Patent Publication Number: US-11020955-B2

Title: Control of solidification in laser powder bed fusion additive manufacturing using a diode laser fiber array

Description:
CROSS-REFERENCE TO RELATED APPLICATIONS 
     This application is a continuation and claims priority to U.S. patent application Ser. No. 15/014,713 filed Feb. 3, 2016 for CONTROL OF SOLIDIFICATION IN LASER POWDER BED FUSION ADDITIVE MANUFACTURING USING A DIODE LASER FIBER ARRAY, which claims priority to U.S. patent application Ser. No. 14/106,970 filed Dec. 16, 2013 for DIODE LASER FIBER ARRAY FOR POWDER BED FABRICATION OR REPAIR, and now issued as U.S. Pat. No. 10,328,685 on Jun. 25, 2019, both of which are hereby incorporated by reference in their entirety. 
    
    
     BACKGROUND 
     The present technology relates generally to the use of a diode laser fiber array for laser powder bed fusion additive manufacturing, for example Direct Metal Laser Melting (DMLM), for use in the fabrication or repair of components, more particularly components of a gas turbine engine. 
     Additive manufacturing is a known technology that enables the “3D-printing” of components of various materials including metals, ceramics and plastics. In additive manufacturing, a part is built in a layer-by-layer manner by leveling metal powder and selectively fusing the powder within a layer using a high-power laser or electron beam. After each layer, more powder is added and the laser patterns the next layer, simultaneously fusing it to the prior layers to fabricate a complete component buried in a powder bed. Additive manufacturing systems and processes are used to fabricate precision three-dimensional components from a digital model. 
     In making a build in current powder bed systems, the laser beam or electron beam is used to scan a layer of powder to sinter and melt the desired pattern in the layers of the powder bed. The typical scanning time for such systems per layer is in the range of 70-100 seconds. For some applications, the build can require days of processing time. One application of DMLM is in the fabrication and repair of airfoils for gas turbine engines for aircraft. The geometries of the airfoils are difficult to form using conventional casting technologies, thus fabrication of the airfoils using a DMLM process or an electron-beam melting process has been proposed. With the layers built upon one another and joined to one another cross-section by cross-section, an airfoil or portion thereof, such as for a repair, with the required geometries, may be produced. The airfoil may require post-processing to provide desired structural characteristics. 
     Another problem of laser scanning Direct Metal Laser Melting (DMLM) systems is rapid cooling rates that can lead to cracking of certain alloys during the additive manufacturing build process. Rapid cooling rates also present difficulties in obtaining desirable grain morphology, pattern and size, for example equiaxed or columnar grains, grain growth that is normal to the layer surface. 
     BRIEF DESCRIPTION 
     In accordance with one example of the technology disclosed herein, a method of forming or repairing a superalloy article having a columnar or equiaxed or directionally solidified or amorphous or single crystal microstructure comprises emitting a plurality of laser beams from selected fibers of a diode laser fiber array corresponding to a pattern of a layer of the article onto a powder bed of the superalloy to form a melt pool; and controlling a temperature gradient and a solidification velocity of the melt pool to form the columnar or single crystal microstructure. 
     In accordance with another example of the technology disclosed herein, a superalloy article or repair is formed by the method of the preceding paragraph. 
    
    
     
       DRAWINGS 
       These and other features, aspects, and advantages of the present technology will become better understood when the following detailed description is read with reference to the accompanying drawings in which like characters represent like parts throughout the drawings, wherein: 
         FIG. 1A  schematically illustrates a diode laser fiber array for use with the present technology; 
         FIG. 1B  schematically illustrates another diode laser fiber array for use with the present technology; 
         FIG. 1C  schematically illustrates another diode laser fiber array for use with the present technology; 
         FIG. 1D  schematically illustrates another diode laser fiber array for use with the present technology; 
         FIG. 2  schematically illustrates a system for simultaneous melting of a pattern in a powder bed layer by a diode laser fiber array according to an example of the present technology; 
         FIG. 3  schematically illustrates a fiber optic construction usable in a diode laser fiber array according to an example of the present technology; 
         FIG. 4A  schematically illustrates a fiber array usable with the system according to the present technology; 
         FIG. 4B  schematically illustrates another fiber array usable with the system according to the present technology: 
         FIG. 5  is a Columnar to Equiaxed (CET) diagram of microstructures as a function of thermal gradient (G) and solidification velocity (V) that may be formed using the diode laser fiber array of the present technology. 
