Source: http://www.knochel.cup.uni-muenchen.de/publications/
Timestamp: 2019-04-25 16:14:00+00:00

Document:
1. Knochel, P., Seebach, D. "Nitroallylation par le Nitro-2-pivaloyloxy-3-propene. Un Reactif a2/a2" Nouv. J. Chim. 1981, 5, 75.
2. Knochel, P., Seebach, D. "Nitroallylation of Highly Reactive Organolithium Compunds by 2-Nitro-2-pivaloyloxy-1-1-propene (NPP)" Tetrahedron Lett. 1981, 22, 3223.
3. Kai Y., Knochel P., Kwiatkowski S., Dunitz J.D., Oth J.F.M., Seebach D.* and Kalinowski H.O.,"Structure, Synthesis and Properties of Some Persubstituted 1,2-Dinitroethanes.In Quest of Nitrocyclopropyl-anion Derivatives" Helv. Chim. Acta 1982, 65, 137-161.
4. Knochel P., Seebach D.*, "Synthesis and Reactions of Substituted Nitro-allylating Reagents" Tetrahedron Lett. 1982, 23, 3897-3900.
5. Knochel P., Seebach D.*, "Deshydratisierung von Nitroaldolen mit DCC: Herstellung von Nitro Olefinen unter Milden Bedingungen" Synthesis 1982, 1017-1018.
6. Seebach D.*, Knochel P., "2'-Nitro-2'-propen-l'-yl 2,2-Dimethylpropanoate (NPP). A Multiple Coupling Reagent" Helv. Chim. Acta, 1984, 67, 261-283.
7. Knochel P., Normant J. F., "Addition of Functionalized Allylic Bromides to Terminal Alkynes" Tetrahedron Lett. 1984, 25, 1475-1473.
8. Knochel P., Normant J. F., "The Reactivity of 3-Bromo-2-trimethylsilyl-1-propene Towards Electrophiles. A Short Synthesis of 2-Substituted-4-trimethylsilylfurans" Tetrahedron Lett. 1984, 25, 4383-4386.
9. Seebach D.*, Calderari G., Knochel P., "Trifluoroacetoxy-phenylselenation of Nitroolefins. Regioselective Preparation of Nitroallylic Alcohol Derivatives and Their Use as Multiple Coupling Ragents" Tetrahedron 1985, 41, 4861-4872.
10. Knochel P.*, Normant J. F., "3-Bromo-2-(tert-butylsulfonyl)- 1-propene. A Multi-coupling Reagent, Part 1" Tetrahedron Lett. 1985, 26, 425-428.
11. Auvray P., Knochel P.*, Normant J. F., "3-Bromo-2-(tert-butylsulfonyl)-1-propene. A Multi-coupling Reagent, Part 2" Tetrahedron Lett. 1985, 26, 2329-2332.
12. Auvray P., Knochel P.*, Normant J. F., "5-Endo-trigonal Ring Closures of Unsaturated Sulfones" Tetrahedron Lett. 1985, 26, 4455-4458.
13. Knochel P.*, Normant J. F., "Synthesis and Reactivity of gem-Dimetallic Organic Compounds. Part 1" Tetrahedron Lett. 1986, 27, 1039-1042.
14. Knochel P.*, Normant J. F., "Mixed gem-Dimetallic Organic Compounds. A New Class of Multi-coupling Reagents. Part 2" Tetrahedron Lett. 1986, 27, 1043-1046.
15. P. Knochel*, J. F. Normant, "Copper and Zinc Mixed gem-Dimetallic Organic Compounds" Tetrahedron Lett. 1986, 27, 4427-4430.
16. Knochel P.*, Normant J. F., "Reactivity of 1-Lithia-1-zincaalkenes. Part 4" Tetrahedron Lett. 1986, 27, 4431-4434.
17. Auvray P., Knochel P.*, Normant J. F., "An Easy Synthesis of the 2-Phenylsulfonyl-substituted Allylic Bromides and Acetates and Their Reactivity Toward Nucleophiles" Tetrahedron Lett. 1986, 27, 5095-5098.
18. Auvray P., Knochel P.*, Normant J. F., "An Easy Synthesis of the 2-Phenylsulfonyl-substituted Allylic Bromides and Acetates and Their Reactivity Toward Nucleophiles" Tetrahedron Lett. 1986, 27, 5095-5098.
19. Knochel P.*, Normant J. F., "Diastereoselective Addition of Functionalized Allylic Zinc Bromides to Alkenyl Organometallics. Part 5" Tetrahedron Lett. 1986, 27, 5727-5730.
20. Knochel P.*, Normant J. F., "Synthese de Dienes-1,4- FonctionnalisÃ©s par Addition de Zinciques Allyliques FonctionnalisÃ©s sur des Alcynes vrais et leur Cyclisation en Heterocycles ou Carbocycles" J. Organomet. Chem. 1986, 309, 1-23.
21. Knochel P.*, Yeh M.C.P., Berk S.C., Talbert J., "Synthesis and Reactivity Toward Acyl chlorides and Enones of the New Highly Functionalized Copper Reagents RCu(CN)ZnI" J. Org. Chem. 1988, 53, 2390-2392.
22. Yeh M.C.P. and Knochel P.* "2-Cyanoethylzinc iodide: A New Reagent with Reactivity Umpolung" Tetrahedron Lett. 1988, 29, 2395-2396.
23. Auvray P.,Knochel P.*, Normant J.F. "3-Bromo-2-t-Butysulfonyl-1-propene: A Versatile Multi-coupling Reagent Part I." Tetrahedron 1988, 44, 4495-4508.
24. Auvray P., Knochel P.*, Normant J.F. "3-Bromo-2-1-Butysulfonyl-1-propene: A Versatile Multi-coupling Reagent. Part II." Tetrahedron 1988, 44, 4509-4519.
25. Yeh M.C.P., Knochel, P., Santa, L.E. "The Reaction of the Highly Functionalized Copper Reagents RCu(CN)ZnI.BF3 with Aldehydes" Tetrahedron Lett. 1988, 29, 3887-3890.
26. Auvray P., Knochel P.*, Normant J. F., "Preparation and Nucleophilic Substitution of(E)-1-Bromo-2-Phenylsulfonyl-2-Alkenes and 3-Acetoxy-2-Phenylsulfonyl-1-Alkenes" Tetrahedron 1988, 44, 6095-6106.
27. Chen H.G.; Knochel P.*, "A New Mild Oxidation of Amines to Aldehydes and Ketones. Part II" Tetrahedron Lett. 1988, 29, 6701-6702.
28. Yeh M.C.P.; Knochel P.*; Butler W.M.; Berk S.C. "1,4-Additions of the Highly Functionalized Copper Reagents RCu(CN)ZnI . 2 BF3 to Trisubstituted Enones. A New BF3 Promoted Cyclization Reaction" Tetrahedron Lett. 1988, 29, 6693-6696.
29. Knochel P.*; Xiao C.; Yeh M. C. P. "A Mild Oxidation of 1,1- Diorganometallics to Ketones and Aldehydes. A New Stereoselective Approach to Aldol Products. Part I" Tetrahedron Lett. 1988, 29, 6697-6700.
30. Berk S. C.; Knochel P.*; Yeh M.C.P. "General Approach to Highly Functionalized Benzylic Organometallics of Zinc and Copper" J. Org. Chem. 1988, 53, 5789-5791.
31. Knochel, P.*; Jeong, N.; Rozema, M.J.; Yeh, M.C.P. "Zinc and Copper Carbenoids as Efficient and Selective a1/d1 Multicoupling Reagents. 1." J. Am. Chem. Soc. 1989, 111, 6474-6476.
32. Chen, H.G.; Hoechstetter, C.; Knochel, P.* "Mixed Copper, Zinc 2-Amino Benzylic Organometallics as Efficient Reagents for the Synthesis of Heterocycles" Tetrahedron Lett. 1989, 30, 4795-4798.
33. Yeh M.C.P.; Knochel, P.* "The Reactivity of the Highly Functionalized Copper, Zinc Reagents RCu(CN)ZnI Toward 1-Haloalkynes and Acetylenic Esters" Tetrahedron Lett. 1989, 30, 4799-4802.
34. Knochel, P.*; Yeh, M.C.P.; Xiao, C. "Preparation and Reactivity of Mixed Benzylic 1,1-Dimetalloalkanes" Organometallics 1989, 8, 2831-2835.
35. Majid, T.N.; Yeh, M.C.P.; Knochel, P.* "Synthesis and Reactivity of Open-Chain and Cyclic 2-Cyano Zinc and Copper Organometallics" Tetrahedron Lett. 1989, 30, 5069-5072.
36. Knochel, P.*; Chou, T.-S.; Chen, H.-G.; Yeh, M.C.P.; Rozema, M.J. "Nucleophilic Reactivity of Zinc and Copper Carbenoids. Part II" J. Org. Chem. 1989, 54, 5202-5204.
37. Retherford, C.; Yeh, M,C.P.; Schipor, I.; Chen, H.-G.; Knochel, P.* "The Addition of the Highly Functionalized Zinc, Copper Reagents RCu(CN)ZnI to Nitro Olefins" J. Org.Chem. 1989, 54, 5200-5202.
38. Berk, S.C.; Yeh, M.C.P.; Jeong, N.; Knochel, P.* "Preparation and Reactions of Functionalized Benzylic Organometallics of Zinc and Copper" Organometallics 1990, 9, 3053-3064.
39. Chen, H.G.; Gage, J.L.; Barrett, S.D., Knochel, P.* "SN2' Substitutions of 1,3-Dichloropropenes with the Functionalized Copper-Zinc Reagents RCu(CN)ZnX" Tetrahedron Lett. 1990, 31, 1829-1832.
40. Retherford, C.; Chou, T.-S.; Schelkun, R.M.; Knochel, P.* "Preparation and Reactivity of Zinc and Copper Phosphonates" Tetrahedron Lett. 1990, 31, 1833-1836.
41. Tucker, C.E.; Achyutha Rao, S.; Knochel, P.* "The Olefination of Functionalized Alkylidene Malonates by 1,1-Dimetalloalkanes: A New Chemo- and Stereoselective Preparation of Functionalized Olefins" J. Org. Chem. 1990, 55, 5446-5448.
42. Knochel, P.*, Achyutha Rao, S. "A Direct Conversion of Vinylic Organocopper Compounds to Allylic Zinc and Copper Organometallics" J. Am. Chem. Soc. 1990, 112, 6146-6148.
43. Chou, T.-S., Knochel, P.* "A General Preparation of Highly Functionalized Zinc and Copper Organometallics at the Alpha Position to an Oxygen" J. Org. Chem. 1990, 55, 4791-4793.
44. Knochel, P.* "A New Approach to Boron-Stabilized Organometallics" J. Am. Chem. Soc. 1990, 112, 7431-7433.
45. Majid, T.N.; Knochel, P.* "A New Preparation of Highly Functionalized Aromatic and Heteroaromatic Zinc and Copper Organometallics" Tetrahedron Lett. 1990, 31, 4413-4416.
46. AchyuthaRao, S.; Tucker, C. E.; Knochel, P.* "Preparation of Functionalized Zinc and Copper Organometallics Containing Sulfur Functionalities at the Alpha or Gamma Position" Tetrahedron Lett. 1990, 31, 7575-7578.
47. Auvray, P.; Knochel, P.; Vaissermann, J.; Normant*, J.F., "Diastereoselective Reaction of (E)-1-Bromo-2-phenylsulfonylalk-2-enes with Aldehydes in the Presence of Zinc or Chromium (II) Salts" Bull Soc. Chim. Fr. 1990, 813-823.
48. Yeh, M. C. P.; Chen, H. G.; Knochel, P. * "1,2-Addition of a -Unsaturatedb,aFunctionalized Zinc and Copper Organometallic (RCu(CN)ZnI) to an Aldehyde: (1H-Isoindole-1,3(2H)-dione,2-(4-hydroxy-6-phenyl-5-hexenyl),(E)-)" Org. Synth. 1991, 70, 195-203.
49. Retherford, C.; Knochel, P.* "Highly Stereoselective Preparation of Nitro Olefins and Nitro-Dienes by the Addition-Elimination of Copper-Zinc-Organometallics to Î²-Alkylthio and Î²-Phenylsulfonyl Nitro Olefins" Tetrahedron Lett. 1991, 32, 441-444.
50. AchyuthaRao, S.; Knochel, P.* "Stereospecific Preparation of Polyfunctional Olefins by the Carbometallation of Alkynes with Polyfunctional Zinc-Copper Organometallics. Stereospecific Preparation of Five-Membered Carbocycles by Intramolecular Carbocupration" J. Am. Chem. Soc. 1991, 113, 5735-5741.
51. Rozema, M.J.; Knochel, P.* "Selective Multiple Methylene Insertion Reactions Mediated by Iodomethylzinc Iodide: Mechanistic Considerations and Synthetic Applications" Tetrahedron Lett. 1991, 32, 1855-1858.
52. Janakiram Rao, C.; Knochel, P.*, "A Direct Preparation of Vinylogous Acyl Anion Equivalents" J. Org. Chem. 1991, 56, 4593-4596.
53. AchyuthaRao, S.; Knochel, P.*, "1, n-Heterometallic Reagents of Zinc and Copper: A New Class of Multi-coupling Reagents" J. Org. Chem. 1991, 56, 4591-4593.
54. Tucker, C.E.; Knochel, P.* "A Highly Stereoselective Olefination of Aldehydes Mediated by New Zinc and Zirconium 1,1-Bimetallic Reagents" J. Am. Chem. Soc. 1991, 113, 9888-9890.
55. Knoess, H.P.; Furlong, M.T.; Rozema, M.J.; Knochel, P.* "Preparation and Reactions of Zinc and Copper Organometallics Bearing Acidic Hydrogens" J. Org. Chem. 1991, 56, 5974-5978.
56. AchyuthaRao, S.; Chou, T.-S.; Schipor, I.; Knochel, P.*, "Preparation of Functionalized Zinc and Copper Organometallics Containing Sulfur Functionalities at the Alpha or Gamma Position" Symposium in print, Tetrahedron 1992, 48, 2025-2043.
57. Rozema, M.J.; AchyuthaRao, S.; Knochel, P.* "Preparation of Functionalized Dialkylzinc Reagents via an Iodine-Zinc Exchange Reaction. Highly Enantioselective Synthesis of Functionalized Secondary Alcohols" J. Org. Chem. 1992, 57, 1956-1958.
58. Tucker, C.E.; Davidson, J.; Knochel, P.* "Mild and Stereoselective Hydroborations of Functionalized Alkynes and Alkenes Using Pinacolborane" J. Org. Chem. 1992, 57, 3482-3485.
59. Tucker, C.E.; Majid, T.N.; Knochel, P.* "Preparation of Highly Functionalized Magnesium, Zinc and Copper Aryl and Alkenyl Organometallics via the Corresponding Organolithiums" J. Amer.Chem.Soc. 1992, 114, 3983-3985.
60. Belyk, K.; Rozema, M.J.; Knochel, P.* "Preparation of Polyfunctional Allenic Alcohols by the Regioselective Addition of Functionalized Propargylic Chromium (III) Organometallics to Carbonyl Compounds" J.Org.Chem. 1992, 57, 4070-4074.
61. Rozema, M.J.; Rajagopal, D.; Tucker, C.E.; Knochel, P.* "Preparation of Polyfunctional Diorganomercurials and their transmetallation to Diorganozincs. Application to the Preparation of Optically Active Secondary Alcohols" J. Organomet. Chem. 1992, 438, 11.
62. Jubert, C.; Knochel, P.* "Preparation of New Classes of Aliphatic, Allylic and Benzylic Zinc and Copper Reagents by the Insertion of Zinc Dust into Organic Halides, Phosphates and Sulfonates" J.Org.Chem. 1992, 57, 5425-5431.
63. Jubert, C.; Knochel, P*. "Preparation of Polyfunctional Nitro Olefins and Nitroalkanes Using the Copper-Zinc Reagents RCu(CN)ZnI" J.Org.Chem. 1992, 57, 5431-5438.
64. S. AchyuthaRao, P. Knochel*, "New Preparation of Butyrolactones Mediated by Iodomethylzinc Iodide" J. Am. Chem. Soc. 1992, 114, 7579-7581.
65. Jubert, C.; Nowotny, S.; Kornemann, D.; Antes, I.; Tucker, C. E.; Knochel, P.* "Stereodivergent Additions of Allylic Chromium (III) Reagents to Aldehydes" J. Org. Chem. 1992, 57, 6384-6386.
66. Venegas, P.; Cahiez, G.*; Tucker, C. E.; Majid, T. N.; Knochel, P.* "Additions of Polyfunctional and Pure (E or Z) Alkenylcoppers and Arylcopper to Alkylidenemalonates" J. Chem. Soc.; Chem. Commun. 1992, 1406-1408.
67. Waas, J.R.; Sidduri, A.; Knochel, P.* "Preparation and Reactions of 1,1- Zinc, Boron and, 1,1- Copper, Boron Alkenyl Bimetallics: A New Class of d1- Reagents" Tetrahedron Lett. 1992, 33, 3717-3720.
68. Sidduri, A.; Budrys, N.; Laine, R. M.*; Knochel, P.* "Preparation of Highly Funtionalized 3,4-Disubstituted Cyclobutene 1,2-Diones Using Functionalized Zinc-Copper Organometallics" Tetrahedron Lett. 1992, 33, 7515-7518.
69. Stemmler, T.; Penner-Hahn, J. E.*; Knochel, P.* "Structural Characterization of Organocopper Reagents by EXAFS Spectroscopy" J. Am. Chem. Soc. 1993, 115, 348-350.
70. JanikaramRao, C.; Knochel, P.*,"Preparation and Reactivity of Functionalized Alkenyl-Zinc, -Copper, and Chromium Organometallics" Tetrahedron 1993, 49, 29-48.
71. Knochel, P.*; Chou, T.-S.; Jubert, C.; Rajagopal, D., "Preparation of Highly Functionalized Organometallics at The Alpha Position of Oxygene or Nitrogen" J. Org.Chem. 1993, 58, 588-599.
72. S. AchyuthaRao; Rozema, M.J.; Knochel, P.*, "Selective Mono- and Poly- Methylene Homologations of Copper Reagents Using (Iodomethyl) zinc iodide" J. Org. Chem. 1993, 58, 2694-2713.
73. Rozema, M.J.; Eisenberg, C.; LÃ¼tjens, H.; Ostwald, R.; Belyk, K.; Knochel, P.* " Enantioselective Preparation of Polyfunctional Secondary Allylic Alcohols Using Functionalized Dialkylzincs Prepared by a Copper(I) Catalyzed Iodine-Zinc Exchange Reaction" Tetrahedron Lett. 1993, 34, 3115-3118.
74. Tucker, C.E.; Knochel, P.* "Preparation of Functionalized Z-Olefins using 1,1-Dimetalloalkanes" Synthesis 1993, 530-536.
75. Brieden, W., Ostwald, R., Knochel, P.* "Enantioselective Catalytic Addition of Functionalized Dialkylzinc compounds to Î²-Stannylated Aldehydes. A Simple Method of preparing nonracemic Î²- and Î³-functionalized secondary alcohols" Angew.Chem. 1993, 105, 629-631.
76. Knochel, P.*; Brieden, W.; Eisenberg, C., Rozema, M.J. "A New Catalytic Approach of Polyfunctional Aldol Products Mediated by Zinc Organometallics" Tetrahedron Lett. 1993, 34, 5881-5884.
77. StadtmÃ¼ller, H.; Lentz, R.; DÃ¶rner, W., StÃ¼demann, T., Tucker C. E., Knochel, P.* "Palladium-Catalyzed Iodine-Zinc Exchange Reactions. A New Palladium-Mediated Intramolecular Carbozincation of Alkenes" J. Am. Chem. Soc. 1993, 115, 7027-7028.
78. Klement, I.; Lennick, K., Tucker, C.E., Knochel, P.*,"Preparation of Polyfunctional Nitriles by the Cyanation of Functionalized Organozinc Halides with p-Toluenesulfonyl Cyanide" Tetrahedron Lett. 1993, 34, 4623-4626.
79. Langer, F., Waas, J.R.; Knochel, P.* "Preparation and Reactions of New Dialkylzincs Obtained by a Boron-Zinc Transmetalation" Tetrahedron Lett. 1993, 34, 5261-5264.
80. Tucker, C.E.; Knochel, P.* "Cross-Coupling Between Functionalized Alkylcopper Reagents and Functionalized Alkyl Halides" J. Org. Chem. 1993, 58, 4781-4782.
81. Semmelhack, M. F.*; Singleton, T.; Knochel, P. "A New Approach to Indole Alkaloids Via Indole Chromium Complexes" Tetrahedron Lett. 1993, 34, 5051-5054.
82. StadtmÃ¼ller, H.; Tucker, C.E.; Vaupel, A.; Knochel, P.* "Stereoselective Synthesis of Polyfunctionlized Di- and Trisubstituted Cyclopentane Derivatives using a New Palladium Catalyzed Cyclization." Tetrahedron Lett. 1993, 34, 7911-7914.
83. Tucker, C. E., Greve, B., Klein, W., Knochel, P.* "Preparation of Polyfunctional Olefins and Allenes Using 1,1-Bimetallics of Zinc and Zirconium." Organometallics 1994, 13, 94-101.
84. FÃ¼rstner, A.*, Singer, R., Knochel, P.* "A convenient Preparation of Functionalized Arylzinc Compounds by the Reaction of Zinc/Silver-Graphite with Aryl Iodides." Tetrahedron Lett. 1994, 35, 1047-1050.
85. Rajagopal, D.; Eckhardt, M; Furlong, M. Knoess, H. P., Berger, S., Knochel, P.* "Preparation and Reactivity of Chiral Related Configurationally Stable Zinc Organometallics" Tetrahedron 1994, 50, 2415-2432.
86. Klement, I., Chau, K., Cahiez, G.*, Knochel, P.* "Preparation of Alkylzinc Bromides Using a New Mn/Cu catalyzed Bromine-Zinc Exchange Reaction" Tetrahedron Lett. 1994, 35, 1177-1180.
87. Ostwald, R.; Chavant, P.-Y., StadtmÃ¼ller, H.; Knochel, P.* "Catalytic Asymmetric Addition of Polyfunctional Dialkylzincs to Î²-Stannylated and Î²-Silylated Unsaturated Aldehydes" J. Org. Chem. 1994, 59, 4143-4153.
88. Langer, F.; Devasagayaraj, A.; Chavant, P.-Y.; Knochel, P.* "Preparation of New Polyfunctional Diorganozincs Using a Boron-Zinc Exchange Reaction" Synlett 1994, 410-412.
89. LÃ¼tjens, H.; Knochel, P.* "Enantioselective Preparation of a C3-Symmetrical Triol" Tetrahedron: Asymmetry, 1994, 5, 1161-1162.
90. Eisenberg, C.; Knochel, P.* "Catalytic Asymmetric Preparation of Polyfunctional Protected 1,2-Diols and Epoxides" J. Org. Chem. 1994, 59, 3760-3761.
91. Nowotny, S.; Vettel, S.; Knochel, P.* "Dramatic Titanium Alkoxide Effect in the Catalytic Enantioselective Addition of Dialklyzincs to Aldehydes" Tetrahedron Lett. 1994, 35, 4539-4549.
92. Vettel, S.; Knochel, P.* "Enantioselective Preparations of C2-Symmetrical 1,4-Diols" Tetrahedron Lett. 1994, 35, 5849-5852.
93. Vaupel, A.; Knochel, P.* "Stereoselective Synthesis of Substituted Tetrahydrofurans and Butyrolactones by a New Nickel Catalyzed Carbozincation" Tetrahedron Lett. 1994, 35, 8349-8352.
94. Marquais, S.; Cahiez, G.*; Knochel, P.* "Stereospecific Synthesis of Polyfunctional Alkenes by the Cross-Coupling of Functionalized Zinc-Copper Reagents with Alkenyl Iodides" Synlett 1994, 849-850.
95. Schwink, L.; Knochel, P.* "Catalytic Asymmetric Reductive Addition of Olefins to Aldehydes Mediated by Boron and Zinc Organometallics" Tetrahedron Lett. 1994, 35, 9007-9010.
96. StadtmÃ¼ller, H.; Greve, B.; Lennick, K.; Chair, A.; Knochel, P.* "Preparation of Secondary Alkyl and Benzylic Zinc Bromides Using Activated Zinc Metal Deposited on Titanium Oxide." Synthesis 1995, 69-72.
97. Vaupel, A.; Knochel, P.* "A Short Formal Synthesis of (-)-Methylenolactocin via a Nickel Catalyzed Intramolecular Carbozincation" Tetrahedron Lett. 1995, 36, 231-232.
98. Berninger, J.; Koert, U.*, Eisenberg-HÃ¶hl, C.; Knochel, P.* "Funktionalisierte Diorganozinkverbindungen: SchlÃ¼sselreagenzien zur Synthese von Enantiomerenreinen 2,5-Disubstituierten Cis- und Trans-Tetrahydrofuranen" Chem. Ber. 1995, 128, 1021-1028.
99. Nowotny, S.; Tucker, C. E.; Jubert, C.; Knochel, P.* "Chromium (II) Mediated Stereodivergent Additions of Allylic Phosphates and Halides to Aldehydes" J. Org. Chem. 1995, 60, 2762-2772.
100. Vettel, S.; Vaupel, A.; Knochel, P.* "A New Preparation of Diorganozincs from Olefins via a Nickel Catalyzed Hydrozincation" Tetrahedron Lett. 1995, 36, 1023-1026.
101. Devasagayaraj, A.; Schwink, L.; Knochel, P.* "Preparation and Reactions of Diorganozincs from Dienic Silyl Enol Ethers" J. Org. Chem. 1995, 60, 3311-3317.
102. StadtmÃ¼ller, H.; Knochel, P.* "Asymmetric Synthesis of (+)-Methyl Jasmonate and (-)-Methyl Curcurbate Using a New Nickel Catalyzed Carbozincation" Synlett 1995, 463-464.
103. Langer, F.; Knochel, P.* "New Efficient Preparation of Polyfunctional phosphines Using Zinc Organometallics" Tetrahedron Lett. 1995, 36, 4591-4594.
104. StadtmÃ¼ller, H.; Knochel, P.* "A New Synthesis of Functionalized Chromium Carbene Complexes Using Zinc Organometallics" Organometallics 1995, 14, 3163-3166.
105. Klement, I.; LÃ¼tjens, H.; Knochel, P.* "Oxidation of Zinc Organometallics Prepared by Hydrozincation or Carbozincation Using Oxygen" Tetrahedron Lett. 1995, 36, 3161-3164.
106. DÃ¶tz, K. H.*; Christoffers, C.; Knochel, P.* "Reaktionen von Komplexliganden LXIII. Diethylzinc-induzierte Dimerisierung von Alkinylcarbenliganden: Regioselektive Synthese eines Cyclopentenyliden-Komplexes" J. Organomet. Chem. 1995, 489, C84-C86.
107. Klement, I. and Knochel, P.* "Selective Oxidation of Zinc Organometallics to Hydroperoxides Using Oxygen in Perfluorohexanes" Synlett 1995, 1113-1114.
108. Schwink, L.; Vettel, S., Knochel, P.* "A New Approach to Chiral Cyclopentadienyl Metal Complexes" Organometallics 1995, 14, 5000-5001.
109. Devasagayaraj, A.; StÃ¼demann, T.; Knochel, P. "A New Nickel Catalyzed Cross-Coupling Reaction between Csp3-Csp3 Centers; Mechanistic and Synthetic Studies" Angew. Chem. 1995, 107, 2952-2954; Angew. Chem. Int. Ed. Engl. 1995, 34, 2723-2725.
110. LÃ¼tjens, H.; Nowotny, S.; Knochel, P.* "New Enantioselective Syntheses of Acetylenic Alcohols Using Functionalized Diorganozincs" Tetrahedron: Asymmetry 1995, 6, 2675-2678.
