Patent Publication Number: US-2023141218-A1

Title: Insulation

Description:
CROSS-REFERENCE TO RELATED APPLICATIONS 
     This application is a continuation of U.S. application Ser. No. 16/317,986, filed Jan. 15, 2019, which is a U.S. national counterpart application of International Application Serial No. PCT/EP2017/067861, filed Jul. 14, 2017, under 35 U.S.C. § 371, which claims priority to GB Application Serial No. 1612314.3, filed Jul. 15, 2016, the disclosures of which are hereby incorporated herein by reference. 
    
    
     TECHNICAL FIELD 
     This invention relates to an insulating product comprising mixed mineral wool fibres and a method of providing such an insulating product. 
     BACKGROUND 
     Thermal insulation is often provided to a support surface of a building element, for example as part of a ceiling, by securing an insulating panel of glass wool fibres or by projecting (also called spraying or wet spraying in the US) glass wool fibres with a binder towards the support surface of the building element. Whilst glass wool provides good thermal insulation, where desired fire resistance is required its softening point is generally too low. At temperatures at which fire resistant building insulation should function, and in appropriate tests simulating these conditions, the glass fibres soften or melt leading to destruction and failure of the glass wool insulation. 
     Rock wool fibres (also known as stone wool fibres) or slag wool have typically been used in to provide thermal insulation in building applications where a level of fire resistance is also required. The higher softening point of stone wool fibres compared with glass wool fibres allows then to maintain their integrity at higher temperatures. However, due to its nature, stone wool insulation, notably when sprayed, generally has a higher density than equivalent glass wool insulation. The additional weight required for stone wool insulation increases the quantity of raw materials required and makes installation, either of panels or sprayed insulation, more difficult. 
     OBJECTS OF THE INVENTION 
     One aim of the present invention is to provide an insulating product having a combination of low density and low lambda value which provides good fire resistance to a building element. Another aim of the present invention is to provide better fire resistance to an insulating product which has initially low fire resistance. 
     SUMMARY 
     In accordance with one of its aspects, the present invention provides a method of providing an insulating layer as defined in claim  1 . Additional aspects of the invention are defined in independent claims. The dependent claims define preferred and/or alternative embodiments. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG.  1    is a picture of a first sprayed insulating product; and 
         FIG.  2    is a picture of a second sprayed insulating product; the product in each case having been subjected to fire test conditions and subsequently allowed to cool to room temperature. 
     
    
    
