Source: http://sioc-journal.cn/Jwk_yjhx/CN/abstract/abstract346915.shtml
Timestamp: 2019-04-25 07:49:32+00:00

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An iron(Ⅲ)-porphyrin-catalyzed cyclization of ketones with dimethyl sulfoxide (DMSO) and ammonium acetate for the synthesis of unsymmetrical and symmetrical pyridines by employing DMSO as C4 or C6 source has been developed. Various aryl ketone derivatives react readily with DMSO, producing the pyridines in yields of 30%～85%. This method uses non-noble metals and proceeds under mild reaction conditions with operational simplicity, which thus allows the expedient assembly of pyridines from readily available ketones. Based on the preliminary experiments, a plausible mechanism of this transformation is disclosed.
刘玉峰, 曹重仲, 苏淼东, 李慧, 符美强, 刘强, 罗伟平, 郭灿城. 铁卟啉催化酮和二甲亚砜以及醋酸铵的环化反应:吡啶的一步合成[J]. 有机化学, 2019, 39(1): 129-136.	Liu Yufeng, Cao Zhongzhong, Su Miaodong, Li Hui, Fu Meiqiang, Liu Qiang, Luo Weiping, Guo Cancheng. Iron(Ⅲ) Porphyrin Catalyzed Cyclization of Ketones with Dimethyl Sulfoxide and Ammonium Acetate: One-Pot Synthesis of Pyridines. Chin. J. Org. Chem., 2019, 39(1): 129-136.
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