Patent Abstract:
A ferroelectric memory device includes a lower interlayer dielectric on a semiconductor substrate, a plurality of ferroelectric capacitors, and a plate line. The ferroelectric capacitors are on the lower interlayer dielectric. The plate line extends across and electrically connects to surfaces of at least two adjacent ones of the plurality of ferroelectric capacitors.

Full Description:
RELATED APPLICATION 
   This application claims priority from Korean Patent Application No. 10-2002-0044224, filed on Jul. 26, 2002, the contents of which are herein incorporated by reference in their entirety. 
   FIELD OF THE INVENTION 
   The present invention relates to semiconductor devices, and more particularly, to ferroelectric memory devices with plate lines and methods of fabricating the same. 
   BACKGROUND OF THE INVENTION 
   Ferroelectric memory devices are nonvolatile devices that retain data after supply of power is stopped. They may also be operated at a supply voltage for the device, like some DRAM or SRAM devices. Ferroelectric memory devices may be used in, for example, smart cards or other memory cards. 
     FIGS. 1 through 4  are cross-sectional views illustrating a method of fabricating a conventional ferroelectric memory device. 
   Referring to  FIG. 1 , a device isolation layer  13  is formed at predetermined regions of a semiconductor substrate  11  to define active regions. Insulated gate electrodes  15 , which serve as word lines, are formed to cross over the active regions and the device isolation layer  13 . Impurity ions are implanted into the active region between the gate electrodes  15 , to form source/drain regions  17   s  and  17   d.  A first lower interlayer dielectric (ILD)  19  is formed on the entire surface of the resultant structure on the source/drain regions  17   s  and  17   d.  The first lower ILD  19  is patterned to form storage node contact holes, which expose the source regions  17   s.  Contact plugs  21  are formed in the storage node contact holes. 
   Referring to  FIG. 2 , ferroelectric capacitors  32 , which are 2-dimensionally arranged, are formed on the entire surface of the semiconductor substrate  11  including the contact plugs  21 . Each of the ferroelectric capacitors  32  includes a lower electrode  27 , a ferroelectric pattern  29 , and an upper electrode  31 , which are sequentially stacked. Each of the lower electrodes  27  covers one of the contact plugs  21 . A first upper ILD  33  is formed on the entire surface of the semiconductor substrate including the ferroelectric capacitors  32 . A plurality of main word lines  35 , which are parallel to the gate electrodes  15 , are formed on the first upper ILD  33 . Each of the main word lines  35  may, for example, control four gate electrodes  15 . 
   The upper and lower electrodes  31  and  27  may be formed of noble metals of the platinum group. Sidewalls of the ferroelectric capacitor  32  have sloped sidewalls, as illustrated in FIG.  4 . 
   Referring to  FIGS. 3 and 4 , a second upper ILD  37  is formed on the entire surface of the semiconductor and the main word lines  35 . The second upper ILD  37  and first upper ILD  33  are patterned to form via holes  39 , which expose the upper electrodes  31 . A wet etch process and a dry etch process may be performed to reduce an aspect ratio of each via hole  39 . As illustrated in  FIG. 3 , the via hole  39  has sloped upper sidewalls  39   a.  A plurality of plate lines  41  are formed to cover the via holes  39 . The plate lines  41  are disposed in parallel with the main word lines  35 . 
   In another approach, the diameter of the via hole  39  may be increased to reduce an aspect ratio of the via hole  39 . However, increasing the diameter may cause a short between the plate line  41  and the main word line  35 . As the integration density of ferroelectric memory devices increases, it may become more difficult to properly align the via hole  39  with the upper electrode  31 . Moreover, space “s” between the via hole  39  and the main word line  35  adjacent to the via hole  39  may become smaller. Increasing the diameter of the via hole  39 , or misaligning the via hole  39  with the upper electrode  31 , may result in the main word line  35  being exposed by the via hole  39  and a corresponding short between the plate line  41  and the main word line  35  (see FIG.  4 ). 
