Patent Publication Number: US-2005130408-A1

Title: Method for forming metal wiring of semiconductor device

Description:
BACKGROUND OF THE INVENTION  
      1. Field of the invention  
      The present invention relates to a method for forming a metal wiring of a semiconductor device, and more particularly to a method for forming a metal wiring of a semiconductor device through carrying out two-step tungsten CMP processes according to density an oxidizing agent included in tungsten slurry.  
      2. Description of the Prior Art  
      Generally, oxidizing agents mainly used in tungsten CMP slurry include H 2 O 2 , KlO 3 , Fe(NO 3 ) 3 , or H 5 lO 6 .  
      Hereinafter, a conventional method for forming a metal wiring by utilizing such oxidizing agents will be explained with reference to  FIGS. 1A and 1B .  
       FIGS. 1A and 1B  are sectional views showing process steps for explaining the conventional method for forming a metal wiring of a semiconductor device.  
      As shown in  FIG. 1A , according to the conventional method for forming the metal wiring, after a metal layer pattern  13  is formed on a lower layer  11 , an oxide interlayer  15  is deposited on the lower layer  11  including the metal layer pattern  13 .  
      Next, after coating photoresist material on an upper surface of the oxide interlayer  15 , an exposure and development process is carried out through a photolithography technique. Then, a resultant structure is selectively etched so that a photoresist film pattern (not shown) is formed.  
      Thereafter, the oxide interlayer  15  is selectively removed by utilizing the photoresist film pattern as a mask, thereby forming a contact hole  17  exposing an upper surface of the metal layer pattern  13 .  
      Then, after forming a barrier layer  19  on a surface of the oxide interlayer  15  including the contact hole  17 , a tungsten film  21  is deposited on the barrier layer  19  with a thickness enough to fill the contact hole  17 , that is, with a thickness exceeding a height of the contact hole  17 .  
      As shown in  FIG. 1B , the tungsten film  21  is planarized by performing a CMP process for one time while utilizing an oxidizing agent widely used in above-mentioned tungsten CMP slurry, such as H 2 O 2 , KlO 3 , Fe(NO 3 ) 3 , or H 5 lO 6 . At this time, as shown in  FIG. 1B , when a planar process is carried out, a recess  23  is formed at a tungsten film  19   a  remaining in the contact hole  17 .  
      However, according to the conventional technique, the oxidizing agent used for the tungsten CMP process may oxidize tungsten in order to increase a polishing rate.  
      Accordingly, when the tungsten CMP process is performed with slurry including a little amount of oxidizing agents, polishing time is lengthened.  
      In contrast, when the tungsten CMP process is performed with slurry including a great amount of oxidizing agents, side effects, such as a contact recess, a dishing, and oxide erosion, may occur.  
     SUMMARY OF THE INVENTION  
      Accordingly, the present invention has been made to solve the above-mentioned problems occurring in the prior art, and an object of the present invention is to provide a method for forming a metal wiring of a semiconductor device capable of reducing a contact recess, a dishing, and oxide erosion through carrying out two-step CMP processes by using slurry including a first oxidizing agent having high density and by using slurry including a second oxidizing agent having low density, respectively.  
      In order to accomplish this object, there is provided a method for forming a metal wiring of a semiconductor device, the method comprising the steps of: forming a metal layer pattern on a lower layer; forming an oxide interlayer on the lower layer including the metal layer pattern; forming a contact hole exposing an upper surface of the metal layer pattern in the oxide interlayer; filling the contact hole by forming a tungsten film on the oxide interlayer including the contact hole; polishing the tungsten film by performing a first CMP process until an upper surface of the oxide interlayer is not exposed; and performing a second CMP process after the first CMP process in such a manner that the tungsten film only remains in the contact hole.  
      According to the preferred embodiment of the present invention, density of oxidizing agent of slurry used in the first CMP process is about 5˜20 wt %.  
      A density of oxidizing agent of slurry used in the second CMP process is about 0.1˜3 wt %.  
      A thickness of the tungsten film remaining in the upper surface of the oxide interlayer in the first CMP process is about 300˜1,000 Å.  
      The oxidizing agent used in first and second CMP processes is one selected from the group consisting of H 2 O 2 , KlO 3 , Fe(NO 3 ) 3 , and H 5 lO 6 . 
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS  
      The above object, features and advantages of the present invention will be more apparent from the following detailed description taken in conjunction with the accompanying drawings, in which:  
       FIGS. 1A and 1B  are sectional views showing process steps for explaining a conventional method of forming a metal wiring of a semiconductor device;  
       FIGS. 2A  to  2 C are sectional views showing process steps for explaining a method of forming a metal wiring of a semiconductor device according to one embodiment of the present invention; and  
       FIG. 3  is a graph view showing a removal rate for a tungsten layer according to density of H 2 O 2  in a method for forming a metal wiring of a semiconductor device according to one embodiment of the present invention. 
    
