Patent Publication Number: US-2023151257-A1

Title: Refrigerant-containing composition, use thereof, refrigerator having same, and method for operating said refrigerator

Description:
TECHNICAL FIELD 
     The present disclosure relates to a composition comprising a refrigerant, use of the composition, a refrigerating machine having the composition, and a method for operating the refrigerating machine. 
     BACKGROUND ART 
     R410A is currently used as an air conditioning refrigerant for home air conditioners etc. R410A is a two-component mixed refrigerant of difluoromethane (CH2F 2 : HFC-32 or R32) and pentafluoroethane (C 2 HF 5 : HFC-125 or R125), and is a pseudo-azeotropic composition. 
     However, the global warming potential (GWP) of R410A is 2088. Due to growing concerns about global warming, R32, which has a GWP of 675, has been increasingly used. 
     For this reason, various low-GWP mixed refrigerants that can replace R410A have been proposed (PTL 1). 
     CITATION LIST 
     Patent Literature 
     
         
         PTL 1: WO2015/141678 
       
    
     SUMMARY OF INVENTION 
     Technical Problem 
     An object of the present disclosure is to provide a novel low-GWP mixed refrigerant. 
     Solution to Problem 
     Item 1. 
     A composition comprising a refrigerant, the refrigerant comprising difluoromethane (R32), trans-1,2-difluoroethylene (HFO-1132 (E)), 1,3,3,3-tetrafluoropropene (R1234ze), and 1,1-difluoroethylene (HFO-1132a). 
     Item 2. 
     The composition according to Item 1, wherein 
     when the mass % of R32, HFO-1132(E), R1234ze, and HFO-1132a based on their sum in the refrigerant is respectively represented by x, y, z, and a, provided that 1.5≤a≤10.0, coordinates (x,y,z) in a ternary composition diagram in which the sum of R32, HFO-1132(E), and R1234ze is (100−a) mass % are within the range of a figure surrounded by straight lines AB, BC, CD, DO, and OA that connect the following 5 points: 
     point A (74.0, −a+26.0, 0.0),
 
point B (73.9, 0.0, −a+26.1),
 
point C (0.0087a 2 −2.2743a+59.574, 0.0, −0.0087a+1.2743a+40.426),
 
point D (0.0, 0.0299a 2 −3.4018a+76.233, −0.0299a 2 +2.4018a+23.767), and
 
point O (0.0, 100.0−a, 0.0),
 
or on the straight lines AB and CD (excluding the points A, B, C, and D).
 
     Item 3. 
     The composition according to Item 1, wherein 
     when the mass % of R32, HFO-1132(E), R1234ze, and HFO-1132a based on their sum in the refrigerant is respectively represented by x, y, z, and a, provided that 1.5≤a≤10.0, coordinates (x,y,z) in a ternary composition diagram in which the sum of R32, HFO-1132(E), and R1234ze is (100−a) mass % are within the range of a figure surrounded by straight lines A′B′, B′C, CD, DO, and OA′ that connect the following 5 points: 
     point A′ (59.2, −a+40.8, 0.0),
 
point B′ (0.0132a+58.891, 0.0, −1.0132a+41.109),
 
point C (0.0087a 2 −2.2743a+59.574, 0.0, −0.0087a 2 +1.2743a+40.426),
 
point D (0.0, 0.0299a 2 −3.4018a+76.233, −0.0299a 2 +2.4018a+23.767), and
 
point O (0.0, 100.0−a, 0.0),
 
or on the straight lines A′B′ and CD (excluding the points A′, B′, C, and D).
 
     Item 4. 
     The composition according to any one of Items 1 to 3, wherein the refrigerant further comprises 2,3,3,3-tetrafluoro-1-propene (R1234yf). 
     Item 5. 
     The composition according to Item 4, wherein 
     when the mass % of R32 is represented by x, the mass % of HFO-1132(E) is represented by y, the total mass % of R1234ze and R1234yf is represented by z, and the mass % of HEO-1132a is represented by a, provided that 1.5≤a≤10.0, based on the sum of R32, HFO-1132(E), R1234ze, R1234yf, and HFO-1132a in the refrigerant, and r=R1234yf/(R1234ze+R1234yf), 
     if 1.5≤a≤4.6, coordinates (x,y,z) in a ternary composition diagram having R32 as a first vertex, HFO-1132(E) as a second vertex, and the sum of R1234ze and R1234yf as a third vertex are within the range of a figure surrounded by straight lines AB r , B r C r , C r D r , D r O, and OA that connect the following 5 points: 
     point A (74.0, −a+26.0, 0.0),
 
point B r  (73.9, 0.0, −a+26.1),
 
point C r  ((0.0349a 2 +0.1094a−1.2427)r 2 +(−0.0202a 2 +0.0907a−10.591)r+(0.0255a 2 −2.3816a+59.715), 0.0, −a−x+100.0), point D h (0.0, (−0.2097a 2 +1.3435a−2.7435)r 2 +(0.2312a 2 −1.507a−5.0597)r+(0.0255a 2 −3.3816a+76.215), −a−y+100.0), and
 
point O (0.0, 100.0−a, 0.0),
 
or on the straight lines AB r  and C r D r (excluding the points A, B r , C r , and D r ); or
 
     if 4.6≤a≤10.0, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines AB r , B r C r , C r D r , D r O, and OA that connect the following 5 points: 
     point A (74.0, −a+26.0, 0.0),
 
point B r (73.9, 0.0, −a+26.1),
 
point C r  ((0.0494a 2 −0.5728a+1.5901)r 2 +(−0.037a 2 +0.763a−13.326)r+(0.0062a 2 −2.2383a+59.465), 0.0, −a−x+100.0), point D r  (0.0, (−0.0648a 2 +1.1685a−5.0037)r 2 +(0.0849a 2 −1.2762a−3.0253)r+(0.0262a 2 −3.346a+76.036), −a−y+100.0), and point O (0.0, 100.0−a, 0.0),
 
or on the straight lines AB r  and C r D r (excluding the points A, B r , C r , and D r ).
 
     Item 6. 
     The composition according to Item 4, 
     wherein 
     when the mass % of R32 is represented by x, the mass % of HFO-1132(E) is represented by y, the total mass % of R1234ze and R1234yf is represented by z, and the mass % of HFO-1132a is represented by a, provided that 1.5≤a≤10.0, based on the sum of R32, HFO-1132(E), R1234ze, R1234yf, and HFO-1132a in the refrigerant, and r=R1234yf/(R1234ze+R1234yf), 
     if 1.5≤a≤4.6, coordinates (x,y,z) in a ternary composition diagram having R32 as a first vertex, HFO-1132(E) as a second vertex, and the sum of R1234ze and R1234yf as a third vertex are within the range of a figure surrounded by straight lines AB r ′, B r ′C r , C r D r , D r O, and OA that connect the following 5 points: 
     point A′ (74.0, −a+26.0, 0.0),
 
point B r ′ ((−0.043a=+0.3269a−0.5935)r 2 +(−0.0188a 2 +0.018a+0.3153)r+(0.0202a 2 =−0.0907a+58.991), 0.0, −a−x+100.0),
 
point C r  ((0.0349a 2 +0.1094a−1.2427)r 2 +(−0.0202a=+0.0907a−10.591)r+(0.0255a 2 −2.3816a+59.715), 0.0, −a−x+100.0),
 
point D r  (0.0, (−0.2097a 2 +1.3435a−2.7435)r 2 +(0.2312a 2 −1.507a−5.0597)r+(0.0255a 2 −3.3816a+76.215), −a−y+100.0), and
 
point O (0.0, 100.0−a, 0.0),
 
or on the straight lines AB r ′ and C r D r  (excluding the points A, B r ′, C r , and D r ); or
 
     if 4.6≤a≤10.0, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines AB′, B r ′C r , C r D r , D r O, and OA that connect the following 5 points: 
     point A (74.0, −a+26.0, 0.0), point B 1 ′ ((−0.0077a 2 +0.1312a−0.4401)r+(0.0013a 2 −0.0223a+59.075), 0.0, −a−x+100.0),
 
point C r ((0.0494a 2 −0.5728a+1.5901) r 2 +(−0.037a 2 +0.763a−13.326)r+(0.0062a 2 −2.2383a+59.465), 0.0, −a−x+100.0),
 
point D r  (0.0, (−0.0648a 2 +1.1685a−5.0037)r 2 +(0.0849a 2 −1.2762a−3.0253)r+(0.0262a 2 −3.346a+76.036), −a−y+100.0), and
 
point O (0.0, 100.0−a, 0.0),
 
or on the straight lines AB r ′ and C r D r  (excluding the points A, B r ′, C r , and D r )).
 
     Item 7. 
     The composition according to any one of Items 1 to 6, for use as a working fluid for a refrigerating machine, wherein the composition further comprises a refrigeration oil. 
     Item 8. 
     The composition according to any one of Items 1 to 6, for use as an alternative refrigerant for R410A. 
     Item 9. 
     Use of the composition according to any one of Items 1 to 6 as an alternative refrigerant for R410A. 
     Item 10. 
     A refrigerating machine comprising the composition according to any one of Items 1 to 6 as a working fluid. 
     Item 11. 
     A method for operating a refrigerating machine, comprising circulating the composition according to any one of Items 1 to 6 as a working fluid in a refrigerating machine. 
     Advantageous Effects of Invention 
     The refrigerant of the present disclosure has a low GWP. 
    
    
     
       BRIEF DESCRIPTION OF DRAWINGS 
         FIG.  1    shows points A to D, points A′ to C′, and point O, as well as line segments connecting these points in a ternary composition diagram in which the sum of R32, HFO-1132(E), and R1234ze is 98.5 mass % (the HFO-1132a content is 1.5 mass %). 
         FIG.  2    shows points A to D, points A′ and B′, and point O, as well as line segments connecting these points in a ternary composition diagram in which the sum of R32, HFO-1132(E), and R1234ze is 98.5 mass % (the HFO-1132a content is 1.5 mass %). 
         FIG.  3    shows points A to D, points A′ and B′, and point O, as well as line segments connecting these points in a ternary composition diagram in which the sum of R32, HFO-1132(E), and R1234ze is 97 mass % (the HFO-1132a content is 3 mass %). 
         FIG.  4    shows points A to D, points A′ and B′, and point O, as well as line segments connecting these points in a ternary composition diagram in which the sum of R32, HFO-1132(E), and R1234ze is 95.4 mass % (the HFO-1132a content is 4.6 mass %). 
         FIG.  5    shows points A to D, points A′ and B′, and point O, as well as line segments connecting these points in a ternary composition diagram in which the sum of R32, HFO-1132(E), and R1234ze is 93 mass % (the HFO-1132a content is 7 mass %). 
         FIG.  6    shows points A to D, points A′ and B′, and point O, as well as line segments connecting these points in a ternary composition diagram in which the sum of R32, HFO-1132(E), and R1234ze is 90 mass % (the HFO-1132a content is 10 mass %). 
         FIG.  7    shows point A, point A′, points B r  to D r , point B r ′ and point 0, as well as line segments connecting these points in a ternary composition diagram in which the sum of R32, HFO-1132(E), and R1234ze is 98.5 mass % (the HFO-1132a content is 1.5 mass %). 
         FIG.  8    shows point A, point A′, points B r  to D r , point B r ′ and point 0, as well as line segments connecting these points in a ternary composition diagram in which the sum of R32, HFO-1132(E), and R1234ze is 97 mass % (the HFO-1132a content is 3 mass %). 
         FIG.  9    shows point A, point A′, points B r  to D r , point B r ′ and point O, as well as line segments connecting these points in a ternary composition diagram in which the sum of R32, HFO-1132(E), and R1234ze is 95.4 mass % (the HFO-1132a content is 4.6 mass %). 
         FIG.  10    shows point A, point A′, points B r  to D r , point Br′ and point 0, as well as line segments connecting these points in a ternary composition diagram in which the sum of R32, HFO-1132(E), and R1234ze is 93 mass % (the HFO-1132a content is 7 mass %). 
         FIG.  11    shows point A, point A′, points B r  to D r , point Br′ and point 0, as well as line segments connecting these points in a ternary composition diagram in which the sum of R32, HFO-1132(E), and R1234ze is 90 mass % (the HFO-1132a content is 10 mass %). 
     
    
    
     DESCRIPTION OF EMBODIMENTS 
     The present inventors conducted intensive studies to solve the above problem, and consequently found that a mixed refrigerant comprising R32, HFO-1132(E), and R1234ze, as well as HFO-1132a has the above properties. 
     The present disclosure has been completed as a result of further research based on this finding. The present disclosure includes the following embodiments. 
     DEFINITION OF TERMS 
     In the present specification, the term “refrigerant” includes at least compounds that are specified in ISO 817 (International Organization for Standardization), and that are given a refrigerant number (ASHRAE number) representing the type of refrigerant with “R” at the beginning; and further includes refrigerants that have properties equivalent to those of such refrigerants, even though a refrigerant number is not yet given. Refrigerants are broadly divided into fluorocarbon compounds and non-fluorocarbon compounds in terms of the structure of the compounds. Fluorocarbon compounds include chlorofluorocarbons (CFC), hydrochlorofluorocarbons (HCFC), and hydrofluorocarbons (HFC). Non-fluorocarbon compounds include propane (R290), propylene (R1270), butane (R600), isobutane (R600a), carbon dioxide (R744), ammonia (R717), and the like. 
     In the present specification, the phrase “composition comprising a refrigerant” at least includes (1) a refrigerant itself (including a mixture of refrigerants), (2) a composition that further comprises other components and that can be mixed with at least a refrigeration oil to obtain a working fluid for a refrigerating machine, and (3) a working fluid for a refrigerating machine containing a refrigeration oil. In the present specification, of these three embodiments, the composition (2) is referred to as a “refrigerant composition” so as to distinguish it from a refrigerant itself (including a mixture of refrigerants). Further, the working fluid for a refrigerating machine (3) is referred to as a “refrigeration oil-containing working fluid” so as to distinguish it from the “refrigerant composition.” 
     In the present specification, when the term “alternative” is used in a context in which the first refrigerant is replaced with the second refrigerant, the first type of “alternative” means that equipment designed for operation using the first refrigerant can be operated using the second refrigerant under optimum conditions, optionally with changes of only a few parts (at least one of the following: refrigeration oil, gasket, packing, expansion valve, dryer, and other parts) and equipment adjustment. In other words, this type of alternative means that the same equipment is operated with an alternative refrigerant. Embodiments of this type of “alternative” include “drop-in alternative,” “nearly drop-in alternative,” and “retrofit,” in the order in which the extent of changes and adjustment necessary for replacing the first refrigerant with the second refrigerant is smaller. 
     The term “alternative” also includes a second type of “alternative,” which means that equipment designed for operation using the second refrigerant is operated for the same use as the existing use with the first refrigerant by using the second refrigerant. This type of alternative means that the same use is achieved with an alternative refrigerant. 
     In the present specification, the term “refrigerating machine” refers to machines in general that draw heat from an object or space to make its temperature lower than the temperature of ambient air, and maintain a low temperature. In other words, refrigerating machines refer to conversion machines that gain energy from the outside to do work, and that perform energy conversion, in order to transfer heat from where the temperature is lower to where the temperature is higher. 
     1. Refrigerant 
     1.1 Refrigerant Component 
     The refrigerant of the present disclosure comprises R32, HFO-1132(E), R1234ze, and HFO-1132a. 
     The refrigerant of the present disclosure is a low-GWP mixed refrigerant. 
     The refrigerant of the present disclosure preferably satisfies the following requirements. In this case, the refrigerant of the present disclosure has a GWP of 500 or less and a refrigerating capacity ratio of 85% or more relative to that of R410A. 
     Requirements 
     When the mass % of R32, HFO-1132(E), R1234ze, and HFO-1132a based on their sum is respectively represented by x, y, z, and a, provided that 1.5≤a≤10.0, coordinates (x,y,z) in a ternary composition diagram in which the sum of R32, HFO-1132(E), and R1234ze is (100−a) mass % are within the range of a figure surrounded by straight lines AB, BC, CD, DO, and OA that connect the following 5 points: 
     point A (74.0, −a+26.0, 0.0),
 
point B (73.9, 0.0, −a+26.1),
 
point C (0.0087a 2 −2.2743a+59.574, 0.0, −0.0087a 2 +1.2743a+40.426),
 
point D (0.0, 0.0299a 2 −3.4018a+76.233, −0.0299a 2 +2.4018a+23.767), and
 
point O (0.0, 100.0−a, 0.0),
 
or on the straight lines AB and CD (excluding the points A, B, C, and D).
 
     The refrigerant of the present disclosure preferably satisfies the following requirements. In this case, the refrigerant of the present disclosure has a GWP of 400 or less and a refrigerating capacity ratio of 85% or more relative to that of R410A. 
     Requirements 
     When the mass % of R32, HFO-1132(E), R1234ze, and HFO-1132a based on their sum is respectively represented by x, y, z, and a, provided that 1.5≤a≤10.0, coordinates (x,y,z) in a ternary composition diagram in which the sum of R32, HFO-1132(E), and R1234ze is (100−a) mass % are within the range of a figure surrounded by straight lines A′B′, B′C, CD, DO, and QA′ that connect the following 5 points: 
     point A′ (59.2, −a+40.8, 0.0),
 
point B′ (0.0132a+58.891, 0.0, −1.0132a+41.109),
 
point C (0.0087a 2 −2.2743a+59.574, 0.0, −0.0087a 2 +1.2743a+40.426),
 
point D (0.0, 0.0299a 2 −3.4018a+76.233, −0.0299a 2 +2.4018a+23.767), and
 
point O (0.0, 100.0−a, 0.0),
 
or on the straight lines A′B′ and CD (excluding the points A′, B′, C, and D).
 
     The refrigerant of the present disclosure may further comprise R1234yf. 
     When the refrigerant of the present disclosure further comprises R1234yf, it preferably satisfies the following requirements. In this case, the refrigerant of the present disclosure has a GWP of 500 or less and a refrigerating capacity ratio of 85% or more relative to that of R410A. 
     Requirements 
     When the mass % of R32 is represented by x, the mass % of HFO-1132(E) is represented by y, the total mass % of R1234ze and R1234yf is represented by z, and the mass % of HFO-1132a is represented by a, provided that 1.5≤a≤10.0, based on the sum of R32, HFO-1132(E), R1234ze, R1234yf, and HFO-1132a, and r=R1234yf/(R1234ze+R1234yf), 
     if 1.5≤a≤4.6, coordinates (x,y,z) in a ternary composition diagram having R32 as a first vertex, HFO-1132 (E) as a second vertex, and the sum of R1234ze and R1234yf as a third vertex are within the range of a figure surrounded by straight lines AB r , B r C r , C r D r , D r O, and OA that connect the following 5 points: 
     point A (74.0, −a+26.0, 0.0),
 
point B r  (73.9, 0.0, −a+26.1),
 
point C r  ((0.0349a 2 +0.1094a−1.2427)r 2 +(−0.0202a 2 +0.0907a−10.591)r+(0.0255a 2 −2.3816a+59.715), 0.0, −a−x+100.0),
 
point D r  (0.0, (−0.2097a 2 +1.3435a−2.7435)r 2 +(0.2312a 2 −1.507a−5.0597)r+(0.0255a 2 −3.3816a+76.215), −a−y+100.0), and
 
point O (0.0, 100.0−a, 0.0),
 
or on the straight lines AB r  and C r D r  (excluding the points A, B r , C r , and D r ); or
 
     if 4.6≤a≤10.0, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines AB r , B r C r , C r D r , D r O, and OA that connect the following 5 points: 
     point A (74.0, −a+26.0, 0.0),
 
point B r  (73.9, 0.0, −a+26.1),
 
point C r  ((0.0494a 2 −0.5728a+1.5901)r 2 +(−0.037a 2 +0.763a−13.326)r+(0.0062a=−2.2383a+59.465), 0.0, −a−x+100.0),
 
point D r (0.0, (−0.0648a 2 +1.1685a−5.0037)r 2 +(0.0849a 2 −1.2762a−3.0253)r+(0.0262a 2 −3.346a+76.036), −a−y+100.0), and
 
point O (0.0, 100.0−a, 0.0),
 
or on the straight lines AB r  and C r D r  (excluding the points A, B r , C r , and D r ).
 
     When the refrigerant of the present disclosure further comprises R1234yf, it preferably satisfies the following requirements. In this case, the refrigerant of the present disclosure has a GWP of 400 or less and a refrigerating capacity ratio of 85% or more relative to that of R410A. 
     Requirements 
     When the mass % of R32 is represented by x, the mass % of HFO-1132(E) is represented by y, the total mass % of R1234ze and R1234yf is represented by z, and the mass % of HFO-1132a is represented by a, provided that 1.5≤a≤10.0, based on the sum of R32, HFO-1132(E), R1234ze, R1234yf, and HFO-1132a, and r=R1234yf/(R1234ze+R1234yf), 
     if 1.5≤a≤4.6, coordinates (x,y,z) in a ternary composition diagram having R32 as a first vertex, HFO-1132(E) as a second vertex, and the sum of R1234ze and R1234yf as a third vertex are within the range of a figure surrounded by straight lines AB r ′, B r ′C r , C r D r , D r O, and OA that connect the following 5 points: 
     point A′ (74.0, −a+26.0, 0.0),
 
point B r ′ ((−0.043a 2 +0.3269a−0.5935)r 2 +(−0.0188a 2 +0.018a+0.3153)r+(0.0202a 2 −0.0907a+58.991), 0.0, −a−x+100.0),
 
point C r  ((0.0349a 2 +0.1094a−1.2427)r 2 +(−0.0202a 2 +0.0907a−10.591)r+(0.0255a 2 −2.3816a+59.715), 0.0, −a−x+100.0),
 
point D r  (0.0, (−0.2097a=+1.3435a−2.7435)r 2 +(0.2312a 2 −1.507a−5.0597)r+(0.0255a 2 −3.3816a+76.215), −a−y+100.0), and
 
point O (0.0, 100.0−a, 0.0),
 
or on the straight lines AB r ′ and C r D r  (excluding the points A, B r ′, C r , and D r ); or
 
     if 4.6≤a≤10.0, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines ABM′, B r ′C r , C r D r , D r O, and OA that connect the following 5 points: 
     point A (74.0, −a+26.0, 0.0),
 
point B r ′ ((−0.0077a 2 +0.1312a−0.4401)r+(0.0013a 2 −0.0223a+59.075), 0.0, −a−x+100.0),
 
point C r  ((0.0494a 2 −0.5728a+1.5901)r 2 +(−0.037a 2 +0.763a−13.326)r+(0.0062a 2 −2.2383a+59.465), 0.0, −a−x+100.0),
 
point D r  (0.0, (−0.0648a 2 +1.1685a−5.0037)r+(0.0849a 2 −1.2762a−3.0253)r+(0.0262a 2 −3.346a+76.036), −a−y+100.0), and
 
point O (0.0, 100.0−a, 0.0),
 
or on the straight lines AB r ′ and C r D r (excluding the points A, B r ′, C r , and D r ).
 
