Patent Publication Number: US-2018033912-A1

Title: Iii-p light emitting device with a superlattice

Description:
CROSS-REFERENCE TO RELATED APPLICATIONS 
     The present application claims priority to U.S. Provisional Patent Application No. 62/367,935, filed Jul. 28, 2016, and European Patent Application No. 16191414.8, filed Sep. 29, 2016. U.S. Provisional Patent Application No. 62/367,935 and European Patent Application No. 16191414.8 are incorporated herein. 
    
    
     BACKGROUND 
     Description of Related Art 
     Light emitting diodes (LEDs) are widely accepted as light sources in many applications that require low power consumption, small size, and high reliability. Energy-efficient diodes that emit light in the yellow-green to red regions of the visible spectrum often contain active layers formed of an AlGaInP alloy. Energy-efficient diodes that emit light in the UV to blue to green regions of the visible spectrum often contain active layers formed of a III-nitride alloy. 
       FIG. 1  is a cross-sectional view of a prior art AlGaInP device, described in more detail in U.S. Pat. No. 6,057,563. The device of  FIG. 1  comprises: a GaAs substrate  10  of a first conductivity-type; a Bragg reflector layer  11  consisting of AlAs/GaAs and formed upon the substrate  10 ; an AlGaInP confinement layer  12  of the first conductivity-type grown upon the Bragg reflector layer  11 ; a conductive AlGaInP active layer  13  grown upon the AlGaInP confinement layer  12 ; an AlGaInP confinement layer  14  of a second conductivity-type grown upon the AlGaInP active layer  13 ; a plurality of conductive GaInP/AlGaInP superlattice layers  15  grown upon the AlGaInP confinement layer  14 ; an ohmic contact layer  16  of the second conductivity-type grown upon the conductive AlGaInP superlattice layer  15 ; a front contact  17  formed on top of the ohmic contact layer  16 ; and a back contact  18  formed on the back side of the substrate  10 . 
     U.S. Pat. No. 6,057,563 teaches “the LED with light transparent window according to the present invention can provide a bright and uniform luminance by enabling current to flow uniformly through the entire LED chip and increasing the transparency of the window layer.” 
     SUMMARY 
     In one aspect a light emitting device is provided that includes a semiconductor structure including a III-P light emitting layer disposed between an n-type region and a p-type region, the n-type region including a superlattice, and an n-contact metal on and in contact with a surface of the superlattice opposite the III-P light emitting layer. The superlattice including a plurality of stacked layer pairs, each layer pair comprising a first layer of AlxGa1-xInP where 0&lt;x&lt;1 and a second layer of AlyGa1-yInP where 0&lt;y&lt;1, the first layer having a smaller aluminum composition than the second layer. 
     In another aspect, a light emitting device is provided that includes a semiconductor structure including a III-P light emitting layer disposed between an n-type region and a p-type region, the n-type region comprising a superlattice, a current spreading layer on and in contact with a surface of the superlattice opposite the III-P light emitting layer; and an n-contact on and in contact with the current spreading layer. The superlattice including a plurality of stacked layer pairs, each layer pair comprising a first layer of AlxGa1-xInP where 0&lt;x&lt;1 and a second layer of AlyGa1-yInP where 0&lt;y&lt;1, the first layer having a smaller aluminum composition than the second layer. 
     In yet another aspect, a method is provided, the method including growing an n-type superlattice on a growth substrate, the superlattice comprising a plurality of stacked layer pairs, each layer pair comprising a first layer of AlGaInP and a second layer of AlGaInP, the first layer having a smaller aluminum composition than the second layer; forming a first metal contact on the p-type region; growing a light emitting region directly on the n-type superlattice; growing a p-type region on the light emitting region; removing the growth substrate to expose a surface of the superlattice; and forming a second metal contact directly on the exposed surface of the superlattice. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1  illustrates a prior art AlGaInP LED device. 
         FIG. 2  is a cross-sectional view of an AlGaInP device structure grown on a substrate. 
         FIG. 3  is a cross-sectional view of an AlGaInP device structure of  FIG. 2  after forming contacts and removing the growth substrate. 
         FIG. 4  is a top view of a thin film AlInGaP device, such as the device of  FIG. 3 . 
     
