Patent Abstract:
It has been found that the insertion of a copper laminate within CoFe, or a CoFe/NiFe composite, leads to higher values of CPP GMR and DRA. However, this type of structure exhibits very negative magnetostriction, in the range of high −10 −6  to −10 −5 . This problem has been overcome by giving the copper laminates an oxygen exposure treatment When this is done, the free layer is found to have a very low positive magnetostriction constant. Additionally, the value of the magnetostriction constant can be adjusted by varying the thickness of the free layer and/or the position and number of the oxygen treated copper laminates.

Full Description:
This is a division of patent application Ser. No. 10/388,289 filing date Mar. 12, 2003 now U.S. Pat. No. 6,998,150, Method Of Adjusting CoFe Free Layer Magnetostriction, which is herein incorporated by reference in its entirety. 
    
    
     FIELD OF THE INVENTION 
     The invention relates to the general field of CPP GMR read heads with particular reference to controlling magnetostriction in magnetically free layers of CoFe. 
     BACKGROUND OF THE INVENTION 
     The principle governing the operation of most magnetic read heads is the change of resistivity of certain materials in the presence of a magnetic field (magneto-resistance or MR). Magneto-resistance can be significantly increased by means of a structure known as a spin valve where the resistance increase (known as Giant Magneto-Resistance or GMR) derives from the fact that electrons in a magnetized solid are subject to significantly less scattering by the lattice when their own magnetization vectors (due to spin) are parallel (as opposed to anti-parallel) to the direction of magnetization of their environment. 
     The key elements of a spin valve are illustrated in  FIG. 1 . They are seed layer  11  on which is antiferromagnetic layer  12  whose purpose is to act as a pinning layer for magnetically pinned layer  345 . The latter is a synthetic antiferromagnet formed by sandwiching antiferromagnetic coupling layer  14  between two antiparallel ferromagnetic layers  13  (AP 2 ) and  15  (AP 1 ). Next is a copper spacer layer  16  on which is low coercivity (free) ferromagnetic layer  17 . A contacting layer  18  lies atop free layer  17  and cap layer  19  is present over layer  18  to protect the structure during processing. 
     When free layer  17  is exposed to an external magnetic field, the direction of its magnetization is free to rotate according to the direction of the external field. After the external field is removed, the magnetization of the free layer will stay at a direction, which is dictated by the minimum energy state, determined by the crystalline and shape anisotropy, current field, coupling field and demagnetization field. If the direction of the pinned field is parallel to the free layer, electrons passing between the free and pinned layers suffer less scattering. Thus, the resistance in this state is lower. If, however, the magnetization of the pinned layer is anti-parallel to that of the free layer, electrons moving from one layer into the other will suffer more scattering so the resistance of the structure will increase. The change in resistance of a spin valve is typically 8-20%. 
     Most GMR devices have been designed so as to measure the resistance of the free layer for current flowing parallel to the film&#39;s plane. However, as the quest for ever greater densities continues, devices that measure current flowing perpendicular to the plane (CPP) have begun to emerge. For devices depending on in-plane current, the signal strength is diluted by parallel currents flowing through the other layers of the GMR stack, so these layers should have resistivities as high as possible while the resistance of the leads into and out of the device need not be particularly low. By contrast, in a CPP device, the resistivity of the leads tend to dominate and should be as low as possible. 
     For application of the CPP SV structure in a reader head, some developers have substituted a CoFe_Cu layer for pure CoFe in both the free layer and in AP 1 . CoFe_Cu is shorthand for a CoFe layer within which has been inserted a very thin laminate of pure copper (designated as  20  in  FIG. 1 ). It has been found that the substitution of CoFe_Cu for CoFe, or a CoFe/NiFe composite, leads to higher values of CPP GMR and DRA. While this represents an important improvement in device behavior, it has been found that this type of structure exhibits very negative magnetostriction, in the range of high −10 −6  to −10 −5 . 
     Magnetostriction is an important form of anisotropy in magnetic materials. It relates the stress in a magnetic material to an anisotropy created by that stress. The dimensionless magnetostriction constant λ is a constant of proportionality. If λ is positive, then application of a tensile (stretching) stress to a bar will create an easy axis in the direction of the applied stress. If a compressive stress is applied, then the direction of the easy axis created will be perpendicular to the stress direction. If the magnetostriction constant for the material is negative, then this is reversed. 
     The magnetostriction constant λ is defined as follows: If a rod having a positive value of λ is magnetized, the rod will stretch in the direction of the magnetization. The fractional increase in length defines the magnetostriction constant λ. If the material has a negative value of λ, then the material will shorten in the direction of the magnetization. The latter is an undesirable value of the magnetostriction for head operation because in actual read heads the stress is compressive. The resulting very large negative magnetostriction will generate large anisotropy along the stripe length direction which greatly reduces the heads output. For read head applications, a low positive magnetostriction is preferred. 
     The present invention discloses a method to adjust the free layer magnetostriction to a very low positive value. 
     A routine search of the prior art was performed with the following references of interest being found: 
     In U.S. Pat. No. 5,627,704, Lederman et al. show a GMR CPP transducer with a flux guide yoke structure but no details are given about the makeup of the stack. In U.S. Pat. No. 6,118,624, Fukuzawa et al. describe a layer of NiFe or the like between the pinned layer and the free layer and adding an oxygen layer between the NiFe and the pinned layer. Dykes et al., in U.S. Pat. No. 5,668,688, show a CCP GMR structure, but give no details about the makeup of the structure. 
     SUMMARY OF THE INVENTION 
     It has been an object of at least one embodiment of the present invention to provide a process to manufacture a CPP GMR magnetic read head. 
     Another object of at least one embodiment of the present invention has been that the free layer in said read head have a low positive magnetostriction constant, as well as a low coercivity. 
     Still another object of at least one embodiment of the present invention has been that said process be compatible with existing processes for the manufacture of CPP GMR devices. 
     These objects have been achieved by using an oxygen exposure treatment on the copper spacer layer and/or laminating very thin layers of copper within the free layer itself, said layers then also receiving similar oxygen treatment. When this is done, the free layer is found to have a very low positive magnetostriction constant. As a further refinement, the value of the magnetostriction constant can be adjusted by varying the thickness of the free layer and/or the position and number of the oxygen treated copper laminates. The magnetic properties and electrical resistance are not changed much by this oxygen exposure treatment. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1  shows a GMR stack of the prior art. 
         FIGS. 2   a  and  2   b  illustrate a key feature—copper layer exposure to oxygen. 
         FIGS. 3-5  show the structures that result from exercising each of the embodiments of the present invention. 
     
