Patent Abstract:
The disclosure relates to a method and apparatus for preventing oxidation or contamination during a circuit printing operation. The circuit printing operation can be directed to OLED-type printing. In an exemplary embodiment, the printing process is conducted at a load-locked printer housing having one or more of chambers. Each chamber is partitioned from the other chambers by physical gates or fluidic curtains. A controller coordinates transportation of a substrate through the system and purges the system by timely opening appropriate gates. The controller may also control the printing operation by energizing the print-head at a time when the substrate is positioned substantially thereunder.

Full Description:
The application claims the filing-date priority of Provisional Application No. 61/142,575, filed Jan. 5, 2009, the disclosure of which is incorporated herein in its entirety; the application also claims priority to U.S. patent application Ser. No. 12/139,391, filed Jun. 13, 2008, the disclosure of which is incorporated herein in its entirety; this application also claims priority to U.S. patent application Ser. No. 12/652,040, filed Jan. 5, 2010, the disclosure of which is incorporated herein in its entirety. 
    
    
     BACKGROUND 
     1. Field of the Invention 
     The disclosure relates to a method and apparatus for efficient deposition of a patterned film on a substrate. More specifically, the disclosure relates to a method and apparatus for supporting and transporting a substrate on gas bearing during thermal jet printing of material on a substrate. 
     2. Description of Related Art 
     The manufacture of organic light emitting devices (OLEDs) requires depositing one or more organic films on a substrate and coupling the top and bottom of the film stack to electrodes. The film thickness is a prime consideration. The total layer stack thickness is about 100 nm and each layer is optimally deposited uniformly with an accuracy of better than .+−.1 nm. Film purity is also important. Conventional apparatuses form the film stack using one of two methods: (1) thermal evaporation of organic material in a relative vacuum environment and subsequent condensation of the organic vapor on the substrate; or, (2) dissolution of organic material into a solvent, coating the substrate with the resulting solution, and subsequent removal of the solvent. 
     Another consideration in depositing the organic thin films of an OLED is placing the films precisely at the desired location on the substrate. There are two conventional technologies for performing this task, depending on the method of film deposition. For thermal evaporation, shadow masking is used to form OLED films of a desired configuration. Shadow masking techniques require placing a well-defined mask over a region of the substrate followed by depositing the film over the entire substrate area. Once deposition is complete, the shadow mask is removed. The regions exposed through the mask define the pattern of material deposited on the substrate. This process is inefficient as the entire substrate must be coated, even though only the regions exposed through the shadow mask require a film. Furthermore, the shadow mask becomes increasingly coated with each use, and must eventually be discarded or cleaned. Finally, the use of shadow masks over large areas is made difficult by the need to use very thin masks (to achieve small feature sizes) that make said masks structurally unstable. However, the vapor deposition technique yields OLED films with high uniformity and purity and excellent thickness control. 
     For solvent deposition, ink jet printing can be used to deposit patterns of OLED films. Ink jet printing requires dissolving organic material into a solvent that yields a printable ink. Furthermore, ink jet printing is conventionally limited to the use of single layer OLED film stacks, which typically have lower performance as compared to multilayer stacks. The single-layer limitation arises because printing typically causes destructive dissolution of any underlying organic layers. Finally, unless the substrate is first prepared to define the regions into which the ink is to be deposited, a step that increases the cost and complexity of the process, ink jet printing is limited to circular deposited areas with poor thickness uniformity as compared to vapor deposited films. The material quality is also lower due to structural changes in the material that occur during the drying process and due to material impurities present in the ink. However, the ink jet printing technique is capable of providing patterns of OLED films over very large areas with good material efficiency. 
     No conventional technique combines the large area patterning capabilities of ink jet printing with the high uniformity, purity, and thickness control achieved with vapor deposition for organic thin films. Because ink jet processed single layer OLED devices continue to have inadequate quality for widespread commercialization, and thermal evaporation remains impractical for scaling to large areas, it is a major technological challenge for the OLED industry to develop a technique that can offer both high film quality and cost-effective large area scalability. 
     Manufacturing OLED displays may also require the patterned deposition of thin films of metals, inorganic semiconductors, and/or inorganic insulators. Conventionally, vapor deposition and/or sputtering have been used to deposit these layers. Patterning is accomplished using prior substrate preparation (e.g., patterned coating with an insulator), shadow masking as described above, and when a fresh substrate or protective layers are employed, conventional photolithography. Each of these approaches is inefficient as compared to the direct deposition of the desired pattern, either because it wastes material or requires additional processing steps. Thus, for these materials as well there is a need for a method and apparatus for depositing high-quality, cost effective, large area scalable films. 
