Patent Publication Number: US-11031284-B2

Title: Semiconductor device and method of forming the same

Description:
PRIORITY CLAIM AND CROSS-REFERENCE 
     This patent is a continuation of U.S. patent application Ser. No. 16/165,525 filed on Oct. 19, 2018, entitled of “A SEMICONDUCTOR DEVICE AND METHOD OF FORMING THE SAME”, now allowed, which is incorporated by reference in its entirety. 
    
    
     BACKGROUND 
     In integrated circuit design, a commonly used method for forming metal lines and vias is known as “damascene.” Generally, this method involves forming an opening in a dielectric layer. Then the opening is filled with metal or metal alloys. Excess metal on the surface of the dielectric layer is then removed by a chemical mechanical polish (CMP). The remaining metal forms vias and/or metal lines. 
     While aluminum and aluminum alloys were most frequently used in the past, the current trend is to use copper (Cu) in the damascene structures because of its low resistivity. Typically, copper is electro-plated into damascene openings. 
     As semiconductor technologies further advance, accurate alignment or overlay may become problematic due to the ever-decreasing sizes of the vias and metal lines. For example, it may be more difficult for vias to be accurately aligned with the desired metal lines above or below. When misalignment or overlay problems occur, conventional methods of fabrication may lead to undesirable over-etching of the below m. It is within this context the following disclosure arises. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
       Aspects of the present disclosure are best understood from the following detailed description when read with the accompanying figures. It is noted that, in accordance with the standard practice in the industry, various features are not drawn to scale. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion. 
         FIG. 1  is a cross section view of a semiconductor device in accordance with some embodiments of the present disclosure. 
         FIG. 2  is a cross section view of a semiconductor device in accordance with some embodiments of the present disclosure. 
         FIG. 3  to  FIG. 13  illustrate a method of forming a semiconductor device in accordance with some embodiments of the present disclosure. 
     
    
    
     DETAILED DESCRIPTION 
     The following disclosure provides many different embodiments, or examples, for implementing different features of the provided subject matter. Specific examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to be limiting. For example, the formation of a first feature over or on a second feature in the description that follows may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features may be formed between the first and second features, such that the first and second features may not be in direct contact. In addition, the present disclosure may repeat reference numerals and/or letters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed. 
     Further, spatially relative terms, such as “beneath,” “below,” “lower,” “above,” “upper” and the like, may be used herein for ease of description to describe one element or feature&#39;s relationship to another element(s) or feature(s) as illustrated in the figures. The spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. The apparatus may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein may likewise be interpreted accordingly. 
     Notwithstanding that the numerical ranges and parameters setting forth the broad scope of the disclosure are approximations, the numerical values set forth in the specific examples are reported as precisely as possible. Any numerical value, however, inherently contains certain errors necessarily resulting from the standard deviation found in the respective testing measurements. Also, as used herein, the term “about” generally means within 10%, 5%, 1%, or 0.5% of a given value or range. Alternatively, the term “about” means within an acceptable standard error of the mean when considered by one of ordinary skill in the art. Other than in the operating/working examples, or unless otherwise expressly specified, all of the numerical ranges, amounts, values and percentages such as those for quantities of materials, durations of times, temperatures, operating conditions, ratios of amounts, and the likes thereof disclosed herein should be understood as modified in all instances by the term “about.” Accordingly, unless indicated to the contrary, the numerical parameters set forth in the present disclosure and attached claims are approximations that can vary as desired. At the very least, each numerical parameter should at least be construed in light of the number of reported significant digits and by applying ordinary rounding techniques. Ranges can be expressed herein as from one endpoint to another endpoint or between two endpoints. All ranges disclosed herein are inclusive of the endpoints, unless specified otherwise. 
     Semiconductor devices and methods of forming the same are provided. In particular, semiconductor devices with a mask for protecting underlying metal are described in greater detail below. In addition, methods of forming semiconductor devices with a mask for protecting underlying metal are also provided below. Other features and processes may also be included. 
     Referring to  FIG. 1 ,  FIG. 1  is a cross section view of a semiconductor device  100  in accordance with some embodiments of the present disclosure. 
