PATENT ABSTRACT
Novel diarylamino phenyl carbazole compounds are provided. By appropriately selecting the nature of the diarylamino substituent and the substitution on the carbazole nitrogen, compounds with appropriate HOMO and LUMO energies can be obtained for use as materials in a secondary hole transport layer.

PATENT DESCRIPTION
[0001]    The claimed invention was made by, on behalf of, and/or in connection with one or more of the following parties to a joint university corporation research agreement: Regents of the University of Michigan, Princeton University, The University of Southern California, and the Universal Display Corporation. The agreement was in effect on and before the date the claimed invention was made, and the claimed invention was made as a result of activities undertaken within the scope of the agreement. 
       FIELD OF THE INVENTION 
       [0002]    The present invention relates to novel diarylamino phenyl carbazole compounds. In particular, these compounds are useful as materials that can be incorporated into a secondary hole transport layer in OLED devices. 
       BACKGROUND 
       [0003]    Opto-electronic devices that make use of organic materials are becoming increasingly desirable for a number of reasons. Many of the materials used to make such devices are relatively inexpensive, so organic opto-electronic devices have the potential for cost advantages over inorganic devices. In addition, the inherent properties of organic materials, such as their flexibility, may make them well suited for particular applications such as fabrication on a flexible substrate. Examples of organic opto-electronic devices include organic light emitting devices (OLEDs), organic phototransistors, organic photovoltaic cells, and organic photodetectors. For OLEDs, the organic materials may have performance advantages over conventional materials. For example, the wavelength at which an organic emissive layer emits light may generally be readily tuned with appropriate dopants. 
         [0004]    OLEDs make use of thin organic films that emit light when voltage is applied across the device. OLEDs are becoming an increasingly interesting technology for use in applications such as flat panel displays, illumination, and backlighting. Several OLED materials and configurations are described in U.S. Pat. Nos. 5,844,363, 6,303,238, and 5,707,745, which are incorporated herein by reference in their entirety. 
         [0005]    One application for phosphorescent emissive molecules is a full color display. Industry standards for such a display call for pixels adapted to emit particular colors, referred to as “saturated” colors. In particular, these standards call for saturated red, green, and blue pixels. Color may be measured using CIE coordinates, which are well known to the art. 
         [0006]    One example of a green emissive molecule is tris(2-phenylpyridine) iridium, denoted Ir(ppy) 3 , which has the following structure: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0007]    In this, and later figures herein, we depict the dative bond from nitrogen to metal (here, Ir) as a straight line. 
         [0008]    As used herein, the term “organic” includes polymeric materials as well as small molecule organic materials that may be used to fabricate organic opto-electronic devices. “Small molecule” refers to any organic material that is not a polymer, and “small molecules” may actually be quite large. Small molecules may include repeat units in some circumstances. For example, using a long chain alkyl group as a substituent does not remove a molecule from the “small molecule” class. Small molecules may also be incorporated into polymers, for example as a pendent group on a polymer backbone or as a part of the backbone. Small molecules may also serve as the core moiety of a dendrimer, which consists of a series of chemical shells built on the core moiety. The core moiety of a dendrimer may be a fluorescent or phosphorescent small molecule emitter. A dendrimer may be a “small molecule,” and it is believed that all dendrimers currently used in the field of OLEDs are small molecules. 
         [0009]    As used herein, “top” means furthest away from the substrate, while “bottom” means closest to the substrate. Where a first layer is described as “disposed over” a second layer, the first layer is disposed further away from substrate. There may be other layers between the first and second layer, unless it is specified that the first layer is “in contact with” the second layer. For example, a cathode may be described as “disposed over” an anode, even though there are various organic layers in between. 
         [0010]    As used herein, “solution processible” means capable of being dissolved, dispersed, or transported in and/or deposited from a liquid medium, either in solution or suspension form. 
         [0011]    A ligand may be referred to as “photoactive” when it is believed that the ligand directly contributes to the photoactive properties of an emissive material. A ligand may be referred to as “ancillary” when it is believed that the ligand does not contribute to the photoactive properties of an emissive material, although an ancillary ligand may alter the properties of a photoactive ligand. 
         [0012]    As used herein, and as would be generally understood by one skilled in the art, a first “Highest Occupied Molecular Orbital” (HOMO) or “Lowest Unoccupied Molecular Orbital” (LUMO) energy level is “greater than” or “higher than” a second HOMO or LUMO energy level if the first energy level is closer to the vacuum energy level. Since ionization potentials (IP) are measured as a negative energy relative to a vacuum level, a higher HOMO energy level corresponds to an IP having a smaller absolute value (an IP that is less negative). Similarly, a higher LUMO energy level corresponds to an electron affinity (EA) having a smaller absolute value (an EA that is less negative). On a conventional energy level diagram, with the vacuum level at the top, the LUMO energy level of a material is higher than the HOMO energy level of the same material. A “higher” HOMO or LUMO energy level appears closer to the top of such a diagram than a “lower” HOMO or LUMO energy level. 
         [0013]    As used herein, and as would be generally understood by one skilled in the art, a first work function is “greater than” or “higher than” a second work function if the first work function has a higher absolute value. Because work functions are generally measured as negative numbers relative to vacuum level, this means that a “higher” work function is more negative. On a conventional energy level diagram, with the vacuum level at the top, a “higher” work function is illustrated as further away from the vacuum level in the downward direction. Thus, the definitions of HOMO and LUMO energy levels follow a different convention than work functions. 
         [0014]    More details on OLEDs, and the definitions described above, can be found in U.S. Pat. No. 7,279,704, which is incorporated herein by reference in its entirety. 
       SUMMARY OF THE INVENTION 
       [0015]    In one aspect, a compound having the formula I is provided: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0000]    In the compound of Formula I, Ar 1  and Ar 2  are independently selected from the group consisting of aryl and heteroaryl, X is selected from the group consisting of O, S, and Se, R 1  and R 2  independently represent mono, di, tri, tetra substitution, or no substitution, and R 1 , R 2 , R 3  and R 4  are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfanyl, sulfonyl, phosphino, and combinations thereof. 
         [0016]    In one aspect, R 3  and R 4  are independently selected from the group consisting of alkyl, heteroalkyl, arylalkyl, aryl, and heteroaryl. In one aspect, R 3  and R 4  are hydrogen or deuterium. 
         [0017]    In one aspect, the compound has the formula: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0018]    In one aspect, Ar 1l  and Ar 2  are independently selected from the group consisting of: 
         [0000]    
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
     
         [0019]    In one aspect, A 1  and Ar 2  are independently selected from the group consisting of: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0020]    In one aspect, A 1  and Ar 2  are independently selected from the group consisting of: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0021]    In one aspect, X is O or S. In one aspect, A 1  and Ar 2  are aryl. 
         [0022]    In one aspect, the compound is selected from the group consisting of: 
         [0000]    
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
     
         [0023]    In one aspect, a first device is provided. The first device comprises an organic light emitting device, further comprising: an anode, a cathode, a hole injection layer disposed between the anode and the emissive layer, a first hole transport layer disposed between the hole injection layer and the emissive layer, and a second hole transport layer disposed between the first hole transport layer and the emissive layer, and wherein the second hole transport layer comprises a compound of formula: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0000]    In the compound of Formula II, Ar 1 , Ar 2 , and Ar 5  are independently selected from the group consisting of aryl and heteroaryl and R 3  and R 4  are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof. 
         [0024]    In one aspect, the compound has the formula: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0000]    wherein X is selected from the group consisting of O, S, and Se, wherein R 1  and R 2  independently represent mono, di, tri, tetra substitution, or no substitution, and wherein R 1  and R 2  are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof. 
         [0025]    In one aspect, the second hole transport layer is disposed adjacent to the first hole transport layer. In one aspect, the first hole transport layer is thicker than the second hole transport layer. In one aspect, the first hole transport layer comprises a compound with the formula: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0000]    wherein Ar a , Ar b , Ar c  and Ar d  are independently selected from the group consisting of aryl and heteroaryl. 
         [0026]    In one aspect, the triplet energy of the compound of Formula II is higher than the emission energy of the emissive layer. 
         [0027]    In one aspect, Ar 1 , Ar 2  and Ar 5  are independently selected from the group consisting of: 
         [0000]    
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
     
         [0028]    In one aspect, Ar 1  and Ar 2  are independently selected from the group consisting of: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0029]    In one aspect, Ar 1  and Ar 2  are independently selected from the group consisting of: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0030]    In one aspect, the first device further comprises a first dopant material that is an emissive dopant comprising a transition metal complex having at least one ligand or part of the ligand if the ligand is more than bidentate selected from the group consisting of: 
         [0000]    
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
     
         [0000]    wherein R a , R b , R c , and R d  may represent mono, di, tri, or tetra substitution, or no substitution and wherein R a , R b , R c , and R d  are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, and wherein two adjacent substituents of R a , R b , R c , and R d  are optionally joined to form a fused ring or form a multidentate ligand. 
         [0031]    In one aspect, the first device is a consumer product. In one aspect, the first device is an organic light-emitting device. In one aspect, the first device comprises a lighting panel. In one aspect, a first device comprising an organic light emitting device, further comprising an anode, a cathode, a first organic layer disposed between the anode and the cathode, and wherein the first organic layer comprises a compound of formula: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0000]    In the compound of Formula I, Ar 1  and Ar 2  are independently selected from the group consisting of aryl and heteroaryl, X is selected from the group consisting of O, S, and Se, R 1  and R 2  independently represent mono, di, tri, tetra substitution, or no substitution, and R 1 , R 2 , R 3  and R 4  are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof. 
         [0032]    In one aspect, the first organic layer is an emissive layer. In one aspect, the emissive layer is a phosphorescent emissive layer. 
     
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         [0033]      FIG. 1  shows an organic light emitting device. 
           [0034]      FIG. 2  shows an inverted organic light emitting device that does not have a separate electron transport layer. 
           [0035]      FIG. 3  shows a compound of Formula I. 
       
    
    
     DETAILED DESCRIPTION 
       [0036]    Generally, an OLED comprises at least one organic layer disposed between and electrically connected to an anode and a cathode. When a current is applied, the anode injects holes and the cathode injects electrons into the organic layer(s). The injected holes and electrons each migrate toward the oppositely charged electrode. When an electron and hole localize on the same molecule, an “exciton,” which is a localized electron-hole pair having an excited energy state, is formed. Light is emitted when the exciton relaxes via a photoemissive mechanism. In some cases, the exciton may be localized on an excimer or an exciplex. Non-radiative mechanisms, such as thermal relaxation, may also occur, but are generally considered undesirable. 
         [0037]    The initial OLEDs used emissive molecules that emitted light from their singlet states (“fluorescence”) as disclosed, for example, in U.S. Pat. No. 4,769,292, which is incorporated by reference in its entirety. Fluorescent emission generally occurs in a time frame of less than 10 nanoseconds. 
         [0038]    More recently, OLEDs having emissive materials that emit light from triplet states (“phosphorescence”) have been demonstrated. Baldo et al., “Highly Efficient Phosphorescent Emission from Organic Electroluminescent Devices,” Nature, vol. 395, 151-154, 1998; (“Baldo-I”) and Baldo et al., “Very high-efficiency green organic light-emitting devices based on electrophosphorescence,” Appl. Phys. Lett., vol. 75, No. 3, 4-6 (1999) (“Baldo-II”), which are incorporated by reference in their entireties. Phosphorescence is described in more detail in U.S. Pat. No. 7,279,704 at cols. 5-6, which are incorporated by reference. 
         [0039]      FIG. 1  shows an organic light emitting device  100 . The figures are not necessarily drawn to scale. Device  100  may include a substrate  110 , an anode  115 , a hole injection layer  120 , a hole transport layer  125 , an electron blocking layer  130 , an emissive layer  135 , a hole blocking layer  140 , an electron transport layer  145 , an electron injection layer  150 , a protective layer  155 , a cathode  160 , and a barrier layer  170 . Cathode  160  is a compound cathode having a first conductive layer  162  and a second conductive layer  164 . Device  100  may be fabricated by depositing the layers described, in order. The properties and functions of these various layers, as well as example materials, are described in more detail in U.S. Pat. No. 7,279,704 at cols. 6-10, which are incorporated by reference. 
         [0040]    More examples for each of these layers are available. For example, a flexible and transparent substrate-anode combination is disclosed in U.S. Pat. No. 5,844,363, which is incorporated by reference in its entirety. An example of a p-doped hole transport layer is m-MTDATA doped with F.sub.4-TCNQ at a molar ratio of 50:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. Examples of emissive and host materials are disclosed in U.S. Pat. No. 6,303,238 to Thompson et al., which is incorporated by reference in its entirety. An example of an n-doped electron transport layer is BPhen doped with Li at a molar ratio of 1:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. U.S. Pat. Nos. 5,703,436 and 5,707,745, which are incorporated by reference in their entireties, disclose examples of cathodes including compound cathodes having a thin layer of metal such as Mg:Ag with an overlying transparent, electrically-conductive, sputter-deposited ITO layer. The theory and use of blocking layers is described in more detail in U.S. Pat. No. 6,097,147 and U.S. Patent Application Publication No. 2003/0230980, which are incorporated by reference in their entireties. Examples of injection layers are provided in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety. A description of protective layers may be found in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety. 
         [0041]      FIG. 2  shows an inverted OLED  200 . The device includes a substrate  210 , a cathode  215 , an emissive layer  220 , a hole transport layer  225 , and an anode  230 . Device  200  may be fabricated by depositing the layers described, in order. Because the most common OLED configuration has a cathode disposed over the anode, and device  200  has cathode  215  disposed under anode  230 , device  200  may be referred to as an “inverted” OLED. Materials similar to those described with respect to device  100  may be used in the corresponding layers of device  200 .  FIG. 2  provides one example of how some layers may be omitted from the structure of device  100 . 
         [0042]    The simple layered structure illustrated in  FIGS. 1 and 2  is provided by way of non-limiting example, and it is understood that embodiments of the invention may be used in connection with a wide variety of other structures. The specific materials and structures described are exemplary in nature, and other materials and structures may be used. Functional OLEDs may be achieved by combining the various layers described in different ways, or layers may be omitted entirely, based on design, performance, and cost factors. Other layers not specifically described may also be included. Materials other than those specifically described may be used. Although many of the examples provided herein describe various layers as comprising a single material, it is understood that combinations of materials, such as a mixture of host and dopant, or more generally a mixture, may be used. Also, the layers may have various sublayers. The names given to the various layers herein are not intended to be strictly limiting. For example, in device  200 , hole transport layer  225  transports holes and injects holes into emissive layer  220 , and may be described as a hole transport layer or a hole injection layer. In one embodiment, an OLED may be described as having an “organic layer” disposed between a cathode and an anode. This organic layer may comprise a single layer, or may further comprise multiple layers of different organic materials as described, for example, with respect to  FIGS. 1 and 2 . 
         [0043]    Structures and materials not specifically described may also be used, such as OLEDs comprised of polymeric materials (PLEDs) such as disclosed in U.S. Pat. No. 5,247,190 to Friend et al., which is incorporated by reference in its entirety. By way of further example, OLEDs having a single organic layer may be used. OLEDs may be stacked, for example as described in U.S. Pat. No. 5,707,745 to Forrest et al, which is incorporated by reference in its entirety. The OLED structure may deviate from the simple layered structure illustrated in  FIGS. 1 and 2 . For example, the substrate may include an angled reflective surface to improve out-coupling, such as a mesa structure as described in U.S. Pat. No. 6,091,195 to Forrest et al., and/or a pit structure as described in U.S. Pat. No. 5,834,893 to Bulovic et al., which are incorporated by reference in their entireties. 
         [0044]    Unless otherwise specified, any of the layers of the various embodiments may be deposited by any suitable method. For the organic layers, preferred methods include thermal evaporation, ink-jet, such as described in U.S. Pat. Nos. 6,013,982 and 6,087,196, which are incorporated by reference in their entireties, organic vapor phase deposition (OVPD), such as described in U.S. Pat. No. 6,337,102 to Forrest et al., which is incorporated by reference in its entirety, and deposition by organic vapor jet printing (OVJP), such as described in U.S. patent application Ser. No. 10/233,470, which is incorporated by reference in its entirety. Other suitable deposition methods include spin coating and other solution based processes. Solution based processes are preferably carried out in nitrogen or an inert atmosphere. For the other layers, preferred methods include thermal evaporation. Preferred patterning methods include deposition through a mask, cold welding such as described in U.S. Pat. Nos. 6,294,398 and 6,468,819, which are incorporated by reference in their entireties, and patterning associated with some of the deposition methods such as ink-jet and OVJD. Other methods may also be used. The materials to be deposited may be modified to make them compatible with a particular deposition method. For example, substituents such as alkyl and aryl groups, branched or unbranched, and preferably containing at least 3 carbons, may be used in small molecules to enhance their ability to undergo solution processing. Substituents having 20 carbons or more may be used, and 3-20 carbons is a preferred range. Materials with asymmetric structures may have better solution processibility than those having symmetric structures, because asymmetric materials may have a lower tendency to recrystallize. Dendrimer substituents may be used to enhance the ability of small molecules to undergo solution processing. 
         [0045]    Devices fabricated in accordance with embodiments of the present invention may further optionally comprise a barrier layer. One purpose of the barrier layer is to protect the electrodes and organic layers from damaging exposure to harmful species in the environment including moisture, vapor and/or gases, etc. The bather layer may be deposited over, under or next to a substrate, an electrode, or over any other parts of a device including an edge. The barrier layer may comprise a single layer, or multiple layers. The barrier layer may be formed by various known chemical vapor deposition techniques and may include compositions having a single phase as well as compositions having multiple phases. Any suitable material or combination of materials may be used for the barrier layer. The barrier layer may incorporate an inorganic or an organic compound or both. The preferred barrier layer comprises a mixture of a polymeric material and a non-polymeric material as described in U.S. Pat. No. 7,968,146, PCT Pat. Application Nos. PCT/US2007/023098 and PCT/US2009/042829, which are herein incorporated by reference in their entireties. To be considered a “mixture”, the aforesaid polymeric and non-polymeric materials comprising the barrier layer should be deposited under the same reaction conditions and/or at the same time. The weight ratio of polymeric to non-polymeric material may be in the range of 95:5 to 5:95. The polymeric material and the non-polymeric material may be created from the same precursor material. In one example, the mixture of a polymeric material and a non-polymeric material consists essentially of polymeric silicon and inorganic silicon. 
         [0046]    Devices fabricated in accordance with embodiments of the invention may be incorporated into a wide variety of consumer products, including flat panel displays, computer monitors, medical monitors, televisions, billboards, lights for interior or exterior illumination and/or signaling, heads up displays, fully transparent displays, flexible displays, laser printers, telephones, cell phones, personal digital assistants (PDAs), laptop computers, digital cameras, camcorders, viewfinders, micro-displays, vehicles, a large area wall, theater or stadium screen, or a sign. Various control mechanisms may be used to control devices fabricated in accordance with the present invention, including passive matrix and active matrix. Many of the devices are intended for use in a temperature range comfortable to humans, such as 18 degrees C. to 30 degrees C., and more preferably at room temperature (20-25 degrees C.). 
         [0047]    The materials and structures described herein may have applications in devices other than OLEDs. For example, other optoelectronic devices such as organic solar cells and organic photodetectors may employ the materials and structures. More generally, organic devices, such as organic transistors, may employ the materials and structures. 
         [0048]    The terms halo, halogen, alkyl, cycloalkyl, alkenyl, alkynyl, arylkyl, heterocyclic group, aryl, aromatic group, and heteroaryl are known to the art, and are defined in U.S. Pat. No. 7,279,704 at cols. 31-32, which are incorporated herein by reference. 
         [0049]    In one embodiment, a compound having the formula I is provided: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0000]    In the compound of Formula I, Ar 1  and Ar 2  are independently selected from the group consisting of aryl and heteroaryl, X is selected from the group consisting of O, S, and Se, R 1  and R 2  independently represent mono, di, tri, tetra substitution, or no substitution, and R 1 , R 2 , R 3  and R 4  are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof. 
         [0050]    In one embodiment, R 3  and R 4  are independently selected from the group consisting of alkyl, heteroalkyl, arylalkyl, aryl, and heteroaryl. In one embodiment, R 3  and R 4  are hydrogen or deuterium. 
         [0051]    In one embodiment, the compound has the formula: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0052]    In one embodiment, A 1  and Ar 2  are independently selected from the group consisting of: 
         [0000]    
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
     