     Certain applications of thermal jet printing require non-oxidizing environment to prevent oxidation of the deposited materials or associated inks. In a conventional method, a sealed nitrogen tent is used to prevent oxidation. Conventional systems use a floating system to support and move the substrate. A floatation system can be defined as a bearing system of alternative gas bearings and vacuum ports. The gas bearings provide the lubricity and non-contacting support for the substrate, while the vacuum supports the counter-force necessary to strictly control the height at which the relatively light-weight substrate floats. Since high-purity nitrogen gas can be a costly component of the printing system, it is important to minimize nitrogen loss to the ambient. 
     Accordingly, there is a need for load-locked printing system which supports a substrate on gas bearings while minimizing system leakage and nitrogen loss. 
     SUMMARY 
     The disclosure relates to a method and apparatus for preventing oxidation or contamination during a thermal jet printing operation. The thermal jet printing operation may include OLED printing and the printing material may include suitable ink composition. In an exemplary embodiment, the printing process is conducted at a load-locked printer housing having one or more chambers. Each chamber is partitioned from the other chambers by physical gates or fluidic curtains. A controller coordinates transportation of a substrate through the system and purges the system by timely opening appropriate gates. The substrate may be transported using gas bearings which are formed using a plurality of vacuum and gas input portals. The controller may also provide a non-oxidizing environment within the chamber using a gas similar to, or different from, the gas used for the gas bearings. The controller may also control the printing operation by energizing the print-head at a time when the substrate is positioned substantially thereunder. 
     In one embodiment, the disclosure relates to a method for printing a film of OLED material on a substrate by (i) receiving the substrate at an inlet chamber; (ii) flooding the inlet load-locked chamber with a noble gas and sealing the inlet chamber; (iii) directing at least a portion of the substrate to a print-head chamber and discharging a quantity of OLED material from a thermal jet discharge nozzle onto the portion of the substrate; (iv) directing the substrate to an outlet chamber; (v) partitioning the print-head chamber from the outlet chamber; and (vi) unloading the print-head from the outlet chamber. In one embodiment of the invention, the print-head chamber pulsatingly delivers a quantity of material from a thermal jet discharge nozzle to the substrate. 
     In another embodiment, the disclosure relates to a method for depositing a material on a substrate. The method includes the steps of: (i) receiving the substrate at an inlet chamber; (ii) flooding the inlet chamber with a chamber gas and sealing the inlet chamber; (iii) directing at least a portion of the substrate to a print-head chamber and discharging a quantity of material from a thermal jet discharge nozzle onto the portion of the substrate; (iv) directing the substrate to an outlet chamber; (v) partitioning the print-head chamber from the outlet chamber; and (vi) unloading the print-head from the outlet chamber. The print-head chamber pulsatingly delivers a quantity of material from a thermal jet discharge nozzle to the substrate. 
     In another embodiment, the disclosure relates to a load-locked printing apparatus, comprising an inlet chamber for receiving a substrate, the inlet chamber having a first partition and a second partition; a print-head chamber in communication with the inlet chamber, the print-head chamber having a discharge nozzle for pulsatingly metering a quantity of ink onto a substrate, the second partition separating the print-head chamber from the inlet chamber; an outlet chamber in communication with the print-head chamber through a third partition, the outlet chamber receiving the substrate from print head chamber and exiting the substrate from a fourth chamber. In a preferred embodiment, the inlet chamber, the print-head chamber and the outlet chamber provide an inert gas environment while the discharge nozzle pulsatingly meters the quantity of ink onto the substrate. Although the implementation of the invention are not limited thereto, the inert gas environment can be a noble gas (e.g. argon, helium, nitrogen or hydrogen). 
