion. Dilution with water gives an emulsion. The formulation has an active compound content of 25% by weight. 
     E) Suspensions (SC, OD) 
     In an agitated ball mill, 20 parts by weight of a mixture according to the invention are comminuted with addition of 10 parts by weight of dispersants and wetting agent and 70 parts by weight of water or an organic solvent to give a fine active compound suspension. Dilution with water gives a stable suspension of the active compound. The active compound content in the formulation is 20% by weight. 
     F) Water-Dispersible Granules and Water-Soluble Granules (WG, SG) 
     50 parts by weight of a mixture according to the invention are ground finely with addition of 50 parts by weight of dispersants and wetting agent and prepared as water-dispersible or water-soluble granules by means of technical appliances (for example extrusion, spray tower, fluidized bed). Dilution with water gives a stable dispersion or solution of the active compound. The formulation has an active compound content of 50% by weight. 
     G) Water-Dispersible Powders and Water-Soluble Powders (WP, SP) 
     75 parts by weight of a mixture according to the invention are ground in a rotor-stator mill with addition of 25 parts by weight of dispersants, wetting agent and silica gel. Dilution with water gives a stable dispersion or solution of the active compound. The active compound content of the formulation is 75% by weight. 
     2. Products to be Applied Undiluted 
     H) Dustable Powders (DP) 
     5 parts by weight of a mixture according to the invention are ground finely and mixed intimately with 95 parts by weight of finely divided kaolin. This gives a dustable product having an active compound content of 5% by weight. 
     J) Granules (GR, FG, GG, MG) 
     0.5 part by weight of a mixture according to the invention is ground finely and associated with 99.5 parts by weight of carriers. Current methods are extrusion, spray-drying or the fluidized bed. This gives granules to be applied undiluted having an active compound content of 0.5% by weight. 
     K) ULV Solutions (UL) 
     10 parts by weight of a mixture according to the invention are dissolved in 90 parts by weight of an organic solvent, for example xylene. This gives a product to be applied undiluted having an active compound content of 10% by weight. 
     The active compounds can be used as such, in the form of their formulations or the use forms prepared therefrom, for example in the form of directly sprayable solutions, powders, suspensions or dispersions, emulsions, oil dispersions, pastes, dustable products, materials for spreading, or granules, by means of spraying, atomizing, dusting, spreading or pouring. The use forms depend entirely on the intended purposes; they are intended to ensure in each case the finest possible distribution of the active compounds. 
     Aqueous use forms can be prepared from emulsion concentrates, pastes or wettable powders (sprayable powders, oil dispersions) by adding water. To prepare emulsions, pastes or oil dispersions, the substances, as such or dissolved in an oil or solvent, can be homogenized in water by means of a wetting agent, tackifier, dispersant or emulsifier. However, it is also possible to prepare concentrates composed of active substance, wetting agent, tackifier, dispersant or emulsifier and, if appropriate, solvent or oil, and such concentrates are suitable for dilution with water. 
     The active compound concentrations in the ready-to-use preparations can be varied within relatively wide ranges. In general, they are between 0.0001 and 10%, preferably between 0.01 and 1%. 
     The active compounds may also be used successfully in the ultra-low-volume (ULV) process, by which it is possible to apply formulations comprising over 95% by weight of active compound, or even to apply the active compound without additives. 
     Various types of oils, wetting agent, adjuvants, herbicides, other pesticides, or bactericides may be added to the active compounds, if desired not until immediately prior to use (tank mix). These agents are usually admixed with the mixtures according to the invention in a weight ratio of 1:100 to 100:1, preferably 1:10 to 10:1. 
     Suitable adjuvants in this sense are in particular: organically modified polysiloxanes, for example Break Thru S 240®; alcohol alkoxylates, for example Atplus 245®, Atplus MBA 1303®, Plurafac LF 300® and Lutensol® ON 30; EO/PO block polymers, for example Pluronic® RPE 2035 and Genapol® B; alcohol ethoxylates, for example Lutensol® XP 80; and sodium dioctylsulfosuccinate, for example Leophen® RA. 
     The compounds I and II or the mixtures or the corresponding formulations are applied by treating the harmful fungi, their habitat or the plants, seeds, soils, areas, materials or spaces to be kept free from them with a fungicidally effective amount of the mixture or, in the case of separate application, of the compounds I and II. Application can be carried out before or after infection by the harmful fungi. 
    
