Patent Publication Number: US-8974876-B2

Title: Printable paper, comprising water-resistant support

Description:
CROSS-REFERENCE TO RELATED PATENT APPLICATIONS 
     This application is a continuation of copending U.S. patent application Ser. No. 12/402,599, filed on Mar. 12, 2009, which claims the benefit of U.S. Provisional Application No. 61/037,472 filed on Mar. 18, 2008, and the benefit of European Patent Application No. 08102728.6 filed on Mar. 18, 2008, each of which is incorporated by reference. 
    
    
     FIELD OF THE INVENTION 
     The present invention concerns a printable paper, a process for producing printable paper, and the use thereof in offset printing. 
     BACKGROUND OF THE INVENTION 
     Synthetic papers may be classified into two different types: one with a fibrous structure like cellulose paper, with synthetic fibers made from polyamides, polyester, or polyolefins replacing the cellulose fibers; and one in which a film is directly extruded from a thermoplastic polymer. These products differ considerably in their structure from cellulose paper and thus present a variety of different problems. 
     Extruded film is produced either by the cast film process or the blown film process in which the melt is forced through a circular die. A variant of the blown film process is the extrusion of foamed film in which through the addition of blowing agents (usually low boiling hydrocarbons) it is possible to produce foamed film from a variety of polymers. Two methods are used for the biaxial stretching of cast film: the simultaneous stretching process, in which the stretching is carried out in both directions at the same time, and the two-stage process, in which the two stretching operations are carried out consecutively. 
     Extruded films have a smooth surface which depends more on the state of the chill rolls than on the material itself. There are no cavities with capillary activity such as between the fibers of cellulose paper or synthetic fiber webs. This combination of smooth surface, low absorbing power, and non-polar structure frequently makes it difficult to print on polymer films: drying times are long, and the adhesion of the printing ink is poor. 
     Lunk and Stange in 1971 in Angewandte Chemie International Edition, volume 10, pages 287-294 stated that one type of surface treatment to improve the printability of extruded films is the application of a pigment coating. In the paper industry, the improvement of the surface of cellulose paper with a pigment coating had been known for some time. Typical binders for these coatings were casein, polyacrylates, or copolymers of butadiene and styrene. China clay, barium sulfate, chalk, or titanium dioxide were used as pigments. In spite of their closed, smooth surface coated papers were sufficiently absorptive for letterpress and offset printing because of their high content of mineral filler. Coated polymer films had similar properties; they could also be used for all printing processes, and the print quality was equal to that of coated papers. However, the demands of the printing industry have increased since 1971 requiring papers with ever higher printability. 
     GB 2 177 413A discloses a coating composition for a plastics substrate and comprising an aqueous system containing polymeric binder, pigment and antistatic agent characterised in that the binder contains carboxyl groups, that the binder:pigment dry weight ratio is in the range 15:100 to 50:100, preferably 22:100 to 35:100, the antistatic agent comprises a water soluble ionic compound present in an amount corresponding to a dry weight:pigment ratio of from 0.4:100 to 2.5:100 and in that the composition also contains an insolubilizing agent which is capable of reacting with carboxyl groups of the binder on drying the composition to insolubilize (as hereinbefore defined) the binder. 
     U.S. Pat. No. 5,397,637 discloses a thermoplastic resin film with satisfactory printability having a coated layer comprising a quaternary ammonium salt copolymer comprising (a) a structural unit represented by formula (I): 
                         
wherein A represents —O— or —NH—; R 1  represents a hydrogen atom or a methyl group; R 2  represents an alkylene group having from 2 to 4 carbon atoms or —CH 2 CH(OH)—CH 2 —; R 3 , R 4 , R 5 , and R 6 , which may be the same or different, each represents an alkyl group having from 1 to 3 carbon atoms; R 7  represents an alkyl group having from 1 to 10 carbon atoms or an aralkyl group having from 7 to 10 carbon atoms; n represents an integer of from 1 to 3; and X represents a chlorine atom, a bromine atom or an iodine atom, (b) a structural unit represented by formula (II):
 
                         
wherein R 8  represents a hydrogen atom or a methyl group; and R 9  represents an alkyl group having from 1 to 22 carbon atoms, an aralkyl group having from 7 to 22 carbon atoms or a cycloalkyl group having from 5 to 22 carbon atoms, and (c) a structural unit derived from a monomer copolymerizable with monomers providing structural units (a) and (b) at a (a):(b):(c) weight ratio of 30 to 70:30 to 70:0 to 40.
 
     JP 11-107194 discloses an offset-printable synthetic paper characterized by providing at least one side of a synthetic substrate with 1-7 g/m 2  of a coating layer comprising 20 to 50 wt % of polyvinyl alcohol, 20 to 50 wt % of a polyurethane resin and 20 to 50 wt % of a silica pigment, with it being preferred that the polyurethane resin is a carboxyl-containing crosslinkable polyurethane resins or a polyester-based polyurethane resin and the particle size of the silica pigment is 2-5 μm, and the synthetic paper has 20-50% opacity determined in accordance with the JIS P 8138. 
     U.S. Pat. No. 6,300,393 discloses a paper coating composition comprising (a) at least one binder containing a plurality of functional groups capable of reacting with carboxylic acid anhydride moieties to form chemical bonds, and (b) at least one insolubilizing agent chosen from the froup consisting of compounds containing a plurality of carboxylic acid anhydride moieties per molecukar entity. 
     WO 03/033577A discloses a printable, opaque coated sheet, suitable for use in contact and/or association with foodstuffs, the coating comprising by dry weight of the coat: (a) from about 30% to about 70% of a copolymer of an ethylenically unsaturated acid; (b) from about 30% to about 70% of an inert particulate filler; where the coating is substantially free from any reactive binder and/or cross-linking agent. WO 03/033577A further discloses that the ethylenically unsaturated acid is preferably neutralised by ammonia and not metal cations, since this has the advantage that on drying ammonia evaporates and acid groups become less moisture sensitive compared to metal cation stabilised ethylene acrylic acid (EAA) copolymer dispersions. 
     US 2004/0146699A1 discloses a composite plastics sheet which is printable on at least one surface, and comprises a base layer and optionally a printable layer forming the printable surface, characterized in that the base layer has a density of 0.65 g/mL or less, or, if there is no separate adhesive layer on the surface opposite the printable surface, a density of 0.7 g/mL or less. 
     US 2006/0257593A1 discloses a printing sheet comprising a substrate and, on at least one side of the substrate, an image receptive coating layer with a cumulative porosity volume of pore widths below 200 nm as measured using nitrogen intrusion methods of more than 0.006 cm 3  per gram paper. 
     EP 1 743 976A1 discloses a coated printing sheet for sheet-fed offset printing with an image receptive coating layer on a paper substrate, characterized in that the image receptive coating layer comprises a top layer and/or at least one second layer below said top layer, said top and/or second layer comprising: a pigment part, wherein this pigment part is composed of 0 to 99 parts in dry weight of a fine particulate carbonate and/or of a fine particulate kaolin 1 to 100 parts in dry weight of a fine particulate silica and a binder part, wherein this binder part is composed of: 5-20 parts in dry weight of binder and less than 4 parts in dry weight of additives. 
     As the foregoing present certain disadvantages, a need exists for an improved paper for use in printing processes. 
     SUMMARY OF THE INVENTION 
     In one aspect the present invention provides a printable paper comprising a water-resistant support having two optionally subbed sides and a single layer on at least one of said optionally subbed sides, wherein said single layer has no substantial compositional variation, has a layer thickness of at least 3 μm, a pore volume of at least 1.2 mL/m 2  and comprises at least one porous pigment. 
     A further aspect of the invention provides a process for producing a printable paper comprising the steps of: (i) optionally providing a water-resistant support having two sides with a subbing layer on at least one side; and (ii) providing at least one side of said optionally subbed water-resistant support with a single layer having no substantial compositional variation, said single layer being applied to said optionally subbed water-resistant support as at least one wet aqueous layer in a single pass for each side of said water-resistant support, said at least one aqueous layer comprising at least one latex, at least one pigment, at least one binder and optionally at least one insolubilizing agent, wherein said latex is an anionic acrylic latex or an aliphatic polyurethane latex. 
     Another aspect of the present invention contemplates the use in printing of the above-described printable paper or that obtained by the above-described production process. 
     Further aspects and advantages of the invention will become apparent from the detailed description of the invention. 
    
    
     DETAILED DESCRIPTION OF THE INVENTION 
     Definitions 
     The term “printable paper”, as used in disclosing the present invention, means paper or a paper-like material capable of being printed by at least one conventional contact or contactless printing technique e.g. offset printing, gravure printing, screen printing, flexographic printing, electrophotographic printing and ink jet printing. 
     The term “overprintable”, as used in disclosing the present invention, means capable of being overprinted by conventional impact and/or non-impact printing processes. 
     The term “conventional printing processes”, as used in disclosing the present invention, includes but is not restricted to ink jet printing, intaglio printing, screen printing, flexographic printing, offset printing, stamp printing, gravure printing, dye transfer printing, thermal sublimation printing and thermal and laser-induced processes. 
     The term “support”, as used in disclosing the present invention, means a “self-supporting material” so as to distinguish it from a “layer” which may be coated as a solution or dispersion, evaporated or sputtered on a support, but which itself is not self-supporting. It also includes an optional conductive surface layer and any treatment necessary for, or layer applied to aid, adhesion. 
     The term “subbing layer”, as used in disclosing the present invention, means any layer or layer configuration required to realize adhesion between the support and the single layer, but plays no role in the printing performance of the printable paper. 
     The term “water-resistant support”, as used in disclosing the present invention, means a support the surfaces of which are resistant to water e.g. synthetic paper and resin-coated cellulosic paper. 
     The term “layer”, as used in disclosing the present invention, means a (continuous) coating covering the whole area of the entity referred to e.g. a support. 
     The term “single layer”, as used in disclosing the present invention, means there is only one layer on each side of the water-resistant support, although it may be applied as a plurality of wet layers in a single pass. The “single layer” has receiving properties, since otherwise the “printable paper” would not be printable. 
     The term “no substantial compositional variation”, as used in disclosing the present invention, means that although the layer may be coated as a plurality of wet layers the layer resulting therefrom has a compositional variation of no more than 5% by weight. 
     The term “porous pigment”, as used in disclosing the present invention, embraces both pigments having primary particles having an internal porosity e.g. a silica gel particles and pigments whose primary particles have no internal porosity and have a specific surface area of at least 100 m 2 /g, which are present as secondary particles having an internal porosity as a result of the aggregation of the primary particles e.g. flame pyrolyzed inorganic particles such as the particles in the Aerosil® range produced by Degussa. 
     The term “latex”, as used in disclosing the present invention, means that the latex polymer is substantially insoluble in water i.e. having a solubility in water of less than 10 mg per 100 g water at a temperature of 25° C., is prepared by standard latex preparation techniques and is supplied and used as an aqueous dispersion. 
     The term “water-soluble binder”, as used in disclosing the present invention, means a binder with a solubility in water of at least 1 g per 100 g water at a temperature of 25° C. 
     The term “inorganic opacifying pigment”, as used in disclosing the present application, means a pigment capable of opacifying (i.e. rendering more opaque) which includes substantially white inorganic pigments having a refractive index of at least 1.4 and pigments, which as a dispersion in a polymer are capable upon stretching of causing opacity due to microvoiding. 
     The term “whitening agent”, as used in disclosing the present invention, means a white/colourless organic compound which exhibits a blue luminescence under the influence of ambient UV-light. 
     The term “insolubilizing agent”, as used in disclosing the present invention, means an agent capable of insolubilizing the latex. 
     The term “colorant”, as used in disclosing the present invention, means dyes and pigments. 
     The term “dye”, as used in disclosing the present invention, means a colorant having a solubility of 10 mg/L or more in the medium in which it is applied and under the ambient conditions pertaining. 
     The term “pigment” is defined in DIN 55943, herein incorporated by reference, as an inorganic or organic, chromatic or achromatic colouring agent that is practically insoluble in the dispersion medium under the pertaining ambient conditions, hence having a solubility of less than 10 mg/L therein. 
     The term “synthetic paper”, as used in disclosing the present invention, means a paper-like material produced either by forming a web from synthetic fibres or by extruding a film from thermoplastic polymers optionally coated on one or both sides with a receiving layer. 
     The term “film”, as used in disclosing the present invention, is an extruded sheet of a particular composition or a sheet consisting of a multiplicity of films with the same or different compositions produced by co-extrusion of liquids with the same or different compositions in contact with one another. The terms film and foil are used interchangeably in the present disclosure 
     The term linear polyester, as used in disclosing the present invention, means a polyester comprising hydrocarbon dimethylene and dicarboxylate monomer units. 
     The term “non-transparent film”, as used in disclosing the present invention, means a film capable of providing sufficient contrast to a transparent image to make the image clearly perceptible. A non-transparent film can be an “opaque film”, but need not necessarily be completely opaque in that there is no residual translucence i.e. no light penetration through the film. Optical density in transmission as measured with a MacBeth TR924 densitometer through a visible filter can provide a measure of the non-transparency of a film. ISO 2471 concerns the opacity of paper backing and is applicable when that property of a paper is involved that governs the extent to which one sheet visually obscures printed matter on underlying sheets of similar paper and defines opacity as “the ratio, expressed as a percentage, of the luminous reflectance factor of a single sheet of the paper with a black backing to the intrinsic luminous reflectance factor of the same sample with a white reflecting backing. 80 g/m 2  copy paper, for example, is white, non-transparent and has an optical density of 0.5 as measured with a MacBeth TR924 densitometer through a yellow filter according to ISO 5-2 and metallized films typically have an optical density ranging from 2.0 to 3.0. 
     The term “voids or microvoids”, as used in disclosing the present invention, means microcells, minute closed cells, cavities, bubbles or pores or cellulation, which, for example, can be formed in an oriented polymeric film during stretching as the result of a void-initiating particle initiated by particles that are immiscible with the polyester matrix. The voids or microvoids can be unfilled or filled with air or a vapour of some sort. Even if initially unfilled the voids or microvoids may over time become filled with air or a vapour of some sort. 
     The term “foam”, as used in disclosing the present invention, means a substance that is formed by trapping many gas bubbles in a liquid or solid. 
     The term “apparent density”, as used in disclosing the present invention, means the weight of a 100 mm×100 mm piece of film with a thickness measured in contact with an inductive probe with ball tip 3 mm in diameter divided by its volume. This value assumes that the surfaces of the piece of film are flat and parallel to one another. This value corresponds to the apparent density values reported in EP-A 0 496 323 and WO 2005/105903A. 
     Printable Paper 
     Aspects of the present invention are realized by a printable paper comprising a water-resistant support having two optionally subbed sides and a single layer on at least one of said optionally subbed sides, wherein said single layer has no substantial compositional variation, has a layer thickness of at least 3 μm, a pore volume of at least 1.2 mL/m 2  and comprises at least one porous pigment, with a pore volume of at least 1.5 mL/m 2  being preferred. 
     The printing paper, according to the present invention, may be coated on both sides each with a single layer in a single pass. However, if coated on one side the non-coated side may be provided with an adhesive layer for label applications. 
     Porosity can be determined by standard techniques such as nitrogen porosimetry, in which nitrogen is condensed in the pores and calculating the pore volumes from the quantities of gas required to fill the pores, and mercury porosimetry, in which liquid mercury is forced into pores by increasing the external pressure, the amount of mercury required to fill the pores being increased incrementally. 
     According to a first embodiment of the printable paper, according to the present invention, the printable paper is exclusive of an antistatic agent comprising a water-soluble ionic inorganic compound. 
     According to a second embodiment of the printable paper, according to the present invention, the opacity of said printable paper determined according to ASTM D589 C/2° is greater than 90%. 
     According to a third embodiment of the printable paper, according to the present invention, the single layer further comprises a hardened melamine-formaldehyde resin e.g. by hardening Madurit MW15 from Vianova Resins N.V. 
     According to a fourth embodiment of the present invention, the single layer further contains a hardened proteinaceous substance e.g. by the hardening of the ammonium salt of casein. 
     Water-Resistant Support 
     According to a fifth embodiment of the printable paper, according to the present invention, said water-resistant support is provided with a subbing layer on at least one side thereof. 
     The term “water-resistant support”, as used in disclosing the present invention, means a support the surfaces of which are resistant to water. Such supports enable overcoating with aqueous solutions or dispersions without affecting the “water-resistant support”. 
     Water-resistant supports include resin-coated cellulosic paper, webs having a fibrous structure formed with synthetic fibers and webs in which a film is directly extruded from a thermoplastic polymer. The resin-coating of resin-coated cellulosic paper can be rendered non-transparent by the inclusion of opacifying pigments therein. Webs having a fibrous structure formed with synthetic fibers and webs in which a film is directly extruded from a thermoplastic polymer can be rendered non-transparent by the inclusion of opacifying pigments. Furthermore, webs in which a film is directly extruded from a thermoplastic polymer can be also rendered non-transparent by axial stretching-induced microvoid formation resulting from the presence of poorly compatible dispersions of amorphous high polymers with a higher glass transition temperature than the glass transition temperature or melting point of the matrix polymer and/or the crystalline high polymers which melt at a higher temperature than the glass transition temperature or melting point of the matrix polymer and axially stretching the extruded film. Widely used matrix polymers include polyethylene, polypropylene, polystyrene, polyamide and polyester. 
     According to a sixth embodiment of the printable paper, according to the present invention, said water-resistant support is resin-coated cellulosic paper, a web having a fibrous structure formed with synthetic fibers or a web in which a film is directly extruded from a thermoplastic polymer. 
     According to a seventh embodiment of the printable paper, according to the present invention, said water-resistant support comprises at least 50% by weight of a linear polyester. 
     According to an eighth embodiment of the printable paper, according to the present invention, said water-resistant support comprises at least 50% by weight of a linear polyester and an opacifying pigment, the opacifying pigment being preferably selected from the group consisting of silica, zinc oxide, zinc sulphide, lithopone, barium sulphate, calcium carbonate, titanium dioxide, aluminium phosphate and clays. 
     According to a ninth embodiment of the printable paper, according to the present invention, said water-resistant support is a non-transparent microvoided axially stretched directly extruded thermoplastic polymer comprising dispersed therein at least one amorphous high polymer with a higher glass transition temperature than the glass transition temperature of the thermoplastic polymer and/or at least one crystalline high polymer having a melting point which is higher than the glass transition of the thermoplastic polymer. 
     According to a tenth embodiment of the printable paper, according to the present invention, said water-resistant support is a non-transparent microvoided axially stretched directly extruded linear polyester having dispersed therein at least one amorphous high polymer having a higher glass transition temperature than that of said linear polyester and/or at least one crystalline high polymer having a higher melting point than the glass transition temperature of said linear polyester matrix, the amorphous high polymer preferably comprising at least one chain-polymerized block. 
     According to an eleventh embodiment of the printable paper, according to the present invention, said water-resistant support is a non-transparent microvoided axially stretched directly extruded linear polyester having dispersed therein at least one amorphous high polymer having a higher glass transition temperature than that of said linear polyester and/or at least one crystalline high polymer having a higher melting point than the glass transition temperature of said linear polyester matrix, wherein said at least amorphous high polymer is selected from the group consisting of polystyrene, styrene copolymers, SAN-polymers, polyacrylates, acrylate-copolymers, polymethacrylates and methacrylate-copolymers, 
     According to a twelfth embodiment of the printable paper, according to the present invention, said water-resistant support is a non-transparent microvoided axially stretched directly extruded linear polyester having dispersed therein at least one amorphous high polymer having a higher glass transition temperature than that of said linear polyester and/or at least one crystalline high polymer having a higher melting point than the glass transition temperature of said linear polyester matrix, wherein said crystalline high polymer is selected from the group consisting of polyethylene, preferably high density polyethylene, polypropylene, preferably isotactic polypropylene, and isotactic poly(4-methyl-1-pentene). 
     According to a thirteenth eleventh embodiment of the printable paper, according to the present invention, said water-resistant support is a non-transparent microvoided axially stretched directly extruded linear polyester having dispersed therein particles of a SAN-polymer and/or at least one crystalline high polymer which has a melting point at a higher temperature than the glass transition temperature of the polyester, with at least one crystalline high polymer selected from the group consisting of high density polyethylene, isotactic polypropylene and isotactic poly(4-methyl-1-pentene) being preferred. 
     According to a fourteenth embodiment of the printable paper, according to the present invention, said water-resistant support is a non-transparent microvoided axially stretched directly extruded linear polyester having dispersed therein particles of at least one amorphous high polymer with a higher glass transition temperature than the glass transition temperature of the linear polyester and/or isotactic poly(4-methyl-1-pentene), with at least one amorphous high polymer selected from the group consisting of SAN (styrene-acrylonitrile)-polymers and ABS (acrylonitrile-butadiene-styrene)-polymers being preferred. 
     According to a fifteenth embodiment of the printable paper, according to the present invention, said water-resistant support is a non-transparent microvoided axially stretched directly extruded linear polyester having dispersed therein 5 to 20% by weight of a styrene-acrylonitrile-block copolymer and 0.1 to 10% by weight of isotactic poly(4-methyl-1-pentene). 
     According to a sixteenth embodiment of the printable paper, according to the present invention, said water-resistant support further comprises an ingredient selected from the group consisting of whitening agents, UV-absorbers, light stabilizers, antioxidants, flame retardants and colorants. 
     Latex 
     According to a seventeenth embodiment of the printable paper, according to the present invention, the single layer further comprises a latex, the latex being preferably an anionic acrylic latex or an aliphatic polyurethane latex. 
     According to an eighteenth embodiment of the printable paper, according to the present invention, the latex is a self-crosslinking latex. 
     Suitable latexes are given in the table below: 
     
       
         
           
               
               
               
               
               
               
               
             
               
                   
               
               
                   
                   
                   
                   
                 acid 
                   
                   
               
               
                   
                   
                   
                 solids 
                 No. 
               
               
                 latex 
                   
                   
                 conc 
                 [mg 
               
               
                 No. 
                   