111. Stemmler, T. L.; Barnhart, T. M.; Penner-Hahn, J. E.*, Tucker, C. E.; Knochel, P.*, BÃ¶hme, M.; Frenking, G.* "Structural Characterization of Organocuprate reagents. EXAFS Spectroscopy and Ab Initio Calculation" J. Am. Chem. Soc. 1995, 117, 12489-12497.
112. Devasagayaraj, A.; Knochel, P.* "Preparation of Polyfunctional Ketones by a Cobalt (II) Mediated Carbonylation of Organozinc Reagents" Tetrahedron Lett. 1995, 36, 8411-8414.
113. Klement, I.; RottlÃ¤nder, M.; Tucker, C. E.; Majid, T. N.; Knochel, P.*, Venegas, P.; Cahiez, G.* "Preparation of Polyfunctional Aryl and Alkenyl Zinc Halides from Functionalized Unsaturated Organolithiums and their Reactivity in Cross-Coupling and Conjugated Addition Reactions" Tetrahedron 1996, 52, 7201-7220.
114. Eick, H.; Knochel, P.* "The Preparation of 1,3-Dizinc Organometallics via a Boron-Zinc Exchange" Angew. Chem. 1996, 108, 229-231; Angew. Chem. Int. Ed. Engl. 1996, 35, 218-220.
115. Schwink, L.; Knochel, P.* "A New Practical Asymmetric Synthesis of C2-Symmetrical 1,1'-Ferrocene Diols via CBS-Reduction" Tetrahedron Lett. 1996, 37, 25-28.
116. Longeau, A.; Langer, F.; Knochel, P.* "Preparation and Reactions of Functionalized Chlorodiorganophine-Borane Complexes Using Organozinc Reagents" Tetrahedron Lett. 1996, 37, 2209-2212.
117. StadtmÃ¼ller, H.; Vaupel, A.; Tucker, C. E.; StÃ¼demann, T.; Knochel, P.* "Stereoselective Preparation of Polyfunctional Cyclopentane Derivatives via a Radical Nickel or Palladium Catalyzed Carbozincation" Chem. Eur. J. 1996, 2, 1204-1220.
118. Reddy, K.; Knochel, P.* "New Cobalt and Iron Catalyzed Reactions of Organozincs" Angew. Chem. 1996, 108, 1812-1813; Angew. Chem. Int. Ed. Engl. 1996, 35, 1700-1701.
119. RottlÃ¤nder, M.; Palmer, N.; Knochel, P.* "Selective Pd (0)-Catalyzed Arylations Using New Electrophilic or Nucleophilic Multi-Coupling Reagents" Synlett, 1996, 573-575.
120. Vaupel, A.; Knochel, P.* "Stereoselective Synthesis of Heterocyclic Zinc Reagents via A Nickel Catalyzed Radical Cyclization" J. Org. Chem. 1996, 61, 5743-5753.
121. Vettel, S.; Vaupel, A.; Knochel, P.* "Nickel-Catalyzed Preparations of Functionalized Organozincs" J. Org. Chem. 1996, 61, 7473-7481.
122. Klement, I.; Knochel, P.* "Direct Oxidation of Organoboranes with Oxygen in Perfluoroalkenes" Synlett 1996 1004-1006.
123. Reddy, Ch. K.; Devasagayaraj, A.; Knochel, P.* "Uncatalyzed Conjugate Additions of Diorganozincs in NMP" Tetrahedron Lett. 1996, 37, 4495-4498.
124. Vettel, S.; Lutz, C.; Knochel, P.* "Enantioselective Synthesis of Protected Î±-Hydroxy Aldehydes and Related 1,2-Amino Alcohols. Applications to the Synthesis of (-)-Exo- and (-)-Endo-Brevicomin", Synlett 1996, 731-733.
125. Langer, F.; Schwink, L.; Devasagayaraj, A.; Chavant, P.-Y., Knochel, P.* "Preparation of Functionalized Dialkylzincs via a Boron-Zinc Exchange. Reactivity and Catalytic Asymmetric Addition to Aldehydes" J. Org. Chem. 1996, 61, 8229-8243.
126. Riguet, E.; Klement, I.; Reddy, K. Ch.; Cahiez, G.*; Knochel, P.* "New Mixed Metal (Mn/Cu) Catalyzed Stereoselective Cyclizations" Tetrahedron Lett. 1996, 37, 5865-5868.
127. Longeau, A.; Knochel, P.* "Lithiated bis Diethylaminophosphine Borane Complex as Useful Nucleophilic Phosphorus reagents" Tetrahedron Lett. 1996, 37, 6099-6102.
128. Stevenson, T.; Prasad, B. A. S.; Citineni, J. R.; Knochel, P. "Preparation of Zinc Organometallics Derived from Nucleosides and Nucleic Acid Bases and Pd(0) Catalyzed Coupling with Aryl Iodides" Tetrahedron Lett. 1996, 37, 8375-8378.
129. PÃ¼ntener, K.; Schwink, L.; Knochel, P.* "New Efficient Catalysts for Enantioselective Transfer Hydrogenations" Tetrahedron Lett. 1996, 37, 8165-8168.
130. StÃ¼demann, T.; Knochel, P.* "New Nickel Catalyzed Carbozincation of Alkynes. A Short Synthesis of (Z)-Tamoxifen" Angew. Chem. 1997, 109, 132-134; Angew. Chem. Int. Ed. Engl. 1997, 36, 93-95.
131. Langer, F.; PÃ¼ntener, K.; StÃ¼rmer, R.; Knochel, P.* "Preparation of Polyfunctional Phosphines using Zinc Organometallics" Tetrahedron: Asymmetry, 1997, 8, 715-738.
132. Micouin, L.; Oestreich, M.; Knochel, P.* "Stereoselective Preparation and Reactions of Secondary Cyclic Zinc Organometallics" Angew. Chem. 1997, 109, 274-276; Int. Ed. Engl. 1997, 36, 245-246.
133. StÃ¼demann, T.; Gupta, V.; Engman, L.; Knochel, P.* "Nickel Catalyzed Tellurium-Zinc Exchange Reactions. A New Preparation of Diarylzincs" Tetrahedron Lett. 1997, 38, 1005-1008.
134. Micouin, L.; Knochel, P.* "Iodine-Zinc Exchange Mediated by i-Pr2Zn. A New Preparation of Secondary Zinc Reagents" Synlett, 1997, 327-328.
135. Klement, I.; LÃ¼tjens, H.; Knochel, P. "Chemoselective Oxidation of Organozinc Reagents with Oxygen" Tetrahedron 1997, 57, 9135-9144.
136. Longeau, A.; Durand, S.; Spiegel, A.; Knochel, P. "Synthesis of New C2-Symmetrical Diphosphines Using Chiral Zinc Organometallics" Tetrahedron: Asymmetry 1997, 8, 987-990.
137. RottlÃ¤nder, M.; Knochel, P. "New Multi-Coupling Benzylic Zinc Reagents for the Preparation of Flexible Aromatic Compounds" Tetrahedron Lett. 1997, 38, 1749-1752.
138. Schwink, L.; Knochel, P. "New Chiral Ferrocenyl Building Blocks for Asymmetric Reactions" Tetrahedron Lett. 1997, 38, 3711-3714.
139. Berger, S.; Langer, F.; Lutz, C.; Knochel, P.; Mobley, T. A.; Reddy, Ch. K., "Mixed -Silyl Diorganozincs; a New Class of Useful Zinc Reagents" Angew. Chem. 1997, 109, 1603-1605; Angew. Chem. Int. Ed. Engl. 1997, 36, 1496-1498.
140. Vettel, S.; Lutz, C.; Diefenbach; G.; Haderlein, S.; Hammerschmidt, S.; KÃ¼hlung, K.; Mofid, M.-R.; Zimmermann, T.; Knochel, P., "Catalytic Asymmetric Synthesis of Protected -Hydroxy Aldehydes and Related 1,2-Difunctional Chiral Building Blocks. An enantioselective Synthesis of (-)-exo and (-)-endo-Brevicomin" Tetrahedron: Asymmetry 1997, 8, 779-800.
141. Klement, I.; LÃ¼tjens, H.; Knochel, P.* "Transition Metal Catalyzed Oxidations in Perfluorinated Solvents" Angew. Chem. 1997, 109, 1605-1607; Angew. Chem. Int. Ed. Engl. 1997, 36, 1454-1456.
142. Prasad, A. S. B.; Stevenson, T. M.; Citineni, J. R.; Nyzam, V.; Knochel, P.*, "Preparation and Reactions of New Zincated Nitrogen-Containing Heterocycles" Tetrahedron 1997, 53, 7237-7254.
143. Lutz, C.; Knochel, P. "Highly Enantioselective Addition of Mixed Diorganozincs to Aldehydes" J. Org. Chem. 1997, 62, 7895-7998.
144. Klement, I.; StadtmÃ¼ller, H.; Knochel, P.; Cahiez, G. "Preparation and Reactivity of Functionalized Aryl and Alkenylmanganese Halides" Tetrahedron Lett. 1997, 38, 1927-1930.
145. CerÃ¨, V.; De Angelis, S.; Pollicino, S.; Ricci, A.; Kishan, Ch, R., Knochel, P.; Cahiez, G. "Preparation of 2-Zinc-1,3-Dithianes and of Di(1,3-dithianyl)zinc and their Reactivity with Highly Functionalized Halides and with Î±,Î²-Unsaturated Carbonyl Compounds" Synthesis, 1997, 1174-1178.
146. LÃ¼tjens, H.; Wahl, G.; Sundermeyer, J.*; Knochel, P.* "New Chiral C3-Symmetric Triols as Ligands for Vanadium and Titanium Complexes" Organometallics 1997, 16, 5869-5878.
147. RottlÃ¤nder, M.; Knochel, P.* "Multiple Cross-Coupling Reactions of Aryl and Benzylic Zinc Halides in Solid-Phase Synthesis of Polyfunctional Aromatics" Synlett 1997, 1084-1086.
148. Almena Perea, J. J.; Ireland, T.; Knochel, P.* "Substitution of Ferrocenyl Acetates with Organozincs. An enantioselective Preparation of Polyfunctional Chiral Ferrocenes" Tetrahedron Lett. 1997, 38, 5961-5964.
149. Betzemeier, B.; Knochel, P.* "Palladium Catalyzed Cross-Coupling of Organozinc Halides with Aryl Iodides in Perfluorinated Solvents" Angew. Chem. 1997, 109, 2736-2739; Angew. Chem. Int. Ed. Engl. 1997, 36, 2623-2624.
150. Prasad, A. S. B.; Knochel, P.* "Preparation and Reactions of 2-Zincated 2-Cyclohexen-1-one and Related Heterocycles" Tetrahedron, 1997, 53, 16711-16720.
151. Jones, P.; Reddy, K. C.; Knochel, P.* "Conjugate Michael-Addition with Mixed Diorganozincs" J. Chem. Soc., 1997, 3117-3118.
152. StÃ¼demann, T.; Ibrahim-Ouali, M., Knochel, P.* "A Nickel-Catalyzed Carbozincation of Aryl substituted Alkynes" Tetrahedron-Symposium 1998, 54, 1299-1316.
153. RottlÃ¤nder, M.; Knochel, P.* "Palladium Catalyzed Cross-Coupling Reactions with Aryl Nonaflates. A Practical Alternative to Aryl Triflates" J. Org. Chem. 1998, 63, 203-208.
154. Lhermitte, F.; Knochel, P.* "Stereoselective Allylic C-H Activation using Tertiary Alkylboranes. A New Method for the Preparation of Cyclopentane Derivatives with three Adjacent Stereocenters" Angew. Chem. 1998, 110, 2598-2599; Angew. Chem. Int. Ed. Engl. 1998, 37, 2460-2461.
155. StÃ¼demann, T.; Ibrahim-Ouali, M.; Cahiez, G.*; Knochel, P.* "Stereoselective Nickel and Manganese Catalyzed Cyclizations of 5-Haloketones" Synlett 1998, 143-144.
156. Schwink, L.; Knochel, P.* "Enantioselective Preparation of C2-symmetrical Ferrocenyl Ligands for Asymmetric Catalysis" Chem. Eur. J. 1998, 4, 950-968.
157. Darcel, C.; Flachsmann, F.; Knochel, P.* "Stereoselective Preparation and Reactions of Configurationally Defined Mixed Acyclic Dialkylzincs" J. Chem. Soc.; Chem. Commun. 1998, 205-206.
158. Prasad, A. S. B.; Eick, H.; Knochel, P.* "The Preparation of 1,3-Dizincapropanes via a Boron-Zinc Transmetalation" J. Organomet. Chem. 1998, 562, 133-139.
159. Schwink, L.; Ireland, T.; PÃ¼ntener, K.; Knochel, P. "New C2-Symmetrical Ferrocenyl Diamines as Ligands for Ruthenium Catalyzed Transfer Hydrogenation" Tetrahedron: Asymmetry 1998, 9, 1143-1163.
160. Schwink, L.; Knochel, P.*; Eberle, T.; Okuda, J.* "Synthesis of Chiral Bridging Î²-Amino-Cyclopentadienes and Their Complexation to Transition Metals" Organometallics 1998, 17, 7-9.
161. Jones, P.; Reddy, C. K.; Knochel, P.* "Conjugate Michael Additions with Mixed Diorganozincs" Tetrahedron, 1998, 54, 1471-1490.
162. Lutz, C.; Graf, C.-D.; Knochel, P.* "New Strategy for the Preparation of Nitrogen- and Phosphorus Containing Chiral Polyfunctional Secondary Alcohols" Tetrahedron 1998, 54, 10317-10328.
163. Boymond, L.; RottlÃ¤nder, M.; Cahiez, G.*, Knochel, P.* "Preparation of Highly Functionalized Grignard Reagents via an Iodine-Magnesium Exchange Reaction. Applications to Solid Phase Synthesis" Angew. Chem. 1998, 110, 1801-1804; Angew. Chem. Int. Ed. Engl. 1998, 37, 1701-1703.
164. Lutz, C.; Lutz, V.; Knochel, P. "Enantioselective Synthesis of 1,2-, 1,3- and 1,4-Aminoalcohols by the Addition of Dialkylzincs to 1,2-, 1,3- and 1,4-Aminoaldehydes" Tetrahedron 1998, 54, 6385-6402.
165. Giovannini, R.; StÃ¼demann, T.; Dussin, G.; Knochel, P.* "A New Efficient Nickel-Catalyzed Cross-Coupling Between Csp3-Centers" Angew. Chem. 1998, 110, 2512-2515; Angew. Chem. Int. Ed. Engl. 1998, 37, 2387-2390.
166. Avedissian, H.; BÃ©rillon, L.; Cahiez, G.*; Knochel, P.* "Cobalt Catalyzed Alkenylation of Zinc Organometallics" Tetrahedron Lett. 1998, 39, 6163-6166.
167. Graf, C.-D.; Malan, C.; Knochel, P.* "New Chiral Ligands with Non-stereogenic Chirotopic Centers for Asymmetric Synthesis" Angew. Chem. 1998, 110, 3215-3218; Angew. Chem. Int. Ed. Engl. 1998, 37, 3014-3016.
168. Betzemeier, B.; Lhermitte, F.; Knochel, P.* "Wacker Oxidation Using a Fluorous Biphasic System. A Mild Preparation of Polyfunctional Ketones" Tetrahedron Lett. 1998, 39, 6667-6670.
169. BÃ©rillon, L; Wagner, R.; Knochel, P.* "Preparation and Reactions of Zincated Thymine Derivatives" J. Org. Chem. 1998, 63, 9117-9121.
170. BÃ©rillon, L.; LeprÃªtre, A., Turck, A.; PlÃ©, N.; Queguiner, G.;* Cahiez, G.; Knochel, P.* "Preparation of Highly Functionalized Pyridylmagnesium Reagents for the Synthesis of Polyfunctional Pyridines" Synlett 1998, 1359-1360.
171. Giovannini, R.; Knochel, P* "Ni (II)-Catalyzed Cross-Coupling Between Polyfunctional Arylzinc Derivatives and Primary Alkyl Iodides" J. Am. Chem. Soc. 1998, 120, 11186-11187.
172. Jones, P.; Millot, N.; Knochel, P.* "Masked Allylic Zinc Reagents" Chem. Commun. 1998, 2405-2406.
173. Jones, P.; Knochel, P. "Highly Diastereoselective Reactions Using Masked Allylic Zinc Reagents" Chem. Commun. 1998, 2407-2408.
174. Almena Perea, J. J.; BÃ¶rner, A.; Knochel, P.* "A Versatile Approach to New Chiral C2-symmetrical Ferrocenyl Ligands: Highly Enantioselective Rh-Catalyzed Hydrogenation of Î±-Acetamidoacrylic Acid Derivatives" Tetrahedron Lett. 1998, 39, 8073-8076.
175. Boudier, A.; Flachsmann, F.; Knochel, P.* "Stereoselective Preparation of Chiral Secondary Cycloalkyl- and Alkyl-Zinc Reagents" Synlett 1998, 39, 1438-1440.
176. RottlÃ¤nder, M.; Boymond, L., Cahiez, G.*; Knochel, P.* "Stereoselective Preparation of Functionalized Alkenylmagnesium Reagents via an Iodine-Magnesium Exchange Reaction" J. Org. Chem. 1999, 64, 1080-1081.
177. DÃ¼bner, F.; Knochel, P.* "Copper (I) Catalyzed Allylation of Allylic Chlorides with Diorganozincs" Angew. Chem. 1999, 111, 391-393; Angew. Chem. Int. Ed. Engl. 1999, 38, 379-381.
178. Giovannini, R.; Knochel, P.* "A New Efficient Nickel-Catalyzed Cross-Coupling reaction between two Csp3-Centers" J. Org. Chem. 1999, 64, 3544-3553.
179. Lutz, C.; Jones, P.; Knochel, P.* "Neopentyl- and Neophyl-Groups: New Non-Transferable Groups for Organocopper and Organozinc Chemistry" Synthesis, 1999, 312-316.
180. Jones, P.; Knochel, P.* "Preparation and Reactions of New Masked Allylic Organozinc Reagents" J. Org. Chem. 1999, 64, 186-195.
181. Boudier, A.; Knochel, P.* "Palladium Catalyzed Stereoselective Cross-Couplings and Acylations of Chiral Secondary Diorganozincs" Tetrahedron Lett. 1999, 40, 687-690.
182. Ireland, T.; Almena, J. J.; Knochel, P.* "Synthesis and Stereoselective Reactions of New Stable Ferrocenyllithium Derivatives. An Umpolung of the Ferrocene Reactivity" Angew. Chem. 1999, 111, 1560-1562; Angew. Chem. Int. Ed. Engl. 1999, 38, 1457-1460.
183. Graf, C.-D.; Knochel, P.* "Asymmetric Hydroboration with New Chiral Monoalkylboranes bearing a Non-Stereogenic, Chirotopic Center" Tetrahedron 1999, 55, 8801-8814.
184. RottlÃ¤nder, M.; Knochel, P.* "Synthesis of 2,4-Disubstituted 2,5-Dihydrofurans and 1-Substituted 1,3-Dihydroisobenzofurans via an Iodine-Magnesium Exchange Reaction" J. Comb. Chem. 1999, 1, 181-183.
185. Almena Perea, J. J.; Lotz, M.; Knochel, P.* "Synthesis and Application of C2-Symmetrical Ferrocenyl Diamino Diphosphine as Ligands for Enantioselective Rh-Catalyzed Preparation of Chiral Î±-Aminoacids" Tetrahedron: Asymmetry 1999, 10, 375-384.
186. Betzemeier, B.; Lhermitte, F.; Knochel, P.* "A Selenium Catalyzed Epoxidation of Perfluorinated Solvents with Hydrogen Peroxide" Synlett 1999, 489-491.
187. Laaziri, H.; Bromm, L. O.; Lhermitte, F.; Gschwind, R.; Knochel, P. "A New Highly Stereoselective Rearrangement of Acyclic Tertiary Organoboranes. An Example of Highly Stereoselective Remote C-H Activation" J. Am. Chem. Soc. 1999, 121, 6940-6941.
188. Tzalis, D.; Knochel, P.* "Cesium Hydroxide: A Superior Base for the Catalytic Alkynylation of Aldehydes and Ketones and Catalytic Alkenylation of Nitriles" Angew. Chem. 1999, 111, 1547-1549.; Angew. Chem. Int. Ed. Engl. 1999, 38, 1463-1465.
189. Demay, S.; Harms K.; Knochel, P.* "Stereoselective Preparation of Phosphine Oxides via a 2,3-Sigmatropic Shift of Allylic Diphenylphosphinites" Tetrahedron Lett. 1999, 40, 4981-4984.
190. Tzalis, D.; Knochel, P.* "Ru-Centered Coordination Complexes as a New Phase Transfer Catalyst for Alkylation of Enolates and Michael-Additions" Tetrahedron Lett. 1999, 40, 3685-3688.
191. Graf, C.-D.; Malan, C.; Harms, K.; Knochel, P.* "New Chiral Ligands bearing a Non-Stereogenic Chirotopic Center Lithiated N,N-Dialkylureas as Chiral Bases and Sterically Crowded Phosphines for Asymmetric Catalysis" J. Org. Chem. 1999, 64, 5581-5588.
192. Varchi, G.; Ricci, A.; Cahiez, G.; Knochel, P.* "Copper Catalyzed Conjugate Addition of Highly Functionalized Arylmagnesium Compounds to Enones" Tetrahedron; Symposium, 2000, 56, 2727-2731.
193. Tzalis, D.; Koradin, C; Knochel, P.* "Cesium Hydroxide Catalyzed Addition of Alcohols and Amine Derivatives to Alkynes and Styrene" Tetrahedron Lett. 1999, 40, 6193-6195.
194. Millot, N.; Knochel, P.* "Preparation and Stereoselective Addition of new Highly Stereoselective Addition of new Highly Substituted Allylic Zinc Reagents. A new Zinc-Ene Reaction" Tetrahedron Lett. 1999, 40, 7779-7782.
195. Lotz, M.; Ireland, T.; Almena, J. J.; Knochel, P.* "Stereoselective Substitution of a-Aminoalkylferrocenes with Diorganozincs. A fast Synthesis of New Chiral FERRIPHOS-Ligands for Asymmetric Catalysis" Tetrahedron Asymmetry 1999, 10, 1839-1842.
196. Ireland, T.; GroÃŸheimann, G.; Knochel, P.* "New Aminoferrocenyl Diphosphines as Ligands for Asymmetric Hydrogenation of Functionalized Double Bonds" Angew. Chem. 1999, 111, 3397-3400; Angew. Chem. Int. Ed. Engl. 1999, 21, 3212-3215.
197. Betzemeier, B.; Knochel, P.* "Perfluorinated Solvents - a Novel Reaction Medium in Organic Chemistry" in Topics of Current Chemistry: New Solvent Systems, Springer Verlag 1999.
198. Abarbri, M.; Dehmel, F.; Knochel, P.* "The Bromine-Magnesium Exchange as a General Tool for the Preparation of Polyfunctional Aryl and Heteroaryl Magnesium Reagents" Tetrahedron Lett. 1999, 40, 7449-7453.
199. Piber, M.; Jensen, A. E.; RottlÃ¤nder, M.; Knochel, P.* "New Efficient Nickel and Palladium Catalyzed Cross-Coupling Reactions Mediated by Tetrabutylammonium Iodide" Org. Lett. 1999, 1, 1324-1326.
200. Abarbri, M.; Knochel, P.* "Preparation and Reactions of Magnesiated Uracil Derivatives" Synlett 1999, 1577-1578.
201. Avolio, S.; Malan, C.; Marek, I.; Knochel, P. "Preparation and Reactions of Functionalized Magnesium Carbenoids" Synlett 1999, 1820-1822.
202. Dehmel, F.; Abarbri, M.; Knochel, P*. "Preparation of new Magnesiated Functionalized Imidazoles and Antipyrines via an Iodine-Magnesium Exchange" Synlett 1999, 345-346.
203. Riese, U.; Faza, N.; Massa, W.; Harms, K.; Breyhan, T.; Knochel, P.*; Ensling, J.; Ksenofontov, V.; GÃ¼tlich, P.; Dehnicke, K. "Phosphoraneiminato Complexes of Manganese and Cobalt with Heterocubane Structure" Z. Anorg. Allg. Chem., 1999, 625, 1494-1499.
204. Aufauvre, L.; Knochel, P.*; Marek, I.; "A new approach towards the synthesis of sp3 1,1-diiodoalkanes" J. Chem. Soc. Chem. Commun. 1999, 2207-2208.
205. Boudier, A.; Darcel, C.; Flachsmann, F; Micouin, L.; Oestreich, M.; Knochel, P.* "Stereoselective preparation and Reactions of Configurationally Defined Dialkylincs" Chem. Eur. J. 2000, 6, 2748-2761.
206. Lotz, M.; Ireland, T.; Tappe, K.; Knochel, P.* "Preparation of New Chiral Borane-Protected P,N-Ferrocenyl Ligands via a Methoxy Directed ortho-Lithiation" Chirality 2000, 12, 389-395.
207. Rodriguez, A.; Koradin, K.; Dohle, W.; Knochel, P.* "Versatile Indole Synthesis by a 5-Endo Dig Cyclization mediated by Potassium or Cesium Base" Angew. Chem. Int. Ed. 2000, 39, 2488-2490.
208. Boudier, A.; Hupe, E.; Knochel, P.* "Highly Diastereoselective Synthesis of Monocyclic and Bicyclic Secondary Diorganozincs with Defined Configuration" Angew. Chem. Int. Ed. 2000, 39, 2294-2297.
209. Abarbri, M.; Thibonnet, J.; BÃ©rillon, L.; Dehmel, F.; RottlÃ¤nder, M.; Knochel, P.* "Preparation of New Polyfunctional Magnesiated Heterocycles Using a Chlorine-, Bromine- or Iodine-Magnesium Exchange" J. Org. Chem. 2000, 65, 4618-4634.
210. Thibonnet, J.; Knochel, P.* "Preparation of Functionalized Alkenylmagnesium Bromides via a Bromine-Magnesium Exchange" Tetrahedron Lett. 2000, 41, 3319-3322. .
211. Millot, N.; Piazza, C.; Avolio, S.; Knochel, P.* "Aminomethylation of Functionalized Organozinc Reagents and Grignard Reagents Using Immonium Trifluoroacetates" Synthesis 2000, 941-948.
212. Bromm, L.O.; Laaziri, H.; Lhermitte, F.; Harms, K; Knochel, P.* "Highly Regio- and Stereoselective Thermal Migration of Organoboranes in Acyclic Molecules" J. Am. Chem. Soc. 2000, 122, 10218-10219.
213. Betzemeier, B.; Cavazzini, M.; Quici, S.; Knochel, P.* "Copper Catalyzed Aerobic Oxidation of Alcohols under Fluorous Biphasic Conditions" Tetrahedron Lett. 2000, 40, 4343-4346.
214. Jensen, S.; Dohle, W.; Knochel, P.* "Improved Nickel-Catalyzed Cross-Coupling Reaction Conditions" Tetrahedron 2000, 56, 4197-4201.
215. Rodriguez, A. L.; Bunlaksananusorn, T.; Knochel, P.* "Potassium tert-Butoxide Catalyzed Addition of Carbonyl Derivatives to Styrenes" Org. Lett. 2000, 2, 3285-3287.
216. Jensen, A. E., Kneisel, F; Knochel, P.* "Ethyl 3-(p-cyanophenyl) propionate from ethyl 3-iodopropionate and p-cyanophenylzinc bromide" Org. Synth. 2002, 79, 35-42.
217. DÃ¼bner, F,; Knochel, P.* "Highly Enantioselective Copper Catalyzed Substitution of Allylic Chlorides with Diorganozincs" Tetrahedron Lett. 2000, 41, 9233-9237.
218. Delacroix, T.; BÃ©rillon, L.; Cahiez, G.; Knochel, P.* "Preparation of Functionalized Arylmagnesium Reagents Bearing an ortho-Chloromethyl Group" J. Org. Chem. 2000, 65, 8108-8110.
