Source: https://pubs.rsc.org/en/content/articlehtml/2019/qi/c8qi00939b?page=search
Timestamp: 2019-04-23 08:08:54+00:00

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Zhendong Liu received his PhD degree in chemical engineering (supervised by Professor Tatsuya Okubo) from The University of Tokyo in September 2015 and carried out postdoctoral research in the same institute until July 2016. He then moved to University of Minnesota at Twin Cities for another postdoctoral research with Professors Michael Tsapatsis and Andreas Stein. Since October 2017, he has been a project assistant professor at The University of Tokyo. His current research focuses on the efficient synthesis of zeolitic materials and nanostructures towards applications in energy and environment.
Jie Zhu received her bachelor's degree from East China University of Science and Technology in 2015 and master's degree from The University of Tokyo in 2017. She is currently a PhD candidate supervised by Professor Tatsuya Okubo in The University of Tokyo. Her current research is on the rational synthesis and catalytic study of noble/transition metal containing zeolites.
Toru Wakihara is an associate professor at the Department of Chemical System Engineering of The University of Tokyo. He received his PhD degree from UTokyo in 2004, and started his academic career at Yokohama National University where he was promoted as assistant professor and associate professor in 2007 and 2012, respectively. He moved back to UTokyo and started to hold his current position in 2013. His research interests include powder technology, synthesis and application of nanosized zeolites, and synthesis of zeolites under extreme conditions.
Tatsuya Okubo is a professor at the Department of Chemical System Engineering, The University of Tokyo. He received his PhD degree from UTokyo and started his academic career at Kyushu University as a research associate in 1988. He moved to UTokyo in 1991, where he was promoted as a lecturer, an associate professor and a full professor in 1994, 1997 and 2006, respectively. He spent one year at California Institute of Technology (USA) as a visiting associate in 1993–1994. His research interests include the synthesis and application of zeolites.
The past few decades have witnessed tremendous progress in the synthesis and application of zeolites, which have greatly benefited modern chemical and petrochemical industries as catalysts, adsorbents and ion-exchangers.1–3 This prospect is mainly due to the fact that zeolites, featuring a highly ordered three-dimensional framework composed of nanometer-sized channels and cages, bring about excellent (hydrothermal) stability, high adsorption capacity and tunable active sites. Recently, driven by the rapid development of nanotechnology and biotechnology, applications of zeolites have been extended to new fields as sensors, optical devices and hosts for nano- and bio-related materials.4–6 These established and emerging applications call for new concepts in the design, engineering and production of zeolites.
Systematic studies into the synthesis of zeolites date back to the 1940s, when Richard Barrer began to investigate the synthesis with water as the solvent, a process today generally called hydrothermal synthesis.11,12 Since then, it has dominated the production of synthetic zeolites. Initially proposed to mimic the geological formation conditions of natural zeolites, the hydrothermal synthesis is effective in converting the amorphous reactants to crystalline phases in an aqueous environment. Nevertheless, this process takes long synthesis periods (usually several hours to several days, and in some cases even several weeks) to obtain the desired products, which renders the synthesis of zeolites less efficient in terms of time, energy and cost.13,14 Considering the ever emerging applications and increasing consumption of zeolites, the development of a fast synthesis route is highly desirable.
Herein, we review the breakthrough and the recent progress on the ultrafast synthesis of zeolites demonstrated by our group. To begin with, we briefly discuss the features of the hydrothermal synthesis and the crystallization mechanism of zeolites, followed by a short introduction of several methods that have been developed to accelerate the crystallization rate. Our purpose is not to a give a comprehensive review of the hydrothermal synthesis as well as the crystallization mechanism but to provide some important features of the crystallization of zeolites to better explain the challenges for a fast synthesis. The history of the hydrothermal synthesis and the mechanism of zeolite crystallization have been thoroughly examined in the previous reviews.20–28 Despite the complicated nature of crystallization, efforts have never ceased to shorten the synthesis period of zeolites. We then present the breakthrough as well as an overview of the ultrafast synthesis of zeolites in a tubular reactor, brief the factors that contribute to the enhancement of crystallization rates and rationalize how these factors work synergistically to lead to the ultrafast synthesis on the order of minutes. The ultrafast synthesis lays a solid foundation to realize a switch from the batch-wise synthesis conducted in conventional autoclaves to the continuous synthesis in flow reactors. Considerations on the establishment of a continuous flow synthesis of zeolites as well as several successful demonstrations are therefore discussed.