    
    
     DETAILED DESCRIPTION 
     The III-P or Al x Ga 1−x InP alloy system is critical for making light emitting diodes (LEDs) and lasers emitting light having a peak wavelength in the wavelength range of about 580 nm (amber) to 770 nm (far red). This range of wavelengths is achieved by adjusting the aluminum-gallium ratio during the growth of the alloy. Increased aluminum (x) composition in the light emitting layers provides shorter wavelengths. One example of an LED has a p-i-n junction epitaxially grown on an absorbing GaAs substrate. The first layer is an n-type lower confining layer (LCL) of Al x Ga 1−x InP , epitaxially grown on the GaAs substrate. An active i-layer of Al x Ga 1−x InP with suitable aluminum-gallium ratio to provide a desired wavelength is then epitaxially grown on the n-type LCL. A p-type upper confinement layer (UCL) of Al x Ga 1−x InP is then epitaxially grown on the active layer. The p-i-n junction has a single light emitting layer, and is a double heterostructure. As an alternative to a single light emitting layer, a III-P LED may have a multiple quantum well light emitting region (also referred to as an active region) sandwiched between n- and p-type regions. A multiple quantum well light emitting regions includes multiple, quantum well light emitting layers, separated by barrier layers. In a surface emitting LED, a front metal electrode is formed on the emitting face of the LED and a back metal electrode is formed in the back. 
     For a given active layer design, efficient LED operation depends on efficient current injection from metal electrodes to the corresponding n- and p-type layers of the LED chip. Ideally, current is distributed as evenly as possible over the entire active region of an LED, without blocking or reflecting light emitted from the active region. Ideal current distribution requires that the n-and p-type layers have the lowest possible sheet resistances, to avoid any current crowding under or near the metal electrodes. Ideal current distribution also requires that the n- and p-type layers have bandgaps larger than the emission wavelength of the active region, to avoid any absorption and/or reflection. Reducing aluminum composition in Al x Ga 1−x InP does reduce the sheet resistance, but also reduces the bandgap of Al x Ga 1−x InP , which may increase absorption of emission from the active layer. This absorption becomes severe at shorter wavelength emitting LEDs. 
     In some embodiments of the invention, an AlGaInP device includes a multiple-layered superlattice semiconductor structure, which may reduce sheet resistance to prevent current crowding in n-contact of an LED, while maintaining a sufficiently high bandgap to prevent significant absorption of light emitted by the active layer of the LED. In some embodiments, the superlattice is formed on the n-type side of the active region, and may comprise n-type layers. 
     Depending on the context, as used herein, “AlGaInP” or “AlInGaP” may refer in particular to a quaternary alloy of aluminum, indium, gallium, and phosphorus, or in general to any binary, ternary, or quaternary alloy of aluminum, indium, gallium, and phosphorus. “III-nitride” may refer to a binary, ternary, or quaternary alloy of any group III atom (such as aluminum, indium, and gallium) and nitrogen. For instance, “AlGaInP” may include (Al x Ga (1−x)r In (1−r) P where 0&lt;x&lt;1, 0&lt;r&lt;1. Depending on the context, as used herein, “contact” may refer in particular to a metal electrode, or in general to the combination of a semiconductor contact layer, a metal electrode, and any structures disposed between the semiconductor contact layer and the metal electrode. 
       FIG. 2  is a cross sectional view of a semiconductor device structure grown over a growth substrate  48 , according to some embodiments. Growth substrate  48  is often GaAs, though any suitable growth substrate may be used. 
