Source: http://www.proceedings.blucher.com.br/article-details/estudo-cintico-e-de-equilbrio-da-biossoro-do-corante-castanho-krom-pelo-resduo-de-vincola-20612
Timestamp: 2019-04-20 10:50:41+00:00

Document:
Neste trabalho avaliou-se a capacidade de remoção do corante Castanho KROM utilizando-se o resíduo de vinícola como biossorvente. Os testes realizados foram conduzidos em sistema batelada sob agitação constante, temperatura e pH controlados. Os testes preliminares indicaram que as condições operacionais de pH 2,0, granulometria intermediária e temperatura de 25°C, favorecem o processo de biossorção do corante, sendo estas condições utilizadas para obtenção dos dados cinéticos e de equilíbrio de adsorção. O tempo de equilíbrio determinado foi de aproximadamente 12 h, sendo o modelo cinético de pseudoprimeira ordem o que melhor representou os dados experimentais. Os dados de equilíbrio de adsorção sugerem um processo em monocamadas, seguindo o modelo de Langmuir, com capacidade máxima de biossorção de 182,2 ± 2,8 mg g-1. Com base nos resultados obtidos, verificou-se que o bagaço de uva apresenta potencial de utilização como biossorvente em sistemas de tratamento de efluentes contendo corantes.
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 CHIEN, S. H.; CLAYTON, W. R.; Application of Elovich equation to the kinetics of phosphate release and sorption in soils; Soil Sci Soc Am J; v. 44; p. 265-268; 1980.
 EL-BINDARY, A.A.; EL-SONBATI, A.Z.; AL-SARAWY, A.A.; MOHAMED, K.S.; FARID, M.A.; Adsorption and thermodynamic studies of hazardous azocoumarin dye from an aqueous solution onto low cost rice straw based carbons; Journal of Molecular Liquids; v. 199; 2014.
 FIORENTIN, L.D.; TRIGUEROS, D.E.G.; MÓDENES, A.N.; ESPINOZA-QUIÑONES, F.R.; PEREIRA, N.C.; BARROS, S.T.D.; SANTOS, O.A.A.; Biosorption of reactive blue 5G dye onto drying orange bagasse in batch system: Kinetic and equilibrium modeling; Chemical Engineering Journal; v. 163; p. 68–77; 2010.
 FREUNDLICH H.; Over the adsorption in solution (Uber die adsorption in Lusungen); Journal of Physical Chemistry (Zeitschrift fur Physikalische Chemie); v. 57; p. 385 - 470; 1906.
 HO, Y.S.; McKAY, G.; A comparison of chemisorption kinetic models applied to pollutant removal on various sorbents; Trans Institution of Chemical Engineers; v. 76, 1998.
 KEBRIA, M.R.S.; JAHANSHAHI, M.; RAHIMPOUR, A.; SiO2 modified polyethyleneimine-based nanofiltration membranes for dye removal from aqueous and organic solutions; Desalination; v. 367; p. 255-264; 2015.
 KUNZ, A., PERALTA-ZAMORA, P., MORAES, S.G., DURÁN, N.; Novas tendências no tratamento de efluentes têxteis; Química Nova; v. 25; n. 1; p. 78 - 82; 2002.
 LAGERGREN, S., About the theory of so-called adsorption of soluble substances; Kungliga Suensk Vetenskapsakademiens Handlingar; v. 4; p. 1 – 39; 1898.
 LANGMUIR, I.; The adsorption of gases on plane surfaces of glass, mica and platinum; Journal of the American Chemical Society; v. 40; n. 9; p. 1361 – 1403; 1918.
 MÓDENES, A.N.; ESPINOZA-QUIÑONES, F.R.; ALFLEN, V.L.; COLOMBO, A.; BORBA, C.E.; Utilização da macrófita Egeria densa na biossorção do corante reativo 5G. Engevista; v. 13; n. 3; p. 160-166; 2011.
 MÓDENES, A.N.; ESPINOZA-QUIÑONES, F.R.; BORBA, F.H.; MANENTI, D.R.; Performance evaluation of an integrated Photo-Fenton – Electrocoagulation process applied to pollutant removal from tannery effluent in batch system; Chemical Engineering Journal; v. 197; p. 1 – 9; 2012.
