Patent Abstract:
Disclosed is a thin film transistor including a gate electrode on a substrate. A gate dielectric layer is disposed on the gate electrode and the substrate, and source/drain electrodes are disposed on the gate dielectric layer overlying two edge parts of the gate electrode. A channel layer is disposed on the gate dielectric layer overlying a center part of the gate electrode, and the channel region contacts the source/drain electrodes. An insulating capping layer overlies the channel layer, wherein the channel layer includes an oxide semiconductor.

Full Description:
CROSS REFERENCE TO RELATED APPLICATIONS 
     This application is a Divisional of U.S. patent application Ser. No. 13/288,579, filed on Nov. 3, 2011 and entitled “Thin film transistors and methods for manufacturing the same”, which claims priority of Taiwan Patent Application No. 99139500, filed on Nov. 17, 2010, the entirety of which is incorporated by reference herein. 
    
    
     BACKGROUND OF THE INVENTION 
     1. Field of the Invention 
     The present invention relates to thin film transistors, and in particular relates to methods and structures of utilizing an oxide semiconductor as channel layers of the thin film transistors. 
     2. Description of the Related Art 
     In the process of forming thin film transistors (TFT), oxide semiconductors have become a main trend for related industries in Japan and Korea. The oxide semiconductors can be zinc oxide (ZnO), gallium-doped zinc oxide (GZO), aluminum zinc oxide (AZO), zinc tin oxide (ZTO), indium zinc oxide (IZO), and indium gallium zinc oxide (IGZO), and the likes. The oxide semiconductor process may adopt a five photomask process such as a back channel etching (BCE) process or a coplanar process for an inverted gate electrode, or adopt a six photomask process such as a process utilizing an etching stop layer. The etching stop layer in the process adopting six photomasks can protect a channel layer, such that devices made thereby have performances which are better than that of the process adopting five photomasks. However, the process utilizing the etching stop layer needs an additional photomask. In the coplanar process for inverted gate electrodes adopting five photomasks, each photomask can individually define each layer of the TFT without being limited by etching selectivity. As such, panel manufacturers only need to slightly change the processes, and benefiting mass production. In the future, large area panels will combine copper metal processes with the oxide semiconductor technology. Before forming a passivation layer covering a copper metal layer, the oxide on the metal surface should be reduced to copper by plasma of reducing atmosphere (e.g. H 2  plasma). The oxide semiconductor is sensitive to the plasma of reducing atmosphere, and the reducing plasma may break a device made thereby. 
     Accordingly, a novel process without additional photomasks is called for, which efficiently protects the channel layer from damage of following processes, such as the reducing plasma process. 
     BRIEF SUMMARY OF THE INVENTION 
     One embodiment of the invention provides a method for manufacturing a thin film transistor, comprising: forming a gate electrode on a substrate; forming a gate dielectric layer on the gate electrode and the substrate; forming source/drain electrodes on the gate dielectric layer overlying two edge parts of the gate electrode; forming an oxide semiconductor layer on the source/drain electrodes and the gate dielectric layer; forming an insulating layer on the oxide semiconductor layer; and patterning the insulating layer and the oxide semiconductor layer to form an insulating capping layer covering a channel layer. 
     Another embodiment of the invention provides a thin film transistor, comprising: a gate electrode on a substrate; a gate dielectric layer on the gate electrode and the substrate; a source/drain electrode on the gate dielectric layer overlying two edge parts of the gate electrode; a channel layer on the dielectric layer overlying a center part of the gate electrode; and an insulating capping layer covering the channel layer, wherein the channel layer comprises an oxide semiconductor. 
     A detailed description is given in the following embodiments with reference to the accompanying drawings. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
       The present invention can be more fully understood by reading the subsequent detailed description and examples with references made to the accompanying drawings, wherein: 
         FIGS. 1A-1B ,  2 A- 2 B,  3 A- 3 C,  4 A- 4 D,  5 A, and  6 A are cross sectional diagrams depicting a process of forming a thin film transistor in some embodiments of the invention; and 
         FIGS. 1C ,  2 C,  3 D,  5 B, and  6 B are top views showing a process of forming a thin film transistor in some embodiment of the invention. 