     
    
    
     DETAILED DESCRIPTION 
     Referring to  FIG. 1A , a diode laser array  101  (e.g., a diode laser bar, fiber pigtail, or stack) includes a plurality of diode lasers, or emitters,  103 , each emitting a beam of laser energy  105 . A plurality of spherical lenses  107  are positioned between the diode lasers  103  and a plurality of optical fibers  109  to couple laser energy from each diode laser  103  to an optical fiber  109 . The optical fibers  109  may be provided in a bundle  102  between the diode lasers and the free ends of the optical fiber array, as shown for example in  FIGS. 1A-1C . However, it should be appreciated that diode fiber laser arrays that do not use coupling optics may be used with the present technology, as discussed below. 
     Referring to  FIG. 1B , the diode laser fiber array  101  may include lenses  117  at the ends of the optical fibers  109 . The lenses  117  may be configured to provide collimated laser beams  120  from the optical fibers  109 . Referring to  FIG. 1C , the diode laser fiber array  101  may not include optics (e.g. a lens) between the diode lasers  103  and the optical fibers  109  and the beams of laser energy  105  may be received by the optical fibers  109  in proximity to the diode lasers  103 . The optical fibers  109  may have lenses  117  at their respective ends. The lenses  117  may be configured to provide a predetermined divergence to the laser beams  120  emitted from the optical fibers  109 . It should also be appreciated that instead of providing lenses, the ends of the optical fibers  109  may be shaped to provide collimated or divergent laser beams  120 . Referring to  FIG. 1D , the diode lasers may include fiber pigtails  123  that are spliced  125  into the input of optical fibers  109 . An f-theta lens collimates the exiting laser beams  120  from the fiber array. 
     Referring to  FIG. 2 , the diode laser fiber array  101  directs laser beams  120  from the optical fibers  109  into a powder bed  130  to simultaneously melt all of the desired powder in a layer. To generate a desired pattern, for example of a repair or a component to be fabricated, the required diode lasers  103  are turned on to affect the desired simultaneous melting from each fiber  109 . The melting process time for the desired pattern may be less than a second, which is at least two orders of magnitude faster than current scanning processes. 
     The powder bed  130  may be provided for a component  150 , for example an airfoil of a gas turbine engine of an aircraft, which is supported on a support  170  to provide a repair to the component. Although the present technology may be applicable to the repair function on components, it should be appreciated that the present technology is applicable for the additive manufacturing build of new make components. The powder bed may be provided on the support  170  and the diode laser fiber array  101  used to build or fabricate the component layer by layer. 
     The support  170  may be moved by an actuator or an actuator system  175  that is configured to move the support  170  in the Z direction (i.e. normal to the powder bed  130 ) as shown in  FIG. 2 . The actuator or actuator system  175  may also be configured to move the support  170  in the XY plane as shown in  FIG. 2 , although the support  170  is not moved in the XY plane during simultaneous melting of the powder bed from each fiber  109 . The actuator or actuator system  175  may be controlled by controller  135  that is configured to control the actuator or actuator system  175  and the diode laser fiber array  101 . The actuator or actuator system  175  may include, for example, a linear motor(s) and/or hydraulic and/or pneumatic piston(s) and/or a screw drive mechanism(s) and/or a conveyor. As the diode laser fiber array  101  is capable of simultaneously melting all of the required powder in the layer for a pattern, there is no need to move either the array  101  or the powder bed  130  during melting, for example as is done with current systems in which a laser beam or electron beam is used to scan a layer of powder. 