     The semiconductor device  100  includes a substrate  102  having a first conductive pattern  104 . The semiconductor device  100  also includes a conductive mask  106  disposed over the first conductive pattern  104 , and a second conductive pattern  108  disposed over the conductive mask  106 . 
     The first conductive pattern  104  includes a first conductive material M 1 . In some embodiments, the first conductive material M 1  may be disposed in a via hole or a via opening of the substrate  102  to form a via and conductive line. In various examples, the first conductive material M 1  may be copper (Cu). In some embodiments, the first conductive material M 1  may be a copper alloy, silver (Ag), gold (Au), tungsten (W), tantalum (Ta), aluminum (Al), and the like. 
     In some embodiments, the first conductive pattern  104  may be formed by a damascene operation, such as a single-damascene operation or a double-damascene operation. A damascene operation which creates either only trenches or vias is known as a single damascene operation. A damascene operation which creates both trenches and vias at the same time is known as a dual-damascene operation. The dual-damascene operation may be the via first trench last (VFTL) approach or the trench first via last (TFVL) approach. 
     The conductive mask  106  includes a second conductive material M 2 . In some embodiments, the conductive mask  106  served as an etch stop layer. In addition to signaling the termination point of an etching operation, the conductive mask  106  protects the underlying first conductive pattern  104  during the etching operation. 
     In various examples, the second conductive material M 2  includes cobalt (Co), nickel (Ni), or other suitable material that may protect the first conductive material M 1  during the etching operation. 
     In some embodiments, the second conductive pattern  108  may be formed by performing an etching operation to a blanket metal layer with the predetermined etchant. In some embodiments, the predetermined etchant includes halogens. For example, the etch recipe may include a plasma etch gas having Cl 2 , BCl 3 , CF 4 , CH 2 F 2 , and/or C 4 F 8 . In some embodiments, the etch recipe may also include H 2 , N 2 , and/or O 2 . It should be noted that the etch recipe shown above is for illustration only, and any other etch recipe can be used for any other vias and metal lines. The second conductive pattern  108  includes a third conductive material M 3 . The second conductive material M 2  has a lower etch rate to a predetermined etchant than the third conductive material M 3  of the second conductive pattern  108 . 
     In some embodiments, the first conductive pattern  104  and the second conductive pattern  108  are formed by different operation. The first conductive pattern  104  is formed by a damascene operation, which includes etching an insulative layer (such as a dielectric layer) to form a via hole, and filling the via hole with a conductive material (such as copper). The second conductive pattern  108  is formed by etching a blanket conductive layer to form a via and/or a metal line, and then performing a dielectric gap filling operation to embed the via and/or metal line. The dielectric embedding the second conductive pattern  108  is not shown in the figures. 
     The second conductive pattern  108  electrically connects with the first conductive pattern  104  through the conductive mask  106 . In some embodiments, the second conductive pattern  108  covers up the conductive mask  106 . 
     In some embodiments, the conductive mask  106  includes two corners  110 A and  110 B as shown in the cross-sectional view in  FIG. 1 . In some embodiments, the second conductive pattern  108  covers up at least one of the two corners  110 A and  110 B. In some embodiments, the second conductive pattern  108  covers up the corner  110 B, while the corner  110 A is free from the second conductive pattern  108 . 
     In some embodiments, from the cross-sectional view, the conductive mask  106  includes a first surface  106 A contacting with the first conductive pattern  104 . The conductive mask  106  also includes a second surface  106 B contacting with the second conductive pattern  108 . Besides, the conductive mask  106  also includes two sidewall surfaces  106 C connected between the first surface  106 A and the second surface  106 B. In some embodiments, the sidewall surfaces  106 C are embedded in the second conductive pattern  108 . In some embodiments, at least one of the sidewall surfaces  106 C is embedded in the second conductive pattern  108 . 
     In some embodiments, the substrate  102  further includes a dielectric material  103 , and the first conductive pattern  104  is embedded in the dielectric material  103 . In some embodiments, a surface  104 S of the first conductive pattern  104  is exposed from the dielectric material  103 . In some embodiments, the whole dielectric material  103  of the substrate  102  is free from the conductive mask  106 . 
     In some embodiments, the substrate  102  has a dielectric surface  102 S coplanar with the surface  104 S of the first conductive pattern  104 . In some embodiments, the conductive mask  106  covers up the surface  104 S of the first conductive pattern  104 , while the dielectric surface  102 S is free from the conductive mask  106 . In some embodiments, the whole dielectric surface  102 S is free from the conductive mask  106 . 
