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Timestamp: 2019-04-20 00:26:29+00:00

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Solubility: very sol H2O; slightly sol ethanol, acetone, acetic acid.
Form Supplied in: brown-red solid. Drying: at 100 °C/0.1 mmHg for 24 h.
Preparative Method: very often prepared in situ from 1 equiv of Palladium(II) Chloride and 2 equiv of Lithium Chloride in the appropriate solvent (MeOH, EtOH, MeCO2H).
Handling, Storage, and Precautions: is hygroscopic and should be stored in the absence of moisture. The trihydrate is formed in aqueous solution. Toxicity data are not available.
1. (a) Heck, R. F. Palladium Reagents in Organic Syntheses; Academic: London, 1985. (b) Maitlis, P. M. The Organic Chemistry of Palladium; Academic: New York, 1971. (c) Tsuji, J. Organic Synthesis with Palladium Compounds; Springer: Berlin, 1980. (d) Ryabov, A. D. S 1985, 233. (e) Gmelin Handbook of Inorganic Chemistry; Springer: Berlin, 1986; Pt Suppl. Vol. A1, pp 299-308. (f) Chemistry of the Platinum Group Metals; Hartley, F. R., Ed.; Elsevier: Amsterdam, 1991.
2. (a) Omae, I. CRV 1979, 79, 287. (b) Newkome, G. R.; Puckett, W. E.; Gupta, V. K.; Kiefer, G. E. CRV 1986, 86, 451. (c) Dunina, V. V.; Zalevskaya, O. A.; Potapov, V. M. RCR 1988, 57, 250. (d) Ryabov, A. D. CRV 1990, 90, 403.
3. Bayer, E.; Geckeler, K. AG(E) 1979, 18, 533.
4. (a) Okano, T.; Okabe, N.; Kiji, J. BCJ 1992, 65, 2589. (b) Kiji, J.; Okano, T.; Konishi, H.; Nishiumi, W. CL 1989, 1873.
5. Tsuji, J.; Nagashima, H.; Hori, K. CL 1980, 257.
6. (a) Tani, K.; Brown, L. D.; Ahmed, J.; Ibers, J. A.; Yokota, M.; Nakamura, A.; Otsuka, S. JACS 1977, 99, 7876. (b) Davis, R. C.; Grinter, T. J.; Leaver, D.; O'Neil, R. M.; Thomson, G. A. JCR(S) 1987, 280.
7. (a) Baldwin, J. E.; Jones, R. H.; Najera, C.; Yus, M. T 1985, 41, 699. (b) Baldwin, J. E.; Najera, C.; Yus, M. CC 1985, 126.
8. Rocherolle, V.; Lopez, J. C.; Olesker, A.; Lukacs, G. CC 1988, 513.
9. (a) Kauffmann, T.; Gaydoul, K. R. TL 1985, 26, 4071. (b) Wipke, W. T.; Goeke, G. L. JOC 1975, 40, 3242.
10. (a) Akermark, B.; Akermark, G.; Hegedus, L. S.; Zetterberg, K. JACS 1981, 103, 3037. (b) Söderberg, B. C.; Akermark, B.; Chen, Y. H.; Hall, S. S. JOC 1990, 55, 1344.
11. Rozenberg, V. I.; Nikanorov, V. A.; Gavrilova, G. V.; Gushchin, V. V.; Bakhmutov, V. I.; Reutov, O. A. IZV 1986, 2393.
12. Nizova, G. V.; Shul'pin, G. B. IZV 1987, 2070.
13. (a) Trost, B. M.; Weber, L.; Strege, P. E.; Fullerton, T. J.; Dietsche, T. J. JACS 1978, 100, 3416. (b) Trost, B. M.; Keinan, E. JOC 1979, 44, 3451.
14. Ozawa, F.; Yamagami, I.; Nakano, M.; Fujisawa, F.; Yamamoto, A. CL 1989, 125.
15. Antonsson, T.; Hansson, S.; Moberg, C. ACS 1985, B39, 593.
16. Poss, A. J.; Smyth, M. S. SC 1987, 17, 1735.

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