                   
                 [wt %] 
                 KOH/g] 
                 pH 
                 comonomers 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
            
               
                 01 
                 Joncryl 
                 BASF 
                 42 
                 90 
                 8.5 
                 styrene 
                 2-ethyl- 
                 ammonium 
               
               
                   
                 FLX5000 
                   
                   
                   
                   
                   
                 hexyl 
                 acrylate 
               
               
                   
                   
                   
                   
                   
                   
                   
                 acrylate 
               
               
                   
                   
                   
                   
                   
                   
                   
                 α-methyl- 
               
               
                   
                   
                   
                   
                   
                   
                   
                 styrene 
               
               
                 02 
                 Joncryl 
                 BASF 
                 32 
                 216  
                 8.3 
                 styrene 
                 α-methyl- 
                 ammonium 
               
               
                   
                 8078 
                   
                   
                   
                   
                   
                 styrene 
                 acrylate 
               
               
                 03 
                 Dispercoll 
                 BAYER 
                 40 
                   
                   
                   
                 aliphatic PU 
               
               
                   
                 U53 
               
               
                 04 
                 Joncryl 
                 BASF 
                 46 
                 &lt;10   
                 8.5 
                 styrene 
                 acrylate 
                 ammonium 
               
               
                   
                 FLX5010 
                   
                   
                   
                   
                   
                   
                 acrylate 
               
               
                 05 
                 Joncryl 
                 BASF 
                 42 
                 111* 
                 7.8 
                 styrene 
                 acrylate 
                 methacrylate 
               
               
                   
                 8050 
               
               
                 06 
                 Hycar PC84 
                 Dow 
                 48 
                   
                 6.0 
                 styrene 
                 acrylic acid 
                 acrylonitrile 
               
               
                   
                   
                 Chemical 
                   
                   
                   
                   
                   
                 ethyl acrylate 
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                 N-hydroxy- 
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                 methyl- 
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                 acrylamide 
               
               
                 07 
                 Carboset 
                 Goodrich 
                 59 
                   
                 6 
                 styrene 
                 acrylate 
               
               
                   
                 GA2364 
               
               
                 08 
                 Joncryl 
                 BASF 
                 49 
                 16 
                 7.9 
                 quat. 
                 acrylate 
               
               
                   
                 8385 
                   
                   
                   
                   
                 mod 
               
               
                 09 
                 Enorax 
                 Collano 
                 30 
                   
                 4.5 
                 cationic 
                 PU 
               
               
                   
                 PU950 
               
               
                 10 
                 wac-17XC 
                 Takamatu 
                 25 
                   
                 8 
                 anionic 
                 polyester 
               
               
                   
                   
                 Oil &amp; Fat 
                   
                   
                   
                   
                 PU 
               
               
                   
                   
                 Co. Ltd 
               
               
                 11 
                 Cromelastic 
                 Cromogenia- 
                   
                   
                 8.3 
                 cationic 
                 aliphatic PU 
               
               
                   
                 C4480 
                 units S.A. 
               
               
                 12 
                 Mowilith 
                 Clariant 
                   
                   
                 6 
                 vinyl 
                 veova 
                 acrylate 
               
               
                   
                 DM 2452 
                   
                   
                   
                   
                 acetate 
                 (vinyl 
               
               
                   
                   
                   
                   
                   
                   
                   
                 versatate) 
               
               
                 13 
                 Wellpur 
                 Van Camp 
                 30 
                   
                 5 
                 cationic 
                 aliphatic PU 
               
               
                   
                 FM10C 
                 Chemicals 
               
               
                 14 
                 Neorez 
                 Avecia 
                 40 
                   
                 8.3 
                   
                 aliphatic PU 
               
               
                   
                 R989 
               
               
                 15 
                 Jetsize 
                 Eka Nobel 
                   
                   
                   
                 cationic 
                 styrene 
                 acrylate 
               
               
                   
                 CE225 
                   
                   
                   
                   
                 monomer 
               
               
                 16 
                 Hycar 
                 Lubriziol 
                 49 
                   
                   
                   
                 carboxy- 
               
               
                   
                 26084 
                   
                   
                   
                   
                   
                 modified 
               
               
                   
                   
                   
                   
                   
                   
                   
                 acrylic 
               
               
                 17 
                 Hycar 2679 
                 Lubrizol 
                 49 
                   
                   
                 acrylic 
               
               
                 18 
                 Hycar 2671 
                 Lubrizol 
                 51 
                   
                   
                   
                 acrylate 
                 acrylonitrile 
               
               
                 19 
                 Impranil 
                 BAYER 
                 60 
                   
                   
                   
                 anionic 
                 polyester- 
               
               
                   
                 DLU 
                   
                   
                   
                   
                   
                 aliphatic 
                 polyurethane 
               
               
                 20 
                 Impranil LP 
                 BAYER 
                   
                   
                   
                   
                   
                 polyurethane 
               
               
                   
                 RSC1997 
               
               
                 21 
                 Impranil LP 
                 BAYER 
                   
                   
                   
                   
                   
                 polyurethane 
               
               
                   
                 RSC3040 
               
               
                 22 
                 Bayhydrol 
                 BAYER 
               
               
                   
                 XP2558 
               
               
                 23 
                 Airflex 
                 Air Products 
                 60 
                   
                   
                   
                 vinyl acetate 
                 ethylene 
               
               
                   
                 EP17 
               
               
                 24 
                 Polysol 
                 Showa 
                 55 
                   
                   
                   
                 vinyl acetate 
                 ethylene 
               
               
                   
                 EVA550 
                 Denko K.K. 
               
               
                   
               
               
                 *from low-MW alkali-soluble styrene/acrylate copolymer 
               
            
           
         
       
     
     In the case of those latexes with high pH&#39;s and good water and alkaline resistance, it is possible that the latex or a stabilizing dispersing agent is solubilized with ammonium hydroxide and with the evaporation of the ammonia the resins are rendered insoluble. 
     Suitable self-crosslinking resins are given in the Table below. 
     
       
         
           
               
               
               
               
               
               
               
             
               
                   
               
               
                   
                   
                   
                 solids 
                 acid No. 
                   
                   
               
               
                   
                   
                   
                 conc 
                 [mg 
               
               
                 latex No. 
                   
                   
                 [wt %] 
                 KOH/g] 
                 pH 
                 comonomers 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                 25 
                 Acronal 
                 BASF 
                 50 
                   
                 8.5-10 
                 acrylic 
                   
               
               
                   
                 LR 8977 
               
               
                 26 
                 Acronal S 
                 BASF 
                 50 
                   
                 8.5-10 
                 acrylic 
               
               
                   
                 760 
               
               
                 27 
                 Joncryl 
                 BASF 
                 41 
                   
                 8.3 
                 acrylic 
               
               
                   
                 1580 
               
               
                 28 
                 Joncryl 
                 BASF 
                 41 
                   
                 8.2 
                 acrylic 
               
               
                   
                 8380 
               
               
                 29 
                 Joncryl 
                 BASF 
                 40 
                 23 
                 8.1 
                 acrylic 
               
               
                   
                 8383 
               
               
                 30 
                 Joncryl 
                 BASF 
                 41 
                 27 
                 8.2 
                 acrylic 
               
               
                   
                 8384 
               
               
                 31 
                 Joncryl 
                 BASF 
                 49 
                 16 
                 7.9 
                 acrylic 
               
               
                   
                 8385 
               
               
                 32 
                 Joncryl 
                 BASF 
                 40 
                 18 
                 8.0 
                 acrylic 
               
               
                   
                 8386 
               
               
                 33 
                 Joncryl 
                 BASF 
                 43.5 
                 50 
                 9.6 
                 acrylic 
               
               
                   
                 8300 
               
               
                 34 
                 Joncryl 
                 BASF 
                 42 
                 26 
                 7.6 
                 acrylic 
               
               
                   
                 8311 
               
               
                 35 
                 Luhydran 
                 BASF 
                 45 
                 0 
                  1.5-2.5 
                 acrylic 
               
               
                   
                 S 937 T 
               
               
                 36 
                 NeoCryl 
                 DSM Neo- 
                   
                   
                   
                 acrylate 
               
               
                   
                 XK-98 
                 Resins 
               
               
                 37 
                 NeoPac R- 
                 DSM Neo- 
                   
                   
                   
                 aliphatic 
                 hybrid 
               
               
                   
                 9029 
                 Resins 
                   
                   
                   
                 urethane 
               
               
                   
               
            
           
         
       
     
     The mechanism of self-crosslinking is not disclosed. However, one skilled in the art would expect crosslinking to be accompanied by insolubilization. 
     Porous Pigment Particles 
     According to a nineteenth embodiment of the printable paper, according to the present invention, the porous pigment is an inorganic pigment and includes pigments having primary particles having an internal porosity and pigments whose primary particles have no internal porosity and have a specific surface area of at least 100 m 2 /g, which are present as secondary particles having an internal porosity as a result of the aggregation of the primary particles. Examples of such primary particles are flame pyrolyzed inorganic particles such as the particles in the Aerosil® range produced by Degussa. 
     According to a twentieth embodiment of the printable paper, according to the present invention, the at least one porous pigment is an polymeric pigment and includes polymeric pigments having primary particles having an internal porosity and pigments whose primary particles have no internal porosity and have a specific surface area of at least 100 m 2 /g, which are present as secondary particles having an internal porosity as a result of the aggregation of the primary particles. 
     According to a twenty-first embodiment of the printable paper, according to the present invention, the at least one porous pigment is a mixture of at least one inorganic porous pigment and at least one organic polymeric porous pigment. 
     Suitable porous inorganic pigments are given in the table below: 
     
       
         
           
               
               
               
               
               
               
               
               
               
               
             
               
                   
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                 Oil 
                   
               
               
                   
                   
                   
                   
                 Average 
                   
                   
                   
                 absorption 
               
               
                   
                   
                   
                   
                 particle 
                   
                 Pore 
                 Pore 
                 capacity 
               
               
                 PP- 
                   
                   
                 Chemical 
                 size 
                   
                 volume 
                 diameter 
                 [mL/ 
                 Surface 
               
               
                 No. 
                 Product name 
                 Producer 
                 composition 
                 [μm] 
                 pH 
                 [mL/g] 
                 [nm] 
                 100 g] 
                 treatment 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
            
               
                 01 
                 Sunsphere H53 
                 Asahi Glass 
                 SiO 2   
                 5 
                   
                 2 
                 30 
                 400 
                   
               
               
                 02 
                 Sunsphere H33 
                 Asahi Glass 
                 SiO 2   
                 3 
                   
                 2 
                 30 
                 400 
               
               
                 03 
                 Sunsphere H52 
                 Asahi Glass 
                 SiO 2   
                 5 
                   
                 2 
                 25 
                 300 
               
               
                 04 
                 Sunsphere H32 
                 Asahi Glass 
                 SiO 2   
                 3 
                   
                 2 
                 25 
                 300 
               
               
                 05 
                 Sunsphere H52 
                 Asahi Glass 
                 SiO 2   
                 5 
                   
                 2 
                 25 
                 300 
               
               
                 06 
                 Sunsphere H32 
                 Asahi Glass 
                 SiO 2   
                 3 
                   
                 2 
                 25 
                 300 
               
               
                 07 
                 Sunsphere H51 
                 Asahi Glass 
                 SiO 2   
                 5 
                   
                 1 
                 5 
                 150 
               
               
                 08 
                 Sunsphere H31 
                 Asahi Glass 
                 SiO 2   
                 3 
                   
                 1 
                 5 
                 150 
               
               
                 09 
                 Sunsil 130H-SC 
                 Sunjin 
                 SiO 2   
                 7 
                   
                 1.4 
                   
                   
                 methicone 
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 treated 
               
               
                 10 
                 Sunsil 130SH 
                 Sunjin 
                 SiO 2   
                 7 
                   
                 2.2 
                   
                   
                 none 
               
               
                 11 
                 Sunsil 130XH 
                 Sunjin 
                 SiO 2   
                 7 
                   
                 3.0 
                   
                   
                 none 
               
               
                 12 
                 Syloid C803 
                 Grace- 
                 SiO 2   
                 3.4-4.0 
                 2.9-3.7 
                 2.0 
                   
                   
                 none 
               
               
                   
                   
                 Davison 
               
               
                 13 
                 Syloid C807 
                 Grace- 
                 SiO 2   
                 6.7-7.9 
                 2.9-3.7 
                 2.0 
                   
                   
                 none 
               
               
                   
                   
                 Davison 
               
               
                 14 
                 Syloid C2006 
                 Grace- 
                 SiO 2   
                 5.4-6.6 
                 3.5 
                 2.0 
                   
                   
                 20% 
               
               
                   
                   
                 Davison 
                   
                   
                   
                   
                   
                   
                 special 
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 organic 
               
               
                 13 
                 Syloid ED2 
                 Grace- 
                 SiO 2   
                   3.9 
                 6.0 
                   
                   
                   
                 none 
               
               
                 15 
                   
                 Davison 
               
               
                 16 
                 Syloid ED5 
                 Grace- 
                 SiO 2   
                  8.4-10.2 
                 6.0-8.5 
                 1.8 
                   
                   
                 none 
               
               
                   
                   
                 Davison 
               
               
                 17 
                 Syloid W500 
                 Grace- 
                 SiO 2   
                 7.8-9.4 
                 8.7-9.7 
                 1.2 
                   
                   
                 none 
               
               
                   
                   
                 Davison 
               
               
                 18 
                 Syloid W300 
                 Grace- 
                 SiO 2   
                 5.3-6.3 
                 8.7-9.7 
                 1.2 
                   
                   
                 none 
               
               
                   
                   
                 Davison 
               
               
                 19 
                 Syloid 72 
                 Grace- 
                 SiO 2   
                 4.5-5.7 
                 6.0-8.0 
                 1.2 
                   
                   
                 npne 
               
               
                   
                   
                 Davison 
               
               
                 20 
                 Syloid 74 
                 Grace- 
                 SiO 2   
                 5.9-7.5 
                 6.0-8.0 
                 1.2 
                   
                   
                 none 
               
               
                   
                   
                 Davison 
               
               
                 21 
                 Syloid 244 
                 Grace- 
                 SiO 2   
                 2.5-3.7 
                 6.0-8.0 
                 1.6 
                   
                   
                 none 
               
               
                   
                   
                 Davison 
               
               
                 22 
                 Spheron L1500 
                 CCIC/Ikeda 
                 SiO 2   
                  3-15 
                   
                 1.46 
               
               
                 23 
                 Spheron P1500 
                 CCIC/Ikeda 
                 SiO 2   
                 7 
                   
                 0.65-0.7 
               
               
                 24 
                 ZeeoSphere G200 
                 3M 
                 SiO 2 ; 
                 5 
                 &gt;3     
                   
                   
                 70 
               
               
                   
                   
                   
                 Al 2 O 3   
               
               
                 25 
                 Micral 9400 
                 J. M. Huber 
                 Al(OH) 3   
               
               
                 26 
                 Digitex 1000 
                 Engelhard 
                 Kaolin- 
               
               
                   
                   
                 Industries 
                 based 
               
               
                   
                   
                   
                 pigment 
               
               
                 27 
                 Syloid SP500- 
                 Grace- 
                 SiO 2   
               
               
                   
                 11007 
                 Davison 
               
               
                   
               
            
           
         
       
     
     Suitable porous polymeric pigments are given in the table below: 
     
       
         
           
               
               
               
               
               
               
               
               
               
             
               
                   
               
               
                   
                   
                   
                   
                 Average 
                   
                   
                   
                 Oil absorption 
               
               
                   
                   
                   
                   
                 particle 
                   
                 Pore 
                 Pore 
                 capacity 
               
               
                 PP- 
                   
                   
                 Chemical 
                 size 
                   
                 volume 
                 diameter 
                 [mL/ 
               
               
                 No. 
                 Product name 
                 Producer 
                 composition 
                 [μm] 
                 pH 
                 [mL/g] 
                 [nm] 
                 100 g] 
               
               
                   
               
             
            
               
                 28 
                 Submicron Filler 
                 Nippon Kasei 
                 urea-form- 
                 1-8# 
                   
                   
                   
                 500-1000 
               
               
                   
                   
                   
                 aldehyde 
               
               
                   
                   
                   
                 resin 
               
               
                 29 
                 Micropearl 
                 Matsumoto 
                 PMMA 
                 4.3 
                   
                 0.45 
               
               
                   
                 M305 
               
               
                 30 
                 Covabead 
                 LCW 
                 PMMA 
                 7.2 
                   
                 1.7  
               
               
                   
                 LH170 
               
               
                 31 
                 Sunpmma-PH 
                 Sunjin 
                 PMMA 
                 8 
                   
                 2.3-2.6 
                 17 
                 2.2 
               
               
                 32 
                 Deuteron OG874 
                 Deuteron 
                 ground 
                   
                 8.0 
               
               
                   
                   
                   
                 polymethylurea 
               
               
                 33 
                 Pergopak M6 
                 Albemarle 
                 polymethylurea 
                 0.3* 
               
               
                 34 
                 Pergopak HP 
                 Albemarle 
                 polymethylurea 
                 0.125* 
               
               
                   
               
               
                 #primary particle size 0.1-0.3 μm 
               
               
                 *primary particle size 
               
            
           
         
       
     
     Porosity can be determined by standard techniques such as nitrogen porosimetry, in which nitrogen is condensed in the pores and calculating the pore volumes from the quantities of gas required to fill the pores, and mercury porosimetry, in which liquid mercury is forced into pores by increasing the external pressure, the amount of mercury required to fill the pores being increased incrementally. 
     Opacifying Pigments 
     According to a twenty-second embodiment of the printable paper, according to the present invention, the single layer further comprises at least one opacifying pigment. 
     Suitable opacifying pigments are given in the table below: 
     
       
         
           
               
               
               
               
               
               
               
               
               
               
             
               
                   
               
               
                   
                   
                   
                   
                   
                   
                   
                   
                 Oil 
                   
               
               
                   
                   
                   
                   
                 Average 
                   
                   
                   
                 absorption 
               
               
                   
                   
                   
                   
                 particle 
                   
                 Pore 
                 Pore 
                 capacity 
               
               
                 OP- 
                   
                   
                 Chemical 
                 size 
                   
                 volume 
                 diameter 
                 [mL/ 
                 Surface 
               
               
                 No. 
                 Product name 
                 Producer 
                 composition 
                 [μm] 
                 pH 
                 [mL/g] 
                 [nm] 
                 100 g] 
                 treatment 
               
               
                   
               
             
            
               
                 01 
                 SpaceRite S-11 
                 Almatis 
                 Al(OH) 3   
                 0.25-0.31 
                 9.8 
                   
                   
                 24-28 
                   
               
               
                 02 
                 Pural BT 
                 Sasol 
                 Al(OH) 3   
                 5 
               
               
                 03 
                 Carbital 110 
                 Zinchem 
                 CaCO 3   
                 2 
               
               
                 04 
                 Carbital 120 
                 Zinchem 
                 CaCO 3   
                 5 
               
               
                 05 
                 Jetcoat 30 
                 Specialty 
                 CaCO 3   
                   
                 7.0 
               
               
                   
                   
                 Minerals 
                 slurry 
               
               
                 06 
                 VPR350ME 
                 SA Omya 
                 CaCO 3   
                   
                 6.5 
               
               
                   
                   
                 Benelux 
                 anionic 
               
               
                   
                   
                   
                 slurry 
               
               
                 07 
                 China Clay 
                 Engelhard 
                 China Clay 
                 0.4 
                 3.5-5.0  
               
               
                   
                 Pigment ASP200 
                 Industries 
               
               
                 08 
                 China Clay Grade B 
                 Zinchem 
                 China Clay 
                 2 
               
               
                 09 
                 Snowtex 
                 Nissan 
                 colloidal 
                 10-20 nm 
                 9.0-10.5 
               
               
                   
                   
                 Chemical 
                 SiO 2   
               
               
                 10 
                 Hydragloss 90 
                 J. M. Huber 
                 fine 
               
               
                   
                   
                   
                 glossing 
               
               
                   
                   
                   
                 coating clay 
               
               
                 11 
                 ArtNo.. 102143 
                 Merck 
                 Ca 5 (PO 4 ) 3 OH 
               
               
                 12 
                 VITOSS 
                 Orthovita 
                 Ca 3 (PO 4 ) 2   
                 0.1* 
               
               
                 13 
                 Kronos 2059 
                 Kronos 
                 TiO 2   
                   
                 7.0 
                   
                   
                 18-21 
               
               
                 14 
                 Ti Pure R900 
                 Du Pont 
                 TiO 2   
                 4 
                 7.3 
               
               
                 15 
                 Finntitan RD5 
                 Keyser &amp; 
                 TiO 2   
                 0.21 
                 7.5 
                   
                   
                 19 
               
               
                   
                   
                 Mackay 
               
               
                   
               
            
           
         
       
     
     Water-Soluble Binder 
     According to a twenty-third embodiment, of the printable paper, according to the present invention, the single layer further comprises at least one water-soluble binder. 
     According to a twenty-fourth embodiment, of the printable paper, according to the present invention, the water-soluble binder is a hydrolyzed polymer or copolymer of a vinylester. 
     According to a twenty-fifth embodiment, of the printable paper, according to the present invention, the water-soluble binder is a hydrolyzed polymer or copolymer of vinyl acetate, with a degree of hydrolysis of at least 85% being preferred, and a degree of hydrolysis of at least 87% being particularly preferred. 
     Suitable water-soluble binders include the hydrolyzed polyvinyl acetates given in the table below. 
     
