Patent Publication Number: US-2021167298-A1

Title: Organic electroluminescence device

Description:
CROSS-REFERENCE TO RELATED APPLICATION(S) 
     This application claims priority to and the benefit of Chinese Patent Application No. CN 201911209540.X, filed Dec. 3, 2019, the disclosure of which is incorporated herein by reference in its entirety. 
     TECHNICAL FIELD 
     The present disclosure relates to an organic electroluminescence device, more particularly, relates to an organic electroluminescence device having a hole injection layer doped with a p-type conductive material, and a display assembly. 
     BACKGROUND 
     Organic electroluminescence devices (OLED) convert electrical energy into light by applying voltages across the device. Generally, one organic electroluminescence device includes an anode, a cathode and an organic layer disposed between the anode and the cathode. The organic layer of the electroluminescent device includes a hole injection layer, a hole transporting layer, an electron blocking layer, a light-emitting layer (including a host material and a doped material), an electron buffer layer, a hole blocking layer, an electron transporting layer, and an electron injection layer. According to different material functions, materials that consist of the organic layer can be divided into hole injection materials, hole transporting materials, electron blocking materials, host materials, light-emitting materials, electron buffer materials, hole blocking materials, electron transporting materials, and hole blocking materials. When a bias voltage is applied to the device, holes are injected from the anode to the light-emitting layer, and electrons are injected from the cathode to the light-emitting layer. The holes and electrons meet each other to form excitons, and the excitons recombine and emit light. 
     The hole injection layer can be a single-material layer, or can be a multiple-material layer. The multiple-material layer generally utilizes a hole transporting layer material doped with a certain proportion of p-type conductive doped material. The doping proportion is usually lower than 5%, and the most commonly used doping proportion is between 1% and 3%. The p-type doping effect can be achieved through the strong electron-capturing ability of the p-type conductive doped material, which improves hole injection and conductivity. Such hole injection layer doped with the p-type conductive material has been widely used, because it usually has a lower voltage than a single layer material. The LUMO energy level of commonly used p-type conductive materials is about −5.1 eV, so such materials can be matched with hole transporting materials whose HOMO energy level is about −5.1 eV. However, there are a variety of hole transporting materials in the industry nowadays, including those whose HOMO energy level is −5.2 eV or deeper. However, p-type conductive materials whose LUMO energy level is −5.1 eV or more shallow may not be able to effectively match hole transporting materials whose HOMO energy level is −5.2 eV or deeper to achieve the p-type doping effect. Therefore, in order to promote the widespread application of p-type doping technology, it is necessary to develop and utilize p-type conductive doped materials whose LUMO energy level is deeper than −5.1 eV. On the other hand, in OLED devices, the HOMO energy level of the host material of most light-emitting layers is around −5.4 eV to −5.6 eV, much deeper than that of the hole transporting layer material, causing holes to encounter a high barrier when they enter the light-emitting layer from the transporting layer. In order to solve this problem, an electron blocking layer (or called a second hole transporting layer) whose HOMO energy level is between the HOMO energy level of the hole transporting layer and the HOMO energy level of the light-emitting layer is usually inserted between the hole transporting layer and the light-emitting layer, that is, a first hole transporting layer and a second hole transporting layer are established between the hole injection layer and the light-emitting layer to form a structure in which potential energy shows a progressive change. However, the hole injection in such structure still faces a large total barrier height from the HOMO energy level of the first hole transporting layer to the HOMO energy level of the host material of the light-emitting layer, and the addition of an extra material also brings more interface defects, thereby affecting the lifetime and increasing the complexity of the process. Therefore, if a hole transporting material whose HOMO energy level is deeper can be used as the only hole transporting material layer between the hole injection layer and the light-emitting layer, not only the potential barrier that holes are faced with from the hole injection layer to the light-emitting layer can be reduced, but also an extra material can be dispensed with. Furthermore, if the same hole transporting material with deep HOMO energy level is also used in the hole injection layer and is doped with a p-type conductive doped material whose LUMO energy level is matched with that of such hole transporting material, the combination of both materials can reduce the total potential barrier for hole injection and avoid of utilization of simple and effective devices which use multiple hole transporting materials. 
     It is relatively common to use organic materials with deep HOMO energy levels as transporting materials in OLED devices. For example, the compound, 
     
       
         
         
             
             
         
       
     
     whose HOMO energy level is −5.28 eV, was disclosed as a hole transporting layer material in JP2009076817A, as an electron blocking layer material in WO2013129835A1, and as a host material in US20150364696A1. The compound, 
     
       
         
         
             
             
         
       
     
     whose HOMO energy level is −5.29 eV, was also disclosed as an electron blocking layer material in WO2019088231A1 and as a hole transporting layer material in U.S. Ser. No. 10/103,338 and US20140319472A1. However, there is currently no public report that the above-mentioned deep-energy level transporting material is used as the hole injection layer material and is doped with the deep-energy level p-type conductive material. 
     SUMMARY 
     The present disclosure aims to provide an organic electroluminescence device including an organic layer having a specific combination in which a deep-HOMO energy level hole transporting material is doped with a deep-LUMO energy level p-type conductive doped material to solve at least part of the above-mentioned problems. 
     After in-depth research using the aforementioned ideas, the inventors have disclosed an organic electroluminescence device which includes an organic layer having a specific combination of a deep-LUMO energy level p-type conductive doped material and a deep-HOMO energy level hole transporting material. The organic electroluminescence device can provide better device performance, such as lifetime improvement and voltage reduction, and a more simplified manufacturing process. 
     According to an embodiment of the present disclosure, an organic electroluminescence device is disclosed. The organic electroluminescence device includes: 
     an anode, 
     a cathode, 
     a light-emitting layer disposed between the anode and the cathode, and 
     a first organic layer disposed between the anode and the light-emitting layer, 
     wherein the first organic layer includes a compound of Formula 1 and a compound of Formula 2; 
     
       
         
         
             
             
         
       
     
     wherein, in Formula 1, 
     X and Y are, at each occurrence identically or differently, selected from NR′, CR″R′″, O, S or Se; 
     Z 1  and Z 2  are, at each occurrence identically or differently, selected from O, S or Se; 
     R, R′, R″ and R′″ are, at each occurrence identically or differently, selected from a group consisting of: hydrogen, deuterium, halogen, a nitroso group, a nitro group, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, SCN, OCN, SF 5 , a boryl group, a sulfinyl group, a sulfonyl group, a phosphoroso group, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted heteroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted arylalkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 20 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 20 carbon atoms, and combinations thereof; 
     each R can be identical or different, and at least one of R, R′, R″ and R′″ is a group having at least one electron-withdrawing group; 
     in Formula 1, adjacent substituents are optionally joined to form a ring; 
     
       
         
         
             
             
         
       
     
     wherein, in Formula 2, 
     X 1  to X 8  are, at each occurrence identically or differently, selected from CR 1  or N; 
     L is, at each occurrence identically or differently, selected from a substituted or unsubstituted arylene group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroarylene group having 3 to 30 carbon atoms, or combinations thereof; 
     Ar 1  and Ar 2  are, at each occurrence identically or differently, selected from a substituted or unsubstituted aryl group having 6 to 30 carbon atoms or a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms; 
     R 1  is, at each occurrence identically or differently, selected from a group consisting of: hydrogen, deuterium, halogen, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted heteroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted arylalkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 20 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 20 carbon atoms, a substituted or unsubstituted amino group having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a nitrile group, an isonitrile group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group, and combinations thereof; and 
     in Formula 2, adjacent substituents are optionally joined to form a ring. 
     According to another embodiment of the present disclosure, a display assembly is further disclosed. The display assembly comprises the organic electroluminescence device described above. 
     The present disclosure discloses an OLED device with a simple structure. The OLED device comprises an organic layer having a deep-LUMO energy level p-type conductive doped material and a deep-HOMO energy level hole transporting material, and can facilitate the injection and transporting of holes due to the effective matching of the two specific materials. In addition, since the HOMO energy level of the specific hole transporting material is close to the HOMO energy level of the host material of the light-emitting layer, the electron blocking layer can be dispensed with, achieving the simplification of the device structure, that is, the process steps are simplified. Meanwhile, because the energy levels are more matched, the process of the injection of holes from the anode and the transporting of holes to the light-emitting layer are smoother, thereby reducing the voltage. Finally, interfaces and the generation of interface defects are reduced due to the reduction of one material, and the lifetime of the device is also improved. 
    
    
     
       BRIEF DESCRIPTION OF DRAWINGS 
         FIG. 1  is a schematic diagram of an organic electroluminescence device  100 . 
     