 MÓDENES, A.N.; ROSS, A.A.; SOUZA, B.V.; DOTTO, J.; GERALDI, C.Q.; ESPINOZA-QUIÑONES F.R.; KROUMOV, A.D.; Biosorption of BF-4B Reactive Red Dye by using Leaves of Macrophytes Eichhornia crassipes; Int. Journal BIOautomation; v. 17; p. 33-44; 2013.
 MONA, S.; KAUSHIK, A.; KAUSHIK, C.P.; Biosorption of reactive dye by waste biomass of Nostoc linckia; Ecological Engineering; v. 37; p. 1589 - 1594; 2011.
 NOREEN, S.; BHATTI, H.N.; Fitting of equilibrium and kinetic data for the removal of Novacron Orange P-2R by sugarcane bagasse; Journal of Industrial and Engineering Chemistry; v. 20; p. 1684 - 1692; 2014.
 PING L.; PIZZI, A.; GUO, Z.D.; BROSSE, N.; Condensed tannins from grape pomace: Characterization by FTIR and MALDI TOF and production of environment friendly wood adhesive; Industrial Crops Andamp; Products; v. 40; p. 13 – 20; 2012.
 RADUSHKEVICH, L.V.; KOLGANOV, V.A.; Experimental Study of the Deposition of Flowing Highly Dispersed Aerosols on Thin Cylinders; Institute of Physical Chemistry; Academy of Sciences of the USSR; Moscow; U.S.S.R. Received; 1967.
 RANGABHASHIYAM, S.; ANU, N.; SELVARAJU, N.; Sequestration of dye from textile industry wastewater using agricultural waste products as adsorbents; Biochemical Pharmacology; v. 1; p. 629 - 641; 2013.
 REDLICH, O., PETERSON, D.L.; A useful adsorption isotherm; The Journal of Physical Chemistry; v.63, p. 1024 – 1026, 1959.
 SALLEH, M.A.M.; MAHMOUD, D.K.; KARIM, W.A.W.A.; IDRIS, A.; Cationic and anionic dye adsorption by agricultural solid wastes: A comprehensive review, Desalination, v. 280; p. 1 - 13; 2011.
 SIPS, R.; Combined form of Langmuir and Freundlich equations; Journal of Chemical Physics; v. 16; p. 490 – 495; 1948.
 SOTO, M.L.; MOURE, A.; DOMÍNGUEZ, H.; PARAJO, J.C.; Charcoal adsorption of phenolic compounds present in distilled grape pomace; Journal of Food Engineering; v. 84; p. 156 – 163; 2008.
 SRINIVASAN, A., VIRARAGHAVAN, T. Decolorization of dye wastewaters by biosorbents: A review; Journal of Environmental Management; v. 91; n. 10; p. 1915 – 1929; 2010.
 TEMKIN, D.E.; Interface Kinetics In The Growth Of Two.Component Crystals; Journal of Crystal Growth; v. 52; p. 299 – 310; 1981.
 TOTH, J.; State equations of the solid gas interface layer; Acta Chimica Academiae Scientiarum Hungaricae; v. 69; p. 311 – 317; 1971.
 YU, J.; ZHU, J.; FENG, L.; CHI, R. Simultaneous removal of cationic and anionic dyes by the mixed sorbent of magnetic and non-magnetic modified sugarcane bagasse; Journal of Colloid and Interface Science; v. 451; p. 153 - 160, 2015.
 ZHANG, Y.; OU, J.; DUAN, Z.; XING, Z.; WANG, Y.; Adsorption of Cr(VI) on bamboo bark-based activated carbon in the absence and presence of humic acid; Colloids and Surfaces A: Physicochemical and Engineering Aspects; v. 481; p. 108-116; 2015.
 ZHOU, Z.; LIN, S.; YUE, T.; LEE, T.; Adsorption of food dyes from aqueous solution by glutaraldehyde cross-linked magnetic chitosan nanoparticles; Journal Of Food Engineering; v. 126; p. 133 - 141; 2014.
 ZHU, F.; DU, B.; ZHENG, L.; LI, J.; Advance on the bioactivity and potential applications of dietary fibre from grape pomace; Food Chemistry; v. 186; p. 207-212; 2015.