     In some embodiments, the first conductive pattern  104  has a first width W 1  that gradually changed. The second conductive pattern  108  has a second width W 2  that gradually changed. In some embodiments, the first width W 1  and the second width W 2  are measured in a direction which is perpendicular to the direction along which the conductive mask  106  stacks on the first conductive pattern  104 . In some embodiments, the first width W 1  and the second width W 2  are gradually changed along the stacking direction. In some embodiments, the first width W 1  of the first conductive pattern  104  and the second width W 2  of the second conductive pattern  108  are gradually increase toward each other. 
     In some embodiments, the first conductive pattern  104  tapers toward a first direction D 1 . In other words, the first conductive pattern  104  has a tapered profile with one end closer to the conductive mask  106  being wider than the another end that farther from the conductive mask  106 . 
     In some embodiments, the first width W 1  tapers inwardly from the side contacting the conductive mask  106  to the opposite side. In some embodiments, the first width W 1  tapers by a varied slope. In some embodiments, the first width W 1  tapers by a constant slope. 
     In some embodiments, the second conductive pattern  108  tapers toward a second direction D 2  that opposite to the first direction D 1 . The second conductive pattern  108  has a tapered profile with one end closer to the conductive mask  106  being wider than the another end that farther from the conductive mask  106 , which is similar to the first conductive pattern  104 . 
     In some embodiments, the second width W 2  tapers inwardly from the side contacting the conductive mask  106  to the opposite side. In some embodiments, the second width W 2  tapers by a varied slope. In some embodiments, the second width W 2  tapers by a constant slope. 
     Referring to  FIG. 2 ,  FIG. 2  is a cross section view of a semiconductor device  200  in accordance with some embodiments of the present disclosure. Since the semiconductor device  200  in  FIG. 2  is similar to the semiconductor device  100  in  FIG. 1 , the identical numbers represent similar components for simplicity of explanation. Such similar components are omitted in the interest of brevity, and only the differences are provided. 
     The semiconductor device  200  is similar to the semiconductor device  100  with the difference that the second conductive pattern  108  is aligned with the conductive mask  106 . In some embodiments, the corners of the conductive mask  106  are partially covered by the second conductive pattern  108 . In some embodiments, the sidewall surfaces  106 C are free from the second conductive pattern  108 . 
     Referring to  FIG. 3  to  FIG. 13 ,  FIG. 3  to  FIG. 13  illustrate a method of forming a semiconductor device in accordance with some embodiments of the present disclosure. 
     The method begins with  FIG. 8 , forming the substrate  102 . Before addressing illustrated embodiments of the method specifically, exemplary embodiments of forming the substrate  102  through a damascene operation are discussed with reference to  FIG. 3  to  FIG. 7 . 
       FIG. 3  illustrates a cross-sectional view of a semiconductor device according to an embodiment of the present disclosure. The semiconductor device of  FIG. 3  includes individual devices  122 , such as transistors, formed on a bottom layer  120 . The bottom layer  120  is a substrate layer where a plurality of drain and source regions of the transistors may be formed. Generally, the individual devices  122  get interconnected with wiring or metallization layers over the bottom layer  120  through the damascene operation. 
     In various examples, the bottom layer  120  may include bulk silicon, doped or undoped, or an active layer of a semiconductor-on-insulator (SOI) substrate. Generally, an SOI substrate includes a layer of a semiconductor material, such as silicon, formed on an insulator layer. The insulator layer may be a buried oxide (BOX) layer or a silicon oxide layer. Other substrates known in the art may also be used. 
     The individual devices  122  may include a gate structure. The gate structure may be a planar or three dimension (such as FinFET) gate. Various materials can be chosen for the gate structure, such as metal, polysilicon, metal alloy, or other suitable materials. 
     In some embodiments, the bottom layer  120  may include p-type and/or n-type doped regions of electrical devices, such as N-type metal-oxide semiconductor (NMOS) devices and/or P-type metal-oxide semiconductor (PMOS) devices. The N/P-type devices may include transistors, capacitors, resistors, diodes, photo-diodes, fuses, and the like, interconnected to perform one or more functions. The functions may include memory structures, processing structures, sensors, amplifiers, power distribution, input/output circuitry, or the like. 