A typical hydrothermal synthesis can be schematically illustrated as shown in Fig. 1a. The amorphous reactants containing a silica source, an aluminium source, an inorganic cation, an organic structure-directing agent (OSDA) and water are mixed to form an aqueous precursor. This precursor undergoes an aging process conducted either at room temperature or an elevated temperature to ensure adequate mixing and tuning of the precursor, and then this aged precursor is fed into a sealed autoclave and heated to the reaction temperature. After a certain synthesis period, the autoclave is cooled down and the crystalline product is recovered by separation, washing and drying.
Fig. 1a depicts that the hydrothermal synthesis involves multiple steps, which are performed at different temperatures. Mixing of the raw materials and the subsequent aging step are carried out at low temperatures (typically below 100 °C). Adequate aging is necessary because a fresh mixture of the starting ingredients may not be homogeneously mixed. More importantly, the events taking place during the aging process are beyond physical mixing. Substantial chemical reactions, for example hydrolysis and condensation of silicates, formation of the aluminosilicate hydrogel and reorganization of the hydrogels, have already started at this stage.29,30 Characterization techniques like nuclear magnetic resonance spectroscopy (NMR),31,32 high resolution transmission electron microscopy (high resolution TEM),33–35 X-ray/neutron scattering with pair distribution function analysis (PDF analysis),36,37 and Raman spectroscopy38 have been intensively employed to study the aging. The results have demonstrated that the species formed in the aging step can essentially influence the subsequent crystallization proceeding at high temperatures and consequently alter the properties of the products obtained. For instance, careful investigations showed that secondary building units like four- and six-membered rings were formed in the aging step, which played an important role in phase determination.39,40 The events occurring in the high temperature synthesis include: (1) further organization of the building units formed during the aging, (2) nucleation, and (3) crystal growth until the consumption of nutrient species. A suitable temperature is chosen for a certain hydrothermal synthesis because the rates of dissociation and reorganization of the (alumino)silicate species can be balanced and a delicate equilibrium achieved under such a temperature so as to prompt the formation of the nuclei and sustain the crystal growth for crystallizing the targeted phase.
Remarkable efforts have been made to speed up the crystallization of zeolites. However, a basis for such claims is lacking. In most cases, the synthesis parameters are so optimized as to achieve the shortest crystallization time under a given range of synthesis conditions. In general, a method is effective only when one or a combination of the following consequences can take place: (1) shortening the induction period, (2) moving a non-ideal synthesis towards its optimum, or (3) altering the balance between nucleation and growth.14 Several methods leading to an accelerated crystallization of zeolites are introduced below.
Microwave-assisted synthesis of zeolites (Fig. 2a) has been extensively studied, which can change the crystallization rate in favorable ways.66,67 The features of microwave include fast heating, which helps to avoid the thermal lag, and selective heating, which may generate a heterogeneous environment containing components with different dielectric properties. Non-thermal effects of microwave irradiation have been claimed, although it was found that the energy of a microwave photon is insufficient to break chemical bonds and that the electric field strength is not enough to shift the chemical equilibrium nor to induce organization.68 Therefore, the enhancement of the crystallization rate by microwave heating may be attributed to either the thermal effect or the non-thermal effect, or a combination of both.69 For example, Cundy et al. performed the microwave-assisted synthesis of ZSM-5 in seeded systems with and without an OSDA.70 They found that microwave heating greatly enhanced the crystallization rate of ZSM-5, in particular, under the conditions in the presence of nanocrystalline seeds. They posited that the hydroxylated surface of the seed crystals and the associated water molecules in the boundary layers could be easily polarized under microwave heating, which resulted in a rapid activation of the seed crystals and consequently a much accelerated crystallization rate.
Fig. 2 Methods aimed at speeding up the synthesis. (a) Microwave-assisted synthesis. (b) Synthesis using FAU zeolite as a starting material. (Adapted with permission from ref. 72. Copyright 2015 American Chemical Society.) (c) Accelerated crystallization via hydroxyl free radicals.
A number of zeolites (such as CHA, *BEA and MFI) have been successfully synthesized through a route which employs FAU type zeolite as a starting material (Fig. 2b).71–74 The crystallization rates for such syntheses were found to be faster compared with those for syntheses with normal starting materials. For example, Honda et al. successfully synthesized *BEA zeolite in only 2 h at 125 °C with FAU zeolite as the starting material.75 While it was supposed that the generation of locally ordered aluminosilicate species through the decomposition/dissolution of the starting FAU zeolite could facilitate the assembly and evolution of another zeolite, further efforts are needed to clarify the role of the FAU zeolite in accelerating the crystallization rate of the targeted zeolite.