    
    
     DETAILED DESCRIPTION 
     The OLED can be fabricated on various types of substrates such as glass, plastic and metal.  FIG. 1  schematically shows an organic electroluminescence device  100  without limitation. The FIGURE is not necessarily drawn to scale, and some of layer structures in the FIGURE can be omitted as needed. The organic electroluminescence device  100  includes an anode layer  101 , a hole injection layer (HIL)  102 , a hole transporting layer (HTL)  103 , an electron blocking layer (also called a second hole transporting layer) (EBL)  104 , a light-emitting layer (EML)  105 , a hole blocking layer (HBL)  106 , an electron transporting layer (ETL)  107 , an electron injection layer (EIL)  108 , and a cathode layer  109 . The device  100  can be fabricated by sequentially depositing the layers described. The properties and functions of the layers as well as exemplary materials are described in detail in U.S. Pat. No. 7,279,704B2, Cols. 6 to 10, the entire contents of which are incorporated herein by reference. 
     There are more examples for each of these layers. For example, a flexible and transparent substrate-anode combination is disclosed in U.S. Pat. No. 5,844,363, which is incorporated by reference in its entirety. An example of p-doped hole transporting layers is m-MTDATA doped with F 4 -TCNQ at a molar ratio of 50:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980 which is incorporated by reference in its entirety. Examples of host materials are described in U.S. Pat. No. 6,360,562 issued to Thompson et al., which is incorporated by reference in its entirety. An example of n-doped electron transporting layers is BPhen doped with Li at a molar ratio of 1:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980 which is incorporated by reference in its entirety. U.S. Pat. Nos. 5,703,436 and 5,707,745, both which are incorporated by reference in their entireties, disclose examples of cathodes, including composite cathodes having a thin metal layer such as Mg:Ag and an overlying transparent, conductive, sputter-deposited ITO layer. The principle and use of blocking layers are described in detail in U.S. Pat. No. 6,097,147 and U.S. Patent Application Publication No. 2003/0230980, both which are incorporated by reference in their entireties. U.S. Patent Application Publication No. 2004/0174116 which is incorporated by reference in its entirety provides examples of injection layers. The description about protective layers can be found in U.S. Patent Application Publication No. 2004/0174116 which is incorporated by reference in its entirety. 
     The above-mentioned layered structure is provided via non-limiting embodiments. The function of the OLED can be implemented by combining the various layers described above, or some layers can be omitted. The OLED can also include other layers that are not explicitly described herein. In each layer, a single material or a mixture of multiple materials can be used to achieve the best performance. Any functional layer can include several sub-layers. For example, the light-emitting layer can have two different layers of light-emitting materials to achieve a desired light-emitting spectrum. 
     In an embodiment, the OLED can be described as an OLED having an “organic layer” disposed between the cathode and the anode. This organic layer can include one or more layers. 
     The device fabricated in accordance with embodiments of the present disclosure can be incorporated into a wide variety of consumer products that have one or more of the electronic component modules (or units) of this device. Some examples of such consumer products include flat panel displays, monitors, medical monitors, televisions, billboards, lights for indoor or outdoor lighting and/or signaling, head-up displays, fully or partially transparent displays, flexible displays, smart phones, tablets, phablets, wearable devices, smart watches, laptop computers, digital cameras, camcorders, viewfinders, micro-displays, 3-D displays, vehicles displays, and vehicle tail lights. 
     The materials and structures described herein can also be used in other organic electronic devices listed above. 
     As used herein, “top” means being located furthest away from the substrate while “bottom” means being located closest to the substrate. In a case where a first layer is described as “being disposed over” a second layer, the first layer is disposed further away from the substrate. There may be other layers between the first and second layers, unless it is specified that the first layer is “in contact with” the second layer. For example, a cathode can still be described as “being disposed over” an anode, even though there are various organic layers between the cathode and the anode. 
     “Solution processible”, as used herein, means that capable of being dissolved, dispersed or transported in a liquid medium in the form of a solution or suspension and/or deposited from a liquid medium. 
     The work function of the metal herein refers to the minimum amount of energy required to move an electron from the interior to the surface of an object. All “work functions of the metal” herein are expressed as negative values, that is, the smaller the numerical value (i.e., the larger the absolute value), the larger amount of energy required to pull the electron to the vacuum level. For example, “the work function of the metal is less than −5 eV” means that the amount of energy required to pull the electron to the vacuum level is greater than 5 eV. 
     The numerical values of highest occupied molecular orbital (HOMO) energy level and lowest occupied molecular orbital (LUMO) energy level herein are measured by electrochemical cyclic voltammetry. The electrochemical cyclic voltammetry is the most commonly used method of measuring organic material energy levels. The test method is as follows: the platinum disk electrode is used as the working electrode, the Ag/AgNO 3  electrode is used as the reference electrode, the platinum wire electrode is used as the auxiliary electrode, the scanning speed is 100 mV/s, the test temperature is 25° C., and the solvent is anhydrous DMF. For example, the LUMO level of HATCN measured by this method is −4.2 eV. All “HOMO energy levels” and “LUMO energy levels” herein are expressed as negative values, and the smaller the numerical value (i.e., the larger the absolute value), the deeper the energy level. 
     Definition of Terms of Substituents 
     Halogen or halide—as used herein includes fluorine, chlorine, bromine, and iodine. 
     Alkyl—contemplates both straight and branched chain alkyl groups. Examples of the alkyl group include methyl group, ethyl group, propyl group, isopropyl group, n-butyl group, s-butyl group, isobutyl group, t-butyl group, n-pentyl group, n-hexyl group, n-heptyl group, n-octyl group, n-nonyl group, n-decyl group, n-undecyl group, n-dodecyl group, n-tridecyl group, n-tetradecyl group, n-pentadecyl group, n-hexadecyl group, n-heptadecyl group, n-octadecyl group, neopentyl group, 1-methylpentyl group, 2-methylpentyl group, 1-pentylhexyl group, 1-butylpentyl group, 1-heptyloctyl group, 3-methylpentyl group. Additionally, the alkyl group may be optionally substituted. The carbons in the alkyl chain can be replaced by other hetero atoms. Of the above, preferred are methyl group, ethyl group, propyl group, isopropyl group, n-butyl group, s-butyl group, isobutyl group, t-butyl group, n-pentyl group, and neopentyl group. 
     Cycloalkyl—as used herein contemplates cyclic alkyl groups. Preferred cycloalkyl groups are those containing 4 to 10 ring carbon atoms and includes cyclobutyl, cyclopentyl, cyclohexyl, 4-methylcyclohexyl, 4,4-dimethylcyclohexyl, 1-adamantyl, 2-adamantyl, 1-norbornyl, 2-norbornyl and the like. Additionally, the cycloalkyl group may be optionally substituted. The carbons in the ring can be replaced by other hetero atoms. 
     Alkenyl—as used herein contemplates both straight and branched chain alkene groups. Preferred alkenyl groups are those containing two to fifteen carbon atoms. Examples of the alkenyl group include vinyl group, allyl group, 1-butenyl group, 2-butenyl group, 3-butenyl group, 1,3-butanedienyl group, 1-methylvinyl group, styryl group, 2,2-diphenylvinyl group, 1,2-diphenylvinyl group, 1-methylallyl group, 1,1-dimethylallyl group, 2-methylallyl group, 1-phenylallyl group, 2-phenylallyl group, 3-phenylallyl group, 3,3-diphenylallyl group, 1,2-dimethylallyl group, 1-phenyl 1-butenyl group, and 3-phenyl-1-butenyl group. Additionally, the alkenyl group may be optionally substituted. 
     Alkynyl—as used herein contemplates both straight and branched chain alkyne groups. Preferred alkynyl groups are those containing two to fifteen carbon atoms. Additionally, the alkynyl group may be optionally substituted. 
     Aryl or aromatic group—as used herein contemplates noncondensed and condensed systems. Preferred aryl groups are those containing six to sixty carbon atoms, preferably six to twenty carbon atoms, more preferably six to twelve carbon atoms. Examples of the aryl group include phenyl, biphenyl, terphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene, preferably phenyl, biphenyl, terphenyl, triphenylene, fluorene, and naphthalene. Additionally, the aryl group may be optionally substituted. Examples of the non-condensed aryl group include phenyl group, biphenyl-2-yl group, biphenyl-3-yl group, biphenyl-4-yl group, p-terphenyl-4-yl group, p-terphenyl-3-yl group, p-terphenyl-2-yl group, m-terphenyl-4-yl group, m-terphenyl-3-yl group, m-terphenyl-2-yl group, o-tolyl group, m-tolyl group, p-tolyl group, p-t-butylphenyl group, p-(2-phenylpropyl)phenyl group, 4′-methylbiphenyl group, 4″-t-butyl p-terphenyl-4-yl group, o-cumenyl group, m-cumenyl group, p-cumenyl group, 2,3-xylyl group, 3,4-xylyl group, 2,5-xylyl group, mesityl group, and m-quarterphenyl group. 
     Heterocyclic group or heterocycle—as used herein contemplates aromatic and non-aromatic cyclic groups. Hetero-aromatic also means heteroaryl. Preferred non-aromatic heterocyclic groups are those containing 3 to 7 ring atoms which includes at least one hetero atom such as nitrogen, oxygen, and sulfur. The heterocyclic group can also be an aromatic heterocyclic group having at least one heteroatom selected from nitrogen atom, oxygen atom, sulfur atom, and selenium atom. 
     Heteroaryl—as used herein contemplates noncondensed and condensed hetero-aromatic groups that may include from one to five heteroatoms. Preferred heteroaryl groups are those containing three to thirty carbon atoms, preferably three to twenty carbon atoms, more preferably three to twelve carbon atoms. Suitable heteroaryl groups include dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine, preferably dibenzothiophene, dibenzofuran, dibenzoselenophene, carbazole, indolocarbazole, imidazole, pyridine, triazine, benzimidazole, 1,2-azaborine, 1,3-azaborine, 1,4-azaborine, borazine, and aza-analogs thereof. Additionally, the heteroaryl group may be optionally substituted. 
     Alkoxy—it is represented by —O-Alkyl. Examples and preferred examples thereof are the same as those described above. Examples of the alkoxy group having 1 to 20 carbon atoms, preferably 1 to 6 carbon atoms include methoxy group, ethoxy group, propoxy group, butoxy group, pentyloxy group, and hexyloxy group. The alkoxy group having 3 or more carbon atoms may be linear, cyclic or branched. 
     Aryloxy—it is represented by —O-Aryl or —O-heteroaryl. Examples and preferred examples thereof are the same as those described above. Examples of the aryloxy group having 6 to 40 carbon atoms include phenoxy group and biphenyloxy group. 
     Arylalkyl—as used herein contemplates an alkyl group that has an aryl substituent. Additionally, the arylalkyl group may be optionally substituted. Examples of the arylalkyl group include benzyl group, 1-phenylethyl group, 2-phenylethyl group, 1-phenylisopropyl group, 2-phenylisopropyl group, phenyl-t-butyl group, alpha.-naphthylmethyl group, 1-alpha.-naphthylethyl group, 2-alpha-naphthylethyl group, 1-alpha-naphthylisopropyl group, 2-alpha-naphthylisopropyl group, beta-naphthylmethyl group, 1-beta-naphthylethyl group, 2-beta-naphthylethyl group, 1-beta-naphthylisopropyl group, 2-beta-naphthylisopropyl group, p-methylbenzyl group, m-methylbenzyl group, o-methylbenzyl group, p-chlorobenzyl group, m-chlorobenzyl group, o-chlorobenzyl group, p-bromobenzyl group, m-bromobenzyl group, o-bromobenzyl group, p-iodobenzyl group, m-iodobenzyl group, o-iodobenzyl group, p-hydroxybenzyl group, m-hydroxybenzyl group, o-hydroxybenzyl group, p-aminobenzyl group, m-aminobenzyl group, o-aminobenzyl group, p-nitrobenzyl group, m-nitrobenzyl group, o-nitrobenzyl group, p-cyanobenzyl group, m-cyanobenzyl group, o-cyanobenzyl group, 1-hydroxy-2-phenylisopropyl group, and 1-chloro2-phenylisopropyl group. Of the above, preferred are benzyl group, p-cyanobenzyl group, m-cyanobenzyl group, o-cyanobenzyl group, 1-phenylethyl group, 2-phenylethyl group, 1-phenylisopropyl group, and 2-phenylisopropyl group. 
     The term “aza” in azadibenzofuran, aza-dibenzothiophene, etc. means that one or more of the C—H groups in the respective aromatic fragment are replaced by a nitrogen atom. For example, azatriphenylene encompasses dibenzo[f,h]quinoxaline, dibenzo[f,h]quinoline and other analogues with two or more nitrogens in the ring system. One of ordinary skill in the art can readily envision other nitrogen analogs of the aza-derivatives described above, and all such analogs are intended to be encompassed by the terms as set forth herein. 
     In the present disclosure, unless otherwise defined, when any term of the group consisting of substituted alkyl, substituted cycloalkyl, substituted heteroalkyl, substituted aralkyl, substituted alkoxy, substituted aryloxy, substituted alkenyl, substituted alkynyl, substituted aryl, substituted heteroaryl, substituted alkylsilyl, substituted arylsilyl, substituted amine, substituted acyl, substituted carbonyl, substituted carboxylic acid group, substituted ester group, substituted sulfinyl, substituted sulfonyl and substituted phosphoroso is used, it means that any group of alkyl, cycloalkyl, heteroalkyl, aralkyl, alkoxy, aryloxy, alkenyl, alkynyl, aryl, heteroaryl, alkylsilyl, arylsilyl, amine, acyl, carbonyl, carboxylic acid group, ester group, sulfinyl, sulfonyl and phosphoroso may be substituted with one or more groups selected from the group consisting of deuterium, a halogen, an unsubstituted alkyl group having 1 to 20 carbon atoms, an unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, an unsubstituted heteroalkyl group having 1 to 20 carbon atoms, an unsubstituted aralkyl group having 7 to 30 carbon atoms, an unsubstituted alkoxy group having 1 to 20 carbon atoms, an unsubstituted aryloxy group having 6 to 30 carbon atoms, an unsubstituted alkenyl group having 2 to 20 carbon atoms, an unsubstituted aryl group having 6 to 30 carbon atoms, an unsubstituted heteroaryl group having 3 to 30 carbon atoms, an unsubstituted alkylsilyl group having 3 to 20 carbon atoms, an unsubstituted arylsilyl group having 6 to 20 carbon atoms, an unsubstituted amino group having 0 to 20 carbon atoms, an alkynyl group, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, an ether group, a cyano group, an isocyano group, a thiol group, a sulfonyl group, a sulfinyl group and a phosphoroso group, and combinations thereof. 
     It is to be understood that when a molecular fragment is described as being a substituent or otherwise attached to another moiety, its name may be written as if it were a fragment (e.g. phenyl, phenylene, naphthyl, dibenzofuryl) or as if it were the whole molecule (e.g. benzene, naphthalene, dibenzofuran). As used herein, these different ways of designating a substituent or attached fragment are considered to be equivalent. 
     In the compounds mentioned in this disclosure, the hydrogen atoms can be partially or fully replaced by deuterium. Other atoms such as carbon and nitrogen, can also be replaced by their other stable isotopes. The replacement by other stable isotopes in the compounds may be preferred due to its enhancements of device efficiency and stability. 
     In the compounds mentioned in this disclosure, multiple substitutions refer to a range that includes a double substitution, up to the maximum available substitutions. 
     In the compounds mentioned in the present disclosure, adjacent substituents in the compounds cannot connect to form a ring unless otherwise explicitly defined, for example, adjacent substituents can be optionally joined to form a ring. In the compounds mentioned in the present disclosure, adjacent substituents can be optionally joined to form a ring, including both the case where adjacent substituents can be joined to form a ring, and the case where adjacent substituents are not joined to form a ring. When adjacent substituents can be optionally joined to form a ring, the ring formed may be monocyclic or polycyclic, as well as alicyclic, heteroalicyclic, aromatic or heteroaromatic. In such expression, adjacent substituents may refer to substituents bonded to the same atom, substituents bonded to carbon atoms which are directly bonded to each other, or substituents bonded to carbon atoms which are more distant from each other. Preferably, adjacent substituents refer to substituents bonded to the same carbon atom and substituents bonded to carbon atoms which are directly bonded to each other. 
     The expression that adjacent substituents can be optionally joined to form a ring is also intended to mean that two substituents bonded to the same carbon atom are joined to each other via a chemical bond to form a ring, which can be exemplified by the following formula: 
     