   Misalignment between the via hole  39  and the upper electrode  31  may also result in etching damage to the pattern  29 . For example, the via hole  39  may be formed using an over-etching technique to facilitate connection between the subsequently formed plate line  41  and the upper electrode  31 . During the formation of the via hole  39 , the sloped sidewalls of the ferroelectric capacitor  32  may be exposed and damaged by the etching. 
   SUMMARY OF THE INVENTION 
   Various embodiments of the present invention provide a ferroelectric memory device that includes a lower interlayer dielectric on a semiconductor substrate, a plurality of ferroelectric capacitors, and a plate line. The ferroelectric capacitors are on the lower interlayer dielectric. The plate line extends across and electrically connects to top surfaces of at least two adjacent ones of the plurality of ferroelectric capacitors. The plate line may simplify the subsequent formation of a slit-type via hole through an upper interlayer dielectric to electrically contact the ferroelectric capacitors, and may reduce the effects of misalignment of the slit-type via hole. 
   In some further embodiments of the present invention, an upper interlayer dielectric is on the lower interlayer dielectric and the plurality of ferroelectric capacitors, and hydrogen barrier spacers are between sidewalls of the ferroelectric capacitors and the lower interlayer dielectric. The plate line cover sidewalls of the hydrogen barrier spacers and a top surface of the lower interlayer dielectric. The plate line includes a local plate line and a main plate line. The local plate line directly contacts top surfaces of the adjacent ferroelectric capacitors. The main plate line is on the upper interlayer dielectric opposite to the local plate line, and directly contacts a top surface of the local plate line via a slit-type via hole through the upper interlayer dielectric. 
   In still further embodiments, sidewalls of the ferroelectric capacitors may be substantially vertical relative to a top surface of the semiconductor substrate. For example, the sidewalls of the ferroelectric my have an inclination of about 70° to about 90° relative to a top surface of the semiconductor substrate. 

   
     BRIEF DESCRIPTION OF THE DRAWINGS 
       FIGS. 1 through 4  are cross-sectional views illustrating a method of fabricating a ferroelectric memory device according to the prior art; 
       FIG. 5  is a top plan view illustrating methods of fabricating a ferroelectric memory device according to a various embodiments of the present invention; 
       FIGS. 6 through 8  are perspective views illustrating ferroelectric memory devices according to various embodiments of the present invention; 
       FIGS. 9 through 14  are cross-sectional views taken along line I-I′ of  FIG. 5 , illustrating methods of fabricating ferroelectric memory devices according to some embodiments of the present invention; and 
       FIGS. 15 through 18  are cross-sectional views taken along line I-I′ of  FIG. 5 , illustrating methods of fabricating ferroelectric memory devices according to some other embodiments of the present invention. 
   

   DESCRIPTION OF EMBODIMENTS 
   The present invention will now be described more fully hereinafter with reference to the accompanying drawings, in which preferred embodiments of the invention are shown. The invention may, however, be embodied in different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art. In the drawings, the thickness of layers and regions are exaggerated for clarity. It will also be understood that when a layer is referred to as being “on” another layer or substrate, it can be directly on the other layer or substrate, or intervening layers may also be present. Like numbers refer to like elements throughout. It will be understood that if part of an element, such as a surface of a conductive line, is referred to as “top,” it is further from the outside of the integrated circuit than other parts of the element. Furthermore, relative terms such as “beneath” may be used herein to describe a relationship of one layer or region to another layer or region relative to a substrate or base layer as illustrated in the figures. It will be understood that these terms are intended to encompass different orientations of the device in addition to the orientation depicted in the figures. 
     FIG. 5  is a top plan view that illustrates a portion of a cell array region of a ferroelectric memory device according various embodiments of the present invention.  FIGS. 6 through 8  are perspective views that illustrate three embodiments of the present invention. 