219. Koradin, C.; Rodriguez, A.; Knochel, P.* "Cesium Catalyzed Addition of Nitriles to Alkynes" Synlett 2000, 1452-1454.
220. Sirieix, J.; OÃŸberger, M.; Betzemeier, B.; Knochel, P.* "Palladium Catalyzed Cross-Couplings of Organozincs in Ionic Liquids" Synlett 2000, 1613-1615.
221. Goldfuss, B.; Knochel, P.*; Bromm, L. O.; Knapp, K. "C-H Aktivierung durch direkte Boran-Kohlenwasserstoff Dehydrierung: Kinetische und Thermodynamische Aspekte" Angew. Chem. 2000, 112, 4302-4305; Angew. Chem. Int. Ed. 2000, 39, 4136-4139.
222. Varghese, J. P.; Knochel, P.*; Marek, I. "New Allene Synthesis via Carbocupration-Zinc Carbenoid Homologation and ÃŸ-Elimination Sequence" Org. Lett. 2000, 2, 2849-2852.
223. Piazza, C.; Millot, N.; Knochel, P.* "New Preparation of Benzylic Zinc Reagents via a Fragmentation Reaction" J. Organomet. Chem. 2001, 624, 88-95.
224. Demay, S.; Volant, F.; Knochel, P.* "New C2-Symmetrical 1,2-Diphospanes for the Efficient Rhodium-Catalyzed Asymmetric Hydroboration of Styrene Derivatives" Angew Chemie Int. Ed. 2001, 40, 1235-1238; Angew. Chem. 2001, 113, 1272-1275.
225. Hupe, E.; Knochel, P.* "Stereoselective Synthesis of Secondary Organozinc Reagents and their Reaction with Heteroatomic Electrophiles" Org. Lett. 2001, 3, 127-130.
226. Varchi, G.; Jensen, A. E.; Dohle, W.; Ricci, A.; Cahiez, G.; Knochel, P.* "Preparation of Functionalized Magnesiated Aniline Derivatives" Synlett 2001, 477-480.
227. Ireland, T.; Tappe, K.; Grossheimann, G.; Knochel, P.* "Synthesis of a new class of chiral 1,5-diphosphino ferrocene ligands and their use in enantioselective hydrogenations" Chem. Eur. J. 2001, 8, 843-852.
228. Bunlaksananusorn, T.; Rodriguez, A. L.; Knochel, P.* "tert-BuOK-Catalyzed Addition of Ketones and Nitriles to Vinylic Silanes, Phosphines and Thio Derivatives" Chem. Comm. 2001, 8, 745-746.
229. Demay, S.; Kotschy, A.; Knochel, P.* "Enantioselective Preparation of a Novel Chiral 1,2-Diamine" Synthesis 2001, 6, 863-866.
230. Bonnet, V.; Mongin, F.; TrÃ©court, F.; QuÃ©guiner, G.; Knochel, P.* "Preparation of Polyfunctional Pyridines by a Palladium (0) Catalyzed Cross-Coupling of Functionalized Aryl and Heteroaryl Grignard Reagents" Tetrahedron Lett. 2001, 42, 5717-5720.
231. Demay, S.; Lotz, M.; Polborn, K.; Knochel, P.* "Preparation of a Rigid Bicyclic Diphosphine by Radical Cyclization" Tetrahedron: Asymmetry 2001, 12, 909-914.
232. Hupe, E.; Knochel, P.* "Formal Enantioselective Michael-Addition with Umpolung of the Reactivity" Angew. Chem. Int. Ed. 2001, 40, 3022-3025.
233. Varela Carrete, J., Pena, D.; Goldfuss, B.; Polborn, K.; Knochel, P.* "Remote C-H Activation of Phenyl Substituted Alkenes by BH3â€¢THF: Mechanism, and Applications" Org. Lett. 2001, 15, 2395-2398.
234. Boucley, C.; Cahiez, G.; Carini, S.; Comes-Franchini, M.; Knochel, P.; Pollicino, S.; Ricci, A. "Stereoselective Addition of Organomanganese Reagents to Chiral Acylsilanes and Aldehydes" J. Organomet. Chem. 2001, 624, 223-228.
235. Knochel; P.*; Hupe, E.; Dohle, W., Lindsay, D. M., Bonnet, V., Queguiner, G., Boudier, A., Kopp, F., Demay, S., Seidel, N., Calaza, M. I., Vu, V. A., Sapountzis, I., Bunlaksananusom, T. "Functionalized Main Group Organometallics for Organic Synthesis" Pure Appl. Chem. 2002, 74, 11-17.
236. Dohle, W.; Lindsay, D. M.; Knochel, P.* "Copper-Mediated Cross-Coupling of Functionalized Alkyl and Benzylic Halides" Org. Lett. 2001, 3, 2871-2873.
237. Jensen, A. E.; Knochel, P.* "Nickel Catalyzed Cross-Coupling between Functionalized Primary or Secondary Alkylzinc Halides and Primary Alkyl Halides" J. Org. Chem. 2002, 67, 79-85.
238. Shibli, A.; Varghese, J. P.; Knochel, P.*; Marek, I. "Improved Preparation of Secondary Zinc Iodides by 1,2-Migration of sp3 Carbenoids" Synlett 2001, 6, 818-820.
239. Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P.* "Fe (III)-Catalyzed Cross-Coupling Between Functionalized Arylmagnesium Compounds and Alkenyl Halides" Synlett 2001, 1901-1904.
240. Sapountzis, I.; Dohle, W.; Knochel, P.* "Stereoselective Preparation of Highly Functionalized (E)-3-Magnesiated Enoates by an Iodine-Magnesium Exchange Reaction" Chem. Commun. 2001, 2068-2069.
241. Vu, V. A.; BÃ©rillon, L.; Knochel, P.* "New Functionalized Alkenylmagnesium Reagents Bearing an Oxygen Function in the Î²â€“Position. Preparation and Reaction of 5-Magnesiated-1,3-Dioxin-4-one Derivatives" Tetrahedron Lett. 2001, 42, 6847-6850.
242. Hupe, E.; Calaza, I.; Knochel, P.* "Extending the Scope of Substrate Controlled Diastereoselective Hydroborations Using a Boron-Zinc Exchange Reaction" Tetrahedron Lett. 2001, 42, 8929-8932.
243. Jensen, A. E.; Knochel, P.* "Preparation of 2-Arylated 1,4-Phenylenediamines by Palladium-Catalyzed Cross-Coupling Reactions" J. Organomet. Chem. 2002, 653, 122-128.
244. Vu, V. A.; Marek, I.; Polborn, K.; Knochel, P.* "Preparation of new functionalized cyclopropylmagnesium reagents" Angewandte Chem. Int. Ed. 2002, 41, 351-352.
245. Jensen, A. E.; Dohle, W.; Sapountzis, I.; Lindsay, D. M.; Vu, V. A.; Knochel, P.* "Practical Synthetic Procedures: Preparation and Reactions of Functionalized Arylmagnesium Reagents" Synthesis 2002, 565-569.
246. Lindsay, D. M.; Dohle, W.; Jensen, A. E., Kopp, F.; Knochel, P.* "Polyfunctional Heterocycles using Highly Functionalized Aminated Arylmagnesium Reagents as Versatile Scaffolds" Org. Lett. 2002, 4 , 1819-1822.
247. Ragagnin, G.; Betzemeier, B.; Quici, S.; Knochel, P.* "Copper-catalysed aerobic oxidation of alcohols using fluorous biphasic catalysis" Tetrahedron Symposium in print, 2002, 58, 3985-3991.
248. Sapountzis, I.: Knochel, P.* "General Preparation of Functionalized o-Nitroarylmagnesium Halides via an Iodine-Magnesium Exchange" Angew. Chem. Int. Ed. 2002, 41, 1610-1711.
249. Bonnet, V.; Mongin, F.; Trecourt, F.; Queguiner, G.; Knochel, P.* "Syntheses of Substituted Pyridines, Quinolines and Diazines via Palladium (0)-catalyzed Cross-coupling of Aryl Grignard Reagents" Tetrahedron 2002, 58, 4429-4438.
250. Bonnet, V.; Mongin, F.; Trecourt, F.; Breton, G.; Knochel, P*; Queguiner,G.* "Cross-coupling Reactions between 3-Pyridylmagnesium Chlorides and Halo Substrates" Synlett 2002, 1008-1010.
251. Koradin, C.; Knochel, P.* "Enantioselective Synthesis of Propargylamines by a Copper Catalyzed Addition of Alkynes to Enamines" Angew. Chem. Int. Ed. 2002, 41, 2535-2538; Angew. Chem. 2002, 114, 2651-2654.
252. Thibonnet, J.; Vu, Viet Anh; BÃ©rillon, L.; Knochel. P.* "Alkenylmagnesium Reagents via a Halide-Magnesium Exchange" Tetrahedron 2002, 58, 4787-4799.
253. Hupe, E.; Calaza, I.M.; Knochel, P.* "One-Pot Chemoselective Functionalization of Arylsilanes via Cascade Metal Metal Exchange Reactions" ChemComm 2002, 1390-1391.
254. Hupe, E.; Marek, I.; Knochel, P.* "Diastereoselective Reduction of Alkenylboronic Esters as a New Method for Controlling the Stereochemistry of up to Three Adjacent Centers in Cyclic and Acyclic Molecules" Org. Lett 2002, 2861-2863.
255. Varchi, G., Kofink, C., Lindsay, D.M., Ricci, A., Knochel, P.* "Direct Preparation of Polyfunctional Amino-Substituted Arylmagnesium via an Iodine-Magnesium Exchange Reaction" Chem. Commun. 2003, 396-397.
256. Kneisel, F. F., Monguchi, Y., Knapp, K. M., Zipse, H., Knochel, P.* "Stereoselective Cyclization Reactions Mediated by Functionalized Organomagnesium Reagents and Catalyzed by Cobalt or Copper Salts" Tetrahedron Lett 2002, 43, 4875-4879.
257. Patti, A.; Lotz, M.; Knochel, P.* "Synthesis of Î±,Î²-disubstituted ferrocenes via a ferrocenylepoxide internmediate. Preparation and catalytic activity of a new chiral ferrocenyloxazoline" Tetrahedron: Asymmetry 2002, 12, 3375-3380.
258. Hupe, E., Knochel, P.*, Szabo, K. J. "Mechanism of the Stereoselective Alkyl Group Exchange between Alkylboranes and Alkylzinc Compounds. Quest for Novel Types of Boron-Metal-Exchange Reactions" Organometallics 2002, 21, 2203-2207.
259. Piazza, C., Knochel, P.* "New Sterically Hindereed Lithium Dialkylcuprates for the Generation of Highly Functionalized Mixed Cuprates via a Halogen-Copper Exchange" Angew. Chem. Int. Ed. 2002, 41, 3263-3265; Angew. Chem. 2002, 114, 3397-3399.
260. Bunlaksananusorn, T.; Knochel, P.* "t-BuOK-Catalyzed Addition of Phosphines to Functionalized Alkenes: A Convenient Synthesis of Polyfunctional PhosphineDerivatives" Tetrahedron Lett 2002, 43, 5817-5819.
261. Ragagnin, G.; Betzemeier, B.; Quici, S.; Knochel, P.* "Copper-catalysed aerobic oxidation of alcohols using fluorous biphasic catalysis" Tetrahedron 2002, 3985-3991.
262. Lotz, M.; Polborn, K.; Knochel, P.* "New Ferrocenyl Ligands with broad Applications in Asymmetric Catalysis" Angew. Chem. Int. Ed. 2002, 41, 4708-4711..
263. Gommermann, N.; Koradin, C.; Knochel, P.* "Synthesis of Polyfunctional Unsaturated Amines by the Addition of Functionalized Organomagnesium Reagents to Unsaturated Imminium Ions" Synthesis 2002, 2143-2149.
264. Lotz, M.; Kramer; G.; Knochel, P.* "Facile Axial Chirality Control by Using A Precursor with Central Chirality. Application to the Preparation of new Axially Chiral Diphosphine Complexes for asymmetric Catalysis" Chem. Commun. 2002, 2546-2547.
265. Koradin, C.; Dohle, W.; Rodriguez, A. L.; Schmid, B.; Knochel, P.* "Synthesis of Polyfunctional Indoles and Related Heterocycles Mediated by Cesium and Potassium Bases" Tetrahedron 2003, 59, 1571-1587.
266. Sapountzis, I, Knochel, P.* "A New General Preparation of Polyfunctional Diarylamines by the Addition of Functionalized Arylmagnesium Compounds to Nitroarenes" J. Am. Chem. Soc. 2002, 124, 9390-9391.
267. Kneisel, F.F., Knochel, P.* "Synthesis and Reactivity of Aryl- and Heteroaryl-Magnesium Reagents Bearing Keto Groups" Synlett 2002, 1799-1802.
268. KlÃ¶tzing, R., Lotz, M., Knochel, P.* "New P,N-ferrocenyl ligands for the rhodium-catalyzed allylic alkylation" Tetrahedron: Asymmetry 2003, 14, 255-264.
269. Staubitz, A., Dohle, W., Knochel, P.* "Expiditious Functionalization of Quinolines in Position 2 and 8 via Polyfunctionalized Aryl- and Heteroaryl-magnesium Intermediates" Synthesis 2003, 233-242.
70. Hupe, E.; Denisenko, D.; Knochel, P.* "Stereoselective Migration of Sterically Hindered Organoboranes in Cyclic and Acyclic Systems. A Stereoselective Allylic C-H Activation Reaction" Chem. Eur. J. 2003, 9, 9187-9198.
271. Varghese, J.P., Zouev, I.; Aufavre, L.; Knochel, P.*; Marek, I.* "Carbocupration/Zinc Carbenoid Homologation and b-Elimination Reactions for a New Synthesis of Allenes-Application to the Enantioselective Synthesis of Chiral Allenes by Deracemization of sp3-Organometallic Derivatives" Eur. J. Org. Chem. 2002, 4151-4158.
272. Hupe, E.; Calaza, I. M.; Knochel, P.* "Substrate Controlled Highly Diastereoselective Synthesis of Primary and Secondary Diorganozinc Reagents via a Hydroboration/ Boron-Zinc Exchange Sequence" Chem. Eur. J. 2003, 9, 2789-2796.
273. Harrington-Frost, N.; Leuser, H.; Calaza, I. M.; Kneisel, F. F.; Knochel, P.* "Highly Stereoselective Anti SN2â€™-Substitutions of Z-Allylic Pentafluorobenzoates with Polyfunctionalized Zinc-Copper Reagents" Org. Lett. 2003, 5, 2111-2114.
274. Koradin, C.; Gommermann, N.; Polborn, K.; Knochel, P.* "Synthesis of Enantiomerically Enriched Propargylamines by Copper Catalyzed Addition of Alkynes to Enamines" Chem. Eur. J. 2003, 9, 2797-2811.
275. Calaza, M. I.; Hupe, E.; Knochel, P* "Highly Anti-Selective SN2â€™-Substitution of Chiral Cyclic 2-Iodo-Allylic Alcohol Derivatives with Mixed Zinc-Copper Reagents" Org. Lett. 2003, 5, 1059-1061.
276. Yang, X.; Rotter, T.; Piazza, C., Knochel, P.* "Successive Iodine-Magnesium or â€“Copper Exchange Reactions for the Selective Functionalization of Polyhalogenated Aromatics" Org. Lett. 2003, 5, 1229-1231.
277. Kopp, F.; Sapountzis, I.; Knochel, P.* "Preparation of Polyfunctionalized Amines by the Addition of Functionalized Organomagnesium Reagents to Nitrosoarenes" Synlett 2003, 885-887.
278. Knapp, K.M.; Goldfuss, B.; Knochel, P.* "Stereoselective Synthesis of 1,4-diols by a BH3-THF mediated Rearrangement of 1,2-Disubstituted Cyclobutenes" Chem. Eur. J. 2003, 9, 5259-5265.
279. Dohle, W.; Staubitz, A.; Knochel, P.* "Mild Synthesis of Polyfunctional Benzimidazoles and Indoles by the Reduction of Functionalized Nitroarenes with Phenylmagnesium Chloride" Chem. Eur. J. 2003, 9, 5323-5331.
280. Bunlaksananusorn, T. Knochel, P.* "New P,N-Ligands for the Performance of Asymmetric Ir- and Pd- Catalyzed Reactions" Angew. Chem. Int. Ed. 2003, 42, 3941-3943.
282. Korn, T.; Cahiez, G., Knochel P.* "New Cobalt-Catalyzed Cross-Coupling Reactions of Heterocyclic Chlorides with Aryl and Heteroaryl Magnesium Halides" Synlett 2003, 1892-1894.
283. Vu, V.-A.; Knochel P.* "Stereoselective Preparation of Functionalized Unsaturated Lactones and Esters via Functionalized Magnesium Carbenoids" Synthesis 2003, 1797-1802.
284. Tappe, K..; Knochel P.* "New Efficient Synthesis of Taniaphos-Ligands. Application in Ruthenium- and Rhodium-Catalyzed Enantioselective Hydrogenations" Tetrahedron: Asymmetry 2004, 15, 91-102.
285. Sapountzis, I.; Knochel, P.* "A New Method for the Selective Amination of 1,3- and 1,4-Dinitrobenzenes and Protected Nitroanilines Leading to Polyfunctional 1,3- and 1,4- Disubstituted Anilines" Synlett 2004, 955-958.
286. Yang, X.; Knochel, P.* "Preparation and Reactions of Polyfunctionalized Magnesium Arylcuprates by an I/Cu-Exchange" Synlett 2004, 81-84.
288. Sapountzis, I.; Knochel, P.* "New General Amination Method Using the Addition of Polyfunctional Arylmagnesium Reagents to Functionalized Arylazo Tosylates" Angew. Chem. Int. Ed. 2004, 43, 897-900.
289. Liron, F.; Knochel, P.* "Stereoselective [2,3] Sigmatropic Rearrangement of Acyclic Allylic Phosphinites" Chem. Commun. 2004, 304-305.
290. Kneisel, F.F.; Dochnahl, M.; Knochel, P.* "Nucleophilic Catalysis of the Iodine-Zinc Exchange Reaction. A New Preparation of Highly Functionalized Diarylzincs" Angew. Chem. Int. Ed. 2004, 43, 1017-1021.
291. Bunlaksananusorn, T.; Luna, A. P.; Bonin, M.; Micouin, L.; Knochel, P.* "New Applications of Camphor-Derived P,N-Ligands for Asymmetric Pd- and Ir-Catalyzed Reactions" Synlett 2003, 2240.
292. Heller, B.; Sundermann, B.; Fischer, C.; You, J.; Chen, W.; Drexler, H.-J.; Knochel, P.*; Bonrath, W.; Gutnov, A. "Facile and Racemization-free Conversion of Chiral Nitriles into Pyridine Derivatives" J.Org.Chem. 2003, 68, 9221-9225.
293. Ragagnin, G.; Knochel, P.* "Aerobic Ru-Catalyzed Epoxidations in Fluorous Biphase System using New Fluorous Benzimidazolic Ligands" Synlett 2004, 951-954.
294. Calaza, M. I.; Yang, X.; Soorukram, D.; Knochel, P.* "Stereoselective SN2-Substitutions using Polyfunctional Lithium Arylcuprates Prepared by an Iodine-Copper Exchange" Org. Lett. 2004, 6, 529-531.
295. Duplais, C.; Bures, F.; Sapountzis, I.; Korn, T.J.; Cahiez, G.; Knochel, P.* "A New Iron-Catalyzed Arylation of Aryl Cyanides â€“ An Efficient Preparation of Polyfunctionalized Diaryl Ketones" Angew. Chem. 2004, 43, 2968-2970.
296. Bunlaksananusorn, T. and Knochel, P.* "t-BuOK-Mediated Hydrophosphination of Functionalized Alkenes: A Novel Synthesis of P,N-Ligands and P,P-Ligands" J. Org. Chem. 2004, 69, 4595-4601.
299. Dube, H., Gommermann, N.; Knochel, P.* "Synthesis of Chiral Aminopyrimidines Using an Enantioselective Three-Component Reaction" Synthesis 2004, 2015-2025.
300. Krasovskiy, A.; Knochel, P.* "A LiCl-Catalyzed Br/Mg-Exchange Reaction for the Preparation of Functionalized Aryl and Heteroaryl Magnesium Compounds" Angew. Chem. Int. Ed. 2004, 43, 3333-3336.
301. Varela, J.A., Pena, D., Goldfuss, B.; Denisenko, D.; Kulhanek, J.; Polborn, K.; Knochel, P.* "Diastereoselective Remote C-H Activation via Hydroboration" Chem. Eur. J. 2004, 10, 4252-4264.
302. Gavryushin,. A, Polborn, K.; Knochel, P.* "Novel chiral diphosphine ligands with a pinene core obtained via allylphosphinite-allylphosphine oxide rearrangement" Tetrahedron: Asymmetry 2004, 15, 2279-2288.
303. Soorukram, D.; Knochel, P.* "Enantioselective Synthesis of alpha-Ionone Derivatives using an Anti-SN2â€™-Substitution of Functionalized Zinc Organometallics" Org. Lett. 2004, 6, 2409-2411..
304. Sapountzis, I.; Lin, W.; Fischer, M.; Knochel, P.* "Preparation of Polyfunctional Arynes via 2-Magnesiated Aryl Arylsulfonates" Angew. Chem. Int. Ed. 2004, 43, 4364-4366.
306. Kopp, F., Krasovskiy, A.; Knochel, P.* "Convenient magnesiation of aromatic and heterocyclic rings bearing a hydroxyl group in the presence of LiCl" Chem. Commun. 2004, 2288-2289.
307. Gommermann, N.; Knochel, P.* "Practical Highly Enantioselective Synthesis of Terminal Propargylamines. An Expeditious Synthesis of (S)-(+)-Coniine" Chem. Commun. 2004, 2324-2325.
308. Sapountzis, I.; Dube, H.; Lewis, R.; Knochel, P.* "Synthesis of Functionalized Nitroarylmagnesium Halides via an Iodine-Magnesium Exchange" J. Org. Chem. 2005, 70, 2445-2454.
309. Ren, H., Krasovskiy, A.; Knochel, P.* "Stereoselective Preparation of Functionalized Acyclic Alkenylmagnesium Reagents Using i-PrMgCl" Org. Lett. 2004, 6, 4215-4217.
310. Sapountzis, I; Lin, W.; Kofink, C. C.; Despotopoulou, C.; Knochel, P.* "Iron-Catalyzed Aryl-Aryl Cross-Couplings Using Magnesium-Derived Copper Reagents" Angew. Chem. Int. Ed. 2004, 44, 1654-1657.
312. Ren, H., Krasovskiy, A.; Knochel, P.* "Preparation of Cyclic Alkenylmagnesium Reagents via an Iodine/Magnesium Exchange" Chem. Commun. 2005, 543-545.
313. Krasovskiy, A.; Gavryushin, A.; Knochel, P.* "A General Thiolation of Zinc and Magnesium Organometallics Using Tetramethylthiuran Disulfide" Synlett 2005, in press.
314. Baron, O.; Knochel, P.* "Preparation and Selective Reactions of Mixed Bimetallic Aromatic and Heterocyclic Reagents of Boron and Magnesium" Angew. Chem. Int. Ed. 2005, 44, 3133-3135.
315. Korn, T. J.; Knochel* "Cobalt (II)-Catalyzed Cross-Coupling Between Polyfunctional Arylcopper Reagents and Aryl Bromides or Chlorides" Angew. Chem. Int. Ed. 2005, 44, 2947-2951.
316. Korn, T. J.; Knochel* "A Direct Preparation of Functionalized Aryl and Heteroaryl Disulfides from Functionalized Zinc Organometallics by Using Sulfur Monochloride (S2Cl2 )" Synlett 2005, 1185-1187.
317. Lin, W.; Sapountzis, I; Knochel, P.* "Preparation of Functionalized Aryl Magnesium Reagents by the Addition of Magnesium Aryl Thiolates and Amides to Arynes" Angew. Chem. Int. Ed. 2005, 44, 4258-4261.
318. Gong, L.-Z..; Knochel, P.* "Preparation of Highly Functionalized Heterocyclic Zinc Organometallics via a Li(acac)-Catalysis of the I/Zn-Exchange Reaction" Synlett 2005, 267-270.
319. Leuser, H.; Perrone, S.; Liron, F.; Kneisel, F. F.; Knochel, P.* "Highly Enantioselective of Alcohols and Amines Attached to a Tertiary Center via Copper-Mediated Diastereoselective Allylic SN2Â´-Substitutions" Angew. Chem. Int. Ed. 2005, 44, 4627-4631.
320. Liu, C.-Y.; Knochel, P.* "Preparation of Polyfunctional Arylmagnesium Reagents Bearing a Triazene Moiety. A new Carbazole Synthesis" Org. Lett. 2005, 7, 2543-2546.
321. Fleming, F. F., Zhang, Z.; Liu, W., Knochel, P.* "Metalated Nitriles: Organolithium, -manesium, and â€“copper Exchange of alpha-Halonitriles" J. Org. Chem. 2005, 70, 2200-2205.
322. Harrington-Frost, N.; Leuser, H.; Calaza, I. M.; Kneisel, F. F.; Knochel, P.* â€œHighly Stereoselective Anti SN2â€™-Substitutions of Z-Allylic Pentafluorobenzoates with Polyfunctionalized Zinc-Copper Reagentsâ€ Org. Lett. 2003, 5, 2111-2114.
323. Koradin, C.; Gommermann, N.; Polborn, K.; Knochel, P.* â€œSynthesis of Enantiomerically Enriched Propargylamines by Copper Catalyzed Addition of Alkynes to Enaminesâ€ Chem. Eur. J. 2003, 9, 2797-2811.
324. Calaza, M. I.; Hupe, E.; Knochel, P* â€œHighly Anti-Selective SN2â€™-Substitution of Chiral Cyclic 2-Iodo-Allylic Alcohol Derivatives with Mixed Zinc-Copper Reagentsâ€ Org. Lett. 2003, 5, 1059-1061.
325. Yang, X.; Rotter, T.; Piazza, C., Knochel, P.* â€œSuccessive Iodine-Magnesium or â€“Copper Exchange Reactions for the Selective Functionalization of Polyhalogenated Aromaticsâ€ Org. Lett. 2003, 5, 1229-1231.
326. Kopp, F.; Sapountzis, I.; Knochel, P.* â€ž Preparation of Polyfunctional Amines by the Addition of Functionalized Organomagnesium Reagents to Nitrosoarenesâ€œ Synlett 2003, 885-887.
327. Knapp, K. M.; Goldfuss, B.; Knochel, P.* â€žStereoselective Synthesis of 1,4-Diols by a BH3-THF mediated Rearrangement of 1,2-Disubstituted Cyclobutenesâ€œ Chem. Eur. J. 2003, 9, 5259-5265.
328. Dohle, W.; Staubitz, A.; Knochel, P.* â€žMild Synthesis of Polyfunctional Benzimidazoles and Indoles by the Reduction of Functionalized Nitroarenes with Phenylmagnesium Chlorideâ€œ Chem. Eur. J. 2003, 9, 5323-5331.
329. Bunlaksananusorn, T.; Polborn, K.; Knochel, P.* â€œNew P,N-Ligands for the Performance of Asymmetric Ir- and Pd- Catalyzed Reactionsâ€ Angew. Chem. Int. Ed. 2003, 42, 3941-3943.
330. Gommermann, N., Koradin, C.; Knochel P.* â€œA New Enantioselective Copper(I)-Catalyzed Three-Component Reaction for the Preparation of Propargylaminesâ€ Angew. Chem 2003, 115, 5941-5944; Angew. Chem. Int. Ed. 2003, 42, 5763-5766.
331. Korn, T.; Cahiez, G., Knochel P.* â€œNew Cobalt-Catalyzed Cross-Coupling Reactions of Heterocyclic Chlorides with Aryl and Heteroaryl Magnesium Halidesâ€ Synlett 2003, 1892-1894.