       
         
         
             
             
         
       
     
     The expression that adjacent substituents can be optionally joined to form a ring is also intended to mean that two substituents bonded to carbon atoms which are directly bonded to each other are joined to each other via a chemical bond to form a ring, which can be exemplified by the following formula: 
     
       
         
         
             
             
         
       
     
     Furthermore, the expression that adjacent substituents can be optionally joined to form a ring is also intended to mean that, in the case where one of the two substituents bonded to carbon atoms which are directly bonded to each other represents hydrogen, the second substituent is bonded at a position at which the hydrogen atom is bonded, thereby forming a ring. This is exemplified by the following formula: 
     
       
         
         
             
             
         
       
     
     According to an embodiment of the present disclosure, an organic electroluminescence device is disclosed. The organic electroluminescence device includes: 
     an anode, 
     a cathode, 
     a light-emitting layer disposed between the anode and the cathode, and 
     a first organic layer disposed between the anode and the light-emitting layer, 
     wherein the first organic layer includes a compound of Formula 1 and a compound of Formula 2; 
     
       
         
         
             
             
         
       
     
     wherein, in Formula 1, 
     X and Y are, at each occurrence identically or differently, selected from NR′, CR″R′″, O, S or Se; 
     Z 1  and Z 2  are, at each occurrence identically or differently, selected from O, S or Se; 
     R, R′, R″ and R′″ are, at each occurrence identically or differently, selected from a group consisting of: hydrogen, deuterium, halogen, a nitroso group, a nitro group, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, SCN, OCN, SF 5 , a boryl group, a sulfinyl group, a sulfonyl group, a phosphoroso group, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted heteroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted arylalkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 20 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 20 carbon atoms, and combinations thereof; 
     each R can be identical or different, and at least one of R, R′, R″ and R′″ is a group having at least one electron-withdrawing group; 
     in Formula 1, adjacent substituents are optionally joined to form a ring; 
     
       
         
         
             
             
         