     
    
    
     DETAILED DESCRIPTION OF THE INVENTION 
     The following description is of the best-contemplated mode of carrying out the invention. This description is made for the purpose of illustrating the general principles of the invention and should not be taken in a limiting sense. The scope of the invention is best determined by reference to the appended claims. 
     The making and using of the TFTs in the embodiments of the disclosure are discussed in detail below. It should be appreciated, however, that the embodiments provide many applicable inventive concepts that can be embodied in a wide variety of specific contexts. The specific embodiments discussed are merely illustrative, and do not limit the scope of the disclosure. 
     As shown in  FIG. 1A , a patterned metal layer  12  is formed on a substrate  10 . The substrate  10  comprises rigid inorganic material such as transparent material (e.g. glass, quartz, and the likes) or opaque material (e.g. wafer, ceramic, and the likes), or flexible organic material (e.g. plastic, rubber, polyester, polycarbonate, and the likes). In some embodiments, the substrate  10  adopts the transparent material, and the final TFT products can be utilized in transmissive, transflective, or reflective LCDs. In other embodiments, the substrate  10  adopts the opaque material, and the final TFT products can be only utilized in reflective LCDs or self illumination displays. 
     The patterned metal layer  12  can be metal, alloys, or multi-layered structures thereof. In some embodiment, the patterned metal layer  12  can be single-layered or multi-layered structures of molybdenum, aluminum, copper, titanium, or alloys thereof. The method of forming the patterned metal layer  12  includes forming a metal layer on the substrate  10 , and then forming the patterned metal layer  12  by photolithography with etching. The step of forming the metal layer includes physical vapor deposition (PVD), sputtering, or the likes. The photolithography process may include processing the steps of photoresist coating, soft baking, mask aligning, exposing, post-exposure baking, developing, hard baking, other suitable steps, or combinations thereof. In addition, the exposing step of the photolithography can be replaced with other step such as maskless lithography, electron beam writing, or ion beam writing. The etching process can be dry etching, wet etching, or combinations thereof. Although the patterned metal layer  12  only serves as a gate electrode in a TFT and a gate line connecting the gate electrode in  FIG. 1C , the patterned metal layer  12  may also serve as a contact pad, a bottom electrode of a storage capacitor, or other elements if necessary. 
     As shown in  FIG. 1B , a dielectric layer  14  is then formed on the patterned metal layer  12 . The dielectric layer  14  can be composed of organic material such as silicon-oxygen compound, or inorganic material such as silicon nitride, silicon oxide, silicon oxynitride, silicon carbide, aluminum oxide, hafnium oxide, or multi-layered structures thereof. The dielectric layer  14  can be formed by chemical vapor deposition (CVD) such as plasma enhanced CVD (PECVD), low-pressure CVD (LPCVD), sub-atmospheric CVD (SACVD), physical vapor deposition (PVD), or the likes. Although the dielectric layer  14  only serves as a gate dielectric layer in the TFT in  FIG. 1C , the dielectric layer  14  may also serve as a capacitor dielectric layer in the storage capacitor or other elements if necessary. It should be understood that a cross section of the line A-A′ in  FIG. 1C  is shown in  FIG. 1B . 
     As shown in  FIG. 2A , another metal layer  16  is formed on the dielectric layer  14 . The metal layer  16  can be metal, alloy, or multi-layered structures thereof. In some embodiment, the metal layer  16  includes copper or copper alloy. Alternatively, the metal layer  16  is free of copper, such as a multi-layered structure of molybdenum/aluminum/molybdenum, a single-layered or a multi-layered structure of molybdenum, aluminum, titanium, or alloys thereof. The metal layer  16  can be formed by plating, electroless plating, PVD, sputtering, or the likes. 
     As shown in  FIG. 2B , a patterned photoresist layer  18  is formed on the metal layer  16  by a photolithography process. The photolithography process is described above and omitted here. The metal layer  16  is then etched with the patterned photoresist layer  18  serving as a mask, thereby forming a source electrode  16 A and a drain electrode  16 B. The etching process can be dry etching, wet etching, or combinations thereof. Afterward, the patterned photoresist layer  18  is removed by a wet striper or a dry ashing process. Although the patterned metal layer  16  only serves as the source electrode  16 A, the drain electrode  16 B, and a source line in  FIG. 2C , the patterned metal layer  16  may also serve as other lines or other elements if necessary. It should be understood that a cross section of the line A-A′ in  FIG. 2C  is shown in  FIG. 2B  after the patterned photoresist layer  18  has been removed. 