     The refrigerant of the present disclosure may further comprise other additional refrigerants in addition to R32, HFO-1132(E), R1234ze, R1234yf, and HFO-1132a, as long as the above properties and effects are not impaired. In this respect, in an embodiment, the refrigerant of the present disclosure preferably comprises R32, HFO-1132(E), R1234ze, and HFO-1132a in a total amount of 99.5 mass % or more, more preferably 99.75 mass % or more, and even more preferably 99.9 mass % or more, based on the entire refrigerant. Further, the refrigerant of the present disclosure may consist of R32, HFO-1132(E), R1234ze, and HFO-1132a. In this case, the refrigerant of the present disclosure may contain impurities inevitably mixed in the production process. In another embodiment, the refrigerant of the present disclosure preferably comprises R32, HFO-1132(E), R1234ze, R1234yf, and HFO-1132a in a total amount of 99.5 mass % or more, more preferably 99.75 mass % or more, and even more preferably 99.9 mass % or more, based on the entire refrigerant. Further, the refrigerant of the present disclosure may essentially consist of R32, HFO-1132(E), R1234ze, R1234yf, and HFO-1132a. In this case, the refrigerant of the present disclosure may contain impurities inevitably mixed in the production process. 
     Such additional refrigerants are not limited, and can be selected from a wide range of refrigerants. The mixed refrigerant may comprise a single additional refrigerant, or two or more additional refrigerants. 
     1.2. Use 
     The refrigerant according to the present disclosure can be preferably used as a working fluid in a refrigerating machine. 
     The composition according to the present disclosure is suitable for use as an alternative refrigerant for R410A. 
     2. Refrigerant Composition 
     The refrigerant composition according to the present disclosure comprises at least the refrigerant according to the present disclosure, and can be used for the same use as the refrigerant according to the present disclosure. Moreover, the refrigerant composition according to the present disclosure can be further mixed with at least a refrigeration oil to thereby obtain a working fluid for a refrigerating machine. 
     The refrigerant composition according to the present disclosure further comprises at least one other component in addition to the refrigerant according to the present disclosure. The refrigerant composition according to the present disclosure may comprise at least one of the following other components, if necessary. As described above, when the refrigerant composition according to the present disclosure is used as a working fluid in a refrigerating machine, it is generally used as a mixture with at least a refrigeration oil. Therefore, it is preferable that the refrigerant composition according to the present disclosure does not substantially comprise a refrigeration oil. Specifically, in the refrigerant composition according to the present disclosure, the content of the refrigeration oil based on the entire refrigerant composition is preferably 0 to 1 mass %, and more preferably 0 to 0.1 mass %. 
     2.1. Water 
     The refrigerant composition according to the present disclosure may contain a small amount of water. The water content of the refrigerant composition is preferably 0.1 mass % or less based on the entire refrigerant. A small amount of water contained in the refrigerant composition stabilizes double bonds in the molecules of unsaturated fluorocarbon compounds that can be present in the refrigerant, and makes it less likely that the unsaturated fluorocarbon compounds will be oxidized, thus increasing the stability of the refrigerant composition. 
     2.2. Tracer 
     A tracer is added to the refrigerant composition according to the present disclosure at a detectable concentration such that when the refrigerant composition has been diluted, contaminated, or undergone other changes, the tracer can trace the changes. 
     The refrigerant composition according to the present disclosure may comprise a single tracer, or two or more tracers. 
     The tracer is not limited, and can be suitably selected from commonly used tracers. 
     Examples of tracers include hydrofluorocarbons, hydrochlorofluorocarbons, chlorofluorocarbons, hydrochlorocarbons, fluorocarbons, deuterated hydrocarbons, deuterated hydrofluorocarbons, perfluorocarbons, fluoroethers, brominated compounds, iodinated compounds, alcohols, aldehydes, ketones, and nitrous oxide (N 2 O). The tracer is particularly preferably a hydrofluorocarbon, a hydrochlorofluorocarbon, a chlorofluorocarbon, a hydrochlorocarbon, a fluorocarbon, or a fluoroether. 
     The following compounds are preferable as the tracer.
     FC-14 (tetrafluoromethane, CF 4 )   HCC-40 (chloromethane, CH 3 Cl)   HFC-23 (trifluoromethane, CHF 3 )   HFC-41 (fluoromethane, CH 3 Cl)   HFC-125 (pentafluoroethane, CF 3 CHF 2 )   HFC-134a (1,1,1,2-tetrafluoroethane, CF 3 CH 2 F)   HFC-134 (1, 1, 2, 2-tetrafluoroethane, CHF 2 CHF 2 )   HFC-143a (1,1, 1-trifluoroethane, CF 3 CH 3 )   HFC-143 (1,1, 2-trifluoroethane, CHF 2 CH 2 F)   HFC-152a (1,1-difluoroethane, CHF 2 CH 3 )   HFC-152 (1,2-difluoroethane, CH 2 FCH 2 F)   HFC-161 (fluoroethane, CH 3 CH 2 F)   HFC-245fa (1,1,1, 3, 3-pentafluoropropane, CF 3 CH 2 CHF 2 )   HFC-236fa (1, 1,1, 3, 3, 3-hexafluoropropane, CF 3 CH 2 CF 3 )   HFC-236ea (1,1,1, 2, 3, 3-hexafluoropropane, CF 3 CHFCHF 2 )   HFC-227ea (1, 1,1,2,3,3, 3-heptafluoropropane, CF 3 CHFCF 3 )   HCFC-22 (chlorodifluoromethane, CHClF 2 )   HCFC-31 (chlorofluoromethane, CH 2 ClF)   CFC-1113 (chlorotrifluoroethylene, CF 2 ═CClF)   HFE-125 (trifluoromethyl-difluoromethyl ether, CF 3 OCHF 2 )   HFE-134a (trifluoromethyl-fluoromethyl ether, CF 3 OCH 2 F)   HFE-143a (trifluoromethyl-methyl ether, CF 3 OCH 3 )   HFE-227ea (trifluoromethyl-tetrafluoroethyl ether, CF 3 OCHFCF 3 )   HFE-236fa (trifluoromethyl-trifluoroethyl ether, CF 3 OCHCF 3 )   

     The refrigerant composition of the present disclosure may contain the tracer in a total amount of about 10 parts per million by weight (ppm) to about 1000 ppm based on the entire refrigerant composition. The refrigerant composition of the present disclosure may contain the tracer in a total amount of preferably about 30 ppm to about 500 ppm, and more preferably about 50 ppm to about 300 ppm, based on the entire refrigerant composition. 
     2.3. Ultraviolet Fluorescent Dye 
     The refrigerant composition according to the present disclosure may comprise a single ultraviolet fluorescent dye, or two or more ultraviolet fluorescent dyes. 
     The ultraviolet fluorescent dye is not limited, and can be suitably selected from commonly used ultraviolet fluorescent dyes. 
     Examples of ultraviolet fluorescent dyes include naphthalimide, coumarin, anthracene, phenanthrene, xanthene, thioxanthene, naphthoxanthene, fluorescein, and derivatives thereof. The ultraviolet fluorescent dye is particularly preferably either naphthalimide or coumarin, or both. 
     2.4. Stabilizer 
     The refrigerant composition according to the present disclosure may comprise a single stabilizer, or two or more stabilizers. 
     The stabilizer is not limited, and can be suitably selected from commonly used stabilizers. 
     Examples of stabilizers include nitro compounds, ethers, and amines. 
     Examples of nitro compounds include aliphatic nitro compounds, such as nitromethane and nitroethane; and aromatic nitro compounds, such as nitro benzene and nitro styrene. 
     Examples of ethers include 1,4-dioxane. 
     Examples of amines include 2,2,3,3,3-pentafluoropropylamine and diphenylamine. 
     Examples of stabilizers also include butylhydroxyxylene and benzotriazole. 
     The content of the stabilizer is not limited. Generally, the content of the stabilizer is preferably 0.01 to 5 mass %, and more preferably 0.05 to 2 mass %, based on the entire refrigerant. 
     2.5. Polymerization Inhibitor 
     The refrigerant composition according to the present disclosure may comprise a single polymerization inhibitor, or two or more polymerization inhibitors. 
     The polymerization inhibitor is not limited, and can be suitably selected from commonly used polymerization inhibitors. 
     Examples of polymerization inhibitors include 4-methoxy-1-naphthol, hydroquinone, hydroquinone methyl ether, dimethyl-t-butylphenol, 2, 6-di-tert-butyl-p-cresol, and benzotriazole. 
     The content of the polymerization inhibitor is not limited. Generally, the content of the polymerization inhibitor is preferably 0.01 to 5 mass %, and more preferably 0.05 to 2 mass %, based on the entire refrigerant. 
     3. Refrigeration Oil-Containing Working Fluid 
     The refrigeration oil-containing working fluid according to the present disclosure comprises at least the refrigerant or refrigerant composition according to the present disclosure and a refrigeration oil, for use as a working fluid in a refrigerating machine. Specifically, the refrigeration oil-containing working fluid according to the present disclosure is obtained by mixing a refrigeration oil used in a compressor of a refrigerating machine with the refrigerant or the refrigerant composition. The refrigeration oil-containing working fluid generally comprises 10 to 50 mass % of refrigeration oil. 
     3.1. Refrigeration Oil 
     The composition according to the present disclosure may comprise a single refrigeration oil, or two or more refrigeration oils. 
     The refrigeration oil is not limited, and can be suitably selected from commonly used refrigeration oils. In this case, refrigeration oils that are superior in the action of increasing the miscibility with the mixture and the stability of the mixture, for example, are suitably selected as necessary. 
     The base oil of the refrigeration oil is preferably, for example, at least one member selected from the group consisting of polyalkylene glycols (PAG), polyol esters (POE), and polyvinyl ethers (PVE). 
     The refrigeration oil may further contain additives in addition to the base oil. The additive may be at least one member selected from the group consisting of antioxidants, extreme-pressure agents, acid scavengers, oxygen scavengers, copper deactivators, rust inhibitors, oil agents, and antifoaming agents. 
     A refrigeration oil with a kinematic viscosity of 5 to 400 cSt at 40° C. is preferable from the standpoint of lubrication. 
     The refrigeration oil-containing working fluid according to the present disclosure may further optionally contain at least one additive. Examples of additives include compatibilizing agents described below. 
     3.2. Compatibilizing Agent 
     The refrigeration oil-containing working fluid according to the present disclosure may comprise a single compatibilizing agent, or two or more compatibilizing agents. 
     The compatibilizing agent is not limited, and can be suitably selected from commonly used compatibilizing agents. 
     Examples of compatibilizing agents include polyoxyalkylene glycol ethers, amides, nitriles, ketones, chlorocarbons, esters, lactones, aryl ethers, fluoroethers, and 1,1,1-trifluoroalkanes. The compatibilizing agent is particularly preferably a polyoxyalkylene glycol ether. 
     4. Method for Operating Refrigerating Machine 
     The method for operating a refrigerating machine according to the present disclosure is a method for operating a refrigerating machine using the refrigerant according to the present disclosure. 
     Specifically, the method for operating a refrigerating machine according to the present disclosure comprises the step of circulating the refrigerant according to the present disclosure in a refrigerating machine. 
     The embodiments are described above; however, it will be understood that various changes in forms and details can be made without departing from the spirit and scope of the claims. 
     EXAMPLES 
     The present disclosure is described in more detail below with reference to Examples. However, the present disclosure is not limited to the Examples. 
     Mixed refrigerants were prepared by mixing R32, HFO-1132(E), R1234ze, and HFO-1132a at mass % shown in Table 1 based on their sum. 
     The GWP of R410A (R32=50%/R125=50%) and the above mixed refrigerants was evaluated based on the values stated in the Intergovernmental Panel on Climate Change (IPCC), fourth report. The GWP of HFO-1132(E), which was not stated therein, was assumed to be 1 from HFO-1132a (GWP=1 or less) and HFO-1123 (GWP=0.3, described in PTL 1). The refrigerating capacity of R410A and the above mixed refrigerants was determined by performing theoretical refrigeration cycle calculations for the mixed refrigerants using the National Institute of Science and Technology (NIST) and Reference Fluid Thermodynamic and Transport Properties Database (Refprop 9.0) under the following conditions. 
     For each of these mixed refrigerants, the COP ratio and refrigerating capacity ratio relative to those of R410A were determined. The calculation conditions were as follows: 
     Evaporating temperature: 5° C.
 
Condensation temperature: 45° C.
 
Superheating temperature: 5 K
 
Subcooling temperature: 5 K
 
Compressor efficiency: 70%
 
     Table1 shows these values together with the GWP of each mixed refrigerant. The COP and refrigerating capacity are ratios relative to R410A. 
     The coefficient of performance (COP) was determined by the following formula. 
       COP=(refrigerating capacity or heating capacity)/power consumption 
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 1 
               
               
                   
               
             
            
               
                   
                   
                 Com 
                 Com 
                 Com 
                   
                   
                   
                   
                   
                 Com 
                 Com 
               
               
                 Item 
                 Unit 
                 Ex. 1 
                 Ex. 2 
                 Ex. 3 
                 Ex. 1 
                 Ex. 2 
                 Ex. 3 
                 Ex. 4 
                 Ex. 5 
                 Ex. 4 
                 Ex. 5 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 R410A 
                 0.0 
                 0.79 
                 1.5 
                 
                   
                 
                 5.0 
                 7.5 
                 
                   
                 
                 12.5 
                 15.0 
               
               
                 R32 
                 mass % 
                   
                 25.0 
                 25.0 
                 25.0 
                 25.0 
                 25.0 
                 25.0 
                 25.0 
                 25.0 
                 25.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                   
                 35.0 
                 35.0 
                 35.0 
                 35.0 
                 35.0 
                 35.0 
                 35.0 
                 35.0 
                 35.0 
               
               
                 R1234ze 
                 mass % 
                   
                 
                   
                 
                 39.25 
                 38.5 
                 37.0 
                 35.0 
                 32.5 
                 30.0 
                 27.5 
                 25.0 
               
               
                 GWP 
                 — 
                 
                   
                 
                 172 
                 171 
                 171 
                 171 
                 171 
                 171 
                 171 
                 171 
                 171 
               
               
                 COP ratio 
                 % (relative 
                 100.0 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 100.4 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
               
               
                   
                 to R410A) 
               
               
                 Refrigerating 
                 % (relative 
                 100.0 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 103.3 
                 107.0 
               
               
                 capacity ratio 
                 to R410A) 
               
               
                 Condensation 
                 ° C. 
                 0 
                 7.1 
                 
                   
                 
                 8.0 
                 8.7 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
               
               
                 glide 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                    om 
                    om 
                 Com 
               
               
                   
                   
                 Ex. 6 
                 Ex. 7 
                 Ex. 8 
                 Ex. 9 
                 Ex. 10 
                 Ex. 11 
                 Ex. 12 
                 Ex. 13 
                 Ex. 14 
                 Ex. 15 
                 Ex. 1   
                 Ex. 1   
                 Ex. 18 
               
               
                 Item 
                 Unit 
                 A 
                 B 
                 A′ 
                 B′ 
                 C 
                 C′ 
                 D 
                 A 
                 B 
                 A′ 
                 B′ 
                 C 
                 D 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
               
               
                 R32 
                 mass % 
                 74.0 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 0.0 
                 74.0 
                 73.9 
                 59.2 
                 
                   
                 
                 
                   
                 
                 0.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 24.5 
                 0.0 
                 
                   
                 
                 0.0 
                 0.0 
                 
                   
                 
                 71.2 
                 23.0 
                 0.0 
                 37.8 
                 0.0 
                 0.0 
                 
                   
                 
               
               
                 R1234ze 
                 mass % 
                 0.0 
                 
                   
                 
                 0.0 
                 
                   
                 
                 
                   
                 
                 40.1  
                 27.3 
                 0.0 
                 
                   
                 
                 0.0 
                 
                   
                 
                 
                   
                 
                 
                   
                 
               
               
                 GWP 
                 — 
                 500 
                 500    
                 400 
                 400    
                 
                   
                 
                 
                   
                 
                 2 
                 500 
                 500 
                 400 
                 400    
                 
                   
                 
                 
                   
                 
               
               
                 COP ratio 
                 % (relative 
                 100.2 
                 102.0  
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 100.0 
                 93.7 
                 
                   
                 
                 98.6 
                 102.8  
                 103.2  
                 
                   
                 
               
               
                   
                 to R410A) 
               
               
                 Refrigerating 
                 % (relative 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 85.0 
                 115.3 
                 
                   
                 
                 115.5 
                 
                   
                 
                 
                   
                 
                 
                   
                 
               
               
                 capacity ratio 
                 to R410A) 
               
               
                 Condensation 
                 ° C. 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 5.4 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 7.5 
               
               
                 glide 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                    om 
                    om 
               
               
                   
                   
                 Ex. 19 
                 Ex. 20 
                 Ex. 21 
                 Ex. 22 
                 Ex. 23 
                 Ex. 24 
                 Ex. 25 
                 Ex. 26 
                 Ex. 27 
                 Ex. 28 
                 Ex.    
                 Ex.    
               
               
                 Item 
                 Unit 
                 A 
                 B 
                 A′ 
                 B′ 
                 C 
                 D 
                 A 
                 B 
                 A′ 
                 B′ 
                 C 
                 D 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
               
               
                 R32 
                 mass % 
                 74.0 
                 73.9 
                 59.2 
                 59.2 
                 49.3 
                  0.0 
                 74.0 
                 73.9 
                 59.2 
                 59.0 
                 44.1 
                 0.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 21.4 
                 0.0 
                 
                   
                 
                 0.0 
                  0.0 
                 
                   
                 
                 
                   
                 
                 0.0 
                 
                   
                 
                 0.0 
                 0.0 
                 
                   
                 
               
               
                 R1234ze 
                 mass % 
                 0.0 
                 21.5 
                  0.0 
                 
                   
                 
                 
                   
                 
                 34.2 
                 0.0 
                 
                   
                 
                 0.0 
                 34.0 
                 
                   
                 
                 
                   
                 
               
               
                 GWP 
                 — 
                 500 
                 500 
                 400   
                 400 
                 
                   
                 
                 
                   
                 
                 500 
                 500 
                 400 
                 400 
                 301 
                 
                   
                 
               
               
                 COP ratio 
                 % (relative 
                 
                   
                 
                 
                   
                 
                 98.1 
                 102.2 
                 102.7  
                 
                   
                 
                 
                   
                 
                 101.0 
                 
                   
                 
                 
                   
                 
                 102.1 
                 28.0  
               
               
                   
                 to R410A) 
               
               
                 Refrigerating 
                 % (relative 
                 116.6 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 105.4 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
               
               
                 capacity ratio 
                 to R410A) 
               
               
                 Condensation 
                 ° C. 
                 
                   
                 
                 4.5 
                  1.5 
                 7.4 
                 
                   
                 
                 
                   
                 
                 2.2 
                 4.9 
                 
                   
                 
                 
                   
                 
                 11.5 
                 
                   
                 
               
               
                 glide 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                   
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
               
               
                   
                   
                   
                 Ex. 36 
                 Ex. 37 
                 Ex. 38 
                 Ex. 39 
                 Ex. 40 
                 Ex. 41 
               
               
                   
                 Item 
                 Unit 
                 A 
                 B 
                 A′ 
                 B′ 
                 C 
                 D 
               
               
                   
                   
               
               
                   
                 HFO-1132a 
                 mass % 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
               
               
                   
                 R32 
                 mass % 
                 74.0 
                 73.9 
                 
                   
                 
                 
                   
                 
                 37.7 
                  0.0 
               
               
                   
                 HFO-1132 (E) 
                 mass % 
                 15.0 
                 0.0 
                 30.0 
                  0.0 
                  0.0 
                 45.2 
               
               
                   
                 R1234ze 
                 mass % 
                 0.0 
                 
                   
                 
                 0.0 
                 
                   
                 
                 
                   
                 
                 44.8 
               
               
                   
                 GWP 
                 — 
                 500 
                 500 
                 400 
                 400   
                 
                   
                 
                 
                   
                 
               
               
                   
                 COP ratio 
                 % (relative 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 100.4 
                 102.5  
                 
                   
                 
               
               
                   
                   
                 to R410A) 
               
               
                   
                 Refrigerating 
                 % (relative 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 100.1 
                 
                   
                 
                 
                   
                 
               
               
                   
                 capacity ratio 
                 to R410A) 
               
               
                   
                 Condensation 
                 ° C. 
                 
                   
                 
                 
                   
                 
                 2.7 
                 
                   
                 
                 
                   
                 
                 
                   
                 
               
               
                   
                 glide 
               
               
                   
                   
               
               
                   
                     indicates data missing or illegible when filed 
               
            
           
         
       
     
     Approximate expressions indicating the coordinates of each point were obtained by determining approximate expressions for the curves connecting five points, as shown in Table 2. 
     
       
         
           
               
               
               
             
               
                 TABLE 2 
               
               
                   
               
             
            
               
                 Item 
                 Unit 
                 Approximate expression calculation of point A 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
            
               
                 a = HFO-1132a 
                 mass % 
                 1.5 
                 3.0 
                 4.6 
                 7.0 
                 10.0 
               
               
                 x = R32 
                 mass % 
                 74.0 
                 74.0 
                 74.0 
                 74.0 
                 74.0 
               
               
                 y = HFO-1132 (E) 
                 mass % 
                 24.5 
                 23.0 
                 21.4 
                 19.0 
                 16.0 
               
               
                 z = R1234ze 
                 mass % 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
               
            
           
           
               
               
            
               
                 Approximate expression of x 
                 74.0 
               
               
                 Approximate expression of y 
                 −a + 26.0 
               
               
                 Approximate expression of z 
                  0.0 
               
               
                   
               
            
           
           
               
               
               
            
               
                 Item 
                 Unit 
                 Approximate expression calculation of point B 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
            
               
                 a = HFO-1132a 
                 mass % 
                 1.5 
                 3.0 
                 4.6 
                 7.0 
                 10.0 
               
               
                 x = R32 
                 mass % 
                 73.9 
                 73.9 
                 73.9 
                 73.9 
                 73.9 
               
               
                 y = HFO-1132 (E) 
                 mass % 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
               
               
                 z = R1234ze 
                 mass % 
                 24.6 
                 23.1 
                 21.5 
                 19.1 
                 16.1 
               
            
           
           
               
               
            
               
                 Approximate expression of x 
                 73.9 
               
               
                 Approximate expression of y 
                 0.0 
               
               
                 Approximate expression of z 
                 −a + 26.1 
               
               
                   
               
            
           
           
               
               
               
            
               
                 Item 
                 Unit 
                 Approximate expression calculation of point A′ 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
            
               
                 a = HFO-1132a 
                 mass % 
                 1.5 
                 3.0 
                 4.6 
                 7.0 
                 10.0 
               
               
                 x = R32 
                 mass % 
                 59.2 
                 59.2 
                 59.2 
                 59.2 
                 59.2 
               
               
                 y = HFO-1132 (E) 
                 mass % 
                 39.3 
                 37.8 
                 36.2 
                 33.8 
                 30.8 
               
               
                 z = R1234ze 
                 mass % 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
               
            
           
           
               
               
            
               
                 Approximate expression of x 
                 59.2 
               
               
                 Approximate expression of y 
                 −a + 40.8 
               
               
                 Approximate expression of z 
                  0.0 
               
               
                   
               
            
           
           
               
               
               
            
               
                 Item 
                 Unit 
                 Approximate expression calculation of point B′ 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
            
               
                 a = HFO-1132a 
                 mass % 
                 1.5 
                 3.0 
                 4.6 
                 7.0 
                 10.0 
               
               
                 x = R32 
                 mass % 
                 58.9 
                 58.9 
                 59.0 
                 59.0 
                 59.0 
               
               
                 y = HFO-1132 (E) 
                 mass % 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
               
               
                 z = R1234ze 
                 mass % 
                 39.6 
                 38.1 
                 36.4 
                 34.0 
                 31.0 
               
            
           
           
               
               
            
               
                 Approximate expression of x 
                  0.0132a + 58.891 
               
               
                 Approximate expression of y 
                 0.0 
               
               
                 Approximate expression of z 
                 −1.0132a + 41.109 
               
               
                   
               
            
           
           
               
               
               
            
               
                 Item 
                 Unit 
                 Approximate expression calculation of point C 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
            
               
                 a = HFO-1132a 
                 mass % 
                 1.5 
                 3.0 
                 4.6 
                 7.0 
                 10.0 
               
               
                 x = R32 
                 mass % 
                 56.2 
                 52.8 
                 49.3 
                 44.1 
                 37.7 
               
               
                 y = HFO-1132 (E) 
                 mass % 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
               
               
                 z = R1234ze 
                 mass % 
                 42.3 
                 44.2 
                 46.1 
                 48.9 
                 52.3 
               
            
           
           
               
               
            
               
                 Approximate expression of x 
                  0.0087a 2  − 2.2743a + 59.574 
               
               
                 Approximate expression of y 
                 0.0 
               
               
                 Approximate expression of z 
                 −0.0087a 2  + 1.2743a + 40.426 
               
               
                   
               
            
           
           
               
               
               
            
               
                 Item 
                 Unit 
                 Approximate expression calculation of point D 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
            
               
                 a = HFO-1132a 
                 mass % 
                 1.5 
                 3.0 
                 4.6 
                 7.0 
                 10.0 
               
               
                 x = R32 
                 mass % 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
               
               
                 y = HFO-1132 (E) 
                 mass % 
                 71.2 
                 66.3 
                 61.2 
                 53.9 
                 45.2 
               
               
                 z = R1234ze 
                 mass % 
                 27.3 
                 30.7 
                 34.2 
                 39.1 
                 44.8 
               
            
           
           
               
               
            
               
                 Approximate expression of x 
                 0.0 
               
               
                 Approximate expression of y 
                 0.0299a 2  − 3.4018a + 76.233 
               
               
                 Approximate expression of 2 
                 =D41 
               
               
                   
               
            
           
         
       
     
     These results demonstrate that the mixed refrigerants of R32, HFO-1132(E), R1234ze, and HFO-1132a have a GWP of 500 or less and a refrigerating capacity ratio of 85% or more relative to that of R410A when they satisfy the following requirements. 
     Requirements 
     When the mass % of R32, HFO-1132(E), R1234ze, and HFO-1132a based on their sum is respectively represented by x, y, z, and a, provided that 1.55a 10.0, coordinates (x,y,z) in a ternary composition diagram in which the sum of R32, HFO-1132(E), and R1234ze is (100−a) mass % are within the range of a figure surrounded by straight lines AB, BC, CD, DO, and OA that connect the following 5 points: 
     point A (74.0, −a+26.0, 0.0),
 
point B (73.9, 0.0, −a+26.1),
 
point C (0.0087a 2 −2.2743a+59.574, 0.0, −0.0087a 2 +1.2743a+40.426),
 
point D (0.0, 0.0299a 2 −3.4018a+76.233, −0.0299a 2 +2.4018a+23.767), and
 
point O (0.0, 100.0−a, 0.0),
 
or on the straight lines AB and CD (excluding the points A, B, C, and D).
 