       
     
     wherein, in Formula 2, 
     X 1  to X 8  are, at each occurrence identically or differently, selected from CR 1  or N; 
     L is, at each occurrence identically or differently, selected from a substituted or unsubstituted arylene group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroarylene group having 3 to 30 carbon atoms, or combinations thereof; 
     Ar 1  and Ar 2  are, at each occurrence identically or differently, selected from a substituted or unsubstituted aryl group having 6 to 30 carbon atoms or a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms; 
     R 1  is, at each occurrence identically or differently, selected from a group consisting of: hydrogen, deuterium, halogen, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted heteroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted arylalkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 20 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 20 carbon atoms, a substituted or unsubstituted amino group having 0 to 20 carbon atoms, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a nitrile group, an isonitrile group, a sulfanyl group, a sulfinyl group, a sulfonyl group, a phosphino group, and combinations thereof; and 
     in Formula 2, adjacent substituents are optionally joined to form a ring. 
     In this embodiment, the expression that in Formula 1, adjacent substituents are optionally joined to form a ring refers to that adjacent substituents R″ and R′″ in Formula 1 may be joined to form a ring. It is apparent for those skilled in the art to determine that adjacent substituents R″ and R′″ in Formula 1 may not be joined to form a ring. 
     In this embodiment, the expression that in Formula 2, adjacent substituents are optionally joined to form a ring refers to that adjacent substituents R 1  in Formula 2 may be joined to form a ring. It is apparent for those skilled in the art to determine that adjacent substituents R 1  in Formula 2 may not be joined to form a ring. 
     According to an embodiment of the present disclosure, X and Y are, at each occurrence identically or differently, selected from NR′ or CR″R′″, and R′, R″ and R′″ are a group having at least one electron-withdrawing group; preferably, R, R′, R″ and R′″ are a group having at least one electron-withdrawing group. 
     According to an embodiment of the present disclosure, X and Y are, at each occurrence identically or differently, selected from O, S or Se, and at least one of R is a group having at least one electron-withdrawing group; preferably, all of R are groups having at least one electron-withdrawing group. 
     According to an embodiment of the present disclosure, the Hammett constant of the electron-withdrawing group is greater than or equal to 0.05, preferably greater than or equal to 0.3, more preferably greater than or equal to 0.5. In the present disclosure, the Hammett substituent constant value of the electron-withdrawing group is greater than or equal to 0.05, preferably greater than or equal to 0.3, more preferably greater than or equal to 0.5. The electron withdrawing ability is relatively strong, which can significantly reduce the LUMO energy level of the compound and achieve the improvement of the charge mobility effect. It should be noted that the Hammett substituent constant value includes a para constant and/or meta constant of the Hammett substituent. As long as one of the para constant and meta constant is greater than or equal to 0.05, the electron-withdrawing group can be used as the group selected in the present disclosure. 
     According to an embodiment of the present disclosure, the electron-withdrawing group is selected from a group consisting of: halogen, a nitroso group, a nitro group, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, SCN, OCN, SF 5 , a boryl group, a sulfinyl group, a sulfonyl group, a phosphoroso group, an aza-aromatic ring group, and any one of the following groups substituted by one or more of halogen, a nitroso group, a nitro group, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, SCN, OCN, SF 5 , a boryl group, a sulfinyl group, a sulfonyl group, a phosphoroso group, and an aza-aromatic ring group: an alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 ring carbon atoms, a heteroalkyl group having 1 to 20 carbon atoms, an arylalkyl group having 7 to 30 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an aryloxy group having 6 to 30 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an alkynyl group having 2 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms, a heteroaryl group having 3 to 30 carbon atoms, an alkylsilyl group having 3 to 20 carbon atoms, an arylsilyl group having 6 to 20 carbon atoms, and combinations thereof; 
     preferably, the electron-withdrawing group is selected from a group consisting of: F, CF 3 , OCF 3 , SF 5 , SO 2 CF 3 , a cyano group, an isocyano group, SCN, OCN, a pyrimidinyl group, a triazinyl group, and combinations thereof. 
     According to an embodiment of the present disclosure, X and Y are, at each occurrence identically or differently, selected from a group consisting of the following structures: 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     wherein R 2  is, at each occurrence identically or differently, selected from a group consisting of: hydrogen, deuterium, halogen, a nitroso group, a nitro group, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, SCN, OCN, SF 5 , a boryl group, a sulfinyl group, a sulfonyl group, a phosphoroso group, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted heteroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted arylalkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 20 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 20 carbon atoms, and combinations thereof; 
     preferably, R 2  is, at each occurrence identically or differently, selected from a group consisting of: F, CF 3 , OCF 3 , SF 5 , SO 2 CF 3 , a cyano group, an isocyano group, SCN, OCN, a pentafluorophenyl group, a 4-cyanotetrafluorophenyl group, a tetrafluoropyridyl group, a pyrimidyl group, a triazinyl group, and combinations thereof; 
     wherein V and W are, at each occurrence identically or differently, selected from CR v R w , NR v , O, S or Se; 
     wherein Ar is, at each occurrence identically or differently, selected from a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, or a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms; 
     wherein A, R a , R b , R e , R d , R e , R f , R g , R h , R v  and R w  are, at each occurrence identically or differently, selected from a group consisting of: hydrogen, deuterium, halogen, a nitroso group, a nitro group, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, SCN, OCN, SF 5 , a boryl group, a sulfinyl group, a sulfonyl group, a phosphoroso group, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted heteroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted arylalkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 20 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 20 carbon atoms, and combinations thereof; 
     wherein A is a group having at least one electron-withdrawing group, and for any of the structures, when one or more of R a , R b , R e , R d , R e , R f , R g , R h , R v  and R w  occur, at least one of R a , R b , R e , R d , R e , R f , R g , R h , R v  and R w  is a group having at least one electron-withdrawing group; preferably, the group having at least one electron-withdrawing group is selected from a group consisting of: F, CF 3 , OCF 3 , SF 5 , SO 2 CF 3 , a cyano group, an isocyano group, SCN, OCN, a pentafluorophenyl group, a 4-cyanotetrafluorophenyl group, a tetrafluoropyridyl group, a pyrimidyl group, a triazinyl group, and combinations thereof. 
     In this embodiment, “*” represents a position where the X and Y groups are joined to a dehydrobenzodioxazole ring, a dehydrobenzodithiazole ring, or a dehydrobenzodiselenazole in Formula 1. 
     According to an embodiment of the present disclosure, X and Y are, at each occurrence identically or differently, selected from a group consisting of the following structures: 
     
       
         
         
             
             
         
       
     
     In this embodiment, “*” represents a position where the X and Y groups are joined to a dehydrobenzodioxazole ring, a dehydrobenzodithiazole ring, or a dehydrobenzodiselenazole in Formula 1. 
     According to an embodiment of the present disclosure, R is, at each occurrence identically or differently, selected from a group consisting of: hydrogen, deuterium, halogen, a nitroso group, a nitro group, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, SCN, OCN, SF 5 , a boryl group, a sulfinyl group, a sulfonyl group, a phosphoroso group, an unsubstituted alkyl group having 1 to 20 carbon atoms, an unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, an unsubstituted alkoxy group having 1 to 20 carbon atoms, an unsubstituted alkenyl group having 2 to 20 carbon atoms, an unsubstituted aryl group having 6 to 30 carbon atoms, an unsubstituted heteroaryl group having 3 to 30 carbon atoms, and any one of following groups substituted by one or more of halogen, a nitroso group, a nitro group, an acyl group, a carbonyl group, a carboxylic acid group, an ester group, a cyano group, an isocyano group, SCN, OCN, SF 5 , a boryl group, a sulfinyl group, a sulfonyl group, and a phosphoroso group: an alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 ring carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms, a heteroaryl group having 3 to 30 carbon atoms, and combinations thereof; 
     preferably, R is, at each occurrence identically or differently, selected from a group consisting of: hydrogen, deuterium, a methyl group, an isopropyl group, NO 2 , SO 2 CH 3 , SCF 3 , C 2 F 5 , OC 2 F 5 , OCH 3 , a diphenylmethylsilyl group, a phenyl group, a methoxyphenyl group, a p-methylphenyl group, a 2,6-diisopropylphenyl group, a biphenylyl group, a polyfluorophenyl group, a difluopyridyl group, a nitrophenyl group, a dimethylthiazolyl group, a vinyl group substituted by one or more of CN or CF 3 , an acetenyl group substituted by one of CN or CF 3 , a dimethylphosphoroso group, a diphenylphosphoroso group, F, CF 3 , OCF 3 , SF 5 , SO 2 CF 3 , a cyano group, an isocyano group, SCN, OCN, a trifluoromethylphenyl group, a trifluoromethoxyphenyl group, a bis(trifluoromethyl)phenyl group, a bis(trifluoromethoxy)phenyl group, a 4-cyanotetrafluorophenyl group, a phenyl or biphenylyl group substituted by one or more of F, CN or CF 3 , a tetrafluoropyridyl group, a pyrimidinyl group, a triazinyl group, a diphenylboryl group, an oxaboraanthryl group, and combinations thereof. 
     According to an embodiment of the present disclosure, X and Y are 
     
       
         
         
             
             
         
       
     