         [0053]    In one embodiment, Ar 1  and Ar 2  are independently selected from the group consisting of: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0054]    In one embodiment, Ar 1  and Ar 2  are independently selected from the group consisting of: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0055]    In one embodiment, X is O or S. In one embodiment, Ar 1  and Ar 2  are aryl. 
         [0056]    In one embodiment, the compound is selected from the group consisting of: 
         [0000]    
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
     
         [0057]    In some embodiments, the compounds are selected from the group consisting of Compound 1-Compound 1183 as depicted in Table 1. The list of substituents in Table 1 is as follows: 
         [0000]    
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
     
         [0058]    The subscript “x” in Ar x  depends on whether the group is Ar 1 , Ar 2 , or Ar 5 . 
         [0000]    
       
         
               
               
               
             
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
               
             
           
               
                   
                   
               
               
                   
                 Ar 5   
                   
               
             
          
           
               
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 Ar 5 - 
                 Ar 5 - 
                 Ar 5 - 
                 Ar 5 - 
                   
               
               
                 Ar 1   
                 Ar 2   
                 Ar 5 -1 
                 Ar 5 -2 
                 Ar 5 -3 
                 Ar 5 -4 
                 Ar 5 -5 
                 Ar 5 -6 
                 Ar 5 -7 
                 Ar 5 -8 
                 Ar 5 -9 
                 10 
                 11 
                 12 
                 13 
                 Compound 
               
               
                   
               
             
          
           
               
                 Ar 1 -1 
                 Ar 2 -1 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1 
               
               
                 Ar 1 -1 
                 Ar 2 -1 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 2 
               
               
                 Ar 1 -1 
                 Ar 2 -1 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 3 
               
               
                 Ar 1 -1 
                 Ar 2 -1 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 4 
               
               
                 Ar 1 -1 
                 Ar 2 -1 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 5 
               
               
                 Ar 1 -1 
                 Ar 2 -1 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 6 
               
               
                 Ar 1 -1 
                 Ar 2 -1 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 7 
               
               
                 Ar 1 -1 
                 Ar 2 -1 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 8 
               
               
                 Ar 1 -1 
                 Ar 2 -1 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 9 
               
               
                 Ar 1 -1 
                 Ar 2 -1 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 10 
               
               
                 Ar 1 -1 
                 Ar 2 -1 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 11 
               
               
                 Ar 1 -1 
                 Ar 2 -1 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 12 
               
               
                 Ar 1 -1 
                 Ar 2 -1 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 13 
               
               
                 Ar 1 -1 
                 Ar 2 -2 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 14 
               
               
                 Ar 1 -1 
                 Ar 2 -2 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 15 
               
               
                 Ar 1 -1 
                 Ar 2 -2 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 16 
               
               
                 Ar 1 -1 
                 Ar 2 -2 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 17 
               
               
                 Ar 1 -1 
                 Ar 2 -2 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 18 
               
               
                 Ar 1 -1 
                 Ar 2 -2 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 19 
               
               
                 Ar 1 -1 
                 Ar 2 -2 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 20 
               
               
                 Ar 1 -1 
                 Ar 2 -2 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 21 
               
               
                 Ar 1 -1 
                 Ar 2 -2 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 22 
               
               
                 Ar 1 -1 
                 Ar 2 -2 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 23 
               
               
                 Ar 1 -1 
                 Ar 2 -2 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 24 
               
               
                 Ar 1 -1 
                 Ar 2 -2 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 25 
               
               
                 Ar 1 -1 
                 Ar 2 -2 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 26 
               
               
                 Ar 1 -1 
                 Ar 2 -3 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 27 
               
               
                 Ar 1 -1 
                 Ar 2 -3 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 28 
               
               
                 Ar 1 -1 
                 Ar 2 -3 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 29 
               
               
                 Ar 1 -1 
                 Ar 2 -3 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 30 
               
               
                 Ar 1 -1 
                 Ar 2 -3 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 31 
               
               
                 Ar 1 -1 
                 Ar 2 -3 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 32 
               
               
                 Ar 1 -1 
                 Ar 2 -3 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 33 
               
               
                 Ar 1 -1 
                 Ar 2 -3 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 34 
               
               
                 Ar 1 -1 
                 Ar 2 -3 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 35 
               
               
                 Ar 1 -1 
                 Ar 2 -3 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 36 
               
               
                 Ar 1 -1 
                 Ar 2 -3 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 37 
               
               
                 Ar 1 -1 
                 Ar 2 -3 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 38 
               
               
                 Ar 1 -1 
                 Ar 2 -3 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 39 
               
               
                 Ar 1 -1 
                 Ar 2 -4 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 40 
               
               
                 Ar 1 -1 
                 Ar 2 -4 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 41 
               
               
                 Ar 1 -1 
                 Ar 2 -4 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 42 
               
               
                 Ar 1 -1 
                 Ar 2 -4 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 43 
               
               
                 Ar 1 -1 
                 Ar 2 -4 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 44 
               
               
                 Ar 1 -1 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 45 
               
               
                 Ar 1 -1 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 46 
               
               
                 Ar 1 -1 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 47 
               
               
                 Ar 1 -1 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 48 
               
               
                 Ar 1 -1 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 49 
               
               
                 Ar 1 -1 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 50 
               
               
                 Ar 1 -1 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 51 
               
               
                 Ar 1 -1 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 52 
               
               
                 Ar 1 -1 
                 Ar 2 -5 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 53 
               
               
                 Ar 1 -1 
                 Ar 2 -5 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 54 
               
               
                 Ar 1 -1 
                 Ar 2 -5 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 55 
               
               
                 Ar 1 -1 
                 Ar 2 -5 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 56 
               
               
                 Ar 1 -1 
                 Ar 2 -5 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 57 
               
               
                 Ar 1 -1 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 58 
               
               
                 Ar 1 -1 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 59 
               
               
                 Ar 1 -1 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 60 
               
               
                 Ar 1 -1 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 61 
               
               
                 Ar 1 -1 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 62 
               
               
                 Ar 1 -1 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 63 
               
               
                 Ar 1 -1 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 64 
               
               
                 Ar 1 -1 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 65 
               
               
                 Ar 1 -1 
                 Ar 2 -6 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 66 
               
               
                 Ar 1 -1 
                 Ar 2 -6 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 67 
               
               
                 Ar 1 -1 
                 Ar 2 -6 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 68 
               
               
                 Ar 1 -1 
                 Ar 2 -6 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 69 
               
               
                 Ar 1 -1 
                 Ar 2 -6 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 70 
               
               
                 Ar 1 -1 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 71 
               
               
                 Ar 1 -1 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 72 
               
               
                 Ar 1 -1 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 73 
               
               
                 Ar 1 -1 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 74 
               
               
                 Ar 1 -1 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 75 
               
               
                 Ar 1 -1 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 76 
               
               
                 Ar 1 -1 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 77 
               
               
                 Ar 1 -1 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 78 
               
               
                 Ar 1 -1 
                 Ar 2 -7 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 79 
               
               
                 Ar 1 -1 
                 Ar 2 -7 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 80 
               
               
                 Ar 1 -1 
                 Ar 2 -7 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 81 
               
               
                 Ar 1 -1 
                 Ar 2 -7 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 82 
               
               
                 Ar 1 -1 
                 Ar 2 -7 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 83 
               
               
                 Ar 1 -1 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 84 
               
               
                 Ar 1 -1 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 85 
               
               
                 Ar 1 -1 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 86 
               
               
                 Ar 1 -1 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 87 
               
               
                 Ar 1 -1 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 88 
               
               
                 Ar 1 -1 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 89 
               
               
                 Ar 1 -1 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 90 
               
               
                 Ar 1 -1 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 91 
               
               
                 Ar 1 -1 
                 Ar 2 -8 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 92 
               
               
                 Ar 1 -1 
                 Ar 2 -8 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 93 
               
               
                 Ar 1 -1 
                 Ar 2 -8 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 94 
               
               
                 Ar 1 -1 
                 Ar 2 -8 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 95 
               
               
                 Ar 1 -1 
                 Ar 2 -8 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 96 
               
               
                 Ar 1 -1 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 97 
               
               
                 Ar 1 -1 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 98 
               
               
                 Ar 1 -1 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 99 
               
               
                 Ar 1 -1 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 100 
               
               
                 Ar 1 -1 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 101 
               
               
                 Ar 1 -1 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 102 
               
               
                 Ar 1 -1 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 103 
               
               
                 Ar 1 -1 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 104 
               
               
                 Ar 1 -1 
                 Ar 2 -9 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 105 
               
               
                 Ar 1 -1 
                 Ar 2 -9 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 106 
               
               
                 Ar 1 -1 
                 Ar 2 -9 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 107 
               
               
                 Ar 1 -1 
                 Ar 2 -9 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 108 
               
               
                 Ar 1 -1 
                 Ar 2 -9 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 109 
               
               
                 Ar 1 -1 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 110 
               
               
                 Ar 1 -1 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 111 
               
               
                 Ar 1 -1 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 112 
               
               
                 Ar 1 -1 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 113 
               
               
                 Ar 1 -1 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 114 
               
               
                 Ar 1 -1 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 115 
               
               
                 Ar 1 -1 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 116 
               
               
                 Ar 1 -1 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 117 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 118 
               
               
                   
                 10 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 119 
               
               
                   
                 10 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 120 
               
               
                   
                 10 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 121 
               
               
                   
                 10 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 122 
               
               
                   
                 10 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 123 
               
               
                   
                 10 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 124 
               
               
                   
                 10 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 125 
               
               
                   
                 10 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 126 
               
               
                   
                 10 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 127 
               
               
                   
                 10 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 128 
               
               
                   
                 10 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 129 
               
               
                   
                 10 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 130 
               
               
                   
                 10 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 131 
               
               
                   
                 11 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 132 
               
               
                   
                 11 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 133 
               
               
                   
                 11 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 134 
               
               
                   
                 11 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 135 
               
               
                   
                 11 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 136 
               
               
                   
                 11 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 137 
               
               
                   
                 11 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 138 
               
               
                   
                 11 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 139 
               
               
                   
                 11 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 140 
               
               
                   
                 11 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 141 
               
               
                   
                 11 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 142 
               
               
                   
                 11 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 143 
               
               
                   
                 11 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 144 
               
               
                   
                 12 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 145 
               
               
                   
                 12 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 146 
               
               
                   
                 12 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 147 
               
               
                   
                 12 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 148 
               
               
                   
                 12 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 149 
               
               
                   
                 12 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 150 
               
               
                   
                 12 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 151 
               
               
                   
                 12 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 152 
               
               
                   
                 12 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 153 
               
               
                   
                 12 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 154 
               
               
                   
                 12 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 155 
               
               
                   
                 12 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 156 
               
               
                   
                 12 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 157 
               
               
                   
                 13 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 158 
               
               
                   
                 13 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 159 
               
               
                   
                 13 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 160 
               
               
                   
                 13 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 161 
               
               
                   
                 13 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 162 
               
               
                   
                 13 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 163 
               
               
                   
                 13 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 164 
               
               
                   
                 13 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 165 
               
               
                   
                 13 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 166 
               
               
                   
                 13 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 167 
               
               
                   
                 13 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 168 
               
               
                   
                 13 
               
               
                 Ar 1 -1 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 169 
               
               
                   
                 13 
               
               
                 Ar 1 -2 
                 Ar 2 -2 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 170 
               
               
                 Ar 1 -2 
                 Ar 2 -2 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 171 
               
               
                 Ar 1 -2 
                 Ar 2 -2 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 172 
               
               
                 Ar 1 -2 
                 Ar 2 -2 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 173 
               
               
                 Ar 1 -2 
                 Ar 2 -2 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 174 
               
               
                 Ar 1 -2 
                 Ar 2 -2 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 175 
               
               
                 Ar 1 -2 
                 Ar 2 -2 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 176 
               
               
                 Ar 1 -2 
                 Ar 2 -2 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 177 
               
               
                 Ar 1 -2 
                 Ar 2 -2 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 178 
               
               
                 Ar 1 -2 
                 Ar 2 -2 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 179 
               
               
                 Ar 1 -2 
                 Ar 2 -2 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 180 
               
               
                 Ar 1 -2 
                 Ar 2 -2 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 181 
               
               
                 Ar 1 -2 
                 Ar 2 -2 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 182 
               
               
                 Ar 1 -2 
                 Ar 2 -3 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 183 
               