     DETAILED DESCRIPTION 
     As used herein the term “mixed mineral wool fibres” means a combination of at least first and second mineral wool fibres which are interspersed with each other in a three-dimensional fibre framework. For example, when looking at a sample of a layer of such mixed mineral wool fibres, one can see the framework of interspersed, entangled or overlapping first and second fibres, preferably with the interspersion of the fibres being substantially homogeneous throughout the volume of the framework. 
     The layer of mixed mineral wool fibres may be a continuous layer, notably a continuous layer extending over the entire area or along an entire surface of the insulating product. The layer of mixed mineral wool fibres may be an external layer of the insulating product; it may be provided adjacent to a further insulating layer. The mineral wool insulating product may comprise an intermediate layer of mixed mineral wool fibres sandwiched between two adjacent layers, for example further insulating layers. The further insulating layer(s) may comprise mineral wool fibres selected from the group consisting of glass wool fibres, rock wool fibres, slag wool, ceramic fibres or combinations thereof. The presence of one or more adjacent layers, notably mineral wool layers, allows optimisation of the thermal and/or fire properties of the product. 
     The mineral wool insulating product may consist essentially of mixed mineral wool fibres and a binder, notably the mineral wool insulating product may comprise at least 95% by weight of mixed mineral wool fibres and a binder, based on the total weight of the mineral wool insulating product. The term “consists essentially of” is intended to limit the scope of a claim to the specified materials or steps and those that do not materially affect the basic and novel characteristic(s) of the claimed invention. 
     The mineral wool insulating product may be provided in the form of one or a plurality of mineral wool insulating panel, i.e. a panel having a substantially parallelepiped shape, having a substantially resilient structure and fixed, pre-determined dimensions, and which may be easily transported on site. The mineral wool insulating panel may have a length which is ≥90 cm, ≥120 cm, ≥150 cm and/or ≤220 cm or ≤180 cm. The panel may have a width which is ≥50 cm, ≥70 cm and/or ≤100 cm or ≤90 cm. 
     The mineral wool insulating product may be in the form of a sprayed layer, notably obtained by projecting a stream of mineral wool fibres, water and a binder towards a support surface of a building element. A sprayed layer is adapted to cover a larger surface than a single insulating panel or even a plurality of juxtapositioned panels, without interruption. For example, a sprayed layer may be arranged to cover the interface between a wall and an adjacent ceiling without interruption or an entire ceiling or other support structure without interruption. Furthermore, covering a support surface by projecting mineral wool fibres, water and binder towards the support surface generally requires less time than covering the same support surface with a plurality of insulating panels. Preferably a primer bonding layer is firstly applied on the support surface before projecting the mineral wool insulating product in the form of a sprayed layer; this facilitates adherence of a sprayed layer to the support surface. The quantity of primer bonding layer may be at least 80 g/cm 2 , at least 100 g/cm 2 , at least 120 g/cm 2  and/or less than 160 g/cm 2 , less than 140 g/cm 2 . 
     When adapted to be projected towards a support surface, the mineral wool fibres may be provided in a package comprising mixed mineral wool fibres, notably in the form of loose fill fibres, preferably with a binder, notably a dry binder, or provided in at least two separate packages, the first package comprising the first loose fill mineral wool fibres, the second package comprising the second loose fill mineral wool fibres. The first mineral wool fibres and the second mineral fibres may be mixed prior to being packaged. A package of loose fill mixed mineral wool fibres may be unloaded into a spraying apparatus, for example in to a hopper, without pre-mixing on site. A package comprising a combination of first mineral wool fibres and second mineral fibres, notably loose and/or mixed first and second mineral fibres, may comprise:
     a quantity of the first mineral wool fibres which is at least 60%, at least 70%, at least 80% or at least 90% by weight with respect to the contents of the package; and/or;   a quantity of the second mineral wool fibres which is at least 10%, at least 20% or at least 30% and/or less than 50%, less than 40% or less than 30% by weight with respect to the contents of the package; and/or;   optionally a quantity of dry binder, notably adapted to bind together the first and second mineral wool fibres subsequent to spraying with water, which is less than 10%, less than 8% or less than 6% and/or at least 3% or at least 4% by weight with respect to the contents of the package; and/or   optionally one or more additives, for example an anti-dust agent, such as an anti-dust oil, and/or an anti-static agent, the quantity of the additive(s) notably being in a quantity of less than 1% by weight with respect to the contents of the package.   