332. Vu, V.-A.; Marek, I.; Knochel P.* â€œStereoselective Preparation of Functionalized Unsaturated Lactones and Esters via Functionalized Magnesium Carbenoidsâ€ Synthesis 2003, 1797-1802.
334. Knochel, P.,* Dohle, W.; Gommermann, N.; Kneisel, F. F.; Kopp, F.; Korn, T. Sapountzis, I.; Vu, V.A. â€žHighly Functionalized Magnesium Organometallics Prepared via a Halogen-Magnesium Exchangeâ€œ Angew. Chem. Int. Ed. 2003, 42, 4302-4320.
335. Hupe, E.; Calaza, M. I.; Knochel, P.* "Synthesis and Reaction of Secondary and Primary Diorganozinc Reagents Using a Boron-Zinc Exchange. A Useful Method for the Stereoselective Formation of New Carbon-Carbon Bonds" J. Organomet. Chem. 2003, 680, 136-142.
336. Bunlaksananusorn, T.; Luna, A. P.; Bonin, M.; Micouin, L.; Knochel, P.* "New Applications of Camphor-Derived P,N-Ligands for Asymmetric Pd- and Ir-Catalyzed Reactions" Synlett 2003, 2240-2242.
337. Heller, B.; Sundermann, B.; Fischer, C.; You, J.; Chen, W.; Drexler, H.-J.; Knochel, P.*; Bonrath, W.; Gutnov, A. "Facile and Racemization-free Conversion of Chiral Nitriles into Pyridine Derivatives" J. Org. Chem. 2003, 68, 9221-9225.
338. Gommermann, N.; Knochel, P.* "Practical Highly Enantioselective Synthesis of Terminal Propargylamines. An Expeditious Synthesis of (S)-(+)-Coniine" Chem. Commun. 2004, 2324-2325.
339. Knochel, P.* "Organozinc Reagents" Science of Synthesis 2004, 3, 5-90.
340. Knochel, P.*; Sapountzis, I.; Gommermann, N. "Carbon-Carbon Bond-Forming Reactions Mediated by Organomagnesium Reagents" in Metal-Catalyzed Cross-Coupling Reactions (2nd Edition) 2004, 2, 671-698.
341. Knochel, P.*; Calaza, M. I.; Hupe, E. "Carbon-Carbon Bond-Forming Reactions Mediated by Organozinc Reagents" in Metal-Catalyzed Cross-Coupling Reactions (2nd Edition) 2004, 2, 619-670.
342. Tappe, K.; Knochel P.* "New Efficient Synthesis of Taniaphos-Ligands. Application in Ruthenium- and Rhodium-Catalyzed Enantioselective Hydrogenations" Tetrahedron: Asymmetry 2004, 15, 91-102.
343. Sapountzis, I.; Knochel, P.* "A New Method for the Selective Amination of 1,3- and 1,4-Dinitrobenzenes and Protected Nitroanilines Leading to Polyfunctional 1,3- and 1,4- Disubstituted Anilines" Synlett 2004, 955-958.
344. Yang, X.; Knochel, P.* "Preparation and Reactions of Polyfunctional Magnesium Arylcuprates by an I/Cu-Exchange" Synlett 2004, 81-84.
345. Fleming, F. F.*; Zhang, Z.; Knochel, P.* "Metallated Nitriles: Halogen-Metal Exchange with alpha-Halonitriles" Org. Lett. 2004, 6, 501-503.
346. Sapountzis, I.; Knochel, P.* "New General Amination Method Using the Addition of Polyfunctional Arylmagnesium Reagents to Functionalized Arylazo Tosylates" Angew. Chem. Int. Ed. 2004, 43, 897-900.
347. Liron, F.; Knochel, P.* "Stereoselective [2,3] Sigmatropic Rearrangement of Acyclic Allylic Phosphinites" Chem. Commun. 2004, 304-305.
348. Kneisel, F. F.; Dochnahl, M.; Knochel, P.* "Nucleophilic Catalysis of the Iodine-Zinc Exchange Reaction. A New Preparation of Highly Functionalized Diarylzincs" Angew. Chem. Int. Ed. 2004, 43, 1017-1021.
349. Ragagnin, G.; Knochel, P.* "Aerobic Ru-Catalyzed Epoxidations in Fluorous Biphase System using New Fluorous Benzimidazolic Ligands" Synlett 2004, 951-954.
350. Calaza, M. I.; Yang, X.; Soorukram, D.; Knochel, P.* "Stereoselective SN2-Substitutions using Polyfunctional Lithium Arylcuprates Prepared by an Iodine-Copper Exchange" Org. Lett. 2004, 6, 529-531.
351. Duplais, C.; Bures, F.; Sapountzis, I.; Korn, T. J.; Cahiez, G.; Knochel, P.* "A New Iron-Catalyzed Arylation of Aroyl Cyanides â€“ An Efficient Preparation of Polyfunctionalized Diaryl Ketones" Angew. Chem.Int. Ed. 2004, 43, 2968-2970.
352. Bunlaksananusorn, T.; Knochel, P.* â€œt-BuOK-Mediated Hydrophosphination of Functionalized Alkenes: A Novel Synthesis of P,N-Ligands and P,P-Ligandsâ€ J. Org. Chem. 2004, 69, 4595-4601.
355. Dube, H., Gommermann, N.; Knochel, P.* "Synthesis of Chiral Aminopyrimidines Using an Enantioselective Three-Component Reaction" Synthesis 2004, 2015-2025.
356. Krasovskiy, A.; Knochel, P.* "A LiCl-Catalyzed Br/Mg-Exchange Reaction for the Preparation of Functionalized Aryl and Heteroaryl Magnesium Compounds" Angew. Chem. Int. Ed. 2004, 43, 3333-3336.
357. Varela, J. A., Pena, D., Goldfuss, B.; Denisenko, D.; Kulhanek, J.; Polborn, K.; Knochel, P.* "Diastereoselective Remote C-H Activation via Hydroboration" Chem. Eur. J. 2004, 10, 4252-4264.
358. Gavryushin, A; Polborn, K.; Knochel, P.* "Novel chiral diphosphine ligands with a pinene core obtained via allylphosphinite-allylphosphine oxide rearrangement" Tetrahedron: Asymmetry 2004, 15, 2279-2288.
359. Soorukram, D.; Knochel, P.* "Enantioselective Synthesis of alpha-Ionone Derivatives using an Anti-SN2â€™-Substitution of Functionalized Zinc Organometallics" Org. Lett. 2004, 6, 2409-2411.
360. Sapountzis, I.; Lin, W.; Fischer, M.; Knochel, P.* "Preparation of Polyfunctional Arynes via 2-Magnesiated Aryl Arylsulfonates" Angew. Chem. Int. Ed. 2004, 43, 4364-4366.
362. Kopp, F., Krasovskiy, A.; Knochel, P.* "Convenient Magnesiation of Aromatic and Heterocyclic Rings Bearing a Hydroxyl Group in the Presence of LiCl" Chem. Commun. 2004, 2288-2289.
363. Ren, H., Krasovskiy, A.; Knochel, P.* "Stereoselective Preparation of Functionalized Acyclic Alkenylmagnesium Reagents Using i-PrMgCl" Org. Lett. 2004, 6, 4215-4217.
364. Knochel, P.*; Yang, X.; Gommermann, N. "Polyfunctional Organocopper Reagents for Organic Synthesis" in Handbook of Functionalized Organometallics, Knochel, P. (Ed.), Wiley-VCH 2005, Chapter 9.
365. Sapountzis, I.; Lin, W.; Kofink, C. C.; Despotopoulou, C.; Knochel, P.* "Iron-Catalyzed Aryl-Aryl Cross-Couplings Using Magnesium-Derived Copper Reagents" Angew. Chem.Int. Ed. 2005, 44, 1654-1658.
366. Sapountzis, I.; Dube, H.; Lewis, R.; Knochel, P.* "Synthesis of Functionalized Nitroarylmagnesium Halides via an Iodine-Magnesium Exchange" J. Org. Chem. 2005, 70, 2445-2454.
367. Ren, H., Krasovskiy, A.; Knochel, P.* "Preparation of Cyclic Alkenylmagnesium Reagents via an Iodine/Magnesium Exchange" Chem. Commun. 2005, 543-545.
368. Krasovskiy, A.; Gavryushin, A.; Knochel, P.* "A General Thiolation of Zinc and Magnesium Organometallics Using Tetramethylthiuran Disulfide" Synlett 2005, 2691-2693.
369. Baron, O.; Knochel, P.* "Preparation and Selective Reactions of Mixed Bimetallic Aromatic and Heterocyclic Reagents of Boron and Magnesium" Angew. Chem. Int. Ed. 2005, 44, 3133-3135.
370. Korn, T. J.; Knochel, P.* "Cobalt (II)-Catalyzed Cross-Coupling Between Polyfunctional Arylcopper Reagents and Aryl Bromides or Chlorides" Angew. Chem. Int. Ed. 2005, 44, 2947-2951.
371. Korn, T. J.; Knochel, P.* "A Direct Preparation of Functionalized Aryl and Heteroaryl Disulfides from Functionalized Zinc Organometallics by Using Sulfur Monochloride (S2Cl2 )" Synlett 2005, 1185-1187.
372. Lin, W.; Sapountzis, I.; Knochel, P.* "Preparation of Functionalized Aryl Magnesium Reagents by the Addition of Magnesium Aryl Thiolates and Amides to Arynes" Angew. Chem. Int. Ed. 2005, 44, 4258-4261.
373. Gong, L.-Z.; Knochel, P.* "Preparation of Highly Functionalized Heterocyclic Zinc Organometallics via a Li(acac)-Catalysis of the I/Zn-Exchange Reaction" Synlett 2005, 267-270.
374. Leuser, H.; Perrone, S.; Liron, F.; Kneisel, F. F.; Knochel, P.* "Highly Enantioselective of Alcohols and Amines Attached to a Tertiary Center via Copper-Mediated Diastereoselective Allylic SN2Â´-Substitutions" Angew. Chem. Int. Ed. Engl. 2005, 44, 4627-4631.
375. Liu, C.-Y.; Knochel, P.* "Preparation of Polyfunctional Arylmagnesium Reagents Bearing a Triazene Moiety. A new Carbazole Synthesis" Org. Lett. 2005, 7, 2543-2546.
376. Fleming, F. F., Zhang, Z.; Liu, W., Knochel, P.* "Metalated Nitriles: Organolithium, -magnesium, and â€“copper Exchange of Î±-Halonitriles" J. Org. Chem. 2005, 70, 2200-2205.
377. Kneisel, F. F.; Leuser, H. Knochel, P.* "Preparation and Reactions of Highly Functionalized Bis-Arylzinc Reagents Using a Li(acac)-Catalyzed Iodine-Zinc Exchange" Synthesis 2005, 2625-2629.
378. Kopp, F.; Sklute, G.; Polborn, K.; Marek, I.; Knochel, P.* "Stereoselective Functionalization of Cyclopropane Derivatives Using Bromine/Magnesium and Sulfoxide/Magnesium Exchange Reactions" Org. Lett. 2005, 7, 3789-3791.
379. Gavryushin, A.; Kofink, C. C.; Manolikakes, G.; Knochel, P.* "Efficient Cross-Coupling of Functionalized Arylzinc Halides Catalyzed by a Nickel Chloride-Diethyl Phosphite System" Org. Lett. 2005, 7, 4871-4874.
380. Yasuike, S.; Kofink, C. C.; Kloetzing, R. J.; Gommermann, N.; Tappe, K.; Gavryushin, A.; Knochel, P.* "Synthesis of JOSIPHOS-type ligands via a diastereoselective three-component reaction and their application in asymmetric rhodium-catalyzed hydroboration" Tetrahedron:Asymmetry, 2005, 16, 3385-3393.
381. Gommermann, N.; Knochel, P.* "2-Phenylallyl as a Versatile Protecting Group for the Asymmetric One-Pot Three-Compoment Synthesis of Propargylamines" Chem. Commun. 2005, 4175-4177.
382. Gommermann, N.; Knochel, P.* "Preparation of functionalized primary chiral amines and amides via an enantioselective synthesis of propargylamines" Tetrahedron 2005, 61, 11418-11426.
383. Gommermann, N.; Knochel, P.* "Highly Enantioselective Synthesis of Propargylamines Using (Mesitylmethyl) benzylamine" Synlett 2005, 2799-2801.
385. Knochel, P.*; Krasovskiy, A.; Sapountzis, I. "Polyfunctional Magnesium Organometallics for Organic Synthesis" in Handbook of Functionalized Organometallics, Knochel, P. (Ed.), Wiley-VCH 2005, Chapter 4.
386. Knochel, P.*; Leuser, H.; Gong, L.-Z.; Perrone, S.; Kneisel, F. F. "Polyfunctional Zinc Organometalics for Organic Synthesis" in Handbook of Functionalized Organometallics, Knochel, P. (Ed.), Wiley-VCH 2005, Chapter 7.
387. Gommermann, N.; Knochel, P.* "Practical Highly Enantioselective Synthesis of Propargylamines via a Copper-Catalyzed One-Pot Three-Component Condensation Reaction" Chem. Eur. J. 2006, 12, 4380-4392.
388. Krasovskiy, A.; Straub, B.*; Knochel, P.* "Highly Efficient Reagents for the Br/Mg Exchange. Mechanisms, Preparation and Synthetic Applications" Angew. Chem. Int. Ed. 2006, 45, 159-162.
389. Stoll, A. H.; Krasovskiy, A.; Knochel, P.* "Preparation of Functionalized Benzylic Magnesium Reagents Using a New Sulfur-Magnesium Exchange Reaction" Angew. Chem. Int.Ed. 2006, 45, 606-609.
390. Krasovskiy, A.; Gavryushin, A.; Knochel, P.* "Higly stereoselective access to sulfur derivatives starting from zinc organometallics" Synlett, 2006, 792-794.
391. Krasovskiy, A.; Knochel, P.* "Convenient titration method of organometallic zinc, magnesium, and lanthanide reagents" Synthesis, 2006, 890-891.
392. Lin, W.; Ilgen, F.; Knochel, P.* "Preparation of highly functionalized arylmagnesium readents by the addition of magnesium phenyl selenide to arynes" Tetrahedron Lett., 2006, 47, 1941-1944.
393. Dunet, G.; Knochel, P.* "Iron- catalyzed cross-coupling between alkenyl and dienyl sulfonates and functionalized arylcooper reagents" Synlett, 2006, 407-410.
394. Kloetzing, R. J.; Thaler, T.; Knochel, P.* "Am improved Asymmetric Reformatsky Reaction Mediated by (-)-N,N-Dimethylaminoisoborneol" Org. Lett. 2006, 8, 1125-1128.
395. Ila, H.; Baron, O.; Wagner, A. J.; Knochel, P.* "Functionalized magnesium organometallics as versatile intermediates for the synthesis of polyfunctional heterocycles" Chem. Commun., 2006, 583-593.
396. Liu, C.-Y.; Ren; H.; Knochel, P.* "Magnesiated Unsaturated Silylated Cyanohygrins as Synthetic Equivalents of Aromatic and Heterocyclic Grignard Reagents Bearing a Ketone or a Aldehyde" Org. Lett. 2006, 8, 617-619.
397. Kloetzing, R.; Knochel, P.* "Ferrocenyl-QUINAP: a planar chiral P,N-ligand for palladium-catalized allylic substitution reactions" Tetrahedron: Asymmetry, 2006, 17, 116-123.
398. Ila, H.; Baron, O.; Wagner, A. J.; Knochel, P.* "Preparation and reactions of heteroaryl organomagnesium compounds" Chem. Lett., 2006, 35, 2-7.
399. Korn, T. J.; Schade, M. A.; Wirth, S.; Knochel, P.* "Cobalt (II)-Catalyzed Cross-Coupling between Polyfunctional Arylcopper Reagents and Aryl Fluorides or Tosylates" Org. Lett., 2006, 8, 725-728.
400. Krasovskiy, A.; Kopp, F.; Knochel, P.* "New Soluble Lanthanide Salts (LnCl3.2LiCl; Ln = La, Ce, Nd) for the improved Addition of Magnesium Organometallics to Carbonyl Derivatives" Angew. Chem. Int. Ed. Engl. 2006, 45, 497-500.
401. Ren, H.; Knochel, P.* “Regioselective Functionalization of Trisubstituted Pyridines Using a Bromine-Magnesium Exchange” Chem. Comm. 2006, 726-728.
402. Krasovskiy, A.; Krasovskaya, V.; Knochel, P.* „Mixed Mg/Li amides of the type R2NMgCl . LiCl as highly efficient bases for the regioselective generation of functionalized aryl and heteroaryl magnesium compounds” Angew. Chem. Int. Ed. Engl. 2006, 45, 2958-2961.
403. Yang, X.; Knochel, P.* „Selective functionalization of imidazoles via an iodine-copper exchange reaction” Chem. Comm. 2006, 2170-2172.
404. Boudet, N.; Knochel, P.* “Chemo- and Regioselective Functionalization of Uracil Derivatives. Applications to the Synthesis of Oxypurinol and Emivirine” Org. Lett. 2006, 8, 3737-3740.
405. Yang, X., Knochel, P.* “Stereoselective Preparation of Higly Functionalized (Z)-3-Copper Enoates by an Iodine-Copper Exchange Reaction” Synthesis 2006, 2167-2172.
406. Yang, X., Knochel, P.* “Direct Preparation of Copper organometallics Bearing an Aldehyde Function via an Iodine-Copper Exchange” Chem. Comm. 2006, 2486-2488.
407. Yang, X., Knochel, P.* “Preparation and Reactions of Functionalized Organocopper Reagents” Synthesis, 2006, 2618-2623.
408. Yang, X.; Knochel, P.* “Stereoselective Functionalization of β-iodo-ά,β-Unsaturated Ketones via an Iodine-Copper Exchange Reaction” Org. Lett. 2006, 8, 1941-1943.
409. Kofink, C. C.; Knochel, P.* “Synthesis of Functionalized Diarylmethanes via a Copper-Catalyzed Cross-Coupling of Arylmagnesium Reagents with Benzylic Phosphates” Org. Lett. 2006, 8, 4121-4124.
410. Sinha, P.; Kofink, C. C.; Knochel, P.* “Preparation of Aryl-Alkylamines via Electrophilic Amination of Functionalized Arylazo Tosylates with Alkylzinc Reagents” Org. Lett. 2006, 8, 3741-3744.
411. Krasovskiy, A.; Malakhov, V.; Gavryushin, A.; Knochel, P.* “Efficient Synthesis of Functionalized Organozinc Compounds by the Direct Insertion of Zinc into Organic Iodides and Bromides” Angew. Chem. Int. Ed. Engl. 2006, 45, 6040-6044.
412. Krasovskiy, A.; Tishkov, A.; del Amo, V.; Mayr, H.; Knochel, P.* “Transition-metal-free homocoupling of organomagnesium compounds” Angew. Chem. Int. Ed. Engl. 2006, 45, 5010-5014.
413. Gavryushin, A.; Kofink, C. C.; Manolikakes, G.; Knochel, P.* “An Efficient Negishi Cross-Coupling Reaction Catalyzed by Nickel(II) and Diethyl Phosphite” Tetrahedron 2006, 62, 7521-7533.
414. Soorukram, D.; Knochel, P.* “Copper-catalyzed Preparation of Ketones bearing a stereogenic center in α-position” Angew. Chem. Int. Ed. Engl. 2006, 45, 3686-3689.
415. Ren, H.; Knochel, P.* “Chemoselective Benzylic C-H Activations for the Preparation of Condenced N-heterocycles” Angew. Chem. Int. Ed. Engl. 2006, 45, 3462-3465.
416. Lin, W.; Baron, O.; Knochel, P.* “Highly Functionalized Benzene Syntheses by Directed Mono or Multiple Magnesiations with TMPMgCl.LiCl” Org. Lett. 2006, 8, 5673-5676.
417. Sinha, P., Knochel, P.* “Preparation of Polyfunctional Tertiary Amines via the Electrophilic Amination of Arylmagnesium Compounds Using N-Chloroamines” Synlett 2006, 3304-3308.
418. Del Amo, V.; Dubbaka, S. R.; Krasovskiy, A.; Knochel, P.* “General preparation of primary, secondary, and tertiary aryl amines by the oxidative coupling of polyfunctional aryl and heteroaryl amidocuprates” Angew. Chem. Int. Ed. Engl. 2006, 45, 7838-7842.
419. 419. Korn, T. J.; Schade, M. A.; Cheemala, M. N.; Wirth, S.; Guevara, S. A.; Cahiez, G.; Knochel, Paul. “Cobalt-catalyzed cross-coupling reactions of heterocyclic chlorides with arylmagnesium halides and of polyfunctionalized arylcopper reagents with aryl bromides, chlorides, fluorides and tosylates.” Synthesis 2006, 3547-3574.
419-1. Knochel, P.*; Leuser, H.; Gong, L.-Z.; Perrone, S.; Kneisel, F. F. “Functionalized organozinc compounds” in Chemistry of Organozinc Compounds, Wiley Int. 2006, Pt. 1, 287-393, ISBN: 978-0-470-09337-5.
420. Krasnokutskaya, E. A.; Semenischeva, N. I.; Filimonov, V. D.; Knochel, P.* "A New, One-Step, Effective Protokol for the Iodination of Aromatic and Heterocyclic Compounds via Aprotic Diazotization of Amines" Synthesis, 2007, 81-84.
421. Soorukram, D.; Knochel, P.* “Formal Enantioselective Synthesis of (+)-Estrone” Org. Lett., 2007, 9, 1021-1023.
422. Soorukram, D.; Knochel, P.* “A Practical Synthesis of Optically Active α-Substituted Ketones in High Enantiomeric Excess” Synthesis 2007, 638-641.
423. Lin, W.; Chen, L.; Knochel, P.* “Preparation of functionalized 3,4-pyridynes via 2-magnesiated diaryl sulfonates” Tetrahedron 2007, 63, 2787-2797.
424. Ren, H.; Li, Z.; Knochel, P.* “Chemoselective C(sp3)-H Bond Activation for the Preparation of Condensed N-Heterocycles” Chem. Asian J. 2007, 2, 416-433.
425. Perrone, S.; Knochel, P.* “Highly Diastereoselective Preparation of (E)-Alkenylsilanes Bearing an α-Chiral Center.” Org. Lett. 2007, 9, 1041-1044.
426. Ren, H.; Dunet, G.; Mayer, P.; Knochel, P.* "Highly Diastereoselective Synthesis of Homoallylic Alcohols Bearing Adjacent Quaternary Centers Using Substituted Allylic Zinc Reagents" J. Am. Chem. Soc. 2007, 129, 5376-5377.
427. Kopp, F.; Knochel, P.* "Iodine-Magnesium Exchange on Unprotected Imidazoles in the Presence of LiCl" Synlett 2007, 0980-0982.
428. Kienle, M.; Dubbaka, S. R.; del Amo, V.; Knochel, P.* “Preparation of Tertiary Amines via the Oxidative Coupling Of Polyfunctional Aryl and Heteroaryl Amidocuprates" Synthesis 2007, 1272-1278.
429. Perrone, S.; Metzger, A.; Knochel, P.* "Chiral Allylic Cyanohydrins as Versatile Substrates for Diastereoselective Copper(I)-mediated SN2' Allylic Substitutions" Synlett 2007, 1047-1050.
430. Kopp, F.; Knochel, P.* "Functionalisation of Unprotected Uracil Derivatives Using the Halogen-Magnesium Exchange" Org. Lett. 2007, 9, 1639-1641.
431. Kopp, F.; Wunderlich, S.; Knochel, P.* "Halogen-magnesium exchange on unprotected aromatic and heteroaromatic carboxylic acids" Chem. Comm. 2007, 2075-2077.
432. Dunet, G.; Knochel, P.* "Highly Stereoselective Cobalt-Catalyzed Allylation of Functionalized Diarylzinc Reagents” Synlett 2007, 1383-1386.
433. Liron, F.; Knochel, P.* "Reactivity of stable neopentyl-Pd intermediates in the absence of nucleophile" Tetrahedron Lett. 2007, 48, 4943-4946.
434. Cheemala, M. N.; Knochel, P.* "New P,N-Ferrocenyl Ligands for the Asymmetric Ir-Catalyzed Hydrogenation of Imines" Org. Lett. 2007, 9, 3089-3092.
435. Kofink, C. C.; Blank, B.; Pagano, S.; Goetz, N.; Knochel, P.* "Iron-catalyzed aryl-aryl cross-coupling reaction tolerating amides and unprotected quinolinones" Chem. Comm. 2007, 1954-1956.
436. Liu, C.-Y.; Knochel, P.* „Preparation of Polyfunctional Aryl Triazenes via a Direct Insertion Reaction of Zn in the Presence of LiCl” Synlett 2007, 2081-2085.
437. Manolikakes, G.; Dastbaravardeh, N.; Knochel, P.* „Nickel-Catalyzed Cross-Coupling Reactions of Aryltitanium(IV) Alkoxides with Aryl Halides” Synlett 2007, 2077-2080.
438. Liu, C.-Y.; Gavryushin, A.; Knochel, P.* „Synthesis of functionalized o-, m-, and p-terphenyl derivatives by consecutive cross-coupling reactions of triazene-substituted arylboronic esters.” Chem. Asian J. 2007, 2, 1020-1030.
439. Liu, C.-Y.; Knochel, P.* „Preparation of Polyfunctional Aryl Azides from Aryl Triazenes. A New Synthesis of Ellipticine, 9-Methoxyellipticine, Isoellipticine, and 7-Carbethoxyisoellipticine” J. Org. Chem. 2007, 72, 7106-7115.
440. Wunderlich, S. H.; Knochel, P.* “(tmp)2Zn•2MgCl2•2LiCl: a chemoselective base for the directed zincation of sensitive arenes and heteroarenes” Angew. Chem. Int. Ed. 2007, 46, 7685-7688.
441. Clososki, G. C.; Rohbogner, C. J.; Knochel, P.* “Direct magnesiation of polyfunctionalized arenes and heteroarenes using (tmp)2Mg•2LiCl” Angew. Chem. Int. Ed. 2007, 46, 7681-7684.
442. Gommermann, N.; Knochel, P.* “N,N-Dibenzyl-N-[1-cyclohexyl-3-(trimethylsilyl)-2-propynyl]-amine from cyclohexanecarbaldehyde, trimethylsilylacetylene and dibenzylamine” Org. Synth. 2007, 84, 1-10.
443. Fleming, F. F.; Gudipati, S.; Vu, V. A.; Mycka, R. J.; Knochel, P.* “Grignard Reagents: Alkoxide-Directed Iodine-Magnesium Exchange at sp3 Centers” Org. Lett. 2007, 9, 4507-4509.
444. Boudet, N.; Sase, S.; Sinha, P.; Liu, C.-Y.; Krasovskiy, A.; Knochel, P.* “Directed Ortho Insertion (DoI): A New Approach to Functionalized Aryl and Heteroaryl Zinc Reagents” J. Am. Chem. Soc. 2007, 129, 12358-12359.
445. Kienle, M.; Dubbaka, S. R.; Brade, K.; Knochel, P.* “Modern amination reactions” Eur. J. Org. Chem. 2007, 25, 4166-4176.
446. Thaler, T.; Geittner, F.; Knochel, P.* „A Novel Synthetic Approach towards Chiral QUINAP via Diastereometric Sulfoxide Intermediates” Synlett 2007, 2655-2658.
447. Melzig, L.; Gavryushin, A.; Knochel, P.* „Direct Aminoalkylation of Arenes and Hetarenes via Ni-Catalyzed Negishi Cross-Coupling Reactions” Org. Lett. 2007, 9, 5529-5532.
448. Soorukram, D.; Boudet, N.; Malakhov, V.; Knochel, P.* “Preparation of polyfunctionalized 2,6-dimethoxypyrimidine derivatives via chemo- and regioselective direct zinc insertion” Synthesis 2007, 3915-3922.