       
         
           
               
               
               
             
               
                   
                   
               
               
                   
                 Degree of 
                 Residual acetyl 
               
               
                   
                 hydrolysis 
                 (Vinyl acetate) 
               
               
                   
                 [mol %] 
                 content [wt %] 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
            
               
                 B01 
                 Erkol 48 20 
                 ACETEX 
                 97.5-99.5 
                   
               
               
                 B02 
                 Mowiol 10-74 
                 Kuraray 
                 74   
               
               
                   
                   
                 Specialties 
               
               
                   
                   
                 Europe (KSE) 
               
               
                 B03 
                 Airvol 350 
                 Air Products 
                 97.5-99.5 
               
               
                 B04 
                 Airvol 540 
                 Air Products 
                 87-88 
               
               
                 B05 
                 Mowiol 15-79 
                 KSE 
                 81.5 
                 15.4 
               
               
                 B06 
                 Mowiol 3-83 
                 KSE 
                 82.6 
                 14.6 
               
               
                 B07 
                 Mowiol 4-88 
                 KSE 
                 87.7 
                 10.8 
               
               
                 B08 
                 Mowiol 5-88 
                 KSE 
                 87.7 
                 10.8 
               
               
                 B09 
                 Mowiol 8-88 
                 KSE 
                 87.7 
                 10.8 
               
               
                 B10 
                 Mowiol 18-88 
                 KSE 
                 87.7 
                 10.8 
               
               
                 B11 
                 Mowiol 23-88 
                 KSE 
                 87.7 
                 10.8 
               
               
                 B12 
                 Mowiol 26-88 
                 KSE 
                 87.7 
                 10.8 
               
               
                 B13 
                 Mowiol 40-88 
                 KSE 
                 87.7 
                 10.8 
               
               
                 B14 
                 Mowiol 47-88 
                 KSE 
                 87.7 
                 10.8 
               
               
                 B15 
                 Mowiol 30-92 
                 KSE 
                 92.4 
                 6.9 
               
               
                 B16 
                 Mowiol 3-96 
                 KSE 
                 97.2 
                 2.7 
               
               
                 B17 
                 Mowiol 3-98 
                 KSE 
                 98.4 
                 1.5 
               
               
                 B18 
                 Mowiol 6-98 
                 KSE 
                 98.4 
                 1.5 
               
               
                 B19 
                 Mowiol 10-98 
                 KSE 
                 98.4 
                 1.5 
               
               
                 B20 
                 Mowiol 20-98 
                 KSE 
                 98.4 
                 1.5 
               
               
                 B21 
                 Mowiol 56-98 
                 KSE 
                 98.4 
                 1.5 
               
               
                 B22 
                 Mowiol 28-99 
                 KSE 
                 99.4 
                 0.6 
               
               
                 B23 
                 Poval PVA 203 
                 Kuraray 
                 88.0 
               
               
                 B24 
                 Poval PVA 205 
                 Kuraray 
                 87.8 
               
               
                 B25 
                 Poval PVA 217 
                 Kuraray 
                 88.0 
               
               
                 B26 
                 Poval PVA 220 
                 Kuraray 
                 88.0 
               
               
                 B27 
                 Poval PVA 224 
                 Kuraray 
                 88.0 
               
               
                 B28 
                 Poval PVA 226 
                 Kuraray 
                 87.5 
               
               
                 B29 
                 Poval PVA 235 
                 Kuraray 
                 88.0 
               
               
                 B30 
                 Poval PVA 403 
                 Kuraray 
                 80.0 
               
               
                 B31 
                 Poval PVA 405 
                 Kuraray 
                 81.5 
               
               
                 B32 
                 Poval PVA 420 
                 Kuraray 
                 79.5 
               
               
                 B33 
                 Poval PVA CST 
                 Kuraray 
                 96.0 
               
               
                 B34 
                 Poval PVA 613 
                 Kuraray 
                 93.5 
               
               
                 B35 
                 Poval PVA 624 
                 Kuraray 
                 95.5 
               
               
                 B36 
                 Poval PVA 706 
                 Kuraray 
                 91.5 
               
               
                 B37 
                 Poval PVA 103 
                 Kuraray 
                 98.5 
               
               
                 B38 
                 Poval PVA 105 
                 Kuraray 
                 98.5 
               
               
                 B39 
                 Poval PVA 110 
                 Kuraray 
                 98.5 
               
               
                 B40 
                 Poval PVA 117 
                 Kuraray 
                 98.5 
               
               
                 B41 
                 Poval PVA 124 
                 Kuraray 
                 98.5 
               
               
                   
               
            
           
         
       
     
     Hardened Polyhydroxy-Resin 
     According to a twenty-sixth embodiment, of the printable paper, according to the present invention, the single layer further comprises at least one hardened initially water-soluble polyhydroxy resin. 
     According to a twenty-seventh embodiment of the present invention, the single layer further contains a hardened hydrolyzed polymer or copolymer of a vinyl ester e.g. by the hardening of POVAL R1130, a silanol modified polyvinyl alcohol. 
     Suitable water-soluble polyhydroxy resins include hydrolyzed polymers or copolymers of a vinylester; cellulose and cellulose derivatives; polysaccharides; and polyalkylene glycols. 
     Suitable hardeners include polyisocyanates, hydrolyzed polyalkoxysilanes e.g. tetraalkyl orthosilicates. 
     Insolubilization Agents 
     Insolubilization is a process in which either a solublization process is reversed e.g. by pH reduction if a pH-change brings about solublization e.g. by conversion of a carboxy group into a carboxylate ion e.g. by acidification or simple evaporation of ammonia if ammonium hydroxide is used to realize the solubilization. Such solubilization can apply to a latex or to a dispersing agent stabilizing a latex dispersion. Alternatively insolublization can be the addition of an insolubilizing agent such as formaldehyde, glutaraldehyde, glyoxal, glyoxal-derivatives, dimethylol urea, polyanionic metallic compounds (see GB 2177413A at page 2, line 5) and melamine-formaldehyde resins and carboxylic acid anhydrides which contain a plurality of anhydride moieties on each molecular entity (see U.S. Pat. No. 6,300,393). These insolubilization agents can catalyze, initiate a reaction with, complex with, cure or otherwise react with the species being insolubilized. Moreover, the insolubilizing agent may require activation in order for it to acquire insolubilizing properties e.g. by heating, exposure to electromagnetic radiation e.g. light, X-rays, electron beams etc., a change in pH or any other means. 
     According to a twenty-eighth embodiment of the printable paper, according to the present invention, the single layer further comprises at least one insolubilizing agent unless said latex is solubilized with ammonium hydroxide. 
     According to a twenty-ninth embodiment of the printable paper, according to the present invention, the single layer further comprises at least one insolubilizing agent selected from the group consisting of: polyisocyanates, formaldehyde, formaldehyde derivatives, glutaraldehyde, glyoxal, glyoxal-derivatives, dimethylol urea, polyanionic metallic compounds and melamine-formaldehyde resins, polyalkoxysilanes (e.g. tetraalkyl orthosilicates), and carboxylic acid anhydrides which contain a plurality of anhydride moieties on each molecular entity. 
     Suitable insolubilizing agents include: 
     
       
         
           
               
               
             
               
                   
               
             
            
               
                 IN01: 
                 Bayhydur 3100, a hydrophilic aliphatic isocyanate based on hexamethylene 
               
               
                   
                 diisocyanate (HDI from Bayer 
               
               
                 IN02: 
                 Parez Resin 707, a dimethylol trimethylolmelamine formaldehyde resin from 
               
               
                   
                 Am Cyanamid 
               
               
                 IN03: 
                 Irgacure 500, a hydrophilic aliphatic isocyanate based on hexamethylene 
               
               
                   
                 diisocyanate (HDI from Bayer 
               
               
                 IN04: 
                 Bayhydur XP2547, a hydrophilic aliphatic isocyanate based on 
               
               
                   
                 hexamethylene diisocyanate (HDI from Bayer 
               
               
                 IN05: 
                 Irgacure 819DW, a UV-initiator from CIBA 
               
               
                 IN06: 
                 Irgacure 500, a UV-initiator from CIBA 
               
               
                 IN07: 
                 Berset ® 2115*, a glyoxal-based reactant as a light straw-coloured liquid (46- 
               
               
                   
                 48 wt %) from Bercen, Inc. 
               
               
                 IN08: 
                 Berset ® 2116*, a glyoxal-based reactant as a clear straw-coloured liquid (49- 
               
               
                   
                 51 wt %) from Bercen, Inc. 
               
               
                 IN09: 
                 Berset ® 2125*, a glyoxal-based reactant as a light straw-coloured liquid (67- 
               
               
                   
                 69 wt %) from Bercen, Inc. 
               
               
                 IN10: 
                 Berset ® 2185*, a glyoxal-based reactant from Bercen, Inc. 
               
               
                 IN11: 
                 Berset ® 2506*, a melamine-formaldehyde resin as a clear to slightly hazy 
               
               
                   
                 liquid (69-71 wt %) from Bercen, Inc. 
               
               
                 IN12: 
                 Berset ® 2700*, a cyclic amide condensate as a clear amber solution (44-46 
               
               
                   
                 wt %) from Bercen, Inc. 
               
               
                 IN13: 
                 Berset ® 2720*, a ammonium zirconium carbonate as a clear to slightly hazy 
               
               
                   
                 solution (30.5-33.5 wt %)# from Bercen, Inc. 
               
               
                 IN14: 
                 Berset ® 2750*, a potassium zirconium carbonate as a clear to slightly hazy 
               
               
                   
                 solution (45-50 wt %) from Bercen, Inc. 
               
               
                   
               
               
                 *supplied by 
               
               
                 #also available from Magnesium Elektron Ltd., Twickenham, England. 
               
            
           
         
       
     
     Matting Agents 
     According to a thirtieth embodiment of the printable paper, according to the present invention, the single layer further comprises a matting agent. 
     Suitable matting agents are given in the table below: 
     
       
         
           
               
               
             
               
                   
               
             
            
               
                 MA01: 
                 a 7-8 μm grafted polymethylmethacrylate matting agent 
               
               
                 MA02: 
                 a 3-12 μm polyethylene wax 
               
               
                 MA03: 
                 Syloid C907, 7 μm silica particles from Grace-Davison 
               
               
                 MA04: 
                 Pergopak M, 6-20 μm polymethylurea particles from Albemarle 
               
               
                 MA05: 
                 Syloid SP4-9701, 11 μm silica particles from Grace-Davison 
               
               
                 MA06: 
                 PMMA 10, 10 μm polymethylmethacrylate particles from H. W. 
               
               
                   
                 Sands 
               
               
                 MA07: 
                 PMMA 10TIGHT, 10 μm crosslinked polymethylmethacrylate 
               
               
                   
                 particles from H. W. Sands 
               
               
                 MA08: 
                 EPOSTAR L15, 10-15 μm benzoguanine-melamine/ 
               
               
                   
                 formaldehyde particles from Nippon Shokubai 
               
               
                 MA09: 
                 Orgasol 3501 EXD NAT1, 10 μm polyamide particles from 
               
               
                   
                 Atochem S.A. 
               
               
                 MA10: 
                 Flo Beads EA209, 10 μm ethylene-acylic acid copolymer 
               
               
                   
                 particles from Sumitomo, 
               
               
                 MA11: 
                 Flo Beads CL2080, 12.5 μm polyethylene particles from 
               
               
                   
                 Sumitomo 
               
               
                 MA12: 
                 Tospearl 3120, 12 μm polydimemylsiloxane particles from 
               
               
                   
                 Toshiba 
               
               
                 MA15 
                 a 6 μm grafted polymethylmethacrylate matting agent 
               
               
                   
               
            
           
         
       
     
     Preservative 
     According to a thirty-first embodiment of the printable paper, according to the present invention, the single layer further comprises a preservative. The purpose of a preservative is to act as a bactericide and fungicide to prevent the growth of mould. 
     According to a thirty-second embodiment of the printable paper, according to the present invention, further comprises a salt of 1,2-benzisothiazolin-3-one e.g. the sodium salt of 1,2-benzisothiazolin-3-one commercially available under the trade name “Proxel” and Bronidox K. 
     Process for Producing a Printable Paper 
     Aspects of the present invention are realized by a process for producing a printable paper comprising the steps of: (i) optionally providing a water-resistant support having two sides with a subbing layer on at least one side; (ii) providing at least one side of said optionally subbed water-resistant support with a single layer having no substantial compositional variation, said single layer being applied to said optionally subbed water-resistant support as at least one wet aqueous layer in a single pass for each side of said water-resistant support, said at least one aqueous layer comprising at least one latex, at least one pigment, at least one binder and optionally at least one insolubilizing agent, wherein said latex is an anionic acrylic latex or an aliphatic polyurethane latex. 
     Industrial Application 
     Non-transparent microvoided axially stretched films, according to the present invention, can be used as synthetic paper for printing and other applications, as a relector in LCD displays and photovoltaic devices, as a support for imaging materials e.g. impact and non-impact (e.g. electrophotography, electrography and ink jet) receiving materials, photothermographic recording materials, substantially light-insensitive thermographic recording materials, dye sublimation printing, thermal transfer printing, etc., in security and anti-counterfeiting applications e.g. in tickets, labels, tags, an ID-card, a bank card, a legal document, banknotes and packaging and can also be integrated into packaging. 
     The invention is illustrated hereinafter by way of comparative examples and examples. The percentages and ratios given in these examples are by weight unless otherwise indicated. 
     Ingredients Used in the Examples and Comparative Examples: 
     Slipping Agents: 
     SL01: Tegoglide 482 a 65% by weight aqueous emulsion of a high molecular weight polydimethylsiloxane surfactant from Goldschmidt 
     Surfactants: 
     S01: Synperonic 91/5, an alcohol ethoxylate with the composition C 9-11 H 19-23 O—(C 2 H 4 O) 5 H from Uniqema; 
     S02: MERSOLAT®H, a sodium pentadecylsulfonate from BAYER; 
     S03: ULTRAVON®W, a sodium arysulfonate from CIBA [UVONAC]; 
     S04: DR247 
     S05: Arkopon T, a sodium salt of N-methyl-N-2-sulfoethyl-oleylamide supplied as a 40% concentrate by Avecia [OTIK]; 
     S06: Envirogem AE01 a 100% mixture of esters from Air Products 
     S07: Zonyl FSO100 a mixture of ethoxylated non-ionic fluoro-surfactant from DuPont with the formula:
 
F(CF 2 CF 2 ) 1-7 CH 2 CH 2 —O—(CH 2 CH 2 O) y H where y=0 to ca. 15 from DuPont
 
     Polyester: 
     
       
         
           
               
               
               
               
               
               
             
               
                   
               
               
                   
                   
                   
                 MFI 270° C./ 
                 Inherent 
                   
               
               
                 PET- 
                   
                   
                 1.20 kg 
                 viscosity** 
                 T g   
               
               
                 No. 
                   
                   
                 [cm 3 /10 min] 
                 [η] [dl/g] 
                 [° C.] 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
            
               
                 01 
                 T03* 
                 polyethylene terephthalate 
                 34.8 
                 0.60 
                 80.5 
               
               
                 02 
                 T04* 
                 polyethylene terephthalate 
                 34.8 
                 0.60 
                 80.5 
               
               
                 03 
                 WP75# 
                 polyester of 98.5 mol % 
                   
                 0.77 
                 80 
               
               
                   
                   
                 terephthalate, 1.5 mol % 
               
               
                   
                   
                 isophthalate and 100 mol % 
               
               
                   
                   
                 ethylene units 
               
               
                 04 
                 DP9990# 
                 polyester of 90 mol % 
                   
                 0.60 
               
               
                   
                   
                 terephthalate, 10 mol % 
               
               
                   
                   
                 isophthalate and 100 mol % 
               
               
                   
                   
                 ethylene units 
               
               
                   
               
               
                 *AGFA-GEVAERT N.V. 
               
               
                 #La Seda 
               
               
                 **inherent viscosity was determined in a 0.5 g/dL solution of 60 wt % phenol and 40 wt % ortho-dichlorobenzene at 25° C. in an Ubbelohde viscometer 
               
            
           
         
       
     
     Styrene-Acrylonitrile Copolymers: 
     
       
         
           
               
               
               
               
               
               
               
               
             
               
                   
               
               
                   
                   
                 Wt % 
                   
                 MFI at 
                   
                   
                   
               
               
                 SAN- 
                   
                 acrylo- 
                 Wt % 
                 270° C./1.20 kg 
               
               
                 No. 
                   
                 nitrile 
                 styrene 
                 [mL/10 min] 
                 Mn 
                 Mw 
                 T g  [° C.] 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                 01 
                 TYRIL 905* 
                 20 
                 80 
                 7.1 
                   
                   
                 105.2 
               
               
                 02 
                 TYRIL 867E* 
                 25 
                 75 
                 5.8 
                   
                   
                 106.5 
               
               
                 03 
                 SAN 140* 
                 27.5 
                 72.5 
                 53.2 
                 47,640 
                 99,820 
                 108.8 
               
               
                 04 
                 LURAN 368R# 
                 28 
                 72 
                 3.9 
                   
                   
                 107.3 
               
               
                 05 
                 TYRIL 790* 
                 29 
                 71 
                 12.1 
                   
                   
                 106.3 
               
               
                 06 
                 SAN 124* 
                 28.5 
                 71.5 
                 37.9 
                 53,940 
                 109,350 
                 108.1 
               
               
                 07 
                 LURAN 388S# 
                 33 
                 67 
                 3.6 
                   
                   
                 108.7 
               
               
                   
               
               
                 *DOW CHEMICAL 
               
               
                 #BASF 
               
               
                 MFI = Melt Flow Index 
               
            
           
         
       
     
     TITANIUM DIOXIDE: Renol-white/PTX 506, a masterbatch from CLARIANT GmbH containing 65% by weight TiO 2  and 35 wt % polyester 
     TPX DX820: a high rigidity isotactic poly(4-methyl-1-pentene) from MITSUI CHEMICAL 
     Examples 1 and 2 
     Production of Subbed Supports 
     A ca. 1100 μm thick extrudate with the composition given in Table 1 below was biaxially stretched according to the conditions given in Table 2 to provide a non-transparent microvoided biaxially stretched self-supporting film with a thickness of 150 μm. 
     
       
         
           
               
               
               
               
               
               
               
               
             
               
                 TABLE 1 
               
               
                   
               
               
                   
                   
                   
                   
                   
                   
                   
                 UVITEX 
               
               
                 EXAMPLE 
                 IPA:TPA 
                 PET02 
                 PET04 
                 SAN 06 
                 TiO 2   
                 TPX 820 
                 OB-one 
               
               
                 No. 
                 ratio 
                 [wt %] 
                 [wt %] 
                 [wt %] 
                 [wt %] 
                 [wt %] 
                 [wt %] 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                 1 
                 0.0769 
                 23.734 
                 59.30 
                 15.00 
                 1.95 
                 — 
                 0.0260 
               
               
                 2 
                 0.0769 
                 23.613 
                 59.00 
                 14.92 
                 1.945 
                 0.497 
                 0.0259 
               
               
                   
               
            
           
         
       
     
     
       
         
           
               
               
               
               
             
               
                   
                 TABLE 2 
               
             
            
               
                   
                   
               
               
                   
                 Longitudinal 
                 Transversal 
                   
               
               
                   
                 stretching 
                 stretch 
               
            
           
           
               
               
               
               
               
               
               
            
               
                 EXAMPLE 
                   
                 force 
                 temperature 
                   
                 speed 
                 Density 
               
               
                 No. 
                 ratio 
                 [N/mm 2 ] 
                 [° C.] 
                 ratio 
                 [%/min] 
                 [g/mL) 
               
               
                   
               
               
                 1/LS1/BS1 
                 3.3 
                 12 
                 110 
                 3.5 
                 1000 
                 1.2 
               
               
                 2/LS1/BS1 
                 3.3 
                 12 
                 110 
                 3.5 
                 1000 
                 1.2 
               
               
                   
               
            
           
         
       
     
     The non-transparent microvoided biaxially stretched self-supporting films 1/LS1/BS1 and 2/LS1/BS1 were then subbed with subbing layers 1, a non-antistatic layer, subbing layer 2, an antistatic subbing layer composition, subbing layer 3, an antistatic subbing layer composition, subbing layer 4, a non-antistatic layer composition or subbing layer 5, an antistatic layer composition, on one or both sides of the support: 
     Subbing Layer 1: 
                                         coverage in           dried layer           [mg/m 2 ]                                            copolymer of 88% vinylidene chloride, 10% methyl   79.1       acrylate and 2% itaconic acid       Kieselsol ® 100F, a colloidal silica from BAYER   18.6       Surfactant No. 2, an anionic surfactant   0.4       Surfactant No. 3, an anionic surfactant   1.9                    
Subbing Layer 2:
 
                                         coverage in           dried layer           [mg/m 2 ]                                                    poly(3,4-ethylenedioxythiophene)/polystyrene   2.58           sulphonic acid (1:2.46 by weight)           Bronidox K   0.02           copolymer of 88% vinylidene chloride, 10%   147.3           methyl acrylate and 2% itaconic acid stabilized           with surfactant S05           Kieselsol ® 100F, a colloidal silica from BAYER   16.4           sorbitol   [24.7*]           Surfactant S02, an anionic surfactant   0.74                       *will substantially evaporate/sublime during the drying process            
Subbing Layer 3:
 
                                             wt % solids   coverage in           in coating   dried layer           dispersion   [mg/m 2 ]                                                poly(3,4-ethylenedioxythiophene)/   6.01    2.838       polystyrene sulphonic acid (1:2.46       by weight)       sorbitol   28.06   [13*]         Proxel Ultra 5   0.03   0.01       Surfactant S01, a non-ionic surfactant   1.66   0.78       a terephthalic acid, isophthalic acid,   64.24   30.2        5-sulfo-isophthalic acid, ethylene glycol       (53:40:7:100 molar ratio) copolyester               *will substantially evaporate/sublime during the drying process            
Subbing Layer 4:
 
                                         coverage in           dried layer           [mg/m 2 ]                                            copolymer of 88% vinylidene chloride, 10% methyl   80.85       acrylate and 2% itaconic acid stabilized with       surfactant S05       Kieselsol ® 100F, a colloidal silica from BAYER   18.75       Surfactant S02, an anionic surfactant   0.4                    
Subbing Layer 5:
 
     
       
         
           
               
               
               
             
               
                   
                   
               
               
                   
                 wt % solids 
                 coverage in 
               
               
                   
                 in coating 
                 dried layer 
               
               
                   
                 dispersion 
                 [mg/m 2 ] 
               
               
                   
                   
               
             
            
               
                   
               
            
           
           
               
               
               
            
               
                 poly(3,4-ethylenedioxythiophene)/ 
                 1.30 
                 4.69 
               
               
                 polystyrene sulphonic acid (1:2.46 
               
               
                 by weight) 
               
               
                 copolymer of 88% vinylidene chloride, 10% 
                 82.16 
                 294.54 
               
               
                 methyl acrylate and 2% itaconic acid 
               
               
                 stabilized with surfactant S05 
               
               
                 Kieselsol 100F-30, a colloidal silca from 
                 9.13 
                 32.72 
               
               
                 BAYER 
               
               
                 Surfactant S02, an anionic surfactant 
                 0.30 
                 0.11 
               
               
                 glucose 
                 6.94 
                 [24.9*] 
               
               
                 Proxel Ultra 5 
                 0.005 
                 0.03 
               
               
                 sorbitol 
                 0.16 
                 [0.57*] 
               
               
                   
               
               
                 *will substantially evaporate/sublime during the drying process 
               
            
           
         
       
     
     Optimalization of the Receiving Layer Composition 
     Example 3 
     Screening of Different Latexes 
     The non-transparent microvoided biaxially stretched self-supporting films 1/LS1/BS1 coated with subbing layer 1 was coated with the compositions in Table 3 in the case of EXAMPLES 3/1 to 3/3 together with small quantities of Tego Glide 482, a high molecular weight polydimethylsiloxane from Goldschmidt, and the surfactant S04; in the case of EXAMPLES 3/4 to 3/8 just with quantities of the surfactant S04; in the case of EXAMPLES 3/9 to 3/19 with a mixture of two surfactants (S04 and S05); in the case of EXAMPLES 3/20 to 3/28 with a mixture of two surfactants (S05 and S06); in the case of EXAMPLES 3/26; in the case of EXAMPLES 3/27 to 3/31 without further additives; and in the case of EXAMPLES 3/32 to 3/38 with a mixture of two surfactants (S05 and S06). 
     