     Further, these results demonstrate that the mixed refrigerants of R32, HFO-1132(E), R1234ze, and HFO-1132a have a GWP of 400 or less and a refrigerating capacity ratio of 85% or more relative to that of R410A when they satisfy the following requirements. 
     Requirements 
     When the mass % of R32, HFO-1132(E), R1234ze, and HFO-1132a based on their sum is respectively represented by x, y, z, and a, provided that 1.5≤a≤10.0, coordinates (x,y,z) in a ternary composition diagram in which the sum of R32, HFO-1132(E), and R1234ze is (100−a) mass % are within the range of a figure surrounded by straight lines A′B′, B′C, CD, DO, and OA′ that connect the following 5 points: 
     point A′ (59.2, −a+40.8, 0.0),
 
point B′ (0.0132a+58.891, 0.0, −1.0132a+41.109),
 
point C (0.0087a 2 −2.2743a+59.574, 0.0, −0.0087a 2 +1.2743a+40.426),
 
point D (0.0, 0.0299a°-3.4018a+76.233, −0.0299a 2 +2.4018a+23.767), and
 
point O (0.0, 100.0−a, 0.0),
 
or on the straight lines A′B′ and CD (excluding the points A′, B′, C, and D).
 
     Mixed refrigerants further comprising R1234yf in addition to R32, HFO-1132(E), R1234ze, and HFO-1132a were evaluated in the same manner as described above. Table 3 shows the results. 
     
       
         
           
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 3 
               
               
                   
               
             
            
               
                   
                   
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
               
               
                   
                   
                 Ex. 42 
                 Ex. 43 
                 Ex. 44 
                 Ex. 45 
                 Ex. 46 
                 Ex. 47 
                 Ex. 48 
                 Ex. 49 
               
               
                 Item 
                 Unit 
                 B   
                 B′   
                 C   
                 D   
                 B   
                 B′   
                 C   
                 D   
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
               
               
                 R32 
                 mass % 
                 73.9 
                 59.0 
                 50.7 
                 0.0 
                 73.9 
                 59.0 
                 44.7 
                 0.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 0.0 
                 0.0 
                 0.0 
                 87.5 
                 0.0 
                 0.0 
                 0.0 
                 63.2 
               
               
                 R1234(yf + ze) 
                 mass % 
                 12.3 
                 
                   
                 
                 
                   
                 
                 15.5 
                 24.6 
                 39.5 
                 
                   
                 
                 35.3 
               
               
                 GWP 
                 — 
                 500 
                 400 
                 345 
                 2 
                 500 
                 400 
                 304 
                 2 
               
               
                 COP ratio 
                 % (relative 
                 102.4 
                 102.6 
                 102.8 
                 99.7 
                 101.9 
                 101.8 
                 101.7 
                 99.3 
               
               
                   
                 to R410A) 
               
               
                 Refrigerating 
                 % (relative 
                 99.2 
                 90.5 
                 85.0 
                 85.0 
                 101.3 
                 93.7 
                 85.0 
                 85.0 
               
               
                 capacity ratio 
                 to R410A) 
               
               
                 Condensation 
                 ° C. 
                 2.5 
                 4.3 
                 
                   
                 
                 4.0 
                 1.5 
                 2.5 
                 4.0 
                 3.6 
               
               
                 glide 
               
               
                   
               
               
                   
                   
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
               
               
                   
                   
                 Ex. 50 
                 Ex. 51 
                 Ex. 52 
                 Ex. 53 
                 Ex. 54 
                 Ex. 55 
                 Ex. 56 
                 Ex. 57 
               
               
                 Item 
                 Unit 
                 B   
                 B′   
                 C   
                 D   
                 B   
                 B′   
                 C   
                 D   
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
               
               
                 R32 
                 mass % 
                 73.9 
                 59.0 
                 47.4 
                 0.0 
                 73.9 
                 59.1 
                 41.7 
                 0.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 0.0 
                 0.0 
                 0.0 
                 82.4 
                 0.0 
                 0.0 
                 0.0 
                 58.2 
               
               
                 R1234(yf + ze) 
                 mass % 
                 11.6 
                 19.0 
                 24.8 
                 17.3 
                 23.9 
                 0.0 
                 
                   
                 
                 38.8 
               
               
                 GWP 
                 — 
                 500 
                 400 
                 322 
                 2 
                 500 
                 400 
                 284 
                 2 
               
               
                 COP ratio 
                 % (relative 
                 101.9 
                 102.1 
                 102.3 
                 99.1 
                 101.3 
                 101.1 
                 101.3 
                 95.7 
               
               
                   
                 to R410A) 
               
               
                 Refrigerating 
                 % (relative 
                 101.4 
                 92.6 
                 85.0 
                 85.0 
                 109.5 
                 114.2 
                 85.0 
                 85.0 
               
               
                 capacity ratio 
                 to R410A) 
               
               
                 Condensation 
                 ° C. 
                 3.0 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 0.4 
                 1.6 
                 5.0 
                 5.1 
               
               
                 glide 
               
               
                   
               
               
                   
                   
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
               
               
                   
                   
                 Ex. 58 
                 Ex. 59 
                 Ex. 60 
                 Ex. 61 
                 Ex. 62 
                 Ex. 63 
                 Ex. 64 
                 Ex. 65 
               
               
                 Item 
                 Unit 
                 B   
                 B′   
                 C   
                 D   
                 B   
                 B′   
                 C   
                 D   
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
                 
                   
                 
               
               
                 R32 
                 mass % 
                 73.9 
                 59.0 
                 44.0 
                 0.0 
                 73.9 
                 59.0 
                 38.7 
                 0.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 0.0 
                 0.0 
                 0.0 
                 57.4 
                 0.0 
                 0.0 
                 0.0 
                 53.1 
               
               
                 R1234(yf + ze) 
                 mass % 
                 10.8 
                 18.2 
                 25.7 
                 10.0 
                 21.5 
                 0.0 
                 56.7 
                 42.3 
               
               
                 GWP 
                 — 
                 500 
                 400 
                 300 
                 3 
                 500 
                 400 
                 254 
                 2 
               
               
                 COP ratio 
                 % (relative 
                 101.4 
                 101.5 
                 101.9 
                 98.5 
                 101.0 
                 102.2 
                 100.8 
                 98.1 
               
               
                   
                 to R410A) 
               
               
                 Refrigerating 
                 % (relative 
                 103.6 
                 94.9 
                 85.0 
                 85.0 
                 105.3 
                 91.8 
                 85.0 
                 85.0 
               
               
                 capacity ratio 
                 to R410A) 
               
               
                 Condensation 
                 ° C. 
                 3.4 
                 5.3 
                 7.8 
                 8.1 
                 2.4 
                 7.4 
                 5.9 
                 
                   
                 
               
               
                 glide 
               
               
                   
               
               
                   
                   
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
               
               
                   
                   
                 Ex. 66 
                 Ex. 67 
                 Ex. 68 
                 Ex. 69 
                 Ex. 70 
                 Ex. 71 
                 Ex. 72 
                 Ex. 73 
               
               
                 Item 
                 Unit 
                 B   
                 B′   
                 C   
                 D   
                 B   
                 B′   
                 C   
                 D   
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
               
               
                 R32 
                 mass % 
                 73.9 
                 59.0 
                 39.2 
                 0.0 
                 73.9 
                 59.1 
                 34.3 
                 0.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 0.0 
                 0.0 
                 0.0 
                 50.0 
                 0.0 
                 0.0 
                 0.0 
                 46.1 
               
               
                 R1234(yf + ze) 
                 mass % 
                 9.6 
                 17.0 
                 
                   
                 
                 21.5 
                 
                   
                 
                 0.0 
                 58.7 
                 46.9 
               
               
                 GWP 
                 — 
                 500 
                 400 
                 
                   
                 
                 3 
                 500 
                 400 
                 234 
                 2 
               
               
                 COP ratio 
                 % (relative 
                 100.7 
                 100.8 
                 101.3 
                 97.8 
                 100.3 
                 
                   
                 
                 100.3 
                 
                   
                 
               
               
                   
                 to R410A) 
               
               
                 Refrigerating 
                 % (relative 
                 106.9 
                 98.4 
                 85.0 
                 85.0 
                 108.4 
                 119.3 
                 85.0 
                 85.0 
               
               
                 capacity ratio 
                 to R410A) 
               
               
                 Condensation 
                 ° C. 
                 3.9 
                 5.0 
                 
                   
                 
                 
                   
                 
                 3.0 
                 3.0 
                 7.4 
                 
                   
                 
               
               
                 glide 
               
               
                   
               
               
                   
                   
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
                 Com 
               
               
                   
                   
                 Ex. 74 
                 Ex. 75 
                 Ex. 76 
                 Ex. 77 
                 Ex. 78 
                 Ex. 79 
                 Ex. 80 
                 Ex. 81 
               
               
                 Item 
                 Unit 
                 B   
                 B′   
                 C   
                 D   
                 B   
                 B′   
                 C   
                 D   
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
               
               
                 R32 
                 mass % 
                 73.9 
                 59.0 
                 33.2 
                  0.0 
                 73.9 
                 59.1 
                 29.1 
                 0.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 0.0 
                 0.0 
                 0.0 
                 
                   
                 
                 0.0 
                 0.0 
                 0.0 
                 38.1 
               
               
                 R1234(yf + ze) 
                 mass % 
                 8.1 
                 
                   
                 
                 28.4 
                 24.2 
                 16.1 
                 0.0 
                 50.9 
                 51.9 
               
               
                 GWP 
                 — 
                 500 
                 400 
                 227 
                 3  
                 500 
                 400 
                 
                   
                 
                 3 
               
               
                 COP ratio 
                 % (relative 
                 99.8 
                 99.8 
                 100.6 
                 97.3 
                 99.5 
                 98.4 
                 99.7 
                 97.1 
               
               
                   
                 to R410A) 
               
               
                 Refrigerating 
                 % (relative 
                 111.0 
                 102.5 
                 85.0 
                 85.0 
                 112.2 
                 
                   
                 
                 85.0 
                 85.0 
               
               
                 capacity ratio 
                 to R410A) 
               
               
                 Condensation 
                 ° C. 
                 4.4 
                 6.4 
                 11.7 
                 
                   
                 
                 
                   
                 
                 3.7 
                 9.1 
                 10.9 
               
               
                 glide 
               
               
                   
               
               
                     indicates data missing or illegible when filed 
               
            
           
         
       
     
     Approximate expressions indicating the coordinates of each point were obtained by determining approximate expressions for the curves connecting three points, as shown in Tables 4 and 5. 
     
       
         
           
               
             
               
                 TABLE 4 
               
               
                   
               
             
            
               
                 Point B   
               
            
           
           
               
               
               
               
               
            
               
                   
                   
                   
                   
                 B   (r = R1234ze/(R1234ze + R1234yf)) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Item 
                 Unit 
                 0.0 
                 0.5 
                 1.0 
                 0.0 
                 0.5 
                 1.0 
                 0.0 
                 0.5 
                 1.0 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Specific 
                 HFO-1132a 
                 mass % 
                 1.5 
                 1.5 
                 1.5 
                 3.0 
                 3.0 
                 3.0 
                 4.6 
                 4.6 
                 4.6 
               
               
                 coordinates 
                 R32 
                 mass % 
                 73.9 
                 73.9 
                 73.9 
                 73.9 
                 73.9 
                 73.9 
                 73.9 
                 73.9 
                 73.9 
               
               
                   
                 HFO-1132E 
                 mass % 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
               
               
                   
                 R1234(ze + yf) 
                 mass % 
                 24.6 
                 24.6 
                 24.6 
                 23.1 
                 23.1 
                 23.1 
                 21.5 
                 21.5 
                 21.5 
               
            
           
           
               
               
               
               
               
            
               
                 r 
                 x = R32 approximate expression 
                 73.9 
                 73.9 
                 73.9 
               
               
                 approximate 
                 y = HFO-1132E approximate expression 
                 0.0 
                 0.0 
                 0.0 
               
               
                 expression 
                 z = R1234(ze + yf) approximate expression 
                 24.6 
                 23.1 
                 21.5 
               
            
           
           
               
               
               
               
               
               
            
               
                 x, y, z 
                 x 
                 a = HFO-1132a 
                 1.5 
                 3.0 
                 4.6 
               
               
                 approximate 
                   
                 Quadratic coefficient 
                 0 
                 0 
                 0 
               
               
                 expressions 
                   
                 Linear coefficient 
                 0 
                 0 
                 0 
               
               
                 represented 
                   
                 Zero coefficient 
                 24.6 
                 23.1 
                 21.5 
               
            
           
           
               
               
               
            
               
                 by a and r 
                 x approximate expression 
                 73.9 
               
               
                   
                 y approximate expression 
                 0.0 
               
               
                   
                 z approximate expression 
                 −x + 26.1 
               
               
                   
               
            
           
           
               
            
               
                 Point B′   
               
            
           
           
               
               
               
               
               
            
               
                   
                   
                   
                   
                 B′   (r = R1234ze/(R1234ze + R1234yf)) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Item 
                 Unit 
                 0.0 
                 0.5 
                 1.0 
                 0.0 
                 0.5 
                 1.0 
                 0.0 
                 0.5 
                 1.0 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Specific 
                 HFO-1132a 
                 mass % 
                 1.5 
                 1.5 
                 1.5 
                 3.0 
                 3.0 
                 3.0 
                 4.6 
                 4.6 
                 4.6 
               
               
                 coordinates 
                 R32 
                 mass % 
                 58.9 
                 59.0 
                 59.0 
                 58.9 
                 59.0 
                 59.1 
                 59.0 
                 59.0 
                 59.0 
               
               
                   
                 HFO-1132E 
                 mass % 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
               
               
                   
                 R1234(ze + yf) 
                 mass % 
                 39.6 
                 39.5 
                 39.5 
                 38.1 
                 39.0 
                 37.9 
                 36.4 
                 36.4 
                 36.4 
               
            
           
           
               
               
               
               
               
            
               
                 r 
                 x = R32 approximate expression 
                 −0.2r 2  + 0.3r + 58.9 
                 0.2r + 58.9 
                 59.0 
               
               
                 approximate 
                 y = HFO-1132E approximate expression 
                 0.0 
                 0.0 
                 0.0 
               
               
                 expression 
                 z = R1234(ze + yf) approximate expression 
                 100-a-x 
                 100-a-x 
                 36.4 
               
            
           
           
               
               
               
               
               
               
            
               
                 x, y, z 
                 y 
                 a = HFO-1132a 
                 1.5 
                 3.0 
                 4.6 
               
               
                 approximate 
                   
                 Quadratic coefficient 
                 −0.2  
                 0 
                 0 
               
               
                 expressions 
                   
                 Linear coefficient 
                 0.3 
                 0.2 
                 0 
               
               
                 represented 
                   
                 Zero coefficient 
                 58.9  
                 58.9 
                 59 
               
            
           
           
               
               
               
            
               
                 by a and r 
                 x approximate expression 
                 (−0.043a 2  + 0.3269a − 0.5935)r 2  + (−0.0188a 2  + 0.018a + 
               
               
                   
                   
                 0.3153)r + (0.0202a 2  − 0.0907a + 58.991) 
               
               
                   
                 y approximate expression 
                 0.0 
               
               
                   
                 z approximate expression 
                 100-a-x 
               
               
                   
               
               
                     indicates data missing or illegible when filed 
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 5 
               
               
                   
               
             
            
               
                 Point C   
               
            
           
           
               
               
               
               
               
            
               
                   
                   
                   
                   
                 C   (r = R1234ze/(R1234ze + R1234yf)) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Item 
                 Unit 
                 0.0 
                 0.5 
                 1.0 
                 0.0 
                 0.5 
                 1.0 
                 0.0 
                 0.5 
                 1.0 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Specific 
                 HFO-1132a 
                 mass % 
                 1.5 
                 1.5 
                 1.5 
                 3.0 
                 3.0 
                 3.0 
                 4.6 
                 4.6 
                 4.6 
               
               
                 coordinates 
                 R32 
                 mass % 
                 56.2 
                 50.7 
                 44.7 
                 52.8 
                 47.4 
                 41.7 
                 49.3 
                 44.0 
                 38.7 
               
               
                   
                 HFO-1132E 
                 mass % 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
               
               
                   
                 R1234(ze + yf) 
                 mass % 
                 42.3 
                 47.8 
                 53.8 
                 44.2 
                 49.6 
                 55.3 
                 46.1 
                 51.4 
                 56.7 
               
            
           
           
               
               
               
               
               
            
               
                 r 
                 x = R32 approximate expression 
                 −r 2  − 10.5r + 56.2 
                 −0.6r 2  − 10.5r + 52.8 
                 −10.6r + 49.3 
               
               
                 approximate 
                 y = HFO-1132E approximate expression 
                 0.0 
                 0.0 
                 0.0 
               
               
                 expression 
                 z = R1234(ze + yf) approximate expression 
                 100-a-x 
                 100-a-x 
                 100-a-x 
               
            
           
           
               
               
               
               
               
               
            
               
                 x, y, z 
                 x 
                 a = HFO-1132a 
                 1.5 
                 3.0 
                 4.6 
               
               
                 approximate 
                   
                 Quadratic coefficient 
                 −1 
                 −0.6 
                 0 
               
               
                 expressions 
                   
                 Linear coefficient 
                 −10.5 
                 −10.5 
                 −10.6 
               
               
                 represented 
                   
                 Zero coefficient 
                 56.2 
                 52.8 
                 49.3 
               
            
           
           
               
               
               
            
               
                 by a and r 
                 x approximate expression 
                 (0.0349a 2  + 0.1094a − 1.2427)r 2  + (−0.0202a 2  + 0.0907a − 
               
               
                   
                   
                 10.591)r + (0.0255a 2  − 2.3816a + 59.715) 
               
               
                   
                 y approximate expression 
                 0.0 
               
               
                   
                 z approximate expression 
                 100-a-x 
               
               
                   
               
            
           
           
               
               
            
               
                 Point D   
                   
               
            
           
           
               
               
               
               
               
               
            
               
                   
                   
                   
                   
                 D   (r = R1234ze/(R1234ze + R1234yf)) 
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Item 
                 Unit 
                 0.0 
                 0.5 
                 1.0 
                 0.0 
                 0.5 
                 1.0 
                 0.0 
                 0.5 
                 1.0 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Specific 
                 HFO-1132a 
                 mass % 
                 1.5 
                 1.5 
                 1.5 
                 3.0 
                 3.0 
                 3.0 
                 4.6 
                 4.6 
                 4.6 
               
               
                 coordinates 
                 R32 
                 mass % 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
               
               
                   
                 HFO-1132E 
                 mass % 
                 71.2 
                 67.5 
                 63.2 
                 66.3 
                 62.4 
                 58.2 
                 61.2 
                 57.4 
                 53.1 
               
               
                   
                 R1234(ze + yf) 
                 mass % 
                 27.3 
                 31.0 
                 35.3 
                 30.7 
                 34.6 
                 38.8 
                 34.2 
                 38.0 
                 42.3 
               
            
           
           
               
               
               
               
               
               
            
               
                 r 
                 x = R32 approximate expression 
                 0.0 
                 0.0 
                 0.0 
                   
               
               
                 approximate 
                 y = HFO-1132E approximate expression 
                 −1.2r 2  − 6.8r + 71.2 
                 −0.6r 2  − 7.5r + 66.3 
                 −r 2  − 7.1r + 61.2 
               
               
                 expression 
                 z = R1234(ze + yf) approximate expression 
                 100-a-y 
                 100-a-y 
                 100-a-y 
               
            
           
           
               
               
               
               
               
               
               
            
               
                 x, y, z 
                 y 
                 a = HFO-1132a 
                 1.5 
                 3.0 
                 4.6 
                   
               
               
                 approximate 
                   
                 Quadratic coefficient 
                 −1.2 
                 −0.6 
                 −1 
               
               
                 expressions 
                   
                 Linear coefficient 
                 −6.8 
                 −7.5 
                 −7.1 
               
               
                 represented 
                   
                 Zero coefficient 
                 71.2 
                 66.3 
                 51.2 
               
            
           
           
               
               
               
               
            
               
                 by a and r 
                 x approximate expression 
                 0.0 
                   
               
               
                   
                 y approximate expression 
                 (−0.2097a 2  + 1.3435a − 2.7435)r 2  + (0.2312a 2  − 1.507a − 
               
               
                   
                   
                 5.0597)r + (0.0255a 2  − 3.3816a + 76.215) 
               
               
                   
                 z approximate expression 
                 100-a-y 
               
               
                   
               
               
                     indicates data missing or illegible when filed 
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 6 
               
               
                   
               
             
            
               
                 Point Br 
               
            
           
           
               
               
               
               
               
            
               
                   
                   
                   
                   
                 B   (r = R1234ze/(R1234ze + R1234yf)) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Item 
                 Unit 
                 0.0 
                 0.5 
                 1.0 
                 0.0 
                 0.5 
                 1.0 
                 0.0 
                 0.5 
                 1.0 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Specific 
                 HFO-1132a 
                 mass % 
                 4.6 
                 4.6 
                 4.6 
                 7.0 
                 7.0 
                 7.0 
                 10.0 
                 10.0 
                 10.0 
               
               
                 coordinates 
                 R32 
                 mass % 
                 73.9 
                 73.9 
                 73.9 
                 73.9 
                 73.9 
                 73.9 
                 73.9 
                 73.9 
                 73.9 
               
               
                   
                 HFO-1132E 
                 mass % 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
               
               
                   
                 R1234(ze + yf) 
                 mass % 
                 21.5 
                 21.5 
                 21.5 
                 19.1 
                 19.1 
                 19.1 
                 16.1 
                 16.1 
                 16.1 
               
            
           
           
               
               
               
               
               
            
               
                 r 
                 x = R32 approximate expression 
                 73.9 
                 73.9 
                 73.9 
               
               
                 approximate 
                 y = HFO-1132E approximate expression 
                 0.0 
                 0.0 
                 0.0 
               
               
                 expression 
                 z = R1234(ze + yf) approximate expression 
                 21.5 
                 19.1 
                 16.1 
               
            
           
           
               
               
               
               
               
               
            
               
                 x, y, z 
                 x 
                 a = HFO-1132a 
                 4.6 
                 7.0 
                 10.0 
               
               
                 approximate 
                   
                 Quadratic coefficient 
                 0 
                 0 
                 0 
               
               
                 expressions 
                   
                 Linear coefficient 
                 0 
                 0 
                 0 
               
               
                 represented 
                   
                 Zero coefficient 
                 21.5 
                 19.1 
                 16.1 
               
            
           
           
               
               
               