449. Cheemala, M. N.; Gayral, M.; Brown, J. M.; Rossen, K.; Knochel, P.* “New paracyclophane phosphine for highly enantioselective ruthenium-catalyzed hydrogenation of prochiral ketones” Synthesis 2007, 3877-3885.
450. Kolodney, G.; Sklute, G.; Perrone, S.; Knochel, P.*; Marek, I. “Diastereodivergent synthesis of enantiomerically pure homoallylic amine derivatives containing quaternary carbon stereocenters” Angew. Chem. Int. Ed. 2007, 46, 9291-9294.
451. Dubbaka, S. R.; Kienle, M.; Mayr, H.; Knochel, P.* “Copper (I)-mediated oxidative cross-coupling between functionalized alkynyl lithium and Aryl magnesium reagents” Angew. Chem. Int. Ed. 2007, 46, 9093-9096.
452. Boudet, N.; Lachs, J. R.; Knochel, P.* “Multiple Regioselective Functionalizations of Quinolines via Magnesiations” Org. Lett. 2007, 9, 5525-5528.
453. Stoll, A. H.; Mayer, P.; Knochel, P.* “Preparation of Di-, Tri-, and Tetra-Substituted Functionalized Ferrocenes via Magnesium Organometallics” Organometallics 2007, 26, 6694-6697.
454. Shi, L.; Chu, Y.; Knochel, P.*; Mayr, H. “Relative rates of bromine-magnesium exchange reactions in substituted bromobenzene derivatives” Angew. Chem. Int. Ed. 2008, 47, 202-204.
455. Stoll, A. H.; Knochel, P.* “Preparation of Fully Substituted Anilines for the Synthesis of Functionalized Indoles” Org. Lett. 2008, 10, 113-116.
456. Manolikakes, G.; Gavryushin, A.; Knochel, P.* “An Efficient Silane-Promoted Nickel-Catalyzed Amination of Aryl and Heteroaryl Chlorides” J. Org. Chem. 2008, 73, 1429-1434.
457. Dunet, G.; Mayer, P.; Knochel, P.* “Highly Diastereoselective Addition of Cinnamylzinc Derivatives to α-Chiral Carbonyl Compounds” Org. Lett. 2008, 10, 117-120.
458. Abu Thaher, B.; Koch, P.; del Amo, V.; Knochel, P.; Laufer, S.* „A Convenient Synthesis of 1-(4-Fluorophenyl)-2-(4-pyridyl)cyclopentene from Cyclopentanone” Synthesis 2008, 225-228.
459. Druzhinin, S. I.; Dubbaka, S. R.; Knochel, P.*; Kovalenko, S. A.; Mayer, P.; Senyushkina, T.; Zachariasse, K. A. “Ultrafast Intramolecular Charge Transfer with Strongly Twisted Aminobenzonitriles: 4-(Di-tert-butylamino) benzonitrile and 3-(Di-tert-butylamino) benzonitrile” J. Phys. Chem. A 2008, 112, 2749-2761.
460. Rohbogner, C. J.; Clososki, G.; Knochel, P.* “A general method for meta- and para- functionalization of arenes using TMP2Mg • 2 LiCl” Angew. Chem. Int. Ed. 2008, 47, 1503-1507.
461. Metzger, A.; Schade, M. A.; Knochel, P.* “LiCl-Mediated Preparation of Highly Functionalized Benzylic Zinc Chlorides” Org. Lett. 2008, 10, 1107-1110.
462. Rauhut, C. B.; Vu, V. A.; Fleming, F. F.; Knochel, P.* “Preparation of Functionalized Alkylmagnesium Derivatives Using an I/Mg-Exchange” Org. Lett. 2008, 10, 1187-1189.
463. Ireland, T.; Tappe, K.; Grossheimann, G.; Knochel, P.* “Synthesis of a new class of chiral 1,5-diphosphanylferrocenyl ligands and their use in enantioselective hydrogenation” Chem. Eur. J. 2008, 14, 3509.
464. Tappe, K.; Knochel P.* “New Efficient Synthesis of Taniaphos-Ligands. Application in Ruthenium- and Rhodium-Catalyzed Enantioselective Hydrogenations” [Tetrahedron: Asymmetry 2004, 15, 91-102] Tetrahedron: Asymmetry 2008, 19, 891.
465. Despotopoulou, C.; Bauer, R. C.; Krasovskiy, A.; Mayer, P.; Stryker, J. M.; Knochel, P.* “Selective mono- and 1,2-difunctionalisation of cyclopentene derivatives via Mg and Cu intermediates” Chem. Eur. J. 2008, 14, 2499-2506.
466. Helm, M. D.; Mayer, P.; Knochel, P.* “Preparation of silyl substituted crotylzinc reagents and their highly diastereoselective addition to carbonyl compounds” Chem. Comm. 2008, 1916-1917.
467. Boudet, N.; Dubbaka, S. R.; Knochel, P.* “Oxidative Amination of Cuprated Pyrimidine and Purine Derivatives” Org. Lett. 2008, 10, 1715-1718.
468. Schade, M. A.; Metzger, A.; Hug, S.; Knochel, P.* “Nickel-catalyzed cross-coupling reactions of benzylic zinc reagents with aromatic bromides, chlorides and tosylates” Chem. Comm. 2008, 3046-3048.
469. Manolikakes, G.; Schade, M. A.; Munoz Hernandez, C.; Mayr, H.; Knochel, P.* “Negishi Cross-Couplings of Unsaturated Halides Bearing Relatively Acidic Hydrogen Atoms with Organozinc Reagents” Org. Lett. 2008, 10, 2765-2768.
470. Ireland, T; Grossheimann, G; Wieser-Jeunesse, C; Knochel, P.* “Ferrocenyl ligands with two phosphanyl substituents in the , positions for the transition metal catalyzed asymmetric hydrogenation of functionalized double bonds” [Erratum to document cited in CA132:122132]. Angew. Chem. Int. Ed. 2008, 47, 3666.
471. Piller, F. M.; Appukkuttan, P.; Gavryushin, A.; Helm, M.; Knochel, P.* „Convenient Preparation of Polyfunctional Aryl Magnesium Reagents by a Direct Magnesium Insertion in the Presence of LiCl” Angew. Chem. Int. Ed. 2008, 47, 6802-6806.
472. Mosrin, M.; Knochel, P.* „Regio- and Chemoselective Multiple Functionalization of Pyrimidine Derivatives by Selective Magnesiations using TMPMgCl LiCl” Org. Lett. 2008, 10, 2497-2500.
473. Sase, S.; Jaric, M.; Metzger, A.; Malakhov, V.; Knochel, P.* “One-Pot Negishi Cross-Coupling Reactions of In Situ Generated Zinc Reagents with Aryl Chlorides, Bromides, and Triflates” J. Org. Chem. 2008, 73, 7380-7382.
474. Rauhut, C. B.; Melzig, L.; Knochel, P.* „Meta- and Para-Difunctionalization of Arenes via a Sulfoxide-Magnesium Exchange Reaction” Org. Lett. 2008, 10, 3891-3894.
475. Metzger, A.; Schade, M. A.; Manolikakes, G.; Knochel, P.* “A General Preparation of Polyfunctional Benzylic Zinc Organometallic Compounds” Chem. Asian J. 2008, 3, 1678-1691.
476. Manolikakes, G.; Munoz Hernandez, C.; Schade, M. A.; Metzger, A.; Knochel, P.* “Palladium- and Nickel-Catalyzed Cross-Couplings of Unsaturated Halides Bearing Relatively Acidic Protons with Organozinc Reagents” J. Org. Chem. 2008, 73, 8422-8436.
477. Wunderlich, S.; Knochel, P.* “High Temperature Metalation of Functionalized Aromatics and Heteroaromatics using (tmp)2Zn 2MgCl2 2LiCl and Microwave Irradiation” Org. Lett. 2008, 10, 4705-4707.
478. Mosrin, M.; Boudet, N.; Knochel, P.* “Regio- and chemoselective magnesiation of protected uracils and thiouracils using TMPMgCl LiCl and TMP2Mg 2LiCl” Org. Biomol. Chem. 2008, 6, 3237-3239.
479. Chen, Y.-H.; Knochel, P.* “Preparation of Aryl and heteroaryl indium(III) reagents by the direct insertion of indium in the presence of LiCl” Angew. Chem. Int. Ed. 2008, 47, 7648-7651.
480. Metzger, A.; Piller, F. M.; Knochel, P.* “Polyfunctional benzylic zinc chlorides by the direct insertion of magnesium into benzylic chlorides in the presence of LiCl and ZnCl2” Chem. Comm. 2008, 5824-5826.
481. Mosrin, M.; Petrera, M.; Knochel, P.* “Multiple Regio- and Chemoselective Functionalizations of Pyrimidine Derivatives Using TMPMgCl•LiCl and TMP2Mg•2LiCl” Synthesis 2008, 3697-3702.
482. Wunderlich, S. H.; Knochel, P.* “Efficient mono- and bis-functionalization of 3,6-dichloropyridazine using (tmp)2Zn 2MgCl2 2LiCl“ Chem. Comm. 2008, 6387-6389.
483. Rauhut, C. B.; Cervino, C.; Krasovskiy, A.; Knochel, P.* “Stereoselective Preparation of Cyclopropylmagnesium Reagents via a Br-Mg Exchange Using i-PrMgCl•LiCl in the Presence of Dioxane” Synlett 2009, 67-70.
484. Piller, F. M.; Knochel, P.* “Regio- and Chemoselective Synthesis of Fully Substituted Thiophenes” Org. Lett. 2009, 11, 445-448.
485. Wunderlich, S H.; Knochel, P.* “Aluminum bases for the highly chemoselective preparation of aryl and heteroaryl aluminum compounds” Angew. Chem. Int. Ed. 2009, 48, 1501-1504.
486. Mosrin, M.; Knochel, P.* “Regio- and chemoselective metalation of chloropyrimidine derivatives with TMPMgCl LiCl and TMP2Zn 2MgCl2 2LiCl” Chem. Eur. J. 2009, 15, 1468-1477.
487. Manolikakes, G.; Dong, Z.; Mayr, H.; Li, J.; Knochel, P.* “Negishi cross-couplings compatible with unprotected amide functions” Chem. Eur. J. 2009, 15, 1324-1328.
488. Manolikakes, G.; Knochel, P.* “Radical catalysis of Kumada cross-coupling reactions using functionalized Grignard reagents” Angew. Chem. Int. Ed. 2009, 48, 205-209.
489. Thaler, T.; Knochel, P.* “Copper-catalyzed asymmetric Michael addition of magnesium, zinc, and aluminum organometallic reagents: efficient synthesis of chiral molecules” Angew. Chem. Int. Ed. 2009, 48, 645-648.
490. Dong, Z.; Clososki, G. C.; Wunderlich, S. H.; Unsinn, A.; Li, J.; Knochel, P.* “Direct zincation of functionalized aromatics and heterocycles by using a magnesium base in the presence of ZnCl2” Chem. Eur. J. 2009, 15, 457-468.
491. Dong, Z.; Manolikakes, G.; Li, J.; Knochel, P.* „Palladium-Catalyzed Cross-Couplings of Unsaturated Halides Bearing Relatively Acidic Hydrogen Atoms with Organozinc Reagents” Synthesis 2009, 681-686.
492. Melzig, L.; Rauhut, C. B.; Knochel, P.* „Meta- and Para-Difunctionalization of Arenes via an Ortho-Magnesiation and a Subsequent Sulfoxide-Magnesium Exchange” Synthesis 2009, 1041-1048.
493. Mosrin, M.; Knochel, P.* „TMPZnCl LiCl: A New Active Selective Base for the Directed Zincation of Sensitive Aromatics and Heteroaromatics” Org. Lett. 2009, 11, 1837-1840.
494. Shi, L.; Chu, Y.; Knochel, P.*; Mayr, H. „Kinetics of Bromine-Magnesium Exchange Reactions in Substituted Bromobenzenes” J. Org. Chem. 2009, 74, 2760-2764.
495. Rohbogner, C. J.; Wunderlich, S. H.; Clososki, G. C.; Knochel, P.* “New mixed Li/Mg and Li/Mg/Zn amides for the chemoselective metallation of arenes and heteroarenes” Eur. J. Org. Chem. 2009, 1781-1795.
496. Chen, Y.-H.; Sun, M.; Knochel, P.* “LiCl-mediated preparation of functionalized benzylic indium(III) halides and highly chemoselective palladium-catalyzed cross-coupling in a protic cosolvent” Angew. Chem. Int. Ed. 2009, 48, 2236-2239.
497. Wunderlich, S. H.; Knochel, P.* “Aluminum bases for the highly chemoselective preparation of aryl and heteroaryl aluminum compounds” Angew. Chem. Int. Ed. 2009, 48, 1501-1504.
498. Metzger, A.; Gavryushin, A.; Knochel, P.* “LaCl3 2LiCl-catalyzed addition of Grignard reagents to ketones” Synlett 2009, 1433-1436.
499. Melzig, L.; Rauhut, C B.; Knochel, P.* “2,3-Functionalization of furans, benzofurans and thiophenes via magnesiation and sulfoxide-magnesium exchange” Chem. Comm. 2009, 24, 3536-3538.
500. Gao, H.; Knochel, P.* “New preparation and reactions of arylaluminum reagents using barbier conditions” Synlett, 2009, 1321-1325.
501. Despotopoulou, C.; Klier, L.; Knochel, P.* “Synthesis of Fully Substituted Pyrazoles via Regio- and Chemoselective Metalations” Org. Lett. 2009, 11, 3326-3329.
502. Mosrin, M.; Bresser, T.; Knochel, P.* “Regio- and Chemoselective Multiple Functionalization of Chloropyrazine Derivatives. Application to the Synthesis of Coelenterazine” Org. Lett. 2009, 11, 3406-3409.
503. Shi, L.; Chu, Y.; Knochel, P.*; Mayr, H. “Kinetics of Bromine-Magnesium Exchange Reactions in Heteroaryl Bromides” Org. Lett. 2009, 11, 3502-3505.
504. Piller, F. M.; Metzger, A.; Schade, M. A.; Haag, B. A.; Gavryushin, A.; Knochel, P.* „Preparation of Polyfunctional Arylmagnesium, Arylzinc, and Benzylic Zinc Reagents by Using Magnesium in the Presence of LiCl” Chem. Eur. J. 2009, 15, 7192-7202.
505. Metzger, A.; Melzig, L.; Despotopoulou, C.; Knochel, P.* „Pd-Catalyzed Cross-Coupling of Functionalized Organozinc Reagents with Thiomethyl-Substituted Heterocycles” Org. Lett. 2009, 11, 4228-4231.
506. Haag, B.; Peng, Z.; Knochel, P.* “Preparation of Polyfunctional Indazoles and Heteroarylazo Compounds Using Highly Functionalized Zinc Reagents” Org. Lett. 2009, 11, 4270-4273.
507. Thaler, T.; Ren, H.; Gommermann, N.; Clososki, G.; C.; Rohbogner, C. J.; Wunderlich, S. H.; Knochel, P.* “New catalytic Cu-, Pd- and stoichiometric Mg-, Zn-mediated bond activations” Activating Unreactive Substrates (Monograph), 2009, 359-377.
508. Mosrin, M.; Monzon, G.; Bresser, T.; Knochel, P.* “High temperature zincation of functionalized aromatics and heteroaromatics using TMPZnCl? LiCl and microwave irradiation” Chem. Comm., 2009, 37, 5615-5617.
509. Wunderlich, S. H.; Kienle, M.; Knochel, P. „Directed Manganation of Functionalized Arenes and Heterocycles Using tmp2Mn? 2 MgCl2? 4 LiCl” Angew. Chem. Int. Ed. 2009, 48, 7256-7260.
510. Kienle, M.; Dunst, C.; Knochel, P.* „Oxidative Amination of Heteroaromatic Zinc Reagents Mediated by PhI(OAc)2” Org. Lett. 2009, 11, 5158-5161.
511. Despotopoulou, C.; Gignoux, C.; McConnell, D.; Knochel, P.* “Functionalization of 4,5-Dihydrobenzo[g]indazoles Using Magnesium- or Zinc-Heterocyclic Intermediates” Synthesis 2009, 3661-3671.
512. Knochel, P. “A flash of magnesium” Nature Chemistry 2009, 1, 740.
513. Gommermann, N.; Knochel, P.*; Rech, J. C.; Ellman, J. A. „N,N-Dibenzyl-N-[1-cyclohexyl-3-(trimethylsilyl)-2-propynyl]amine from cyclohexanecarbaldehyde, trimethylsilylacetylene and dibenzylamine” Org. Syntheses 2009, Collective (Vol. 11), 189-196.
514. Wunderlich, S. H.; Knochel, P*. „Preparation of Functionalized Aryl Iron(II) Compounds and a Nickel-Catalyzed Cross-Coupling with Alkyl Halides” Angew. Chem. Int. Ed. 2009, 48, 9717-9720.
515. Rohbogner, C. J.; Wagner, A. J.; Clososki, G. C.; Knochel, P.* “Magnesiation of weakly activated arenes using tmp2Mg? 2LiCl: synthesis of tert-butyl ethyl phthalate” Org. Synth. 2009, 86 374-384.
516. Dong, Z.-B.; Manolikakes, G.; Shi, L.; Knochel, P.*; Mayr, H. “Structure-Reactivity Relationships in Negishi Cross-Coupling Reactions” Chem. Eur. J. 2010, 16, 248-253.
517. Thaler, T.; Haag, B.; Gavryushin, A.; Schober, K.; Hartmann, E.; Gschwind, R. M.; Zipse, H.; Mayer, P.; Knochel, P.* “Highly diastereoselective Csp3-Csp2 Negishi cross-coupling with 1,2-, 1,3- and 1,4-substituted cycloalkylzinc compounds” Nature Chemistry 2010, 2, 125-130.
518. Wunderlich, S. H.; Rohbogner, C. J.; Unsinn, A.; Knochel, P.* “Scaleable Preparation of Functionalized Organometallics via Directed Ortho Metalation Using Mg- and Zn-Amide Bases” Org. Process Res. Dev. 2010, 14, 339-345.
519. Monzon, G.; Knochel, P.* “Directed ortho- and meta-magnesiation or zincation of polyfunctional aryl nonaflates” Synlett 2010, 304-308.
520. Melzig, L.; Metzger, A.; Knochel, P.* „Room Temperature Cross-Coupling of Highly Functionalized Organozinc Reagents with Thiomethylated N-Heterocycles by Nickel Catalysis” J. Org. Chem. 2010, 75, 2131-2133.
521. Rohbogner, C. J.; Diene, C. R.; Korn, T. J.; Knochel, P.* „A Cobalt-Catalyzed Sulfonate/Copper Exchange for the Preparation of Highly Functionalized Electron-Deficient Aryl Copper Reagents” Angew. Chem. Int. Ed. 2010, 49, 1874-1877.
522. Wunderlich, S. H.; Knochel, P.* „Atom-Economical Preparation of Aryl- and Heteroaryl-Lanthanum Reagents by Directed ortho-Metalation by Using tmp3[La]” Chem. Eur. J. 2010, 16, 3304-3307.
523. Bluemke, T.; Chen, Y.-H.; Peng, Z.; Knochel, P.* „Preparation of functionalized organoaluminiums by direct insertion of aluminium to unsaturated halides” Nature Chemistry 2010, 2, 313-318.
524. Crestey F.; Knochel, P.* “Regioselective Functionalization of Chlorophthalazine Derivatives” Synthesis 2010, 1097-1106.
525. Yamada, S.; Gavryushin, A.; Knochel, P.* „Convenient Electrophilic Fluorination of Functionalized Aryl and Heteroaryl Magnesium Reagents” Angew. Chem. Int. Ed. 2010, 49, 2215-2218.
526. Metzger, A.; Argyo, C.; Knochel, P.* “Large-scale preparation of polyfunctional benzylic zinc reagents by direct insertion of zinc dust into benzylic chlorides in the presence of lithium chloride” Synthesis 2010, 882-891.
527. Rohbogner, C. J.; Wirth, S.; Knochel, * “Phosphorodiamidate-Directed Metalation of N-Heterocycles using Mg- and Zn-TMP Bases” Org. Lett. 2010, 12, 1984-1987.
528. Kienle, M.; Knochel, P.* “i-PrI Acceleration of Negishi Cross-Coupling Reactions” Org. Lett. 2010, 12, 2702-2705.
529. Bluemke, T. D.; Piller, F. M.; Knochel, P.* “Preparation of highly functionalized alkylzinc halides from alkyl bromides using Mg, ZnCl2 and LiCl” Chem. Comm., 2010, 46, 4082-4084.
530. Wunderlich, S. H.; Kienle, M.; Knochel, P.* “Corrigendum: Directed Manganation of Functionalized Arenes and Heterocycles Using tmp2Mn? 2 MgCl2 ? 4 LiCl” Angew. Chem. Int. Ed. 2010, 49, 4157.
531. Piller, F. M.; Bresser, T.; Fischer, M. K. R.; Knochel, P.* “Preparation of Functionalized Cyclic Enol Phosphates by Halogen-Magnesium Exchange and Directed Deprotonation Reactions” J. Org. Chem. 2010, 75, 4365-4375.
532. Bresser, T.; Mosrin, M.; Monzon, G.; Knochel, P.* “Regio- and Chemoselective Zincation of Sensitive and Moderately Activated Aromatics and Heteroaromatics Using TMPZnCl • LiCl” J. Org. Chem. 2010, 75, 4686-4695.
533. Dunst, C.; Kienle, M.; Knochel, P.* „Preparation of Heterocyclic Amines via a Copper(I)-Mediated Oxidative Cross-Coupling of Organozinc Reagents with Lithium Amides” Synthesis 2010, 2313-2318.
534. Metzger, A.; Bernhardt, S.; Manolikakes, G.; Knochel, P.* “MgCl2-Accelerated Addition of Functionalized Organozinc Reagents to Aldehydes, Ketones, and Carbon Dioxide” Angew. Chem. Int. Ed. 2010, 49, 4665-4668.
535. Kienle, M.; Unsinn, A.; Knochel, P.* “Synthesis of Dibenzothiophenes and Related Classes of Heterocycles by Using Functionalized Dithiocarbamates” Angew. Chem. Int. Ed. 2010, 49, 4751-4754.
536. Jaric, M.; Haag, B. A.; Unsinn, A.; Karaghiosoff, K.; Knochel, P.* “Highly Selective Metalations of Pyridines and Related Heterocycles Using New Frustrated Lewis Pairs or tmp-Zinc and tmp-Magnesium Bases with BF3? OEt2” Angew. Chem. Int. Ed. 2010, 49, 5451-5455.
537. Melzig, L.; Stemper, J.; Knochel, P.* “A novel palladium-catalyzed cross-coupling of thiomethylated alkynes with functionalized organozinc reagents” Synthesis 2010, 2085-2091.
538. Schade, M. A.; Manolikakes, G.; Knochel, P.* “Preparation of Primary Amides from Functionalized Organozinc Halides” Org. Lett. 2010, 12, 3648-3650.
539. Wunderlich, S. H.; Bresser, T.; Dunst, C.; Monzon, G.; Knochel, P.* „Efficient Preparation of Polyfunctional Organometallics via Directed ortho-Metallation” Synthesis 2010, 2670-2678.
540. Yamada, S.; Knochel, P.* “Large-Scale Preparation of Aromatic Fluorides via Electrophilic Fluorination with Functionalized Aryl- or Heteroarylmagnesium Reagents” Synthesis 2010, 2490-2494.
541. Metzger, A.; Melzig, L.; Knochel, P.* “Scaled-up transition-metal-catalyzed cross-coupling reactions of thioether-substituted N-heterocycles with organozinc reagents” Synthesis 2010, 2853-2858.
542. Schade, M. A.; Fleckenstein, J. E.; Knochel, P.*; Koszinowski, K. “Charged Tags as Probes for Analyzing Organometallic Intermediates and Monitoring Cross-Coupling Reactions by Electrospray-Ionization Mass Spectrometry” J. Org. Chem. 2010, 75, 6848-6857.
544. Bresser, T.; Monzon, G.; Mosrin, M.; Knochel, P.* “Scaleable Preparation of Sensitive Functionalized Aromatics and Heteroaromatics via Directed Metalation Using tmpZnCl • LiCl” Org. Proc. Res. Dev., 2010, in press.
545. Jeganmohan, M.; Knochel, P.* “tmp4Zr: An Atom-Economical Base for the Metalation of Functionalized Arenes and Heteroarenes” Angew. Chem. Int. Ed. 2010, 49, 8520-8524.
546. Peng, Z.; Bluemke, T. D.; Mayer, P.; Knochel, P.* “Diastereoselective Synthesis of Homoallylic Alcohols with Adjacent Tertiary and Quaternary Centers by Using Functionalized Allylic Aluminum Reagents” Angew. Chem. Int. Ed. 2010, 49, 8516-8519.
547. Peng, Z.; Haag, B. A.; Knochel, P.* “Preparation of 2-Magnesiated 1,3,5-Triazines via an Iodine-Magnesium Exchange” Org. Lett. 2010, in press.
548. Lotz, M.; Schuecker, R.; Mereiter, K.; Knochel, P.* “Synthesis of Exclusively Centrostereogenic 1,3-Bidentate Ferrocenyldiphosphane Ligands and Their Use in Enantioselective Hydrogenations” Organometallics, 2010, in press.
549. Brueckl, T.; Thoma, I.; Wagner, A. J.; Knochel, P.*; Carell, T. “Efficient Synthesis of Deazaguanosine-Derived tRNA Nucleosides PreQ0, PreQ1, and Archaeosine Using the Turbo-Grignard Method” Eur. J. Org. Chem. 2010, 34, 6517-6519.
550. Haag, B. A.; Zhang, Z.-G.; Li, J.-S.; Knochel, P.* “Fischer Indole Synthesis with Organozinc Reagents” Angew. Chem. Int. Ed. 2010, 49, 9513-9516.
551. Knochel, P.*; Thaler, T.; Diene, C. „Pd-, Ni-, Fe-, and Co-Catalyzed Cross-Couplings Using Functionalized Zn-, Mg-, Fe-, and In-Organometallics” Isr. J. Chem. 2010, 50, 547-557.
552. Bernhardt, S.; Metzger, A.; Knochel, P.* “Direct addition of functionalized organozinc reagents to carbon dioxide, ketones, and aldehydes in the presence of MgCl2” Synthesis 2010, 3802-3810.
553. Kunz, T.; Knochel, P.* “Selective Multiple Magnesiations of the Thieno[3,2]-thiophene Scaffold.” Chem. Eur. J. 2011, 17, 866-872.
554. Zimdars, S.; du Jourdin, X. M.; Crestey, F.; Carell, T.; Knochel, P.* “Trifunctionalization of the Purine Scaffold Using Mg and Zn Organometallic Intermediates” Org. Lett. 2011, 13, 792-795.
555. Kienle, M.; Wagner, A. J.; Dunst, C.; Knochel, P.* ”Preparation of Heterocyclic Amines by an Oxidative Amination of Zinc Organometallics Mediated by CuI: A New Oxidative Cycloamination for the Preparation of Annulated Indole Derivatives.” Chem. Asian J. 2011, 6, 517-523.
556. Dogru, M.; Sonnauer, A.; Gavryushin, A.; Knochel, P.*; Bein, T. “A Covalent Organic Framework with 4 nm open pores.” Chem. Comm. 2011, 47, 1707-1709.
557. Zhang, Z.-G.; Haag, B. A.; Li, J-S.; Knochel, P.* „Efficient preparation of polyfunctional indoles via a zinc organometallic variation of the Fisher indole synthesis” Synthesis 2011, 23-29.
558. Seel, S.; Thaler, T.; Takatsu, K.; Zhang, C.; Zipse, H.; Straub, B. F.; Mayer, P.; Knochel, P.* „Highly Diastereoselective Arylations of Substituted Piperidines” J. Am. Chem. Soc. 2011, 133, 4774-4777.