   Referring to  FIGS. 5 and 6 , a device isolation layer  53  is formed in a predetermined region of a semiconductor substrate  51 . The device isolation layer  53  defines a plurality of active regions  53   a,  which may be 2-dimensionally arranged. A plurality of insulated gate electrodes  57 , which may serve as word lines, cross over the active regions  53   a  and the device isolation layer  53 . The gate electrodes  57  are parallel in a row direction (y-axis). Each of the active regions  53   a  intersects with a pair of gate electrodes  57 , thereby dividing the each of the active regions  53   a  into three portions. A common drain region  61   d  is formed in the active region  53   a  between the pair of gate electrodes  57 , and source regions  61   s  are formed in the active regions  53   a  on both sides of the common drain region  61   d.  Cell transistors are formed where the gate electrodes  57  intersect with the active regions  53   a.  Accordingly, the illustrated cell transistors are arranged in 2-dimensions along row (x-axis) and column (y-axis) directions. It will be understood that the x and y axes are the row and column designations are used herein to indicate two different directions, which need not be orthogonal. 
   A lower ILD  74  is formed on the surface of the semiconductor substrate  51  and the cell transistors. A plurality of bit lines  71  are formed in the lower ILD  74  to cross over the word lines  57 . Each of the bit lines  71  is electrically connected to the common drain region  61   d  via a bit line contact hole  71   a.  The source regions  61   s  are exposed by storage node contact holes  75   a  that penetrate the lower ILD  74 . The storage node contact holes  75   a  may have upper sidewalls with a sloped profile. Each of the storage node contact holes  75   a  may be filled with a contact plug  75 . Accordingly, as illustrated in  FIG. 6 , the contact plug  75  may have an upper portion that has a larger diameter (upper diameter) than that of a lower portion (lower diameter). 
   A plurality of ferroelectric capacitors  82  (CP shown in  FIG. 5 ) may be 2-dimensionally arranged in the row direction (x-axis) and column direction (y-axis) on the contact plugs  75  and the surface of the semiconductor substrate  51 . The ferroelectric capacitors  82  may have substantially vertical sidewalls, which may have an inclination of about 70 to about 90° relative to a top surface of the semiconductor substrate  51 . The ferroelectric capacitors  82  may each include a lower electrode  77 , a ferroelectric pattern  79 , and an upper electrode  81 , which are sequentially stacked. The lower electrode  77  may be on the contact plug  75  so as to be electrically connected to the source region  61   s.  The lower and upper electrodes  77  and  81  may be, for example, Ru, RuO 2 , or may be a material selected from the group consisting of platinum (Pt), iridium (Ir), rhodium (Rh), osmium (Os), oxides thereof, and/or combinations thereof. 
   The ferroelectric pattern  79  may be PZT(Pb, Zr, TiO 3 ), which may be formed using PbTiO 3  as a seed layer. The ferroelectric pattern  79  may alternatively be a material that is selected from the group consisting of PZT(Pb, Zr, TiO 3 ), SrTiO 3 , BaTiO 3 , (Ba, Sr)TiO 3 , Pb(Zr,Ti)O 3 , SrBi 2 Ta 2 O 9 , (Pb,La)(Zr,Ti)O 3 , Bi 4 Ti 3 O 12 , and/or combinations thereof. Use of PZT(Pb, Zr, TiO 3 ) as a seed layer may allow the thickness of the ferroelectric pattern  79  to be about 100 nm or less. A thinner ferroelectric pattern  79  may allow more easy fabrication of substantially vertical sidewalls for the ferroelectric capacitor  82 . 
   Hydrogen barrier spacers  83   a  are formed on the sidewalls of the ferroelectric capacitors  82 . The hydrogen barrier spacers  83   a  may be a material that is selected from the group consisting of TiO 2 , Al 2 O 3 , ZrO 2 , CeO 2 , and/or combinations thereof. The hydrogen barrier spacers  83   a  may prevent or inhibit penetration of hydrogen atoms into the ferroelectric pattern  79 . 
   When hydrogen atoms are injected into the ferroelectric pattern  79 , the characteristics (e.g., reliability) of the ferroelectric pattern  79  may be reduced. For example, if hydrogen atoms are injected into a ferroelectric layer of PZT(Pb, Zr, TiO 3 ), oxygen atoms in the PZT layer may react with the hydrogen atoms to cause oxygen vacancy into the PZT layer. The oxygen vacancy may deteriorate a polarization characteristic of the ferroelectric pattern  79 , which may cause the memory device to malfunction. 