     An etch stop layer (not shown) may be grown over substrate  48 . The etch stop layer may be any material that may be used to stop an etch used to later remove substrate  48 . The etch stop layer may be, for example, InGaP, AlGaAs, or AlGaInP. The material of the etch stop layer may be lattice-matched to the growth substrate (typically GaAs), though it need not be. Etch stop layers that are not lattice matched to the growth substrate may be thin enough to avoid relaxation and/or may be strain compensated. The thickness of the etch stop layer depends on the selectivity of the etch solutions used to remove the GaAs substrate; the less selective the etch, the thicker the etch stop layer. An AlGaAs etch stop layer may be, for example, between 2000 and 5000 Å, though a thicker etch stop layer may be used if the etch stop layer is used to texture the emitting surface of the device, as described below. The composition x of an Al x Ga 1−x As etch stop layer may be, for example, between 0.50 and 0.95. 
     The device layers, including at least one light emitting layer in a light emitting or active region sandwiched between an n-type region and a p-type region, are grown over the etch stop layer. 
     In some embodiments, the n-type region  50  includes a multiple-layered superlattice semiconductor structure. The superlattice may provide a low sheet resistance and tuneable bandgap. In some embodiments, the superlattice includes a stack of alternating layers of lower aluminum content Al x Ga 1−x InP and higher aluminum content Al x Ga 1−x InP (wherein 0&lt;x&lt;1). The lower aluminum content layers in the superlattice may provide a path of lower sheet resistance for better current spreading. The superlattice may be designed to obtain a desired bandgap by appropriately choosing the thickness and the aluminum content of the layers in the superlattice. In some embodiments, the lower aluminum content layers in the superlattice may act as quantum wells, surrounded by the higher aluminum content layers, which may act as quantum barriers. Thin enough quantum barriers may cause the energy states of the quantum wells to resonate and generate minibands for electrons and holes, which define the bandgap of the superlattice. Minibands of the superlattice can be tuned to provide a bandgap that lies between the bandgaps of the lower aluminum content layers and the higher aluminum content layers. 
     Depending on the peak emission wavelength of the LED, the Al composition of the Al x Ga 1−x InP LCL may be at least x=0.3 (30% Al) in some embodiments, and no more than x=0.65 (65% Al) in some embodiments. An Al x Ga 1−x InP LCL with 30% Al has a bandgap of about 2.08 eV and an absorption edge of about 596 nm. On the other end, an Al x Ga 1−x InP LCL with 65% Al has a bandgap of about 2.23 eV and an absorption edge of about 553 nm. The 30% Al LCL may be suitable for an LED with a peak emission wavelength greater than 660 nm in some embodiments. For LEDs with peak emission wavelengths below 660 nm, the Al composition in the LCL may be increased, reaching up to 65% for a peak emission wavelength of about 590 nm in some embodiments. For a given superlattice structure, Al concentration of the lower aluminum content AlGaInP layers in the superlattice and higher aluminum content AlGaInP layers in the superlattice may range from 30% to 65% in some embodiments. Bandgap (or absorption edge) of the superlattice layer targeted for a given LED color not only depends on the Al concentration, but also on the thicknesses of the individual layers. In one embodiment, the superlattice includes 100 Å thick Al 0.45 Ga 0.55 InP layers alternating with 100 Å thick Al 0.35 Ga 0.65 InP layers, which provides an effective bandgap of about 2.14 and an absorption edge of about 578 nm. This bandgap and absorption edge is very closely matched to a bulk (i.e., single layer of uniform composition) AlInGaP layer with 40% Al. To achieve a higher bandgap (or lower absorption edge), the thickness of the lower Al content layers may be reduced, and/or the Al composition in either or both of the layers may be increased. 
     The higher and lower aluminum composition layers in the superlattice may have a dopant concentration of at least 1×10 17 /cm 3  in some embodiments, no more than 1×10 19 /cm 3  in some embodiments, at least 0.5×10 18 /cm 3  in some embodiments, and no more than 1.5×10 18 /cm 3  in some embodiments. The higher and lower aluminum composition layers may be doped differently. In some embodiments, the superlattice layers may be doped in gradient with the doping profile changing across the superlattice. Any suitable dopants may be used, including, for example, n-type dopant(s), Si, and Te. The doping could be modulated to match the modulation of composition. For example, higher bandgap layers may be more highly doped, and lower bandgap layers may be less doped. Alternatively, higher bandgap layers may be less doped, and lower bandgap layers may be more highly doped. The n-type region  50  may include a non-uniform doping concentration, such as one or more thick regions doped at 1×10 18  cm −3 , and one or more thin regions that are doped more heavily, up to, for example, 1×10 19  cm −3 . These highly doped regions may be doped with Te, Si, S, or other suitable dopants, and the high doping concentration can be achieved either by epitaxial growth, by dopant diffusion, or both. 
