PATENT CLAIM ANALYSIS

Application Number: 16198317
Application Type: Utility
Filing Date: 2018-11
Publication Date: 2019-03
Patent Classification: ["423", "700000"]

Abstract:
A new family of crystalline microporous metalloalumino(gallo)phosphosilicates designated MeAPSO-82 has been synthesized. These metalloalumino(gallo)phosphosilicates are represented by the empirical formula of: R p+ r A + m M 2+ w E x PSi y O z  where A is an alkali metal such as potassium, R is an quaternary ammonium cation such as ethyltrimethylammonium, M is a divalent metal such as Zn and E is a trivalent framework element such as aluminum or gallium. This family of metalloalumino(gallo)phosphosilicate materials are stabilized by combinations of alkali and quaternary ammonium cations, enabling unique, high charge density compositions. The MeAPSO-82 family of materials have the CGS topology and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.

Claim (Index 17):
A hydrocarbon conversion process comprising contacting a hydrocarbon stream with a catalyst at hydrocarbon conversion conditions to generate at least one converted product or a separation process comprising contacting at least two components with a material to generate at least one separated component, wherein the catalyst or the material is selected from the group consisting of a crystalline microporous MeAPSO-82 material, a crystalline microporous modified MeAPSO-82 material and mixtures thereof, where MeAPSO-82 is a crystalline microporous metalloalumino(gallo)phosphosilicate material having a three-dimensional framework of [M 2+ O 4/2 ] 2\u2212 , [EO 4/2 ] \u2212 , [PO 4/2 ] +  and SiO 4/2  tetrahedral units and an empirical composition in the as synthesized form and on an anhydrous basis expressed by an empirical formula of:\n R p+ r A + m M 2+ w E x PSi y O z  \n where R is at least one quaternary ammonium cation selected from the group consisting of ethyltrimethylammonium (ETMA + ), hexamethonium (HM 2+ ), choline [Me 3 NCH 2 CH 2 OH] + , trimethylpropylammonium, trimethyli sopropylammonium, trimethylbutylammonium, tetramethylammonium (TMA + ), diethyldimethylammonium (DEDMA + ), tetraethylammonium (TEA + ), tetrapropylammonium (TPA + ) and mixtures thereof, \u201cr\u201d is the mole ratio of R to P and has a value of about 0.1 to about 1.5, \u201cp\u201d is the weighted average valence of R and varies from 1 to 2, A is an alkali metal such as Li + , Na + , K + , Rb +  and Cs +  and mixtures thereof, \u201cm\u201d is the mole ratio of A to P and varies from 0.1 to 1.5, M is a divalent metal selected from the group Zn, Co, Mg, Mn and mixtures thereof, \u201cw\u201d is the mole ratio of M to P and varies from 0.2 to 0.9, E is a trivalent element selected from the group consisting of aluminum and gallium and mixtures thereof, \u201cx\u201d is the mole ratio of E to P and varies from 0.1 to 0.8, \u201cy\u201d is the mole ratio of Si to P and varies from 0.02 to about 2.5, and \u201cz\u201d is the mole ratio of O to P and has a value determined by the equation:\n z =( m+p\u00b7r+ 2\u00b7 w+ 3\u00b7 x+ 5+4\u00b7 y )/2 \n \n and is characterized in that it has the x-ray diffraction pattern having at least the d-spacings and intensities set forth in Table A: \n TABLE A 2\u0398 d(\u212b) I/I 0  % 8.32-8.05 10.62-10.97 vs 10.89-10.62 8.12-8.32 w-m 11.68-11.47 7.57-7.71 w-m 12.58-12.11 7.03-7.30 m 13.16-12.88 6.72-6.87 w 13.34-13.11 6.63-6.75 w 16.65-16.13 5.32-5.49 m-s\u2002 17.04-16.53 5.20-5.36 w-m 17.37-16.87 5.10-5.25 w 19.36-18.95 4.58-4.68 m-s\u2002 19.76-19.28 4.49-4.60 w-m 21.98-20.93 4.04-4.24 w-m 22.09-21.34 4.02-4.16 w-m 22.49-21.77 3.95-4.08 w-m 23.02-22.38 3.86-3.97 w 23.21-22.72 3.83-3.91 w-m 23.45-23.08 3.79-3.85 w 24.03-23.33 3.70-3.81 w-m 24.37-23.71 3.65-3.75 w-m 25.06-24.54 \u20023.55-3.625 m-s\u2002 26.43-25.99 \u20023.37-3.425 w-m 27.00-26.27 3.30-3.39 w-m 27.59-26.63 \u20023.23-3.345 w 29.26-28.40 3.05-3.14 m-s\u2002 29.76-28.78 3.00-3.10 m 30.70-29.91 \u20022.91-2.985 w-m 31.03-30.17 2.88-2.96 w-m 31.94-30.81 2.80-2.90 w-m 32.17-31.19 \u20022.78-2.865 w-m 33.60-32.59 2.665-2.745 w-m 34.13-33.03 2.625-2.71\u2002 w 34.47-34.00 \u20022.60-2.635 w-m 35.16-34.94 \u20022.55-2.566 w-m and the crystalline microporous modified MeAPSO-82 consists of a three-dimensional framework of [M 2+ O 4/2 ] 2\u2212 , [EO 4/2 ] \u2212 , [PO 4/2 ] +  and SiO 4/2  tetrahedral units derived from MeAPSO-82 via the modification processes of calcination, ammonia calcinations, ion-exchange, steaming, various acid extractions, ammonium hexafluorosilicate treatment, or any combination thereof.

Metadata:
- Claim Count in Document: 47.0
- Percentile: 98.0
- Lexical Diversity: 1.55914
- Patent Class: 423.0
- Transitional Phrase Type: open
- Component Type: 1
- Foreign Priority: False
- Related Applications: ['16198189', '15593209', '13689887', '15588967', '15446296']

Analysis Scores:
- 35 USC 101 Eligibility (BERT): 0.8005328907889886
- 35 USC 102 Novelty (BERT): 0.5868393218541377
- Combined Prediction Score: 0.7791635338955035
- Mean Citation Score: 444.577894
- Max Citation Score: 494.5619
- Similarity Product: 431.8612080295324

Labels:
- Claim Label 101: 1
- Claim Label 102: 1
- Claim Label 103: 1
- Claim Label 112: 0
- Combined Label: 1
- Label 101 Adjusted: 1

Dataset: test