            
               
                 by a and r 
                 x approximate expression 
                 73.9 
               
               
                   
                 y approximate expression 
                 0.0 
               
               
                   
                 z approximate expression 
                 −x + 26.1 
               
               
                   
               
            
           
           
               
            
               
                 Point B′r 
               
            
           
           
               
               
               
               
               
            
               
                   
                   
                   
                   
                 B′   (r = R1234ze/(R1234ze + R1234yf)) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Item 
                 Unit 
                 0.0 
                 0.5 
                 1.0 
                 0.0 
                 0.5 
                 1.0 
                 0.0 
                 0.5 
                 1.0 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Specific 
                 HFO-1132a 
                 mass % 
                 4.6 
                 4.6 
                 4.6 
                 7.0 
                 7.0 
                 7.0 
                 10.0 
                 10.0 
                 10.0 
               
               
                 coordinates 
                 R32 
                 mass % 
                 59.0 
                 59.0 
                 59.0 
                 59.0 
                 59.0 
                 59.1 
                 59.0 
                 59.0 
                 59.1 
               
               
                   
                 HFO-1132E 
                 mass % 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
               
               
                   
                 R1234(ze + yf) 
                 mass % 
                 36.4 
                 36.4 
                 36.4 
                 34.0 
                 34.0 
                 33.9 
                 31.0 
                 31.0 
                 30.9 
               
            
           
           
               
               
               
               
               
            
               
                 r 
                 x = R32 approximate expression 
                 59.0 
                 0.1r + 58.983 
                 0.1r + 58.983 
               
               
                 approximate 
                 y = HFO-1132E approximate expression 
                 0.0 
                 0.0 
                 0.0 
               
               
                 expression 
                 z = R1234(ze + yf) approximate expression 
                 36.4 
                 100-a-x 
                 36.4 
               
            
           
           
               
               
               
               
               
               
            
               
                 x, y, z 
                 x 
                 a = HFO-1132a 
                 4.6 
                 7.0 
                 10.0 
               
               
                 approximate 
                   
                 Quadratic coefficient 
                 0 
                 0 
                 0 
               
               
                 expressions 
                   
                 Linear coefficient 
                 0 
                 0.1 
                 0.1 
               
               
                 represented 
                   
                 Zero coefficient 
                 59 
                 58.983 
                 58.983 
               
            
           
           
               
               
               
            
               
                 by a and r 
                 x approximate expression 
                 (−0.0077a 2  + 0.1312a − 0.4401)r + (0.0013a 2  − 0.0223a + 59.075) 
               
               
                   
                 y approximate expression 
                 0.0 
               
               
                   
                 z approximate expression 
                 100-a-x 
               
               
                   
               
               
                     indicates data missing or illegible when filed 
               
            
           
         
       
     
     
       
         
           
               
             
               
                 TABLE 7 
               
               
                   
               
             
            
               
                 Point Cr 
               
            
           
           
               
               
               
               
               
            
               
                   
                   
                   
                   
                 C   (r = R1234ze/(R1234ze + R1234yf)) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Item 
                 Unit 
                 0.0 
                 0.5 
                 1.0 
                 0.0 
                 0.5 
                 1.0 
                 0.0 
                 0.5 
                 1.0 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Specific 
                 HFO-1132a 
                 mass % 
                 4.6 
                 4.6 
                 4.6 
                 7.0 
                 7.0 
                 7.0 
                 10.0 
                 10.0 
                 10.0 
               
               
                 coordinates 
                 R32 
                 mass % 
                 49.3 
                 44.0 
                 38.7 
                 44.1 
                 39.2 
                 34.3 
                 37.7 
                 33.2 
                 29.1 
               
               
                   
                 HFO-1132E 
                 mass % 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
               
               
                   
                 R1234(ze + yf) 
                 mass % 
                 46.1 
                 51.4 
                 56.7 
                 48.9 
                 53.8 
                 58.7 
                 52.3 
                 56.8 
                 60.9 
               
            
           
           
               
               
               
               
               
            
               
                 r 
                 x = R32 approximate expression 
                 −10.6r + 49.3 
                 −9.8r + 44.1 
                 0.8r 2  − 9.4r + 37.7 
               
               
                 approximate 
                 y = HFO-1132E approximate expression 
                 0.0 
                 0.0 
                  0.0 
               
               
                 expression 
                 z = R1234(ze + yf) approximate expression 
                 100-a-x 
                 100-a-x 
                 100-a-x 
               
            
           
           
               
               
               
               
               
               
            
               
                 x, y, z 
                 x 
                 a = HFO-1132a 
                 4.6 
                 7.0 
                 10.0 
               
               
                 approximate 
                   
                 Quadratic coefficient 
                 0 
                 0 
                  0.8 
               
               
                 expressions 
                   
                 Linear coefficient 
                 −10.6 
                 −9.8 
                 −9.4 
               
               
                 represented 
                   
                 Zero coefficient 
                 49.3 
                 44.1 
                 37.7 
               
            
           
           
               
               
               
            
               
                 by a and r 
                 x approximate expression 
                 (0.0494a 2  − 0.5728a + 1.5901)r 2  + (−0.037a 2  + 0.763a − 
               
               
                   
                   
                 13.326)r + (0.0062a 2  − 2.2383a + 59.465) 
               
               
                   
                 y approximate expression 
                 0.0 
               
               
                   
                 z approximate expression 
                 100-a-x 
               
               
                   
               
            
           
           
               
            
               
                 Point Dr 
               
            
           
           
               
               
               
               
               
            
               
                   
                   
                   
                   
                 D   (r = R1234ze/(R1234ze + R1234yf)) 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Item 
                 Unit 
                 0.0 
                 0.5 
                 1.0 
                 0.0 
                 0.5 
                 1.0 
                 0.0 
                 0.5 
                 1.0 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Specific 
                 HFO-1132a 
                 mass % 
                 4.6 
                 4.6 
                 4.6 
                 7.0 
                 7.0 
                 7.0 
                 10.0 
                 10.0 
                 10.0 
               
               
                 coordinates 
                 R32 
                 mass % 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
                 0.0 
               
               
                   
                 HFO-1132E 
                 mass % 
                 61.2 
                 57.4 
                 53.1 
                 53.9 
                 50.0 
                 46.1 
                 45.2 
                 41.6 
                 38.1 
               
               
                   
                 R1234(ze + yf) 
                 mass % 
                 34.2 
                 38.0 
                 42.3 
                 39.1 
                 43.0 
                 46.9 
                 44.8 
                 48.4 
                 51.9 
               
            
           
           
               
               
               
               
               
            
               
                 r 
                 x = R32 approximate expression 
                 0.0 
                 0.0 
                 0.0 
               
               
                 approximate 
                 y = HFO-1132E approximate expression 
                 −r 2  − 7.1r + 61.2 
                 −7.8r + 53.9 
                 0.2r 2  − 7.3r + 45.2 
               
               
                 expression 
                 z = R1234(ze + yf) approximate expression 
                 100-a-y 
                 100-a-y 
                 100-a-y 
               
            
           
           
               
               
               
               
               
               
            
               
                 x, y, z 
                 x 
                 a = HFO-1132a 
                 4.6 
                 7.0 
                 10.0 
               
               
                 approximate 
                   
                 Quadratic coefficient 
                 −1 
                 0 
                 0.2 
               
               
                 expressions 
                   
                 Linear coefficient 
                 −7.1 
                 −7.8 
                 −7.3 
               
               
                 represented 
                   
                 Zero coefficient 
                 61.2 
                 53.9 
                 45.2 
               
            
           
           
               
               
               
            
               
                 by a and r 
                 x approximate expression 
                 0.0 
               
               
                   
                 y approximate expression 
                 (−0.0548a 2  + 1.1685a − 5.0037)r 2  + (0.0849a 2  − 1.2762a − 
               
               
                   
                   
                 3.0253)r + (0.0262a 2  − 3.346a + 76.036) 
               
               
                   
                 z approximate expression 
                 100-a-y 
               
               
                   
               
               
                     indicates data missing or illegible when filed 
               
            
           
         
       
     
     The mixed refrigerants further comprising R1234yf in addition to R32, HFO-1132(E), R1234ze, and HFO-1132a have a GWP of 500 or less and a refrigerating capacity ratio of 85% or more relative to that of R410A, because they satisfy the following requirements. 
     Requirements 
     When the mass % of R32 is represented by f, the mass % of HFO-1132(E) is represented by y, the total mass % of R1234ze and R1234yf is represented by z, and the mass % of HFO-1132a is represented by a, provided that 1.5≤a≤10.0, based on the sum of R32, HFO-1132(E), R1234ze, R1234yf, and HFO-1132a, and r=R1234yf/(R1234ze+R1234yf), 
     if 1.5≤a≤4.6, coordinates (x,y,z) in a ternary composition diagram having R32 as a first vertex, HFO-1132(E) as a second vertex, and the sum of R1234ze and R1234yf as a third vertex are within the range of a figure surrounded by straight lines AB r , B r C r , C r D r , D r O, and OA that connect the following 5 points: 
     point A (74.0, −a+26.0, 0.0),
 
point B r  (73.9, 0.0, −a+26.1),
 
point C r  ((0.0349a 2 +0.1094a−1.2427)r 2 +(−0.0202a 2 +0.0907a−10.591)r+(0.0255a 2 −2.3816a+59.715), 0.0, −a−x+100.0), point D. (0.0, (−0.2097a 2 +1.3435a−2.7435)r 2 +(0.2312a 2 −1.507a−5.0597)r+(0.0255a 2 −3.3816a+76.215), −a−y+100.0), and
 
point O (0.0, 100.0−a, 0.0),
 
or on the straight lines AB r  and C r D r  (excluding the points A, B r , C r , and D r ); or
 
     if 4.6≤a≤10.0, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines AB r , B r C r , C r D r , D r O, and OA that connect the following 5 points: 
     point A (74.0, −a+26.0, 0.0),
 
point B r  (73.9, 0.0, −a+26.1),
 
point C r  ((0.0494a 2 −0.5728a+1.5901)r 2 +(−0.037a 2 +0.763a−13.326)r+(0.0062a 2 −2.2383a+59.465), 0.0, −a−x+100.0),
 
point D r  (0.0, (−0.0648a 2 +1.1685a−5.0037)r 2 +(0.0849a 2 −1.2762a−3.0253)r+(0.0262a 2 −3.346a+76.036), −a−y+100.0), and
 
point O (0.0, 100.0−a, 0.0),
 
or on the straight lines AB r  and C r D r  (excluding the points A, B r , C r , and D r ).
 
     The mixed refrigerants further comprising R1234yf in addition to R32, HFO-1132(E), R1234ze, and HFO-1132a have a GWP of 400 or less and a refrigerating capacity ratio of 85% or more relative to that of R410A, because they satisfy the following requirements. 
     Requirements 
     When the mass % of R32 is represented by x, the mass % of HFO-1132(E) is represented by y, the total mass % of R1234ze and R1234yf is represented by z, and the mass % of HFO-1132a is represented by a, provided that 1.5≤a≤10.0, based on the sum of R32, HFO-1132(E), R1234ze, R1234yf, and HFO-1132a, and r=R1234yf/(R1234ze+R1234yf), 
     if 1.5≤a≤4.6, coordinates (x,y,z) in a ternary composition diagram having R32 as a first vertex, HFO-1132(E) as a second vertex, and the sum of R1234ze and R1234yf as a third vertex are within the range of a figure surrounded by straight lines AB r ′, B r ′C r , C r D r , D r O, and OA that connect the following 5 points: 
     point A′ (74.0, −a+26.0, 0.0),
 
point B r ′ ((−0.043a 2 +0.3269a−0.5935) r 2 +(−0.0188a 2 +0.018a+0.3153)r+(0.0202a=−0.0907a+58.991), 0.0, −a−x+100.0),
 
point C r  ((0.0349a 2 +0.1094a−1.2427)r 2 +(−0.0202a 2 =+0.0907a−10.591)r+(0.0255a 2 −2.3816a+59.715), 0.0, −a−x+100.0),
 
point D r  (0.0, (−0.2097a 2 +1.3435a−2.7435)r 2 =+(0.2312a 2 −1.507a−5.0597)r+(0.0255a 2 −3.3816a+76.215), −a−y+100.0), and
 
point O (0.0, 100.0−a, 0.0),
 
or on the straight lines AB r ′ and C r D r  (excluding the points A, B r ′, C r , and D r ); or
 
     if 4.6≤a≤10.0, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines AB r ′, B r ′C r , C r D r , D r O, and OA that connect the following 5 points: 
     point A (74.0, −a+26.0, 0.0),
 
point B r ′ ((−0.0077a 2 +0.1312a−0.4401)r+(0.0013a=−0.0223a+59.075), 0.0, −a−x+100.0),
 
point C r  ((0.0494a 2 −0.5728a+1.5901)r 2 +(−0.037a 2 +0.763a−13.326)r+(0.0062a 2 −2.2383a+59.465), 0.0, −a−x+100.0),
 
point D r  (0.0, (−0.0648a 2 +1.1685a−5.0037)r 2 +(0.0849a=−1.2762a−3.0253)r+(0.0262a 2 −3.346a+76.036), −a−y+100.0), and
 
point O (0.0, 100.0−a, 0.0),
 
or on the straight lines AB r ′ and C r D r  (excluding the points A, B r ′, C r , and D r ).
 
     Further, the mixed refrigerants shown in the following tables were also evaluated, and the above effects were confirmed. 
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 8 
               
               
                   
               
             
            
               
                   
                   
                 Com 
                   
                   
                 Com 
                   
                   
                   
                 Com 
                   
               
               
                 Item 
                 Unit 
                 Ex. 83 
                 Ex. 6 
                 Ex. 7 
                 Ex. 84 
                 Ex. 8 
                 Ex. 9 
                 Ex. 10 
                 Ex. 85 
                 Ex. 11 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
               
               
                 R32 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 20.0 
                 20.0 
                 20.0 
                 20.0 
                 30.0 
                 30.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 50.0 
                 70.0 
                 80.0 
                 40.0 
                 50.0 
                 50.0 
                 70.0 
                 20.0 
                 40.0 
               
               
                 R1234(yf + ze) (r = 0) 
                 mass % 
                 38.5 
                 18.5 
                 8.5 
                 38.5 
                 28.5 
                 18.5 
                 8.5 
                 48.5 
                 28.5 
               
               
                 GWP 
                 — 
                 70 
                 69 
                 69 
                 138 
                 137 
                 137 
                 136 
                 206 
                 205 
               
               
                 COP ratio 
                 % (relative 
                 100.9 
                 99.1 
                 98.5 
                 101.1 
                 
                   
                 
                 99.0 
                 98.3 
                 102.9 
                 100.2 
               
               
                   
                 to R410A) 
               
               
                 Refrigerating 
                 % (relative 
                 81.9 
                 93.8 
                 99.6 
                 84.5 
                 90.7 
                 96.8 
                 102.7 
                 79.7 
                 92.8 
               
               
                 capacity ratio 
                 to R410A) 
               
               
                 Condensation 
                 ° C. 
                 7.9 
                 4.2 
                 2.5 
                 8.0 
                 6.0 
                 4.1 
                 2.4 
                 9.7 
                 5.9 
               
               
                 glide 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                   
                   
                 Com 
                   
                   
                   
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 12 
                 Ex. 13 
                 Ex. 86 
                 Ex. 14 
                 Ex. 15 
                 Ex. 16 
                 Ex. 17 
                 Ex. 18 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
               
               
                 R32 
                 mass % 
                 30.0 
                 30.0 
                 40.0 
                 40.0 
                 40.0 
                 40.0 
                 50.0 
                 50.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 50.0 
                 60.0 
                 10.0 
                 30.0 
                 40.0 
                 50.0 
                 10.0 
                 20.0 
               
               
                 R1234(yf + ze) (r = 0) 
                 mass % 
                 18.5 
                 8.5 
                 48.5 
                 28.5 
                 18.5 
                 8.5 
                 38.5 
                 28.5 
               
               
                 GWP 
                 — 
                 204 
                 204 
                 273 
                 272 
                 272 
                 271 
                 340 
                 339 
               
               
                 COP ratio 
                 % (relative 
                 
                   
                 
                 98.4 
                 103.4 
                 100.7 
                 99.8 
                 
                   
                 
                 102.6 
                 101.3 
               
               
                   
                 to R410A) 
               
               
                 Refrigerating 
                 % (relative 
                 99.0 
                 105.1 
                 80.5 
                 
                   
                 
                 100.7 
                 107.0 
                 87.9 
                 94.9 
               
               
                 capacity ratio 
                 to R410A) 
               
               
                 Condensation 
                 ° C. 
                 3.0 
                 2.2 
                 
                   
                 
                 
                   
                 
                 3.8 
                 2.0 
                 
                   
                 
                 5.3 
               
               
                 glide 
               
               
                   
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 Com 
               
               
                 Item 
                 Unit 
                 Ex. 19 
                 Ex. 20 
                 Ex. 21 
                 Ex. 22 
                 Ex. 23 
                 Ex. 24 
                 Ex. 25 
                 Ex. 87 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
               
               
                 R32 
                 mass % 
                 50.0 
                 50.0 
                 60.0 
                 60.0 
                 60.0 
                 70.0 
                 70.0 
                 80.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 30.0 
                 40.0 
                 10.0 
                 20.0 
                 30.0 
                 10.0 
                 20.0 
                 10.0 
               
               
                 R1234(yf + ze) (r = 0) 
                 mass % 
                 18.5 
                 8.5 
                 28.5 
                 18.5 
                 8.5 
                 18.5 
                 8.5 
                 8.5 
               
               
                 GWP 
                 — 
                 338 
                 338 
                 407 
                 405 
                 405 
                 474 
                 473 
                 541 
               
               
                 COP ratio 
                 % (relative 
                 100.2 
                 99.3 
                 102.1 
                 101.0 
                 99.9 
                 101.8 
                 100.7 
                 101.5 
               
               
                   
                 to R410A) 
               
               
                 Refrigerating 
                 % (relative 
                 101.7 
                 108.2 
                 95.0 
                 102.0 
                 108.7 
                 101.8 
                 
                   
                 
                 107.9 
               
               
                 capacity ratio 
                 to R410A) 
               
               
                 Condensation 
                 ° C. 
                 
                   
                 
                 1.9 
                 4.9 
                 3.4 
                 
                   
                 
                 3.1 
                 1.8 
                 1.7 
               
               
                 glide 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                 Com 
                   
                   
                 Com 
                   
                   
                   
                 Com 
                   
               
               
                 Item 
                 Unit 
                 Ex. 88 
                 Ex. 26 
                 Ex. 27 
                 Ex. 89 
                 Ex. 28 
                 Ex. 29 
                 Ex. 30 
                 Ex. 90 
                 Ex. 31 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
               
               
                 R32 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 20.0 
                 20.0 
                 20.0 
                 20.0 
                 30.0 
                 30.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 50.0 
                 70.0 
                 80.0 
                 30.0 
                 50.0 
                 60.0 
                 70.0 
                 20.0 
                 40.0 
               
               
                 R1234(yf + ze) (r = 0.25) 
                 mass % 
                 38.5 
                 18.5 
                 8.5 
                 48.5 
                 28.5 
                 18.5 
                 8.5 
                 48.5 
                 28.5 
               
               
                 GWP 
                 — 
                 70 
                 69 
                 69 
                 138 
                 137 
                 137 
                 136 
                 205 
                 204 
               
               
                 COP ratio 
                 % (relative 
                 100.4 
                 98.8 
                 98.5 
                 101.7 
                 99.6 
                 98.8 
                 
                   
                 
                 102.1 
                 99.8 
               
               
                   
                 to R410A) 
               
               
                 Refrigerating 
                 % (relative 
                 
                   
                 
                 94.5 
                 99.9 
                 79.9 
                 91.8 
                 97.5 
                 103.0 
                 81.5 
                 94.0 
               
               
                 capacity ratio 
                 to R410A) 
               
               
                 Condensation 
                 ° C. 
                 6.9 
                 3.7 
                 2.3 
                 
                   
                 
                 5.2 
                 3.6 
                 2.2 
                 8.4 
                 5.1 
               
               
                 glide 
               
               
                   
               
               
                   
                   
                   
                   
                 Com 
                   
                   
                   
                   
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 32 
                 Ex. 33 
                 Ex. 91 
                 Ex. 34 
                 Ex. 35 
                 Ex. 36 
                 Ex. 37 
                 Ex. 38 
                 Ex. 39 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
               
               
                 R32 
                 mass % 
                 30.0 
                 30.0 
                 40.0 
                 40.0 
                 40.0 
                 40.0 
                 40.0 
                 50.0 
                 50.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 50.0 
                 50.0 
                 10.0 
                 20.0 
                 30.0 
                 40.0 
                 50.0 
                 10.0 
                 20.0 
               
               
                 R1234(yf + ze) (r = 0.25) 
                 mass % 
                 18.5 
                 8.5 
                 48.5 
                 38.5 
                 28.5 
                 18.5 
                 8.5 
                 38.5 
                 28.5 
               
               
                 GWP 
                 — 
                 204 
                 204 
                 273 
                 272 
                 272 
                 271 
                 271 
                 340 
                 339 
               
               
                 COP ratio 
                 % (relative 
                 99.0 
                 98.3 
                 102.7 
                 101.4 
                 100.3 
                 99.4 
                 98.7 
                 102.2 
                 101.0 
               
               
                   
                 to R410A) 
               
               
                 Refrigerating 
                 % (relative 
                 99.9 
                 105.5 
                 82.4 
                 89.1 
                 95.4 
                 101.5 
                 107.4 
                 89.6 
                 96.2 
               
               
                 capacity ratio 
                 to R410A) 
               
               
                 Condensation 
                 ° C. 
                 3.4 
                 1.9 
                 7.7 
                 6.4 
                 4.8 
                 3.3 
                 
                   
                 
                 
                   
                 
                 4.5 
               
               
                 glide 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 Com 
               
               
                 Item 
                 Unit 
                 Ex. 40 
                 Ex. 41 
                 Ex. 42 
                 Ex. 43 
                 Ex. 44 
                 Ex. 45 
                 Ex. 46 
                 Ex. 92 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
               
               
                 R32 
                 mass % 
                 50.0 
                 50.0 
                 60.0 
                 60.0 
                 60.0 
                 70.0 
                 70.0 
                 80.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 30.0 
                 40.0 
                 10.0 
                 20.0 
                 30.0 
                 10.0 
                 20.0 
                 10.0 
               
               
                 R1234(yf + ze) (r = 0.25) 
                 mass % 
                 18.5 
                 8.5 
                 28.5 
                 18.5 
                 8.5 
                 18.5 
                 8.5 
                 8.5 
               
               
                 GWP 
                 — 
                 339 
                 338 
                 407 
                 406 
                 406 
                 474 
                 473 
                 541 
               
               
                 COP ratio 
                 % (relative 
                 100.0 
                 99.2 
                 101.8 
                 100.8 
                 99.8 
                 101.6 
                 100.6 
                 101.4 
               
               
                   
                 to R410A) 
               
               
                 Refrigerating 
                 % (relative 
                 102.5 
                 108.5 
                 96.3 
                 102.9 
                 109.1 
                 102.6 
                 109.0 
                 108.3 
               
               
                 capacity ratio 
                 to R410A) 
               
               
                 Condensation 
                 ° C. 
                 3.1 
                 1.7 
                 4.1 
                 2.9 
                 
                   
                 
                 2.7 
                 1.5 
                 1.5 
               
               
                 glide 
               
               
                   
               
               
                     indicates data missing or illegible when filed 
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 9 
               
               
                   
               
             
            
               
                   
                   
                 Com 
                   
                   
                   
                 Com 
                   
                   
                   
                 Com 
                   
               
               
                 Item 
                 Unit 
                 Ex. 93 
                 Ex. 47 
                 Ex. 48 
                 Ex. 49 
                 Ex. 94 
                 Ex. 50 
                 Ex. 51 
                 Ex. 52 
                 Ex. 95 
                 Ex. 53 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
               
               
                 R32 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 20.0 
                 20.0 
                 20.0 
                 20.0 
                 30.0 
                 30.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 40.0 
                 50.0 
                 70.0 
                 80.0 
                 30.0 
                 60.0 
                 60.0 
                 70.0 
                 20.0 
                 30.0 
               