     The individual layers in the superlattice may be at least 5 nm in some embodiments, no more than 100 nm thick in some embodiments, and no more than 20 nm thick in some embodiments. The total thickness of the entire superlattice may be at least 1 μm thick in some embodiments, no more than 8 μm thick in some embodiments, at least 2 μm thick in some embodiments, and no more than 5 μm thick in some embodiments. The superlattice may include at least 100 pairs of lower and higher Al composition layers in some embodiments, no more than 1600 pairs in some embodiments, and no more than 400 pairs in some embodiments. 
     In some embodiments, n-type region  50  includes a separate AlGaInP n-contact layer, on which a metal n-contact may be formed. In some embodiments, a metal n-contact is formed on the first or other layer pair in the superlattice. A separate n-contact layer may be a layer with doping and/or composition that is optimized for contact formation, rather than for the superlattice. 
     In some embodiments, the superlattice as a whole is lattice-matched to the growth substrate, often GaAs. In some embodiments, individual layers of the superlattice layer may be strained (i.e., not lattice matched to the growth substrate). In some embodiments, individual layers of the superlattice layer may be lattice-matched to the growth substrate. 
     In one example, the superlattice includes thin layers of AlGaInP with 45% aluminum, which act as barrier layers to thin layers of AlGaInP with 35% aluminum, which act as quantum well layers. By choosing the correct thickness of the 35% and 45% aluminum layers, the effective bandgap of the superlattice can be tuned to the bandgap of a single layer of uniform composition AlGaInP with 40% aluminum. 
     In one example, the superlattice includes first layers comprising Al x Ga 1−x InP, wherein x&gt;0, and second layers comprising Al y Ga 1−y InP, wherein y&gt;0. The first layers may have a composition 0.3&lt;x&lt;0.4 and the second layers may have a composition 0.4&lt;y&lt;0.5. In one example, the superlattice includes first layers comprising Al x Ga 1−x InP , wherein x&gt;0, and second layers comprising Al y Ga 1−y InP, wherein y&gt;0. The first layers may have a composition 0.2&lt;x&lt;0.5 and the second layers may have a composition 0.3&lt;y&lt;0.65. 
     In one example, the superlattice includes alternating layers of 10 nm thick (Al 0.35 Ga 0.65 ) 0.51 In 0.49 P and 10 nm thick (Al 0.35 Ga 0.65 ) 0.51 In 0.49 P. The superlattice includes 225 pairs of these layers, grown epitaxially over a GaAs substrate. This superlattice layer provides an effective bandgap of ˜2.14 (absorption edge ˜578 nm), and may be used in an LED with a peak emission wavelength of at least 620 nm in some embodiments and no more than 700 nm in some embodiments. 
     A given superlattice can be used for multiple peak emission wavelengths. The lower limit of emission wavelength is set by the superlattice (determined by the superlattice absorption edge), however any active region with a peak wavelength longer than the lower limit is suitable for use with the superlattice. 
     The following table illustrates several examples of superlattice structures. Four superlattice structures are illustrated. The thickness and aluminum composition for the lower Al composition layers and the higher Al composition layers is given, as well as the effective bandgap. The “Effective WL cut-off” is the wavelength below which light will be absorbed by the superlattice. In some embodiments, the active regions emits little or no light below the cut-off wavelength. In some embodiments, the active region may emit some light that is below the cut-off wavelength, and which may be absorbed by the superlattice (for example, to optimize the conductivity of the layer vs. its absorption edge). The examples given are merely illustrations and not meant to be limiting. 
     