     The dielectric material  103  is formed on the bottom layer  120  as an insulating layer, i.e., an inter-layer dielectric (ILD) layer. 
     The dielectric material  103  may include a low dielectric constant (k value) material or an extra low dielectric constant (ELK) material. Generally, a low-k dielectric material has a dielectric constant of less than about 3.5, and an ELK dielectric material has a dielectric constant of less than about 2.8. For example, the dielectric material  103  may include silicon dioxide (SiO 2 ), carbon-doped silicon dioxide, porous silicon dioxide, horophosphosilicate glass (BPSG), tetraethyl orthosilicate (TEOS), spin-on glass (SOG), undoped silicate glass (USG), fluorinated silicate glass (FSG), high-density plasma (FIDP) oxide, or plasma-enhanced TEOS (PETEOS). A planarization operation, such as chemical-mechanical polishing (CMP), may be performed to planarize the dielectric material  103 . 
     In some embodiments, the dielectric material  103  may be a composite film. For example, the composite film may include an etching stop layer, a low-k or extra low-k (ELK) dielectric layer, an anti-reflective coating (ARC) layer, and a metal-hard-mask (MHM) layer. 
     In some embodiments, the dielectric material  103  can be deposited by chemical vapor deposition (CVD), plasma enhanced chemical vapor deposition (PECVD), high density plasma chemical vapor deposition (HDP-CVD) atmospheric pressure chemical vapor deposition (APCVD), or other suitable operation known in the art. 
     To form via holes  124  in the dielectric material  103 , a photoresist layer may be defined on the dielectric material  103 . The photoresist layer is required to be patterned based on the desired layout configuration of vias and metal lines in the dielectric material  103 . 
     The photoresist layer may include adhesive agents, sensitizers and solvents. It may be a positive or a negative resist. The photoresist layer may be formed by spin on methods on a rotating chuck. The photoresist layer may then be etched to transfer the pattern into the dielectric material  103 . 
     The underlying individual devices  122  or bottom layer  120  may be exposed through the via holes  124 . Though two via holes  124  are shown in the figures, the numbers are for explanation purpose only, and the present disclosure is not limited thereto. 
     The via holes  124  in the dielectric material  103  is intentionally configured to have a tapered profile. As the critical dimensions (CD) of vias or metal lines to be formed in the dielectric material  103  become smaller, in physical vapor deposition (PVD), CVD, or atomic layer deposition (ALD), barrier or copper seed layer may preferentially deposit near the top corners of the via holes, and leading to a “bottleneck” shape, i.e. necking effect. By forming the via holes  124  with a tapered profile, the above issue can be mitigated. 
     Referring to  FIG. 4 , in some embodiments, a barrier layer  126  may be deposited in the via holes  124 . The barrier layer  126  covers the sidewalls and the bottom of the via holes  124 . The barrier layer  126  may be formed by CVD, PVD, PECVD, plasma enhanced PVD (PEPVD), ALD, combinations of these, or the like. The barrier layer  126  may include tantalum nitride (TaN), although other materials, such as tantalum (Ta), titanium (Ti), titanium nitride (TiN), combinations of these, and the like may alternatively be used. The barrier layer  126  is used to prevent copper diffusion in the dielectric material  103 . The excess portions formed around the top corners of the via holes  124  are often referred to as overhangs. In this embodiment, by enlarging the top opening and forming the tapered profile, the subsequent copper filling operation is not greatly affected by the necking effect induced from overhangs. 
     Referring to  FIG. 5 , in some embodiments, a seed layer  128  may be deposited on the barrier layer  126  to improve the quality of the electrode surface. In this way, high quality plating may be obtained for the copper to be deposited in the next step. In an exemplary deposition operation, argon (Ar) is first introduced to generate argon plasma. The positively charged argon ions are attracted to the negatively charged copper material, causing a bombardment. Copper ions are thus sputtered from the copper material, and deposited onto the barrier layer  126 , forming the seed layer  128 . 
