Source: https://patents.google.com/patent/EP1364639A2/en
Timestamp: 2019-04-21 17:32:54+00:00

Document:
The invention concerns a Cosmetic formulation comprising 99,9 weight -% - 70 weigth-% of a basic cosmetic fomulation selected from the group of transparent pearly lotion, gel cologne with sparkles, pearlescent waterproof sun creme, bronze self tanning cream, sunscreen creme, pearl bronze/copper suntan cream, Icy gel toothpaste, face mask for oily skin, moisturizing body veil, clarifying bright lotion, snow white body cream, cleansing scrub, silky BHA lotion, sunshine body cream, skin moisturizing gel, liquid pearl bath soap, bath dusting powder, bath and shower gel, highlighting hair gel, conditioner, low pH shampoo, sparkle hair spray, festival hair gel, iridescent hair conditioner, conditioning shampoo, pearly foundation cream, blush stick, face bronze pressed powder, silky finish loose face powder, liquid makeup, body veil, earthtone makeup powder, liquid foundation, creamy peral blush, sheer leg makeup, face bronzer with sunscreen, silky face powder, shimmering pearl pressed powder blush, all purpose color stick, dual face powder, radiance pressed powder blush, gel blush frost, sparkling ruby nail enamel, poured eye shadow, cream eye shadow, emulsion cream mascera, eye shadow, liquid eyeliner, pressed powder eye shadow, emulsion cream eye shadow, charcoal silky powder eyeliner, loose powder eye shadow, concealer, sheer satin pressed powder eye shadows, crayon eye shadow, velvety pressed powder eye shadow, waterproof mascara, slender stick eye shadow, silky pressed powder eye shadow, lipstick, fair taupe lipstick, lip gloss with sunscreen, glossy lipstick, shimmering brick lipstick, lip pomade, soft lipstick, pressed lip powder, long wear lipstick, lipstick with sunscreen, lip glaze-formulation.
The invention is characterized in that 0,01 - 30 weight-% glasses or color glass or glass ceramics or ceramics or glass powders or color glass powders or glass ceramic powders or ceramic powders or composite materials comprising glass or glass ceramics or ceramic powders or mixtures of glass, ceramic and glass ceramic powders.
The invention relates to cosmetic formulations with glasses or color glass or glass ceramics or ceramics or glass powders or color glass powders or glass ceramic powders or ceramic powders or composite materials comprising glass or glass ceramics or ceramic powders or mixtures of glass, ceramic and glass ceramic powders.
Glasses could be e.g. glasses with antimicrobial, anti inflammatory, light absorbion, light scattering, light reflecting, mineral building, bioactive and coloring properties.
Ceramics could be e.g. oxide ceramics like Alumina, Zirconia, Mica (e.g. inorganic pigments), Silicates, Talc or Non oxide ceramics like Boronnitide, Aluminumnitride and Siliconcarbide.
All powders could be coated with inorganic functional layers e.g. TiO2, SiO2 and silane or organic functional layers.
The powders could be mixed with organic or inorganic pigments for coloring.
Powders include powders, spheres, granulates, nanoparticles, flakes and fibers.
Antimikrobiell glasses are known e.g. from US 5,290,544, US 6,143,318 , JP 10218637, JP 08245240, JP 07291654, JP 03146436, JP 2000264674, JP 2000203876, DE 19932238, der DE 19932239 und der WO 01/0365.
The essential feature of bioactive glass are known for the man skilled in the art and described e.g. in US 5,074,916. Bioactive glasses are characterized in that living tissue is bound by it. Bioactive glass e.g. bounds to the tissue thereby providing for a Hydroxyl-Apatit-Layer.
Color glasses are glasses with a color effect. This color effect can be produced e.g. by ions or nanoparticles. The nanoparticles can be metallic nanoparticles or semiconductor nanoparticles. Color glasses are used for coloring cosmetic products or for absorbing UV- or IR-radiation.
Object of the invention is to provide for cosmetic formulations with glasses or color glass or glass ceramics or ceramics or glass powders or color glass powders or glass ceramic powders or ceramic powders or composite materials comprising glass or glass ceramics or ceramic powders or mixtures of glass, ceramic and glass ceramic powders.
This object is solved by one claim 1.
transparent pearly lotion, gel cologne with sparkles, pearlescent waterproof sun creme, bronze self tanning cream, sunscreen creme, pearl bronze/copper suntan cream, Icy gel toothpaste, face mask for oily skin, moisturizing body veil, clarifying bright lotion, snow white body cream, cleansing scrub, silky BHA lotion, sunshine body cream, skin moisturizing gel, liquid pearl bath soap, bath dusting powder, bath and shower gel, highlighting hair gel, conditioner, low pH shampoo, sparkle hair spray, festival hair gel, iridescent hair conditioner, conditioning shampoo, pearly foundation cream, blush stick, face bronze pressed powder, silky finish loose face powder, liquid makeup, body veil, earthtone makeup powder, liquid foundation, creamy peral blush, sheer leg makeup, face bronzer with sunscreen, silky face powder, shimmering pearl pressed powder blush, all purpose color stick, dual face powder, radiance pressed powder blush, gel blush frost, sparkling ruby nail enamel, poured eye shadow, cream eye shadow, emulsion cream mascera, eye shadow, liquid eyeliner, pressed powder eye shadow, emulsion cream eye shadow, charcoal silky powder eyeliner, loose powder eye shadow, concealer, sheer satin pressed powder eye shadows, crayon eye shadow, velvety pressed powder eye shadow, waterproof masara, slender stick eye shadow, silky pressed powder eye shadow, lipstick, fair taupe lipstick, lip gloss with sunscreen, glossy lipstick, shimmering brick lipstick, lip pomade, soft lipstick, pressed lip powder, long wear lipstick, lipstick with sunscreen, lip glaze.