559. Duez, S.; Bernhardt, S.; Heppekausen, J.; Fleming, F. F.; Knochel, P.* „Pd-Catalyzed ?-Arylation of Nitriles and Esters and ?-Arylation of Unsaturated Nitriles with TMPZnCl•LiCl” Org. Lett. 2011, 13, 1690-1693.
560. Melzig, L.; Metzger, A.; Knochel, P.* „Pd- and Ni-Catalyzed Cross-Coupling Reactions of Functionalized Organozinc Reagents with Unsaturated Thioethers” Chem. Eur. J. 2011, 17, 2948-2956.
561. Thaler, T.; Guo, L.-N.; Mayer, P.; Knochel, P.* “Highly Diastereoselective C(sp3–C(sp) Cross-Coupling Reactions between 1,3- and 1,4-Substituted Cyclohexylzinc Reagents and Bromoalkynes through Remote Stereocontrol” Angew. Chem. Int. Ed. 2011, 50, 2174-2177.
562. Bresser, T.; Knochel, P.* “Selective Magnesiation or Zincation of Highly Functionalized Alkenes and Cycloalkenes Using 2,2,6,6-Tetramethylpiperidyl Bases” Angew. Chem. Int. Ed. 2011, 50, 1914-1917.
563. Steib, A. K.; Thaler, T.; Komeyama, K.; Mayer, P.; Knochel, P.* „Highly Diastereoselective Iron-Mediated C(sp2–C(sp3) Cross-Coupling Reactions between Aryl Grignard Reagents and Cyclic Iodohydrine Derivatives” Angew. Chem. Int. Ed. 2011, 50, 3303-3307.
564. Schade, M. A.; Yamada, S.; Knochel, P.* “Synthesis of Polyfunctional Allenes by Succesive Copper-Mediated Substitutions” Chem. Eur. J. 2011, 17, 4232-4237.
565. Jaric, M.; Haag, B. A.; Manolikakes, S.; Knochel, P.* “Selective and Multiple Functionalization of pyridines and Alkaloids via Mg- and Zn-Organometllic Intermediates” Org. Lett. 2011, 13, 2306-2309.
566. Melzig, L.; Rauhut, C. B.; Naredi-Rainer, N.; Knochel, P.* “Disfunctionalisation of Arenes and Heteroarenes by Directed Metallation and Sulfoxide-Magnesium Exchange” Chem. Eur. J. 2011, 17, 5362-5372.
567. Zimdars, S.; Langhals, H.; Knochel, P.* „Functionalization of the Benzo[c][1,2,5]thiadiazole Scaffold vianMg-, Zn- and Mn-Intermediates” Synthesis 2011, 1302-1308.
568. Peng, Z.; Knochel, P.* “Preparation of Functionalized Organomanganese(II) Reagents by Direct Insertion of Manganese to Aromatic and Benzylic Halides” Org. Lett. 2011, 13, 3198-3201.
569. Thaler, T.; Guo, L.-N.; Steib, A. K.; Raducan, M.; Karaghiosoff, K.; Mayer, P.; Knochel, P.* “Sulfoxide-Alkene Hybrids: A New Class of Chiral Ligands for the Hayashi-Miyaura Reaction” Org. Lett. 2011, 13, 3182-3185.
570. Melzig, L.; Diene, C. R.; Rohbogner, C. J.; Knochel, P.* “Preparation of Polyfunctional Zinc Organometallics Using an Fe- or Co-Catalyzed Cl/Zn-Exchange” Org. Lett. 2011, 13, 3174-3177.
571. Duez, S.; Steib, A. K.; Manolikakes, S. M.; Knochel, P.* “Lewis Acid Promoted Benzylic Cross-Couplings of Pyridines with Aryl Bromides” Angew. Chem. Int. Ed. 2011, 50, 7686-7690.
572. Haag, B. A.; Saemann, C.; Jana, A.; Knochel, P.* “Practical One-Pot Preparation of Magnesium Di(hetero)aryl- and Magnesium Dialkenylboronates for Suzuki-Miyaura Cross-Coupling Reactions” Angew. Chem. Int. Ed. 2011, 50, 7290-7294.
573. Dunst, C.; Knochel, P.* “Regioselective Functionalization of the Thiazole Scaffold using TMPMgCl•LiCl and TMP2Zn•2MgCl2•2LiCl” J. Org. Chem. 2011, 76, 6972-6978.
574. Melzig, L.; Dennenwaldt, T.; Gavryushin, A.; Knochel, P.* “Direct Aminoalkylation of Arenes, Heteroarenes, and Alkenes via Ni-Catalyzed Negishi Cross-Coupling Reactions” J. Org. Chem. 2011, 76, 8891-8901.
575. Bernhardt, S.; Manolikakes, G.; Kunz, T.; Knochel, P.* “Preparation of Solid Salt-Stabilized Functionalized Organozinc Compounds and their Application to Cross-Coupling and Carbonyl Addition Reactions” Angew. Chem. Int. Ed. 2011, 50, 9205-9209.
576. Farina, V.; Lemaire, S.; Houpis, I.; Digard, E.; Gozlan, C.; Wang, Y.; Diene, C.; Gavryushin, A.; Knochel, P.* “New C-glycosylation methodology” Abstracts of Papers, 242nd ACS National Meeting & Exposition, Denver, CO, US, Aug. 28 – Sept. 1, 2011, ORGN-188.
577. Piller, F. M.; Knochel, P.* “Regio- and chemoselective synthesis of fully substituted furans” Synthesis 2011, 1751-1758.
578. Haag, B.; Mosrin, M.; Hiriyakkanavar, I.; Malakhov, V.; Knochel, P.* “Regio- and Chemoselective Metalation of Arenes and Heteroarenes Using Hindered Metal Amide Bases” Angew. Chem. Int. Ed. 2011, 50, 9794-9824.
579. Knochel, P.*; Schade, M. A.; Bernhardt, S.; Manolikakes, G.; Metzger, A.; Piller, F. M.; Rohbogner, C. J.; Mosrin, M. “Functionalization of heterocyclic compounds using polyfunctional magnesium and zinc reagents” Beilstein J. Org. Chem. 2011, 7, 1261-1277, No. 147.
580. Knochel, P.*; Diene, C. “Preparation of functionalized Zn- and Mg-organometallics. Application to the performance of diastereoselective cross-couplings” Compt. Rend. Chim. 2011, 14, 842-850.
581. Bluemke, T. D.; Groll, K.; Karaghiosoff, K.; Knochel, P.* “New preparation of benzylic aluminum and zinc organometallics by direct insertion of aluminum powder” Org. Lett. 2011, 6440-6443.
582. Dienstmaier, J. F.; Gigler, A. M.; Goetz, A. J.; Knochel, P.; Bein, T.; Lyapin, A.; Reichlmaier, S.; Heckl, W. M.; Lackinger, M. “Synthesis of Well-Ordered COF Monolayers: Surface Growth of Nanocrystalline Precursors versus Direct On-Surface Polycondensation” ACS Nano 2011, 5, 9737-9745.
583. Guo, L.-N.; Gao, H.; Mayer, P.; Knochel, P.* “Corrigendum: Preparation of Organoaluminum Reagents from Propargylic Bromides and Aluminum Activated by PbCl2 and Their Regio- and Diastereoselective Addition to Carbonyl Derivatives” Chem. Eur. J. 2011, 17, 12536.
584. Li, Y.; Keilbach, A.; Kienle, M.; Goto, Y.; Inagaki, S.; Knochel, P.*; Bein, T. “Hierarchically structured biphenylene-bridged periodic mesoporous organosilica” J. Mater. Chem. 2011, 21, 17338-17344.
585. Dunst, C.; Knochel, P.* “Selective Mg insertion into substituted mono- and dichloro arenes in the presence of LiCl: a new preparation of boscalid” Synlett 2011, 14, 2064-2068.
586. Dunst, C.; Metzger, A.; Zaburdaeva, E. A.; Knochel, P.* “Stereoselective Synthesis of Polyfunctional Tetrasubstituted Alkenyl Sulfides via a Carbocupration of Alkynyl Sulfides with Aryl and Benzylic Diorganozincs” Synthesis 2011, 3453-3462.
587. Knochel, P.* “Allyltrimethylsilylzinc chloride” Edited by Fuchs, P. L. From “Handbook of Reagents for Organic Synthesis: Reagents for Silicon-Mediated” Org. Synthesis 2011, 24-25.
588. Knochel, P.* “Tracking two chemistry nobel prize winners. Improved metalorganic intermediates for cross-coupling reactions” GIT Labor-Fachzeitschrift 2011, 55(11), 799-801.
589. Brodmann, T.; Koos, P.; Metzger, A.; Knochel, P.*; Ley, S. V. “Continuous Preparation of Arylmagnesium Reagents in Flow with Inline IR Monitoring” Org. Proc. Res. & Dev. 2012, 16, 1102-1113.
590. Kunz, T.; Knochel, P.* “Synthesis of Functionalized Benzo[b]thiophenes by the Intramolecular Copper-Catalyzed Carbomagnesiation of Alkynyl(aryl)thioethers” Angew. Chem. Int. Ed. 2012, 51, 1958-1961.
591. Shi, L.; Chu, Y.; Knochel, P.*; Mayr, H. “Leaving Group Dependence of the Rates of Halogen-Magnesium Exchange Reactions” Org. Lett. 2012, 14, 2602-2605.
592. Duez, S.; Steib, A. K.; Knochel, P.* “Benzylic Arylation of 2-Methyl-5-membered Heterocycles Using TMP-Bases” Org. Lett. 2012, 14, 1951-1953.
593. Lemaire, S.; Houpis, I. N.; Xiao, T.; Li, J.; Digard, E.; Gozlan, C.; Liu, R.; Gavryushin, A.; Diène, C.; Wang, Y.; Farina, V.; Knochel, P.* “Stereoselective C-Glycosylation Reactions with Arylzinc Reagents” Org. Lett. 2012, 14(6), 1480-1483.
594. Unsinn, A.; Knochel, P.* “Regioselective zincation of indazoles using TMP2Zn and Negishi cross-coupling with aryl and heteroaryl iodides” Chem. Comm. 2012, 48, 2680-2682.
595. Berionni, G.; Maji, B.; Knochel, P.*; Mayr, H. “Nucleophilicity parameters for designing transition metal-free C-C bond forming reactions of organoboron compounds” Chem. Science 2012, 3, 878-882.
596. Frischmuth, A.; Unsinn, A.; Groll, K.; Stadtmüller, H.; Knochel, P.* „Preparations and Reactions of SF5 Substituted Aryl nd Heteroaryl Derivatives via Mg and Zn Organometallics“ Chem. Eur. J. 2012, 18, 10234-10238.
597. Malysheva, Y. B.; Combes, S.; Allegro, D.; Peyrot, V.; Knochel, P.; Gavryushin, A. E.; Fedorov, A. Y. “Synthesis and biological evaluation of novel anticancer bivalent colchicine-tubulizine hybrids” Bioorg. Med. Chem. 2012, 20, 4271-4278.
598. Dienstmaier, J. F.; Medina, D. D.; Dogru, M.; Knochel, P.; Bein, T.; Heckl, W. M.; Lackinger, M. „Isoreticular Two-Dimensional Covalent Organic Frameworks Synthesized by On-Surface Condensation of Diboronic Acids“ ACS Nano, 2012, 6, 7234-7242.
599. Malysheva, Y. B.; Combes, S.; Fedorov, A. Y.; Knochel, P.; Gavryushin, A. E. “New Method of Synthesis and Biological Evaluation of Some Combretastatin A-4 Analogues” Synlett 2012, 23, 1205-1208.
600. Klier, L.; Bresser, T.; Nigst, T. A.; Karaghiosoff, K.; Knochel, P.* “Lewis Acid-Triggered Selective Zincation of Chromones, Quinolones, and Thiochromones: Application to the Preparation of Natural Flavones and Isoflavones” J. Am. Chem. Soc. 2012, 134, 13584-13587.
601. Mycka, R. J.; Duez, S.; Bernhardt, S.; Heppekausen, J.; Knochel, P.; Fleming, F. F. “Cyclohexylcarbonitriles: Diastereoselective Arylations with TMPZnCl•LiCl” J. Org. Chem. 2012, 77, 7671-7676.
602. Stathakis, C. I.; Bernhardt, S.; Quint, V.; Knochel, P.* „Improved Air-Stable Solid Aromatic and Heterocyclic Zinc Reagents by Highly Selective Metalations for Negishi Cross-Couplings” Angew. Chem. Int. Ed. 2012, 51, 9428-9432.
603. Blümke, T. D.; Klatt, T.; Koszinowski, K.; Knochel, P.* “InCl3-Catalyzed Synthesis of 1,2-Dimetallic Compounds by Direct Insertion of Aluminum or Zinc Powder” Angew. Chem. Int. Ed. 2012, 51, 9926-9930.
604. Kuzmina, O. M.; Steib, A. K.; Flubacher, D.; Knochel, P.* “Iron-Catalyzed Cross-Coupling of N-Heterocyclic Chlorides and Bromides with Arylmagnesium Reagents” Org. Lett. 2012, 14, 4818-4821.
605. Monzón, G.; Tirotta, I.; Yuji, N.; Knochel, P. “The ortho and meta Magnesiation of Functionalized Anilines and Amino-Substituted Pyridines and Pyrazines at Room Temperature” Angew. Chem Int. Ed., 2012, 51, 10624–10627.
606. Knochel, P. “Water in Organic Synthesis” Workbench Edition (Sience of Synthesis); Shu Kobayashi, Ed. Synthesis 2012, 44, 2474.
607. Groll, K.; Blümke, T. D.; Unsinn, A.; Haas, D.; Knochel, P. “Direct Pd-Catalyzed Cross-Coupling of Functionalized Organoaluminum Reagents” Angew. Chem. Int. Ed. 2012, 51, 11157-11161.
608. Sämann, C.; Haag, B.; Knochel, P. „Highly Regioselective Preparation of Heteroaryl-Magnesium Reagents by Using a Br/Mg Exchange“ Chem. Eur. J. 2012, 18, 16145-16152.
609. Dogru, M.; Handloser, M.; Auras, F.; Kunz, T.; Medina, D.; Hartschuh, A.; Knochel, P.*; Bein, T.* „A Photoconductive Thienothiophene-Based Covalent Organic Framework Showing Charge Transfer Towards Included Fullerene“ Angew. Chem. Int. Ed. 2013, 52, 2920-2924.
610. Monzon, G.; Tirotta, I.; Knochel, P.* “Corrigendum: The ortho and meta Magnesiation of Functionalized Anilines and Amino-Substituted Pyridines and Pyrazines at Room Temperature“ Angew. Chem. Int. Ed. 2012, 51, 11662.
611. Langhals, H.; Knochel, P.; Walter, A.; Zimdars, S. “Benzothiadiazoloperylenes and Benzoxadiazoloperylenes: Amorphous Functional Materials” Synthesis 2012, 44, 3465-3477.
612. Unsinn, A.; Dunst, C.; Knochel, P. „Stereoselective synthesis of tetrasubstituted alkenes via a sequential cabocupration and a new sulfur-lithium exchange“ Beilstein J. Org. Chem. 2012, 8, 2202-2206.
614. Seel, S.; Dagousset, G.; Thaler, T.; Frischmuth, A.; Karaghiosoff, K.; Zipse, H.; Knochel, P.* „Preparation of Stereodefined Secondary Alkyllithium Compounds“ Chem. Eur. J. 2013, 19, 4614-4622.
615. Dogru, M.; Sonnauer, A.: Zimdars, S.: Döblinger, M.; Knochel, P.; Bein, T.* „Facile synthesis of a mesoporous benzothiadiazole-COF based on a transesterification process“ CrystEngComm 2013, 15, 1500-1502.
616. Manolikakes, S. M.; Jaric, M.; Karaghiosoff, K.; Knochel, P.* „Metalated N-heterocyclic reagents prepared by the frustrated Lewis pair TMPMgCl•BF3 and their addition to aromatic aldehydes and activated ketones” Chem. Comm. 2013, 49, 2124-2126.
617. Unsinn, A.; Ford, M. J.; Knochel, P.* „New Preparation of TMPZnCl•LiCl by Zn Insertion into TMPCI. Application to the Functionalization of Dibromodiazines” Org. Lett. 2013, 15, 1128-1131.
618. Stathakis, C. I.; Manolikakes, S. M.; Knochel, P.* “TMPZnOPiv•LiCl: A New Base for the Preparation of Air-Stable Solid Zinc Pivalates of Sensitive Aromatics and Heteroaromatics” Org. Lett. 2013, 15, 1302-1305.
619. Unsinn, A.; Wunderlich, S. H.; Knochel, P.* „Accelerated Zincations for an Efficient and Mild Functionalization of Aromatics and Heterocycles“ Adv. Synt. & Cat. 2013, 355, 989-995.
620. Quan, C.; Mollat du Jourdin, X.; Knochel, P.* “Transition-Metal-Free BF3-Mediated Regioselective Direct Alkylation and Arylation of Functionalized Pyridines Using Grignard or Organozinc Reagents” J. Am. Chem. Soc. 2013, 135, 4958-4961.
621. Kuzmina, O. M.; Steib, A. K.; Markiewicz, J. T.; Flubacher, D.; Knochel, P.* “Ligand-Accelerated Iron-and Cobalt-Catalyzed Cross-Coupling Reactions between N-Heteroaryl Halides and Aryl Magnesium Reagents” Angew. Chem. Int. Ed. 2013, 52, 4945-4949.
622. Berionni, G.; Morozova, V.; Heininger, M.; Mayer, P.; Knochel, P.; Mayr, H.* “Electrophilic Aromatic Substitutions of Aryltrifluoroborates with Retention of the BF3-Group: Quantification of the Activating and Directing Effects of the Trifluoroborate Group” J. Am. Chem. Soc. 2013, 135, 6317-6324.
623. Sämann, C.; Schade, M.A.; Yamada, S; Knochel, P.* “Functionalized Alkenylzinc Reagents Bearing Carbonyl Groups: Preparation by Direct Metal Insertion and Reaction with Electrophiles” Angew. Chem. Int. Ed. 2013, 52, 9495-9499.
624. Unsinn, A.; Rohbogner, C. J.; Knochel, P.* “Directed Magnesiation of Polyhaloaromatics using the Tetramethylpiperidylmagnesium Reagents TMP2Mg•2LiCl and TMPMgCl•LiCl” Adv. Syn. & Cat. 2013, 355, 1553-1560.
625. Groll, K.; Manolikakes, S. M.; Mollat du Jourdin, X.; Jaric, M.; Bredihhin, A.; Karaghiosoff, K.; Carell, T.; Knochel, P.* “Regioselective Metalations of Pyrimidines and Pyrazines by Using Frustrated Lewis Pairs of BF3•OEt2 and Hindered Magnesium- and Zinc-Amide Bases” Angew. Chem. Int. Ed. 2013, 52, 6776-6780.
626. Klatt, T.; Groll, K.; Knochel, P.* “Generation of functionalized aryl and heteroaryl aluminum reagents by halogen-lithium exchange” Chem. Comm. 2013, 49, 6953-6955.
627. Barl, N. M.; Sansiaume-Dagousset, E.; Karaghiosoff, K.; Knochel, P.* „Full Functionalization of the 7-Azaindole Scaffold by Selective Metalation and Sulfoxide/Magnesium Exchange” Angew. Chem. Int. Ed. 2013, 52, 10093-10096.
628. Manolikakes, S. M.; Barl, N. M.; Saemann, C.; Knochel, P.* “Regioselective functionalization of pyridines using a directed metalation or a halogen/metal exchange” Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences 2013, 68, 411-422.
629. Frischmuth, A.; Knochel, P.* „Preparation of Functionalized Indoles and Azaindoles by the Intramolecular Copper-Mediated Carbomagnesiation of Ynamides” Angew. Chem. Int. Ed. 2013, 52, 10084-10088.
630. Sämann, C.; Knochel, P.* “A Convenient Synthesis of ?-Substituted ?,?-Unsaturated Ketones and Esters via the Direct Addition of substituted Allylic Zinc Reagents Prepared by Direct Insertion“ Synthesis 2013, 45, 1870-1876.
631. Druzhinin, S. I.; Dubbaka, S. R.; Knochel, P.; Kovalenko, S. A.; Mayer, P.; Senyushkina, T.; Zachariasse, K. A. Correction to “Ultrafast Intramolecular Charge Transfer with Strongly Twisted Aminobenzonitriles: 4-(Di-tert-butylamino)benzonitrile and 3-(Di-tert-butylamino)benzonitrile” J. Phys. Chem. A 2008, 112, 2749-2761.
632. Unsinn, A.; Wunderlich, S. H.; Jana, A.; Karaghiosoff, K.; Knochel, P.* “A Convenient Alumination of Functionalized Aromatics by Using the Frustrated Lewis Pair Et3Al and TMPMgCl•LiCl” Chem. Eur. J. 2013, 19, 14687-14696.
633. Steib, A. K.; Kuzmina, O. M.; Fernandez, S.; Flubacher, D.; Knochel, P.* „Efficient Chromium(II)-Catalyzed Cross-Coupling Reactions between Csp2 Centers“ J. Am. Chem. Soc. 2013, 135, 15346-15349.
634. Benhaim, C.; Lemaire, S.; Gaekens, T.; Govaerts, T.; Houpis, I. N.; Reniers, P.; Looy, A. V.; Vermeulen, W. A. A.; Bernhardt, S.; Diène, C.; Knochel, P.* „Synthesis of (4’R)-azido-(2’R)-2‘-deoxy-2‘-C-methyluridine and its esters by direct iodide displacement“ Synlett 2013, 24, 1697-1701.
635. Hiriyakkanavar, I.; Markiewicz, J. T.; Malakhov, V.; Knochel, P.* “Metalated indoles, indazoles, benzimidazoles, and azaindoles and their synthetic applications” Synthesis 2013, 45, 2343-2371.
636. Knochel, P. “Organomagnesium and organozinc chemistry” in “Organometallics in Synthesis” Ed.: Schlosser, M. Wiley –VCH Verlag, Weinheim, 2013, 223-372.
637. Haas, D.; Mosrin, M.; Knochel, P.* „Regioselective Functionalization of the Oxazole Scaffold Using TMP-Bases of Mg and Zn” Org. Lett. 2013, 15, 6162-6165.
638. Knochel, P.; Bluemke, T.; Groll, K. Chen, Y-H. “Preparation organoalanes for organic synthesis” in “Topics in Organometallic Chemistry” Springer-Verlag 2013, 41, 173-186.
639. Colombe, J. R.; Bernhardt, S.; Stathakis, C.; Buchwald, St. L.; Knochel, P.* „Synthesis of Solid 2-Pyridylzinc Reagents and Their Application in Negishi Reactions“ Org. Lett. 2013, 15, 5754-5757.
640. Crestey, F.; Zimdars, S.; Knochel, P*. „Regioselective functionalization of purine derivatives at positions 8 and 6 using hindered TMP-amide bases of Zn and Mg“ Synthesis 2013, 45, 3029-3037.
641. Dagousset, G.; Moriya, K.; Mose, R.; Berionni, G.; Karaghiosoff, K.; Knochel, P.* „Diastereoselective Synthesis of Open-Chain Secondary Alkyllithiums Compounds and Trapping Reactions with Electrophiles“ Angew. Chem. Int. Ed. 2014, 53, 1425-1429.
642. Didier, D.; Delaye, P.-O.; Simaan, M.; Island, B.; Eppe, G.; Eijsberg, H.; Kleiner, A.; Knochel, P.; Marek, I.* „Modulable and Highly Diastereoselective Carbometalations of Cyclopropenes” Chem. Eur. J. 2014, 20, 1038-1048.
643. Hernán-Gómez, A.; Herd, E.; Hevia, E.; Kennedy, A. R.; Knochel, P.*; Koszinovski, K.; Manolikakes, S.; Mulvey, R. E.*; Schnegelsberg, C. “Organozinc Pivalate Reagents: Segregation, Solubility, Stabilisation and Structural Insights” Angew. Chem. Int. Ed. 2014, 53, 2706-2710.
644. Sämann, C.; Coya, E.; Knochel, P.* „Full Functionalization of the Imidazole Scaffold by Selective Metalation and Sulfoxide/Magnesium Exchange“ Angew. Chem. Int. Ed. 2014, 53, 1430-1434.
645. Shen, Z.; Peng, Z.; Yang, C.; Helberg, J.; Mayer, P.; Marek, I.; Knochel, P.* „Highly Diastereoselective Preparation of Aldol Products Using New Functionalized Allylic Aluminum Reagents” Org. Lett. 2014, 16, 956-959.
646. Barl, N.; Werner, V.; Saemann, C.; Knochel, P.* “The halogen/magnesium-exchange using iPrMgCl•LiCl and related exchange reagents” Heterocycles 2014, 88, 827-844.
647. Moriya, K.; Knochel, P.* “Diastereoconvergent Negishi Cross-Coupling Using Functionalized Cyclohexylzinc Reagents” Org. Lett. 2014, 16, 924-927.
648. Klatt, T.; Roman, Daniela S.; Leon, T.; Knochel, P.* “TMP-Magnesium and TMP-Zinc Bases for the Regioselective Metalation of the Cinnoline Scaffold” Org. Lett. 2014, 16, 1232-1235.
649. Medina, D.; Werner, V.; Auras, F.; Tautz, R.; Dogru, M.; Schuster, J.; Linke, S.; Doblinger, M.; Feldmann, J.; Knochel, P.;* Bein, T. “Oriented Thin Films of a Benzodithiophene Covalent Organic Framework” ACS Nano 2014, ACS Nano 2014, 8, 4042-4052.
650. Knochel, P. “Award Address (Herbert C. Brown Award for Creative Research in Synthetic Methods sponsored by the Purdue Borane Research Fund and the Herbert C. Brown Award Endowment). Polyfunctional Zn- and Mg-organometallics in organic synthesis” Abstracts of Papers, 247th ACS National Meeting & Exposition, Dallas, TX, United States, March 16-20, 2014 (2014), ORGN-204.
651. Chen, Q.; Leon, T.; Knochel, P.* “Transition-Metal-Free BF3-Mediated Oxidative and Non-Oxidative Cross-Coupling of Pyridines” Angew. Chem. Int. Ed. 2014, in print.
652. Saemann, C.; Dhayalan, V.; Schreiner, P. R.; Knochel, P.* “Synthesis of Substituted Adamantylzinc Reagents Using a Mg-Insertion in the Presence of ZnCl2 and Further Functionalizations” Org. Lett. 2014, 16, 2418-2421.
653. Barl, N. M.; Sansiaume-Dagousset, E.; Monzon, G.; Wagner, A. J.; Knochel, P.* „Preparation and Reactions of Heteroarylmethylzinc Reagents” Org. Lett. 2014, 16, 2422-2425.
654. Klatt, T.; Markiewicz, J. T.; Saemann, C.; Knochel, P* „Strategies to Prepare and Use Functionalized Organometallic Reagents” J. Org. Chem. 2014, in print.
655. Werner, V.; Klatt, T.; Fujii, M.; Markiewicz, Jen.; Apeloig, Y.; Knochel, P.* „Preparation and Regioselective Metalation of Bis(trimethylsilyl)methyl-Substituted Aryl Derivatives” Chem. Eur. J. 2014, 20, 8338-8342.
656. Frischmuth, A.; Fernandez, M.; Barl, N. M.; Achrainer, F.; Zipse, H.; Berionni, G.; Mayr, H.; Karaghiosoff, K.; Knochel, P.* „New In Situ Trapping Metalations of Functionalized Arenes and Heteroarenes with TMPLi in the Presence of ZnCl2 and Other Metal Salts” Angew. Chem. Int. Ed. 2014, in print.
657. Petersen, T. P.; Becker, M. R.; Knochel, P.* „Continuous Flow Magnesiation of Functionalized Heterocycles and Acrylates with TMPMgCl•LiCl” Angew. Chem. Int. Ed. 2014, in print.