     The seed layer  128  is a thin copper layer on the surface where a metal layer will be plated. The chemical vapor deposition (CVD) may be used to deposit the seed layer  128 . Optionally, before the formation of the seed layer  128 , the barrier layer  126  is pre-cleaned. The pre-cleaning greatly improves the surface texture of the barrier layer  126  so that the subsequently formed seed layer  128  may be more conformal. 
     Referring to  FIG. 6 , a conductive material  130  (i.e., the first material M 1 ), such as copper (Cu), may be disposed over the seed layer  128 , into the via holes  124 , to form the vias and the metal lines. Other material, such as tungsten (W), may also be used. The conductive material  130  may be formed by an electro-chemical plating process. 
     Referring to  FIG. 7 , a planarization operation, such as a CMP process, may be performed to expose the low-k or ELK dielectric layer  103 . The first conductive pattern  104  and the dielectric layer  103  are together referred as the substrate  102 . Although the figures show only one metallization layer for interconnecting the individual devices  122 , there may be other layers form on the bottom layer  120  for other functions. The bottom layer  120 , the individual devices  122 , the barrier layer  126 , and the seed layer  128  are omitted in the interest of brevity in the following figures. 
     Turning now to  FIG. 8 ,  FIG. 8  illustrates the substrate  102  formed through the damascene operation described above in relation to  FIG. 3  to  FIG. 7 . The substrate  102  has the dielectric material  103  and the first conductive pattern  104  embedded in the dielectric material  103 . The first conductive pattern  104  includes the first material M 1 . 
     Referring to  FIG. 9 , the conductive mask  106  is formed on the exposed surface  104 S of the first conductive pattern  104 . 
     In some embodiments, the conductive mask  106  may be formed by technique such as metal-metal epitaxy on silicon (MMES), or other metal growth techniques, including sputtering and other thin film deposition techniques. 
     In some embodiments, the conductive mask  106  grows on the first conductive pattern  104  as epitaxial islands. It is known in the art that, the lattice constant is a measure of the structural compatibility between different materials in epitaxial growth. Lattice constant matching is important for the growth of materials on other materials. Metal grows easily on a surface with little lattice spacing difference. 
     In some embodiments, the first material M 1  and the second material M 2  may be predetermined or be under control so that the second material M 2  only grows on the first material M 1 , but not grows on the dielectric material  103 . In an example where the first material M 1  is copper, cobalt or nickel may grow on the copper with little lattice spacing difference. 
     Certain metals do not exhibit a lattice match with copper. Such metals require one or more additional metal seed layers before epitaxial growth is achieved. For example, gold (Au), silver (Ag), platinum (Pt), iron (Fe), vanadium (V) and chromium (Cr) will grow epitaxially when palladium (Pd) is first deposited on copper. Tungsten (W) and molybdenum (Mo), for instance, do not grow epitaxially on palladium but will grow epitaxially when gold (Au) is first deposited on palladium. In such embodiment, the conductive mask  106  may be a composite film. 
     Referring to  FIG. 10 , a blanket metal layer  500  is deposited over the substrate  102  and the conductive mask  106 . In some embodiments, the blanket metal layer  500  includes copper (Cu), cobalt (Co), aluminum (Al), titanium (Ti), ruthenium (Ru), tungsten (W), rhodium (Rh), molybdenum (Mo), or other suitable metal or alloy thereof. The blanket metal layer  500  can be formed by any of several methods that are well known in the art, such as CVD, PVD, PECVD, PEPVD, ALD, spin coating, or sputtering. 
     Referring to  FIG. 11 , a photo-sensitive polymer layer  600  is formed the blanket metal layer  500  to pattern the blanket metal layer  500 . In some embodiments, the photo-sensitive polymer layer  600  includes photoresist materials including, but not limited to, positive photoresist materials and negative photoresist materials. In the illustrated example in  FIG. 11 , the photo-sensitive polymer layer  600  is formed from a positive photoresist material such as, but not limited to, a novolak positive photoresist material or a poly-methyl-meth-acrylate (PMMA) positive photoresist material. The photo-sensitive polymer layer  600  can be formed using any suitable technique, such as CVD, LPCVD or PECVD. 
     In some embodiments, as shown in  FIG. 11 , the photo-sensitive polymer layer  600  is patterned by using a standard method of photolithography. For example, the photo-sensitive polymer layer  600  is patterned by photoresist coating, exposure and development process. Then a portion of the blanket metal layer  500  is exposed from the photo-sensitive polymer  600 . 