Examples of basic cosmetic formulations for the above mentioned cosmetic products from Engelhard Corporation, 101 Wood Avenue, P.O.-Box 707 Iselin, NJ 08830-0770 are given in the appendix to the application.
The basic cosmetic formulations can be applied in colour cosmetics, hair, skin, and nail. The individual components of the basic cosmetic formulation are numerous and varied, but are also well known to one skilled in the art.
The basic cosmetic composition may comprise one or more of the members selected from the group consisting of acidifying agents, alkalizing agents, aerosol propellants, antimicrobial agents, antioxidants, buffering agents, chelating agents, coloring additives, dermotologicaly active agents, dispersing agents, emollients, emulsifying agents, humectants, fragrances, preservatives, sugars, sunscreen agents, surfactants, suspending agents, thickening agents, an vehicles. These ingredients are discussed below. Examples of these agents are listed below as well as in the International Cosmetic Ingredient Dictionary and Handbook, eds. Wenninger and McEwen (The Cosmetic, Toiletry, and Fragrance Assoc., Washington, D.C., 7.sup.th Edition, 1997) (hereinafter "ICT Handbook").
Acidifying and alkalizing agents are added to obtain the desired pH of the composition. Examples of is acidifying agents included citric acid, lactic acid, glycolic acid, acetic acid, glacial acetic acid, malic acid, and proprionic acid. Examples of alkalizing agent include edetol, potassium carbonate, potassium hydroxide, sodium borate, sodium carbonate, sodium citrate, sodium lactate, sodium glycolate, and sodium hydroxide. Other acidifying and alkalizing agents are listed on page 1653 of the ICT handbook.
Aerosol propellants are used when the composition is to be administered as an aerosol under pressure. Examples of aerosol propellants include halogenated hydrocarbons such as dichlorodifluoromethane, dichlorotetrafluoroethane, and trichloromonfluoromethane, nitrogen, and volatile hydrocarbons such as butane, propane, isobutane, or mixtures thereof. Other aerosol propellants are listed on page 1655 of the ICT handbook.
Antimicrobial agents are used when the area that the composition is to be applied is prone to microbial infection, e.g., by bacteria, fungal, or protozoa. Examples of such agents include benzyl alcohol, chlorobutanol, phenylethyl alcohol, phenylmercuric acetate, potassium sorbate, and sorbic acid, benzoic acid, butylparaben, ethylparaben, methylparaben, propyl paraben, and sodium benzoate. Other antimicrobial agents are listed on page 1612 of the ICT handbook.
Antioxidants are used to protect ingredients of the composition from oxidizing agents that are included within or come in contact with the composition. Examples of antioxidants include water soluble antioxidants such as grape seed extract, camellia oleifera extract, N-acetyl-L-cysteine, ascorbic acid, sodium sulfite, sodium formaldehyde, isoascorbic acid, cysteine hydrochloride, 1,4-diazobicyclo-(2,2,2)-octane, and mixtures thereof. Examples of oil-soluble antioxidants include ascorbyl palmitate, butytlated hydroxyanisole, butylated hydroxytoluene, potassium propyl gallate, octyl gallate, dodecyl gallate, phenyl-.alpha.-napthyl-amine, and tocopherols such as .alpha.-tocopherol. Other antioxidants are listed on pages 1612-13 of the ICT Handbook.
Buffering agents are used to maintain an established pH of the composition. Examples of buffering agents included calcium acetate, potassium metaphosphate, potassium phosphate monobasic, sodium citrate, and tataric acid. Other buffering agents are listed on page 1612 of the ICT handbook.
Chelating agents are used to maintain the ionic strength of the composition and/or bind to destructive compounds and metals that are included within or come in contact with the composition. Examples of chelating agents included edatate dipotassium, edetate disodium, edetic acid, and ethylenediamine tetracetic acid (EDTA) and its salts (e.g., tetrasodium EDTA). Other chelating agents are listed on page 1626 of the ICT handbook.
Coloring additives are used to add color to the composition in order to help the user identify the area in which the composition has been applied and/or modify the tanning color produced by the self-tanning agent in the composition. Examples of such coloring additives include caramel, carmine, fluorescein derivatives, methoxsalen, trioxsalen, carbon black, azo dyes, anthraquinone dyes, blue azulenes, guajazulene, chamuzulene, erythrosin, bengal rose, phloxin, cyanosin, daphinin, eosin G, cosin 10B, and Acid Red 51. Other coloring additives are listed on page 1628-30 of the ICT handbook. As discussed above, it is preferred not to use coloring additives which contain nitrogen or metals.
Examples of dispersing and suspending agents include poligeenan, magnesium aluminum silicate, xanthum gum, and silicon dioxide. Other dispersing or suspending agents are listed on page 1612 of the ICT handbook.