Hydrothermal synthesis of zeolites is typically performed in the autoclave, which provides a relatively facile and safe platform to stand against the long-time synthesis under harsh conditions. The features of the autoclave sometimes exert important influence on the synthesis of zeolites. In view of the realization of ultrafast synthesis, however, the conventional autoclave is less incapable because it lacks the proper time resolution to accommodate an ultrafast synthesis, that is, long time is needed for the autoclave for mixing and heating/cooling, making it even impossible to accurately investigate the changes taking place in small time intervals. To increase the time resolution, a “mini autoclave” made from a standard ¼′′ stainless steel tube (denoted as “tubular reactor”) was designed and introduced to the synthesis of zeolites.101–109 The length of the tubular reactor is ca. 13.5 cm, and its two ends are sealed with standard Swagelok® caps. Thanks to its small size and high surface-to-volume ratio, this “mini autoclave” can enable faster heating and cooling, and thus provide a higher time resolution compared with its conventional counterpart. Fig. 3 shows a comparison of the heating curves obtained in the tubular reactor and that in a typical autoclave (Teflon-lined autoclave, #4749, Parr Instrument Company). It takes at least one hour for the autoclave to complete the temperature raise. In stark contrast, the tubular reactor can give a much faster heating rate. In particular, only one minute is required to complete the temperature raise if the tubular reactor is heated in a preheated oil bath, which enables the tubular reactor to be capable of probing any change taking place within very short time intervals.
This feature of the tubular reactor, together with the rational design of synthesis precursors as well as the employment of seeding, allowed us to develop an ultrafast synthesis on the order of minutes. Fig. 4 gives an overview of the typical zeolites that have been synthesized via the ultrafast synthesis route. Typically, the synthesis periods were shortened to tens of and even several minutes.101 As a comparison, several hours or several days are the common synthesis periods reported in the previous studies. The results in Fig. 4 cover various frameworks and compositions, and the range is still expanding. Several representative cases of the ultrafast synthesis are featured below.
The first success of the ultrafast synthesis was demonstrated on AlPO4-5, an aluminophosphate with an AFI structure. Different approaches including microwave-assisted hydrothermal synthesis, dry gel conversion and microemulsion-based synthesis have been attempted to synthesize AlPO4-5, but in general it takes several hours or days to obtain fully crystalline AlPO4-5.110–112 By combining fast heating in the tubular reactor with the addition of a seed, the one-minute synthesis of AlPO4-5 was realized.101 Both fast heating and seeding were found to be crucial to the ultrafast synthesis. In the case of synthesis in the conventional autoclave, a by-product of VPI-5 was formed before the appearance of AlPO4-5 even though the same amount of the seed was added.
The aluminosilicate zeolites are a class of materials of higher importance than the aluminophosphates due to their practical applications. In this sense, the establishment of the ultrafast synthesis of SSZ-13 represents a milestone, as the SSZ-13 case was the first success in terms of aluminosilicates. The synergistic effect of the addition of the seed, choice of the proper aluminum source and employment of high temperature was found to be effective in easing the bottlenecks in the overall process of the crystallization of SSZ-13, resulting in the ultrafast synthesis in 10 min. This synthesis period is remarkably shorter than the synthesis time reported in the previous reports (typically, greater than 5 days).113,114 Selection of the aluminum source was of particular importance to the ultrafast synthesis of SSZ-13. The ten-minute synthesis of SSZ-13 was realized when aluminum hydroxide with the gibbsite structure was used. In stark contrast, it took a much longer time (several hours) if non-crystalline aluminum hydroxide was used under otherwise similar conditions. These results indicate that the crystallization pathways may vary with aluminum sources, leading to different crystallization rates.