     The support surface may be the support surface, notably a ceiling or wall, of a crawl space, a cellar, a car park, a building or a domestic house. The support surface may comprise wood, metal, gypsum, plaster or concrete, notably as an exposed surface to which the insulating product is secured. The support surface may comprise a covering layer such as paint or varnish. The support surface may be horizontal, vertical or oblique. For example, the support surface may be a metal beam or column of a building, for example a vertical or horizontal load-bearing metal beam. 
     The combination of the support surface and the mineral wool insulating product may be provided as a pre-fabricated assembly adapted to be transported to its place of use. For example, the mineral wool insulating product may be provided in a prefabricated structure, notably a prefabricated structure comprising the mineral wool insulating product incorporated in a prefabricated wall or panel, for example incorporated in the cavity of a pre-fabricated wall, timber frame or wooden structure or sandwiched between metal plates, for example of a sandwich panel. Generally, however, the mineral wool insulating product will be secured to its support surface on site. 
     The terminology “first mineral wool fibres” and “second mineral wool fibres” as used herein means that the first mineral wool fibres have a first chemical composition and the second mineral wool fibres have a second, different chemical composition. As used herein, the term, “the same chemical composition” in relation be mineral wool fibres means substantially the same chemical composition, allowance being made for usual industrial manufacturing variations and tolerance and, notably, mineral wool fibres have the same composition when the variation in their chemical composition is within the range:
     ±2.5% points for each oxide present in a quantity that is ≥15 wt-%; and   ±1.5% points for each oxide present in a quantity that is ≥2 wt-% and &lt;15 wt-%; and   ±1.0% point for each oxide present in a quantity that is &lt;2 wt %;   with the proviso that (CaO+MgO) and (Na 2 O+K 2 O) are each treated as one oxide component.   For example, for SiO 2  present in a quantity of 63 wt-%, the tolerance expressed above is 63% ±2.5% points i.e. 60.5% to 65.5%.   The term “different chemical composition” as used herein means that the chemical compositions are not the same and notably that the two compositions fall outside the above tolerances.   For individual fibres which have a homogeneous composition throughout their volume the composition can be measured from a single portion of the fibre. Alternatively, the fibre may be melted to provide a mass having a homogeneous composition for analysis.   

     Preferably, the difference of softening point between the first mineral wool fibres and the second mineral wool fibres is at least 150° C. The difference of softening point may be at least 200° C., preferably at least 250° C., more preferably at least 300° C. The mineral wool fibres may be selected such that:
         the softening point of the first mineral wool fibres is below a softening threshold; and   the softening point of the second mineral wool fibres is above the softening threshold; and where   the softening threshold is a temperature selected from 750° C., 800° C., 850° C., 900° C. and 950° C.       