Emollients are agents which soften and smooth the skin. Examples of emollients include hydrocarbon oils and waxes such as mineral oil, petrolatum, microcrystaline wax, polyethylene, triglyceride esters such as those of castor oil, cocoa butter, safflower oil, cottonseed oil, corn oil, olive oil, cod liver oil, almond oil, avocado oil, palm oil, sesame oil, squalene, and soybean oil, acetylated monoglycerides, ethoxylated glycerides, fatty acids, alkyl esters of fatty acids, alkyl esters of benzoic acid (e.g., benzoates), alkenyl esters of fatty acids, fatty alcohols, fatty alcohol ethers, ether-esters, lanolin and derivatives of lanolin, polyhydric alcohol esters, wax esters such as beeswax, vegetable waxes, phospholidds, and sterols. Other emollients are listed on pages 1656-61 of the ICT handbook.
Emulsifying agents are used for preparing the oil-in-water emulsions of the present invention. Examples of emulsifying agents include Arlacel sub. 165. TM. and methyl gluceth sesquisterate, fatty alcohols, fatty alcohols and alkyl phenols condensed with ethylene oxide. Other emulsifiers are listed on pages 1679-87 of the ICT Handbook. Emulsion stabilizers are listed on pages 1634-35 of the ICT Handbook.
Humectants are agents which promote the retention of moisture, e.g., moisturizers. Examples of humectants include sorbitol, glycerin, glycereth 5 lactate, glycereth 7 triacetate, glycereth 7 diisononoate, hexanetriol, glycols such as methyl-propanediol, 1,2-pentanediol, hexylene glycol, and propylene glycol, alkoxylated glucose, D-panthenol and derivatives thereof, and hyaluronic acid. Other humectants are listed on pages 1661-62 of the ICT Handbook.
Examples of fragrances include peppermint, rose oil, rose water, aloe vera, clove oil, menthol, camphor, eucalyptus oil, and other plant extracts. Certain fragrances may require a solubilizer, e.g., PPG-5-ceteth-20. To eliminate certain odors from compositions, masking agents may be used. An example of a masking agent includes ethylene brassylate. Other fragrances and masking agents are listed on pages 1639-40 of the ICT Handbook.
Preservatives are used to protect the composition from degradation. Examples of preservatives include phenoxyethanol, benzoic aicd, benzyl alcohol, parabens such as methylparaben, propylparaben, butylparaben, isopropylparaben, and isobutylparaben, diazolidinyl urea, imidazolidinyl urea, diazolindyl urea, benzalkonium chloride, benzethonium chloride, phenol, and mixtures thereof (e.g., the paraben mixture Liquipar Oil.TM.). Other preservatives are listed on pages 1654-55 of the ICT Handbook.
Sugars are used to improve the results obatined by the self-tanning agents. Examples of sugars include monosaccharides, disaccharides, sorbitol, and polysccharides such as glucose, xylose, fructose, reose, ribose, pentose, arabinose, allose, tallose, altrose, mannose, galactose, lactose, sucrose, erythrose, glyceraldehyde, or any combination thereof.
Sunscreen agents are agents used to screen or reduce the amount of ultraviolet radiation impinging on the skin (e.g., by absorption, scattering, and reflection of the ultraviolet radiation). Segarin, et al., Cosmetics Science and Technology, Chapter VIII, pages 189, et seq. discloses numerous examples of sunscreen agents. Examples of sunscreen agents include both organic compounds and their salts such as phenylbenzimidazole sulfonic aicd, octyl methoxycinnamate, octyl salicylate, benzophenones such as benzophenone-3, homosalate, octocrylene, avobenzone, and menthyl anthranilate, as well as inorganic particulate materials such as zinc oxide and titanium dioxide. Other sunscreen agents are listed on page 1672 of the ICT Handbook. Generally, the composition will contain from about 1 % to about 50%, by weight, of sunscreen agent(s). The exact amounts will vary depending on the sunscreen used and the desired sun-protection factor (SPF), e.g., and SPF of at least 4 or an SPF of at least 15.
Surfactants are agents used to stabilize multi-component compositions, e.g., used as wetting agents, antifoam agents, emulsifiers, dispersing agents, and penetrants. Examples of surfactants include alkene oxide, ethers of fatty alcohols, glucose, and sorbitol, methyl gluceth 20, decyl polyglucoside, laureth 4, laureth 9, monoethanolamine, nonoxynol 4, nonoxynol 9, nonoxynol 10, nonoxynol 15, nonoxynol 30, poloxalene, polyoxyl 8, 40, and 50 stearate, polysorbate 20, polysorbate 40, polysorbate 60, polysorbate 65, polysorbate 80, and polysorbate 85, sodium lauryl sulfate, sorbitan and its derivatives. Other surfactants are listed on page 1672-90 of the ICT Handbook.
Vehicles are often referred to as the base for the basic cosmetic composition, e.g., a fluid that is capable of delivering the other components of the composition to the skin with acceptable absorption of those components into the skin. Examples of vehicles include water (e.g., deionized water), oil-in-water emulsions (e.g., where the continuous water phase contains the water soluble agents and the discontinuous oil phase contains the oil soluble agents), and water-in-oil emulsions (e.g., where the continuous oil phase contains the oil soluble agents and the discontinuous water phase contains the water soluble agents). The oil phase may be established by the addition of an animal/vegetable derived oil, ester, or ether, a hydrocarbon and/or silicone solvents, e.g., dimethicone and cyclomethicone, together with various emulsifying agents.