       
         
           
               
               
               
               
               
               
             
               
                   
                 TABLE 3 
               
             
            
               
                   
                   
               
               
                   
                 Porous 
                   
                 Wt ratio 
                   
                 printing properties 
               
            
           
           
               
               
               
               
               
               
               
            
               
                   
                 pigment 
                 Latex 
                 porous 
                   
                 dry 
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
            
               
                 Example 
                   
                 coverage 
                   
                 coverage 
                 pigment 
                 ballpen 
                 time 
                   
                   
               
               
                 No. 
                 No. 
                 [mg/m 2 ] 
                 No. 
                 [g/m 2 ] 
                 to latex 
                 writability 
                 [min] 
                 set-off 
                 mottle 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
            
               
                 3/1 
                 PP21 
                 760 
                 01 
                 2000 
                 0.380 
                 repulsion in 
                   
                   
                   
               
               
                   
                   
                   
                   
                   
                   
                 centre 
               
               
                 3/2 
                 PP21 
                 760 
                 PAZ 
                 2000 
                 0.380 
                 v. good 
               
               
                 3/3 
                 PP21 
                 760 
                 02 
                 2000 
                 0.380 
                 good 
               
               
                 3/4 
                 PP21 
                 762 
                 01 
                 2031 
                 0.375 
                 good 
               
               
                 3/5 
                 PP21 
                 762 
                 02 
                 2031 
                 0.375 
                 repulsion in 
               
               
                   
                   
                   
                   
                   
                   
                 centre 
               
               
                 3/6 
                 PP21 
                 762 
                 MS16826 
                 2031 
                 0.375 
                 good 
                 5 
                 no 
               
               
                 3/7 
                 PP21 
                 762 
                 MS5291 
                 2031 
                 0.375 
                 repulsion in 
               
               
                   
                   
                   
                   
                   
                   
                 centre 
               
               
                 3/8 
                 PP21 
                 762 
                 L23 
                 2031 
                 0.375 
                 — 
                 5 
                 no 
               
               
                 3/9 
                 PP21 
                 762 
                 01 
                 2031 
                 0.375 
                 repulsion in 
                   
                 strong 
                 yes 
               
               
                   
                   
                   
                   
                   
                   
                 centre 
               
               
                 3/10 
                 PP21 
                 2031 
                 01 
                 2031 
                 1.00 
                 good 
                   
                 no 
                 slight 
               
               
                 3/11 
                 PP21 
                 1500 
                 01 
                 2031 
                 0.739 
                 moderate 
                   
                 no 
                 slight 
               
               
                   
                   
                   
                   
                   
                   
                 density 
               
               
                 3/12 
                 PP21 
                 762 
                 L24 
                 2031 
                 0.375 
                 v. moderate 
                   
                 yes 
                 strong 
               
               
                   
                   
                   
                   
                   
                   
                 density 
               
               
                 3/13# 
                 PP21 
                 1500 
                 L24 
                 2031 
                 0.739 
                 good 
                   
                 no 
                 slight 
               
               
                 3/14 
                 PP21 
                 762 
                 L23 
                 2031 
                 0.375 
                 repulsion in 
                   
                 no 
                 slight 
               
               
                   
                   
                   
                   
                   
                   
                 centre 
               
               
                 3/15# 
                 PP21 
                 1500 
                 L23 
                 2031 
                 0.739 
                 repulsion in 
                   
                 no 
                 no 
               
               
                   
                   
                   
                   
                   
                   
                 centre 
               
               
                 3/16 
                 PP21 
                 762 
                 04 
                 2031 
                 0.375 
                 repulsion in 
                   
                 strong 
                 yes 
               
               
                   
                   
                   
                   
                   
                   
                 centre 
               
               
                 3/17 
                 PP21 
                 1500 
                 04 
                 2031 
                   
                 v. good 
                   
                 yes 
                 yes 
               
               
                 3/18 
                 PP21 
                 762 
                 05 
                 2031 
                 0.375 
                 repulsion in 
                   
                 strong 
                 yes 
               
               
                   
                   
                   
                   
                   
                   
                 centre 
               
               
                 3/19 
                 PP21 
                 1500 
                 05 
                 2031 
                 0.739 
                 repulsion in 
                   
                 no 
                 no 
               
               
                   
                   
                   
                   
                   
                   
                 centre 
               
               
                 3/20 
                 PP21 
                 990 
                 01 
                 2010 
                 0.491 
                 repulsion in 
                   
                 slight 
                 yes 
               
               
                   
                   
                   
                   
                   
                   
                 centre 
               
               
                 3/21* 
                 PP21 
                 990 
                 L23 
                 2010 
                 0.491 
                   
                   
                 no 
                 slight 
               
               
                 3/22 
                 PP21 
                 990 
                 06 
                 2010 
                 0.491 
                   
                   
                 slight 
                 yes 
               
               
                 3/23 
                 PP21 
                 990 
                 07 
                 2010 
                 0.491 
                   
                   
                 slight 
                 yes 
               
               
                 3/24 
                 PP21 
                 1500 
                 MS60054 
                 2031 
                 0.739 
                   
                   
                 yes 
                 yes 
               
               
                 3/25 
                 PP21 
                 762 
                 05 
                 2031 
                 0.375 
                   
                   
                 yes 
                 slight 
               
               
                 3/26 
                 PP21 
                 1500 
                 05 
                 2031 
                 0.739 
                   
                   
                 no 
               
               
                 3/27## 
                 PP21 
                   
                 B01 
                   
                   
                   
                   
                 no 
                 slight 
               
               
                 3/28** 
                 PP21 
                   
                 B01 
                   
                   
                   
                   
                 no 
                 no 
               
               
                 3/29*** 
                 PP21 
                   
                 B01 
                   
                   
                   
                   
                 no 
                 no 
               
               
                 3/30# 
                 PP21 
                 750 
                 MS16357 
                 2000 
                 0.375 
                   
                   
                   
                 yes 
               
               
                 3/31# 
                 PP21 
                 1500 
                 MS16357 
                 2000 
                 0.750 
                   
                   
                   
                 no 
               
               
                 3/32 
                 PP21 
                 750 
                 CP3077 
                 2000 
                 0.375 
                   
                   
                 yes 
                 no 
               
               
                 3/33 
                 PP21 
                 750 
                 CE1611 
                 2000 
                 0.375 
                   
                   
                 yes 
                 slight 
               
               
                 3/34 
                 PP21 
                 1500 
                 CE1611 
                 2000 
                 0.750 
                   
                   
                 yes 
                 no 
               
               
                 3/35 
                 PP21 
                 1000 
                 08 
                 2000 
                 0.500 
                   
                   
                 slight 
                 yes 
               
               
                 3/36 
                 PP21 
                 1000 
                 09 
                 2000 
                 0.500 
                   
                   
                 slight 
                 yes 
               
               
                 3/37 
                 PP21 
                 1000 
                 10 
                 2000 
                 0.500 
                   
                   
                 strong 
                 yes 
               
               
                 3/38**** 
                 PP21 
                 1000 
                 10 
                 2000 
                 0.500 
                   
                   
                 v. strong 
                 no 
               
               
                   
               
               
                 #poor adhesion 
               
               
                 *not scratch-resistant 
               
               
                 PAZ = MS16686 
               
               
                 ##hardened with 100% glyoxal at pH 4 
               
               
                 **hardened with 50% tetramethyl orthosilicate at pH 4 
               
               
                 ***hardened with 100% tetramethyl orthosilicate at pH 4 
               
               
                 ****hardened with 0.999 g/m 2  MS15262 MS16357 POVAL R1130 
               
            
           
         
       
     
     A lack of adhesion between the support and the single layer is remediable by adapting the modifying the subbing layer or by providing a subbing layer comprising the plurality of subbing layers required to realize adhesion between the support and the single layer. 
     Example 4 
     Screening of Different Latexes 
     The non-transparent microvoided biaxially stretched self-supporting films 1/LS1/BS1 coated with subbing layer 3 was coated with the compositions in Table 4 with 0.04 g/m 2  of the surfactant S07. 
     
       
         
           
               
               
               
               
               
             
               
                 TABLE 4 
               
             
            
               
                   
               
               
                 Ex- 
                 Porous 
                   
                 Wt ratio 
                   
               
               
                 am- 
                 pigment 
                 Latex 
                 porous 
                 Binder 
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                 ple 
                   
                 coverage 
                   
                 coverage 
                 pigment 
                   
                 coverage 
               
               
                 No. 
                 No. 
                 [g/m 2 ] 
                 No. 
                 [g/m 2 ] 
                 to latex 
                 No. 
                 [g/m 2 ] 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                 4/1 
                 PP21 
                 1.5 
                 L04 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                 4/2 
                 PP21 
                 2.0 
                 L04 
                 2.0 
                 1.0 
                 — 
                 — 
               
               
                 4/3 
                 PP21 
                 2.0 
                 L04 
                 2.0 
                 1.0 
                 B01 
                 0.2 
               
               
                 4/4 
                 PP21 
                 1.5 
                 L32 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                 4/5 
                 PP21 
                 2.0 
                 L32 
                 2.0 
                 1.0 
                 — 
                 — 
               
               
                 4/6 
                 PP21 
                 2.0 
                 L32 
                 2.0 
                 1.0 
                 B01 
                 0.2 
               
               
                 4/7 
                 PP21 
                 1.5 
                 L20 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                 4/8 
                 PP21 
                 2.0 
                 L20 
                 2.0 
                 1.0 
                 — 
                 — 
               
               
                 4/9 
                 PP21 
                 2.0 
                 L20 
                 2.0 
                 1.0 
                 B01 
                 0.2 
               
               
                 4/10 
                 PP21 
                 1.5 
                 L19 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                 4/11 
                 PP21 
                 2.0 
                 L19 
                 2.0 
                 1.0 
                 — 
                 — 
               
               
                 4/12 
                 PP21 
                 2.0 
                 L19 
                 2.0 
                 1.0 
                 B01 
                 0.2 
               
               
                 4/13 
                 PP21 
                 1.5 
                 L22 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                 4/14 
                 PP21 
                 2.0 
                 L22 
                 2.0 
                 1.0 
                 — 
                 — 
               
               
                 4/15 
                 PP21 
                 2.0 
                 L22 
                 2.0 
                 1.0 
                 B01 
                 0.2 
               
               
                 4/16 
                 PP21 
                 2.0 
                 L04 
                 2.0 
                 1.0 
                 B01 
                 0.2 
               
               
                 4/17 
                 PP21 
                 2.0 
                 L04 
                 2.0 
                 1.0 
                 B01 
                 0.2 
               
               
                 4/18 
                 PP21 
                 1.5 
                 04 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                 4/19 
                 PP21 
                 2.0 
                 04 
                 2.0 
                 1.0 
                 — 
                 — 
               
               
                 4/20 
                 PP21 
                 2.0 
                 04 
                 2.0 
                 1.0 
                 B01 
                 0.2 
               
               
                 4/21 
                 PP21 
                 1.5 
                 L16 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                 4/22 
                 PP21 
                 2.0 
                 L16 
                 2.0 
                 1.0 
                 — 
                 — 
               
               
                 4/23 
                 PP21 
                 2.0 
                 L16 
                 2.0 
                 1.0 
                 B01 
                 0.2 
               
               
                 4/24 
                 PP21 
                 1.5 
                 L17 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                 4/25 
                 PP21 
                 2.0 
                 L17 
                 2.0 
                 1.0 
                 — 
                 — 
               
               
                 4/26 
                 PP21 
                 2.0 
                 L17 
                 2.0 
                 1.0 
                 B01 
                 0.2 
               
               
                 4/27 
                 PP21 
                 1.5 
                 L18 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                 4/28 
                 PP21 
                 2.0 
                 L18 
                 2.0 
                 1.0 
                 — 
                 — 
               
               
                 4/29 
                 PP21 
                 2.0 
                 L18 
                 2.0 
                 1.0 
                 B01 
                 0.2 
               
               
                 4/30* 
                 PP21 
                 2.2 
                 L21 
                 2.14 
                 0.973 
                 B01 
                  0.22 
               
               
                   
               
               
                 *MMA01 in concentration of 0.1 g/m 2   
               
            
           
         
       
     
     Printing tests were carried out on a Heidelberg GT046 printing press with a K+E800 ink and as fountain 4% AGFA FS330 with 10% isopropanol. The results of qualitative printability tests are summarized in Table 5. 
     
       
         
           
               
               
               
             
               
                   
                 TABLE 5 
               
             
            
               
                   
                   
               
               
                   
                   
                 IGT 
               
               
                   
                   
                 tests 
               
               
                   
                 Printing tests 
                 drying 
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                   
                   
                 Wt ratio 
                   
                   
                   
                 Dot 
                 time to 
               
               
                   
                   
                 porous 
                   
                   
                   
                 gain 
                 avoid 
               
               
                 Example 
                   
                 pigment 
                 ballpen 
                 Tape test dry 
                   
                 50% 
                 set-off 
               
               
                 No. 
                 Latex 
                 to latex 
                 writability 
                 [10 min] 
                 mottle 
                 screen 
                 [s] 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                 4/1 
                 L04 
                 0.75 
                 repulsion 
                 OK 
                 yes 
                 24 
                 &gt;58 
               
               
                   
                   
                   
                 in centre 
               
               
                 4/2 
                 L04 
                 1.0 
                 repulsion 
                 cohesive 
                 no 
                 25 
                 48 
               
               
                   
                   
                   
                 in centre 
                 break 
               
               
                 4/3 
                 L04 
                 1.0 
                 repulsion 
                 OK 
                 no 
                 25 
                 31 
               
               
                   
                   
                   
                 in centre 
               
               
                 4/4 
                 L32 
                 0.75 
                 repulsion 
                 OK 
                 yes 
                 26 
                 31 
               
               
                   
                   
                   
                 in centre 
               
               
                 4/5 
                 L32 
                 1.0 
                 repulsion 
                 OK 
                 slight 
                 25 
                 31 
               
               
                   
                   
                   
                 in centre 
               
               
                 4/6 
                 L32 
                 1.0 
                 good 
                 OK 
                 no 
                 25 
                 9 
               
               
                 4/7 
                 L20 
                 0.75 
                 repulsion 
                 cohesive 
                 yes 
                 26 
               
               
                   
                   
                   
                 in centre 
                 break 
               
               
                 4/8 
                 L20 
                 1.0 
                 repulsion 
                 delaminates 
                 yes 
                 25 
               
               
                   
                   
                   
                 in 
               
               
                   
                   
                   
                 centre/cracking 
               
               
                 4/9 
                 L20 
                 1.0 
                 repulsion 
                 OK 
                 yes 
                 24 
               
               
                   
                   
                   
                 in centre/ 
               
               
                   
                   
                   
                 cracking 
               
               
                 4/10 
                 L19 
                 0.75 
                 good 
                 delaminates 
               
               
                 4/11 
                 L19 
                 1.0 
                 good 
                 delaminates 
               
               
                 4/12 
                 L19 
                 1.0 
                 repulsion 
                 delaminates 
               
               
                   
                   
                   
                 in centre 
               
               
                 4/13 
                 L22 
                 0.75 
                 repulsion 
                 OK 
               
               
                   
                   
                   
                 in centre/ 
               
               
                   
                   
                   
                 cracking 
               
               
                 4/14 
                 L22 
                 1.0 
                 repulsion 
                 cohesive 
               
               
                   
                   
                   
                 in centre 
                 break 
               
               
                 4/15 
                 L22 
                 1.0 
                 repulsion 
                 OK 
               
               
                   
                   
                   
                 in centre 
               
               
                 4/16 
                 L04 
                 1.0 
                   
                 OK 
                 no 
                 25 
               
               
                 4/17 
                 L04 
                 1.0 
                   
                 OK 
                 no 
                 26 
               
               
                 4/18 
                 04 
                 0.75 
                   
                 OK 
                 strong 
                 29 
               
               
                 4/19 
                 04 
                 1.0 
                   
                 slight 
                 strong 
                 27 
               
               
                   
                   
                   
                   
                 cohesive 
               
               
                   
                   
                   
                   
                 break 
               
               
                 4/20 
                 04 
                 1.0 
                   
                 OK 
                 no 
                 27 
               
               
                 4/21 
                 L16 
                 0.75 
                   
                 OK 
                 slight 
                 28 
               
               
                 4/22 
                 L16 
                 1.0 
                   
                 strong 
                 no 
                 26 
               
               
                   
                   
                   
                   
                 cohesive 
               
               
                   
                   
                   
                   
                 break 
               
               
                 4/23 
                 L16 
                 1.0 
                   
                 slight 
                 no 
                 25 
               
               
                   
                   
                   
                   
                 cohesive 
               
               
                   
                   
                   
                   
                 break 
               
               
                 4/24 
                 L17 
                 0.75 
                   
                 delaminates 
                 slight 
                 29 
               
               
                 4/25 
                 L17 
                 1.0 
                   
                 delaminates 
                 strong 
                 27 
               
               
                 4/26 
                 L17 
                 1.0 
                   
                 OK 
                 slight 
                 27 
               
               
                 4/27 
                 L18 
                 0.75 
                   
                 delaminates 
                 strong 
                 27 
               
               
                 4/28 
                 L18 
                 1.0 
                   
                 delaminates 
                 no 
                 27 
               
               
                 4/29 
                 L18 
                 1.0 
                   
                 strong 
                 no 
                 27 
               
               
                   
                   
                   
                   
                 cohesive 
               
               
                   
                   
                   
                   
                 break 
               
               
                 4/30* 
                 L21 
                 0.973 
                   
                 OK 
                 no 
                 27 
               
               
                   
               
               
                 *Linimark evaluation of scratch resistance carried out with a Roberta apparatus gave a force before scratching was observed of 31 mN 
               
            
           
         
       
     
     Table 6 summarize the findings of EXAMPLES 3 and 4 in respect of the choice of latex for use in the single layer coated on at least on side of an optionally subbed support. 
     