     According to an embodiment of the present disclosure, R is, at each occurrence identically or differently, selected from a group consisting of the following structures: 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     In this embodiment, “ ” represents a position where the R group is joined to a dehydrobenzodioxazole ring, a dehydrobenzodithiazole ring, or a dehydrobenzodiselenazole in Formula 1. 
     According to an embodiment of the present disclosure, both of R in a compound represented by Formula 1 are identical. 
     According to an embodiment of the present disclosure, the compound of Formula 1 has a structure represented by Formula 3: 
     
       
         
         
             
             
         
       
     
     wherein, in Formula 3, structures of both Z are identical, structures of both R are identical or different, and the Z, X, Y and R are respectively and correspondingly selected from atoms or groups shown in the table in claim  11 ; 
     wherein, the compound having the structure of Formula 3 is selected from Compound 1 to Compound 1356, wherein specific structures of Compound 1 to Compound 1356 are shown in claim  11 . 
     According to an embodiment of the present disclosure, L is a substituted or unsubstituted phenylene group, a substituted or unsubstituted biphenylene group, a substituted or unsubstituted terphenylene group, a substituted or unsubstituted naphthylene group, a substituted or unsubstituted fluorenylidene group, a substituted or unsubstituted silafluorenylidene group, a substituted or unsubstituted carbazolylene group, a substituted or unsubstituted dibenzofurylidene group, a substituted or unsubstituted dibenzothienylene group, a substituted or unsubstituted dibenzoselenophenylene group, a substituted or unsubstituted phenanthrylene group, a substituted or unsubstituted triphenylenylene group, a substituted or unsubstituted pyridylene group, a substituted or unsubstituted spirobifluorenylidene group, a substituted or unsubstituted anthrylene group, a substituted or unsubstituted pyrenylene group, or combinations thereof; preferably, L is a substituted or unsubstituted phenylene group or a substituted or unsubstituted biphenylene group; more preferably, L is a phenylene group or a biphenylene group. 
     According to an embodiment of the present disclosure, R 1  is hydrogen, deuterium, halogen, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, or a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms; preferably, R 1  is hydrogen, deuterium, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, or a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms. 
     According to an embodiment of the present disclosure, Ar 1  and Ar 2  are a substituted or unsubstituted aryl group having 6 to 20 carbon atoms or a substituted or unsubstituted heteroaryl group having 3 to 20 carbon atoms; preferably, Ar 1  and Ar 2  are a phenyl group, a biphenylyl group, a terphenyl group, a naphthyl group, a fluorenyl group, a dibenzothienyl group, a spirobifluorenyl group, a pyridyl group, or a pyrimidinyl group. 
     According to an embodiment of the present disclosure, the compound having the structure of Formula 2 is selected from a group consisting of Compound H-1 to Compound H-176, wherein specific structures of Compound H-1 to Compound H-176 are shown in claim  15 . 
     According to an embodiment of the present disclosure, the organic electroluminescence device further comprises a second organic layer disposed between the anode and the light-emitting layer, and the second organic layer includes the compound of Formula 2. 
     According to an embodiment of the present disclosure, the first organic layer is in contact with the anode. 
     According to an embodiment of the present disclosure, the compound of Formula 1 included in the first organic layer accounts for not higher than 5% or not higher than 3%, preferably not higher than 2% or not higher than 1% by weight of the entire first organic layer. 
     According to an embodiment of the present disclosure, the second organic layer is in contact with the light-emitting layer. 
     According to an embodiment of the present disclosure, the organic electroluminescence device further comprises a third organic layer disposed between the anode and the light-emitting layer, and the third organic layer comprises a compound different from the compound included in the second organic layer. 
     According to another embodiment of the present disclosure, a display assembly is further disclosed. The display assembly comprises the organic electroluminescence device described in any one of the embodiments described above. 
     A typical OLED device structure diagram is shown in  FIG. 1 . The OLED device  100  includes an anode layer  101 , a hole injection layer (HIL)  102 , a hole transporting layer (HTL)  103 , an electron blocking layer (also called a second hole transporting layer) (EBL)  104 , a light-emitting layer (EML)  105 , a hole blocking layer (HBL)  106 , an electron transporting layer (ETL)  107 , an electron injection layer (EIL)  108 , and a cathode layer  109 . The light-emitting layer  105  generally further comprises at least one host material and at least one light-emitting material, and the electron blocking layer  104  and the hole blocking layer  106  are optional layers. The hole injection layer  102  can be a single-material layer such as the commonly used HATCN. The hole injection layer  102  can also be a hole transporting layer material doped with a certain proportion of p-type conductive doped material. The doping proportion is generally lower than 5%, and the most commonly used doping proportion is between 1% and 3%. Such a hole injection layer doped with the p-type conductive material generally has a lower voltage than the single layer material, and thus is widely applied. The HOMO energy level of commonly used hole transporting layer materials, such as compound HT materials, is generally around −5.1 eV, which is close to the work function of commonly used anode layer ITO, −4.8 eV, ensuring effective injection of holes from the anode layer. However, the HOMO energy level of most host materials of light-emitting layers is around −5.4 eV to −5.6 eV, much deeper than that of the hole transporting layer material, causing holes to encounter a high barrier when they enter the light-emitting layer from the transporting layer. In order to solve this problem, a second hole transporting layer whose HOMO energy level is between the HOMO energy level of the hole transporting layer and the HOMO energy level of the light-emitting layer is usually inserted between the hole transporting layer and the light-emitting layer, forming a structure in which potential energy shows a progressive change. However, the holes in such structure still face a large total barrier height, and the addition of an extra material also brings more interface defects, thereby affecting the lifetime and increasing the complexity of the process. If the HOMO energy level of the hole injection layer can also be close to a host energy level, the barrier before the holes are transported into the light-emitting layer will be reduced or even disappear. However, a too deep HOMO energy level will make it difficult to inject holes from the anode layer, and the ohmic contact will become poor, resulting in an increase in voltage. Injecting p-type conductive doped material into deep-energy level hole injection materials can alleviate this phenomenon [Lussem et al. PSS A 210, No. 1, 9-43 (2013)]. However, the LUMO energy level of commonly used p-type conductive doped materials such as Compound PD, is just −5.06 eV, and thus the combination of such doped materials and deep-energy level hole transporting materials cannot form a good doping effect. For better matching, the LUMO energy level of the p-type conductive doped materials also needs to be deeper. 
     In the present disclosure, a p-type conductive doped material having a deep LUMO energy level (such as the compound shown in Formula 1, whose LUMO energy level is around −5.2 eV) and a hole transporting material having a deep HOMO energy level (such as the compound shown in Formula 2, whose HOMO energy level is around −5.2 eV) are co-evaporated to form a hole injection layer, then this hole transporting material is used as a hole transporting layer, and a light emitting layer is directly evaporated on the hole transporting layer. Since the energy levels are more matched, film layers and materials are reduced, so that the voltage of the device is reduced, the lifetime is improved, and the process is simplified. 
     Examples 
     Hereinafter, the present disclosure will be described in more detail with reference to the following examples. The compounds used in the following examples can be easily obtained by those skilled in the art, so synthesis methods of these compounds will not be repeated herein. For example, these compounds can be found in the Chinese patent CN201911046002.3 which is incorporated by reference in its entirety. Apparently, the following examples are only for illustrative purposes and are not intended to limit the scope of the present disclosure. Based on the following examples, those skilled in the art can obtain other examples of the present disclosure by conducting improvements on these examples. 
     Example 1-1: First, a glass substrate having a thickness of 0.7 mm, on which an Indium Tin Oxide (ITO) anode with a thickness of 80 mm had been patterned, was washed with deionized water and detergent, and then the ITO surface was treated with oxygen plasma and UV ozone. Then, the substrate was dried in a glove box to remove moisture, and loaded on a support and transferred into a vacuum chamber. The organic layers specified below were sequentially deposited on the ITO anode layer by vacuum thermal evaporation at a rate of 0.1 to 5 angstroms/sec under the condition of a vacuum of about 10 −8  Torr: Compound H-26 and Compound 70 were deposited simultaneously to form the hole injection layer (HIL, 97:3, 100 Å), Compound H-26 was deposited to form the hole transporting layer (HTL, 1250 Å), Compound BH and Compound BD were deposited simultaneously to form the light-emitting layer (EML, 96:4, 250 Å), Compound HB was deposited to form the hole blocking layer (HBL, 50 Å), Compound ET and Liq were co-deposited to form the electron transporting layer (ETL, 40:60, 300 Å), and finally, Liq with a thickness of 10 Å was deposited to form the electron injection layer (EIL), and aluminum with a thickness of 120 nm was deposited to form the cathode. The device was transferred back to the glove box and encapsulated with a glass lid to complete the fabrication of the device. 
     Comparative Example 1-1: The preparation method was the same as that in Example 1-1, except that Compound PD and Compound H-26 were deposited simultaneously to form the hole injection layer (HIL, 3:97, 100 Å). 
     Comparative Example 1-2: The preparation method was the same as that in Example 1-1, except that Compound PD and Compound HT were deposited simultaneously to form the hole injection layer (HIL, 3:97, 100 Å), Compound HT was deposited to form the hole transporting layer (HTL, 1200 Å), and Compound H-26 was deposited on the HTL to form the second hole transporting layer (HTL2, 50 Å). 
     Structures and thicknesses of part of layers of the device are shown in the following table in detail. The layers using more than one material were obtained by doping different compounds at weight proportions as recorded. 
     