               
                 Ar 1 -2 
                 Ar 2 -3 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 184 
               
               
                 Ar 1 -2 
                 Ar 2 -3 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 185 
               
               
                 Ar 1 -2 
                 Ar 2 -3 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 186 
               
               
                 Ar 1 -2 
                 Ar 2 -3 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 187 
               
               
                 Ar 1 -2 
                 Ar 2 -3 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 188 
               
               
                 Ar 1 -2 
                 Ar 2 -3 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 189 
               
               
                 Ar 1 -2 
                 Ar 2 -3 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 190 
               
               
                 Ar 1 -2 
                 Ar 2 -3 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 191 
               
               
                 Ar 1 -2 
                 Ar 2 -3 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 192 
               
               
                 Ar 1 -2 
                 Ar 2 -3 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 193 
               
               
                 Ar 1 -2 
                 Ar 2 -3 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 194 
               
               
                 Ar 1 -2 
                 Ar 2 -3 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 195 
               
               
                 Ar 1 -2 
                 Ar 2 -4 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 196 
               
               
                 Ar 1 -2 
                 Ar 2 -4 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 197 
               
               
                 Ar 1 -2 
                 Ar 2 -4 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 198 
               
               
                 Ar 1 -2 
                 Ar 2 -4 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 199 
               
               
                 Ar 1 -2 
                 Ar 2 -4 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 200 
               
               
                 Ar 1 -2 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 201 
               
               
                 Ar 1 -2 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 202 
               
               
                 Ar 1 -2 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 203 
               
               
                 Ar 1 -2 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 204 
               
               
                 Ar 1 -2 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 205 
               
               
                 Ar 1 -2 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 206 
               
               
                 Ar 1 -2 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 207 
               
               
                 Ar 1 -2 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 208 
               
               
                 Ar 1 -2 
                 Ar 2 -5 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 209 
               
               
                 Ar 1 -2 
                 Ar 2 -5 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 210 
               
               
                 Ar 1 -2 
                 Ar 2 -5 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 211 
               
               
                 Ar 1 -2 
                 Ar 2 -5 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 212 
               
               
                 Ar 1 -2 
                 Ar 2 -5 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 213 
               
               
                 Ar 1 -2 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 214 
               
               
                 Ar 1 -2 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 215 
               
               
                 Ar 1 -2 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 216 
               
               
                 Ar 1 -2 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 217 
               
               
                 Ar 1 -2 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 218 
               
               
                 Ar 1 -2 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 219 
               
               
                 Ar 1 -2 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 220 
               
               
                 Ar 1 -2 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 221 
               
               
                 Ar 1 -2 
                 Ar 2 -6 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 222 
               
               
                 Ar 1 -2 
                 Ar 2 -6 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 223 
               
               
                 Ar 1 -2 
                 Ar 2 -6 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 224 
               
               
                 Ar 1 -2 
                 Ar 2 -6 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 225 
               
               
                 Ar 1 -2 
                 Ar 2 -6 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 226 
               
               
                 Ar 1 -2 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 227 
               
               
                 Ar 1 -2 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 228 
               
               
                 Ar 1 -2 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 229 
               
               
                 Ar 1 -2 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 230 
               
               
                 Ar 1 -2 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 231 
               
               
                 Ar 1 -2 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 232 
               
               
                 Ar 1 -2 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 233 
               
               
                 Ar 1 -2 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 234 
               
               
                 Ar 1 -2 
                 Ar 2 -7 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 235 
               
               
                 Ar 1 -2 
                 Ar 2 -7 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 236 
               
               
                 Ar 1 -2 
                 Ar 2 -7 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 237 
               
               
                 Ar 1 -2 
                 Ar 2 -7 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 238 
               
               
                 Ar 1 -2 
                 Ar 2 -7 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 239 
               
               
                 Ar 1 -2 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 240 
               
               
                 Ar 1 -2 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 241 
               
               
                 Ar 1 -2 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 242 
               
               
                 Ar 1 -2 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 243 
               
               
                 Ar 1 -2 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 244 
               
               
                 Ar 1 -2 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 245 
               
               
                 Ar 1 -2 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 246 
               
               
                 Ar 1 -2 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 247 
               
               
                 Ar 1 -2 
                 Ar 2 -8 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 248 
               
               
                 Ar 1 -2 
                 Ar 2 -8 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 249 
               
               
                 Ar 1 -2 
                 Ar 2 -8 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 250 
               
               
                 Ar 1 -2 
                 Ar 2 -8 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 251 
               
               
                 Ar 1 -2 
                 Ar 2 -8 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 252 
               
               
                 Ar 1 -2 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 253 
               
               
                 Ar 1 -2 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 254 
               
               
                 Ar 1 -2 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 255 
               
               
                 Ar 1 -2 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 256 
               
               
                 Ar 1 -2 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 257 
               
               
                 Ar 1 -2 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 258 
               
               
                 Ar 1 -2 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 259 
               
               
                 Ar 1 -2 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 260 
               
               
                 Ar 1 -2 
                 Ar 2 -9 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 261 
               
               
                 Ar 1 -2 
                 Ar 2 -9 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 262 
               
               
                 Ar 1 -2 
                 Ar 2 -9 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 263 
               
               
                 Ar 1 -2 
                 Ar 2 -9 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 264 
               
               
                 Ar 1 -2 
                 Ar 2 -9 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 265 
               
               
                 Ar 1 -2 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 266 
               
               
                 Ar 1 -2 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 267 
               
               
                 Ar 1 -2 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 268 
               
               
                 Ar 1 -2 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 269 
               
               
                 Ar 1 -2 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 270 
               
               
                 Ar 1 -2 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 271 
               
               
                 Ar 1 -2 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 272 
               
               
                 Ar 1 -2 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 273 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 274 
               
               
                   
                 10 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 275 
               
               
                   
                 10 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 276 
               
               
                   
                 10 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 277 
               
               
                   
                 10 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 278 
               
               
                   
                 10 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 279 
               
               
                   
                 10 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 280 
               
               
                   
                 10 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 281 
               
               
                   
                 10 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 282 
               
               
                   
                 10 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 283 
               
               
                   
                 10 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 284 
               
               
                   
                 10 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 285 
               
               
                   
                 10 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 286 
               
               
                   
                 10 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 287 
               
               
                   
                 11 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 288 
               
               
                   
                 11 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 289 
               
               
                   
                 11 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 290 
               
               
                   
                 11 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 291 
               
               
                   
                 11 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 292 
               
               
                   
                 11 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 293 
               
               
                   
                 11 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 294 
               
               
                   
                 11 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 295 
               
               
                   
                 11 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 296 
               
               
                   
                 11 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 297 
               
               
                   
                 11 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 298 
               
               
                   
                 11 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 299 
               
               
                   
                 11 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 300 
               
               
                   
                 12 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 301 
               
               
                   
                 12 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 302 
               
               
                   
                 12 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 303 
               
               
                   
                 12 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 304 
               
               
                   
                 12 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 305 
               
               
                   
                 12 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 306 
               
               
                   
                 12 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 307 
               
               
                   
                 12 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 308 
               
               
                   
                 12 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 309 
               
               
                   
                 12 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 310 
               
               
                   
                 12 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 311 
               
               
                   
                 12 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 312 
               
               
                   
                 12 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 313 
               
               
                   
                 13 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 314 
               
               
                   
                 13 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 315 
               
               
                   
                 13 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 316 
               
               
                   
                 13 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 317 
               
               
                   
                 13 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 318 
               
               
                   
                 13 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 319 
               
               
                   
                 13 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 320 
               
               
                   
                 13 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 321 
               
               
                   
                 13 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 322 
               
               
                   
                 13 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 323 
               
               
                   
                 13 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 324 
               
               
                   
                 13 
               
               
                 Ar 1 -2 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 325 
               
               
                   
                 13 
               
               
                 Ar 1 -3 
                 Ar 2 -3 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 326 
               
               
                 Ar 1 -3 
                 Ar 2 -3 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 327 
               
               
                 Ar 1 -3 
                 Ar 2 -3 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 328 
               
               
                 Ar 1 -3 
                 Ar 2 -3 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 329 
               
               
                 Ar 1 -3 
                 Ar 2 -3 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 330 
               
               
                 Ar 1 -3 
                 Ar 2 -3 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 331 
               
               
                 Ar 1 -3 
                 Ar 2 -3 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 332 
               
               
                 Ar 1 -3 
                 Ar 2 -3 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 333 
               
               
                 Ar 1 -3 
                 Ar 2 -3 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 334 
               
               
                 Ar 1 -3 
                 Ar 2 -3 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 335 
               
               
                 Ar 1 -3 
                 Ar 2 -3 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 336 
               
               
                 Ar 1 -3 
                 Ar 2 -3 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 337 
               
               
                 Ar 1 -3 
                 Ar 2 -3 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 338 
               
               
                 Ar 1 -3 
                 Ar 2 -4 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 339 
               
               
                 Ar 1 -3 
                 Ar 2 -4 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 340 
               
               
                 Ar 1 -3 
                 Ar 2 -4 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 341 
               
               
                 Ar 1 -3 
                 Ar 2 -4 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 342 
               
               
                 Ar 1 -3 
                 Ar 2 -4 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 343 
               
               
                 Ar 1 -3 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 344 
               
               
                 Ar 1 -3 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 345 
               
               
                 Ar 1 -3 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 346 
               
               
                 Ar 1 -3 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 347 
               
               
                 Ar 1 -3 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 348 
               
               
                 Ar 1 -3 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 349 
               
               
                 Ar 1 -3 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 350 
               
               
                 Ar 1 -3 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 351 
               
               
                 Ar 1 -3 
                 Ar 2 -5 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 352 
               
               
                 Ar 1 -3 
                 Ar 2 -5 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 353 
               
               
                 Ar 1 -3 
                 Ar 2 -5 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 354 
               
               
                 Ar 1 -3 
                 Ar 2 -5 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 355 
               
               
                 Ar 1 -3 
                 Ar 2 -5 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 356 
               
               
                 Ar 1 -3 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 357 
               
               
                 Ar 1 -3 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 358 
               
               
                 Ar 1 -3 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 359 
               
               
                 Ar 1 -3 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 360 
               
               
                 Ar 1 -3 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 361 
               
               
                 Ar 1 -3 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 362 
               
               
                 Ar 1 -3 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 363 
               
               
                 Ar 1 -3 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 364 
               
               
                 Ar 1 -3 
                 Ar 2 -6 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 365 
               
               
                 Ar 1 -3 
                 Ar 2 -6 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 366 
               
               
                 Ar 1 -3 
                 Ar 2 -6 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 367 
               
               
                 Ar 1 -3 
                 Ar 2 -6 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 368 
               
               
                 Ar 1 -3 
                 Ar 2 -6 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 369 
               
               
                 Ar 1 -3 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 370 
               
               
                 Ar 1 -3 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 371 
               
               
                 Ar 1 -3 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 372 
               
               
                 Ar 1 -3 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 373 
               
               
                 Ar 1 -3 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 374 
               
               
                 Ar 1 -3 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 375 
               
               
                 Ar 1 -3 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 376 
               
               
                 Ar 1 -3 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 377 
               
               
                 Ar 1 -3 
                 Ar 2 -7 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 378 
               
               
                 Ar 1 -3 
                 Ar 2 -7 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 379 
               
               
                 Ar 1 -3 
                 Ar 2 -7 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 380 
               
               
                 Ar 1 -3 
                 Ar 2 -7 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 381 
               
               
                 Ar 1 -3 
                 Ar 2 -7 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 382 
               
               
                 Ar 1 -3 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 383 
               
               
                 Ar 1 -3 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 384 
               
               
                 Ar 1 -3 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 385 
               
               
                 Ar 1 -3 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 386 
               
               
                 Ar 1 -3 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 387 
               
               
                 Ar 1 -3 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 388 
               
               
                 Ar 1 -3 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 389 
               
               
                 Ar 1 -3 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 390 
               
               
                 Ar 1 -3 
                 Ar 2 -8 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 391 
               
               
                 Ar 1 -3 
                 Ar 2 -8 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 392 
               
               
                 Ar 1 -3 
                 Ar 2 -8 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 393 
               
               
                 Ar 1 -3 
                 Ar 2 -8 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 394 
               
               
                 Ar 1 -3 
                 Ar 2 -8 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 395 
               
               
                 Ar 1 -3 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 396 
               
               
                 Ar 1 -3 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 397 
               
               
                 Ar 1 -3 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 398 
               
               
                 Ar 1 -3 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 399 
               
               
                 Ar 1 -3 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 400 
               
               
                 Ar 1 -3 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 401 
               
               
                 Ar 1 -3 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 402 
               
               
                 Ar 1 -3 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 403 
               
               
                 Ar 1 -3 
                 Ar 2 -9 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 404 
               
               
                 Ar 1 -3 
                 Ar 2 -9 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 405 
               
               
                 Ar 1 -3 
                 Ar 2 -9 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 406 
               
               
                 Ar 1 -3 
                 Ar 2 -9 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 407 
               
               
                 Ar 1 -3 
                 Ar 2 -9 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 408 
               
               
                 Ar 1 -3 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 409 
               
               
                 Ar 1 -3 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 410 
               
               
                 Ar 1 -3 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 411 
               
               
                 Ar 1 -3 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 412 
               
               
                 Ar 1 -3 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 413 
               
               
                 Ar 1 -3 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 414 
               
               
                 Ar 1 -3 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 415 
               
               
                 Ar 1 -3 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 416 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 417 
               
               
                   
                 10 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 418 
               
               
                   
                 10 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 419 
               
               
                   
                 10 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 420 
               
               
                   
                 10 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 421 
               
               
                   
                 10 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 422 
               
               
                   
                 10 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 423 
               
               
                   
                 10 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 424 
               
               
                   
                 10 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 425 
               
               
                   
                 10 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 426 
               
               
                   
                 10 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 427 
               
               
                   
                 10 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 428 
               
               
                   
                 10 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 429 
               
               
                   
                 10 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 430 
               
               
                   
                 11 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 431 
               
               
                   
                 11 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 432 
               
               
                   
                 11 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 433 
               
               
                   
                 11 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 434 
               
               
                   
                 11 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 435 
               
               
                   
                 11 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 436 
               
               
                   
                 11 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 437 
               
               
                   
                 11 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 438 
               
               
                   
                 11 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 439 
               
               
                   
                 11 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 440 
               
               
                   
                 11 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 441 
               
               
                   
                 11 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 442 
               
               
                   
                 11 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 443 
               
               
                   
                 12 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 444 
               
               
                   
                 12 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 445 
               
               
                   
                 12 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 446 
               
               
                   
                 12 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 447 
               
               
                   
                 12 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 448 
               
               
                   
                 12 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 449 
               
               
                   
                 12 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 450 
               
               
                   
                 12 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 451 
               
               
                   
                 12 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 452 
               
               
                   
                 12 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 453 
               
               
                   
                 12 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 454 
               
               
                   
                 12 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 455 
               
               
                   
                 12 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 456 
               
               
                   
                 13 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 457 
               
               
                   
                 13 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 458 
               
               
                   
                 13 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 459 
               
               
                   
                 13 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 460 
               
               
                   
                 13 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 461 
               
               
                   
                 13 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 462 
               
               
                   
                 13 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 463 
               
               
                   
                 13 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 464 
               
               
                   
                 13 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 465 
               
               
                   
                 13 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 466 
               
               
                   
                 13 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 467 
               
               
                   
                 13 
               
               
                 Ar 1 -3 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 468 
               
               
                   
                 13 
               
               
                 Ar 1 -4 
                 Ar 2 -4 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 469 
               
               
                 Ar 1 -4 
                 Ar 2 -4 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 470 
               
               
                 Ar 1 -4 
                 Ar 2 -4 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 471 
               
               
                 Ar 1 -4 
                 Ar 2 -4 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 472 
               
               
                 Ar 1 -4 
                 Ar 2 -4 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 473 
               
               
                 Ar 1 -4 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 474 
               
               
                 Ar 1 -4 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 475 
               
               
                 Ar 1 -4 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 476 
               
               
                 Ar 1 -4 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 477 
               
               
                 Ar 1 -4 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 478 
               
               
                 Ar 1 -4 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 479 
               
               
                 Ar 1 -4 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 480 
               
               
                 Ar 1 -4 
                 Ar 2 -4 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 481 
               
               
                 Ar 1 -4 
                 Ar 2 -5 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 482 
               