   Moreover, hydrogen atoms that are caught in the interfaces between the ferroelectric pattern  79  and the upper and lower electrodes  81  and  77  may cause the ferroelectric capacitor  82  to have a poor leakage current characteristic. Consequently, the hydrogen barrier spacer  83   a  may improve characteristics, such as reliability, of the ferroelectric capacitor  82 . As described above, because the ferroelectric capacitors  82  may be formed to have substantially vertical sidewalls, damage to the ferroelectric pattern  79  during subsequent process steps may be avoided, in contrast to the prior art process that is illustrated in FIG.  4 . 
   A plurality of local plate lines  87  (PL of  FIG. 5 ) are formed on the ferroelectric capacitors  82 , and may be parallel to the row direction (y-axis) and cover sidewalls of the hydrogen barrier spacers  83   a  and top surfaces of the lower ILD  74 . Each of the local plate lines  87  may cover at least two ferroelectric capacitors  82  in two adjacent rows. The local plate line  87  may directly contact the adjacent upper electrode  81 , and may be insulated from the lower electrode  77  by the hydrogen barrier spacers  83   a.  An upper ILD may cover the local plate lines  87  and the surface of the semiconductor substrate  51 . The upper ILD may include first and second upper ILDs  89  and  93 , which are sequentially stacked. 
   A plurality of main word lines may be between portions of the first and second upper ILDs  89  and  93 . Each of the main word lines  91  may, for example, control four word lines  57  via a decoder. A main plate line  97  may be on the upper ILD between the main word lines  91 . The main plate line  97  may be electrically connected to the local plate line  87  via a slit-type via hole  95  that penetrates the upper ILD ( 89  and  93 ). The slit-type via hole  95  may be parallel to the row direction (y-axis). As illustrated in  FIG. 6 , the slit-type via hole  95  may have a larger width than the via hole  39  that is illustrated in FIG.  3 . 
   The local plate line  87  and the main plate line  97 , which form a plate line, may be in directly contact with each other. The plate line may alternatively be formed from only main plate line  97 , as will be discussed below with regard to a third example embodiment of the ferroelectric memory device. The plate line may, for example, be a material that is selected from the group consisting of the platinum group including ruthenium (Ru), platinum (Pt), iridium (Ir), rhodium (Rh), Osmium (Os), and palladium (Pd), oxides thereof, and/or combinations thereof. The plate line may alternatively be a material that is conventionally used in a metal layer of a semiconductor device. In a first example embodiment that is illustrated in  FIG. 16 , a first upper ILD pattern  89   a  may be between the local plate line  87  and the main plate line  97 . As illustrated, the first upper ILD pattern  89   a  fills a gap region formed between the hydrogen barrier spacers  83   a  that are covered by the local plate line  87 . 
     FIG. 7  is a perspective view of a ferroelectric memory device according to a second example embodiment of the present invention. In the second embodiment, cell transistors, lower ILD, upper ILD, contact plugs, ferroelectric capacitors, and hydrogen barrier spacers have the same structures as those shown for the first example embodiment of the present invention. Thus, further description of those structures will be omitted here for brevity. 
   Referring to  FIGS. 5 and 7 , a gap region between outer sidewalls of the hydrogen barrier spacers  83   a  is filled with an insulation pattern  85   a.  The insulation pattern  85   a  is also between the local plate line  87  and the lower ILD  74 . The lower electrode  77  is electrically insulated from the local plate line  87  by, for example, the insulation pattern  85   a  and the hydrogen barrier space  83   a.  The insulation pattern  85   a  may be an oxide layer containing a small amount of hydrogen, and may have a top surface that is aligned with a top surface of the ferroelectric capacitor  82 . 