     In still another embodiment, the disclosure relates to a load-locked thermal jet printing system. The system includes a housing with an inlet partition and an outlet partition. The housing defines a print-head chamber for depositing a quantity of ink onto a substrate. The housing also includes an inlet partition and an outlet partition for receiving and dispatching the substrate. A gas input provides a first gas to the housing. A controller communicates with the print-head chamber, the gas input and the inlet and outlet partitions. The controller comprises a processor circuit in communication with a memory circuit, the memory circuit instructing the processor circuit to (i) receive the substrate at the inlet partition; (ii) purge the housing with the first gas; (iii) direct the substrate to a discharge nozzle at the print-head chamber; (iv) energize the thermal jet discharge nozzle to pulsatingly deliver a quantity of film material from the discharge nozzle onto the substrate; and (v) dispatch the substrate from the housing through the outlet partition. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
       These and other embodiments of the disclosure will be discussed with reference to the following exemplary and non-limiting illustrations, in which like elements are numbered similarly, and where: 
         FIG. 1  is a schematic representation of a conventional substrate floatation system; 
         FIG. 2  is a schematic representation of an exemplary load-locked printing housing; 
         FIG. 3  is a schematic representation of the load-locked printing housing of  FIG. 2  receiving a substrate; 
         FIG. 4  schematically shows the substrate received at the print-head chamber of the housing; 
         FIG. 5  schematically shows the completion of the printing process of  FIGS. 3 and 4 ; 
         FIG. 6  is a schematic representation of a print-head for use with the load-locked housing of  FIG. 2 ; and 
         FIG. 7  is an exemplary load-locked system according to an embodiment of the invention; 
         FIG. 8  shows several types of substrate misalignment within the print system, and 
         FIG. 9  shows a substrate pattern including fiducials and initial locus of area viewed by a camera or other imaging devices. 
     
    
    
     DETAILED DESCRIPTION 
       FIG. 1  is a schematic representation of a conventional substrate floatation system. More specifically,  FIG. 1  shows a portion of a flotation system in which substrate  100  is supported by air bearings. The air bearings are shown schematically as arrows entering and leaving between baffles  110 . The substrate floatation system of  FIG. 1  is typically housed in a sealed chamber (not shown). The chamber includes multiple vacuum outlet ports and gas bearing inlet ports, which are typically arranged on a flat surface. Substrate  100  is lifted and kept off a hard surface by the pressure of a gas such as nitrogen. The flow out of the bearing volume is accomplished by means of multiple vacuum outlet ports. The floating height is typically a function of the gas pressure and flow. In principle, any gas can be utilized for such a substrate floatation system; however, in practice it is preferable to utilize a floatation gas that is inert to the materials that come into contact with the gas. As a result, it is conventional to use noble gases (e.g., nitrogen, argon, and helium) as they usually demonstrate sufficient inertness. 
     The floatation gas is an expensive component of the substrate floatation system. The cost is compounded when the printing system calls for substantially pure gas. Thus, it is desirable to minimize any gas loss to the environment. 
       FIG. 2  is a simplified representation of an exemplary load-locked printing housing according to one embodiment of the disclosure. Housing  200  is divided into three chambers, including inlet chamber  210 , print-head chamber  220  and outlet chamber  230 . As will be discussed, each chamber is separated from the rest of housing  200  through a gate or a partition. In one embodiment of the disclosure the gates or partitions substantially seal the chambers from the ambient environment and from the rest of housing  200 . In another embodiment of the disclosure (not shown), chamber  230  is not included in housing  200 , and chamber  210  is utilized as both an inlet and an outlet chamber. 
       FIG. 3  is a schematic representation of the load-locked printing housing of  FIG. 2  receiving a substrate. During operation, substrate  350  is received at inlet chamber  310  through inlet gates  312 . Inlet gates  312  can comprise a variety of options, including single or multiple moving gates. The gates can also be complemented with an air curtain (not shown) for minimizing influx of ambient gases into inlet chamber  310 . Alternatively, the gates can be replaced with air curtains acting as a partition. Similar schemes can be deployed in all gates of the housing. Once substrate  350  is received at inlet chamber  310 , inlet gates  312  close. The substrate can then be detained at inlet chamber  310 . At this time, the inlet chamber can be optionally purged from any ambient gases and refilled with the desired chamber gas, which is conventionally selected to be the same as the floatation gas, e.g. pure nitrogen or other noble gases. During the purging process, print-head inlet gate  322  as well as inlet gate  312  remain closed. Print-head inlet gate  322  can define a physical or a gas curtain. Alternatively, print-head inlet gate  322  can define a physical gate similar to inlet gate  312 . 
       FIG. 4  schematically shows the substrate received at the print-head chamber of the housing. Air bearings can be used to transport substrate  450  from inlet chamber  410  through print-head inlet gate  422  and into print-chamber  420 . Print-head chamber  420  houses the thermal jet print-head, and optionally, the ink reservoir. The printing process occurs at print-head chamber  420 . In one implementation of the invention, once substrate  450  is received at print-head chamber  420 , print-head gates  422  and  424  are closed during the printing process. Print-head chamber can be optionally purged with a chamber gas (e.g., high purity nitrogen) for further purification of the printing environment. In another implementation, substrate  450  is printed while gates  422  and  424  remain open. During the printing operation, substrate  450  can be supported by air bearings. The substrate&#39;s location in relation to housing  400  can be controlled using a combination of air pressure and vacuum, such as those shown in  FIG. 1 . In an alternative embodiment, the substrate is transported through housing  400  using a conveyer belt. 