BRAGIÃO, MARIA EDUARDA; MÓDENES, APARECIDO NIVALDO; OLIVEIRA, ANA PAULA DE; BEZERRA, ISABELLA GARCIA DE OLIVEIRA; TRIGUEROS, DANIELA ESTELITA GÓES; SAUSEN, MATEUS GUSTAVO; "ESTUDO CINÉTICO E DE EQUILÍBRIO DA BIOSSORÇÃO DO CORANTE CASTANHO KROM PELO RESÍDUO DE VINÍCOLA", p. 270-279 . In: In Anais do XXXVII Congresso Brasileiro de Sistemas Particulados - ENEMP 2015 [=Blucher Engineering Proceedings]. São Paulo: Blucher, 2015. . São Paulo: Blucher, 2015.
ANASTOPOULOS, I.; KYZAS G.Z.; Agricultural peels for dye adsorption: A review of recent literature; Journal of Molecular Liquids; v. 200; p. 381-389; 2014. BAKHEET, B.; YUAN, S.; LI, Z.; WANG, H.; ZUO, J.; KOMARNENI, S.; WANG, Y. Electro-peroxone treatment of Orange II dye wastewater; Water research; v. 47; p. 6234– 6243; 2013. BRAHIM, M.; GAMBIER, F.; BROSSE, N. Optimization of polyphenols extraction from grape residues in water medium; Industrial Crops and Products; v. 52; p. 18–22; 2014. CHIEN, S. H.; CLAYTON, W. R.; Application of Elovich equation to the kinetics of phosphate release and sorption in soils; Soil Sci Soc Am J; v. 44; p. 265-268; 1980. EL-BINDARY, A.A.; EL-SONBATI, A.Z.; AL-SARAWY, A.A.; MOHAMED, K.S.; FARID, M.A.; Adsorption and thermodynamic studies of hazardous azocoumarin dye from an aqueous solution onto low cost rice straw based carbons; Journal of Molecular Liquids; v. 199; 2014. FIORENTIN, L.D.; TRIGUEROS, D.E.G.; MÓDENES, A.N.; ESPINOZA-QUIÑONES, F.R.; PEREIRA, N.C.; BARROS, S.T.D.; SANTOS, O.A.A.; Biosorption of reactive blue 5G dye onto drying orange bagasse in batch system: Kinetic and equilibrium modeling; Chemical Engineering Journal; v. 163; p. 68–77; 2010. FREUNDLICH H.; Over the adsorption in solution (Uber die adsorption in Lusungen); Journal of Physical Chemistry (Zeitschrift fur Physikalische Chemie); v. 57; p. 385 - 470; 1906. GUPTA, V.K.; SUHAS.; Application of low- cost adsorbents for dye removal – A review; Journal of Environmental Management; v. 90; 2009. HO, Y.S.; McKAY, G.; A comparison of chemisorption kinetic models applied to pollutant removal on various sorbents; Trans Institution of Chemical Engineers; v. 76, 1998. KEBRIA, M.R.S.; JAHANSHAHI, M.; RAHIMPOUR, A.; SiO2 modified polyethyleneimine-based nanofiltration membranes for dye removal from aqueous and organic solutions; Desalination; v. 367; p. 255-264; 2015. KUNZ, A., PERALTA-ZAMORA, P., MORAES, S.G., DURÁN, N.; Novas tendências no tratamento de efluentes têxteis; Química Nova; v. 25; n. 1; p. 78 - 82; 2002. LAGERGREN, S., About the theory of so-called adsorption of soluble substances; Kungliga Suensk Vetenskapsakademiens Handlingar; v. 4; p. 1 – 39; 1898. LANGMUIR, I.; The adsorption of gases on plane surfaces of glass, mica and platinum; Journal of the American Chemical Society; v. 40; n. 9; p. 1361 – 1403; 1918. MANENTI, D.R.; SOARES, P.A.; MÓDENES, A.N.; ESPINOZA-QUIÑONES, F.R.; BOAVENTURA, R.A.R.; BERGAMASCO, R.; VILAR, V.J.P.; Insights into solar photo-Fenton process using iron(III) organic ligand complexes applied to real textile wastewater treatment; Chemical Engineering Journal; v. 266; p. 203 - 212; 2015. MÓDENES, A.N.; ESPINOZA-QUIÑONES, F.R.; ALFLEN, V.L.; COLOMBO, A.; BORBA, C.E.; Utilização da macrófita Egeria densa na biossorção do corante reativo 5G. Engevista; v. 13; n. 3; p. 160-166; 2011. MÓDENES, A.N.; ESPINOZA-QUIÑONES, F.R.; BORBA, F.H.; MANENTI, D.R.; Performance