     FIG. 8  is a perspective view of a ferroelectric memory device according to a third example embodiment of the present invention. In the third embodiment, cell transistors, lower ILD, upper ILD, contact plugs, ferroelectric capacitors, and hydrogen barrier spacers have the same structures as shown for the first example embodiment of the present invention. Thus, the description of those structures will be omitted here for brevity. Referring to  FIGS. 5 and 8 , unlike the first embodiment of the present invention that is illustrated in  FIG. 6 , a main plate line  97  directly contacts top surfaces of adjacent upper electrodes  81 . 
   A gap region under the main plate line  97  and between the hydrogen barrier spacers  83   a  is filled with a first upper ILD pattern  89   b.  The first upper ILD pattern  89   b  is between the main plate line  97  and the lower ILD  74 . The first upper ILD pattern  89   b  may be formed of the same material as the first upper ILD  89 , or may be an oxide layer containing a small amount of hydrogen. 
   A variation of the third example embodiment of a ferroelectric memory device is illustrated in  FIG. 18 , in which the main plate line  97  directly contacts the top surface of the lower ILD  74  and the top surface of the two adjacent upper electrodes  81 , and covers outward sidewalls of the hydrogen barrier spacer  83   a.    
   Methods of fabricating ferroelectric memory devices will now be described with reference to  FIGS. 9 through 14 .  FIGS. 9 through 14  are cross-sectional views taken along line I-I′ of  FIG. 5 , and illustrate methods of fabricating ferroelectric memory devices according to a first example embodiment of the present invention. 
   Referring to  FIG. 9 , a device isolation layer  53  is formed at predetermined regions of a semiconductor substrate  51  to define active regions  53   a.  A gate insulation layer, a gate conductive layer, and a capping oxide layer may be sequentially formed on the entire surface of the semiconductor substrate  51  and the active regions  53   a.  The capping oxide layer, the gate conductive layer, and the gate insulation layer are successively patterned to form a plurality of gate patterns  60 , which may be parallel with each other and cross over the active regions and the device isolation layer  53 . Each of the gate patterns  60  may be formed of a gate insulation pattern  55 , a gate electrode  57 , and a capping insulation pattern  59 . Each of the active regions  53   a  may intersect a pair of the gate electrodes  57 . The gate electrode  57  may form a word line. 
   Impurity ions may be implanted into active regions using the gate patterns  60  and the device isolation layer  53  as an ion implantation mask. Thus, three impurity regions may be formed in each active region  53   a.  The middle impurity region may correspond to a common drain region  61   d,  and the other two impurity regions may correspond to source regions  61   s.  Thus, a pair of cell transistors may be formed in each of the active regions  53   a.  As shown in  FIG. 9 , the cell transistors may be arranged 2-dimensionally in row and column directions. Spacers  63  may be formed on sidewalls of the gate pattern  60  by, for example, a conventional fabrication process. 
   Referring to  FIG. 10 , a first lower ILD  65  may be formed on the spacer  63  and the surface of the semiconductor substrate  51 . The first lower ILD  65  is patterned to form a pad contact hole that exposes the source and drain regions  61   s  and  61   d.  Storage node pads  67   s  and bit line pads  67   d  are formed in the pad contact hole by, for example, a conventional fabrication process. The storage node pads  67   s  are connected to the source regions  61   s,  and the bit line pads  67   d  are connected to the common drain region  61   d.  A second lower ILD  69  is formed on the pads  67   s  and  67   d  and an exposed surface of the semiconductor substrate  51 . The second lower ILD  69  is patterned to form bit line contact holes ( 71   a  in  FIG. 5 ) that expose the bit line pads  67   d.  A plurality of bit lines  71 , which may be parallel with each other, are formed to cover the bit line contact holes. The bit lines  71  cross over top surfaces of the word lines  57 . 
   Referring to  FIG. 11 , a third lower ILD  73  is formed on an exposed surface of the semiconductor substrate and the bit lines  71 . The first through third lower ILDs  65 ,  67 , and  73  form a lower ILD  74 . The second and third lower ILDs  69  and  73  are patterned to form storage node contact holes ( 75   a  in  FIG. 5 ) that expose the storage node pads  67   s.  The storage node contact hole ( 75   a  in  FIG. 5 ) may be formed using, for example, wet or dry etching processes so as to increase its upper diameter. Thus, the storage node contact hole ( 75   a  in FIG.  5 ), can include upper sidewalls with a sloped profile, which may reduce electrical resistance between a subsequently formed lower electrode and the source region  61   s.  Contact plugs  75  are formed in the storage node contact holes ( 75   a  in FIG.  5 ). 