     The distance D between the array of optical fibers  109  (i.e. the ends of the optical fibers  109 ) and the powder bed  130  may be controlled by moving the support  170  in the Z direction. The distance D may depend on the type of laser beams  120  emitted by the optical fibers  109  (e.g. whether the laser beams  120  are collimated or divergent, and the amount of divergence), the average output power of each diode laser  103 , the pulse energy of each diode laser  103 , the pulse width of each diode laser  103 , and/or the beam mode (e.g. Gaussian, top hat, etc. distribution). The ends of the optical fibers  109  may be located at, for example, about 5 mm to about 150 mm, for example about 20 mm to about 80 mm above the powder bed  130  so that any region of a layer of the powder bed  130  can be melted at the same time by turning the required diode lasers  103  on at the same time. 
     The controller  135  controls the turning on and turning off of each diode laser  103 , and the initial power of each diode laser. The controller may also control the rate at which the power of each diode laser  103  is reduced when turned off. The controller  135  may turn each diode laser  103  on and off within a time frame of, for example, about 5 to 15 milliseconds, or longer if needed. For a given layer of powder  130 , for example above an airfoil to be repaired, the desired laser diodes  103  are activated to melt the powder in the desired shape per a CAD design, which may be input and/or stored in the controller  135 . This process may be repeated as many times as necessary to build up the required repair region. In the case of the system being used to fabricate a component, e.g. an airfoil, the process is repeated as many times as necessary to build the component. The controller  135  controls the actuator or actuator  175  to move the support  170  downwardly as layers of powder are added and subsequently processed by the diode laser fiber array. Each layer formed may be, for example, about 1 μm to about 1 mm thick. In the case of repair of an airfoil, each layer may be formed, for example, about 100 μm thick. 
     The controller  135  may be a computer processor or other logic-based device, software components (e.g., software applications), and/or a combination of hardware components and software components (e.g., a computer processor or other logic-based device and associated software application, a computer processor, or other logic-based device having hard-wired control instructions, or the like). 
     The diode laser fiber array  101  may be controlled by the controller  135  to control the temperature of powder near or adjacent to the melted region to control the cooling rate of the melted region. The controller  135  may also control the diode laser fiber array  101  to preheat the powder bed  130  and/or the component  150 . The pre-heating power densities of the diode lasers  103  may be from about 100-100,000 watts/cm 2  the powder bed  130  and/or the component  150  and/or heating the region near or. By preheating adjacent to the melt region, the thermal gradient may be controlled to be substantially only in the direction normal to the powder bed (i.e. in the Z direction in  FIG. 2 ). This may help with materials that are crack sensitive to fast solidification cooling rates. Desirable grain growth that is normal to the layer surface may be achievable with planar cooling of a powder bed layer. This allows formation of a directionally solidified (DS) type grain structure or a single crystal structure with the build repair of an airfoil type structure. It should also be appreciated that the diode lasers  103  may be controlled to heat the powder bed  130  to control the temperature and temperature gradient of the melted region. Controlling the temperature and the temperature gradient of the melted region allows control over, for example, evaporation of the powder, the grain structure of the solidified layer, and/or the surface finish of the repair or component. Spatial control of the cooling rates in the 2D plane of each build layer allows the grain structure of each build layer to be controlled, as well as the grain structure in 35 as the build layers are added to form the build. Spatial control of the cooling rates in the 2D plane of each build layer also enables special treatments of the volumes that will form the surfaces of the 3D build or part. This allows control of the surface roughness and density (porosity) at the surface, which may improve mechanical properties of the part, for example fatigue. 
     The material in the powder bed  130  may be metal powder, for example, CoCrMo powder. It should be appreciated that other materials, for example plastic, ceramic, or glass, may be used for the powder bed. Depending on the material in the powder bed, the power of each diode laser  103  may be from about 10 to about 60 watts. The power of the diode lasers  103  that are used may be related to the diameter of the optical fibers  109  used. The power density from each diode laser fiber  103  may be up to about 1,000,000 watts/cm 2  for melting the powder within a layer from each fiber. 
     The fiber centering position in the fiber array (e.g. as shown in  FIGS. 4A and 4B ) is set by the diameter of a buffer, or coating  115  of the optical fiber  109 . Referring to  FIG. 3 , the optical fiber  109  comprises a core  111 , formed of for example silica, and cladding  113 , formed for example of silica, around the core  111 . In order to create a numerical aperture and provide total internal reflection within the fiber  109 , the refractory index of the silica core may be larger than the refractory index of the silica cladding. For example, the silica core may have a refractive index of about 1.45 and the silica cladding may have a refractive index of about 1.43. The cladding  113  may have a thickness of about 10 μm. 