     As shown in  FIG. 3A , the patterned photoresist layer  18  in  FIG. 2B  is removed, an oxide semiconductor layer  32  is then formed on the structure in  FIG. 2B  without the patterned photoresist layer  18 , and an insulating layer  34  is then formed on the oxide semiconductor layer  32 . In one embodiment, the oxide semiconductor layer  32  can be zinc oxide, indium oxide, indium gallium zinc oxide, or tin oxide. In other embodiments, the semiconductor layer  32  is a combination of at least two compounds selected from zinc oxide, indium oxide, indium gallium zinc oxide, tin oxide, gallium oxide, aluminum oxide, and titanium oxide. The oxide semiconductor layer  32  can be formed by a CVD process such as a PECVD, LPCVD, or SACVD process, or a PVD process, solution synthesis, or the likes. In one embodiment, the insulating layer  34  can be an organic material, such as acrylic series material, which is formed by spin-on coating, slit coating, dipping, or the likes. In another embodiment, the insulating layer  34  can be an inorganic material, such as silicon oxide, silicon nitride, silicon oxynitride, aluminum oxide, titanium oxide, hafnium oxide, or aluminum nitride, which is formed by a sputtering, or CVD process such as a PECVD, LPCVD, or SACVD process, or the likes. In other embodiments, the insulating layer  34  is composed of a passivated metal layer such as aluminum oxide, titanium oxide, titanium nitride, or other oxidized or nitrided metal layer. The method of forming the passivated metal layer first forms a metal layer on the oxide semiconductor layer  32 , and then passivates the metal layer by oxygen or nitrogen. Note that not all of the passivated metal layers can serve as the insulating layer  34 . For example, both the aluminum oxide and aluminum nitride are insulating materials, such that aluminum can be passivated by oxidizing or nitriding. Otherwise, titanium oxide is an insulating material but titanium nitride is still a conductive material, such that the titanium is passivated by oxidizing not nitriding. The above processes should be performed at an isobaric condition such as in a vacuum. In one embodiment, the steps of forming the oxide semiconductor layer  32  and the insulating layer  34  are performed in a same reaction chamber. In other embodiments, the steps of forming the oxide semiconductor layer  32  and the insulating layer  34  are performed in different reaction chambers of an isobaric system. 
     As shown in  FIG. 3B , a patterned photoresist layer  36  is formed on the insulating layer  34  by a photolithography process. The photolithography process is described above and omitted here. Subsequently, the insulating layer  34  and the oxide semiconductor layer  32  not covered by the patterned photoresist layer  36  are removed by a single step etching process, thereby forming an insulating capping layer  37  covering the channel layer  38 . The single step etching process can be a dry etching process utilizing a mixture gas of alkane, hydrogen, argon, halogen acid, and the likes, or a wet etching process utilizing hydrofluoric acid. Thereafter, the patterned photoresist layer  36  is removed to obtain the structure as shown in  FIG. 3C . 
     The processes in  FIGS. 4A-4D  are similar to the processes in  FIGS. 3A-3C , and the only difference therebetween is the insulating capping layer  37  and the channel layer  38  being formed by a multi-step etching process in  FIGS. 4A-4D  rather than the single step etching in  FIGS. 3A-3C . For example, the insulating layer  34  not covered by the patterned photoresist layer  36  is firstly removed to form the insulating capping layer  37  as shown in  FIG. 4C . The removal is performed by a first step etching process. Thereafter, the oxide semiconductor layer  32  not covered by the patterned photoresist layer  36  is removed to form the channel layer  38 . The removal is performed by a second step etching process. The patterned photoresist layer  36  is then removed as shown in  FIG. 4D . Corresponding to the selectivities of the oxide semiconductor layer  32  and the insulating layer  34 , the first step etching and the second step etching may adopt different dry or wet etching conditions. For example, the insulating layer  34  is firstly etched by a general dry etching gas for an oxide, and the oxide semiconductor layer  32  is then etched by a wet etching process of oxalic acid or aluminic acid. For the single step etching process or the multi-step etching process, the channel layer  38  should be covered by the insulating capping layer  37 . It should be understood that a cross section of the line A-A′ in  FIG. 3D  is shown in  FIG. 3C  or  4 D. 