               
                 R1234(yf + ze) (r = 0.5) 
                 mass % 
                 48.5 
                 28.5 
                 18.5 
                 8.5 
                 48.5 
                 28.5 
                 18.5 
                 8.5 
                 48.5 
                 38.5 
               
               
                 GWP 
                 — 
                 70 
                 70 
                 69 
                 69 
                 138 
                 137 
                 137 
                 136 
                 205 
                 205 
               
               
                 COP ratio 
                 % (relative 
                 100.9 
                 99.3 
                 
                   
                 
                 98.4 
                 101.0 
                 99.2 
                 
                   
                 
                 98.2 
                 101.4 
                 100.4 
               
               
                   
                 to R410A) 
               
               
                 Refrigerating 
                 % (relative 
                 79.0 
                 
                   
                 
                 95.3 
                 100.3 
                 
                   
                 
                 93.0 
                 98.3 
                 103.4 
                 83.4 
                 
                   
                 
               
               
                 capacity ratio 
                 to R410A) 
               
               
                 Condensation 
                 ° C. 
                 7.4 
                 
                   
                 
                 3.3 
                 2.1 
                 7.4 
                 4.5 
                 3.1 
                 
                   
                 
                 7.0 
                 5.7 
               
               
                 glide 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                   
                   
                   
                 Com 
                   
                   
                   
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 54 
                 Ex. 55 
                 Ex. 56 
                 Ex. 96 
                 Ex. 57 
                 Ex. 58 
                 Ex. 59 
                 Ex. 60 
                 Ex. 61 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
               
               
                 R32 
                 mass % 
                 30.0 
                 30.0 
                 30.0 
                 40.0 
                 40.0 
                 40.0 
                 40.0 
                 40.0 
                 50.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 40.0 
                 50.0 
                 50.0 
                 10.0 
                 20.0 
                 30.0 
                 40.0 
                 50.0 
                 10.0 
               
               
                 R1234(yf + ze) (r = 0.5) 
                 mass % 
                 28.5 
                 18.5 
                 8.5 
                 48.5 
                 38.5 
                 28.5 
                 18.5 
                 8.5 
                 38.5 
               
               
                 GWP 
                 — 
                 204 
                 204 
                 204 
                 273 
                 272 
                 272 
                 271 
                 271 
                 340 
               
               
                 COP ratio 
                 % (relative 
                 99.5 
                 98.8 
                 98.3 
                 102.0 
                 100.9 
                 100.0 
                 99.2 
                 98.6 
                 101.7 
               
               
                   
                 to R410A) 
               
               
                 Refrigerating 
                 % (relative 
                 
                   
                 
                 100.7 
                 
                   
                 
                 84.4 
                 90.7 
                 96.7 
                 102.4 
                 107.2 
                 91.3 
               
               
                 capacity ratio 
                 to R410A) 
               
               
                 Condensation 
                 ° C. 
                 4.3 
                 3.0 
                 1.7 
                 6.4 
                 5.3 
                 4.0 
                 
                   
                 
                 1.5 
                 
                   
                 
               
               
                 glide 
               
               
                   
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 Com 
               
               
                 Item 
                 Unit 
                 Ex. 62 
                 Ex. 63 
                 Ex. 64 
                 Ex. 65 
                 Ex. 66 
                 Ex. 67 
                 Ex. 68 
                 Ex. 69 
                 Ex. 97 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
               
               
                 R32 
                 mass % 
                 50.0 
                 50.0 
                 50.0 
                 60.0 
                 60.0 
                 60.0 
                 70.0 
                 70.0 
                 80.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 20.0 
                 30.0 
                 40.0 
                 10.0 
                 20.0 
                 30.0 
                 10.0 
                 20.0 
                 10.0 
               
               
                 R1234(yf + ze) (r = 0.5) 
                 mass % 
                 28.5 
                 18.5 
                 8.5 
                 28.5 
                 18.5 
                 8.5 
                 18.5 
                 8.5 
                 8.5 
               
               
                 GWP 
                 — 
                 339 
                 339 
                 338 
                 407 
                 406 
                 406 
                 474 
                 473 
                 541 
               
               
                 COP ratio 
                 % (relative 
                 100.7 
                 99.8 
                 99.1 
                 101.6 
                 100.6 
                 99.8 
                 101.5 
                 100.5 
                 101.3 
               
               
                   
                 to R410A) 
               
               
                 Refrigerating 
                 % (relative 
                 97.5 
                 103.4 
                 108.9 
                 97.5 
                 103.7 
                 109.5 
                 103.4 
                 109.4 
                 108.7 
               
               
                 capacity ratio 
                 to R410A) 
               
               
                 Condensation 
                 ° C. 
                 3.7 
                 2.6 
                 1.5 
                 3.4 
                 2.5 
                 1.4 
                 2.3 
                 1.4 
                 1.3 
               
               
                 glide 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                 Com 
                   
                   
                   
                 Com 
                   
                   
                   
                 Com 
                   
               
               
                 Item 
                 Unit 
                 Ex. 98 
                 Ex. 70 
                 Ex. 71 
                 Ex. 72 
                 Ex. 99 
                 Ex. 73 
                 Ex. 74 
                 Ex. 75 
                 Ex. 10   
                 Ex. 76 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
               
               
                 R32 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 20.0 
                 20.0 
                 20.0 
                 20.0 
                 30.0 
                 30.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 40.0 
                 60.0 
                 70.0 
                 80.0 
                 30.0 
                 50.0 
                 60.0 
                 70.0 
                 15.0 
                 30.0 
               
               
                 R1234(yf + ze) (r = 0.75) 
                 mass % 
                 48.5 
                 28.5 
                 18.5 
                 8.5 
                 48.5 
                 28.5 
                 18.5 
                 8.5 
                 53.5 
                 38.5 
               
               
                 GWP 
                 — 
                 70 
                 69 
                 69 
                 69 
                 137 
                 137 
                 136 
                 136 
                 205 
                 205 
               
               
                 COP ratio 
                 % (relative 
                 100.2 
                 89.0 
                 98.6 
                 98.3 
                 100.4 
                 98.9 
                 98.4 
                 98.1 
                 101.3 
                 99.9 
               
               
                   
                 to R410A) 
               
               
                 Refrigerating 
                 % (relative 
                 
                   
                 
                 91.1 
                 
                   
                 
                 100.5 
                 83.3 
                 94.1 
                 99.1 
                 103.8 
                 82.2 
                 91.0 
               
               
                 capacity ratio 
                 to R410A) 
               
               
                 Condensation 
                 ° C. 
                 6.3 
                 3.8 
                 2.8 
                 1.9 
                 6.2 
                 3.8 
                 2.7 
                 1.7 
                 6.3 
                 4.7 
               
               
                 glide 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                   
                   
                   
                 Com 
                   
                   
                   
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 77 
                 Ex. 78 
                 Ex. 79 
                 Ex. 10   
                 Ex. 80 
                 Ex. 81 
                 Ex. 82 
                 Ex. 83 
                 Ex. 84 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
               
               
                 R32 
                 mass % 
                 30.0 
                 30.0 
                 30.0 
                 40.0 
                 40.0 
                 40.0 
                 40.0 
                 40.0 
                 50.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 40.0 
                 50.0 
                 60.0 
                 5.0 
                 20.0 
                 30.0 
                 40.0 
                 50.0 
                 10.0 
               
               
                 R1234(yf + ze) (r = 0.75) 
                 mass % 
                 28.5 
                 18.5 
                 8.5 
                 53.5 
                 38.5 
                 28.5 
                 18.5 
                 8.5 
                 38.5 
               
               
                 GWP 
                 — 
                 204 
                 204 
                 203 
                 272 
                 272 
                 272 
                 271 
                 271 
                 339 
               
               
                 COP ratio 
                 % (relative 
                 99.1 
                 98.6 
                 98.2 
                 101.9 
                 100.5 
                 99.7 
                 99.0 
                 98.5 
                 101.3 
               
               
                   
                 to R410A) 
               
               
                 Refrigerating 
                 % (relative 
                 
                   
                 
                 101.5 
                 105.3 
                 83.1 
                 92.3 
                 97.9 
                 103.2 
                 108.1 
                 92.9 
               
               
                 capacity ratio 
                 to R410A) 
               
               
                 Condensation 
                 ° C. 
                 3.5 
                 2.5 
                 1.5 
                 5.6 
                 4.3 
                 3.3 
                 2.3 
                 1.4 
                 3.8 
               
               
                 glide 
               
               
                   
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 Com 
               
               
                 Item 
                 Unit 
                 Ex. 85 
                 Ex. 86 
                 Ex. 87 
                 Ex. 88 
                 Ex. 89 
                 Ex. 90 
                 Ex. 91 
                 Ex. 92 
                 Ex. 102 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
                 1.5 
               
               
                 R32 
                 mass % 
                 50.0 
                 50.0 
                 50.0 
                 60.0 
                 60.0 
                 60.0 
                 70.0 
                 70.0 
                 80.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 20.0 
                 30.0 
                 40.0 
                 10.0 
                 20.0 
                 30.0 
                 10.0 
                 20.0 
                 10.0 
               
               
                 R1234(yf + ze) (r = 0.75) 
                 mass % 
                 28.5 
                 18.5 
                 8.5 
                 28.5 
                 18.5 
                 8.5 
                 18.5 
                 8.5 
                 8.5 
               
               
                 GWP 
                 — 
                 339 
                 339 
                 335 
                 406 
                 406 
                 406 
                 473 
                 473 
                 549 
               
               
                 COP ratio 
                 % (relative 
                 100.4 
                 99.6 
                 99.0 
                 101.3 
                 100.4 
                 99.7 
                 101.3 
                 100.4 
                 101.2 
               
               
                   
                 to R410A) 
               
               
                 Refrigerating 
                 % (relative 
                 98.5 
                 104.2 
                 109.3 
                 98.9 
                 104.6 
                 109.9 
                 104.2 
                 109.7 
                 109.0 
               
               
                 capacity ratio 
                 to R410A) 
               
               
                 Condensation 
                 ° C. 
                 3.0 
                 2.2 
                 1.3 
                 2.7 
                 2.0 
                 1.2 
                 1.8 
                 1.2 
                 1.2 
               
               
                 glide 
               
               
                   
               
               
                     indicates data missing or illegible when filed 
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 10 
               
               
                   
               
             
            
               
                   
                   
                 Com 
                   
                   
                   
                 Com 
                   
                   
                   
                 Com 
               
               
                 Item 
                 Unit 
                 Ex. 10   
                 Ex. 93 
                 Ex. 94 
                 Ex. 95 
                 Ex. 10   
                 Ex. 96 
                 Ex. 97 
                 Ex. 98 
                 Ex. 10   
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
               
               
                 R32 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 20.0 
                 20.0 
                 20.0 
                 20.0 
                 30.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 45.0 
                 60.0 
                 70.0 
                 80.0 
                 35.0 
                 50.0 
                 60.0 
                 70.0 
                 20.0 
               
               
                 R1234(yf + ze) (r = 0) 
                 mass % 
                 42.0 
                 27.0 
                 17.0 
                 7.0 
                 42.0 
                 27.0 
                 17.0 
                 7.0 
                 47.0 
               
               
                 GWP 
                 — 
                 71 
                 70 
                 69 
                 69 
                 138 
                 137 
                 137 
                 136 
                 206 
               
               
                 COP ratio 
                    relative 
                 100.5 
                 99.0 
                 98.2 
                 97.7 
                 100.8 
                 99.0 
                 98.2 
                 97.5 
                 102.0 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 81.5 
                 90.6 
                 96.5 
                 102.3 
                 83.9 
                 93.3 
                 99.4 
                 105.3 
                 82.2 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 10.0 
                 6.9 
                 4.9 
                 3.2 
                 9.8 
                 6.7 
                 4.7 
                 2.9 
                 10.5 
               
               
                 glide 
               
               
                   
               
               
                   
                   
                   
                   
                   
                 Com 
               
               
                 Item 
                 Unit 
                 Ex. 99 
                 Ex. 100 
                 Ex. 101 
                 Ex. 10   
                 Ex. 102 
                 Ex. 103 
                 Ex. 104 
                 Ex. 105 
                 Ex. 106 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
               
               
                 R32 
                 mass % 
                 30.0 
                 30.0 
                 30.0 
                 40.0 
                 40.0 
                 40.0 
                 40.0 
                 40.0 
                 50.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 40.0 
                 50.0 
                 60.0 
                 10.0 
                 20.0 
                 30.0 
                 40.0 
                 50.0 
                 10.0 
               
               
                 R1234(yf + ze) (r = 0) 
                 mass % 
                 27.0 
                 17.0 
                 7.0 
                 47.0 
                 37.0 
                 27.0 
                 17.0 
                 7.0 
                 37.0 
               
               
                 GWP 
                 — 
                 205 
                 204 
                 204 
                 273 
                 272 
                 272 
                 271 
                 271 
                 340 
               
               
                 COP ratio 
                    relative 
                 99.4 
                 98.4 
                 97.6 
                 102.7 
                 101.2 
                 99.9 
                 98.9 
                 98.0 
                 102.0 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 95.3 
                 101.6 
                 107.7 
                 82.9 
                 89.9 
                 95.6 
                 103.1 
                 109.4 
                 90.3 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 5.4 
                 4.4 
                 2.5 
                 9.8 
                 8.1 
                 6.1 
                 4.1 
                 2.3 
                 7.5 
               
               
                 glide 
               
               
                   
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 Com 
               
               
                 Item 
                 Unit 
                 Ex. 107 
                 Ex. 108 
                 Ex. 109 
                 Ex. 110 
                 Ex. 111 
                 Ex. 112 
                 Ex. 113 
                 Ex. 114 
                 Ex. 107 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
               
               
                 R32 
                 mass % 
                 50.0 
                 50.0 
                 50.0 
                 60.0 
                 60.0 
                 60.0 
                 70.0 
                 70.0 
                 80.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 20.0 
                 30.0 
                 40.0 
                 10.0 
                 20.0 
                 30.0 
                 10.0 
                 20.0 
                 10.0 
               
               
                 R1234(yf + ze) (r = 0) 
                 mass % 
                 27.0 
                 17.0 
                 7.0 
                 27.0 
                 17.0 
                 7.0 
                 17.0 
                 7.0 
                 7.0 
               
               
                 GWP 
                 — 
                 339 
                 339 
                 338 
                 407 
                 406 
                 406 
                 474 
                 473 
                 541 
               
               
                 COP ratio 
                    relative 
                 100.7 
                 99.6 
                 98.6 
                 101.5 
                 100.4 
                 99.3 
                 101.3 
                 100.1 
                 101.0 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 97.3 
                 104.1 
                 110.6 
                 97.4 
                 104.4 
                 111.1 
                 104.1 
                 110.9 
                 110.2 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 5.7 
                 3.9 
                 2.2 
                 5.3 
                 3.7 
                 2.1 
                 3.5 
                 2.1 
                 2.0 
               
               
                 glide 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                 Com 
                   
                   
                   
                 Com 
                   
                   
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 10   
                 Ex. 115 
                 Ex. 116 
                 Ex. 117 
                 Ex. 10   
                 Ex. 118 
                 Ex. 119 
                 Ex. 120 
                 Ex. 121 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
               
               
                 R32 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 20.0 
                 20.0 
                 20.0 
                 20.0 
                 20.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 40.0 
                 60.0 
                 70.0 
                 80.0 
                 30.0 
                 40.0 
                 50.0 
                 60.0 
                 70.0 
               
               
                 R1234(yf + ze) (r = 0.25) 
                 mass % 
                 47.0 
                 27.0 
                 17.0 
                 7.0 
                 47.0 
                 37.0 
                 27.0 
                 17.0 
                 7.0 
               
               
                 GWP 
                 — 
                 71 
                 70 
                 69 
                 69 
                 138 
                 137 
                 137 
                 137 
                 136 
               
               
                 COP ratio 
                    relative 
                 100.6 
                 98.7 
                 98.1 
                 97.6 
                 100.9 
                 99.7 
                 98.7 
                 98.0 
                 97.5 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 80.0 
                 91.6 
                 97.2 
                 102.6 
                 82.4 
                 88.5 
                 94.4 
                 100.1 
                 105.6 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 9.7 
                 6.1 
                 4.5 
                 3.0 
                 9.5 
                 7.7 
                 5.9 
                 4.2 
                 2.7 
               
               
                 glide 
               
               
                   
               
               
                   
                   
                 Com 
                   
                   
                   
                   
                 Com 
               
               
                 Item 
                 Unit 
                 Ex. 11   
                 Ex. 122 
                 Ex. 123 
                 Ex. 124 
                 Ex. 125 
                 Ex. 11   
                 Ex. 126 
                 Ex. 127 
                 Ex. 128 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
               
               
                 R32 
                 mass % 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 40.0 
                 40.0 
                 40.0 
                 40.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 15.0 
                 30.0 
                 40.0 
                 50.0 
                 60.0 
                 5.0 
                 20.0 
                 30.0 
                 40.0 
               
               
                 R1234(yf + ze) (r = 0.25) 
                 mass % 
                 52.0 
                 37.0 
                 27.0 
                 17.0 
                 7.0 
                 52.0 
                 37.0 
                 27.0 
                 17.0 
               
               
                 GWP 
                 — 
                 206 
                 205 
                 204 
                 204 
                 204 
                 273 
                 272 
                 272 
                 271 
               
               
                 COP ratio 
                    relative 
                 102.1 
                 100.1 
                 99.1 
                 98.2 
                 97.6 
                 102.7 
                 100.7 
                 99.6 
                 98.7 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 80.7 
                 90.3 
                 96.4 
                 102.3 
                 108.0 
                 81.3 
                 91.5 
                 97.8 
                 103.9 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 9.9 
                 7.3 
                 5.6 
                 3.9 
                 2.4 
                 9.0 
                 6.9 
                 5.3 
                 3.6 
               
               
                 glide 
               
               
                   
               
               
                 Item 
                 Unit 
                 Ex. 129 
                 Ex. 130 
                 Ex. 131 
                 Ex. 132 
                 Ex. 133 
                 Ex. 134 
                 Ex. 135 
                 Ex. 136 
                 Ex. 137 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
               
               
                 R32 
                 mass % 
                 40.0 
                 50.0 
                 50.0 
                 50.0 
                 50.0 
                 60.0 
                 60.0 
                 60.0 
                 70.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 50.0 
                 10.0 
                 20.0 
                 30.0 
                 40.0 
                 10.0 
                 20.0 
                 30.0 
                 10.0 
               
               
                 R1234(yf + ze) (r = 0.25) 
                 mass % 
                 7.0 
                 37.0 
                 27.0 
                 17.0 
                 7.0 
                 27.0 
                 17.0 
                 7.0 
                 17.0 
               
               
                 GWP 
                 — 
                 271 
                 340 
                 339 
                 339 
                 338 
                 407 
                 406 
                 406 
                 474 
               
               
                 COP ratio 
                    relative 
                 98.0 
                 101.5 
                 100.4 
                 99.4 
                 98.5 
                 101.3 
                 100.2 
                 99.3 
                 101.1 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 109.8 
                 91.9 
                 98.6 
                 104.9 
                 110.9 
                 98.6 
                 105.2 
                 111.4 
                 104.8 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 2.1 
                 6.4 
                 4.9 
                 3.5 
                 2.0 
                 4.6 
                 3.3 
                 2.0 
                 3.1 
               
               
                 glide 
               
               
                   
               
               
                     indicates data missing or illegible when filed 
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
             
               
                   
                 TABLE 11 
               
               
                   
                   
               
             
            
               
                   
                   
                   
                   
                 Com 
               
               
                   
                 Item 
                 Unit 
                 Ex. 138 
                 Ex. 112 
               
               
                   
                   
               
               
                   
                 HFO-1132a 
                 mass % 
                 3.0 
                 3.0 
               
               
                   
                 R32 
                 mass % 
                 70.0 
                 80.0 
               
               
                   
                 HFO-1132 (E) 
                 mass % 
                 20.0 
                 10.0 
               
               
                   
                 R1234(yf + ze) (r = 0.25) 
                 mass % 
                 7.0 
                 7.0 
               
               
                   
                 GWP 
                 — 
                 473 
                 541 
               
               
                   
                 COP ratio 
                    relative 
                 100.1 
                 100.9 
               
               
                   
                   
                 to R41   
               
               
                   
                 Refrigerating 
                    relative 
                 111.2 
                 110.5 
               
               
                   
                 capacity r   
                 to R41   
               
               
                   
                 Condensation 
                 ° C. 
                 1.9 
                 1.8 
               
               
                   
                 glide 
               
               
                   
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                 Com 
                   
                   
                   
                   
                 Com 
                   
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 11   
                 Ex. 139 
                 Ex. 140 
                 Ex. 141 
                 Ex. 142 
                 Ex. 11   
                 Ex. 143 
                 Ex. 144 
                 Ex. 145 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
               
               
                 R32 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 20.0 
                 20.0 
                 20.0 
                 20.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 40.0 
                 50.0 
                 60.0 
                 70.0 
                 80.0 
                 30.0 
                 50.0 
                 50.0 
                 70.0 
               
               
                 R1234(yf + ze) (r = 0.5) 
                 mass % 
                 47.0 
                 37.0 
                 27.0 
                 17.0 
                 7.0 
                 47.0 
                 27.0 
                 17.0 
                 7.0 
               
               
                 GWP 
                 — 
                 70 
                 70 
                 69 
                 69 
                 69 
                 138 
                 137 
                 136 
                 136 
               
               
                 COP ratio 
                    relative 
                 100.0 
                 99.1 
                 98.4 
                 97.9 
                 97.6 
                 100.3 
                 98.4 
                 97.8 
                 97.4 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 81.5 
                 87.2 
                 92.6 
                 97.8 
                 102.8 
                 84.0 
                 95.4 
                 100.8 
                 105.9 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 8.4 
                 6.8 
                 5.3 
                 4.0 
                 2.8 
                 8.2 
                 5.1 
                 3.7 
                 2.5 
               
               
                 glide 
               
               
                   
               
               
                   
                   
                 Com 
                   
                   
                   
                   
                 Com 
                   
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 11   
                 Ex. 146 
                 Ex. 147 
                 Ex. 148 
                 Ex. 149 
                 Ex. 11   
                 Ex. 150 
                 Ex. 151 
                 Ex. 152 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
               
               
                 R32 
                 mass % 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 40.0 
                 40.0 
                 40.0 
                 40.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 15.0 
                 30.0 
                 40.0 
                 50.0 
                 60.0 
                 5.0 
                 20.0 
                 30.0 
                 40.0 
               
               
                 R1234(yf + ze) (r = 0.5) 
                 mass % 
                 52.0 
                 37.0 
                 27.0 
                 17.0 
                 7.0 
                 52.0 
                 37.0 
                 27.0 
                 17.0 
               
               
                 GWP 
                 — 
                 205 
                 205 
                 204 
                 204 
                 203 
                 273 
                 272 
                 272 
                 271 
               
               
                 COP ratio 
                    relative 
                 101.4 
                 99.7 
                 98.8 
                 98.1 
                 97.5 
                 102.0 
                 100.3 
                 99.3 
                 98.6 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 82.6 
                 91.8 
                 97.5 
                 103.0 
                 108.3 
                 83.3 
                 93.0 
                 99.0 
                 104.7 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 8.4 
                 6.2 
                 4.8 
                 3.4 
                 2.2 
                 7.6 
                 5.8 
                 4.5 
                 3.2 
               
               
                 glide 
               
               
                   
               
               
                 Item 
                 Unit 
                 Ex. 153 
                 Ex. 154 
                 Ex. 155 
                 Ex. 156 
                 Ex. 157 
                 Ex. 158 
                 Ex. 159 
                 Ex. 160 
                 Ex. 161 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
               
               
                 R32 
                 mass % 
                 40.0 
                 50.0 
                 50.0 
                 50.0 
                 50.0 
                 60.0 
                 60.0 
                 60.0 
                 70.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 50.0 
                 10.0 
                 20.0 
                 30.0 
                 40.0 
                 10.0 
                 20.0 
                 30.0 
                 10.0 
               
               
                 R1234(yf + ze) (r = 0.5) 
                 mass % 
                 7.0 
                 37.0 
                 27.0 
                 17.0 
                 7.0 
                 27.0 
                 17.0 
                 7.0 
                 17.0 
               