The ultrafast synthesis can also be extended to silicoaluminophosphates, which are considered to be a result of incorporating Si atoms into the framework of aluminophosphates yet possess unique properties different from aluminophosphates and aluminosilicate zeolites.115–117 The minute-order synthesis of two representative silicoaluminophosphates (SAPO-34 and SAPO-5) was demonstrated, resulting in a much accelerated synthesis in the tubular reactor (10 min and 5 min for SAPO-34 and SAPO-5, respectively). Because of similarities in chemical compositions and formation conditions, SAPO-34 and SAPO-5 usually appear as a pair of competing phases in the conventional synthesis, no matter whether SAPO-34 is the targeted phase or SAPO-5.118,119 Owing to the feature of fast heating, the tubular reactor proved to be a facile and precise platform to control the phase selection between SAPO-34 and SAPO-5 by tuning the parameters of the ultrafast synthesis (e.g., the synthesis temperature and the method of pretreating the starting materials).
The ultrafast synthesis of high-silica erionite (ERI) zeolite is challenging as it was typically synthesized by the so-called charge density mismatch (CDM) approach.120 The CDM approach has proved to be a feasible way to discover new zeolites or synthesize the high-silica form of an existing zeolite.121–123 In that method, a charge density mismatch barrier (CDM barrier) is intentionally created by mixing an aluminosilicate solution with high charge density and one or several structure-directing agent(s) with low charge density, which obstructs the crystallization of any zeolites. This CDM barrier is then overcome by adding a sufficient amount of another SDA with higher charge density so as to make the crystallization possible and to proceed through the subsequent hydrothermal synthesis. Although the CDM barrier holds potential for new discoveries, it is not favorable for the ultrafast synthesis. In the case of the high-silica ERI zeolite with the CDM approach, the crystallization rate could hardly be improved by common techniques such as seeding, high temperature synthesis and even the combination of both. We therefore proposed that the ultrafast synthesis could be possible only if the CDM barrier is removed by skipping the CDM method. Inspired by this idea, we carefully designed the synthesis conditions and successfully realized the ultrafast synthesis of the high-silica ERI zeolite in 20 min (Fig. 5).
In terms of ultrafast synthesis, the importance of aging is several-fold. First, it provides the homogeneity and the nutrient species that can support immediate crystal growth. Second, the interaction between inorganic and organic species has been started, which can protect the organic cations against decomposition when subjected to high temperature treatment. Third, the seed can be well mixed and starts its partial dissolution to create a better environment for seeded growth. Lastly, a sufficient nucleus may also be generated through adequate aging, which can eliminate the necessity of adding the seed.
Nucleation is generally viewed as the major kinetic barrier in the synthesis. The addition of the seed is a useful practice to shorten the synthesis period, as it can help avoid the heterogeneous nucleation.139–143 Seeding is also expected to provide other merits like serving as a directing agent towards a desired phase and controlling the particle size distribution of the resultant crystals. Recently, OSDA-free synthesis of a series of zeolites by the seeding method has been realized.83–85,144 Effective seeding is viewed to be essential to a successful OSDA-free synthesis.
Nevertheless, the employment of high temperature has its limit, that is, the synthesis temperature should be within an acceptable range that can ensure the formation of the desired phase rather than undesired ones. It is a common observation in the synthesis of zeolites that the desired phase can only be formed in a proper temperature range, beyond which undesired phases such as dense phases may appear or even dominate in the final product. This phenomenon is primarily because each phase may have its own optimal temperature at which it is the most kinetically preferred. If the OSDA is used, considerations should also be made to avoid the overly fast decomposition of OSDA at high temperatures.
Fast heating of the tubular reactor can offer other benefits that cannot be expected in the conventional autoclaves. For one thing, the tubular reactor can help address the negative effects associated with the thermal lag that exist in the conventional autoclaves. During the temperature increasing step, many reactions may take place, including the ones that can exert adverse effects on the synthesis, such as the decomposition of OSDA and the dissolution of the seed. For example, it was reported that the quaternary ammonium cations can decompose through Hoffman degradation.151–153 Meanwhile, the decomposition of the isolated quaternary ammonium cations is more pronounced compared with those that are trapped inside aluminosilicates.154 These results indicate that the decomposition of the OSDA at the temperature increasing stage cannot be neglected, especially when the heating is performed in a slow manner. The tubular reactor can to some extent minimize the negative effect of the OSDA decomposition, because it allows fast heating and avoids thermal lag. Consequently, fast crystallization at high temperatures can consume the OSDA before the onset of its considerable decomposition. In a similar manner, fast heating can also help avoid the undesired dissolution of the seed which may occur in a slow heating environment.
Based on the above discussion, a generalized scheme of the ultrafast synthesis was proposed, which takes into consideration the events taking place consequently under different temperatures and at different time scales (Fig. 8).