               
                 Ar 1 -4 
                 Ar 2 -5 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 483 
               
               
                 Ar 1 -4 
                 Ar 2 -5 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 484 
               
               
                 Ar 1 -4 
                 Ar 2 -5 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 485 
               
               
                 Ar 1 -4 
                 Ar 2 -5 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 486 
               
               
                 Ar 1 -4 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 487 
               
               
                 Ar 1 -4 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 488 
               
               
                 Ar 1 -4 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 489 
               
               
                 Ar 1 -4 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 490 
               
               
                 Ar 1 -4 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 491 
               
               
                 Ar 1 -4 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 492 
               
               
                 Ar 1 -4 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 493 
               
               
                 Ar 1 -4 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 494 
               
               
                 Ar 1 -4 
                 Ar 2 -6 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 495 
               
               
                 Ar 1 -4 
                 Ar 2 -6 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 496 
               
               
                 Ar 1 -4 
                 Ar 2 -6 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 497 
               
               
                 Ar 1 -4 
                 Ar 2 -6 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 498 
               
               
                 Ar 1 -4 
                 Ar 2 -6 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 499 
               
               
                 Ar 1 -4 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 500 
               
               
                 Ar 1 -4 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 501 
               
               
                 Ar 1 -4 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 502 
               
               
                 Ar 1 -4 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 503 
               
               
                 Ar 1 -4 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 504 
               
               
                 Ar 1 -4 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 505 
               
               
                 Ar 1 -4 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 506 
               
               
                 Ar 1 -4 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 507 
               
               
                 Ar 1 -4 
                 Ar 2 -7 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 508 
               
               
                 Ar 1 -4 
                 Ar 2 -7 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 509 
               
               
                 Ar 1 -4 
                 Ar 2 -7 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 510 
               
               
                 Ar 1 -4 
                 Ar 2 -7 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 511 
               
               
                 Ar 1 -4 
                 Ar 2 -7 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 512 
               
               
                 Ar 1 -4 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 513 
               
               
                 Ar 1 -4 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 514 
               
               
                 Ar 1 -4 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 515 
               
               
                 Ar 1 -4 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 516 
               
               
                 Ar 1 -4 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 517 
               
               
                 Ar 1 -4 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 518 
               
               
                 Ar 1 -4 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 519 
               
               
                 Ar 1 -4 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 520 
               
               
                 Ar 1 -4 
                 Ar 2 -8 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 521 
               
               
                 Ar 1 -4 
                 Ar 2 -8 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 522 
               
               
                 Ar 1 -4 
                 Ar 2 -8 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 523 
               
               
                 Ar 1 -4 
                 Ar 2 -8 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 524 
               
               
                 Ar 1 -4 
                 Ar 2 -8 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 525 
               
               
                 Ar 1 -4 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 526 
               
               
                 Ar 1 -4 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 527 
               
               
                 Ar 1 -4 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 528 
               
               
                 Ar 1 -4 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 529 
               
               
                 Ar 1 -4 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 530 
               
               
                 Ar 1 -4 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 531 
               
               
                 Ar 1 -4 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 532 
               
               
                 Ar 1 -4 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 533 
               
               
                 Ar 1 -4 
                 Ar 2 -9 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 534 
               
               
                 Ar 1 -4 
                 Ar 2 -9 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 535 
               
               
                 Ar 1 -4 
                 Ar 2 -9 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 536 
               
               
                 Ar 1 -4 
                 Ar 2 -9 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 537 
               
               
                 Ar 1 -4 
                 Ar 2 -9 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 538 
               
               
                 Ar 1 -4 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 539 
               
               
                 Ar 1 -4 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 540 
               
               
                 Ar 1 -4 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 541 
               
               
                 Ar 1 -4 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 542 
               
               
                 Ar 1 -4 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 543 
               
               
                 Ar 1 -4 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 544 
               
               
                 Ar 1 -4 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 545 
               
               
                 Ar 1 -4 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 546 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 547 
               
               
                   
                 10 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 548 
               
               
                   
                 10 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 549 
               
               
                   
                 10 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 550 
               
               
                   
                 10 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 551 
               
               
                   
                 10 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 552 
               
               
                   
                 10 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 553 
               
               
                   
                 10 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 554 
               
               
                   
                 10 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 555 
               
               
                   
                 10 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 556 
               
               
                   
                 10 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 557 
               
               
                   
                 10 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 558 
               
               
                   
                 10 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 559 
               
               
                   
                 10 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 560 
               
               
                   
                 11 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 561 
               
               
                   
                 11 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 562 
               
               
                   
                 11 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 563 
               
               
                   
                 11 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 564 
               
               
                   
                 11 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 565 
               
               
                   
                 11 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 566 
               
               
                   
                 11 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 567 
               
               
                   
                 11 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 568 
               
               
                   
                 11 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 569 
               
               
                   
                 11 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 570 
               
               
                   
                 11 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 571 
               
               
                   
                 11 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 572 
               
               
                   
                 11 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 573 
               
               
                   
                 12 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 574 
               
               
                   
                 12 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 575 
               
               
                   
                 12 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 576 
               
               
                   
                 12 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 577 
               
               
                   
                 12 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 578 
               
               
                   
                 12 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 579 
               
               
                   
                 12 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 580 
               
               
                   
                 12 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 581 
               
               
                   
                 12 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 582 
               
               
                   
                 12 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 583 
               
               
                   
                 12 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 584 
               
               
                   
                 12 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 585 
               
               
                   
                 12 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 586 
               
               
                   
                 13 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 587 
               
               
                   
                 13 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 588 
               
               
                   
                 13 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 589 
               
               
                   
                 13 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 590 
               
               
                   
                 13 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 591 
               
               
                   
                 13 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 592 
               
               
                   
                 13 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 593 
               
               
                   
                 13 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 594 
               
               
                   
                 13 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 595 
               
               
                   
                 13 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 596 
               
               
                   
                 13 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 597 
               
               
                   
                 13 
               
               
                 Ar 1 -4 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 598 
               
               
                   
                 13 
               
               
                 Ar 1 -5 
                 Ar 2 -5 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 599 
               
               
                 Ar 1 -5 
                 Ar 2 -5 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 600 
               
               
                 Ar 1 -5 
                 Ar 2 -5 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 601 
               
               
                 Ar 1 -5 
                 Ar 2 -5 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 602 
               
               
                 Ar 1 -5 
                 Ar 2 -5 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 603 
               
               
                 Ar 1 -5 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 604 
               
               
                 Ar 1 -5 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 605 
               
               
                 Ar 1 -5 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 606 
               
               
                 Ar 1 -5 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 607 
               
               
                 Ar 1 -5 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 608 
               
               
                 Ar 1 -5 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 609 
               
               
                 Ar 1 -5 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 610 
               
               
                 Ar 1 -5 
                 Ar 2 -5 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 611 
               
               
                 Ar 1 -5 
                 Ar 2 -6 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 612 
               
               
                 Ar 1 -5 
                 Ar 2 -6 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 613 
               
               
                 Ar 1 -5 
                 Ar 2 -6 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 614 
               
               
                 Ar 1 -5 
                 Ar 2 -6 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 615 
               
               
                 Ar 1 -5 
                 Ar 2 -6 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 616 
               
               
                 Ar 1 -5 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 617 
               
               
                 Ar 1 -5 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 618 
               
               
                 Ar 1 -5 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 619 
               
               
                 Ar 1 -5 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 620 
               
               
                 Ar 1 -5 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 621 
               
               
                 Ar 1 -5 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 622 
               
               
                 Ar 1 -5 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 623 
               
               
                 Ar 1 -5 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 624 
               
               
                 Ar 1 -5 
                 Ar 2 -7 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 625 
               
               
                 Ar 1 -5 
                 Ar 2 -7 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 626 
               
               
                 Ar 1 -5 
                 Ar 2 -7 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 627 
               
               
                 Ar 1 -5 
                 Ar 2 -7 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 628 
               
               
                 Ar 1 -5 
                 Ar 2 -7 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 629 
               
               
                 Ar 1 -5 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 630 
               
               
                 Ar 1 -5 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 631 
               
               
                 Ar 1 -5 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 632 
               
               
                 Ar 1 -5 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 633 
               
               
                 Ar 1 -5 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 634 
               
               
                 Ar 1 -5 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 635 
               
               
                 Ar 1 -5 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 636 
               
               
                 Ar 1 -5 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 637 
               
               
                 Ar 1 -5 
                 Ar 2 -8 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 638 
               
               
                 Ar 1 -5 
                 Ar 2 -8 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 639 
               
               
                 Ar 1 -5 
                 Ar 2 -8 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 640 
               
               
                 Ar 1 -5 
                 Ar 2 -8 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 641 
               
               
                 Ar 1 -5 
                 Ar 2 -8 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 642 
               
               
                 Ar 1 -5 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 643 
               
               
                 Ar 1 -5 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 644 
               
               
                 Ar 1 -5 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 645 
               
               
                 Ar 1 -5 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 646 
               
               
                 Ar 1 -5 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 647 
               
               
                 Ar 1 -5 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 648 
               
               
                 Ar 1 -5 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 649 
               
               
                 Ar 1 -5 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 650 
               
               
                 Ar 1 -5 
                 Ar 2 -9 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 651 
               
               
                 Ar 1 -5 
                 Ar 2 -9 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 652 
               
               
                 Ar 1 -5 
                 Ar 2 -9 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 653 
               
               
                 Ar 1 -5 
                 Ar 2 -9 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 654 
               
               
                 Ar 1 -5 
                 Ar 2 -9 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 655 
               
               
                 Ar 1 -5 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 656 
               
               
                 Ar 1 -5 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 657 
               
               
                 Ar 1 -5 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 658 
               
               
                 Ar 1 -5 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 659 
               
               
                 Ar 1 -5 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 660 
               
               
                 Ar 1 -5 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 661 
               
               
                 Ar 1 -5 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 662 
               
               
                 Ar 1 -5 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 663 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 664 
               
               
                   
                 10 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 665 
               
               
                   
                 10 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 666 
               
               
                   
                 10 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 667 
               
               
                   
                 10 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 668 
               
               
                   
                 10 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 669 
               
               
                   
                 10 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 670 
               
               
                   
                 10 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 671 
               
               
                   
                 10 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 672 
               
               
                   
                 10 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 673 
               
               
                   
                 10 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 674 
               
               
                   
                 10 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 675 
               
               
                   
                 10 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 676 
               
               
                   
                 10 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 677 
               
               
                   
                 11 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 678 
               
               
                   
                 11 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 679 
               
               
                   
                 11 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 680 
               
               
                   
                 11 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 681 
               
               
                   
                 11 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 682 
               
               
                   
                 11 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 683 
               
               
                   
                 11 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 684 
               
               
                   
                 11 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 685 
               
               
                   
                 11 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 686 
               
               
                   
                 11 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 687 
               
               
                   
                 11 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 688 
               
               
                   
                 11 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 689 
               
               
                   
                 11 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 690 
               
               
                   
                 12 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 691 
               
               
                   
                 12 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 692 
               
               
                   
                 12 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 693 
               
               
                   
                 12 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 694 
               
               
                   
                 12 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 695 
               
               
                   
                 12 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 696 
               
               
                   
                 12 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 697 
               
               
                   
                 12 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 698 
               
               
                   
                 12 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 699 
               
               
                   
                 12 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 700 
               
               
                   
                 12 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 701 
               
               
                   
                 12 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 702 
               
               
                   
                 12 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 703 
               
               
                   
                 13 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 704 
               
               
                   
                 13 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 705 
               
               
                   
                 13 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 706 
               
               
                   
                 13 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 707 
               
               
                   
                 13 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 708 
               
               
                   
                 13 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 709 
               
               
                   
                 13 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 710 
               
               
                   
                 13 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 711 
               
               
                   
                 13 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 712 
               
               
                   
                 13 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 713 
               
               
                   
                 13 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 714 
               
               
                   
                 13 
               
               
                 Ar 1 -5 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 715 
               
               
                   
                 13 
               
               
                 Ar 1 -6 
                 Ar 2 -6 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 716 
               
               
                 Ar 1 -6 
                 Ar 2 -6 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 717 
               
               
                 Ar 1 -6 
                 Ar 2 -6 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 718 
               
               
                 Ar 1 -6 
                 Ar 2 -6 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 719 
               
               
                 Ar 1 -6 
                 Ar 2 -6 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 720 
               
               
                 Ar 1 -6 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 721 
               
               
                 Ar 1 -6 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 722 
               
               
                 Ar 1 -6 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 723 
               
               
                 Ar 1 -6 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 724 
               
               
                 Ar 1 -6 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 725 
               
               
                 Ar 1 -6 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 726 
               
               
                 Ar 1 -6 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 727 
               
               
                 Ar 1 -6 
                 Ar 2 -6 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 728 
               
               
                 Ar 1 -6 
                 Ar 2 -7 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 729 
               
               
                 Ar 1 -6 
                 Ar 2 -7 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 730 
               
               
                 Ar 1 -6 
                 Ar 2 -7 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 731 
               
               
                 Ar 1 -6 
                 Ar 2 -7 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 732 
               
               
                 Ar 1 -6 
                 Ar 2 -7 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 733 
               
               
                 Ar 1 -6 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 734 
               
               
                 Ar 1 -6 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 735 
               
               
                 Ar 1 -6 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 736 
               
               
                 Ar 1 -6 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 737 
               
               
                 Ar 1 -6 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 738 
               
               
                 Ar 1 -6 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 739 
               
               
                 Ar 1 -6 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 740 
               
               
                 Ar 1 -6 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 741 
               
               
                 Ar 1 -6 
                 Ar 2 -8 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 742 
               
               
                 Ar 1 -6 
                 Ar 2 -8 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 743 
               
               
                 Ar 1 -6 
                 Ar 2 -8 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 744 
               
               
                 Ar 1 -6 
                 Ar 2 -8 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 745 
               
               
                 Ar 1 -6 
                 Ar 2 -8 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 746 
               
               
                 Ar 1 -6 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 747 
               
               
                 Ar 1 -6 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 748 
               
               
                 Ar 1 -6 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 749 
               
               
                 Ar 1 -6 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 750 
               
               
                 Ar 1 -6 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 751 
               
               
                 Ar 1 -6 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 752 
               
               
                 Ar 1 -6 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 753 
               
               
                 Ar 1 -6 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 754 
               
               
                 Ar 1 -6 
                 Ar 2 -9 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 755 
               
               
                 Ar 1 -6 
                 Ar 2 -9 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 756 
               
               
                 Ar 1 -6 
                 Ar 2 -9 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 757 
               
               
                 Ar 1 -6 
                 Ar 2 -9 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 758 
               
               
                 Ar 1 -6 
                 Ar 2 -9 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 759 
               
               
                 Ar 1 -6 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 760 
               
               
                 Ar 1 -6 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 761 
               
               
                 Ar 1 -6 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 762 
               
               
                 Ar 1 -6 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 763 
               
               
                 Ar 1 -6 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 764 
               
               
                 Ar 1 -6 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 765 
               
               
                 Ar 1 -6 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 766 
               
               
                 Ar 1 -6 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 767 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 768 
               
               
                   
                 10 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 769 
               
               
                   
                 10 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 770 
               
               
                   
                 10 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 771 
               
               
                   
                 10 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 772 
               
               
                   
                 10 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 773 
               
               
                   
                 10 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 774 
               
               
                   
                 10 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 775 
               
               
                   
                 10 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 776 
               
               
                   
                 10 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 777 
               
               
                   
                 10 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 778 
               
               
                   
                 10 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 779 
               
               
                   
                 10 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 780 
               
               
                   
                 10 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 781 
               
               
                   
                 11 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 782 
               
               
                   
                 11 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 783 
               
               
                   
                 11 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 784 
               
               
                   
                 11 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 785 
               
               
                   
                 11 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 786 
               
               
                   
                 11 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 787 
               
               
                   
                 11 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 788 
               
               
                   
                 11 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 789 
               
               
                   
                 11 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 790 
               
               
                   
                 11 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 791 
               
               
                   
                 11 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 792 
               
               
                   
                 11 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 793 
               
               
                   
                 11 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 794 
               
               
                   
                 12 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 795 
               
               
                   
                 12 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 796 
               
               
                   
                 12 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 797 
               
               
                   
                 12 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 798 
               
               
                   
                 12 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 799 
               
               
                   
                 12 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 800 
               
               
                   
                 12 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 801 
               
               
                   
                 12 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 802 
               
               
                   