658. Kuzmina, O. M.; Knochel, P.* “Room-Temperature Chromium(II)-Catalyzed Direct Arylation of Pyridines, Aryl Oxazolines, and Imines Using Arylmagnesium Reagents” Org. Lett. 2014, in print.
659. Klatt, T.; Bluemke, T. D.; Ganiek, M. A.; Knochel, P.* “Synthesis of 1,2-dimetallic compounds via direct insertion of zinc powder in the presence of InCl3: synthesis of ortho-bis-functionalized aromatics” Synthesis 2014, 6, 290-294.
660. Manolikakes, S. M.; Ellwart, M.; Stathakis, C. I.; Knochel, P.* “Air-Stable Solid Aryl and Heteroaryl Organozinc Pivalates: Syntheses and Applications in Organic Synthesis” Chem. Eur. J. 2014, 20, 12289-12297.
661. Klier, L.; Diene, C. R.; Schickinger, M.; Metzger, A.; Wagner, A. J.; Karaghiosoff, K.; Marek, I.; Knochel, P.* „Isoxazole-Embedded Allylic Zinc Reagent for the Diastereoselective Preparation of Highly Functionalized Aldol-Type Derivatives Bearing a Stereocontrolled Quaternary Center” Chem. Eur. J. 2014, Ahead of Print.
662. Leon, T.; Quinio, P.; Chen, Q.; Knochel, P.* “BF3-mediated oxidative cross-coupling of pyridines with alkynyllithium reagents and further reductive functionalizations of the pyridine scaffold” Synthesis 2014, 10, 1374-1379.
663. Blanc, R.; Groll, K.; Bernhardt, S.; Stockmann, P. N.; Knochel, P.* “Efficient cross-coupling reactions of (pivaloyloxymethyl)zinc chloride” Synthesis 2014, 8, 1052-1058.
664. Kuzmina, O. M.; Knochel, P.* „Room-Temperature Chromium(II)-Catalyzed Direct Arylation of Pyridines, Aryl Oxazolines, and Imines Using Arylmagnesium Reagents” Org. Lett. 2014, 16, 5208-5211.
665. Nafe, J.; Herbert, S.; Auras, F.; Karaghiosoff, K.; Bein, T.; Knochel, P.* “Functionalization of Quinoxalines by Using TMP Bases: Preparation of Tetracyclic Heterocycles with High Photoluminescene Quantum Yields” Chem. Eur. J. 2014, Ahead of Print.
666. Dagousset, G.; Francois, C.; Leon, T.; Blanc, R.; Sansiaume-Dagousset, E.; Knochel, P.* “Preparation of Functionalized Lithium, Magnesium, Aluminum, Zinc, Manganese, and Indium Organometallics from Functionalized Organic Halides” Synthesis 2014, 46, 3133-3171.
667. Steib, A. K.; Kuzmina, O. M.; Fernandez, S.; Malhotra, S.; Knochel, P.* „Chemoselective Chromium(II)-Catalyzed Cross-Coupling Reactions of Dichlorinated Heteroaromatics with Functionalized Aryl Grignard Reagents” Chem. Eur. J. 2014, Ahead of Print.
668. Hammann, J. M.; Steib, A. K.; Knochel, P.* „Cobalt-Mediated Diastereoselective Cross-Coupling Reactions between Cyclic Halohydrins and Arylmagnesium Reagents” Org. Lett. 2014, 16, 6500-6503.
669. Knochel, P.*; Editor “Comprehensive Organic Synthesis: Second Edition: Volume 7: Oxidation” 933 pp., Book, 2014, ISBN: 978-0-08-097742-3, Elsevier B.V., Amsterdam, Neth.
670. Steib, A. K.; Kuzmina, O. M.; Fernandez, S.; Malhotra, S.; Knochel, P.* „Chemoselective Chromium(II)-Catalyzed Cross-Coupling Reactions of Dichlorinated Heteroaromatics with Functionalized Aryl Grignard Reagents” Chem. Eur. J. 2015, 21, 1961-1965.
671. Barl, N. M.; Malakhov, V.; Mathes, C.; Lustenberger, P.; Knochel, P.* „Palladium-Catalyzed Cross-Coupling between 7-Azaindoles and Reformatsky Reagents” Synthesis 2015, 47, 692-700.
672. Nafe, J.; Herbert, S.; Auras, F.; Karaghiosoff, K.; Bein, T.; Knochel, P.* “Functionalization of Quinoxalines by Using TMP Bases: Preparation of Tetracyclic Heterocycles with High Photoluminescene Quantum Yields” Chem. Eur. J. 2015, 23, 1102-1107.
673. Medina, D. D.; Rotter, J. M.; Hu, Y.; Dogru, M.; Werner, V.; Auras, F.; Markiewicz, J. T.; Knochel, P.*; Bein, T. „Room Temperature Synthesis of Covalent-Organic Framework Films through Vapor-Assisted Conversion” J. Am. Chem. Soc. 2015, 137, 1016-1019.
674. Dhayalan, V.; Saemann, C.; Knochel, P.* „Synthesis of polyfunctional secondary amines by the addition of functionalized zinc reagents to nitrosoarenes” Chem. Commun., 2015, 51, 3239-3242.
675. Quinio, P.; Benischke, A. D.; Moyeux, A.; Cahiez, G.; Knochel, P.* „New Preparation of Benzylic Manganese Chlorides by the Direct Insertion of Magnesium into Benzylic Chlorides in the Presence of MnCl2•2LiCl” Synlett 2015, 26, 514-518.
676. Moriya, K.; Didier, D.; Simon, M.; Hammann, J. M.; Berionni, G.; Karaghiosoff, K.; Zipse, H.; Mayr, H.; Knochel, P.* „Stereoselective Synthesis and Reactions of Secondary Alkyllithium Reagents Functionalized at the 3-Position” Angew. Chem. Int. Ed. 2015, 54, 2754-2757.
677. Quinio, P.; François, C.; Escribano C., A.; Steib, A. K.; Achrainer, F.; Zipse, H.; Karaghiosoff, K.; Knochel, P.* “Preparation of Tri- and Tetrasubstituted Allenes via Regioselective Lateral Metalation of Benzylic (Trimethylsilyl)alkynes Using TMPZnCl•LiCl” Org. Lett. 2015, 17, 1010-1013.
678. Steib, A. K.; Fernandez, S.; Kuzmina, O. M.; Corpet, M.; Gosmini, C.; Knochel, P.* „Chromium(II)-Catalyzed Amination of N-Heterocyclic Chlorides with Magnesium Amides” Synlett 2015, 26, 1049-1054.
679. Hammann, J. M.; Haas, D.; Steib, A. K.; Knochel, P.* „Highly Diastereoselective Cobalt-Mediated C(sp3)-C(sp2) Cross-Coupling Reactions of Cyclic Halohydrins with (Hetero)Aryl Grignard Reagents” Synthesis 2015, 47, 1461-1468.
680. Shen, Z.-L.; Knochel, P.* „C60-Catalyzed Preparation of Aryl and Heteroaryl Magnesium and Zinc Reagents Using Mg/LiCl” ACS Catal. 2015, 5, 2324-2328.
681. Haas, D.; Hofmayer, M- S.; Bresser, T.; Knochel, P.* „Zincation of 4,4-dimethyloxazoline using TMPZnCl•LiCl. A new preparation of 2-aryloxazolines“ Chem. Commun. 2015, 51, 6415-6417.
682. Hammann, J. M.; Haas, D.; Knochel, P.* „Cobalt-Catalyzed Negishi Cross-Coupling Reactions of (Hetero)Arylzinc Reagents with Primary and Secondary Alkyl Bromides and Iodides” Angew. Chem. Int. Ed. 2015, 54, 4478-4481.
683. Shen, Z.-L.; Knochel, P.* “Stereoselective Preparation of Polyfunctional Alkenylindium(III) Halides and Their Cross-Coupling with Unsaturated Halides” Chem. Eur. J. 2015, 21, 7061-7065.
684. Kuzmina, O. M.; Steib, A. K.; Moyeux, A.; Cahiez, G.; Knochel, P.* „Recent Advances in Iron-Catalyzed Csp2-Csp2 Cross-Couplings” Synthesis 2015, 47, 1696-1705.
685. Werner, V.; Ellwart, M.; Wagner, A. J.; Knochel, P.* „Preparation of Tertiary Amines by the Reaction of Iminium Ions Derived from Unsymmetrical Aminals with Zinc and Magnesium Organometallics” Org. Lett. 2015, 17, 2026-2029.
686. Klatt, T.; Werner, V.; Maximova, M. G.; Didier, D.; Apeloig, Y.; Knochel, P.* “Preparation and Regioselective Magnesiation or Lithiation of Bis(trimethylsilyl)methyl-Substituted Heteroaryls for the Generation of Highly Functionalized Heterocycles” Chem. Eur. J. 2015, 21, 7830-7834.
687. Kuzmina, O. M.; Steib, A. K.; Fernandez, S.; Boudot, W.; Markiewicz, J. T.; Knochel, P.* “Practical Iron- and Cobalt-Catalyzed Cross-Coupling Reactions between N-Heterocyclic Halides and Aryl or Heteroaryl Magnesium Reagents” Chem. Eur. J. 2015, 21, 8242-8249.
688. Knochel, P. “Natural Products in the Chemical Industry by Bernd Schafer” Synthesis 2015, 47, 1356.
689. Corral-Bautista, F.; Klier, L.; Knochel, P.*; Mayr, H. “From Carbanions to Organometallic Compounds: Quantification of Metal Ion Effects on Nucleophilic Reactivities” Angew. Chem. Int. Ed. 2015, in print.
690. Becker, M. R.; Knochel, P.* „Practical Continuous-Flow Trapping Metalations of Functionalized Arenes and Heteroarenes Using TMPLi in the Presence of Mg, Zn, Cu, or La Halides” Angew. Chem. Int. Ed. 2015, in print.
691. Shen, Z.-L.; Sommer, K.; Knochel, P.* “Expedient Preparation of Aryllithium and Arylzinc Reagents from Aryl Chlorides Using Lithium 4,4'-Di-tert-Butylbiphenylide and Zinc(II) Chloride” Synthesis 2015, in print.
692. Schluecker, T.; Dhayalan, V.; Langhals, H.; Saemann, C.; Knochel, P.* „Soluble Adamantyl-Substituted Oligothiophenes with Short Fluorescence Decay: An Approach for Ultrafast Optical Signal Processing” Asian J. Org. Chem. 2015, in print.
693. Haas, D.; Hammann, J. M.; Moyeux, A.; Cahiez, G.; Knochel, P.* „Oxidative Homocoupling of Diheteroaryl- or Diarylmanganese Reagents Generated via Directed Manganation Using TMP2Mn” Synlett 2015, in print.
694. Ellwart, M.; Knochel, P.* “Preparation of Solid, Substituted Allylic Zinc Reagents and Their Reactions with Electrophiles” Angew. Chem. Int. Ed. 2015, 54, 10662-10665.
695. Becker, M. R.; Ganiek, M. A.; Knochel, P.* “Practical and economic lithiations of functionalized arenes and heteroarenes using Cy2NLi in the presence of Mg, Zn or La halides in a continuous flow” Chem. Science 2015, 6, 6649-6653.
696. Moriya, K.; Simon, M.; Mose, R.; Karaghiosoff, K.; Knochel, P.* „Stereoselective retentive domino transmetalations of secondary alkyllithium compounds to functionalized secondary alkylcopper reagents” Angew. Chem. Int. Ed. 2015, 54, 10963-10967.
697. Dhayalan, Vasudevan; Knochel, P.* “Synthesis of polyfunctional secondary amines by the reaction of functionalized organomagnesium reagents with tertiary nitroalkanes” Synthesis 2015, 47, 3246-3256.
698. Quinio, P.; Roman, D. S.; Leon, T.; William, S.; Karaghiosoff, K.; Knochel, P.* “Transition-Metal-Free Cross-Coupling of Aryl and N-Heteroaryl Cyanides with Benzylic Zinc Reagents” Org. Lett. 2015, 17, 4396-4399.
699. Dhayalan, Vasudevan; Alcaniz, F. R.; Werner, V.; Karaghiosoff, K.; Knochel, P.* „Preparation of a New Spirobi[thieno[2,3-c]pyran] and Its Selective Mono- and Dimetalation: Application for the Preparation of Soluble Conjugated Oligothiophenes and Pyrene Derivatives” Synthesis 2015, Synthesis 2015, 47, 3972-3982.
700. Nafe, J.; Auras, F.; Karaghiosoff, K.; Bein, T.; Knochel, P.* “Selective Functionalization of Tetrathiafulvalene Using Mg- and Zn-TMP-Bases: Preparation of Mono-, Di-, Tri-, and Tetrasubstituted Derivatives” Org. Lett. 2015, 17, 5356-5359.
701. Moegling, J.; Benischke, A. D.; Hammann, J. M.; Veprek, N. A.; Zoller, F.; Rendenbach, B.; Hoffmann, A.; Sievers, H.; Schuster, M.; Knochel, P.*; Herres-Pawlis, S. “Bis(pyrazolyl)methane Copper Complexes as Robust and Efficient Catalysts for Sonogashira Couplings” Eur. J. Org. Chem. 2015, 7475–7483.
702. Druzhinin, S. I.; Galievsky, V. A.; Demeter, A.; Kovalenko, S. A.; Senyushkina, T. A.; Dubbaka, S. R.; Knochel, P.*; Mayer, P.; Grosse, C.; Stalke, D.; Zachariasse, K. A. “Two-State Intramolecular Charge Transfer (ICT) with 3,5-Dimethyl-4-(Dimethylamino)benzonitrile (MMD) and Its Meta-Isomer mMMD. Ground State Amino Twist Not Essential for ICT” J. Phys. Chem. A 2015, J. Phys. Chem. A 2015, 119, 11820-11836.
703. Moriya, K.; Simon, M.; Mose, R.; Karaghiosoff, K.; Knochel, P.* “Stereoselective retentive domino transmetalations of secondary alkyllithium compounds to functionalized secondary alkylcopper reagents [Erratum to document cited in CA163:373882]” Angew. Chem. Int. Ed. 2015, 54, 12537.
704. Ren, H.; Knochel, P.* “Chemoselective benzylic C-H activations for the preparation of condensed N-heterocycles [Erratum to document cited in CA145:188632]” Angew. Chem. Int. Ed. 2015, 54, 8584.
705. Ren, H.; Li, Z.; Knochel, P.* “Chemoselective C(sp3)-H Activations for the Preparation of Condensed N-Heterocycles” (CORRIGENDUM) Chem. Asian J. 2015, 10, 1812.
706. Snieckus, V.; Knochel, P.* “Cluster Preface: Resurgence of Synthetic Aromatic Chemistry” Synlett 2015, 26, 2782-2783.
707. Castello-Mico, Alicia; Herbert, Simon A.; Leon, Thierry; Bein, Thomas; Knochel, P.* “Functionalizations of Mixtures of Regioisomeric Aryllithium Compounds by Selective Trapping with Dichlorozirconocene” Angew. Chem. Int. Ed. 2016, 55, 401.
708. Greiner, R.; Blanc, R.; Petermayer, C.; Karaghiosoff, K.; Knochel, P.* “Preparation of Functionalized 2,7-Naphthyridines by Directed Lithiation with (2,2,6,6-Tetramethylpiperidyl)lithium and Their Regioselective Iron-Catalyzed Cross Couplings” Synlett 2016, 27, 231-236.
709. Nafe, J.; Knochel, P.* “Selective Metalation of 1,3-Dithiole-2-thiones: An Effective Preparation of New Symmetrically and Nonsymmetrically Tetraarylated Tetrathiafulvalenes” Synthesis 2016, 48, 103-114.
710. Benischke, A. D.; Ellwart, M.; Becker, M. R.; Knochel, P.* „Polyfunctional Zinc and Magnesium Organometallics for Organic Synthesis: Some Perspectives” Synthesis 2016, 48, 1101-1107.
711. Benischke, A. D.; Knoll, I.; Rerat, A.; Gosmini, C.; Knochel, P.* „A practical cobalt-catalyzed cross-coupling of benzylic zinc reagents with aryl and heteroaryl bromides or chlorides” Chem. Comm. 2016, 52, 3171-3174.
712. Haas, D.; Hammann, J. M.; Greiner, R.; Knochel, P.* “Recent Developments in Negishi Cross-Coupling Reactions” ACS Catal. 2016, 6, 1540-1552.
713. Ganiek, M. A.; Becker, M. R.; Ketels, M.; Knochel, P.* “Continuous Flow Magnesiation or Zincation of Acrylonitriles, Acrylates, and Nitroolefins. Application to the Synthesis of Butenolides” Org. Lett. 2016, 18, 828-831.
714. Benischke, A. D.; Breuillac, A. J. A.; Moyeux, A.; Cahiez, G.; Knochel, P.* “Iron-Catalyzed Cross-Coupling of Benzylic Manganese Chlorides with Aryl and Heteroaryl Halides” Synlett 2016, 27, 471-476.
715. Haas, D.; Hammann, J. M.; Lutter, F. H.; Knochel, P.* “Mild Cobalt-Catalyzed Negishi Cross-Couplings of (Hetero)arylzinc Reagents with (Hetero)aryl Halides” Angew. Chem., Int. Ed. 2016, 55, 3809-3812.
716. Klier, L.; Aranzamendi, E.; Ziegler, D.; Nickel, J.; Karaghiosoff, K.; Carell, T.; Knochel, P.* „Lewis Acid Triggered Regioselective Magnesiation and Zincation of Uracils, Uridines, and Cytidines” Org. Lett. 2016, 18, 1068-1071.
717. Barroso, S.; Lemaire, S.; Farina, V.; Steib, A. K.; Blanc, R.; Knochel, P.* “Cine Substitution with Arylzinc Reagents: Scope and Mechanistic Studies” J. Org. Chem. 2016, 81, 2804-2816.
718. Becker, M. R.; Knochel, P.* „High-Temperature Continuous-Flow Zincations of Functionalized Arenes and Heteroarenes Using (Cy2N)2Zn•2LiCl” Org. Lett. 2016, 18, 1462-1465.
719. Lohse, M. S.; Rotter, J. M.; Margraf, J. T.; Werner, V.; Becker, M.; Herbert, S.; Knochel, P.*; Clark, T.; Bein, T.; Medina, D. D. „From benzodithiophene to diethoxy-benzodithiophene covalent organic frameworks - structural investigations” CrystEngComm 2016, in print.
720. Shen, Z.-L.; Dhayalan, V.; Benischke, A. D.; Greiner, R.; Karaghiosoff, K.; Mayer, P.; Knochel, P.* „Polyfunctional Lithium, Magnesium, and Zinc Alkenyl Reagents as Building Blocks for the Synthesis of Complex Heterocycles” Angew. Chem., Int. Ed. 2016, in print.
721. Quinio, P.; Kohout, L.; Roman, D. S.; Gaar, J.; Karaghiosoff, K.; Knochel, P.* „Sc(OTf)3-Catalyzed Addition of Bromomagnesium 2-Vinyloxy Ethoxide to Various Aldehydes Leading to Protected Aldol Products” Synlett 2016, in print.
722. Moriya, K.; Schwaerzer, K.; Karaghiosoff, K.; Knochel, P.* „Stereoselective Synthesis of Secondary Alkyllithiums and Their Application to Stereoselective Cuprations or Intramolecular Carbolithiations for the Stereoselective Synthesis of Alkylidenecyclobutanes” Synthesis 2016, 48, 3141-3154.
723. Morozova, V.; Moriya, K.; Mayer, P.; Knochel, P.* “Stereoselective Synthesis and Retentive Trapping of α-Chiral Secondary Alkyllithiums Leading to Stereodefined α,β-Dimethyl Carboxylic Esters” Chem. Eur. J. 2016, 22, 9962-9965.
724. Fernandez, S.; Ganiek, M. A.; Karpacheva, M.; Hanusch, F. C.; Reuter, S.; Bein, T.; Auras, F.; Knochel, P.* „Synthesis and Reactivity of Triazaphenanthrenes” Org. Lett. 2016, 18, 3158-3161.
725. Ellwart, M.; Makarov, I. S.; Achrainer, F.; Zipse, H.; Knochel, P.* „Regioselective Transition-Metal-Free Allyl-Allyl Cross-Couplings” Angew. Chem. Int. Ed. 2016, 55, 10502-10506.
726. Benischke, A. D.; Leroux, M.; Knoll, I.; Knochel, P.* „Iron-Catalyzed Acylation of Polyfunctionalized Aryl- and Benzylzinc Halides with Acid Chlorides” Org. Lett. 2016, 18, 3626-3629.
727. Nickel, J.; Fernandez, M.; Klier, L.; Knochel, P.* „Synthesis of Pyrrolo[2,3-d]pyrimidines by Copper-Mediated Carbomagnesiations of N-Sulfonyl Ynamides and Application to the Preparation of Rigidin A and a 7-Azaserotonin Derivative” Chem. Eur. J. 2016, 22, 14397-14400.
728. Hammann, J. M.; Haas, D.; Tüllmann, C.-P.; Karaghiosoff, K.; Knochel, P.* „Diastereoselective Cobalt-Mediated Cross-Couplings of Cycloalkyl Iodides with Alkynyl or (Hetero)Aryl Grignard Reagents” Org. Lett. 2016, 18, 4778−4781.
729. Greshock, T. J.;* Moore, K. P.; McClain, R. T.; Bellomo, A.; Chung, C. K.; Dreher, S. D.; Kutchukian, P. S.; Peng, Z.; Davies, I. W.; Vachal, P.; Ellwart, M.; Manolikakes, S M.; Knochel, P.* and Nantermet, P. G. “Synthesis of Complex Druglike Molecules by the Use of Highly Functionalized Bench-Stable Organozinc Reagents” Angew. Chem. Int. Ed. 2016, 55, 13714-13718.
730. Knochel, P. “Jean F. Normant (1936-2016)“ Angew. Chem. Int. Ed. 2016, 55, 13376.
731. Haas, D.; Sustac-Roman, D.; Schwarz, S.; Knochel, P.* „Directed Zincation with TMPZnCl·LiCl and Further Functionalization of the Tropolone Scaffold” Org. Lett. 2016, 18, 6380-6383.
732. Hofmayer, M. S.; Hammann, J. M.; Haas, D.; Knochel, P.* „Cobalt-Catalyzed C(sp2)-C(sp3) Cross-Coupling Reactions of Diarylmanganese Reagents with Secondary Alkyl Iodides” Org. Lett. 2016, 18, 6456-6459.
733. Bellan, A. B.; Kuzmina, O. M.; Vetsova, V. A.; Knochel, P.* „Chromium-Catalyzed Cross-Coupling Reactions of Alkylmagnesium Reagents with Halo-Quinolines and Activated Aryl Chlorides” Synthesis 2017, 49, 188-194.
734. Cai, Y.; Benischke, A. D.; Knochel, P.*; Gosmini, C. „Cobalt-Catalyzed Reductive Cross-Coupling Between Styryl and Benzyl Halides” Chem. Eur. J. 2017, 23, 250-253.
735. Benischke, A. D.; Le Corre, G.; Knochel, P.* „Preparation of Polyfunctional Organozinc Halides by an InX3- and LiCl-Catalyzed Zinc Insertion to Aryl and Heteroaryl Iodides and Bromides” Chem. Eur. J. 2017, 23, 778-782.
736. Hammann, Jeffrey M.; Lutter, Ferdinand H.; Haas, Diana; Knochel, P.* “A Robust and Broadly Applicable Cobalt-Catalyzed Cross-Coupling of Functionalized Bench-Stable Organozinc Pivalates with Unsaturated Halides” Angew. Chem. Int. Ed. 2017, 56, 1082-1086.
737. Castello-Mico, A.; Nafe, J.; Higashida, K.; Karaghiosoff, K.; Gingras, M.; Knochel, P.* „ Selective Metalations of 1,4-Dithiins and Condensed Analogues Using TMP-Magnesium and -Zinc Bases” Org. Lett. 2017, 19, 360-363.
738. Balkenhohl, M.; Francois, C.; Sustac-Roman, D.; Quinio, P.; Knochel, P.* “Transition-Metal-Free Amination of Pyridine-2-sulfonyl Chloride and Related N-Heterocycles Using Magnesium Amides” Org. Lett. 2017, 19, 536-539.
739. Knochel, P. „Preface - Burgenstock Junior Contributions” Synthesis 2017, 49, 775.
740. Ketels, M.; Konrad, D. B.; Karaghiosoff, K.; Trauner, D.; Knochel, P.* „Selective Lithiation, Magnesiation, and Zincation of Unsymmetrical Azobenzenes Using Continuous Flow” Org. Lett. 2017, 19, 1666-1669.
741. Klier, L.; Ziegler, D. S.; Rahimoff, R.; Mosrin, M.; Knochel, P.* „Practical Large-Scale Regioselective Zincation of Chromone Using TMPZnCl·LiCl Triggered by the Presence or Absence of MgCl2” Org. Process Res. Dev. 2017, 21, 660-663.
742. Chen, Y.-H.; Ellwart, M.; Toupalas, G.; Ebe, Y.; Knochel, P.* „Preparation and Application of Solid, Salt-Stabilized Zinc Amide Enolates with Enhanced Air and Moisture Stability” Angew. Chem. Int. Ed. 2017, 56, 4612-4616.
743. Hofmayer, M. S.; Hammann, J. M.; Lutter, F. H.; Knochel, P.* „Large-Scale Cobalt-Catalyzed Cross-Couplings of Functionalized Bench-Stable Arylzinc Pivalates with (Hetero)Aryl and Alkenyl Halides” Synthesis 2017, in print.
744. Rager, S.; Dogru, M.; Werner, V.; Gavryushin, A.; Goetz, M.; Engelke, H.; Medina, D. D.; Knochel, P.*; Bein, T. „Pore wall fluorescence labeling of covalent organic frameworks” CrystEngComm 2017, 19, 4886-4891.
745. Hammann, J. M.; Hofmayer, M. S.; Lutter, F. H.; Thomas, L.; Knochel, P.* “Recent Advances in Cobalt-​Catalyzed Csp2 and Csp3 Cross-​Couplings” Synthesis 2017, 49, 3887-3894.
746. Chen, Y.-H.; Ellwart, M.; Malakhov, V.; Knochel, P.* „Solid organozinc pivalates: a new class of zinc organometallics with greatly enhanced air- and moisture-​stability” Synthesis 2017, 49, 3215-3223.
747. Ketels, M.; Ziegler, D. S.; Knochel, P.* „Selective Zincation of 1,​2-​Dicyanobenzene and Related Benzonitriles in Continuous Flow Using In Situ Trapping Metalations” Synlett 2017, in print.
748. Chen, Y.-H.; Tuellmann, C. P.; Ellwart, M.; Knochel, P.* „Preparation of Solid Polyfunctional Alkynylzinc Pivalates with Enhanced Air and Moisture Stability for Organic Synthesis” Angew. Chem. Int. Ed. 2017, 56, 9236-9239.
749. Hammann, J. M.; Thomas, L.; Chen, Y.-H.; Haas, D.; Knochel, P.* „Cobalt-​Catalyzed Cross-​Couplings of Bench-​Stable Alkynylzinc Pivalates with (Hetero)​Aryl and Alkenyl Halides” Org. Lett. 2017, 19, 3847-3850.
750. Nishii, Y.; Hirai, T.; Fernandez, S.; Knochel, P.*; Mashima, K. „Zinc-​Catalyzed Esterification of N-​β-​Hydroxyethylamides: Removal of Directing Groups under Mild Conditions” Eur. J. Org. Chem. 2017, 5010-5014.
7751. Ganiek, M. A.; Becker, M. R.; Berionni, G.; Zipse, H.; Knochel, P.* „Barbier Continuous Flow Preparation and Reactions of Carbamoyllithiums for Nucleophilic Amidation” Chem. Eur. J. 2017, 23, 10280-10284.