               
                 GWP 
                 — 
                 271 
                 339 
                 339 
                 339 
                 338 
                 406 
                 406 
                 406 
                 473 
               
               
                 COP ratio 
                    relative 
                 97.9 
                 101.1 
                 100.1 
                 99.2 
                 98.5 
                 101.0 
                 100.1 
                 99.2 
                 100.9 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 110.1 
                 93.5 
                 99.7 
                 105.6 
                 111.2 
                 99.8 
                 105.9 
                 111.7 
                 105.6 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 2.0 
                 5.3 
                 4.2 
                 3.0 
                 1.8 
                 3.9 
                 2.9 
                 1.8 
                 2.7 
               
               
                 glide 
               
               
                   
               
            
           
           
               
               
               
               
               
            
               
                   
                   
                   
                   
                 Com 
               
               
                   
                 Item 
                 Unit 
                 Ex. 162 
                 Ex. 117 
               
               
                   
                   
               
               
                   
                 HFO-1132a 
                 mass % 
                 3.0 
                 3.0 
               
               
                   
                 R32 
                 mass % 
                 70.0 
                 80.0 
               
               
                   
                 HFO-1132 (E) 
                 mass % 
                 20.0 
                 10.0 
               
               
                   
                 R1234(yf + ze) (r = 0.5) 
                 mass % 
                 7.0 
                 7.0 
               
               
                   
                 GWP 
                 — 
                 473 
                 540 
               
               
                   
                 COP ratio 
                    relative 
                 100.0 
                 100.8 
               
               
                   
                   
                 to R41   
               
               
                   
                 Refrigerating 
                    relative 
                 111.5 
                 110.8 
               
               
                   
                 capacity r   
                 to R41   
               
               
                   
                 Condensation 
                 ° C. 
                 1.8 
                 1.7 
               
               
                   
                 glide 
               
               
                   
                   
               
               
                   
                     indicates data missing or illegible when filed 
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 12 
               
               
                   
               
             
            
               
                   
                   
                 Com 
                   
                   
                   
                 Com 
                   
                   
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 11   
                 Ex. 163 
                 Ex. 164 
                 Ex. 165 
                 Ex. 11   
                 Ex. 166 
                 Ex. 167 
                 Ex. 168 
                 Ex. 169 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
               
               
                 R32 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 20.0 
                 20.0 
                 20.0 
                 20.0 
                 20.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 40.0 
                 60.0 
                 70.0 
                 80.0 
                 25.0 
                 40.0 
                 50.0 
                 60.0 
                 70.0 
               
               
                 R1234(yf + ze) (r = 0.75) 
                 mass % 
                 47.0 
                 27.0 
                 17.0 
                 7.0 
                 52.0 
                 37.0 
                 27.0 
                 17.0 
                 7.0 
               
               
                 GWP 
                 — 
                 70 
                 59 
                 59 
                 69 
                 138 
                 137 
                 137 
                 136 
                 136 
               
               
                 COP ratio 
                    relative 
                 99.5 
                 98.2 
                 97.8 
                 97.5 
                 100.2 
                 98.8 
                 98.2 
                 97.7 
                 97.3 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 83.0 
                 93.6 
                 98.5 
                 103.1 
                 82.7 
                 91.2 
                 96.5 
                 101.5 
                 106.2 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 7.2 
                 4.6 
                 3.6 
                 2.6 
                 7.5 
                 5.6 
                 4.4 
                 3.3 
                 2.3 
               
               
                 glide 
               
               
                   
               
               
                   
                   
                 Com 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 12   
                 Ex. 170 
                 Ex. 171 
                 Ex. 172 
                 Ex. 173 
                 Ex. 174 
                 Ex. 175 
                 Ex. 176 
                 Ex. 177 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
               
               
                 R32 
                 mass % 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 40.0 
                 40.0 
                 40.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 10.0 
                 20.0 
                 30.0 
                 40.0 
                 50.0 
                 60.0 
                 10.0 
                 20.0 
                 30.0 
               
               
                 R1234(yf + ze) (r = 0.75) 
                 mass % 
                 57.0 
                 47.0 
                 37.0 
                 27.0 
                 17.0 
                 7.0 
                 47.0 
                 37.0 
                 27.0 
               
               
                 GWP 
                 — 
                 205 
                 205 
                 204 
                 204 
                 204 
                 203 
                 272 
                 272 
                 272 
               
               
                 COP ratio 
                    relative 
                 101.3 
                 100.1 
                 99.2 
                 98.5 
                 97.9 
                 97.5 
                 100.9 
                 99.9 
                 99.1 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 81.2 
                 87.4 
                 93.2 
                 98.7 
                 103.8 
                 108.6 
                 88.4 
                 94.5 
                 100.1 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 7.5 
                 6.4 
                 5.2 
                 4.0 
                 3.0 
                 2.0 
                 5.8 
                 4.8 
                 3.7 
               
               
                 glide 
               
               
                   
               
               
                 Item 
                 Unit 
                 Ex. 178 
                 Ex. 179 
                 Ex. 180 
                 Ex. 181 
                 Ex. 182 
                 Ex. 183 
                 Ex. 184 
                 Ex. 185 
                 Ex. 186 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
                 3.0 
               
               
                 R32 
                 mass % 
                 40.0 
                 40.0 
                 50.0 
                 50.0 
                 50.0 
                 50.0 
                 60.0 
                 60.0 
                 60.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 40.0 
                 50.0 
                 10.0 
                 20.0 
                 30.0 
                 40.0 
                 10.0 
                 20.0 
                 30.0 
               
               
                 R1234(yf + ze) (r = 0.75) 
                 mass % 
                 17.0 
                 7.0 
                 37.0 
                 27.0 
                 17.0 
                 7.0 
                 27.0 
                 17.0 
                 7.0 
               
               
                 GWP 
                 — 
                 271 
                 271 
                 339 
                 339 
                 339 
                 338 
                 406 
                 406 
                 406 
               
               
                 COP ratio 
                    relative 
                 98.4 
                 97.8 
                 100.7 
                 99.8 
                 99.1 
                 98.4 
                 100.7 
                 99.9 
                 99.1 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 105.4 
                 110.4 
                 95.0 
                 100.9 
                 106.4 
                 111.5 
                 101.0 
                 106.7 
                 112.0 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 2.7 
                 1.8 
                 4.3 
                 3.5 
                 2.6 
                 1.7 
                 3.2 
                 2.4 
                 1.6 
               
               
                 glide 
               
               
                   
               
            
           
           
               
               
               
               
               
               
            
               
                   
                   
                   
                   
                   
                 Com 
               
               
                   
                 Item 
                 Unit 
                 Ex. 187 
                 Ex. 188 
                 Ex. 12   
               
               
                   
                   
               
               
                   
                 HFO-1132a 
                 mass % 
                 3.0 
                 3.0 
                 3.0 
               
               
                   
                 R32 
                 mass % 
                 70.0 
                 70.0 
                 80.0 
               
               
                   
                 HFO-1132 (E) 
                 mass % 
                 10.0 
                 20.0 
                 10.0 
               
               
                   
                 R1234(yf + ze) (r = 0.75) 
                 mass % 
                 17.0 
                 7.0 
                 7.0 
               
               
                   
                 GWP 
                 — 
                 473 
                 473 
                 540 
               
               
                   
                 COP ratio 
                    relative 
                 100.8 
                 99.9 
                 100.8 
               
               
                   
                   
                 to R41   
               
               
                   
                 Refrigerating 
                    relative 
                 106.3 
                 111.8 
                 111.0 
               
               
                   
                 capacity r   
                 to R41   
               
               
                   
                 Condensation 
                 ° C. 
                 2.3 
                 1.6 
                 1.6 
               
               
                   
                 glide 
               
               
                   
                   
               
               
                   
                     indicates data missing or illegible when filed 
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 13 
               
               
                   
               
             
            
               
                   
                   
                 Com 
                   
                   
                   
                   
                 Com 
                   
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 12   
                 Ex. 189 
                 Ex. 190 
                 Ex. 191 
                 Ex. 192 
                 Ex. 12   
                 Ex. 193 
                 Ex. 194 
                 Ex. 195 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
               
               
                 R32 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 20.0 
                 20.0 
                 20.0 
                 20.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 40.0 
                 50.0 
                 60.0 
                 70.0 
                 80.0 
                 25.0 
                 40.0 
                 50.0 
                 60.0 
               
               
                 R1234(yf + ze) (r = 0) 
                 mass % 
                 45.4 
                 35.4 
                 25.4 
                 15.4 
                 5.4 
                 50.4 
                 35.4 
                 25.4 
                 15.4 
               
               
                 GWP 
                 — 
                 71 
                 70 
                 70 
                 69 
                 69 
                 138 
                 138 
                 137 
                 137 
               
               
                 COP ratio 
                    relative 
                 100.2 
                 99.0 
                 98.0 
                 97.3 
                 96.8 
                 101.4 
                 99.3 
                 98.2 
                 97.3 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 81.3 
                 87.4 
                 93.5 
                 99.4 
                 105.1 
                 80.2 
                 89.8 
                 96.0 
                 102.1 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 12.1 
                 9.8 
                 7.6 
                 5.5 
                 3.7 
                 12.9 
                 9.5 
                 7.2 
                 5.1 
               
               
                 glide 
               
               
                   
               
               
                   
                   
                   
                 Com 
                   
                   
                   
                   
                 Com 
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 195 
                 Ex. 12   
                 Ex. 197 
                 Ex. 198 
                 Ex. 199 
                 Ex. 200 
                 Ex. 12   
                 Ex. 201 
                 Ex. 202 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
               
               
                 R32 
                 mass % 
                 20.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 40.0 
                 40.0 
                 40.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 70.0 
                 15.0 
                 30.0 
                 40.0 
                 50.0 
                 60.0 
                 5.0 
                 20.0 
                 30.0 
               
               
                 R1234(yf + ze) (r = 0) 
                 mass % 
                 5.4 
                 50.4 
                 35.4 
                 25.4 
                 15.4 
                 5.4 
                 50.4 
                 35.4 
                 25.4 
               
               
                 GWP 
                 — 
                 136 
                 206 
                 205 
                 204 
                 204 
                 203 
                 273 
                 272 
                 272 
               
               
                 COP ratio 
                    relative 
                 96.7 
                 102.0 
                 99.8 
                 98.6 
                 97.6 
                 96.9 
                 102.7 
                 100.5 
                 99.2 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 108.0 
                 81.5 
                 91.5 
                 98.0 
                 104.2 
                 110.3 
                 81.9 
                 92.5 
                 99.2 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 3.3 
                 12.3 
                 9.0 
                 6.8 
                 4.7 
                 2.9 
                 11.3 
                 8.5 
                 6.5 
               
               
                 glide 
               
               
                   
               
               
                 Item 
                 Unit 
                 Ex. 203 
                 Ex. 204 
                 Ex. 205 
                 Ex. 206 
                 Ex. 207 
                 Ex. 208 
                 Ex. 209 
                 Ex. 210 
                 Ex. 211 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
               
               
                 R32 
                 mass % 
                 40.0 
                 40.0 
                 50.0 
                 50.0 
                 50.0 
                 50.0 
                 60.0 
                 60.0 
                 60.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 40.0 
                 50.0 
                 10.0 
                 20.0 
                 30.0 
                 40.0 
                 10.0 
                 20.0 
                 30.0 
               
               
                 R1234(yf + ze) (r = 0) 
                 mass % 
                 15.4 
                 5.4 
                 35.4 
                 25.4 
                 15.4 
                 5.4 
                 25.4 
                 15.4 
                 5.4 
               
               
                 GWP 
                 — 
                 271 
                 271 
                 340 
                 339 
                 339 
                 338 
                 407 
                 406 
                 406 
               
               
                 COP ratio 
                    relative 
                 98.2 
                 97.3 
                 101.3 
                 100.0 
                 98.9 
                 97.9 
                 100.9 
                 99.8 
                 98.7 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 105.8 
                 112.0 
                 92.9 
                 99.9 
                 106.6 
                 113.1 
                 99.9 
                 106.9 
                 113.5 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 4.4 
                 2.6 
                 7.9 
                 6.1 
                 4.2 
                 2.4 
                 5.7 
                 4.0 
                 2.4 
               
               
                 glide 
               
               
                   
               
            
           
           
               
               
               
               
               
               
            
               
                   
                   
                   
                   
                   
                 Com 
               
               
                   
                 Item 
                 Unit 
                 Ex. 212 
                 Ex. 213 
                 Ex. 126 
               
               
                   
                   
               
               
                   
                 HFO-1132a 
                 mass % 
                 4.6 
                 4.6 
                 4.6 
               
               
                   
                 R32 
                 mass % 
                 70.0 
                 70.0 
                 80.0 
               
               
                   
                 HFO-1132 (E) 
                 mass % 
                 10.0 
                 20.0 
                 10.0 
               
               
                   
                 R1234(yf + ze) (r = 0) 
                 mass % 
                 15.4 
                 5.4 
                 5.4 
               
               
                   
                 GWP 
                 — 
                 474 
                 473 
                 540 
               
               
                   
                 COP ratio 
                    relative 
                 100.7 
                 99.5 
                 100.4 
               
               
                   
                   
                 to R41   
               
               
                   
                 Refrigerating 
                    relative 
                 106.5 
                 113.3 
                 112.6 
               
               
                   
                 capacity r   
                 to R41   
               
               
                   
                 Condensation 
                 ° C. 
                 3.8 
                 2.4 
                 2.3 
               
               
                   
                 glide 
               
               
                   
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                 Com 
                   
                   
                   
                   
                 Com 
                   
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 12   
                 Ex. 214 
                 Ex. 215 
                 Ex. 216 
                 Ex. 217 
                 Ex. 12   
                 Ex. 218 
                 Ex. 219 
                 Ex. 220 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
               
               
                 R32 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 20.0 
                 20.0 
                 20.0 
                 20.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 40.0 
                 50.0 
                 60.0 
                 70.0 
                 80.0 
                 25.0 
                 40.0 
                 50.0 
                 60.0 
               
               
                 R1234(yf + ze) (r = 0.25) 
                 mass % 
                 45.4 
                 35.4 
                 25.4 
                 15.4 
                 5.4 
                 50.4 
                 35.4 
                 25.4 
                 15.4 
               
               
                 GWP 
                 — 
                 70 
                 70 
                 70 
                 69 
                 69 
                 138 
                 137 
                 137 
                 136 
               
               
                 COP ratio 
                    relative 
                 99.7 
                 98.6 
                 97.8 
                 97.2 
                 96.7 
                 100.8 
                 98.9 
                 97.9 
                 97.2 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 82.7 
                 88.7 
                 94.4 
                 100.0 
                 105.3 
                 81.9 
                 91.1 
                 97.0 
                 102.7 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 10.6 
                 8.6 
                 6.8 
                 5.1 
                 3.6 
                 11.2 
                 8.3 
                 6.4 
                 4.7 
               
               
                 glide 
               
               
                   
               
               
                     indicates data missing or illegible when filed 
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 14 
               
               
                   
               
             
            
               
                   
                   
                   
                 Com 
                   
                   
                   
                   
                 Com 
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 
                 Ex. 12   
                 Ex. 222 
                 Ex. 223 
                 Ex. 224 
                 Ex. 225 
                 Ex. 13   
                 Ex. 226 
                 Ex. 227 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
               
               
                 R32 
                 mass % 
                 20.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 40.0 
                 40.0 
                 40.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 70.0 
                 15.0 
                 30.0 
                 40.0 
                 50.0 
                 60.0 
                 5.0 
                 20.0 
                 30.0 
               
               
                 R1234(yf + ze) (r = 0.25) 
                 mass % 
                 5.4 
                 50.4 
                 35.4 
                 25.4 
                 15.4 
                 5.4 
                 50.4 
                 35.4 
                 25.4 
               
               
                 GWP 
                 — 
                 136 
                 205 
                 205 
                 204 
                 204 
                 203 
                 273 
                 272 
                 272 
               
               
                 COP ratio 
                    relative 
                 96.6 
                 101.4 
                 99.4 
                 98.3 
                 97.5 
                 96.8 
                 102.0 
                 100.1 
                 98.9 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 108.2 
                 83.2 
                 92.9 
                 99.0 
                 104.9 
                 110.6 
                 83.8 
                 94.0 
                 100.3 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 3.1 
                 10.6 
                 7.9 
                 6.0 
                 4.3 
                 2.7 
                 9.7 
                 7.4 
                 5.7 
               
               
                 glide 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Item 
                 Unit 
                 Ex. 228 
                 Ex. 229 
                 Ex. 230 
                 Ex. 231 
                 Ex. 232 
                 Ex. 233 
                 Ex. 234 
                 Ex. 235 
                 Ex. 236 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
               
               
                 R32 
                 mass % 
                 40.0 
                 40.0 
                 50.0 
                 50.0 
                 50.0 
                 50.0 
                 60.0 
                 60.0 
                 60.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 40.0 
                 50.0 
                 10.0 
                 20.0 
                 30.0 
                 40.0 
                 10.0 
                 20.0 
                 30.0 
               
               
                 R1234(yf + ze) (r = 0.25) 
                 mass % 
                 15.4 
                 5.4 
                 35.4 
                 25.4 
                 15.4 
                 5.4 
                 25.4 
                 15.4 
                 5.4 
               
               
                 GWP 
                 — 
                 271 
                 271 
                 340 
                 339 
                 339 
                 338 
                 407 
                 406 
                 406 
               
               
                 COP ratio 
                    relative 
                 98.0 
                 97.3 
                 100.9 
                 99.8 
                 98.8 
                 97.9 
                 100.7 
                 99.6 
                 98.6 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 106.4 
                 112.3 
                 94.4 
                 101.0 
                 107.3 
                 113.3 
                 101.0 
                 107.6 
                 113.8 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 4.0 
                 2.4 
                 6.8 
                 5.3 
                 3.8 
                 2.3 
                 5.0 
                 3.6 
                 2.2 
               
               
                 glide 
               
               
                   
               
            
           
           
               
               
               
               
               
               
            
               
                   
                   
                   
                   
                   
                 Com 
               
               
                   
                 Item 
                 Unit 
                 Ex. 237 
                 Ex. 238 
                 Ex. 131 
               
               
                   
                   
               
               
                   
                 HFO-1132a 
                 mass % 
                 4.6 
                 4.6 
                 4.6 
               
               
                   
                 R32 
                 mass % 
                 70.0 
                 70.0 
                 80.0 
               
               
                   
                 HFO-1132 (E) 
                 mass % 
                 10.0 
                 20.0 
                 10.0 
               
               
                   
                 R1234(yf + ze) (r = 0.25) 
                 mass % 
                 15.4 
                 5.4 
                 5.4 
               
               
                   
                 GWP 
                 — 
                 473 
                 473 
                 540 
               
               
                   
                 COP ratio 
                    relative 
                 100.6 
                 99.5 
                 100.4 
               
               
                   
                   
                 to R41   
               
               
                   
                 Refrigerating 
                    relative 
                 107.2 
                 113.6 
                 112.8 
               
               
                   
                 capacity r   
                 to R41   
               
               
                   
                 Condensation 
                 ° C. 
                 3.4 
                 2.2 
                 2.2 
               
               
                   
                 glide 
               
               
                   
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                 Com 
                   
                   
                   
                   
                 Com 
                   
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 13   
                 Ex. 239 
                 Ex. 240 
                 Ex. 241 
                 Ex. 242 
                 Ex. 13   
                 Ex. 243 
                 Ex. 244 
                 Ex. 245 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
               
               
                 R32 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 20.0 
                 20.0 
                 20.0 
                 20.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 40.0 
                 50.0 
                 60.0 
                 70.0 
                 80.0 
                 25.0 
                 40.0 
                 50.0 
                 60.0 
               
               
                 R1234(yf + ze) (r = 0.5) 
                 mass % 
                 45.4 
                 35.4 
                 25.4 
                 15.4 
                 5.4 
                 50.4 
                 35.4 
                 25.4 
                 15.4 
               
               
                 GWP 
                 — 
                 70 
                 70 
                 69 
                 69 
                 69 
                 138 
                 137 
                 137 
                 136 
               
               
                 COP ratio 
                    relative 
                 99.2 
                 98.3 
                 97.6 
                 97.0 
                 96.7 
                 100.1 
                 98.5 
                 97.6 
                 97.0 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 84.2 
                 89.9 
                 95.3 
                 100.5 
                 105.5 
                 83.5 
                 92.4 
                 98.0 
                 103.4 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 9.2 
                 7.6 
                 6.0 
                 4.7 
                 3.4 
                 9.7 
                 7.2 
                 5.6 
                 4.2 
               
               
                 glide 
               
               
                   
               
               
                   
                   
                   
                 Com 
                   
                   
                   
                   
                   
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 246 
                 Ex. 13   
                 Ex. 247 
                 Ex. 248 
                 Ex. 249 
                 Ex. 250 
                 Ex. 251 
                 Ex. 252 
                 Ex. 253 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
               
               
                 R32 
                 mass % 
                 20.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 40.0 
                 40.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 70.0 
                 10.0 
                 20.0 
                 30.0 
                 40.0 
                 50.0 
                 60.0 
                 10.0 
                 20.0 
               
               
                 R1234(yf + ze) (r = 0.5) 
                 mass % 
                 5.4 
                 64.4 
                 45.4 
                 35.4 
                 25.4 
                 15.4 
                 5.4 
                 45.4 
                 35.4 
               
               
                 GWP 
                 — 
                 136 
                 206 
                 205 
                 205 
                 204 
                 204 
                 203 
                 272 
                 272 
               
               
                 COP ratio 
                    relative 
                 96.6 
                 101.8 
                 100.1 
                 98.9 
                 98.0 
                 97.3 
                 96.8 
                 100.8 
                 99.7 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 108.5 
                 78.7 
                 88.2 
                 94.3 
                 100.0 
                 105.5 
                 110.8 
                 89.0 
                 95.4 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 3.0 
                 10.1 
                 8.3 
                 6.7 
                 5.2 
                 3.8 
                 2.6 
                 7.6 
                 6.3 
               
               
                 glide 
               
               
                   
               
               
                     indicates data missing or illegible when filed 
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 15 
               
               
                   
               
             
            
               
                 Item 
                 Unit 
                 Ex. 254 
                 Ex. 255 
                 Ex. 256 
                 Ex. 257 
                 Ex. 258 
                 Ex. 259 
                 Ex. 260 
                 Ex. 261 
                 Ex. 262 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
               
               
                 R32 
                 mass % 
                 40.0 
                 40.0 
                 40.0 
                 50.0 
                 50.0 
                 50.0 
                 50.0 
                 60.0 
                 60.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 30.0 
                 40.0 
                 50.0 
                 10.0 
                 20.0 
                 30.0 
                 40.0 
                 10.0 
                 20.0 
               
               
                 R1234(yf + ze) (r = 0.5) 
                 mass % 
                 25.4 
                 15.4 
                 5.4 
                 35.4 
                 25.4 
                 15.4 
                 5.4 
                 25.4 
                 15.4 
               
               
                 GWP 
                 — 
                 272 
                 271 
                 271 
                 339 
                 339 
                 339 
                 338 
                 406 
                 406 
               
               
                 COP ratio 
                    relative 
                 98.7 
                 97.9 
                 97.2 
                 100.5 
                 99.5 
                 98.6 
                 97.8 
                 100.5 
                 99.5 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 101.4 
                 107.1 
                 112.5 
                 95.8 
                 102.1 
                 108.0 
                 113.6 
                 102.1 
                 108.3 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 4.9 
                 3.5 
                 2.3 
                 5.8 
                 4.6 
                 3.4 
                 2.2 
                 4.3 
                 3.2 
               
               
                 glide 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
            
               
                   
                   
                   
                   
                   
                   
                 Com 
               
               
                   
                 Item 
                 Unit 
                 Ex. 263 
                 Ex. 264 
                 Ex. 265 
                 Ex. 135 
               
               
                   
                   
               
               
                   
                 HFO-1132a 
                 mass % 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
               
               
                   
                 R32 
                 mass % 
                 60.0 
                 70.0 
                 70.0 
                 80.0 
               
               
                   
                 HFO-1132 (E) 
                 mass % 
                 30.0 
                 10.0 
                 20.0 
                 10.0 
               