                 12 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 803 
               
               
                   
                 12 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 804 
               
               
                   
                 12 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 805 
               
               
                   
                 12 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 806 
               
               
                   
                 12 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 807 
               
               
                   
                 13 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 808 
               
               
                   
                 13 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 809 
               
               
                   
                 13 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 810 
               
               
                   
                 13 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 811 
               
               
                   
                 13 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 812 
               
               
                   
                 13 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 813 
               
               
                   
                 13 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 814 
               
               
                   
                 13 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 815 
               
               
                   
                 13 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 816 
               
               
                   
                 13 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 817 
               
               
                   
                 13 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 818 
               
               
                   
                 13 
               
               
                 Ar 1 -6 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 819 
               
               
                   
                 13 
               
               
                 Ar 1 -7 
                 Ar 2 -7 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 820 
               
               
                 Ar 1 -7 
                 Ar 2 -7 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 821 
               
               
                 Ar 1 -7 
                 Ar 2 -7 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 822 
               
               
                 Ar 1 -7 
                 Ar 2 -7 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 823 
               
               
                 Ar 1 -7 
                 Ar 2 -7 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 824 
               
               
                 Ar 1 -7 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 825 
               
               
                 Ar 1 -7 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 826 
               
               
                 Ar 1 -7 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 827 
               
               
                 Ar 1 -7 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 828 
               
               
                 Ar 1 -7 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 829 
               
               
                 Ar 1 -7 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 830 
               
               
                 Ar 1 -7 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 831 
               
               
                 Ar 1 -7 
                 Ar 2 -7 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 832 
               
               
                 Ar 1 -7 
                 Ar 2 -8 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 833 
               
               
                 Ar 1 -7 
                 Ar 2 -8 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 834 
               
               
                 Ar 1 -7 
                 Ar 2 -8 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 835 
               
               
                 Ar 1 -7 
                 Ar 2 -8 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 836 
               
               
                 Ar 1 -7 
                 Ar 2 -8 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 837 
               
               
                 Ar 1 -7 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 838 
               
               
                 Ar 1 -7 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 839 
               
               
                 Ar 1 -7 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 840 
               
               
                 Ar 1 -7 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 841 
               
               
                 Ar 1 -7 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 842 
               
               
                 Ar 1 -7 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 843 
               
               
                 Ar 1 -7 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 844 
               
               
                 Ar 1 -7 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 845 
               
               
                 Ar 1 -7 
                 Ar 2 -9 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 846 
               
               
                 Ar 1 -7 
                 Ar 2 -9 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 847 
               
               
                 Ar 1 -7 
                 Ar 2 -9 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 848 
               
               
                 Ar 1 -7 
                 Ar 2 -9 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 849 
               
               
                 Ar 1 -7 
                 Ar 2 -9 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 850 
               
               
                 Ar 1 -7 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 851 
               
               
                 Ar 1 -7 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 852 
               
               
                 Ar 1 -7 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 853 
               
               
                 Ar 1 -7 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 854 
               
               
                 Ar 1 -7 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 855 
               
               
                 Ar 1 -7 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 856 
               
               
                 Ar 1 -7 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 857 
               
               
                 Ar 1 -7 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 858 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 859 
               
               
                   
                 10 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 860 
               
               
                   
                 10 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 861 
               
               
                   
                 10 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 862 
               
               
                   
                 10 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 863 
               
               
                   
                 10 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 864 
               
               
                   
                 10 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 865 
               
               
                   
                 10 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 866 
               
               
                   
                 10 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 867 
               
               
                   
                 10 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 868 
               
               
                   
                 10 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 869 
               
               
                   
                 10 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 870 
               
               
                   
                 10 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 871 
               
               
                   
                 10 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 872 
               
               
                   
                 11 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 873 
               
               
                   
                 11 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 874 
               
               
                   
                 11 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 875 
               
               
                   
                 11 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 876 
               
               
                   
                 11 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 877 
               
               
                   
                 11 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 878 
               
               
                   
                 11 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 879 
               
               
                   
                 11 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 880 
               
               
                   
                 11 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 881 
               
               
                   
                 11 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 882 
               
               
                   
                 11 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 883 
               
               
                   
                 11 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 884 
               
               
                   
                 11 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 885 
               
               
                   
                 12 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 886 
               
               
                   
                 12 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 887 
               
               
                   
                 12 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 888 
               
               
                   
                 12 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 889 
               
               
                   
                 12 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 890 
               
               
                   
                 12 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 891 
               
               
                   
                 12 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 892 
               
               
                   
                 12 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 893 
               
               
                   
                 12 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 894 
               
               
                   
                 12 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 895 
               
               
                   
                 12 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 896 
               
               
                   
                 12 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 897 
               
               
                   
                 12 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 898 
               
               
                   
                 13 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 899 
               
               
                   
                 13 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 900 
               
               
                   
                 13 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 901 
               
               
                   
                 13 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 902 
               
               
                   
                 13 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 903 
               
               
                   
                 13 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 904 
               
               
                   
                 13 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 905 
               
               
                   
                 13 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 906 
               
               
                   
                 13 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 907 
               
               
                   
                 13 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 908 
               
               
                   
                 13 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 909 
               
               
                   
                 13 
               
               
                 Ar 1 -7 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 910 
               
               
                   
                 13 
               
               
                 Ar 1 -8 
                 Ar 2 -8 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 911 
               
               
                 Ar 1 -8 
                 Ar 2 -8 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 912 
               
               
                 Ar 1 -8 
                 Ar 2 -8 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 913 
               
               
                 Ar 1 -8 
                 Ar 2 -8 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 914 
               
               
                 Ar 1 -8 
                 Ar 2 -8 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 915 
               
               
                 Ar 1 -8 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 916 
               
               
                 Ar 1 -8 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 917 
               
               
                 Ar 1 -8 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 918 
               
               
                 Ar 1 -8 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 919 
               
               
                 Ar 1 -8 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 920 
               
               
                 Ar 1 -8 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 921 
               
               
                 Ar 1 -8 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 922 
               
               
                 Ar 1 -8 
                 Ar 2 -8 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 923 
               
               
                 Ar 1 -8 
                 Ar 2 -9 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 924 
               
               
                 Ar 1 -8 
                 Ar 2 -9 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 925 
               
               
                 Ar 1 -8 
                 Ar 2 -9 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 926 
               
               
                 Ar 1 -8 
                 Ar 2 -9 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 927 
               
               
                 Ar 1 -8 
                 Ar 2 -9 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 928 
               
               
                 Ar 1 -8 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 929 
               
               
                 Ar 1 -8 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 930 
               
               
                 Ar 1 -8 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 931 
               
               
                 Ar 1 -8 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 932 
               
               
                 Ar 1 -8 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 933 
               
               
                 Ar 1 -8 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 934 
               
               
                 Ar 1 -8 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 935 
               
               
                 Ar 1 -8 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 936 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 937 
               
               
                   
                 10 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 938 
               
               
                   
                 10 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 939 
               
               
                   
                 10 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 940 
               
               
                   
                 10 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 941 
               
               
                   
                 10 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 942 
               
               
                   
                 10 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 943 
               
               
                   
                 10 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 944 
               
               
                   
                 10 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 945 
               
               
                   
                 10 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 946 
               
               
                   
                 10 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 947 
               
               
                   
                 10 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 948 
               
               
                   
                 10 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 949 
               
               
                   
                 10 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 950 
               
               
                   
                 11 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 951 
               
               
                   
                 11 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 952 
               
               
                   
                 11 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 953 
               
               
                   
                 11 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 954 
               
               
                   
                 11 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 955 
               
               
                   
                 11 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 956 
               
               
                   
                 11 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 957 
               
               
                   
                 11 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 958 
               
               
                   
                 11 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 959 
               
               
                   
                 11 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 960 
               
               
                   
                 11 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 961 
               
               
                   
                 11 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 962 
               
               
                   
                 11 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 963 
               
               
                   
                 12 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 964 
               
               
                   
                 12 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 965 
               
               
                   
                 12 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 966 
               
               
                   
                 12 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 967 
               
               
                   
                 12 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 968 
               
               
                   
                 12 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 969 
               
               
                   
                 12 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 970 
               
               
                   
                 12 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 971 
               
               
                   
                 12 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 972 
               
               
                   
                 12 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 973 
               
               
                   
                 12 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 974 
               
               
                   
                 12 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 975 
               
               
                   
                 12 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 976 
               
               
                   
                 13 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 977 
               
               
                   
                 13 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 978 
               
               
                   
                 13 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 979 
               
               
                   
                 13 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 980 
               
               
                   
                 13 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 981 
               
               
                   
                 13 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 982 
               
               
                   
                 13 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 983 
               
               
                   
                 13 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 984 
               
               
                   
                 13 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 985 
               
               
                   
                 13 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 986 
               
               
                   
                 13 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 987 
               
               
                   
                 13 
               
               
                 Ar 1 -8 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 988 
               
               
                   
                 13 
               
               
                 Ar 1 9 
                 Ar 2 -9 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 989 
               
               
                 Ar 1 9 
                 Ar 2 -9 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 990 
               
               
                 Ar 1 9 
                 Ar 2 -9 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 991 
               
               
                 Ar 1 9 
                 Ar 2 -9 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 992 
               
               
                 Ar 1 9 
                 Ar 2 -9 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 993 
               
               
                 Ar 1 9 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 994 
               
               
                 Ar 1 9 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 995 
               
               
                 Ar 1 9 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 996 
               
               
                 Ar 1 9 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 997 
               
               
                 Ar 1 9 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 998 
               
               
                 Ar 1 9 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 999 
               
               
                 Ar 1 9 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 1000 
               
               
                 Ar 1 9 
                 Ar 2 -9 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 1001 
               
               
                 Ar 1 9 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1002 
               
               
                   
                 10 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1003 
               
               
                   
                 10 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1004 
               
               
                   
                 10 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1005 
               
               
                   
                 10 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 1006 
               
               
                   
                 10 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 1007 
               
               
                   
                 10 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 1008 
               
               
                   
                 10 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 1009 
               
               
                   
                 10 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 1010 
               
               
                   
                 10 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 1011 
               
               
                   
                 10 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 1012 
               
               
                   
                 10 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 1013 
               
               
                   
                 10 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 1014 
               
               
                   
                 10 
               
               
                 Ar 1 9 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1015 
               
               
                   
                 11 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1016 
               
               
                   
                 11 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1017 
               
               
                   
                 11 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1018 
               
               
                   
                 11 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 1019 
               
               
                   
                 11 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 1020 
               
               
                   
                 11 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 1021 
               
               
                   
                 11 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 1022 
               
               
                   
                 11 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 1023 
               
               
                   
                 11 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 1024 
               
               
                   
                 11 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 1025 
               
               
                   
                 11 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 1026 
               
               
                   
                 11 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 1027 
               
               
                   
                 11 
               
               
                 Ar 1 9 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1028 
               
               
                   
                 12 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1029 
               
               
                   
                 12 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1030 
               
               
                   
                 12 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1031 
               
               
                   
                 12 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 1032 
               
               
                   
                 12 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 1033 
               
               
                   
                 12 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 1034 
               
               
                   
                 12 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 1035 
               
               
                   
                 12 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 1036 
               
               
                   
                 12 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 1037 
               
               
                   
                 12 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 1038 
               
               
                   
                 12 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 1039 
               
               
                   
                 12 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 1040 
               
               
                   
                 12 
               
               
                 Ar 1 9 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1041 
               
               
                   
                 13 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1042 
               
               
                   
                 13 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1043 
               
               
                   
                 13 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1044 
               
               
                   
                 13 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 1045 
               
               
                   
                 13 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 1046 
               
               
                   
                 13 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 1047 
               
               
                   
                 13 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 1048 
               
               
                   
                 13 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 1049 
               
               
                   
                 13 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 1050 
               
               
                   
                 13 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 1051 
               
               
                   
                 13 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 1052 
               
               
                   
                 13 
               
               
                 Ar 1 9 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 1053 
               
               
                   
                 13 
               
               
                 Ar 1 10 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1054 
               
               
                   
                 10 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1055 
               
               
                   
                 10 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1056 
               
               
                   
                 10 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1057 
               
               
                   
                 10 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 1058 
               
               
                   
                 10 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 1059 
               
               
                   
                 10 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 1060 
               
               
                   
                 10 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 1061 
               
               
                   
                 10 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 1062 
               
               
                   
                 10 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 1063 
               
               
                   
                 10 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 1064 
               
               
                   
                 10 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 1065 
               
               
                   
                 10 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 1066 
               
               
                   
                 10 
               
               
                 Ar 1 10 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1067 
               
               
                   
                 11 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1068 
               
               
                   
                 11 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1069 
               
               
                   
                 11 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1070 
               
               
                   
                 11 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 1071 
               
               
                   
                 11 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 1072 
               
               
                   
                 11 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 1073 
               
               
                   
                 11 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 1074 
               
               
                   
                 11 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 1075 
               
               
                   
                 11 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 1076 
               
               
                   
                 11 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 1077 
               
               
                   
                 11 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 1078 
               
               
                   
                 11 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 1079 
               
               
                   
                 11 
               
               
                 Ar 1 10 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1080 
               
               
                   
                 12 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1081 
               
               
                   
                 12 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1082 
               
               
                   
                 12 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1083 
               
               
                   
                 12 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 1084 
               
               
                   
                 12 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 1085 
               
               
                   
                 12 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 1086 
               
               
                   
                 12 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 1087 
               
               
                   
                 12 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 1088 
               
               
                   
                 12 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 1089 
               
               
                   
                 12 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 1090 
               
               
                   
                 12 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 1091 
               
               
                   
                 12 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 1092 
               
               
                   
                 12 
               
               
                 Ar 1 10 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1093 
               
               
                   
                 13 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1094 
               
               
                   
                 13 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1095 
               
               
                   
                 13 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1096 
               
               
                   
                 13 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 1097 
               
               
                   
                 13 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 1098 
               
               
                   
                 13 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 1099 
               
               
                   
                 13 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 1100 
               
               
                   
                 13 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 1101 
               
               
                   
                 13 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 1102 
               
               
                   
                 13 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 1103 
               
               
                   
                 13 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 1104 
               
               
                   
                 13 
               
               
                 Ar 1 10 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 1105 
               
               
                   
                 13 
               
               
                 Ar 1 11 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1106 
               
               
                   
                 11 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1107 
               
               
                   
                 11 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1108 
               
               
                   
                 11 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1109 
               
               
                   
                 11 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 1110 
               
               
                   
                 11 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 1111 
               
               
                   
                 11 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 1112 
               
               
                   
                 11 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 1113 
               
               
                   
                 11 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 1114 
               
               
                   
                 11 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 1115 
               
               
                   
                 11 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 1116 
               
               
                   
                 11 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 1117 
               
               
                   
                 11 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 1118 
               
               
                   
                 11 
               
               
                 Ar 1 11 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1119 
               
               
                   
                 12 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1120 
               
               
                   
                 12 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1121 
               
               
                   
                 12 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1122 
               
               
                   
                 12 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 1123 
               
               
                   
                 12 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 1124 
               
               
                   
                 12 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 1125 
               
               
                   
                 12 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 1126 
               
               
                   
                 12 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 1127 
               
               
                   
                 12 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 1128 
               
               
                   
                 12 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 1129 
               
               
                   
                 12 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 1130 
               
               
                   
                 12 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 1131 
               
               
                   
                 12 
               
               
                 Ar 1 11 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1132 
               
               
                   
                 13 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1133 
               
               
                   
                 13 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1134 
               
               
                   
                 13 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1135 
               
               
                   
                 13 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 1136 
               
               
                   
                 13 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 1137 
               
               
                   
                 13 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 1138 
               
               
                   
                 13 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 1139 
               
               
                   
                 13 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 1140 
               
               
                   
                 13 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 1141 
               
               
                   
                 13 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 1142 
               
               
                   
                 13 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 1143 
               
               
                   
                 13 
               
               
                 Ar 1 11 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 1144 
               
               
                   
                 13 
               
               
                 Ar 1 12 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1145 
               
               
                   
                 12 
               
               
                 Ar 1 12 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1146 
               
               
                   
                 12 
               
               
                 Ar 1 12 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1147 
               
               
                   
                 12 
               
               
                 Ar 1 12 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1148 
               
               
                   
                 12 
               
               
                 Ar 1 12 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 1149 
               
               
                   
                 12 
               
               
                 Ar 1 12 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 1150 
               
               
                   