    
    
     DESCRIPTION OF THE PREFERRED EMBODIMENTS 
     Since it is known that magnetostriction of bulk Co 90 Fe 10  (henceforth referred to as CoFe) is close to zero, the large negative values seen in spin valve structures can be attributed to the nature of the underlying materials in the GMR stack. In particular, when the very thin film of CoFe attempts to conform to the underlying layer&#39;s crystal structure, it will be forced to deviate from its bulk structure. As the strain of the CoFe layer changes so does the magnetostriction. So appropriate alteration of the underneath layer structure and/or the CoFe layer structure, should make it possible to change the strain and magnetostriction of the CoFe layer. As will be described in greater detail below, exposure of the free and/or spacer layer to a small amount of oxygen has been found to alter the structure effectively. 
     Experimental data collected in this regard are displayed below in TABLE I which lists the thicknesses of the various sub-layers from which the spacer and free layers were formed. 
     
       
         
               
               
               
               
             
               
               
               
               
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
               
               
               
               
             
           
               
                   
                   
               
               
                   
                 Spacer 
                   
                   
               
               
                   
                 Structure 
                 Free Layer Structure 
                 Properties 
               
             
          
           
               
                 # 
                 Cu 
                 SL 
                 Cu 
                 CoFe 
                 Cu 
                 SL 
                 CoFe 
                 Cu 
                 CoFe 
                 λ 
                 H c   
               
               
                   
               
             
          
           
               
                 1 
                 10 
                 * 
                 16 
                 10 
                 3 
                 * 
                 10 
                 3 
                 10 
                 +3.4 
                 12.1 
               
               
                 2 
                 10 
                 * 
                 16 
                 13 
                 3 
                 * 
                 8.5 
                 3 
                 8.5 
                 −3.4 
                 12.1 
               
               
                 3 
                 10 
                 * 
                 16 
                 15 
                 3 
                 * 
                 7.5 
                 3 
                 7.5 
                 −10 
                 12.8 
               
               
                 4 
                 26 
                 x 
                 — 
                 10 
                 3 
                 x 
                 10 
                 — 
                 — 
                 −80 
                 10.9 
               
               
                 5 
                 10 
                 * 
                 16 
                 10 
                 3 
                 x 
                 10 
                 3 
                 10 
                 −59 
                 11.5 
               
               
                   
               
               
                 λ values are ×10 −7   
               
               
                 H c  = coercivity in Oe 
               
               
                 all thicknesses in Angstroms 
               
               
                 SL is an internal acronym and stands for oxygen exposure: 10 sccm for 10 sec. 
               