               
                   
                 R1234(yf + ze) (r = 0.5) 
                 mass % 
                 5.4 
                 15.4 
                 5.4 
                 5.4 
               
               
                   
                 GWP 
                 — 
                 406 
                 473 
                 473 
                 540 
               
               
                   
                 COP ratio 
                    relative 
                 98.6 
                 100.4 
                 99.4 
                 100.3 
               
               
                   
                   
                 to R41   
               
               
                   
                 Refrigerating 
                    relative 
                 114.0 
                 107.9 
                 113.8 
                 113.0 
               
               
                   
                 capacity r   
                 to R41   
               
               
                   
                 Condensation 
                 ° C. 
                 2.1 
                 3.0 
                 2.1 
                 2.1 
               
               
                   
                 glide 
               
               
                   
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                 Com 
                   
                   
                   
                   
                 Com 
                   
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 13   
                 Ex. 266 
                 Ex. 267 
                 Ex. 268 
                 Ex. 269 
                 Ex. 13   
                 Ex. 270 
                 Ex. 271 
                 Ex. 272 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
               
               
                 R32 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 20.0 
                 20.0 
                 20.0 
                 20.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 35.0 
                 50.0 
                 60.0 
                 70.0 
                 80.0 
                 20.0 
                 30.0 
                 40.0 
                 50.0 
               
               
                 R1234(yf + ze) (r = 0.75) 
                 mass % 
                 50.4 
                 35.4 
                 25.4 
                 15.4 
                 5.4 
                 55.4 
                 45.4 
                 35.4 
                 25.4 
               
               
                 GWP 
                 — 
                 70 
                 70 
                 69 
                 69 
                 69 
                 138 
                 137 
                 137 
                 137 
               
               
                 COP ratio 
                    relative 
                 99.2 
                 97.9 
                 97.3 
                 96.9 
                 96.6 
                 100.1 
                 99.0 
                 98.1 
                 97.4 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 82.7 
                 91.0 
                 96.2 
                 101.1 
                 106.7 
                 82.1 
                 88.1 
                 93.7 
                 99.0 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 8.7 
                 6.6 
                 5.3 
                 4.2 
                 3.3 
                 8.9 
                 7.5 
                 6.1 
                 4.9 
               
               
                 glide 
               
               
                   
               
               
                   
                   
                   
                   
                 Com 
                   
                   
                   
                   
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 273 
                 Ex. 274 
                 Ex. 13   
                 Ex. 275 
                 Ex. 276 
                 Ex. 277 
                 Ex. 278 
                 Ex. 279 
                 Ex. 280 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
               
               
                 R32 
                 mass % 
                 20.0 
                 20.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 40.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 60.0 
                 70.0 
                 10.0 
                 20.0 
                 30.0 
                 40.0 
                 50.0 
                 60.0 
                 10.0 
               
               
                 R1234(yf + ze) (r = 0.75) 
                 mass % 
                 15.4 
                 5.4 
                 55.4 
                 45.4 
                 35.4 
                 25.4 
                 15.4 
                 5.4 
                 45.4 
               
               
                 GWP 
                 — 
                 136 
                 136 
                 205 
                 205 
                 204 
                 204 
                 204 
                 203 
                 272 
               
               
                 COP ratio 
                    relative 
                 96.9 
                 96.5 
                 100.7 
                 99.5 
                 98.5 
                 97.8 
                 97.2 
                 96.7 
                 100.3 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 104.0 
                 108.7 
                 83.5 
                 89.8 
                 95.6 
                 101.1 
                 106.2 
                 111.0 
                 90.7 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 3.8 
                 2.8 
                 8.1 
                 6.9 
                 5.7 
                 4.5 
                 3.4 
                 2.4 
                 6.3 
               
               
                 glide 
               
               
                   
               
               
                 Item 
                 Unit 
                 Ex. 281 
                 Ex. 282 
                 Ex. 283 
                 Ex. 284 
                 Ex. 285 
                 Ex. 286 
                 Ex. 287 
                 Ex. 288 
                 Ex. 289 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
               
               
                 R32 
                 mass % 
                 40.0 
                 40.0 
                 40.0 
                 40.0 
                 50.0 
                 50.0 
                 50.0 
                 50.0 
                 60.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 20.0 
                 30.0 
                 40.0 
                 50.0 
                 10.0 
                 20.0 
                 30.0 
                 40.0 
                 10.0 
               
               
                 R1234(yf + ze) (r = 0.75) 
                 mass % 
                 35.4 
                 25.4 
                 15.4 
                 5.4 
                 35.4 
                 25.4 
                 15.4 
                 5.4 
                 25.4 
               
               
                 GWP 
                 — 
                 272 
                 271 
                 271 
                 271 
                 339 
                 339 
                 339 
                 338 
                 406 
               
               
                 COP ratio 
                    relative 
                 99.3 
                 98.4 
                 97.7 
                 97.2 
                 100.2 
                 99.3 
                 98.5 
                 97.8 
                 100.2 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 96.8 
                 102.5 
                 107.8 
                 112.7 
                 97.3 
                 103.2 
                 108.7 
                 113.8 
                 103.2 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 5.2 
                 4.2 
                 3.1 
                 2.2 
                 4.8 
                 3.9 
                 2.9 
                 2.0 
                 3.6 
               
               
                 glide 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                   
                   
                   
                   
                   
                   
                   
                 Com 
               
               
                   
                 Item 
                 Unit 
                 Ex. 290 
                 Ex. 291 
                 Ex. 292 
                 Ex. 293 
                 Ex. 139 
               
               
                   
                   
               
               
                   
                 HFO-1132a 
                 mass % 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
                 4.6 
               
               
                   
                 R32 
                 mass % 
                 60.0 
                 50.0 
                 70.0 
                 70.0 
                 80.0 
               
               
                   
                 HFO-1132 (E) 
                 mass % 
                 20.0 
                 30.0 
                 10.0 
                 20.0 
                 10.0 
               
               
                   
                 R1234(yf + ze) (r = 0.75) 
                 mass % 
                 15.4 
                 5.4 
                 15.4 
                 5.4 
                 5.4 
               
               
                   
                 GWP 
                 — 
                 406 
                 406 
                 473 
                 473 
                 540 
               
               
                   
                 COP ratio 
                    relative 
                 99.3 
                 98.5 
                 100.3 
                 99.4 
                 100.3 
               
               
                   
                   
                 to R41   
               
               
                   
                 Refrigerating 
                    relative 
                 108.9 
                 114.2 
                 108.5 
                 114.0 
                 113.2 
               
               
                   
                 capacity r   
                 to R41   
               
               
                   
                 Condensation 
                 ° C. 
                 2.8 
                 2.0 
                 2.7 
                 2.0 
                 1.9 
               
               
                   
                 glide 
               
               
                   
                   
               
               
                   
                     indicates data missing or illegible when filed 
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 16 
               
               
                   
               
             
            
               
                   
                   
                 Com 
                   
                   
                   
                   
                 Com 
                   
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 14   
                 Ex. 294 
                 Ex. 295 
                 Ex. 296 
                 Ex. 297 
                 Ex. 14   
                 Ex. 298 
                 Ex. 299 
                 Ex. 300 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
               
               
                 R32 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 20.0 
                 20.0 
                 20.0 
                 20.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 30.0 
                 50.0 
                 60.0 
                 70.0 
                 80.0 
                 20.0 
                 30.0 
                 40.0 
                 50.0 
               
               
                 R1234(yf + ze) (r = 0) 
                 mass % 
                 53.0 
                 33.0 
                 23.0 
                 13.0 
                 3.0 
                 53.0 
                 43.0 
                 33.0 
                 23.0 
               
               
                 GWP 
                 — 
                 71 
                 70 
                 70 
                 69 
                 69 
                 138 
                 138 
                 137 
                 137 
               
               
                 COP ratio 
                    relative 
                 100.4 
                 97.6 
                 96.7 
                 96.0 
                 95.4 
                 101.1 
                 99.4 
                 98.0 
                 96.9 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 79.2 
                 91.6 
                 97.6 
                 103.5 
                 109.2 
                 80.9 
                 87.5 
                 93.8 
                 100.0 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 15.9 
                 10.7 
                 8.3 
                 6.2 
                 4.3 
                 15.2 
                 12.7 
                 10.1 
                 7.7 
               
               
                 glide 
               
               
                   
               
               
                   
                   
                   
                   
                 Com 
                   
                   
                   
                   
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 301 
                 Ex. 302 
                 Ex. 14   
                 Ex. 303 
                 Ex. 304 
                 Ex. 305 
                 Ex. 306 
                 Ex. 307 
                 Ex. 308 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
               
               
                 R32 
                 mass % 
                 20.0 
                 20.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 40.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 60.0 
                 70.0 
                 10.0 
                 20.0 
                 30.0 
                 40.0 
                 50.0 
                 60.0 
                 10.0 
               
               
                 R1234(yf + ze) (r = 0) 
                 mass % 
                 13.0 
                 3.0 
                 53.0 
                 43.0 
                 33.0 
                 23.0 
                 13.0 
                 3.0 
                 43.0 
               
               
                 GWP 
                 — 
                 136 
                 136 
                 206 
                 205 
                 205 
                 204 
                 204 
                 203 
                 273 
               
               
                 COP ratio 
                    relative 
                 96.1 
                 95.4 
                 101.7 
                 100.1 
                 98.6 
                 97.4 
                 96.4 
                 95.7 
                 100.9 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 106.1 
                 112.0 
                 81.9 
                 88.8 
                 95.4 
                 101.9 
                 108.1 
                 114.2 
                 89.3 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 5.6 
                 3.7 
                 14.2 
                 12.0 
                 9.6 
                 7.2 
                 5.1 
                 3.2 
                 11.2 
               
               
                 glide 
               
               
                   
               
               
                 Item 
                 Unit 
                 Ex. 309 
                 Ex. 310 
                 Ex. 311 
                 Ex. 312 
                 Ex. 313 
                 Ex. 314 
                 Ex. 315 
                 Ex. 316 
                 Ex. 317 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
               
               
                 R32 
                 mass % 
                 40.0 
                 40.0 
                 40.0 
                 40.0 
                 50.0 
                 50.0 
                 50.0 
                 50.0 
                 60.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 20.0 
                 30.0 
                 40.0 
                 50.0 
                 10.0 
                 20.0 
                 30.0 
                 40.0 
                 10.0 
               
               
                 R1234(yf + ze) (r = 0) 
                 mass % 
                 33.0 
                 23.0 
                 13.0 
                 3.0 
                 33.0 
                 23.0 
                 13.0 
                 3.0 
                 23.0 
               
               
                 GWP 
                 — 
                 272 
                 272 
                 271 
                 271 
                 340 
                 339 
                 339 
                 338 
                 407 
               
               
                 COP ratio 
                    relative 
                 99.4 
                 98.1 
                 97.1 
                 96.2 
                 100.3 
                 99.1 
                 97.9 
                 96.9 
                 100.1 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 96.3 
                 103.1 
                 109.6 
                 115.8 
                 96.6 
                 103.6 
                 110.4 
                 116.8 
                 103.6 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 9.0 
                 6.8 
                 4.7 
                 2.8 
                 8.5 
                 6.5 
                 4.5 
                 2.7 
                 6.1 
               
               
                 glide 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                   
                   
                   
                   
                   
                   
                   
                 Com 
               
               
                   
                 Item 
                 Unit 
                 Ex. 318 
                 Ex. 319 
                 Ex. 320 
                 Ex. 321 
                 Ex. 143 
               
               
                   
                   
               
               
                   
                 HFO-1132a 
                 mass % 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
               
               
                   
                 R32 
                 mass % 
                 60.0 
                 60.0 
                 70.0 
                 70.0 
                 80.0 
               
               
                   
                 HFO-1132 (E) 
                 mass % 
                 20.0 
                 30.0 
                 10.0 
                 20.0 
                 10.0 
               
               
                   
                 R1234(yf + ze) (r = 0) 
                 mass % 
                 13.0 
                 3.0 
                 13.0 
                 3.0 
                 3.0 
               
               
                   
                 GWP 
                 — 
                 406 
                 406 
                 473 
                 473 
                 540 
               
               
                   
                 COP ratio 
                    relative 
                 98.9 
                 97.8 
                 99.9 
                 98.7 
                 99.6 
               
               
                   
                   
                 to R41   
               
               
                   
                 Refrigerating 
                    relative 
                 110.6 
                 117.2 
                 110.1 
                 116.9 
                 116.0 
               
               
                   
                 capacity r   
                 to R41   
               
               
                   
                 Condensation 
                 ° C. 
                 4.3 
                 2.6 
                 4.2 
                 2.6 
                 2.6 
               
               
                   
                 glide 
               
               
                   
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                 Com 
                   
                   
                   
                   
                 Com 
                   
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 14   
                 Ex. 322 
                 Ex. 323 
                 Ex. 324 
                 Ex. 325 
                 Ex. 14   
                 Ex. 326 
                 Ex. 327 
                 Ex. 328 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
               
               
                 R32 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 20.0 
                 20.0 
                 20.0 
                 20.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 30.0 
                 50.0 
                 60.0 
                 70.0 
                 80.0 
                 20.0 
                 30.0 
                 40.0 
                 50.0 
               
               
                 R1234(yf + ze) (r = 0.25) 
                 mass % 
                 53.0 
                 33.0 
                 23.0 
                 13.0 
                 3.0 
                 53.0 
                 43.0 
                 33.0 
                 23.0 
               
               
                 GWP 
                 — 
                 71 
                 70 
                 69 
                 69 
                 69 
                 138 
                 138 
                 137 
                 137 
               
               
                 COP ratio 
                    relative 
                 99.8 
                 97.3 
                 96.5 
                 95.9 
                 95.4 
                 100.4 
                 98.9 
                 97.7 
                 96.7 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 80.6 
                 92.7 
                 98.4 
                 104.0 
                 109.3 
                 82.5 
                 88.9 
                 95.0 
                 100.9 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 13.8 
                 9.5 
                 7.5 
                 5.8 
                 4.2 
                 13.2 
                 11.1 
                 8.9 
                 7.0 
               
               
                 glide 
               
               
                   
               
               
                     indicates data missing or illegible when filed 
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 17 
               
               
                   
               
             
            
               
                   
                   
                   
                   
                 Com 
                   
                   
                   
                 Com 
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 329 
                 Ex. 330 
                 Ex. 14   
                 Ex. 331 
                 Ex. 332 
                 Ex. 333 
                 Ex. 13   
                 Ex. 334 
                 Ex. 335 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
               
               
                 R32 
                 mass % 
                 20.0 
                 20.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 40.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 60.0 
                 70.0 
                 10.0 
                 20.0 
                 30.0 
                 40.0 
                 50.0 
                 60.0 
                 10.0 
               
               
                 R1234(yf + ze) (r = 0.25) 
                 mass % 
                 13.0 
                 3.0 
                 53.0 
                 43.0 
                 33.0 
                 23.0 
                 13.0 
                 3.0 
                 43.0 
               
               
                 GWP 
                 — 
                 95.9 
                 99.4 
                 101.1 
                 99.6 
                 98.3 
                 97.2 
                 96.3 
                 95.7 
                 100.4 
               
               
                 COP ratio 
                    relative 
                 136 
                 136 
                 206 
                 205 
                 205 
                 204 
                 204 
                 203 
                 273 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 106.6 
                 112.1 
                 83.6 
                 90.3 
                 96.7 
                 102.8 
                 108.7 
                 114.3 
                 90.9 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 5.2 
                 3.6 
                 12.3 
                 10.4 
                 8.4 
                 6.5 
                 4.7 
                 3.1 
                 9.7 
               
               
                 glide 
               
               
                   
               
               
                 Item 
                 Unit 
                 Ex. 336 
                 Ex. 337 
                 Ex. 338 
                 Ex. 339 
                 Ex. 340 
                 Ex. 341 
                 Ex. 342 
                 Ex. 343 
                 Ex. 344 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
               
               
                 R32 
                 mass % 
                 40.0 
                 40.0 
                 40.0 
                 40.0 
                 50.0 
                 50.0 
                 50.0 
                 50.0 
                 50.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 20.0 
                 30.0 
                 40.0 
                 50.0 
                 10.0 
                 20.0 
                 30.0 
                 40.0 
                 10.0 
               
               
                 R1234(yf + ze) (r = 0.25) 
                 mass % 
                 33.0 
                 23.0 
                 13.0 
                 3.0 
                 33.0 
                 23.0 
                 13.0 
                 3.0 
                 23.0 
               
               
                 GWP 
                 — 
                 272 
                 272 
                 271 
                 271 
                 339 
                 339 
                 339 
                 338 
                 406 
               
               
                 COP ratio 
                    relative 
                 99.1 
                 97.9 
                 97.0 
                 96.2 
                 100.0 
                 98.8 
                 97.8 
                 96.9 
                 99.9 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 97.5 
                 104.0 
                 110.1 
                 115.9 
                 98.0 
                 104.6 
                 111.0 
                 116.9 
                 104.6 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 7.9 
                 6.1 
                 4.3 
                 2.7 
                 7.3 
                 5.7 
                 4.1 
                 2.6 
                 5.4 
               
               
                 glide 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                   
                   
                   
                   
                   
                   
                   
                 Com 
               
               
                   
                 Item 
                 Unit 
                 Ex. 345 
                 Ex. 346 
                 Ex. 347 
                 Ex. 348 
                 Ex. 147 
               
               
                   
                   
               
               
                   
                 HFO-1132a 
                 mass % 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
               
               
                   
                 R32 
                 mass % 
                 50.0 
                 50.0 
                 70.0 
                 70.0 
                 80.0 
               
               
                   
                 HFO-1132 (E) 
                 mass % 
                 20.0 
                 30.0 
                 10.0 
                 20.0 
                 10.0 
               
               
                   
                 R1234(yf + ze) (r = 0.25) 
                 mass % 
                 13.0 
                 3.0 
                 13.0 
                 3.0 
                 3.0 
               
               
                   
                 GWP 
                 — 
                 406 
                 406 
                 473 
                 473 
                 540 
               
               
                   
                 COP ratio 
                    relative 
                 98.7 
                 97.7 
                 99.7 
                 98.6 
                 99.6 
               
               
                   
                   
                 to R41   
               
               
                   
                 Refrigerating 
                    relative 
                 111.1 
                 117.3 
                 110.7 
                 117.0 
                 116.1 
               
               
                   
                 capacity r   
                 to R41   
               
               
                   
                 Condensation 
                 ° C. 
                 4.0 
                 2.5 
                 3.8 
                 2.6 
                 2.6 
               
               
                   
                 glide 
               
               
                   
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                 Com 
                   
                   
                   
                   
                   
                 Com 
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 14   
                 Ex. 349 
                 Ex. 350 
                 Ex. 351 
                 Ex. 352 
                 Ex. 353 
                 Ex. 14   
                 Ex. 354 
                 Ex. 355 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
               
               
                 R32 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 20.0 
                 20.0 
                 20.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 30.0 
                 40.0 
                 50.0 
                 60.0 
                 70.0 
                 80.0 
                 20.0 
                 30.0 
                 40.0 
               
               
                 R1234(yf + ze) (r = 0.5) 
                 mass % 
                 53.0 
                 43.0 
                 33.0 
                 23.0 
                 13.0 
                 3.0 
                 53.0 
                 43.0 
                 33.0 
               
               
                 GWP 
                 — 
                 71 
                 70 
                 70 
                 69 
                 69 
                 69 
                 138 
                 138 
                 137 
               
               
                 COP ratio 
                    relative 
                 99.3 
                 98.0 
                 97.0 
                 96.3 
                 96.8 
                 95.4 
                 99.8 
                 98.4 
                 97.3 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 82.1 
                 88.1 
                 93.8 
                 99.2 
                 104.4 
                 109.4 
                 84.1 
                 90.3 
                 96.2 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 12.0 
                 10.2 
                 8.4 
                 6.8 
                 5.4 
                 4.1 
                 11.3 
                 9.6 
                 7.8 
               
               
                 glide 
               
               
                   
               
               
                     indicates data missing or illegible when filed 
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 18 
               
               
                   
               
             
            
               
                   
                   
                   
                   
                   
                 Com 
                   
                   
                   
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 356 
                 Ex. 357 
                 Ex. 358 
                 Ex. 15   
                 Ex. 359 
                 Ex. 360 
                 Ex. 361 
                 Ex. 362 
                 Ex. 363 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
               
               
                 R32 
                 mass % 
                 20.0 
                 20.0 
                 20.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 50.0 
                 60.0 
                 70.0 
                 5.0 
                 20.0 
                 30.0 
                 40.0 
                 50.0 
                 60.0 
               
               
                 R1234(yf + ze) (r = 0.5) 
                 mass % 
                 23.0 
                 13.0 
                 3.0 
                 58.0 
                 43.0 
                 33.0 
                 23.0 
                 13.0 
                 3.0 
               
               
                 GWP 
                 — 
                 137 
                 136 
                 136 
                 206 
                 205 
                 205 
                 204 
                 204 
                 203 
               
               
                 COP ratio 
                    relative 
                 96.5 
                 95.8 
                 95.4 
                 101.2 
                 99.1 
                 97.9 
                 97.0 
                 96.2 
                 95.7 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 101.8 
                 107.1 
                 112.2 
                 82.8 
                 91.8 
                 97.9 
                 103.7 
                 109.2 
                 114.4 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 6.2 
                 4.8 
                 3.5 
                 11.1 
                 8.9 
                 7.3 
                 5.7 
                 4.3 
                 3.0 
               
               
                 glide 
               
               
                   
               
               
                 Item 
                 Unit 
                 Ex. 364 
                 Ex. 365 
                 Ex. 366 
                 Ex. 367 
                 Ex. 368 
                 Ex. 369 
                 Ex. 370 
                 Ex. 371 
                 Ex. 372 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
               
               
                 R32 
                 mass % 
                 40.0 
                 40.0 
                 40.0 
                 40.0 
                 40.0 
                 50.0 
                 50.0 
                 50.0 
                 50.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 10.0 
                 20.0 
                 30.0 
                 40.0 
                 50.0 
                 10.0 
                 20.0 
                 30.0 
                 40.0 
               
               
                 R1234(yf + ze) (r = 0.5) 
                 mass % 
                 43.0 
                 33.0 
                 23.0 
                 13.0 
                 3.0 
                 33.0 
                 23.0 
                 13.0 
                 3.0 
               
               
                 GWP 
                 — 
                 272 
                 272 
                 272 
                 271 
                 271 
                 339 
                 339 
                 339 
                 338 
               
               
                 COP ratio 
                    relative 
                 99.9 
                 98.7 
                 97.7 
                 96.9 
                 96.2 
                 99.7 
                 98.6 
                 97.7 
                 96.9 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 92.5 
                 98.9 
                 105.0 
                 110.7 
                 116.1 
                 99.3 
                 105.6 
                 111.5 
                 117.1 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 8.2 
                 6.8 
                 5.3 
                 3.9 
                 2.7 
                 6.3 
                 5.0 
                 3.7 
                 2.5 
               
               
                 glide 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                   
                   
                   
                   
                   
                   
                   
                 Com 
               
               
                 Item 
                 Unit 
                 Ex. 373 
                 Ex. 374 
                 Ex. 375 
                 Ex. 376 
                 Ex. 377 
                 Ex. 151 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
               
               
                 R32 
                 mass % 
                 60.0 
                 60.0 
                 60.0 
                 70.0 
                 70.0 
                 80.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 10.0 
                 20.0 
                 30.0 
                 10.0 
                 20.0 
                 10.0 
               
               
                 R1234(yf + ze) (r = 0.5) 
                 mass % 
                 23.0 
                 13.0 
                 3.0 
                 13.0 
                 3.0 
                 3.0 
               
               
                 GWP 
                 — 
                 406 
                 406 
                 406 
                 473 
                 473 
                 540 
               
               
                 COP ratio 
                    relative 
                 99.6 
                 98.6 
                 97.7 
                 99.6 
                 98.6 
                 99.6 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 105.6 
                 111.7 
                 117.4 
                 111.2 
                 117.1 
                 116.3 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 4.7 
                 3.6 
                 2.5 
                 3.5 
                 2.5 
                 2.5 
               
               
                 glide 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                 Com 
                   
                   
                   