       
         
           
               
               
             
               
                 TABLE 6 
               
               
                   
               
               
                 latex No. 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
            
               
                 01 
                 Joncryl 
                 BASF 
                 REFERENCE; pH 8.5; poor mottle; no alkali 
               
               
                   
                 FLX5000 
                   
                 resistance; water resistant [fensterklar] 
               
               
                 02 
                 Joncryl 
                 BASF 
                 cf. FLX 5000; pH 8.3; ammonia-neutralized; 
               
               
                   
                 8078 
                   
                 poor mottle; non alkali-resistant; poorer drying 
               
               
                   
                   
                   
                 than REF; poor adhesion 
               
               
                 03 
                 Joncryl 
                 BASF 
                 pH 8.5; better alkali-resistance; poor mottle; 
               
               
                   
                 FLX5010 
                   
                 water resistant 
               
               
                 04 
                 Joncryl 
                 BASF 
                 cf. FLX 5000; pH 7.8; partially neutralized 
               
               
                   
                 8050 
                   
                 resin; with as emulsifier a low-molecular- 
               
               
                   
                   
                   
                 weight alkali-soluble styrene/acrylate 
               
               
                   
                   
                   
                 copolymer; poor mottle; non alkali-resistant 
               
               
                 05 
                 Hycar 
                 Dow 
                 pH 6.0; cf. FLX 5000; poor mottle; non alkali- 
               
               
                   
                 PC84 
                 Chemical 
                 resistant; self-crosslinking 
               
               
                 06 
                 Carboset 
                 Goodrich 
                 PH 5.5, 6.5; cf. FLX 5000; poor mottle; non 
               
               
                   
                 GA2364 
                   
                 alkali-resistant 
               
               
                 07 
                 Joncryl 
                 BASF 
                 pH 7.9; self-crosslinking; cf. FLX 5000; poor 
               
               
                   
                 8385 
                   
                 mottle; no alkali resistance 
               
               
                 08 
                 Enorax 
                 Collano 
                 pH 4.5; very good (better than FLX 5000); no 
               
               
                   
                 PU950 
                   
                 longer commercially available 
               
               
                 09 
                 wac- 
                 Takamatu 
                 pH 7, 9; cf. FLX 5000; poor mottle; no alkali 
               
               
                   
                 17XC 
                 Oil &amp; Fat 
                 resistance 
               
               
                   
                   
                 Co. Ltd 
               
               
                 10 
                 Crom- 
                 Cromogenia- 
                 pH 8.3; cf. FLX 5000; better mottle; no alkali 
               
               
                   
                 elastic 
                 units S.A. 
                 resistance 
               
               
                   
                 C4480 
               
               
                 11 
                 Mowilith 
                 Clariant 
                 pH 5, 7; cf. FLX 5010; no alkali resistance 
               
               
                   
                 DM 2452 
               
               
                 12 
                 Wellpur 
                 Van Camp 
                 pH 4, 6; no mottle; alkali resistant; layer 
               
               
                   
                 FM10C 
                 Chemicals 
                 appears flocked; rough to touch 
               
               
                 13 
                 Neorez 
                 Avecia 
                 pH 8.3; cf. FLX 5000; no alkali resistance; 
               
               
                   
                 R989 
                   
                 mottle better 
               
               
                 14 
                 Jetsize 
                 Eka Nobel 
                 cf. FLX 5010; better alkali-resistance; poor 
               
               
                   
                 CE225 
                   
                 mottle 
               
               
                   
               
            
           
         
       
     
     Example 5 
     Screening of Different Porous Pigments 
     The non-transparent microvoided biaxially stretched self-supporting films 1/LS1/BS1 coated with subbing layer 1 was coated with the compositions in Table 7 in the case of EXAMPLES 5/1 to 5/15 together with small quantities of Tego Glide 482, a high molecular weight polydimethylsiloxane from Goldschmidt, and surfactant S04; in the case of EXAMPLES 5/16 to 5/xx with 
     
       
         
           
               
               
               
               
               
               
             
               
                   
                 TABLE 7 
               
             
            
               
                   
                   
               
               
                   
                 Porous 
                   
                 Wt ratio 
                   
                   
               
               
                   
                 pigment 
                 Latex 
                 porous 
                   
                 printing properties 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
            
               
                 Example 
                   
                 coverage 
                   
                 coverage 
                 pigment to 
                 ballpen 
                 dry time 
                 set- 
                   
               
               
                 No. 
                 No. 
                 [mg/m 2 ] 
                 No. 
                 [g/m 2 ] 
                 latex 
                 writ-ability 
                 [min] 
                 off 
                 mottle 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
            
               
                 5/1 
                 PP21 
                 76 
                 01 
                 203 
                 0.374 
                 repulsion in 
                   
                   
                   
               
               
                   
                   
                   
                   
                   
                   
                 centre 
               
               
                 5/2 
                 — 
                 — 
                 01 
                 203 
                 — 
                 no 
               
               
                 5/3 
                 PP13 
                 76 
                 01 
                 203 
                 0.374 
                 good 
               
               
                 5/4 
                 OP03 
                 76 
                 01 
                 203 
                 0.374 
                 v. poor 
               
               
                 5/5 
                 OP04 
                 76 
                 01 
                 203 
                 0.374 
                 poor 
               
               
                 5/6 
                 OP07 
                 76 
                 01 
                 203 
                 0.374 
                 poor 
               
               
                 5/7 
                 OP08 
                 76 
                 01 
                 203 
                 0.374 
                 poor 
               
               
                 5/8 
                 OP11 
                 76 
                 01 
                 203 
                 0.374 
                 good 
               
               
                 5/9 
                 PP21 
                 760 
                 01 
                 2000 
                 0.380 
                 repulsion in 
               
               
                   
                   
                   
                   
                   
                   
                 centre 
               
               
                 5/10 
                 PP21 
                 1500 
                 01 
                 2000 
                 0.750 
                 repulsion in 
               
               
                   
                   
                   
                   
                   
                   
                 centre 
               
               
                 5/11 
                 PP21 
                 2000 
                 01 
                 2000 
                 1.00 
                 denser but 
                 5 
                 no 
               
               
                   
                   
                   
                   
                   
                   
                 repulsion in 
               
               
                   
                   
                   
                   
                   
                   
                 centre 
               
               
                 5/12 
                 OP13 
                 760 
                 01 
                 2000 
                 0.380 
                 no 
               
               
                 5/13 
                 PP21 
                 375 
                 01 
                 2000 
                 0.188 
                 v. poor 
               
               
                   
                 OP13 
                 375 
                   
                   
                 0.188 
               
               
                 5/14 
                 OP13 
                 760 
                 01 
                 2000 
                 0.380 
                 v. poor 
               
               
                   
               
            
           
         
       
     
     Example 6 
     Screening of Different Porous Pigments 
     The non-transparent microvoided biaxially stretched self-supporting films 1/LS1/BS1 coated with subbing layer 3 was coated with the compositions in Table 8 with in the case of EXAMPLES 6/1 to 6/38 with a mixture of two surfactants (S05 and S06). 
     
       
         
           
               
               
               
               
               
             
               
                 TABLE 8 
               
             
            
               
                   
               
               
                 Ex- 
                 Porous 
                   
                 Wt ratio 
                   
               
               
                 am- 
                 pigment 
                 Latex 
                 porous 
                 Binder 
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                 ple 
                   
                 coverage 
                   
                 coverage 
                 pigment 
                   
                 coverage 
               
               
                 No. 
                 No. 
                 [g/m 2 ] 
                 No. 
                 [g/m 2 ] 
                 to latex 
                 No. 
                 [g/m 2 ] 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                 6/1 
                 PP21 
                 1.5 
                 L05 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                 6/2 
                 PP21 
                 0.75 
                 L05 
                 2.0 
                 0.375 
                 — 
                 — 
               
               
                 6/3 
                 PP21 
                 0.75 
                 L05 
                 2.0 
                 0.375 
                 — 
                 — 
               
               
                   
                 OP06 
                 0.25 
               
               
                 6/4 
                 PP21 
                 0.75 
                 L05 
                 2.0 
                 0.375 
                 — 
                 — 
               
               
                   
                 OP06 
                 0.50 
               
               
                 6/5 
                 PP21 
                 0.75 
                 L05 
                 2.0 
                 0.375 
                 — 
                 — 
               
               
                   
                 OP06 
                 0.75 
               
               
                 6/6 
                 OP06 
                 0.75 
                 L05 
                 2.0 
                 — 
                 — 
                 — 
               
               
                 6/7 
                 OP06 
                 0.25 
                 L05 
                 2.0 
                 — 
                 — 
                 — 
               
               
                 6/8 
                 PP21 
                 1.5 
                 L01 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                 6/9 
                 PP21 
                 2.0 
                 L01 
                 2.0 
                 1.0 
                 — 
                 — 
               
               
                 6/10 
                 PP01 
                 1.5 
                 L01 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                 6/11 
                 PP01 
                 2.0 
                 L01 
                 2.0 
                 1.0 
                 — 
                 — 
               
               
                 6/12 
                 PP02 
                 1.5 
                 L01 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                 6/13 
                 PP02 
                 2.0 
                 L01 
                 2.0 
                 1.0 
                 — 
                 — 
               
               
                 6/14 
                 PP21 
                 1.0 
                 L01 
                 2.0 
                 0.5 
                 — 
                 — 
               
               
                 6/15 
                 PP21 
                 1.5 
                 L01 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                 6/16 
                 PP21 
                 2.0 
                 L01 
                 2.0 
                 1.00 
                 — 
                 — 
               
               
                 6/17 
                 OP01 
                 1.0 
                 L01 
                 2.0 
                 0.5 
                 — 
                 — 
               
               
                 6/18 
                 OP01 
                 1.5 
                 L01 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                 6/19 
                 OP01 
                 2.0 
                 L01 
                 2.0 
                 1.00 
                 — 
                 — 
               
               
                 6/20 
                 OP02 
                 1.0 
                 L01 
                 2.0 
                 0.5 
                 — 
                 — 
               
               
                 6/21 
                 OP02 
                 1.5 
                 L01 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                 6/22 
                 OP02 
                 2.0 
                 L01 
                 2.0 
                 1.00 
                 — 
                 — 
               
               
                 6/23 
                 PP28 
                 1.0 
                 L01 
                 2.0 
                 0.5 
                 — 
                 — 
               
               
                 6/24 
                 PP28 
                 1.5 
                 L01 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                 6/25 
                 PP28 
                 2.0 
                 L01 
                 2.0 
                 1.00 
                 — 
                 — 
               
               
                 6/26 
                 PP21 
                 1.5 
                 L01 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                 6/27 
                 PP21 
                 1.0 
                 L01 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                   
                 PP28 
                 0.5 
               
               
                 6/28 
                 PP21 
                 0.75 
                 L01 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                   
                 PP28 
                 0.75 
               
               
                 6/29 
                 PP21 
                 0.5 
                 L01 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                   
                 PP28 
                 1.0 
               
               
                 6/30 
                 PP28 
                 1.5 
                 L01 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                 6/31 
                 PP21 
                 1.0 
                 L01 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                   
                 PP02 
                 0.5 
               
               
                 6/32 
                 PP21 
                 0.75 
                 L01 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                   
                 PP02 
                 0.75 
               
               
                 6/33 
                 PP21 
                 0.5 
                 L01 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                   
                 PP02 
                 1.0 
               
               
                 6/34 
                 PP02 
                 1.5 
                 L01 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                 6/35 
                 PP21 
                 1.5 
                 L01 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                 6/36 
                 PP15 
                 1.5 
                 L01 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                 6/37 
                 PP12 
                 1.5 
                 L01 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                 6/38 
                 PP28 
                 1.5 
                 L01 
                 2.0 
                 0.75 
                 — 
                 — 
               
               
                   
               
            
           
         
       
     
     Printing tests were carried out on a A.B. Dick D9890 printing press with a K+E800 ink and as fountain 4% Emerald Premium with 10% isopropanol and an IGT Global Standard Tester 2. The results are summarized in Table 9. 
     
       
         
           
               
               
               
               
             
               
                   
                 TABLE 9 
               
             
            
               
                   
                   
               
               
                   
                 Weight 
                 Printing tests 
                 IGT tests 
               
            
           
           
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                 ratio 
                   
                   
                 Dot 
                 penetration 
                   
                 time to 
               
               
                   
                   
                 porous 
                   
                   
                 gain 
                 test 
                 penetration 
                 avoid 
               
               
                 Example 
                 Porous 
                 pigment 
                   
                   
                 50% 
                 length 
                 test 
                 set-off 
               
               
                 No. 
                 pigments 
                 to latex 
                 set-off 
                 mottle 
                 screen 
                 [mm] 
                 OD 
                 [s] 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
            
               
                 6/1 
                 PP21 
                 0.75 
                 no 
                 yes 
                   
                   
                   
                   
               
               
                 6/2 
                 PP21 
                 0.375 
                 v. strong 
                 yes 
               
               
                 6/3 
                 PP21 
                 0.375 
                 strong 
                 yes 
               
               
                   
                 OP06 
               
               
                 6/4 
                 PP21 
                 0.375 
                 yes 
                 yes 
               
               
                   
                 OP06 
               
               
                 6/5 
                 PP21 
                 0.375 
                 slight 
                 yes 
               
               
                   
                 OP06 
               
               
                 6/6 
                 OP06 
                 — 
                 very 
                 yes 
               
               
                   
                   
                   
                 strong 
               
               
                 6/7 
                 OP06 
                 — 
                 yes 
                 yes 
               
               
                 6/8 
                 PP21 
                 0.75 
                   
                 yes 
                   
                 125.0 
               
               
                 6/9 
                 PP21 
                 1.0 
                   
                 slight 
                   
                 103.0 
               
               
                 6/10 
                 PP01 
                 0.75 
                   
                 slight 
                   
                 88.7 
               
               
                 6/11 
                 PP01 
                 1.0 
                   
                 slight 
                   
                 89.7 
               
               
                 6/12 
                 PP02 
                 0.75 
                   
                 slight 
                   
                 106.3 
               
               
                 6/13 
                 PP02 
                 1.0 
                   
                 ca. no 
                   
                 94.3 
               
               
                 6/14 
                 PP21 
                 0.5 
                   
                 yes 
               
               
                 6/15 
                 PP21 
                 0.75 
                   
                 yes 
               
               
                 6/16 
                 PP21 
                 1.00 
                   
                 slight 
               
               
                 6/17 
                 OP01 
                 0.5 
                 v. strong 
                 ? 
               
               
                 6/18 
                 OP01 
                 0.75 
                 v. strong 
                 ? 
               
               
                 6/19 
                 OP01 
                 1.00 
                 v. strong 
                 ? 
               
               
                 6/20 
                 OP02 
                 0.5 
                 strong 
                 yes 
               
               
                 6/21 
                 OP02 
                 0.75 
                 strong 
                 no 
               
               
                 6/22 
                 OP02 
                 1.00 
                 strong 
                 no 
               
               
                 6/23 
                 PP28 
                 0.5 
                   
                 slight 
               
               
                 6/24 
                 PP28 
                 0.75 
                   
                 no 
               
               
                 6/25 
                 PP28 
                 1.00 
                   
                 no 
               
               
                 6/26 
                 PP21 
                 0.75 
                 yes 
                 yes 
                   
                 111.0 
               
               
                 6/27 
                 PP21 
                 0.75 
                 yes 
                 no 
                   
                 90.0 
               
               
                   
                 PP28 
               
               
                 6/28 
                 PP21 
                 0.75 
                 no 
                 no 
                   
                 84.3 
               
               
                   
                 PP28 
               
               
                 6/29 
                 PP21 
                 0.75 
                 no 
                 no 
                   
                 87.3 
               
               
                   
                 PP28 
               
               
                 6/30 
                 PP28 
                 0.75 
                 no 
                 no 
                   
                 76.3 
               
               
                 6/31 
                 PP21 
                 0.75 
                 no 
                 yes 
                   
                 124.3 
               
               
                   
                 PP02 
               
               
                 6/32 
                 PP21 
                 0.75 
                 no 
                 slight 
                   
                 110.3 
               
               
                   
                 PP02 
               
               
                 6/33 
                 PP21 
                 0.75 
                 no 
                 slight 
                   
                 108.3 
               
               
                   
                 PP02 
               
               
                 6/34 
                 PP02 
                 0.75 
                 no 
                 slight 
                   
                 104.3 
               
               
                 6/35 
                 PP21 
                 0.75 
                 no 
                 yes 
                   
                 121.3 
               
               
                 6/36 
                 PP15 
                 0.75 
                 slight 
                 yes 
                   
                 142.0 
               
               
                 6/37 
                 PP12 
                 0.75 
                 slight 
                 yes 
                   
                 120.0 
               
               
                 6/38 
                 PP28 
                 0.75 
                 slight 
                 yes 
                   
                 131.0 
               
               
                   
               
            
           
         
       
     
     Replacement of PP21 with PP28 (submicron filler from Nippon Kasei) brings about a reduction in mottle, which is already evident at a coverage of 0.5 g/m 2 , and also more rapid drying as seen by the strongly reduced penetration length in the results with the IGT Global Standard Tester 2. Replacement of P21 with PP02 (Sunsphere H33) also brings about a reduction in mottle, but less than with PP28. 
     Example 7 
     Combination of an Inorganic Porous Pigment and an Organic Polymeric Porous Pigment 
     The non-transparent microvoided biaxially stretched self-supporting films 1/LS1/BS1 coated with subbing layer 3 was coated with the compositions in Table 10 with 0.04 g/m 2  of the surfactant S07. 
     
       
         
           
               
               
               
               
               
             
               
                 TABLE 10 
               
             
            
               
                   
               
               
                 Ex- 
                 Porous 
                   
                 Wt ratio 
                   
               
               
                 am- 
                 pigment 
                 Latex 
                 porous 
                 Binder 
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                 ple 
                   
                 coverage 
                   
                 coverage 
                 pigment 
                   
                 coverage 
               
               
                 No. 
                 No. 
                 [g/m 2 ] 
                 No. 
                 [g/m 2 ] 
                 to latex 
                 No. 
                 [g/m 2 ] 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                 7/1 
                 PP21 
                 1.5 
                 L04 
                 2.0 
                 0.75 
                 B01 
                 0.2 
               
               
                 7/2 
                 PP21 
                 1.75 
                 L04 
                 2.0 
                 1.0 
                 B01 
                 0.2 
               
               
                 7/3 
                 PP21 
                 2.0 
                 L04 
                 2.0 
                 1.0 
                 B01 
                 0.2 
               
               
                 7/4 
                 PP21 
                 1.0 
                 L04 
                 2.0 
                 0.75 
                 B01 
                 0.2 
               
               
                   
                 PP28 
                 0.5 
               
               
                 7/6 
                 PP21 
                 1.5 
                 L04 
                 2.0 
                 0.875 
                 B01 
                 0.2 
               
               
                   
                 PP28 
                 0.25 
               
               
                 7/7 
                 PP21 
                 1.5 
                 L04 
                 2.0 
                 1.0 
                 B01 
                 0.2 
               
               
                   
                 PP28 
                 0.5 
               
               
                 7/8 
                 PP21 
                 1.0 
                 L04 
                 2.0 
                 0.75 
                 B01 
                 0.2 
               
               
                   
                 PP34 
                 0.5 
               
               
                 7/10 
                 PP21 
                 1.5 
                 L04 
                 2.0 
                 0.875 
                 B01 
                 0.2 
               
               
                   
                 PP34 
                 0.25 
               
               
                 7/11 
                 PP21 
                 1.5 
                 L04 
                 2.0 
                 1.0 
                 B01 
                 0.2 
               
               
                   
                 PP34 
                 0.5 
               
               
                 7/12 
                 PP21 
                 1.0 
                 L04 
                 2.0 
                 0.75 
                 B01 
                 0.2 
               
               
                   
                 PP33 
                 0.5 
               
               
                 7/14 
                 PP21 
                 1.5 
                 L04 
                 2.0 
                 0.875 
                 B01 
                 0.2 
               
               
                   
                 PP33 
                 0.25 
               
               
                 7/15 
                 PP21 
                 1.5 
                 L04 
                 2.0 
                 1.0 
                 B01 
                 0.2 
               
               
                   
                 PP33 
                 0.5 
               
               
                 7/16 
                 PP21 
                 1.0 
                 L04 
                 2.0 
                 0.75 
                 B01 
                 0.2 
               
               
                   
                 PP32 
                 0.5 
               
               
                 7/18 
                 PP21 
                 1.5 
                 L04 
                 2.0 
                 0.875 
                 B01 
                 0.2 
               
               
                   
                 PP32 
                 0.25 
               
               
                 7/19 
                 PP21 
                 1.5 
                 L04 
                 2.0 
                 1.0 
                 B01 
                 0.2 
               
               
                   
                 PP32 
                 0.5 
               
               
                   
               
            
           
         
       
     
     Printing tests were carried out on a Heidelberg GT046 printing press with a K+E800 ink and as fountain 4% AGFA FS330 with 10% isopropanol and an IGT Global Standard Tester 2. The results are summarized in Table 11. 
     
       
         
           
               
               
               
               
             
               
                   
                 TABLE 11 
               
             
            
               
                   
                   
               
               
                   
                 Weight 
                 Printing tests 
                 IGT tests 
               
            
           
           
               
               
               
               
               
               
               
               
               
            
               
                   
                   
                 ratio 
                   
                   
                 Dot 
                 penetration 
                   
                 time to 
               
               
                   
                   
                 porous 
                   
                   
                 gain 
                 test 
                 penetration 
                 avoid 
               
               
                 Example 
                 Porous 
                 pigment 
                 scratch 
                   
                 50% 
                 length 
                 test 
                 set-off 
               
               
                 No. 
                 pigments 
                 to latex 
                 resistance 
                 mottle 
                 screen 
                 [mm] 
                 OD 
                 [s] 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
            
               
                 7/1 
                 PP21 
                 0.75 
                 not OK 
                 no 
                 29 
                 123.0 
                 0.37 
                 &gt;58 
               
               
                 7/2 
                 PP21 
                 1.0 
                 not OK 
                 no 
                 29 
                 106.0 
                 0.50 
                 24 
               
               
                 7/3 
                 PP21 
                 1.0 
                 not OK 
                 no 
                 28 
                 90.0 
                 0.60 
                 9 
               
               
                 7/4 
                 PP21 
                 0.75 
                 OK 
                 v. good 
                 28 
                 93.0 
                 0.49 
                 &gt;58 
               
               
                   
                 PP28 
               
               
                 7/6 
                 PP21 
                 0.875 
                 not OK 
                 v. good 
                 29 
                 97.0 
                 0.51 
                 31 
               
               
                   
                 PP28 
               
               
                 7/7 
                 PP21 
                 1.0 
                 not OK 
                 v. good 
                 28 
                 83.0 
                 0.61 
                 24 
               
               
                   
                 PP28 
               
               
                 7/8 
                 PP21 
                 0.75 
                 OK 
                 no 
                 29 
                 95.0 
                 0.43 
                 &gt;58 
               
               
                   
                 PP34 
               
               
                 7/10 
                 PP21 
                 0.875 
                 not OK 
                 no 
                 28 
                 92.0 
                 0.50 
                 39 
               
               
                   
                 PP34 
               
               
                 7/11 
                 PP21 
                 1.0 
                 not OK 
                 v. good 
                 28 
                 82.0 
                 0.55 
                 24 
               
               
                   
                 PP34 
               
               
                 7/12 
                 PP21 
                 0.75 
                 OK 
                 no 
                 29 
                 114.0 
                 0.43 
                 &gt;58 
               
               
                   
                 PP33 
               
               
                 7/14 
                 PP21 
                 0.875 
                 OK 
                 no 
                 28 
                 97.0 
                 0.48 
                 39 
               
               
                   
                 PP33 
               
               
                 7/15 
                 PP21 
                 1.0 
                 not OK 
                 no 
                 28 
                 92.0 
                 0.57 
                 18 
               
               
                   
                 PP33 
               
               
                 7/16 
                 PP21 
                 0.75 
                 OK 
                 no 
                 30 
                 114.0 
                 0.42 
                 &gt;58 
               
               
                   
                 PP32 
               
               
                 7/18 
                 PP21 
                 0.875 
                 ca. OK 
                 no 
                 29 
                 105.0 
                 0.50 
                 24 
               
               
                   
                 PP32 
               
               
                 7/19 
                 PP21 
                 1.0 
                 OK 
                 no 
                 28 
                 99.0 
                 0.52 
                 18 
               
               
                   
                 PP32 
               
               
                   
               
            
           
         
       
     
     There was no significant difference in dot gain or ink acceptance. Furthermore, no set-off was observed and there was no difference in ink adhesion. Moreover, the papers of EXAMPLES 7/4, 7/7, 7/8 and 7/14 gave very uniform ink layers. PP28 (Submicron filler from Nippon Kasei) and PP34 have a higher absorption speed than PP21 and PP28 (Submicron filler from Nippon Kasei) had the highest absorption capacity of the inorganic porous pigments evaluated. 
     Example 8 
     Combination of Porous and Opacifying Pigments 
     The non-transparent microvoided biaxially stretched self-supporting films 1/LS1/BS1 coated with subbing layer 3 was coated with the compositions in Table 12 with Latex 04 with different combinations of porous and opacifying pigments. 
     