     The buffer, or coating,  115  surrounds the cladding  113  and may be formed of, for example, acrylate. To reduce the center spacing between the optical fibers  109 , the buffer (acrylate coating)  115  may be replaced by a thinner acrylate coating to reduce the overall fiber diameter. The thickness of the buffer, or coating  115  may be about 62 μm. The total diameter of the fiber  109  may be about 200 μm to about 250 μm. 
     The diameter of the fiber core  111  may be about 105 μm. It should be appreciated that fiber core diameters of about 60 μm may be used. In addition, it should be appreciated that optical fibers  109  of various cross sections, may be used. For example, square or hexagonal fibers may be used to increase fiber packing. The melt pool size produced by the laser beam(s)  120  from each optical fiber  109  corresponds to the effective laser spot size produced by the laser beam(s)  120 . In the case of collimated laser beams  120 , the melt pool size corresponds generally to the diameter of the fiber core  111 . However, the laser beams  120  from the fibers I  09  may be controlled to produce a melt pool size that is, for example, two to four times as large as the diameter of the fiber core  111 . The laser beams  120  may be controlled to have a divergence to provide a melt pool size larger than the diameter of the fiber core  111 . In the case of divergent laser beams  120 , the distance D from the ends of the fibers  109  of the array  101  to the powder bed  130  will also influence the melt pool size of each fiber. The pulse width of the laser beams and the laser beam mode distribution may also be controlled to adjust the melt pool size provided by each fiber. 
     Referring to  FIGS. 4A and 4B , the array of fibers  109  may be linear as shown in  FIG. 4A  or closed packed arrangement as shown in  FIG. 4B . Other arrays, for example hexagonal, may be used. It should also be appreciated that the array may be in a shape corresponding to the shape of a component to be fabricated. The spacing between the fibers  109  may be equal to the diameter of the buffer, or coating,  115 . 
     As discussed herein, the use of superalloys for repair and/or build of components such as gas turbine blades is desirable due to their excellent mechanical strength, resistance to thermal creep deformation, good surface stability and resistance to corrosion or oxidation. Single crystal superalloys are currently used due to their ability withstand loading at temperatures near their melting point, their creep and oxidation resistance. Components formed of single crystal superalloys are currently formed using techniques such as Bridgman casting. 
     Referring to  FIG. 5 , microstructures that may be formed using the diode laser fiber array of the present technology are shown as a function of thermal gradient (G) along the X-axis and the solidification velocity (V) along the Y-axis. As shown, conventional DMLM systems and processes, for example done by single laser scanning, generally produce a microstructure that is columnar for Ni-based superalloys. Conventional DMLM is generally regarded as high temperature gradient and high solidification velocity processing. Certain conventional DMLM systems and processes may produce an equiaxed structure. Planar growth occurs in the space above and below the equiaxed and columnar regions shown in the figure. High solidification rates in the top region of the figure result in complete solute trapping, as limited time is available for chemical inhomogeneities to occur. The constitutional undercooling limit is shown the lower right of the figure and planar growth is expected to occur in this region where a flat interface between the liquid and solid results with no branching. Reducing the amount of undercooling needed for nucleation expands the equiaxed region, while increasing the amount reduces the equiaxed region. 
     Referring still to  FIG. 5 , the inventors have discovered that a region of the CET diagram in the mid- to high-temperature gradient and the low- to high-velocity solidification front may provide single crystal, directionally solidified (DS) superalloys. The microstructure may be obtained by controlling the thermal gradient G and the solidification velocity V of the melt pool using a diode laser fiber array system and processes as disclosed herein. The rectangular area shown in the figure defines a range of microstructures that may be obtained. The cooling rate may vary from 0.1 s (second) to 100 s. The microstructure that may be obtained with these cooling rates span a region from high substrate heating shown on the left side of the rectangular area to no substrate heating shown on the right. The rectangular area shown in the figure could be further expanded upward and to the right, beyond the area indicated, by decreasing the thickness of the powder layer. As used herein the term “high substrate heating” means heating the substrate (the article or component beneath the powder bed) to a temperature close to, but below, the melting temperature of the substrate. It should be appreciated that a prior layer(s) of the material that is formed, or deposited, on the substrate may be heated, for example post-heated, to control, e.g. reduce, the cooling rate. These structures have a columnar, dendritic (i.e. branching or tree-like) structure. The grains produced by the systems and processes disclosed herein may be regarded as large, for example from 10 μm to 100 μm. Heating of the substrate may be performed by any suitable process, including radiant heating, induction heating, microwave heating, etc. In addition, the heating may be provided by the diode laser fiber array  101 . 
