Patent Document

CROSS REFERENCE TO RELATED APPLICATIONS 
       [0001]    This application claims the priority benefit of French patent application number 08/50350, filed on Jan. 21, 2008 entitled “METHOD FOR MANUFACTURING AN EEPROM CEL,” which is hereby incorporated by reference to the maximum extent allowable by law. 
       BACKGROUND OF THE INVENTION 
       [0002]    1. Field of the Invention 
         [0003]    The present invention relates to methods for manufacturing electrically erasable and programmable non-volatile memory cells or EEPROM cells and to memory cells obtained with such methods. 
         [0004]    2. Discussion of the Related Art 
         [0005]    An EEPROM cell generally comprises a selection element and a storage element. As an example, the selection element corresponds to a MOS transistor and the storage element corresponds to a dual-gate MOS transistor comprising a floating gate covered with a control gate. The floating gate insulator comprises a thinned-down portion at the level of the dual-gate transistor drain which forms a tunnel window. 
         [0006]    The operation of such a memory cell is the following. An erasing operation in the memory cell is performed by turning on the selection transistor, by setting the drain and the source of the dual-gate transistor to 0 volt, and by setting the control gate of the dual-gate transistor to a given voltage. This causes the passing of charges from the drain to the floating gate of the dual-gate transistor through the tunnel window and the storage of charges in the floating gate. A write operation in the memory is performed by turning on the selection transistor, by applying a write voltage between the drain and the source of the dual-gate transistor and by maintaining the control gate of the dual-gate transistor at 0 volt. This causes the evacuation of the charges stored in the floating gate through the tunnel window. A read operation is performed by turning on the selection transistor, by applying a read voltage, smaller than the write voltage, between the drain and the source of the dual-gate transistor, and by setting the control gate of the dual-gate transistor to a given voltage. The magnitude of the current conducted by the dual-gate transistor is representative of the presence or of the absence of charges in the floating gate. 
         [0007]    Conventional methods for manufacturing such a memory cell generally comprise several photolithographic etch steps requiring use of masks. As an example, a first mask is used to delimit the source and drain regions of the dual-gate transistor and a second mask is used to delimit the tunnel window. 
         [0008]    A critical point on manufacturing of the dual-gate transistor is the positioning of the drain region with respect to the tunnel window, that is, the positioning of the first mask relative to the second mask. Indeed, to ensure a proper operation of the dual-gate transistor, it is necessary for the drain region to extend under the entire tunnel window and to extend slightly beyond the tunnel window. It is desirable for this extension or projection of the drain region out of the tunnel window to be as small as possible to enable decreasing the memory cell dimensions. However, given the accuracy of currently-used mask positioning methods, it is generally necessary to provide a minimum projection greater than 0.1 μm. It is further desirable for the projection to be substantially the same from one memory cell to the other to ensure a homogeneity of the operating properties of memory cells. Memory cells being generally formed in pairs of adjacent cells symmetrical with respect to the common edge between cells, a misalignment between the first and second masks translates as projections which are different between the two asymmetrical cells. The operating properties of the memory cells of a same memory may then not be identical (odd/even effect). 
       SUMMARY OF THE INVENTION  
       [0009]    An aspect of the present invention aims at a method for manufacturing an EEPROM cell which ensures an accurate positioning between the drain region and the tunnel window of the dual-gate transistor of the memory cell. 
         [0010]    According to another aspect, the method for manufacturing the memory cell requires using one less mask than a conventional manufacturing method. 
         [0011]    Another aspect of the present invention aims at a memory cell with a structure which enables recognizing that it has been formed according to a specific embodiment of the method of the present invention. 
         [0012]    Thus, an embodiment of the present invention provides a method for manufacturing a cell of a non-volatile electrically erasable and programmable memory comprising a dual-gate MOS transistor. The method comprises the steps of: 
         [0013]    (a) providing a semiconductor substrate covered with a stack of first and second layers, the first layer being insulating; 
         [0014]    (b) forming at least one first opening in the second layer; 
         [0015]    (c) forming, in the first layer, a second opening continuing the first opening; 
         [0016]    (d) enlarging the first opening by isotropic etching; 
         [0017]    (e) forming a first doped region in the substrate by implantation through the first enlarged opening, the first doped region taking part in the forming of the transistor drain or source; 
         [0018]    (f) forming, in the third opening, a thinned-down insulating portion thinner than the first layer; and 
         [0019]    (g) forming the gates of the MOS transistor at least partially extending over the thinned-down insulating portion. 