       
         
           
               
             
               
                 TABLE 1 
               
             
            
               
                   
               
               
                 Structures of devices in Example 1-1, Comparative Example 1-1 
               
               
                 and Comparative Example 1-2 
               
            
           
           
               
               
               
               
               
               
               
            
               
                 Device ID 
                 HIL 
                 HTL 
                 HTL2 
                 EML 
                 HBL 
                 ETL 
               
               
                   
               
            
           
           
               
               
               
               
               
               
            
               
                 Example 1-1 
                 H-26:70 (97:3) 
                 H-26 
                 BH:BD (96:4) 
                 HB (50 Å)  
                 ET:Liq 
               
               
                   
                 (100 Å) 
                 (1250Å) 
                 (250 Å) 
                   
                 (40:60) (300Å) 
               
               
                 Comparative 
                 H-26:PD (97:3) 
                 H-26 
                 BH:BD (96:4) 
                 HB (50 Å)  
                 ET:Liq 
               
               
                 Example 1-1 
                 (100 Å) 
                 (1250Å) 
                 (250 Å) 
                   
                 (40:60) (300 Å) 
               
            
           
           
               
               
               
               
               
               
               
            
               
                 Comparative 
                 HT:PD (97:3) 
                 HT 
                 H-26 
                 BH:BD (96:4) 
                 HB (50 Å) 
                 ET:Liq 
               
               
                 Example 1-2 
                 (100 Å) 
                 (1200 Å) 
                 (50 Å) 
                 (250 Å) 
                   
                 (40:60) (300 Å) 
               
               
                   
               
            
           
         
       
     
     The structure formulas of Compounds 70, H-26, HT, PD, BH, BD, HB, ET and Liq are as follows: 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     The performance of devices in Example 1-1, Comparative Example 1-1 and Comparative Example 1-2 is summarized in Table 2. The chromaticity coordinates and voltage were measured at the current density of 15 mA/cm 2 , and the lifetime of the device (LT95) was the measured time for the device to decay to 95% of initial brightness at 80 mA/cm 2 . 
     
       
         
           
               
             
               
                 TABLE 2 
               
             
            
               
                   
               
               
                 Performance data of devices in Example 1-1, 
               
               
                 Comparative Example 1-1 and Comparative Example 1-2 
               
            
           
           
               
               
               
            
               
                   
                 At 15 mA/cm 2   
                   
               
            
           
           
               
               
               
               
               
            
               
                   
                   
                   
                 Voltage 
                 At 80 mA/cm 2   
               
               
                   
                 CIEx 
                 CIEy 
                 [V] 
                 LT95 [h] 
               
               
                   
               
            
           
           
               
               
               
               
               
            
               
                 Example 1-1 
                 0.138 
                 0.094 
                 4.2 
                 14.7 
               
               
                 Comparative 
                 0.138 
                 0.093 
                 4.5 
                 6.8 
               
               
                 Example 1-1 
                   
                   
                   
                   
               
               
                 Comparative 
                 0.139 
                 0.094 
                 4.3 
                 7.2 
               
               
                 Example 1-2 
                   
                   
                   
                   
               
               
                   
               
            
           
         
       
     
     In Example 1-1, Compound 70 with a LUMO energy level of −5.20 eV was used as a p-type conductive doped material, and was doped in Compound H-26, a hole transporting material with a HOMO energy level of −5.28 eV. In Comparative Example 1-1, Compound PD with a LUMO energy level of −5.06 eV was used as a p-type conductive doped material, and was doped in Compound H-26, a hole transporting material with a HOMO energy level of −5.28 eV. Although the color of the two devices were similar, the voltage of the device in Example 1-1 was 0.3 V lower than that in Comparative Example 1-1, and the lifetime was more than doubled. It is indicated that by combining a hole transporting material having a deep HOMO energy level and a p-type conductive doped material having a deep LUMO energy level, the injection and transporting of holes are facilitated, and the device performance of such device is better than that of the device formed by the combination of a p-type conductive doped material having a shallow LUMO energy level and a hole transporting material having a deep HOMO energy level. 
     Since the p-type conductive doped material having a shallow LUMO energy level and the hole transporting material having a shallow HOMO energy level constitute a relatively better combination in the prior art, the example of the present disclosure is compared with such a combination. In Comparative Example 1-2, Compound PD with a LUMO energy level of −5.06 eV was used as a p-type conductive doped material and was doped to Compound HT, a hole transporting material with a HOMO energy level of −5.14 eV to form the hole injection layer, and Compound HT was used to form the hole transporting layer. However, a large barrier is presented between the HOMO energy level of Compound HT and the HOMO energy level of the light-emitting layer BH (−5.66 eV). Compound H-26 was thus added as the second hole transporting layer, thereby forming a potential energy progression to facilitate the injection of holes to the light-emitting layer. Such a device structure is also a method commonly used in the industry. Results showed that the voltage of the device in Example 1-1 was 0.1 V lower than that in Comparative Example 1-2, and the lifetime was more than doubled. It is indicated that although the method commonly used in industry uses the combination of a p-type conductive doped material having a shallow LUMO energy level and a hole transporting material having a shallow HOMO energy level and adds a second hole transporting layer to form potential energy progression, the method commonly used in the industry is still inferior to the method in the examples of the present disclosure, especially in terms of lifetime. The advantages of the present disclosure are obvious. 
     Example 2-1: The preparation method was the same as that in Example 1-1, except that all Compounds H-26 were replaced by Compound H-124. 
     Comparative Example 2-1: The preparation method was the same as that in Example 2-1, except that Compound PD and Compound H-124 were used to form the hole injection layer (HIL, 3:97, 100 Å). 
     Comparative Example 2-2: The preparation method was the same as that in Example 2-1, except that Compound PD and Compound HT were used to form the hole injection layer (HIL, 3:97, 100 Å), Compound HT was used to form the hole transporting layer (HTL, 1200 Å), and Compound H-124 was deposited on the HTL to form the second hole transporting layer (HTL2, 50 Å). 
     Structures and thicknesses of part of layers of the device are shown in the following table in detail. The layers using more than one material were obtained by doping different compounds at weight proportions as recorded. 
     
       
         
           
               
             
               
                 TABLE 3 
               
             
            
               
                   
               
               
                 Structures of devices in Example 2-1, Comparative Example 2-1 
               
               
                 and Comparative Example 2-2 
               
            
           
           
               
               
               
               
               
               
               
            
               
                 Device ID 
                 HIL 
                 HTL 
                 HTL2 
                 EML 
                 HBL 
                 ETL 
               
               
                   
               
            
           
           
               
               
               
               
               
               
            
               
                 Example 2-1 
                 H-124:70 (97:3) 
                 H-124 
                 BH:BD (96:4) 
                 HB (50 Å) 
                 ET:Liq (40:60) 
               
               
                   
                 (100 Å) 
                 (1250Å) 
                 (250 Å) 
                   
                 (300 Å) 
               
               
                 Comparative 
                 H-124:PD 
                 H-124 
                 BH:BD (96:4) 
                 HB (50 Å) 
                 ET:Liq (40:60) 
               
               
                 Example 2-1 
                 (97:3) (100 Å) 
                 (1250Å) 
                 (250 Å) 
                   
                 (300 Å) 
               
            
           
           
               
               
               
               
               
               
               
            
               
                 Comparative 
                 HT:PD (97:3) 
                 HT 
                 H-124 
                 BH:BD (96:4) 
                 HB (50 Å) 
                 ET:Liq (40:60) 
               
               
                 Example 2-2 
                 (100 Å) 
                 (1200 Å) 
                 (50 Å) 
                 (250 Å) 
                   
                 (300 Å) 
               
               
                   
               
            
           
         
       
     
     The example of Compound H-124 is as follows: 
     
       
         
         
             
             
         
       
     
     The performance of devices in Example 2-1, Comparative Example 2-1 and Comparative Example 2-2 is summarized in Table 4. The chromaticity coordinates and voltage were measured at the current density of 15 mA/cm 2 , and the lifetime of the device (LT95) was the measured time for the device to decay to 95% of initial brightness at 80 mA/cm 2 . 
     