     The insulating product may comprise first mineral wool fibres having a softening point which is ≤750° C.; ≤800° C. or ≤850° C. and second mineral wool fibres having a softening point which is ≥900° C., ≥950° C. or ≥1000° C. 
     The term “softening point” as used herein means the temperature at which the mineral fibre composition deforms under its own weight and which occurs at a viscosity of 10 7.6  poise (10 6.6  Pa·s). Preferably the softening point herein is determined in accordance with International standards ISO 7884-1 and ISO 7884-2; alternatively, it may be determined in accordance with International standards ISO 7884-1 and ISO 7884-6 (versions in force at 15 Jul. 2016). 
     Without wishing to be bound by theory, it is believed that when subjected to fire conditions representative of building fire resistance tests, the layer of mixed mineral wool fibres forms a protective, agglomerated, high viscosity layer on its side exposed to the fire; this protective layer, which may be a magma layer, appears to provide a protective, refractory or refractory-like layer providing improved fire resistance and protecting the unexposed portion of the mineral wool insulating product. It seems that when the mixed mineral wool fibres reach a temperature above the lower softening point of its first and second mineral wool fibres, these mineral wool fibres will start softening and will connect with the fibres of the second mineral wool fibres having a higher softening point. This is surprising as it would have been thought that the lower softening point mineral wool fibres would simply melt away, notably taking some of the other mineral wool fibres with it, without contributing in any significant way to the product&#39;s fire resistance. 
     In fire resistance tests or conditions the unexposed layer of mixed mineral wool fibres beneath the agglomerated surface layer preferably remains substantially intact. Even if the or part of such an agglomerated, protective high viscosity or refractory layer detaches from the product, a new agglomerated protective high viscosity or refractory layer may be formed from the previous underlying material. Due to this protective high viscosity or refractory layer and its possible regeneration, the mineral wool insulating product is able to provide significantly greater fire resistance compared to glass wool fibres insulating products. As long as the insulating product is still present, the support surface may be protected from fire. 
     The layer of mixed mineral wool fibres may comprise at least 60% wt, at least 70% wt, at least 80% wt, at least 90% wt or at least 95% by weight of mineral wool fibres. The first mineral wool fibres may be glass fibres and the second mineral fibres may be selected from the group consisting of: rock wool, slag wool, ceramic fibres and combinations thereof. In a preferred embodiment, the first mineral wool fibres are glass wool fibres and the second mineral wool fibres are rock wool fibres. 
     The amount of first mineral wool fibres may be at least 60%, at least 70%, at least 80% or at least 90% by weight with respect of the total weight of the layer of mixed mineral wool fibres. 
     The amount of second mineral wool fibres may be at least 10%, at least 20% or at least 30% and/or less than 50%, less than 40% or less than 30% by weight with respect of the total weight of the layer of mixed mineral wool fibres. 
     It has been found surprising that, when the amount of rock wool fibres in the insulating layer is significantly less than the amount of glass wool fibres, notably less than 30% of rock wool fibres and greater than 60% or 70% of glass wool fibres, the insulating product, notably the sprayed insulating layer, has physical properties, for example density, closer to a glass wool product but has fire resistance properties closer to a rock wool product. Furthermore, even with high proportions, for example at least 70 or 80% wt, of glass wool fibres, the sprayed insulating layer exposed to fire does not react like a glass wool insulating layer, notably the product remains in place to provide fire resistance and does not all melt away. 
     The glass mineral wool fibres may comprise: ≥55 wt-% silicon oxide (SiO 2 ) and/or ≤10 wt-% aluminium oxide (Al 2 O 3 ); and/or an alkali/alkaline-earth ratio of their composition which is &gt;1; and/or a combined quantity of CaO and MgO&lt;20 wt-%; and/or a combined quantity of Na 2 O and K 2 O&gt;8% wt. The glass wool fibres may have a softening point in the range 600-750° C., notably in the range 650-700° C. 
     The rock mineral fibres may comprise: between 30 and 55 wt-% SiO 2  and/or between 10 and 30 wt-% Al 2 O 3 ; and/or an alkali/alkaline-earth ratio of their composition which is ≤1; and/or a combined quantity of CaO and MgO ranging from 20 to 35 wt-%; and/or a combined quantity of Na 2 O and K 2 O&lt;8 wt %; and/or a total iron content expressed as Fe 2 O 3  of between 4 and 10 wt-%. The amount of shots (or beads) in the sprayed insulating layer may be less than 1% wt, a shot being defined as a particle having a largest apparent diameter of less than 60 μm. The rock wool fibres may have a softening point in the range 900-1200° C., notably in the range 1000-1100° C. 
     The first and/or second mineral wool fibres may have an average diameter of less than 8 μm, preferably less than 6 μm, more preferably less than 4 μm. The first and/or second mineral wool fibres may have an average length of at least 10 μm, at least 12 μm and/or less than 40 μm or less than 20 μm. The first mineral wool fibres and the second mineral wool fibres may have different average lengths, notably a difference of at least 10%, at least 15% or at least 20%. A difference of lengths of between the first and second mineral wool fibres may facilitate entanglement and cohesion of the fibres in the fibre framework. 