     Once the printing process is complete, the substrate is transported to the outlet chamber as shown in  FIG. 5 . Here, print-head gates  522  and  524  are closed to seal off outlet chamber  530  from the remainder of housing  500 . Outlet gate  532  is opened to eject substrate  550  as indicated by the arrow. The process shown in  FIGS. 3-5  can be repeated to continuously print OLED materials on multiple substrates. Alternatively, gates  512 ,  522 ,  524  and  532  can be replaced with air curtains to provide for continuous and uninterrupted printing process. In another embodiment of the disclosure, once the printing process is complete, the substrate is transported back to the inlet chamber  310  through gate  322 , where gate  322  can be subsequently sealed off and gate  312  opened to eject the substrate. In this embodiment, inlet chamber  310  functions also as the outlet chamber, functionally replacing outlet chamber  530 . 
     The print-head chamber houses the print-head. In a preferred embodiment, the print-head comprises an ink chamber in fluid communication with nozzle. The ink chamber receives ink, comprising particles of the material to be deposited on the substrate dissolved or suspended in a carrier liquid, in substantially liquid form from a reservoir. The ink head chamber then meters a specified quantity of ink onto an upper face of a thermal jet discharge nozzle having a plurality of conduits such that upon delivery to the upper face, the ink flows into the conduits. The thermal jet discharge nozzle is activated such that the carrier liquid is removed leaving behind in the conduits the particles in substantially solid form. The thermal jet discharge nozzle is then further pulsatingly activated to deliver the quantity of material in substantially vapor form onto the substrate, where it condenses into substantially solid form. 
       FIG. 6  is a schematic representation of a thermal jet print-head for use with the load-locked housing of  FIG. 2 . Print-head  600  includes ink chamber  615  which is surrounded by top structure  610  and energizing element  620 . Ink chamber  615  is in liquid communication with an ink reservoir (not shown). Energizing element  620  can comprise a piezoelectric element or a heater. Energizing element  620  is energized intermittently to dispense a metered quantity of ink, optionally in the form of a liquid droplet, on the top surface of the thermal jet discharge nozzle  640 . 
     Bottom structure  630  supports nozzle  640  through brackets  660 . Brackets  660  can include and integrated heating element. The heating element is capable of instantaneously heating thermal jet discharge nozzle  640  such that the ink carrier liquid evaporates from the conduits  650 . The heating element is further capable of instantaneously heating the thermal jet discharge nozzle  650  such that substantially solid particles in the discharge nozzle are delivered from the conduits in substantially vapor form onto the substrate, where they condense into substantially solid form. 
     Print-head  600  operates entirely within the print-head chamber  220  and housing  200  of  FIG. 2 . Thus, for properly selected chamber and floatation gases (e.g. high purity nitrogen in most instances), the ink is not subject to oxidation during the deposition process. In addition, the load-locked housing can be configured to receive a transport gas, such as a noble gas, for carrying the material from the thermal jet discharge nozzle  640  onto the substrate surface. The transport gas may also transport the material from the thermal jet discharge nozzle  640  to the substrate by flowing through conduits  650 . In a preferred embodiment, multiple print-heads  600  are arranged within a load-locked print system as an array. The array can be configured to deposit material on a substrate by activating the print-heads simultaneously or sequentially. 
       FIG. 7  is an exemplary load-locked system according to an embodiment of the invention. Load-locked system of  FIG. 7  includes a housing with inlet chamber  710 , print-head chamber  720  and outlet chamber  730 . Inlet chamber  710  communicates through gates  712  and  722 . Print-head chamber  720  receives substrate  750  from the inlet chamber and deposits organic LED material thereon as described in relation to  FIG. 6 . Gate  724  communicates substrate  750  to outlet chamber  730  after the printing process is completed. The substrate exists outlet chamber  730  through gate  732 . 
     Vacuum and pressure can be used to transport substrate  750  through the load-locked system of  FIG. 7 . To control transporting the substrate, controller  770  communicates with nitrogen source  762  and vacuum  760  through valves  772  and  774 , respectively. Controller  770  comprises one or more processor circuits (not shown) in communication with one or more memory circuit (not shown). The controller also communicates with the load-locked housing and ultimately with the print nozzle. In this manner, controller  770  can coordinate opening and closing gates  712 ,  722 ,  724  and  732 . Controller  770  can also control ink dispensing by activating the piezoelectric element and/or the heater (see  FIG. 6 ). The substrate can be transported through the load-locked print system through air bearings or by a physical conveyer under the control of the controller. 