752. Knochel, P.* “Preface - Special Issue Dedicated to Professor Herbert Mayr” Synthesis 2017, 49, I.
753. Balkenhohl, Moritz; Greiner, Robert; Makarov, Ilya S.; Heinz, Benjamin; Karaghiosoff, Konstantin; Zipse, Hendrik; Knochel, P.* „Zn-​, Mg-​, and Li-​TMP Bases for the Successive Regioselective Metalations of the 1,​5-​Naphthyridine Scaffold (TMP=2,​2,​6,​6-​Tetramethylpiperidyl)” Chem. Eur. J. 2017, 23, 13046-13050.
754. Nishii, Y.; Hirai, T.; Fernandez, S.; Knochel, P.*; Mashima, K. „Cover Feature: Zinc-​Catalyzed Esterification of N-​β-​Hydroxyethylamides: Removal of Directing Groups under Mild Conditions (Eur. J. Org. Chem. /2017)“ Eur. J. Org. Chem. 2017, 4995.
755. Ellwart, M.; Hoefner, G.; Gerwien, A.; Wanner, K. T.; Knochel, P.* „Synthesis and Bioactivity of Novel N-​Benzylic and N-​Phenethylic Ephedrine Derivatives” Synthesis 2017, in print.
756. Castello-Mico, A.; Knochel, P.* “Zincation and Magnesiation of Functionalized Silylated Cyanohydrins Using TMP-​Bases” Synthesis 2017, in print.
757. Makarov, I. S.; Brocklehurst, C. E.; Karaghiosoff, K.; Koch, G.; Knochel, P.* „Synthesis of Bicyclo[1.1.1]​pentane Bioisosteres of Internal Alkynes and para-​Disubstituted Benzenes from [1.1.1]​Propellane” Angew. Chem. Int. Ed. 2017, 56, 12774-12777.
758. Hofmayer, M. S.; Hammann, J. M.; Cahiez, G.; Knochel, P.* „Iron-​Catalyzed C(sp2)​-​C(sp3) Cross-​Coupling Reactions of Di(hetero)​arylmanganese Reagents and Primary and Secondary Alkyl Halides” Synlett 2017, in print.
759. Ketels, M.; Ganiek, M. A.; Weidmann, N.; Knochel, P.* „Synthesis of Polyfunctional Diorganomagnesium and Diorganozinc Reagents through In Situ Trapping Halogen-​Lithium Exchange of Highly Functionalized (Hetero)​aryl Halides in Continuous Flow” Angew. Chem. Int. Ed. 2017, 56, 12770-12773.
760. Greiner, R.; Ziegler, D. S.; Cibu, D.; Jakowetz, A. C.; Auras, F.; Bein, T.; Knochel, P.* „Preparation of Polyfunctional Naphthyridines by Cobalt-​Catalyzed Cross-​Couplings of Halogenated Naphthyridines with Magnesium and Zinc Organometallics” Org. Lett. 2017, 19, 6384-6387.
761. Ziegler, D. S.; Greiner, R.; Lumpe, H.; Kqiku, L.; Karaghiosoff, K.; Knochel, P.* „Directed Zincation or Magnesiation of the 2-​Pyridone and 2,​7-​Naphthyridone Scaffold Using TMP Bases” Org. Lett. 2017, 19, 5760-5763.
762. Benischke, A. D.; Anthore-Dalion, L.; Berionni, G.; Knochel, P.* „Preparation of Functionalized Diaryl- and Diheteroaryllanthanum Reagents by Fast Halogen-​Lanthanum Exchange” Angew. Chem. Int. Ed. 2017, 56, 16390-16394.
763. Knochel, P. “Zinc1” e-EROS Encyclopedia of Reagents for Organic Synthesis 2017, 1-18.
764. Chen, Yi-H.; Grassl, S.; Knochel, P.* “Cobalt-​Catalyzed Electrophilic Amination of Aryl- and Heteroarylzinc Pivalates with N-​Hydroxylamine Benzoates” Angew. Chem. Int. Ed. 2018, 57, 1108-1111.
765. Morozova, V.; Skotnitzki, J.; Moriya, K.; Karaghiosoff, K.; Knochel, P.* “Preparation of Optically Enriched Secondary Alkyllithium and Alkylcopper Reagents-​Synthesis of (-​)​-​Lardolure and Siphonarienal” Angew. Chem. Int. Ed. 2018, 57, 5516-5519.
766. Thomas, L.; Lutter, F. H.; Hofmayer, M. S.; Karaghiosoff, K.; Knochel, P.* “Cobalt-​Catalyzed Diastereoselective Cross-​Couplings between Alkynylzinc Pivalates and Functionalized Cyclic Iodides or Bromides” Org. Lett. 2018, 20, 2441-2444.
767. Skotnitzki, J.; Morozova, V.; Knochel, P.* “Diastereoselective Copper-​Mediated Cross-​Couplings between Stereodefined Secondary Alkylcoppers with Bromoalkynes” Org. Lett. 2018, 20, 2365-2368.
768. Ziegler, D. S.; Karaghiosoff, K.; Knochel, P.* „Generation of Aryl and Heteroaryl Magnesium Reagents in Toluene by Br​/Mg or Cl​/Mg Exchange” Angew. Chem. Int. Ed. 2018, 57, 6701-6704.
769. Balkenhohl, M.; Salgues, B.; Hirai, T.; Karaghiosoff, K.; Knochel, P.* „Regioselective Metalation and Functionalization of the Pyrazolo[1,​5-​a]​pyridine Scaffold Using Mg- and Zn-​TMP Bases” Org. Lett. 2018, 20, 3114-3118.
770. Simon, M.; Karaghiosoff, K.; Knochel, P.* „Diastereoselective Intramolecular Carbolithiations of Stereodefined Secondary Alkyllithiums Bearing a Remote Alkynylsilane” Org. Lett. 2018, 20, 3518-3521.
771. Benischke, A. D.; Anthore-Dalion, L.; Kohl, F.; Knochel, P.* „Synthesis of Polyfunctionalized Triaryllanthanum Reagents by Using Ph3La and Related Species as Exchange Reagents” Chem.Eur. J. 2018, 24, 11103-11109.
772. Weidmann, N.; Ketels, M.; Knochel, P.* „Sodiation of Arenes and Heteroarenes in Continuous Flow” Angew. Chem. Int. Ed. 2018, 57, 10748-10751.
773. Tuellmann, Carl Phillip; Chen, Yi-Hung; Schuster, Robin J.; Knochel, P.* „Preparation and Reactions of Mono- and Bis-​Pivaloyloxyzinc Acetylides” Org. Lett. 2018, 20, 4601-4605.
774. Li, J.; Knochel, P.* “Cobalt-​Catalyzed Cross-​Couplings between Alkenyl Acetates and Aryl or Alkenyl Zinc Pivalates” Angew. Chem. Int. Ed. 2018, 57, 11436-11440.
775. Ziegler, D. S.; Klier, L.; Mueller, N.; Karaghiosoff, K.; Knochel, P.* „ Directed Zincation or Magnesiation of 2- and 4-​Pyrones and Their Derivatives” Synthesis 2018, 50, 4383-4394.
776. Ellwart, M.; Chen, Y.-H.; Tuellmann, C. P.; Malakhov, V.; Knochel, P.* „Preparation of solid organozinc pivalates and their reaction in Pd-​catalyzed cross-​couplings” Org. Synth. 2018 , 95, 127-141.
777. Knochel, P.* “Preface - Special Issue Dedicated to Professor Scott E. Denmark in Honor of his 65th Birthday” Synthesis 2018, 50, 22.
778. Dong, Z.-B.; Balkenhohl, M.; Tan, E.; Knochel, P.* „Synthesis of Functionalized Diaryl Sulfides by Cobalt-​Catalyzed Coupling between Arylzinc Pivalates and Diaryl Disulfides” Org. Lett. 2018, in print.
1. Stuermer, R.; Laupichler, L.; Knochel, P.; Falk, L. “Preparation of optically active phosphine and their metal complexes and their use in asymmetric synthesis” Ger. Offen. 1996, DE 19516968 CAN 126:60177.
2. Knochel, P.; Lutz, C. “Method for selective alkylation of aldehydes by organozinc compounds” Ger. Offen. 1999, DE 19809341 CAN 131:144190.
3. Boymond, L.; Rottlaender, M.; Cahiez, G.; Knochel, P. “Method for the production of Grignard reagents” PCT Int. Appl. 1999, WO 9951609 CAN 131:257694.
5. Aiscar, B. J. J.; Henkelmann, J.; Preiss, T.; Knochel, P.; Tzalis, D.; Koradin, C. „Process and cesium hydroxide monohydrate catalysts for the hydroamination of a-olefins with amines” Ger. Offen. 2000, DE 19924051 CAN 134:4751.
6. Knochel, P.; Duebner, F.; “Copper-catalyzed enantioselective allylic substitution reactions” PCT Int. Appl. 2000, WO 20000309 CAN 139:222063.
7. Koradin, C.; Aiscar, B. J. J.; Henkelmann, J.; Preiss, T.; Knochel, P.; Tzalis, D. „Process and catalyst for the preparation of hydroxyalkynes from the addition reaction of terminal alkynes with aldehydes or ketones” Eur. Pat. Appl. 2000, EP 1055656 CAN 134:17164.
8. Aiscar, B. J. J.; Henkelmann, J.; Preiss, T.; Knochel, P.; Tzalis, D.; Koradin, C. „Process for the preparation of alkenyl compounds“ Eur. Pat. Appl. 2000, EP 1055653 CAN 134:17163.
12. Bosch, B. E.; Monsees, A.; Dingerdissen, U.; Knochel, P.; Hupe, E. “Cycloaliphatic/aromatic diphosphines and use thereof in catalysis” PCT Int. Appl. 2002, WO 2002014330 CAN 136:200302.
13. Demay, S.; Kotschy, A.; Knochel, P.; Volant, F.; Lotz, M. “Preparation of chiral diphosphines via 2,3 –sigmatropic rearrangement for use in asymmetric transition metal catalysis.” Eur. Pat. Appl. 2002, EP 1182205 CAN 136:200304.
17. Knochel, P.; Lotz, M.; Monsees, A.; Riermeier, T.; Kadyrov, R.; Almena, J. “Preparation of phosphino ferrocenyl ligands as a cocatalyst for rhodium catalyzed asymmetric hydrogenation reactions” Ger. Offen. 2003, DE 10219490 CAN 139:365071.
18. Scholz, U.; Schlummer, B.; Knochel, P.; Bunlaksananusorn, T. „Preparation of chiral phosphine ligands and their transition metal complexes and their use as catalysts in asymmetric synthesis” PCT Int. Appl. 2004, WO 2004104014 CAN 142:23392.
20. Knochel, P.; Krasovskiy, A. “Method of preparing organomagnesium compounds” Eur. Pat. Appl. 2005, EP 1582523 CAN 143:347288.
21. Knochel, P.; Bunlaksananusorn, T.; Gavryushin, A. “An improved process for preparation of chiral diphosphines with cyclopentane backbone as ligands for asymmetric transition metal-catalyzed hydroboration, hydrogenation and allylic substitution” Eur. Pat. Appl. 2005, EP 1595885 CAN 143:460277.
22. Knochel, P.; Bunlaksananusorn, T.; Gavryushin, A. “Chiral diphosphines with cyclic diterpene backbone as ligands for transition metal-catalyzed asymmetric hydrogenation, addition and substitution reactions and process for preparation thereof” Eur. Pat. Appl. 2005, EP 1595886 CAN 143:460278.
23. Knochel, P.; Bunlaksananusorn, T.; Gavryushin, A. “Chiral diphosphinoterpenes and transition metal complexes thereof” US Pat. Appl. Publ. 2005, US 2005267316 CAN 144:6923.
24. Knochel, P.; Sapountzis, I.; Korn, T.; Lin, W.; Kofink, C. „Iron- or cobalt-catalyzed carbon-carbon coupling reactions of arylenes, alkenes and alkynes with copper reagents“ Ger. Offen. 2006, DE 2004-102004049508 CAN 144:390561.
25. Knochel, P.; Gavriushin, Andrei; Manolikakes, G.; Kofink, C. C “Or iron-catalyzed carbon-carbon coupling reaction of arylenen, alkenes and alkines nickel” Ger. Offen. 2007, DE 102005043337 A1 20070315 AN 2007:284966.
26. Knochel, P.; Krasovskiy, A.; Kopp, F. ”Solutions of anhydrous lanthanide salts and its preparation.” Eur. Pat. Appl. 2007, EP 1759765 A1 20070307 AN 2007:247914.
27. Knochel, P.; Krasovskiy, A.; Krasovskaya, V. "Preparation and use of magnesium amides" PCT Int. Appl. 2007, WO 2007082911 A1 20070726 AN 2007:813869.
28. Knochel, P.; Gavryushin, A.; Malakhov, V.; Krasovskiy, A. “Improved process for preparation of organometallic compounds by direct metalation of organic derivs. with metals in presence of lithium salts” Ger. Offen. 2007, DE 102006015378 CAN 147:406953.
29. Knochel, P.; Mayr, H.; Krasovskiy, A.; Kienle, M.; Dubbaka, S. R.; Del Amo, V.; Tishkov, A. “Oxidative coupling of organometallic compounds using a quinone as redox reagent” PCT Int. Appl., 2007, WO 2007128601 A2 20071115 AN 2007:1303088.
30. Clososki, G. C.; Rohbogner, C. J.; Knochel, P. „Preparation and use of magnesium amides” PCT Int. Appl., 2008, WO 2008087057 A1 20080724 AN 2008:887903.
31. Knochel, P.; Wunderlich, S. „Bisamide-zinc bases“ PCT Int. Appl. 2008, WO 2008138946 A1 20081120 AN 2008:1402357.
32. Knochel, P.; Wunderlich, S. „Until amide zinc bases [Machine Translation]“ Ger. Offen. 2008, DE 102007022490 A1 20081120 AN 2008:1398637.
33. Knochel, P.; Wunderlich, S. „Process for preparation of diamidozinc bases as metalation reagents for aromatic and heterocyclic compounds” PCT Int. Appl. 2008, WO 2008138946 A1 20081120 CAN 149:569531 AN 2008:1402357.
34. Knochel, P.; Wunderlich, S. „Process for preparation of diamidozinc bases as metalation reagents for aromatic and heterocyclic compounds” Ger. Offen. 2008, DE 102007022490 A1 20081120 CAN 149:569530 AN 2008:1398637.
35. Knochel, Paul; Mosrin, M. “Preparation of zinc amides as selective bases for the directed zincation of aromatics and heteroaromatics” Ger. Offen. 2010, DE 102010007833 A1 20100819 CAN 153:334216 AN 2010:1040654.
36. Knochel, P.; Bluemke, T.; Chen, Yi-H. „Process for preparation of functionalized substituted biaryls and allylarenes by cross-coupling of aryl and allyl halides with arylaluminum compounds mediated by metal halides” PCT Int. Appl. 2011, WO 2011023791 A2 20110303; Ger. Offen. 2011, DE 102009028939 A1 20110303.
37. Langhals, H.; Knochel, P.; Walter, A.; Esterbeuer, A. J.; Zimdars, S. „Benzothiadiazoloperylene amorphous bichromophoric substances” Ger. Offen. 2011, DE 102009048848 A1 20110505.
38. Knochel, P.; Bernhardt, S.; Metzger, A. “Carboxylation of organozinc compounds in preparation of organic carboxylic acids” PCT Int. Appl. 2011, WO 2011113925 A2 20110922.
39. Knochel, P.; Bernhardt, S.; Manolokakes, G. “Organozinc complexes and processes for making and using the same” PCT Int. Appl. 2012, WO 2012085168 A1 20120628.
40. Knochel, P.; Haag, B. “Process for making organoboron compounds, products obtainable thereby, and their use” PCT Int. Appl. 2012, WO 2012085170 A2 20120628.
41. Knochel, P.; Haag, B. “Process for making organoboron compounds, products obtainable thereby, and their use” PCT Int. Appl. 2012, WO 2012085170 A2 20120628.
42. Langhals, H.; Knochel, P.; Schluecker, T.; Saemann, C.; Dhayalan, Vasudevan „Terminal substituted oligothiophenes and use thereof in optical signal transmission systems and/or as color pigments” PCT Int. Appl. 2015, WO 2015135867 A1 20150917.
45. Knochel, P.; Becker, M. „Process for producing metalated aromatic and heteroaromatic compounds by deprotonation with lithium amides and transmetalation with metal salts in continuous flow conditions” PCT Int. Appl. 2016, WO 2016184652 A1 20161124.
46. Knochel, P.; Ellwart, M. „Organozinc reagents and processes for preparing and using the same” PCT Int. Appl. 2016, WO 2016146689 A1 20160922 (Eur. Pat. Appl. 2016, EP 3070083 A1 20160921).
47. Knochel, P.; Becker, M. “Preparation of organozinc composition” Eur. Pat. Appl. 2017, EP 3168224 A1 20170517.
1. Knochel, P.*; Rozema, M. J.; Tucker, C.E.; Retherford, C.; Furlong, M.; AchyuthaRao, S. "The Chemistry of Polyfunctional Organozinc and Copper Reagents" Pure and Appl. Chem. 1992, 64, 361.
2. Knochel, P.* "Stereoselective Addition Reactions of Organozinc, Cadmium and Mercury Reagents" Ed. Trost, B. M. in Comprehensive Organic Synthesis, Vol.1, p. 211-230, Pergamon Press 1991.
3. Knochel, P.* "Carbometallation of Alkenes and Alkynes" Ed. Trost, B. M. in Comprehensive Organic Synthesis, Vol.4, p. 865-912, Pergamon Press 1991.
4. Knochel, P.*; Rozema, M. J.; Tucker, C.E.; "Preparation of Highly Functionalized Copper Reagents" in "Practical Approach Series in Chemistry-Organocopper Reagents" Taylor, R. J. K., Oxford University Press, 1993, 348.
5. Knochel, P.*; Singer, R. D. "Preparation and Reactions of Polyfunctional Organozinc Reagents for Organic Synthesis" Chem. Rev. 1993, 93, 2117-2188.
6. Knochel, P.* "Organozinc and Organocadmium Reagents in Organic Synthesis" Ed. Hegedus, L. S. in Comprehensive Organometallic Chemistry II, Vol.11, p. 159-190, Pergamon Press 1995.
7. Knochel, P.* "UniversitÃ¤tssausbildung am Forschungsstandort USA" Chemie Heute 1994/95, 32-34.
8. Knochel, P.* "Allyltrimethylsilylzinc Chloride" Encyclopedia of Reagents for Organic Synthesis, Ed. Paquette, L. A. wiley and Sons, 1995, Vol. 1, p. 136-137.
9. Knochel, P.* "Diethylzinc" Encyclopedia of Reagents for Organic Synthesis, Ed. Paquette, L. A. wiley and Sons, 1995, Vol. 3, p. 1861-1866.
10. Knochel, P.* "Diethylzinc-Bromoform-Oxygen" Encyclopedia of Reagents for Organic Synthesis, Ed. Paquette, L. A. wiley and Sons, 1995, Vol. 3, p. 1867.
11. Knochel, P.* "Ethyliodomethylzinc Iodide" Encyclopedia of Reagents for Organic Synthesis, Ed. Paquette, L. A. wiley and Sons, 1995, Vol. 4, p. 2473.
12. Knochel, P.* "Ethylzinc Iodide" Encyclopedia of Reagents for Organic Synthesis, Ed. Paquette, L. A. wiley and Sons, 1995, Vol. 4, p. 2532-2533.
13. Knochel, P.* "Iodomethylzinc Iodide" Encyclopedia of Reagents for Organic Synthesis, Ed. Paquette, L. A. wiley and Sons, 1995, Vol. 4, p. 2835-2836.
14. Knochel, P.* "Lithium Tri-t-butylzincate" Encyclopedia of Reagents for Organic Synthesis, Ed. Paquette, L. A. wiley and Sons, 1995, Vol. 5, p. 3176-3177.
15. Knochel, P.* "Lithium Trimethylzincate" Encyclopedia of Reagents for Organic Synthesis, Ed. Paquette, L. A. wiley and Sons, 1995, Vol. 5, p. 3185-3186.
16. Knochel, P.* "2-Nitro-3-Pivaloyloxy-1-Propene" Encyclopedia of Reagents for Organic Synthesis, Ed. Paquette, L. A. wiley and Sons, 1995, Vol. 6, p. 3756-3757.
18. Knochel, P.* "Titanocenemethylene-Zinc Halide Complex" Encyclopedia of Reagents for Organic Synthesis, Ed. Paquette, L. A. wiley and Sons, 1995, Vol. 7, p. 4106-4107.
19. Knochel, P.* "Zinc" Encyclopedia of Reagents for Organic Synthesis, Ed. Paquette, L. A. wiley and Sons, 1995, Vol. 8, p. 5525-5531.
21. Knochel, P.* "Preparation and Applications of Functionalized Organozinc Reagents" Chapter in "Activated Metals" Ed. FÃ¼rstner A. Verlag Chemie, 1995, 191-236.
22. Knochel, P.*; Vettel, S.; Eisenberg, C. "Catalytic Asymmetric Synthesis of Chiral Secondary Polyfunctional Alcohols Using Diorganozincs" Applied Organomet. Chem. 1995, 9, 175-188.
23. Knochel, P.* "Stereoselective Reactions Mediated by Functionalized Diorganozincs" Synlett 1995, 393-403.
24. Knochel, P.* "New Preparations of Polyfunctional Dialkylzincs and Their Application in Asymmetric Synthesis" Organic Chemistry Edition of CHEMTRACTS in Org. Chem. 1995, 8, 205-221.
25. Knochel, P.* "Carbon-Carbon Bond Formation Mediated by Organozinc Reagents" in "Metal-Catalyzed Cross Coupling Reactions" edited by Stang, P. and Diederich, F., VCH Verlag, Weinheim, 1997, 387-419.
26. Knochel, P.* "The Preparation of 1,1-Bimetallics of Magnesium and Zinc" in "Handbook of Grignard Reagents" edited by Silverman, G. S. and Rakita, P. E., Marcel Dekker, Inc., New-York, Basel, Hong Kong, 1996, 633-644.
27. Knochel, P.*, Langer, F.; Longeau, A.; RottlÃ¤nder, M.; StÃ¼demann, T. "New Coupling Reactions and Phosphorylations Using Organzinc Reagents" Chem. Ber. 1997, 130, 1021-1027.
28. Knochel, P.*; Almena, J.; Jones, P. "Organozinc Mediated Reactions" Tetrahedron 1998, 54, 8275-8319.
29. Knochel, P.* "New Preparations and Reactions of Organozinc Reagents" in Selective Reactions of Metal-Activated Molecules, third Symposium, Werner, H.; Schrein, P. Eds. Vieweg Verlag, 1998, 117-130.
30. RottlÃ¤nder, M.; Boymond, L.; BÃ©rillon, L.; LeprÃªtre, A.; Varchi, G.; Avolio, S.; Laaziri, H.; QuÃ©guiner, G.; Ricci, A.; Cahiez, G.; Knochel, P.* "New Polyfunctional Magnesium Reagents for Organic Synthesis" Chem. Eur. J. 2000, 6, 767.
31. Betzemeier, B.; Knochel, P.* "Perfluorinated Solvents - a Novel Reaction Medium in Organic Chemistry" in Topics of Current Chemistry: New Solvent Systems, Springer Verlag 1999.
33. Boudier, A.; Bromm, L.O.; Lotz, M.; Knochel, P.* "New Applications of Polyfunctional Organometallics in Organic Synthesis" Angew. Chem. Int. Ed. 2000, 39, 4414-4435.
34. Knochel; P.*; Boudier, A.; Bromm, L. O.; Hupe, E.; Knapp, K.; Varela, J.; Laaziri; H.; Lhermitte, F. "New Stereoselective Transformations Involving Organoboranes and Organozinc Compounds" Pure Appl. Chem. 2001, Vol. 72, No. 9, 1699-1703.
35. Betzemeier, B.; Knochel, P.* "Oxidation Reactions in Perfluorinated Solvents" Peroxide Chemistry, Wiley-VCH 2000, 8, 453-468.
36. Knochel, P.*; Millot, N.; Rodriguez, A.; Tucker, C. E.; "Preparations and Applications of Functionalized Organozinc Compounds" Organic Reactions 2001, 58, 417-731.
37. Knochel, P.*; Boudier, A.; Bromm, L. O.; Hupe, E.; Knapp, K.; Varela Carrete, J.; Rodriguez, A.; Koradin, C.; Bunlaksananusorn, T.; Laaziri, H.; Lhermitte, F. "Selective Transformations Mediated by Main Group Organometallics" Pure Appl. Chem. 2000, 72, 1699-1703.
38. Knochel, P.* "Organozinc Reagents" Science of Synthesis 2004, 3, 5-90.
39. Knochel, P.*; Betzemeier, B. "Transmetalation Reactions Leading to Organocopper Reagents" VCH Verlag, 2002, 45-78.
40. Knochel, P.*; Lotz, M. "Catalysts for the Fine Chemical Industry" Wiley VCH, 2000, in press.
42. Knochel,P.*, Dohle, W.; Gommermann, N.; Kneisel, F. F.; Kopp, F.; Korn, T. Sapountzis, I.; Vu, V.A. "Highly Functionalized Magnesium Organometallics Prepared via a Halogen-Magnesium Exchange" Angew. Chem. Int. Ed. 2003, 42, 4302-4320.
43. Hupe, E.; Calaza, M. I.; Knochel, P.* "Synthesis and Reaction of Secondary and Primary Diorganoznc Reagents Using a Boron-Zinc Exchange. A Useful Method for the Stereoselective Formation of New Carbon-Carbon Bonds" J. Organomet. Chem. 2003, 680, 136-142.
44. Knochel, P.*; Sapountzis, I.; Gommermann, N. "Carbon-carbon bond-forming reactions mediated by organomagnesium reagents" in Metal-Catalyzed Cross-Coupling Reactions (2nd Edition) 2004, 2 , 671-698.
45. Knochel, P.; Calaza, M. I.; Hupe, E. "Carbon-Carbon Bond-Forming Reactions Mediated by Organozinc Reagents" in Metal-Catalyzed Cross-Coupling Reactions< (2nd Edition) 2004, 2, 619-670.
46. Knochel, P.*; Krasovskiy, A.; Sapountzis, I. "Polyfunctional Magnesium Organometalics for Organic Synthesis" in Handbook of Functionalized Organometallics, Knochel, P. (Ed.), Wiley-VCH 2005, Chapter 4.
47. Knochel, P.*; Leuser, H.; Gong, L.-Z.; Perrone, S.; Kneisel, F. F. "Polyfunctional Zinc Organometalics for Organic Synthesis" in Handbook of Functionalized Organometallics, Knochel, P. (Ed.), Wiley-VCH 2005, Chapter 7.
48. Knochel, P.*; Yang, X.; Gommermann, N. "Polyfunctional Organocopper Reagents for Organic Synthesis" in Handbook of Functionalized Organometallics, Knochel, P. (Ed.), Wiley-VCH 2005, Chapter 9.
49. Knochel, P.*; Ila, H.; Korn, T.; Baron, O. "Functionalized Organoborane Derivatives in Organic Synthesis" in Handbook of Functionalized Organometallics, Knochel, P. (Ed.), Wiley-VCH 2005, Chapter 3.
50. Ila, H.; Baron, O.; Wagner, A. J.; Knochel, P. "Preparation and Reactions of Heteroaryl Organomagnesium Compounds" Chem. Commun. 2005, in press.
51. Ila, H.; Baron, O.; Wagner, A. J.; Knochel, P. "Functionalized Magnesium Organometallics as Versatile Intermediates for the Synthesis of Polyfunctional Heterocycles" Chem. Commun. 2005, in press.
52. Knochel, P.*; Leuser, H.; Gong, L.-Z.; Perrone, S.; Kneisel, F. F. "Functionalized organozinc compounds" in The chemistry of organozinc compounds, Rappoport, Z. (Ed.); Marek, I. (Ed.), John Wiley & Sons, Ltd 2006, in press.

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