     The mineral wool fibres may be substantially free of silicon, i.e. having a silicon quantity of less than 1% by weight, notably less than 0.1% by weight silicon or be free or substantially free of silicon. Providing mineral wool fibres substantially free of silicon facilitates spraying. 
     The mineral wool fibres may comprise virgin fibres notably in an amount of at least 70% wt, preferably at least 80% wt, more preferably at least 90% wt, 95% wt or 98% wt, based on the total weight of the mineral wool fibres. Preferably, such virgin fibres are binder free and/or silicon free. The mineral wool fibres may comprise recycled mineral wool fibres, notably in an amount of less than 20% wt or 10% wt based on the total weight of the mineral wool fibres. 
     As used herein the term virgin mineral wool fibres means mineral wool fibres that have not previously been incorporated in to a mineral fibre product. As used herein, the term recycled fibres means mineral wool fibres that have been recovered from a formed insulation product, for example from edge trim or scrap product. Preferably the mineral wool fibres are free of flocks comprising fibres and cured binder, for example, from scrap. Preferably, the first and/or the second mineral wool fibres are in the form of fibres and are free from agglomerations of fibres in the form of flocks, notably free from flocks having a geometrical diameter, determined by the apparent circumscribed circle, of at least 4 mm or at least 5 mm, notably in the range 5-30 mm 
     The mineral wool insulating product may have a parting strength in the machine direction of at least 2 kPa, at least 4 kPa and/or less than 10 kPa, or less than 8 kPa, notably in accordance with EN 1607. 
     The mineral wool insulating product may comprise less than 10% by weight of binder, preferably less than 8%, more preferably less than 6%. It may comprise at least 3% by weight or at least 4% by weight of a binder. The binder may be in the form of a dry binder or in the form of an aqueous binder solution, notably prior to being sprayed towards a support surface. The aqueous binder solution may comprise a dry binder mixed with water and preferably comprises a dry binder in the range 5 to 10% wt with respect to the total binder solution. The binder preferably comprises an organic binder, for example PVOH or an acrylic binder, such as EVA. 
     In fire applications, it would have been thought that using an inorganic binder, such as cement, rather than organic binder was preferable. It could be supposed that cohesion between the mineral wool fibres in the fibre framework was mainly due to the binder, and thus, following decomposition of an organic binder when exposed to fire conditions, the cohesion between the fibres will be reduced and thus the insulating product and/or the layer of mixed mineral wool fibres would be likely to disintegrate or fall. It has been found surprising that despite the use of an organic binder, the fibre framework of the layer of mixed mineral wool fibres is maintained even after decomposition of an organic binder. 
     The mineral wool insulating product may have a fire reaction classification of at least B, A2 or A1 according to European Standard EN 13501-1. The mineral wool insulating product may have or provide a fire resistance of at least 20 minutes, at least 30 minutes, at least 45 minutes, at least 60 minutes or at least 90 minutes. The fire resistance is notably determined according to EN 1363-1, EN 1365-1, EN 1365-2, EN 1365-3; EN 1365-4, EN 13381-3, EN 13381-4, EN 13381-5, EN 13381-6, EN 13381-7 (the appropriate standard being selected as a function of the building structure or support surface). 
     The mineral wool insulating product may have a lambda value of less the 42 mW/m·K., preferably less the 40 mW/m·K., more preferably less the 38 mW/m·K, notably when measured at 10° C. 
     Preferably, the mineral wool insulating product has a substantially white colour. This provides a light reflective product which may improve brightness of an interior. Alternatively, the mineral wool insulating product may be brownish or greyish. 
     The mineral wool insulating product may comprise one or more additives, for example an anti-dust agent, such as an anti-dust oil, and/or an anti-static agent. The quantity of additive(s) may be less than 1% by weight with respect of the total weight of the mineral wool insulating product. 
     The layer of mixed mineral wool product may be substantially homogeneous. Preferably the difference of one or more physical measurable properties selected from lambda value, density, and ratio between the two mineral wool fibres, is less than 10%, preferably less than 5%, more preferably less than 3%. This provides substantially even fire resistance in all points of the layer of mixed mineral wool product. 
     The layer of mixed mineral wool fibres and/or the mineral wool insulating product may have a thickness of at least 30 mm, at least 100 mm or at least 150 mm and/or less than 250 mm or less than 200 mm. The mineral wool insulating product may have a density of at least 50 kg/m 3  or at least 60 kg/m 3  and/or less than 120 kg/m 3 , less than 80 kg/m 3  or less than 70 kg/m 3 . These combinations of thicknesses and densities provide good thermal and fire resistance properties without excessive weight which complicates installation. 
     The density of the layer of mixed mineral wool fibres may be:
         in the range 100 to 120 kg/m 3 , notably when the layer of mixed mineral wool fibres comprises glass wool fibres in the range 50-60% wt and rock wool fibres (or slag wool) in the range 40-50% by weight;   in the range 60 to 70 kg/m 3 , notably when the layer of mixed mineral wool fibres comprises glass wool fibres in the range 70-80% wt and rock wool fibres (or slag wool) in the range 20-30% by weight.       It has been found that when the amount of glass wool fibres in the layer of mixed mineral wool fibres is increased, the density of the layer of mixed mineral wool fibres decreases, notably abruptly between 60 and 70% by weight of glass wool fibres.   