             
          
         
       
     
     Sample # 4 represents the prior art for reference. As can be seen, it showed very negative magnetostriction of −80×10 −7 . By adding the oxygen exposure step, the magnetostriction value was reduced to about −60×10 −7  (sample 5). However this is still too large for practical applications. By adding one more oxygen exposure (inside the free layer), the value of magnetostriction changed dramatically (samples 1, 2, and 3). It was also determined that the magnetostriction depended on the thickness of the free layer. Within a thickness range of about 5 to 15 Angstroms, the thicker the free layer, the more positive the magnetostriction. This finding enabled us to adjust λ in a controllable manner from a low negative to a low positive value. In this manner the optimum structure (sample 1) was obtained. 
     It is important to note that, as seen in TABLE I, adding the oxygen exposure step to formation of the spacer and/or free layer did not change the free layer coercivity very much. In other words, the magnetic properties of the free layer were maintained. The sheet resistances all samples, including the reference sample 4, were almost same (not shown in the table), which indicates that the transport properties are not much altered either. 
     The effectiveness of the present invention is confirmed by the data presented in TABLE II below. The two structures that are A and B where A is of the prior art and B is an example of the present invention. The makeup of each was as follows:
     A. Seed/IrMn/[FeCo11/Ta1] 2 /FeCo8/Ru/[CoFe9/Cu3] 3 CoFe8/Cu26/[CoFe10/Cu3] 3 /Cu7/cap   B. Seed/IrMn/[FeCo11/Ta1] 2 /FeCo8/Ru/[CoFe9/Cu3] 3 CoFe8/Cu10/SL/Cu16/CoFe10/Cu3/ SL[CoFe10/Cu3] 2 /Cu7/cap   

     
       
         
               
               
               
               
             
               
               
               
               
             
           
               
                 TABLE II 
               
               
                   
               
               
                 STRUCTURE 
                 RA (ohmμm 2 ) 
                 DRA (mohmμm 2 ) 
                 CPP GMR (%) 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 A 
                 0.105 
                 1.87 
                 1.8 
               
               
                 B 
                 0.134 
                 1.41 
                 1.82 
               
               
                   
               
             
          
         
       
     