         [0020]    According to an embodiment, at step (b), a third opening is formed in the second layer. At step (c), a fourth opening extending the third opening is formed in the first layer. At step (d), the third opening is enlarged by said isotropic etching. At step (e), a second additional doped region is formed in the substrate by implantation through the third enlarged opening. At step (f), an additional thinned-down insulating portion thinner than the first layer is formed in the fourth opening, the gates of the MOS transistor extending between the thinned-down insulating portion and the additional thinned-down insulating portion and at least partially over the additional thinned-down insulating portion, the second additional doped region taking part in the forming of the transistor drain or source. 
         [0021]    According to an embodiment, the first region extends beyond the thinned-down insulation portion by at least 60 nm. 
         [0022]    According to an embodiment, step (e) is followed by an activation anneal step. 
         [0023]    According to an embodiment, step (f) is preceded by a step of elimination of the second layer. 
         [0024]    According to an embodiment, step (d) is performed by etching under an oxygen plasma. 
         [0025]    According to an embodiment, the first layer has a thickness smaller than 20 nm and the thinned-down insulating portion has a thickness smaller than 7 nm. 
         [0026]    Another embodiment of the the present invention also provides a cell of a non-volatile electrically erasable and programmable memory formed according to the previously-described method at the level of a semiconductor substrate. The cell comprises a dual-gate MOS transistor in which a gate is separated from the substrate by an insulating layer, the insulating layer comprising two thinned-down insulating portions, the gate extending between and on at least a portion of the thinned-down insulating portions, and in which a drain and a source each comprise a doped region formed in the substrate and extending under all of one of the thinned-down insulating portions. 
     
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS  
         [0027]    The foregoing objects, features, and advantages of the present invention will be discussed in detail in the following non-limiting description of specific embodiments in connection with the accompanying drawings. 
           [0028]      FIGS. 1A to 1I  show the structures obtained at successive steps of a conventional example of an EEPROM cell forming method; and 
           [0029]      FIGS. 2A to 2I  show the structures obtained at successive steps of an example of a method for manufacturing an EEPROM cell according to the present invention. 
       
    
    
     DETAILED DESCRIPTION  
       [0030]    For clarity, the same elements have been designated with the same reference numerals in the different drawings and, further, as usual in the representation of integrated circuits, the various drawings are not to scale. 
         [0031]      FIGS. 1A to 1I  are cross-section views of an EEPROM cell at successive steps of a conventional manufacturing method. 
         [0032]      FIG. 1  A shows the structure obtained after the steps of: 
         [0033]    forming on a semiconductor substrate  10 , for example, a P-type doped single-crystal silicon substrate, of an insulating layer  12 ; 
         [0034]    deposition of a masking film  14  on insulating layer  12 ; and 
         [0035]    forming of openings  16 ,  17  in film  14 , by a photolithographic etch method using a first mask (not shown) to insolate film  14 . Openings  16 ,  17  are respectively formed above the portions of substrate  10  where drain and sources regions of the dual-gate transistor are desired to be formed. The dimension of opening  16  along the direction perpendicular in the cross-section plane to the stack direction of layers  12  and  14  is called width d 0 . 
         [0036]      FIG. 1B  shows the structure obtained after having carried out an implantation step resulting in the forming of doped regions  18 ,  20 , for example, of type N, in substrate  10  in continuation of openings  16 ,  17 . 
         [0037]      FIG. 1C  shows the structure obtained after having removed film  14  and after having carried out an activation anneal. The anneal causes a diffusion of dopant elements from regions  18  and  20 , whereby an expansion of regions  18  and  20  occurs. 
         [0038]      FIG. 1D  shows the structure obtained after having deposited a masking film  22  on insulating layer  12  and after having formed an opening  24  in film  22  above the portion of insulating layer  12  where the tunnel window of the dual-gate transistor is desired to be formed. The etching of film  22  is carried out by a photolithographic etch method using a second mask (not shown) to insolate film  22 . The width of opening  24  is called d 1 . 
         [0039]      FIG. 1E  shows the structure obtained after having etched insulating layer  12  to form an opening  26  in continuation of opening  24 . 
         [0040]      FIG. 1F  shows the structure obtained after having removed film  22  and after having formed a thinned-down insulating portion  28 , at the level of opening  26 , thinned-down insulating portion  28  forming the tunnel window of the dual-gate transistor. Region  18  extends under the entire tunnel window  28 . The projection or extension of region  18  beyond tunnel window  28  on the side where the gates of the dual-gate transistor must be formed is called d 2 . 
         [0041]      FIG. 1G  shows the structure obtained after having deposited on layer  12  a first polysilicon layer  30 , an insulating layer  32 , and a second polysilicon layer  34 . 