     The temperature gradient G and the solidification velocity may be controlled by controlling a decay rate of the power of the diode laser fiber array. For example, for a 10 W average output power of each diode laser, the laser energy may decay, for example linearly, at a rate of 10 W/s (for a is cool, as shown in  FIG. 5 ), or at rate of 1 W/s (for a 10 s cool, as shown in  FIG. 5 ), or 0.1 W/s (for a 100 s cool, as shown in  FIG. 5 ), but not limited to linear decay. As another example, the output from each diode laser may be decreased asymptotically to a set value, which may differ for each diode laser. It should also be appreciated that the output power of each laser diode may “instantaneously” decay, i.e. be turned off. 
     Other parameters that may be controlled to produce a single crystal, directionally solidified superalloy microstructure include laser mode distribution (e.g. Top-Hat or Gaussian) laser spot diameter, laser power, laser on-time, laser efficiency (a), and a centerline spacing between laser beams. It should be appreciated that the values (e.g. ranges) of the parameters may be dependent on the material. For example, the single crystal, directionally solidified microstructure shown in  FIG. 5  may be produced using a Top-Hat mode distribution, a laser spot diameter of 0.05-0.2 mm, a laser power of 5-60 W, an on-time of 5-50 ms, an efficiency a of 0.5, and a 80 μm centerline spacing. 
     By controlling the parameters of the diode laser fiber array, the shape of the melt pool can be controlled to achieve a flat solidification front to provide a controlled DS solidification condition. The parameters may be controlled to achieve a quasi-static melt pool. The size, including the depth, of the melt pool may be dependent on the particle size of the powder. A melt pool having a depth of 20 μm to 150 μm and a width from 3-100,000 times the depth may be formed using the diode laser fiber array. Particle sizes of the powder usable with the systems and processes disclosed herein may range from 10 μm to 150 μm, for example a powder particle size for a Ni-based superalloy may be 40 μm. 
     Although the CET diagram of  FIG. 5  is for a particular superalloy, it should be appreciated that other CET diagrams may be generated to determine the microstructures of other superalloys that may be formed using the systems and processes disclosed herein. 
     The diode laser fiber array of the present technology may be used to process a powder bed layer by exposing the layer with simultaneous laser energy from required diode laser beam sources. The present technology also allows melting the complete pattern in the layer in one time frame that could be less than a second and, when required, control the heat of the powder near and/or adjacent to the melted region to control the cooling rate of the melted region. The diode laser fiber array allows permits grain structure control. The commercial advantages for diode laser fiber array systems include fewer required systems to produce the same amount of parts as current systems and tailoring power bed systems to the size of the parts of interest. The technology disclosed herein may also be used to perform sintering, for example direct metal laser sintering. 
     The diode laser fiber array of the present technology also allows formation of microstructures over a region of mid- to high-temperature gradients and low- to high-solidification velocities, covering a large feasible region for equiaxed or columnar/dendritic (DS/SX), by controlling, inter alia, substrate temperature and laser power as a function of time. 
     It is to be understood that not necessarily all such objects or advantages described above may be achieved in accordance with any particular example. Thus, for example, those skilled in the art will recognize that the systems and techniques described herein may be embodied or carried out in a manner that achieves or optimizes one advantage or group of advantages as taught herein without necessarily achieving other objects or advantages as may be taught or suggested herein. 
     While only certain features of the present technology have been illustrated and described herein, many modifications and changes will occur to those skilled in the art. It is, therefore, to be understood that the appended claims are intended to cover all such modifications and changes.