       
         
           
               
               
               
               
               
               
             
               
                   
               
               
                 % Al, 
                 Thickness, 
                 % Al, 
                 Thickness, 
                   
                 Effective  
               
               
                 low Al 
                 low Al  
                 high Al  
                 high Al 
                 Effective 
                 WL 
               
               
                 layers 
                 layers 
                 layers 
                 layers 
                 bandgap 
                 cut-off 
               
               
                   
               
             
            
               
                 30 
                 10 nm 
                 40 
                 10 nm 
                  2.1 eV 
                 590 nm 
               
               
                 35 
                 10 nm 
                 45 
                 10 nm 
                 2.14 eV 
                 580 nm 
               
               
                 45 
                 10 nm 
                 55 
                 10 nm 
                 2.2  
                 564 nm 
               
               
                 55 
                 10 nm 
                 65 
                 10 nm 
                 2.24 
                 554 nm 
               
               
                   
               
            
           
         
       
     
     A light emitting or active region  52  is grown over n-type region  50 . Examples of suitable light emitting regions include a single light emitting layer, and a multiple well light emitting region, in which multiple thick or thin light emitting wells are separated by barrier layers. In one example, the light emitting region  52  of a device configured to emit red light includes (A 10.06 Ga 0.94)0.5 In 0.5 P light emitting layers separated by (Al 0.65 Ga 0.35)0.5 In 0.5 P barriers. The light emitting layers and the barriers may each have a thickness between, for example, 20 and 200 Å. The total thickness of the light emitting region may be, for example, between 500 Å and 3 μm. 
     A p-type region  54  is grown over light emitting region  52 . P-type region  54  is configured to confine carriers in light emitting region  52 . In one example, p-type region  54  is (Al 0.65 Ga 0.35 ) 0.5 In 0.5 P and includes a thin layer of high Al composition to confine electrons. The thickness of p-type region  54  may be on the order of microns; for example, between 0.5 and 3 μm. The proximity of the light emitting layers of the light emitting region to the p-contact through a thin p-type region  54  may also reduce the thermal impedance of the device. 
     In some embodiments, a p-type contact layer (not shown) may be grown over p-type region  54 . The p-type contact layer may be highly doped and transparent to light emitted by the light emitting region  52 . For example, the p-type contact layer may be doped to a hole concentration of at least 5×10 18  cm −3  in some embodiments, and at least 1×10 19  cm  −3  in some embodiments. In this case, the p-type contact layer may have a thickness between 100 Å and 1000 Å. If the p-type contact layer is not highly doped then the thickness may be increased to as much as 12 μm, for example with a hole concentration up to 5×10 18 cm −3 . In some embodiments, the p-type contact layer is highly doped GaP. For example, a GaP contact layer grown by metal organic chemical vapor deposition may be doped with Mg or Zn, activated to a hole concentration of at least 8×10 18  cm −3 . The GaP layer may be grown at low growth temperature and low growth rate; for example, at growth temperatures approximately 50 to 200° C. below typical GaP growth temperatures of ˜850° C., and at growth rates of approximately 1% to 10% of typical GaP growth rates of ˜5 μm/hr. A GaP contact grown by molecular beam epitaxy may be doped with C to a concentration of at least 1×10 19  cm −3 . In some embodiments, as an alternative to incorporating dopants during growth, the p-type contact layer may be grown, then the dopants may be diffused into the p-type contact layer from a vapor source after growth, for example by providing a high pressure dopant source in a diffusion furnace or in the growth reactor, as is known in the art. 
       FIG. 3  illustrates the semiconductor structure of  FIG. 2  formed into a device. After growth, a p-contact  60  is formed in electrical contact with p-type region  54  (on p-contact layer, if present, or on p-type region  54 ). In some embodiments, p-contact  60  is a metal mirror, such as AuZn, with Zn diffusing into the semiconductor. In some embodiments, p-contact  60  includes many small contacts spaced apart on the semiconductor layer, with a dielectric layer formed over the small contacts, such that a majority of the semiconductor surface is covered in a dielectric, which functions as a mirror for much of the emitted light based on the principle of total internal reflection. The dielectric may be covered with a metal that is an excellent mirror but does not make good ohmic contact with the semiconductor, such as Ag or Au. Such a structure is often referred to as a composite or hybrid mirror and is known in the art. In some embodiments, a distributed Bragg reflector is used in place of the single dielectric layer described above. The p-contact  60  may include other materials including, for example, a guard material such as TiW or any other suitable material. The guard layer may seal the reflective metal layer in place and function as a barrier to the environment and other layers. 