   Referring to  FIG. 12 , a lower electrode layer, a ferroelectric layer, and an upper electrode layer are sequentially formed on the contact plugs  75  and the lower ILD  74 . The upper electrode layer, the ferroelectric layer, and the lower electrode layer are successively patterned to form a plurality of ferroelectric capacitors  82  (CP of FIG.  5 ), which may be 2-dimensionally arranged in row and column directions. Each of the ferroelectric capacitors  82  may include a lower electrode  77 , a ferroelectric pattern  79 , and an upper electrode  81 , which are sequentially stacked. Each of the lower electrodes  77  may contact, or otherwise be electrically connected with, the contact plugs  75 . As a result, each of the ferroelectric capacitors  82  is electrically connected to the source regions  61   s.    
   The ferroelectric capacitors  82  may be patterned to have substantially vertical sidewalls, which may have an inclination of about 70° to about 90° relative to a top surface of the semiconductor substrate  51 . Such patterning may be facilitated by forming the lower and upper electrodes  77  and  81  of at least one of Ru and RuO 2 , and/or using an anisotropic etching process such as, for example, a plasma etching containing oxygen. When the Ru and RuO 2  are etched using plasma containing oxygen, volatile RuO 4  may be created. The upper and lower electrodes  81  and  77  may alternatively be formed from, for example, a material that is selected from the group consisting of the platinum group including ruthenium (Ru), platinum (Pt), iridium (Ir), rhodium (Rh), and Osmium (Os), and oxides thereof, and/or combinations thereof. 
   The ferroelectric pattern  79  may be PZT(Pb, Zr, TiO 3 ) that si formed using PbTiO 3  as a seed layer. The ferroelectric pattern  79  may alternatively be formed from at least one material selected from the group consisting of Pb(Zr, Ti)O 3 , SrTiO 3 , BaTiO 3 , (Ba, Sr)TiO 3 , Pb(Zr,Ti)O 3 , SrBi 2 Ta 2 O 9 , (Pb,La)(Zr,Ti)O 3 , and Bi 4 Ti 3 O 12 . A PZT and PbTiO 3  thin layer may be formed using CSD. The CSD process may use as a precursor lead acetate[Pb(CH3CO 2 ) 2 3H 2 O], zirconium n-butoxide [Zr(n-OC 4 H 9 ) 4 ], and titanium isopropoxide [Ti(i-OC 3 H 7 ) 4 ], and using a solvent 2-methoxyethano [CH 3 OCH 2 CH 2 OH]. Thin PZT and PbTiO 3  layers may be stacked using, for example, spin coating and baking at about 200° C. The resultant structures may be annealed using, for example, rapid thermal processing (RTP) in an oxygen atmosphere of 500 to 675° C. The resulting ferroelectric pattern  79  may exhibit an improved ferroelectric characteristics, and which may allow a corresponding reduction in the thickness of the ferroelectric pattern  79  and, thereby, a reduction in the thickness of the ferroelectric capacitor. Reducing the thickness of the ferroelectric capacitor  82  allows the sidewalls of the ferroelectric capacitor  82  to be patterned to be substantially vertical sidewalls or close to vertical. For example, the ferroelectric pattern  79  and the ferroelectric capacitor  82  may have respective thicknesses of 100 nm or less and 400 nm or less. 