     When sprayed towards a support surface of a building element, the stream of first and second mineral wool fibres may be mixed with a binder so as to form a layer of mixed mineral wool fibres projected towards the support surface. The distance between the insulation nozzle and the support surface may be at least 0.5 m, at least 1 m and/or less than 3 m, less or less than 2 m. In a crawl space, cellar or car park, the distance may be in the range 0.5 m to 2.5 m. 
     According to another aspect, the invention provides a sprayed mineral wool insulating product comprising a layer of first mineral fibres, notably glass wool fibres, and an adjacent layer of second layer mineral wool fibres, notably selected from: rock wool fibres, slag wool, ceramic fibres or combinations thereof. The sprayed mineral wool product may be provided by:
         spraying towards the support surface a stream of one mineral wool fibres with a binder so as to provide a first sprayed mineral wool layer; and   subsequently spraying towards the first sprayed mineral wool layer, a stream of the other mineral wool fibres with a binder so as to provide a second sprayed mineral wool layer adjacent to the first sprayed mineral wool layer.       Prior to spraying a primer bonding layer may be applied to the support surface.   

     According to a further aspect, the present invention provides a mineral wool insulating product comprising a layer, notably a continuous layer, of mixed mineral wool fibres which comprises (in % by weight based on the total weight of the layer):
         a binder;   at least 50% wt of first mineral wool fibres having a first composition;   at least 5% wt of second mineral wool fibres having a second composition.       The first mineral wool fibres and the second mineral wool fibres may have a difference of softening point which is at least 150° C., preferably at least 250° C.   The mineral wool insulating product may comprise at least 60% wt of mixed mineral wool fibres, preferably at least 75% wt of mixed mineral wool fibres, based on the total weight of the mineral wool insulating product.   The mineral wool insulating product may have a fire reaction classification of at least B, in accordance to EN 13501-1 and/or may provide an additional fire resistance to a building element of at least 20 minutes, preferably at least 30 minutes, more preferably at least 45 minutes, in accordance to EN 1363-1, EN 1365 and/or EN 13381.   The mineral wool insulating product may have a lambda value of less than 42 mW/m·K, preferably less than 40 mW/m·K , more preferably less than 38 mW/m·K.   In a preferred embodiment, the first mineral wool fibres are glass wool fibres and the second mineral wool fibres are selected from the group consisting of rock wool fibres, slag wool fibres, ceramic fibres and combinations thereof.   Preferably, the binder comprises an organic binder, notably PVOH or acrylic binder. The layer of mixed mineral wool fibres may comprise between 3 and 8% wt of binder with respect to the total weight of the layer, preferably in the range 4-6% wt, more preferably in the range 5-6% wt.   The layer of mixed mineral wool fibres may have a thickness in the range 30 mm to 210 mm and/or a density in the range 50 kg/m 3  to 100 kg/m 3 , notably in the range 60 kg/m 3  to 80 kg/m 3 .   The mineral wool insulating product may be in the form of a mineral wool insulating panel or in the form of a sprayed insulating layer.   The insulating layer may be provided on a support surface of a building element by spraying mixed mineral wool fibres, together with water and a binder, towards the support surface of the building element to provide a layer of mixed mineral wool fibres, the layer comprising (in % by weight with respect of the total weight of the layer):
       the binder;   at least 50% wt of first mineral wool fibres having a first composition;   at least 5% wt of second mineral wool fibres having a second composition.   
       