The basic cosmetic formulation may be in a number of different delivery forms, e.g., a spray, mist, aerosol, semi-solid cream, liquid such as a solution, emulsion, or suspension, lotion, gel, solid such as a powder, adherent stick, flexible mask, or self-hardening liquid or gel, or other suitable forms intended to be-applied to the hair, skin, or nails of a subject. Water-in-oil emulsions (e.g., ratio of about 10:1 to about 1:100 such as about 1:1 to about 1:10) and oil-in-water emulsions (e.g., ratio of about 10:1 to about 1:100 such as about 1:1 to about 1:10) are typically used in preparing lotions and creams.
The viscosity of the basic cosmetic composition depends upon the type of formulation being prepared, e.g., a liquid formulation will have a higher viscosity than a cream or gel formulation. Typically, the viscosity of cream formulations of the present invention will range from 5,000 to 150,000 cps (e.g., about 10,000 to about 40,000 cps). Bulking agents may be used to increase the viscosity of the composition. An example of a bulking agent is talc, magnesium aluminum salicate, and starches Other bulking agents are listed on page 1625-26 of the ICT Handbook. Other viscosity increasing agents are listed on pages 1693-97 of the ICT Handbook. Viscosity decreasing agents are listed on pages 1692-92 of the ICT Handbook.
The basic cosmetic formulation may be prepared using methodology that is well known by an artisan of ordinary skill (e.g., by using well-known mixing and blending procedures). For examples, for emulsion products of the present invention, each phase of the emulsion may be separately prepared with all of the components contained in their appropriate phases. The emulsion is then formed by adding one phase to the other phase with agitation.
The composition or product of the present invention may be packaged in a container that is well known by an artisan of ordinary skill, e.g., in a polyethylene or PVC tube with a dispensing cap.
The composition of the present invention may be prepared using methodology that is well known by an artisan of ordinary skill.
The basis glass for the glasses or color glass or glass ceramics or glass powders or color glass powders or glass ceramic powders or composite material which are mixed with the above mentioned cosmetic formulations comprise advantageously the following components.
Furthermore glasses with components given above can comprise ions as Fe, Co, Cr, V, Ce, Cu, Mn, Ni, Bi, Sn, Ag, Au, J up to a sum of 10 Gew-%. By this components a color effect or a anti-inflammatory effect can be achieved or a antimicrobiel glass can be obtained.
The glasses can also be used in composite materials comprising nanoparticles such as TiO2, ZnO, ZrO2, metallic gold or silver. The nanoparticles are smaller than 500nm, smaller than 200 nm, smaller than 100 nm, smaller than 50 nm, preferably smaller than 10 nm in size. The composit materials comprise nanoparticles up to 30 weight-%, up to 15 weight-%, up to 5 weight-% preferably up to 1 weight-% and most preferably up to 0,1 weight-%.
Preferred embodiments of the above mentioned glasses are given in table 1.
The glasses can be pulverized to glass powder. The particle size of the glass powder is < 100 µm, preferably < 50 µm 20 µm, most preferable < 10 µm. Advantagously the glass particles are < 1 µm. Glass powder of different siza can be combined.
Instead of glasses glass-ceramic-materials can be used. Glasses as given above and especially in table 1 are ceramized under temperatures 50- 400°C above Tg. The amount of the crystalline phase in the glass ceramic material is preferably greater than 5 weight-%, preferably greater than 30 weight-%, most preferably greater than 50 weight-%.
Usually the glass ceramic material is used as glass ceramic powder.
Glass ceramic powder can be obtained either by pulverizing the glass first and then ceramizing the pulverized glass powder or first ceramizing a block of glass and thereafter pulverizing the block or ribbon of glass ceramic material.
The particle size of the ceramic powder is < 500µm, preferably < 100µm, more preferably < 50 µm , most preferable < 10 µm. Advantagously the glass particles are < 1 µm. Glass powder of different size can be combined.
The invention will be described now by special embodiments without being restricted to them.
The preferred glasses as a basis for the glasses or color glass or glass ceramics or ceramics or glass powders or color glass powders or glass ceramic powders or ceramic powders or composite materials comprising glass or glass ceramics or ceramic powders or mixtures of glass, ceramic and glass ceramic powders which are mixed with basic cosmetic formulations as given in the appendix are shown in table 1.