         [0042]      FIG. 1H  shows the structure obtained after having deposited a masking film  36  on insulating layer  34  and after having etched openings  38  in film  36  which follow the contours of the selection transistor and of the dual-gate transistor of the EEPROM cell. The etching of film  36  is performed by a photolithography method using a third mask (not shown) to insolate film  36 . 
         [0043]      FIG. 1I  shows the structure obtained after having anisotropically etched the stack of layers  30 ,  32 ,  34  in continuation of openings  38  of film  36  and after having carried out an implantation step. The etch step enables delimiting, for each memory cell, dual-gate transistor MEM and selection transistor SEL. The implantation step causes the forming in substrate  10  of heavily-doped N-type regions  52 ,  54 ,  56  in continuation of openings  38 . Region  54  forms, with region  18 , drain region D_MEM of dual-gate transistor MEM. Further, region  54  forms the source of selection transistor SEL. Region  52  forms the drain of transistor SEL. Region  56  forms, with region  20 , source S_MEM of transistor MEM. The gate width of transistor MEM is called d 3 . 
         [0044]    To ensure a proper operation of the memory cell, it is necessary for region  18  to extend under the entire tunnel window  28  and to extend beyond tunnel window  28  on the side of gate portion  40 , that is, projection d 2  must be strictly positive. According to the previously-described manufacturing method, projection d 2  is defined by two masks, the first mask being used to delimit region  18  (before the anneal step) and the second mask being used to delimit opening  26  in which tunnel window  28  is formed. It is thus necessary to accurately control the positioning of the first mask with respect to the second mask so that projection d 2  has the desired value. 
         [0045]    For a dual-gate transistor MEM for which width d 3  varies, for example, from 500 nm to 1000 nm, given the accuracy of conventional mask-positioning methods, it is necessary for projection d 2  to be on the order of 100 nm. 
         [0046]      FIGS. 2A to 2I  are cross-section views of an EEPROM cell at successive steps of an example of a manufacturing method according to the present invention. 
         [0047]      FIG. 2A  is similar to  FIG. 1A  and shows the structure obtained after the steps of: 
         [0048]    forming on a semiconductor substrate  60 , for example, a P-type doped single-crystal silicon substrate, an insulating layer  62 , for example, a silicon oxide layer having a thickness on the order of 20 nm; 
         [0049]    depositing a masking film  64 , for example a resist, on insulating layer  62 ; and 
         [0050]    forming openings  66 ,  67  in film  64  by a photolithographic etch method using a first mask (not shown) to insolate film  64 . The width of opening  66  is called d 1 ′. 
         [0051]    Opening  66  is formed above the portion of substrate  60  in which the drain region of the dual-gate transistor is desired to be formed, but width d 1 ′ is smaller than the width of the desired drain region (before the activation anneal). Indeed, width d 1 ′ corresponds to the desired width of the tunnel window of the dual-gate transistor. Opening  67  is formed at the level of the portion of substrate  60  in which the source region of the dual-gate transistor is desired to be formed. 
         [0052]      FIG. 2B  shows the structure obtained after having anisotropically etched insulating layer  62  to form openings  68 ,  69  in continuation of openings  66 ,  67 . An etching by a hydrofluoric bath may be used. 
         [0053]      FIG. 2C  shows the structure obtained after having performed a partial isotropic etching of film  64 . This etching is, for example, an isotropic etching under an oxygen plasma which causes an etching of film  64  on all its surfaces. The etch parameters are defined so that width d 0 ′ of opening  66  after etching is increased with respect to width d 1 ′ by twice a distance r selected according to the desired subsequent projection. 
         [0054]      FIG. 2D  shows the structure obtained after having carried out an implantation step causing the forming of doped regions  70 ,  72 , for example, of type N, in substrate  60  in continuation of openings  66 ,  67 . The width of region  70 , which substantially corresponds to width d 0 ′ of the corresponding opening  66 , is thus greater than width d 1 ′ of opening  68 . 
         [0055]      FIG. 2E  shows the structure obtained after having removed film  64  and after having carried out an activation anneal. The anneal results in a diffusion of dopant elements from regions  70 ,  72 , which results in an expansion of regions  70 ,  72 . 
         [0056]      FIG. 2F  shows the structure obtained after having formed thinned-down insulating portions  74 ,  76  in openings  68 ,  69 , for example silicon oxide portions, having a thickness on the order of 7 nm. Portions  74 ,  76  may be formed by a thermal oxidation method which tends to cause the forming of oxide on substrate  60  in openings  68 ,  69  but also, to a smaller degree, on insulating layer  62 . Thinned-down insulating portion  74  forms the tunnel window of the dual-gate transistor. Region  70  extends under the entire tunnel window  74 . The projection or extension of region  70  with respect to tunnel window  74  on the side where the gates of the dual-gate transistor must be formed is called d 2 ′. Similarly, region  72  extends under thinned-down insulating portion  76  and beyond on the side where the dual-gate transistor gates must be formed. 