                 12 
               
               
                 Ar 1 12 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 1151 
               
               
                   
                 12 
               
               
                 Ar 1 12 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 1152 
               
               
                   
                 12 
               
               
                 Ar 1 12 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 1153 
               
               
                   
                 12 
               
               
                 Ar 1 12 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 1154 
               
               
                   
                 12 
               
               
                 Ar 1 12 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 1155 
               
               
                   
                 12 
               
               
                 Ar 1 12 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 1156 
               
               
                   
                 12 
               
               
                 Ar 1 12 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 1157 
               
               
                   
                 12 
               
               
                 Ar 1 12 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1158 
               
               
                   
                 13 
               
               
                 Ar 1 12 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1159 
               
               
                   
                 13 
               
               
                 Ar 1 12 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1160 
               
               
                   
                 13 
               
               
                 Ar 1 12 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1161 
               
               
                   
                 13 
               
               
                 Ar 1 12 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 1162 
               
               
                   
                 13 
               
               
                 Ar 1 12 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 1163 
               
               
                   
                 13 
               
               
                 Ar 1 12 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 1164 
               
               
                   
                 13 
               
               
                 Ar 1 12 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 1165 
               
               
                   
                 13 
               
               
                 Ar 1 12 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 1166 
               
               
                   
                 13 
               
               
                 Ar 1 12 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 1167 
               
               
                   
                 13 
               
               
                 Ar 1 12 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 1168 
               
               
                   
                 13 
               
               
                 Ar 1 12 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 1169 
               
               
                   
                 13 
               
               
                 Ar 1 12 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 1170 
               
               
                   
                 13 
               
               
                 Ar 1 13 
                 Ar 2 - 
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1171 
               
               
                   
                 13 
               
               
                 Ar 1 13 
                 Ar 2 - 
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1172 
               
               
                   
                 13 
               
               
                 Ar 1 13 
                 Ar 2 - 
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1173 
               
               
                   
                 13 
               
               
                 Ar 1 13 
                 Ar 2 - 
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 1174 
               
               
                   
                 13 
               
               
                 Ar 1 13 
                 Ar 2 - 
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                   
                 1175 
               
               
                   
                 13 
               
               
                 Ar 1 13 
                 Ar 2 - 
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                   
                 1176 
               
               
                   
                 13 
               
               
                 Ar 1 13 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                   
                 1177 
               
               
                   
                 13 
               
               
                 Ar 1 13 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                   
                 1178 
               
               
                   
                 13 
               
               
                 Ar 1 13 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                   
                 1179 
               
               
                   
                 13 
               
               
                 Ar 1 13 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                   
                 1180 
               
               
                   
                 13 
               
               
                 Ar 1 13 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                   
                 1181 
               
               
                   
                 13 
               
               
                 Ar 1 13 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                   
                 1182 
               
               
                   
                 13 
               
               
                 Ar 1 13 
                 Ar 2 - 
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                   
                 x 
                 1183 
               
               
                   
                 13 
               
               
                   
               
             
          
         
       
     
         [0059]    In one embodiment, a first device is provided. The first device comprises an organic light emitting device, further comprising: an anode, a cathode, a hole injection layer disposed between the anode and the emissive layer, a first hole transport layer disposed between the hole injection layer and the emissive layer, and a second hole transport layer disposed between the first hole transport layer and the emissive layer, and wherein the second hole transport layer comprises a compound of formula: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0000]    In the compound of Formula II, Ar 1 , Ar 2 , and Ar 5  are independently selected from the group consisting of aryl and heteroaryl and R 3  and R 4  are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfanyl, sulfonyl, phosphino, and combinations thereof. 
         [0060]    As used herein, a hole transporting layer (HTL) in an OLED can be disposed between the and anode and the emissive layer. It is preferred that the HTL is relatively hole conductive, which helps avoid high operating voltage. In order to achieve high hole conductivity, high hole mobility materials are used. These materials are usually triarylamine compounds. These compounds may have HOMO/LUMO levels and/or triplet energy which are not compatible with the emissive layer for optimum device performance and lifetime. On the other hand, in order to have an HTL with more compatible HOMO/LUMO levels and/or triplet energy, hole mobility may be compromised. 
         [0061]    In order to achieve a low voltage, higher device performance and lifetime device, the introduction of a secondary hole transporting layer, in addition to the primary hole transporting layer has been demonstrated and shown to be effective. The primary hole transporting layer is largely responsible for hole transport. The secondary hole transporting layer, sandwiched between the primary hole transporting layer and the emissive layer, functions as a bridging layer. The thickness of the secondary hole transport layer is preferably low in order to not significantly increase the operating voltage. However, the hole injection from the secondary hole transporting layer to the emissive layer, charge confinement and excition confinement between the secondary hole transporting layer and the emissive layer are controlled by the energy levels and single/triplet energy of the secondary hole transporting layer. Since the secondary hole transporting layer thickness is low, there is relatively little concern about the hole mobility. This allows for a higher flexibility in the design of materials with appropriate energy levels and single/triplet energy to function well with the emissive layer. 
         [0062]    It has surprisingly been discovered that compounds of Formula I and Formula II are useful materials in the secondary hole transporting layer. In the compounds of Formula I, the most electron rich portion of the molecule is the N(Ar 1 )(Ar 2 ) group. Without being bound by theory, this part is believed to be mostly responsible for the hole transport. 
         [0063]    The carbazole-N—Ar 5  moiety may be less electron rich and may provide a relatively accessible LUMO level and π-conjugation to stabilize radical anions if the material is reduced. In particular, Ar 5  is preferably a high triplet fused-ring aromatic as disclosed herein. In some embodiments, Ar 5  can be triphenylene or heteroaromatic group such as dibenzofuran, dibenzothiophene and dibenzoselenophene. It has been discovered that the aforementioned substitution pattern for Ar 1 , Ar 2 , and Ar 5  can render compounds with high triplet energy and significant charge stabilization. 
         [0064]    In one embodiment, the compound has the formula: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0000]    wherein X is selected from the group consisting of O, S, and Se, wherein R 1  and R 2  independently represent mono, di, tri, tetra substitution, or no substitution, and wherein R 1  and R 2  are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof. 
         [0065]    In one embodiment, the second hole transport layer is disposed adjacent to the first hole transport layer. By “adjacent” it is meant that the second hole transport layer is physically in contact with the first hole transport layer. In one embodiment, the first hole transport layer is thicker than the second hole transport layer. In one embodiment, the first hole transport layer comprises a compound with the formula: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0000]    wherein Ar a , Ar b , Ar c  and Ar d  are independently selected from the group consisting of aryl and heteroaryl. 
         [0066]    In one embodiment, the triplet energy of the compound of Formula II is higher than the emission energy of the emissive layer. 
         [0067]    In one embodiment, Ar 1 , Ar 2  and Ar 5  are independently selected from the group consisting of: 
         [0000]    
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
     
         [0068]    In one embodiment, Ar 1  and Ar 2  are independently selected from the group consisting of: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0069]    In one embodiment, Ar 1  and Ar 2  are independently selected from the group consisting of: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0070]    In one embodiment, the first device further comprises a first dopant material that is an emissive dopant comprising a transition metal complex having at least one ligand or part of the ligand if the ligand is more than bidentate selected from the group consisting of: 
         [0000]    
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
     
         [0000]    wherein R a , R b , R c , and R d  may represent mono, di, tri, or tetra substitution, or no substitution and wherein R a , R b , R c , and R d  are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, and wherein two adjacent substituents of R a , R b , R c , and R d  are optionally joined to form a fused ring or form a multidentate ligand. 
         [0071]    In one embodiment, the first device is a consumer product. In one embodiment, the first device is an organic light-emitting device. In one embodiment, the first device comprises a lighting panel. In one embodiment, a first device comprising an organic light emitting device, further comprising an anode, a cathode, a first organic layer disposed between the anode and the cathode, and wherein the first organic layer comprises a compound of formula: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0000]    In the compound of Formula I, Ar 1  and Ar 2  are independently selected from the group consisting of aryl and heteroaryl, X is selected from the group consisting of O, S, and Se, R 1  and R 2  independently represent mono, di, tri, tetra substitution, or no substitution, and R 1 , R 2 , R 3  and R 4  are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof. 
         [0072]    In one embodiment, the first organic layer is an emissive layer. In one embodiment, the emissive layer is a phosphorescent emissive layer. 
       Device Examples 
       [0073]    All OLED device examples were fabricated by high vacuum (&lt;10 −7  Torr) thermal evaporation (VTE). The anode electrode is ˜800 Å of indium tin oxide (ITO). The cathode consisted of 10 Å of LiF followed by 1,000 Å of A1. All devices were encapsulated with a glass lid sealed with an epoxy resin in a nitrogen glove box (&lt;1 ppm of H 2 O and O 2 ) and a moisture getter was incorporated inside the package. 
         [0074]    The organic stack of the Device Examples in Table 2 consists of sequentially, from the ITO surface, 100 Å of LG101 (purchased from LG Chem) as the hole injection layer (HIL), 500 Å of NPD as the primary hole transporting layer (HTL), 50 Å of the secondary hole transporting layer, 300 Å of Compound A doped with 10% or 12% of phosphorescent dopant Compound B as the emissive layer (EML), 50 Å of Compound A as the ETL2 and 450 Å of Alq 3  as the ETL1. 
         [0075]    Comparative Example 1 was fabricated in the same way except that there was no secondary hole transporting layer, and the thickness of the primary hole transporting layer was increased to 550 Å to match the combined thickness of the primary and secondary hole transporting layers in the Device Examples. 
         [0076]    The structures of the aforementioned device components are as follows: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0000]    
       
         
               
             
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
               
               
               
             
           
               
                 TABLE 2 
               
             
             
               
                   
               
               
                 Device performance summary. 
               
             
          
           
               
                   
                   
                   
                   
                 At L = 1000 cd/m 2   
                 At J = 40 mA/cm 2   
               
             
          
           
               
                   
                 Secondary 
                   
                 1931 CIE 
                 Voltage 
                 LE 
                 EQE 
                 PE 
                 L 0   
                 LT 80   
               
             
          
           
               
                 Example 
                 HTL [50 Å] 
                 EML [300 Å] 
                 x 
                 y 
                 [V] 
                 [cd/A] 
                 [%] 
                 [lm/W] 
                 [cd/m 2 ] 
                 [h] 
               
               
                   
               
               
                 Device 
                 Compound 
                 Compound A: 
                 0.330 
                 0.624 
                 4.9 
                 76.5 
                 20.9 
                 49.0 
                 25338 
                 200 
               
               
                 Example 1 
                 113 
                 Compound B 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                   
                   
                 12% 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Device 
                 Compound 
                 Compound A: 
                 0.322 
                 0.629 
                 4.8 
                 76.3 
                 20.9 
                 50.3 
                 25112 
                 422 
               
               
                 Example 2 
                 178 
                 Compound B 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                   
                   
                 10% 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Device 
                 Compound 
                 Compound A: 
                 0.322 
                 0.629 
                 4.7 
                 75.5 
                 20.7 
                 50.3 
                 24932 
                 420 
               
               
                 Example 3 
                 182 
                 Compound B 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                   
                   
                 10% 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Comparative 
                 none 
                 Compound A: 
                 0.327 
                 0.626 
                 4.9 
                 68.1 
                 18.6 
                 43.8 
                 19596 
                 290 
               
               
                 Device 
                   
                 Compound B 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                 Example 1 
                   
                 12% 
                   
                   
                   
                   
                   
                   
                   
                   
               
               
                   
               
             
          
         
       
     
         [0077]    Device Examples 1-3 are the same as Comparative Device Example 1 except for the presence of the secondary HTL in former and the absence of the secondary HTL in latter. Device Examples 1-3 have Compounds 113, 178 and 182 respectively as the secondary HTL. The efficiencies of Device Examples 1-3 are higher (EQE=20.7-20.9%) than the efficiency of Comparative Device Example 1 (EQE=18.6%). The operation lifetimes of Device Examples 2 and 3 are remarkably high. The LT 80 , the time required for the initial luminance (L 0 ) to drop to 80% of its initial value, at a constant current density of 40 mA/cm 2 , is ˜420 h, compared to 290 h of Comparative Device Example 1. Without being bound by theory, the improved efficiency and lifetime when Compounds 178 and 182 are used as the secondary HTL may be due to the high triplet energy, providing improved exciton confinement; the presence of a dibenzothiophene or triphenylene group, providing a high triplet, charge stabilization moiety; and a sufficiently shallow HOMO level (Compound 178 HOMO=−5.23 eV, Compound 182 HOMO=−5.21 eV, NPD HOMO=−5.17 eV) for hole transport. 
         [0078]    Although hole conductivity may be reduced in compounds of Formula I or Formula II with respect to traditionally used triarylamine compounds such as NPD, compounds of Formula I and Formula II that bear substituents such as 
         [0000]    
       
                 
         
             
             
         
       
     
         [0000]    at the Ar 1  and Ar 2  positions have better hole mobility that compounds bearing substituents such as 
         [0000]    
       
                 
         
             
             
         
       
     
         [0000]    at these same positions because the latter group of substituents, deepens the HOMO levels, which causes a larger increase in hole conductivity. Additionally, although device lifetimes for a given thickness of the secondary HTL are sometimes reduced for compounds bearing Group 2 substituents compared with Group 1 substituents, this difference can be mitigated by decreasing the thickness of the secondary HTL. 
         [0079]    The HOMO and LUMO levels and triplet energy are summarized in Table 3. The LT 80  of Device Example 1 with Compound 113 as the secondary HTL is 200 h, less stable than Device. Example 1 (422 h) with Compound 178 as the secondary HTL. The difference between Compound 113 and Compound 178 is the N(Ar 1 )(Ar 2 ) group. In general, if the N is connected to a dibenzofuran or dibenzothiphene group, the HOMO gets deeper (Compound I HOMO=−5.31 eV, NPD HOMO=−5.17 eV) and hole conductivity may be reduced. This may lead to shorter device operation lifetime if the hole conductivity of the secondary HTL is not high enough, even though its thickness is kept low. 
         [0000]                                      TABLE 3                   HOMO, LUMO levels and triplet energy            Compound   HOMO (eV)*   LUMO (eV)*   Triplet energy (nm) #                 NPD   −5.17   −1.98   500       Compound 113   −5.31   −1.98   436       Compound 178   −5.23   −1.99   450       Compound 182   −5.21   −2.04   450               *By solution electrochemistry using ferrocene as the standard         # By DFT/B3LYP/6-31 g (d) optimized geometry            
Combination with Other Materials
 