    
     PREPARATION EXAMPLES 
     1.) Synthesis of ortho-(3-chlorophenyl)aniline 
     1.82 g of 3-cyanobromobenzene, 2.66 g of 2-aminophenylboronic acid, 2.12 g of sodium carbonate and 0.08 g of tetrakis(triphenylphosphine)palladium(0) were added to a mixture of 38 ml of ethylene glycol dimethyl ether and 13 ml of water. After 6 hours of stirring under reflux, 0.04 g of tetrakis(triphenylphosphine)palladium(0) was added, and stirring under reflux was continued for a further 14 hours. The reaction mixture was then concentrated under reduced pressure and the residue was taken up in methyl tert-butyl ether. The mixture was washed three times with water and the organic phase was dried over magnesium sulfate and concentrated under reduced pressure. Chromato-graphic purification of the crude product using a mixture of cyclohexane and methyl tert-butyl ether (1:1) gave 1.9 g of the product. 
     2.) Synthesis of 1-methyl-3-trifluoromethyl-N-(ortho-(3-cyanophenyl)phenyl)pyrazole-4-carboxamide 
     0.243 g of ortho-(3-cyanophenyl)aniline and 0.15 ml of pyridine were dissolved in 8.5 ml of toluene. After dropwise addition of 0.266 g of 1-methyl-3-trifluoromethylpyrazole-4-carbonyl chloride, the reaction mixture was stirred for 16 hours. 30 ml of tetrahydrofuran and 20 ml of methyl tert-butyl ether were then added. The mixture was washed once with 2% strength hydrochloric acid, twice with 2% strength aqueous sodium hydroxide solution and once with aqueous sodium chloride solution. The organic phase was dried over magnesium sulfate and concentrated under reduced pressure. The crude product obtained in this manner was recrystallized from toluene and washed with pentane. This gave 0.28 g of the product as a colorless powder. M.p. 76-78° C. 
     In addition to the compound described above, Table 9 below lists, in an exemplary manner, further 3-monosubstituted N-biphenyl-pyrazolecarboxamides of the formula I, which compounds were prepared or are preparable in the same manner. 
     
       
         
           
               
               
             
               
                 TABLE 9 
               
             
            
               
                   
               
               
                   
                 Ia 
               
               
                 
                   
                     
                     
                         
                         
                     
                   
                 
               
               
                   
               
            
           
           
               
               
               
               
               
               
            
               
                   
                 Comp. 
                 R 1   
                 R 2   
                 R 3   
                 m.p. 
               
               
                   
                   
               
               
                   
                 I.1 
                 Cl 
                 CF 3   
                 H 
                 92-94° C. 
               
               
                   
                 I.2 
                 F 
                 CF 3   
                 H 
                 125-120° C. 
               
               
                   
                 I.3 
                 CH 3   
                 CF 3   
                 H 
                 97-99° C. 
               
               
                   
                 I.4 
                 CF 3   
                 CF 3   
                 H 
                 132-134° C. 
               
               
                   
                 I.5 
                 CN 
                 CF 3   
                 H 
                 76-78° C. 
               
               
                   
                 I.6 
                 NO 2   
                 CF 3   
                 H 
                 84-87° C. 
               
               
                   
                 I.7 
                 SCF 3   
                 CF 3   
                 H 
                 56-59° C. 
               
               
                   
                 I.8 
                 SCH 3   
                 CF 3   
                 H 
                 94-96° C. 
               
               
                   
                 I.9 
                 CF 3   
                 CHF 2   
                 H 
                 124-125° C. 
               
               
                   
                 I.10 
                 Cl 
                 CH 3   
                 H 
                 104-106° C. 
               
               
                   
                 I.11 
                 Cl 
                 CH 2 F 
                 H 
                 96-99° C. 
               