     In an exemplary operation, a memory circuit (not shown) of controller  770  provides instructions to a processor circuit (not shown) to: (i) receive the substrate at the inlet partition; (ii) purge the housing with the first gas; (iii) direct the substrate to a discharge nozzle at the print-head chamber; (iv) energize the discharge nozzle to pulsatingly deliver a quantity of material from the thermal jet discharge nozzle onto the substrate; and (v) dispatch the substrate from the housing through the outlet partition. The first gas and the second gas can be different or identical gases. The first and/or the second gas can be selected from the group comprising nitrogen, argon, and helium. 
     Controller  770  may also identify the location of the substrate through the load-locked print system and dispense ink from the print-head only when the substrate is at a precise location relative to the print-head. 
     Another aspect of the invention relates to registering the substrate relative to the print-head. Printing registration is defined as the alignment and the size of one printing process with respect to the previous printing processes performed on the same substrate. In order to achieve appropriate registration, the print-head and the substrate need to be aligned substantially identically in each printing step. In one implementation of the invention, the substrate is provided with horizontal motion (i.e., motion in the x direction) and the print-head is provided with another horizontal motion (i.e., motion in the y direction). The x and y directions may be orthogonal to each other. With this arrangement, the movement of the print-head with respect to the substrate can be defined with a combination of these two horizontal directions. 
     When the substrate is loaded onto a load-locked system, the areas to be printed are usually not perfectly aligned in the x and y directions of the system. Thus, there is a need for detecting the misalignment, determining the required corrections to the motion of the print-head relative to the substrate and applying the corrections. 
     According to one embodiment of the invention, the pattern or the previous printing is detected using a pattern recognition system. This pattern can be inherent in the previous printing or may have been added deliberately (i.e., fiducials) for the pattern recognition step. By means of its recognition of the pattern, the misalignment of the substrate to the printing system&#39;s motion, direction or axis can be determined. This manifests itself as a magnification misalignment, a translational misalignment and an angular misalignment. 
       FIG. 8  shows several types of substrate misalignment within the print system, including translational misalignment, rotational misalignment, magnification misalignment and combinational misalignment. For each print-head scan motion relative to the substrate, the pattern recognition system will look for and find/recognize the desired pattern. The pattern recognition system can optionally be integrated with the controller (see  FIG. 7 ). The pattern recognition system will look for and find/recognize the desired pattern. The pattern recognition system will provide the degree of error/misalignment in the x and y directions to the system&#39;s controller, which will then reposition the print-head and substrate to eliminate the error/misalignment. This means that for several motions of the print-head with respect to the substrate, the motion control system will check for misalignment and make the necessary corrections. 
     Alternatively, an initial scan of the entire substrate can be performed by the pattern recognition system utilizing the x and y motions available in the printing system.  FIG. 9  shows a substrate pattern including fiducials and initial locus of area viewed by a camera or other imaging devices. In  FIG. 9 , fiducials or alignment targets are identified as boxes  910  in each replicated “pixel.” Each pixel in this example, and in many OLED applications, comprises three sub-pixels each having a distinct color: red, green, and blue (RGB). The camera or the pattern recognition device initially focuses on an area of the substrate identified by circle  930 . Once the amount of misalignment is determined, the motion control system can compensate for the misalignment by causing the x and the y directions to move in a rotated and translated set of axes x 1  and y 1  such that these axis are a linear combination of the previous motions. 
     For either alignment technique, the printing control system will then cause the print-head to fire appropriately at the desired print axis as it scans the substrate. In the case of the embodiment described above, the print system will periodically use the pattern recognition system to update and adjust for any misalignment, causing the print-head to fire after alignment has been achieved. Depending on the degree of misalignment, the required update and adjustment steps may have to be repeated more often during the printing operations. Alternatively, the pattern recognition system must scan the substrate initially to assess the amount and direction of misalignment, then printing control system will utilize the misalignment information to adjust the print-head firing accordingly. 
     While the principles of the disclosure have been illustrated in relation to the exemplary embodiments shown herein, the principles of the disclosure are not limited thereto and include any modification, variation or permutation thereof. For example, while the exemplary embodiments are discussed in relation to a thermal jet discharge nozzle, the disclosed principles can be implemented with different type of nozzles. Moreover, the same or different gases can be used for floating the substrate and for providing a non-oxidizing environment within the chamber. These gases need not be noble gases. Finally, the substrate may enter the system from any direction and the schematic of a tri-chamber system is entirely exemplary.

Technology Classification (CPC): 1