                   
                   
                 Com 
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 15   
                 Ex. 378 
                 Ex. 379 
                 Ex. 380 
                 Ex. 381 
                 Ex. 382 
                 Ex. 15   
                 Ex. 383 
                 Ex. 384 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
               
               
                 R32 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 20.0 
                 20.0 
                 20.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 25.0 
                 40.0 
                 50.0 
                 60.0 
                 70.0 
                 80.0 
                 10.0 
                 20.0 
                 30.0 
               
               
                 R1234(yf + ze) (r = 0.75) 
                 mass % 
                 58.0 
                 43.0 
                 33.0 
                 23.0 
                 13.0 
                 3.0 
                 63.0 
                 53.0 
                 43.0 
               
               
                 GWP 
                 — 
                 70 
                 70 
                 70 
                 69 
                 69 
                 69 
                 138 
                 138 
                 137 
               
               
                 COP ratio 
                    relative 
                 99.4 
                 97.6 
                 96.7 
                 96.1 
                 95.7 
                 95.4 
                 100.6 
                 99.2 
                 97.9 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 80.4 
                 89.3 
                 94.8 
                 100.0 
                 104.9 
                 109.5 
                 79.2 
                 85.7 
                 91.7 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 11.2 
                 8.8 
                 7.4 
                 6.1 
                 5.0 
                 4.1 
                 11.0 
                 9.7 
                 8.2 
               
               
                 glide 
               
               
                   
               
               
                 Item 
                 Unit 
                 Ex. 385 
                 Ex. 386 
                 Ex. 387 
                 Ex. 388 
                 Ex. 389 
                 Ex. 390 
                 Ex. 391 
                 Ex. 392 
                 Ex. 393 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
               
               
                 R32 
                 mass % 
                 20.0 
                 20.0 
                 20.0 
                 20.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 40.0 
                 50.0 
                 60.0 
                 70.0 
                 10.0 
                 20.0 
                 30.0 
                 40.0 
                 50.0 
               
               
                 R1234(yf + ze) (r = 0.75) 
                 mass % 
                 33.0 
                 23.0 
                 13.0 
                 3.0 
                 53.0 
                 43.0 
                 33.0 
                 23.0 
                 13.0 
               
               
                 GWP 
                 — 
                 137 
                 137 
                 136 
                 136 
                 205 
                 205 
                 204 
                 204 
                 204 
               
               
                 COP ratio 
                    relative 
                 97.0 
                 96.3 
                 95.7 
                 95.4 
                 99.8 
                 98.6 
                 97.5 
                 96.7 
                 96.1 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 97.3 
                 102.6 
                 107.6 
                 112.3 
                 87.0 
                 93.3 
                 99.1 
                 104.6 
                 109.7 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 6.8 
                 5.5 
                 4.4 
                 3.4 
                 8.8 
                 7.5 
                 6.2 
                 5.0 
                 3.9 
               
               
                 glide 
               
               
                   
               
               
                     indicates data missing or illegible when filed 
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 19 
               
               
                   
               
             
            
               
                 Item 
                 Unit 
                 Ex. 394 
                 Ex. 395 
                 Ex. 396 
                 Ex. 397 
                 Ex. 398 
                 Ex. 399 
                 Ex. 400 
                 Ex. 401 
                 Ex. 402 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
               
               
                 R32 
                 mass % 
                 30.0 
                 40.0 
                 40.0 
                 40.0 
                 40.0 
                 40.0 
                 50.0 
                 50.0 
                 50.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 60.0 
                 10.0 
                 20.0 
                 30.0 
                 40.0 
                 50.0 
                 10.0 
                 20.0 
                 30.0 
               
               
                 R1234(yf + ze) (r = 0.75) 
                 mass % 
                 3.0 
                 43.0 
                 33.0 
                 23.0 
                 13.0 
                 3.0 
                 33.0 
                 23.0 
                 13.0 
               
               
                 GWP 
                 — 
                 203 
                 272 
                 272 
                 271 
                 271 
                 271 
                 339 
                 339 
                 338 
               
               
                 COP ratio 
                    relative 
                 95.6 
                 99.4 
                 98.4 
                 97.5 
                 96.7 
                 96.2 
                 99.4 
                 98.4 
                 97.6 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 114.5 
                 94.1 
                 100.2 
                 105.9 
                 111.2 
                 116.2 
                 100.6 
                 106.6 
                 112.1 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 2.9 
                 6.9 
                 5.8 
                 4.6 
                 3.6 
                 2.6 
                 5.3 
                 4.4 
                 3.4 
               
               
                 glide 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                   
                   
                   
                   
                   
                   
                 Com 
               
               
                 Item 
                 Unit 
                 Ex. 403 
                 Ex. 404 
                 Ex. 405 
                 Ex. 406 
                 Ex. 407 
                 Ex. 408 
                 Ex. 154 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
                 7.0 
               
               
                 R32 
                 mass % 
                 50.0 
                 50.0 
                 60.0 
                 60.0 
                 70.0 
                 70.0 
                 80.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 40.0 
                 10.0 
                 20.0 
                 30.0 
                 10.0 
                 20.0 
                 10.0 
               
               
                 R1234(yf + ze) (r = 0.75) 
                 mass % 
                 3.0 
                 23.0 
                 13.0 
                 3.0 
                 13.0 
                 3.0 
                 3.0 
               
               
                 GWP 
                 — 
                 338 
                 406 
                 406 
                 406 
                 473 
                 473 
                 540 
               
               
                 COP ratio 
                    relative 
                 96.9 
                 99.4 
                 98.5 
                 97.7 
                 99.5 
                 98.6 
                 99.5 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 117.2 
                 106.5 
                 112.2 
                 117.5 
                 111.7 
                 117.3 
                 116.4 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 2.4 
                 4.1 
                 3.3 
                 2.4 
                 3.2 
                 2.4 
                 2.4 
               
               
                 glide 
               
               
                   
               
               
                     indicates data missing or illegible when filed 
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 20 
               
               
                   
               
             
            
               
                   
                   
                 Com 
                   
                   
                   
                   
                 Com 
                   
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 15   
                 Ex. 409 
                 Ex. 410 
                 Ex. 411 
                 Ex. 412 
                 Ex. 15   
                 Ex. 413 
                 Ex. 414 
                 Ex. 415 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
               
               
                 R32 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 20.0 
                 20.0 
                 20.0 
                 20.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 25.0 
                 40.0 
                 50.0 
                 60.0 
                 70.0 
                 15.0 
                 30.0 
                 40.0 
                 50.0 
               
               
                 R1234(yf + ze) (r = 0) 
                 mass % 
                 55.0 
                 40.0 
                 30.0 
                 20.0 
                 10.0 
                 55.0 
                 40.0 
                 30.0 
                 20.0 
               
               
                 GWP 
                 — 
                 71 
                 70 
                 70 
                 69 
                 69 
                 139 
                 138 
                 137 
                 137 
               
               
                 COP ratio 
                    relative 
                 99.8 
                 97.3 
                 96.0 
                 95.0 
                 94.3 
                 100.6 
                 98.0 
                 96.5 
                 95.4 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 81.1 
                 90.5 
                 96.6 
                 102.6 
                 108.4 
                 82.5 
                 92.3 
                 98.7 
                 104.9 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 18.3 
                 14.0 
                 11.2 
                 8.8 
                 6.6 
                 17.3 
                 13.2 
                 10.5 
                 8.0 
               
               
                 glide 
               
               
                   
               
               
                   
                   
                   
                 Com 
               
               
                 Item 
                 Unit 
                 Ex. 416 
                 Ex. 15   
                 Ex. 417 
                 Ex. 418 
                 Ex. 419 
                 Ex. 420 
                 Ex. 421 
                 Ex. 422 
                 Ex. 423 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
               
               
                 R32 
                 mass % 
                 20.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 40.0 
                 40.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 60.0 
                 5.0 
                 10.0 
                 20.0 
                 30.0 
                 40.0 
                 50.0 
                 10.0 
                 20.0 
               
               
                 R1234(yf + ze) (r = 0) 
                 mass % 
                 10.0 
                 55.0 
                 50.0 
                 40.0 
                 30.0 
                 20.0 
                 10.0 
                 40.0 
                 30.0 
               
               
                 GWP 
                 — 
                 136 
                 206 
                 206 
                 205 
                 205 
                 204 
                 204 
                 273 
                 273 
               
               
                 272 
                    relative 
                 94.5 
                 101.4 
                 100.5 
                 98.8 
                 97.2 
                 96.0 
                 95.0 
                 99.7 
                 98.2 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 110.9 
                 83.0 
                 86.6 
                 93.5 
                 100.1 
                 106.6 
                 112.8 
                 94.0 
                 101.0 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 5.8 
                 16.1 
                 15.0 
                 12.5 
                 9.9 
                 7.4 
                 5.2 
                 11.7 
                 9.3 
               
               
                 glide 
               
               
                   
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 Com 
               
               
                 Item 
                 Unit 
                 Ex. 424 
                 Ex. 425 
                 Ex. 426 
                 Ex. 427 
                 Ex. 428 
                 Ex. 429 
                 Ex. 430 
                 Ex. 431 
                 Ex. 15   
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
               
               
                 R32 
                 mass % 
                 40.0 
                 40.0 
                 50.0 
                 50.0 
                 50.0 
                 60.0 
                 60.0 
                 70.0 
                 80.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 30.0 
                 40.0 
                 10.0 
                 20.0 
                 30.0 
                 10.0 
                 20.0 
                 10.0 
                 5.0 
               
               
                 R1234(yf + ze) (r = 0) 
                 mass % 
                 20.0 
                 40.0 
                 30.0 
                 20.0 
                 10.0 
                 20.0 
                 10.0 
                 10.0 
                 5.0 
               
               
                 GWP 
                 — 
                 272 
                 271 
                 340 
                 339 
                 339 
                 406 
                 406 
                 473 
                 540 
               
               
                 COP ratio 
                    relative 
                 96.8 
                 95.8 
                 99.2 
                 97.9 
                 96.7 
                 99.0 
                 97.7 
                 98.8 
                 99.3 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 107.2 
                 114.2 
                 101.2 
                 108.2 
                 114.9 
                 108.1 
                 115.0 
                 114.5 
                 116.9 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 7.0 
                 4.8 
                 8.8 
                 6.7 
                 4.6 
                 6.4 
                 4.5 
                 4.4 
                 3.6 
               
               
                 glide 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                 Com 
                   
                   
                   
                   
                 Com 
                   
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 15   
                 Ex. 432 
                 Ex. 433 
                 Ex. 434 
                 Ex. 435 
                 Ex. 16   
                 Ex. 436 
                 Ex. 437 
                 Ex. 438 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
               
               
                 R32 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 20.0 
                 20.0 
                 20.0 
                 20.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 20.0 
                 40.0 
                 50.0 
                 60.0 
                 70.0 
                 10.0 
                 20.0 
                 30.0 
                 40.0 
               
               
                 R1234(yf + ze) (r = 0.25) 
                 mass % 
                 60.0 
                 40.0 
                 30.0 
                 20.0 
                 10.0 
                 60.0 
                 50.0 
                 40.0 
                 30.0 
               
               
                 GWP 
                 — 
                 71 
                 70 
                 70 
                 69 
                 69 
                 139 
                 138 
                 138 
                 137 
               
               
                 COP ratio 
                    relative 
                 100.1 
                 96.9 
                 95.8 
                 94.9 
                 94.3 
                 100.8 
                 99.1 
                 97.5 
                 96.2 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 79.1 
                 91.6 
                 97.5 
                 103.3 
                 108.8 
                 80.4 
                 87.2 
                 93.6 
                 99.7 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 17.2 
                 12.4 
                 10.1 
                 8.1 
                 5.3 
                 15.1 
                 13.9 
                 11.5 
                 9.4 
               
               
                 glide 
               
               
                   
               
               
                   
                   
                   
                   
                 Com 
               
               
                 Item 
                 Unit 
                 Ex. 439 
                 Ex. 440 
                 Ex. 14   
                 Ex. 441 
                 Ex. 442 
                 Ex. 443 
                 Ex. 444 
                 Ex. 445 
                 Ex. 446 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
               
               
                 R32 
                 mass % 
                 20.0 
                 20.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 40.0 
                 40.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 50.0 
                 50.0 
                 10.0 
                 20.0 
                 30.0 
                 40.0 
                 50.0 
                 10.0 
                 20.0 
               
               
                 R1234(yf + ze) (r = 0.25) 
                 mass % 
                 20.0 
                 10.0 
                 50.0 
                 40.0 
                 30.0 
                 20.0 
                 10.0 
                 40.0 
                 30.0 
               
               
                 GWP 
                 — 
                 137 
                 136 
                 205 
                 205 
                 205 
                 204 
                 204 
                 272 
                 272 
               
               
                 COP ratio 
                    relative 
                 95.2 
                 94.4 
                 99.9 
                 98.3 
                 96.9 
                 95.8 
                 94.9 
                 99.2 
                 97.8 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 105.6 
                 111.3 
                 88.1 
                 94.8 
                 101.2 
                 107.4 
                 113.2 
                 95.4 
                 102.1 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 7.3 
                 5.5 
                 13.0 
                 10.9 
                 8.8 
                 6.7 
                 4.9 
                 10.1 
                 8.2 
               
               
                 glide 
               
               
                   
               
               
                     indicates data missing or illegible when filed 
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 21 
               
               
                   
               
             
            
               
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 Com 
               
               
                 Item 
                 Unit 
                 Ex. 447 
                 Ex. 448 
                 Ex. 449 
                 Ex. 450 
                 Ex. 451 
                 Ex. 452 
                 Ex. 453 
                 Ex. 454 
                 Ex. 161 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
               
               
                 R32 
                 mass % 
                 40.0 
                 40.0 
                 50.0 
                 50.0 
                 50.0 
                 50.0 
                 60.0 
                 70.0 
                 80.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 30.0 
                 40.0 
                 10.0 
                 20.0 
                 30.0 
                 10.0 
                 20.0 
                 10.0 
                 5.0 
               
               
                 R1234(yf + ze) (r = 0.25) 
                 mass % 
                 20.0 
                 10.0 
                 30.0 
                 20.0 
                 10.0 
                 20.0 
                 10.0 
                 10.0 
                 5.0 
               
               
                 GWP 
                 — 
                 272 
                 271 
                 339 
                 339 
                 338 
                 406 
                 405 
                 473 
                 540 
               
               
                 COP ratio 
                    relative 
                 96.7 
                 96.7 
                 98.9 
                 97.7 
                 96.6 
                 98.8 
                 97.7 
                 98.8 
                 99.2 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 108.5 
                 114.6 
                 102.4 
                 109.1 
                 115.3 
                 108.9 
                 115.5 
                 114.9 
                 117.1 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 6.3 
                 4.5 
                 7.7 
                 6.0 
                 4.3 
                 5.7 
                 4.2 
                 4.1 
                 3.4 
               
               
                 glide 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                 Com 
                   
                   
                   
                   
                   
                 Com 
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 16   
                 Ex. 455 
                 Ex. 456 
                 Ex. 457 
                 Ex. 458 
                 Ex. 459 
                 Ex. 16   
                 Ex. 460 
                 Ex. 461 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
               
               
                 R32 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 20.0 
                 20.0 
                 20.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 20.0 
                 30.0 
                 10.0 
                 50.0 
                 60.0 
                 40.0 
                 10.0 
                 30.0 
                 40.0 
               
               
                 R1234(yf + ze) (r = 0.5) 
                 mass % 
                 60.0 
                 50.0 
                 40.0 
                 30.0 
                 20.0 
                 10.0 
                 60.0 
                 40.0 
                 30.0 
               
               
                 GWP 
                 — 
                 71 
                 70 
                 70 
                 70 
                 69 
                 69 
                 138 
                 137 
                 137 
               
               
                 COP ratio 
                    relative 
                 99.5 
                 97.9 
                 96.6 
                 95.5 
                 94.8 
                 94.2 
                 100.1 
                 97.1 
                 95.9 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 80.4 
                 85.8 
                 92.8 
                 98.5 
                 103.9 
                 109.1 
                 82.0 
                 94.8 
                 100.7 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 14.9 
                 12.9 
                 10.9 
                 9.1 
                 7.4 
                 5.9 
                 13.8 
                 10.1 
                 8.3 
               
               
                 glide 
               
               
                   
               
               
                 Item 
                 Unit 
                 Ex. 462 
                 Ex. 463 
                 Ex. 464 
                 Ex. 465 
                 Ex. 466 
                 Ex. 467 
                 Ex. 468 
                 Ex. 469 
                 Ex. 470 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
               
               
                 R32 
                 mass % 
                 20.0 
                 20.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 40.0 
                 40.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 50.0 
                 60.0 
                 5.0 
                 20.0 
                 30.0 
                 40.0 
                 50.0 
                 10.0 
                 20.0 
               
               
                 R1234(yf + ze) (r = 0.5) 
                 mass % 
                 20.0 
                 10.0 
                 55.0 
                 40.0 
                 30.0 
                 20.0 
                 10.0 
                 40.0 
                 30.0 
               
               
                 GWP 
                 — 
                 137 
                 136 
                 205 
                 205 
                 204 
                 204 
                 204 
                 272 
                 272 
               
               
                 COP ratio 
                    relative 
                 95.0 
                 94.4 
                 100.1 
                 97.8 
                 96.6 
                 95.6 
                 94.9 
                 98.8 
                 97.6 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 106.3 
                 111.6 
                 86.2 
                 96.2 
                 102.3 
                 108.1 
                 113.6 
                 96.8 
                 103.3 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 6.6 
                 5.2 
                 11.9 
                 9.4 
                 7.7 
                 6.1 
                 4.6 
                 8.7 
                 7.2 
               
               
                 glide 
               
               
                   
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 Com 
               
               
                 Item 
                 Unit 
                 Ex. 471 
                 Ex. 472 
                 Ex. 473 
                 Ex. 474 
                 Ex. 475 
                 Ex. 476 
                 Ex. 477 
                 Ex. 478 
                 Ex. 16   
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
               
               
                 R32 
                 mass % 
                 40.0 
                 40.0 
                 50.0 
                 50.0 
                 50.0 
                 60.0 
                 60.0 
                 70.0 
                 80.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 30.0 
                 40.0 
                 10.0 
                 20.0 
                 30.0 
                 10.0 
                 20.0 
                 10.0 
                 5.0 
               
               
                 R1234(yf + ze) (r = 0.5) 
                 mass % 
                 20.0 
                 10.0 
                 30.0 
                 20.0 
                 10.0 
                 20.0 
                 10.0 
                 10.0 
                 5.0 
               
               
                 GWP 
                 — 
                 271 
                 271 
                 339 
                 339 
                 338 
                 406 
                 406 
                 473 
                 540 
               
               
                 COP ratio 
                    relative 
                 96.5 
                 95.6 
                 98.7 
                 97.5 
                 96.5 
                 98.7 
                 97.6 
                 98.7 
                 99.2 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 109.3 
                 115.0 
                 103.6 
                 109.9 
                 115.8 
                 109.7 
                 115.9 
                 115.3 
                 117.2 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 5.7 
                 4.2 
                 6.7 
                 5.4 
                 4.0 
                 5.1 
                 3.9 
                 3.9 
                 3.3 
               
               
                 glide 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                 Com 
                   
                   
                   
                   
                 Com 
                   
                   
                   
               
               
                 Item 
                 Unit 
                 Ex. 16   
                 Ex. 479 
                 Ex. 480 
                 Ex. 481 
                 Ex. 482 
                 Ex. 16   
                 Ex. 483 
                 Ex. 484 
                 Ex. 485 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
               
               
                 R32 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 20.0 
                 20.0 
                 20.0 
                 20.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 20.0 
                 40.0 
                 50.0 
                 60.0 
                 70.0 
                 5.0 
                 20.0 
                 30.0 
                 40.0 
               
               
                 R1234(yf + ze) (r = 0.75) 
                 mass % 
                 60.0 
                 40.0 
                 30.0 
                 20.0 
                 10.0 
                 65.0 
                 50.0 
                 40.0 
                 30.0 
               
               
                 GWP 
                 — 
                 71 
                 70 
                 69 
                 69 
                 69 
                 138 
                 138 
                 137 
                 137 
               
               
                 COP ratio 
                    relative 
                 99.0 
                 96.2 
                 95.3 
                 94.6 
                 94.1 
                 100.4 
                 98.0 
                 96.7 
                 95.6 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 81.7 
                 93.9 
                 99.4 
                 104.6 
                 109.4 
                 79.9 
                 90.0 
                 96.0 
                 101.7 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 12.9 
                 9.6 
                 8.1 
                 6.8 
                 5.6 
                 12.4 
                 10.4 
                 8.8 
                 7.3 
               
               
                 glide 
               
               
                   
               
               
                     indicates data missing or illegible when filed 
               
            
           
         
       
     
     
       
         
           
               
               
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 22 
               
               
                   
               
             
            
               
                 Item 
                 Unit 
                 Ex. 486 
                 Ex. 487 
                 Ex. 488 
                 Ex. 489 
                 Ex. 490 
                 Ex. 491 
                 Ex. 492 
                 Ex. 493 
                 Ex. 494 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
               
               
                 R32 
                 mass % 
                 20.0 
                 20.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 30.0 
                 40.0 
                 40.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 50.0 
                 60.0 
                 10.0 
                 20.0 
                 30.0 
                 40.0 
                 50.0 
                 10.0 
                 20.0 
               
               
                 R1234(yf + ze) (r = 0.75) 
                 mass % 
                 20.0 
                 10.0 
                 50.0 
                 40.0 
                 30.0 
                 20.0 
                 10.0 
                 40.0 
                 30.0 
               
               
                 GWP 
                 — 
                 137 
                 136 
                 205 
                 205 
                 204 
                 204 
                 204 
                 272 
                 272 
               
               
                 COP ratio 
                    relative 
                 94.9 
                 94.3 
                 98.7 
                 97.4 
                 96.3 
                 95.5 
                 94.8 
                 98.4 
                 97.3 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 107.0 
                 112.0 
                 91.1 
                 97.5 
                 103.4 
                 108.9 
                 114.0 
                 98.2 
                 104.4 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 6.0 
                 4.9 
                 9.4 
                 8.1 
                 6.7 
                 5.4 
                 4.3 
                 7.4 
                 6.2 
               
               
                 glide 
               
               
                   
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 Com 
               
               
                 Item 
                 Unit 
                 Ex. 495 
                 Ex. 496 
                 Ex. 497 
                 Ex. 498 
                 Ex. 499 
                 Ex. 500 
                 Ex. 501 
                 Ex. 502 
                 Ex. 167 
               
               
                   
               
               
                 HFO-1132a 
                 mass % 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
                 10.0 
               
               
                 R32 
                 mass % 
                 40.0 
                 40.0 
                 50.0 
                 50.0 
                 50.0 
                 60.0 
                 60.0 
                 70.0 
                 80.0 
               
               
                 HFO-1132 (E) 
                 mass % 
                 30.0 
                 40.0 
                 10.0 
                 20.0 
                 30.0 
                 10.0 
                 20.0 
                 10.0 
                 5.0 
               
               
                 R1234(yf + ze) (r = 0.75) 
                 mass % 
                 20.0 
                 10.0 
                 30.0 
                 20.0 
                 10.0 
                 20.0 
                 10.0 
                 10.0 
                 5.0 
               
               
                 GWP 
                 — 
                 271 
                 271 
                 339 
                 339 
                 338 
                 406 
                 406 
                 473 
                 540 
               
               
                 COP ratio 
                    relative 
                 96.3 
                 95.5 
                 98.4 
                 97.3 
                 96.4 
                 98.5 
                 97.5 
                 98.6 
                 99.1 
               
               
                   
                 to R41   
               
               
                 Refrigerating 
                    relative 
                 110.1 
                 115.4 
                 104.7 
                 110.7 
                 116.1 
                 110.5 
                 116.2 
                 115.7 
                 117.4 
               
               
                 capacity r   
                 to R41   
               
               
                 Condensation 
                 ° C. 
                 5.0 
                 3.9 
                 5.8 
                 4.8 
                 3.7 
                 4.6 
                 3.7 
                 3.6 
                 3.2 
               
               
                 glide 
               
               
                   
               
               
                     indicates data missing or illegible when filed