     A bonding layer  66  may be formed over the p-contact  60 , and/or on the mount  68  described below. The bonding layer may be, for example, Au or TiAu and may be formed by, for example, evaporation. The device may be temporarily attached to a support, or permanently bonded to a mount  68 , through the bonding layer  66 , in order to facilitate further processing. The mount may be selected to have a coefficient of thermal expansion (CTE) that is reasonably closely matched to the CTE of the semiconductor layers. The mount may be, for example, GaAs, Si, a metal such as molybdenum, or any other suitable material. A bond is formed between the device and the mount by, for example, thermocompression bonding, or any other suitable technique. 
     Growth substrate  48  is removed by a technique suitable to the growth substrate material. For example, a GaAs growth substrate may be removed by a wet etch that terminates on an etch-stop layer grown over the growth substrate before the device layers. The semiconductor structure may optionally be thinned Removing the growth substrate may expose a surface of the n-type region  50 , such as a surface of the superlattice. 
     The surface of n-type region  50  exposed by removing the growth substrate may be roughened to improve light extraction, for example by photoelectrochemical etching, or patterned by, for example, nanoimprint lithography to form a photonic crystal or other light scattering structure. In other embodiments, a light-extracting feature is buried in the structure. The light extracting feature may be, for example, a variation in index of refraction in a direction parallel to the top surface of the device (i.e. perpendicular to the growth direction of the semiconductor layers). In some embodiments, the surface of the p-type region or p-type contact layer may be roughened or patterned prior to forming the p-contact  60 . In some embodiments, before or during growth of the semiconductor structure, a layer of low index material is deposited on the growth substrate or on a semiconductor layer and patterned to form openings in the low index material or posts of low index material. Semiconductor material is then grown over the patterned low index layer to form a variation in index of refraction that is disposed within the semiconductor structure. 
     N-contact metal  34 , such as, for example, Au/Ge/Au or any other suitable contact metal or metals, may be deposited on the top surface  32  of the superlattice, then patterned to form an n-contact. For example, a photoresist layer may be deposited and patterned, then covered with the contact metal(s), then the photoresist is removed. Alternatively, the contact metal(s) may be blanket coated, then a pattern formed via photoresist, and some of the metal etched. 
       FIG. 4  is a top view of a device, illustrating one example of the arrangement of an n-contact metal. As described above, n-contact  34  may be, for example, gold, AuGe, or any other suitable metal. The n-contact  34  may have arms  35  that form a square and extensions  36  that extend from the corners of the square, though it need not. N-contact may have any suitable shape. N-contact arms  35  and extensions  36  may be 1 to 100 microns wide in some embodiments, 1 to 30 microns wide in some embodiments, and 20 to 50 microns wide in some embodiments. The n-contact arms  35  and extensions  36  are generally kept as narrow as possible to minimize light blockage or absorption, but wide enough not to incur excessive electrical contact resistance. The contact resistance increases for widths less than the transfer length Lt, which depends on the metal-to-semiconductor resistance and sheet resistance of the underlying semiconductor n-type layer. The n-contact segment width may be twice Lt since the contact arm injects current from both sides, or 1 to 30 microns for the above-described device, depending on the specific material parameters. 
     In some embodiments, the n-contact  34  is made highly reflective (R&gt;0.8). In some embodiments, a current-spreading layer is disposed between the n-type region  50  and n-contact  34  in order to improve current spreading, and potentially to minimize the surface of the n-contact thus reducing optical losses. The current-spreading layer material is selected for low optical loss and good electrical contact. Suitable materials for the current-spreading layer include are Indium Tin Oxide, Zinc Oxide, or other transparent conducting oxides. 
     N-contact  34  connects to a bonding pad  38 . Bonding pad  38  is large enough to accommodate a wire bond, wire bridge, or other suitable electrical contact to an external current source. Though in the device of  FIG. 4  bonding pad  38  is located in the corner of the device, bonding pad  38  may be located in any suitable position, including, for example, in the center of the device. 
     After forming n-contact  34 , the structure may be heated, for example to anneal n-contact  34  and/or p-contacts  60 . 
     A wafer of devices may then be tested and laser-singulated into individual devices. Individual devices may be placed in packages, and an electric contact such as a wire bond may be formed on the bonding pad  38  of the device to connect the n-contact to a part of the package such as a lead. 
     In operation, current is injected in the p-type region by contact  60  via the mount. Current is injected in the n-type region by bonding pad  38 , on the top surface of the device. 
     The devices illustrated in  FIGS. 3 and 4  are thin film devices, meaning that the growth substrate is removed from the final device. The total thickness between the top contact and the top surface of the bonding layers that connect the device to the mount in the thin film devices described above is no more than 20 microns in some embodiments and no more than 15 microns in some embodiments. 
     Having described the invention in detail, those skilled in the art will appreciate that, given the present disclosure, modifications may be made to the invention without departing from the spirit of the inventive concept described herein. Therefore, it is not intended that the scope of the invention be limited to the specific embodiments illustrated and described.