       
         
           
               
             
               
                 TABLE 4 
               
             
            
               
                   
               
               
                 Performance data of devices in Example 2-1, Comparative 
               
               
                 Example 2-1 and Comparative Example 2-2 
               
            
           
           
               
               
               
            
               
                   
                 At 15 mA/cm 2   
                   
               
            
           
           
               
               
               
               
               
            
               
                   
                   
                   
                 Voltage 
                 At 80 mA/cm 2   
               
               
                   
                 CIEx 
                 CIEy 
                 [V] 
                 LT95 [h] 
               
               
                   
               
            
           
           
               
               
               
               
               
            
               
                 Example 2-1 
                 0.140 
                 0.098 
                 4.4 
                 128 
               
               
                 Comparative 
                 0.140 
                 0.100 
                 6.1 
                 107 
               
               
                 Example 2-1 
                   
                   
                   
                   
               
               
                 Comparative 
                 0.138 
                 0.094 
                 4.3 
                 18 
               
               
                 Example 2-2 
                   
                   
                   
                   
               
               
                   
               
            
           
         
       
     
     In Example 2-1, Compound 70 with a LUMO energy level of −5.20 eV was used as a p-type conductive doped material and was doped to Compound H-124, a hole transporting material with a HOMO energy level of −5.29 eV. In Comparative Example 2-1, Compound PD with a LUMO energy level of −5.06 eV was used as a p-type conductive doped material and was doped to Compound H-124, a hole transporting material with a HOMO energy level of −5.29 eV. The color of the two devices were similar, and results showed that the voltage of the device in Example 2-1 was 1.7 V lower than that in Comparative Example 2-1, and the lifetime was increased by 20%. It is indicated that by combining a hole transporting material having a deep HOMO energy level and a p-type conductive doped material having a deep LUMO energy level, the injection and transporting of holes are facilitated, and the device performance of such device is better than that of the device formed by the combination of a p-type conductive doped material having a shallow LUMO energy level and a hole transporting material having a deep HOMO energy level. 
     Since the p-type conductive doped material having a shallow LUMO energy level and the hole transporting material having a shallow HOMO energy level constitute a relatively better combination in the prior art, the example of the present disclosure is compared with such a combination. In Comparative Example 2-2, Compound PD with a LUMO energy level of −5.06 eV was used as a p-type conductive doped material and was doped to Compound HT, a hole transporting material with a HOMO energy level of −5.14 eV to form the hole injection layer, and Compound HT was used to form the hole transporting layer. However, a large barrier is presented between the HOMO energy level of Compound HT and the HOMO energy level of the light-emitting layer BH (−5.66 eV). Compound H-124 was thus added as the second hole transporting layer, thereby forming a potential energy progression to facilitate the injection of holes to the light-emitting layer. Such a device structure is also a method commonly used in the industry. Although the voltage of the device in Example 2-1 was 0.1 V higher than that in Comparative Example 2-2, the lifetime was increased more than 6 times. It is indicated that although the method commonly used in industry uses the combination of a p-type conductive doped material having a shallow LUMO energy level and a hole transporting material having a shallow HOMO energy level and adds a second hole transporting layer to form potential energy progression, the method commonly used in the industry is still inferior to the method in the examples of the present disclosure, especially in terms of lifetime. The advantages of the present disclosure are highlighted again. 
     Example 3-1: The preparation method was the same as that in Example 1-1, except that all Compounds H-26 were replaced by Compound H-176. 
     Comparative Example 3-1: The preparation method was the same as that in Example 3-1, except that Compound PD and Compound H-176 were used to form the hole injection layer (HIL, 3:97, 100 Å). 
     Comparative Example 3-2: The preparation method was the same as that in Example 3-1, except that Compound PD and Compound HT were used to form the hole injection layer (HIL, 3:97, 100 Å), Compound HT was used to form the hole transporting layer (HTL, 1200 Å), and Compound H-176 was deposited on the HTL to form the second hole transporting layer (HTL2, 50 Å). 
     Structures and thicknesses of part of layers of the device are shown in the following table in detail. The layers using more than one material were obtained by doping different compounds at weight proportions as recorded. 
     
       
         
           
               
             
               
                 TABLE 5 
               
             
            
               
                   
               
               
                 Structures of devices in Example 3-1, Comparative Example 3-1 
               
               
                 and Comparative Example 3-2 
               
            
           
           
               
               
               
               
               
               
               
            
               
                 Device ID 
                 HIL 
                 HTL 
                 HTL2 
                 EML 
                 HBL 
                 ETL 
               
               
                   
               
            
           
           
               
               
               
               
               
               
            
               
                 Example 3-1 
                 H-176:70 
                 H-176 
                 BH:BD (96:4) 
                 HB (50 Å) 
                 ET:Liq (40:60) 
               
               
                   
                 (97:3)(100 Å) 
                 (1250 Å) 
                 (250 Å) 
                   
                 (300 Å) 
               
               
                 Comparative 
                 H-176:PD 
                 H-176 
                 BH:BD (96:4) 
                 HB (50 Å) 
                 ET:Liq (40:60) 
               
               
                 Example 3-1 
                 (97:3) (100 Å) 
                 (1250 Å) 
                 (250 Å) 
                   
                 (300 Å) 
               
            
           
           
               
               
               
               
               
               
               
            
               
                 Comparative 
                 HT:PD (97:3) 
                 HT 
                 H-176 
                 BH:BD (96:4) 
                 HB (50 Å) 
                 ET:Liq (40:60) 
               
               
                 Example 3-2 
                 (100 Å) 
                 (1200 Å) 
                 (50 Å) 
                 (250 Å) 
                   
                 (300 Å) 
               
               
                   
               
            
           
         
       
     
     The example of Compound H-176 is as follows: 
     
       
         
         
             
             
         
       
     
     The performance of devices in Example 3-1, Comparative Example 3-1 and Comparative Example 3-2 is summarized in Table 6. The chromaticity coordinates, external quantum efficiency and voltage were measured at the current density of 15 mA/cm 2 , and the lifetime of the device (LT95) was the measured time for the device to decay to 95% of initial brightness at 80 mA/cm 2 . 
     
       
         
           
               
             
               
                 TABLE 6 
               
             
            
               
                   
               
               
                 Performance data of devices in Example 3-1, Comparative 
               
               
                 Example 3-1 and Comparative Example 3-2 
               
            
           
           
               
               
               
            
               
                   
                 At 15 mA/cm 2   
                   
               
            
           
           
               
               
               
               
               
               
            
               
                   
                   
                   
                 Voltage 
                   
                 At 80 mA/cm 2   
               
               
                   
                 CIEx 
                 CIEy 
                 [V] 
                 EQE [%] 
                 LT95 [h] 
               
               
                   
               
            
           
           
               
               
               
               
               
               
            
               
                 Example 3-1 
                 0.137 
                 0.093 
                 4.7 
                 9.4 
                 40 
               
               
                 Comparative 
                 0.140 
                 0.097 
                 6.1 
                 8.7 
                 1.3 
               
               
                 Example 3-1 
                   
                   
                   
                   
                   
               
               
                 Comparative 
                 0.139 
                 0.089 
                 4.3 
                 9.1 
                 20 
               
               
                 Example 3-2 
                   
                   
                   
                   
                   
               
               
                   
               
            
           
         
       
     
     In Example 3-1, Compound 70 with a LUMO energy level of −5.20 eV was used as a p-type conductive doped material and was doped to Compound H-176, a hole transporting material with a HOMO energy level of −5.29 eV. In Comparative Example 3-1, Compound PD with a LUMO energy level of −5.06 eV was used as a p-type conductive doped material and was doped to Compound H-176, a hole transporting material with a HOMO energy level of −5.29 eV. Although the color of the two devices were similar, the voltage of the device in Example 3-1 was 1.4 V lower than that in Comparative Example 3-1, and the lifetime was increased more than 30 times. It is indicated that by combining a hole transporting material having a deep HOMO energy level and a p-type conductive doped material having a deep LUMO energy level, the injection and transporting of holes are facilitated, and the device performance of such device is better than that of the device formed by the combination of a p-type conductive doped material having a shallow LUMO energy level and a hole transporting material having a deep HOMO energy level. 
     Since the p-type conductive doped material having a shallow LUMO energy level and the hole transporting material having a shallow HOMO energy level constitute a relatively better combination in the prior art, the example of the present disclosure is compared with such a combination. In Comparative Example 3-2, Compound PD with a LUMO energy level of −5.06 eV was used as a p-type conductive doped material and was doped to Compound HT hole transporting material with a HOMO energy level of −5.09 eV to form the hole injection layer, and Compound HT was used to form the hole transporting layer. However, a large barrier is presented between the HOMO energy level of Compound HT and the HOMO energy level of the light-emitting layer BH (−5.66 eV), Compound H-176 was added as the second hole transporting layer, thereby forming a potential energy progression to facilitate the injection of holes to the light-emitting layer. Such a device structure is also a method commonly used in the industry. Although the voltage of the device in Example 3-1 was 0.4 V higher than that in Comparative Example 3-2, the lifetime was doubled. It is indicated that although the method commonly used in industry uses the combination of a p-type conductive doped material having a shallow LUMO energy level and a hole transporting material having a shallow HOMO energy level and adds a second hole transporting layer to form potential energy progression, the method commonly used in the industry is still inferior to the method in the examples of the present disclosure, especially in terms of lifetime. The advantages of the present disclosure are highlighted again. 
     Example 4-1: First, a glass substrate having a thickness of 0.7 mm, on which an Indium Tin Oxide (ITO) anode with a thickness of 120 mm had been patterned, was washed with deionized water and detergent, and then the ITO surface was treated with oxygen plasma and UV ozone. Then, the substrate was dried in a glove box to remove moisture, and loaded on a support and transferred into a vacuum chamber. The organic layers specified below were sequentially deposited on the ITO anode layer by vacuum thermal evaporation at a rate of 0.1 to 5 angstroms/sec under the condition of a vacuum of about 10 −8  Torr: Compound H-124 and Compound 70 were deposited simultaneously to form the hole injection layer (HIL, 97:3, 100 Å), Compound H-124 was deposited to form the hole transporting layer (HTL, 450 Å), Compound RH and Compound RD were deposited simultaneously to form the light-emitting layer (EML, 98:2, 400 Å), Compound GH2 was deposited to form the hole blocking layer (HBL, 50 Å), Compound ET2 and Liq were co-deposited to form the electron transporting layer (ETL, 40:60, 350 Å), and finally, Liq with a thickness of 10 Å was deposited to form the electron injection layer (EIL), and aluminum with a thickness of 120 nm was deposited to form the cathode. The device was transferred back to the glove box and encapsulated with a glass lid to complete the fabrication of the device. 
     Comparative Example 4-1: The preparation method was the same as that in Example 4-1, except that Compound HATCN was used to form the hole injection layer (HIL, 100 Å), Compound HT was used to form the hole transporting layer (HTL, 400 Å), and Compound H-124 was used to form the second hole transporting layer (HTL2, 50 Å). 
     