   A hydrogen barrier layer is formed on the surface of the semiconductor substrate and the ferroelectric capacitors  82 . The hydrogen barrier layer may be formed from, for example, at least one selected from the group consisting of TiO 2 , Al 2 O 3 , ZrO 2 , and CeO 2 . The hydrogen barrier layer may be anisotropically etched until the top surfaces of the ferroelectric capacitors  82  are exposed, thereby forming hydrogen barrier spacers  83   a  on the sidewalls of the ferroelectric capacitors  82 . Because the ferroelectric capacitors  82  have substantially vertical sidewalls, the hydrogen barrier spacers  83   a  may have the shape of a conventional spacer, and hydrogen atoms that are used in later fabrication processes may not penetrate into the ferroelectric pattern  79 , or penetration may be reduced. But for the hydrogen barrier spacers  83   a,  hydrogen atoms may be allowed to be injected into the ferroelectric capacitors  79 , and which may result in degraded characteristics, such as reduced polarization and increased leakage current. Accordingly, the hydrogen barrier spacer  83   a  may enhance the characteristics of the ferroelectric capacitor  82 . 
   Referring to  FIG. 13 , a lower plate layer is formed on the exposed surface of the semiconductor substrate and the hydrogen barrier spacer  83   a.  The lower plate layer is patterned to form a plurality of local plate lines  87  (PL in FIG.  5 ), that may be parallel to the word lines  57  (the row direction or y-axis in FIG.  5 ). Each of the local plate lines  87  may directly contact a plurality of upper electrodes  81  that are, for example, in two adjacent rows. The local plate lines  87  may also cover outward sidewalls of the hydrogen barrier spacers  83   a  and an exposed top surface of the lower ILD  74  therebetween. The local plate lines  87  are insulated from the lower electrodes  77  by the hydrogen barrier spacers  83   a  therebetween. The lower plate layer may be formed from, for example, at least one material selected from the group consisting of the platinum group including ruthenium (Ru), platinum (Pt), iridium (Ir), rhodium (Rh), Osmium (Os), and palladium (Pd), and oxides thereof. 
   An upper ILD is formed on the exposed surface of the semiconductor substrate and the local plate lines  87 . The upper ILD may be formed by sequentially stacking the first and second upper ILDs  89  and  93 . Before forming the second upper ILD  93 , a plurality of main word lines  91 , which are parallel with each other, may be formed on the first upper ILD  89 . A single main word line  91  may control, for example, four word lines  57  via a decoder. 
   Referring to  FIG. 14 , the upper ILD is patterned to form a slit-type via hole  95  that exposes the local plate line  87 . The slit-type via hole  95  is between the main word lines  91  and may be parallel with the main word lines  91 . As illustrated in  FIG. 14 , an upper portion of the slit-type via hole  95  may have a greater width than a lower portion thereof. However, as illustrated, a space A may still be present between the slit-type via hole  95  and main word lines  91 , in contrast to the via hole  39  that is illustrated in  FIG. 4  that exposes the main word line  35 . Consequently, even if the slit-type via hole  95  is formed using wet or dry etching processes to reduce an aspect ratio of the slit-type via hole  95 , the main word lines  91  may not be exposed. Accordingly, an aspect ratio of the slit-type via hole  95  may be reduced without exposing the main word lines  91 , and/or the exposed area of the local plate line  87  may be increased. 
   Next, an upper plate layer such as a metal layer may be formed on the exposed surface of the resultant structure including the slit-type via hole  95 . Because the slit-type via hole  95  may have a low aspect ratio, the upper plate layer may exhibit good step coverage. The upper plate layer may be patterned to form a main plate line  97  that covers the slit-type via hole  95 . A plate line may then include one or both of the local plate line  87  and the main plate line  97 . 
     FIGS. 15 and 17  are cross-sectional views that illustrate methods of fabricating ferroelectric memory devices according to second and third example embodiments of the present invention.  FIGS. 16 and 18  are cross-sectional views that illustrate methods of fabricating ferroelectric memory devices according to further variations of the second and third example embodiments of the present invention, respectively. The following embodiments include steps that described with reference to  FIGS. 9 through 12 . 
   The steps of forming an upper ILD and a main word line may be the same as those in the first embodiment, and accordingly these steps will not be repeated here for brevity. 