evaluation of an integrated Photo-Fenton – Electrocoagulation process applied to pollutant removal from tannery effluent in batch system; Chemical Engineering Journal; v. 197; p. 1 – 9; 2012. MÓDENES, A.N.; ROSS, A.A.; SOUZA, B.V.; DOTTO, J.; GERALDI, C.Q.; ESPINOZA-QUIÑONES F.R.; KROUMOV, A.D.; Biosorption of BF-4B Reactive Red Dye by using Leaves of Macrophytes Eichhornia crassipes; Int. Journal BIOautomation; v. 17; p. 33-44; 2013. MONA, S.; KAUSHIK, A.; KAUSHIK, C.P.; Biosorption of reactive dye by waste biomass of Nostoc linckia; Ecological Engineering; v. 37; p. 1589 - 1594; 2011. NOREEN, S.; BHATTI, H.N.; Fitting of equilibrium and kinetic data for the removal of Novacron Orange P-2R by sugarcane bagasse; Journal of Industrial and Engineering Chemistry; v. 20; p. 1684 - 1692; 2014. PING L.; PIZZI, A.; GUO, Z.D.; BROSSE, N.; Condensed tannins from grape pomace: Characterization by FTIR and MALDI TOF and production of environment friendly wood adhesive; Industrial Crops Andamp; Products; v. 40; p. 13 – 20; 2012. RADUSHKEVICH, L.V.; KOLGANOV, V.A.; Experimental Study of the Deposition of Flowing Highly Dispersed Aerosols on Thin Cylinders; Institute of Physical Chemistry; Academy of Sciences of the USSR; Moscow; U.S.S.R. Received; 1967. RANGABHASHIYAM, S.; ANU, N.; SELVARAJU, N.; Sequestration of dye from textile industry wastewater using agricultural waste products as adsorbents; Biochemical Pharmacology; v. 1; p. 629 - 641; 2013. REDLICH, O., PETERSON, D.L.; A useful adsorption isotherm; The Journal of Physical Chemistry; v.63, p. 1024 – 1026, 1959. SALLEH, M.A.M.; MAHMOUD, D.K.; KARIM, W.A.W.A.; IDRIS, A.; Cationic and anionic dye adsorption by agricultural solid wastes: A comprehensive review, Desalination, v. 280; p. 1 - 13; 2011. SIPS, R.; Combined form of Langmuir and Freundlich equations; Journal of Chemical Physics; v. 16; p. 490 – 495; 1948. SOTO, M.L.; MOURE, A.; DOMÍNGUEZ, H.; PARAJO, J.C.; Charcoal adsorption of phenolic compounds present in distilled grape pomace; Journal of Food Engineering; v. 84; p. 156 – 163; 2008. SRINIVASAN, A., VIRARAGHAVAN, T. Decolorization of dye wastewaters by biosorbents: A review; Journal of Environmental Management; v. 91; n. 10; p. 1915 – 1929; 2010. TEMKIN, D.E.; Interface Kinetics In The Growth Of Two.Component Crystals; Journal of Crystal Growth; v. 52; p. 299 – 310; 1981. TOTH, J.; State equations of the solid gas interface layer; Acta Chimica Academiae Scientiarum Hungaricae; v. 69; p. 311 – 317; 1971. YU, J.; ZHU, J.; FENG, L.; CHI, R. Simultaneous removal of cationic and anionic dyes by the mixed sorbent of magnetic and non-magnetic modified sugarcane bagasse; Journal of Colloid and Interface Science; v. 451; p. 153 - 160, 2015. ZHANG, Y.; OU, J.; DUAN, Z.; XING, Z.; WANG, Y.; Adsorption of Cr(VI) on bamboo bark-based activated carbon in the absence and presence of humic acid; Colloids and Surfaces A: Physicochemical and Engineering Aspects; v. 481; p. 108-116; 2015. ZHOU, Z.; LIN, S.; YUE, T.; LEE, T.; Adsorption of food dyes from aqueous solution by glutaraldehyde cross-linked magnetic chitosan nanoparticles; Journal Of Food Engineering; v. 126; p. 133 - 141; 2014. ZHU, F.; DU, B.; ZHENG, L.; LI, J.; Advance on the bioactivity and potential applications of dietary fibre from grape pomace; Food Chemistry; v. 186; p. 207-212; 2015.

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