     According to a yet further aspect, the present invention provides a method of providing a fire resistant layer to a support surface of a building element comprising:
         introducing a combination at least 50% wt of glass wool fibres having a first composition and at least 5% wt of second mineral fibres, notably selected from the group consisting of rock wool fibres, slag wool, ceramic fibres and combination thereof, having a second composition into an inlet of a spraying apparatus; and   projecting simultaneously the glass wool fibres, the mineral wool fibres, water and a binder from a spraying nozzle of the spraying apparatus towards the support surface so as to provide a layer of mixed mineral wool fibres on the support surface.       The first and second mineral wool fibres are preferably provided in the form of loose fill fibres.   

     An embodiment of the invention will now be described, by way of example only, with reference to the accompanying drawing of which:
       FIG.  1    is a picture of a first sprayed insulating product; and     FIG.  2    is a picture of a second sprayed insulating product;   the product in each case having been subjected to fire test conditions and subsequently allowed to cool to room temperature.   

     A support surface consisting of a plaster board  10  is firstly prepared by spraying a bonding primer on the support surface so that the quantity of bonding primer is about 120 g/m 2 . 
     A first sample  1  illustrated in  FIG.  1    after testing comprises a first sprayed layer of rock mineral wool fibres, in contact with the bonding primer and a second sprayed layer of glass mineral wool fibres. Each sprayed layer is prepared by mixing mineral wool fibres free of binder and free of silicon with an aqueous binder solution comprising 6% by weight of Tris(1chloro-2-propyl)phosphate into a mixing apparatus so as to provide a mixed mineral wool fibres comprising about 94.5% wt of mineral wool fibres and a binder content of the mixture being about 5.5% wt. 
     A second sample  2  illustrated in  FIG.  2    after testing is prepared by mixing glass wool fibres and rock wool fibres which are both free of binder and free of silicon, with an aqueous binder solution comprising 6% by weight of Tris(1chloro-2-propyl)phosphate into a mixing apparatus so as to provide a mixed mineral wool fibres comprising about 94.5% wt of mineral wool fibres and a binder content of the mixture being about 5.5% wt. The mineral wool fibres comprise about 60% wt of glass wool fibres and about 40% wt of rock wool fibres. 
     Holding the spraying nozzle at a distance of about 1.5 m from the plaster board  10  at a projecting angle of about 90°, an operator sprays, in a single and continuous step, each mixture so as to form a sprayed insulating product  10 ,  20 . The sprayed insulating product of sample  1  and sample  2  have a thickness of about 200 mm and an average density of about 100 kg/m 3 . In sample  1 , the sprayed insulating layer consists of two layers having a thickness of about 100 mm. 
     Each sample  1 ,  2  is placed in a vertical position in an oven configured to simulate fire conditions with rising temperature and a maximum temperature of about 900° C. Each test is scheduled to last 30 minutes. 
     As seen in  FIG.  1   , the exposed glass sprayed insulating product  10  of the first sample  1  is greatly damaged. Due to the melting of fibres from the sample  1 , the test was reduced to 15 minutes. The average thickness of the sprayed insulating product has decreased from about 200 mm to about 110 mm, and with local thickness having further decreased to about 70 mm. However, the sprayed layer of rock wool fibres is still present and may provide a fire resistance layer to the support structure. 
     As seen in  FIG.  2   , the sprayed insulating product  20  has an average thickness of about 190 mm, the decrease being mainly due to the shrinkage of the sprayed insulating product when subjected to fire conditions. A protective, refractory or refractory-like layer  200  has been formed at the exposed surface of the sprayed insulating product  20 . During the fire test this layer had the appearance of a high viscosity magma layer. The unexposed sprayed insulating product is substantially intact and still has the same fire resistance as prior to the test. Contrary to the result achieved, it would have been supposed that the glass wool fibres would have melted and caused disintegration of the entire product.