         [0080]    The materials described herein as useful for a particular layer in an organic light emitting device may be used in combination with a wide variety of other materials present in the device. For example, emissive dopants disclosed herein may be used in conjunction with a wide variety of hosts, transport layers, blocking layers, injection layers, electrodes and other layers that may be present. The materials described or referred to below are non-limiting examples of materials that may be useful in combination with the compounds disclosed herein, and one of skill in the art can readily consult the literature to identify other materials that may be useful in combination. 
       HIL/HTL: 
       [0081]    A hole injecting/transporting material to be used in the present invention is not particularly limited, and any compound may be used as long as the compound is typically used as a hole injecting/transporting material. Examples of the material include, but not limit to: a phthalocyanine or porphryin derivative; an aromatic amine derivative; an indolocarbazole derivative; a polymer containing fluorohydrocarbon; a polymer with conductivity dopants; a conducting polymer, such as PEDOT/PSS; a self-assembly monomer derived from compounds such as phosphonic acid and sliane derivatives; a metal oxide derivative, such as MoO x ; a p-type semiconducting organic compound, such as 1,4,5,8,9,12-Hexaazatriphenylenehexacarbonitrile; a metal complex, and a cross-linkable compounds. 
         [0082]    Examples of aromatic amine derivatives used in HIL or HTL include, but not limit to the following general structures: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0083]    Each of Ar 1  to Ar 9  is selected from the group consisting aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, azulene; group consisting aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and group consisting 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Wherein each Ar is further substituted by a substituent selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfonyl, sulfonyl, phosphine, and combinations thereof. 
         [0084]    In one aspect, Ar 1  to Ar 9  is independently selected from the group consisting of: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0085]    k is an integer from 1 to 20; X 1  to X 8  is C (including CH) or N; Ar 1  has the same group defined above. 
         [0086]    Examples of metal complexes used in HIL or HTL include, but not limit to the following general formula: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0087]    M is a metal, having an atomic weight greater than 40; (Y 1 —Y 2 ) is a bidentate ligand, Y 1  and Y 2  are independently selected from C, N, O, P, and S; L is an ancillary ligand; m is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and m+n is the maximum number of ligands that may be attached to the metal. 
         [0088]    In one aspect, (Y 1 —Y 2 ) is a 2-phenylpyridine derivative. 
         [0089]    In another aspect, (Y 1 —Y 2 ) is a carbene ligand. 
         [0090]    In another aspect, M is selected from Ir, Pt, Os, and Zn. 
         [0091]    In a further aspect, the metal complex has a smallest oxidation potential in solution vs. Fc + /Fc couple less than about 0.6 V. 
       Host: 
       [0092]    The light emitting layer of the organic EL device of the present invention preferably contains at least a metal complex as light emitting material, and may contain a host material using the metal complex as a dopant material. Examples of the host material are not particularly limited, and any metal complexes or organic compounds may be used as long as the triplet energy of the host is larger than that of the dopant. While the Table below categorizes host materials as preferred for devices that emit various colors, any host material may be used with any dopant so long as the triplet criteria is satisfied. 
         [0093]    Examples of metal complexes used as host are preferred to have the following general formula: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0094]    M is a metal; (Y 3 —Y 4 ) is a bidentate ligand, Y 3  and Y 4  are independently selected from C, N, O, P, and S; L is an ancillary ligand; m is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and m+n is the maximum number of ligands that may be attached to the metal. 
         [0095]    In one aspect, the metal complexes are: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0096]    (O—N) is a bidentate ligand, having metal coordinated to atoms O and N. 
         [0097]    In another aspect, M is selected from Ir and Pt. 
         [0098]    In a further aspect, (Y 3 —Y 4 ) is a carbene ligand. 
         [0099]    Examples of organic compounds used as host are selected from the group consisting aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, azulene; group consisting aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and group consisting 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Wherein each group is further substituted by a substituent selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfonyl, sulfonyl, phosphino, and combinations thereof. 
         [0100]    In one aspect, host compound contains at least one of the following groups in the molecule: 
         [0000]    
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
     
         [0101]    R 1  to R 7  is independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, when it is aryl or heteroaryl, it has the similar definition as Ar&#39;s mentioned above. 
         [0102]    k is an integer from 0 to 20. 
         [0103]    X 1  to X 8  is selected from C (including CH) or N. 
         [0104]    Z 1  and Z 2  is selected from NR&#39;, O, or S. 
       HBL: 
       [0105]    A hole blocking layer (HBL) may be used to reduce the number of holes and/or excitons that leave the emissive layer. The presence of such a blocking layer in a device may result in substantially higher efficiencies as compared to a similar device lacking a blocking layer. Also, a blocking layer may be used to confine emission to a desired region of an OLED. 
         [0106]    In one aspect, compound used in HBL contains the same molecule or the same functional groups used as host described above. 
         [0107]    In another aspect, compound used in HBL contains at least one of the following groups in the molecule: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0108]    k is an integer from 0 to 20; L is an ancillary ligand, m is an integer from 1 to 3. 
       ETL: 
       [0109]    Electron transport layer (ETL) may include a material capable of transporting electrons. Electron transport layer may be intrinsic (undoped), or doped. Doping may be used to enhance conductivity. Examples of the ETL material are not particularly limited, and any metal complexes or organic compounds may be used as long as they are typically used to transport electrons. 
         [0110]    In one aspect, compound used in ETL contains at least one of the following groups in the molecule: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0111]    R 1  is selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, when it is aryl or heteroaryl, it has the similar definition as Ar&#39;s mentioned above. 
         [0112]    Ar 1  to Ar 3  has the similar definition as Ar&#39;s mentioned above. 
         [0113]    k is an integer from 0 to 20. 
         [0114]    X 1  to X 8  is selected from C (including CH) or N. 
         [0115]    In another aspect, the metal complexes used in ETL contains, but not limit to the following general formula: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0116]    (O—N) or (N—N) is a bidentate ligand, having metal coordinated to atoms O, N or N,N; L is an ancillary ligand; m is an integer value from 1 to the maximum number of ligands that may be attached to the metal. 
         [0117]    In any above-mentioned compounds used in each layer of the OLED device, the hydrogen atoms can be partially or fully deuterated. 
         [0118]    In addition to and/or in combination with the materials disclosed herein, many hole injection materials, hole transporting materials, host materials, dopant materials, exiton/hole blocking layer materials, electron transporting and electron injecting materials may be used in an OLED. Non-limiting examples of the materials that may be used in an OLED in combination with materials disclosed herein are listed in Table 4 below. Table 4 lists non-limiting classes of materials, non-limiting examples of compounds for each class, and references that disclose the materials. 
         [0000]    
       
         
               
               
               
             
               
             
               
               
               
             
               
             
               
               
               
             
               
             
               
               
               
             
               
             
               
               
               
             
               
             
               
               
               
             
               
             
               
               
               
             
               
             
               
               
               
             
               
             
               
               
               
             
               
             
               
               
               
             
               
             
               
               
               
             
           
               
                 TABLE 4 
               
               
                   
               
               
                 MATERIAL  
                 EXAMPLES OF MATERIAL  
                 PUBLICATIONS 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 Hole injection materials  
               
             
          
           
               
                 Phthalocyanine  and porphryin  compounds  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 69, 2160 (1996)  
               
               
                   
               
               
                 Starburst  triarylamines  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 J. Lumin. 72-74, 985 (1997)  
               
               
                   
               
               
                 CF x   Fluorohydrocarbon polymer  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 78, 673 (2001)  
               
               
                   
               
               
                 Conducting polymers (e.g., PEDOT:PSS, polyaniline, polypthiophene)  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Synth. Met. 87, 171 (1997) WO2007002683  
               
               
                   
               
               
                 Phosphonic acid  and sliane SAMs  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20030162053  
               
               
                   
               
               
                 Triarylamine or polythiophene  polymers with  conductivity  dopants  
                                           
                            
                            
 
                 EP1725079A1  
               
               
                   
               
               
                 Organic  compounds with conductive inorganic compounds, such as molybdenum and  tungsten oxides  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20050123751 SID Symposium Digest, 37, 923 (2006) WO2009018009  
               
               
                   
               
               
                 n-type  semiconducting organic  complexes  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20020158242  
               
               
                   
               
               
                 Metal  organometallic complexes  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20060240279  
               
               
                   
               
               
                 Cross-linkable  compounds  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20080220265  
               
               
                   
               
               
                 Polythiophene  based polymers and  copolymers  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2011075644 EP2350216  
               
               
                   
               
             
          
           
               
                 Hole transporting materials  
               
             
          
           
               
                 Triarylamines (e.g., TPD, α-NPD)  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 51, 913 (1987)  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US5061569  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 EP650955  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 J. Mater. Chem. 3, 319 (1993)  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 90, 183503 (2007)  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 90, 183503 (2007)  
               
               
                   
               
               
                 Triaylamine on spirofluorene  core  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Synth. Met. 91, 209 (1997)  
               
               
                   
               
               
                 Arylamine  carbazole compounds  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Adv. Mater. 6, 677 (1994), US20080124572  
               
               
                   
               
               
                 Triarylamine with (di)benzothiophene/ (di)benzofuran  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20070278938, US20080106190 US20110163302  
               
               
                   
               
               
                 Indolocarbazoles  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Synth. Met. 111, 421 (2000)  
               
               
                   
               
               
                 Isoindole  compounds  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Chem. Mater. 15, 3148 (2003)  
               
               
                   
               
               
                 Metal carbene  complexes  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20080018221  
               
               
                   
               
             
          
           
               
                 Phosphorescent OLED host materials  
               
               
                 Red hosts  
               
             
          
           
               
                 Arylcarbazoles  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 78, 1622 (2001)  
               
               
                   
               
               
                 Metal 8- hydroxyquinolates (e.g., Alq 3 , BAlq)  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Nature 395, 151 (1998)  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20060202194  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2005014551  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2006072002  
               
               
                   
               
               
                 Metal phenoxybenzothiazole compounds  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 90, 123509 (2007)  
               
               
                   
               
               
                 Conjugated  oligomers and polymers (e.g., polyfluorene)  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Org. Electron. 1, 15 (2000)  
               
               
                   
               
               
                 Aromatic fused rings  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2009066779, WO2009066778, WO2009063833, US20090045731, US20090045730, WO2009008311, US20090008605, US20090009065  
               
               
                   
               
               
                 Zinc complexes  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2010056066  
               
               
                   
               
               
                 Chrysene based compounds  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2011086863  
               
               
                   
               
             
          
           
               
                 Green hosts  
               
             
          
           
               
                 Arylcarbazoles  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 78, 1622 (2001)  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20030175553  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2001039234  
               
               
                   
               
               
                 Aryltriphenylene compounds  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20060280965  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20060280965  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2009021126  
               
               
                   
               
               
                 Poly-fused  heteroaryl compounds  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20090309488 US20090302743 US20100012931  
               
               
                   
               
               
                 Donor acceptor  type molecules  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2008056746  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2010107244  
               
               
                   
               
               
                 Aza-carbazole/ DBT/DBF  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 JP2008074939  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20100187984  
               
               
                   
               
               
                 Polymers  (e.g., PVK)  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 77, 2280 (2000)  
               
               
                   
               
               
                 Spirofluorene  compounds  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2004093207  
               
               
                   
               
               
                 Metal phenoxybenzooxazole compounds  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2005089025  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2006132173  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 JP200511610  
               
               
                   
               
               
                 Spirofluorene- carbazole compounds  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 JP2007254297  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 JP2007254297  
               
               
                   
               
               
                 Indolocabazoles  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2007063796  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2007063754  
               
               
                   
               
               
                 5-member ring  electron deficient  heterocycles (e.g., triazole,  oxadiazole)  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 J. Appl. Phys. 90, 5048 (2001)  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2004107822  
               
               
                   
               
               
                 Tetraphenylene  complexes  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20050112407  
               
               
                   
               
               
                 Metal  phenoxypyridine compounds  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2005030900  
               
               
                   
               
               
                 Metal coordination complexes  (e.g., Zn, Al with N{circumflex over ( )}N ligands)  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20040137268, US20040137267  
               
               
                   
               
             
          
           
               
                 Blue hosts  
               
             
          
           
               
                 Arylcarbazoles  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett, 82, 2422 (2003)  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20070190359  
               
               
                   
               
               
                 Dibenzothiophene/ Dibenzofuran- carbazole compounds  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2006114966, US20090167162  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20090167162  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2009086028  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20090030202, US20090017330  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20100084966  
               
               
                   
               
               
                 Silicon aryl  compounds  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20050238919  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2009003898  
               
               
                   
               
               
                 Silicon/ Germanium aryl compounds  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 EP2034538A  
               
               
                   
               
               
                 Aryl benzoyl ester  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2006100298  
               
               
                   
               
               
                 Carbazole linked  by non- conjugated groups  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20040115476  
               
               
                   
               
               
                 Aza-carbazoles  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20060121308  
               
               
                   
               
               
                 High triplet metal organometallic  complex  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US7154114  
               
               
                   
               
             
          
           
               
                 Phosphorescent dopants  
               
               
                 Red dopants  
               
             
          
           
               
                 Heavy metal  porphyrins (e.g., PtOEP)  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Nature 395, 151 (1998)  
               
               
                   
               
               
                 Iridium(III)  organometallic complexes  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 78, 1622 (2001)  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US2006835469  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US2006835469  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20060202194  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20060202194  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20070087321  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20080261076 US20100090591  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20070087321  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Adv. Mater. 19, 739 (2007)  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2009100991  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2008101842  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US7232618  
               
               
                   
               
               
                 Platinum(II) organometallic  complexes  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2003040257  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20070103060  
               
               
                   
               
               
                 Osminum(III)  complexes  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Chem. Mater. 17, 3532 (2005)  
               
               
                   
               
               
                 Ruthenium(II)  complexes  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Adv. Mater. 17, 1059 (2005)  
               
               
                   
               
               
                 Rhenium (I), (II),  and (III) complexes  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20050244673  
               
               
                   
               
             
          
           
               
                 Green dopants  
               
             
          
           
               
                 Iridium(III)  organometallic complexes  
                                           
   and its derivatives  
                 Inorg. Chem. 40, 1704 (2001)  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20020034656  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US7332232  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20090108737  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2010028151  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 EP1841834B  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20060127696  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20090039776  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US6921915  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20100244004  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US6687266  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Chem. Mater. 16, 2480 (2004)  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20070190359  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20060008670 JP2007123392  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2010086089, WO2011044988  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Adv. Mater. 16, 2003 (2004)  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Angew. Chem. Int. Ed. 2006, 45, 7800  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2009050290  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20090165846  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20080015355  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20010015432  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20100295032  
               
               
                   
               
               
                 Monomer for  polymeric metal  organometallic compounds  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US7250226, US7396598  
               
               
                   
               
               
                 Pt(II) organometallic complexes, including polydentated ligands  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 86, 153505 (2005)  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 86, 153505 (2005)  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Chem. Lett. 34, 592 (2005)  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2002015645  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20060263635  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20060182992 US20070103060  
               
               
                   
               
               
                 Cu complexes  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2009000673  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20070111026  
               
               
                   
               
               
                 Gold complexes  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Chem. Commun. 2906 (2005)  
               
               
                   
               
               
                 Rhenium(III)  complexes  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Inorg. Chem. 42, 1248 (2003)  
               
               
                   
               
               
                 Osmium(II)  complexes  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US7279704  
               
               
                   
               
               
                 Deuterated  organometallic complexes  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20030138657  
               
               
                   
               
               
                 Organometallic  complexes with two or  more metal centers  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20030152802  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US7090928  
               
               
                   
               
             
          
           
               
                 Blue dopants  
               
             
          
           
               
                 Iridium(III)  organometallic complexes  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2002002714  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2006009024  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20060251923 US20110057559 US20110204333  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US7393599, WO2006056418, US20050260441, WO2005019373  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US7534505  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2011051404  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US7445855  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20070190359, US20080297033 US20100148663  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US7338722  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20020134984  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Angew. Chem. Int. Ed. 47, 1 (2008)  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Chem. Mater. 18, 5119 (2006)  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Inorg. Chem. 46, 4308 (2007)  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2005123873  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2005123873  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2007004380  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2006082742  
               
               
                   
               
               
                 Osmium(II)  complexes  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US7279704  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Organometallics 23, 3745 (2004)  
               
               
                   
               
               
                 Gold complexes  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 74, 1361 (1999)  
               
               
                   
               
               
                 Platinum(II)  complexes  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2006098120, WO2006103874  
               
               
                   
               
               
                 Pt tetradentate  complexes with at least  one metal- carbene bond  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US7655323  
               
               
                   
               
             
          
           
               
                 Exciton/hole blocking layer materials  
               
             
          
           
               
                 Bathocuprine  compounds (e.g., BCP,  BPhen)  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 75, 4 (1999)  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 79, 449 (2001)  
               
               
                   
               
               
                 Metal 8- hydroxyquinolates (e.g., BAlq)  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 81, 162 (2002)  
               
               
                   
               
               
                 5-member ring  electron deficient  heterocycles such as triazole,  oxadiazole, imidazole,  benzoimidazole  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 81, 162 (2002)  
               
               
                   
               
               
                 Triphenylene  compounds  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20050025993  
               
               
                   
               
               
                 Fluorinated aromatic compounds  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 79, 156 (2001)  
               
               
                   
               
               
                 Phenothiazine-S-oxide  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2008132085  
               
               
                   
               
               
                 Silylated five- membered nitrogen, oxygen,  sulfur or phosphorus dibenzoheterocycles  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2010079051  
               
               
                   
               
               
                 Aza-carbazoles  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20060121308  
               
               
                   
               
             
          
           
               
                 Electron transporting materials  
               
             
          
           
               
                 Anthracene- benzoimidazole compounds  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 WO2003060956  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20090179554  
               
               
                   
               
               
                 Aza triphenylene derivatives  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20090115316  
               
               
                   
               
               
                 Anthracene- benzothiazole compounds  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 89, 063504 (2006)  
               
               
                   
               
               
                 Metal 8- hydroxyquinolates (e.g., Alq 3 , Zrq 4 )  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 51, 913 (1987) US7230107  
               
               
                   
               
               
                 Metal hydroxybenoquinolates  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Chem. Lett. 5, 905 (1993)  
               
               
                   
               
               