         [0057]      FIG. 2G  shows the structure obtained after having deposited, on layer  62 , a first polysilicon layer  80 , for example having a thickness of approximately 100 nm, an insulating layer  82 , for example corresponding to a silicon oxide layer having a thickness of approximately 16 nm, and a second polysilicon layer  84 , for example having a thickness of approximately 200 nm. 
         [0058]      FIG. 2H  shows the structure obtained after having deposited a masking film  86 , for example a resist, on layer  84  and after having etched openings  88  in film  86  which follow the contours of the selection transistor and of the dual-gate transistor. The etching of film  86  is performed by a photolithographic etch method using a second mask (not shown) to insolate film  86 . 
         [0059]      FIG. 2I  shows the structure obtained after having anisotropically etched the stack of layers  80 ,  82 ,  84  in continuation of openings  88  of film  86 , and after having performed an implantation step. The etch step enables delimiting, for each memory cell, dual-gate transistor MEM and selection transistor SEL. Dual-gate transistor MEM comprises a portion  90  of polysilicon layer  80  which forms the floating gate, a portion  92  of insulating layer  82  which forms the control gate insulator, and a portion  94  of polysilicon layer  84  which forms the control gate. Selection transistor SEL comprises a portion  96  of layer  80 , a portion  98  of layer  82 , and a portion  100  of layer  84 . It may be desirable for the operation of transistor SEL to be similar to that of a conventional single-gate MOS transistor. For this purpose, an opening may be provided in insulating portion  98  so that portions  96  and  100  are short-circuited. The implantation step causes the forming in substrate  60  of heavily-doped N-type regions  102 ,  104 ,  106  in continuation of openings  88 . Region  104  forms, with region  70 , drain region D_MEM of dual-gate transistor MEM. Further, region  104  forms the source of selection transistor SEL. Region  102  forms the drain of transistor SEL. Region  106  forms with region  72  source S_MEM of transistor MEM. 
         [0060]    As appears in  FIG. 2E , projection d 2 ′ between region  70  and tunnel window  74  is defined by the dimensions of opening  66  provided in film  64  before and after the isotropic etching performed at the step illustrated in  FIG. 2C . Given that only the anisotropic etching implemented to initially form opening  66  requires use of a mask, projection d 2 ′ is thus defined by a single mask. 
         [0061]    As compared with the method previously described in relation with  FIGS. 1A to 1I , the present embodiment thus enables avoiding the use of a mask. This enables decreasing the memory cell manufacturing cost. 
         [0062]    Further, the defining of projection d 2 ′ does not depend on the relative position of the two masks. Thereby, projection d 2 ′ may be obtained with greater accuracy. Projection d 2 ′ can thus be decreased with respect to what can be envisaged for a conventional manufacturing method. As an example, for a dual-gate transistor having its width varying from 500 nm to 1000 nm, projection d 2 ′ may be smaller than 100 nm, preferably smaller than 60 nm, for example, on the order of 50 nm. Further, projection d 2 ′ is constant for all memory cells, since they are arranged in symmetrical pairs. 
         [0063]    The present manufacturing process example results in the forming of a thinned-down insulating portion  76  on the source side of dual-gate transistor MEM. An easily-identifiable structural characteristic enabling ensuring that the previously-described method example, which enables more accurately defining projection d 2 ′, has been implemented, is thus available in this case. Due to the applied voltages, thinned-down insulating portion  76  does not take part in the operation of dual-gate transistor MEM, with the charge only occurring through tunnel window  74 . 
         [0064]    Specific embodiments of the present invention have been described. Various alterations, modifications, and improvements will occur to those skilled in the art. In particular, the present invention has been described for a memory cell comprising a dual-gate transistor and a selection transistor. However, the present invention may apply to other memory cell structures, for example, memory cells for which the selection transistors are arranged in common between several memory cells. Further, in the previously-described embodiment, the MOS selection transistor is formed concurrently to the dual-gate MOS transistor and itself comprises a possibly short-circuited dual-gate structure. It should, however, be clear that the selection MOS transistor may comprise a single gate. Further, although the previously-described examples relate to N-channel transistors, it should be clear that the present invention also applies to P-channel transistors, where the voltages applied to the transistors should be modified accordingly. 
         [0065]    Such alterations, modifications, and improvements are intended to be part of this disclosure, and are intended to be within the spirit and the scope of the present invention. Accordingly, the foregoing description is by way of example only and is not intended to be limiting. The present invention is limited only as defined in the following claims and the equivalents thereto.

Technology Category: 5