       FIGS. 3C and 4D  show that a bottom surface of the insulating capping layer  37  and a top surface of the channel layer  38  have a substantially similar width. In other embodiments, the bottom surface of the insulating capping layer  37  can be slightly larger or smaller than the top surface of the channel layer  38 , and the width difference therebetween is from 0 μm to 2 μm. Preferably, the bottom surface insulating capping layer  37  and the top surface of the channel layer  38  have identical widths. If the width difference therebetween is over 2 μm, it will be disadvantageous for following processes. 
     Subsequently, the passivation layer  52  is formed on the structure in  FIG. 3C  (or  FIG. 4D ). The passivation layer  52  can be silicon nitride, silicon oxide, silicon oxynitride, silicon carbide, aluminum oxide, titanium oxide, hafnium oxide, or multi-layered structures thereof. The passivation layer  52  can be formed by CVD, PECVD, or PVD process. In one embodiment, the structure surface in  FIG. 3C  (or  FIG. 4D ) is treated by reducing plasma (e.g. H 2  plasma) before forming the passivation layer  52 , thereby enhancing the adhesion of the passivation layer  52 . When the source/drain electrodes  16 A/ 16 B includes copper, the processes for defining the channel layer  38  such as a photolithography and an etching process may oxidize the source/drain electrodes  16 A/ 16 B surface. Accordingly, the copper oxide of the source/drain electrodes  16 A/ 16 B surface should be further reduced to copper by the reducing plasma or a reducing process (e.g. H 2 ). If the channel layer  38  is not covered by the insulating capping layer  37 , the oxide semiconductor of the channel layer  38  will be reduced to a conductive material and the device function will be broken by the described reducing plasma and/or the reducing process. 
     Next, a patterned photoresist layer (not shown) is formed on the passivation layer  52  by a photolithography process. The passivation layer  52  is then etched with the patterned photoresist layer serving as a mask, thereby forming a via hole  54  as shown in  FIG. 5A . It should be understood that a cross section of the line A-A′ in  FIG. 5B  is shown in  FIG. 5A . 
     As shown in  FIG. 6A , a conductive pattern  62  is formed on the structure in  FIG. 5A . The conductive pattern  62  is formed on the passivation layer  52  to be a pixel electrode. Furthermore, the conductive pattern  62  electrically connects the drain electrode  16 B through the via hole  54 . The conductive pattern  62  can be formed by forming a conductive layer, and then patterning the conductive layer by a photolithography and an etching process to complete the TFT. If the TFT is applied in a transmissive LCD, the conductive pattern  62  includes indium tin oxide (ITO), indium zinc oxide (IZO), aluminum zinc oxide (AZO), cadmium tin oxide (CTO), tin oxide (SnO 2 ), zinc oxide (ZnO), or other transparent conductive materials. If the TFT is applied in a reflective LCD, the conductive pattern  62  includes aluminum, gold, tin, silver, copper, iron, lead, chromium, tungsten, molybdenum, neodymium, nitrides thereof, oxides thereof, oxynitrides thereof, alloys thereof, or combinations thereof. In addition, the reflective conductive pattern  62  has a rough surface to enhance the reflective and scattering effects of light. If the TFT is applied in a transflective LCD, the transparent material and the reflective material are adopted in transmissive regions and reflective regions thereof, respectively. 
     While the invention has been described by way of example and in terms of the preferred embodiments, it is to be understood that the invention is not limited to the disclosed embodiments. To the contrary, it is intended to cover various modifications and similar arrangements (as would be apparent to those skilled in the art). Therefore, the scope of the appended claims should be accorded the broadest interpretation so as to encompass all such modifications and similar arrangements.

Technology Classification (CPC): 7