In the appendix examples for basic cosmetic formulations for transparent pearly lotion, gel cologne with sparkles, pearlescent waterproof sun creme, bronze self tanning cream, sunscreen creme, pearl bronze/copper suntan cream, Icy gel toothpaste, face mask for oily skin, moisturizing body veil, clarifying bright lotion, snow white body cream, cleansing scrub, silky BHA lotion, sunshine body cream, skin moisturizing gel, liquid pearl bath soap, bath dusting powder, bath and shower gel, highlighting hair gel, conditioner, low pH shampoo, sparkle hair spray, festival hair gel, iridescent hair conditioner, conditioning shampoo, pearly foundation cream, blush stick, face bronze pressed powder, silky finish loose face powder, liquid makeup, body veil, earthtone makeup powder, liquid foundation, creamy peral blush, sheer leg makeup, face bronzer with sunscreen, silky face powder, shimmering pearl pressed powder blush, all purpose color stick, dual face powder, radiance pressed powder blush, gel blush frost, sparkling ruby nail enamel, poured eye shadow, cream eye shadow, emulsion cream mascera, eye shadow, liquid eyeliner, pressed powder eye shadow, emulsion cream eye shadow, charcoal silky powder eyeliner, loose powder eye shadow, concealer, sheer satin pressed powder eye shadows, crayon eye shadow, velvety pressed powder eye shadow, waterproof masara, slender stick eye shadow, silky pressed powder eye shadow, lipstick, fair taupe lipstick, lip gloss with sunscreen, glossy lipstick, shimmering brick lipstick, lip pomade, soft lipstick, pressed lip powder, long wear lipstick, lipstick with sunscreen, lip glaze-formulations are given which can be mixed with the glasses or color glass or glass ceramics or ceramics or glass powders or color glass powders or glass ceramic powders or ceramic powders or composite materials comprising glass or glass ceramics or ceramic powders or mixtures of glass, ceramic and glass ceramic powders are given.
In a preferred embodiment 99,9 weigth-%- 70 weight-% of a basic cosmetic formulation as given for example in the appendix is mixed with about 0,01 - 30 weight-% bioactive glasses, color glass, glass-powders, color glass powders, glassceramic-powders or composit materials comprising glass and nanoparticles.
I. Thoroughly blend and disperse Phase A in appropriate dry blending/dispersing equipment.
II. Spray premixed Phase B into premixed Phase A and continue blending.
II. Add Phase B ingredients into a support vessel. Heat and mix until uniform.
III. Spray Phase B into premixed Phase A and continue blending.
IV. Pulverize and return to blender.
V. Add Phase C to Phase A-B and mix until uniform.
III. Add in Phase C and mix with constant stirring.
IV. Pour at 75° ± 5°C.
V. Mold, cool and flame the lipsticks.
Note: If iron oxide or organic pigments are used, they should first be dispersed in Castor oil; this mixture should then be milled in either a colloid or roller mill.
I. Weigh all the ingredients in Phase A into a heated vessel and raise temperature to 85° ± 3°C, stirring until melted and uniform.
II. Add in Phase B and mix until all the pearl pigment is well dispersed.
2. Whittaker, dark & Daniels, Inc.
4. Hispano Quimica S.A./Centerchem, Inc.
II. Spray Phase B into premixed Phase A and continue blending.
I. Thoroughly blend and disperse Phase A in appropriate dry Mending/dispersing equipment.
5. Frank B. Ross Co., Inc.
I. Heat combined Phase A to 83° ± 3°C with stirring until a clear solution is obtained.
II. Add Phase B to Phase A and stir until uniform.
III. Cool to 62° ± 3°C and add Phase C.
IV. Continue mixing and fill at 50° ± 5°C.
I. Combine Phase A ingredients in a vessel fitted with a propeller type mixer and stir until uniform.
II. Combine Phase B ingredients (thinners) in a secondary vessel and mix well until uniform.
III. Add Phase B to Phase A while stirring until uniform.
Note: The quantity of Phase B may be varied to compensate for evaporation or viscosity adjustment.
I. Add Phase A ingredients to a heated vessel and stir bringing temperature to 80° ± 3°C.
II. Pulverize Phase B ingredients and add to Phase A with thorough agitation.
III. Pour into holding kettles or appropriate compacts.
1. R. T. Vanderbilt Company, inc.
I. Disperse Veegum into water using high-shear mixing until smooth.
II. Blend Phase B and add to Phase A, mixing until thoroughly dispersed.
III. Add Phase C slurry to Phase A-B and mix until smooth.
IV. Add Phase D to Phase A-B-C with gentle agitation and heat to 75° ± 5°C.
V. In a support vessel heat Phase E ingredients to 75° ± 5°C with gentle agitation.
VI. Add Phase E to Phase A-B-C-D with gentle agitation, maintaining temperature at 75° ± 5°C.
VII. Maintain constant agitation and cool batch to 35° ± 5°C; store or fill into appropriate containers.
4. Frank B. Ross Co., Inc.
I. Add Phase A ingredients to the main vessel.
II. Add Phase B to Phase A with agitation, and raise the temperature to 75° ± 3°C.
III. Add Phase C to the support vessel and mix while raising temperature to 80° ± 3°C.
IV. When the water and oil phases are both at 75° ± 3°C, add Phase C to Phase A-B and maintain sweep agitation.
V. With constant agitation cool batch to 50°C and add premixed Phase D solution to Phase A-B-C.
VI. Continue stirring and cooling to 40°C; batch may be filled below this temperature.
5. Bernel Chemical Company, inc.
IV. Pulverize and mix until uniform.
1. R.T. Vanderbilt Company, Inc.
II. Add Phase B to Phase A, mixing until thoroughly dispersed.
III. Add Phase C to Phase A-B and mix until smooth.
IV. Blend Phase D and add to Phase A-B-C with gentle agitation and heat to 75° ± 5°C.
2. Whittaker, Clark & Daniels, Inc.
III. Pulverize and return to blender.
IV. Add Phase C to Phase A-B and mix until uniform.
I. Add Phase B ingredients to a heated vessel and stir, bringing temperature to 75°±3°C.
II. Add Phase A ingredient to the primary vessel and heat to 75° ± 3°C, mixing until uniform.
III. Add Phase B to Phase A with constant sweep agitation.
IV. Cool gradually to 35° ± 5°C and fill.
1, R. T. Vanderbilt Company, Inc.