               
                   
                 I.12 
                 Cl 
                 CHF 2   
                 H 
                 110-112° C. 
               
               
                   
                 I.13 
                 F 
                 CH 2 F 
                 H 
                 138-141° C. 
               
               
                   
                 I.14 
                 F 
                 CHF 2   
                 H 
                 130-135° C. 
               
               
                   
                 I.15 
                 CN 
                 CH 3   
                 F 
                 137-138° C. 
               
               
                   
                 I.16 
                 NO 2   
                 CH 3   
                 F 
                 137-139° C. 
               
               
                   
                 I.17 
                 CF 3   
                 CH 3   
                 F 
                 113-114° C. 
               
               
                   
                   
               
            
           
         
       
     
     Use Example 
     The synergistic action of the mixtures according to the invention was demonstrated by the following tests: 
     The active compounds, separately or jointly, were prepared as a stock solution comprising 25 mg of active compound which was made up to 10 ml using a mixture of acetone and/or dimethyl sulfoxide and the emulsifier Uniperol® EL (wetting agent having an emulsifying and dispersing action based on ethoxylated alkylphenols) in a ratio by volume of solvent/emulsifier of 99:1. The mixture was then made up to 100 ml with water. This stock solution was diluted with the solvent/emulsifier/water mixture described to give the concentration of active compound stated below. 
     Alternatively, the active compounds epoxiconazole, triticonazole and pyraclostrobin were used as a commercial formulation and diluted with water to the stated active compound concentrations. 
     The visually determined percentages of infected leaf areas were converted into efficacies in % of the untreated control. 
     The efficacy (E) is calculated as follows using Abbot&#39;s formula: 
       E=(1−α/β)·100 
     α corresponds to the fungicidal infection of the treated plants in % and
 
β corresponds to the fungicidal infection of the untreated (control) plants in %
 
     An efficacy of 0 means that the infection level of the treated plants corresponds to that of the untreated control plants; an efficacy of 100 means that the treated plants were not infected. 
     The expected efficacies of active compound mixtures were determined using Colby&#39;s formula [R. S. Colby, “Calculating synergistic and antagonistic responses of herbicide combinations”, Weeds 15, 20-22 (1967)] and compared with the observed efficacies. 
       Colby&#39;s formula: E= x+y−x·y/ 100     E expected efficacy, expressed in % of the untreated control, when using the mixture of the active compounds A and B at the concentrations a and b;   x efficacy, expressed in % of the untreated control, when using the active compound A at the concentration a;   y efficacy, expressed in % of the untreated control, when using the active compound B at the concentration b;   
     Use Example 1 
     Activity Against Gray Mold on Bell Pepper Leaves Caused by  Botrytis cinerea,  1 Day Protective Application 
     Bell pepper seedlings of the cultivar “Neusiedler Ideal Elite” were, after 2-3 leaves were well developed, sprayed to runoff point with an aqueous suspension in the active compound concentration stated below. The next day, the treated plants were inoculated with a spore suspension of  Botrytis cinerea  which comprised 1.7×10 6  spores/ml in a 2% strength biomalt solution. The test plants were then placed in a dark climatized chamber at 22 to 24° C. and high atmospheric humidity. After 5 days, the extent of the fungal infection on the leaves could be determined visually in %. 
     
       
         
           
               
               
               
               
               
             
               
                   
               
               
                   
                   
                   
                   
                 Activity 
               
               
                   
                 Con- 
                   
                 Observed 
                 calculated 
               
               
                   
                 cen- 
                   
                 activity 
                 according 
               
               
                 Active compound/active 
                 tration 
                   
                 (% 
                 to 
               
               
                 compound mixture 
                 [mg/l] 
                 Ratio 
                 infection) 
                 Colby (%) 
               
               
                   
               
             
            
               
                 (control) 
                 — 
                 — 
                 0 (100% 
                 — 
               
               
                   
                   
                   
                 infection) 
               
               
                 No. I.1 
                 1 
                 — 
                  0 
                 — 
               
               
                 5-chloro-7-(4-methylpiperidin-1- 
                 4 
                 — 
                 40 
                 — 
               