Fig. 8 A generalized scheme for the ultrafast synthesis, which is proposed by taking into consideration the events taking place at different stages under different temperatures and at different time scales.
Secondly, the addition of the seed can help avoid heterogeneous nucleation, a major bottleneck hindering the fast synthesis. It is worth noting that the size of the seed crystal matters. The seed with a smaller size is more effective than the one with a larger size because the smaller seed can provide sufficient external surface area to support seeded growth. Meanwhile, the timing for seeding should be tuned to optimize the seeding effect. The timing is particularly important in the case where aging is carried out at a relatively higher temperature, because dissolution of the seed may occur and be prompted at elevated temperatures.
Through the above tuning, a precursor ready for crystal growth has been created. Crystal growth may have already started at this moment, but at a less noticeable rate. Superficially, this precursor would lead to the formation of the desired phase at a relatively faster rate once it is subjected to hydrothermal treatment at high temperatures. However, that is not taken for granted. When the synthesis is carried out in an autoclave, nucleation of a competing phase may occur, leading to the formation of a by-product. This situation is primarily due to the fact that the slow heating in the autoclave creates an environment where the formation of a comparably metastable phase may be favored. To prevent any undesired phase from being formed, the tubular reactor which is to be heated in a preheated oil bath is a better alternative. Due to the feature of fast heating, the tubular reactor can help avoid the negative effects associated with thermal lag and thereof the generation of the undesired phases.
Finally, high temperatures are preferred to achieve an ultrafast crystal growth. Theoretically, the higher the synthesis temperature, the faster the crystallization rate. However, the maximum temperature is restrained by several aspects, which include but may not be limited to the following points: (1) the possibility of forming a denser phase, (2) the decomposition of OSDA (if any), (3) the limitation from the heating tool and medium, and (4) safety considerations.
Generally, a continuous flow design may be easily applied to a reaction which has a fast reaction rate or to a reaction in which no solid reagents and/or products are involved.168 For example, several metal–organic framework (MOF) materials have been synthesized in continuous flow reactors, largely because the target crystalline materials could be obtained within a short period of synthesis time, i.e., a short residence time.169–171 Specific to zeolites, however, two features of the synthesis – the long synthesis period and the formation of a solid product – render the continuous flow synthesis difficult to perform.
A comprehensive strategy is therefore needed to address this challenge. The first prerequisite is to improve the overall crystallization rate of zeolites so as to shorten the residence time. Efforts aimed at modifying the hydrodynamic conditions should also be made to overcome possible flow failures. In addition, the synthesis conditions need careful tuning to avoid the generation of any undesired phases. Though the ultrafast synthesis lays a solid basis, other factors should be considered to realize a continuous-flow synthesis. The key to achieve continuous-flow preparation of high-silica zeolites is to match the kinetics, thermodynamics and hydrodynamics (Fig. 9a).102 Mismatch among these three factors may cause practical difficulties or even make continuous-flow synthesis impossible.
The one-minute synthesis of AlPO4-5 in the tubular reactor was successfully reproduced in a continuous flow reactor where the synergistic effect between the seed-assisted method and fast heating could be achieved.172 The product synthesized in the continuous flow reactor was shown to possess the same properties as the one obtained in the tubular reactor. Meanwhile, the reuse of the product synthesized in the continuous flow reactor as a seed was also demonstrated, which can avoid the production of seed materials using the conventional method. The continuous flow synthesis of AlPO4-5 represents a simple, one-stage design (Fig. 9b), and can be applied to other cases (for example, SAPO-5 and SAPO-34)105 where the fluidity of the synthesis mixture can be well maintained throughout the synthesis.
As discussed above, due to fast heating and thereof high time resolution, the tubular reactor has opened the possibility to synthesize zeolites on the order of minutes. But it does not mean that the limit of the crystallization rate has been reached. In fact, a higher crystallization rate could not be expected in the tubular reactor because it still takes around 1 min for heat transfer from the external heating medium to the reactant inside. Meanwhile, higher temperature could not be employed due to the restrictions from the heating medium. A new synthesis platform is thus required to explore the limit of crystallization further.