II. Add Phase B slurry to Phase A and mix until smooth.
III. Pulverize Phase C and add to Phase A-B using high-shear mixing until smooth.
IV. Add Phase D to Phase A-B-C while heating to 75° ± 5°C and mix until smooth.
1. Strahl & Pitsch, Inc.
III. Pour at 75° ± 5°C.
III. Spray Phase B into premixed Phase A and mix until uniform.
I. Add Phase A ingredients to a vessel equipped with a high-shear agitator; heat to 95° ± 2°C with gentle agitation until a clear solution is obtained.
II. Add Phase B to Phase A and mix until uniform. Note: Care should be taken to avoid loss of volatile solvents.
III. Add Phase C to Phase A-B and mix vigorously until smooth.
IV. Add Phase D to Phase A-B-C with slow agitation; a heavy gel will form.
V. Cool batch to 60°C and fill or pump into storage drums.
I. Weigh all the ingredients in Phase A into a vessel and heat to 85° ± 3°C, stirring until melted and uniform.
III. Pour at 75° ± 3°C.
V, Mold, cool and flame the lipsticks.
8. Dr. Madis Laboratories, Inc.
I. Weigh all the ingredients in Phase A into a heated vessel and raise temperature to 85°± 3°C, stirring until melted and uniform.
Ill, Add in Phase C and mix with constant stirring.
lV. Pour at 75° ± 5°C.
I. Weigh all the ingredients in Phase A into a heated vessel and raise temperature to 75° ± 5°C, stirring until melted and uniform.
II. Add Phase B ingredients to Phase A maintaining temperature at 75° ± 5°C.
III. Add Phase C and mix with constant stirring.
V. Moid, cool and flame the lipsticks.
2. Elf Atochem North America, Inc.
I. Blend ingredients in Phase A, pulverize and return to blender.
II. Add ingredients in Phase B to Phase A and blend until uniform.
III. Melt, add and disperse premixed Phase C to premixed Phase A-B.
IV. Pulverize entire batch without screen and store.
I. Weigh all the ingredients in Phase A into heated vessel. Heat 85° ± 5°C and stir until melted and uniform.
II. Stir in Phase B and mix slowly until all the pear! pigment is well dispersed and no air bubbles form on the surface.
II. Stir in Phase B and mix slowly until all the pearl pigment is well dispersed and no air bubbles form on the surface.
lV. Mold, cool and flame the lipsticks.
I. Add Phase A ingredients to a heated vessel equipped with a homogenizer.
II. Raise temperature to 75° ± 5°C and homogenize Phase A for 30 minutes until smooth.
III. Add Phase B ingredients to Phase A, maintaining temperature at 75° ± 5°C and agitating with a marine type mixer.
IV. When the Ozokerite Wax has melted and product is uniform, add Phase C ingredients and mix an additional 15 minutes.
V. Add Phase D and mix with constant stirring.
VI. Cool to 40° ± 5°C and fill into containers.
Note: If iron oxide or organic pigments are used, they should first be dispersed in mineral oil; this mixture should then be milled in either a colloid or roller mill.
7. Frank B. Ross Co., Inc.
I. Add water to a vessel equipped with a high-shear agitator. Heat to 75° ± 3°C and add Carbomer, mixing until dispersed.
II. Add Phase B to Phase A and continue mixing, maintaining temperature at 75°±3°C.
III. Add Phase C to support vessel and heat to 75° ± 3°C using moderate agitation.
IV. Add Phase C to Phase A-B maintaining temperature and using constant agitation.
V. Cool to 55° ± 5°C and add Phase D ingredients.
VI. Continue mixing and cool to 25°C. Pass through a colloid mill and store.
I. Add Phase A ingredient to a vessel equipped with a side sweep agitator.
II. Mix in Phase B with gentle agitation until smooth. Heat to 75°C.
III. Premix Phase C ingredients and heat to 75°C. Add Phase C to Phase A-B.
IV. Disperse pigment (Phase D) into hot base. Mix until completely uniform.
V. Cool and pour into appropriate packaging.
Note: Care should be taken to avoid loss of volatile solvents.
Preservatives (oil soluble) & Antioxidant q.s.
I. Heat Phase A to 85° ± 3°C with stirring until all ingredients are melted.
II. In a separate vessel heat Phase B to 85°± 3°C with stirring until fully dispersed.
III. Add Phase C to Phase B with stirring until fully dispersed and uniform.
IV. Add Phase A to combined Phase B-C with stirring and remove from heat.
V. Add Phase D with stirring at 43° ± 3°C.
VI. Drop batch below 30°C and fill at room temperature.
2. Frank B. Ross Co., Inc.
I. Disperse gums into water using high-shear mixing until smooth.
II. Add Phase B to Phase A and mix until smooth.
IV. In a support vessel heat Phase D ingredients to 75° ± 5°C with gentle agitation.
V. Add Phase D to Phase A-B-C- with gentle agitation, maintaining temperature at 75° ± 5°C.
VI. Maintain constant agitation and cool batch to 35° ± 5°C; store or fill into appropriate containers.
II. Blend Phase B ingredients until uniform.
I. Using moderate propeller agitation sprinkle the carbomer into the water and allow to mix until fully hydrated, then add the alcohol.