               
                 yl)-6-(2,4,6-trifluorophenyl)- 
               
               
                 [1,2,4]triazolo[1,5-a]pyrimidine 
               
               
                 No. I.1 + 5-chloro-7-(4- 
                 1 + 4 
                 1:4 
                 97 
                 40 
               
               
                 methylpiperidin-1-yl)-6-(2,4,6- 
               
               
                 trifluorophenyl)- 
               
               
                 [1,2,4]triazolo[1,5-a]pyrimidine 
               
               
                   
               
            
           
         
       
     
     Use Example 2 
     Activity Against Mildew of Wheat Caused by  Erysiphe  [syn.  Blumeria]graminis  forma specialis.  tritici    
     Leaves of potted wheat seedlings were sprayed to runoff point with an aqueous suspension having the active compound concentration stated below. The suspension or emulsion was prepared as described above. 24 hours after the spray coating had dried on, the plants were dusted with spores of mildew of wheat ( Erysiphe [syn.  Blumelia] graminis  forma specialis.  tritici ). The test plants were then placed in a greenhouse at temperatures between 20 and 24° C. and at 60 to 90% relative atmospheric humidity. After 7 days, the extent of the mildew development was determined visually in % infection of the entire leaf area. 
     
       
         
           
               
               
               
               
               
             
               
                   
               
               
                   
                   
                   
                   
                 Activity 
               
               
                   
                   
                   
                 Observed 
                 calculated 
               
               
                   
                   
                   
                 activity 
                 according 
               
               
                 Active compound/active 
                 Concentration 
                   
                 (% 
                 to 
               
               
                 compound mixture 
                 [mg/l] 
                 Ratio 
                 infection) 
                 Colby (%) 
               
               
                   
               
             
            
               
                 (control) 
                 — 
                 — 
                 0 (90% 
                 — 
               
               
                   
                   
                   
                 infection) 
               
               
                 No. I.9 
                 1 
                 — 
                  0 
                 — 
               
               
                 No. I.1 
                 1 
                 — 
                  0 
                 — 
               
               
                 triticonazole 
                 1 
                 — 
                 40 
                 — 
               
               
                 pyraclostrobin 
                 1 
                 — 
                 40 
                 — 
               
               
                 No. I.9 + triticonazole 
                 1 + 1 
                 1:1 
                 80 
                 40 
               
               
                 No. I.1 + triticonazole 
                 1 + 1 
                 1:1 
                 95 
                 40 
               
               
                 No. I.1 + pyraclostrobin 
                 1 + 1 
                 1:1 
                 70 
                 40 
               
               
                   
               
            
           
         
       
     
     Use Example 3 
     Curative Activity Against Brown Rust of Wheat Caused by  Puccinia recondita    
     Leaves of potted wheat seedlings of the cultivar “Kanzler” were inoculated with a spore suspension of brown rust ( Puccinia recondita ). The pots were then placed in a chamber with high atmospheric humidity (90 to 95%) and at 20 to 22° C. for 24 hours. During this time, the spores germinated and the germ tubes penetrated into the leaf tissue. The next day, the infected plants were sprayed to runoff point with the above-described active compound solution at the active compound concentration stated below. After the spray coating had dried on, the test plants were cultivated in a greenhouse at temperatures between 20 and 22° C. and at 65 to 70% relative atmospheric humidity for 7 days. The extent of the rust fungus development on the leaves was then determined. 
     
       
         
           
               
               
               
               
               
             
               
                   
               
               
                   
                   
                   
                   
                 Activity 
               
               
                   
                   
                   
                 Observed 
                 calculated 
               
               
                   
                   
                   
                 activity 
                 according 
               
               
                 Active compound/active 
                 Concentration 
                   
                 (% 
                 to 
               
               
                 compound mixture 
                 [mg/l] 
                 Ratio 
                 infection) 
                 Colby (%) 
               
               
                   
               
             
            
               
                 (control) 
                 — 
                 — 
                 0 (90% 
                 — 
               
               
                   
                   
                   
                 infection) 
               