   A second example embodiment is illustrated in  FIG. 15 , that, in comparison to the embodiment illustrated in  FIG. 14 , further comprises an insulation pattern  85   a  and a local plate line  87 . An insulation layer may be formed on the exposed surface of the semiconductor substrate and the hydrogen barrier spacers  83   a.  The insulation layer may be, for example, a material containing a small amount of hydrogen, and have less tensile stress. The insulation pattern  85   a  may then be formed by planarizing the insulation layer, such as by etching, until the top surface of the upper electrode  81  is exposed. Etching may be performed using an etch selectivity with respect to the upper electrode  81  and the hydrogen barrier spacer  83   a.  The insulation pattern  85   a  may thereby fill a gap region between the hydrogen barrier spacers  83   a.  The insulation pattern  85   a  may alternatively have a lower top surface than the ferroelectric capacitor  82 . 
   A lower plate layer may be formed on the surface of the semiconductor substrate and the insulation pattern  85   a,  and then patterned to form the local plate line  87 . The patterning process may use an etch selectivity with respect to the insulation pattern  85   a  or the hydrogen barrier spacers  83   a.  Each of the local plate lines  87  may directly contact the upper electrodes  81 , such as contacting, for example, two adjacent rows of upper electrode  81 . The local plate lines  87  cover the top surfaces of the insulation pattern  85   a.  The remaining steps for forming the ferroelectric memory device, including forming the main plate line  97 , may be the same as those described above for  FIG. 14 , and which are not repeated here for brevity. 
   The ferroelectric memory device that is illustrated in  FIG. 16  is similar to the one shown in  FIG. 14  except for the formation of a slit-type via hole  95 . Using fabrication steps that were discussed with reference to  FIG. 13 , a local plate line  87  and an upper ILD are formed. The upper ILD is patterned to form a slit-type via hole  95  that exposes the top surface of the local plate line  87 . A patterning process is performed so that the first upper ILD pattern  89   a  surrounded by the local plate line  87  remains between the hydrogen barrier spacer  83   a.  Top surfaces of the local plate lines  87  are prevented from etching damages during the patterning process. The main plate line  97  is formed thereon. 
   The ferroelectric memory devices that are illustrated in  FIGS. 17 and 18  are similar to the one shown in  FIG. 14  except for the absence of a local plate line ( 87  of FIG.  14 ). A first upper ILD  89 , a main word line  91 , and a second upper ILD  93  are formed on structure that includes the semiconductor substrate  51  and the hydrogen barrier spacers  83   a.  The upper ILDs  93  and  89  are patterned to form a slit-type via hole  93  that exposes the top surface of the plurality of upper electrodes  81 , which may be arranged in two rows adjacent to each other. 
   The slit-type via hole  95  may be patterned such that the upper ILD  89  remains between the hydrogen barrier spacers  83   a  (see FIG.  17 ). Thus, a first upper ILD pattern  89   b  is between the hydrogen barrier spacers  83   a.  In contrast as illustrated in  FIG. 18 , the slit-type via hole  95  exposes the top surface of the lower ILD  74 . The hydrogen barrier spacer  83   a  and the first upper ILD  89  may be formed of materials having an etch selectivity with respect to each other. 
   An upper plate layer is formed on the surface of the resultant structure where the slit-type via hole  95  is formed. The upper plate layer may be patterned to form a man plate line  97  covering the slit-type via hole  95 . The main plate line  97  may directly contact, for example, two adjacent electrodes  81  that are in two rows. 
   Accordingly, various embodiments of the present invention may provide a plate line that directly contacts upper electrodes of a plurality of capacitors, and which may be arranged in at least two adjacent rows. The use of a plate line may increase the integration density of the ferroelectric memory device and/or improve its characteristics, such as its reliability. 
   Various embodiments may provide ferroelectric capacitors that have substantially vertical sidewalls. Accordingly, damage to ferroelectric patterns may be avoided or reduced when hydrogen barrier spacers are formed to insulate the plate line from lower electrodes, and the characteristics of the ferroelectric capacitor, such as its reliability, may be improved. 
   While the present invention has been described in detail, it should be understood that various changes, substitutions and alterations could be made hereto without departing from the spirit and scope of the invention as defined by the appended claims.

Technology Classification (CPC): 7