       
         
           
               
               
               
               
               
             
               
                   
                 TABLE 12 
               
             
            
               
                   
                   
               
               
                   
                 Porous 
                   
                   
                   
               
               
                   
                 pigment 
                 Latex 
                 Binder 
                 Surfactants 
               
            
           
           
               
               
               
               
               
               
               
               
               
            
               
                 Example 
                   
                 coverage 
                   
                 coverage 
                   
                 coverage 
                   
                 coverage 
               
               
                 No. 
                 No. 
                 [g/m 2 ] 
                 No. 
                 [g/m 2 ] 
                 No. 
                 [g/m 2 ] 
                 No. 
                 [g/m 2 ] 
               
               
                   
               
               
                 8/1  
                 PP21 
                 2.0 
                 L04 
                 2.2 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                 FLX5010 
               
               
                 8/2  
                 PP21 
                 1.5 
                 L04 
                 2.2 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                 8/3  
                 PP21 
                 1.0 
                 L04 
                 2.0 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                 8/4  
                 PP21 
                 0.5 
                 L04 
                 2.0 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                 8/5  
                 — 
                 — 
                 L04 
                 2.2 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                 8/6  
                 PP21 
                 1.5 
                 L04 
                 2.0 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                   
                 OP05 
                 0.5 
               
               
                 8/7  
                 PP21 
                 1.0 
                 L04 
                 2.2 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                   
                 OP05 
                 1.0 
               
               
                 8/8  
                 PP21 
                 0.5 
                 L04 
                 2.0 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                   
                 OP05 
                 1.5 
               
               
                 8/9  
                 P05 
                 2.0 
                 L04 
                 2.0 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                 8/10 
                 PP21 
                 1.5 
                 L04 
                 2.2 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                   
                 OP10 
                 0.5 
               
               
                 8/11 
                 PP21 
                 1.0 
                 L04 
                 2.0 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                   
                 OP10 
                 1.0 
               
               
                 8/12 
                 PP21 
                 0.5 
                 L04 
                 2.2 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                   
                 OP10 
                 1.5 
               
               
                 8/13 
                 OP10 
                 2.0 
                 L04 
                 2.0 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                 8/14 
                 PP21 
                 1.5 
                 L04 
                 2.0 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                   
                 PP25 
                 0.5 
               
               
                 8/15 
                 PP21 
                 1.0 
                 L04 
                 2.2 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                   
                 PP25 
                 1.0 
               
               
                 8/16 
                 PP21 
                 0.5 
                 L04 
                 2.0 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                   
                 PP25 
                 1.5 
               
               
                 8/17 
                 PP25 
                 2.0 
                 L04 
                 2.2 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                 8/18 
                 PP21 
                 1.5 
                 L04 
                 2.0 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                   
                 OP09 
                 0.5 
               
               
                 8/19 
                 PP21 
                 1.0 
                 L04 
                 2.0 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                   
                 OP09 
                 1.0 
               
               
                 8/20 
                 PP21 
                 0.5 
                 L04 
                 2.2 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                   
                 OP09 
                 1.5 
               
               
                 8/21 
                 OP09 
                 2.0 
                 L04 
                 2.0 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                 8/22 
                 PP21 
                 1.5 
                 L04 
                 2.2 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                   
                 PP26 
                 0.5 
               
               
                 8/23 
                 PP21 
                 1.0 
                 L04 
                 2.0 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                   
                 PP26 
                 1.0 
               
               
                 8/24 
                 PP21 
                 0.5 
                 L04 
                 2.0 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                   
                 PP26 
                 1.5 
               
               
                 8/25 
                 PP26 
                 2.0 
                 L04 
                 2.2 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                   
               
            
           
         
       
     
     These papers were then subjected to printing tests using a Heidelberg GTO46 printing press with a K+E 123w ink and a fountain of 4% AGFA FS330 with 10% isopropanol. The resulting prints were evaluated on the basis of tape tests, powder tests, dot-gain evaluated with a Gretag Spectroeye densitometer, print mottle and scratch resistance with the results being given in Table 13 below. 
     
       
         
           
               
               
               
               
               
               
               
               
             
               
                   
                 TABLE 13 
               
             
            
               
                   
                   
               
               
                   
                   
                   
                 Dot 
                   
                   
                   
                 IGT test 
               
               
                   
                 Pigment 
                 Tape 
                 gain 
                 Surface 
                   
                   
                 time to 
               
            
           
           
               
               
               
               
               
               
               
               
               
            
               
                 Example 
                   
                 coverage 
                 test dry 
                 50% 
                 energy 
                 print 
                   
                 avoid set- 
               
               
                 No. 
                 No. 
                 [g/m 2 ] 
                 [10 min] 
                 screen 
                 [mN/m] 
                 mottle 
                 Set-off 
                 off [s] 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
            
               
                 8/1  
                 PP21 
                 2.0 
                   
                 31 
                 &lt;36 
                 no 
                 no 
                 9 
               
               
                 FLX5010 
               
               
                 8/2  
                 PP21 
                 1.5 
                   
                 33 
                 &lt;36 
                 no 
                 no 
                 48 
               
               
                 8/3  
                 PP21 
                 1.0 
                   
                 36 
                 &lt;36 
                 yes 
                 no 
                 &gt;58 
               
               
                 8/4  
                 PP21 
                 0.5 
                   
                 36 
                 38-40 
                 strong 
                 strong 
                 &gt;&gt;58 
               
               
                 8/5  
                 — 
                 — 
                   
                 29 
                 36 
                 strong 
                 moderate 
               
               
                 8/6  
                 PP21 
                 1.5 
                   
                 33 
                 36 
                 yes 
                 no 
               
               
                   
                 OP05 
                 0.5 
               
               
                 8/7  
                 PP21 
                 1.0 
                   
                 35 
                 42 
                 strong 
                 no 
               
               
                   
                 OP05 
                 1.0 
               
               
                 8/8  
                 PP21 
                 0.5 
                   
                 36 
                 36 
                 strong 
                 no 
               
               
                   
                 OP05 
                 1.5 
               
               
                 8/9  
                 OP05 
                 2.0 
                   
                 37 
                 42 
                 strong 
                 no 
               
               
                 8/10 
                 PP21 
                 1.5 
                   
                 34 
                 &lt;36 
                 moderate 
                 no 
               
               
                   
                 OP10 
                 0.5 
               
               
                 8/11 
                 PP21 
                 1.0 
                   
                 36 
                 &lt;36 
                 yes 
                 no 
               
               
                   
                 OP10 
                 1.0 
               
               
                 8/12 
                 PP21 
                 0.5 
                   
                 38 
                 36 
                 strong 
                 yes 
               
               
                   
                 OP10 
                 1.5 
               
               
                 8/13 
                 OP10 
                 2.0 
                   
                 15 
                 &lt;&lt;36 
                 v. 
                 v. 
               
               
                   
                   
                   
                   
                   
                   
                 strong 
                 strong 
               
               
                 8/14 
                 PP21 
                 1.5 
                   
                 32 
                 &lt;36 
                 no 
                 no 
                 24 
               
               
                   
                 PP25 
                 0.5 
               
               
                 8/15 
                 PP21 
                 1.0 
                   
                 34 
                 &lt;36 
                 slight 
                 no 
                 &gt;58 
               
               
                   
                 PP25 
                 1.0 
               
               
                 8/16 
                 PP21 
                 0.5 
                   
                 36 
                 36 
                 yes 
                 no 
                 &gt;&gt;58 
               
               
                   
                 PP25 
                 1.5 
               
               
                 8/17 
                 PP25 
                 2.0 
                   
                 33 
                 &lt;36 
                 strong 
                 yes 
                 &gt;&gt;58 
               
               
                 8/18 
                 PP21 
                 1.5 
                   
                 33 
                 &lt;36 
                 yes 
                 no 
               
               
                   
                 OP09 
                 0.5 
               
               
                 8/19 
                 PP21 
                 1.0 
                   
                 34 
                 36 
                 strong 
                 no 
               
               
                   
                 OP09 
                 1.0 
               
               
                 8/20 
                 PP21 
                 0.5 
                   
                 36 
                 42 
                 strong 
                 strong 
               
               
                   
                 OP09 
                 1.5 
               
               
                 8/21 
                 OP09 
                 2.0 
                   
                 39 
                 36 
                 v. 
                 v. 
               
               
                   
                   
                   
                   
                   
                   
                 strong 
                 strong 
               
               
                 8/22 
                 PP21 
                 1.5 
                   
                 31 
                 &lt;36 
                 slight 
                 no 
                 &gt;58 
               
               
                   
                 PP26 
                 0.5 
               
               
                 8/23 
                 PP21 
                 1.0 
                   
                 32 
                 38 
                 yes 
                 no 
                 &gt;&gt;58 
               
               
                   
                 PP26 
                 1.0 
               
               
                 8/24 
                 PP21 
                 0.5 
                   
                 34 
                 36 
                 strong 
                 no 
                 &gt;&gt;58 
               
               
                   
                 PP26 
                 1.5 
               
               
                 8/25 
                 PP26 
                 2.0 
                   
                 32 
                 36 
                 strong 
                 no 
                 &gt;&gt;58 
               
               
                   
               
            
           
         
       
     
     Decreasing the PP21-content increase mottle and dot gain with at PP21-contents below 1 g/m 2  poor drying, set-off and poor ink adhesion. 
     Replacement of PP21 with OP05 (Jetcoat 30, CaCO 3 ) resulted in a strong increase in print mottle and poorer ink adhesion, although Jetcoat 30 provides a contribution to the ink-drying process, allbeit small. 
     Replacement of PP21 with OP10 (Hydragloss 90, china clay/kaolin) resulted in a strong increase in print mottle and poorer ink adhesion. Moreover, OP10 provided no contribution to the ink-drying process. 
     Replacement of PP21 with PP25 [Mitral 9400, [Al(OH) 3 ] resulted in an improvement in ink adhesion and a slight increase in mottle. Moreover, PP25 contributed to the drying process, although less strongly than PP21 as shown by the complete replacement of PP21 with PP25 resulting in poor drying and strong mottle. 
     Replacement of PP21 with OP09 (Snowtex ST40, colloidal silica) resulted in a strong increase in print mottle and poorer ink adhesion. Moreover, OP09 provided no contribution to the ink-drying process. 
     Replacement of PP21 with PP26 (Digitex 1000, kaolin) had no effect on the mottle and improved the drying and ink adhesion. 
     Example 9 
     Screening of Different Water-Soluble Binders 
     The non-transparent microvoided biaxially stretched self-supporting films 1/LS1/BS1 coated with subbing layer 3 was coated with the compositions in Table 14 with Latex 03 and Latex 04 with different binders to investigate whether this might reduce the print mottle. 
     
       
         
           
               
               
               
               
               
             
               
                   
                 TABLE 14 
               
             
            
               
                   
                   
               
               
                   
                 Porous 
                   
                   
                   
               
               
                   
                 pigment 
                 Latex 
                 Binder 
                 Surfactants 
               
            
           
           
               
               
               
               
               
               
               
               
               
            
               
                 Example 
                   
                 coverage 
                   
                 coverage 
                   
                 coverage 
                   
                 coverage 
               
               
                 No. 
                 No. 
                 [g/m 2 ] 
                 No. 
                 [g/m 2 ] 
                 No. 
                 [g/m 2 ] 
                 No. 
                 [g/m 2 ] 
               
               
                   
               
               
                 9/1  
                 PP21 
                 2.2 
                 L03 
                 2.2 
                 — 
                 — 
                 S07 
                 0.01 
               
               
                 Dispercoll 
               
               
                 U53 
               
               
                 9/2  
                 PP21 
                 2.0 
                 L03 
                 2.0 
                 — 
                 — 
                 S07 
                 0.01 
               
               
                 9/3  
                 PP21 
                 2.2 
                 L03 
                 2.2 
                 B01 
                 0.22 
                 S07 
                 0.01 
               
               
                 9/4  
                 PP21 
                 2.0 
                 L03 
                 2.0 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                 9/5  
                 PP21 
                 2.0 
                 L03 
                 2.0 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                 9/6  
                 PP21 
                 2.2 
                 L03 
                 2.2 
                 B02 
                 0.22 
                 S07 
                 0.01 
               
               
                 9/7  
                 PP21 
                 2.0 
                 L03 
                 2.0 
                 B02 
                 0.60 
                 S07 
                 0.01 
               
               
                 9/8  
                 PP21 
                 2.2 
                 L03 
                 2.2 
                 B03 
                 0.22 
                 S07 
                 0.01 
               
               
                 9/9  
                 PP21 
                 2.2 
                 L03 
                 2.2 
                 B04 
                 0.22 
                 S07 
                 0.01 
               
               
                 9/10 
                 PP21 
                 2.0 
                 L03 
                 2.0 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                   
                   
                   
                   
                   
                 IN02 
                 0.20 
               
               
                 9/11 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 — 
                 — 
                 S07 
                 0.01 
               
               
                 FLX5010 
               
               
                 9/12 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 S07 
                 0.01 
               
               
                 9/13 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 S07 
                 0.01 
               
               
                 9/14 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B02 
                 0.22 
                 S07 
                 0.01 
               
               
                 9/15 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B02 
                 0.22 
                 S07 
                 0.01 
               
               
                 9/16 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B02 
                 0.33 
                 S07 
                 0.01 
               
               
                 9/17 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B02 
                 0.44 
                 S07 
                 0.01 
               
               
                 9/18 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B02 
                 0.50 
                 S07 
                 0.01 
               
               
                 9/19 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B03 
                 0.22 
                 S07 
                 0.01 
               
               
                 9/20 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B04 
                 0.22 
                 S07 
                 0.01 
               
               
                   
               
            
           
         
       
     
     These papers were then subjected to printing tests using a Heidelberg GT046 printing press with a K+E 123w ink and a fountain of 4% Emerald Premium with 10% isopropanol. The resulting prints were evaluated on the basis of tape tests, powder tests, dot-gain evaluated with a Gretag Spectroeye densitometer, print mottle and scratch resistance with the results being given in Table 15 below. 
     
       
         
           
               
               
               
               
               
             
               
                   
                 TABLE 15 
               
             
            
               
                   
                   
               
               
                   
                   
                   
                 Dot 
                   
               
               
                   
                 Binder 
                   
                 gain 
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                 Example 
                   
                 coverage 
                 Tape test 
                 Powder 
                 50% 
                 print 
                 Scratch 
               
               
                 No.. 
                 No. 
                 [g/m 2 ] 
                 dry 10 min 
                 test 
                 screen 
                 mottle 
                 resistance 
               
               
                   
               
               
                 9/1  
                 — 
                 — 
                 strong 
                 OK 
                 20 
                 no 
                 OK 
               
               
                 Dispercoll 
                   
                   
                 cohesive 
               
               
                 U53 
                   
                   
                 break 
               
               
                 9/2  
                 — 
                 — 
                 strong 
                 OK 
                   
                 yes 
                 OK 
               
               
                   
                   
                   
                 cohesive 
               
               
                   
                   
                   
                 break 
               
               
                 9/3  
                 B01 
                 0.22 
                 strong 
                 light 
                 22 
                 no 
                 OK 
               
               
                   
                   
                   
                 cohesive 
               
               
                   
                   
                   
                 break 
               
               
                 9/4  
                 B01 
                 0.20 
                 OK 
                 powdery 
                 33 
                 no 
                 OK 
               
               
                 9/5  
                 B01 
                 0.20 
                 light 
                 powdery 
                   
                 no 
                 OK 
               
               
                   
                   
                   
                 cohesive 
               
               
                   
                   
                   
                 break 
               
               
                 9/6  
                 B02 
                 0.22 
                 strong 
                 light 
                 20 
                 yes 
                 OK 
               
               
                   
                   
                   
                 cohesive 
               
               
                   
                   
                   
                 break 
               
               
                 9/7  
                 B02 
                 0.20 
                 strong 
                 OK 
                 31 
                 no 
                 OK 
               
               
                   
                   
                   
                 cohesive 
               
               
                   
                   
                   
                 break 
               
               
                 9/8  
                 B03 
                 0.22 
                 strong 
                 OK 
                 22 
                 no 
                 OK 
               
               
                   
                   
                   
                 cohesive 
               
               
                   
                   
                   
                 break 
               
               
                 9/9  
                 B04 
                 0.22 
                 strong 
                 OK 
                 22 
                 no 
                 OK 
               
               
                   
                   
                   
                 cohesive 
               
               
                   
                   
                   
                 break 
               
               
                 9/10 
                 B01 
                 0.20 
                 OK 
                 OK 
                   
                 slight 
                 OK 
               
               
                   
                 IN02 
                 0.20 
               
               
                 FLX5010 
                 — 
                 — 
                 light 
                 light 
                 23 
                 no 
                 OK 
               
               
                 9/11 
                   
                   
                 cohesive 
               
               
                   
                   
                   
                 break 
               
               
                 9/12 
                 B01 
                 0.22 
                 OK 
                 OK 
                 19 
                 no 
                 OK 
               
               
                 9/13 
                 B01 
                 0.22 
                 — 
                 — 
                 26 
                 no 
                 OK 
               
               
                 9/14 
                 B02 
                 0.22 
                 strong 
                 OK 
                 23 
                 yes 
                 OK 
               
               
                   
                   
                   
                 cohesive 
               
               
                   
                   
                   
                 break 
               
               
                 9/15 
                 B02 
                 0.22 
                 — 
                 — 
                 27 
                 no 
                 OK 
               
               
                 9/16 
                 B02 
                 0.33 
                 — 
                 — 
                 27 
                 no 
                 OK 
               
               
                 9/17 
                 B02 
                 0.44 
                 — 
                 — 
                 28 
                 no 
                 OK 
               
               
                 9/18 
                 B02 
                 0.50 
                 — 
                 — 
                 28 
                 no 
                 OK 
               
               
                 9/19 
                 B03 
                 0.22 
                 OK 
                 OK 
                 24 
                 no 
                 OK 
               
               
                 9/20 
                 B04 
                 0.22 
                 OK 
                 OK 
                 24 
                 no 
                 OK 
               
               
                   
               
            
           
         
       
     
     Surprisingly it was found that the papers with L03 as latex exhibited strong cohesive fracture in the receiving layer, whether or not a binder was used except when a combination of B01 and IN02 was used. The papers with L04 as latex only exhibited strong cohesive fracture when a polyvinyl alcohol with a low degree of hydrolysis, e.g. 74%, was used as a binder and the use polyvinyl alcohol with a degree of hydrolysis of at least 87-88% improved the resistance of the receiving layer to cohesive fracture. Increasing the concentration of B02 was not possible due to foaming and high viscosities. 
     Example 10 
     Printing Performance with Added Binder and/or Hardeners 
     The non-transparent microvoided biaxially stretched self-supporting films 1/LS1/BS1 coated with subbing layer 3 was coated with the compositions in Table 16 including a binder to improve reduce the print mottle. 
     
       
         
           
               
               
               
               
               
               
             
               
                   
                 TABLE 16 
               
             
            
               
                   
                   
               
               
                   
                 Porous 
                   
                   
                   
                   
               
               
                   
                 pigment 
                 Latex 
                 Binder 
                 matting agent 
                 Surfactants 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Example 
                   
                 coverage 
                   
                 coverage 
                   
                 coverage 
                   
                 coverage 
                   
                 coverage 
               
               
                 No. 
                 No. 
                 [g/m 2 ] 
                 No. 
                 [g/m 2 ] 
                 No. 
                 [g/m 2 ] 
                 No. 
                 [g/m 2 ] 
                 No. 
                 [g/m 2 ] 
               
               
                   
               
               
                 10/1 
                 PP21 
                 2.0 
                 L01 
                 2.0 
                 B01 
                 0.2 
                 MA01 
                 0.06 
                 S05 
                 0.02 
               
               
                 FLX5000 
                   
                   
                   
                   
                   
                   
                   
                   
                 S06 
                 0.04 
               
               
                 10/2 
                 PP21 
                 3.0 
                 L01 
                 3.0 
                 B01 
                 0.3 
                 MA01 
                 0.06 
                 S05 
                 0.02 
               
               
                 FLX5000 
                   
                   
                   
                   
                   
                   
                   
                   
                 S06 
                 0.04 
               
               
                 10/3 
                 PP21 
                 2.0 
                 L01 
                 2.0 
                 B01 
                 0.2 
                 MA01 
                 0.06 
                 S05 
                 0.02 
               
               
                 FLX5000 
                   
                   
                   
                   
                   
                   
                   
                   
                 S06 
                 0.04 
               
               
                 10/4 
                 PP21 
                 2.0 
                 L01 
                 2.0 
                 B01 
                 0.2 
                 MA01 
                 0.06 
                 S05 
                 0.02 
               
               
                 FLX5000 
                   
                   
                   
                   
                   
                   
                   
                   
                 S06 
                 0.04 
               
               
                 10/5 
                 PP21 
                 2.0 
                 L03 
                 2.0 
                 B01 
                 0.2 
                 MA01 
                 0.06 
                 S05 
                 0.02 
               
               
                 Dispercoll 
                   
                   
                   
                   
                   
                   
                   
                   
                 S06 
                 0.04 
               
               
                 U53 
               
               
                 10/6 
                 PP21 
                 2.0 
                 L01 
                 2.0 
                 B01 
                 0.2 
                 MA01 
                 0.06 
                 S05 
                 0.02 
               
               
                 FLX5000 
                   
                   
                   
                   
                   
                   
                   
                   
                 S06 
                 0.04 
               
               
                   
               
            
           
         
       
     
     These papers were then subjected to printing tests using an A.B. Dick 9860 with a K+E 123w ink and a fountain of 4% Emerald Premium in isopropanol. During the printing first the quantity of fountain was varied for a constant quantity of ink and then the quantity of fountain was kept constant and the quantity of ink varied. The resulting prints were evaluated on the basis of solid optical densities and dot gain with a Gretag Spectroeye densitometer with the results being given in Table 17. Furthermore, print penetration and drying time tests were carried out on the papers with an IGT Global Standard Tester 2, with the results also being given in Table 17. 
     