II. Add premixed Phase B to Phase A.
III. In a separate vessel weigh out the Hispagel 200. Add Phase A-B ingredients to the Hispagel 200 with gentle mixing. Add the rest of Phase C ingredients.
IV. Add premixed Phase D to Phase A-B-C.
V. Add Phase E to Phase A-B-C-D.
3. Hispano Quimica S.A./Centerchem, Inc.
I. Heat Phase A to 85° ± 3°C while mixing until completely uniform.
II. Heat Phase B to 85° ± 3°C while mixing.
III. Pulverize Phase C and add to Phase B using high-shear mixing until smooth.
IV. Add Phase A to Phase B-C maintaining constant agitation and cool batch to 35° ± 5°C.
V. Add premixed Phase D to Phase A-B-C with gentle agitation while mixing until completely uniform.
VI. Store or fill into appropriate containers.
I. Thorough blend and disperse Phase A in appropriate dry blending/dispersing equipment.
3. Whittaker, Clark & Daniels, Inc.
I. Weigh all the ingredients in Phase A into a heated vessel. Heat and stir until melted and uniform.
ll. Add Phase B maintaining temperature at 75° ± 3°C and mix until ail the pigment is well dispersed.
lll. Add Phase C and mix with constant stirring.
II. Mix Phase B into Phase A. Then cool to 40° ± 3°C. Add Phase C and mix until the pigment is well dispersed.
III. Continue mixing and fill.
Citric Acid (20% solution) q.s.
I. Disperse preservatives, Copolymer and Xanthan gum into de-ionized water with high-shear agitation.
II. Add Phase B ingredients in listed order to Phase A and mix until uniform.
III. Add premixed Phase C to Phase A-B with gentle agitation.
IV. Adjust pH with Citric Acid.
7. Technology, Flavors & Fragrances, Inc.
I. Using moderate propeller agitation, add ingredients of the Phase A in the order listed, at room temperature.
II. Add the premixed Phase B with mixing.
III. Add Phase C and mix until uniform.
2. Rohm and Haas Company, Inc.
I. Combine Phase A ingredients and mix until thoroughly dispersed.
II. Add premixed Phase B to Phase A while mixing until completely uniform.
III. Add Phase C to Phase A-B while under agitation.
IV. Heat premixed Phase D until PVP is dissolved and add to Phase A-B-C.
V. Add premixed Phase E to Phase A-B-C-D.
I. Disperse Stabileze in water at room temperature with mixing. Start heating to 70°C and mix until uniform.
II. Add PVP at 60°C and mix while cooling.
III. Add the rest of the ingredients of Phase A at 45°C with mixing.
IV. At 35°C add the premixed Phase B and Phase C ingredients. Mix until uniform.
I. Using moderate propeller agitation, add Celquat from Phase A with mixing at room temperature. Heat to 50°C and add Structure Plus with mixing.
II. Add Phase B ingredients in the order listed at 50°C with mixing. Avoid aeration.
III. Cool down to 40°C and add Phase C ingredients one by one. Stop mixing at 35°C.
5. Rohm and Haas Company, Inc.
I. Disperse ingredients of Phase A in water, heat to 70°C and mix until uniform.
II. Cool to 35°C and add ingredients of Phase B one by one. Mix until uniform.
I. Mix all the ingredients in Phase A in a suitable vessel until completely uniform.
III. In a separate vessel, combine all ingredients in Phase C.
V. Add premixed Phase D to Phase A-B-C and mix until uniform.
I. Disperse Carbopol ETD-2020 in water in a suitable vessel with constant agitation. Mix until uniform and add the rest of the ingredients.
II. Heat to 65°C and add one by one Phase B ingredients with continuing mixing.
III. Cool down to 40°C and add Phase C and Phase D.
5. Technology, Flavors & Fragrances, Inc.
I. Premix a dry master batch of perfume oil and Magnesium Carbonate.
II. Mix with the rest of ingredients until uniform.
Preservatives, Fragrance and Color q.s.
I. Disperse Xanthan Gum in water.
II. Add TEA-Lauryl Sulfate with stirring.
III. Continue stirring and add Flamenco Superpearl 120C.
IV. When well dispersed, add other ingredients and continue to stir until uniform.
I. Using moderate propeller agitation, dissolve preservatives in water. Then sprinkle the Carbomer into the water and allow to mix until fully hydrated.
II. Add Phase B to Phase A.
III. In a separate vessel weigh out the Hispagel 200. Add Phase A-B ingredients to the Hispagel 200 with gentle mixing. Add the rest of Phase C ingredients to Phase A-B.