               
                 No. I.9 
                 0.25 
                 — 
                 11 
                 — 
               
               
                 dimethomorph 
                 1 
                 — 
                 0 
                 — 
               
               
                 metrafenone 
                 1 
                 — 
                 0 
                 — 
               
               
                 5-chloro-7-(4- 
                 1 
                 — 
                 0 
                 — 
               
               
                 methylpiperidin-1-yl)- 
               
               
                 6-(2,4,6-trifluorophenyl)- 
               
               
                 [1,2,4]triazolo[1,5- 
               
               
                 a]pyrimidine 
               
               
                 No. I.9 + dimethomorph 
                 0.25 + 1 
                 1:4 
                 67 
                 11 
               
               
                 No. I.9 + metrafenone 
                 0.25 + 1 
                 1:4 
                 78 
                 11 
               
               
                 No. I.9 + 5-chloro-7-(4- 
                 0.25 + 1 
                 1:4 
                 97 
                 11 
               
               
                 methylpiperidin-1-yl)-6- 
               
               
                 (2,4,6-trifluorophenyl)- 
               
               
                 [1,2,4]triazolo[1,5- 
               
               
                 a]pyrimidine 
               
               
                   
               
            
           
         
       
     
     Use Example 4 
     Protective Activity Against  Puccinia recondita  on Wheat (Brown Rust of Wheat) 
     Leaves of potted wheat seedlings of the cultivar “Kanzler” were sprayed to runoff point with an aqueous suspension having the concentration of active compound stated below. The next day the treated plants were inoculated with a spore suspension of brown rust of wheat ( Puccinia recondita ). The plants were then placed in a chamber at high atmospheric humidity (90 to 95%) at 20 to 22° C. for 24 hours. During this time, the spores germinated and the germ tubes penetrated into the leaf tissue. The next day, the test plants were returned to the greenhouse and cultivated at temperatures between 20 and 22° C. and 65 to 70% relative atmospheric humidity for a further 7 days. The extent of the rust fungus development on the leaves was then determined visually. 
     
       
         
           
               
               
               
               
               
             
               
                   
               
               
                   
                   
                   
                   
                 Activity 
               
               
                   
                 Con- 
                   
                 Observed 
                 calculated 
               
               
                 Active compound/active 
                 centration 
                   
                 activity 
                 according to 
               
               
                 compound mixture 
                 [mg/l] 
                 Ratio 
                 (% infection) 
                 Colby (%) 
               
               
                   
               
             
            
               
                 (control) 
                 — 
                 — 
                 0 (90% 
                 — 
               
               
                   
                   
                   
                 infection) 
               
               
                 No. I.4 
                 16 
                 — 
                 0 
                 — 
               
               
                 prochloraz 
                 63 
                 — 
                 0 
                 — 
               
               
                 No. I.4 + prochloraz 
                 16 + 63 
                 1:4 
                 78 
                 0 
               
               
                   
               
            
           
         
       
     
     Use example 5 
     Activity Against Net Blotch of Barley Caused by  Pyrenophora teres,  1 Day Protective Application 
     Leaves of potted barley seedlings were sprayed to runoff point with an aqueous suspension having the active compound concentration stated below. 24 hours after the spray coating had dried on, the test plants were inoculated with an aqueous spore suspension of  Pyrenophora  [syn.  Drechslera ] teres, the net blotch pathogen. The test plants were then placed in a greenhouse at temperatures between 20 and 24° C. and at 95 to 100% relative atmospheric humidity. After 6 days, the extent of the development of the disease was determined visually in % infection of the entire leaf area. 
     