       
         
           
               
               
             
               
                   
                 TABLE 17 
               
             
            
               
                   
                   
               
               
                   
                 Example No. 
               
            
           
           
               
               
               
               
               
               
               
            
               
                   
                 10/1 
                 10/2 
                 10/3 
                 10/4 
                 10/5 
                 10/6 
               
               
                   
                   
               
            
           
           
               
            
               
                 Fountain environment 
               
            
           
           
               
               
               
               
               
               
               
            
               
                 optimum 
                 45% Dg 
                 45% Dg 
                 45% Dg 
                 45% Dg 
                 45% Dg 
                 45% Dg 
               
               
                 window below 
                 10% 
                 10% 
                 10% 
                  5% 
                 10% 
                 10% 
               
               
                 window above 
                 20% 
                 15% 
                 15% 
                 15% 
                 30% 
                 30% 
               
            
           
           
               
            
               
                 Ink environment 
               
            
           
           
               
               
               
               
               
               
               
            
               
                 optimum ink 
                 10 
                 10 
                 10 
                   
                 8 
                   
               
               
                 setting 
               
               
                 window below 
                 0 
                 0 
                 0 
                   
                 4 
               
               
                 window above 
                 10 
                 5 
                 5 
                   
                 8 
               
            
           
           
               
            
               
                 dot gain for 50% screen at optimum setting 
               
            
           
           
               
               
               
               
               
               
               
            
               
                 Gretag 
                 26% 
                 23% 
                 24% 
                 25% 
                 22% 
                 28% 
               
               
                 Spectroeye 
               
               
                 mottle 
                 slight 
                 slight 
                 v. slight 
                 v. slight 
                 no 
                 v. slight 
               
            
           
           
               
            
               
                 print penetration test with IGT Global Standard Tester 2 
               
            
           
           
               
               
               
               
               
               
               
            
               
                 length of ink 
                 89.3 
                 90.7 
                 90.3 
                 91.3 
                 89.0 
                 90.3 
               
               
                 streak on 
               
               
                 rotating 
               
               
                 drum [mm] 
               
               
                 optical density 
                 0.59 
                 0.67 
                 0.56 
                 0.57 
                 0.49 
                 0.56 
               
            
           
           
               
            
               
                 set-off test with Huber set-off ink with IGT Global Standard Tester 2 
               
            
           
           
               
               
               
               
               
               
               
            
               
                 drying time [s] 
                 8 
                 &gt;11 
                 &gt;11 
                 7 
                 5 
                 5 
               
               
                   
               
            
           
         
       
     
     Using the paper of EXAMPLE 10/1 as a reference, the paper of EXAMPLE 10/2 with an increased layer thickness gave a marginally improved set-off performance and significantly reduced dot gain. The paper of EXAMPLE 10/3 with Zonyl FS0100, S07, as a surfactant rather than a mixture of surfactants exhibited similar set-off properties, but exhibited significantly reduced dot gain. However, the paper of EXAMPLE 10/4 with double the quantity of surfactant S07 resulted in a further reduction in dot gain, but at the expense of coating defects. Adding the silica and binder together, as in the paper of EXAMPLE 10/6, had no effect on the printing performance. 
     A comparison of the printing performance of the paper of EXAMPLE 10/5 with that of EXAMPLE 10/1 shows that the change in the latex from Latex 01 to Latex 03 resulted in a significant improvement: a reduction in set-off, i.e. in drying speed together with a significant reduction in dot gain. 
     Example 11 
     The non-transparent microvoided biaxially stretched self-supporting films 1/LS1/BS1 coated with subbing layer 3 was coated with the compositions in Table 18 including a binder to improve reduce the print mottle. 
     
       
         
           
               
               
               
               
               
             
               
                   
                 TABLE 18 
               
             
            
               
                   
                   
               
               
                   
                 Porous 
                   
                   
                   
               
               
                   
                 pigment 
                 Latex 
                 Binder 
                 Surfactant 
               
            
           
           
               
               
               
               
               
               
               
               
               
            
               
                 Example 
                   
                 coverage 
                   
                 coverage 
                   
                 coverage 
                   
                 coverage 
               
               
                 No. 
                 No. 
                 [g/m 2 ] 
                 No. 
                 [g/m 2 ] 
                 No. 
                 [g/m 2 ] 
                 No. 
                 [g/m 2 ] 
               
               
                   
               
               
                 11/1 
                 PP21 
                 2.6 
                 L04 
                 2.6 
                 B01 
                 0.26 
                 S07 
                 0.01 
               
               
                 FLX5010 
               
               
                 11/2 
                 PP21 
                 3.0 
                 L04 
                 3.0 
                 B01 
                 0.30 
                 S07 
                 0.01 
               
               
                 FLX5010 
               
               
                 11/3 
                 PP21 
                 4.0 
                 L04 
                 4.0 
                 B01 
                 0.40 
                 S07 
                 0.01 
               
               
                 FLX5010 
               
               
                 11/4 
                 PP21 
                 2.0 
                 L04 
                 2.0 
                 B01 
                 0.20 
                 S07 
                 0.01 
               
               
                 FLX5010 
               
               
                 11/5 
                 PP21 
                 2.6 
                 L03 
                 2.6 
                 B01 
                 0.26 
                 S07 
                 0.01 
               
               
                 Dispercoll 
               
               
                 U53 
               
               
                 11/6 
                 PP21 
                 3.0 
                 L03 
                 3.0 
                 B01 
                 0.30 
                 S07 
                 0.01 
               
               
                 Dispercoll 
               
               
                 U53 
               
               
                 11/7 
                 PP21 
                 4.0 
                 L03 
                 4.0 
                   
                 0.40 
                 S07 
                 0.01 
               
               
                 Dispercoll 
               
               
                 U53 
               
               
                 11/8 
                 PP21 
                 2.0 
                 L03 
                 2.0 
                   
                 0.20 
                 S07 
                 0.01 
               
               
                 Dispercoll 
               
               
                 U53 
               
               
                   
               
            
           
         
       
     
     Print penetration tests were carried out on the papers of EXAMPLES 11/1 to 11/8 with an IGT Global Standard Tester 2, with the results also being given in Table 19. 
     
       
         
           
               
               
             
               
                   
                 TABLE 19 
               
             
            
               
                   
                   
               
               
                   
                 Example No. 
               
            
           
           
               
               
               
               
               
               
               
               
               
            
               
                   
                 11/1 
                 11/2 
                 11/3 
                 11/4 
                 11/5 
                 11/6 
                 11/7 
                 11/8 
               
               
                   
                   
               
            
           
           
               
            
               
                 print penetration test with IGT Global Standard Tester 2 
               
            
           
           
               
               
               
               
               
               
               
               
               
            
               
                 length 
                 109.7 
                 113.3 
                 89.7 
                 100.3 
                 83.3 
                 88 
                 81 
                 85.7 
               
               
                 of ink 
               
               
                 streak 
               
               
                 on 
               
               
                 rotating 
               
               
                 drum 
               
               
                 [mm] 
               
               
                 optical 
                 0.54 
                 0.51 
                 0.66 
                 0.55 
                 0.60 
                 0.69 
                 0.80 
                 0.53 
               
               
                 density 
               
               
                   
               
            
           
         
       
     
     The results in Table xx clearly show the more rapid penetration of ink into layers containing Latex 03, Dispercoll U53, compared to comparable layers containing Latex 04, JONCRYL FLX5010. 
     Example 12 
     Evaluation of Matting Agents 
     The non-transparent microvoided biaxially stretched self-supporting films 1/LS1/BS1 coated with subbing layer 3 was coated with the compositions in Table 20 including different matting agents to improve the transport properties of the papers. 
     
       
         
           
               
               
               
               
               
               
             
               
                   
                 TABLE 20 
               
             
            
               
                   
                   
               
               
                   
                 Porous 
                   
                   
                   
                   
               
               
                   
                 pigment 
                 Latex 
                 Binder 
                 matting agent 
                 Surfactants 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
            
               
                 Example 
                   
                 coverage 
                   
                 coverage 
                   
                 coverage 
                   
                 coverage 
                   
                 coverage 
               
               
                 No. 
                 No. 
                 [g/m 2 ] 
                 No. 
                 [g/m 2 ] 
                 No. 
                 [g/m 2 ] 
                 No. 
                 [g/m 2 ] 
                 No. 
                 [g/m 2 ] 
               
               
                   
               
               
                 12/1  
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 — 
                 — 
                 S07 
                 0.01 
               
               
                 FLX5010 
               
               
                 12/2  
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 — 
                 — 
                 S07 
                 0.01 
               
               
                 12/3  
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 — 
                 — 
                 S07 
                 0.01 
               
               
                 12/4  
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA01 
                 0.05 
                 S07 
                 0.01 
               
               
                 12/5  
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA01 
                 0.1 
                 S07 
                 0.01 
               
               
                 12/6  
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA01 
                 0.1 
                 S07 
                 0.01 
               
               
                 12/7  
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA01 
                 0.1 
                 S07 
                 0.01 
               
               
                 12/8  
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA01 
                 0.1 
                 S07 
                 0.01 
               
               
                 12/9  
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA01 
                 0.15 
                 S07 
                 0.01 
               
               
                 12/10 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA01 
                 0.20 
                 S07 
                 0.01 
               
               
                 12/11 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA01 
                 0.25 
                 S07 
                 0.01 
               
               
                 12/12 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA01 
                 0.25 
                 S07 
                 0.01 
               
               
                 12/13 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA01 
                 0.30 
                 S07 
                 0.01 
               
               
                 12/14 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA01 
                 0.5 
                 S07 
                 0.01 
               
               
                 12/15 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA02 
                 0.1 
                 S07 
                 0.01 
               
               
                 12/16 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA03 
                 0.1 
                 S07 
                 0.01 
               
               
                 12/17 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA04 
                 0.1 
                 S07 
                 0.01 
               
               
                 12/18 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA05 
                 0.1 
                 S07 
                 0.01 
               
               
                 12/19 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA06 
                 0.1 
                 S07 
                 0.01 
               
               
                 12/20 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA07 
                 0.1 
                 S07 
                 0.01 
               
               
                 12/21 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA08 
                 0.1 
                 S07 
                 0.01 
               
               
                 12/22 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA09 
                 0.1 
                 S07 
                 0.01 
               
               
                 12/23 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA10 
                 0.04 
                 S07 
                 0.01 
               
               
                 12/24 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA10 
                 0.06 
                 S07 
                 0.01 
               
               
                 12/25 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA10 
                 0.08 
                 S07 
                 0.01 
               
               
                 12/26 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA10 
                 0.1 
                 S07 
                 0.01 
               
               
                 12/27 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA10 
                 0.1 
                 S07 
                 0.01 
               
               
                 12/28 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA11 
                 0.1 
                 S07 
                 0.01 
               
               
                 12/29 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA12 
                 0.04 
                 S07 
                 0.01 
               
               
                 12/30 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA12 
                 0.06 
                 S07 
                 0.01 
               
               
                 12/31 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA12 
                 0.08 
                 S07 
                 0.01 
               
               
                 12/32 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA12 
                 0.1 
                 S07 
                 0.01 
               
               
                 12/33 
                 PP21 
                 2.2 
                 L04 
                 2.2 
                 B01 
                 0.22 
                 MA12 
                 0.1 
                 S07 
                 0.01 
               
               
                   
               
            
           
         
       
     
     The papers were evaluated in a series of tests to establish the physical effect of the matting agents on the surface smoothness and the frictional coefficient between sheets. Surface roughness was determined by Bekk tests and Perth-O-meter measurements. 
     Furthermore the scratch resistance was evaluated qualitatively using a nail test and quantitatively using the Linimark evaluation method with a Roberta apparatus giving the threshold force at and above which scratching was observed. The results are summarized in Table 21 below. 
     
       
         
           
               
               
             
               
                   
                 TABLE 21 
               
             
            
               
                   
                   
               
               
                   
                 Scratch resistance tests 
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                   
                   
                   
                 R a  from 
                   
                   
                 Lini- 
                   
               
               
                   
                 matting agent 
                 Bekk 
                 Pert-O- 
                   
                   
                 mark 
               
            
           
           
               
               
               
               
               
               
               
               
               
            
               
                 Example 
                   
                 coverage 
                 test 
                 meter 
                 Static frictional 
                 nail 
                 wet 
                 Lini-mark dry 
               
               
                 No. 
                 No. 
                 [g/m 2 ] 
                 [sec] 
                 [μm] 
                 coefficient 
                 test 
                 [mN] 
                 [mN] 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
            
               
                 12/1  
                 — 
                 — 
                 2285 
                 0.36 
                 0.76 
                 OK 
                   
                   
               
               
                 12/2  
                 — 
                 — 
                 1205 
                 — 
                 — 
                 ca. 
               
               
                   
                   
                   
                   
                   
                   
                 OK 
               
               
                 12/3  
                 — 
                 — 
                 1701 
                   
                   
                 ca. 
               
               
                   
                   
                   
                   
                   
                   
                 OK 
               
               
                 12/4  
                 MA01 
                 0.05 
                 1175 
                 — 
                 — 
                 ca. 
               
               
                   
                   
                   
                   
                   
                   
                 OK 
               
               
                 12/5  
                 MA01 
                 0.1 
                 1407 
                 0.34 
                 0.61 
                 OK 
               
               
                 12/6  
                 MA01 
                 0.1 
                 1147 
                 — 
                 — 
                 ca. 
               
               
                   
                   
                   
                   
                   
                   
                 OK 
               
               
                 12/7  
                 MA01 
                 0.1 
                 1406 
                   
                   
                 ca. 
               
               
                   
                   
                   
                   
                   
                   
                 OK 
               
               
                 12/8  
                 MA01 
                 0.1 
                 1737 
                   
                   
                 OK 
                 21 
                 33 
               
               
                 12/9  
                 MA01 
                 0.15 
                 1108 
                 — 
                 — 
                 ca. 
               
               
                   
                   
                   
                   
                   
                   
                 OK 
               
               
                 12/10 
                 MA01 
                 0.20 
                 1187 
                 — 
                 — 
                 ca. 
               
               
                   
                   
                   
                   
                   
                   
                 OK 
               
               
                 12/11 
                 MA01 
                 0.25 
                 1025 
                 0.50 
                 0.61 
                 OK 
               
               
                 12/12 
                 MA01 
                 0.25 
                 1061 
                 — 
                 — 
                 ca. 
               
               
                   
                   
                   
                   
                   
                   
                 OK 
               
               
                 12/13 
                 MA01 
                 0.30 
                 1009 
                 — 
                 — 
                 ca. 
               
               
                   
                   
                   
                   
                   
                   
                 OK 
               
               
                 12/14 
                 MA01 
                 0.5 
                 854 
                 0.48 
                 0.55 
                 ca. 
               
               
                   
                   
                   
                   
                   
                   
                 OK 
               
               
                 12/15 
                 MA02 
                 0.1 
                 409 
                 0.37 
                 0.69 
                 v. 
               
               
                   
                   
                   
                   
                   
                   
                 good 
               
               
                 12/16 
                 MA03 
                 0.1 
                 1153 
                 0.33 
                 0.78 
                 not 
               
               
                   
                   
                   
                   
                   
                   
                 OK 
               
               
                 12/17 
                 MA04 
                 0.1 
                 152.3 
                 0.58 
                 0.84 
                 not 
               
               
                   
                   
                   
                   
                   
                   
                 OK 
               
               
                 12/18 
                 MA05 
                 0.1 
                 423 
                   
                   
                 ca. 
               
               
                   
                   
                   
                   
                   
                   
                 OK 
               
               
                 12/19 
                 MA06 
                 0.1 
                 258 
                   
                   
                 ca. 
               
               
                   
                   
                   
                   
                   
                   
                 OK 
               
               
                 12/20 
                 MA07 
                 0.1 
                 685 
                   
                   
                 ca. 
               
               
                   
                   
                   
                   
                   
                   
                 OK 
               
               
                 12/21 
                 MA08 
                 0.1 
                 291 
                   
                   
                 OK 
               
               
                 12/22 
                 MA09 
                 0.1 
                 566 
                   
                   
                 OK 
               
               
                 12/23 
                 MA10 
                 0.04 
                 462 
                   
                   
                 OK 
                 15 
                 20 
               
               
                 12/24 
                 MA10 
                 0.06 
                 392 
                   
                   
                 OK 
                 15 
                 26 
               
               
                 12/25 
                 MA10 
                 0.08 
                 245 
                   
                   
                 OK 
                 17 
                 29 
               
               
                 12/26 
                 MA10 
                 0.1 
                 491 
                   
                   
                 OK 
               
               
                 12/27 
                 MA10 
                 0.1 
                 228 
                   
                   
                 OK 
                 19 
                 34 
               
               
                 12/28 
                 MA11 
                 0.1 
                 816 
                   
                   
                 ca. 
               
               
                   
                   
                   
                   
                   
                   
                 OK 
               
               
                 12/29 
                 MA12 
                 0.04 
                 116 
                   
                   
                 ca. 
               
               
                   
                   
                   
                   
                   
                   
                 OK 
               
               
                 12/30 
                 MA12 
                 0.06 
                 61 
                   
                   
                 ca. 
               
               
                   
                   
                   
                   
                   
                   
                 OK 
               
               
                 12/31 
                 MA12 
                 0.08 
                 49 
                   
                   
                 ca. 
               
               
                   
                   
                   
                   
                   
                   
                 OK 
               
               
                 12/32 
                 MA12 
                 0.1 
                 170 
                   
                   
                 OK 
               
               
                 12/33 
                 MA12 
                 0.1 
                 34 
                   
                   
                 ca. 
               
               
                   
                   
                   
                   
                   
                   
                 OK 
               
               
                   
               
            
           
         
       
     
     The Bekk tests showed that a greater surface roughness was realized with matting agents MA02 and MA04 to MA12 than with MA01 or MA03, whereas according to the Pert-O-meter measurements papers with MA01 and MA04 exhibited higher R a  values than with MA02 and MA03. The frictional measurements showed a significant reduction in friction with matting agents MA01 and MA02, whereas the paper of EXAMPLE 12/13 exhibited no significant change and the paper of EXAMPLE 12/14 showed an increase in frictional coefficients. 
     Printing evaluation was carried out using a Heidelberg GT046 printing press with a K+E 123W ink and a fountain of 4% Emerald Premium with 10% isopropanol with an Azura printing plate exposed at 275 mJ/cm 2  with a CREO exposure station. The printing results are summarized in Table 22 below. 
     
       
         
           
               
               
               
               
               
               
             
               
                   
                 TABLE 22 
               
             
            
               
                   
                   
               
               
                   
                   
                 Tape 
                   
                   
                 IGT test 
               
               
                   
                 matting agent 
                 test 
                 dot gain 
                   
                 time to 
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                 Example 
                   
                 coverage 
                 dry 
                   
                 for 50% 
                 Print 
                 avoid set- 
               
               
                 No. 
                 No. 
                 [g/m 2 ] 
                 [10 min] 
                 Powder test 
                 screen 
                 mottle 
                 off [s] 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                 12/1  
                 — 
                 — 
                 OK 
                 slight 
                 27 
                 no 
                   
               
               
                 12/2  
                 — 
                 — 
                 — 
                 OK 
                   
                 yes/no 
                 9 
               
               
                 12/3  
                 — 
                 — 
                 OK 
                 v. slight 
                 24 
                 yes/no 
               
               
                 12/4  
                 MA01 
                 0.05 
                 — 
                 OK 
                   
                 no 
                 24 
               
               
                 12/5  
                 MA01 
                 0.1 
                 OK 
                 v. slight 
                 26 
                 no 
               
               
                 12/6  
                 MA01 
                 0.1 
                 — 
                 OK 
                   
                 no 
                 13 
               
               
                 12/7  
                 MA01 
                 0.1 
                 OK 
                 v. slight 
                 23 
                 yes/no 
               
               
                 12/8  
                 MA01 
                 0.1 
                 OK 
                 OK 
                 28 
                 no 
               
               
                 12/9  
                 MA01 
                 0.15 
                 — 
                 OK 
                   
                 yes/no 
                 18 
               
               
                 12/10 
                 MA01 
                 0.20 
                 — 
                 OK 
                   
                 yes/no 
                 18 
               
               
                 12/11 
                 MA01 
                 0.25 
                 OK 
                 v. slight 
                 26 
                 no 
               
               
                 12/12 
                 MA01 
                 0.25 
                 — 
                 OK 
                   
                 yes/no 
                 18 
               
               
                 12/13 
                 MA01 
                 0.30 
                 — 
                 OK 
                   
                 yes/no 
                 18 
               
               
                 12/14 
                 MA01 
                 0.5 
                 OK 
                 v. slight 
                 27 
                 no 
               
               
                 12/15 
                 MA02 
                 0.1 
                 OK 
                 v. slight 
                 29 
                 no 
               
               
                 12/16 
                 MA03 
                 0.1 
                 OK 
                 slight 
                 31 
                 no 
               
               
                 12/17 
                 MA04 
                 0.1 
                 OK 
                 v. slight 
                 26 
                 no 
               
               
                 12/18 
                 MA05 
                 0.1 
                 OK 
                 powdery 
                 23 
                 yes/no 
               
               
                 12/19 
                 MA06 
                 0.1 
                 OK 
                 v. slight 
                 23 
                 yes/no 
               
               
                 12/20 
                 MA07 
                 0.1 
                 OK 
                 v. slight 
                 23 
                 yes/no 
               
               
                 12/21 
                 MA08 
                 0.1 
                 OK 
                 v. slight 
                 23 
                 yes/no 
               
               
                 12/22 
                 MA09 
                 0.1 
                 OK 
                 powdery 
                 23 
                 yes/no 
               
               
                 12/23 
                 MA10 
                 0.04 
                 OK 
                 OK 
                 28 
                 no 
               
               
                 12/24 
                 MA10 
                 0.06 
                 OK 
                 OK 
                 28 
                 no 
               
               
                 12/25 
                 MA10 
                 0.08 
                 OK 
                 OK 
                 28 
                 no 
               
               
                 12/26 
                 MA10 
                 0.1 
                 OK 
                 v. good 
                 23 
                 yes/no 
               
               
                 12/27 
                 MA10 
                 0.1 
                 OK 
                 OK 
                 28 
                 no 
               
               
                 12/28 
                 MA11 
                 0.1 
                 OK 
                 powdery 
                 23 
                 yes/no 
               
               
                 12/29 
                 MA12 
                 0.04 
                 OK 
                 OK 
                 28 
                 no 
               
               
                 12/30 
                 MA12 
                 0.06 
                 OK 
                 OK 
                 27 
                 no 
               
               
                 12/31 
                 MA12 
                 0.08 
                 OK 
                 OK 
                 27 
                 no 
               
               
                 12/32 
                 MA12 
                 0.1 
                 OK 
                 v. slight 
                 22 
                 yes/no 
               
               
                 12/33 
                 MA12 
                 0.1 
                 OK 
                 OK 
                 27 
                 no 
               
               
                   
               
            
           
         
       
     
     An increase in dot gain was observed with papers with MA02 and MA03 and a slight reduction in the case of MA01 and MA04 to MAl2. The scratch resistance of the papers was improved with the matting agents MA2 (polyethylene particles), MA8 (benzoguanine-melamine/formaldehyde particles), MA9 (polyamide particles) and MA 10 (ethylene-acrylic acid copolymer particles), was acceptable with the matting agent MA1, but deteriorated with matting agents MA3 and MA4. 
     Example 13 
     Printing Performance 
     The film 1/LS1/BS1 subbed with subbing layer 3 was coated with a single layer on both sides of the different receiving layer with the compositions and coating weights given in Table 23. 
     