Recently, we have demonstrated a synthetic process for ZSM-5 on the order of seconds in a continuous flow reactor using pressurized hot water as a heating medium (Fig. 10).179 Owing to specific physical and chemical properties, the pressurized hot water with extremely high temperatures can be advantageous to the hydrothermal processing.180,181 By directly mixing a well-tuned synthesis precursor at 90 °C with a flow of the pressurized hot water preheated to 370 °C in the continuous flow reactor, immediate heating to high temperatures (240 to 300 °C, depending on the synthesis precursor to pressurized hot water ratio) could be achieved, which prompted the crystallization of ZSM-5 to completion within several seconds. This result is the first observation indicating the crystallization of zeolites on the order of seconds.
The instantaneous heating to high temperature is one of the key factors for the synthesis on the order of seconds. Obvious crystal growth was observed even after a residence time as short as 1 s, indicating a time resolution of one second. This instantaneous heating could further minimize the thermal lag effect, which is very crucial, because the crystal growth can be induced immediately and completed before the total decomposition of the OSDA under strongly basic, high-temperature conditions. In a tubular reactor heated in an aluminium block, it took almost 5 min to complete the crystallization as opposed to 6 s in the continuous flow reactor, even though both syntheses were performed at the same temperature.
Proper tuning of the precursor is another key contributing factor. Aging at 90 °C for several hours was performed in an attempt to tune the precursor, and the synthesis time was found to be dependent on the aging time. An ultrafast synthesis within 16 s could also be achieved even when the synthesis precursor was aged for as short as 2 h. Characterization results indicated that the aging prompted the interactions between the inorganic and organic species and created a precursor with short-range order that could result in immediate crystal growth once it was subjected to high temperatures. It is worth noting that no ZSM-5 seed was added in this case, as proper aging could provide sufficient nuclei to support an immediate crystal growth.
The complexity of the formation of zeolites determines that the ultrafast synthesis is not an easy task. Establishment of the ultrafast synthesis should be based on a comprehensive strategy considering both engineering and chemistry perspectives. In the review, both the kinetic and thermodynamic barriers behind the crystallization and the factors that contribute to the ultrafast synthesis were discussed. The factors contributing to the ultrafast synthesis were individually analyzed. The results showed that a comprehensive strategy is needed to overcome the particular thresholds at each certain stage of crystallization. In general, this strategy aims to skip the steps that are actually unnecessary or could be conducted at a low temperature environment prior to the high temperature synthesis, which finally leads to successful synthesis in a very short period of time. These efforts would definitely be helpful to direct the ultrafast synthesis of other zeolites in the future. Based on the ultrafast synthesis, the continuous flow synthesis of zeolites was successfully demonstrated. Furthermore, continuous flow synthesis of ZSM-5 on the order of seconds was also achieved, which was the first observation showing that crystallization of zeolites could be completed within a period of time as short as several seconds, indicating a far-reaching consequence of the ultrafast synthesis.
The potential of the ultrafast synthesis has just been revealed. There might still be room to explore even further increases in the crystallization rate of zeolites. To this end, new reaction systems as well as new ideas for easing the synthesis bottlenecks should be conceived. It is worth noting that the entire synthesis includes not only the crystallization of zeolites taking place in the hydrothermal synthesis but also the pre-synthesis operation such as mixing and aging as well as the post-synthesis treatment such as washing and drying. Therefore, endeavors should be made to enhance the efficiency in these steps. In particular, the long period of aging should be carefully studied in order to shorten the overall preparation period. Such efforts towards the realization of a much faster synthesis, in return, would further benefit the understanding of the nature of crystallization of microporous materials. Recently, we have demonstrated the ultrafast synthesis of *BEA zeolite in 10 min, in which case aging was not involved but the optimization of the composition of the synthesis precursor was found to be crucial.182 This result could help us better understand and design the ultrafast synthesis of zeolites.
From another point of view, the ultrafast synthesis has opened a window for the mechanistic study of crystallization. Since the complexity of crystallization of zeolites is far from being fully understood, there are many fields where new perspectives are expected from new synthesis techniques/tools. The following are the fields where the ultrafast synthesis and the associate reactors can show advantages: (1) precise control over the properties, for example, morphology and the distribution of T-atoms, (2) preparation of zeolites for which competitive phases always exist, (3) fast incorporation of heteroatoms into zeolites, and (4) combination with post-treatment techniques to explore the properties of zeolites.
We thank the coauthors of the papers that the Okubo group has published on the ultrafast synthesis and the continuous flow synthesis of zeolites and Mitsubishi Chemical Cooperation for partially funding those investigations. We also thank the New Energy and Industrial Technology Development Organization for partially funding those investigations.
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