                 Bathocuprine  compounds such as BCP,  BPhen, etc  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 91, 263503 (2007)  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 79, 449 (2001)  
               
               
                   
               
               
                 5-member ring  electron deficient  heterocycles (e.g., triazole,  oxadiazole, imidazole, benzoimidazole)  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 74, 865 (1999)  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Appl. Phys. Lett. 55, 1489 (1989)  
               
               
                   
               
               
                   
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Jpn. J. Apply. Phys. 32, L917 (1993)  
               
               
                   
               
               
                 Silole compounds  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 Org. Electron. 4, 113 (2003)  
               
               
                   
               
               
                 Arylborane  compounds  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 J. Am. Chem. Soc. 120, 9714 (1998)  
               
               
                   
               
               
                 Fluorinated aromatic compounds  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 J. Am. Chem. Soc. 122, 1832 (2000)  
               
               
                   
               
               
                 Fullerene (e.g., C60)  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20090101870  
               
               
                   
               
               
                 Triazine complexes  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US20040036077  
               
               
                   
               
               
                 Zn (N{circumflex over ( )}N) complexes  
                 
                   
                             
                     
                         
                         
                     
                   
                 
                 US6528187 
               
               
                   
               
             
          
         
       
     
       Experimental 
       [0119]    Chemical abbreviations used throughout this document are as follows: Cy is cyclohexyl, dba is dibenzylideneacetone, EtOAc is ethyl acetate, DME is dimethoxyethane, dppe is 1,2-bis(diphenylphosphino)ethane, THF is tetrahydrofuran, DMF is dimethylformamide, DCM is dichloromethane, S-Phos is dicyclohexyl(2′,6′-dimethoxy-[1,1′-biphenyl]-2-yl)phosphine, Tf is trifluoromethylsulfonate. Unless specified otherwise, references to degassing a particular solvent refer to saturating the solvent sufficiently with dry nitrogen gas (by bubbling it in the solvent) to substantially remove gaseous oxygen from the solvent. 
       Synthesis of Compound 113 
     Synthesis of N-(4-bromophenyl)-N-phenyldibenzo[b,d]thiophen-4-amine 
       [0120]    
       
                 
         
             
             
         
       
     
         [0121]    Toluene (125 mL) was bubbled with nitrogen gas for 15 minutes, and subsequently 1,1′-Bis(diphenylphosphino)ferrocene (0.2 g, 0.4 mmol) and Pd 2 (dba) 3  (0.1 g, 0.1 mmol) were added. The mixture was bubbled with nitrogen gas for 15 minutes, then N-phenyldibenzo[b,d]thiophen-4-amine (3.2 g, 11.6 mmol), 1-bromo-4-iodobenzene (4.5 g, 15.9 mmol), NaO t Bu (1.5 g, 15.6 mmol) were added. The mixture was bubbled with nitrogen gas for 15 minutes and refluxed for 12 hours. After cooling, the reaction mixture was filtered through a silica pad and washed with 50% CH 2 Cl 2 /hexane. The solvent was removed in vacuo and the residue was purified by flash chromatography using 10-15% CH 2 Cl 2 /hexane to afford N-(4-bromophenyl)-N-phenyldibenzo[b,d]thiophen-4-amine (4.0 g, 80% yield) as a white solid. 
         [0000]    
       
                 
         
             
             
         
       
     
       Synthesis of N-phenyl-N-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)dibenzo[b,d]thiophen-4-amine 
       [0122]    To a solution of N-(4-bromophenyl)-N-phenyldibenzo[b,d]thiophen-4-amine (8.3 g, 19.3 mmol) in 1,4-dioxane (250 mL) was added bis(pinacolato)diboron (7.6 g, 29.9 mmol), KOAc (3.9 g, 39.8 mmol), and the solution was bubbled with nitrogen for 15 minutes. Pd(dppf)Cl 2 .CH 2 Cl 2  (0.5 g, 0.6 mmol) was then added to the solution, and the reaction mixture was bubbled with nitrogen for 15 minutes. The resultant mixture was refluxed for 12 hours. After cooling, H 2 O (1 mL) was added and stirred for 15 min. The reaction mixture was filtered through a silica pad and washed with 75% CH 2 Cl 2 /hexane. The solvent was removed in vacuo and the residue was purified by flash chromatography using 25-40% CH 2 Cl 2 /hexane to afford N-phenyl-N-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)dibenzo[b,d]thiophen-4-amine (5.9 g, 64% yield) as a white solid. 
         [0000]    
       
                 
         
             
             
         
       
     
       Synthesis of N-(4-(9H-carbazol-3-yl)phenyl)-N-phenyldibenzo[b,d]thiophen-4-amine 
       [0123]    To a solution of N-phenyl-N-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)dibenzo[b,d]thiophen-4-amine (5.9 g, 12.4 mmol), 3-bromocabazole (3.5 g, 14.2 mmol), K 2 CO 3  (16.6 g, 120.0 mmol) in toluene (150 mL), water (50 mL) and EtOH (50 mL) was bubbled for 30 min. Pd(PPh 3 ) 4  (0.4 g, 0.4 mmol) was added. The mixture was bubbled for 15 min. The resultant mixture was refluxed for 12 h. After cooling, the reaction mixture was extracted by CH 2 Cl 2  and dried by MgSO 4 . The solvent was removed in vacuo and the residue was purified by flash chromatography using 25-50% CH 2 Cl 2 /hexane to afford N-(4-(9H-carbazol-3-yl)phenyl)-N-phenyldibenzo[b,d]thiophen-4-amine (5.8 g, 91% yield) as a white solid. 
       Synthesis of Compound 113 
       [0124]    
       
                 
         
             
             
         
       
     
         [0125]    Xylene (175 mL) was bubbled with nitrogen for 15 minutes, followed by addition of 2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl (2.3 g, 5.6 mmol) and Pd 2 (dba) 3  (1.3 g, 1.4 mmol). The mixture was again bubbled nitrogen for 15 minutes, then N-(4-(9H-carbazol-3-yl)phenyl)-N-phenyldibenzo[b,d]thiophen-4-amine (3.4 g, 6.6 mmol), 4-iododibenzothiophene (3.3 g, 10.6 mmol), sodium tert-butoxide (1.4 g, 14.0 mmol) were added. The mixture was bubbled with nitrogen for 15 minutes and refluxed for 12 hours. After cooling, the reaction mixture was filtered through a silica pad and washed with 80% CH 2 Cl 2 /hexane. The solvent was removed in vacuo and the residue was purified by flash chromatography using 20-35% CH 2 Cl 2 /hexane to afford Compound 113 (2.9 g, 63% yield) as a white solid. 
       Synthesis of Compound 178 
     Synthesis of bis(4-bromophenyl)amine 
       [0126]    
       
                 
         
             
             
         
       
     
         [0127]    N-bromosuccinimide (17.8 g, 0.1 mol) in 50 mL of DMF was added slowly to diphenylamine (8.46 g, 0.05 mol) in 50 mL of DMF at 0° C. in 30 minutes. The reaction was allowed to warm to room temperature and stir overnight. The white precipitate was filtered and air dried, and 16 g of product was collected. 
       Synthesis of di([1,1′-biphenyl]-4-yl)amine 
       [0128]    
       
                 
         
             
             
         
       
     
         [0129]    Bis(4-bromophenyl)amine (4.0 g, 12.3 mmol) and phenylboronic acid (4.0 g, 32.7 mmol) were mixed in 250 mL of toluene and 60 mL of ethanol. The solution was bubbled with nitrogen while stirring for 15 minutes. Pd(PPh 3 ) 4  (1.4 g, 1.23 mmol) and K 3 PO 4  (13.5 g, 64 mmol) were added in sequence. The mixture was heated to reflux overnight under nitrogen. After cooling, the reaction mixture was filtered through filter paper and the solvent was then evaporated. The solid was redissolved in nitrogen-purged hot toluene and was filtered through a Celite®/silica pad when the solution was still hot. The solvent was then evaporated. The white crystalline solid was washed by hexane and air dried to obtain 3.8 g of product. 
       Synthesis of N-([1′,1′-biphenyl]-4-yl)-N-(4-bromophenyl)-[1,1′-biphenyl]-4-amine 
       [0130]    
       
                 
         
             
             
         
       
     
         [0131]    Di([1,1′-biphenyl]-4-yl)amine (3.5 g, 10.9 mmol) and 1-bromo-4-iodobenzene (6.0 g, 21.3 mmol) were mixed in 300 mL of dry toluene. The solution was bubbled with nitrogen while stirring for 15 minutes. Pd(OAc) 2  (36 mg, 0.16 mmol), triphenylphosphine (0.16 g, 0.6 mmol) and sodium t-butoxide (2.0 g, 20.8 mmol) were added in sequence. The mixture was heated to reflux overnight under nitrogen. After cooling, the reaction mixture was filtered through Celite®/silica pad and the solvent was then evaporated. The residue was then purified by column chromatography using DCM:hexane (1:4, v/v) as the eluent to obtain 3.9 g of product. 
       Synthesis of 9-(dibenzo[b,d]thiophen-4-yl)-9H-carbazole 
       [0132]    
       
                 
         
             
             
         
       
     
         [0133]    Carbazole (0.62 g, 3.67 mmol) and 4-iododibenzothiophene (1.2 g, 3.87 mmol) were mixed in 70 mL of dry xylene. The solution was bubbled nitrogen while stirring for 15 minutes. Pdz(dba) 3  (0.16 g, 0.17 mmol), 2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl (0.24 g, 0.58 mmol) and sodium tert-butoxide (1.0 g, 10.4 mmol) were added in sequence. The mixture was heated to reflux for 3 days under nitrogen. After cooling, the reaction mixture was filtered through a Celite®/silica pad and the solvent was then evaporated. The residue was then purified by column chromatography using DCM:hexane (1:4, v/v) as the eluent to obtain 0.64 g of product. 
       Synthesis of 3-bromo-9-(dibenzo[b,d]thiophen-4-yl)-9H-carbazole 
       [0134]    
       
                 
         
             
             
         
       
     
         [0135]    N-bromosuccinimide (0.31 g, 1.74 mmol) in 5 mL DMF was added slowly to 9-(dibenzo[b,d]thiophen-4-yl)-9H-carbazole (0.6 g, 1.72 mmol) in 50 mL of DCM at 0° C. The reaction was allowed to warm to room temp and stirred overnight. The reaction mixture was extracted with DCM and dried over MgSO 4  and the solvent was evaporated. The residue was purified by column chromatography using DCM:hexane (1:4, v/v) as the eluent to obtain 0.45 g of product. 
       Synthesis of 9-(dibenzo thiophen-4-yl)-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9H-carbazole 
       [0136]    
       
                 
         
             
             
         
       
     
         [0137]    3-bromo-9-(dibenzo[b,d]thiophen-4-yl)-9H-carbazole (0.45 g, 1.1 mmol), bis(pinacolato)diboron (0.43 g, 1.4 mmol) and KOAc (0.31 g, 3.1 mmol) were mixed in 150 mL of dry 1,4-dioxane. The solution was bubbled with nitrogen while stirring for 15 minutes, then Pd(dppf)Cl 2 .CH 2 Cl 2  (26 mg, 0.03 mmol) was added. The mixture was heated to reflux overnight under nitrogen. After cooling, the reaction mixture was filtered through Celite®/silica pad and the solvent was then evaporated. The residue was then purified by column chromatography using DCM:hexane (3:7, v/v) as the eluent to obtain 0.4 g of product. 
       Synthesis of Compound 178 
       [0138]    
       
                 
         
             
             
         
       
     
         [0139]    N-([1,1′-biphenyl]-4-yl)-N-(4-bromophenyl)-[1,1′-biphenyl]-4-amine (2.5 g, 5.25 mmol), and 9-(dibenzo[b,d]thiophen-4-yl)-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9H-carbazole (2.64 g, 5.58 mmol) were mixed in 250 mL of toluene and 30 mL of deionized water. The solution was bubbled with nitrogen while stirring for 15 minutes, then Pd 2 (dba) 3  (0.12 g, 0.13 mmol), 2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl (0.21 g, 0.51 mmol) and K 3 PO 4  (3.5 g, 16.5 mmol) were added in sequence. The mixture was heated to reflux overnight under nitrogen. Bromobenzene (1 mL) was added to the reaction mixture and the reaction was further refluxed for 4 hours. After cooling, the reaction mixture was filtered through a Celite®/silica pad and the solvent was then evaporated. Compound 178 (2.4 g) was collected and purified by recrystallization from 20 mL of degassed toluene. 
       Compound 182 
     Synthesis of 9-(triphenylen-2-yl)-9H-carbazole 
       [0140]    
       
                 
         
             
             
         
       
     
         [0141]    To a stirred solution of Pd 2 (dba) 3  (0.52 g, 0.57 mmol) in o-xylene (140 mL), 2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl (0.94 g, 2.3 mmol) was added and degassed with nitrogen for 15 minutes. Carbazole (5.33 g, 31.9 mmol) and 2-bromotriphenylene (7.0 g, 22.7 mmol), sodium tert-butoxide (6.57 g, 68.3 mmol) were added and degassed with nitrogen for another 15 minutes. The reaction was refluxed for 2 days. The reaction mixture was filtered through silica, washed with DCM and dried under vacuum. Silica gel chromatography with 10% DCM/hexane, yielded 4.98 g of a while solid (56%) as the product. 
       Synthesis of 3-bromo-9-(triphenylen-2-yl)-9H-carbazole 
       [0142]    
       
                 
         
             
             
         
       
     
         [0143]    To a stirred solution of 9-(triphenylen-2-yl)-9H-carbazole (4.7 g, 11.9 mmol) in DMF (24 mL) at 0° C. under N 2 , NBS (N-bromosuccinimide) (2.1 g, 11.9 mmol) in DMF (24 mL) was added dropwise. After the completion of addition, the reaction mixture was warmed to room temperature overnight with vigorous stirring. The reaction mixture was precipitated with water and the solid was filtered. The pale grey solid was re-dissolved in a small amount of THF, added on a silica plug and flushed with 30% DCM/hexane. The filtrate was dried under vacuum and the white solid was used without further purification (5.5 g, 98 N. 
       Synthesis of 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9-(triphenylen-2-yl)-9H-carbazole 
       [0144]    
       
                 
         
             
             
         
       
     
         [0145]    To a stirred solution of 3-bromo-9-(triphenylen-2-yl)-9H-carbazole (3.0 g, 6.4 mmol) in 1,4-dioxane (90 mL), bis(pinacolato)diboron (2.4 g, 9.5 mmol) and KOAc (1.8 g, 19.1 mmol) were added and degassed with nitrogen for 15 min, then Pd(dppf)Cl 2 .CH 2 Cl 2  (0.14 g, 0.2 mmol) was added and the mixture was degassed with nitrogen for another 15 minutes. The solution was refluxed for 2 days. After cooling to room temperature, water (1 mL) was added and the reaction mixture was stirred for 30 minutes. The reaction mixture was filtered through silica and dried under vacuum. The solid was column chromatographed with 20-50% DCM/hexane, yielding 2.0 g of a while solid (61%) as the product. 
       Synthesis of Compound 182 
       [0146]    
       
                 
         
             
             
         
       
     
         [0147]    To a stirred solution of N-([1,1′-biphenyl]-4-yl)-N-(4-bromophenyl)-[1,1′-biphenyl]-4-amine (0.9 g, 1.9 mmol) in toluene (29 mL) and water (2.9 mL), 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9-(triphenylen-2-yl)-9H-carbazole (1.0 g, 1.9 mmol) and K 3 PO 4  (2.4 g, 11.3 mmol) were added and the mixture was degassed with nitrogen for 15 minutes, then Pd 2 (dba) 3  (86 mg, 0.09 mmol) and 2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl (0.16 g, 0.38 mmol) were added and degassed with nitrogen for another 15 minutes. The mixture was refluxed overnight. After cooling to room temperature, the reaction mixture was filtered through silica, washed with DCM and dried under vacuum. It was column chromatographed with 20-50% DCM/hexane yielding 1.03 g of a while solid (69%) as Compound 182. 
         [0148]    It is understood that the various embodiments described herein are by way of example only, and are not intended to limit the scope of the invention. For example, many of the materials and structures described herein may be substituted with other materials and structures without deviating from the spirit of the invention. The present invention as claimed may therefore include variations from the particular examples and preferred embodiments described herein, as will be apparent to one of skill in the art. It is understood that various theories as to why the invention works are not intended to be limiting.