       
         
           
               
               
               
               
               
               
               
               
             
               
                 TABLE 23 
               
             
            
               
                   
               
               
                   
                   
                   
                   
                 Slip 
                   
                   
                   
               
               
                   
                   
                 Porous 
                   
                 agent/matting 
                   
                   
                 Coating 
               
               
                 Example 
                 Latex 
                 pigment 
                 Binder 
                 agent 
                 Surfactant 
                 Proxel 
                 wt 
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 No. 
                 No. 
                 wt % 
                 No. 
                 wt % 
                 No. 
                 wt % 
                 No. 
                 wt % 
                 No. 
                 wt % 
                 wt % 
                 [g/m 2 ] 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
               
               
               
               
            
               
                 13/1 
                 L01 
                 67.8 
                 PP21 
                 25.4 
                 — 
                 — 
                 SL01 
                 6.8 
                 — 
                 — 
                   
                 2.95 
               
               
                 FLX5000 
               
               
                 13/2 
                 L01 
                 67.5 
                 PP21 
                 25.3 
                 — 
                 — 
                 SL01 
                 6.8 
                 S05 
                 0.2 
                   
                 2.96 
               
               
                 FLX5000 
                   
                   
                   
                   
                   
                   
                   
                   
                 S06 
                 0.1 
               
               
                 13/3 
                 L01 
                 55.4 
                 PP21 
                 41.5 
                 — 
                 — 
                 MA15 
                 2.8 
                 S05 
                 0.2 
                   
                 3.61 
               
               
                 FLX5000 
                   
                   
                   
                   
                   
                   
                   
                   
                 S06 
                 0.1 
               
               
                 13/4 
                 L04 
                 47.58 
                 PP21 
                 47.48 
                 B01 
                 4.76 
                 — 
                 — 
                 S07 
                 0.18 
                   
                 4.84 
               
               
                 FLX5010 
               
               
                 13/5 
                 L03 
                 47.5 
                 PP21 
                 47.5 
                 B01 
                 4.8 
                 — 
                 — 
                 S07 
                 0.2 
                   
                 4.38 
               
               
                 Dispercoll 
               
               
                 U53 
               
               
                 13/6 
                 L04 
                 46.62 
                 PP21 
                 46.51 
                 B01 
                 4.66 
                 MA01 
                 2.0 
                 S07 
                 0.17 
                 0.004 
                 4.94 
               
               
                 FLX5010 
               
               
                   
               
            
           
         
       
     
     A single layer with the composition of EXAMPLE 6 was also successfully coated on film 1/LS1/BS1 subbed with subbing layers 4 and 5. Furthermore, it could be coated on corona-treated PGA paper, corona-treated KLEPA paper and also on cast-coated paper. 
     The most significant differences in the papers of EXAMPLES 3 to 8 lie in the coating weight of the porous pigment PP21 rising from 0.75 g/m2 for the papers of EXAMPLES 3 and 4 to 1.5 g/m2 in the case of the paper of EXAMPLE 5 to 2.9 g/m2 in the case of the papers of EXAMPLES 6 and 7. This had a parallel effect on the drying behaviour of the papers, since the porosity of the receiving layers is determined by the quantity of porous pigment present therein, with the papers of EXAMPLES 3 and 4 exhibiting poor drying behaviour, whereas drying was acceptable in the case of the papers of EXAMPLES 5, 6 and 7. The scratch resistance of the papers of EXAMPLES 3, 4 and 5 was good, that of the paper of EXAMPLE 6 poor and those of the papers of EXAMPLES 7 and 8 made acceptable by the incorporation of a water-soluble binder to counter problems due to flaking. 
     The different latexes used had an influence upon the alkali resistance in which the paper of EXAMPLES 13/1, 13/2 and 13/3 with JONCRYL FLX5000 scored poorly, whereas the papers of EXAMPLES 13/4, 13/5 and 13/6 with JONCRYL FLX5010, also a styrene-acrylic latex and DISPERCOLL U53, a polyurethane resin scored well in this regard. However, DISPERCOLL U53 scored poorly in respect of UV-stability, whereas JONCRYL FLX 5000 and 5010 scored well in this regard. 
     The surface energies of the papers of EXAMPLES 13/3, 13/4, 13/5 and 13/6 were measured via contact angle measurements and the polar and disperse contributions determined. The results are summarized in Table 24. 
     
       
         
           
               
               
             
               
                   
                 TABLE 24 
               
             
            
               
                   
                   
               
               
                   
                 Surface free energy 
               
            
           
           
               
               
               
               
               
            
               
                 Example No. 
                 γSp mN/m 
                 γSd mN/m 
                 γS mN/m 
                 liquids used 
               
               
                   
               
            
           
           
               
               
               
               
               
            
               
                 13/3 
                 0.00 
                 34.12 
                 34.12 
                 all liquids 
               
               
                 13/4 
                 0.79 
                 41.92 
                 42.71 
                 only glycerine 
               
               
                   
                 2.59 
                 42.46 
                 45.06 
                 all liquids 
               
               
                 13/5 
                 34.40 
                 27.16 
                 61.56 
                 only glycerine 
               
               
                 13/6 
                 4.63 
                 39.86 
                 44.49 
                 all liquids 
               
               
                   
               
            
           
         
       
     
     These papers were then subjected to printing tests using a Heidelbery GT052 printing press equipped with a Dahlgren fountain system, which allowed the quantity of fountain by printing to be accurately set. During the printing first the quantity of fountain was varied for a constant quantity of ink and then the quantity of fountain was kept constant and the quantity of ink varied. The resulting prints were evaluated on the basis of solid optical densities and dot gain with a Gretag Spectroeye densitometer with the results being given in Table 25. 
     
       
         
           
               
               
             
               
                   
                 TABLE 25 
               
             
            
               
                   
                   
               
               
                   
                 Example No. 
               
            
           
           
               
               
               
               
               
               
               
            
               
                   
                 13/1 
                 13/2 
                 13/3 
                 13/4 
                 13/5 
                 13/6 
               
               
                   
                   
               
            
           
           
               
            
               
                 Fountain environment 
               
            
           
           
               
               
               
               
               
               
               
            
               
                 optimum 
                   
                   
                 50% Dg 
                 55% Dg 
                 50% Dg 
                 60% Dg 
               
               
                 window below 
                   
                   
                 20% 
                 25% 
                 20% 
                 25% 
               
               
                 window above 
                   
                   
                  5% 
                 20% 
                 25% 
                 25% 
               
            
           
           
               
            
               
                 Ink environment 
               
            
           
           
               
               
               
               
               
               
               
            
               
                 optimum ink setting 
                   
                   
                 8 
                 8 
                 8 
                 8 
               
               
                 window below 
                   
                   
                 4 
                 4 
                 4 
                 4 
               
               
                 window above 
                   
                   
                 2 
                 6 
                 6 
                 10  
               
            
           
           
               
            
               
                 dot gain for 50% screen at optimum setting 
               
            
           
           
               
               
               
               
               
               
               
            
               
                 Gretag Spectroeye 
                   
                   
                 30% 
                 19% 
                 16% 
                 16% 
               
               
                   
               
            
           
         
       
     
     The papers of EXAMPLES 13/1 and 13/2 had an acceptable printing window, but set-off was a problem due to the poor drying performance of these papers. EXAMPLES 13/4 and 13/5 had clearly a greater printing window and less dot gain than the paper of EXAMPLE 13/3. Furthermore, the paper of EXAMPLE 5 exhibited print mottle, which was not observed with the papers of EXAMPLES 13/4 and 13/5. The papers of EXAMPLES 13/4 and 13/5 exhibited no set-off, rapid drying even at high ink settings, stable printing performance and exhibited identical printing behaviour to paper. No significant difference was observed between the printing performances of the papers of EXAMPLES 13/4 and 13/5. 
     Example 14 
     Optimalization of Receiving Layer Composition 
     The subbed film 1/LS1/BS1 was coated with a single layer on both sides of the different receiving layer compositions in Table 26. 
     
       
         
           
               
               
               
               
               
               
               
               
               
             
               
                 TABLE 26 
               
               
                   
               
               
                   
                   
                   
                   
                   
                   
                 Total 
                   
                   
               
               
                   
                 latex 
                   
                 wt ratio 
                 binder 
                 Surfactact 
                 coating 
                 pore 
                 oil 
               
               
                 Example 
                 L04 
                 PP 12 
                 latex/porous 
                 B01 
                 S07 
                 weight 
                 volume* 
                 absorption* 
               
               
                 No. 
                 [g/m 2 ] 
                 [g/m 2 ] 
                 pigment 
                 [g/m 2 ] 
                 [g/m 2 ] 
                 [g/m 2 ] 
                 [mL/m 2 ] 
                 [mg/cm 2 ] 
               
               
                   
               
             
            
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
            
               
                 14/1  
                 2 
                 2 
                 1.00 
                 0.20 
                 0.01 
                   
                 3.2 
                 60 
               
               
                 14/2  
                 3 
                 2 
                 1.50 
                 0.20 
                 0.01 
                   
                 3.2 
                 60 
               
               
                 14/3  
                 4 
                 2 
                 2.00 
                 0.20 
                 0.01 
                   
                 3.2 
                 60 
               
               
                 14/4  
                 4 
                 3 
                 1.33 
                 0.20 
                 0.01 
                   
                 4.8 
                 90 
               
               
                 14/5  
                 4 
                 4 
                 1.00 
                 0.20 
                 0.01 
                   
                 6.4 
                 120 
               
               
                 14/6  
                 4 
                 3 
                 2.00 
                 0.20 
                 0.01 
                   
                 4.8 
                 90 
               
               
                 14/7  
                 2 
                 0.75 
                 2.67 
                 0.20 
                 0.01 
                   
                 1.2 
                 22.5 
               
               
                 14/8  
                 2 
                 1 
                 2.00 
                 0.20 
                 0.01 
                   
                 1.6 
                 30 
               
               
                 14/9  
                 2 
                 1.25 
                 1.60 
                 0.20 
                 0.01 
                   
                 2 
                 37.5 
               
               
                 14/10 
                 2 
                 1.5 
                 1.33 
                 0.20 
                 0.01 
                   
                 2.4 
                 45 
               
               
                 14/11 
                 2 
                 1.75 
                 1.14 
                 0.20 
                 0.01 
                   
                 2.8 
                 52.5 
               
               
                 14/12 
                 2 
                 2 
                 1.00 
                 0.20 
                 0.01 
                   
                 3.2 
                 60 
               
               
                 14/13 
                 2.5 
                 1.5 
                 1.67 
                 0.20 
                 0.01 
                   
                 2.4 
                 45 
               
               
                 14/14 
                 3 
                 1.5 
                 2.00 
                 0.20 
                 0.01 
                   
                 2.4 
                 45 
               
               
                 14/15 
                 3.5 
                 1.5 
                 2.33 
                 0.20 
                 0.01 
                   
                 2.4 
                 45 
               
               
                 14/16 
                 4 
                 1.5 
                 2.67 
                 0.20 
                 0.01 
                   
                 2.4 
                 45 
               
               
                 14/17 
                 2 
                 2 
                 1.00 
                 0.20 
                 0.01 
                 4.20 
                 3.2 
                 60 
               
               
                 14/18 
                 1.75 
                 1.75 
                 1.00 
                 0.17 
                 0.01 
                 3.67 
                 2.8 
                 52.5 
               
               
                 14/19 
                 1.5 
                 1.5 
                 1.00 
                 0.15 
                 0.01 
                 3.15 
                 2.4 
                 45 
               
               
                 14/20 
                 1.25 
                 1.25 
                 1.00 
                 0.12 
                 0.01 
                 2.62 
                 2 
                 37.5 
               
               
                 14/21 
                 1 
                 1 
                 1.00 
                 0.10 
                 0.01 
                 2.10 
                 1.6 
                 30 
               
               
                 14/22 
                 0.75 
                 0.75 
                 1.00 
                 0.07 
                 0.01 
                 1.57 
                 1.2 
                 22.5 
               
               
                 14/23 
                 0.5 
                 0.5 
                 1.00 
                 0.05 
                 0.01 
                 1.05 
                 0.8 
                 15 
               
               
                 14/24 
                 1.5 
                 1.5 
                 1.00 
                 0.20 
                 0.01 
                 3.20 
                 2.4 
                 45 
               
               
                 14/25 
                 1.0 
                 1.0 
                 1.00 
                 0.20 
                 0.01 
                 2.20 
                 1.6 
                 30 
               
               
                 14/26 
                 0.5 
                 0.5 
                 1.00 
                 0.20 
                 0.01 
                 1.20 
                 0.8 
                 15 
               
               
                   
               
               
                 *calculated on the basis of the coverage of porous pigment from a pore volume of 1.6 mL/g and oil absorption of 300 g/100 g 
               
            
           
         
       
     
     These papers were then subjected to printing tests using a Heidelberg GT052 printing press with K+E 123w ink and a 4% Emerald Premium fountain with 10% isopropanol. This printing press was equipped with a Dahlgren fountain system, which allowed the quantity of fountain by printing to be accurately set. 
     The print quality was evaluated both by qualitative visual inspection tests and quantitative tests with an IGT Global Tester-2 in which the drying time to avoid set-off was determined according to ISO 3783 and ink penetration evaluated on the basis of the track formed and optical density of a 0.6 μL coloured dibutyl phthalate droplet applied to a paper with the receiving layer composition being evaluated on a rotating drum according to NEN 1836. The results are also given in Table 27. 
     
       
         
           
               
               
               
             
               
                   
                 TABLE 27 
               
             
            
               
                   
                   
               
               
                   
                   
                 tests with IGT Global 
               
               
                   
                 visual inspection tests 
                 Standard Tester-2 
               
            
           
           
               
               
               
               
               
               
               
               
            
               
                   
                 pore 
                 oil 
                   
                   
                 drying 
                 ink penetration 
                 time to 
               
            
           
           
               
               
               
               
               
               
               
               
               
            
               
                 Example 
                 volume* 
                 absorption* 
                 print 
                   
                 time 
                 length 
                   
                 avoid set- 
               
               
                 No. 
                 [mL/m 2 ] 
                 [mg/cm 2 ] 
                 mottle 
                 set-off 
                 [hr] 
                 [mm] 
                 OD 
                 off [s] 
               
               
                   
               
            
           
           
               
               
               
               
               
               
               
               
               
            
               
                 14/1  
                 3.2 
                 60 
                 no 
                   
                   
                   
                   
                   
               
               
                 14/2  
                 3.2 
                 60 
                 yes 
               
               
                 14/3  
                 3.2 
                 60 
                 yes 
               
               
                 14/4  
                 4.8 
                 90 
                 yes 
               
               
                 14/5  
                 6.4 
                 120 
                 no 
               
               
                 14/6  
                 4.8 
                 90 
                 yes 
               
               
                 14/7  
                 1.2 
                 22.5 
                 yes 
                 yes 
               
               
                 14/8  
                 1.6 
                 30 
                 yes 
                 yes 
               
               
                 14/9  
                 2 
                 37.5 
                 yes 
                 no 
               
               
                 14/10 
                 2.4 
                 45 
                 yes 
                 no 
               
               
                 14/11 
                 2.8 
                 52.5 
                 yes 
                 no 
               
               
                 14/12 
                 3.2 
                 60 
                 no 
                 no 
               
               
                 14/13 
                 2.4 
                 45 
                 yes 
                 no 
               
               
                 14/14 
                 2.4 
                 45 
                 yes 
                 slight 
               
               
                 14/15 
                 2.4 
                 45 
                 yes 
                 yes 
               
               
                 14/16 
                 2.4 
                 45 
                 yes 
                 yes 
               
               
                 14/17 
                 3.2 
                 60 
                 no 
                 no 
                   
                 105.3 
                 0.53 
                 3 
               
               
                 14/18 
                 2.8 
                 52.5 
                 no 
                 no 
                   
                 108.7 
                 0.51 
                 3 
               
               
                 14/19 
                 2.4 
                 45 
                 no 
                 no 
                   
                 112.0 
                 0.5 
                 4 
               
               
                 14/20 
                 2 
                 37.5 
                 no 
                 no 
                   
                 109.3 
                 0.48 
                 5 
               
               
                 14/21 
                 1.6 
                 30 
                 no 
                 yes 
                 &gt;24 
                 116.0 
                 0.41 
                 6 
               
               
                 14/22 
                 1.2 
                 22.5 
                 yes/no 
                 yes 
                 &gt;24 
                 126.3 
                 0.36 
                 &gt;13 
               
               
                 14/23 
                 0.8 
                 15 
                 yes 
                 yes 
                 &gt;120 
                 143.0 
                 0.29 
                 &gt;13 
               
               
                 14/24 
                 2.4 
                 45 
                 no 
                 no 
                   
                 115.3 
                 0.51 
                 3 
               
               
                 14/25 
                 1.6 
                 30 
                 no 
                 no 
                   
                 121.3 
                 0.42 
                 5 
               
               
                 14/26 
                 0.8 
                 15 
                 no 
                 yes 
                 &gt;24 
                 139.7 
                 0.33 
                 &gt;13 
               
               
                   
               
            
           
         
       
     
     The results in Table 27 clearly show for receiving layers based on Latex 04 and porous pigment PP21 that the combined requirements of avoiding print mottle and avoiding set-off with sufficiently rapid drying could only be realized with a ca. 1:1 weight ratio of Latex 04 to porous pigment PP21 together with a sufficient coverage of both ingredients i.e. sufficient porosity. These results clearly show that the required results were only realized at or above a theoretically available pore volume in the layer of 1.5 mL/m 2 . Print mottle is due to the solvent content of the printing ink being absorbed too slowly and set-off is due to the ink drying insufficiently quickly. 
     It has been surprisingly found that excellent printing behaviour can be obtained by practicing the various aspects of the present invention, these aspects including but not limited to coating a water-resistant support with a single layer with a layer thickness of at least 3 μm, a pore volume of at least 1.2 mL/m 2  and which comprises at least one porous pigment. 
     The papers of the present invention provide, among other advantages, satisfactory printing under a wide range of printing conditions ensuring a constant printing quality over a long print run, e.g., variation in the quantity of ink, variation in the quantity of fountain in offset printing, with sufficiently fast drying to avoid offset of the image on following sheets (so-called ghost images) while ensuring that the ink is completely transferred to the paper during the printing process. These papers also exhibit acceptable whiteness, so not affect the colour of the print, exhibit acceptable opacity, are water-resistant, exhibit good scratch resistance, exhibit good chemical resistance to acids and alkali&#39;s and/or are suitable for outside applications, i.e., are resistant to UV-exposure and oxidation. 
     The present invention may include any feature or combination of features disclosed herein either implicitly or explicitly or any generalisation thereof. In view of the foregoing description it will be evident to a person skilled in the art that various modifications may be made within the scope of the invention. 
     Having described in detail preferred embodiments of the current invention, it will now be apparent to those skilled in the art that numerous modifications can be made therein without departing from the scope of the invention as defined in the following claims. 
     All references, including publications, patent applications, and patents, cited herein are hereby incorporated by reference to the same extent as if each reference were individually and specifically indicated to be incorporated by reference and were set forth in its entirety herein. 
     The use of the terms “a” and “an” and “the” and similar referents in the context of describing the invention (especially in the context of the following claims) are to be construed to cover both the singular and the plural, unless otherwise indicated herein or clearly contradicted by context. Recitation of ranges of values herein are merely intended to serve as a shorthand method of referring individually to each separate value falling within the range, unless otherwise indicated herein, and each separate value is incorporated into the specification as if it were individually recited herein. All methods described herein can be performed in any suitable order unless otherwise indicated herein or otherwise clearly contradicted by context. The use of any and all examples, or exemplary language (e.g., “such as”) provided herein, is intended merely to better illuminate the invention and does not pose a limitation on the scope of the invention unless otherwise claimed. No language in the specification should be construed as indicating any non-claimed element as essential to the practice of the invention. 
     Preferred embodiments of this invention are described herein, including the best mode known to the inventors for carrying out the invention. Of course, variations of those preferred embodiments will become apparent to those of ordinary skill in the art upon reading the foregoing description. The inventors expect skilled artisans to employ such variations as appropriate, and the inventors intend for the invention to be practiced otherwise than as specifically described herein. Accordingly, this invention includes all modifications and equivalents of the subject matter recited in the claims appended hereto as permitted by applicable law. Moreover, any combination of the above-described elements in all possible variations thereof is encompassed by the invention unless otherwise indicated herein or otherwise clearly contradicted by context.