     In some embodiments, as shown in  FIG. 11 , the photo-sensitive polymer layer  600  is patterned with an offset  602  from the dashed line boxes  603 . The dashed line boxes  603  are aligned with fringe of the conductive mask  106 . In such way, the second conductive pattern  108  formed in the subsequent step will be aligned to the conductive mask  106  with the offset  602 . In some embodiments, the second conductive pattern  108  is aligned to covers at least one corner of the conductive mask  106 , such as the corner  110 B. 
     In some embodiments, the second conductive pattern  108  is aligned to the conductive mask  106  with no offset, forming the semiconductor device  200  in  FIG. 2 . 
     Referring to  FIG. 12 , the blanket metal layer  500  is etched, using the photo-sensitive polymer layer  600  as a mask. Since the photo-sensitive polymer layer  600  is a positive photoresist illustrated example, the exposed portions of the blanket metal layer  500  is etched away by the predetermined etchant. In an embodiment where the photo-sensitive polymer layer  600  is a negative photoresist, the alignment of the sensitive polymer layer  600  may also be deformed, and the covered portions of the blanket metal layer  500  is etched away. 
     In some embodiments, the predetermined etchant includes halogens. As mentioned above, the second conductive material M 2  of the conductive mask  106  has a lower etch rate to the predetermined etchant than the third conductive material M 3  of the second conductive pattern  108 . In some embodiments, the conductive mask  106  has a lower etch rate to the predetermined etchant than the blanket metal layer  500 . The second conductive pattern  108  is formed on the substrate  102  and the conductive mask  106 , as shown in  FIG. 12 . The second conductive pattern  108  is formed with a tapered profile, with the top width being smaller than the respective bottom width. In other words, sidewalls of the second conductive pattern  108  are slanted, with the inner angles α being less than 90 degrees. 
     The sensitive polymer layer  600  may be stripped after transferring the pattern to the blanket metal layer  500 , forming the semiconductor device  100  in  FIG. 13 . 
     Some embodiments of the present disclosure provide a semiconductor device. The semiconductor device includes a substrate having a first conductive pattern and a conductive mask disposed over the first conductive pattern. The first conductive pattern includes a first conductive material and the conductive mask includes a second conductive material. The semiconductor device further includes a second conductive pattern disposed over the conductive mask, and electrically connecting with the first conductive pattern through the conductive mask. The conductive mask has a lower etch rate to a predetermined etchant than the second conductive pattern. A method for forming the semiconductor device is also provided. 
     Some embodiments of the present disclosure provide a semiconductor device. The semiconductor device includes a substrate having a first conductive via, and a conductive mask disposed over the first conductive via. The semiconductor device further includes a second conductive via disposed over the conductive mask. The first conductive via has a first width gradually changed. The second conductive via has a second width gradually changed. The first width of the first conductive via and the second width of the second conductive via are gradually increase toward each other. 
     Some embodiments of the present disclosure provide a method for forming a semiconductor device. The method includes forming a substrate having a dielectric material and a first conductive pattern embedded in the dielectric material. The first conductive pattern includes a first conductive material. The method further includes forming a conductive mask over the first conductive pattern. The method further includes forming second conductive pattern over the conductive mask and electrically connecting with the first conductive pattern through the conductive mask, wherein the conductive mask has a lower etch rate to a predetermined etchant than the second conductive pattern. 
     The foregoing outlines features of several embodiments so that those skilled in the art may better understand the aspects of the present disclosure. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments introduced herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they may make various changes, substitutions, and alterations herein without departing from the spirit and scope of the present disclosure. 
     Moreover, the scope of the present application is not intended to be limited to the particular embodiments of the process, machine, manufacture, composition of matter, means, methods and steps described in the specification. As one of ordinary skill in the art will readily appreciate from the disclosure of the present invention, processes, machines, manufacture, compositions of matter, means, methods, or steps, presently existing or later to be developed, that perform substantially the same function or achieve substantially the same result as the corresponding embodiments described herein may be utilized according to the present invention. Accordingly, the appended claims are intended to include within their scope such processes, machines, manufacture, compositions of matter, means, methods, or steps.