4. Technology, Flavors & Fragrances, Inc.
I. Add ingredients of Phase A in the order listed and heat to 75°C with mixing.
II. Heat Phase B at 75°C and add it to Phase A with mixing.
III. Premix the ingredients of Phase C and add them to Phase A-B at 45°C.
IV. Premix ingredients of Phase D and add them to the batch at 40°C. Stop mixing at 35°C.
7. Dr. Madis Laboratories, Inc.
I. Mix ingredients of Phase A at room temperature. Heat to 60°C and add Phase B. Mix until uniform.
II. Cool to 45°C and add Phase C ingredients one by one with mixing.
III. Add the premixed Phase D ingredients.
IV. Add Phase E and mix until uniform.
5. Dr. Madis Laboratories, Inc.
I. Disperse Carbopol in water with high-shear agitation. Mix until uniform.
II. Add ingredients of Phase B one by one and mix until uniform.
lV. Premix ingredients of Phase D and add them to the batch at 40°C. Stop mixing at 35°C.
I. Using moderate propeller agitation, disperse Natrosol 250HR in water and heat to 70°C. Add the rest of the ingredients with mixing.
II. Heat Phase B ingredients to 70°C and add them to Phase A.
III. Cool to 40°C and add Phase C. Mix until uniform.
IV. At 35°C add Phase D ingredients one by one. Mix until uniform.
8. Hispano Quimica S.A./Centerchem, Inc.
I. Using moderate propeller agitation, add ingredients of Phase A in the order listed, at room temperature.
II. Add Triethanolamine and mix until the gel is formed.
III. Premix the ingredients of Phase C and add them to the kettle. Add Phase D with gentle agitation.
4. Dr. Madis Laboratories, Inc.
I. Using moderate propeller agitation, add ingredients of Phase A in the order listed at room temperature and mix until uniform. Heat to 75°C with mixing.
II. Add Phase B at 75°C and homogenize for 15 minutes.
III. Premix the ingredients of Phase C and heat to 75°C with mixing.
IV. Add Phase C to A and B and mix until uniform using propeller agitation.
V. Cool down to 45°C and add Phase D and E. Stop mixing at 35°C.
6. Frank B. Ross Co., Inc.
I. Premix water, Sorbitol and Glycerin, and disperse Cellulose Gum with mixing until thoroughly dispersed.
II. Add PEG-32 and heat to 50°C.
III. At 40°C add premixed Phase B to Phase A while mixing until completely uniform.
IV. Add Phase C to Phase A-B while under agitation.
V. Add Phase D ingredients one by one to Phase A-B-C mixing until completely uniform.
I. Separately heat Phase A and B to 80° ± 3°C.
II. Stir Phase A into Phase B until homogeneous. Then cool to 40°C with slow stirring.
III. Disperse pigment (Phase C) into Phase A-B.
IV. Cool to 30°C and fill.
5 Frank B. Ross Co., Inc.
I. Separately heat Phase A and Phase C to 80° ± 3°c while mixing until completely uniform.
II. Stir Phase A into Phase B until homogeneous.
As determined by an independent laboratory based on a 5 subject screening panel.
III. Add premixed Phase C To Phase A-B and then cool to 40°C with slow stirring.
IV. Add Phase D with stirring.
V. Cool to 30°C and fill.
I. Using moderate propeller agitation, add Phospholipid SV in water and heat to 70°C. Add the rest of the ingredients with mixing.
ll. Heat Phase B ingredients to 70°C and add them to Phase A.
lll. Cool to 40°C and add Phase C. Mix until uniform.
IV. Add the premixed Phase D with mixing. Stop mixing at 35°C.
I. Separately heat Phase A and Phase B to 80° ± 3°C while mixing until completely uniform.
III. Add Phase C to Phase A-B. Then cool to 40°C with slow stirring.
IV. Disperse pigment (Phase D) into warm base.
I. Disperse Carbopol in water at room temperature and mix until uniform.
II. Add AMP with mixing.
III. Add premixed Phase B-C to Phase A and continue to mix.
I. Add Phase A to Phase B.
II. Add combined Phases A and B to Phase C slowly with good, but not excessive agitation. (High speed agitation may cause fragmentation of the pearl essence crystals, with consequent decrease of luster.) Color may be introduced at any point as desired. Moisturizers, emollients and skin conditioners which do not reduce transparency may be added for special effects.
0,01 - 30 weight-% glasses or color glass or glass ceramics or ceramics or glass powders or color glass powders or glass ceramic powders or ceramic powders or composite materials comprising glass or glass ceramics or ceramic powders or mixtures of glass, ceramic and glass ceramic powders.
Cosmetic composition according to claim 1, wherein the particle size of the glass powder or the glass ceramic powder is < 100 µm, preferably < 50 µm, most preferable < 10 µm at most preferably < 1 µm.
FR2918561B1 (en) * 2007-07-09 2009-10-09 Oreal Use for coloring skin of dehydroascorbic acid or derivative polymers; care processes and / or makeup.
FR2920971B1 (en) * 2007-09-14 2014-03-28 Oreal cosmetic composition comprising at least one specific cationic polymer, at least one surfactant, at least one cationic or amphoteric polymer and at least one mineral particle, and cosmetic treatment process.
IT201700038032A1 (en) * 2017-04-06 2018-10-06 Ripar Cosmetici S R L cosmeceutical composition for use in non-invasive treatment of skin blemishes.
ES2239657T3 (en) 2005-10-01 cosmetic composition comprising a transfer-volatile silicone compound not a nonvolatile hydrocarbon oil and an inert particulate phase.

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