       
         
           
               
             
               
                 TABLE 7 
               
             
            
               
                   
               
               
                 Structures of devices in Example 4-1 and Comparative Example 4-1 
               
            
           
           
               
               
               
               
               
               
               
            
               
                 Device ID 
                 HIL 
                 HTL 
                 HTL2 
                 EML 
                 HBL 
                 ETL 
               
               
                   
               
            
           
           
               
               
               
               
               
               
            
               
                 Example 4-1 
                 H-124:70 
                 H-124 (450 Å) 
                 RH:RD 
                 GH2 (50 Å) 
                 ET2:Liq 
               
               
                   
                 (97:3)(100 Å) 
                   
                 (98:2)(400 Å) 
                   
                 (40:60) (350 Å) 
               
            
           
           
               
               
               
               
               
               
               
            
               
                 Comparative 
                 HATCN 
                 HT 
                 H-124 
                 RH:RD 
                 GH2 (50 Å) 
                 ET2:Liq 
               
               
                 Example 4-1 
                 (100 Å) 
                 (400 Å) 
                 (50 Å) 
                 (98:2)(400 Å) 
                   
                 (40:60) (350 Å) 
               
               
                   
               
            
           
         
       
     
     Examples of Compounds HATCN, RH, RD, GH2 and ET2 are as follows: 
     
       
         
         
             
             
         
       
       
         
         
             
             
         
       
     
     The performance of devices in Example 4-1 and Comparative Example 4-1 is summarized in Table 8. The chromaticity coordinates, external quantum efficiency and voltage were measured at the current density of 15 mA/cm 2 , and the lifetime of the device (LT95) was the measured time for the device to decay to 95% of initial brightness at 80 mA/cm 2 . 
     
       
         
           
               
             
               
                 TABLE 8 
               
             
            
               
                   
               
               
                 Performance data of devices in Example 4-1  
               
               
                 and Comparative Example 4-1 
               
            
           
           
               
               
               
            
               
                   
                 At 15 mA/cm 2   
                   
               
            
           
           
               
               
               
               
               
               
            
               
                   
                   
                   
                 Voltage 
                   
                 At 80 mA/cm 2   
               
               
                   
                 CIEx 
                 CIEy 
                 [V] 
                 EQE [%] 
                 LT95 [h] 
               
               
                   
               
            
           
           
               
               
               
               
               
               
            
               
                 Example 4-1 
                 0.682 
                 0.317 
                 4.8 
                 22.9 
                 160 
               
               
                 Comparative 
                 0.681 
                 0.317 
                 4.8 
                 23.2 
                 140 
               
               
                 Example 4-1 
                   
                   
                   
                   
                   
               
               
                   
               
            
           
         
       
     
     In Example 4-1, in the red light device, Compound 70 with a LUMO energy level of −5.20 eV was used as a p-type conductive doped material and was doped to Compound H-124, a hole transporting material with a HOMO energy level of −5.29 eV. Comparative Example 4-1 was a structure of a red light device commonly used in the industry, and it can be known from the device data that it had the high performance of a red light device in the industry. Compared with Comparative Example 4-1, under the premise of ensuring the color, the voltage and efficiency of the device in Example 4-1 were basically maintained, and the lifetime was increased by 14%. That is, the simple device structure that utilizes the combination of a hole transporting material having a deep HOMO energy level and a p-type conductive doped material also having a deep LUMO energy level can significantly improve the performance of a red light device, especially in terms of lifetime of the device. 
     Example 5-1: The preparation method was the same as that in Example 4-1, except that all Compounds H-124 were replaced by Compound H-176. 
     Comparative Example 5-1: The preparation method was the same as that in Example 5-1, except that Compound HATCN was used to form the hole injection layer (HIL, 100 Å), Compound HT was used to form the hole transporting layer (HTL, 400 Å), and Compound H-176 was used to form the second hole transporting layer (HTL2, 50 Å). 
     
       
         
           
               
             
               
                 TABLE 9 
               
             
            
               
                   
               
               
                 Structures of devices in Example 5-1 and Comparative Example 5-1 
               
            
           
           
               
               
               
               
               
               
               
            
               
                 Device ID 
                 HIL 
                 HTL 
                 HTL2 
                 EML 
                 HBL 
                 ETL 
               
               
                   
               
            
           
           
               
               
               
               
               
               
            
               
                 Example 5-1 
                 H-176:70 
                 H-176 (450 Å) 
                 RH:RD 
                 GH2 (50 Å) 
                 ET2:Liq 
               
               
                   
                 (97:3)(100 Å) 
                   
                 (98:2)(400 Å) 
                   
                 (40:60) (350 Å) 
               
            
           
           
               
               
               
               
               
               
               
            
               
                 Comparative 
                 HATCN 
                 HT 
                 H-176 
                 RH:RD 
                 GH2 (50 Å) 
                 ET2:Liq 
               
               
                 Example 5-1 
                 (100 Å) 
                 (400 Å) 
                 (50 Å) 
                 (98:2)(400 Å) 
                   
                 (40:60) (350 Å) 
               
               
                   
               
            
           
         
       
     
     The performance of devices in Example 5-1 and Comparative Example 5-1 is summarized in Table 10. The chromaticity coordinates, external quantum efficiency and voltage were measured at the current density of 15 mA/cm 2 , and the lifetime of the device (LT95) was the measured time for the device to decay to 95% of initial brightness at 80 mA/cm 2 . 
     
       
         
           
               
             
               
                 TABLE 10 
               
             
            
               
                   
               
               
                 Performance data of devices in Example 5-1  
               
               
                 and Comparative Example 5-1 
               
            
           
           
               
               
               
            
               
                   
                 At 15 mA/cm 2   
                   
               
            
           
           
               
               
               
               
               
               
            
               
                   
                   
                   
                 Voltage 
                   
                 At 80 mA/cm 2   
               
               
                   
                 CIEx 
                 CIEy 
                 [V] 
                 EQE [%] 
                 LT95 [h] 
               
               
                   
               
            
           
           
               
               
               
               
               
               
            
               
                 Example 5-1 
                 0.681 
                 0.318 
                 4.8 
                 23.7 
                 150 
               
               
                 Comparative 
                 0.681 
                 0.317 
                 4.8 
                 23.6 
                 135 
               
               
                 Example 5-1 
                   
                   
                   
                   
                   
               
               
                   
               
            
           
         
       
     
     In Example 5-1, in the red light device, Compound 70 with a LUMO energy level of −5.20 eV was used as a p-type conductive doped material and was doped to Compound H-176, a hole transporting material with a HOMO energy level of −5.29 eV. Comparative Example 5-1 was a structure of a red light device commonly used in the industry, and it can be known from the device data that it had the high performance of a red light device in the industry. Compared with Comparative Example 5-1, under the premise of ensuring the color, the voltage and efficiency of the device in Example 5-1 were basically maintained the same, and the lifetime was increased by 11%. That is, it is further proved that the simple device structure that utilizes the combination of a hole transporting material having a deep HOMO energy level and a p-type conductive doped material having a deep LUMO energy level can also significantly improve the performance of a red light device, especially in terms of lifetime of the device. 
     In summary, by combining a hole transporting material having a deep HOMO energy level and a p-type conductive doped material having a deep LUMO energy level, the injection and transporting of holes are facilitated, and the device performance of such device is better than that of the device formed by the combination of a p-type conductive doped material having a shallow LUMO energy level and a hole transporting material having a deep HOMO energy level. Furthermore, the combination in the present disclosure can effectively improve device performance when applied to various organic electroluminescence devices, and is a material combination with great development potential. 
     It should be understood that various embodiments described herein are examples and not intended to limit the scope of the present disclosure. Therefore, it is apparent to those skilled in the art that the present disclosure as claimed may include variations of specific embodiments and preferred embodiments described herein. Many of the materials and structures described herein may be replaced with other materials and structures without departing from the spirit of the present disclosure. It should be understood that various theories as to why the present disclosure works are not intended to be limitative.