    
     DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS  
      Hereinafter, a preferred embodiment of the present invention will be described with reference to the accompanying drawings. In the following description and drawings, the same reference numerals are used to designate the same or similar components, and so repetition of the description on the same or similar components will be omitted.  
       FIGS. 2A  to  2 C are sectional views showing process steps for explaining a method of forming a metal wiring of a semiconductor device according to one embodiment of the present invention.  
       FIG. 3  is a graph view showing a removal rate for a tungsten layer according to density of H 2 O 2  in a method for forming a metal wiring of a semiconductor device according to one embodiment of the present invention.  
      As shown in  FIG. 2A , according to the method for forming the metal wiring of the semiconductor device of the present invention, after forming a metal layer pattern  33  on a lower layer  31 , and an oxide interlayer  35  is deposited on the lower layer  31  including the metal layer pattern  33 .  
      Next, after coating a photoresist material on the oxide interlayer  35 , an exposure and development process is carried out through a photolithography technique. Then, a resultant structure is selectively etched, thereby forming a photoresist film pattern (not shown).  
      Thereafter, the oxide interlayer  35  is selectively removed by utilizing the photoresist film pattern as a mask in order to form a contact hole  37  exposing an upper surface of the metal layer pattern  33 .  
      Then, after forming a barrier layer  39  on a surface of the oxide interlayer  35  including the contact hole  37 , a tungsten film  41  is deposited on the barrier layer  39  with a thickness enough to fill the contact hole  37 , that is, with a thickness exceeding the height of the contact hole  37 .  
      Next, as shown in  FIG. 2B , the tungsten film  41  is planarized by performing two-step CMP processes. At this time, a first CMP process is performed by utilizing slurry including a first oxidizing agent having high density, such as H 2 O 2 , KlO 3 , Fe(NO 3 ) 3 , or H 5 lO 6 , thereby planarizing the tungsten film  41  in such a manner that the tungsten film  41  has a predetermined thickness. At this time, as is understood from an “A” portion shown in  FIG. 3 , density of the oxidizing agent included in slurry used for the first CMP process is about 5˜20 wt %. In addition, it is preferred to determine a polishing time by considering an etching rate when the first CMP process is performed. In addition, when the first CMP process is performed, a polishing target must be set in such a manner that a polishing process has been finished when the tungsten film formed on the oxide interlayer  35  has a thickness of about 300˜1000□.  
      Then, as shown in  FIG. 2C , a second CMP process is additionally performed by utilizing slurry including a second oxidizing agent having low density, such as H 2 O 2 , KlO 3 , Fe(NO 3 ) 3 , or H 5 lO 6 , thereby completely polishing tungsten film parts remaining in predetermined regions expect for the contact hole  37 . At this time, as is understood from a “B” portion shown in  FIG. 3 , density of the oxidizing agent included in slurry used for the second CMP process is about 0.1˜3 wt %.  
      As described above, according to the method for forming the metal wiring of the semiconductor device of the present invention, two-step tungsten CMP processes are performed by using two kinds of slurry having first and second oxidizing agents, which have mutually different densities, in order to maintain a high polishing rate. Accordingly, the present invention can reduce a contact recess, dishing, and oxide erosion as compared with the conventional technique without lowering the polishing rate.  
      Although a preferred embodiment of the present invention has been described for illustrative purposes, those skilled in the art will appreciate that various modifications, additions and substitutions are possible, without departing from the scope and spirit of the invention as disclosed in the accompanying claims.