     This confirms that the oxygen treatment can increase RA and DRA about 29% 0. This increase of DRA will enhance the sensor signal output. 
     The following three embodiments of the invention describe the process of the invention in greater detail, while at the same time further clarifying the structure of the present invention. 
     1 st  Embodiment 
     Referring now to  FIG. 5 , the process of the present invention begins with the provision of a substrate (not shown) on which is deposited seed layer  11 . Typical materials for the latter include NiCr and Ta. The purpose of the seed layer is to provide an improved nucleating surface for antiferromagnetic layer  12  which is deposited next and which will serve as a pinning layer. Layer  12  can be MnPt, IrMn, NiMn, or similar material. The synthetic antiferromagnet, made up of layers  13 ,  14 , and  15  (which was discussed earlier) is now deposited and becomes the pinned layer. 
     Following deposition of the pinned layer, in a departure from the prior art, copper sub-layer  16   a  is deposited to a thickness between about 5 and 20 Angstroms, less then the full thickness of the spacer. Layer  16   a  is then exposed to oxygen in the manner already described above so that its surface becomes equivalent to layer  31  seen earlier as part of the free layer. 
     This is followed by the deposition of second copper sub-layer  16   b  on sub-layer  31  to complete formation of the spacer layer to a total thickness between about 6 and 21 Angstroms. 
     Next, in another departure from prior art practice, the CoFe free layer is deposited in three stages. The first of these is sub-layer  17   a  which is deposited onto copper spacer layer  16  to a thickness between about 5 and 15 Angstroms. Then, copper sub-layer  31  is deposited on CoFe sub-layer  17   a . The thickness of layer  31  (and other copper sub-layers that may be used later in the process) is between about 1 and 4 Angstroms. 
     Now follows a novel feature of the invention. Copper sub-layer  31  is exposed to oxygen. We illustrate this step in greater detail in  FIG. 2   a  where layer  31  is seen to have been deposited onto layer  17   a , with layer  21  representing the set of layers below  17   a . Exposure to oxygen is symbolized by arrow  24  and represents a flow rate of oxygen over layer  31  of between about 5 and 50 SCCM, with about 10 SCCM being preferred, for between about 5 and 60 seconds, with about 10 seconds being preferred. In our apparatus, this flow rate corresponds to an oxygen pressure of about 10 −4  torr. 
     Following the oxygen treatment of layer  31 , second CoFe layer  17   b  is deposited on copper sub-layer  31  to a thickness between about 7.5 and 12.5 Angstroms. This is illustrated in  FIG. 2   b.    
     Returning now to  FIG. 5 , second copper sub-layer  20  is deposited on CoFe layer  17   b , followed by the deposition thereon of third CoFe layer  17   c  (deposited to a thickness between about 0.5 and 7.5 Angstroms). No oxygen treatment was given to layer  20  as it s magnetostriction was already in the desired range. This completed the formation of the free layer. 
     Manufacture of the read head was now concluded with the deposition of contacting layer  18  followed by cap layer  19 . 
     2 nd  Embodiment 
     Referring now to  FIG. 3 , the process for this embodiment begins with the provision of a substrate (not shown) on which is deposited seed layer  11 . Typical materials for the latter include NiCr and Ta. The purpose of the seed layer is to provide an improved nucleating surface for antiferromagnetic layer  12  which is deposited next and which will serve as a pinning layer. Layer  12  can be MnPt, IrMn, NiMn, or similar material. The synthetic antiferromagnet, made up of layers  13 ,  14 , and  15  (which was discussed earlier) is now deposited and becomes the pinned layer. This is followed by the deposition of copper spacer layer  16 . 
     Next, in a departure from prior art practice, the CoFe free layer is deposited in three stages. The first of these is sub-layer  17   a  which is deposited onto copper spacer layer  16  to a thickness between about 5 and 15 Angstroms. Then, copper sub-layer  31  is deposited on CoFe sub-layer  17   a . The thickness of layer  31  (and other copper sub-layers that may be used later in the process) is between about 1 and 4 Angstroms. 
     Now follows a novel feature of the invention. Copper sub-layer  31  is exposed to oxygen. We illustrate this step in greater detail in  FIG. 2   a  where layer  31  is seen to have been deposited onto layer  17   a , with layer  21  representing the set of layers below  17   a . Exposure to oxygen is symbolized by arrow  24  and represents a flow rate of oxygen over layer  31  of between about 5 and 50 SCCM, with about 10 SCCM being preferred, for between about 5 and 60 seconds, with about 10 seconds being preferred. In our apparatus, this flow rate corresponds to an oxygen pressure of about 10 −4  torr. 
     Following the oxygen treatment of layer  31 , second CoFe layer  17   b  is deposited on copper sub-layer  31  to a thickness between about 7.5 and 12.5 Angstroms. This is illustrated in  FIG. 2   b.    
     Returning now to  FIG. 3 , second copper sub-layer  20  is deposited on CoFe layer  17   b , followed by the deposition thereon of third CoFe layer  17   c  (deposited to a thickness between about 0.5 and 7.5 Angstroms). No oxygen treatment was given to layer  20  as it s magnetostriction was already in the desired range. This completed the formation of the free layer. 
     Manufacture of the read head was now concluded with the deposition of contacting layer  18  followed by cap layer  19 . 
     3 rd  Embodiment 
     As seen in  FIG. 4 , this embodiment is similar to the second embodiment for all steps up to completion of the pinned layer. Formation of the spacer layer is, however, different from the prior art: 
     Following deposition of the pinned layer, copper sub-layer  16   a  is deposited to a thickness between about 5 and 20 Angstroms, less then the full thickness of the spacer. Layer  16   a  is then exposed to oxygen in the manner already described above so that its surface becomes equivalent to layer  31  seen earlier as part of the free layer. 
     This is followed by the deposition of second copper sub-layer  16   b  on sub-layer  31  to complete formation of the spacer layer to a total thickness between about 6 and 21 Angstroms. The remainder of the process of the second embodiment follows standard sub-processes—deposition of contacting layer  18  and cap layer  19 .

Technology Classification (CPC): 1