       
         
           
               
               
               
               
               
             
               
                   
               
               
                   
                   
                   
                   
                 Activity 
               
               
                   
                 Con- 
                   
                 Observed 
                 calculated 
               
               
                 Active compound/active 
                 centration 
                   
                 activity 
                 according to 
               
               
                 compound mixture 
                 [mg/l] 
                 Ratio 
                 (% infection) 
                 Colby (%) 
               
               
                   
               
             
            
               
                 (control) 
                 — 
                 — 
                 0 (90% 
                 — 
               
               
                   
                   
                   
                 infection) 
               
               
                 No. I.1 
                 4 
                 — 
                 26 
                 — 
               
               
                 epoxiconazole 
                 1 
                 — 
                 0 
                 — 
               
               
                 dimethomorph 
                 16 
                 — 
                 0 
                 — 
               
               
                 prochloraz 
                 16 
                 — 
                 0 
                 — 
               
               
                 metrafenone 
                 16 
                 — 
                 0 
                 — 
               
               
                 No. I.1 + epoxiconazole 
                 4 + 1  
                 4:1 
                 88 
                 26 
               
               
                 No. I.1 + prochloraz 
                 4 + 16 
                 1:4 
                 88 
                 26 
               
               
                 No. I.1 + dimethomorph 
                 4 + 16 
                 1:4 
                 75 
                 26 
               
               
                 No. I.1 + metrafenone 
                 4 + 16 
                 1:4 
                 94 
                 26 
               
               
                   
               
            
           
         
       
     
     Use Example 6 
     Activity Against the Speckled Leaf Blotch Pathogen  Septoria tritici  in the Microtiter Test 
     For this test, the active compounds were formulated separately as a stock solution having a concentration of 10 000 ppm in dimethyl sulfoxide. 
     The stock solution was mixed according to the ratio, pipetted onto a microtiter plate (MTP) and diluted to the stated active compound concentration using a malt-based aqueous nutrient medium for fungi. An aqueous spore suspension of  Septoria tritici  was then added. The plates were placed in a water vapor-saturated chamber at temperatures of 18° C. Using an absorption photometer, the MTPs were measured at 405 nm on day 7 after the inoculation. 
     The measured parameters were compared to the growth of the active compound-free control variant (100%) and the fungus- and active compound-free blank value to determine the relative growth in % of the pathogens in the individual active compounds. 
     
       
         
           
               
               
               
               
               
             
               
                   
               
               
                   
                   
                   
                   
                 Activity 
               
               
                   
                 Con- 
                   
                 Observed 
                 calculated 
               
               
                 Active compound/active 
                 centration 
                   
                 activity 
                 according to 
               
               
                 compound mixture 
                 [mg/l] 
                 Ratio 
                 (% infection) 
                 Colby (%) 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
            
               
                 No. I.4 
                 0.25 
                 — 
                 20 
                 — 
               
               
                 metiram 
                 1 
                 — 
                 1 
                 — 
               
               
                 No. I.4 + metiram 
                 0.25 + 1 
                 1:4 
                 79 
                 21 
               
               
                   
               
            
           
         
       
     
     Use Example 7 
     Activity Against the Rice Blast Pathogen  Pyricularia oryzae  in the Microtiter Test 
     For this test, the active compounds were formulated separately as a stock solution having a concentration of 10 000 ppm in dimethyl sulfoxide. 
     The stock solutions were mixed according to the ratio, pipetted onto a microtiter plate (MTP) and diluted to the stated active compound concentration using a malt-based aqueous nutrient medium for fungi. An aqueous spore suspension of  Pyricularia oryzae  was then added. The plates were placed in a water vapor-saturated chamber at temperatures of 18° C. Using an absorption photometer, the MTPs were measured at 405 nm on day 7 after the inoculation. 
     The measured parameters were compared to the growth of the active compound-free control variant (=100%) and the fungus- and active compound-free blank value to determine the relative growth in % of the pathogens in the individual active compounds. 
     
       
         
           
               
               
               
               
               
             
               
                   
               
               
                   
                   
                   
                   
                 Activity 
               
               
                   
                 Con- 
                   
                 Observed 
                 calculated 
               
               
                 Active compound/active 
                 centration 
                   
                 activity 
                 according to 
               
               
                 compound mixture 
                 [mg/l] 
                 Ratio 
                 (% infection) 
                 Colby (%) 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
            
               
                 No. I.1 
                 4 
                 — 
                 0 
                 — 
               
               
                 metiram 
                 16 
                 — 
                 52 
                 — 
               
               
                 No. I.1 + metiram 
                 4 + 16 
                 1:4 
                 84 
                 52